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Mossbauer investigation of Fe 57 in Linde L Zeolite Wedd, Robert William James
Abstract
Two independent Fe³⁺ species have been simultaneously introduced into Linde L zeolite. One is an exchanged Fe³⁺ species while the other is the molecular species FeCI₃, By simpIe outgassing at 573°K, the exchanged Fe³⁺ is reduced to Fe²⁺. By sweeping the system at 523°K with H₂, both species are converted to ferrous and, at 573°K, the exchanged species is reduced to Feº and the FeCI₃ is reduced to FeCI₂. Outgassing the latter system at 573°K oxidizes the Feº to Fe₂O₃ while the FeCI₂ remains intact. These valency changes were examined using Mössbauer Spectroscopy and, using this technique, a Morin transition appears to have been detected in the Feº species.
Item Metadata
Title |
Mossbauer investigation of Fe 57 in Linde L Zeolite
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Creator | |
Publisher |
University of British Columbia
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Date Issued |
1969
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Description |
Two independent Fe³⁺ species have been simultaneously introduced into Linde L zeolite. One is an exchanged Fe³⁺ species while the other
is the molecular species FeCI₃, By simpIe outgassing at 573°K, the
exchanged Fe³⁺ is reduced to Fe²⁺. By sweeping the system at 523°K with
H₂, both species are converted to ferrous and, at 573°K, the exchanged species is reduced to Feº and the FeCI₃ is reduced to FeCI₂. Outgassing the latter system at 573°K oxidizes the Feº to Fe₂O₃ while the FeCI₂ remains intact. These valency changes were examined using Mössbauer Spectroscopy and, using this technique, a Morin transition appears to have been detected in the Feº species.
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Genre | |
Type | |
Language |
eng
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Date Available |
2011-06-07
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Provider |
Vancouver : University of British Columbia Library
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Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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DOI |
10.14288/1.0059877
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URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
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Campus | |
Scholarly Level |
Graduate
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Aggregated Source Repository |
DSpace
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Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.