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UBC Theses and Dissertations
Study of the Renner effect in the linear XY2 molecule Carlone, Cosmo
Abstract
A variational principle is applied to the Schroedinger equation for theXY₂ linear molecule. Trial solutions are synthesized from the nuclear eigenstates, which are assumed to be simple harmonic oscillator eigenstates, and from the unperturbed electronic states, whose azimuthal dependence is known because of the cylindrical symmetry of the field of the nuclei. The secular equation is discussed, and an expression for the Renner splitting of the π state is obtained.
Item Metadata
| Title |
Study of the Renner effect in the linear XY2 molecule
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| Creator | |
| Publisher |
University of British Columbia
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| Date Issued |
1965
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| Description |
A variational principle is applied to the Schroedinger equation for theXY₂ linear molecule. Trial solutions are synthesized from the nuclear eigenstates, which are assumed to be simple harmonic oscillator eigenstates, and from the unperturbed electronic states, whose azimuthal dependence is
known because of the cylindrical symmetry of the field of the nuclei. The
secular equation is discussed, and an expression for the Renner splitting of the π state is obtained.
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| Genre | |
| Type | |
| Language |
eng
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| Date Available |
2011-10-14
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| Provider |
Vancouver : University of British Columbia Library
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| Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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| DOI |
10.14288/1.0302542
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| URI | |
| Degree | |
| Program | |
| Affiliation | |
| Degree Grantor |
University of British Columbia
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| Campus | |
| Scholarly Level |
Graduate
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| Aggregated Source Repository |
DSpace
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Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.