- Library Home /
- Search Collections /
- Open Collections /
- Browse Collections /
- UBC Theses and Dissertations /
- A new reaction for coordinated dinitrogen
Open Collections
UBC Theses and Dissertations
UBC Theses and Dissertations
A new reaction for coordinated dinitrogen MacKay, Bruce Alexander
Abstract
The chemistry of the tantalum dinitrogen complex [NPN]Ta(μ-H)₂(μ-η¹:η²- N₂)Ta[NPN] (where [NPN] = (PhNSiMe₂CH₂)₂PPh) with main group hydride reagents is explored. The H-E bond of these reagents (E = B, Al, Si) undergoes addition across a Ta-N π bond, leading to formation of a new N-E bond and a new tantalum hydride. These complexes undergo spontaneous cleavage of the remaining N-N bond, coupled to reductive elimination of bridging hydride ligands as H₂. [the rest of the abstract can be found in the attached PDF file]
Item Metadata
| Title |
A new reaction for coordinated dinitrogen
|
| Creator | |
| Publisher |
University of British Columbia
|
| Date Issued |
2004
|
| Description |
The chemistry of the tantalum dinitrogen complex [NPN]Ta(μ-H)₂(μ-η¹:η²- N₂)Ta[NPN] (where [NPN] = (PhNSiMe₂CH₂)₂PPh) with main group hydride reagents is explored. The H-E bond of these reagents (E = B, Al, Si) undergoes addition across a Ta-N π bond, leading to formation of a new N-E bond and a new tantalum hydride. These complexes undergo spontaneous cleavage of the remaining N-N bond, coupled to reductive elimination of bridging hydride ligands as H₂. [the rest of the abstract can be found in the attached PDF file]
|
| Extent |
18381899 bytes
|
| Genre | |
| Type | |
| File Format |
application/pdf
|
| Language |
eng
|
| Date Available |
2009-11-30
|
| Provider |
Vancouver : University of British Columbia Library
|
| Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
|
| DOI |
10.14288/1.0061149
|
| URI | |
| Degree | |
| Program | |
| Affiliation | |
| Degree Grantor |
University of British Columbia
|
| Graduation Date |
2004-05
|
| Campus | |
| Scholarly Level |
Graduate
|
| Aggregated Source Repository |
DSpace
|
Item Media
Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.