- Library Home /
- Search Collections /
- Open Collections /
- Browse Collections /
- UBC Theses and Dissertations /
- Microwave dielectric measurements on MEM(TCNQ)₂ and...
Open Collections
UBC Theses and Dissertations
UBC Theses and Dissertations
Microwave dielectric measurements on MEM(TCNQ)₂ and TTF-TCNQ Morrow, Michael Robert
Abstract
The microwave dielectric constant and conductivity of MEM(TCNQ)₂ were studied in the neighbourhood of the monomer to dimer transition at 61°C using cavity-perturbation techniques at 9 GHz. The conductivity was found to be in general agreement with four-probe d.c. results. Thus, doubts about the reliability of the d.c. measurements above the destructive transition have been removed.
The complex dielectric constant of TTF-TCNQ at liquid helium temperatures was studied using dielectric resonance techniques. Some anomalies regarding the interpretation of the dielectric resonance mode plots were resolved. Values for Є’ of (3.0±0.4)X10³ and for Є’of greater than 9 were implied by the results.
Finally, preliminary results and proposed directions for a bolometric absorption measurement in TTF-TCNQ in the microwave bands are presented. This technique may prove useful for the direct observation of the pinned charge density wave in TTF-TCNQ.
Item Metadata
| Title |
Microwave dielectric measurements on MEM(TCNQ)₂ and TTF-TCNQ
|
| Creator | |
| Publisher |
University of British Columbia
|
| Date Issued |
1979
|
| Description |
The microwave dielectric constant and conductivity of MEM(TCNQ)₂ were studied in the neighbourhood of the monomer to dimer transition at 61°C using cavity-perturbation techniques at 9 GHz. The conductivity was found to be in general agreement with four-probe d.c. results. Thus, doubts about the reliability of the d.c. measurements above the destructive transition have been removed.
The complex dielectric constant of TTF-TCNQ at liquid helium temperatures was studied using dielectric resonance techniques. Some anomalies regarding the interpretation of the dielectric resonance mode plots were resolved. Values for Є’ of (3.0±0.4)X10³ and for Є’of greater than 9 were implied by the results.
Finally, preliminary results and proposed directions for a bolometric absorption measurement in TTF-TCNQ in the microwave bands are presented. This technique may prove useful for the direct observation of the pinned charge density wave in TTF-TCNQ.
|
| Genre | |
| Type | |
| Language |
eng
|
| Date Available |
2010-03-19
|
| Provider |
Vancouver : University of British Columbia Library
|
| Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
|
| DOI |
10.14288/1.0085205
|
| URI | |
| Degree (Theses) | |
| Program (Theses) | |
| Affiliation | |
| Degree Grantor |
University of British Columbia
|
| Campus | |
| Scholarly Level |
Graduate
|
| Aggregated Source Repository |
DSpace
|
Item Media
Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.