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Electron transfer from the hydroxide ion to a carbon-carbon triple bond Halliwell, Janet Elizabeth
Abstract
A one-electron transfer from the hydroxide ion to the electron acceptor p-nitrotolan was studied in aqueous dimethylsulfoxide by means of visible spectroscopy and electron spin resonance techniques. The possibility of initial nucleophilic attack followed by electron transfer from the carbanion so formed was eliminated. The analogous reaction of methoxide with p-nitrotolan was briefly examined.
Item Metadata
Title |
Electron transfer from the hydroxide ion to a carbon-carbon triple bond
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Creator | |
Publisher |
University of British Columbia
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Date Issued |
1970
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Description |
A one-electron transfer from the hydroxide ion to the electron acceptor p-nitrotolan was studied in aqueous dimethylsulfoxide by means of visible spectroscopy and electron spin resonance techniques. The possibility of initial nucleophilic attack followed by electron transfer from the carbanion so formed was eliminated. The analogous reaction of methoxide with p-nitrotolan was briefly examined.
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Genre | |
Type | |
Language |
eng
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Date Available |
2011-05-20
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Provider |
Vancouver : University of British Columbia Library
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Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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DOI |
10.14288/1.0059942
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URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
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Campus | |
Scholarly Level |
Graduate
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Aggregated Source Repository |
DSpace
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Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.