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UBC Theses and Dissertations
Synthesis and reactivity of macrocyclic β-keto lactones Sharadendu, Anurag
Abstract
As a part of a continuing study of the chemistry and conformational behaviour of macrocyclic β-keto lactones, 3-oxo-13-tetradecanolide (74) and 3-oxo-15-hexadecanolide (84) were synthesized via intra- and intermolecular alcoholysis of hydroxy Meldrum's acid derivatives. A number of 14- and 16-membered lactones, derived from 74 and 84 were used to investigate a series of alkylation and reduction reactions. [more abstract available in pdf]
Item Metadata
Title |
Synthesis and reactivity of macrocyclic β-keto lactones
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Creator | |
Publisher |
University of British Columbia
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Date Issued |
1996
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Description |
As a part of a continuing study of the chemistry and conformational behaviour of
macrocyclic β-keto lactones, 3-oxo-13-tetradecanolide (74) and 3-oxo-15-hexadecanolide (84) were synthesized via intra- and intermolecular
alcoholysis of hydroxy Meldrum's acid derivatives. A number of 14- and
16-membered lactones, derived from 74 and 84 were used to investigate a
series of alkylation and reduction reactions.
[more abstract available in pdf]
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Extent |
7314188 bytes
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Genre | |
Type | |
File Format |
application/pdf
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Language |
eng
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Date Available |
2009-02-18
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Provider |
Vancouver : University of British Columbia Library
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Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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DOI |
10.14288/1.0059553
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URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
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Graduation Date |
1996-05
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Campus | |
Scholarly Level |
Graduate
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Aggregated Source Repository |
DSpace
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Item Media
Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.