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UBC Theses and Dissertations
Molecular polarizations of some phosphonitrilic compounds Arsenault, Maureen A.
Abstract
A study of the dielectric properties of some phosphonitrilic fluorides, chlorides and chloride-fluorides in cyclohexane solutions was carried out and evidence was found to support the hypothesis that these compounds all have a non-negligible atom polarization caused by low frequency vibrations of the molecules. The distortion polarization of one of the geminally substituted isomers of the compound N₄P₄F₄Cl₄ was measured and this datum was used as support for assigning the 1,1,3,3-isomer structure to the compound.
Item Metadata
Title |
Molecular polarizations of some phosphonitrilic compounds
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Creator | |
Publisher |
University of British Columbia
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Date Issued |
1973
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Description |
A study of the dielectric properties of some phosphonitrilic
fluorides, chlorides and chloride-fluorides in cyclohexane solutions
was carried out and evidence was found to support the hypothesis
that these compounds all have a non-negligible atom polarization
caused by low frequency vibrations of the molecules. The distortion
polarization of one of the geminally substituted isomers of the
compound N₄P₄F₄Cl₄ was measured and this datum was used as support
for assigning the 1,1,3,3-isomer structure to the compound.
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Genre | |
Type | |
Language |
eng
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Date Available |
2011-03-23
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Provider |
Vancouver : University of British Columbia Library
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Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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DOI |
10.14288/1.0060113
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URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
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Campus | |
Scholarly Level |
Graduate
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Aggregated Source Repository |
DSpace
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Item Media
Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.