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Study of lithium intercalation in titanium disulphide using time differential perturbed angular correlations Surono, Djoko
Abstract
Lithium intercalation into layered compound TiS₂ was studied using time-differential perturbed angular correlations (TDPAC). Fast electrochemical intercalation was performed to bring Li atoms into the host. The probe atoms ¹⁸¹ Hf registered two nuclear quadrupole interactions corresponding to the empty host TiS₂ with quadrupole frequency ⅴq₁=461(5) MHz and a high packing density LixTiS₂. (x≈l) compound with quadrupole frequency ⅴq₂=599(6) MHz. The contribution fractions of both interactions evolved as a function of charge transport, nF. The second intercalation becomes dominant at nF > 0.3. No evidence was found for intermediate x values.
Item Metadata
Title |
Study of lithium intercalation in titanium disulphide using time differential perturbed angular correlations
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Creator | |
Publisher |
University of British Columbia
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Date Issued |
1991
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Description |
Lithium intercalation into layered compound TiS₂ was studied using time-differential perturbed angular correlations (TDPAC). Fast electrochemical intercalation was performed to bring Li atoms into the host. The probe atoms ¹⁸¹ Hf registered two nuclear
quadrupole interactions corresponding to the empty host TiS₂ with quadrupole frequency ⅴq₁=461(5) MHz and a high packing density LixTiS₂. (x≈l) compound with quadrupole frequency ⅴq₂=599(6) MHz. The contribution fractions of both interactions evolved as a function of charge transport, nF. The second intercalation becomes dominant at nF > 0.3. No evidence was found for intermediate x values.
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Genre | |
Type | |
Language |
eng
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Date Available |
2010-12-13
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Provider |
Vancouver : University of British Columbia Library
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Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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DOI |
10.14288/1.0084965
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URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
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Campus | |
Scholarly Level |
Graduate
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Aggregated Source Repository |
DSpace
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Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.