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The Origins of the Hydrogen Sulphide (H₂S) Gas in the Triassic Montney Formation, British Columbia, Canada

Multidisciplinary Digital Publishing Institute

The inexplicable distribution of souring wells (presence of H₂S gas) of the unconventional Montney Formation hydrocarbon resource (British Columbia; BC) is investigated by analysing sulphur and oxygen isotopes, coupled with XRD mineralogy, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDX). The sulphur isotopic analysis indicates that the sulphur isotopic range for Triassic anhydrite (δ³⁴S 8.9 to 20.98‰ VCDT) is the same as the H₂S sulphur that is produced from the Montney Formation (δ³⁴S 9.3 to 20.9‰ VCDT). The anhydrite in the Triassic rocks is the likely source of the sulphur in the H₂S produced in the Montney Formation. The deeper Devonian sources are enriched in ³⁴S and are not the likely source for sulphur (δ³⁴S 17.1 and 34‰ VCDT). This is contradictory to studies on Montney Formation producers in Alberta, with heavier (³⁴S-enriched) sulphur isotopic signatures in H₂S gas of all souring Montney Formation producers. These studies conclude that deep-seated faults and fractures have provided conduits for sulphate and/or H₂S gas to migrate from deeper sulphur sources in the Devonian strata. There are several wells that show a slightly heavier (³⁴S-enriched) isotopic signature (δ³⁴S 18 to 20‰ VCDT) within the Montney Formation H₂S gas producing within close proximity to the deformation front. This variation may be due to such deep-seated faults that acted as a conduit for Devonian sulphur to migrate into the Montney Formation. Our geological model suggests the sulphate-rich fluids have migrated from the Charlie Lake Formation prior to hydrocarbon generation in the Montney Formation (BC). Sulphate has concentrated in discrete zones due to precipitation in conduits like fracture and fault systems. The model fits the observation of multi-well pads containing both sour- and sweet-producing wells indicating that the souring is occurring in very narrow and discrete zones with the Montney Formation (BC). Government agencies and operators in British Columbia should map the anhydrite-rich portions of the Charlie Lake Formation, together with the structural elements from three-dimensional seismic to reduce the risk of encountering unexpected souring.

Article

eng

Vancouver : University of British Columbia Library

10.14288/1.0445398

Science, Faculty of; Non UBC; Earth, Ocean and Atmospheric Sciences, Department of

10.3390/geosciences14080224

Faculty; Researcher

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