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UBC Theses and Dissertations

O₂-oxidations catalyzed by trans-dioxoporphyrinatoruthenium(VI) species Cheng, Stephen Yau Sang


Some trans-Ru[sup VI](porp)(0)2 complexes [porp = TMP (1), TDCPP (2), TDCPP-Cl₈ (3)] were synthesized and used to oxidize, both stoichiometrically and (in the presence of air/O₂) catalytically, a variety of organic compounds in benzene under relatively mild conditions. [Chemical Compound Diagram followed by complex abstract. See pp. 3-6 of the accompanying pdf].

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