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A new reaction for coordinated dinitrogen MacKay, Bruce Alexander
Abstract
The chemistry of the tantalum dinitrogen complex [NPN]Ta(μ-H)₂(μ-η¹:η²- N₂)Ta[NPN] (where [NPN] = (PhNSiMe₂CH₂)₂PPh) with main group hydride reagents is explored. The H-E bond of these reagents (E = B, Al, Si) undergoes addition across a Ta-N π bond, leading to formation of a new N-E bond and a new tantalum hydride. These complexes undergo spontaneous cleavage of the remaining N-N bond, coupled to reductive elimination of bridging hydride ligands as H₂. [the rest of the abstract can be found in the attached PDF file]
Item Metadata
| Title |
A new reaction for coordinated dinitrogen
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| Creator | |
| Publisher |
University of British Columbia
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| Date Issued |
2004
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| Description |
The chemistry of the tantalum dinitrogen complex [NPN]Ta(μ-H)₂(μ-η¹:η²- N₂)Ta[NPN] (where [NPN] = (PhNSiMe₂CH₂)₂PPh) with main group hydride reagents is explored. The H-E bond of these reagents (E = B, Al, Si) undergoes addition across a Ta-N π bond, leading to formation of a new N-E bond and a new tantalum hydride. These complexes undergo spontaneous cleavage of the remaining N-N bond, coupled to reductive elimination of bridging hydride ligands as H₂. [the rest of the abstract can be found in the attached PDF file]
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| Extent |
18381899 bytes
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| Genre | |
| Type | |
| File Format |
application/pdf
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| Language |
eng
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| Date Available |
2009-11-30
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| Provider |
Vancouver : University of British Columbia Library
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| Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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| DOI |
10.14288/1.0061149
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| URI | |
| Degree (Theses) | |
| Program (Theses) | |
| Affiliation | |
| Degree Grantor |
University of British Columbia
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| Graduation Date |
2004-05
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| Campus | |
| Scholarly Level |
Graduate
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| Aggregated Source Repository |
DSpace
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Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.