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Synthesis and characterization of EDOT-based conducting polymer actuators Vandesteeg, Nathan A.; Madden, P.G.; Madden, John D.; Anquetil, Patrick A.; Hunter, Ian W.
Abstract
Freestanding films of poly(3,4-ethylenedioxythiopene), PEDOT, were synthesized electrochemically from a solution containing EDOT monomer, tetrabutylammonium hexafluorophosphate, and water in propylene carbonate. The films were tested mechanically under constant stresses ranging from 0.6 to 2.1 MPa and subjected to various electrochemical waveforms while immersed in a bath containing propylene carbonate and an electrolyte. The characterization resulted in observations of ultimate linear strains of 2%, strain rates of 0.003 Hz, and strain to charge densities of 4 x 10-10 m3/C, comparable to the conventional conducting polymer polypyrrole. In addition to the quantitative analysis, evidence of both anionic and cationic intercalation into the polymer is presented with a discussion of prospective mechanisms and consequences. Copyright 2003 Society of Photo-Optical Instrumentation Engineers. One print or electronic copy may be made for personal use only. Systematic reproduction and distribution, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper are prohibited.
Item Metadata
Title |
Synthesis and characterization of EDOT-based conducting polymer actuators
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Creator | |
Publisher |
Society of Photo-Optical Instrumentation Engineers (SPIE)
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Date Issued |
2003
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Description |
Freestanding films of poly(3,4-ethylenedioxythiopene), PEDOT, were synthesized electrochemically from a solution containing EDOT monomer, tetrabutylammonium
hexafluorophosphate, and water in propylene carbonate. The films were tested mechanically under constant stresses ranging from 0.6 to 2.1 MPa and subjected to
various electrochemical waveforms while immersed in a bath containing propylene carbonate and an electrolyte. The characterization resulted in observations of
ultimate linear strains of 2%, strain rates of 0.003 Hz, and strain to charge densities of 4 x 10-10 m3/C, comparable to the conventional conducting polymer
polypyrrole. In addition to the quantitative analysis, evidence of both anionic and cationic intercalation into the polymer is presented with a discussion of
prospective mechanisms and consequences.
Copyright 2003 Society of Photo-Optical Instrumentation Engineers.
One print or electronic copy may be made for personal use only. Systematic reproduction and distribution,
duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper are prohibited.
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Genre | |
Type | |
Language |
eng
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Date Available |
2011-06-01
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Provider |
Vancouver : University of British Columbia Library
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Rights |
Attribution-NonCommercial-NoDerivatives 4.0 International
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DOI |
10.14288/1.0107530
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URI | |
Affiliation | |
Citation |
Vandesteeg, Nathan A.; Madden, Peter .G. A.; Madden, John D.; Anquetil, Patrick A.; Hunter, Iian W. Synthesis and characterization of EDOT-based conducting polymer actuators. Smart Structures and Materials 2003: Electroactive Polymer Actuators and Devices (EAPAD), edited by Yoseph Bar-Cohen, Proceedings of SPIE Volume 5051, 349-356, 2003.
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Publisher DOI |
10.1117/12.484418
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Peer Review Status |
Reviewed
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Scholarly Level |
Faculty
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Copyright Holder |
Madden, John D.
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Rights URI | |
Aggregated Source Repository |
DSpace
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Item Media
Item Citations and Data
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International