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Kozakevich, Jordan Roger; Sediako, Dimitry; Weiss, David; Vogel, Sven C.

Multidisciplinary Digital Publishing Institute

As the issue of climate change becomes more prevalent, engineers have focused on developing lightweight Al alloys capable of increasing the power density of powertrains. The characterization of these alloys has been focused on mechanical properties and less on the fundamental response of microstructures to achieve these properties. Therefore, this study assesses the quality of the microstructure of two high-temperature Al alloys (A356 + 3.5RE and Al-8Ce-10Mg), comparing them to T6 A356. These alloys underwent thermal conditioning at 250 and 300 °C for 200 h. Time-of-flight neutron diffraction experiments were performed before and after conditioning. The phase evolution was quantified using Rietveld refinement. It was found that the Si phase grows significantly (13–24%) in T6 A356, A356 + 3.5RE, and T6 A356 + 3.5RE alloys, which is typically correlated with a reduction in mechanical properties. Subjecting the A356 3.5RE alloy to a T6 heat treatment stabilizes the orthorhombic Al₄Ce₃Si₆ and monoclinic β-Al₅FeSi phases, making them resistant to thermal conditioning. These two phases are known for enhancing mechanical properties. Additionally, the T6 treatment reduced the vol.% of the cubic Al₂₀CeTi₂ and hexagonal Π-Al₉FeSi₃Mg₅ phases by 13% and 23%, respectively. These phases have detrimental mechanical properties. The Al-8Ce-10Mg alloy cubic β-Al₃Mg₂ phase showed significant growth (82–101%) in response to conditioning, while the orthorhombic Al₁₁Ce₃ phase remained stable. The growth of the beta phase is known to decrease the mechanical properties of this alloy. These efforts give valuable insight into how these alloys will perform and evolve in demanding high-temperature environments.

Article

eng

Vancouver : University of British Columbia Library

10.14288/1.0445427

Applied Science, Faculty of; Non UBC; Engineering, School of (Okanagan)

10.3390/ma17174311

Faculty; Researcher

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