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UBC Theses and Dissertations

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UBC Theses and Dissertations

Conjugated schiff base-type metal-containing polymers Leung, Alfred Chi Wook

Abstract

The work in this thesis describes the synthesis and characterization of a series of conjugated polymers containing Schiff base transition metal complexes. High molecular weight poly(salphenyleneethynylene)s (PSPEs) were synthesized using the Sonogashira-Hagihara protocol and they were characterized using nuclear magnetic resonance spectroscopy and gel permeation chromatography. Their optical properties were investigated by UV-vis and fluorescence spectroscopies. PSPEs containing Zn saiphen moieties were found to exhibit strong aggregation that is facilitated by the presence of Zn to O interactions, and it was discovered that the polymers interact with various Lewis bases to undergo aggregation and deaggregation. New ladder-type conjugated polymers, as well as a series of model compounds that are representative of the repeating units of the polymers, were synthesized using Schiff base condensation methods. The electronic and magnetic properties of these ladder-polymers were studied using cyclic voltammetry, electron paramagnetic resonance spectroscopy, and magnetic susceptibility measurements.

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Attribution-NonCommercial-NoDerivatives 4.0 International