Science, Faculty of
Earth, Ocean and Atmospheric Sciences, Department of
DSpace
UBCV
Cayer, Erika Mary
Master of Science - MSc
University of British Columbia
Many diamondiferous kimberlites in the Lac de Gras region of the Northwest Territories are concealed by several metres of glacial drift and are therefore challenging to detect by traditional exploration techniques. Soil samples were collected in a 50x60 metre grid crossing the DO-18 kimberlite (Peregrine Diamonds Ltd.), concealed by 5-20 metres of glacial sediments, to evaluate the potential of surface geochemical target discrimination techniques to detect the presence of a kimberlite through cover. Physicochemical measurements were recorded at each sample site, and soil samples were analysed by ICP-MS following 4-Acid, Aqua Regia and De-Ionized Water digestions, as well as field portable X-Ray Fluorescence (fp-XRF), spatiotemporal geochemical hydrocarbons (SGH), and select samples by X-Ray Diffraction (XRD) and Sequential Leach. AGI Inc. Goresorber™ Hydrocarbon Collectors were also installed at each site. Surficial material, soil type, topographic variation and vegetation were mapped to give insight to the influences of geomorphological processes on geochemistry. An east-west trending slope break divides the research site into a topographically high region in the north, and a low-lying region in the south. The north consists of till, and the south comprises till, organics and glaciofluvial and glaciolacustrine sediments. 4-Acid and Aqua Regia digestion data display a dispersal of Cr, Mg, Nb, and Ni from directly above the kimberlite in the north, to the edge of the sampling grid, in the down-ice direction. Fp-XRF data exhibits a similar distribution in all elements except Mg, as does SGH data in light benzenes. Ni and Mg concentrations in the kimberlite demonstrate that it is the source of the geochemical anomalies. Glacial transport is hypothesized to have generated the geochemical anomalies, and glaciolacustrine and glaciofluvial processes are considered to have generated the lower topography and diluted the geochemical responses in the south.
THE DEVELOPMENT OF SURFACE GEOCHEMICAL TECHNOLOGIES FOR THE DETECTION OF KIMBERLITES CONCEALED BY GLACIAL DRIFT IN THE NORTHWEST TERRITORIES, CANADA. By Erika Mary Cayer B.Sc., The University of Western Ontario, 2014 A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE in THE FACULTY OF GRADUATE AND POSTDOCTORAL STUDIES (Geological Sciences) THE UNIVERSITY OF BRITISH COLUMBIA (Vancouver) October 2017 © Erika Mary Cayer, 2017 ii Abstract Many diamondiferous kimberlites in the Lac de Gras region of the Northwest Territories are concealed by several metres of glacial drift and are therefore challenging to detect by traditional exploration techniques. Soil samples were collected in a 50x60 metre grid crossing the DO-18 kimberlite (Peregrine Diamonds Ltd.), concealed by 5-20 metres of glacial sediments, to evaluate the potential of surface geochemical target discrimination techniques to detect the presence of a kimberlite through cover. Physicochemical measurements were recorded at each sample site, and soil samples were analysed by ICP-MS following 4-Acid, Aqua Regia and De-Ionized Water digestions, as well as field portable X-Ray Fluorescence (fp-XRF), spatiotemporal geochemical hydrocarbons (SGH), and select samples by X-Ray Diffraction (XRD) and Sequential Leach. AGI Inc. Goresorber™ Hydrocarbon Collectors were also installed at each site. Surficial material, soil type, topographic variation and vegetation were mapped to give insight to the influences of geomorphological processes on geochemistry. An east-west trending slope break divides the research site into a topographically high region in the north, and a low-lying region in the south. The north consists of till, and the south comprises till, organics and glaciofluvial and glaciolacustrine sediments. 4-Acid and Aqua Regia digestion data display a dispersal of Cr, Mg, Nb, and Ni from directly above the kimberlite in the north, to the edge of the sampling grid, in the down-ice direction. Fp-XRF data exhibits a similar distribution in all elements except Mg, as does SGH data in light benzenes. Ni and Mg concentrations in the kimberlite demonstrate that it is the source of the geochemical anomalies. Glacial transport is hypothesized to have generated the geochemical anomalies, and glaciolacustrine and glaciofluvial processes are considered to have generated the lower topography and diluted the geochemical responses in the south. iii Lay Summary Kimberlites are among the most common host rocks for diamond deposits. Many kimberlites are located in the Northwest Territories, Canada, in the Lac de Gras kimberlite cluster. These kimberlites are commonly covered by sediments deposited directly by glaciers, or till. This research concludes that due to the unique chemistry of kimberlites in comparison to their host rocks, kimberlitic material entrained in till can be detected by strong digestions of soil samples collected above till. The detection of kimberlitic material, when combined with knowledge of the most prevalent glacial movement direction, can be traced up-ice to its source, thus locating a potential diamond deposit. iv Preface The author and supervisor, Dr. Peter Winterburn, are responsible for project design and identification of research objectives. Dr. Maya Kopylova, Dr. Derek Turner, and Dr. Craig Hart are credited for providing input at committee meetings and through independent correspondence. The author is accountable for the collection of each of the soil samples, spontaneous potential (SP) data, physicochemical data, and surficial data used to generate surficial material and vegetation maps and models of geomorphological processes. The author is also responsible for installation of AGI Inc. Goresorber™ Hydrocarbon Collectors, and the selection of samples for Sequential Leach and XRD analyses, and the completion of the XRD and petrographic analyses. Soil samples were analysed at ALS Minerals (ALS) in North Vancouver by 4-Acid, Aqua Regia, De-Ionized Water, and on the selected samples, Sequential Leach. Lithogeochemical analysis was also conducted at ALS, on three kimberlite drill core samples selected and lent to the project by Peregrine Diamonds Ltd., and one clay sample donated by the Northwest Territories Geological Survey. SGH analysis was conducted by Activation Laboratories (ActLabs) in Ancaster, Ontario. Hydrocarbon analysis from Goresorber™ Hydrocarbon Collectors was completed by AGI. Inc. in the U.S.A. Thin sections for petrgraphic analysis of core samples were prepared by Vancouver Petrographics Ltd. in Langley. The author is responsible for interpretation of data from each analysis, under the supervision of Dr. Peter Winterburn. Interpretations of both SGH and Goresorber™ Hydrocarbon Collectors were provided by ActLabs and AGI. Inc., respectively; however, the author’s independent interpretations of these data sets are also included in this study. v Table of Contents Abstract .......................................................................................................................................... ii Lay Summary ............................................................................................................................... iii Preface ........................................................................................................................................... iv Table of Contents ...........................................................................................................................v List of Tables ..................................................................................................................................x List of Figures ............................................................................................................................. xiii Acknowledgements .................................................................................................................. xxiv Chapter 1: Introduction ................................................................................................................1 1.1 Project Rationale ............................................................................................................. 1 1.2 Objectives ....................................................................................................................... 1 1.3 Thesis Structure .............................................................................................................. 2 1.4 Kimberlite Mineralogy and Geochemistry ..................................................................... 4 1.5 Kimberlite Weathering, Glacial Transport, Frost Heave and Element Migration .......... 9 1.5.1 Kimberlite Weathering................................................................................................ 9 1.5.2 Glacial Transport and Frost Heave ........................................................................... 10 1.5.3 Element Migration .................................................................................................... 12 1.6 Current Exploration Techniques for Kimberlites in Glaciated Terrain ........................ 17 1.7 Summary ....................................................................................................................... 20 Chapter 2: Geologic Overview ....................................................................................................22 2.1 Geology and Tectonic Evolution of the Slave Province ............................................... 22 2.2 Geology of the DO-18 Kimberlite ................................................................................ 28 vi 2.3 Discovery History of the Tli Kwi Cho Kimberlite Complex ........................................ 34 2.4 Glacial History of the DO-18 Region ........................................................................... 35 2.5 Summary ....................................................................................................................... 37 Chapter 3: Methodology..............................................................................................................39 3.1 Sampling Program Design ............................................................................................ 40 3.1.1 Global Positioning System (GPS) Navigation .......................................................... 41 3.2 Soil Sample Collection ................................................................................................. 41 3.2.1 Environmental Considerations .................................................................................. 41 3.2.2 Anthropogenic Considerations.................................................................................. 42 3.3 Surficial Field Data ....................................................................................................... 42 3.4 Soil Geochemical Analyses .......................................................................................... 43 3.4.1 Inorganic Geochemistry ............................................................................................ 43 3.4.2 Organic Geochemistry .............................................................................................. 44 3.5 Spontaneous Potential ................................................................................................... 45 3.6 Lithogeochemistry of the DO-18 Kimberlite ................................................................ 45 3.7 Petrography of the DO-18 Kimberlite .......................................................................... 46 3.8 X-Ray Diffraction Analysis .......................................................................................... 46 3.9 Quality Assurance/Quality Control............................................................................... 46 3.9.1 Soil Sampling ............................................................................................................ 46 3.9.2 Surficial Field Data ................................................................................................... 47 3.9.3 Inorganic Geochemistry ............................................................................................ 47 3.9.4 Organic Geochemistry .............................................................................................. 47 3.9.5 SP Survey .................................................................................................................. 48 vii Chapter 4: Physiography, Surface Geology, Soil and Environment .......................................49 4.1 Physiography of the DO-18 Field Site .......................................................................... 49 4.2 Surficial Geology .......................................................................................................... 52 4.3 Soil Classification ......................................................................................................... 56 4.4 Vegetation ..................................................................................................................... 63 4.5 Summary ....................................................................................................................... 65 Chapter 5: Results........................................................................................................................66 5.1 DO-18 Lithogeochemistry ............................................................................................ 66 5.2 Petrography ................................................................................................................... 70 5.3 Inorganic Geochemistry ................................................................................................ 71 5.3.1 4-Acid Digestion ICP-MS Analysis.......................................................................... 71 5.3.1.1 Quality Control ................................................................................................. 71 5.3.1.2 4-Acid Digestion ICP-MS Rationale ................................................................ 73 5.3.1.3 4-Acid Digestion ICP-MS Results .................................................................... 74 5.3.2 Aqua Regia ICP-MS Analysis .................................................................................. 79 5.3.2.1 Aqua Regia ICP-MS Rationale ......................................................................... 79 5.3.2.2 Aqua Regia ICP-MS Results ............................................................................ 79 5.3.3 De-Ionized Water ICP-MS Analysis ........................................................................ 83 5.3.3.1 De-Ionized Water ICP-MS Rationale ............................................................... 83 5.3.3.2 De-Ionized Water ICP-MS Results ................................................................... 83 5.3.4 Field Portable X-Ray Fluorescence (fp-XRF; Soil Mode) ....................................... 87 5.3.4.1 Fp-XRF Rationale ............................................................................................. 87 5.3.4.2 Fp-XRF (Soil Mode) Results ............................................................................ 88 viii 5.3.5 Sequential Leach Analysis ........................................................................................ 92 5.3.5.1 Sequential Leach Rationale............................................................................... 92 5.3.5.2 Sequential Leach Results .................................................................................. 93 5.3.6 X-Ray Diffraction Results ........................................................................................ 96 5.3.7 Discussion of Inorganic Geochemical Results ......................................................... 97 5.4 Organic Geochemistry ................................................................................................ 102 5.4.1 Total Organic Carbon (Corg).................................................................................... 102 5.4.2 Spatiotemporal Geochemical Hydrocarbons (SGH) ............................................... 103 5.4.2.1 Quality Control ............................................................................................... 103 5.4.2.2 Background ..................................................................................................... 104 5.4.2.3 Spatiotemporal Geochemical Hydrocarbon Results ....................................... 105 5.4.3 Amplified Geochemical Imaging Inc. Goresorber™ Hydrocarbon Collectors ...... 109 5.4.4 Discussion of Organic Geochemistry Results......................................................... 110 5.4.4.1 Total Organic Carbon ..................................................................................... 110 5.4.4.2 Spatiotemporal Geochemical Hydrocarbons .................................................. 111 5.4.4.3 AGI Inc. Goresorber™ Hydrocarbon Collectors ............................................ 112 5.5 Physicochemical Measurements ................................................................................. 113 5.5.1 Quality Control ....................................................................................................... 113 5.5.2 Physicochemical Results ......................................................................................... 114 5.6 Spontaneous Potential (SP) Results ............................................................................ 124 5.7 Discussion of Surficial Data and SP ........................................................................... 126 5.8 Summary ..................................................................................................................... 128 Chapter 6: Discussions ..............................................................................................................129 ix 6.1 Mineralogical Controls on Minor and Trace Element Geochemistry ......................... 129 6.2 Organic Geochemical Controls on Trace Element Geochemistry .............................. 136 6.2.1 Total Organic Carbon ............................................................................................. 136 6.2.2 Spatiotemporal Geochemical Hydrocarbons (SGH) ............................................... 137 6.3 Influence of Geomorphological Processes on Geochemistry ..................................... 139 6.4 Summary ..................................................................................................................... 147 Chapter 7: Exploration Implications .......................................................................................148 7.1 Surficial Materials and Glacial Flow Direction Mapping........................................... 148 7.2 Sampling Program Design .......................................................................................... 148 7.3 Soil Sample Analysis .................................................................................................. 149 7.4 Data Interpretation ...................................................................................................... 150 Chapter 8: Conclusions and Recommendations for Future Work .......................................152 8.1 Recommendations for Future Work............................................................................ 154 References ...................................................................................................................................155 Appendix A: Methodologies ......................................................................................................171 Appendix B: Quality Assurance/Quality Control (QA/QC) ..................................................196 Appendix C: Raw Surficial Data ..............................................................................................239 Appendix D: Raw Geochemical Data .......................................................................................312 Appendix E: Data Interpretation from Activation Laboratories and AGI. Inc. .................605 x List of Tables Table 1.1. Minerals typically present in Group I kimberlites, and those which preclude kimberlites (Modified after Mitchell, 1995). .................................................................................. 5 Table 1.2. Average major and trace element abundances in Group I kimberlites. Major element data from Dawson (1967), compatible element data from Mitchell (1986), HFSE data is averaged from data cited in Mitchell (1995) from South African kimberlite from Smith et al. (1985), Zaire Kimberlites from Kampata (1993), and Kimberley Group Kimberlites from Clement (1982) and Mitchell (1995). REE data from Maramatsu (1983). ...................................................................... 8 Table 1.3. Common weathering products of primary kimberlite minerals (Wilson, 2004; Bosch, 1971; Mitchell, 1986; Mitchell, 1995). ......................................................................................... 10 Table 4.1. Descriptions of common Brunisolic Eutric Turbic Cryosol (BE.TC) and Histic Eutric Static Cryosol (HE.SC) soil horizons. Of and Om horizons are categorized as organic horizons, containing greater than 17% organic carbon or 30% organic matter by weight. Ah, Ae, Bm, BCy, Cg, Cgy and Cz horizons are mineral horizons, which contain less than 17% organic carbon or 30% organic matter by weight (after Soil Classification Working Group, 1998). ....................... 61 Table 4.2. Variation of soil horizons within the DO-18 research site. % Occurrence refers to the percentage of soil pits in which a horizon was observed within the research site. Median thickness of the Bm horizon was only recorded when the base was observed (i.e. a C horizon was present). Occasionally, multiple Om horizons were encountered; % Occurrence of Om (one horizon only) does not include any holes containing multiple Om horizons. Median depth to horizon remains constant for both cases as this is the median depth at which the first Om horizon was recorded. ................................................................................................................................ 62 xi Table 5.1. Lithogeochemistry of the DO-18 Kimberlite, from samples: K2P-0018b, K2P-0027b, K2P-0067 (Peregrine Diamonds Ltd.); and NGO-RC15-061-13a, (Northwest Territories Geological Survey). Elements shown are kimberlite pathfinder elements as defined by McClenaghan and Kjarsgaard (2001) and Sader (2011). The DO-18 kimberlite chemistry of the drill core samples is compared to the average kimberlite composition and the average composition of the Contwoyto and Yamba granitic plutonic suites to show the contrast between the kimberlite geochemistry and its host rocks. Sample NGO-RC15-061-13a is not included in the sample concentration average as it is highly contaminated. Elements in bold (Cr, MgO, Nb and Ni) denote elements in the samples and average kimberlite concentration which are at least one order of magnitude greater than their granitic suite counterparts. ......................................... 68 Table 5.2. Concentrations of oxides used to calculate the contamination index (CI) of each of the kimberlite samples, as per Clement (1982). Values are given in %, with the exception of CI, which is unitless. ........................................................................................................................... 69 Table 5.3. Response ratios for 4-Acid ICP-MS results of Cr, Mg, Nb, and Ni. ........................... 75 Table 5.4. Response ratios for Aqua Regia ICP-MS results of Cr, Mg, Nb, and Ni. ................... 80 Table 5.5. Response ratios for Deionized Water ICP-MS results for Ce, K, Nb, and Y. ............. 84 Table 5.6. Calculated detection limits for calibrated trace elements in Soil Mode. ..................... 88 Table 5.7. Response ratios for fp-XRF results of Cr, Nb, Ni, and Zn. ......................................... 89 Table 5.8. ALS Laboratories sequential leach methods in order of increasing strength (Hall et al., 1996; Seneshen, 1997; Hall, 1998). .............................................................................................. 92 Table 5.9. Justification for samples submitted for sequential leach analysis. .............................. 94 Table 5.10. Response ratios for SGH results of the light benzene compounds C003, C005, C008, C009, and C012. ......................................................................................................................... 105 xii Table 5.11. Compounds which detected the kimberlite and their degree of detection. All compound classes were considered, and light benzenes were the only designated kimberlite pathfinder class by ActLabs to successfully detect the kimberlite. Light alkanes, light branched alkanes and light aromatics also detected DO-18 in this study. ................................................. 106 Table 6.1. Primary mineral hosts for Cr, Mg, Nb, and Ni (given in bold) within the DO-18 kimberlite, based on observed mineralogy (Chapter 2; Section 6.3; Mitchell, 1986; Muggeridge, 1995; De Hoog et al., 2010). ....................................................................................................... 129 xiii List of Figures Figure 1.1. Morphology of a dispersal train of indicator minerals from a buried kimberlite, as well as techniques which may be used to detect the kimberlite (modified after McClenaghan and Kjarsgaard, 2007). ......................................................................................................................... 11 Figure 2.1. Simplified geologic map of the Slave province (modified after Davis et al. 1994), after Hoffman (1989). ................................................................................................................... 23 Figure 2.2. Location of the DO-18 and DO-27 Kimberlite (modified after Harder et al., 2009). Coordinates given in UTM NAD83 Zone 12N............................................................................. 29 Figure 2.3. Local geologic map of the study area. Modified from geologic map of the Slave craton compiled by Hoffman and Hall (1993), from Open File 2559, Geological Survey of Canada. Coordinates given in UTM NAD83 Zone 12N............................................................... 30 Figure 2.4. Cross sections of the DO-18 kimberlite showing the distribution of KIMB-1 and KIMB-2 units. Both OTHER-K and RFW units are classified as RVK, however, they are not discussed in this section (modified after Harder et al., 2008). ...................................................... 32 Figure 2.5. a) and b) DIGHEM Interpolated I[Bz] and R[Bz] components, respectively, at 900 Hz collected from the coplanar orientation. c) shows interpolated AeroTEM data, d) shows interpolated VTEM data (modified after Fournier et al., 2014). Kimberlites are delineated well, and surveys reveal no major structural features. ........................................................................... 35 Figure 2.6. Evolution of ice movement directions in the Lac de Gras region (modified after Dredge et al., 1994). The star marks the location of the research site. ......................................... 37 Figure 3.1. Planned sample points above the DO-18 kimberlite. Sampling grid was planned parallel to ice movement direction. ............................................................................................... 39 xiv Figure 3.2. Soil sample and AGI Gore Module installation sites in the DO-18 research area. Note that AGI Inc. GoreSorberTM hydrocarbon collectors were also installed at soil sample sites. ..... 40 Figure 4.1. Aerial photo (0.95 m/pixel resolution, multiband) of the project study site. Slope break separates higher topography in the northern region from the low-lying region in the south. Red outline delineates the research site boundary. Photo courtesy of Peregrine Diamonds Ltd. Arrows indicate viewpoints of photos in Figure 4.2. DO-27 is located south of the image. ........ 50 Figure 4.2. a) Photo taken from a helicopter above the field site looking directly south. Slope break is visible and delineated by the dashed yellow line. Approximate size and location of DO-18 and DO-27 kimberlites are shown. Tli Kwi Cho Lake is visible above DO-27. The river in the southwest of the study area and the two small ponds south of the slope break are visible in the background. b) Photo taken from a helicopter looking directly west. The slope break is delineated by a yellow dashed line. The southeast flowing river in the southwest corner of the field site is visible in the background, as is the beaded drainage in the southeastern quadrant. Cryoturbation, patterned ground and frost boils are common north of the slope break and east of the area with beaded drainage. ...................................................................................................... 51 Figure 4.3. Distribution of sediment types at the typical sample depth (approximately 5-35 cm), mapped by sampled sediment type. Regions where organic deposits and permafrost conceal underlying materials are mapped as organics. Note that in some cases thin sediments of a different type overly the mapped sediment at sampling depth. .................................................... 52 Figure 4.4. Distribution of surficial materials. Map legend follows the Geological Survey of Canada (GSC) Geologic Symbol Standard Style File – Surficial Symbols; from GSC Open File 8041 (Cocking et al., 2016), Surficial Database model v. 2.2, current as of February 1, 2016. xv Note that GLv is mapped as clay in Figure 4.3 only near its northern boundary because of its limited thickness in this area. Samples in this area were taken from the Tb, below the GLv. ..... 53 Figure 4.5. Organic deposits at the DO-18 research site. ‘Thick’ organic deposits are thicker than one absolute deviation from the median Om horizon thickness (Table 4.2), in this case, 5.5 cm. Sites with multiple Om horizons (representing various cycles of moss mat growth) are also given this classification as they are invariably thicker than 5.5 cm. Conversely, ‘thin’ organics are thinner than 5.5 cm. ...................................................................................................................... 55 Figure 4.6. Distribution of Brunisolic Eutric Turbic Cryosols (BE.TC) and Histic Eutric Static Cryosols (HE.SC) within the research site. Soil cross sections of each point are given in Figure 4.7.................................................................................................................................................. 58 Figure 4.7. East-west soil horizon cross-sections by sampling lines (refer to Figure 4.6 for sample site locations). 150x vertical exaggeration. ‘Clay’ refers to clay lenses observed below Of and above Om horizons. ............................................................................................................... 60 Figure 4.8. Photos of soil horizon groups commonly encountered. a) Site 119: (557,197 m E, 7,134,859 m N), b) Site 49b: (556,863 m E, 7,134,681 m N) c) Site 78: (557,522 m E, 7,134,636 m N) d) Site 108b: (557,442 m E, 7,134,769 m N), and e) Site 60: (557,412 m E, 7,134,591 m N). ................................................................................................................................................. 62 Figure 4.9. Permafrost surface encountered in organic deposits at Site 47 (557,552 m E; 7,134,507 m N), at approximately 30 centimetres depth. ............................................................. 63 Figure 4.10. Vegetation patterns within the DO-18 research site, mapped based on primary field observations. ................................................................................................................................. 64 Figure 4.11. Vegetation classifications within the research site. a) Moss and lichen, b) hummocky grassland, c) thin shrubs, and d) thick shrubs. ........................................................... 65 xvi Figure 5.1. 2x magnification of K2P-0018 under a) plane polarized light, and b) under cross polarized light. Minerals present include broken, serpentinized olivine, granitic xenoliths and xenocrysts, clasts of resedimented volcaniclastic kimberlite (RVK), in a serpentine and ash matrix. It is therefore likely from the KIMB-1 domain (Harder et al., 2008; Chapter 2). ............ 70 Figure 5.2. QA/QC using the CRMs to evaluate the accuracy of the 4-Acid ICP-MS analysis for a) Cr, b) Mg, c) Nb, and d) Ni. SD refers to Standard Deviations. ............................................... 72 Figure 5.3. Field reproducibility (MPD) analysis using field duplicates of the 4-Acid ICP-MS analysis for a) Cr, b) Mg, c) Nb, and d) Ni. .................................................................................. 73 Figure 5.4. Probability plots of 4-Acid ICP-MS results for a) Cr, b) Mg, c) Nb, and d) Ni concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.5........................................................................................................................................................ 75 Figure 5.5. 4-Acid ICP-MS results for a) Cr, b) Mg, c) Nb, and d) Ni concentrations, with organic-rich samples omitted. Intervals are based on probability plots (Figure 5.4). .................. 77 Figure 5.6. Sum of concentrations of elements, Cr, Mg, Nb and Ni (normalized by percentile prior to summation) from 4-Acid ICP-MS data, overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to delineate plotting boundaries. ........................ 78 Figure 5.7. Probability plots of Aqua Regia ICP-MS results for a) Cr, b) Mg, c) Nb, and d) Ni concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.8........................................................................................................................................................ 80 Figure 5.8. Aqua Regia ICP-MS results for a) Cr, b) Mg, c) Nb, and d) Ni concentrations, with organic samples omitted. Intervals are based on probability plots (Figure 5.7). .......................... 81 xvii Figure 5.9. Sum of concentrations of elements, Cr, Mg, Nb and Ni (normalized by percentile prior to summation) from Aqua-Regia ICP-MS data, overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to delineate plotting boundaries. ........... 82 Figure 5.10. Probability plots of De-Ionized Water ICP-MS results for a) Ce, b) K, c) Nb, and d) Y concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.11................................................................................................................................................ 84 Figure 5.11. De-Ionized Water Leach ICP-MS results for a) Ce, b) K, c) Nb, and d) Y concentrations, with organic samples omitted. Intervals are based on probability plots (Figure 5.10). ............................................................................................................................................. 85 Figure 5.12. Sum of concentrations of elements, Ce, K, Nb, and Y (normalized by percentile prior to summation) from De-Ionized Water ICP-MS data, overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to delineate plotting boundaries. ... 86 Figure 5.13. Probability plots of fp-XRF Soil Mode results for a) Cr, b) Nb, c) Ni, and d) Zn concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.14................................................................................................................................................ 89 Figure 5.14. Fp-XRF Soil Mode results for a) Cr, b) Nb, c) Ni, and d) Zn concentrations, with organic samples omitted. Intervals are based on probability plots in Figure 5.13........................ 90 Figure 5.15. Sum of concentrations of elements for Cr, Nb, Ni and Zn (normalized by percentile prior to summation) from fp-XRF data, overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to delineate plotting boundaries. ................................ 91 Figure 5.16. Sequential leach results for the most prominent geochemical anomalies: Cr, Mg, Nb and Ni. In most cases, the recovery by sequential leach is comparable to the recovery by the total 4-Acid Digestion (solid red bar below each sequential leach reading for each sample), with the xviii exception of sample Q5156695SL, where Nb recovery is significantly greater than that of the total digestion. ‘4Atot’ indicates recovery from the 4-Acid ICP-MS analysis (Section5.3.1). .... 95 Figure 5.17. Representative mineralogy of samples also sent for sequential leach analysis. Typical mineralogy includes quartz, biotite, albite, orthoclase, phlogopite, vermiculite, clinochlore, hornblende, nontronite, and illite. ............................................................................. 97 Figure 5.18. 4-Acid ICP-MS results versus those of fp-XRF for a) Cr, b) Nb, c) Ni, and d) Zn. The slope (m) of the line of best fit represents the recovery by 4-Acid digest of each element versus recovery by fp-XRF, where m>1 indicates greater recovery by 4-Acid, m=1 indicates equal recovery by 4-Acid and fp-XRF, and 1>m>0 indicates greater recovery by fp-XRF. The Pearson correlation coefficient (r) represents the strength of the relationship, where r=0 indicates no relationship, r=1 indicates a perfect positive correlation, and r=-1 indicates a perfect negative correlation. The variance, or proportion of data closest to the line of best fit, is given by r2, where r2=1 shows no variance. .............................................................................................................. 100 Figure 5.19. 4-Acid ICP-MS results versus those of Aqua Regia ICP-MS for a) Cr, b) Mg, c) Nb, and d) Ni. The slope (m) of the line of best fit represents the recovery by 4-Acid digest of each element versus recovery by fp-XRF, where m>1 indicates greater recovery by 4-Acid, m=1 indicates equal recovery by 4-Acid and fp-XRF, and 1>m>0 indicates greater recovery by fp-XRF. The Pearson correlation coefficient (r) represents the strength of the relationship, where r=0 indicates no relationship, r=1 indicates a perfect positive correlation, and r=-1 indicates a perfect negative correlation. The variance, or proportion of data closest to the line of best fit, is given by r2, where r2=1 shows no variance. ................................................................................ 101 Figure 5.20. Box plots of Corg per surficial material. .................................................................. 102 xix Figure 5.21 MPD analysis for SGH compounds of interest a) C005, b) C008, c) C009, and d) C012. Due to the semi-quantitative nature of the SGH analysis, units are not provided. .......... 103 Figure 5.22. The relative average molecular weight of each of the 19 compound classes in the SGH range of analysis. Low/medium/high refers to each given class, and is not used between classes e.g. light PAH (compound class 9) has a similar molecular weight to that of a heavy propyl-benzene, class 7 (modified after Sutherland et al., 2004). Diagram is schematic. ‘MW’ refers to molecular weight. ......................................................................................................... 104 Figure 5.23. Probability plots of SGH results for a) C005, b) C008, c) C009, and d) C012 concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.24.............................................................................................................................................. 106 Figure 5.24. SGH results for a) C005, b) C008, c) C009, and d) C012, with organic samples omitted. ‘LB’ refers to ‘light benzene’. Intervals are based on probability plots in Figure 5.23. As SGH analysis is semi-quantitative, units are not provided. ........................................................ 107 Figure 5.25. Sum of SGH compounds C005, C008, C009 and C012 (normalized by percentile prior to summation) overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to generate the legend. .............................................................................. 108 Figure 5.26. SGH light benzenes compared to the sum of AGI light benzene compounds, benzene, toluene, ethylbenzene and propylbenzene. No correlation exists between the SGH light benzene compounds and the sum of four lightest AGI light benzenes analysed. ....................... 110 Figure 5.27. Interpretations offered by ActLabs for SGH data within the research site using kimberlite pathfinder compounds. Four kimberlites were detected in the northern region, and an E-W trending fault zone through the centre, though this is not supported by geophysical data (Chapter 2). ................................................................................................................................. 112 xx Figure 5.28. QA/QC duplicate analysis for a) slurry pH, b) Acidified slurry pH, c) Eh, and d) TDS. ............................................................................................................................................ 114 Figure 5.29. TDS data presented for each line of the sampling grid. The location of the kimberlite is given in purple. Organic horizon samples are not shown. ..................................... 116 Figure 5.30. Slurry pH data presented for each line of the sampling grid. Slurry pH readings are presented in blue and acidified slurry pH readings are given in orange. The location of the kimberlite is given in purple. Organic horizon samples are not shown. ..................................... 117 Figure 5.31. Eh data presented for each line of the sampling grid. The location of the kimberlite is given in purple. Organic horizon samples are not shown. ...................................................... 118 Figure 5.32. a) TDS, b) slurry pH, c) Eh, and d) acidified slurry pH probability plots used to delineate plotting boundaries in Figure 5.33. .............................................................................. 119 Figure 5.33. a) TDS, b) slurry pH, c) Eh, and d) acidified slurry pH data plotted in plan-view. Samples from the organic horizons are omitted, and plotting intervals are based on probability plots in Figure 5.32. .................................................................................................................... 120 Figure 5.34. Eh-pH Pourbaix diagram for calcium, where [Ca] = 0.0001 mol/kg and [C] = 0.01. mol/kg. pH values are from the slurry pH readings, Eh are from the ORP readings. Most samples (purple) do not exist within conditions conducive for calcite formation. pH boundaries for CaCO3(s) are similar to that described by Langmuir (1968)........................................................ 121 Figure 5.35. Sequential leach results for Ca. The majority of Ca was digested by the 4-Acid digestion, with minute levels of Ca from the ammonium acetate leach, indicating low abundances of calcite. ................................................................................................................. 122 Figure 5.36. Inverse difference hydrogen (IDH) values presented for each line of the sampling grid. The location of the kimberlite is given in purple. Organic-rich samples are not shown. ... 123 xxi Figure 5.37. SP readings at each sample site for lines 4, 5 and 9. .............................................. 125 Figure 5.38. TOC versus Lab pH. A negative correlation indicates that as the content of TOC increases, the pH is more acidic. ................................................................................................. 127 Figure 5.39. Slurry pH versus Lab pH displays a weak correlation due to differences in sample preparation prior to analysing lab pH; slurry pH was conducted on samples screened by 0.25 inch mesh, and lab pH was conducted on samples screened to -180 microns. ................................... 127 Figure 6.1. Major element correlations with Cr using data from the 4-Acid ICP-MS analysis. Cr is correlated with a) Mg, b) Fe, c) Ti, and d) Al. Organic samples are not considered. The cutoff value for anomalous Cr concentrations is 36 ppm, as per Figure 5.4. ........................................ 132 Figure 6.2. Major element correlations with Mg using data from the 4-Acid ICP-MS analysis. Mg is correlated with a) Fe, b) Al, and c) Ti. Organic samples are not considered. The cutoff value for anomalous Mg concentrations is 0.46%, as per Figure 5.4. ........................................ 133 Figure 6.3. Major element correlations with Nb using data from the 4-Acid ICP-MS analysis. Nb is correlated with a) Mg and b) Cr. Organic samples are not considered. The cutoff value for anomalous Nb concentrations is 4.4 ppm, as per Figure 5.4. ..................................................... 134 Figure 6.4. Major element correlations with Ni using data from the 4-Acid ICP-MS analysis. Ni is correlated with a) Mg, b) Fe, c) Ti, and d) Cr. Organic samples are not considered. The cutoff value for anomalous Ni concentrations is 15.8 ppm, as per Figure 5.4. ..................................... 135 Figure 6.5. Concentrations of Ni and Mg in each of the kimberlite core samples. Regression lines are extrapolated from Figure 6.4a, and do not include the kimberlite core samples. Diamond indicates the composition of an average granitic shell (Beus and Grigorian, 1977). ................. 136 Figure 6.6. Elements of interest, represented by Nb concentrations from 4-Acid ICP-MS data, are not positively correlated with TOC, therefore TOC does not exhibit a control on their xxii concentration when a) organic samples are not considered, and b) when organic samples are considered. .................................................................................................................................. 137 Figure 6.7. SGH compound classes of interest are moderately correlated with elements of interest, represented by Nb concentrations from the 4-Acid ICP-MS analysis. Graph is representative of each of the compound classes and elements of interest. Organic samples are not considered. .................................................................................................................................. 138 Figure 6.8. Concentrations of SGH compounds in surficial materials. a) C113 is higher in concentration in till, and is low in organic-rich material, and b) C001 is higher in concentration in organic deposits. ..................................................................................................................... 138 Figure 6.9. Geomorphological processes hypothesized to have occurred within the research site. a) Movement of the Laurentide Ice Sheet towards the northwest, entraining kimberlitic material and generating the observed geochemical anomalies. b) Lake formed in a lower topography region of the till blanket, bound by the slope break at its northern boundary. c) Lake drainage towards the south into Tli Kwi Cho Lake, generating fluvial sediments south of the slope break. d) Current distribution of surficial sediments (as per Figure 4.3). Frost boils are ubiquitous in the till blanket north of the slope break, with few observed in till south of the slope break. ........... 140 Figure 6.10 a) Map of drill holes near the research site completed as part of the SPSMPS RC drilling program in 2015. Red outline denotes boundary of drill holes considered. Drill hole locations and logs are provided by Normandeau et al. (2016). KIM counts for samples in each hole are provided by Elliott and Normandeau (2016). Drill holes for cross sections A and B are illustrated. Maximums in each drill hole profile are highlighted as the dispersal train. Cross Section A illustrates dispersal trains of kimberlitic material in the down-ice direction, as observed in b) peridotitic pyrope abundances per 10 kg of sediment and c) Ni concentrations for xxiii each sample taken at a given depth in each drill hole. Dispersal of kimberlitic material is also evident in Cross Section B for d) peridotitic pyrope abundances per 10 kg of sediment and e) Ni concentrations. Diagram is schematic......................................................................................... 142 Figure 6.11. Peridotitic pyrope abundances per 10kg of sediment in surface samples (less than 3m depth) for each drill hole. Abundances are significantly greater north of the slope break, and subdued in the southern region. Lower pyrope abundances are indicative of sediment mixing in the south. KIM data provided by Elliott and Normandeau (2016). ............................................ 145 Figure 6.12. Summary of the evolution of the geochemical response within the field site. In the northern region, cryoturbation is hypothesized to have enhanced the presence of the geochemical response. In the south, glaciofluvial and glaciolacustrine sediments have buried and diluted the geochemical signal. The geochemical signal is represented by Ni data from the 4-Acid ICP-MS analysis. Diagram is schematic. .................................................................................................. 146 xxiv Acknowledgements I would first and foremost like to extend a thank-you to Dr. Peter Winterburn. Through an open-door policy and eagerness to help, Peter has consistently helped me stay on track and complete this project efficiently. Peter’s devotion to his students and enthusiasm for teaching is highly appreciated, and his guidance has significantly improved the quality of this thesis. Committee members Dr. Maya Kopylova, Dr. Derek Turner and Dr. Craig Hart are also sincerely thanked for their contributions and improvements to this project. I would like to thank Bureau Veritas, Acme DMMT and NSERC for their financial support, as well as the Northwest Territories Geological Survey for funding for the Spatiotemporal Geochemical Hydrocarbon analyses and organizing logistical support at the research site. Aurora Geosciences Ltd., and Peregrine Diamonds Ltd. are also thanked for their in-kind support. The Society of Economic Geologists are thanked for awarding me a student research grant from the Hickok-Radford Memorial Fund. Olympus are also thanked for the fp-XRF instrument loaned to the Exploration Geochemistry Initiative, as is AGI Inc. for the installation training and financial support for the Goresorber™ Hydrocarbon Collectors. This research opportunity for myself and the Exploration Geochemistry Initiative would not be possible without the help of these organizations. Rachel Hansen is thanked for her assistance in the field. Her positive attitude and hard work helped accomplish as much as possible during our limited time in the field. I also thank Dr. Martin Ross and Dr. Sam Kelley for their help and valuable input at the research site. xxv I would like to thank my fellow researchers, Matt Bodnar, Shane Rich, Rachel Chouinard and Ally Brown for their stimulating and constructive discussion at our regular meetings. Those with whom I have shared an office, including Kaleb Boucher, Nikolett Kovacs and Paula Brunetti, are also thanked for their advice and moral support. I also extend a thanks to Sara Jenkins for the many hours she has dedicated to helping me navigate ArcGIS. I would like to thank my parents, Robert and Elizabeth Cayer, for their endless support for the duration of this project. Finally, I would like to thank Derek Cooper, for his unwavering support, patience, and encouragement. The completion of this degree would not have been possible without each of you. 1 Chapter 1: Introduction 1.1 Project Rationale The presence of glacial drift presents a challenge in mineral exploration in many regions of the world with high potential to contain mineral deposits (Seneshen, 1997; Hall, 1998; Kelley et al., 2004; Leslie et al., 2013; van Geffen et al., 2015). The Lac de Gras region of the Northwest Territories, Canada, is presumed to contain several undiscovered diamondiferous kimberlites, which are buried or obscured by glacial drift remaining after the retreat of the Laurentide Ice Sheet (Kjarsgaard, 1996; Wilkinson et al., 2001). Though geophysical exploration methods can detect kimberlites through cover (Fournier et al., 2014; Kang et al., 2015), false positives are commonplace and result in expensive, unsuccessful drilling. Thus, there is motivation to develop surface geochemical target discrimination techniques (Seneshen, 1997; Hall, 1998; Wilkinson et al., 2001), which, when combined with geophysical data, may vastly enhance exploration success (McClenaghan and Kjarsgaard, 2001). This study aims to investigate the DO-18 kimberlite (Peregrine Diamonds Ltd.) and its glacial cover to evaluate the potential of target discrimination techniques to identify surface geochemical anomalies associated with kimberlites. 1.2 Objectives The objectives of this research are to: 1. Identify the presence of a drift concealed kimberlite based on surficial organic-, inorganic- and physicochemistry of the soil above the kimberlite. 2 2. Integrate geomorphological process models with till geochemical data and indicator mineral information to understand the mechanism and evolution of the geochemical responses. 3. Develop reproducible and cost-effective sampling and analytical strategies to increase the exploration success rate. 1.3 Thesis Structure This thesis is structured by chapters outlined below. Chapter 1: Introduction Introduces the rationale and objectives of the project, and appropriate background information, including: the mineralogy and geochemistry of kimberlites; and geochemical anomaly formation and element transport mechanisms in soil. Chapter 2: Geologic Overview Geologic overview of the Slave province including glacial history and the geology of the DO-18 kimberlite. Chapter 3: Methodologies Methodologies employed in the research are discussed, including: sampling program design; sample collection; environmental and anthropogenic considerations; and instruments used in collecting organic and inorganic geochemical data, physicochemical data, lithogeochemical, and mineralogical data. 3 Chapter 4: Physiography, Surface Geology, Soil and Environment Details the physiography of the DO-18 research site and characterization of surficial geology, vegetation, and the soil profiles at each sample site. Chapter 5: Results Presents results and a brief discussion of each method undertaken to identify a geochemical anomaly associated with the DO-18 kimberlite, including lithogeochemistry and petrography of the kimberlite, and inorganic-, organic- and physicochemistry. Chapter 6: Discussion Compares of the influence of surface materials on geochemistry; controls on hydrocarbon chemistry and its influence on inorganic chemistry; the influence of geomorphological processes on till geochemistry and anomaly formation; and kimberlite indicator mineral (KIM) counts versus till geochemistry. Chapter 7: Exploration Implications and Future Research Implications for the exploration of kimberlites in glaciated terrains based on the origin and transport mechanisms of the geochemical anomaly. The most effective method(s) for anomaly detection and sampling best practices are presented, in addition to recommendations for future research. Chapter 8: Conclusions Concluding remarks. 4 1.4 Kimberlite Mineralogy and Geochemistry Kimberlites are volatile-rich (mainly CO2), potassic, ultrabasic rocks which often display an inequigranular texture due to the presence of large crystals contained within a fine grained matrix (Mitchell, 1986). Kimberlites exhibit a complex mineralogy (Table 1.1; mineralogy based on Group I kimberlites as DO-18 is classified as a Group I kimberlite), as minerals within kimberlites generally originate from three distinct sources: country rock xenoliths; mantle xenoliths; and primary phases which have crystallized from the magma, comprising phenocrysts, microphenocrysts and groundmass minerals (Mitchell, 1995). Xenoliths are foreign rock fragments which have been incorporated into the magma during emplacement. Country rock xenoliths are those which originate from the host rocks of the kimberlite. Mantle xenoliths, the host rocks of diamond in a kimberlite, are sourced from the mantle, and commonly comprise (Mitchell, 1995; Dawson, 1980):  garnet and/or spinel lherzolite  garnet and/or chromite harzburgite  metasomatized peridotite  websterite  eclogite, and  the MARID (mica-amphibole-rutile-ilmenite-diopside) rock suite. Xenocrysts form due to the disintegration of xenoliths. Those that originated from mantle xenoliths are termed megacrysts and macrocrysts (terms which lack genetic implications). These are identified based on the composition of corresponding xenoliths found within the kimberlite, for example: Cr-diopside and Cr-pyrope derived from garnet lherzolite. In some cases, xenocrysts may have compositions nearly congruent in composition to primary crystallized 5 phases, which are commonly incorporated into the megacryst and macrocryst assemblage. Megacrysts are characterized as being more than 1 cm in their longest dimension, whereas macrocrysts are defined as crystals of 0.5 to 1 cm in size (Mitchell, 1995). Most commonly, megacryst and macrocryst mineralogy includes olivine (or serpentinized olivine), picro-ilmenite, pyroxene, chromite, phlogopite, and garnet (Dawson, 1980; Mitchell, 1986). Megacrysts and macrocrysts may also be round in shape and show reaction textures with the surrounding matrix, such as garnets with kelyphitic rims made of fine-grained phlogopite and spinel (Dawson, 1980). Table 1.1. Minerals typically present in Group I kimberlites, and those which preclude kimberlites (Modified after Mitchell, 1995). Mineral Phase Abundance Olivine Macrocryst (dominantly xenocrysts) Abundant Phenocryst (Fo87-90, subhedral/euhedral) Common Monticellite groundmass (May be pseudomorphed by calcite or serpentine) Common Mica Phlogopite macrocrysts Minor Phlogopite microphenocrysts Rare Phlogopite groundmass Common Spinel Mg-Chromite (zoned to Mg-ulvöspinel) goundmass or macrocrysts Abundant Pyroxene Cr-diopside macrocryst Common Perovskite Groundmass Abundant Apatite Euhedral prisms or acicular radiating aggregates in serptentine-calcite segregations Common to rare Carbonates Groundmass or matrix (usually calcite, occasionally dolomite) Abundant Serpentine Secondary alteration mineral of olivine Abundant Minerals Absent from Kimberlites: Sanidine, K-Richterite, Leucite, REE-Phosphates, Quartz Primary kimberlitic phases include phenocrysts, microphenocrysts, and groundmass and mesostasis minerals which have crystallized in-situ (Mitchell, 1995). Crystals with a subhdral to euhedral habit and are >0.5 mm in size are termed phenocrysts, or microphenocrysts if they are 0.1-0.5 mm in size. Phenocrysts generally comprise olivine, phlogopite and chromite. 6 Microphenocrysts typically include olivine, phlogopite, Ti-spinels, perovskite, ilmenite, diopside, monticellite, apatite, calcite and serpentine (Mitchell, 1986; Dawson, 1980). Crystals approximately 0.1 mm or smaller are typically considered groundmass minerals. Groundmass minerals may be contained within a matrix, or mesostasis, which forms after the crystallization of groundmass crystals is complete (Mitchell, 1995). Matrix minerals typically include euhedral, primary olivine (second generation) and phlogopite, perovskite, spinel (Ti-Mg-Al chromite), Al- and Ti-poor diopside, monticellite, apatite, calcite and Fe-rich primary late stage serpentine (Mitchell, 1986). Olivine, phlogopite, monticellite and apatite are commonly replaced by deuteric serpentine and calcite (Mitchell, 1986). Occasionally, kimberlites may contain Ni-sulphides and rutile (Mitchell, 1986). Kimberlite geochemistry is complex for the same reasons kimberlites display complex mineralogy: multiple sources of material. Mitchell (1986) outlines common problems with defining the geochemistry of kimberlites without contamination, including: 1. the absence of aphyric or glassy grains to serve as a geochemical reference point with which to identify relationships of primitive liquids to their mantle sources or differentiation processes; 2. the inclusion of crustal xenoliths, which typically contributes SiO2, Al2O3 and K2O; and 3. magma devolatilization during emplacement, resulting in a loss of CO2, H2O, or other volatile gases. Previous studies regarding the geochemistry of kimberlites, such as Dawson (1980), attempt to remove xenolithic material prior to analysis to diminish contamination, but mentions 7 that eliminating mantle xenocryst input is arduous due to the difficulty in distinguishing certain xenocrysts from primary phases. Fine particles of crustal xenolithic material may remain throughout the kimberlite, rendering separation onerous (Mitchell, 1986). Mitchell (1986) further points out that even hypabyssal kimberlites that contain few crustal xenoliths may still exhibit contamination due to the inclusion of mantle-derived components not originally part of the parent magma. Clement (1982) presented a contamination index to determine the degree of crustal contamination or kimberlite weathering, which measures ratios of SiO2 plus Al2O3 and Na2O to MgO and 2*K2O, where a contamination index close to 1 indicates relatively fresh kimberlite. Regardless of the issues with evaluating the geochemistry of a kimberlite, general trends can be identified. Due to their ultrabasic nature, Al2O3 and Na2O contents are low, with highly variable SiO2, CaO, MgO, CO2 and H2O (Mitchell, 1986), and with low Mg/Fe and high K/Na and Fe3+/Fe2+ ratios (Dawson, 1967). Table 1.2 shows the representative average major and trace element composition of Group I kimberlites. The high level of variation within a single kimberlite and between other kimberlites renders the average compositions presented relatively insignificant geochemically, and only broad comparisons and vague conclusions can be made (Mitchell, 1986). Two major groups of trace elements exist: compatible and incompatible. Compatible elements are preferentially incorporated into crystallizing phases, and are therefore rapidly depleted from the magma during fractional crystallization (Mitchell, 1986). Compatible elements in kimberlites include Sc, V, Cr, Co, Ni, Cu and Zn, all of which are mainly hosted within olivines and spinels; and to a lesser extent perovskite (Sc), sulphides (Cu, Ni) and diopside (Cr, 8 V, Ni) (Mitchell, 1986). Therefore, compatible element abundance is proportional to olivine and spinel abundance and inversely proportional to crustal xenoliths, which have a dilution effect (Mitchell, 1986). Table 1.2. Average major and trace element abundances in Group I kimberlites. Major element data from Dawson (1967), compatible element data from Mitchell (1986), HFSE data is averaged from data cited in Mitchell (1995) from South African kimberlite from Smith et al. (1985), Zaire Kimberlites from Kampata (1993), and Kimberley Group Kimberlites from Clement (1982) and Mitchell (1995). REE data from Maramatsu (1983). Major Element Oxide Abundance (%) Trace Element Abundance (ppm) Rare Earth Element Abundance (ppm) SiO2 35.2 Sc 14 La 150 TiO2 2.32 V 100 Ce 200 Al2O3 4.4 Cr 893 Pr 22 FeO 8.8 Ni 965 Nd 85 MnO 0.11 Co 65 Sm 13 MgO 27.9 Zn 69 Eu 3 CaO 7.6 Ba 885 Gd 8 Na2O 0.32 Sr 847 Tb 1 K2O 0.98 Ta 12 Ho 0.55 P2O5 0.7 Nb 171 Er 1.45 CO2 3.3 Zr 263 Tm 0.23 H2O 7.4 Hf 5 Yb 1.2 Total 100.3 Th 20 Lu 0.16 U 4 Y 22 Incompatible elements in kimberlites are similar to those found in alkaline rocks such as carbonatites and potassic lavas, and include Ba, Sr, Zr, Hf, Nb, Ta, U and Th, and rare earth elements (REEs) (Mitchell, 1986). Incompatible elements remain in the melt until late stage crystallization, usually of the groundmass minerals. Incompatible elements are dominantly hosted within phlogopite, Sr, U and Th are found within apatite and groundmass diopside, and perovskite is the main host of Zr, Hf, Nb, Ta, U and Th (Mitchell, 1986). Zr and Hf are generally well correlated with each other within kimberlites, in contrast to Nb-Ta and Ba-Sr relationships (Mitchell, 1986). REE patterns are characterized by enrichment in LREEs relative to HREEs, 9 resulting in elevated La/Yb ratios. REEs are most commonly found within perovskite and apatite (Mitchell, 1986, Dawson 1980). 1.5 Kimberlite Weathering, Glacial Transport, Frost Heave and Element Migration 1.5.1 Kimberlite Weathering Rates of silicate weathering are dependent on temperature and the availability of water (White and Blum, 1995). Kimberlite weathering severity is thus greater at the margins and near the surface, due to the abundance of fractures, hydration, and oxidation (Dawson, 1980). The abundance of high-Mg minerals and highly porous nature of crater and diatreme facies kimberlites also encourages kimberlite weathering (Fairbairn and Roberston, 1966; McClenaghan and Kjarsgaard, 2001; Cornelius et al., 2005). In cold climates, such as the Canadian tundra, kimberlite weathering is characterized by low temperature replacement of primary groundmass minerals and macrocrysts, most commonly by clay minerals, carbonates and oxides (Table 1.3; Mitchell, 1986; McClenaghan and Kjarsgaard, 2001; Wilson, 2004). Alteration of primary minerals to clay minerals will lead to a relative increase in SiO2 and Al2O3, as MgO and additional soluble cations are removed (Mitchell, 1986). 10 Table 1.3. Common weathering products of primary kimberlite minerals (Wilson, 2004; Bosch, 1971; Mitchell, 1986; Mitchell, 1995). Weathering Product of Primary Kimberlite Mineral Primary Kimberlite Mineral(s) Mineral Formula (General) Serpentine Olivine, Apatite D3[Si2O5](OH)4 D= Mg, Fe, Ni, Mn, Al, Zn Chlorite Olivine, Phlogopite A5-6T4Z18 A = Al, Fe2+, Fe3+, Li, Mg, Mn, or Ni T = Al, Fe3+, Si Z = O and/or OH Vermiculite Olivine, Phlogopite Mg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O Saponite Pyroxene Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O Nontronite Pyroxene Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O Halloysite Phlogopite Al2(Si2O5)(OH)4 Iddingsite Olivine MgO·Fe2O3·3SiO2·4H2O Goethite Olivine, Pyroxene, Phlogopite Fe3+O(OH) Calcite Apatite, Carbonates CaCO3 Dolomite Carbonates CaMg(CO3)2 1.5.2 Glacial Transport and Frost Heave Glacial transport is characterized as entrainment of material by glacial erosion processes, producing a dispersal train (Figure 1.1; Miller, 1984). A single ice flow direction typically produces a ribbon-shaped dispersal train, though multiple ice flows may rework the dispersal train into a fan or palimpsest shape (McClenaghan et al., 1997). Weathered kimberlite is more susceptible to weathering and glacial erosion than surrounding bedrock, forming topographically low areas due to volume loss by glacial entrainment and loss of Mg and soluble cations during weathering (Fairbairn and Robertson, 1966; McClenaghan and Kjarsgaard, 2001). They are therefore often discovered under swamps or lakes, or covered by thick glacial sediments (McClenaghan and Kjarsgaard, 2001). Both preglacially weathered and competent kimberlite may be removed by glacial erosion, and in some cases, glacial erosion may expose kimberlite 11 outcrop with clear glacial striations, though usually several meters of weathered clay rich kimberlite remain (McClenaghan and Kjarsgaard, 2001). In permafrost regions, frost boils are a common surface feature capable of vertically transporting sediments from depth. Frost boils are patches of barren or sparsely vegetated soil formed by cryoturbation or differential frost heave (Walker et al., 2004). Frost boils occur in regular patterns over much of the Arctic, and, in the Northwest Territories, have been documented to upheave sediment through frost heave at a rate of up to 10-14 cm per year, depending on moisture content (Mackay et al., 1979). Thus, given sufficient time, frost boils which occur over kimberlite dispersal trains can transport entrained kimberlitic material from depth to the surface. Figure 1.1. Morphology of a dispersal train of indicator minerals from a buried kimberlite, as well as techniques which may be used to detect the kimberlite (modified after McClenaghan and Kjarsgaard, 2007). 12 1.5.3 Element Migration In glaciated terrain, soil geochemical responses through till have been reported frequently; however, the transport mechanism which moves elements through the glacial cover from the source is less apparent (Hamilton, 2000). Several element transport mechanisms have been proposed to account for these soil geochemical anomalies. These processes include: clastic dispersion (glacial transport in particular); advective transport within the phreatic zone, including groundwater flow along a hydraulic gradient, convection, and bubble migration (metal adsorption onto bubble surfaces); electrochemical dispersion; diffusion; dilatancy (seismic) pumping; and capillary rise in the vadose zone. As most glacial deposits in Canada are between 12 ka and 8 ka in age, proposed transport mechanisms must be able to operate within this time frame (Hamilton, 2000). Transport mechanisms which have been proposed specifically for arid climates will not be considered. These include vadose zone processes such as: gaseous transport, in which oxidizing ore bodies (usually sulphides) emit gases such as COS or H2S, which are used to detect the ore body; and supercedency, in which alluvium deposition mixes with residual soil or regolith, and subsequent dissolution of water soluble metals which infiltrates downwards and is later evaporated, causing metal enrichment on the surface (Aspiandar et al., 2006; Kelley et al., 2004). Advective Transport: Groundwater Upwelling Advective water transport in the phreatic zone involves water movement along a hydraulic gradient: groundwater which contains dissolved, colloidal, or suspended pathfinder elements from a deposit may migrate upwards, generating a surficial geochemical anomaly (Aspiandar et al., 2006). Most often, advective transport occurs laterally, particularly in stratified 13 materials, though vertical flow (upwelling) can occur (Hamilton, 2000) through processes such as groundwater recharge. Bolviken and Logn (1975) and Smee (1983) proposed groundwater upwelling as a possible mechanism for element migration from mineralization to account for observed geochemical anomalies. Sader (2011) also proposed groundwater upwelling to account for geochemical anomalies over kimberlites in the Attawapiskat region. Advective Transport: Convection Upward migration of fluids from depth via convection are a result of density or buoyancy gradients generated by differences in temperature, salinity, or solute content (Freeze and Cherry 1979; Domenico and Schwartz 1998). Convection cells contain increased density currents within the groundwater, generally in either finger or lobe geometries (Aspiandar et al., 2006). The increased buoyancy gradient also results in faster migration rates than diffusion (Simons et al., 2001). Buoyancy gradients may be triggered via: increased solute content in groundwater through mineral dissolution (Aspiandar et al., 2006); exothermic sulphide oxidation reactions which generate heat (Mann et al., 2005; Hamilton, 2007); and thermal conduction from depth in sulphides relative to host rocks, particularly in cold climates (Hamilton, 2007). Advective Transport: Bubble Migration Element migration via bubble movement occurs when elements dissolved in groundwater separate into a gas phase in pressure gradients (Malmqvist and Kristiansson, 1984); gases with sufficient concentration to form bubbles are referred to as carrier gases, mainly CO2 and CH4 (Etiope and Martinelli, 2002). As the bubbles migrate, their surfaces may collect particulates, and transfer these particles from bubble to bubble, resulting in rapid metal transfer (Aspiandar et 14 al., 2006). The rate of bubble migration is dependent on bubble diameter, density, groundwater density and viscosity. Bubble diameter is dependent on the porosity and grainsize of the medium (Etiope and Lombardi, 1996). Electrochemical Dispersion The most recent model for electrochemical dispersion to account for surface geochemical anomalies was proposed by Hamilton (1998), largely built off that of Sato and Mooney (1960). Self-potential, or spontaneous potential (SP) anomalies are generated by conductive bodies acting as a conduit for electrons, conducting electrons to areas of higher Eh at the bedrock surface from those of low Eh at depth. The conductive body is not considered to partake in the reaction, but rather acts solely as a conduit for electrons (Sato and Mooney, 1960; Hamilton, 1998). The model proposed by Hamilton (1998) involves the upward migration of reduced species through till, triggered by the redox gradient generated by the lower Eh at the bedrock surface and high Eh at the till surface. Oxidizing agents in groundwater are consumed near the upper end of the conductor (near the bedrock surface) and become reduced. These reduced agents must then dissipate from the conductor into the overlying glacial sediments or the voltage differential ceases as the buildup of reducing conditions occurs (Hamilton, 1998). Once the oxidizing agents are consumed, the now-reduced anions dissipate upward and outward, generating a ‘reduced front’ or ‘reduced column’ (Hamilton, 1998). The reduced front propagates as it consumes oxidizing agents by ‘charge transfer’ via redox reactions, altering oxidation states, or reducing, species it contacts (Hamilton, 1998). Upon the full development of the reduced column, electric current is focused at the flanks of the column as voltage differential 15 is greater laterally than vertically (Hamilton, 1998). Additionally, Hamilton (1998) states that electronic conductors are not limited to sulphides, but that other sources are possible, including: a vertical, more conductive zone in bedrock, such as a fault gouge; a distinct bedrock depression infilled with conductive glacial sediments; a boundary between lithological units with distinct redox properties, such as a kimberlite in granitic host rocks; or a zone of reduced organic matter, such as coal. Caveats of Hamilton’s (1998) model, however, include the difficulty in explaining how the ions which form the geochemical anomalies are actually carried to surface (Cameron et al., 2004). Additionally, several technical difficulties arise when evaluating processes which occur in the reduced column to generate element migration rates well beyond that of chemical diffusion (Cameron et al., 2004). Diffusion Diffusion along concentration gradients has been proposed as an element migration mechanism to explain surficial geochemical anomalies (Govett and Chork, 1977; Smee, 1979 and 1983) However, Smee (1979) calculated that ions do not diffuse quickly enough to account for most observed anomalies, as the Canadian glacial sediments through which they were travelling are 12 ka to 8 ka in age. In this timeframe, no ions were calculated to be able to migrate greater than 10 metres, except for H+, which travelled upwards of 28 metres. Anomalies have been reported above targets covered by upwards of 45 metres of young, glacial sediments (Smee, 1979; Hamilton, 2000). Thus, diffusion becomes a likely transport mechanism with increasing age or decreasing thickness of the till overlying the deposit (Hamilton, 2000). 16 Dilatancy (Seismic) Pumping Metal-bearing water can be transferred to the surface via faults as a result of dilatancy pumping, in which compressional stress along faults, caused by earth tremors, forces the water upwards (Cameron et al., 2002; Aspiandar et al., 2006). Pre-seismic fractures in the brittle upper crust may act as storage and pathways for water movement; compressional stress triggers the closing of these fractures, forcing water upwards to areas of lower pressure at the surface, ultimately being transported upwards through overlying sediments (Aspiandar et al., 2006). This can cause surface discharge of water and subsequent rapid evaporation, generating a redistribution of metals around buried deposits, and potentially a surface geochemical anomaly (Kelley et al., 2004; Aspiandar et al., 2006). Geochemical anomalies associated with dilatancy pumping would likely be characterized by strong, structurally controlled distributions, and chemical associations similar to the groundwater chemistry (Kelley et al., 2004). However, this mechanism is generally restricted to regions with limited rainfall and regular seismic activity (Aspiandar et al., 2006). Capillary Rise Capillary rise can aid in upward migration of metal-bearing groundwater several metres above the water table, as surface tension of the air-water interface generates an upward pull at the water table (Aspiandar et al., 2006). Water will continue to rise as the curvature of pores is small enough to generate a hydraulic gradient across the air-water interface (Gillham, 1984). In coarse sand, capillary rise can account for a maximum of 0.15 metres of fluid migration; 0.3 metres in medium sand; 1 metre in fine sand; 1-10 metres in silt; 10-30 metres in clay, and greater for colloidal sized material (Jumikis, 1967; Mann et al., 2005). 17 1.6 Current Exploration Techniques for Kimberlites in Glaciated Terrain Exploration for mineral deposits in glaciated terrain requires the understanding of several variables, including: past glacial movement directions; glacial sediment thickness; bedrock topography; and the bedrock and surficial geology at an appropriate scale (McClenaghan and Kjarsgaard, 2001; Paulen, 2013). The distance from the dispersal train to the source, located in the up-ice direction, may be determined by applying each of the aforementioned concepts (Paulen, 2013). Furthermore, multiple cycles of till re-entrainment and deposition may obscure the dispersal train or generate a palimpsest train (reworked dispersal train) (Paulen, 2013). If not recognized prior to sampling, only a portion of the train may be sampled, or traced up-ice in the wrong direction. Therefore, understanding the strength of each past glacial trajectory will aid in understanding the entirety of the dispersal train and the narrowing down of potential target areas (Paulen, 2013). Glacial sediment sampling and stream sediment sampling for kimberlite indicator minerals (KIMs) and kimberlitic boulders are currently the most common kimberlite exploration techniques in glaciated terrain to detect a clastic dispersal signal (McClenaghan et al., 1997; McClenaghan and Kjarsgaard, 2001; Thorleifson, 2013). KIMs are mantle-derived, high pressure minerals (megacrysts and/or macrocrysts) brought to surface via entrainment in kimberlite magma, and exhibit visual and compositional characteristics distinct from crustal minerals (Nowicki et al., 2007). Chemical compositions of certain KIMs may also give insight as to whether the kimberlite has sampled the mantle within the diamond stability field (Nowicki et al., 2007). As they are commonly dispersed into the secondary environment, but resistant to weathering, they are appropriate to use as kimberlite indicator minerals (Nowicki et al., 2007). 18 Common KIMs include: Cr-pyrope; eclogitic garnet; Cr-diopside; Mg-ilmenite (picroilmenite); Cr-spinel (chromite); olivine; and occasionally, diamond (Muggeridge, 1995; McClenaghan et al., 1997; McClenaghan and Kjarsgaard, 2001; Nowicki et al., 2007). KIM sampling typically involves large sample sizes (10-20 kg) of C horizon soil (Chapter 4; Thorleifson, 2013). Samples are screened in the field to remove large clasts (McClenaghan and Kjarsgaard, 2001). Sampling media may include frost boils, glaciofluvial sand from eskers, braided subaerial outwash, proximal subaqueous outwash, kames, or moraines; however, medium to very coarse sand should be present to obtain the ideal sediment fraction for indicator minerals and to avoid eolian and littoral deposits (McClenaghan and Kjarsgaard, 2001). If present, fluvial, glaciofluvial or beach sediment are sampled for KIMs first (Mckinlay et al., 1997), and till sampling is undertaken next at a regional scale (McClenaghan and Kjarsgaard, 2001). If areas of interest are identified, a higher sampling density is undertaken in conjunction with airborne geophysical surveys (Mckinlay et al., 1997). In regions where till is thin, samples are collected down-ice of geophysical anomalies or targets along transects perpendicular to the dominant ice-flow direction (McClenaghan and Kjarsgaard, 2001). It is imperative that the regional and local glacial history are known at this stage for proper data interpretation (McClenaghan and Kjarsgaard, 2001). Once samples are collected, heavy mineral concentrates are prepared (McClenaghan and Kjarsgaard, 2001). KIMs are picked from medium sand (0.25-0.5 mm), coarse sand (0.5-1.0 mm), or very coarse sand (1.0-2.0 mm), though they are most abundant in the medium sand fraction (McClenaghan and Kjarsgaard, 2001; Nowicki et al., 2007). KIMs are then separated and analysed using analytical methods such as qualitative electron microprobe to determine 19 major and trace element composition to evaluate the diamond potential of the kimberlite (Ward et al., 1996; McClenaghan et al., 1997; McClenaghan and Kjarsgaard, 2001). Dispersal trains are easier to locate than kimberlites due to their larger size (McClenaghan et al., 1997). A sample spacing of tens of kilometres (continental scale) may detect large-scale trains hundreds of kilometres long, whereas kilometre-scale (regional) sampling may detect a kimberlite cluster (McClenaghan et al., 1999). Sample spacing at the metre scale (local) may be used to delineate narrow trains or to test deposit-scale targets (McClenagan et al., 1997). Soil or till geochemical surveys are gaining popularity as they use smaller sample sizes, are more versatile in local and regional surveys, and are significantly cheaper and faster than till sampling for indicator minerals (McClenaghan and Kjarsgaard, 2001). Kimberlites possess unique major and trace element compositions; thus, soil geochemical surveys may be used to detect kimberlites or their dispersal trains (McClenaghan and Kjarsgaard, 2001). Kimberlite pathfinder elements include: Ni; Cr; Ba; Co; Sr; Rb; Nb; Mg; Ta; Ca; Fe; K; Ti and REEs (McClenaghan and Kjarsgaard, 2001). The usefulness of the aforementioned pathfinder elements depends in part on the kimberlite composition, in addition to the surrounding bedrock composition (McClenaghan and Kjarsgaard, 2001). Kimberlites can also be distinguished from other mafic or ultramafic rocks geochemically, as kimberlites are much more enriched in Cs, Rb, Ba, Th, U, Ta, Nb, La, Sr, and P (Mitchell, 1986). The element migration mechanisms described in Section 1.5.3 generate anomalies which may be detected using different techniques, determined by the host of the element or the binding mechanism (generally identified via selective or sequential leaches) (Seneshen, 1997; Hall, 20 1998). B horizons (Chapter 4) are typically sampled as they contain elements that may be dispersed by aqueous or gaseous processes, such as those detailed above (McClenaghan et al., 1997; Thorleifson, 2013). Anomalies generated by the movement of groundwater via advection, including groundwater upwelling, convection, and bubble migration, in addition to capillary rise, diffusion and electrochemical migration, may be detected using a selective leach. These anomalies are post-transport and are considered labile elements in a secondary environment, which may bind by chemical sorption, precipitation, chelation or complexation (Hall, 1998). Elements which are transported by glacial processes may be less mobile, and therefore may require stronger digestions (Seneshen, 1997). Organic geochemical anomalies associated with redox variations may be detected using techniques which analyse hydrocarbon type and abundance (Sutherland et al, 2004; Sutherland, 2007; Hamilton, 2007). Physicochemical anomalies may be detected by the use of probes which detect redox potential, electrical conductivity, hydrogen ion concentration, and total dissolved solids (Hamilton, 2007). Chapters 3 and 5 outline methods employed for anomaly detection at the DO-18 kimberlite and their results, respectively. 1.7 Summary Attention is being aimed at surficial geochemical target discrimination techniques in drift-covered terrains, such as the Lac de Gras region of the Northwest Territories, as it is presumed that many kimberlites remain undiscovered. The young age of the glacial sediments which covers many kimberlites, including the DO-18 kimberlite, presents more challenges in determining which element migration mechanisms are responsible for the geochemical anomalies reported. Migration mechanisms proposed include: clastic dispersion (physical 21 movement); advective transport within the phreatic zone, including groundwater flow along a hydraulic gradient, convection, and bubble migration; electrochemical dispersion; diffusion; and capillary rise in the vadose zone. Objectives of this study include: 1) identifying the presence of a kimberlite using surficial geochemistry; 2) data integration with geomorphological process models to understand the mechanism and evolution of the geochemical responses; and 3) refine current sampling and analytical strategies. 22 Chapter 2: Geologic Overview 2.1 Geology and Tectonic Evolution of the Slave Province The Slave craton is approximately 213,000 square kilometres in area (Padgham and Fyson, 1992) and is host to a range of intrusive and extrusive rocks of the Yellowknife Supergroup (YKSG). These rocks are up to approximately 3.96 Ga in age, the oldest being the Acasta gneisses (Bowring et al., 1989). The YKSG is bound on the west by the Wopmay Orogen, and on the east by Thelon Magmatic Zone (Figure 2.1; Hoffman, 1989; Davis, 1991). Archean rocks of the Slave province are commonly divided into three lithotectonic groups (Davis, 1991; Yamashita et al., 1999): 1. 3.96 – 2.84 Ga pre-Yellowknife Supergroup (pre-YKSG) basement; 2. the 2.72 – 2.65 Ga Yellowknife Supergroup (YKSG), and; 3. late-Archean (2.62 – 2.58 Ga) felsic granitoids, largely coeval with the 2.63 – 2.58 Ga regional metamorphism, deformation and associated plutonism (Fyson and Helmstaedt, 1988; Davis, 1991; Davis et al., 1994; Yamashita, 1998; and Yamashita et al., 1999). Pre-YKSG basement rocks include granitoids, heterogeneous gneisses and supracrustal sequences and are observed mainly in the western Slave province (Bowring et al., 1989; Hoffman, 1989; Isachsen and Bowring, 1994;). These rocks dominantly consist of amphibolitic-tonalite and tonalitic gneisses, massive tonalites and granites (Frith et al., 1986). The 3.96-2.84 Ga age range suggests the basement rocks are composed of early, mid and late-Archean rocks, though their relationship remains undetermined (Davis, 1991). 23 Figure 2.1. Simplified geologic map of the Slave province (modified after Davis et al. 1994), after Hoffman (1989). 24 Supracrustal rocks of the YKSG are characterized as greywacke-mudstone with turbidite deposits (Henderson, 1981; Lambert and van Breemen, 1991; Yamashita et al., 1999), which generally overlie plutonic and volcanic sequences. However, the overall tectono-stratigraphic relationship between the igneous and sedimentary rocks is not well documented (Davis, 1991, Davis et al., 1994). Plutonic and volcanic rocks exhibit compositions of the bimodal tholeiitic series and calc-alkaline intermediate series (labelled by Padgham (1992) as Yellowknife-type and Hackett-River type, respectively). 2.66 Ga turbiditic sedimentary rocks comprise nearly 80% of the YKSG, and exhibit a mixed volcanic and plutonic provenance (Henderson, 1981; Hoffman, 1989; Lambert and van Breemen, 1991). It is possible that these turbidites could have been deposited any time between the age of volcanic rocks (2.7 – 2.67 Ga; Kusky, 1989) incorporated into the turbidites and the 2.6 Ga deformation and plutonism (Davis, 1991). Younger 2.62 – 2.59 Ga sandstone and polymictic conglomerates unconformably overlie the turbidite sequences (Isachsen and Bowring, 1994). The late Archean granitoids are typically divided into 2.62 – 2.60 Ga syn-deformational granitoids and 2.60 – 2.58 Ga post-deformational granitoids (Davis, 1991; Davis et al., 1994; Yamashita, 1998). Earlier granitoids exhibit metaluminous to weakly peraluminous granodiorite compositions, to peralumionous tonalite to syenogranite compositions in later granitoids (Davis, 1991; Davis et al., 1994). These granitoids are contemporaneous with the 2.63 – 2.58 Ga regional deformation in addition to the greenschist to granulite facies metamorphism (Yamashita, 1998). Syn-deformational granitoids include: the Defeat, Consession and Seige plutonic suites, and the 2.61 Ga granitoids from the Wijinnedi Lake region (Davis et al. 1994). Post-deformational 25 plutonic suites comprise the Stagg, Awry, Prosperous, Contwoyto and Yamba suites, as well as granitoids from the Wijinnedi Lake and MacNaughton Lake regions (Yamashita et al., 1999). Several contrasting models have been suggested for the tectonic evolution of the Slave province. Models proposed by Kusky (1989), Fyson and Helmstaedt (1988), and Yamashita (1998) are briefly described below to provide insight into the variation of interpretations, but do not exhaust all models suggested by additional authors. Fyson and Helmstaedt (1988) propose a model analogous to the geologic evolution of Newfoundland. First, the tectonic evolution of the Slave province began with the rifting of sialic basement crust predating ~3 Ga, producing oceanic crust. This was followed by the closure of that basin via east-dipping subduction, and obduction of oceanic crust onto the western Slave. Concurrently in the eastern slave province, subduction resulted in calc-alkaline magmatism. As tectonic underplating of the eastern Slave province ensues with subduction of the western Slave province, a westward migration of calc-alkaline magmatism continues. Fyson and Helmstaedt further suggest that the zig-zag pattern of granitoid contacts was likely the result of the granitoid intrusions following fracture systems within the basement crust. The small age range of the late Archean plutonism is explained by rapid basin closure and consequent swift westward migration of subduction (Fyson and Helmstaedt, 1988). Kusky (1989) proposed that the Slave province can be divided into four high-strain zones which have been juxtaposed upon collision. From west to east, these zones include: the Anton terrane, an Archean microcontinent; the Sleepy Dragon terrane, an exhumed wedge of the 26 eastern portion of the Anton terrane; the Contwoyto terrane, a westward verging fold and thrust belt; and the Hackett River terrane, an Archean island arc. The Contwoyto and Hackett River terranes collided after an east-dipping subduction event, and are thus referred to as the Contwoyto and Hackett River accretionary prism and island arc. Kusky (1989) presents a model in which east-dipping subduction causes the collision of the 3.48 Ga Anton terrane quartzofeldspathic gneisses, overlying sedimentary sequences and mafic dykes with the Contwoyto terrane and Hackett River arc accretionary prism and island arc. Continued convergence resulted in the uplift and transportation of the Sleepy Dragon Complex with greenstone slivers. Late to post-tectonic granitoid intrusions ensue with increased crustal thickening (Kusky, 1989). Yamashita (1998) suggests the evolution of the Slave province began with the 4.0 Ga Acasta gneisses, which later underwent an unconstrained tectonomagmatic event, producing the 3.4 Ga tonalites. Although this tectonic environment remains undetermined, the continuous northwest to southeast younging of tonalites and felsic volcanics suggest north-northwestward subduction of oceanic crust (Yamashita, 1998). Following a period of repose, westward subduction of oceanic crust began at 2.72 Ga; this event generated a felsic-dominated fore-arc setting in the eastern Slave province and a mafic-dominated back-arc setting in the west-central Slave, reminiscent of the present-day tectonic setting of Japan (Yamashita, 1998). At about 2.64 Ga, the YKSG volcanic and plutonic activity was discontinued by the collision of a portion of crust (hypothesized to no longer exist) in the eastern-most slave province. This collision would explain the time gap between the syn-volcanic plutons and later syn- to post-deformational magmatism corresponding to the back-arc basin closure and consequent crustal thickening 27 (Yamashita, 1998). Partial melting of existing mafic crust in addition to mantle-derived magma generated the 2.61 Ga metaluminous to peraluminous granitoids. The final stage of this model entails 2.59 Ga post-deformational peraluminous granitoids generated through partial melting of either tonalitic or sedimentary rocks. This shift in granitoid chemistry from metaluminous to peraluminous is in agreement with the stratigraphy of the back-arc system, essentially sedimentary rocks overlying igneous rocks (Yamashita, 1998). Following the accretion of the Slave province, four swarms of Proterozoic aged diabase dykes intruded the Archean units. The earliest dyke swarm is the northeast trending Malley dykes (2.23 Ga), followed by the east trending MacKay dykes (2.1 Ga), the north trending Lac de Gras swarm (2.02 Ga), and the youngest, northnorthwest trending Mackenzie swarm (1.27 Ga) (LeCheminant and van Breemen, 1994). Subsequent deposition of Paleozoic carbonates occurred in the southwestern and north central Slave, followed by Cretaceous marine sediments comprising silts and shales deposited by an inland sea (Doyle et al., 1999). Kimberlites have intruded each of the aforementioned units in both the eastern and western Slave province (Pell, 1997; Eggleston et al., 2014). The Slave province provides a favourable setting for diamondiferous kimberlites as it contains a stable Archean craton with a cool mantle root (Pell, 1997). This is essential for the formation of conditions favourable for diamond stabiltiy (as per favourable temperature, pressure and redox conditions outlined by Haggerty (1986)). Kimberlites in the Lac de Gras region are generally distributed in an arcuate pattern (Pell, 1997) which trends northwest of Lac de Gras for approximately 135 kilometres, changing trend to the northeast for approximately 100 kilometres. This research focuses on the 28 DO-18 kimberlite, part of the Tli Kwi Cho kimberlite complex, a member of the Lac de Gras kimberlite cluster (Doyle et al., 1998; Harder et al., 2009). 2.2 Geology of the DO-18 Kimberlite The DO-18 kimberlite is a part of the Tli Kwi Cho kimberlite complex comprising the DO-18 and DO-27 kimberlite (location shown in Figure 2.2). DO-27 lies approximately 400 m south of DO-18. The kimberlite complex intruded a post-deformational, two-mica, aluminous, garnetiferous granitoid, which had previously assimilated supracrustal turbidites (Doyle et al., 1999; Eggleston et al., 2014). These host rocks in particular have been labelled by the Geological Survey of Canada (GSC) as ‘undifferentiated Archean granitoids’ (Figure 2.3). Overall mineralogy of the granitoid is characterized by quartz, potash, albite, biotite, muscovite, hornblende, epidote apatite, chlorite, sillimanite and garnet (Doyle et al., 1999). At the time of emplacement of DO-18, Cretaceous mudstones overlapped the Archean granitoids. Mudstones present at the surface were deposited during the northernmost standstill of the Western Interior Seaway, and during the DO-18 pipe emplacement were integrated into the pipe infill, though have since been eroded away (Doyle et al., 1998, Harder et al., 2008). These mudstones range from dark brown to silvery grey and can be soft, unconsolidated matrix material or hard, distinct clasts. Marine palynomorphs found within these mudstones are dominantly dinocysts. Non-marine palynomorphs, including fern spores and conifer and angiosperm pollen were also found within these mudstones, and also in cedar wood fragments (Doyle et al., 1999). The presence of both marine and non-marine palynomorphs indicate a dominantly terrestrial environment into which the DO-18 kimberlite was emplaced, but with a strong marine influence, perhaps in a near shore environment, following a marine transgression 29 (Doyle et al., 1999, Harder et al., 2008). Palynology dating of the sediments constrains the age of DO-18 to be between 75 to 45 Ma, or Late Cretaceous to Eocene in age (Doyle et al., 1998; Doyle et al., 1999; Harder et al., 2008). Figure 2.2. Location of the DO-18 and DO-27 Kimberlite (modified after Harder et al., 2009). Coordinates given in UTM NAD83 Zone 12N. 30 Figure 2.3. Local geologic map of the study area. Modified from geologic map of the Slave craton compiled by Hoffman and Hall (1993), from Open File 2559, Geological Survey of Canada. Coordinates given in UTM NAD83 Zone 12N.31 The DO-18 kimberlite is a Group I kimberlite with a projected surface expression under till of about 4 hectares, with a classic kimberlite carrot shape (Harder et al, 2008). DO-18 is mainly comprised of pyroclastic kimberlite, though re-sedimented volcaniclastic kimberlite (RVK) is occasionally observed along the southern pipe margin (Harder et al., 2008). The high content of marginal country rock breccias and accessory granite is a feature atypical of Lac de Gras kimberlites. Overall, the DO-18 pipe was likely excavated and infilled by a relatively low energy and short lived eruption (Harder et al., 2008). Two main kimberlite domains are identified, labelled KIMB-1 and KIMB-2 (Figure 2.4; Harder et al., 2008). KIMB-1 is the most dominant phase, and is green-grey in colour, clast supported, poorly sorted, and contains 30-40% fine to medium grained serpentinized olivine. The mineralogy of KIMB-1 is typified by high levels (>25%) of country rock granite, lesser occurrences of RVK, and an interclast matrix of serpentine and kimberlitic ash (Harder et al., 2008). Juvenile clasts (kimberlitic pyroclastic material consequent of eruption processes) comprised of an olivine phenocryst-rich clast type and a phlogopite bearing clast type are present and are in <10% abundance. Mineral composition data indicate that the kimberlite sampled the mantle within the diamond stability field. The indicator mineral suite is dominated by peridotitc garnets, Cr-diopside, with lesser chromite and eclogitic and pyroxenitic garnet (Harder et al., 2008). KIMB-1 is classified as a pyroclastic kimberlite, as it was likely deposited by primary pyroclastic processes (Harder et al., 2008). It is likely that the formation of KIMB-1 was via the collapse of an eruption column during early emplacement, as two distinct juvenile clast types are present, indicative of mixing of two separate kimberlite phases. It is possible that this was the result of 32 Figure 2.4. Cross sections of the DO-18 kimberlite showing the distribution of KIMB-1 and KIMB-2 units. Both OTHER-K and RFW units are classified as RVK, however, they are not discussed in this section (modified after Harder et al., 2008).33 incorporation of material from an earlier eruption of DO-18, or perhaps by inclusion of material from a nearby kimberlite volcano into the eruption column (Harder et al., 2008). Fresh KIMB-2 is grey brown in colour, locally bedded and juvenile clast rich, with an interclast matrix of mud and kimberlitic ash, in addition to accretionary lapilli with concentric rims of mud and kimberlitic ash (Harder et al., 2008). Distinct bedding is visible in terms of granitic xenocrysts, olivine grain size and mud clasts. Granitic xenocrysts make up roughly 40% of KIMB-2, though this unit contains less accessory granite than KIMB-1. KIMB-2 displays a more complex texture than KIMB-1, ranging from clast-supported in granitic xenocryst-rich areas to matrix-supported by mud and kimberlitic ash (Harder et al., 2008). Approximately 25-30% of KIMB-2 is comprised of serptentinized olivine, though local variation can range from 15-40%, particularly in regions where distinct bedding is observed. Glauconite-bearing mud clasts are a distinct feature to KIMB-2 (Harder et al., 2008). Juvenile clasts make up less than 5% and are the same as those found in KIMB-1, indicating that they are sourced from the same kimberlite phase, and thus the mantle component is the same in both units (Harder et al., 2008). KIMB-2 is texturally classified as a resedimented volcaniclastic kimberlite (RVK), as it is primarily re-sedimentation of the extra-crater deposits (Harder et al., 2008). The difference in observed textures between KIMB-1 and KIMB-2 is likely caused by different primary volcanic and secondary re-sedimentation processes, as opposed to separate kimberlite eruption phases (Harder et al., 2008). Boundaries between KIMB-1 and KIMB-2 are gradational, indicating that during lower intensity or lulls in pyroclastic emplacement of KIMB-1, re-sedimentation processes of KIMB-2 were active (Harder et al., 2008). 34 2.3 Discovery History of the Tli Kwi Cho Kimberlite Complex The claims comprising the Tli Kwi Cho kimberlite complex were targeted for geophysical and geochemical exploration in 1992, following the announcement of the Point Lake (Ekati) discovery in 1991 in the Lac de Gras kimberlite field, which sparked the largest staking rush in North American history (McClenaghan et al., 2002; Eggleston et al., 2014). Three airborne electromagnetic (EM) surveys were conducted with the aim of kimberlite detection, a frequency domain in 1992, and two time-domain surveys in 2003 and 2004. The airborne frequency domain survey (DIGHEM) was flown above the Tli Kwi Cho kimberlite complex in 1992, discovering the DO-18 and DO-27 kimberlites. Several subsequent surveys, including two ground magnetic surveys, an airborne magnetic/electromagnetic/VLF-EM survey, a nanoTEM survey and ground gravity survey were conducted in 1993 to aid in confirming an delineating the Tli Kwi Cho kimberlite complex (Jansen and Witherly, 2004; Eggleston et al., 2014). These targets were also confirmed via drill testing in 1993 (Eggleston et al., 2014; Fournier et al., 2014). The DIGHEM data collected in 1992 measured five frequencies ranging from 900-56k Hz. Surveys were flown directly east at a 200 metre line spacing, with measurements taken every 10 metres along the line (Figure 2.5a and b; Fournier et al., 2014). In 2003, an AeroTEM survey was conducted by Aeroquest, in which 19 lines were surveyed at 75 metre separation, with measurements taken every 3 metres along the lines (Figure 2.5c; Fournier et al., 2014). In 2004, a VTEM survey was completed by Geotech, with 20 lines oriented 90 ⁰E at 75 metre line spacing, and a 10 Hz sampling frequency (Figure 2.5d; Fournier et al., 2014). The surveys outline the kimberlites well, and reveal no major structural features. 35 Figure 2.5. a) and b) DIGHEM Interpolated I[Bz] and R[Bz] components, respectively, at 900 Hz collected from the coplanar orientation. c) shows interpolated AeroTEM data, d) shows interpolated VTEM data (modified after Fournier et al., 2014). Kimberlites are delineated well, and surveys reveal no major structural features. 2.4 Glacial History of the DO-18 Region During the peak of the Late Wisconsinan glaciation, the Slave province was capped by the 2-4 kilometre thick Keewatin Sector of the Laurentide Ice Sheet (Dyke and Prest, 1987; Dredge et al., 1994). In the Slave province, till is the most abundant surficial sediment type, 36 deposited by several glacial advances (Dredge et al., 1994). At the regional scale, till can be divided into thin veneers, blanket deposits up to 10 metres thick, and hummocky till up to 30 metres thick, though only one stratigraphic unit of till is recognized (Dredge et al., 1994; Ward et al., 1994; Dredge et al., 1999). Deglaciation in the Slave province is characterized by rapid eastword retreat, beginning approximately 10 14C ka BP, and uncovered the Lac de Gras region by approximately 9.0 – 8.5 14C ka BP (Dyke and Prest, 1987; Dyke, 2004). Isolated beaches and wave-cut terraces in the region indicate that lake levels were higher during and immediately after deglaciation due to the influx of glacial meltwater (McClenaghan et al., 2002; Dyke, 2004). Related meltwater features include glaciofluvial sediments deposited by meltwater channels, as well as fine-grained glaciolacustrine deposits in low-lying areas, often overlain by organic deposits (McClenaghan et al., 2002). Three dominant ice flow directions have been identified (Dredge et al., 1994; Ward et al., 1996). The oldest of these flowed towards the southwest, followed by flow towards the west, and then the youngest flow towards the west to northwest (Figure 2.6). Striae, grooves, crescentic and lunate fractures on the property suggest the most recent ice direction was 290⁰ – 295⁰ (Dredge et al., 1994; Ward et al., 1994). Of these ice flow directions, the last direction to the west-northwest is the most significant for the dispersal of kimberlite indicator minerals. Well-established plumes of indicator minerals oriented in this direction emanate from both DO-18 and DO-27, as well as other well-known deposits in the region (e.g. Ekati, Diavik, Ranch Lake) (Doyle et al., 1998; Doyle et al., 1999; McClenaghan et al., 2002). Till, cryoturbated by polygonal frost boils, and frost-heaved granitic boulders dominate the glacially-derived surficial 37 material above the Tli Kwi Cho kimberlite complex (Eggleston et al., 2014). Till covering the DO-18 kimberlite is between 5 and 20 metres thick (Eggleston et al., 2014). Figure 2.6. Evolution of ice movement directions in the Lac de Gras region (modified after Dredge et al., 1994). The star marks the location of the research site. 2.5 Summary The DO-18 kimberlite intruded a post-deformational, two-mica granitoid, located within the Lac de Gras kimberlite province within the Archean Slave craton. The Slave craton consists of three lithotectonic groups: 1) 3.96 – 2.84 Ga pre-Yellowknife Supergroup (pre-YKSG) basement, 2) 2.72 – 2.65 Ga Yellowknife Supergroup (YKSG), and 3) late-Archean (2.62 – 2.58 Ga) felsic granitoids. The DO-18 kimberlite, which intruded the post-deformational granitoid, is Late Cretaceous to Eocene in age. It is characterized by two main kimberlite lithologies, labeled KIMB-1 (the most dominant phase) and KIMB-2, a pyroclastic kimberlite and a resedimented 38 volcaniclastic kimberlite, respectively. KIMB-1 is green-grey in colour, clast supported, poorly sorted, contains 30-40% serpentinized olivine, high levels of country rock granite and an interclast matrix of serpentine and kimberlitic ash. KIMB-2 is characterized by 25-30% serpentinized olivine, glauconite-bearing mud clasts and regions of distinct bedding. Gradational boundaries between KIMB-1 and KIMB-2 indicate that during lulls in pyroclastic emplacement of KIMB-1, resedimentation processes of KIMB-2 were active. During the Late Wisconsinan the region was covered by the Laurentide Ice Sheet, which retreated approximately 9.0-8.5 ka 14C BP, concealing the DO-18 kimberlite beneath 5-20 metres of till. In 1992, an airborne frequency domain survey was flown above the Tli Kwi Cho kimberlite complex in 1992, discovering the DO-18 and DO-27 kimberlites. These targets were later confirmed by additional geophysical surveys and drill testing in 1993. 39 Chapter 3: Methodology 144 sample sites were planned in a 16 x 9 grid, at 50 m E-W x 60 m N-S spacing, covering approximately 0.4 square kilometres (Figure 3.1; UTM coordinates given for each figure are given in NAD83 Zone 12N, unless noted otherwise). The grid was oriented parallel to the ice flow direction (290⁰-295⁰; Chapter 4). Due to an unforeseen decrease in available time (three weeks) in the field with helicopter support, the sampling program was re-evaluated in the field (Section 3.1). Figure 3.1. Planned sample points above the DO-18 kimberlite. Sampling grid was planned parallel to ice movement direction. 40 3.1 Sampling Program Design Five of the planned sites were inaccessible due to high water levels in the river valley in the southwest corner, leaving 139 available sample sites (Figure 3.2). At each site, Gore-Sorber® hydrocarbon collectors from Amplified Geochemical Imaging (AGI) Inc. were installed prior to soil sampling. 121 sites were soil sampled (time constraints prevented collection of all 139 planned samples); one third of which were collected directly above the kimberlite, with the remaining two thirds collected off the kimberlite to adequately evaluate background geochemistry. Surficial data, including physical parameters of sample media, topography, vegetation, and physicochemical measurements were also recorded at each site. Figure 3.2. Soil sample and AGI Gore Module installation sites in the DO-18 research area. Note that AGI Inc. GoreSorberTM hydrocarbon collectors were also installed at soil sample sites. 41 3.1.1 Global Positioning System (GPS) Navigation The Garmin GPSMAP® 64 was used for in-field navigation to each sample site, as well as for traversing during surficial sediment mapping (refer to Appendix A.1 for complete mapping procedure). The coordinates of the actual sample site were recorded as a waypoints (location recorded and stored in the device). 3.2 Soil Sample Collection Approximately 1 kg of the top 1-11 centimetres of the B horizon soil were the targeted sample media for soil sampling. The top 1 centimetre of the B horizon was not collected to avoid contamination from the horizon above. Separate samples were collected for geochemical, SGH, and microbiological (not presented in this thesis) analyses. The B horizon was targeted as it is organic poor, and it is the zone of accumulation of metal, particularly due to the leaching of above horizons by organic acids (Chapter 4; Jackson, 1995; Hamilton, 2007; Seneshen, 1997). In cases where permafrost prevented sampling the B horizon, O horizon material (peat) was collected from as deep as possible. Where cryoturbation caused mixing of B with C horizons (generating a BC horizon), or where B horizons were not present, samples were taken from BC and C horizons. Samples were screened using a 0.25 inch stainless steel screen in the field prior to collection to remove large clasts. Refer to Appendix A.2 for full sampling procedure. 3.2.1 Environmental Considerations To prevent contamination or introduction of foreign material by geomorphological processes, slopes were avoided when sampling. To restore the environment post-sampling, holes 42 were backfilled with the removed sediment and vegetation ‘caps’ were replaced, to avoid potential hazards for wildlife and damage to the local environment. 3.2.2 Anthropogenic Considerations The DO-18 kimberlite was previously an exploration target; thus, drilling and foot traffic may have introduced anthropogenic influence. Waste products from previous drilling programs, including tarps and drill casings, were present at the research site. Where evidence of potential contamination was present, these sites were avoided when sampling and the sample site was relocated. 3.3 Surficial Field Data Physical parameters and physicochemical measurements of each soil horizon were recorded at each site prior to sample collection. Physical parameters included: soil horizon depth; thickness; colour; grainsize; textures; clast abundance, type, shape and size; vegetation cover; and sediment type. In-situ physicochemical measurements were taken using probes inserted into each soil horizon. These measurements included: electrical conductivity (EC), measured using the Hanna HI 98331 Direct Soil Conductivity and Temperature Meter; pH, using the Bluelab Soil pH pen; and soil moisture, recorded with the Extech Instruments MO750 soil moisture meter. Soil slurry measurements (using a 1:1 soil to water volume ratio) of pH, acidified pH, and total dissolved solids (TDS) were taken using the Oakton Multi-Parameter PTTestr® 35 pH & TDS Meter. Oxidation-reduction potential (ORP) was measured using the Oakton Waterproof ORP Testr® 10 with Ag/AgCl electrode. The probe remained in the slurry for approximately 30 seconds to stabilize prior to recording results. Refer to Appendix A.2 for entire procedure. 43 3.4 Soil Geochemical Analyses 3.4.1 Inorganic Geochemistry Samples from each of the 121 sites (136 samples total, including field duplicates and certified reference materials (CRMs)) were submitted to ALS Minerals Laboratories in North Vancouver. Prior to each analysis, samples were dried at <60 ⁰C and sieved to -180 microns as per standard ALS Minerals sample preparation procedures for soil samples. The -180 micron fraction was analysed using 4-Acid Digestion (ME-MS61), Aqua Regia Digestion (ME-MS41L), and De-Ionized Water Leach with pH (pH-MS03), each coupled with ICP-MS. Samples were also analysed by Field-portable X-Ray Fluorescence (fp-XRF) using the Olympus Delta DP-6050-CC at 50 keV to determine whole rock geochemistry (including Si), at the University of British Columbia (UBC). Fp-XRF was completed on the unused portion of the dried -180 micron fraction soil samples. Following initial analysis and result evaluation, seven samples were selected for a Sequential Leach analysis to identify the mineral phases in the soil hosting the geochemical responses, two of which were anomalous in Cr, Nb, Mg and Ni, and five of which were background samples. Sequential Leach analyses comprised several selective leaches applied sequentially, including: a De-Ionized Water Leach (ME-MS03); Ammonium Acetate Leach (ME-MS04); Cold Hydroxylamine Hydrochloride Leach (ME-MS05); Hot Hydroxylamine Hydrochloride Leach (ME-MS06); Sodium Pyrophosphate Leach (ME-MS07); Aqua Regia Digestion (ME-MS41L); and 4-Acid Digestion (ME-MS61), each coupled with ICP-MS. Refer to Appendix A.3 through A.6, as well as A.8 and A.10 for the complete procedure of each analysis. 44 3.4.2 Organic Geochemistry Total organic carbon (C-IR06a) was analysed on the full sample suite at ALS Laboratories on the -180 micron fraction. Refer to Appendix A.7 for total organic carbon analysis procedure. Samples were also sent to Activation Laboratories (ActLabs) for Spatiotemporal Geochemical Hydrocarbon (SGH) analysis to determine the total content of hydrocarbon classes (Chapter 5) in the C5 to C17 range adsorbed onto materials near-surface. Samples are dried at 40 ⁰C and sieved to the -250 micron fraction. A hexane and acetone extraction is applied to samples to extract surface-bound hydrocarbons (P. Winterburn, pers. commun., 2017). Extractants are analysed using gas chromatography – mass spectrometry (GC-MS). Refer to Appendix A.12 for complete SGH analysis procedure. Hydrocarbon compounds are considered to be the hydrocarbons mobilised from the deposit at depth (www.actlabs.com). An interpretation of the data was also provided by ActLabs (Appendix E.1). AGI Gore-Sorber® hydrocarbon collectors were installed in the research area at each of the 139 sites prior to soil sample collection and remained for 21 days to accumulate hydrocarbons, though 60 days insertion time is considered optimal (Refer to Appendix A.13 for complete installation procedure). Comprised of an adsorbent enveloped in a hydrophobic expanded polytetrafluoroethylene (ePTFE) membrane, Gore-Sorber® modules do not allow penetration of soil or water, but hydrocarbons are able to diffuse through the membrane to the adsorbent (Anderson, 2006). Gore-Sorber® module installation involved first clearing the surface of vegetation to avoid contamination, and subsequent insertion using a metal rod to a depth of 40 to 66 centimetres. Hydrocarbons in the C2 to C20 range, in addition to carbon dioxide 45 and several organo-sulphur compounds were later analysed by thermal desorption GC-MS. Upon completion of analysis, AGI Inc. also provided a QA/QC assessment and interpretation of the data (Appendix E.2). 3.5 Spontaneous Potential A spontaneous potential (SP) survey was conducted in three east-west transects: two above the kimberlite (sites 48 to 59 and 64 to 79) and one transect north of the kimberlite (sites 128 to 143). Cu (solid)-CuSO4 (gel) electrodes were linked by 1 kilometre of insulated, 80 gauge copper wire and connected to a voltmeter. Stationary electrodes were installed at the westernmost site of each transect and the mobile electrode was used to measure the latent voltage differential in mV at 50 metre intervals. Refer to Appendix A.14 for complete procedure. 3.6 Lithogeochemistry of the DO-18 Kimberlite Three drill core samples of the DO-18 kimberlite were lent to this project by Peregrine Diamonds Ltd., in addition to a highly weathered, clay-rich sample donated by the Northwest Territories Geological Survey (NTGS). Lead isotope analysis (PbIS-RAT61) and whole rock analysis (CCP-PKG01) was undertaken at ALS Minerals Laboratories to characterize the geochemical changes of increasingly weathered kimberlite (Appendix A.9 for complete analytical procedure). 46 3.7 Petrography of the DO-18 Kimberlite Petrography was completed on the aforementioned drill core samples of DO-18 at the UBC Microscopy Lab (Appendix A.11), using the Nikon Eclipse E600 POL polarizing microscope. Photomicrographs were taken using the Canon Rebel EOS T21 camera. 3.8 X-Ray Diffraction Analysis X-Ray diffraction (XRD) analysis was completed using the Bruker D8 Focus (0-20 LynxEye detector) X-ray diffractometer. This was undertaken on a separate portion of the same seven samples as those submitted for sequential leach analysis to confirm which mineral phases were present in the soil. Data was analysed using DIFFRAC.EVA software. Refer to Appendix A.15 for the complete procedure. 3.9 Quality Assurance/Quality Control 3.9.1 Soil Sampling To avoid contamination between soil horizons and between sample sites, instruments and equipment were cleaned after each measurement. When mottling of soil horizons was observed, samples were collected beneath the mottling to avoid potential sampling of other horizons. A ‘clean hands/dirty hands’ sample protocol ensured samples and in-situ measurements were taken by one person while the other person cleaned and sanitized equipment with ethanol to avoid contamination. 47 3.9.2 Surficial Field Data Regular calibration of instruments prevented analytical drift. The Bluelab Soil pH Pen, Oakton Multi-Parameter PTTestr® 35 pH & TDS Meter and Hanna HI 98331 Direct Soil Conductivity and Temperature Meter were calibrated daily. The calibration of the Oakton Waterproof ORP Testr® 10 Meter or Extech Instruments MO750 soil moisture meter was checked regularly, and calibration proved unnecessary. Duplicate measurements were taken at every 18th field site in a duplicate hole to determine reproducibility. Refer to Appendix B.1 for duplicate analysis of physicochemical measurements. 3.9.3 Inorganic Geochemistry Field duplicates were taken every at 18th site to determine the field reproducibility. CRM OREAS25a was inserted every 16th sample to evaluate accuracy of analysis. Refer to Appendix B.2 through B.8 for CRM and duplicate analyses on each of the inorganic geochemical methods. 3.9.4 Organic Geochemistry Equipment was sanitized with ethanol between samples, and contact with skin was prevented. Samples collected for microbiological analysis were also stored in sterilized plastic bags, kept cold for the duration of the sampling program, and frozen upon return to UBC. Installation of AGI Gore-Sorber® hydrocarbon collectors required that sunscreen, insect repellant, deodorants and other hydrocarbon-bearing chemicals not be worn on the skin due to the sensitivity of the hydrocarbon collectors. Field duplicate Gore-Sorber® modules were 48 installed every 18th site. Refer to Appendix B.9 and B.10 for duplicate analysis of SGH and hydrocarbon collector data. 3.9.5 SP Survey Triplicate measurements of each site were taken during the SP survey to determine site reproducibility in the data. The presence of metal drill casings left behind from previous drilling programs was recorded, as they may interfere with SP readings. 49 Chapter 4: Physiography, Surface Geology, Soil and Environment 4.1 Physiography of the DO-18 Field Site The DO-18 kimberlite is located in the Canadian Arctic tundra, approximately 90 kilometres north of the tree line and the southern limit of continuous permafrost (Dredge et al., 1999; Eggleston et al., 2014). Active layer (seasonal thaw layer) depths may depend on vegetation cover, but typically range from 15 centimetres where thick organic mats are present, to greater than 120 centimetres where covering vegetation is thin (Dredge et al., 1999). Temperatures range from -45⁰C in the winter to +25⁰C in the summer (Eggleston et al., 2014). The regional topography is low lying and undulating, largely influenced by bedrock relief and glacial features (Eggleston et al., 2014). Numerous lakes are present in the region, often connected by ephemeral fluvial incision with drainage influenced by glacial features. Proximal to the DO-27 exploration site, 400 metres south of the DO-18 pipe, granitic rocks outcrop as hills to a maximum of 30 metres above lake level (Eggleston et al., 2014). The research site is divided by an east-west trending slope break (Figures 4.1 and 4.2a), with approximately 10 metres of vertical offset. North of the slope break is higher topography and south of the slope break is low-lying. A southeast flowing river cuts through the southwest corner of the field site and drains into the 4 metre-deep Tli Kwi Cho Lake, which covers the DO-27 kimberlite (Eggleston et al., 2014). Two small ponds are present near the centre of the site, both just south of the slope break. Beaded drainage (channels with regularly-spaced pools up to 2 metres deep; Oswood et al., 1989) is present in the southeastern quadrant of the site. Frost boils 50 are ubiquitous north of the slope break, and are abundant in the southeastern and southwestern-most corner (Figure 4.2b). Figure 4.1. Aerial photo (0.95 m/pixel resolution, multiband) of the project study site. Slope break separates higher topography in the northern region from the low-lying region in the south. Red outline delineates the research site boundary. Photo courtesy of Peregrine Diamonds Ltd. Arrows indicate viewpoints of photos in Figure 4.2. DO-27 is located south of the image. 51 Figure 4.2. a) Photo taken from a helicopter above the field site looking directly south. Slope break is visible and delineated by the dashed yellow line. Approximate size and location of DO-18 and DO-27 kimberlites are shown. Tli Kwi Cho Lake is visible above DO-27. The river in the southwest of the study area and the two small ponds south of the slope break are visible in the background. b) Photo taken from a helicopter looking directly west. The slope break is delineated by a yellow dashed line. The southeast flowing river in the southwest corner of the field site is visible in the background, as is the beaded drainage in the southeastern quadrant. Cryoturbation, patterned ground and frost boils are common north of the slope break and east of the area with beaded drainage. 52 4.2 Surficial Geology A variety of surficial materials cover the research site. Each material varies in thickness and character, and reflects the processes and depositional environments that have been active in the area since deglaciation. Within the research site, surficial materials were mapped by sampled sediment type (Figure 4.3) and by surficial material (Figure 4.4; Appendix C.2). Figure 4.3. Distribution of sediment types at the typical sample depth (approximately 5-35 cm), mapped by sampled sediment type. Regions where organic deposits and permafrost conceal underlying materials are mapped as organics. Note that in some cases thin sediments of a different type overly the mapped sediment at sampling depth. 53 Figure 4.4. Distribution of surficial materials. Map legend follows the Geological Survey of Canada (GSC) Geologic Symbol Standard Style File – Surficial Symbols; from GSC Open File 8041 (Cocking et al., 2016), Surficial Database model v. 2.2, current as of February 1, 2016. Note that GLv is mapped as clay in Figure 4.3 only near its northern boundary because of its limited thickness in this area. Samples in this area were taken from the Tb, below the GLv. 54 Till is the most dominant surficial sediment within the research site, and it is the only sediment type present north of the slope break; however, south of the slope break, till, glaciolacustrine clay, and glaciofluvial silt, sand and gravel are present, in addition to both thin and thick organic deposits. Primary structures, such as graded bedding, are absent within each unit. Geomorphological processes and their influence on the physicochemical and geochemical results will be considered in section 6.4. The following are descriptions of each surficial material (Figure 4.4): O – Organic Deposits, Undifferentiated Organic deposits within the research site vary in thickness and underlie active vegetation and overlie the sampled sediments (Figure 4.5). Organic deposits are partially decomposed, organic soil horizons (Om horizon; Table 4.1). Most organic deposits in the research area were likely deposited in stagnant water no longer present. Thin and thick organic deposits have not been differentiated in Figure 4.4, as they orginate from common depositional environments. Occasionally, they act as an insulating layer, preserving permafrost beneath them. In these instances, the type of sediments underlying the organic layers could not be identified. GFp – Glaciofluvial Outwash Plain Sediments Glaciofluvial sediments are deposited by glacial meltwater streams that incised into the underlying glaciolacustrine sediment and till. The glaciofluvial deposits dominantly consist of well sorted sand and gravel, with occasional boulders. A solifluction lobe containing large boulders exists as colluvial material proximal to the GFp, generated by continuous cycles of freeze-thaw activity and removal of fine particles between boulders by groundwater flow (M. 55 Ross, pers. commun., 2015). This indicates that, although the GFp is more permeable than other surficial materials, it can retain enough water to contain significant interstitial ice. The thickness of the GFp is unknown due to shallow sampling depth. Figure 4.5. Organic deposits at the DO-18 research site. ‘Thick’ organic deposits are thicker than one absolute deviation from the median Om horizon thickness (Table 4.2), in this case, 5.5 cm. Sites with multiple Om horizons (representing various cycles of moss mat growth) are also given this classification as they are invariably thicker than 5.5 cm. Conversely, ‘thin’ organics are thinner than 5.5 cm. GLv – Glaciolacustrine Veneer Glaciolacustrine veneers are deposited in shallow lake environments, producing a thin package of well sorted, clay-rich sediments. GLv exists in the southeast quadrant of the study 56 site. Primary sedimentary structures are not apparent. As the GLv is relatively thin, the underlying till blanket was locally exposed below the GLv. Tb – Glacial Sediments: Blanket Till is material deposited directly by glacial ice. The till in the region is comprised of only one till sheet (Chapter 2). The till in the study area consists of dominantly sandy diamict with local variations in matrix grain size, ranging from coarse sand matrix to clay- and silt-rich matrix. Clasts within the till are mainly of equant and prolate shape and range in size from 0.5 centimetres to boulders 1 to 2 metres in diameter. The till is generally matrix supported, but can be clast supported. Imbrication or preferred clast orientation is absent. The till blanket within the research site ranges in thickness from 5 to 20 metres (Eggleston et al., 2014; Normandeau et al., 2016). Cryoturbation is evident within the till blanket, with ubiquitous frost boils in some areas (Figure 4.1). A lack of vegetation and freshly upheaved sediments on the surface, and cryoturbation observed in soil pits, indicates that many of these frost boils are currently active. 4.3 Soil Classification Occupying most of the northern third of Canada, Cryosols are the most common soil order north of the tree line and where permafrost exists near the surface (Soil Classification Working Group, 1998). There are three Great Groups of Crysols: Turbic Cryosols; Static Cryosols; and Organic Cryosols. Within each Great Group, soils can be further classified by subgroup based on the type and arrangement of soil horizons (Soil Classification Working Group, 1998), with each group containing unique diagnostic features and horizons. 57 Several soil types may exist within a small area (Soil Classification Working Group, 1998). Two soil types dominate within the research site: Brunisolic Eutric Turbic Cryosols (BE.TC) and Histic Eutric Turbic Cryosols (HE.TC). Turbic Cryosols are typically found in patterned ground, including cryogenic forms such as polygons (Soil Classification Working Group, 1998). They are mineral soils that have permafrost within 2 metres of the surface, and display evidence of cryoturbation within the active layer, such as mixed or broken soil horizons, displaced material, or both (Soil Classification Working Group, 1998). Static Cryosols rarely show evidence of cryoturbation, and have permafrost within one metre of the surface. Both soils are formed in either mineral or organic materials (Soil Classification Working Group, 1998). BE.TC commonly contain the following soil horizon sequence: Om, Bm, Bmy or BCy, Cgy, Omy, and Cz (Table 4.1; Soil Classification Working Group, 1998); however, Ae and Ah horizons were also observed. BE.TC are also characterized by the following properties (Soil Classification Working Group, 1998):  Contain a Bm horizon at least 10 cm thick, relatively unaffected by cryoturbation;  Horizons other than the Bm are affected by cryoturbation (broken or discontinuous);  Soil pH is approximately 5.5 or more alkaline in some or all of the B horizons (refer to Appendix C.2 for slurry pH values); HE.SC commonly contain the following soil horizon sequence: Om, Ah, Bm, Cg, and Cz (Table 4.1; Soil Classification Working Group, 1998); however, Ae horizons were also observed. HE.SC are also characterized by the following properties (Soil Classification Working Group, 1998):  Has a continuous surface horizon (O or H), from 15-40 cm in thickness;  Continuous Bm horizons; 58  Soil pH is approximately 5.5 or more alkaline in some or all of the B horizons (refer to Appendix C.2 for slurry pH values); Other soil types may be present within the research site, including Regosols, which are characterized as well to imperfectly drained, and lacking a recognizable B horizon at least 5 cm thick, generally due to the young age of parent materials (Soil Classification Working Group, 1998). Parent materials often include recent alluvium, or colluvium on slopes (Soil Classification Working Group, 1998); thus, they are commonly found proximal to rivers, such as that in the southwest corner of the research site. However, as the river was avoided when sampling, the presence of other soil types other than Cryosols were not confirmed. Only dominant soil types observed within the research area were mapped (Figure 4.6). Figure 4.6. Distribution of Brunisolic Eutric Turbic Cryosols (BE.TC) and Histic Eutric Static Cryosols (HE.SC) within the research site. Soil cross sections of each point are given in Figure 4.7. 59 The distribution of soil horizons in the research site are highly variable (Figures 4.7 and 4.8; Table 4.2); however, the soil horizons present and their general sequence verifies both soil classifications. The presence of permafrost within 30-40 cm depth within the areas mapped as HE.SC (Figure 4.9) further confirms its classification. During sampling, the lack of necessity to dig holes deeper than approximately 40 cm prevented the observation of permafrost within the areas mapped as BE.TC, as well as some C horizons in both soils. Sites where permafrost limited the depth of the hole were recorded as containing only the horizons that could be observed. At sites with shallow permafrost, multiple Om horizons were often encountered, indicating that they act as an insulating layer. Sediments beneath permafrost could not be observed and were therefore not identified. Refer to Appendix C.2 for soil horizon data for each sample and corresponding surficial measurements. 60 Figure 4.7. East-west soil horizon cross-sections by sampling lines (refer to Figure 4.6 for sample site locations). 150x vertical exaggeration. ‘Clay’ refers to clay lenses observed below Of and above Om horizons. 61 Table 4.1. Descriptions of common Brunisolic Eutric Turbic Cryosol (BE.TC) and Histic Eutric Static Cryosol (HE.SC) soil horizons. Of and Om horizons are categorized as organic horizons, containing greater than 17% organic carbon or 30% organic matter by weight. Ah, Ae, Bm, BCy, Cg, Cgy and Cz horizons are mineral horizons, which contain less than 17% organic carbon or 30% organic matter by weight (after Soil Classification Working Group, 1998). Soil Horizon Soil Type Description Of BE.TC HE.SC Subclass of organic (O) horizon containing fibric, partially decomposed material, with less recognizable plant matter. Om BE.TC HE.SC Subclass of O horizon containing mesic (moist) material, and is at a stage of decomposition intermediate between that of fibric and humic materials. Ah HE.SC A horizon subclass which forms near the surface, enriched with organic matter. It is darker in colour than underlying horizons, or contains 0.5% more organic carbon than the C horizon, or both. Ae BE.TC HE.SC A horizon subclass. Eluviation of clay, iron, aluminum or organic matter. Often lighter in colour than the underlying B horizons due to the removal of organic matter and iron, and of coarser grain size due to the removal of clay. Bm BE.TC HE.SC B horizon slightly altered by hydrolysis, oxidation, or solution, or all three, resulting in a change in colour, structure, or both. This horizon is redder than others, contains some weatherable minerals, and lacks cementation. BCy BE.TC B and C mixed horizon affected by cryoturbation, as evidenced by broken horizons, and incorporation of material from other horizons. Cg HE.SC C horizon soils are unaffected by pedogenic processes relative to the A and B horizons. Similar to that of the Aeg horizon, Cg is a C horizon with prominent mottling, incorporation of grey colours, or both, suggesting episodic or permanent intense reduction. Cgy BE.TC C horizon which may still be of reddish hue despite long periods of reduction, with grey mottling or bleaching. This horizon has also undergone cryoturbation and may be broken or contain material from other horizons. Cz BE.TC HE.SC Cz indicates a frozen C horizon. 62 Figure 4.8. Photos of soil horizon groups commonly encountered. a) Site 119: (557,197 m E, 7,134,859 m N), b) Site 49b: (556,863 m E, 7,134,681 m N) c) Site 78: (557,522 m E, 7,134,636 m N) d) Site 108b: (557,442 m E, 7,134,769 m N), and e) Site 60: (557,412 m E, 7,134,591 m N). Table 4.2. Variation of soil horizons within the DO-18 research site. % Occurrence refers to the percentage of soil pits in which a horizon was observed within the research site. Median thickness of the Bm horizon was only recorded when the base was observed (i.e. a C horizon was present). Occasionally, multiple Om horizons were encountered; % Occurrence of Om (one horizon only) does not include any holes containing multiple Om horizons. Median depth to horizon remains constant for both cases as this is the median depth at which the first Om horizon was recorded. Soil Horizon % Occurrence Median Thickness (cm) Median Depth to horizon (cm) Of 98% 3.0 n/a Om (one Om horizon only) 77% 4.0 3.0 Om (several Om horizons) 14% 32.5 3.0 Ah 12% 2.5 6.0 Ae 33% 3.0 6.0 Bm 83% 8.5 9.0 Cg 7% n/a 12.0 BCy 2% n/a 15.0 Cgy 11% n/a 14.0 63 Figure 4.9. Permafrost surface encountered in organic deposits at Site 47 (557,552 m E; 7,134,507 m N), at approximately 30 centimetres depth. 4.4 Vegetation Vegetation in the region is dominated by dwarf arctic willows, flowering and berry producing plants, grass, and moss and lichen (Figure 4.10; Eggleston et al., 2014). Overall, the vegetation is loosely correlated with surficial sediment type; till-dominated areas tend to be covered by moss and lichen, and fluvial sediments and organic deposits tends to be covered by hummocky grassland and shrubs. Vegetation classifications are depicted in Figure 4.11. In general, a combination of moss and lichen is prevalent north of the slope break, with lesser hummocks and thin and thick shrubs. South of the slope break, hummocky grassland, thin and thick shrubs (up to two metres in height) dominate with lesser moss and lichen. The vegetation covering the GLv and small till polygons in the southeast of the study area (Figure 4.4) range 64 from hummocky grassland to thin and thick shrubs regardless of sediment type, suggesting an increase in moisture in the surface sediments. This is likely caused the higher clay content in the GLv and till, which affects active layer thicknesses and decreases the porosity and drainage of this area. The thick shrubs are most concentrated on till in the southeastern portion of the field site and other low-lying areas with more poorly drained sediment. Figure 4.10. Vegetation patterns within the DO-18 research site, mapped based on primary field observations. 65 Figure 4.11. Vegetation classifications within the research site. a) Moss and lichen, b) hummocky grassland, c) thin shrubs, and d) thick shrubs. 4.5 Summary The physiography of the DO-18 research site is characterized by a region of high elevation in the north and a low-lying region in the south, separated by an east-west trending slope break. The surficial materials comprise a mix of organics, till, glaciofluvial and glaciolacustrine sediment. North of the slope break, till was the only sampled material, deposited directly by glacial ice. South of the slope break, sampled sediment types include sand, clay and gravel deposited by glaciofluvial and glaciolacustrine systems, and organic deposits. Soil horizons encountered within each sediment type display a high degree of variation, but are mostly classified as Cryosols. Vegetation is also loosely correlated with surficial materials, likely due to the porosity, drainage and active layer thicknesses associated with each material. 66 Chapter 5: Results A suite of inorganic, organic, and physicochemical analyses were completed on each sample taken at the research site. Petrography, sequential leach analysis and X-Ray diffraction were also completed on select samples (Chapter 3). Results from the analyses are presented in this chapter. 5.1 DO-18 Lithogeochemistry The chemistry of the DO-18 kimberlite was analysed in selected drill core samples donated by Peregrine Diamonds Ltd., and a clay sample, identified as weathered kimberlite based on REE signatures, donated by the Northwest Territories Geological Survey (NTGS) from the Slave Province Surficial Materials and Permafrost Study (SPSMPS) RC drilling program in 2015. Kimberlites in the Slave province dominantly intruded granites and metasediments (Pell, 1997; Chapter 2); thus, the contrast in geochemistry between the kimberlites in the Slave province and their host rocks presents an opportunity to use soil geochemistry as a robust exploration tool. As kimberlite fragments are mechanically distributed via dispersal trains in till in glaciated terrain (Chapter 1), understanding the chemistry of kimberlites in contrast to their host rocks is paramount for determining detection parameters. The results from the lithogeochemical analysis from samples were averaged and compared to average Group I kimberlite geochemistry and host rock geochemistry. The host rocks to the DO-18 kimberlite are labeled as ‘undifferentiated Archean granitoids’ (Hoffman and Hall, 1993; Chapter 2). In the absence of host rock samples for analysis, the Yamba and Contwoyto plutonic suites were taken to represent host rock geochemistry as both are post-67 deformational Archean granitoids within the Slave province, similar to the granites into which the DO-18 kimberlite has intruded (Davis et al., 1991; Davis et al., 1994; Yamashita, 1998; Yamashita et al., 1999). Elevated concentrations (greater than one order of magnitude) of Cr, Mg, Nb and Ni are noted in both the DO-18 lithogeochemistry (Table 5.1; kimberlite pathfinder elements only, refer to Appendix D.1 and D.2 for complete suite of elements) and the average Group I kimberlite concentration, relative to the host rock geochemistry. 68 Table 5.1. Lithogeochemistry of the DO-18 Kimberlite, from samples: K2P-0018b, K2P-0027b, K2P-0067 (Peregrine Diamonds Ltd.); and NGO-RC15-061-13a, (Northwest Territories Geological Survey). Elements shown are kimberlite pathfinder elements as defined by McClenaghan and Kjarsgaard (2001) and Sader (2011). The DO-18 kimberlite chemistry of the drill core samples is compared to the average kimberlite composition and the average composition of the Contwoyto and Yamba granitic plutonic suites to show the contrast between the kimberlite geochemistry and its host rocks. Sample NGO-RC15-061-13a is not included in the sample concentration average as it is highly contaminated. Elements in bold (Cr, MgO, Nb and Ni) denote elements in the samples and average kimberlite concentration which are at least one order of magnitude greater than their granitic suite counterparts. *Elements reported in ppm unless otherwise noted. ˣ Sample NGO-RC15-061-13a is not included in average due to possible contamination. 1 Major element data from Dawson (1967). 2 HFSE data is averaged from the South African kimberlite (Smith et al., 1985), Zaire Kimberlites from Kampata (1993); and Kimberley Group Kimberlites from Clement (1982) and Mitchell (1995), each as reported in Mitchell (1995). 3 REE data from Maramatsu (1983). 4 Compatible element data from Mitchell (1986). 5 Yamba and Contwoyto plutonic suite geochemistry values averaged from Davis (1991). K2P-0067b K2P-0027b K2P-0018b NGO-RC15-061-13a Average Kimberlite Average Group I Kimberlite Average Yamba Average Contwoyto Element* n =1 n =1 n =1 n =1 Sample Concentrationx Concentration1,2,3,4 Suite Concentration5 Suite Concentration5CaO % 3.34 3.53 2.76 0.97 3.2 7.6 1.19 0.98MgO % 16.6 13.2 12.6 4.71 14.1 27.9 0.478 0.343K2O % 2.9 3.55 3.58 3.17 3.3 0.98 5.398 4.027TiO2 % 0.26 0.31 0.24 0.51 0.3 2.32 0.248 0.153Co 46.0 35.0 33.0 18.0 38.0 65.0 -- --Cr 440.0 420.0 350.0 80.0 403.3 893.0 7.0 6.0Ni 789.0 557.0 532.0 80.0 626.0 965.0 BD BDBa 1055.0 1100.0 873.0 595.0 1009.3 885.0 703.333 443.2Rb 84.7 103.5 100.5 137.5 96.2 -- 171.833 186.6Sr 382.0 422.0 342.0 126.5 382.0 847.0 140.667 133.2Nb 56.3 56.3 41.6 15.1 51.4 171.0 8.783 8.36La 51.7 49.7 41.0 33.7 47.5 150.0 61.45 15.972Ce 92.0 89.6 73.6 63.5 85.1 200.0 121.167 30.1Pr 9.13 9.07 7.89 7.39 8.7 22.0 13.278 3.467Nd 31.9 31.6 26.3 27.8 29.9 85.0 46.5 12.33Sm 4.03 4.02 3.72 5.16 3.9 13.0 6.837 2.398Eu 0.76 0.96 0.62 0.99 0.8 3.0 0.638 0.355Gd 2.52 2.84 2.12 4.38 2.5 8.0 4.833 1.867Tb 0.3 0.33 0.31 0.68 0.3 1.0 0.598 0.253Dy 1.41 1.73 1.18 3.83 1.4 -- 2.815 1.338Ho 0.27 0.33 0.21 0.81 0.3 0.55 0.478 0.238Er 0.55 0.86 0.59 2.11 0.7 1.45 1.14 0.617Tm 0.1 0.12 0.1 0.31 0.1 0.23 0.142 0.08Yb 0.7 0.71 0.46 2.18 0.6 1.2 0.882 0.535Lu 0.08 0.11 0.07 0.31 0.1 0.16 0.133 0.075Y 6.7 8.0 6.1 22.9 6.9 22.0 -- --69 In addition to mechanical dispersion, kimberlite weathering also releases elements into the soil through dissolution; however, the rate of kimberlite weathering in the Arctic tundra is significantly decreased due to lower temperatures for most of the year (Nowicki et al., 2007). The degree of weathering and contamination in a kimberlite are defined by a contamination index (CI), which measures proportions of SiO2, Al2O3, and Na2O, relative to MgO and K2O, where a CI close to 1 indicates fresh, hypabyssal facies kimberlite (Clement, 1982). Common kimberlite contaminants, including shales and basement rocks, are richer in silica, aluminum and sodium, and contain less magnesium, and therefore contribute to greater CIs (Clement, 1982). Additionally, weathered kimberlite is enriched in SiO2, Al2O3, and Na2O, either directly, or indirectly by leaching of Mg and K (Clement, 1982). The equation used to determine the CI of a kimberlite (Equation 5.1) is as follows (Clement, 1982): 𝐶𝐼 = (𝑆𝑖𝑂2 + 𝐴𝑙2𝑂3 + 𝑁𝑎2𝑂)(𝑀𝑔𝑂 + 2𝐾2𝑂) Equation 5.1. Contamination index (CI) calculation. Samples K2P-0067b, K2P-0027b, K2P-0018b and NGO-RC15-061-13a are ordered by increasing degree of contamination and weathering, based on CI values (Table 5.2). Samples K2P-0018, K2P-0027, and K2P-0067 gradually display a slight relative increase in K2O and Rb, and a decrease in CaO, MgO, Co, Cr, Ni, Ba, Nb, and LREEs. TiO2 and HREEs do not fluctuate greatly. Table 5.2. Concentrations of oxides used to calculate the contamination index (CI) of each of the kimberlite samples, as per Clement (1982). Values are given in %, with the exception of CI, which is unitless. Sample SiO2 Al2O3 Na2O MgO K2O CI K2P-0067b 50.0 8.12 0.67 16.6 2.90 2.62 K2P-0027b 52.6 9.70 1.21 13.2 3.55 3.13 K2P-0018b 56.4 9.65 1.47 12.6 3.58 3.42 NGO-RC15-061-13a 42.7 13.65 0.15 4.71 3.17 5.11 70 5.2 Petrography Petrography of drill core samples was undertaken (Figure 5.1) to better understand the mineralogy of the DO-18 kimberlite, the mineralogical source of certain kimberlite pathfinder elements, and to confirm the kimberlite type and domain within DO-18. Refer to Appendix D.3 for petrography of each kimberlite core sample. Figure 5.1. 2x magnification of K2P-0018 under a) plane polarized light, and b) under cross polarized light. Minerals present include broken, serpentinized olivine, granitic xenoliths and xenocrysts, clasts of resedimented volcaniclastic kimberlite (RVK), in a serpentine and ash matrix. It is therefore likely from the KIMB-1 domain (Harder et al., 2008; Chapter 2). 71 5.3 Inorganic Geochemistry Results from the inorganic geochemical analyses on the B-horizon soil sample suite are detailed below. These analyses included: 4-Acid Digestion; Aqua Regia Digestion; De-Ionized Water Leach (each coupled with ICP-MS); fp-XRF; and pH. Note that organic-rich samples (samples which contain >17% organic carbon) are omitted from the inorganic geochemical results discussed herein. Refer to Appendix D.4 through D.10 for the raw data corresponding to analyses described in this section. 5.3.1 4-Acid Digestion ICP-MS Analysis 5.3.1.1 Quality Control Prior to assessing the results of each analysis, evaluating the quality of the data through QA/QC techniques is imperative, as low-level geochemical responses may be sensitive to poor field reproducibility or poor instrumental analysis. The accuracy of analysis and field reproducibility of each analysis were determined by the insertion of CRMs every 16th sample and field duplicates taken at every 18th site, respectively (Chapter 3). The accuracy of analysis was evaluated by determining if data from CRM samples fall within acceptable intervals, in this instance, ± 3 standard deviations from the certified value for each element for a given analysis. Field reproducibility in duplicate samples was determined using mean percent difference (MPD), which measures the difference in concentrations of original and duplicate samples, given as a percentage (Equation 5.2); less than 20% difference in data is considered to be high quality data, and less than 10% difference is considered to be very high quality data, particularly if data are greater than 10 times the detection limit for each element in a given analysis. 72 𝑀𝑃𝐷 (%) = (|𝑜𝑟𝑖𝑔𝑖𝑛𝑎𝑙 − 𝑑𝑢𝑝𝑙𝑖𝑐𝑎𝑡𝑒|)(𝑜𝑟𝑖𝑔𝑖𝑛𝑎𝑙 + 𝑑𝑢𝑝𝑙𝑖𝑐𝑎𝑡𝑒)/2 ∗ 100 Equation 5.2 Mean percent difference (MPD) calculation. Only the 4-Acid data are considered herein, as it was the most successful method for the detection of the kimberlite in this study. It is evident that for the elements of interest, the data analysis is well within the acceptable interval, and most data exhibit less than 20% MPD; therefore, the anomalies discussed below cannot be attributed to instrument drift or noise, and display high field reproducibility (Figures 5.2 and 5.3, respectively). Figure 5.2. QA/QC using the CRMs to evaluate the accuracy of the 4-Acid ICP-MS analysis for a) Cr, b) Mg, c) Nb, and d) Ni. SD refers to Standard Deviations. 73 Figure 5.3. Field reproducibility (MPD) analysis using field duplicates of the 4-Acid ICP-MS analysis for a) Cr, b) Mg, c) Nb, and d) Ni. 5.3.1.2 4-Acid Digestion ICP-MS Rationale A 4-Acid (HF-HCl-HNO3-HClO4) digest was applied to each of the soil samples collected at the research site. This digests the majority of silicates and some refractory silicates and oxides (physically and chemically stable at high temperatures), crystalline and amorphous 74 Fe- and Mn-oxides, organic materials, carbonates, surface adsorbed analytes and soluble salts (Hall et al., 1996; Seneshen, 1997; Hall, 1998). Refractory minerals which are not typically fully digested include tourmaline, beryl, chromite, titanite, and diamond (Hall et al., 1996). A 4-Acid digestion was completed on soil samples principally to maximize recovery of the mobile and immobile elements, including kimberlite pathfinder elements (Chapter 1) contained in Aqua Regia-insolube phases. 5.3.1.3 4-Acid Digestion ICP-MS Results Probability plots were constructed from the 4-Acid ICP-MS results to identify anomalous populations (Figure 5.4), and to determine if the data sets contained multiple populations shown by inflection points within the distribution (Sinclair, 1974). The N-score of each plot is shown on the x-axis, and represents the Z-scores (number of standard deviations the data are from the mean) from a standard normal distribution, where the mean is zero and the standard deviation is one. Y-axes display the concentration of each element. Inflection points mark the break between populations, and each population was assigned an interval used to demarcate the legend in Figure 5.5. Cut-offs for anomalous values are the highest value of the background intervals (Table 5.3). Results from the 4-Acid ICP-MS analysis present a soil geochemical anomaly from the centre of the DO-18 kimberlite to the northwestern edge of the sample grid, in the down-ice direction, approximately 290⁰-295⁰. Low-level, but anomalous values of Cr, Mg, Nb and Ni (Figures 5.5a, b, c, and d, respectively), and to a slightly lesser extent, Zn, were detected down-ice of the kimberlite, and are concentrated north of the E-W trending slope break, in the high topography region. Ni has the highest response ratio (the average of anomalous values relative to 75 the average of background values, Table 5.3). Elements which showed similar, but lower-level anomalies which detect the kimberlite dispersal train include Sc, Ga, Li, Rb, Cs, La, and Ce. Table 5.3. Response ratios for 4-Acid ICP-MS results of Cr, Mg, Nb, and Ni. Element Anomalous Concentration Cut-off* Average of Background Samples* Average of Anomalous Samples* Response Ratio Cr 36 28.57 44.42 1.55 Mg 0.46% 0.34% 0.58% 1.68 Nb 4.4 3.43 5.45 1.59 Ni 15.8 12.35 24.16 1.96 *ppm unless otherwise noted Figure 5.4. Probability plots of 4-Acid ICP-MS results for a) Cr, b) Mg, c) Nb, and d) Ni concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.5. The anomalous response can be enhanced further by adopting a multi-element approach to the data such as summing the concentration of the elements following normalization to percentile interval to reduce the data to a non-parametric normalized scale (Figure 5.6). 76 Anomalous values are concentrated in till north of the slope break in the down-ice direction from the kimberlite (influences of geomorphological processes on the geochemistry of surface materials will be discussed in section 6.4). 77 Figure 5.5. 4-Acid ICP-MS results for a) Cr, b) Mg, c) Nb, and d) Ni concentrations, with organic-rich samples omitted. Intervals are based on probability plots (Figure 5.4). 78 Figure 5.6. Sum of concentrations of elements, Cr, Mg, Nb and Ni (normalized by percentile prior to summation) from 4-Acid ICP-MS data, overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to delineate plotting boundaries. 79 5.3.2 Aqua Regia ICP-MS Analysis 5.3.2.1 Aqua Regia ICP-MS Rationale The Aqua Regia (HNO3:3HCl) digestion is considered ‘conventional’ due to its frequent use for the digestion of soils over shallow, transported sediments (Seneshen, 1997), as well as its extensive application in areas of residual cover elsewhere in the world. It is commonly used as it is hypothesized that the sediment or substrate will not be digested, but rather only the pathfinder elements related to potential underlying deposits, maximizing contrast between elements of interest and background (Seneshen, 1997). Aqua Regia digestion was undertaken to evaluate the concentration of kimberlite pathfinder elements within the soil, by digesting: crystalline Fe-oxides; amorphous Fe- and Mn-oxides, and phases adsorbed to them; residual sulphides; secondary mineral phases; and phases associated with clays and carbonates, organics, and water soluble salts (Hall et al., 1996; Seneshen, 1997; Hall, 1998). 5.3.2.2 Aqua Regia ICP-MS Results Probability plots (Figure 5.7) were constructed from Aqua Regia ICP-MS results to identify anomalous populations which were used to delineate plotting boundaries in Figure 5.8. Overall, Aqua Regia ICP-MS results were successful in detecting Cr, Mg, Nb and Ni anomalies from the centre of the DO-18 kimberlite, in the down-ice direction, to the northwestern edge of the sampling grid (Figure 5.8a, b, c, and d, respectively). Each element displayed lower concentrations than the 4-Acid results, though the morphology of the anomaly remained the same, as each anomaly was concentrated within the northwestern quadrant of the sampling grid, within the higher topography region. The response ratios are as follows, in decreasing order: Mg, 80 Ni, Nb, Cr (Table 5.4). Elements which showed similar, but lower-level anomalies within the Aqua Regia results included Ba, Cd, Rb, Sb, Sr, and Zn. Figure 5.7. Probability plots of Aqua Regia ICP-MS results for a) Cr, b) Mg, c) Nb, and d) Ni concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.8. Table 5.4. Response ratios for Aqua Regia ICP-MS results of Cr, Mg, Nb, and Ni. Element Anomalous Concentration Cut-off* Average of Background Samples* Average of Anomalous Samples* Response Ratio Cr 20.6 15.24 24.69 1.62 Mg 0.26% 0.17% 0.38% 2.19 Nb 0.7 0.52 0.98 1.89 Ni 11.8 8.50 18.05 2.12 *ppm unless otherwise noted The sum of these elements shows the same overall pattern as Cr, Mg, Nb and Ni individually, with anomalous values north of the slope break in the down-ice direction from the kimberlite (Figure 5.9). Overall, similar to that of the 4-Acid results, the anomaly is constrained to till in the northwest quadrant.81 Figure 5.8. Aqua Regia ICP-MS results for a) Cr, b) Mg, c) Nb, and d) Ni concentrations, with organic samples omitted. Intervals are based on probability plots (Figure 5.7). 82 Figure 5.9. Sum of concentrations of elements, Cr, Mg, Nb and Ni (normalized by percentile prior to summation) from Aqua-Regia ICP-MS data, overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to delineate plotting boundaries. 83 5.3.3 De-Ionized Water ICP-MS Analysis 5.3.3.1 De-Ionized Water ICP-MS Rationale The De-Ionized Water Leach was undertaken to identify and quantify concentrations of labile, soluble, suspended, or colloidal kimberlite-related pathfinder elements within the soil (Seneshen; 1997; Cameron et al., 2004, van Geffen et al., 2015). In young, transported sediments, it is exogenic phases (elements from an external source) which enter the soil in water-soluble form, and become incorporated in water soluble salts and loosely adsorbed to mineral surfaces as the process of secondary mineral formation progresses (Cameron et al., 2004). 5.3.3.2 De-Ionized Water ICP-MS Results Probability plots were used to identify anomalous populations (Figure 5.10) which were used to delineate the plotting boundaries for Figure 5.11. The De-Ionized Water ICP-MS results were moderately successful in detecting ultra-low-level responses of kimberlite pathfinder elements Ce, K, Nb and Y (Figure 5.11a, b, c, and d, respectively). Similar to the 4-Acid and Aqua Regia ICP-MS results, the anomaly resided within the higher topography region, north of the slope break, and spanned from the centre of the kimberlite to the northwestern edge of the sampling grid in the down-ice direction. In decreasing order, the response ratios are as follows: Nb, Y, Ce, and K (Table 5.5). Mg showed a similar but much lower-level anomaly. 84 Figure 5.10. Probability plots of De-Ionized Water ICP-MS results for a) Ce, b) K, c) Nb, and d) Y concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.11. The sum of Ce, K, Nb and Y (Figure 5.12) exhibits an anomaly with a morphology similar to that of 4-Acid and Aqua Regia digestions, though more tightly constrained to the till within the northwest quadrant of the sampling grid than each element individually. Table 5.5. Response ratios for Deionized Water ICP-MS results for Ce, K, Nb, and Y. Element Anomalous Concentration Cut-off* Average of Background Samples* Average of Anomalous Values* Response Ratio Ce 0.0323 0.0151 0.0639 4.2 K 9 4.99 17.04 3.4 Nb 0.003 0.0009 0.0103 10.98 Y 0.0086 0.0044 0.0194 4.4 *ppm unless otherwise noted 85 Figure 5.11. De-Ionized Water Leach ICP-MS results for a) Ce, b) K, c) Nb, and d) Y concentrations, with organic samples omitted. Intervals are based on probability plots (Figure 5.10).86 Figure 5.12. Sum of concentrations of elements, Ce, K, Nb, and Y (normalized by percentile prior to summation) from De-Ionized Water ICP-MS data, overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to delineate plotting boundaries. 87 5.3.4 Field Portable X-Ray Fluorescence (fp-XRF; Soil Mode) 5.3.4.1 Fp-XRF Rationale Fp-XRF is a portable, hand held device which provides non-destructive, rapid, multi-element analysis (Hou et al., 2004; Shand and Wendler, 2014). A total analysis is provided by fp-XRF, and reports elements not reported by commercial analyses, such as Si, which becomes volatilised during 4-Acid digestions as SiF4 (P. Winterburn, pers. commun., 2017). Fp-XRF analysis provides real-time results, usually with accuracy and precision near that of commercial analyses, and has thus earned status as a reliable field tool, allowing on-site prioritization of targets (Glanzman and Closs, 2007). Despite the general success of fp-XRF, its use is not without caveats: detection limits are higher than lab-based XRF instruments or wet chemical analyses, and elements with low atomic mass may be more challenging to detect (Shand and Wendler, 2014). Adequate sample preparation is critical, as data quality is compromised by moisture, surface roughness, and overall heterogeneities of the sample medium (Shand and Wendler, 2014). Additionally, not all elements are measured reliably. In this research, calibration of the fp-XRF instrument was undertaken using a range of CRMs and 15 soil samples collected from the research site, the Woodjam Property, and the Lara property. Samples were analysed by fusion ICP-OES/MS to ensure total recovery, as well as by fp-XRF. Regression calculations were completed using a linear regression. Refer to Appendix A.10 for complete calibration procedure. 88 5.3.4.2 Fp-XRF (Soil Mode) Results In this application, both ‘Soil’ and ‘Geochem’ (also referred to as Mining) modes were used to analyse each sample (Chapter 3). In general, Soil Mode is used to determine concentrations of minor and trace elements, and Geochem mode is used to evaluate major elements (Hall et al., 2011). This section focuses on results from the Soil Mode, as in this case, elements of interest (Cr, Nb, Ni, and Zn) are at trace element levels (refer to Appendix D.7 and D.8 for remaining Soil mode and Geochem mode results, respectively). Detection limits for each element calibrated were calculated using the lowest value greater than zero, with less than ± 100% error (Table 5.6; refer to Appendix A.10 for calibration graphs for each element). Table 5.6. Calculated detection limits for calibrated trace elements in Soil Mode. Element Calculated LOD+ (ppm) Cr 38.7 Ni* 5.1 Mn 117.4 Zn 2.4 Cu 6.7 Rb 1.6 Sr 59.9 Ba 19 V 10.5 Nb 1.7 Y 8.7 Zr 42.1 *Ni did not require calibration as results were nearly congruent to those from 4-Acid ICP-MS from samples used to calibrate the fp-XRF. +LOD = limit of detection Anomalous populations were identified using probability plots (Figure 5.13). Successful detection of the DO-18 kimberlite was evident by the presence of Cr, Nb, Ni, and Zn anomalies (Figure 5.14a, b, c and d, respectively; response ratios given in Table 5.7), which spanned from the DO-18 kimberlite to the northwestern edge of the sample grid, in the down-ice direction. Mg 89 concentrations were too low to be reliably detected by fp-XRF (<1%; in both Soil and Geochem Mode). Similar to previous analyses in this study, this anomaly was concentrated north of the slope break. Elements which showed similar patterns above the kimberlite include K and Rb. Figure 5.13. Probability plots of fp-XRF Soil Mode results for a) Cr, b) Nb, c) Ni, and d) Zn concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.14. Table 5.7. Response ratios for fp-XRF results of Cr, Nb, Ni, and Zn. Element Anomalous Concentration Cut-off* Average of Background Samples* Average of Anomalous Samples* Response Ratio Cr 68.20 56.21 79.21 1.49 Nb 5.70 3.95 6.31 1.60 Ni 20.63 9.15 25.21 2.75 Zn 27.03 19.56 31.45 1.61 *ppm unless otherwise noted The sum of Cr, Nb, Ni and Zn (normalized by percentile prior to summation; Figure 5.15) displays a strong anomaly tightly constrained to the till within the northwestern quadrant, similar to the 4-acid, aqua regia, and deionized water results.90 Figure 5.14. Fp-XRF Soil Mode results for a) Cr, b) Nb, c) Ni, and d) Zn concentrations, with organic samples omitted. Intervals are based on probability plots in Figure 5.13. 91 Figure 5.15. Sum of concentrations of elements for Cr, Nb, Ni and Zn (normalized by percentile prior to summation) from fp-XRF data, overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to delineate plotting boundaries. 92 5.3.5 Sequential Leach Analysis 5.3.5.1 Sequential Leach Rationale Sequential leaches are undertaken to determine which phases in the soil are associated with the elements of interest. A sequential leach comprises a series of selective leaches, run sequentially on the samples, beginning with the weakest (such as De-Ionized Water), and ending with the strongest (such as 4-Acid or Fusion). The principal objective of each leach or digestion is to target each phase individually or groups of phases and extract them or to dissolve the elements loosely adsorbed to them (Hall, 1998), and analyse the trace metal contents by ICP-MS (Cameron et al., 2004; Table 5.8). Table 5.8. ALS Laboratories sequential leach methods in order of increasing strength (Hall et al., 1996; Seneshen, 1997; Hall, 1998). Digestion Name Abbreviation Digested Phases ME-MS03 De-Ionized Water Leach DW Labile elements and water soluble salts ME-MS04 Buffered Ammonium Acetate Leach AAc Acetate-soluble secondary minerals, surface-adsorbed analytes, carbonates ME-MS05 Cold Hydroxylamine-HCl Leach CHA Analytes adsorbed to Fe/Mn-oxides, digests Mn-oxides and some amorphous Fe-oxides ME-MS06 Hot Hydroxylamine HCl Leach HHA Most amorphous Fe oxides ME-MS07 Sodium Pyrophosphate Leach NaP Leaches some crystalline Fe-oxides and digests humus and highly organic rich soils ME-MS41 Aqua Regia Digestion AR Digests crystalline Fe/Mn-oxides, sulphides, and various phyllosilicates (e.g. chlorite) ME-MS61 Four Acid Digestion 4A Digests most silicates and aluminosilicates, some major refractory mineral 93 In essesnce, sequential leaches can identify: a) elements which have migrated from a specific source and subsequently become immobilized (exogenic), b) primary elements which have originated in their current environment (endogenic), and c) which minerals these elements reside with (Cameron et al., 2004; MacFarlane et al., 2005). In transported sediments, it is hypothesized that exogenic elements, which are often ore deposit pathfinder elements, have been immobilized by specific phases in the near-surface environment, including: humic and fulvic components of organic material; or secondary minerals, such as Fe- and Mn-oxides and clay minerals, which have broken down from primary rock forming minerals (Hall, 1998; Cameron et al., 2004; MacFarlane et al., 2005). The migrated, exogenic elements are generally bound to these secondary minerals or organic components by physical or chemical adsorption at surfaces, chelation, complexation, and coprecipitation (Hall, 1998). In till, it has been suggested by Hamilton (2007) that selective leaches are more successful at detecting geochemical anomalies rather than solely 4-acid or aqua regia. Stronger digestions such as 4-acid or aqua regia, can dissolve much of the substrate, causing a dilution effect; however, weaker leaches will detect the labile elements, which will be more effective as elements associated with the anomaly enter the secondary environment as a mobile component (Hamilton, 2007). 5.3.5.2 Sequential Leach Results Seven samples were selected for sequential leach analysis based on criteria presented in Table 5.9. Samples anomalous in Cr, Mg, Nb and Ni are compared to background samples to assess which minerals host the elements of interest (Figure 5.16). Only minerals observed within the DO-18 pipe (and their likely weathering products) are considered. 94 The anomalous levels of Cr were leached by the 4-Acid and Aqua Regia digestions, indicating that it was sourced from silicates, refractory silicates and/or oxides, crystalline Fe-oxides, and phyllosilicates. Anomalous levels of Mg were also dominantly extracted by 4-Acid and Aqua Regia, and therefore likely hosts of Mg include silicates and phyllosilicates. In particular, anomalous-Mg samples also display a significant portion of digestion by HHA, indicating some Mg contained within amorphous Fe-oxides. 4-Acid digested almost the entirety of the Nb contents, thus it is likely that Nb is contained in silicates or refractory silicates and/or oxides. Lesser amounts were digested by Aqua Regia, suggesting that low levels of Nb were contained in crystalline Fe-oxides. Ni was mostly digested by Aqua Regia, and to a lesser extent, 4-Acid, suggesting its containment within crystalline Fe-oxides or phyllosilicates and lesser silicates. HHA also digested significant portions of Ni within anomalous samples, likely sourced from amorphous Fe-oxides. Table 5.9. Justification for samples submitted for sequential leach analysis. Sample Site Response Elements Elevation Location Organic Content Q515576SL 102 Anomalous Cr, Mg, Nb, Ni High Down-ice Low Q515695SL 72 Anomalous Cr, Mg, Nb, Ni High Down-ice Low Q515665SL 44 Background -- Low Up-ice Low Q515581SL 107 Background -- High Up-ice Low Q515572SL 98 Background -- High Down-ice Low Q515653SL 34 Background -- Low Down-ice Low Q515501SL 26 Background -- Low Up-ice Low 95 Figure 5.16. Sequential leach results for the most prominent geochemical anomalies: Cr, Mg, Nb and Ni. In most cases, the recovery by sequential leach is comparable to the recovery by the total 4-Acid Digestion (solid red bar below each sequential leach reading for each sample), with the exception of sample Q5156695SL, where Nb recovery is significantly greater than that of the total digestion. ‘4Atot’ indicates recovery from the 4-Acid ICP-MS analysis (Section 5.3.1). 96 5.3.6 X-Ray Diffraction Results X-Ray diffraction (XRD) was undertaken on the same seven samples as those for sequential leach analysis to assess the bulk mineralogy of each soil sample (Figure 5.17). Kimberlite-related minerals which were detected include phlogopite, clinochlore (chlorite), nontronite, and vermiculite, each weathering products of primary kimberlitic minerals (Chapter 1). Concentrations of most primary kimberlitic minerals, such as olivine, pyrope, chromite, Cr-diopside, serpentine, perovskite, and ilmenite, which are hypothesized to host the elements of interest, are too low to be detected by XRD in comparison to more abundant minerals. In ideal circumstances, mineral abundances as low as 0.5% can be detected, however the degree of peak overlap, solid solution, degree of crystallization, preferred orientation, and disorder in sheet silicates may increase the detection limit (E. Pani, pers. commun., 2017). Concentrations of Cr, Mg, Nb and Ni from 4-Acid ICP-MS results indicate that the abundance of their host minerals is significantly less than 0.5%. Felsic minerals identified by XRD from surrounding granite-gneiss host rocks include quartz, albite, orthoclase, and illite, a weathering product of feldspar (Wilson, 2004). 97 Figure 5.17. Representative mineralogy of samples also sent for sequential leach analysis. Typical mineralogy includes quartz, biotite, albite, orthoclase, phlogopite, vermiculite, clinochlore, hornblende, nontronite, and illite. 5.3.7 Discussion of Inorganic Geochemical Results The ability of each method to detect inorganic soil geochemical responses related to the DO-18 kimberlite increases as the strength of the digestion increases. Though De-Ionized Water ICP-MS analysis (weakest leach) displays high response ratios of kimberlite pathfinder elements Ce, K, Nb and Y, the response of each element individually was not as tightly constrained down-ice of the kimberlite as each of the other analyses; and, though the sum of the aforementioned elements was slightly more constrained to the northwestern quadrant down-ice of the kimberlite, several anomalous samples are still present in the up-ice direction. Conversely, peat groundwater samples taken above the Yankee, Zulu, Alpha-1, Bravo-1, and X-ray kimberlites in the Attawapiskat region by Sader et al. (2009b), displayed elevated levels of dissolved kimberlite pathfinder elements Ca, and Mg directly above the kimberlite. This supports the notion that kimberlitic pathfinder elements can exist in labile or suspended form and potentially form geochemical anomalies above a kimberlite detectable by a weak leach. However, due to lack of 98 constraint of the Ce, K, Nb and Y anomalies in this study, the confidence in this method to detect the kimberlite is decreased relative to other, more robust methods available, particularly in practical application of this study where the location of the potential kimberlite is uncertain. The strongest digestion completed on the samples was the 4-Acid coupled with ICP-MS, the results of which most successfully detected the presence of the DO-18 kimberlite. Overall, the Cr, Mg, Nb and Ni anomalies detected by the 4-Acid ICP-MS analysis were the most tightly constrained down-ice of the kimberlite, with very few anomalous samples up-ice. As mentioned, Aqua Regia is considered ‘conventional’ due to its frequent use for the digestion of soils for anomaly detection, and has been previously proven successful in the Lac de Gras region for kimberlite detection (e.g. Wilkinson et al., 2001); however, the anomaly given by the 4-Acid ICP-MS analysis in this study is the least ambiguous relative to Aqua Regia and fp-XRF, as it is most tightly constrained within the northwest quadrant, with few anomalous samples up-ice. Therefore, 4-Acid digestion is ideal for the detection of geochemical responses sourced from kimberlites, particularly in the Lac de Gras region. The relatively low response ratios given by the 4-Acid data may be due to the digest dissolving the substrate; this may have a dilution effect where trace elements within the substrate are also analysed in addition to the labile and adsorbed elements (Seneshen, 1997). The total analysis provided by the fp-XRF identified an anomaly similar to that of the 4-Acid digest; however, the anomaly detected by fp-XRF was not as tightly constrained to the northwest quadrant due to increased noise in the data. Nevertheless, the real-time data provided by this method potentially allows for in-field prioritization of targets, rendering fp-XRF a 99 valuable exploration tool, particularly given its similarity in results to the 4-Acid digest (Figure 5.18), and success at identifying a geochemical response related to the DO-18 kimberlite. Of the inorganic geochemical analyses, the 4-Acid digest is recommended for successful detection of a buried kimberlite. Its effectiveness is likely due to the kimberlite mineralogy (Chapter 2). Anomalous elements Cr, Mg, Nb and Ni and Zn are dominantly hosted in silicates, phyllosilicates and refractory silicates and/or oxides; thus, a strong digestion such as 4-Acid is required to dissolve these minerals to detect the kimberlite as Aqua Regia will not digest the minerals sufficiently (Figure 5.19). 100 Figure 5.18. 4-Acid ICP-MS results versus those of fp-XRF for a) Cr, b) Nb, c) Ni, and d) Zn. The slope (m) of the line of best fit represents the recovery by 4-Acid digest of each element versus recovery by fp-XRF, where m>1 indicates greater recovery by 4-Acid, m=1 indicates equal recovery by 4-Acid and fp-XRF, and 1>m>0 indicates greater recovery by fp-XRF. The Pearson correlation coefficient (r) represents the strength of the relationship, where r=0 indicates no relationship, r=1 indicates a perfect positive correlation, and r=-1 indicates a perfect negative correlation. The variance, or proportion of data closest to the line of best fit, is given by r2, where r2=1 shows no variance. m=0.5326 r=0.63 r2=0.399 m=0.443 r=0.63 r2=0.394 m=0.7727 r=0.82 r2=0.667 m=0.9874 r=92 r2=0.849 101 Figure 5.19. 4-Acid ICP-MS results versus those of Aqua Regia ICP-MS for a) Cr, b) Mg, c) Nb, and d) Ni. The slope (m) of the line of best fit represents the recovery by 4-Acid digest of each element versus recovery by fp-XRF, where m>1 indicates greater recovery by 4-Acid, m=1 indicates equal recovery by 4-Acid and fp-XRF, and 1>m>0 indicates greater recovery by fp-XRF. The Pearson correlation coefficient (r) represents the strength of the relationship, where r=0 indicates no relationship, r=1 indicates a perfect positive correlation, and r=-1 indicates a perfect negative correlation. The variance, or proportion of data closest to the line of best fit, is given by r2, where r2=1 shows no variance. m=1.095 r=0.96 r2=0.9307 m=4.4876 r=0.81 r2=0.649 m=1.4731 r=0.96 r2=0.9239 m=1.4954 r=0.90 r2=0.8152 102 5.4 Organic Geochemistry A suite of organic geochemical analyses were completed on soil samples collected from the research site, including spatiotemporal geochemical hydrocarbons (SGH) at Activation Laboratories, hydrocarbon analysis using GoreSorber™ hydrocarbon collectors from Amplified Geochemical Imaging (AGI) Inc., and total organic carbon, analysed by ALS Laboratories (Chapter 3). Refer to Appendix D.11 and D.12 for raw SGH and hydrocarbon collector data, respectively. 5.4.1 Total Organic Carbon (Corg) Organic material can be a significant component of soil, and within the research site, is concentrated within the organic deposits (Figure 5.20; Chapter 4). The generation of organic acids is a result of the breakdown of plant material; these acids possess a high ability to entrap trace metals via adsorption, reduction, and complexation (Idiz et al., 1986). Fulvic acids are commonly responsible for the mobility of trace elements, and humic acids are typically involved in the formation of organo-mineral complexes (Zaccone et al., 2008). Figure 5.20. Box plots of Corg per surficial material. 103 5.4.2 Spatiotemporal Geochemical Hydrocarbons (SGH) 5.4.2.1 Quality Control As total organic carbon was analysed specifically to evaluate its potential controls on inorganic geochemistry, and results from AGI hydrocarbon collectors did not detect the kimberlite, only the QA/QC for SGH data is included herein. Field duplicates, taken at every 18th site, were the only QA/QC measure undertaken as there is no CRM available for SGH. MPD was used to determine the quality of the data, as detailed in Section 5.3.1 (Figure 5.21). Figure 5.21 MPD analysis for SGH compounds of interest a) C005, b) C008, c) C009, and d) C012. Due to the semi-quantitative nature of the SGH analysis, units are not provided. 104 Compounds of interest (C005, C008, C009, and C012) exhibit a range of field reproducibility, though the majority display MPD values of less than 50%. Thus, field reproducibility is largely considered moderate, and therefore acceptable, as per Heberlein and Samson (2010). 5.4.2.2 Background Spatiotemporal Geochemical Hydrocarbons (previously Soil Gas Hydrocarbons; SGH) is a method which analyses ultra-low levels (ppt) of organic compounds in the C5 to C17 range by GC-MS following release of these compounds which were adsorbed onto near-surface samples (Sutherland, 2007). Results reported by ActLabs are given in compound groups (e.g. ‘light benzenes’, as opposed to benzene or methyl-benzene), rather than individual compounds (Figure 5.22). Compounds which are considered ‘kimberlite pathfinders’ by ActLabs comprise polycyclic aromatic hydrocarbons (PAH), biphenyls, benzenes, and alkenes (Sutherland et al., 2004). Figure 5.22. The relative average molecular weight of each of the 19 compound classes in the SGH range of analysis. Low/medium/high refers to each given class, and is not used between classes e.g. light PAH (compound class 9) has a similar molecular weight to that of a heavy propyl-benzene, class 7 (modified after Sutherland et al., 2004). Diagram is schematic. ‘MW’ refers to molecular weight. 105 SGH responses above kimberlites typically comprise concentric patterns of increased hydrocarbon variability toward the centre of the target, above the ‘reduced chimney’ (Chapter 1); this is hypothesized to be caused by increase in type and abundance of autotrophic organisms (organisms that are able to make energy-containing organic molecules from inorganic raw material) occupying concentric pH and redox regimes in the ‘reduced chimney’ above the buried deposit (Hamilton, 2007). Ultimately, the death of bacteria and consequent membrane rupture are hypothesized to be the source for many of the hydrocarbon responses (Sutherland, 2007). 5.4.2.3 Spatiotemporal Geochemical Hydrocarbon Results Light benzenes (ActLabs compound class 1, groups C005, C008, C009 and C012, and C003, to a lesser extent; Table 5.10) successfully detected the DO-18 kimberlite in the same distribution as pathfinder elements from 4-Acid, Aqua Regia, De-Ionized Water and fp-XRF analyses, whereby the signal is concentrated in till in the northwest quadrant of the sampling grid (Figure 5.24; probability plots given in Figure 5.23). Light alkanes, light branched alkanes, and light aromatics also detected the kimberlite to a lesser degree, and exhibited a similar distribution (Table 5.11). Table 5.10. Response ratios for SGH results of the light benzene compounds C003, C005, C008, C009, and C012. Compound Anomalous Concentration Cut-off Average of Background Samples Average of Anomalous Samples Response Ratio C003 98 174.61 42.39 4.12 C005 32.7 16.04 64.99 4.05 C008 82.0 284.84 41.00 6.95 C009 8.72 27.71 4.74 5.85 C012 10.0 28.51 5.15 5.53 106 Table 5.11. Compounds which detected the kimberlite and their degree of detection. All compound classes were considered, and light benzenes were the only designated kimberlite pathfinder class by ActLabs to successfully detect the kimberlite. Light alkanes, light branched alkanes and light aromatics also detected DO-18 in this study. Compound(s) Class Degree of Kimberlite Detection ‘Pathfinder’ Compound (ActLabs) C001, C002, C004 Light Alkanes High No C003, C005-C012 Light Benzenes High Yes C020 Light Alkanes Moderate No C022 Light Branched Alkane Moderate No C023, C025 Light Aromatics Moderate No Figure 5.23. Probability plots of SGH results for a) C005, b) C008, c) C009, and d) C012 concentrations. These probability plots were used to delineate plotting boundaries in Figure 5.24. The sum of each compound exhibits similar behaviour to the 4-acid, aqua regia, deionized water, and fp-XRF results (Figure 5.25): the anomaly is tightly constrained to the northwestern quadrant and is visible only in till. 107 Figure 5.24. SGH results for a) C005, b) C008, c) C009, and d) C012, with organic samples omitted. ‘LB’ refers to ‘light benzene’. Intervals are based on probability plots in Figure 5.23. As SGH analysis is semi-quantitative, units are not provided. 108 Figure 5.25. Sum of SGH compounds C005, C008, C009 and C012 (normalized by percentile prior to summation) overlain on the surficial materials map (Figure 4.4), accompanied by the probability plot used to generate the legend. 109 5.4.3 Amplified Geochemical Imaging Inc. Goresorber™ Hydrocarbon Collectors Amplified Geochemical Imaging (AGI) Inc. Goresorber™ hydrocarbon collectors (also referred to as Gore Modules) consist of a hydrophobic adsorbent encased in a microporous, expanded polytetrafluoroethylene (ePTFE) membrane (Anderson, 2006). This membrane does not not allow water to enter the module, but only molecules of interest including volatile gases, such as ethane, or volatile liquids, such as benzene (Anderson, 2006). These molecules are then able to adsorb to the contained adsorbent unhampered. Gore modules are placed in wet or dry soils (Anderson, 2006), where after a given period of time, they accumulate measureable concentrations (as low as 1 ppt, using thermal desorption GC-MS) of 86 hydrocarbon compounds within the soil (refer to Appendix E.2 for list of compounds, analytical method, factor analysis, and provided preliminary interpretations and conclusions). In this study, the AGI hydrocarbon compounds did not detect the DO-18 kimberlite. Additionally, light benzene molecules from the AGI collectors also do not show a correlation with light benzenes from the SGH analysis (Figure 5.26). The SGH compounds C005, C008, C009 and C012 are compared to the sum of benzene, toluene, ethylbenzene and propylbenzene, the four lightest AGI benzene molecules analysed. No compounds appeared to correlate with lithological unit or depositional environment. 110 Figure 5.26. SGH light benzenes compared to the sum of AGI light benzene compounds, benzene, toluene, ethylbenzene and propylbenzene. No correlation exists between the SGH light benzene compounds and the sum of four lightest AGI light benzenes analysed. 5.4.4 Discussion of Organic Geochemistry Results 5.4.4.1 Total Organic Carbon In terms of total organic carbon results, the ability of organic acids to adsorb, reduce, and form complexes with trace metals is high (Idiz et al., 1986; Zaccone et al., 2008); thus, samples with high organic content (generally from the organic soil horizons) have been omitted when considering soil geochemical anomalies potentially related to the DO-18 kimberlite. In a designed survey, organic deposits would be avoided when sampling. Consequently, the possibility of discovering false positives related to the aforementioned process is greatly decreased. 111 5.4.4.2 Spatiotemporal Geochemical Hydrocarbons Each of the SGH anomalies (C005, C008, C009 and C012) exhibit a similar distribution to that of the 4-Acid anomalies, rather than that predicted by Sutherland (2007) and Hamilton (2007), in which the SGH compounds form a concentric anomaly directly above the kimberlite. The SGH technique also successfully identified targets during the Soil Gas Hydrocarbons CAMIRO 01E02 project, (unpublished; 2002-2004) which tested surface samples over 20 known deposits, including kimberlites (Sutherland, 2007; Hamilton, 2007). In most cases, indications of an SGH response were present, and were most prominent in kimberlites (Hamilton, 2007). In this study, various compound classes from SGH data detected anomalous responses coincident with those from inorganic geochemistry results; however, the SGH technique itself did not identify the presence of the kimberlite, as the ActLabs-designated kimberlite pathfinder compounds identified four targets which are not supported by geophysical data. These targets were detailed in interpretations of the SGH data offered by ActLabs upon completion of analysis (Appendix E.1), in which ActLabs selected four targets based on the ActLabs-designated kimberlite pathfinder compound classes (Figure 5.27). These targets were given a ‘confidence rating’ by ActLabs as 4.5 out of 6; a decrease in confidence attributed by ActLabs to both wide sample spacing and a “[lack of] experience at interpreting the presence of a Kimberlitic [sic] cluster field”. A significant E-W trending fault zone through the centre of the research site was also noted by ActLabs; however, neither the fault zone, nor the four targets outlined by ActLabs are supported by geophysical data (Chapter 4). SGH compounds were also compared to ORP data, as Hamilton (2007) indicated that certain bacteria occupy certain redox regimes; however, none of the SGH compounds was found 112 to correlate with ORP data (Section 5.4) or vegetation. In summary, the lack of correlation with ORP data and the distribution of the SGH anomalies suggest that they were likely generated by the bacteria occupying the weathering kimberlite in-situ prior to transport down-ice. Figure 5.27. Interpretations offered by ActLabs for SGH data within the research site using kimberlite pathfinder compounds. Four kimberlites were detected in the northern region, and an E-W trending fault zone through the centre, though this is not supported by geophysical data (Chapter 2). 5.4.4.3 AGI Inc. Goresorber™ Hydrocarbon Collectors The AGI GoreSorbersTM did not detect an anomaly related to the DO-18 kimberlite, nor did any hydrocarbons correlate with surficial materials, vegetation, or ORP, despite success in 113 previous studies (e.g. Sader et al., 2009a). Gore Modules were installed at a 60 cm depth for 5 months over the Honerat kimberlite in western Quebec by Sader et al. (2009a), where elevated levels of dimethyl sulphide and lower levels of methyl butane were discovered above the kimberlite (Sader et al., 2009a). The lack of hydrocarbon anomalies by Gore Modules in this study may be attributed to the short installation period (21 day installation rather than the recommended 60 day installation period). Interpretations and preliminary conclusions provided by AGI Inc. (Appendix E.2) also acknowledge this possibility. 5.5 Physicochemical Measurements Physicochemical measurements comprise measurements taken in-situ with probes inserted directly into the soil horizons, or probes which measure the properties of a soil slurry mixed at the sample site. These measurements include electrical conductivity (EC), total dissolved solids (TDS), redox potential (ORP, reported as Eh), and pH. In terms of in-situ EC, most sites gave a 0 mS reading with occasional and sporadic highs, and thus EC results are not shown in this section (refer to Appendix C.2). In-situ pH is also not reported, as the pH pen in use proved unreliable (Appendix C). 5.5.1 Quality Control QA/QC duplicates for TDS, slurry pH, acidified slurry pH, and Eh are detailed herein. Field duplicates, taken at every 18th site, were the only QA/QC measure undertaken as there is no CRM available. Meters were calibrated daily to maximize accuracy and precision. MPD was used to determine the quality of the data, as detailed in Section 5.3.1 (Figure 5.28). The majority of slurry pH, acidified slurry pH, and Eh data exhibit less than 10% MPD, and are therefore 114 considered acceptable. TDS data are of moderate quality as most are less than 50% MPD, and therefore considered acceptable as per Heberlein and Samson (2010). Figure 5.28. QA/QC duplicate analysis for a) slurry pH, b) Acidified slurry pH, c) Eh, and d) TDS. 5.5.2 Physicochemical Results TDS readings do not detect the kimberlite, though an increase in TDS is present above the kimberlite in Lines 6 and 7 (Figure 5.29). Slurry pH readings exhibit dominantly circumneutral responses, and do not detect the kimberlite. In terms of acidified slurry pH (1 drop 115 of 10% HCl in 1:1 soil:water by volume), Lines 2, 3 and 4 display acidic responses relative to background above the kimberlite; Line 6 exhibits less acidic responses flanking the kimberlite; and Line 7 exhibits less acidic responses directly above the kimberlite (Figure 5.30). ORP is reported as Eh, converted using the following values: for Ag/AgCl reference electrode with 3M KCl electrolyte, at 25 ⁰C (summer temperature range at the research site), [Eh = ORP + 0.209 V], as per Langmuir (1971). Eh readings are inconsistent and do not detect the kimberlite (Figure 5.31). Data from slurry pH, TDS and Eh measurements were also considered in a spatial context. Probability plots used to delineate plotting boundaries are given in Figure 5.32. As spatial plots are best used to recognize high points in data, they were less effective than line plots at evaluating fluctuations in physicochemical measurements (Figure 5.33). 116 Figure 5.29. TDS data presented for each line of the sampling grid. The location of the kimberlite is given in purple. Organic horizon samples are not shown. 117 Figure 5.30. Slurry pH data presented for each line of the sampling grid. Slurry pH readings are presented in blue and acidified slurry pH readings are given in orange. The location of the kimberlite is given in purple. Organic horizon samples are not shown. 118 Figure 5.31. Eh data presented for each line of the sampling grid. The location of the kimberlite is given in purple. Organic horizon samples are not shown.119 Figure 5.32. a) TDS, b) slurry pH, c) Eh, and d) acidified slurry pH probability plots used to delineate plotting boundaries in Figure 5.33. 120 Figure 5.33. a) TDS, b) slurry pH, c) Eh, and d) acidified slurry pH data plotted in plan-view. Samples from the organic horizons are omitted, and plotting intervals are based on probability plots in Figure 5.32. 121 The addition of one drop of 10% HCl solution to each slurry aids in determining the buffering capacity of the soil. The ability of the soil to buffer the addition of HCl is dependent on the content of acid-neutralizing compounds, primarily calcium carbonate (calcite), whereby a significant increase in hydrogen ions in a slurry following acidification indicates a lack of calcite (Smee, 2003). Within the research site, the lack of buffering is apparent as the slurry pH became significantly more acidic. This is likely caused by the lack of calcite present, as soil conditions within the research site do not promote calcium carbonate stability (Figure 5.34). This is supported by the sequential leach data, which exhibits a lack of calcite digested by the ammonium acetate leach, in conjunction with the high calcium content sourced from silicates or refractory silicates and/or oxides, such as feldspars from the granitic host rocks (Figure 5.35). Figure 5.34. Eh-pH Pourbaix diagram for calcium, where [Ca] = 0.0001 mol/kg and [C] = 0.01. mol/kg. pH values are from the slurry pH readings, Eh are from the ORP readings. Most samples (purple) do not exist within conditions conducive for calcite formation. pH boundaries for CaCO3(s) are similar to that described by Langmuir (1968). 122 Figure 5.35. Sequential leach results for Ca. The majority of Ca was digested by the 4-Acid digestion, with minute levels of Ca from the ammonium acetate leach, indicating low abundances of calcite. Inverse difference hydrogen (IDH) is also indicative of the buffering capacity in a soil slurry. After slurry pH and acidified slurry pH readings are taken, IDH is calculated as per Equation 5.3, as per Smee (2009). Greater IDH values indicate an increased buffering capacity, as the difference between acidified and original slurry pH is less. It is hypothesized that greater IDH values may occur over kimberlites due to their calcite content (Hamilton, 2007), though IDH data largely exhibits low values flanked by elevated values above the kimberlite in this research (Figure 5.36). 𝐼𝐷𝐻 = 1(𝐴𝑐𝑖𝑑𝑖𝑓𝑖𝑒𝑑 [𝐻+] − 𝑂𝑟𝑖𝑔𝑖𝑛𝑎𝑙 [𝐻+]) 𝑤ℎ𝑒𝑟𝑒 [𝐻+] = 10−𝑝𝐻 Equation 5.3. Calculating inverse difference hydrogen (IDH). 123 Figure 5.36. Inverse difference hydrogen (IDH) values presented for each line of the sampling grid. The location of the kimberlite is given in purple. Organic-rich samples are not shown. 124 5.6 Spontaneous Potential (SP) Results Lithologies with vastly differing compositions, such as ultramafic rocks (or kimberlites) which intrude granitic rocks, will generate a significant redox contrast which may produce a spontaneous potential (SP) anomaly (Hamilton, 2000). SP surveys are designed to detect spontaneous potential anomalies, pinpointed by a redox contrast between two lithologies (Hamilton, 2000; Hamilton, 2006). SP readings and moisture measurements were taken over Lines 4, 5 and 9. Data above Lines 4 and 9 do not appear to identify the DO-18 kimberlite, though Line 5 displays a high directly above the kimberlite (Figure 5.37). As triplicate readings were taken at each site, error bars were calculated for both moisture and SP values using the standard deviation of the three readings (Appendix C.3). 125 Figure 5.37. SP readings at each sample site for lines 4, 5 and 9. 126 5.7 Discussion of Surficial Data and SP Line 5 of SP readings show elevated values directly above the kimberlite, however it correlates well with moisture content, which influences SP readings by altering the electrical potential of the soil (Burr, 1982; Corry et al., 1983). This is likely due to the moist sediments and peat deposits coincidentally located above the kimberlite rather than directly detecting DO-18. Thus, SP did not detect the kimberlite. In this study, slurry pH exhibits circumneutral pH values, and acidified slurry pH displays acidic responses, with occasional less-acidic responses above the kimberlite. This is inconsistent with Sader et al. (2009b) and Sader (2011), where alkaline responses were documented above the Attawapiskat kimberlites. The variance in pH responses in this study may be attributed to differences in organic content at each site: though the slurry pH does not show a correlation with organic content, pH levels evaluated by ALS Laboratories as a part of the De-Ionized Water leach (lab pH) from soil samples show a correlation between pH and organic content. Increased organic content is associated with more acidic soil samples (Figure 5.38), likely due to the accumulation of organic acids. Lab pH and slurry pH are not well correlated (Figure 5.39), due to differences in sample preparation prior to analysing lab pH; slurry pH was conducted on samples screened by 0.25 inch mesh, and lab pH was conducted on samples screened to -180 microns as a part of the De-Ionized Water Leach analysis. Sader et al. (2009a) also reported a reduced chimney (with Eh lows flanked by Eh highs) above the Honerat kimberlite in Western Quebec. Thus, Eh responses above the DO-18 kimberlite are not consistent with Sader (2009a), as a ‘reduced chimney’ is not detected above the DO-18 kimberlite. 127 Figure 5.38. TOC versus Lab pH. A negative correlation indicates that as the content of TOC increases, the pH is more acidic. Figure 5.39. Slurry pH versus Lab pH displays a weak correlation due to differences in sample preparation prior to analysing lab pH; slurry pH was conducted on samples screened by 0.25 inch mesh, and lab pH was conducted on samples screened to -180 microns. r= -0.67 r2=0.4477 r= 0.32 r2=0.1045 128 Overall, each method presented above detects DO-18 to a certain extent; however, results are inconsistent and therefore less robust. Surficial analyses are not recommended to detect a kimberlite, as they are less robust than other methods. 5.8 Summary Inorganic geochemical results demonstrate that the 4-Acid ICP-MS analysis of the -180 micron fraction of the Bm horizon soil was the most successful method at detecting the DO-18 kimberlite, displaying high contrast, tightly constrained anomalies in Cr, Mg, Nb and Ni, and to a lesser extent, Zn. Sequential leach results indicated that Cr is dominantly sourced from silicates, refractory silicates and/or oxides, crystalline Fe-oxides, and phyllosilicates; Mg is hosted in mainly silicates and phyllosilicates; Nb is hosted in silicates and refractory silicates and/or oxides; and Ni is hosted within crystalline Fe-oxides, phyllosilicates, and lesser silicates. Fp-XRF results in this study demonstrated the potential value of fp-XRF as an exploration tool, as it also detected the DO-18 kimberlite, and can be used for rapid prioritization of targets in the field. Select light benzene compounds from the SGH data detected anomalous responses coincident with those from inorganic geochemical results, though the SGH technique itself did not identify the presence of the kimberlite. Each of the physicochemical measurements applied to soil horizons in-situ detected the kimberlite to a certain extent; however, results were inconsistent and thus physicochemical methods are not recommended in future application as they are less robust. 129 Chapter 6: Discussions 6.1 Mineralogical Controls on Minor and Trace Element Geochemistry Concentrations of the elements of interest were compared to the major element concentrations within each sample to gain insight as to the mineralogical controls on the elements of interest. This was undertaken using data from the 4-Acid ICP-MS analysis, with organic-rich samples omitted (Figures 6.1 to 6.5). Data was divided into background and anomalous populations based on probability plots (Figure 5.4) to highlight elemental variations in the anomalous population. Primary kimberlitic minerals and their major and trace element chemistry are listed in Table 6.1, comprising minerals observed within the DO-18 kimberlite and indicator minerals present within the research site (Chapter 2 and Section 6.3, respectively). Weathering products (Chapter 1) are also considered in the discussion, but are omitted from Table 6.1 as they are not primary kimberlitic minerals. Table 6.1. Primary mineral hosts for Cr, Mg, Nb, and Ni (given in bold) within the DO-18 kimberlite, based on observed mineralogy (Chapter 2; Section 6.3; Mitchell, 1986; Muggeridge, 1995; De Hoog et al., 2010). Host Formula Major Elements Common Substitutions Common Trace Elements Olivine (Mg,Fe2+)2SiO4 Mg, Fe Ni, Cr V, Mn, Co, Cu, Zn, Li Chromite (Cr-Spinel) Fe2+Cr23+O4 Fe, Cr Al, Mg, Ti, Mn Sc, V, Co, Ni, Cu, Zn Cr-Diopside (Ca,Cr)MgSi2O6 Ca, Cr, Mg Fe, Cr, Al, Na V, Ni Phlogopite KMg3(AlSi3O10)(OH)2 K, Al, Mg Ti, Cr, Fe Rb, Ba, Sr, Li, Zn, F, Cl Perovskite CaTiO3 Ca, Ti Na, Ca, Ba, Nb, Zr, Al, Fe, Ce, U, Th, REE (mainly La, Ce, Pr, Nd, Sm, Y), Hf, Zr Picroilmenite (Mg-Ilmenite) Fe2+TiO3 Mg, Fe, Ti Cr, Mn, Al Nb, Ta, Zr, Hf, Ni, V Pyrope Mg3Al2(SiO4)3 Mg, Al Ti, Cr, Fe, Ca Ga, Sc, V, Co, Ni, Pb, Cu 130 Sequential leach data indicated that anomalous Cr concentrations is sourced from silicates, some refractory silicates and/or oxides, phyllosilicates, and crystalline Fe-oxides (25-35% Cr extracted by Aqua Regia, and 49-63% extracted by 4-Acid). As anomalous Cr concentrations are dominantly controlled by Mg and Fe, and to a lesser extent, Ti and Al (Figure 6.1a, b, c and d, respectively), mineralogical controls on Cr are expected to be by olivine, chromite, pyrope, and picroilmenite (Mg-ilmenite). Alteration products of olivine, including serpentine, chlorite, and vermiculite, may also exhibit controls on Cr. Anomalous concentrations of Mg are moderately correlated with Fe, Al, and weakly correlated with Ti (Figure 6.2a, b, and c, respectively), demonstrating that Mg is associated with pyrope, olivine, and picroilmenite, as well as olivine weathering products, including serpentine, vermiculite, chlorite and iddingsite. The lack of a strong correlation between Mg and Fe, Al and Ti indicates that Mg may also be associated with minerals present within the host rocks, including biotite and hornblende (Chapter 2). Sequential leach data indicates that Mg is associated with silicates and refractory silicates and/or oxides, phyllosilicates, and amorphous Fe-oxides (17-21% extracted by HHA, 45% extracted by Aqua Regia, and 34% extracted by 4-Acid). Anomalous concentrations of Nb are controlled by Mg (Figure 6.3a), and exhibit a strong correlation with Cr (Figure 6.3b). This indicates that Nb is controlled by mainly picroilmenite, which also contains Cr as a common substitution. This is supported by sequential leach data, which indicates that Nb is dominantly sourced from silicates and refractory silicates and/or oxides (86-88% extracted by 4-Acid). 131 Ni is highly correlated with Mg, weakly correlated with Fe and Ti, and also exhibits a strong correlation with Cr (Figure 6.4a, b, c and d, respectively); this indicates a control by olivine and its weathering products, picroilmenite and chromite. Sequential leach data indicates that Ni is sourced from silicates and some refractory silicates and/or oxides, phyllosilicates, and amorphous Fe-oxides (25-34% extracted by HHA, 40-49% extracted by Aqua Regia, and 18-23% extracted by 4-Acid). The concentrations of Ni and Mg in the kimberlite core samples compared to the Ni and Mg concentrations in the soil demonstrate that the source of the Ni and Mg is largely kimberlitic (Figure 6.5; extrapolated from Figure 6.4a). The regression line for anomalous data in Figure 6.5 does not include the kimberlite core samples. 132 Figure 6.1. Major element correlations with Cr using data from the 4-Acid ICP-MS analysis. Cr is correlated with a) Mg, b) Fe, c) Ti, and d) Al. Organic samples are not considered. The cutoff value for anomalous Cr concentrations is 36 ppm, as per Figure 5.4. 133 Figure 6.2. Major element correlations with Mg using data from the 4-Acid ICP-MS analysis. Mg is correlated with a) Fe, b) Al, and c) Ti. Organic samples are not considered. The cutoff value for anomalous Mg concentrations is 0.46%, as per Figure 5.4. 134 Figure 6.3. Major element correlations with Nb using data from the 4-Acid ICP-MS analysis. Nb is correlated with a) Mg and b) Cr. Organic samples are not considered. The cutoff value for anomalous Nb concentrations is 4.4 ppm, as per Figure 5.4. 135 Figure 6.4. Major element correlations with Ni using data from the 4-Acid ICP-MS analysis. Ni is correlated with a) Mg, b) Fe, c) Ti, and d) Cr. Organic samples are not considered. The cutoff value for anomalous Ni concentrations is 15.8 ppm, as per Figure 5.4. 136 Figure 6.5. Concentrations of Ni and Mg in each of the kimberlite core samples. Regression lines are extrapolated from Figure 6.4a, and do not include the kimberlite core samples. Black diamond indicates the composition of an average granitic shell (Beus and Grigorian, 1977). 6.2 Organic Geochemical Controls on Trace Element Geochemistry 6.2.1 Total Organic Carbon When organic-rich samples are excluded, the concentrations of Cr, Mg, Nb, Ni and Zn from 4-Acid ICP-MS analysis data are not correlated with organic carbon content (Figure 6.6a). When organic-rich samples are considered, a negative correlation between TOC and elements of interest becomes clearer (Figure 6.6b). In both instances, the decrease in concentration of Cr, Mg, Nb, Ni and Zn is likely due to dilution of the mineral content of the soil by organic matter caused by increasing TOC contents. 137 Figure 6.6. Elements of interest, represented by Nb concentrations from 4-Acid ICP-MS data, are not positively correlated with TOC, therefore TOC does not exhibit a control on their concentration when a) organic samples are not considered, and b) when organic samples are considered. 6.2.2 Spatiotemporal Geochemical Hydrocarbons (SGH) Anomalous concentrations of compound classes from SGH analysis which detected the DO-18 dispersal train are moderately correlated with elements of interest (Cr, Mg, Nb and Ni) (Figure 6.7). It is likely that SGH compounds are not exhibiting control on the elements of interest, but that their correlation is coincident. It is hypothesized that local variations in content of kimberlitic material are producing local changes in environment, altering the type and 138 abundance of organisms present; thus samples with a greater content of kimberlitic material also exhibit higher abundances of SGH compound classes of interest. Variations in surface materials also influence SGH concentrations, contrary to Sutherland (2007). Distinct concentration of several SGH compounds were noted in till (Figure 6.8a) and in organic deposits (Figure 6.8b). Figure 6.7. SGH compound classes of interest are moderately correlated with elements of interest, represented by Nb concentrations from the 4-Acid ICP-MS analysis. Graph is representative of each of the compound classes and elements of interest. Organic samples are not considered. Figure 6.8. Concentrations of SGH compounds in surficial materials. a) C113 is higher in concentration in till, and is low in organic-rich material, and b) C001 is higher in concentration in organic deposits. 139 6.3 Influence of Geomorphological Processes on Geochemistry The geomorphological processes active in the research site since glaciation are reflected in the distribution of surficial materials (Chapter 4; Figure 4.4), surface geochemistry, till geochemistry at depth (Normandeau et al., 2016) and KIM distributions (Elliott and Normandeau, 2016). These processes are hypothesized to have occurred as follows: 1. The movement of the Laurentide Ice Sheet over the DO-18 kimberlite in a dominantly northwestern direction, 290⁰-295⁰ (Ward et al., 1994). Kimberlitic material is entrained and transported down-ice and deposited in a dispersal train (Figure 6.9a). 2. The formation of lakes in topographic lows during deglaciation, particularly in the low-lying region south of the slope break, is facilitated by topographic heterogeneities in till and glacial meltwater scouring (Figure 6.9b). The presence of the lake produced glaciolacustrine sediments observed in the southeastern portion of the field site. It is hypothesized that this lake was fed by meltwater channels. 3. Subsequent draining of this lake occurred towards the south, into modern-day Tli Kwi Cho Lake. As the lake receded, the meltwater channels which fed the lake incised the till within the research site, producing the glaciofluvial sediments observed south of the slope break (Figure 6.9c). 4. Cryoturbation and frost boils are present and active, as evidenced by fresh upheaved sediment within the till blanket. This is hypothesized to aid in generating the geochemical responses observed directly over the kimberlite, based on sediment upheaval rates previously observed in the Northwest Territories (Figure 6.9d; Mackay et al., 1979). 140 Figure 6.9. Geomorphological processes hypothesized to have occurred within the research site. a) Movement of the Laurentide Ice Sheet towards the northwest, entraining kimberlitic material and generating the observed geochemical anomalies. b) Lake formed in a lower topography region of the till blanket, bound by the slope break at its northern boundary. c) Lake drainage towards the south into Tli Kwi Cho Lake, generating fluvial sediments south of the slope break. d) Current distribution of surficial sediments (as per Figure 4.3). Frost boils are ubiquitous in the till blanket north of the slope break, with few observed in till south of the slope break. 141 The distribution of surficial materials indicates that till was deposited prior to glaciofluvial or glaciolacustrine sediments, as till is observed beneath glaciolacustrine sediments and as local patches at the surface within glaciolacustrine and glaciofluvial sediments. As only till is present north of the slope break, the slope break likely represents the northern boundary of the small lake which produced the glaciolacustrine sediments. Drainage into Tli Kwi Cho Lake is supported by the morphology of the glaciofluvial unit; it is apparent that glaciofluvial sediments assume a stream-like morphology, leading to Tli Kwi Cho Lake, bound by local topography. These geomorphological processes influence the geochemistry of the sediments within the research site, resulting in a topographic control on the elements of interest. The influence of geomorphological processes on geochemistry can be characterized as having a dilution and burial effect within the southern, low-lying portion of the research site. In essence, it is hypothesized that the geochemical anomalies may have also been present south of the slope break at the same magnitude as that in the northern region; however, burial and mixing of till with glaciofluvial sediments and diluted and concealed the kimberlitic content, and thus the elements of interest. Elements of interest in the south, when considered independently of the north, do not exhibit a geochemical anomaly down-ice of the kimberlite. The influence of geomorphological processes can also be observed in KIM distributions. In the coarse fraction (0.5 mm – 1 mm) of surficial sediments within the research site, distributions of peridotitic pyrope, eclogitic pyrope, chromite, chrome diopside, and to a lesser extent, olivine, provide evidence of glacial transport as the dominant transport mechanism (KIM data from Elliott and Normandeau (2016), and drill hole locations and logs are given in 142 Normandeau et al. (2016)). Their abundances are greatest above the DO-18 kimberlite, and gradually decrease in the down-ice direction; furthermore, maximum abundances of the aforementioned KIMs gradually occur closer to the surface within each drill hole down-ice (Figure 6.10; Normandeau et al., 2016; Elliott and Normandeau, 2016). Figure 6.10 a) Map of drill holes near the research site completed as part of the SPSMPS RC drilling program in 2015. Red outline denotes boundary of drill holes considered. Drill hole locations and logs are provided by Normandeau et al. (2016). KIM counts for samples in each hole are provided by Elliott and Normandeau (2016). Drill holes for cross sections A and B are illustrated. Maximums in each drill hole profile are highlighted as the dispersal train. Cross Section A illustrates dispersal trains of kimberlitic material in the down-ice direction, as observed in b) peridotitic pyrope abundances per 10 kg of sediment and c) Ni concentrations for each sample taken at a given depth in each drill hole. Dispersal of kimberlitic material is also evident in Cross Section B for d) peridotitic pyrope abundances per 10 kg of sediment and e) Ni concentrations. Diagrams are schematic. a) 143 Figure 6.10. Continued from above. b) c) 144 Figure 6.10. Continued from above. Evidence of glacial transport is also present in concentrations of Cr, Mg, Nb, Ni and Zn, as distributions of these elements are similar to those of the KIMs, as per the partial digestion analysis data for each drill hole sample (Normandeau et al., 2016). Evidence of dilution of kimberlitic material south of the slope break is also present. In sediment samples collected from surface (dominantly till, at less than three metres depth) from drill holes, abundances of peridotitic pyrope, eclogitic pyrope, chrome diopside and chromite in the coarse fraction are d) e) 145 greater north of the slope break than samples collected in the southern region (Figure 6.11; Normandeau et al., 2016; Elliott and Normandeau, 2016). As these KIMs are fairly resistant to weathering, particularly in cold environments (Nowikci et al., 2007), it is likely that dilution is caused by sediment mixing. Figure 6.11. Peridotitic pyrope abundances per 10kg of sediment in surface samples (less than 3m depth) for each drill hole. Abundances are significantly greater north of the slope break, and subdued in the southern region. Lower pyrope abundances are indicative of sediment mixing in the south. KIM data provided by Elliott and Normandeau (2016). The evolution of the geochemical response in the research site is summarized in Figure 6.12. Glacial transport is the dominant mechanism for kimberlitic material down-ice, and glaciofluvial and glaciolacustrine sediments in the south have buried and diluted the geochemical response. Cyroturbation in the northern region is hypothesized to have enhanced the geochemical response, particularly directly above the kimberlite. 146 Figure 6.12. Summary of the evolution of the geochemical response within the field site. In the northern region, cryoturbation is hypothesized to have enhanced the presence of the geochemical response. In the south, glaciofluvial and glaciolacustrine sediments have buried and diluted the geochemical signal. The geochemical signal is represented by Ni data from the 4-Acid ICP-MS analysis. Diagram is schematic. 147 6.4 Summary Elements of interest are controlled by primary kimberlitic minerals and their weathering products, as demonstrated by 4-Acid ICP-MS data, XRD data and sequential leach data. Cr is dominantly controlled by olivine, chromite, pyrope and picroilmenite; Mg by pyrope, olivine and picroilmenite; Nb by picroilmenite; and Ni by olivine, picroilmenite and chromite. Increases in SGH compound classes of interest are correlated with local variations in kimberlitic material content. Concentrations of certain SGH compounds may also be influenced by variation in surficial materials. KIM distributions in till overlying the kimberlite from drill hole samples indicate that glacial transport is the dominant mechanism for transport of kimberlitic material down ice of the kimberlite, supported by the distribution of the elements of interest as per partial digestion analysis data from the same samples. Sediment mixing and burial from deposition of glaciofluvial and glaciolacustrine materials south of the slope break is demonstrated by the distribution of KIMS and elements of interest, as both are in higher in concentration in the northern region, down ice of the kimberlite, and lesser in the southern region. 148 Chapter 7: Exploration Implications This research highlights techniques that can be applied for the purposes of surficial geochemical target discrimination of geophysical targets by detection of kimberlite through cover. Their implications for exploration are detailed herein. 7.1 Surficial Materials and Glacial Flow Direction Mapping Prior to sampling, the identification and mapping of surficial materials and glacial flow direction indicators is imperative. This research has demonstrated that till is the dominant host for surficial geochemical anomalies, as kimberlitic material was transported glacially, and that other surficial materials, including organics, dilute the geochemical responses. Organic materials also have the potential to mobilize and entrap pathfinder elements (Idiz et al., 1986; Zaccone et al., 2008), and should therefore be particularly avoided. Thus, a surficial materials map aids in avoiding undesirable materials when sampling. Glacial flow direction indicators suggest the most recent or dominant glacial flow direction, and provide insight as to the likely direction of dispersal of kimberlitic material. Ultimately, mapping surficial materials and glacial direction indicators aid in avoiding potentially costly samples which may not contribute valuable data. 7.2 Sampling Program Design Prior to sampling, a sampling program design should be established which incorporates knowledge of as many variables as possible, including those mentioned above. This research indicates that sampling in a grid formation is ideal for anomaly identification as opposed to line surveys, which may provide ambiguous results and increase difficulty in data interpretation. Grid 149 density is reliant on target size, though a grid density where one third of the samples are above the target, one third are down-ice of the target, and one third are up-ice has proven useful in this research. Additionally, grids oriented parallel to ice flow direction are ideal to maximize the potential to obtain samples either above or within the dispersal train, increasing the likelihood that sample data will display a surface geochemical anomaly. In the absence of glacial direction indicators, a simple regular grid randomly oriented, however with the same principles of grid density outlined previously would be appropriate. Samples should be taken from a consistent media if possible, ideally the upper B soil horizon, as it is organic poor and is the zone of metal accumulation (Jackson, 1995; Seneshen, 1997; Hamilton, 2007). 7.3 Soil Sample Analysis 4-Acid ICP-MS analysis proved to be the most effective technique in this research for the identification of a surface geochemical anomaly related to the kimberlite. The success of the 4-Acid ICP-MS analysis in this research is likely due to the nature of the kimberlitic minerals which host the anomaly. A potential caveat of a 4-Acid digestion is that the substrate may also be digested, thus decreasing the contrast between anomalous and background concentrations of pathfinder elements. However, due to the unique chemistry of a kimberlite relative to its host rocks, it is unlikely that anomalous concentrations of a combination of certain kimberlite pathfinder elements (e.g. Cr, Mg, Nb and Ni) can be attributed to other sources. Fp-XRF analysis also proved to be an effective analysis for the detection of a surface geochemical anomaly, as fp-XRF analysis provided similar results to that of the 4-Acid ICP-MS analysis in this research. Reliable, real-time results allow for on-site prioritization of targets rendering fp-XRF a valuable and robust field tool. 150 7.4 Data Interpretation A multi-element approach to data is a more robust method when evaluating geochemical responses, as opposed to evaluating responses from individual elements, as kimberlites are uniquely enriched in several elements which distinguish them from other rock types. Kimberlite pathfinder elements typically include Ni, Cr, Ba, Co, Sr, Rb, Nb, Mg, Ta, Ca, Fe, K, Ti, and REEs, though their usefulness depends on the composition of the kimberlite relative to their host rocks (McClenaghan and Kjarsgaard, 2001). Though kimberlites in the Lac de Gras region have largely intruded granitic rocks, which exhibit a stark compositional contrast to kimberlites, kimberlites in the Lac de Gras region have also intruded mafic rocks such as diabase dykes (Pell, 1997; Eggleston et al., 2014). In this case, elements Cs, Rb, Ba, Th, U, Ta, Nb, La, Sr and P may be more useful as pathfinder elements, as kimberlites are more enriched in these elements relative to other mafic rocks (Mitchell, 1986). In terrains comprising alkaline rocks, such as carbonatites, syenites, nephelenites, etc., the converse range of kimberlite pathfinder elements such as Mg, Cr, and Ni, representing the mafic signal would be more appropriate. In this research, the most consistent kimberlite pathfinder elements included Cr, Mg, Nb and Ni, though Zn was also identified as a pathfinder element. When observed as a single parameter as a sum of elements normalized prior to summation, the anomaly given by the sum of elements was the least ambiguous in comparison to the anomaly of each individual element. A statistical assessment of the identified geochemical anomalies should be undertaken to identify true anomalous populations in the data, and to determine if data sets contain multiple populations. In this research, this was accomplished using probability plots, where element 151 concentrations were compared to their normal score. As inflection points mark boundaries between populations (Sinclair, 1974), true anomalous populations in data could be identified. 152 Chapter 8: Conclusions and Recommendations for Future Work The DO-18 kimberlite, buried beneath 5-20 metres of glacial sediments, can be detected using surficial geochemical target discrimination techniques. These techniques identify and quantify organic- and inorganic geochemical responses of the sampled sediments. Inorganic geochemical responses comprise anomalies in Cr, Mg, Nb, Ni and Zn, beginning from the centre of the kimberlite in the northern region of the research site, to the western edge of the sampling grid. These anomalies are observed in 4-Acid and Aqua Regia data, though the 4-Acid ICP-MS analysis has proven to be most robust, particularly given that source of the geochemical anomalies is dominantly silicates and refractory silicates and/or oxides. Organic geochemical anomalies are dominantly observed in SGH data, particularly in light benzene compounds; however, it should be noted that the anomalous responses detected by SGH data are only coincident with those from inorganic geochemical data, and that ActLabs-designated kimberlite pathfinder compounds did not detect the kimberlite. Therefore, the SGH technique itself did not identify the presence of the DO-18 kimberlite. AGI. Inc. Goresorber™ Hydrocarbon Collectors did not detect a response related to the kimberlite, hypothesized to be due to their short installation period (21 days as opposed to the recommended 60+ days installation). Mapping surficial materials, soil type, topographic variation, and vegetation aid in identifying the geomorphological processes which have been active at the research site since deglaciation. Generating a model of these processes gives insight as to the evolution of the geochemical responses. It is concluded that glacial transport is the dominant mechanism of 153 transport for elements of interest, as demonstrated by the distribution of elements of interest and KIMs both on the surface and in the till profile. Evidence of electrochemical mass transport or a ‘reduced chimney’ as proposed by Hamilton (1998) is absent in this research. It is hypothesized cryoturbation has enhanced the geochemical anomaly in the north by upheaval of kimberlitic material from the dispersal train to the surface. A geochemical anomaly may have once existed in till in the southern region of the research site, though glaciolacustrine and glaciofluvial processes which shaped the topography at the research site are also responsible for the dilution and burial of the kimberlitic material and elements of interest. As a result of the permafrost, groundwater interaction between the kimberlite and the surface environment is restricted. Consequently, simple field based analytical techniques such as physicochemical measurements (pH, IDH, TDS and Eh) are not appropriate. However, this does not preclude their use beyond the southern limit of permafrost. Overall, reproducible and cost-effective sampling and analytical strategies can be identified from this research. Surface materials and glacial direction indicator mapping is imperative, and aids in the design of the sampling grid. Grids should be at an appropriate density, based on geophysical target size. Samples should be taken from consistent media, such as the upper B soil horizon. An appropriate sample analysis should be chosen to obtain data ideal for anomaly identification; in the case of kimberlite exploration, a 4-Acid ICP-MS analysis is recommended. Interpretation of data should take into account the chemistry of the host rocks relative to that of a typical kimberlite, and a statistical assessment of the identified geochemical anomalies should be undertaken to identify true anomalous populations in the data. Through 154 surficial geochemical target discrimination techniques, the potential of undertaking expensive drilling of false-positive geophysical targets is greatly decreased. 8.1 Recommendations for Future Work Based on the conclusions in this research, recommendations for future research is suggested herein. 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Zaccone, C., Cocozza, C., Cheburkin, A.K., Shotyk, W., and Miano, T.M., 2008, Distribution of As, Cr, Ni, Rb, Ti, and Zr between peat and its humic fraction along an undisturbed ombrotrophic bog profile (NW Switzerland): Applied Geochemistry, v. 23, p. 25-33. 171 Appendix A: Methodologies A.1 Surface Materials Mapping Surface materials mapping was conducted in part through soil sampling, as the sampled material at each site was recorded (e.g. sand, diamict, etc.), as well as N-S transects for each line in the sampling grid. Topographic variations, physical features, water, and vegetation were recorded while traversing. These data were transferred onto a satellite image of the research site to aid in data interpretation and to construct a surface materials map subsequently used for interpretation of geochemical data. A.2 Soil Sampling Prior to sampling, a sampling program design must be completed. The methods for designing the sampling program for this research is given in Chapter 3, and suggestions for future sampling programs are given in Chapter 7. The full procedure undertaken for soil sampling in this research is outlined herein. Equipment List: • Flagging tape • Garmin GPSMAP® 64 Handheld GPS • ExTech Instruments MO750 Soil Moisture Meter • Hanna HI 98331 Direct Soil Conductivity and Temperature Meter • Bluelab Soil pH pen • Oakton Multi-Parameter PTTestr® 35 pH & TDS Meter • Oakton Waterproof ORP Testr® 10 Meter with Ag/AgCl electrode • 15 ml plastic measuring spoon • Plastic 25 ml calibration cylinder • Plastic 100 ml beaker for slurry tests 172 • Oakton NIST Traceable Solutions pH 7 and pH 4 buffer • Oakton NIST Traceable Solutions 1413 micro Siemens conductivity calibration solution • YSI 3682 Zobell ORP calibration solution • 1.5V replacement batteries for probes • Stirring rod • 500 ml plastic spray bottle • Ruler tape • Bottle of deionised water • Bottle of water for cleaning • Kim wipes • Ethanol • Small bottle 10% HCl • Knee pads or kneeling pad • USCS soil classification chart • Soil horizon markers • Nitrile sampling gloves • Black permanent marker • Numbered sample tag book • Gilson stainless steel soil screen with ¼ inch sieve • 5 x 8 inch thick plastic Ziploc bag for soil microbe and hydrocarbon samples • 12 x 20 inch thick plastic bag for multi-element soil samples • Packaging tape • Plastic trowel • Geological hammer • Hand lens • Camera • Paint free steel pick axe • Paint free steel shovel • Tool bag Sampling Procedure: 1) Meters must be calibrated prior to departure for sampling (calibration procedure below). 2) Sampling sites are chosen as close to the planned sample sites as possible, though slopes, animal manure, and evidence of anthropogenic activity (e.g. drill holes, drilling sites) are avoided. 173 3) Prior to sampling, a photo of the site number and sample ID are taken, as well as a plan-view photo of the sample location, in which the pickaxe handle is laid in the centre with the handle pointing north. 4) The ‘vegetation cap’ is removed with the shovel, approximately 40 cm x 40 cm in size, and set aside to be replaced upon the completion of sampling to preserve the environment. 5) A hole is dug with the dimensions 40 cm x 40 cm x 40 cm, wide enough to operate the meters in-situ within the hole, and for efficient soil sampling. 6) Each soil horizon is identified and clearly marked. A photograph is taken with the ruler tape laid top to bottom in the photo frame. 7) For each horizon, colours and depths from the surface are recorded, as well as any other noteworthy distinguishing features. 8) In-situ measurements of electrical conductivity, soil moisture and pH are taken in the centre of every soil horizon, beginning from the bottom horizon, upwards. This is done using the Hanna HI 98331 Direct Soil Conductivity and Temperature Meter, ExTech Instruments MO750 Soil Moisture Meter, and the Bluelab Soil pH pen, respectively. The meter with the narrowest diameter is used first, as the same hole is used for each measurement, and cavities around the meter are to be avoided. Meters are inserted smoothly also to avoid generating cavities around them. 9) With the trowel, approximately 1 kilogram of soil intended for multi-element geochemistry is sampled from the upper 1-11 cm of the B horizon, leaving room to avoid contamination from horizons above. If the B horizon is less than 11 cm thick, the sample is taken from the entire B horizon. If necessary (i.e. if numerous large clasts are present), 174 the soil is sieved through the ¼ inch sieve. The soil sample is collected into a 12 x 20 inch thick plastic bag with a numbered sample tag. The bag is folded over itself and sealed using packing tape. 10) Approximately 0.25 kg of B horizon soil is sampled for SGH analysis and collected in a 5 x 8 inch Ziploc bag with a numbered sample tag. 11) Approximately 0.25 kg of B horizon soil is sampled for microbe analysis. It is collected in a 5 x 8 inch Ziploc bag with a numbered sample tag. All three sample types from the same sample site are given the same sample ID number. 12) To prepare the slurry, 30 mL of de-ionized water are measured into the beaker. 30 mL of screened B horizon soil (measured with the 15 mL measuring spoon) are poured into the beaker, making a 1:1 soil to water volume ratio, and stirred for 30 seconds using the stirring rod. This slurry is used for all slurry measurements. 13) The Oakton Waterproof ORP Testr® 10 Meter is used to measure ORP. It is immersed in the slurry for 60 seconds to allow the meter to stabilize prior to recording the measurement. Do not exceed 5 minutes for meter stabilization. 14) TDS and pH of the slurry is measured using an Oakton Multi-Parameter PTTestr® 35 pH & TDS Meter. Once the meter has stabilized, the measurements are recorded. 15) 10% HCl is added to the slurry, and pH and TDS are measured again. 16) The trowel, shovel, pickaxe and sieve are cleaned thoroughly between sample sites. Beakers, meters and measuring spoons are to be cleaned first with tap water followed by distilled water. Meters must be maintained following the manufacturers recommendations. 17) Clast lithology, shape, and abundance are recorded. 175 18) Vegetation, sample material (e.g. sand, diamict, etc.), geomorphological features, and slope (if applicable) are recorded. 19) Hole is backfilled and ‘vegetation cap’ is replaced to preserve the environment. 20) A duplicate soil sample, in which each of the above steps are repeated, was taken no more than 5 to 6 metres from the original site (within 10% of the sampling grid spacing, in this case, 50 m x 60 m). This was performed every 18th sample to determine the field reproducibility. A CRM (OREAS25a) inserted every 16th sample to evaluate accuracy of the analysis. Both are packaged and labelled similar to ordinary samples. Meter Calibration Procedure: 1) The Bluelab Soil pH pen is calibrated every evening prior to departure for soil sampling the next morning. It is calibrated with the Oakton NIST Traceable Solutions pH 7 and pH 4 buffer. The meter is calibrated by insertion directly into the solution packets, and calibration is complete once it reads the same pH as both of the solution packets. 2) The Oakton Multi-Parameter PTTestr® 35 pH & TDS Meter is calibrated every evening prior to departure for soil sampling the next morning. The pH parameter is calibrated in the same fashion as Step 1, and is directly after the Bluelab Soil pH pen as it uses the same Oakton NIST Traceable Solutions pH 7 and pH 4 buffer solution packets. The TDS parameter is calibrated using Oakton NIST Traceable Solutions 1413 micro Siemens conductivity calibration solution by pouring the contents of the packet into a beaker. Calibration is complete once the meter reads 1413 micro Siemens. 3) The Hanna HI98331 Soil Test EC & Temp Meter was checked every evening, also using the Oakton NIST Traceable Solutions 1413 micro Siemens conductivity calibration 176 solution, though it generally did not require calibration. When calibration is required, it is performed in a non-conductive plastic cylinder. 4) The Oakton Waterproof ORP Testr ® 10 Meter is checked daily using YSI 3682 Zobell ORP calibration solution. A.3 Laboratory Sample Submission Prior to analysis, sample preparation must be undertaken to create a homogeneous, representative sub-sample. Soil samples were submitted to ALS Minerals Laboratories (ALS) in North Vancouver with the ALS code PREP-41 instructions: 1) Split the sample in half, preserve one half in the original sample bag. 2) Dry the remaining half at <60⁰C. 3) Sieve the sample to -180 microns (80 mesh). 4) The coarse fraction (+ 180 microns) is set aside in a separate sample bag. 5) The fine fraction (-180 microns) is submitted for analyses (described below). Every 16th sample, the CRM OREAS25a is to be analysed. The CRM is not to be split, dried or screened. A.4 ME-MS61 – 4-Acid Digestion 0.25 grams of a prepared sample are digested with perchloric (HClO4), nitric (HNO3), hydrofluoric (HF) and hydrochloric (HCl) acids, for a near-total digestion. The residue is topped up with dilute HCl and analysed by inductively coupled plasma – atomic emission spectroscopy 177 (ICP-AES) and subsequent analysis by inductively coupled plasma – mass spectrometry (ICP-MS). Results are corrected for spectral interelement interferences. A.5 ME-MS41L – Aqua Regia Digestion 0.5 grams of a prepared sample are digested by the standard ALS Aqua Regia 3:1 HCl:HNO3 in a graphite heating block. The solution is analysed by ICP-AES and ICP-MS and results are corrected for spectral interelement interferences. A.6 ME-MS03 De-Ionized Water Leach with pH 1.0 grams of a prepared sample are leached with de-ionized water and digested in a water bath at 60⁰C for two hours. Solids are separated from the solution via centrifuging and decanting the supernatant (liquid lying above the solid residue). The solution is then analysed by ICP-MS for trace elements and ICP-AES for major elements, including Al, Ca, Fe, K, Mg, Mg, Na and P. The De-Ionized Water Leach was done twice in this study, as the first set of results exhibited strong evidence of instrument drift. Data shown in Chapter 5 and appendices are from the second analysis. A.7 Organic Carbon (C-IR06a) Total organic carbon was measured at ALS Minerals Laboratories by Leco direct combustion and infrared absorption. A 0.1-0.2 gram prepared sample is boiled in dilute (25%) hydrochloric acid to remove inorganic carbon (carbonate). The solution is subsequently filtered through a porous Leco crucible to separate the organic carbon. The residue is washed with de-ionized water and dried prior to placement in a high frequency Leco induction furnace in a 178 stream of oxygen. The response by the Leco detector is processed and displayed as total organic carbon by percentage. A.8 Sequential Leach Seven samples were submitted to ALS Minerals Laboratories for a Sequential Leach Analysis. These samples include: Q515576SL; Q515695SL; Q515665SL; Q515581SL; Q515572SL; Q515653SL; and Q515501SL (refer to Chapter 5 for sample selection justification). The order in which extractions are applied, as well as their full procedure, are described below. Information is provided by Katerina Paley, Senior Account Manager, ALS Minerals Division. 1) De-Ionized Water (ME-MS03) Methodology described above. Reagents: De-ionized water Starting pH: 6.0 to 7.0 Leaching time: 2 hours  Leaches most of the water soluble salts 2) Ammonium Acetate Leach (ME-MS04) 1.0 grams of prepared sample is leached with 40 mL of ammonium acetate in acetic solution and shaken for 2 hours. The solution is separated from solids via centrifuging and decanting the supernatant, and analysed by ICP-MS for trace elements and ICP-AES for major elements. Reagents: 0.1M ammonium acetate Starting pH: 5.0 to 5.2 179 Leaching time: 2 hours  Leaches most of the acetate soluble secondary minerals, surface adsorbed analytes, carbonates 3) Cold Hydroxylamine-Hydrochloride Leach (ME-MS05) 1.0 grams of prepared sample is mixed with 25 mL of hydroxylamine hydrochloride solution and digested in a water bath for 2 hours at 60⁰C for two hours. The solution is separated from solids via centrifuging and decanting the supernatant, and analysed by ICP-MS for trace elements and ICP-AES for major elements. Reagents: 0.1M ammonium acetate Starting pH: 5.0 to 5.2 Leaching time: 2 hours  Leaches most of the acetate soluble secondary minerals, surface adsorbed analytes, carbonates 4) Hot Hydroxylamine-Hydrochloride Leach (ME-MS06) 1.0 grams of prepared sample is 25 mL of a hydroxylamine hydrochloride solution and rolled for 2 hours at room temperature. The solution is separated from solids via centrifuging and decanting the supernatant, and analysed by ICP-MS for trace elements and ICP-AES for major elements. Reagents: 0.25M NH2OH HCl in 0.25M HCl Starting pH: 0.9 to 1.3 Leaching time: 2 hours  Digests most amorphous Fe oxides 180 5) Sodium Pyrophosphate Leach (ME-MS07) 1.0 grams of prepared sample is mixed with 25 mL of sodium pyrophosphate solution and rolled for 1 hour at room temperature. The solution is separated from solids via centrifuging and decanting the supernatant, and analysed by ICP-MS for trace elements and ICP-AES for major elements. Reagents: 0.1M Na4P2O7 10H2O Starting pH: 9.9 to 10.3 Leaching time: 1 hour  Leaches some crystalline Fe oxides  Appropriate for humus and very organic-rich soils Upon completion of the sodium pyrophosphate leach, the residue is prepared for aqua regia digestion. After the aqua regia digestion, the residue is dried and split: one portion of the residue is sent for 4-Acid digestion (ME-4ACD81), and the other for fusion analysis (ME-MS81). The residue is split because both the 4-Acid digestion and fusion cannot be undertaken on the same portion of the residue, as both methods will dissolve the majority of the residue (the 4-Acid digestion being a near-total digestion, and the fusion analysis being a total digestion). 6) Aqua Regia Digestion (ME-MS41L) Methodology described above. 7) 4-Acid Digestion (ME-4ACD81) Methodology described above. Reagents: HCl (ρ20 1.16 – 1.18 g/mL); HNO3 (ρ20 1.42 g/mL); HCLO4 (ρ20 1.70 g/mL); HF (ρ20 1.20 g/mL) 181 Digestion time: 145-180 minutes  HF digests majority of silicates and alumino-silicates  Silica is volatilized as silicon tetrafluoride  Will not dissolve significant quantities of major refractory minerals (chromite, columbite-tantalite, cassiterite, magnetite, rutile, wolframite and zircon) 8) Lithium Borate Fusion (ME-MS81) Reagents: Lithium borate flux - 12:22 (consisting of 35.3% lithium tetraborate (Li2B4O7) and 64.7% lithium metaborate (LiBO3). Fusion time: 20-25 minutes  Lithophile elements tend to occur in matrices requiring stronger dissolution procedures to separate them from their bulk matter  Lithium tetraborate is a more acidic flux appropriate for alkaline oxides such as CaO, MnO, MgO and FeO. Lithium metaborate is more basic and appropriate for acidic (felsic) sample types such as TiO2 and SiO2. A.9 Whole Rock Lithogeochemistry Three kimberlite drill core samples (K2P-0018, K2P-0027, and K2P-0067) were lent to the project by Peregrine Diamonds Ltd. (Peregrine). Samples were cut in half, and one half was cut into quarters. One half was returned to Peregrine, one quarter submitted for thin section preparation, and the remaining quarter submitted to ALS Minerals Laboratories for whole rock lithogeochemical analysis. As many large xenoliths as possible were removed from the core prior to submission to reduce contamination. 182 A clay sample (NGO-RC15-061-13a) was donated to the project by the Northwest Territories Geological Survey. This sample was also submitted ALS Minerals Laboratories for whole rock lithogeochemical analysis to determine the origin of the sample, as it was recovered directly above the DO-18 kimberlite during the Slave Province Surficial Materials and Permafrost Study RC Drilling Program (2015), and did not resemble other clay-rich sediments in the vicinity. This sample later determined to be kimberlitic based on rare earth element geochemistry. Each of the four samples were also submitted to ALS Laboratories for lead isotope analysis. The whole rock lithogeochemical analysis (ALS package CCP-PKG01) and lead isotope analysis methodologies are as follows. ME-ICP06 (Analyses major element oxides) and OA-GRA05 (Measures loss on ignition (LOI)) A prepared sample (0.2 g) is added to a lithium metaborate/lithium tetraborate flux (0.9 g), mixed, and fused in a furnace at 1000⁰C. The melt is cooled and dissolved in 100 mL of nitric acid (4%)/hydrochloric acid (2%). The solution is analysed by ICP-AES. Oxide concentration is calculated from elemental concentration. Oxides analysed include SiO2, Al2O3, Fe2O3, CaO, MgO, Na2O, K2O, Cr2O3, TiO2, MnO, P2O5, SrO, and BaO. The total oxide content may be determined from LOI values if required. A prepared sample (1.0g) is placed in an oven at 1000⁰C for one hour, cooled, and weighed. The LOI (%) is calculated from the difference in weight. 183 C-IR07 (Measures total carbon content) Total carbon content of a prepared sample is measured using a Leco Furnace (as described above). S-IR08 (Measures total sulphur content) A sample weighing 0.01-0.1 g is heated to approximately 1350⁰C in an induction furnace while passing a stream of oxygen through the sample. Sulphur dioxide released is measured by an IR detection system which provides the total sulphur result. ME-MS42 (Measures volatile gold-related trace elements) An Aqua Regia extraction (as described above), used to measure gold-related elements, including As, Bi, Hg, In, Re, Sb, Se, Te, and Tl. ME-4ACD81 (Measures base metal concentrations) A 4-Acid digestion (as described above), used to analyse base mental concentrations, including Ag, Cd, Co, Cu, Li, Mo, Ni, Pb, Sc, and Zn. ME-MS81 (Analyses resistive elements) A prepared sample (0.20 g) is added to a lithium metaborate flux (0.90 g), mixed, and fused in a furnace at 1000⁰C. The melt is cooled and dissolved in 100 mL of HNO3 (4%)/HCl3 (2%) solution. The resultant solution is analysed by ICP-MS for elements including Ba, Ce, Cr, Cs, Dy, Er, Eu, Ga, Ge, Gd, Hf, Ho, La, Lu, Nb, Nd, Pr, Rb, Sm, Sn, Sr, Ta, Tb, Th, Tm, U, V, W, Y, Yb and Zr. 184 A.10 X-Ray Fluorescence (XRF) Analysis XRF analysis was completed at The University of British Columbia using the Olympus Delta DP-6050-CC at 50 keV in a certified stand to enable analysis in closed-beam mode. Software for remote instrument operation was provided by Reflex Canada. Prior to analysis, calibration of the instrument was undertaken using certified reference materials (Till-1, Till-2, Till-3, and OREAS-25a) and a total of 15 soil samples collected from the research site in this project, the Woodjam property (Consolidated Woodjam Copper Corp.), and the Lara property (Treasury Metals Inc.). Soil samples were analysed by fusion ICP-OES/MS to ensure total element recovery. CRMs and soil samples were analysed in plastic cups covered by a 4 micron prolene film interface between the instrument and the sample. Geochem and Soil modes were used to determine total concentrations of major and trace elements, respectively. Regression calculations were undertaken using a linear regression in Excel without forcing the data through the intercept. Regression parameters and intercepts were used to define the calibrations for both Soil Mode and Geochem Mode, though Geochem Mode is not discussed herein (Figure A.1). Sample analysis was undertaken using both Soil Mode and Geochem Mode on the unused portion of the dried -180 micron fraction of each of the soil samples collected at the research site, loaded into plastic cups and covered by a 4 micron prolene film. Detection limits for each element calibrated were calculated using the lowest value greater than zero, and with a reported 3 times standard deviation error less than 100% of the reported value. Detection limits for each trace element analysed in Soil Mode are given Chapter 5, with the exception of Mg, as its concentration was too low for reliable detection.185 Figure A.1. Recession graphs for fp-XRF Soil Mode data. Only calibrated elements are shown. Note, Ni is not shown as calibration was unnecessary due to its insignificant effect on the data. 186 Figure A.1. Continued from above. 187 Figure A.1. Continued from above. 188 Figure A.1. Continued from above. 189 A.11 Petrography Petrography was completed on the aforementioned drill core samples of DO-18 (K2P-0018, K2P-0027, and K2P-0067) at The University of British Columbia Microscopy Lab, using the Nikon Eclipse E600 POL polarizing microscope. Photomicrographs were taken using the Canon Rebel EOS T21 camera. A.12 Spatiotemporal Geochemical Hydrocarbons (SGH) Soil samples collected were sent to Activation Laboratories (ActLabs) in Lancaster, Ontario for Spatiotemporal Geochemical Hydrocarbon (SGH) analysis to determine the total content of hydrocarbon classes in the C5 to C17 range. Samples are dried at 40⁰C and sieved to the -250 micron fraction. A hexane and acetone extraction is applied to samples to extract surface-bound hydrocarbons (P. Winterburn, pers. commun., 2017). Extractants are analysed using gas chromatography – mass spectrometry (GC-MS). An interpretation of the data was also provided by ActLabs (Appendix E.1). A.13 Amplified Geochemical Imaging (AGI) Inc. GoreSorber™ Hydrocarbon Collectors GoreSorber™ hydrocarbon collectors comprise an adsorbed enveloped in a hydrophobic ePTFE membrane which allows the penetration of hydrocarbons and repels water. At AGI. Laboratories, hydrocarbons in the C2 to C20 range, in addition to carbon dioxide and several organo-sulphur compounds are analysed by thermal desorption GC-MS. Upon completion of analysis, AGI Inc. also provided a QA/QC assessment and interpretation of the data (Appendix E.2). 190 Equipment List: • GoreSorber™ Hydrocarbon Collectors provided by AGI Inc. • Insertion rod • 12-inch screwdriver • Hammer • Bright coloured string • Scissors • Nitrile gloves • Shovel • Ethanol • Paper towels • Flagging tape • GPS • Garbage bag Hydrocarbon Collector Installation Procedure: 1) Prior to installation, products that contain hydrocarbons, including deodorants, insect repellant, or sunscreen, should not be worn to avoid contamination of hydrocarbon collectors. Nitrile gloves should be worn for the entirety of the installation process. 2) Use ethanol to clean scissors and insertion rod and scissors. 3) Using the shovel, dig a hole approximately 12 inches deep, ensuring the hole is wide enough to manoeuver the 12 inch screwdriver. 4) Hammer the screwdriver into the bottom of the hole, a minimum of 6 inches, up to 12 inches. This is to ensure the hydrocarbon collector will be inserted into the ground at 18 to 24 inches depth (Figure A.2a) 5) Cut a segment of string approximately 60 cm in length and tie a loop in one end. This step can also be completed in advance, as long as nitrile gloves are worn and string is kept separate from contaminants. 191 6) Select a hydrocarbon collector to be installed. Record the hydrocarbon collector number, box number, GPS coordinates and date of installation. 7) Remove the hydrocarbon collector from its jar and secure the string to the hydrocarbon collector by looping the two together, forming a secure knot. 8) Use the insertion rod to insert the hydrocarbon collector into the hole created by the screwdriver (Figure A.2b). 9) Remove the insertion rod and backfill the hole, covering the hydrocarbon collector as quickly as possible (Figure A.2c). 10) Completely backfill the hole to its original surface level (Figure A.2d). 11) Record the time and depth of insertion. 12) Use flagging tape to clearly mark the area, ensuring the hole can be found again to retrieve the hydrocarbon collector. 13) A 60 day installation period is recommended by AGI Inc. Hydrocarbon Collector Retrieval Procedure: 1) Using GPS, locate the hydrocarbon collector. 2) Wearing nitrile gloves, carefully excavate the hole to locate the string and gently pull the hydrocarbon collector from the ground. 3) Remove the string. If scissors are required, ensure they are cleaned with ethanol in advance. 4) Place the hydrocarbon collector in its original jar, ensuring that the number on the jar matches the number on the hydrocarbon collector. Place the jar back in its assigned position in the storage box. 192 5) Record the date and time of hydrocarbon collector retrieval, as well as any other relevant information (e.g. lost or damaged collector, animal tampering, etc.). 6) Once each of the hydrocarbon collectors are retrieved, follow laboratory instructions and return them to AGI Inc. laboratories promptly. Figure A.2. Hydrocarbon collector installation procedure. a) Hole dug with shovel and by hammering the screwdriver into the bottom of the hole. b) Hydrocarbon collector is inserted upright into the hole using the insertion rod. c) Promptly cover the hydrocarbon collector by backfilling the hole, ensuring the string can be easily located upon retrieval. d) Backfill the hole to its original surface level. A.14 Spontaneous Potential (SP) Equipment List: • Copper – copper sulphate electrodes and UV resistant carrying case • 80 gauge insulated copper wire (1 km length was used in this research) • Length of wood approximately 1 m in length to allow the coil to rotate • Fluke 28 II True RMS Multimeter 193 • GPS • Shovel • Wire strippers • Alligator clips • Trowel • ExTech Instruments MO750 Soil Moisture Meter • Wood stake • Electrical tape • Plastic sample bags Before entering the field: 1. Ensure electrodes are saturated with copper sulphate gel. 2. Test connections by attaching alligator clips to electrodes, both ends of the copper wire, and multimeter. 3. Label electrodes A, B and C. Assign one electrode as the base electrode, and another as the mobile electrode. The third is a spare. Ensure the electrode carrying case blocks sunlight, as UV radiation on electrodes may cause a drift in readings. 4. Check the weather forecast as electrical storms may cause the voltage to oscillate, generating inaccurate readings. 5. Establish a survey design. In this application, each E-W grid line was a separate survey. Base stations were the western-most site in each grid line. Base stations should be above the water table, away from low Eh and alkaline pH environments (e.g. swamps), and at least 500 m from anthropogenic influences, such as power lines or drill casings. In the field: 1. Locate the base station for the survey. 194 2. Use the shovel to dig a hole until the top of the B or C horizon is exposed. Use the trowel to dig a smaller hole, and insert the base electrode. Pack sediments firmly around the electrode to ensure a tight seal, completely covering the ceramic portion of the electrode. 3. Insert wood stake into the ground approximately 24 inches from the base electrode. 4. Wrap one end of the wire around the stake 3 times. This will ensure the probe is not pulled out of the ground during the survey. 5. Connect the same end which was wrapped around the stake to the electrode using an alligator clip. Secure the connection with electrical tape (Figure A.3a) 6. If applicable, protect connection from rain using a thick plastic sample bag. 7. Test the connection by repeating Step 2, but using the mobile electrode, a short distance from the base electrode. 8. Connect the unused end of the copper wire to the negative lead on the multimeter to connect it to the base electrode, and the mobile electrode to the positive lead. 9. Record the resistance. If resistance is less than 50 kΩ, the connection is good. Note, in dry areas, resistance may be higher. 10. Set the multimeter to read mV, and record the voltage between the two electrodes (Figure A.3b). 11. When the test is complete, disconnect the multimeter and remove the mobile electrode and place it in the carrying case. 12. Locate the next site in the survey, unraveling the wire along the way, leaving one end of the copper wire connected to the base electrode. At the site, record the moisture content using the moisture meter. Install the mobile electrode by repeating Step 2. 13. Connect the multimeter to the base station and the mobile electrode by repeating Step 8. 195 14. Record resistance and voltage as per Steps 9 and 10, as well as distance from base station. In this study, triplicate readings (3 separate probe installations) were taken at each site to determine field reproducibility and precision. 15. Continue to the next station and repeat Steps 12-14. 16. If the survey line is longer than the copper wire, mark the final station as the next base station and repeat the survey to the end of the survey line. Figure A.3. Spontaneous potential methods. a) Connecting the base electrode to the copper wire and wrapping the wire around a wooden stake to avoid pulling out the base electrode. b) Recording resistance and voltage after connecting the base electrode and the mobile electrode to the multimeter. A.15 X-Ray Diffraction (XRD) Analysis X-Ray diffraction (XRD) analysis was completed on a separate portion of the same 7 samples as those submitted for sequential leach analysis to confirm which mineral phases were present in the soil. Sample preparation involved grinding the samples into micron-sized particles and mixed with ethanol to form a paste. The paste was then smeared onto a sample mount, and upon drying, inserted into the Bruker D8 Focus (0-20 LynxEye detector) X-ray diffractometer. Data was analysed using DIFFRAC.EVA software. 196 Appendix B: Quality Assurance/Quality Control (QA/QC) For 4-Acid and Aqua Regia ICP-MS analyses, both certified reference materials (CRMs) and field duplicates are used to determine the quality of the data and evaluate field reproducibility, respectively. Field duplicates were taken at every 18th field site, and CRMs (OREAS25a) were inserted into the sample suite every 16th sample. Field duplicates comprise sample material collected from a separate sample hole within 2 metres from the original, sampled using the same criteria as the original. Accuracy of analysis is considered acceptable within ± 3 standard deviations from the certified value for the CRM for each element; where a certified value is not given, the median value ± 30% is used. Field reproducibility and precision in duplicate samples is determined using mean percent difference (MPD; Equation 5.2), where less than 20% difference in data is considered to be high quality data. As the physicochemical measurements, De-Ionized Water ICP-MS analysis, SGH and AGI hydrocarbon analyses do not have CRMs, the MPD is the only QA/QC implemented on these data sets. For the fp-XRF analysis, analytical duplicates, (comprising same puck as the original, but re-positioned) and CRMs were analysed every 20th sample. Field duplicates remained in the same sequence as those in other analyses. Included in this section are results from QA/QC analyses for each of the aforementioned data sets. Where CRM values are given in red text where they are greater than the certified value plus 3 standard deviations, or less than the certified value minus 3 standard deviations. Values are also given in red text where values are greater than the median plus 30%, or less than the median minus 30%. In terms of duplicate analyses, values are given in red text where the MPD is 197 greater than 20%. Elements reported as less than their detection limit are reported herein as half of their detection limit (refer to Appendix D for raw data values for each analysis). The QA/QC analyses herein include:  B.1. Physicochemical Measurements – Field Duplicate Analysis  B.2. 4-Acid ICP-MS – CRM Analysis  B.3. 4-Acid ICP-MS – Field Duplicate Analysis  B.4. Aqua Regia ICP-MS – CRM Analysis  B.5. Aqua Regia ICP-MS – Field Duplicate Analysis  B.6. De-Ionized Water ICP-MS – Field Duplicate Analysis  B.7. fp-XRF Soil Mode – Field and Analytical Duplicate Analysis  B.8. fp-XRF Soil Mode – CRM Analysis  B.9. SGH Hydrocarbons – Field Duplicate Analysis  B.10. AGI Hydrocarbons – Field Duplicate Analysis B.1 Physicochemical Measurements Duplicates - MPD (%)Original Duplicate Original Duplicate Original Duplicate Q515592 Q515593 MPD Q515654 Q515655 MPD Q515695 Q515696 MPDParameter Unit 18 18b (%) 35 35b (%) 72 72b (%)In-Situ pH - 4.1 4.3 4.2 1.19 5.1 5.1 5.1 0.00 3.4 3.4 3.4 0.00Slurry pH - 5.9 5.9 5.9 0.00 5.6 5.8 5.7 0.88 5.8 5.6 5.7 0.88Acidified Slurry pH - 3 4.9 3.95 12.03 3.7 3.7 3.7 0.00 4.7 4.4 4.55 1.65TDS ppm 18 10 14 14.29 19 13 16 9.38 24 25 24.5 1.02Acidified TDS ppm 558 455 506.5 5.08 205 217 211 1.42 176 190 183 1.91ORP mV 257 253 255 0.39 310 304 307 0.49 288 173 230.5 12.47Eh mV 466 462 464 0.22 519 513 516 0.29 497 382 439.5 6.54Original Duplicate Original Duplicate Q515582 Q515583 MPD Q515588 Q515589 MPDParameter Unit 108 108b (%) 126 126b (%)in-situ pH - 5 4.7 4.85 1.55 4.3 4.2 4.25 0.59Slurry pH - 6.7 6.4 6.55 1.15 6.2 6 6.1 0.82Acidified Slurry pH - 2.9 2.7 2.8 1.79 2.8 2.8 2.8 0.00TDS ppm 16 9 12.5 14.00 9 8 8.5 2.94Acidified TDS ppm 567 570 568.5 0.13 450 427 438.5 1.31ORP mV 254 246 250 0.80 259 270 264.5 1.04Eh mV 463 455 459 0.44 468 479 473.5 0.58Mean Mean MeanMean Mean198ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Certified Standard Certified Certified Sample Sample Sample Sample Sample Sample Sample SampleElement Unit Value Deviation (SD) Value + 3SD Value - 3SD Q515516a Q515551a Q515583a Q515599a Q515666a Q515667a Q515683a Q515700aAl % 8.87 0.425 10.148 7.598 9.25 9.53 9.23 9.39 9.49 9.65 9.63 9.69Ba ppm 147 5 160.952 132.926 160 160 150 160 160 160 160 160Be ppm 1.02 0.17 1.527 0.522 0.87 0.85 0.88 0.85 0.88 0.89 0.92 0.93Bi ppm 0.35 0.034 0.451 0.249 0.36 0.35 0.34 0.35 0.34 0.35 0.35 0.35Ca % 0.309 0.008 0.333 0.285 0.32 0.31 0.31 0.31 0.31 0.32 0.32 0.32Ce ppm 48.9 2.71 57.034 40.797 46.7 50.4 50.7 49.3 52 52.5 52 53.5Co ppm 8.20 0.663 10.188 6.208 7.4 7.5 7.6 7.4 7.3 7.4 7.5 7.5Cr ppm 115 8 138.935 90.250 118 117 115 120 121 125 122 117Cs ppm 6.46 0.334 7.464 5.458 6.34 6.41 6.49 6.53 6.56 6.63 6.72 6.85Cu ppm 33.9 2.29 40.781 27.026 30.6 30.5 31.8 31.1 30.1 30.8 33.6 32.7Fe % 6.60 0.157 7.066 6.127 6.72 6.7 6.53 6.69 6.78 6.85 6.84 6.84Ga ppm 25.9 1.77 31.207 20.575 27.3 25.8 26.2 26.2 25.7 26.2 26.6 26.9Hf ppm 4.53 0.53 6.130 2.934 4.9 4.4 4.8 5.1 4.9 5.1 4.8 4.9K % 0.482 0.014 0.526 0.439 0.5 0.49 0.49 0.49 0.5 0.49 0.5 0.51La ppm 21.8 2.02 27.877 15.784 22 23 23.7 23 24.2 24.1 24.1 24.8Li ppm 36.7 1.34 40.781 32.713 35.7 34.6 36 33.7 34.1 34.1 35.2 36.7Mg % 0.327 0.017 0.377 0.277 0.32 0.32 0.31 0.31 0.31 0.32 0.33 0.33Mn % 0.047 0.002 0.052 0.043 0.0487 0.0484 0.0473 0.0479 0.0483 0.0485 0.0497 0.0498Mo ppm 2.55 0.158 3.023 2.078 2.45 2.35 2.47 2.44 2.4 2.39 2.44 2.49Na % 0.134 0.004 0.146 0.121 0.14 0.14 0.13 0.14 0.14 0.14 0.14 0.15Nb ppm 22.4 1.71 27.530 17.274 23.4 22.9 23.7 23 23.3 24 24 24.2Ni ppm 45.8 4.05 57.996 33.690 43.1 42.8 44.6 44.4 43.8 44.6 44.9 45.3P ppm 480.256 24.375 553.381 407.130 520 510 500 500 510 530 530 530Pb ppm 25.2 1.87 30.837 19.587 24.2 25 24.5 24.1 24 26.9 24 24.4Rb ppm 61 3.9 72.617 48.945 59.6 61.1 61.1 63.1 62.3 63.2 61.7 63.4S % 0.051 0.002 0.058 0.044 0.06 0.05 0.05 0.05 0.05 0.06 0.06 0.05Sb ppm 0.67 0.048 0.816 0.525 0.69 0.72 0.73 0.64 0.65 0.69 0.7 0.7Sc ppm 13.7 1.05 16.882 10.554 14.7 13.3 13.8 13.2 13.1 13.6 14.1 14.7Sn ppm 4.06 0.196 4.651 3.473 3.8 3.9 4 3.9 3.8 3.9 4 4Sr ppm 48.5 1.99 54.428 42.506 49.6 46.5 47.9 47.2 46.5 47.8 48.7 50.9Ta ppm 1.60 0.134 2.000 1.194 1.67 1.65 1.63 1.73 1.68 1.75 1.71 1.73Th ppm 15.8 0.97 18.726 12.899 16.2 17.5 16 16.45 16.85 17.15 16.95 17.5B.2 4-Acid Certified Reference Materials199ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Certified Standard Certified Certified Sample Sample Sample Sample Sample Sample Sample SampleElement Unit Value Deviation (SD) Value + 3SD Value - 3SD Q515516a Q515551a Q515583a Q515599a Q515666a Q515667a Q515683a Q515700aB.2 4-Acid Certified Reference MaterialsTi % 0.977 0.059 1.155 0.799 1.045 1.015 1.01 1.015 1.035 1.075 1.07 1.065Tl ppm 0.35 0.030 0.440 0.262 0.33 0.34 0.33 0.36 0.35 0.36 0.34 0.34U ppm 2.94 0.088 3.204 2.676 2.7 3 2.9 3 2.9 3 3.1 3.2V ppm 157 8 182.261 132.325 162 158 158 157 157 160 164 164W ppm 2.10 0.201 2.700 1.493 2.3 2.3 2.4 2.4 2.3 2.5 2.3 2.4Y ppm 12.3 2.1 18.451 6.086 12.8 11.4 12.3 12.2 12.4 14.4 13.6 14.9Zn ppm 44.4 2.60 52.235 36.659 44 45 45 45 45 46 45 44Median 30% ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61(CRM not of Median Median Median Sample Sample Sample Sample Sample Sample Sample SampleElement Unit available) (SD n/a) +30% -30% Q515516a Q515551a Q515583a Q515599a Q515666a Q515667a Q515683a Q515700aAg ppm 0.04 0.012 0.052 0.028 0.04 0.04 0.04 0.04 0.04 0.03 0.04 0.03As ppm 10.2 3.06 13.26 7.14 10.7 10.3 10.1 9.7 9.4 9.8 10.8 10.6Cd ppm 0.03 0.009 0.039 0.021 0.04 0.04 0.03 0.03 0.03 0.03 0.05 0.03Ge ppm 0.125 0.0375 0.1625 0.0875 0.16 0.12 0.17 0.13 0.14 0.12 0.1 0.12In ppm 0.091 0.0273 0.1183 0.0637 0.089 0.091 0.089 0.091 0.092 0.091 0.092 0.089Re ppm 0.001 0.0003 0.0013 0.0007 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001Se ppm 3.5 1.05 4.55 2.45 4 3 4 4 3 4 3 3Te ppm 0.0375 0.01125 0.04875 0.02625 0.025 0.025 0.07 0.025 0.05 0.025 0.05 0.07Zr ppm 178.25 53.475 231.725 124.775 178 175.5 181 188 178.5 180.5 167 172200ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Q515582 Q515583 MPD Q515588 Q515589 MPD Q515592 Q515593 MPDElement Unit Original Duplicate (%) Original Duplicate (%) Original Duplicate (%)Ag ppm 0.05 0.05 0.05 0.00 0.05 0.05 0.05 0.00 0.1 0.06 0.08 50.00Al % 5.99 5.92 5.96 1.18 6.01 5.9 5.955 1.85 6.35 6.37 6.36 0.31As ppm 5.4 5.9 5.65 8.85 7.4 7 7.2 5.56 8.1 7 7.55 14.57Ba ppm 390 390 390.00 0.00 380 390 385 2.60 410 440 425.00 7.06Be ppm 1.69 1.33 1.51 23.84 1.41 1.33 1.37 5.84 1.25 1.43 1.34 13.43Bi ppm 0.12 0.13 0.13 8.00 0.18 0.17 0.175 5.71 0.25 0.2 0.23 22.22Ca % 1.32 1.3 1.31 1.53 1.26 1.29 1.275 2.35 1.2 1.28 1.24 6.45Cd ppm 0.08 0.06 0.07 28.57 0.07 0.08 0.075 13.33 0.07 0.08 0.08 13.33Ce ppm 51.6 52 51.80 0.77 53.3 52.2 52.75 2.09 46.9 57.4 52.15 20.13Co ppm 4 4.3 4.15 7.23 4.6 3.7 4.15 21.69 5.5 5.9 5.70 7.02Cr ppm 28 28 28.00 0.00 29 29 29 0.00 35 37 36.00 5.56Cs ppm 2.05 2.05 2.05 0.00 2.19 2.16 2.175 1.38 2.53 2.65 2.59 4.63Cu ppm 12.8 12.6 12.70 1.57 14.4 9.7 12.05 39.00 15.7 13.3 14.50 16.55Fe % 1.08 1.11 1.10 2.74 1.14 1.11 1.125 2.67 1.54 1.44 1.49 6.71Ga ppm 12.25 12 12.13 2.06 12.55 12.05 12.3 4.07 13 13.35 13.18 2.66Ge ppm 0.2 0.21 0.21 4.88 0.2 0.22 0.21 9.52 0.12 0.13 0.13 8.00Hf ppm 3.5 4 3.75 13.33 3.4 3.9 3.65 13.70 3 3.7 3.35 20.90In ppm 0.014 0.014 0.01 0.00 0.017 0.012 0.015 34.48 0.02 0.019 0.02 5.13K % 1.76 1.77 1.77 0.57 1.77 1.73 1.75 2.29 1.85 2 1.93 7.79La ppm 24.5 24.8 24.65 1.22 25.3 24.6 24.95 2.81 22.7 27.3 25.00 18.40Li ppm 24 24.1 24.05 0.42 25.8 25.9 25.85 0.39 25.3 27.1 26.20 6.87Mg % 0.37 0.37 0.37 0.00 0.38 0.37 0.375 2.67 0.44 0.48 0.46 8.70Mn ppm 198 204 201.00 2.99 192 197 194.5 2.57 217 219 218.00 0.92Mo ppm 0.45 0.46 0.46 2.20 0.49 0.48 0.485 2.06 1.16 0.57 0.87 68.21Na % 2.3 2.24 2.27 2.64 2.25 2.23 2.24 0.89 2.21 2.27 2.24 2.68Nb ppm 3.9 3.8 3.85 2.60 4.1 3.7 3.9 10.26 3.6 4.3 3.95 17.72Ni ppm 12.1 12.3 12.20 1.64 13.6 12.3 12.95 10.04 18.4 18.4 18.40 0.00P ppm 710 680 695.00 4.32 690 660 675 4.44 620 780 700.00 22.86Pb ppm 13.9 13.6 13.75 2.18 14.2 13.4 13.8 5.80 15.6 14.3 14.95 8.70Rb ppm 54.7 54.1 54.40 1.10 57.6 54.3 55.95 5.90 57.3 62.7 60.00 9.00Re ppm 0.001 0.001 0.00 0.00 0.001 0.001 0.001 0.00 0.001 0.001 0.00 0.00S % 0.005 0.01 0.01 66.67 0.005 0.01 0.008 66.67 0.01 0.01 0.01 0.00Sb ppm 0.11 0.11 0.11 0.00 0.11 0.11 0.11 0.00 0.1 0.1 0.10 0.00B.3 4-Acid Duplicates - MPD (%)Mean Mean Mean201ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Q515582 Q515583 MPD Q515588 Q515589 MPD Q515592 Q515593 MPDElement Unit Original Duplicate (%) Original Duplicate (%) Original Duplicate (%)B.3 4-Acid Duplicates - MPD (%)Mean Mean MeanSc ppm 4.5 4.6 4.55 2.20 4.8 4.6 4.7 4.26 4.6 5.3 4.95 14.14Se ppm 1 1 1.00 0.00 1 1 1 0.00 1 1 1.00 0.00Sn ppm 0.8 0.7 0.75 13.33 0.7 0.7 0.7 0.00 0.7 0.8 0.75 13.33Sr ppm 290 284 287.00 2.09 284 284 284 0.00 276 276 276.00 0.00Ta ppm 0.35 0.35 0.35 0.00 0.36 0.31 0.335 14.93 0.33 0.42 0.38 24.00Te ppm 0.025 0.025 0.03 0.00 0.025 0.025 0.025 0.00 0.025 0.025 0.03 0.00Th ppm 5.99 6.28 6.14 4.73 6.15 6.56 6.355 6.45 6.55 7.06 6.81 7.49Ti % 0.191 0.19 0.19 0.52 0.184 0.181 0.183 1.64 0.188 0.212 0.20 12.00Tl ppm 0.31 0.31 0.31 0.00 0.33 0.29 0.31 12.90 0.34 0.36 0.35 5.71U ppm 1.7 1.7 1.70 0.00 1.7 1.6 1.65 6.06 1.9 1.9 1.90 0.00V ppm 29 29 29.00 0.00 29 28 28.5 3.51 35 36 35.50 2.82W ppm 3.4 0.5 1.95 148.72 0.5 0.5 0.5 0.00 0.6 0.6 0.60 0.00Y ppm 9 8.8 8.90 2.25 8.8 8.6 8.7 2.30 8 9.7 8.85 19.21Zn ppm 19 19 19.00 0.00 20 19 19.5 5.13 26 27 26.50 3.77Zr ppm 128 152.5 140.25 17.47 129.5 150.5 140 15.00 109.5 132 120.75 18.63202Element UnitAg ppmAl %As ppmBa ppmBe ppmBi ppmCa %Cd ppmCe ppmCo ppmCr ppmCs ppmCu ppmFe %Ga ppmGe ppmHf ppmIn ppmK %La ppmLi ppmMg %Mn ppmMo ppmNa %Nb ppmNi ppmP ppmPb ppmRb ppmRe ppmS %Sb ppmME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Q515654 Q515655 MPD Q515678 Q515679 MPD Q515695 Q515696 MPDOriginal Duplicate (%) Original Duplicate (%) Original Duplicate (%)0.03 0.04 0.04 28.57 0.12 0.1 0.11 18.18 0.06 0.06 0.06 0.005.48 5.74 5.61 4.63 1.77 1.23 1.5 36.00 6.44 6.42 6.43 0.310.8 1.6 1.20 66.67 3.4 3.7 3.55 8.45 5.3 2.7 4.00 65.00360 370 365.00 2.74 150 90 120 50.00 500 490 495.00 2.021.24 1.17 1.21 5.81 0.43 0.38 0.405 12.35 1.69 1.54 1.62 9.290.1 0.11 0.11 9.52 0.2 0.17 0.185 16.22 0.18 0.16 0.17 11.761.08 1.18 1.13 8.85 0.38 0.26 0.32 37.50 1.21 1.29 1.25 6.400.05 0.06 0.06 18.18 0.34 0.43 0.385 23.38 0.09 0.09 0.09 0.0033.2 40.4 36.80 19.57 31.5 31.2 31.35 0.96 57 75.5 66.25 27.921.9 2.4 2.15 23.26 2.3 2 2.15 13.95 6.7 5.8 6.25 14.4018 19 18.50 5.41 19 18 18.5 5.41 55 60 57.50 8.701.47 1.7 1.59 14.51 0.61 0.36 0.485 51.55 3.06 2.66 2.86 13.993 3.9 3.45 26.09 115 124.5 119.8 7.93 19.1 14.9 17.00 24.710.55 0.72 0.64 26.77 0.22 0.14 0.18 44.44 1.48 1.33 1.41 10.6810.75 11 10.88 2.30 3.33 2.35 2.84 34.51 13.45 13.1 13.28 2.640.12 0.11 0.12 8.70 0.12 0.1 0.11 18.18 0.12 0.15 0.14 22.222.5 2.6 2.55 3.92 1.1 0.6 0.85 58.82 3.6 4.1 3.85 12.990.01 0.012 0.01 18.18 0.012 0.009 0.011 28.57 0.018 0.021 0.02 15.381.62 1.67 1.65 3.04 0.42 0.21 0.315 66.67 1.93 1.89 1.91 2.0916.4 19.8 18.10 18.78 15.4 15.8 15.6 2.56 27.7 36.8 32.25 28.2213.7 17.1 15.40 22.08 2.3 1.4 1.85 48.65 25.9 23.5 24.70 9.720.23 0.29 0.26 23.08 0.06 0.04 0.05 40.00 0.73 0.71 0.72 2.78122 152 137.00 21.90 43 30 36.5 35.62 214 226 220.00 5.450.14 0.2 0.17 35.29 1.33 1.09 1.21 19.83 0.41 0.22 0.32 60.322.2 2.29 2.25 4.01 0.53 0.27 0.4 65.00 2.17 2.27 2.22 4.502.5 2.5 2.50 0.00 1.4 1.1 1.25 24.00 8.9 10.1 9.50 12.636.3 7.8 7.05 21.28 12.5 11.7 12.1 6.61 35.3 33.2 34.25 6.13300 520 410.00 53.66 670 710 690 5.80 690 710 700.00 2.8612 12.5 12.25 4.08 5.4 3.2 4.3 51.16 13.6 14.3 13.95 5.0247.3 48.7 48.00 2.92 13.7 7.1 10.4 63.46 63.5 62.6 63.05 1.430.001 0.001 0.00 0.00 0.002 0.002 0.002 0.00 0.001 0.001 0.00 0.000.01 0.01 0.01 0.00 0.5 0.62 0.56 21.43 0.01 0.01 0.01 0.000.06 0.06 0.06 0.00 0.13 0.09 0.11 36.36 0.11 0.13 0.12 16.67Mean MeanMeanB.3 4-Acid Duplicates - MPD (%)203Element UnitSc ppmSe ppmSn ppmSr ppmTa ppmTe ppmTh ppmTi %Tl ppmU ppmV ppmW ppmY ppmZn ppmZr ppmME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Q515654 Q515655 MPD Q515678 Q515679 MPD Q515695 Q515696 MPDOriginal Duplicate (%) Original Duplicate (%) Original Duplicate (%)Mean MeanMeanB.3 4-Acid Duplicates - MPD (%)2.7 3 2.85 10.53 2.9 2.8 2.85 3.51 5.8 5.8 5.80 0.001 1 1.00 0.00 1 1 1 0.00 1 1 1.00 0.000.5 0.5 0.50 0.00 0.3 0.2 0.25 40.00 0.8 0.8 0.80 0.00266 278 272.00 4.41 77.5 44.1 60.8 54.93 280 294 287.00 4.880.22 0.22 0.22 0.00 0.11 0.08 0.095 31.58 0.65 0.72 0.69 10.220.025 0.001 0.01 184.62 0.025 0.025 0.025 0.00 0.025 0.025 0.03 0.004.02 5.38 4.70 28.94 5.23 3.93 4.58 28.38 6.93 9.07 8.00 26.750.132 0.138 0.14 4.44 0.058 0.042 0.05 32.00 0.212 0.229 0.22 7.710.28 0.29 0.29 3.51 0.11 0.08 0.095 31.58 0.37 0.37 0.37 0.001.1 1.4 1.25 24.00 4.2 4 4.1 4.88 2.3 2.7 2.50 16.0016 19 17.50 17.14 8 10 9 22.22 41 39 40.00 5.000.4 0.2 0.30 66.67 0.4 0.4 0.4 0.00 0.6 0.7 0.65 15.384.7 6.3 5.50 29.09 5.8 6.3 6.05 8.26 9.6 10.9 10.25 12.6810 13 11.50 26.09 6 4 5 40.00 31 29 30.00 6.6792.7 95.6 94.15 3.08 38.8 17.9 28.35 73.72 122.5 141 131.75 14.04204ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LCertified Standard Certified Certified Sample Sample Sample Sample Sample Sample Sample Sample Element Unit Value Deviation (SD) Value + 3SD Value - 3SD Q515516a Q515551a Q515583a Q515599a Q515666a Q515667a Q515683a Q515700aAl % 5.85 0.78 8.20 3.50 5.19 5.4 5.42 5.57 5.58 5.67 5.75 5.49Ba ppm 56 7 76.01 35.76 54.5 56.5 56 56.6 56.2 57.4 57.4 53.5Bi ppm 0.30 0.025 0.38 0.23 0.279 0.272 0.28 0.258 0.271 0.284 0.273 0.261Ca % 0.150 0.014 0.19 0.11 0.14 0.15 0.15 0.15 0.14 0.15 0.15 0.14Ce ppm 33.1 5.3 49.08 17.02 28.9 29.5 31.6 30.5 30.6 31.3 30.8 30.3Co ppm 5.72 0.69 7.79 3.64 5.14 5.36 5.42 5.33 5.39 5.77 5.57 5.27Cr ppm 73 5.2 88.31 57.34 64.2 67.6 72.1 69.8 68.2 72 69.7 68.3Cs ppm 4.45 0.86 7.03 1.87 3.65 3.51 3.51 3.38 3.64 3.7 3.71 3.57Cu ppm 24.9 2.8 33.17 16.58 22.1 23.3 23.5 22.7 22.7 24.5 23.6 22.2Fe % 5.99 0.459 7.37 4.61 5.52 5.71 5.77 5.81 5.73 5.84 5.82 5.65Ga ppm 20.6 2.6 28.51 12.70 18.7 17.95 19.7 19.9 18.8 19.65 19.6 17.55K % 0.131 0.009 0.16 0.10 0.12 0.12 0.12 0.13 0.13 0.13 0.13 0.12Mn ppm 424.739 32.247 521.48 328.00 386 400 399 399 399 401 399 396Ni ppm 26.9 3.4 37.08 16.64 22.9 24.6 25.9 25.8 26.7 28.7 28.1 25.6P % 0.037 0.004 0.05 0.03 0.036 0.038 0.037 0.037 0.037 0.037 0.037 0.035Pb ppm 21.0 2.01 27.07 15.03 19.25 18.75 21.2 20.2 19.5 19.9 19.9 19.05Sc ppm 8.64 0.799 11.04 6.25 9.1 8.72 9.45 9.69 8.72 8.91 8.79 8.51Sn ppm 2.70 0.27 3.52 1.88 2.58 2.53 2.52 2.5 2.53 2.62 2.54 2.44Sr ppm 17.3 1.18 20.87 13.81 17.5 16.8 17.95 17.7 17.1 18.1 18.05 16.45Th ppm 10.7 0.97 13.63 7.82 9.85 9.34 9.88 9.22 9.54 9.97 9.76 9.14Tl ppm 0.20 0.02 0.27 0.14 0.186 0.181 0.186 0.173 0.189 0.194 0.198 0.182U ppm 1.49 0.18 2.03 0.94 1.465 1.445 1.555 1.455 1.44 1.505 1.48 1.465V ppm 117 11 149.63 84.44 118 121.5 121.5 119.5 123 126.5 124 118.5Y ppm 4.56 0.74 6.77 2.35 4.32 4.25 4.27 4.17 4.14 4.46 4.32 4.1Zn ppm 30.1 3.4 40.26 19.87 26.8 27.2 31.5 30.9 29 30.4 30.6 29.2B.4 Aqua Regia Certified Reference Materials205Median 30% ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L(CRM not of Median Median Median Sample Sample Sample Sample Sample Sample Sample Sample Element Unit available) (SD n/a) +30% -30% Q515516a Q515551a Q515583a Q515599a Q515666a Q515667a Q515683a Q515700aAg ppm 0.03 0.01 0.04 0.02 0.026 0.028 0.027 0.033 0.03 0.028 0.043 0.028Au ppm 0.0006 0.0002 0.00078 0.00042 0.0006 0.0006 0.0004 0.0009 0.0007 0.0005 0.0006 0.0007As ppm 2.76 0.83 3.59 1.93 2.83 2.8 2.95 2.71 2.7 2.72 2.46 2.85B ppm 5.00 1.50 6.50 3.50 5 5 5 5 5 5 5 5Be ppm 0.59 0.18 0.77 0.41 0.64 0.59 0.64 0.61 0.57 0.58 0.59 0.57Cd ppm 0.03 0.01 0.04 0.02 0.037 0.032 0.036 0.031 0.031 0.03 0.038 0.029Ge ppm 0.06 0.02 0.08 0.04 0.06 0.047 0.066 0.052 0.069 0.066 0.069 0.052Hf ppm 0.33 0.10 0.43 0.23 0.304 0.327 0.343 0.334 0.327 0.334 0.316 0.364Hg ppm 0.06 0.02 0.08 0.04 0.059 0.054 0.068 0.058 0.059 0.062 0.059 0.06In ppm 0.07 0.02 0.09 0.05 0.073 0.081 0.068 0.063 0.058 0.084 0.064 0.079La ppm 12.80 3.84 16.64 8.96 12.45 12.8 13 12.8 12.8 13.25 13.2 12.5Li ppm 18.55 5.57 24.12 12.99 18.6 17.5 18.5 18.5 18.3 19 19 19Mg % 0.18 0.05 0.23 0.13 0.17 0.18 0.18 0.18 0.18 0.19 0.19 0.18Mo ppm 1.39 0.42 1.81 0.97 1.53 1.38 1.41 1.3 1.35 1.4 1.34 1.5Na % 0.03 0.01 0.04 0.02 0.03 0.033 0.028 0.029 0.034 0.034 0.035 0.035Nb ppm 0.63 0.19 0.82 0.44 0.645 0.648 0.601 0.574 0.65 0.641 0.626 0.615Pd ppm 0.00 0.00 0.00 0.00 0.001 0.001 0.001 0.001 0.0005 0.001 0.001 0.001Pt ppm 0.00 0.00 0.00 0.00 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001Rb ppm 28.40 8.52 36.92 19.88 28.5 27.8 27.2 27.4 28.8 30.7 30.8 28.3Re ppm 0.0005 0.00015 0.00065 0.00035 0.001 0.001 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005S % 0.05 0.02 0.07 0.04 0.04 0.05 0.04 0.04 0.06 0.06 0.05 0.05Sb ppm 0.18 0.05 0.23 0.13 0.22 0.168 0.179 0.18 0.173 0.174 0.204 0.227Se ppm 0.80 0.24 1.04 0.56 0.9 0.8 0.8 0.8 0.9 0.8 0.8 0.8Ta ppm 0.00 0.00 0.00 0.00 0.0025 0.0025 0.0025 0.0025 0.0025 0.0025 0.0025 0.0025Te ppm 0.03 0.009 0.039 0.021 0.03 0.01 0.02 0.04 0.02 0.03 0.04 0.03Ti % 0.05 0.02 0.07 0.04 0.049 0.049 0.048 0.051 0.056 0.053 0.055 0.05W ppm 0.03 0.01 0.04 0.02 0.034 0.031 0.033 0.027 0.033 0.029 0.028 0.036Zr ppm 14.78 4.43 19.21 10.34 13.65 14.95 15.2 15.05 14.5 15 14.6 14.2B.4 Aqua Regia Certified Reference Materials206ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LQ515582 Q515583 MPD Q515588 Q515589 MPD Q515592 Q515593 MPDElement Unit Original Duplicate (%) Original Duplicate (%) Original Duplicate (%)Au ppm 0.0016 0.0014 0.0015 13.33 0.0007 0.0034 0.00205 131.71 0.0017 0.0012 0.00145 34.48Ag ppm 0.012 0.01 0.011 18.18 0.013 0.017 0.015 26.67 0.068 0.022 0.045 102.22Al % 0.38 0.41 0.395 7.59 0.44 0.38 0.41 14.63 0.79 0.63 0.71 22.54As ppm 4.08 5.29 4.685 25.83 6.43 5.8 6.115 10.30 8.04 6.15 7.095 26.64B ppm 5 5 5 0.00 5 5 5 0.00 5 5 5 0.00Ba ppm 26.1 26.6 26.35 1.90 28.4 26.1 27.25 8.44 34.7 38.8 36.75 11.16Be ppm 0.17 0.18 0.175 5.71 0.2 0.15 0.175 28.57 0.27 0.23 0.25 16.00Bi ppm 0.094 0.098 0.096 4.17 0.11 0.128 0.119 15.13 0.201 0.132 0.1665 41.44Ca % 0.14 0.14 0.14 0.00 0.15 0.12 0.135 22.22 0.11 0.16 0.135 37.04Cd ppm 0.021 0.021 0.021 0.00 0.022 0.019 0.0205 14.63 0.026 0.033 0.0295 23.73Ce ppm 37 35.5 36.25 4.14 38.3 32.9 35.6 15.17 34.1 41.9 38 20.53Co ppm 2.27 2.77 2.52 19.84 2.74 1.995 2.3675 31.47 4.16 4.01 4.085 3.67Cr ppm 13.9 14.25 14.075 2.49 15.05 13.95 14.5 7.59 22.7 20.8 21.75 8.74Cs ppm 0.739 0.771 0.755 4.24 0.835 0.787 0.811 5.92 1.305 1.21 1.2575 7.55Cu ppm 11.8 12.3 12.05 4.15 13.3 8.81 11.055 40.62 13.2 11.7 12.45 12.05Fe % 0.6 0.63 0.615 4.88 0.67 0.6 0.635 11.02 1.03 0.89 0.96 14.58Ga ppm 1.71 1.79 1.75 4.57 1.855 1.76 1.8075 5.26 2.99 2.51 2.75 17.45Ge ppm 0.067 0.062 0.0645 7.75 0.077 0.072 0.0745 6.71 0.066 0.084 0.075 24.00Hf ppm 0.052 0.038 0.045 31.11 0.041 0.036 0.0385 12.99 0.034 0.057 0.0455 50.55Hg ppm 0.002 0.002 0.002 0.00 0.002 0.002 0.002 0.00 0.01 0.002 0.006 133.33In ppm 0.0025 0.0025 0.0025 0.00 0.0025 0.0025 0.0025 0.00 0.008 0.0025 0.00525 104.76K % 0.1 0.1 0.1 0.00 0.11 0.09 0.1 20.00 0.14 0.16 0.15 13.33La ppm 17.3 16.65 16.975 3.83 17.75 15.5 16.625 13.53 15.95 19.45 17.7 19.77Li ppm 11.3 11.9 11.6 5.17 12.2 10.7 11.45 13.10 17 16.6 16.8 2.38Mg % 0.18 0.18 0.18 0.00 0.19 0.16 0.175 17.14 0.26 0.27 0.265 3.77Mn ppm 53.9 57.6 55.75 6.64 60.2 49.1 54.65 20.31 70.8 78.2 74.5 9.93Mo ppm 0.29 0.36 0.325 21.54 0.35 0.34 0.345 2.90 0.55 0.35 0.45 44.44Na % 0.003 0.003 0.003 0.00 0.002 0.002 0.002 0.00 0.004 0.003 0.0035 28.57Nb ppm 0.251 0.346 0.2985 31.83 0.428 0.448 0.438 4.57 0.765 0.657 0.711 15.19Ni ppm 7.6 8.21 7.905 7.72 8.76 7.66 8.21 13.40 12.6 12.85 12.725 1.96P % 0.052 0.053 0.0525 1.90 0.057 0.049 0.053 15.09 0.048 0.063 0.0555 27.03Pb ppm 2.12 2.35 2.235 10.29 2.46 2.12 2.29 14.85 3.27 3.05 3.16 6.96Pd ppm 0.0005 0.001 0.00075 66.67 0.001 0.001 0.001 0.00 0.0005 0.0005 0.0005 0.00B.5 Aqua Regia Duplicates - MPD (%)Mean Mean Mean207ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LQ515582 Q515583 MPD Q515588 Q515589 MPD Q515592 Q515593 MPDElement Unit Original Duplicate (%) Original Duplicate (%) Original Duplicate (%)B.5 Aqua Regia Duplicates - MPD (%)Mean Mean MeanPt ppm 0.001 0.001 0.001 0.00 0.001 0.001 0.001 0.00 0.001 0.001 0.001 0.00Rb ppm 5.9 6.3 6.1 6.56 6.63 5.97 6.3 10.48 8.78 9.82 9.3 11.18Re ppm 0.0005 0.0005 0.0005 0.00 0.0005 0.0005 0.0005 0.00 0.0005 0.0005 0.0005 0.00S % 0.005 0.005 0.005 0.00 0.005 0.005 0.005 0.00 0.005 0.005 0.005 0.00Sb ppm 0.013 0.01 0.0115 26.09 0.009 0.008 0.0085 11.76 0.009 0.015 0.012 50.00Sc ppm 1.24 1.23 1.235 0.81 1.295 1.165 1.23 10.57 1.86 1.775 1.8175 4.68Se ppm 0.2 0.2 0.2 0.00 0.3 0.2 0.25 40.00 0.3 0.3 0.3 0.00Sn ppm 0.14 0.16 0.15 13.33 0.17 0.14 0.155 19.35 1.03 0.21 0.62 132.26Sr ppm 4.59 4.71 4.65 2.58 4.54 3.78 4.16 18.27 3.76 4.51 4.135 18.14Ta ppm 0.0025 0.0025 0.0025 0.00 0.0025 0.0025 0.0025 0.00 0.007 0.0025 0.00475 94.74Te ppm 0.01 0.02 0.015 66.67 0.005 0.005 0.005 0.00 0.01 0.01 0.01 0.00Th ppm 4.71 4.15 4.43 12.64 4.77 3.94 4.355 19.06 4.13 5.21 4.67 23.13Ti % 0.029 0.029 0.029 0.00 0.031 0.028 0.0295 10.17 0.045 0.042 0.0435 6.90Tl ppm 0.057 0.06 0.0585 5.13 0.062 0.048 0.055 25.45 0.071 0.079 0.075 10.67U ppm 1.11 1.015 1.0625 8.94 1.175 0.942 1.0585 22.01 1.205 1.295 1.25 7.20V ppm 12.6 13.1 12.85 3.89 13.4 12.8 13.1 4.58 20.8 17.6 19.2 16.67W ppm 0.156 0.435 0.2955 94.42 0.202 0.198 0.2 2.00 0.399 0.276 0.3375 36.44Y ppm 4.32 4.21 4.265 2.58 4.72 3.97 4.345 17.26 3.92 4.94 4.43 23.02Zn ppm 11.6 11.9 11.75 2.55 12 11.4 11.7 5.13 17.1 18.1 17.6 5.68Zr ppm 2.7 1.89 2.295 35.29 2.14 1.67 1.905 24.67 1.79 2.51 2.15 33.49208Element UnitAu ppmAg ppmAl %As ppmB ppmBa ppmBe ppmBi ppmCa %Cd ppmCe ppmCo ppmCr ppmCs ppmCu ppmFe %Ga ppmGe ppmHf ppmHg ppmIn ppmK %La ppmLi ppmMg %Mn ppmMo ppmNa %Nb ppmNi ppmP %Pb ppmPd ppmME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LQ515664 Q515665 MPD Q515678 Q515679 MPD Q515695 Q515696 MPDOriginal Duplicate (%) Original Duplicate (%) Original Duplicate (%)0.0099 0.002 0.00595 132.77 0.0014 0.0015 0.00145 6.90 0.0018 0.0012 0.0015 40.000.011 0.032 0.0215 97.67 0.103 0.092 0.0975 11.28 0.038 0.025 0.0315 41.270.44 0.65 0.545 38.53 0.42 0.53 0.475 23.16 0.72 0.6 0.66 18.187.35 1.71 4.53 124.50 2.34 2.61 2.475 10.91 4.56 2.28 3.42 66.675 5 5 0.00 5 5 5 0.00 5 5 5 0.0024.2 36.2 30.2 39.74 48.7 42 45.35 14.77 74.8 74.6 74.7 0.270.17 0.29 0.23 52.17 0.23 0.24 0.235 4.26 0.28 0.19 0.235 38.300.168 0.161 0.1645 4.26 0.154 0.138 0.146 10.96 0.139 0.122 0.1305 13.030.14 0.15 0.145 6.90 0.14 0.13 0.135 7.41 0.14 0.15 0.145 6.900.014 0.029 0.0215 69.77 0.295 0.373 0.334 23.35 0.043 0.047 0.045 8.8932.8 40.6 36.7 21.25 20.2 26.9 23.55 28.45 40.9 44.2 42.55 7.762.06 2.95 2.505 35.53 2.07 1.92 1.995 7.52 5.06 3.88 4.47 26.4013.7 22.8 18.25 49.86 12.45 11.8 12.125 5.36 25.6 22.1 23.85 14.680.838 1.385 1.1115 49.21 0.217 0.175 0.196 21.43 1.445 1.165 1.305 21.468.36 16.8 12.58 67.09 106 119.5 112.75 11.97 17.65 12.35 15 35.330.66 0.65 0.655 1.53 0.122 0.09 0.106 30.19 0.91 0.74 0.825 20.611.79 2.7 2.245 40.53 0.953 1.13 1.0415 16.99 2.71 2.23 2.47 19.430.057 0.067 0.062 16.13 0.036 0.04 0.038 10.53 0.067 0.069 0.068 2.940.036 0.017 0.0265 71.70 0.004 0.009 0.0065 76.92 0.015 0.053 0.034 111.760.002 0.014 0.008 150.00 0.065 0.072 0.0685 10.22 0.002 0.004 0.003 66.670.0025 0.0025 0.0025 0.00 0.012 0.0025 0.00725 131.03 0.005 0.007 0.006 33.330.07 0.08 0.075 13.33 0.01 0.01 0.01 0.00 0.11 0.1 0.105 9.5215.6 19.35 17.475 21.46 9.36 13.05 11.205 32.93 19.7 20.5 20.1 3.9810.5 16.6 13.55 45.02 0.4 0.3 0.35 28.57 17 14.1 15.55 18.650.17 0.26 0.215 41.86 0.02 0.02 0.02 0.00 0.5 0.45 0.475 10.5345.8 60.6 53.2 27.82 4.9 4.4 4.65 10.75 74.2 62.5 68.35 17.120.46 0.14 0.3 106.67 0.97 0.95 0.96 2.08 0.38 0.12 0.25 104.000.007 0.011 0.009 44.44 0.007 0.006 0.0065 15.38 0.013 0.012 0.0125 8.000.573 0.731 0.652 24.23 0.45 0.456 0.453 1.32 1.76 1.605 1.6825 9.218.09 11.4 9.745 33.97 10.4 10.75 10.575 3.31 29.9 26.6 28.25 11.680.053 0.049 0.051 7.84 0.045 0.05 0.0475 10.53 0.047 0.051 0.049 8.162.16 2.71 2.435 22.59 1.505 1.59 1.5475 5.49 3.03 3.17 3.1 4.520.001 0.0005 0.00075 66.67 0.002 0.002 0.002 0.00 0.0005 0.0005 0.0005 0.00MeanMean MeanB.5 Aqua Regia Duplicates - MPD (%)209Element UnitPt ppmRb ppmRe ppmS %Sb ppmSc ppmSe ppmSn ppmSr ppmTa ppmTe ppmTh ppmTi %Tl ppmU ppmV ppmW ppmY ppmZn ppmZr ppmME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LQ515664 Q515665 MPD Q515678 Q515679 MPD Q515695 Q515696 MPDOriginal Duplicate (%) Original Duplicate (%) Original Duplicate (%)MeanMean MeanB.5 Aqua Regia Duplicates - MPD (%)0.001 0.001 0.001 0.00 0.001 0.001 0.001 0.00 0.001 0.001 0.001 0.004.98 7.81 6.395 44.25 0.609 0.612 0.6105 0.49 10.95 10.3 10.625 6.120.0005 0.0005 0.0005 0.00 0.003 0.002 0.0025 40.00 0.0005 0.0005 0.0005 0.000.02 0.03 0.025 40.00 0.42 0.54 0.48 25.00 0.02 0.02 0.02 0.000.0025 0.011 0.00675 125.93 0.031 0.043 0.037 32.43 0.05 0.04 0.045 22.221.135 1.945 1.54 52.60 0.497 0.638 0.5675 24.85 1.8 1.74 1.77 3.390.2 0.3 0.25 40.00 0.9 0.9 0.9 0.00 0.4 0.3 0.35 28.570.16 0.29 0.225 57.78 0.16 0.18 0.17 11.76 0.26 0.21 0.235 21.284.79 5.71 5.25 17.52 15.65 13.95 14.8 11.49 10.55 7.62 9.085 32.250.0025 0.0025 0.0025 0.00 0.0025 0.006 0.00425 82.35 0.0025 0.0025 0.0025 0.000.005 0.01 0.0075 66.67 0.005 0.01 0.0075 66.67 0.02 0.01 0.015 66.673.88 4.8 4.34 21.20 0.122 0.17 0.146 32.88 3.17 4.92 4.045 43.260.029 0.043 0.036 38.89 0.016 0.017 0.0165 6.06 0.04 0.039 0.0395 2.530.052 0.087 0.0695 50.36 0.032 0.03 0.031 6.45 0.092 0.094 0.093 2.150.922 1.21 1.066 27.02 3.35 3.5 3.425 4.38 1.395 1.32 1.3575 5.5218.3 16.4 17.35 10.95 5.3 7.6 6.45 35.66 19.7 18 18.85 9.020.155 0.193 0.174 21.84 0.113 0.148 0.1305 26.82 0.112 0.071 0.0915 44.814.35 4.73 4.54 8.37 4.15 5.67 4.91 30.96 4.48 4.56 4.52 1.779.7 17 13.35 54.68 3.9 3.3 3.6 16.67 23.8 19.6 21.7 19.351.57 0.86 1.215 58.44 0.34 0.49 0.415 36.14 0.56 2.15 1.355 117.34210ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Q515582 Q515583 MPD Q515588 Q515589 MPD Q515592 Q515593 MPDElement Unit Original Duplicate (%) Original Duplicate (%) Original Duplicate (%)Ag ppm 0.001 0.001 0.00100 0.00 0.001 0.001 0.00100 0.00 0.001 0.002 0.00150 66.67Al ppm 3 2 2.50000 40.00 4 7 5.50000 54.55 2 4 3.00000 66.67As ppm 0.02 0.005 0.01250 120.00 0.005 0.02 0.01250 120.00 0.005 0.005 0.00500 0.00Au ppm 0.0005 0.0005 0.00050 0.00 0.0005 0.0005 0.00050 0.00 0.0005 0.0005 0.00050 0.00B ppm 0.1 0.1 0.10000 0.00 0.1 0.1 0.10000 0.00 0.1 0.1 0.10000 0.00Ba ppm 0.005 0.03 0.01750 142.86 0.05 0.13 0.09000 88.89 0.11 0.11 0.11000 0.00Be ppm 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00Bi ppm 0.0015 0.0015 0.00150 0.00 0.0015 0.0015 0.00150 0.00 0.0015 0.0015 0.00150 0.00Br ppm 0.5 0.5 0.50000 0.00 0.5 0.5 0.50000 0.00 0.5 0.5 0.50000 0.00Ca ppm 10 10 10.00000 0.00 10 0.5 5.25000 180.95 10 10 10.00000 0.00Cd ppm 0.0005 0.0005 0.00050 0.00 0.0005 0.001 0.00075 66.67 0.0005 0.0005 0.00050 0.00Ce ppm 0.0179 0.0164 0.01715 8.75 0.0187 0.008 0.01335 80.15 0.0035 0.005 0.00425 35.29Co ppm 0.004 0.01 0.00700 85.71 0.024 0.007 0.01550 109.68 0.027 0.017 0.02200 45.45Cr ppm 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00Cs ppm 0.0011 0.0008 0.00095 31.58 0.001 0.0018 0.00140 57.14 0.0022 0.0032 0.00270 37.04Cu ppm 0.05 0.025 0.03750 66.67 0.05 0.05 0.05000 0.00 0.025 0.025 0.02500 0.00Dy ppm 0.0014 0.0007 0.00105 66.67 0.0007 0.0006 0.00065 15.38 0.00025 0.00025 0.00025 0.00Er ppm 0.0009 0.00025 0.00058 113.04 0.00025 0.00025 0.00025 0.00 0.00025 0.00025 0.00025 0.00Eu ppm 0.00025 0.00025 0.00025 0.00 0.0005 0.00025 0.00038 66.67 0.00025 0.00025 0.00025 0.00Fe ppm 3 2 2.50000 40.00 3 11 7.00000 114.29 2 2 2.00000 0.00Ga ppm 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00Gd ppm 0.0058 0.0008 0.00330 151.52 0.0008 0.0011 0.00095 31.58 0.00025 0.0007 0.00048 94.74Ge ppm 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00Hf ppm 0.00025 0.00025 0.00025 0.00 0.00025 0.00025 0.00025 0.00 0.00025 0.00025 0.00025 0.00Hg ppm 0.005 0.005 0.00500 0.00 0.01 0.005 0.00750 66.67 0.005 0.01 0.00750 66.67Ho ppm 0.0003 0.0002 0.00025 40.00 0.0001 0.0002 0.00015 66.67 0.0001 0.0002 0.00015 66.67I ppm 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00 0.1 0.025 0.06250 120.00In ppm 0.0005 0.0005 0.00050 0.00 0.0005 0.0005 0.00050 0.00 0.0005 0.0005 0.00050 0.00K ppm 8 2.5 5.25000 104.76 5 6 5.50000 18.18 6 6 6.00000 0.00La ppm 0.0088 0.0082 0.00850 7.06 0.0114 0.0038 0.00760 100.00 0.0013 0.0023 0.00180 55.56Li ppm 0.04 0.03 0.03500 28.57 0.05 0.06 0.05500 18.18 0.06 0.05 0.05500 18.18Lu ppm 0.0001 0.0001 0.00010 0.00 0.00005 0.0001 0.00008 66.67 0.00005 0.00005 0.00005 0.00Mg ppm 2.2 1.8 2.00000 20.00 1.9 1.5 1.70000 23.53 1.8 0.9 1.35000 66.67B.6 De-Ionized Water (Rerun) Duplicates - MPD (%)Mean Mean Mean211ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Q515582 Q515583 MPD Q515588 Q515589 MPD Q515592 Q515593 MPDElement Unit Original Duplicate (%) Original Duplicate (%) Original Duplicate (%)B.6 De-Ionized Water (Rerun) Duplicates - MPD (%)Mean Mean MeanMn ppm 0.08 0.18 0.13000 76.92 0.41 0.07 0.24000 141.67 0.39 0.55 0.47000 34.04Mo ppm 0.008 0.005 0.00650 46.15 0.004 0.004 0.00400 0.00 0.0005 0.002 0.00125 120.00Na ppm 2.5 2.5 2.50000 0.00 2.5 2.5 2.50000 0.00 2.5 2.5 2.50000 0.00Nb ppm 0.00025 0.00025 0.00025 0.00 0.00025 0.00025 0.00025 0.00 0.00025 0.00025 0.00025 0.00Nd ppm 0.0168 0.0088 0.01280 62.50 0.0104 0.0059 0.00815 55.21 0.002 0.0026 0.00230 26.09Ni ppm 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00 0.05 0.025 0.03750 66.67P ppm 0.5 0.5 0.50000 0.00 0.5 1 0.75000 66.67 0.5 0.5 0.50000 0.00Pb ppm 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00Pr ppm 0.0031 0.0025 0.00280 21.43 0.0027 0.0012 0.00195 76.92 0.0004 0.0007 0.00055 54.55Rb ppm 0.025 0.042 0.03350 50.75 0.043 0.055 0.04900 24.49 0.06 0.065 0.06250 8.00Re ppm 0.0001 0.0001 0.00010 0.00 0.0001 0.0001 0.00010 0.00 0.0001 0.0001 0.00010 0.00Sb ppm 0.0009 0.0005 0.00070 57.14 0.00025 0.00025 0.00025 0.00 0.00025 0.00025 0.00025 0.00Se ppm 0.01 0.01 0.01000 0.00 0.01 0.01 0.01000 0.00 0.02 0.01 0.01500 66.67Sm ppm 0.0035 0.0015 0.00250 80.00 0.0017 0.0007 0.00120 83.33 0.00025 0.0007 0.00048 94.74Sn ppm 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00Sr ppm 0.049 0.063 0.05600 25.00 0.079 0.049 0.06400 46.88 0.038 0.06 0.04900 44.90Ta ppm 0.001 0.001 0.00100 0.00 0.001 0.001 0.00100 0.00 0.001 0.001 0.00100 0.00Tb ppm 0.0003 0.0001 0.00020 100.00 0.0002 0.00005 0.00013 120.00 0.0001 0.0001 0.00010 0.00Te ppm 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00Th ppm 0.0018 0.0014 0.00160 25.00 0.0018 0.0011 0.00145 48.28 0.00025 0.0008 0.00053 104.76Ti ppm 0.11 0.06 0.08500 58.82 0.11 0.13 0.12000 16.67 0.025 0.09 0.05750 113.04Tl ppm 0.0005 0.0005 0.00050 0.00 0.001 0.001 0.00100 0.00 0.001 0.0005 0.00075 66.67Tm ppm 0.0002 0.0001 0.00015 66.67 0.0001 0.0001 0.00010 0.00 0.00005 0.00005 0.00005 0.00U ppm 0.0051 0.0035 0.00430 37.21 0.0045 0.0025 0.00350 57.14 0.0021 0.0016 0.00185 27.03V ppm 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00W ppm 0.0005 0.001 0.00075 66.67 0.001 0.0005 0.00075 66.67 0.0005 0.001 0.00075 66.67Y ppm 0.0069 0.0041 0.00550 50.91 0.0039 0.0031 0.00350 22.86 0.001 0.0018 0.00140 57.14Yb ppm 0.0007 0.0007 0.00070 0.00 0.0005 0.00025 0.00038 66.67 0.00025 0.00025 0.00025 0.00Zn ppm 0.025 0.025 0.02500 0.00 0.025 0.05 0.03750 66.67 0.025 0.025 0.02500 0.00Zr ppm 0.005 0.004 0.00450 22.22 0.003 0.002 0.00250 40.00 0.0005 0.001 0.00075 66.67Final pH Unity 4.9 5.1 5.00000 4.00 4.8 4.5 4.65000 6.45 4.7 4.5 4.60000 4.35C organic % 0.02 0.05 0.03500 85.71 0.13 0.15 0.14000 14.29 0.22 0.09 0.15500 83.87212Element Unit Ag ppmAl ppmAs ppmAu ppmB ppmBa ppmBe ppmBi ppmBr ppmCa ppmCd ppmCe ppmCo ppmCr ppmCs ppmCu ppmDy ppmEr ppmEu ppmFe ppmGa ppmGd ppmGe ppmHf ppmHg ppmHo ppmI ppmIn ppmK ppmLa ppmLi ppmLu ppmMg ppmME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Q515654 Q515655 MPD Q515678 Q515679 MPD Q515695 Q515696 MPDOriginal Duplicate (%) Original Duplicate (%) Original Duplicate (%)0.001 0.001 0.00100 0.00 0.001 0.001 0.00100 0.00 0.001 0.001 0.00100 0.002 1 1.50000 66.67 28 33 30.50000 16.39 15 7 11.00000 72.730.005 0.01 0.00750 66.67 0.24 0.26 0.25000 8.00 0.09 0.12 0.10500 28.570.0005 0.0005 0.00050 0.00 0.0005 0.0005 0.00050 0.00 0.0005 0.0005 0.00050 0.000.1 0.1 0.10000 0.00 0.2 0.2 0.20000 0.00 0.1 0.1 0.10000 0.000.07 0.05 0.06000 33.33 0.96 0.94 0.95000 2.11 0.36 0.36 0.36000 0.000.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.000.0015 0.0015 0.00150 0.00 0.0015 0.0015 0.00150 0.00 0.0015 0.0015 0.00150 0.000.5 0.5 0.50000 0.00 0.5 0.5 0.50000 0.00 0.5 0.5 0.50000 0.000.5 0.5 0.50000 0.00 80 90 85.00000 11.76 10 10 10.00000 0.000.0005 0.0005 0.00050 0.00 0.003 0.003 0.00300 0.00 0.0005 0.0005 0.00050 0.000.0037 0.0038 0.00375 2.67 0.0303 0.0475 0.03890 44.22 0.0508 0.036 0.04340 34.100.002 0.004 0.00300 66.67 0.08 0.086 0.08300 7.23 0.015 0.016 0.01550 6.450.025 0.025 0.02500 0.00 0.025 0.05 0.03750 66.67 0.05 0.05 0.05000 0.000.0008 0.0016 0.00120 66.67 0.0063 0.0033 0.00480 62.50 0.0038 0.0019 0.00285 66.670.025 0.025 0.02500 0.00 0.38 0.34 0.36000 11.11 0.14 0.15 0.14500 6.900.00025 0.00025 0.00025 0.00 0.0018 0.0027 0.00225 40.00 0.0023 0.0012 0.00175 62.860.00025 0.00025 0.00025 0.00 0.001 0.0014 0.00120 33.33 0.0009 0.00025 0.00058 113.040.00025 0.00025 0.00025 0.00 0.0005 0.0008 0.00065 46.15 0.0008 0.0005 0.00065 46.150.5 0.5 0.50000 0.00 5 3 4.00000 50.00 11 7 9.00000 44.440.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.000.0008 0.00025 0.00053 104.76 0.003 0.0044 0.00370 37.84 0.0043 0.0023 0.00330 60.610.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.000.00025 0.00025 0.00025 0.00 0.0009 0.0009 0.00090 0.00 0.0009 0.0006 0.00075 40.000.01 0.01 0.01000 0.00 0.01 0.005 0.00750 66.67 0.005 0.005 0.00500 0.000.0001 0.0001 0.00010 0.00 0.0003 0.0004 0.00035 28.57 0.0004 0.0001 0.00025 120.000.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.00 0.025 0.025 0.02500 0.000.0005 0.0005 0.00050 0.00 0.0005 0.0005 0.00050 0.00 0.0005 0.0005 0.00050 0.002.5 2.5 2.50000 0.00 11 12 11.50000 8.70 17 22 19.50000 25.640.002 0.0013 0.00165 42.42 0.0163 0.0267 0.02150 48.37 0.0252 0.0145 0.01985 53.900.03 0.03 0.03000 0.00 0.05 0.04 0.04500 22.22 0.06 0.08 0.07000 28.570.0001 0.00005 0.00008 66.67 0.0002 0.0003 0.00025 40.00 0.0003 0.0002 0.00025 40.001.2 1.6 1.40000 28.57 30.7 30.1 30.40000 1.97 13.5 11.5 12.50000 16.00Mean MeanMeanB.6 De-Ionized Water (Rerun) Duplicates - MPD (%)213Element Unit Mn ppmMo ppmNa ppmNb ppmNd ppmNi ppmP ppmPb ppmPr ppmRb ppmRe ppmSb ppmSe ppmSm ppmSn ppmSr ppmTa ppmTb ppmTe ppmTh ppmTi ppmTl ppmTm ppmU ppmV ppmW ppmY ppmYb ppmZn ppmZr ppmFinal pH UnityC organic %ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Q515654 Q515655 MPD Q515678 Q515679 MPD Q515695 Q515696 MPDOriginal Duplicate (%) Original Duplicate (%) Original Duplicate (%)Mean MeanMeanB.6 De-Ionized Water (Rerun) Duplicates - MPD (%)0.025 0.025 0.02500 0.00 0.2 0.21 0.20500 4.88 0.12 0.1 0.11000 18.180.001 0.0005 0.00075 66.67 0.006 0.004 0.00500 40.00 0.007 0.003 0.00500 80.002.5 2.5 2.50000 0.00 2.5 12 7.25000 131.03 2.5 2.5 2.50000 0.000.00025 0.00025 0.00025 0.00 0.0018 0.0022 0.00200 20.00 0.0127 0.006 0.00935 71.660.0019 0.0024 0.00215 23.26 0.0162 0.025 0.02060 42.72 0.0231 0.0141 0.01860 48.390.025 0.025 0.02500 0.00 0.17 0.18 0.17500 5.71 0.13 0.12 0.12500 8.002 1 1.50000 66.67 8 6 7.00000 28.57 4 2 3.00000 66.670.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.000.0006 0.001 0.00080 50.00 0.0037 0.0061 0.00490 48.98 0.006 0.0038 0.00490 44.900.014 0.018 0.01600 25.00 0.042 0.109 0.07550 88.74 0.091 0.143 0.11700 44.440.0001 0.0001 0.00010 0.00 0.0001 0.0003 0.00020 100.00 0.0001 0.0001 0.00010 0.000.00025 0.00025 0.00025 0.00 0.0028 0.00025 0.00153 167.21 0.002 0.003 0.00250 40.000.01 0.02 0.01500 66.67 0.05 0.05 0.05000 0.00 0.03 0.04 0.03500 28.570.0008 0.00025 0.00053 104.76 0.0035 0.0054 0.00445 42.70 0.0035 0.0027 0.00310 25.810.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.000.038 0.032 0.03500 17.14 0.767 0.807 0.78700 5.08 0.179 0.095 0.13700 61.310.001 0.001 0.00100 0.00 0.0005 0.0005 0.00050 0.00 0.001 0.0005 0.00075 66.670.0001 0.00005 0.00008 66.67 0.0004 0.0005 0.00045 22.22 0.0006 0.0004 0.00050 40.000.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.00 0.0025 0.0025 0.00250 0.000.0007 0.00025 0.00048 94.74 0.0148 0.009 0.01190 48.74 0.006 0.0058 0.00590 3.390.07 0.08 0.07500 13.33 0.31 0.27 0.29000 13.79 0.71 0.23 0.47000 102.130.001 0.0005 0.00075 66.67 0.003 0.003 0.00300 0.00 0.001 0.001 0.00100 0.000.00005 0.00005 0.00005 0.00 0.0002 0.0003 0.00025 40.00 0.0002 0.0001 0.00015 66.670.0006 0.0006 0.00060 0.00 0.0092 0.0102 0.00970 10.31 0.0104 0.0118 0.01110 12.610.025 0.025 0.02500 0.00 0.08 0.1 0.09000 22.22 0.11 0.35 0.23000 104.350.0005 0.0005 0.00050 0.00 0.001 0.0005 0.00075 66.67 0.001 0.001 0.00100 0.000.0015 0.0009 0.00120 50.00 0.0125 0.0177 0.01510 34.44 0.0146 0.0082 0.01140 56.140.00025 0.00025 0.00025 0.00 0.0011 0.0017 0.00140 42.86 0.0015 0.001 0.00125 40.000.025 0.025 0.02500 0.00 0.06 0.05 0.05500 18.18 0.025 0.025 0.02500 0.000.002 0.0005 0.00125 120.00 0.022 0.023 0.02250 4.44 0.028 0.068 0.04800 83.334.4 4.7 4.55000 6.59 3.8 3.6 3.70000 5.41 4.6 4.6 4.60000 0.000.45 0.46 0.45500 2.20 26.8 29.7 28.25000 10.27 0.59 0.27 0.43000 74.42214XRF Soil XRF Soil XRF Soil XRF Soil XRF Soil XRF SoilQ515513 Q515513DUP MPD Q515552 Q515552DUP MPD Q515572 Q515572DUP MPDElement Unit Original Duplicate (%) Original Duplicate (%) Original Duplicate (%)Ba ppm 384.180 386.475 386.475 0.149 27.742 39.964 39.964 9.026 344.797 357.146 357.146 0.880Ca ppm 12809.458 12796.517 12796.517 0.025 5621.845 5702.566 5702.566 0.356 11586.944 11561.352 11561.352 0.055Cr ppm 59.779 55.569 55.569 1.825 56.110 60.441 60.441 1.858 40.195 52.445 52.445 6.611Cu ppm 16.942 11.006 11.006 10.620 138.833 132.079 132.079 1.247 13.397 15.028 15.028 2.869Fe ppm 13170.082 13233.803 13233.803 0.121 8752.204 8749.667 8749.667 0.007 12215.780 12146.732 12146.732 0.142K ppm 15390.167 15483.001 15483.001 0.150 59.000 59.000 59.000 0.000 13768.758 14036.785 14036.785 0.482Mn ppm 209.986 210.351 210.351 0.043 133.174 129.902 129.902 0.622 209.412 200.383 200.383 1.102Nb ppm 4.639 3.700 3.700 5.632 0.850 1.276 1.276 10.017 3.849 4.389 4.389 3.273Ni ppm 14.067 14.149 14.149 0.145 2.550 2.550 2.550 0.000 2.550 7.321 7.321 24.168Rb ppm 50.515 51.808 51.808 0.632 1.608 2.168 2.168 7.412 47.464 49.075 49.075 0.834Sr ppm 268.018 261.918 261.918 0.576 59.954 56.430 56.430 1.514 254.712 252.030 252.030 0.265Ti ppm 2137.053 2076.218 2076.218 0.722 972.109 981.074 981.074 0.229 1903.317 1906.190 1906.190 0.038V ppm 29.994 31.387 31.387 1.135 13.065 14.284 14.284 2.229 24.503 23.911 23.911 0.612Y ppm 11.545 14.628 14.628 5.890 9.000 7.577 7.577 4.292 8.793 9.618 9.618 2.240Zn ppm 25.329 21.516 21.516 4.070 2.403 2.884 2.884 4.548 14.645 15.591 15.591 1.565Zr ppm 171.362 178.602 178.602 1.034 42.119 44.130 44.130 1.166 143.504 148.434 148.434 0.844B.7 fp-XRF Soil Mode Analytical and Field Duplicates - MPD (%)Mean Mean Mean 215Element UnitBa ppmCa ppmCr ppmCu ppmFe ppmK ppmMn ppmNb ppmNi ppmRb ppmSr ppmTi ppmV ppmY ppmZn ppmZr ppmXRF Soil XRF Soil XRF Soil XRF Soil XRF Soil XRF SoilQ515592 Q515592DUP MPD Q515663 Q515663DUP MPD Q515685 Q515685DUP MPDOriginal Duplicate (%) Original Duplicate (%) Original Duplicate (%)392.691 371.162 371.162 1.409 342.298 387.991 387.991 3.128 369.077 352.634 352.634 1.13911969.273 12037.715 12037.715 0.143 13068.176 13011.553 13011.553 0.109 12474.729 12342.219 12342.219 0.26754.653 61.769 61.769 3.056 48.810 44.683 44.683 2.207 50.123 44.335 44.335 3.06417.825 17.398 17.398 0.606 16.274 13.041 13.041 5.513 16.396 12.642 12.642 6.46415580.908 15374.008 15374.008 0.334 12332.471 12319.542 12319.542 0.026 11695.337 11631.544 11631.544 0.13715763.709 15932.033 15932.033 0.266 15441.109 15047.163 15047.163 0.646 13548.425 13536.701 13536.701 0.022214.344 215.536 215.536 0.139 207.566 206.277 206.277 0.156 206.368 201.762 201.762 0.5643.413 4.695 4.695 7.904 4.045 4.167 4.167 0.746 4.869 2.568 2.568 15.46716.564 16.590 16.590 0.040 12.375 6.418 6.418 15.850 6.702 8.297 8.297 5.31852.421 51.120 51.120 0.628 47.623 48.450 48.450 0.430 46.753 46.880 46.880 0.068243.051 240.802 240.802 0.232 273.329 277.819 277.819 0.407 258.007 244.730 244.730 1.3202187.084 2202.460 2202.460 0.175 2084.212 2032.539 2032.539 0.628 1736.107 1729.093 1729.093 0.10136.851 33.983 33.983 2.024 34.065 29.980 29.980 3.189 26.844 29.127 29.127 2.03912.432 11.241 11.241 2.517 12.065 14.525 14.525 4.624 12.060 10.802 10.802 2.74923.940 25.268 25.268 1.350 19.209 22.409 22.409 3.845 17.488 16.359 16.359 1.668154.587 154.109 154.109 0.078 179.228 179.385 179.385 0.022 155.067 148.600 148.600 1.065Mean B.7 fp-XRF Soil Mode Analytical and Field Duplicates - MPD (%)Mean Mean 216Element UnitBa ppmCa ppmCr ppmCu ppmFe ppmK ppmMn ppmNb ppmNi ppmRb ppmSr ppmTi ppmV ppmY ppmZn ppmZr ppmXRF Soil XRF Soil XRF Soil XRF Soil XRF Soil XRF SoilQ515582 Q515583 MPD Q515588 Q515589 MPD Q515592 Q515593 MPDOriginal Duplicate (%) Original Duplicate (%) Original Duplicate (%)374.195 342.994 342.994 2.175 384.398 366.801 366.801 1.171 392.691 413.934 413.934 1.31713291.682 13654.196 13654.196 0.673 13108.986 12944.721 12944.721 0.315 11969.273 12918.292 12918.292 1.90755.314 55.747 55.747 0.195 53.211 53.934 53.934 0.337 54.653 59.417 59.417 2.08818.860 18.256 18.256 0.813 23.105 11.211 11.211 17.329 17.825 23.931 23.931 7.31212407.330 13000.137 13000.137 1.167 13258.151 12969.729 12969.729 0.550 15580.908 14887.597 14887.597 1.13815270.306 15547.707 15547.707 0.450 15857.201 15447.134 15447.134 0.655 15763.709 17707.551 17707.551 2.904211.152 226.543 226.543 1.758 216.823 213.684 213.684 0.365 214.344 235.635 235.635 2.3664.454 3.676 3.676 4.785 4.656 3.432 3.432 7.568 3.413 4.496 4.496 6.8416.133 11.012 11.012 14.230 15.293 2.550 2.550 35.709 16.564 13.861 13.861 4.44249.692 49.963 49.963 0.136 51.269 48.159 48.159 1.564 52.421 57.854 57.854 2.463274.964 262.195 262.195 1.189 270.706 286.508 286.508 1.418 243.051 255.598 255.598 1.2582147.961 2154.086 2154.086 0.071 2174.601 2198.798 2198.798 0.277 2187.084 2372.809 2372.809 2.03732.735 33.783 33.783 0.788 37.324 33.280 33.280 2.864 36.851 37.139 37.139 0.19515.537 12.043 12.043 6.335 13.221 15.661 15.661 4.223 12.432 12.089 12.089 0.70118.439 22.279 22.279 4.715 18.771 17.709 17.709 1.455 23.940 28.739 28.739 4.555185.326 162.937 162.937 3.214 172.778 176.500 176.500 0.533 154.587 176.005 176.005 3.239B.7 fp-XRF Soil Mode Analytical and Field Duplicates - MPD (%)Mean Mean Mean 217Element UnitBa ppmCa ppmCr ppmCu ppmFe ppmK ppmMn ppmNb ppmNi ppmRb ppmSr ppmTi ppmV ppmY ppmZn ppmZr ppmXRF Soil XRF Soil XRF Soil XRF Soil XRF Soil XRF SoilQ515654 Q515655 MPD Q515678 Q515679 MPD Q515695 Q515696 MPDOriginal Duplicate (%) Original Duplicate (%) Original Duplicate (%)351.162 340.210 340.210 0.792 62.613 27.522 27.522 19.466 419.371 428.605 428.605 0.54511375.356 12036.012 12036.012 1.411 6010.464 5400.982 5400.982 2.670 11930.856 12629.501 12629.501 1.42248.341 43.737 43.737 2.500 51.013 60.485 60.485 4.247 97.769 100.391 100.391 0.6627.039 11.119 11.119 11.236 214.417 236.610 236.610 2.460 20.327 17.738 17.738 3.4018869.681 9789.190 9789.190 2.464 7879.864 7267.207 7267.207 2.022 15391.083 14339.288 14339.288 1.76913355.328 12539.020 12539.020 1.576 1050.954 96.165 96.165 41.617 16667.391 16195.984 16195.984 0.717162.023 170.977 170.977 1.345 117.477 121.593 121.593 0.861 229.204 247.333 247.333 1.9022.406 2.442 2.442 0.377 1.895 1.567 1.567 4.735 8.419 8.273 8.273 0.4382.550 2.550 2.550 0.000 2.550 2.550 2.550 0.000 16.995 38.504 38.504 19.37844.601 43.799 43.799 0.454 10.344 5.516 5.516 15.223 59.104 56.421 56.421 1.161257.832 268.701 268.701 1.032 136.852 92.239 92.239 9.737 260.407 267.879 267.879 0.7071688.435 1726.523 1726.523 0.558 1236.039 1122.471 1122.471 2.408 2541.704 2556.892 2556.892 0.14919.842 20.170 20.170 0.410 10.577 9.839 9.839 1.807 46.359 49.604 49.604 1.69110.317 10.214 10.214 0.249 9.402 15.547 15.547 12.316 13.223 14.346 14.346 2.03712.735 14.930 14.930 3.967 8.225 4.672 4.672 13.773 32.898 29.392 29.392 2.814137.510 145.895 145.895 1.479 82.982 64.624 64.624 6.219 178.564 190.829 190.829 1.660B.7 fp-XRF Soil Mode Analytical and Field Duplicates - MPD (%)Mean Mean Mean 21830% Median Median OREAS25a OREAS25a OREAS25a OREAS25a OREAS25a OREAS25aElement Unit Median of Median +30% -30% Q515513s Q515552s Q515572s Q515592s Q515663s Q515685sBa ppm 115.23 34.57 149.80 80.66 145.71 110.72 91.91 90.65 125.81 119.75Ca ppm 3160.46 948.14 4108.60 2212.32 3177.49 3235.84 3143.43 3316.62 3141.59 3132.00Cr ppm 117.44 35.23 152.67 82.21 117.67 126.09 106.36 117.95 117.21 102.99Cu ppm 21.74 6.52 28.26 15.21 26.35 21.11 23.70 18.46 22.36 12.14Fe ppm 69621.58 20886.47 90508.05 48735.11 69411.54 69926.33 69555.55 69687.61 69519.89 70000.34K ppm 4085.08 1225.52 5310.60 2859.55 4092.96 4009.31 4103.20 4165.49 4010.09 4077.19Mn ppm 540.09 162.03 702.12 378.06 539.74 540.45 545.27 537.94 557.41 537.50Nb ppm 25.57 7.67 33.24 17.90 25.21 26.02 23.67 24.92 25.93 26.39Ni ppm 25.83 7.75 33.58 18.08 31.76 20.37 17.63 35.87 31.29 19.28Rb ppm 58.77 17.63 76.41 41.14 57.18 59.58 58.10 59.45 57.68 59.76Sr ppm 65.44 19.63 85.07 45.81 64.73 61.81 72.10 67.04 61.71 66.15Ti ppm 11832.76 3549.83 15382.58 8282.93 11696.52 11816.53 11848.98 11854.13 11979.99 11789.72V ppm 130.45 39.13 169.58 91.31 135.83 128.51 135.11 124.31 129.43 131.47Y ppm 22.39 6.72 29.11 15.67 25.23 22.60 22.18 27.60 21.31 21.49Zn ppm 42.47 12.74 55.21 29.73 43.68 42.07 41.56 42.89 41.87 42.88Zr ppm 402.20 120.66 522.86 281.54 400.95 403.15 401.25 406.69 397.64 415.53B.8 fp-XRF Soil Mode Certified Reference Materials219Original Duplicate Original Duplicate Original DuplicateCompound Unit Q515582 Q515583 Q515588 Q515589 Q515592 Q515593C001_LA ppt 36.7 38.8 37.8 5.6 38.8 42.8 40.8 9.8 42.4 40.4 41.4 4.8C002_LA ppt 203.0 258.0 230.5 23.9 226.0 295.0 260.5 26.5 334.0 345.0 339.5 3.2C003_LB ppt 6.7 24.4 15.5 114.0 19.0 37.4 28.2 65.2 28.7 37.7 33.2 27.1C004_LA ppt 1.4 2.7 2.0 63.1 1.7 2.5 2.1 34.3 3.0 2.9 3.0 1.4C005_LB ppt 2.0 9.3 5.6 129.1 7.2 11.8 9.5 48.9 11.8 16.1 14.0 30.8C006_LB ppt 1.1 7.8 4.5 150.8 5.7 9.3 7.5 48.5 12.7 14.8 13.8 15.3C007_LA ppt 0.5 2.1 1.3 121.6 1.3 1.6 1.4 21.8 1.8 1.6 1.7 9.6C008_LB ppt 5.6 35.0 20.3 144.8 20.5 27.3 23.9 28.5 46.8 50.0 48.4 6.6C009_LB ppt 3.7 4.9 4.3 29.4 2.8 2.9 2.8 6.7 6.4 6.3 6.4 1.9C010_LB ppt 3.5 13.7 8.6 119.0 13.8 12.8 13.3 7.5 12.9 12.6 12.8 2.4C011_LA ppt 0.5 4.6 2.6 160.8 1.3 1.6 1.5 21.9 3.8 2.6 3.2 35.9C013_LBA ppt 0.5 4.0 2.3 155.9 1.1 1.4 1.2 24.1 3.8 5.3 4.5 34.4C014_LB ppt 1.7 7.3 4.5 123.2 4.1 3.1 3.6 27.3 8.0 6.8 7.4 15.7C015_LAR ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C016_LB ppt 1.7 7.3 4.5 123.2 4.1 3.1 3.6 27.3 8.0 6.8 7.4 15.7C017_LB ppt 2.1 6.4 4.3 102.3 4.2 3.2 3.7 27.0 7.4 6.4 6.9 13.9C018_LB ppt 4.1 12.4 8.2 101.0 8.2 6.4 7.3 24.0 14.1 12.5 13.3 12.0C019_LB ppt 4.2 12.6 8.4 100.7 8.3 6.6 7.4 23.7 14.3 12.7 13.5 11.9C020_LA ppt 2.1 10.1 6.1 132.2 3.4 2.8 3.1 19.1 3.0 3.2 3.1 6.1C021_LPH ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C022_LBA ppt 1.8 9.8 5.8 138.5 3.2 0.5 1.8 145.4 0.5 2.9 1.7 141.0C023_LAR ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C024_LB ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C025_LAR ppt 1.3 2.1 1.7 45.8 1.9 1.5 1.7 25.8 2.5 2.3 2.4 8.8C026_LBA ppt 0.5 2.0 1.2 119.7 1.1 0.5 0.8 71.0 1.4 1.2 1.3 19.6C027_LB ppt 4.2 7.2 5.7 51.2 5.3 3.8 4.5 32.6 7.7 6.4 7.1 18.7C028_ALK ppt 0.5 3.0 1.8 143.3 3.3 2.8 3.1 15.1 3.4 1.2 2.3 95.2C029_HB ppt 1.5 0.5 1.0 98.5 1.4 1.1 1.2 26.7 0.5 1.4 1.0 96.9C030_HB ppt 0.5 1.6 1.1 106.5 1.1 0.5 0.8 77.3 0.5 1.5 1.0 97.4C031_HB ppt 1.4 1.7 1.6 20.5 1.5 1.2 1.3 24.2 1.4 1.6 1.5 11.4C032_HB ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C033_HB ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C034_HB ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C035_LAR ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0B.9 SGH Duplicates - MPD (%)MPD (%)MeanMPD (%)MeanMPD (%)Mean220Original Duplicate Original Duplicate Original DuplicateCompound Unit Q515582 Q515583 Q515588 Q515589 Q515592 Q515593B.9 SGH Duplicates - MPD (%)MPD (%)MeanMPD (%)MeanMPD (%)MeanC036_LBA ppt 0.5 4.6 2.6 160.8 1.3 0.5 0.9 88.9 4.1 3.2 3.7 25.8C037_HB ppt 0.5 1.7 1.1 107.4 0.5 0.5 0.5 0.0 2.5 0.5 1.5 133.1C038_LBA ppt 0.5 1.7 1.1 110.3 1.2 1.1 1.1 7.9 1.2 3.4 2.3 93.0C039_LAR ppt 1.9 2.2 2.0 16.8 2.0 1.7 1.9 14.9 2.3 2.0 2.1 9.8C040_LPB ppt 1.8 2.4 2.1 27.9 2.0 1.6 1.8 23.1 2.3 2.0 2.2 15.7C041_LBA ppt 3.9 42.0 23.0 165.9 12.0 9.3 10.6 25.6 12.0 9.7 10.9 21.0C042_LPB ppt 1.4 1.5 1.4 8.3 1.5 1.3 1.4 13.1 1.5 1.4 1.4 6.2C043_HB ppt 1.1 0.5 0.8 75.0 1.6 1.2 1.4 23.5 1.5 1.4 1.4 5.6C044_HB ppt 1.6 2.1 1.9 28.6 2.0 1.8 1.9 12.8 2.0 1.9 2.0 6.1C045_LA ppt 3.3 44.8 24.1 172.2 12.8 9.4 11.1 31.0 12.4 9.9 11.1 22.6C046_LPH ppt 0.5 3.5 2.0 149.9 1.4 1.3 1.3 9.8 1.4 1.3 1.4 7.4C047_LBA ppt 3.8 4.8 4.3 24.6 6.4 5.3 5.8 17.8 6.2 4.9 5.6 23.0C048_HB ppt 1.1 1.5 1.3 28.6 1.2 1.2 1.2 5.0 1.3 1.2 1.3 8.7C049 -HB ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 1.3 0.9 85.7C050_LBA ppt 0.5 6.7 3.6 172.3 5.7 4.1 4.9 32.5 5.0 3.9 4.4 24.9C051_LBI ppt 0.5 1.0 0.8 67.5 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C052_LPB ppt 0.5 1.1 0.8 72.6 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C053_LPB ppt 1.5 1.5 1.5 3.4 1.5 1.4 1.4 7.8 1.5 1.4 1.5 4.8C054_HB ppt 1.2 1.6 1.4 29.6 1.4 1.2 1.3 11.5 1.4 1.3 1.3 9.0C055_LPB ppt 0.5 1.1 0.8 71.8 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C056_LBI ppt 0.5 1.2 0.9 82.4 1.8 1.2 1.5 41.6 1.3 0.5 0.9 86.4C057_ALK ppt 1.9 4.1 3.0 75.2 4.0 2.1 3.0 60.5 2.5 1.6 2.0 44.5C058_LPB ppt 1.3 1.3 1.3 0.7 1.3 1.1 1.2 12.6 1.3 1.2 1.2 9.1C059_LPB ppt 1.9 1.5 1.7 24.3 1.8 1.4 1.6 22.2 1.7 1.4 1.6 19.7C060_LPH ppt 9.2 4.6 6.9 67.8 5.9 6.2 6.1 5.9 5.5 3.8 4.6 36.2C061_LBI ppt 0.5 3.6 2.0 151.0 2.4 0.5 1.5 131.5 2.3 2.1 2.2 8.1C062_LBA ppt 1.3 14.4 7.8 167.6 10.3 8.3 9.3 21.3 11.9 12.5 12.2 4.9C063_LPH ppt 6.4 3.6 5.0 55.7 4.2 4.3 4.3 0.9 4.2 3.2 3.7 28.0C064_LBA ppt 4.8 16.6 10.7 109.7 10.2 9.0 9.6 12.9 12.9 13.9 13.4 7.5C065_HPB ppt 2.9 3.3 3.1 13.1 2.7 2.2 2.4 20.4 2.3 2.1 2.2 8.7C066_LBA ppt 12.1 74.0 43.1 143.8 38.4 24.7 31.6 43.4 30.6 28.1 29.4 8.5C067_LBI ppt 2.0 0.5 1.2 118.4 2.7 2.2 2.5 20.1 2.4 2.2 2.3 7.0C068_HPB ppt 6.5 8.5 7.5 26.7 5.7 3.7 4.7 43.7 3.5 2.8 3.1 20.4C069_LA ppt 12.5 76.8 44.7 144.0 39.6 24.8 32.2 46.0 31.6 29.1 30.4 8.2221Original Duplicate Original Duplicate Original DuplicateCompound Unit Q515582 Q515583 Q515588 Q515589 Q515592 Q515593B.9 SGH Duplicates - MPD (%)MPD (%)MeanMPD (%)MeanMPD (%)MeanC070_HPB ppt 11.7 15.0 13.4 24.7 9.4 5.8 7.6 47.8 5.2 3.9 4.6 30.3C071_HPB ppt 14.6 19.0 16.8 26.2 12.4 7.2 9.8 53.1 6.7 4.7 5.7 35.2C072_HPB ppt 19.2 12.8 16.0 40.0 7.1 0.5 3.8 173.8 7.0 4.8 5.9 38.6C073_HBA ppt 7.7 29.8 18.7 118.0 16.8 14.5 15.7 14.7 18.3 18.0 18.2 1.7C074_HBA ppt 8.4 32.4 20.4 117.3 19.0 14.4 16.7 27.5 17.5 14.5 16.0 18.8C075_HPB ppt 15.6 20.8 18.2 28.6 11.1 6.5 8.8 52.0 5.7 4.0 4.9 35.4C076_LPH ppt 2.4 11.3 6.9 129.7 4.2 2.8 3.5 40.2 3.5 2.9 3.2 16.9C077_MAR ppt 2.2 8.3 5.2 117.6 3.6 2.7 3.1 27.8 3.3 2.9 3.1 14.5C078_ALK ppt 0.5 12.3 6.4 184.4 5.2 2.0 3.6 90.5 3.9 2.5 3.2 42.0C079_LBI ppt 0.5 3.6 2.1 151.5 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C080_LPH ppt 2.2 6.8 4.5 102.6 3.3 2.5 2.9 29.6 2.8 2.4 2.6 13.0C081_MAR ppt 6.4 6.2 6.3 1.9 4.6 3.2 3.9 37.4 2.9 2.3 2.6 22.6C082_LPH ppt 2.5 8.4 5.4 108.5 3.8 2.8 3.3 30.5 3.1 2.7 2.9 13.4C083_HBA ppt 27.9 86.8 57.4 102.7 54.8 5.1 30.0 165.8 5.4 24.9 15.1 129.1C084_HBA ppt 1.2 3.8 2.5 100.6 1.5 1.1 1.3 26.0 1.1 0.5 0.8 78.0C085_LPH ppt 26.3 73.6 50.0 94.7 48.8 4.0 26.4 169.4 35.4 24.2 29.8 37.6C086_LBI ppt 5.6 7.5 6.5 28.7 6.4 5.9 6.1 8.5 5.7 5.4 5.5 5.8C087_MAR ppt 4.2 4.5 4.4 6.4 2.5 2.0 2.3 25.3 1.8 1.4 1.6 24.7C088_HBA ppt 32.1 89.6 60.9 94.5 60.0 44.0 52.0 30.8 43.6 27.4 35.5 45.6C089_THI ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C090_HPB ppt 8.0 7.4 7.7 8.8 5.8 5.6 5.7 3.5 5.2 0.5 2.8 164.7C091_LBI ppt 5.9 9.7 7.8 48.2 7.9 6.4 7.1 20.7 6.4 5.4 5.9 17.1C092_LPH ppt 6.0 4.1 5.0 38.1 4.4 4.4 4.4 0.9 4.2 3.7 4.0 12.5C093_LA ppt 54.8 90.4 72.6 49.0 82.0 54.4 68.2 40.5 52.4 29.9 41.2 54.7C094_LBI ppt 6.2 10.8 8.5 53.5 8.4 6.1 7.3 31.9 5.7 4.5 5.1 22.7C095_MAR ppt 0.5 0.5 0.5 0.0 5.1 0.5 2.8 164.4 5.1 0.5 2.8 164.2C096_LPH ppt 1.4 5.7 3.6 119.5 5.5 5.5 5.5 0.0 5.3 0.5 2.9 165.6C097_HBA ppt 68.0 109.0 88.5 46.3 99.6 70.4 85.0 34.4 64.4 34.3 49.4 61.0C098_THI ppt 2.3 3.1 2.7 30.2 3.3 0.5 1.9 147.2 0.5 0.5 0.5 0.0C099_LPH ppt 6.5 5.6 6.0 14.6 5.4 5.2 5.3 3.0 5.4 0.5 3.0 166.1C100_LPH ppt 6.3 5.5 5.9 13.6 5.4 5.4 5.4 0.0 5.2 0.5 2.8 164.7C101_MAR ppt 5.5 6.2 5.9 12.2 5.9 5.7 5.8 4.1 5.3 4.9 5.1 8.6C102_MBI ppt 4.4 7.4 5.9 51.7 5.8 4.7 5.3 20.5 4.4 3.6 4.0 20.6C103_LPH ppt 2.2 6.1 4.1 96.0 6.0 6.1 6.0 2.0 1.6 0.5 1.1 104.8222Original Duplicate Original Duplicate Original DuplicateCompound Unit Q515582 Q515583 Q515588 Q515589 Q515592 Q515593B.9 SGH Duplicates - MPD (%)MPD (%)MeanMPD (%)MeanMPD (%)MeanC104_MAR ppt 18.7 10.2 14.5 58.8 9.6 7.8 8.7 21.6 6.9 5.4 6.1 24.8C105_ALK ppt 30.2 57.2 43.7 61.8 44.0 27.2 35.6 47.2 24.0 11.2 17.6 72.7C106_MBI ppt 5.4 6.3 5.9 15.0 6.1 5.0 5.6 18.7 4.7 3.9 4.3 20.3C107_MBI ppt 5.2 5.3 5.3 2.3 5.0 5.0 5.0 0.0 0.5 0.5 0.5 0.0C108_LPH ppt 17.3 16.7 17.0 3.5 16.6 16.6 16.6 0.0 0.5 0.5 0.5 0.0C109_MAR ppt 29.2 34.8 32.0 17.5 34.0 24.0 29.0 34.5 20.3 13.0 16.7 43.8C110_HBA ppt 110.0 123.0 116.5 11.2 127.0 108.0 117.5 16.2 90.4 54.4 72.4 49.7C111_MAR ppt 0.5 0.5 0.5 0.0 3.6 0.5 2.1 151.5 0.5 0.5 0.5 0.0C112_MBI ppt 19.6 19.9 19.8 1.5 20.2 19.0 19.6 6.1 17.9 0.5 9.2 189.1C113 -HBA ppt 117.0 121.0 119.0 3.4 131.0 112.0 121.5 15.6 91.2 53.2 72.2 52.6C114_MBI ppt 28.4 26.7 27.6 6.2 25.2 25.8 25.5 2.4 21.0 0.5 10.8 190.7C115_MBI ppt 32.5 29.0 30.8 11.4 26.7 28.5 27.6 6.5 22.3 17.6 20.0 23.6C116_MAR ppt 13.3 12.1 12.7 9.4 12.6 11.6 12.1 8.3 11.2 9.7 10.4 14.6C117_HA ppt 292.0 164.0 228.0 56.1 223.0 235.0 229.0 5.2 192.0 102.0 147.0 61.2C118_MPH ppt 16.4 14.9 15.7 9.6 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C119_HBA ppt 236.0 134.0 185.0 55.1 182.0 192.0 187.0 5.3 153.0 75.2 114.1 68.2C120_THI ppt 9.2 0.5 4.9 179.5 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C121_MPH ppt 18.7 16.5 17.6 12.5 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C122_MPH ppt 16.0 17.0 16.5 6.1 16.6 15.4 16.0 7.5 14.7 13.1 13.9 11.5C123_MPH ppt 17.1 15.2 16.2 11.8 15.3 15.2 15.3 0.7 0.5 0.5 0.5 0.0C124_MBI ppt 20.0 18.5 19.3 7.8 18.3 18.0 18.2 1.7 17.2 0.5 8.9 188.7C125_HAR ppt 12.6 12.8 12.7 1.6 11.5 10.2 10.9 12.0 10.8 9.8 10.3 10.1C126_MPH ppt 17.0 14.6 15.8 15.2 14.6 0.5 7.6 186.8 0.5 0.5 0.5 0.0C127_MPH ppt 18.2 15.8 17.0 14.1 0.5 15.3 7.9 187.3 0.5 0.5 0.5 0.0C128_MPH ppt 17.4 16.1 16.8 7.8 16.0 15.9 16.0 0.6 0.5 0.5 0.5 0.0C129_HAR ppt 14.6 14.5 14.6 0.7 14.0 12.4 13.2 12.1 12.6 0.5 6.6 184.7C130_HAR ppt 18.5 16.7 17.6 10.2 16.6 16.4 16.5 1.2 15.3 0.5 7.9 187.3C131_MPH ppt 16.6 14.5 15.6 13.5 14.6 15.3 15.0 4.7 14.7 0.5 7.6 186.8C132_ALK ppt 314.0 158.0 236.0 66.1 188.0 193.0 190.5 2.6 164.0 80.4 122.2 68.4C133_HAR ppt 42.8 0.5 21.7 195.4 0.5 35.6 18.1 194.5 33.8 0.5 17.2 194.2C134_HAR ppt 70.4 46.0 58.2 41.9 53.2 56.0 54.6 5.1 44.8 33.2 39.0 29.7C135_MPH ppt 35.6 32.5 34.1 9.1 32.5 31.8 32.2 2.2 32.8 31.6 32.2 3.7C136_MPH ppt 32.6 0.5 16.6 194.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C137_HBI ppt 42.0 32.9 37.5 24.3 34.2 37.3 35.8 8.7 34.1 31.0 32.6 9.5223Original Duplicate Original Duplicate Original DuplicateCompound Unit Q515582 Q515583 Q515588 Q515589 Q515592 Q515593B.9 SGH Duplicates - MPD (%)MPD (%)MeanMPD (%)MeanMPD (%)MeanC138_HBI ppt 43.2 34.3 38.8 23.0 35.3 36.5 35.9 3.3 33.4 0.5 17.0 194.1C139_HPH ppt 35.6 0.5 18.1 194.5 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C140_HPH ppt 34.9 0.5 17.7 194.4 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C141_HBI ppt 35.5 32.6 34.1 8.5 32.2 33.1 32.7 2.8 32.4 0.5 16.5 193.9C142_HPH ppt 31.3 0.5 15.9 193.7 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C143_HA ppt 288.0 120.0 204.0 82.4 147.0 170.0 158.5 14.5 169.0 102.0 135.5 49.4C144_HBI ppt 34.1 30.6 32.4 10.8 30.0 30.4 30.2 1.3 30.9 0.5 15.7 193.6C145_HBA ppt 120.0 66.4 93.2 57.5 76.4 87.2 81.8 13.2 84.0 62.0 73.0 30.1C146_HPH ppt 30.4 0.5 15.5 193.5 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C147_HBI ppt 30.6 0.5 15.6 193.6 7.3 30.0 18.7 121.5 0.5 0.5 0.5 0.0C148_HPH ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C149_HBI ppt 30.2 0.5 15.4 193.5 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C150_HPH ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C151_HBI ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C152_HPH ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C153_HPH ppt 45.6 0.5 23.1 195.7 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C154_HPH ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C155_HPH ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C156_HBI ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C157_HAR ppt 46.0 0.5 23.3 195.7 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C158_HBA ppt 108.0 76.8 92.4 33.8 83.6 86.4 85.0 3.3 91.2 78.4 84.8 15.1C159_HBA ppt 42.8 0.5 21.7 195.4 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C160_HBI ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0C161_HA ppt 140.0 100.0 120.0 33.3 108.0 108.0 108.0 0.0 114.0 101.0 107.5 12.1C162_HPH ppt 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0224Compound UnitC001_LA pptC002_LA pptC003_LB pptC004_LA pptC005_LB pptC006_LB pptC007_LA pptC008_LB pptC009_LB pptC010_LB pptC011_LA pptC013_LBA pptC014_LB pptC015_LAR pptC016_LB pptC017_LB pptC018_LB pptC019_LB pptC020_LA pptC021_LPH pptC022_LBA pptC023_LAR pptC024_LB pptC025_LAR pptC026_LBA pptC027_LB pptC028_ALK pptC029_HB pptC030_HB pptC031_HB pptC032_HB pptC033_HB pptC034_HB pptC035_LAR pptOriginal Duplicate Original Duplicate Original DuplicateQ515654 Q515655 Q515679 Q515678 Q515696 Q51569538.4 39.1 38.8 1.8 111.0 108.0 109.5 2.7 116.0 106.0 111.0 9.0250.0 273.0 261.5 8.8 868.0 676.0 772.0 24.9 6240.0 4240.0 5240.0 38.239.3 39.8 39.6 1.3 196.0 173.0 184.5 12.5 226.0 235.0 230.5 3.92.3 2.8 2.6 22.3 11.2 5.8 8.5 63.5 202.0 65.6 133.8 101.912.0 12.7 12.4 5.7 54.4 38.4 46.4 34.5 31.2 142.0 86.6 127.910.4 9.2 9.8 12.7 14.4 17.6 16.0 20.0 32.9 23.4 28.2 33.71.4 1.3 1.3 6.9 4.4 3.0 3.7 37.2 208.0 37.2 122.6 139.321.3 17.6 19.5 19.0 104.0 64.4 84.2 47.0 904.0 282.0 593.0 104.92.4 2.2 2.3 9.2 10.0 7.0 8.5 35.3 102.0 30.8 66.4 107.29.7 9.4 9.6 3.3 20.9 12.6 16.8 49.6 63.2 27.5 45.4 78.71.9 2.6 2.2 33.0 6.8 3.2 5.0 72.5 206.0 29.1 117.6 150.50.5 2.2 1.3 125.1 1.2 2.9 2.1 79.0 175.0 26.3 100.7 147.71.7 1.5 1.6 15.2 5.8 4.0 4.9 37.7 76.4 15.2 45.8 133.60.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 11.6 3.1 7.4 115.61.7 1.5 1.6 15.2 5.8 4.0 4.9 37.7 76.4 15.2 45.8 133.61.5 1.4 1.4 11.1 6.3 3.9 5.1 46.6 62.0 11.2 36.6 138.83.0 2.7 2.9 10.1 13.0 8.1 10.5 46.7 117.0 21.6 69.3 137.73.1 2.8 3.0 10.1 13.1 8.2 10.7 46.0 117.0 21.6 69.3 137.72.2 1.7 2.0 28.1 6.5 2.7 4.6 82.0 96.8 18.4 57.6 136.10.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 6.0 1.2 3.6 131.62.5 0.5 1.5 132.7 6.8 2.9 4.8 81.0 100.0 19.2 59.6 135.60.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 10.3 2.3 6.3 127.20.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 1.7 0.5 1.1 109.10.5 0.5 0.5 0.0 2.1 1.6 1.8 28.6 17.6 3.3 10.5 136.40.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 9.6 2.2 5.9 124.11.7 1.5 1.6 8.8 5.4 3.7 4.6 39.1 45.6 8.4 27.0 138.00.5 0.5 0.5 0.0 1.1 0.5 0.8 75.0 29.4 5.1 17.3 140.70.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 1.1 0.5 0.8 71.0 1.4 0.5 0.9 93.60.5 0.5 0.5 0.0 1.2 0.5 0.9 84.4 7.6 1.9 4.8 121.30.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 2.6 0.5 1.6 135.50.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 1.8 0.5 1.1 112.30.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 1.3 0.5 0.9 89.5MPD (%)MeanMPD (%)MeanMPD (%)MeanB.9 SGH Duplicates - MPD (%)225Compound UnitC036_LBA pptC037_HB pptC038_LBA pptC039_LAR pptC040_LPB pptC041_LBA pptC042_LPB pptC043_HB pptC044_HB pptC045_LA pptC046_LPH pptC047_LBA pptC048_HB pptC049 -HB pptC050_LBA pptC051_LBI pptC052_LPB pptC053_LPB pptC054_HB pptC055_LPB pptC056_LBI pptC057_ALK pptC058_LPB pptC059_LPB pptC060_LPH pptC061_LBI pptC062_LBA pptC063_LPH pptC064_LBA pptC065_HPB pptC066_LBA pptC067_LBI pptC068_HPB pptC069_LA pptOriginal Duplicate Original Duplicate Original DuplicateQ515654 Q515655 Q515679 Q515678 Q515696 Q515695MPD (%)MeanMPD (%)MeanMPD (%)MeanB.9 SGH Duplicates - MPD (%)1.9 1.7 1.8 12.2 2.6 1.8 2.2 36.9 13.3 3.9 8.6 109.31.6 1.4 1.5 13.7 0.5 1.7 1.1 107.0 1.7 2.3 2.0 29.42.0 1.8 1.9 12.5 2.8 1.9 2.4 34.9 13.3 1.7 7.5 155.11.1 1.2 1.1 0.9 1.8 1.5 1.6 18.1 6.2 2.0 4.1 101.61.2 1.2 1.2 1.7 1.8 1.5 1.6 18.1 6.9 2.1 4.5 108.26.2 5.1 5.7 20.5 15.3 5.7 10.5 91.2 102.0 26.8 64.4 116.81.1 1.1 1.1 0.9 1.4 1.3 1.3 10.6 3.4 1.5 2.4 77.70.5 0.5 0.5 0.0 1.3 1.1 1.2 13.4 2.7 1.5 2.1 56.61.5 1.2 1.3 17.2 1.8 1.6 1.7 12.0 3.2 2.1 2.7 38.86.1 5.0 5.5 19.5 15.8 5.6 10.7 94.8 109.0 28.0 68.5 118.21.1 1.1 1.1 3.7 1.7 1.1 1.4 44.8 7.3 2.5 4.9 97.82.8 2.3 2.6 21.2 4.5 2.4 3.5 59.8 21.0 3.3 12.2 145.50.5 0.5 0.5 0.0 1.1 1.0 1.1 8.4 2.2 1.3 1.7 50.40.5 0.5 0.5 0.0 1.1 1.0 1.1 9.2 2.1 1.3 1.7 44.52.3 1.8 2.0 23.8 3.8 2.1 3.0 56.3 14.2 4.6 9.4 101.50.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 1.6 0.5 1.1 104.80.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 1.3 0.5 0.9 88.90.5 0.5 0.5 0.0 1.3 1.2 1.3 7.1 3.2 1.4 2.3 78.41.0 0.5 0.8 67.5 1.2 1.1 1.2 10.2 2.1 1.4 1.7 39.50.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 1.3 0.5 0.9 90.70.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 1.7 1.2 1.4 38.90.5 0.5 0.5 0.0 1.4 0.5 0.9 91.9 4.7 0.5 2.6 161.40.5 0.5 0.5 0.0 1.1 0.5 0.8 73.4 2.3 1.1 1.7 70.60.5 0.5 0.5 0.0 1.4 0.5 0.9 93.6 3.5 1.5 2.5 81.91.2 0.5 0.8 79.5 3.3 3.0 3.1 9.0 7.1 2.9 5.0 83.20.5 0.5 0.5 0.0 2.2 0.5 1.4 126.7 3.7 0.5 2.1 152.65.9 4.6 5.2 25.3 2.7 4.0 3.3 39.5 15.8 6.7 11.2 81.12.1 0.5 1.3 122.8 2.6 2.4 2.5 7.2 5.2 2.5 3.8 70.86.3 5.0 5.7 23.3 5.3 4.0 4.6 27.6 16.2 7.2 11.7 76.50.5 0.5 0.5 0.0 2.0 1.9 1.9 3.6 2.9 2.0 2.5 39.016.2 12.5 14.4 25.8 24.4 9.6 17.0 87.1 98.8 34.9 66.9 95.62.0 0.5 1.2 119.7 2.3 0.5 1.4 129.6 3.9 2.3 3.1 53.20.5 0.5 0.5 0.0 2.7 2.6 2.6 5.7 6.3 2.9 4.6 75.116.6 12.8 14.7 25.9 25.2 9.7 17.5 88.7 102.0 35.9 69.0 95.9226Compound UnitC070_HPB pptC071_HPB pptC072_HPB pptC073_HBA pptC074_HBA pptC075_HPB pptC076_LPH pptC077_MAR pptC078_ALK pptC079_LBI pptC080_LPH pptC081_MAR pptC082_LPH pptC083_HBA pptC084_HBA pptC085_LPH pptC086_LBI pptC087_MAR pptC088_HBA pptC089_THI pptC090_HPB pptC091_LBI pptC092_LPH pptC093_LA pptC094_LBI pptC095_MAR pptC096_LPH pptC097_HBA pptC098_THI pptC099_LPH pptC100_LPH pptC101_MAR pptC102_MBI pptC103_LPH pptOriginal Duplicate Original Duplicate Original DuplicateQ515654 Q515655 Q515679 Q515678 Q515696 Q515695MPD (%)MeanMPD (%)MeanMPD (%)MeanB.9 SGH Duplicates - MPD (%)2.6 2.4 2.5 9.7 3.6 3.3 3.5 7.5 9.6 4.1 6.9 80.22.9 2.4 2.7 16.2 4.0 3.7 3.8 7.3 12.4 4.6 8.5 91.80.5 0.5 0.5 0.0 3.8 0.5 2.2 153.7 12.0 0.5 6.3 184.08.3 6.6 7.5 22.5 6.9 4.6 5.7 40.6 10.6 8.8 9.7 18.610.0 7.1 8.6 33.6 6.6 5.0 5.8 27.8 21.1 7.5 14.3 95.32.5 2.3 2.4 8.9 3.0 3.0 3.0 0.7 8.8 3.8 6.3 78.12.2 2.1 2.1 4.7 2.9 2.3 2.6 23.3 10.8 3.0 6.9 113.52.1 0.5 1.3 124.2 2.4 2.0 2.2 17.2 5.6 2.2 3.9 86.71.1 0.5 0.8 78.0 3.7 0.5 2.1 152.6 7.6 1.4 4.5 139.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 3.0 0.5 1.8 143.30.5 0.5 0.5 0.0 2.5 2.1 2.3 17.2 5.6 2.3 4.0 83.81.9 0.5 1.2 117.4 2.1 2.0 2.1 6.8 2.9 2.2 2.5 29.02.2 2.1 2.2 6.9 2.7 2.2 2.4 20.6 6.3 2.5 4.4 85.316.6 2.6 9.6 145.7 24.2 13.0 18.6 60.2 2.3 12.8 7.5 139.55.0 0.5 2.8 163.6 5.6 4.9 5.2 12.2 1.7 1.1 1.4 44.814.3 10.4 12.4 31.6 21.6 11.0 16.3 65.0 28.6 11.9 20.3 82.54.9 0.5 2.7 162.8 5.2 4.8 5.0 7.2 5.6 0.5 3.0 167.00.5 0.5 0.5 0.0 5.2 5.1 5.1 2.3 1.5 5.2 3.3 111.315.9 11.5 13.7 32.1 22.2 11.8 17.0 61.2 29.0 12.7 20.9 78.20.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 4.9 0.5 2.7 163.10.5 0.5 0.5 0.0 5.2 0.5 2.9 165.2 5.7 0.5 3.1 167.80.5 0.5 0.5 0.0 3.6 3.6 3.6 0.3 4.2 0.5 2.3 157.119.8 13.1 16.5 40.7 30.8 14.6 22.7 71.4 37.2 18.0 27.6 69.64.2 0.5 2.4 157.4 4.9 4.1 4.5 17.9 5.0 0.5 2.8 163.60.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 5.6 0.5 3.0 167.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 5.2 0.5 2.8 164.722.2 13.3 17.8 50.1 34.8 16.1 25.5 73.5 38.1 19.3 28.7 65.50.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 5.1 0.5 2.8 164.40.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 5.0 0.5 2.7 163.40.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 5.0 0.5 2.7 163.43.0 0.5 1.8 142.9 3.2 3.0 3.1 8.1 3.5 0.5 2.0 150.40.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 1.5 0.5 1.0 101.0227Compound UnitC104_MAR pptC105_ALK pptC106_MBI pptC107_MBI pptC108_LPH pptC109_MAR pptC110_HBA pptC111_MAR pptC112_MBI pptC113 -HBA pptC114_MBI pptC115_MBI pptC116_MAR pptC117_HA pptC118_MPH pptC119_HBA pptC120_THI pptC121_MPH pptC122_MPH pptC123_MPH pptC124_MBI pptC125_HAR pptC126_MPH pptC127_MPH pptC128_MPH pptC129_HAR pptC130_HAR pptC131_MPH pptC132_ALK pptC133_HAR pptC134_HAR pptC135_MPH pptC136_MPH pptC137_HBI pptOriginal Duplicate Original Duplicate Original DuplicateQ515654 Q515655 Q515679 Q515678 Q515696 Q515695MPD (%)MeanMPD (%)MeanMPD (%)MeanB.9 SGH Duplicates - MPD (%)0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 5.8 0.5 3.2 168.36.7 0.5 3.6 172.3 8.7 0.5 4.6 178.2 12.2 0.5 6.4 184.30.5 0.5 0.5 0.0 3.9 0.5 2.2 154.2 4.0 0.5 2.2 155.30.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.012.6 0.5 6.6 184.7 12.2 11.2 11.7 8.5 13.3 11.6 12.5 13.736.1 25.4 30.8 34.8 45.2 29.0 37.1 43.7 48.0 30.2 39.1 45.50.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.036.8 26.0 31.4 34.4 43.6 28.9 36.3 40.6 45.6 30.1 37.9 41.00.5 0.5 0.5 0.0 18.0 0.5 9.3 189.2 0.5 0.5 0.5 0.016.6 0.5 8.6 188.3 18.8 17.7 18.3 6.0 17.0 16.6 16.8 2.40.5 0.5 0.5 0.0 9.5 0.5 5.0 180.0 9.0 0.5 4.8 179.060.0 40.8 50.4 38.1 66.0 42.0 54.0 44.4 61.2 46.0 53.6 28.40.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.045.6 31.9 38.8 35.4 56.8 35.8 46.3 45.4 52.0 35.4 43.7 38.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.011.2 0.5 5.9 182.9 12.6 12.3 12.5 2.4 13.0 11.3 12.2 14.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 9.3 0.5 4.9 179.60.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.046.0 0.5 23.3 195.7 0.5 0.5 0.5 0.0 54.0 0.5 27.3 196.30.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 32.4 31.5 32.0 2.8 32.6 0.5 16.6 194.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0228Compound UnitC138_HBI pptC139_HPH pptC140_HPH pptC141_HBI pptC142_HPH pptC143_HA pptC144_HBI pptC145_HBA pptC146_HPH pptC147_HBI pptC148_HPH pptC149_HBI pptC150_HPH pptC151_HBI pptC152_HPH pptC153_HPH pptC154_HPH pptC155_HPH pptC156_HBI pptC157_HAR pptC158_HBA pptC159_HBA pptC160_HBI pptC161_HA pptC162_HPH pptOriginal Duplicate Original Duplicate Original DuplicateQ515654 Q515655 Q515679 Q515678 Q515696 Q515695MPD (%)MeanMPD (%)MeanMPD (%)MeanB.9 SGH Duplicates - MPD (%)0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 30.0 30.6 30.3 2.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.064.0 59.2 61.6 7.8 67.6 54.8 61.2 20.9 82.4 70.4 76.4 15.70.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.048.0 44.4 46.2 7.8 48.4 43.2 45.8 11.4 56.4 48.8 52.6 14.40.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 30.1 30.7 30.4 2.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.063.6 61.6 62.6 3.2 72.4 64.8 68.6 11.1 78.4 70.4 74.4 10.80.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.00.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.080.4 79.6 80.0 1.0 92.4 82.8 87.6 11.0 101.0 90.4 95.7 11.10.5 0.5 0.5 0.0 0.5 0.5 0.5 0.0 0.5 0.5 0.5 0.022900760785.D 00760752.D 00760856.D 00760812.DCompound Unit Original Duplicate Original DuplicateCarbon Dioxide ppt 5563599 5450019 5506809.0 2.1 4829071 5443361.001 5136216.0 12.0Carbonyl Sulfide ppt 39.38 59.14 49.3 40.1 30.17 62 45.8 68.4Dimethyl Sulfide ppt 13.67 2.96 8.3 128.7 6.07 2.39 4.2 87.0Dimethyl Disulfide ppt 25.62 0.57 13.1 191.2 0.01 0.92 0.5 194.8Ethene/Ethane ppt 18.01 19.91 19.0 10.0 14.36 23.86 19.1 49.8Ethane ppt 40.95 42.12 41.5 2.8 39.35 41.33 40.3 4.9Propene ppt 46.25 87.85 67.0 62.0 41.37 106.33 73.9 88.0Propane ppt 46.52 46.21 46.4 0.7 80.81 47.54 64.2 51.91-Butene ppt 178.08 357.43 267.8 67.0 133.46 413.40 273.4 102.4Butane ppt 284.01 320.41 302.2 12.0 162.39 350.10 256.2 73.32-Methylbutane ppt 1471.49 4512.16 2991.8 101.6 868.64 4561.02 2714.8 136.01-Pentene ppt 38.02 47.28 42.6 21.7 18.96 54.88 36.9 97.3Pentane ppt 582.53 2377.48 1480.0 121.3 656.01 2419.05 1537.5 114.7Furan ppt 57.22 146.21 101.7 87.5 72.11 179.70 125.9 85.4Carbon Disulfide ppt 187.70 799.72 493.7 124.0 184.42 854.61 519.5 129.0Cyclopentane ppt 4195.54 5501.08 4848.3 26.9 3367.39 4699.31 4033.3 33.02-Methylpentane ppt 206.02 655.94 431.0 104.4 201.53 2772.25 1486.9 172.93-Methylpentane ppt 4.92 19.57 12.2 119.6 2.22 13.04 7.6 141.71-Hexene ppt 1.98 13.78 7.9 149.8 2.49 12.07 7.3 131.6Hexane ppt 7.86 53.61 30.7 148.9 9.77 46.45 28.1 130.52-Methylfuran ppt 0.65 3.77 2.2 141.1 0.69 3.69 2.2 136.7Methylcyclopentane ppt 7.65 41.04 24.3 137.2 9.11 38.64 23.9 123.72-4-Dimethylpentane ppt 1.57 4.14 2.9 90.2 5.79 6.53 6.2 12.1Cyclohexane ppt 10.84 41.07 26.0 116.5 9.02 39.46 24.2 125.6Benzene ppt 1.75 3.60 2.7 69.1 0.96 3.27 2.1 109.12-Methylhexane ppt 0.89 3.83 2.4 124.7 0.88 3.76 2.3 124.13-Methylhexane ppt 1.57 6.36 4.0 120.7 1.44 7.24 4.3 133.7cis-1-3-Dimethylcyclopentane ppt 0.31 0.78 0.5 87.4 0.15 0.61 0.4 122.4trans-1-3-Dimethylcyclopentane ppt 0.46 1.52 1.0 107.7 0.34 1.28 0.8 115.5trans-1-2-Dimethylcyclopentane ppt 0.43 1.99 1.2 129.2 0.46 2.15 1.3 129.51-Heptene ppt 0.45 23.66 12.1 192.5 9.66 3.00 6.3 105.3Heptane ppt 1.54 6.51 4.0 123.6 2.41 7.29 4.9 100.5Methylcyclohexane ppt 2.06 9.22 5.6 126.9 2.26 8.94 5.6 119.3B.10 AGI Hydrocarbon Duplicates - MPD (%)Mean (ppt) MPD (%) Mean MPD (%)23000760785.D 00760752.D 00760856.D 00760812.DCompound Unit Original Duplicate Original DuplicateB.10 AGI Hydrocarbon Duplicates - MPD (%)Mean (ppt) MPD (%) Mean MPD (%)2-5-Dimethylhexane ppt 0.40 1.66 1.0 122.8 0.39 1.33 0.9 109.4Toluene ppt 8.34 42.31 25.3 134.1 11.63 49.38 30.5 123.73-Methylheptane ppt 0.46 1.75 1.1 117.2 0.33 1.54 0.9 128.7cis-1-3/1-4-Dimethylcyclohexane ppt 2.77 4.84 3.8 54.3 2.29 4.89 3.6 72.41-Octene ppt 2.22 6.35 4.3 96.5 17.02 13.72 15.4 21.5Cycloheptane ppt 0.01 0.15 0.1 175.1 0.03 0.29 0.2 158.2cis-1-2-Dimethylcyclohexane ppt 0.09 0.60 0.3 148.3 0.14 0.62 0.4 126.7Octane ppt 1.32 7.73 4.5 141.6 1.32 5.01 3.2 116.6trans-1-3/1-4-Dimethylcyclohexane ppt 0.21 0.99 0.6 129.0 0.18 0.88 0.5 133.02-6-Dimethylheptane ppt 0.37 0.92 0.6 85.4 0.31 0.58 0.4 59.9trans-1-2-Dimethylcyclohexane ppt 0.28 1.45 0.9 135.1 0.45 0.99 0.7 74.3Ethylcyclohexane ppt 0.49 2.10 1.3 123.8 0.40 2.24 1.3 138.8Ethylbenzene ppt 1.07 6.88 4.0 146.0 1.17 5.57 3.4 130.5m-p-Xylene ppt 2.65 14.43 8.5 137.9 2.48 11.61 7.0 129.61-Nonene ppt 1.25 6.46 3.9 135.1 2.15 3.25 2.7 40.8o-Xylene ppt 1.17 6.87 4.0 141.9 1.13 5.18 3.2 128.6Nonane ppt 1.93 15.86 8.9 156.6 2.11 7.01 4.6 107.6Cyclooctane ppt 0.77 8.23 4.5 165.8 2.75 5.03 3.9 58.6Propylcyclohexane ppt 0.26 2.13 1.2 157.1 0.40 1.17 0.8 98.0alpha-Pinene ppt 1.04 6.00 3.5 141.1 13.66 28.56 21.1 70.6Propylbenzene ppt 0.41 3.21 1.8 154.3 1.68 4.43 3.1 90.21-Ethyl-2/3-methylbenzene ppt 0.94 9.68 5.3 164.4 0.99 4.85 2.9 132.51-3-5-Trimethylbenzene ppt 1.79 4.33 3.1 83.1 0.94 2.94 1.9 102.8beta-Pinene ppt 0.46 4.74 2.6 164.8 26.24 10.64 18.4 84.61-Ethyl-4-methylbenzene ppt 0.51 3.32 1.9 146.9 0.86 2.06 1.5 82.01-Decene ppt 17.68 117.15 67.4 147.6 20.34 66.46 43.4 106.3Decane ppt 7.67 71.92 39.8 161.5 8.79 37.36 23.1 123.81-2-4-Trimethylbenzene ppt 1.20 10.39 5.8 158.5 1.19 5.62 3.4 129.9Octanal ppt 29.27 220.57 124.9 153.1 26.52 112.22 69.4 123.5Benzofuran ppt 0.15 0.44 0.3 100.1 0.00 0.26 0.1 195.3Indane ppt 0.21 2.10 1.2 163.4 0.27 1.25 0.8 127.8Indene ppt 0.17 0.58 0.4 109.5 0.13 0.38 0.3 98.8Butylbenzene ppt 0.68 5.01 2.8 152.0 3.05 18.45 10.7 143.323100760785.D 00760752.D 00760856.D 00760812.DCompound Unit Original Duplicate Original DuplicateB.10 AGI Hydrocarbon Duplicates - MPD (%)Mean (ppt) MPD (%) Mean MPD (%)1-Undecene ppt 4.68 21.38 13.0 128.2 79.63 10.03 44.8 155.3Undecane ppt 15.28 73.72 44.5 131.3 31.35 48.38 39.9 42.7Nonanal ppt 130.52 1061.47 596.0 156.2 135.00 589.50 362.3 125.51-2-4-5-Tetramethylbenzene ppt 0.34 2.88 1.6 157.7 0.44 1.98 1.2 127.4Camphor ppt 0.30 0.99 0.6 107.5 1.37 5.33 3.4 118.3Dodecane ppt 17.45 106.52 62.0 143.7 26.15 66.71 46.4 87.4Naphthalene ppt 2.32 10.93 6.6 129.9 3.29 7.28 5.3 75.5Decanal ppt 72.27 345.57 208.9 130.8 54.83 189.87 122.3 110.4Benzothiazole ppt 0.96 4.04 2.5 123.2 2.33 3.88 3.1 49.7Tridecane ppt 32.46 118.50 75.5 114.0 64.59 72.81 68.7 12.02-Methylnaphthalene ppt 1.00 5.54 3.3 139.0 1.78 3.71 2.7 70.2Tetradecane ppt 44.10 241.30 142.7 138.2 68.19 137.33 102.8 67.3Caryophyllene ppt 21.41 2.58 12.0 156.9 9.47 47.13 28.3 133.1Acenaphthylene ppt 0.23 0.83 0.5 114.9 0.43 0.55 0.5 24.1Pentadecane ppt 60.50 311.32 185.9 134.9 92.13 157.87 125.0 52.6Hexadecane ppt 31.29 498.81 265.0 176.4 46.77 177.38 112.1 116.5Heptadecane ppt 19.63 397.37 208.5 181.2 34.92 120.73 77.8 110.3Pristane ppt 18.05 262.13 140.1 174.2 24.70 80.02 52.4 105.7Octadecane ppt 10.84 472.13 241.5 191.0 14.68 105.14 59.9 151.0Phytane ppt 9.35 225.46 117.4 184.1 13.63 61.12 37.4 127.1232Compound UnitCarbon Dioxide pptCarbonyl Sulfide pptDimethyl Sulfide pptDimethyl Disulfide pptEthene/Ethane pptEthane pptPropene pptPropane ppt1-Butene pptButane ppt2-Methylbutane ppt1-Pentene pptPentane pptFuran pptCarbon Disulfide pptCyclopentane ppt2-Methylpentane ppt3-Methylpentane ppt1-Hexene pptHexane ppt2-Methylfuran pptMethylcyclopentane ppt2-4-Dimethylpentane pptCyclohexane pptBenzene ppt2-Methylhexane ppt3-Methylhexane pptcis-1-3-Dimethylcyclopentane ppttrans-1-3-Dimethylcyclopentane ppttrans-1-2-Dimethylcyclopentane ppt1-Heptene pptHeptane pptMethylcyclohexane ppt00760840.D 00760886.D 00760794.D 00760890.DOriginal Duplicate Original Duplicate6779644 5526923.004 6153283.5 20.4 3974913 4854488.003 4414700.5 19.936.38 35 35.6 4.1 38.34 67 52.5 54.04.06 11.50 7.8 95.7 2.00 2.78 2.4 33.06.40 19.50 13.0 101.1 12.04 4.61 8.3 89.22.95 42.40 22.7 174.0 30.30 24.03 27.2 23.149.37 45.87 47.6 7.3 35.17 39.51 37.3 11.65.39 18.04 11.7 108.0 26.09 20.20 23.1 25.46.19 27.75 17.0 127.0 41.03 38.81 39.9 5.667.25 369.71 218.5 138.4 295.06 188.98 242.0 43.823.50 712.39 367.9 187.2 425.88 268.97 347.4 45.2275.50 1096.24 685.9 119.7 1095.89 1281.27 1188.6 15.67.07 1466.55 736.8 198.1 900.65 23.24 461.9 189.9366.72 3606.19 1986.5 163.1 2488.85 1004.39 1746.6 85.028.65 59.32 44.0 69.7 74.85 36.30 55.6 69.480.05 455.84 267.9 140.3 416.43 399.07 407.8 4.31473.37 1660.55 1567.0 11.9 1849.32 1871.42 1860.4 1.2125.04 128.93 127.0 3.1 1791.38 96.03 943.7 179.60.80 12.69 6.7 176.2 5.49 13.81 9.7 86.31.52 10.71 6.1 150.4 7.44 8.25 7.8 10.35.24 38.05 21.6 151.6 21.96 44.46 33.2 67.80.78 2.48 1.6 104.6 0.96 1.93 1.4 67.16.73 22.12 14.4 106.7 22.73 28.65 25.7 23.01.35 3.15 2.2 79.7 5.81 2.34 4.1 85.17.84 21.93 14.9 94.6 23.71 21.31 22.5 10.70.95 2.28 1.6 81.8 2.59 2.50 2.5 3.41.45 4.40 2.9 101.0 2.80 2.54 2.7 10.01.74 4.97 3.4 96.4 5.00 5.03 5.0 0.40.16 0.54 0.4 110.0 0.29 0.52 0.4 55.40.29 1.00 0.6 111.0 0.82 0.97 0.9 15.90.48 1.77 1.1 115.3 1.86 1.47 1.7 23.20.82 1.93 1.4 81.3 1.11 0.42 0.8 91.32.24 6.43 4.3 96.5 4.68 4.93 4.8 5.22.39 7.11 4.7 99.5 7.06 6.26 6.7 12.0B.10 AGI Hydrocarbon Duplicates - MPD (%)Mean MPD (%) Mean MPD (%)233Compound Unit2-5-Dimethylhexane pptToluene ppt3-Methylheptane pptcis-1-3/1-4-Dimethylcyclohexane ppt1-Octene pptCycloheptane pptcis-1-2-Dimethylcyclohexane pptOctane ppttrans-1-3/1-4-Dimethylcyclohexane ppt2-6-Dimethylheptane ppttrans-1-2-Dimethylcyclohexane pptEthylcyclohexane pptEthylbenzene pptm-p-Xylene ppt1-Nonene ppto-Xylene pptNonane pptCyclooctane pptPropylcyclohexane pptalpha-Pinene pptPropylbenzene ppt1-Ethyl-2/3-methylbenzene ppt1-3-5-Trimethylbenzene pptbeta-Pinene ppt1-Ethyl-4-methylbenzene ppt1-Decene pptDecane ppt1-2-4-Trimethylbenzene pptOctanal pptBenzofuran pptIndane pptIndene pptButylbenzene ppt00760840.D 00760886.D 00760794.D 00760890.DOriginal Duplicate Original DuplicateB.10 AGI Hydrocarbon Duplicates - MPD (%)Mean MPD (%) Mean MPD (%)0.47 1.48 1.0 103.1 1.78 1.68 1.7 5.71.67 33.83 17.7 181.2 33.12 34.56 33.8 4.30.76 1.24 1.0 47.8 1.79 1.59 1.7 12.23.93 2.12 3.0 59.7 2.71 2.87 2.8 5.61.86 7.20 4.5 117.8 8.71 4.80 6.8 57.70.31 0.60 0.5 63.6 0.24 0.00 0.1 196.40.42 1.62 1.0 118.4 0.51 0.65 0.6 22.71.65 8.51 5.1 135.0 5.30 5.80 5.5 9.10.47 0.68 0.6 37.2 2.00 0.64 1.3 102.50.69 1.82 1.3 90.1 1.13 1.47 1.3 26.20.47 2.04 1.3 125.6 1.18 1.31 1.2 11.10.35 1.46 0.9 122.6 3.40 6.68 5.0 64.92.25 5.53 3.9 84.2 9.76 10.20 10.0 4.40.66 19.45 10.1 186.9 23.56 19.72 21.6 17.80.90 2.67 1.8 99.0 2.95 5.64 4.3 62.70.37 9.60 5.0 185.3 11.75 10.95 11.4 7.02.53 14.97 8.8 142.2 7.78 12.15 10.0 43.81.60 5.10 3.4 104.2 5.42 6.96 6.2 24.70.49 2.17 1.3 126.9 2.18 2.89 2.5 28.10.53 4.36 2.4 156.9 3.71 4.67 4.2 22.80.40 2.40 1.4 143.4 2.48 3.24 2.9 26.41.22 7.58 4.4 144.7 8.44 10.42 9.4 21.10.71 4.12 2.4 141.2 4.81 4.35 4.6 10.00.60 1.97 1.3 106.0 1.69 2.52 2.1 39.50.48 2.65 1.6 138.4 3.02 3.38 3.2 11.13.29 14.46 8.9 125.9 26.11 64.24 45.2 84.43.35 15.90 9.6 130.4 17.54 35.50 26.5 67.81.79 8.21 5.0 128.5 8.90 11.48 10.2 25.39.16 27.95 18.6 101.3 44.15 25.02 34.6 55.30.07 0.32 0.2 129.0 0.47 0.58 0.5 20.00.24 1.51 0.9 146.0 1.55 2.23 1.9 35.70.21 0.32 0.3 41.9 0.31 0.53 0.4 52.00.43 2.09 1.3 132.2 2.47 3.39 2.9 31.6234Compound Unit1-Undecene pptUndecane pptNonanal ppt1-2-4-5-Tetramethylbenzene pptCamphor pptDodecane pptNaphthalene pptDecanal pptBenzothiazole pptTridecane ppt2-Methylnaphthalene pptTetradecane pptCaryophyllene pptAcenaphthylene pptPentadecane pptHexadecane pptHeptadecane pptPristane pptOctadecane pptPhytane ppt00760840.D 00760886.D 00760794.D 00760890.DOriginal Duplicate Original DuplicateB.10 AGI Hydrocarbon Duplicates - MPD (%)Mean MPD (%) Mean MPD (%)9.28 18.46 13.9 66.2 16.79 49.99 33.4 99.411.06 27.08 19.1 84.0 39.99 65.24 52.6 48.036.23 219.61 127.9 143.4 293.07 203.22 248.1 36.20.57 1.36 1.0 82.4 1.60 2.84 2.2 55.80.38 0.71 0.5 59.4 0.84 1.11 1.0 27.95.01 27.10 16.1 137.6 41.52 56.59 49.1 30.71.69 4.15 2.9 84.3 5.52 9.55 7.5 53.423.91 39.60 31.8 49.4 72.70 45.49 59.1 46.11.32 0.65 1.0 67.1 1.49 3.18 2.3 72.38.67 28.65 18.7 107.1 46.16 74.30 60.2 46.70.69 1.53 1.1 75.2 2.64 4.67 3.7 55.87.63 34.05 20.8 126.7 50.36 88.86 69.6 55.39.18 2.10 5.6 125.6 4.82 6.92 5.9 35.90.11 0.15 0.1 35.2 0.35 0.72 0.5 67.617.01 64.52 40.8 116.5 86.38 130.23 108.3 40.54.91 25.81 15.4 136.1 77.84 83.57 80.7 7.111.68 16.14 13.9 32.0 37.97 49.27 43.6 25.94.32 17.19 10.8 119.6 30.74 44.23 37.5 36.02.55 11.10 6.8 125.3 38.19 40.02 39.1 4.75.16 10.78 8.0 70.6 23.28 27.76 25.5 17.6235Compound UnitCarbon Dioxide pptCarbonyl Sulfide pptDimethyl Sulfide pptDimethyl Disulfide pptEthene/Ethane pptEthane pptPropene pptPropane ppt1-Butene pptButane ppt2-Methylbutane ppt1-Pentene pptPentane pptFuran pptCarbon Disulfide pptCyclopentane ppt2-Methylpentane ppt3-Methylpentane ppt1-Hexene pptHexane ppt2-Methylfuran pptMethylcyclopentane ppt2-4-Dimethylpentane pptCyclohexane pptBenzene ppt2-Methylhexane ppt3-Methylhexane pptcis-1-3-Dimethylcyclopentane ppttrans-1-3-Dimethylcyclopentane ppttrans-1-2-Dimethylcyclopentane ppt1-Heptene pptHeptane pptMethylcyclohexane ppt00760743.D 00760882.D 00760776.D 00760780.DOriginal Duplicate Original Duplicate5388131 4854956.001 5121543.5 10.4 5148109 4753363.003 4950736.0 8.045.72 40 42.6 14.6 41.98 53 47.3 22.62.09 1.21 1.7 53.6 0.43 1.19 0.8 94.219.78 1.50 10.6 171.9 0.80 0.02 0.4 190.517.50 21.83 19.7 22.0 16.49 21.81 19.2 27.840.32 38.15 39.2 5.5 37.02 43.80 40.4 16.844.43 90.37 67.4 68.2 50.13 84.94 67.5 51.635.32 52.44 43.9 39.0 55.53 70.21 62.9 23.4251.59 412.98 332.3 48.6 229.75 274.08 251.9 17.6364.18 433.43 398.8 17.4 239.36 223.34 231.4 6.92935.55 3982.17 3458.9 30.3 2504.40 2858.32 2681.4 13.2354.81 1097.47 726.1 102.3 28.15 23.56 25.9 17.81009.51 3155.63 2082.6 103.1 1027.10 930.45 978.8 9.977.53 165.50 121.5 72.4 100.58 84.24 92.4 17.7306.63 727.10 516.9 81.4 415.18 391.84 403.5 5.85316.68 5737.32 5527.0 7.6 4132.61 6538.99 5335.8 45.1384.09 991.17 687.6 88.3 2946.94 428.54 1687.7 149.27.79 14.81 11.3 62.1 3.23 9.98 6.6 102.23.60 10.00 6.8 94.1 4.52 5.15 4.8 13.113.53 39.52 26.5 98.0 14.42 20.13 17.3 33.01.27 2.44 1.9 63.0 1.44 1.14 1.3 23.712.07 27.96 20.0 79.4 17.65 15.69 16.7 11.82.36 3.27 2.8 32.5 4.90 1.78 3.3 93.516.55 35.45 26.0 72.7 19.77 19.02 19.4 3.91.62 3.04 2.3 60.8 1.47 1.50 1.5 2.21.25 2.93 2.1 80.7 1.39 1.28 1.3 7.62.01 5.53 3.8 93.3 2.93 2.43 2.7 18.60.44 0.58 0.5 26.2 0.25 0.46 0.4 57.80.67 1.23 0.9 59.3 0.62 0.82 0.7 27.70.92 1.66 1.3 57.3 1.36 0.94 1.1 36.70.80 1.76 1.3 74.7 15.35 1.98 8.7 154.32.24 4.70 3.5 71.0 3.63 2.25 2.9 46.93.27 7.49 5.4 78.4 4.12 3.57 3.8 14.2B.10 AGI Hydrocarbon Duplicates - MPD (%)Mean MPD (%)Mean MPD (%)236Compound Unit2-5-Dimethylhexane pptToluene ppt3-Methylheptane pptcis-1-3/1-4-Dimethylcyclohexane ppt1-Octene pptCycloheptane pptcis-1-2-Dimethylcyclohexane pptOctane ppttrans-1-3/1-4-Dimethylcyclohexane ppt2-6-Dimethylheptane ppttrans-1-2-Dimethylcyclohexane pptEthylcyclohexane pptEthylbenzene pptm-p-Xylene ppt1-Nonene ppto-Xylene pptNonane pptCyclooctane pptPropylcyclohexane pptalpha-Pinene pptPropylbenzene ppt1-Ethyl-2/3-methylbenzene ppt1-3-5-Trimethylbenzene pptbeta-Pinene ppt1-Ethyl-4-methylbenzene ppt1-Decene pptDecane ppt1-2-4-Trimethylbenzene pptOctanal pptBenzofuran pptIndane pptIndene pptButylbenzene ppt00760743.D 00760882.D 00760776.D 00760780.DOriginal Duplicate Original DuplicateB.10 AGI Hydrocarbon Duplicates - MPD (%)Mean MPD (%)Mean MPD (%)0.58 1.30 0.9 76.0 0.74 1.12 0.9 41.013.77 37.35 25.6 92.2 22.59 16.59 19.6 30.60.64 1.09 0.9 51.5 0.86 0.54 0.7 45.51.68 3.02 2.4 57.4 3.69 3.65 3.7 1.03.04 6.70 4.9 75.1 1.69 1.39 1.5 19.40.09 0.20 0.1 76.2 0.00 0.00 0.0 18.30.09 0.52 0.3 140.3 0.30 0.00 0.2 198.11.82 6.09 4.0 107.9 3.37 1.70 2.5 65.61.89 0.59 1.2 104.8 0.33 0.27 0.3 21.40.33 0.46 0.4 33.0 0.50 0.45 0.5 10.50.71 1.50 1.1 71.3 0.73 0.54 0.6 31.00.58 1.10 0.8 61.5 1.05 0.60 0.8 54.71.27 3.59 2.4 95.5 2.60 1.37 2.0 62.33.11 7.69 5.4 84.7 5.70 2.53 4.1 77.21.10 2.32 1.7 71.3 3.00 0.97 2.0 101.91.42 3.73 2.6 89.5 2.95 1.28 2.1 78.71.41 6.09 3.8 124.7 4.85 2.34 3.6 69.80.79 3.47 2.1 125.5 3.66 0.82 2.2 126.40.36 1.07 0.7 100.6 0.85 0.37 0.6 79.51.54 5.00 3.3 105.8 2.47 1.58 2.0 43.80.43 1.54 1.0 113.3 1.29 0.39 0.8 106.50.80 4.74 2.8 142.2 3.91 0.82 2.4 130.52.39 2.89 2.6 18.7 2.39 0.88 1.6 92.10.53 2.82 1.7 136.4 1.65 0.43 1.0 116.90.51 1.74 1.1 108.9 1.44 0.40 0.9 113.710.25 48.90 29.6 130.7 49.72 12.34 31.0 120.54.42 25.84 15.1 141.6 23.11 5.62 14.4 121.71.01 5.33 3.2 136.3 4.56 0.97 2.8 130.018.83 88.85 53.8 130.1 93.83 40.58 67.2 79.20.01 0.23 0.1 180.7 0.16 0.03 0.1 140.90.14 1.07 0.6 155.0 0.85 0.22 0.5 116.80.12 0.35 0.2 100.2 0.29 0.15 0.2 66.40.54 3.16 1.8 141.7 3.47 0.67 2.1 134.8237Compound Unit1-Undecene pptUndecane pptNonanal ppt1-2-4-5-Tetramethylbenzene pptCamphor pptDodecane pptNaphthalene pptDecanal pptBenzothiazole pptTridecane ppt2-Methylnaphthalene pptTetradecane pptCaryophyllene pptAcenaphthylene pptPentadecane pptHexadecane pptHeptadecane pptPristane pptOctadecane pptPhytane ppt00760743.D 00760882.D 00760776.D 00760780.DOriginal Duplicate Original DuplicateB.10 AGI Hydrocarbon Duplicates - MPD (%)Mean MPD (%)Mean MPD (%)3.35 9.40 6.4 94.9 145.65 6.05 75.8 184.111.14 49.62 30.4 126.7 55.42 23.70 39.6 80.2100.25 598.14 349.2 142.6 541.78 172.21 357.0 103.50.25 1.50 0.9 141.8 1.39 0.48 0.9 97.80.27 0.96 0.6 112.3 0.86 0.92 0.9 6.213.36 73.98 43.7 138.8 47.73 27.46 37.6 53.91.48 4.85 3.2 106.3 4.54 2.77 3.7 48.326.79 116.79 71.8 125.4 173.84 145.75 159.8 17.60.73 1.55 1.1 72.4 2.56 1.23 1.9 70.425.77 83.53 54.6 105.7 144.70 57.44 101.1 86.30.77 2.58 1.7 108.0 2.23 1.45 1.8 42.444.92 160.96 102.9 112.7 44.69 112.44 78.6 86.28.40 7.20 7.8 15.4 6.85 3.21 5.0 72.40.22 0.52 0.4 81.0 0.43 0.58 0.5 30.354.10 180.71 117.4 107.8 96.29 139.11 117.7 36.432.31 295.85 164.1 160.6 40.51 179.49 110.0 126.311.97 114.67 63.3 162.2 17.55 92.37 55.0 136.113.58 76.52 45.1 139.7 10.99 46.40 28.7 123.410.61 132.23 71.4 170.3 37.33 74.32 55.8 66.38.60 59.72 34.2 149.6 22.41 27.81 25.1 21.5238239 Appendix C: Raw Surficial Data This section comprises raw surficial data, collected in-situ or at the surface within the research site. These data sets include:  C.1. Sample ID, site number, coordinates, and sample type  C.2. Sampled material, surficial material classification, physicochemical measurements, and vegetation, soil profile images  C.3. Spontaneous potential (SP) raw data For Appendix C.2, note that the Of soil horizon is excluded, with the exception of sites at which it was the only observable soil horizon, as physicochemical measurements were not taken within it. Where the Bm horizon was not present, measurements and samples were taken from Om, BCy, Cgy, or Cg horizons instead. In-situ pH measurements taken with the Bluelab Soil pH pen proved unreliable due to instrument drift, as per Figure B.1. Sites at which samples were not collected include site 55 and site 72. ‘Sampled material’ refers to the distribution of sampled material as per Figure 4.3, and ‘Surficial material’ refers to the distribution of surficial material as per Figure 4.4. 240 Figure B.1. The Bluelab Soil pH pen exhibited instrument drift within the a) Bm Horizon and b) Om horizon. As the pH pen was replaced approximately halfway through the sampling campaign, readings given by the first pH pen are given in blue, and readings given by the second pH pen are given in orange. C.1 Sample Type and CoordinatesSoil Sample ID Sample Site Type AGI Vial X Actual Y Actual Z ActualQ515501 26 Soil 00760846 557291 7134488 423Q515502 27 Soil 00760773 557339 7134480 427Q515503 28 Soil 00760825 557392 7134473 428Q515504 29 Soil 00760778 557448 7134469 425Q515505 30 Soil 00760791 557490 7134455 427Q515506 31 Soil 00760871 557537 7134443 426Q515507 125 Soil 00760837 557497 7134817 437Q515508 124 Soil 00760897 557451 7134825 438Q515509 123 Soil 00760868 557396 7134838 438Q515510 122 Soil 00760793 557349 7134845 438Q515511 121 Soil 00760770 557292 7134854 436Q515512 120 Soil 00760720 557253 7134859 436Q515513 119 Soil 00760809 557196 7134861 435Q515514 118 Soil 00760865 557156 7134879 435Q515515 117 Soil 00760768 557102 7134884 435Q515516 116 Soil 00760741 557056 7134898 435Q515516a N/A CRMQ515517 14 Soil 00760802 557484 7134395 425Q515518 15 Soil 00760717 557540 7134386 428Q515519 13 Soil 00760831 557438 7134397 424Q515520 12 Soil 00760836 557386 7134413 423Q515521 11 Soil 00760753 557328 7134423 420Q515522 10 Soil 00760730 557285 7134431 420Q515523 9 Soil 00760847 557236 7134441 417Q515524 8 Soil 00760829 557187 7134449 418Q515525 7 Soil 00760754 557136 7134456 418Q515526 115 Soil 00760811 557007 7134908 436Q515527 114 Soil 00760748 556955 7134912 435Q515528 113 Soil 00760766 556910 7134922 434Q515529 112 Soil 00760903 556870 7134914 433Q515530 6 Soil 00760783 557089 7134460 419Q515531 5 Soil 00760884 557043 7134468 421Q515551 77 Soil 00760805 557474 7134641 431Q515551a N/A CRMQ515552 78 Soil 00760880 557523 7134635 431Q515553 79 Soil 00760760 557571 7134628 429Q515554 95 Soil 00760796 557573 7134685 428Q515555 94 Soil 00760764 557529 7134675 427Q515556 93 Soil 00760733 557476 7134668 427Q515557 92 Soil 00760843 557433 7134726 432Q515558 91 Soil 00760816 557386 7134711 429Q515559 90 Soil 00760861 557329 7134719 428Q515560 89 Soil 00760718 557280 7134734 426Q515561 88 Soil 00760893 557234 7134744 424Q515562 87 Soil 00760747 557194 7134756 424UTM NAD 83 Zone 12N241C.1 Sample Type and CoordinatesSoil Sample ID Sample Site Type AGI Vial X Actual Y Actual Z ActualUTM NAD 83 Zone 12NQ515563 86 Soil 00760801 557123 7134760 423Q515564 85 Soil 00760902 557075 7134770 424Q515565 84 Soil 00760740 557034 7134773 423Q515566 83 Soil 00760845 556987 7134783 424Q515567 82 Soil 00760910 556933 7134793 424Q515568 81 Soil 00760758 556887 7134796 426Q515569 80 Soil 00760873 556839 7134806 428Q515570 96 Soil 00760859 556842 7134867 431Q515571 97 Soil 00760881 556898 7134863 431Q515572 98 Soil 00760808 556946 7134852 432Q515573 99 Soil 00760866 557001 7134842 432Q515574 100 Soil 00760813 557066 7134840 431Q515575 101 Soil 00760737 557099 7134828 430Q515576 102 Soil 00760765 557147 7134813 431Q515577 103 Soil 00760728 557199 7134810 428Q515578 104 Soil 00760830 557247 7134809 429Q515579 105 Soil 00760810 557297 7134797 430Q515580 106 Soil 00760895 557348 7134792 437Q515581 107 Soil 00760755 557393 7134776 438Q515582 108 Soil 00760743 557444 7134763 436Q515583 108b Duplicate 00760882 557444 7134763 436Q515583a CRMQ515584 109 Soil 00760842 557495 7134766 435Q515585 110 Soil 00760889 557539 7134745 433Q515586 111 Soil 00760867 557596 7134741 432Q515587 127 Soil 00760782 557604 7134805 435Q515588 126 Soil 00760776 557546 7134811 436Q515589 126b Duplicate 00760780 557546 7134811 436Q515590 16 Soil 00760815 556804 7134579 425Q515591 17 Soil 00760906 556840 7134563 425Q515592 18 Soil 00760785 556891 7134553 426Q515593 18b Duplicate 00760752 556895 7134553 426Q515594 19 Soil 00760823 556947 7134549 424Q515595 20 Soil 00760888 556991 7134533 422Q515596 21 Soil 00760792 557043 7134528 421Q515597 22 Soil 00760756 557092 7134519 419Q515598 23 Soil 00760744 557141 7134516 419Q515599 24 Soil 00760759 557194 7134505 421Q515599a N/A CRMQ515600 25 Soil 00760905 557248 7134499 423Q515651 32 Soil 00760874 556811 7134636 425Q515652 33 Soil 00760839 556861 7134626 424Q515653 34 Soil 00760803 556913 7134616 422Q515654 35 Soil 00760856 556964 7134604 422Q515655 35b Duplicate 00760812 556966 7134604 422242C.1 Sample Type and CoordinatesSoil Sample ID Sample Site Type AGI Vial X Actual Y Actual Z ActualUTM NAD 83 Zone 12NQ515657 36 Soil 00760838 557008 7134591 420Q515658 37 Soil 00760901 557056 7134591 422Q515659 38 Soil 00760834 557108 7134589 420Q515660 39 Soil 00760826 557159 7134583 419Q515661 40 Soil 00760721 557207 7134565 422Q515662 41 Soil 00760806 557252 7134559 423Q515663 42 Soil 00760883 557305 7134549 425Q515664 43 Soil 00760749 557356 7134543 426Q515665 44 Soil 00760876 557404 7134531 428Q515666 45 Soil 00760862 557469 7134514 426Q515666a N/A CRMQ515667 46 Soil 00760781 557498 7134517 426Q515667a N/A CRMQ515668 47 Soil 00760775 557553 7134507 425Q515669 63 Soil 00760788 557560 7134570 427Q515670 62 Soil 00760738 557507 7134570 425Q515671 61 Soil 00760735 557460 7134585 426Q515672 60 Soil 00760795 557405 7134597 426Q515673 59 Soil 00760818 557363 7134560 425Q515674 58 Soil 00760745 557312 7134609 424Q515675 57 Soil 00760907 557273 7134617 421Q515676 56 Soil 00760789 557217 7134617 419N/A 55 N/A 00760855 557167 7134622 457Q515678 54 Soil 00760840 557109 7134641 451Q515679 54b Duplicate 00760886 557108 7134640 451Q515680 53 Soil 00760800 557060 7134647 447Q515681 52 Soil 00760898 557006 7134657 442Q515682 51 Soil 00760767 556960 7134660 441Q515683 50 Soil 00760729 556924 7134679 439Q515683a N/A CRMQ515685 49 Soil 00760832 556863 7134682 439Q515686 48 Soil 00760824 556817 7134689 437Q515687 64 Soil 00760885 556826 7134751 440Q515688 65 Soil 00760736 556881 7134742 436Q515689 66 Soil 00760817 556932 7134726 433Q515690 67 Soil 00760734 556985 7134724 436Q515691 68 Soil 00760784 557036 7134716 433Q515692 69 Soil 00760833 557080 7134720 428Q515693 70 Soil 00760790 557141 7134704 427Q515694 71 N/A 00760887 557180 7134689 428Q515695 72 Soil 00760794 557229 7134689 426Q515696 72b Duplicate 00760890 557229 7134689 426Q515697 73 Soil 00760771 557279 7134679 429Q515698 74 Soil 00760731 557325 7134669 429Q515699 75 Soil 00760892 557375 7134659 432243C.1 Sample Type and CoordinatesSoil Sample ID Sample Site Type AGI Vial X Actual Y Actual Z ActualUTM NAD 83 Zone 12NQ515700 76 Soil 00760820 557424 7134651 431Q515700a CRM CRMN/A 128 00760875 556871 7134988 436N/A 129 00760742 556919 7134972 435N/A 130 00760835 556968 7134969 435N/A 131 00760899 557016 7134966 436N/A 132 00760896 557067 7134954 438N/A 133 00760719 557120 7134942 437N/A 134 00760844 557167 7134936 435N/A 135 00760798 557215 7134926 436N/A 136 00760804 557266 7134922 437N/A 137 00760762 557321 7134911 438N/A 138 00760787 557372 7134902 439N/A 139 00760860 557416 7134893 440N/A 140 00760732 557464 7134892 439N/A 141 00760746 557511 7134882 438N/A 142 00760819 557565 7134871 438N/A 143 00760821 557616 7134870 438244SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q5155017134488423 5572912 26Diamict30Tb104.60.04 0.000.0Rusty brownSand matrixEquant, prolate4.3 4.62655.63.213495Pebble to boulder sized clastsDominantly graniticThick shrubsNone.Soil Classification: HE.SC2None5Equant, prolatePebble to boulder sized clastsDominantly graniticThick shrubsAe mottled with B. Diamict sampled below GLv sediments. Soil Classification: HE.SCQ515502713448042755733927Diamict41GLv/Tb105.90.03 0.000.0Rusty brown3.3 4.42735.63.013482180.000.04.4None5Om Bm Om Ae BmSand matrixBm Horizon: Bm Horizon:245SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q5155037134473428 5573922 28Diamict30GLv/Tb100.00.00 0.000.0Rusty brownSand matrixEquant, prolate4.4 4.22945.43.511260Pebble sized clasts, abundantDominantly graniticThick shrubsDiamict sampled below GLv sediments. Soil Classification: HE.SC2None7N/AN/AN/AThin shrubsPermafrost concealed horizons below, measurements and sample taken from Om horizon instead.Soil Classification: HE.SCQ515504713446942555744829Organics43O4.30.05Black brownPeat4.12655.34.525137Yes10Ah Bm OmBm Horizon: Om Horizon:246SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q5155057134455427 5574902 30Diamict38GLv/Tb305.10.04 0.000.0BrownSand matrixEquant4.1 4.33145.33.615221Few, pebble sized clastsDominantly graniticThin shrubsDiamict sampled below GLv sediments. Soil Classification: HE.SC2Yes9EquantFew, pebble sized clastsDominantly graniticMoss and lichen with lesser grass and shrubsSample and measurements taken from Cg horizon. Diamict sampled below GLv sediments. Soil Classification: HE.SCQ515506713444342655753731Diamict32GLv/Tb51.90.01 0.000.0Grey brownSand-rich clay matrix4.0 4.21236.24.013198None3Om Bm Om CgBm Horizon: Cg Horizon:247SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51550771348174375574978 125Diamict35Tb30.00.00 0.000.0Light grey brownSand matrixEquant4.0 4.62265.93.116357Few, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNoneSoil Classification: BE.TC8None1EquantFew, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNoneSoil Classification: BE.TCQ5155087134825438557451124Diamict37Tb4.50.00.00 0.000.0Light brownSand matrix3.6 3.82286.03.41323270.000.04.8None2Om Cgy OmCgy Horizon: Bm Horizon:Ah Bm248SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q5155097134838438 5573968 123Diamict37Tb53.10.02 0.000.0Light brownSand matrixEquant4.5 4.72306.23.19210Few, pebble sized clastsDominantly graniticMoss and lichen with lesser shrubsNoneSoil Classification: BE.TC8None1EquantAbundant, pebble sized clasts with bouldersDominantly graniticMoss and lichen with lesser shrubsAe mottled with Bm from 4-8 cm depth.Soil Classification: BE.TCQ5155107134845438557349122Diamict32Tb40.00.00 0.000.0Rusty brownSand matrix3.8 4.42455.63.41121180.000.04.4None2Om Bm Om AeBm Horizon: Bm Horizon:Bm249SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51551171348544365572928 121Diamict35Tb40.00.00 0.000.0BrownSand matrixEquant4.9 5.82436.03.28213130.000.04.7Abundant, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsAe mottled with Bm from 4-13 cm.Soil Classification: BE.TC8None2EquantAbundant, pebble sized clasts with boulders.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TCQ5155127134859436557253120Diamict45Tb70.00.02 0.00 0.000.0 0.032Rusty brownSand matrix4.1 4.6 4.72335.63.410207100.000.04.7None2Om Ae OmBm Horizon: Bm Horizon:Ae BmBm Cgy250SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51551371348614355571968 119Diamict42Tb94.20.01 0.02 0.002.7 0.032Rusty brownSand matrixEquant3.6 3.7 4.42665.53.58180110.000.04.1Abundant, pebble sized clasts with boulders.Dominantly graniticMoss and lichen with lesser grass and shrubsDense, compacted O horizons.Soil Classification: BE.TC8None6EquantFew, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TCQ5155147134879435557156118Diamict34Tb40.70.00 0.00 0.000.0 0.030Rusty brownSand matrix3.7 4.1 4.52705.73.5720170.000.04.5None2Om Om2 Om AeBm Horizon: Bm Horizon:BmAe Cgy140.000.04.4Bm Cgy251SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51551571348844355571028 117Diamict33Tb60.00.02 0.00 0.000.0 0.030BrownSand matrixEquant3.8 4.1 4.72895.23.5252108.50.000.04.7Few, pebble sized clasts.Dominantly graniticMoss and lichen with shrubsNone.Soil Classification: BE.TC8None2EquantFew, pepple sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TCQ5155167134898435557056116Diamict35Tb50.00.00 0.000.0Rusty brownSand matrix4.3 4.52215.93.48307None3Om Ae OmBm Horizon: Bm Horizon:BmBm Cgy252SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51551771343954255574841 14Clay35GLv0.00.00Light brownClayN/A4.41845.73.4716360.000.04.5N/AN/AThin shrubsSwelling clay.Soil Classification: HE.SC1None3EquantFew, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TCQ515518713438642855754015Diamict40Tb54.90.03 0.000.0BrownFine sand matrix4.0 4.72455.63.218245None2Om Om BmBm Horizon: Bm Horizon:Bm130.000.04.5Cg253SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51551971343974245574381 13Diamict35GLv/Tb171.00.03 0.000.0Rusty brownFine sand matrixEquant4.5 4.52725.43.712157Few, pebble sized clasts.Dominantly graniticThick shrubsDiamict sampled below GLv sediments. Soil Classification: HE.SC1None10EquantAbundant, pepple sized clasts with boulders.Dominantly graniticThick shrubsPossible dormant stream bed. Diamict sampled below GLv sedi-ments. Soil Classification: HE.SCQ515520713441342355738612Diamict33GLv/Tb107.20.03 0.020.5Rusty brownSand matrix4.8 4.63045.24.319133130.000.04.5None7Om Bm OmBm Horizon: Bm Horizon:Ah Bm254SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51552171344234205573281 11Diamict26GLv/Tb1.30.02Light brownSand matrixEquant3.72795.23.510222100.000.04.0Few, pebble sized clasts.Dominantly graniticThick shrubs and grassDiamict sampled below GLv sediments. Soil Classification: HE.SC1None4EquantFew, pebble sized clasts.Dominantly graniticThick shrubs and grassNone.Soil Classification: HE.SCQ515522713443142055728510Diamict35Tb50.00.00 0.000.0Rusty brownSand matrix4.4 4.92355.83.38200None3Om Om BmBm Horizon: Bm Horizon:Bm255SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51552371344414175572361 9Sand34GFp30.00.01 0.000.0Rusty brownSandN/A4.4 4.62485.63.38170N/AN/AThin shrubs and grass with lesser moss and lichenNone.Soil Classification: HE.SC1None1N/AN/AN/AThin shrubs and grass with lesser moss and lichenNone.Soil Classification: HE.SCQ51552471344494185571878Sand33GFp95.60.03 0.000.0Rusty brownSand3.6 4.52685.33.525195None2.5Om Bm OmBm Horizon: Bm Horizon:Bm256SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51552571344564185571361 7Sand32GFp0.00.01 0.000.018.5Rusty brownSandN/A4.6 4.72795.93.272183.50.000.04.8N/AN/AThin shrubs and grassPortion of Cg horizon observed within the Bm horizon likely due to cryoturbation.Soil Classification: HE.SC8None2EquantFew, pebble sized clasts.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TCQ5155267134908436557007115Diamict38Tb6.50.00.00 0.000.0Light brownSand matrix4.4 4.82795.23.621260None2Om Om BmBm Horizon: Bm Horizon:Bm Bm80.000.04.7Cg257SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51552771349124355569558 114Diamict36Tb60.00.00 0.000.0BrownSand matrixEquant4.3 4.52625.53.612253Few, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsEluviated patches in Bm horizon.Soil Classification: BE.TC8None2EquantFew, pebble sized clasts with bouldersDominantly graniticThin shrubs and grassNone.Soil Classification: BE.TCQ5155287134922434556910113Diamict31Tb63.70.02 0.010.0Light brownSand matrix4.5 4.22985.33.11028990.010.04.2None2Om Bm OmBm Horizon: Bm Horizon:Ah Bm258SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51552971349144335568708 112Diamict38Tb8.30.09Rusty brownSand matrixEquant5.62566.23.91318460.000.04.7Few, pebble sized clasts with bouldersDominantly graniticThin shrubsNone.Soil Classification: BE.TC1None2N/AN/AN/AHummocky grasslandSample taken from O horizon as remaining horizons are concealed by permafrost.Soil Classification: HE.SCQ51553071344604195570896Organics46O3.50.03Black brownPeat4.62155.24.016101Yes35Om OmBm Horizon Om Horizon:Bm120.000.04.7Cgy259SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51553171344684215570431 5Sand52GFp84.10.02 0.000.0BrownCoarse sandN/A4.6 4.62895.43.8787410.000.04.5N/AN/AHummocky grasslandGleyed horizons.Soil Classification: HE.SC5None2N/AN/AN/AHummocky grasslandClay layer from 5-10cm depth. Sample taken from O horizon as remaining horizons are concealed by permafrost.Soil Classification: HE.SCQ515551713464143155747477Organics35O108.20.01 0.036.3Black brownPeat3.3 3.63044.74.522189Yes5Om Om2 OmBm Horizon: Om2 Horizon:Om2Bm260SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51555271346354315575235 78Organics40O5.90.04Black brownPeatN/A2.92695.14.119208250.024.63.0N/AN/AHummocky grasslandSample taken from O horizon as remaining horizons are concealed by permafrost.Soil Classification: HE.SC5Yes6N/AN/AN/AHummocky grasslandSample taken from O horizon as remaining horizons are concealed by permafrost.Soil Classification: HE.SCQ515553713462842955757179Organics33O95.50.02 0.023.5Black brownPeat2.5 2.73264.74.027153130.023.32.8Yes7Om Om Om2Om2 Horizon: Om3 Horizon:Om3Om2261SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51555471346854285575736 95Sand48GFp356.10.02 0.000.0BrownSandN/A2.3 2.42525.43.912167N/AN/AHummocky grasslandPermafrost at 48cm. Gelisol.Soil Classification: HE.SC6Yes13Equant, prolateAbundant, pebble sized clasts.Dominantly graniticHummocky grasslandNone.Soil Classification: HE.SCQ515555713467542755752994Diamict40Tb267.80.05 0.000.0Greenish brownSand matrix2.8 2.82775.63.416255None10Om Bm OmBm Horizon: Cg Horizon:Cg262SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51555671346684275574766 93Diamict36Tb0.00.00BrownSand matrixEquant, prolate3.01836.44.312163Abundant, pebble to cobble sized clasts.Dominantly graniticMoss and lichenGelisol.Soil Classification: BE.TC6None8EquantAbundant, pebble sized clasts.Dominantly graniticMoss and lichenAe mottled with Bm. Soil Classification: BE.TCQ515557713472643255743392Diamict39Tb80.00.00 0.000.0Rusty brownSand matrix3.3 3.62265.83.69199120.000.03.0None2Bm Om AeBm Horizon: Bm Horizon:Bm263SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51555871347114295573866 91Diamict34Tb50.00.00 0.00 0.000.0 0.022Rusty brownSand matrixEquant2.9 3.7 3.52565.94.21019070.000.03.5Abundant, pebble sized clasts.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TC6None3Equant, prolateAbundant, pebble sized clasts and boulders.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TCQ515559713471942855732990Diamict40Tb5.50.00.00 0.00 0.000.0 0.018Rusty brownSand matrix4.4 4.6 4.72365.53.325275130.000.04.7None3Om Ae OmBm Horizon: Bm Horizon:AeBm Cgy Bm Cgy264SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51556071347344265572806 89Diamict40Tb8.80.04Rusty brownSand matrixEquant, prolate3.82615.63.62224570.000.03.9Abundant, pebble to cobble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TC6None5EquantAbundant, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsSwelling clay.Soil Classification: BE.TCQ515561713474442455723488Diamict40Tb77.60.06 0.000.0Rusty brownSand-rich clay matrix3.7 3.92735.63.51726890.000.04.0None4.5Om Om AeBm Horizon: Bm Horizon:BmAe90.000.04.1Bm265SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51556271347564245571946 87Diamict40Tb80.00.00 0.000.0BrownCoarse sand matrixEquant3.6 3.52705.13.230435130.000.04.0Abundant, pebble and cobble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsGravel layers at 16-20cm, and 30-35cm. Soil Classification: BE.TC6None5Equant, prolateAbundant, pebbles, cobble-sized clasts and boulders.Dominantly graniticMoss and lichen with lesser shrubs.At 1-15cm depth is cobble layer, 10-24cm depth is boulder layer. Soil Classification: BE.TCQ515563713476042355712386Diamict50Tb104.90.05 0.000.0BrownSand-rich clay matrix3.9 4.21816.04.113146None6Om Ae OmBm Horizon: Bm Horizon:BmBm266SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51556471347704245570756 85Diamict40Tb0.00.00Rusty brownSand matrixEquant, prolate4.42396.13.21352450.000.04.4Abundant, pebble to cobble sized clasts.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TC6None2EquantFew, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubs and grassNone.Soil Classification: BE.TCQ515565713477342355703484Diamict36Tb110.00.00 0.000.0BrownSand matrix4.1 4.32486.13.69202160.000.04.2None7Om Om AeBm Horizon: Bm Horizon:BmAe7.50.000.04.0Bm267SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51556671347834245569876 83Diamict40Tb6.50.00.00 0.000.0Rusty brownSand-rich clay matrixEquant, prolate4.1 4.22376.24.017157Abundant, pebble and cobble sized clasts.Dominantly graniticThin shrubs with grassSwelling clay.Soil Classification: BE.TC6None3Equant, prolateFew, pebble sized clastsDominantly graniticThin shrubsMottling of Om within Bm horizon.Soil Classification: BE.TCQ515567713479342455693382Diamict37Tb80.00.00 0.000.0Rusty brownFine sandy matrix4.3 4.52845.73.320278None4Om Bm OmBm Horizon: Bm Horizon:Bm268SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51556871347964265568876 81Diamict37Tb0.00.00Rusty brownSand-rich clay matrixEquant, prolate4.62396.43.612247Few, pebble sized clasts.Dominantly graniticThin shrubsMottling within Bm horizon.Soil Classification: BE.TC6None2.5EquantFew, pebble sized clasts.Dominantly graniticThick shrubsNone.Soil Classification: BE.TCQ515569713480642855683980Diamict37Tb250.00.00 0.000.0Rusty brownSand matrix4.5 6.22496.13.315288None2.5Bm Bm BCyBm Horizon: Bm Horizon:269SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51557071348674315568427 96Diamict35Tb100.70.01 0.000.0Rusty brownClay-rich sand matrixEquant, prolate4.7 4.52426.63.416269150.000.0Abundant, pebble sized clasts.Dominantly graniticThick shrubsMottling within Bm horizon.Soil Classification: BE.TC7None6Equant, prolateAbundant, pebble sized clastsDominantly graniticThick shrubs with moss and lichenMottling within Bm horizon.Soil Classification: BE.TCQ515571713486343155689897Diamict36Tb97.60.06 0.000.0BrownSand matrix3.7 4.42636.53.411433None4Om Bm OmBm Horizon: Bm Horizon:BmBCy270SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51557271348524325569467 98Diamict42Tb2.70.00Rusty brownSand matrixEquant, prolate4.22366.23.21138260.000.04.9Abundant, pebble sized clasts.Dominantly graniticMoss and lichenMottling of Om and Ae within Bm horizon.Soil Classification: BE.TC7None2EquantAbundant, pebble sized clasts.Dominantly graniticMoss and lichenOriginal site was on slope, site moved to above coordinates.Soil Classification: BE.TCQ515573713486143255701799Diamict39Tb60.00.00 0.000.0BrownSand matrix4.5 4.62326.53.29363None2Om Om BmBm Horizon: Bm Horizon:Ae120.000.04.6Bm271SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51557471348404315570667 100Diamict35Tb70.00.00 0.000.0BrownSand matrixEquant, prolate3.9 4.72536.43.510301Few, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TC7None4Equant, prolateAbundant, pebble to boulder sized clastsDominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TCQ5155757134828430557099101Diamict40Tb165.20.02 0.000.0BrownSand matrix3.6 3.92935.83.111354None4Om Bm OmBm Horizon: Bm Horizon:Bm272SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51557671348134315571477 102Diamict37Tb0.00.00Rusty brownSand matrixEquant, prolate3.92676.24.0931870.000.04.4Abundant, pebble to cobble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TC7None2EquantAbundant, pebble sized clasts.Dominantly graniticMoss and lichen with grassSwelling clay.Soil Classification: BE.TCQ5155777134810428557199103Diamict40Tb121.10.00 0.021.1BrownSand-rich clay matrix4.2 4.42695.24.424166None5Om Om BmBm Horizon: Bm Horizon:Bm273SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51557871348094295572477 104Diamict32Tb70.00.00 0.000.0BrownSand-rich clay matrixEquant, prolate4.3 4.62265.63.816168Abundant, pebble sized clasts.Dominantly graniticMoss and lichenGelisol. Hole quickly flooded after sampling. Soil Classification: BE.TC7None2Equant, prolateFew, pebble sized clasts.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TCQ5155797134797430557297105Diamict38Tb75.40.04 0.000.0Rusty brownSand matrix4.1 4.72475.63.413333None3Om Bm OmBm Horizon: Bm Horizon:Bm274SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51558071347924375573487 106Diamict38Tb0.00.00 0.000.019Rusty brownSand matrixEquant, prolate4.3 4.92386.04.0828260.000.04.8Few, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsMottling of Ae in Bm horizon.Soil Classification: BE.TC7None2EquantFew, pebble sized clasts.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TCQ5155817134776438557393107Diamict35Tb30.00.01 0.00 0.000.0 0.012BrownSand matrix4.4 4.5 4.72595.92.91340850.000.04.7None1.5Om Om AeBm Horizon Bm Horizon:BmAe Bm80.000.04.7Ah Cgy275SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51558271347634365574447 108Diamict36Tb20.00.01 0.00 0.000.0 0.012BrownSand matrixEquant, prolate4.5 4.9 5.02546.72.91656740.000.05.0Few, pebble sized clasts.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TC7None0.5Equant, prolateFew, pebble sized clasts.Dominantly graniticMoss and lichenDuplicate sample of Site 108 (Q515582).Soil Classification: BE.TCQ5155837134763436557444108bDiamict32Tb30.00.04 0.000.0BrownSand matrix4.6 5.02462.73.4957050.000.04.7None1Om Ah OmBm Horizon: BCy Horizon:AhBm Cgy BCy276SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51558471347664355574957 109Diamict40Tb0.00.00Rusty brownSand matrixEquant, prolate4.42466.02.99431160.000.04.4Abundant, pebble to cobble sized clasts.Dominantly graniticMoss and lichen with shrubsMottling in Bm horizon.Soil Classification: BE.TC7None6EquantAbundant, pebble sized clasts.Dominantly graniticMoss and lichenMottling in Bm horizon.Soil Classification: BE.TCQ5155857134745433557539110Diamict38Tb51.50.02 0.000.0BrownSand matrix4.0 4.32536.12.77607120.000.04.3None1.5Bm Om BmBm Horizon: Bm Horizon:CgyCgy277SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51558671347414325575967 111Diamict30Tb41.50.00 0.000.0BrownSand-rich clay matrixEquant, prolate4.1 4.52745.73.521266Abundant, pebble sized clasts.Dominantly graniticHummocky grassland with lesser shrubs, moss and lichenGelisol. Hole quickly flooded. Soil Classification: BE.TC8None1.5Equant, prolateAbundant, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TCQ5155877134805435557604127Diamict40Tb70.00.00 0.000.0BrownSand matrix4.0 4.52405.92.88440None2Om Bm OmBm Horizon: Bm Horizon:Bm278SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51558871348114365575468 126Diamict36Tb0.00.01BrownSand matrixEquant, prolate4.02596.22.894504.50.000.04.3Few, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TC8None2EquantAbundant, pebble sized clasts.Dominantly graniticMoss and lichenDuplicate of Site 126 (Q515588).Soil Classification: BE.TCQ5155897134811436557546126bDiamict30Tb54.30.01 0.00 0.000.0 0.018BrownSand matrix3.5 4.1 4.22706.02.8842790.000.04.2None2.5Om Om AeBm Horizon: Bm Horizon:BmBm110.000.04.3Cgy Cgy279SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51559071345794255568042 16Diamict30Tb5-0.04 0.00-BrownSand matrixEquant, prolate4.4 5.12475.63.729239Few, pebble sized clasts.Dominantly graniticMoss and lichenMoisture measurement not taken.Soil Classification: BE.TC2None1.5Equant, prolateAbundant, pebble to cobble sized clasts.Dominantly graniticMoss and lichenMoisture measurement not taken. Soil Classification: BE.TCQ515591713456342555684017Diamict34Tb5-0.00 0.00-Greyish brownSand matrix3.6 5.32366.12.920534None2Om Bm OmBm Horizon: BCy Horizon:BCy280SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51559271345534265568912 18Diamict40Tb-0.01BrownCoarse sand matrixEquant, prolate3.62575.93.0185583.00.00-3.7Abundant, pebble sized clasts with occasional boulders.Dominantly graniticMoss and lichenMottling of all horizons within Bm Horizon. Moisture measurement not taken. Soil Classification: BE.TC 2None1.5EquantAbundant, pebble sized clasts with occasional boulders.Dominantly graniticMoss and lichen with lesser shrubsMottling of all horizons within Bm horizon. Moisture measurement not taken. Duplicate of Site 18 (Q515592).Soil Classification: BE.TCQ515593713455342655689518bDiamict34Tb4-0.05 0.00-BrownCoarse sand matrix3.7 4.02535.94.91045560.00-4.3None1.5Om Om AhBm Horizon: Bm Horizon:BmAh50.00-4.1Bm281SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51559471345494245569472 19Diamict36Tb3-0.02 0.00-Rusty brownSand matrixEquant, prolate3.6 4.23015.52.9164985.50.00-4.2Abundant, pebble sized clasts with occasional boulders.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TC2None1Equant, prolateFew, pebble sized clasts.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TCQ515595713453342255699120Diamict40Tb6-0.04 0.00-Rusty brownSand matrix3.6 4.03005.63.21138980.00-4.2None2.5Om Ah OmBm Horizon: Bm Horizon:AeBm Bm282SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51559671345284215570432 21Sand44GFp-0.03BrownSandN/A4.52475.53.719255310.03-4.5N/AN/AHummocky grasslandHole quickly flooded.Soil Classification: HE.SC2Yes3N/AN/AN/AHummocky grasslandNone.Soil Classification: HE.SCQ515597713451941955709222Sand37GFp34-0.05 0.00-BrownClay-rich sand2.9 4.12775.54.013158Yes10Om Om BmBm Horizon: Bm Horizon:Om2420.00-4.3Bm283SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51559871345164195571412 23Sand50GFp49-0.05 0.00-BrownClay-rich sandN/A4.6 4.31975.84.114184N/AN/AHummocky grasslandNone.Soil Classification: HE.SC2Yes4N/AN/AN/AThin shrubs with moss and lichenNone.Soil Classification: HE.SCQ515599713450542155719424Sand40GFp5-0.02 0.00-Rusty brownClay-rich sand3.4 4.02475.63.02234680.00-4.1None3Om Bm OmBm Horizon: Bm Horizon:Ae Bm284SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51560071344994235572482 25Sand40GFp7.60.05Rusty brownSandN/A3.72605.33.7162155.50.000.04.0N/AN/AThin shrubs with moss and lichenNone.Soil Classification: HE.SC3None3EquantFew, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TCQ515651713463642555681132Diamict27Tb110.00.00 0.000.0Rusty brownSand matrix4.8 4.82756.74.331180None2Om Bm CgyBm Horizon: Bm Horizon:Ae80.000.04.1Bm285SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51565271342624245568613 33Diamict35Tb60.30.00 0.030.0Rusty brownSand matrixEquant, prolate4.9 4.92786.23.217571Few, pebble sized clasts.Dominantly graniticMoss and lichen with lesser shrubsNone.Soil Classification: BE.TC3None.4Equant, prolateFew, pebble sized clasts.Dominantly graniticMoss and lichenNone.Soil Classification: BE.TCQ515653713461642255691334Diamict40Tb60.00.02 0.020.0BrownSilt-rich sand matrix5.8 6.52786.23.913163None3Ah Bm AeBm Horizon: Bm Horizon:Bm286SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51565471346044225569643 35Sand30GFp7.30.04BrownSandN/A4.23105.63.719205100.077.24.6N/AN/AHummocky grasslandNone.Soil Classification: HE.SC3None6N/AN/AN/AHummocky grasslandDuplicate of Site 35 (Q515654).Soil Classification: HE.SCQ515655713460442255696635bDiamict40Tb122.70.03 0.050.6Rusty brownSand3.8 4.63045.83.71321713.50.010.05.1None7Om Om AeBm Horizon: Bm Horizon:BmAe110.051.25.1Bm287SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51565771345914205570083 36Organics35O147.30.06 --Black brownPeatN/A3.0 -2624.53.326-N/AN/AHummocky grassland (including cottongrass) and lesser shrubsOm horizon sampled. Measurement not taken for acidified TDS in Om horizon and no measurements not taken for Om2 horizon. Soil Classification: HE.SC3Yes5N/AN/AN/AHummocky grasslandNone.Soil Classification: HE.SCQ515658713459142255705637Sand39GFp270.00.00 0.000.0BrownSand2.9 3.53115.54.112110Yes23Om Om2 OmOm Horizon: Bm Horizon:Bm288SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51565971345894205571083 38Sand44GFp5.70.03BrownFine sandN/A3.42925.33.911127270.000.03.9N/AN/AHummocky grassland with shrubs.None.Soil Classification: HE.SC3None1N/AN/AN/AHummocky grasslandOnly horizon at this site is Of, with permafrost at the bottom of the hole. Soil Classification: HE.SCQ515660713458341955715939Organics46O8.10.05Black brownPeat3.42904.63.330288Yes0Om OfBm Horizon: Of Horizon:Bm289SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51566171345654225572073 40Organics39O7.40.04Black brownPeatN/A3.92734.84.229191N/AN/AHummocky grasslandOm horizon sampled. Soil Classification: HE.SC3Yes5N/AN/AN/AThin shrubs with grass, moss and lichenDrill hole casing at site. Soil Classification: HE.SCQ515662713455942355725241Sand29GFp77.10.04 0.000.7BrownSand with few pebbles3.3 3.82755.93.710156100.000.04.3None5Om OmOm Horizon: Bm Horizon:Ah Bm290SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51566371345494255573053 42Sand38GFp0.30.01Rusty brownFine sandN/A2.92476.03.21029670.000.03.1N/AN/AThick shrubs with moss and lichenAe mottled with Bm. Soil Classification: HE.SC3None3.5Equant, prolateFew, pebble sized clasts.Dominantly graniticThick shrubsDiamict sampled below GLv sediments. Soil Classification: HE.SCQ515664713454342655735643Diamict36GLv/Tb90.00.01 0.00 0.000.0 0.017Rusty brownSand matrix3.9 5.6 5.52835.83.59258120.000.05.7None6Om Om AhBm Horizon: Bm Horizon:AeAe100.000.03.7Bm Bm291SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51566571345314285574043 44Diamict43GLv/Tb10.57.40.04 0.021.9Greenish brownClay rich sand matrixEquant3.6 4.13126.03.318277180.000.04.9Few, pebble sized clasts with occasional boulders.Dominantly graniticThin shrubs with moss and lichenDiamict sampled below GLv sediments. Soil Classification: HE.SC3None. 5N/AN/AN/AThin shrubs with moss and lichenClassified as Organics (O) as Bm horizon material could not be properly identified due to permafrost. Gleying visible in pit. Soil Classification: HE.SCQ515666713451442655746945Organics35O15.50.70.01 0.04 0.023.0 1.525Black brownPeat4.5 4.4 4.53395.44.02016522.50.020.34.5Yes7Om Ah OmCg Horizon: Bm Horizon:AhCg Ae Bm292SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51566771345174265574983 46Organics33O7.20.02Black brownPeatN/A4.23205.74.520140170.012.54.4N/AN/AThin shrubsClassified as Organics (O) as Bm horizon material could not be prop-erly identified or sampled due to permafrost. Moisture measurement not taken in Bm horizon. Soil Classification: HE.SC3Yes11N/AN/AN/AThin shrubs with moss and lichenClassified as Organics (O) as Bm horizon material could not be properly identified due to permafrost. Soil Classification: HE.SCQ515668713450742555755347Organics36O237.90.03 0.047.1Black brownPeat3.8 4.03654.83.850184Yes11Om Om BmBm Horizon: Bm Horizon:Om2320.00-4.4Bm293SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51566971345704275575604 63Organics32O157.20.04 0.06 0.037.7 3.226Black brownPeatN/A4.0 4.2 4.33205.53.815156200.047.24.3N/AN/AThin shrubs with grassNone. Soil Classification: HE.SC4Yes10N/AN/AN/AHummocky grasslandNone.Soil Classification: HE.SCQ515670713457042555750762Clay43GLv177.40.03 0.023.1Greenish brownClay4.1 4.31896.34.210146240.000.04.5None5Om Om2 OmOm4 Horizon: Cg Horizon:Om2Om3 Om4 Cg294SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51567171345854265574604 61Clay33GLv4.10.02BrownClayN/A3.92645.53.732265170.047.14.1N/AN/AHummocky grassland with shrubsNone.Soil Classification: HE.SC4Yes8N/AN/AN/AHummocky grassland with shrubsNone.Soil Classification: HE.SCQ515672713459742655740560Clay42GLv0.00.00Greenish brownSand-rich clay5.11256.54.135185None3Om CgBm Horizon: Cg Horizon:Om2270.000.04.4Bm295SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51567371345604255573634 59Diamict38GLv/Tb0.00.00Grey brownClay-rich sand matrixEquant4.22086.03.312230Few, pebble sized clastsDominantly graniticThick shrubsDiamict sampled below GLv sediments. Soil Classification: HE.SC4None.5.5N/AN/AN/AThin shrubs with moss and lichenNone.Soil Classification: HE.SCQ515674713460942455731258Sand31GFp62.00.00 0.000.0Rusty brownClay rich sand with few pebbles4.1 4.03495.92.895238.50.000.04.4None3Cg OmCg Horizon: Bm Horizon:Ae Bm296SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51567571346174215572734 57Clay25GFp7.10.20BrownSand rich clay with cobblesN/A5.22426.03.21541290.000.05.5N/AN/AThin shrubs with grassGelisol. Hole quickly flooded.Soil Classification: HE.SC4None.2N/AN/AN/AHummocky grasslandNone.Soil Classification: HE.SCQ515676713461741955721756Sand48GFp0.00.02BrownSand5.42405.44.141153None39Om BmBm Horizon: Bm Horizon:Bm297SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51567871346414515571094 54Organics38O5.10.03Black brownPeatN/A4.63314.53.9166166N/AN/AHummocky grasslandNo sample taken at Site 55 (Q515577) as it was entirely Of horizon sediments.Soil Classification: HE.SC4Yes20N/AN/AN/AHummocky grassland with lesser shrubsDuplicate of Site 54 (Q515678).Soil Classification: HE.SCQ515679713464045155710854bOrganics35O3.00.02Black brownPeat3.83184.83.819170None24Om OmOm Horizon: Om Horizon:298SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51568071346474475570604 53Clay45GFp0.00.00BrownClayN/A4.21925.54.234195N/AN/AHummocky grassland with lesser shrubsSwelling clay.Soil Classification: HE.SC4None.4EquantAbundant, coarse sand-sized clasts.Dominantly graniticHummocky grassland with lesser shrubsNone.Soil Classification: HE.SCQ515681713465744255700652Diamict42Tb352.70.01 0.010.0BrownSand-rich clay matrix4.7 5.12795.64.132161Yes15Bm Om BmBm Horizon: Bm Horizon:299SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51568271346604415569604 51Organics40O7.70.05Black brownPeatN/A4.13164.94.130128N/AN/AHummocky grasslandOm horizon sampled. Soil Classification: HE.SC4Yes18EquantAbundant, pebble sized clasts. Dominantly graniticHummocky grassland with lesser shrubsNone.Soil Classification: HE.SCQ515683713467943955692450Diamict41Tb108.00.05 0.04 0.005.9 0.027BrownSand-rich clay matrix4.4 4.8 5.03115.63.721206210.000.04.9None4Om OmOm Horizon: Bm Horizon:Om2 Ae Bm300SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51568571346824395568634 49bGravel55GFp2.60.00 0.000.044BrownVery coarse sand to gravelN/A4.5 4.72605.73.41927822.50.000.04.5N/AN/AMoss and lichen with grass and shrubsOriginal sample (Q515684) discarded. Q515685 is not a duplicate sample. Soil Classification: BE.TC4None.8N/AN/AN/AMoss and lichenNone.Soil Classification: BE.TCQ515686713468943755681748Gravel41GFp60.00.01 0.000.0Rusty brownFine gravel4.3 4.32585.72.915540150.000.04.4None. 4Om Om AeBm Horizon: Bm Horizon:BmOm2 Bm320.000.04.7Ae301SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51568771347514405568265 64Sand40GFp20.00.00 0.000.0Rusty brownClay-rich sandN/A4.5 4.62545.93.91222450.000.04.9N/AN/AThick shrubsNone. Soil Classification: HE.SC5None. 1N/AN/A N/AThick shrubs Gelisol. Soil Classification: HE.SCQ515688713474243655688165Sand27GFp67.20.01 0.000.0Rusty brownClay-rich sand4.2 4.72606.13.616407100.000.04.8None2Om Ae OmBm Horizon: Bm Horizon:AeBm Bm302SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51568971347264335569325 66Sand46GFp0.00.01Rusty brown SandN/A3.62555.63.62327280.000.03.7N/AN/AThin shrubsNone. Soil Classification: HE.SC5None.3EquantFew, pebble sized clastsDominantly graniticThin shrubsAe horizon mottled with Bm, sample taken below mottling.Soil Classification: BE.TCQ515690713472443655698567Diamict40Tb30.30.01 0.00 0.000.0 0.011Rusty brownSand matrix3.4 3.9 3.92705.23.6773765.50.000.04.2None. 1.5Om Om AhBm Horizon: Bm Horizon:AeAe180.000.03.8Bm Bm303SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51569171347164335570365 68Diamict35Tb2.50.00.00 0.000.0Rusty brownSand matrixEquant4.4 4.32355.93.71027460.000.04.7Abundant, pebble sized clasts.Dominantly graniticThin shrubsNone. Soil Classification: BE.TC5None. 1EquantFew, pebble sized clasts.Dominantly graniticHummocky grassland with shrubsGelisol. Soil Classification: BE.TCQ515692713472042855708069Diamict29Tb138.40.05 0.000.0BrownClay-rich sand matrix4.1 4.42605.53.220540None.1Om Ae OmBm Horizon: Bm Horizon:BmBm304SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51569371347044275571415 70Organics26O8.00.05Black brownPeatN/A2.92864.53.946233N/AN/AHummocky grasslandNone. Soil Classification: HE.SC5Yes.10N/AN/AN/AHummocky grasslandNo sample taken at this site.Soil Classification: HE.SCQ515694713468942855718071Organics36O97.60.03 0.068.2Black brownPeat3.0 3.02705.23.677376160.047.43.1Yes2Om Om Om2Om Horizon: Om3 Horizon:Om3305SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51569571346894265572295 72Diamict39Tb1110.30.08 0.054.6Rusty brownClay-rich sand matrixEquant3.0 3.22885.84.724176230.021.13.4Few, pebble sized clasts.Dominantly graniticThin shrubsNone. Soil Classification: BE.TC5None. 7EquantFew, pebble sized clasts.Dominantly graniticThin shrubs with grassSamples taken up-slope of drill casings near site. Duplicate of Site 72 (Q515695).Soil Classification: BE.TCQ515696713468942655722972bDiamict35Tb208.90.10 0.021.0BrownClay-rich sand matrix3.2 3.41735.64.425190None.10Om Om2 OmBm Horizon: Bm Horizon:BmBm306SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51569771346794295572795 73Clay27GFp0.00.00Rusty brownSand- rich clay with few pebblesN/A4.51575.84.53519050.011.43.8N/AN/AThin shrubs with moss and lichen Gleying visible. Soil Classification: HE.SC5None. 3N/AN/AN/AThin shrubsNone. Soil Classification: HE.SCQ515698713466942955732574Sand39GFp7.50.00.01 0.000.0Rusty brownSand with few pebbles2.9 3.22685.53.413322140.000.03.0None.5Ae Om AeBm Horizon: Bm Horizon:BmBm307SAMPLE ID: VegetationProfileLine: Site: North (m): (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): Slurry:pH: TDS (ppm): Top of (cm):East (m): Elevation(m): Site Comment: Vegetation:TDS [acidified] (ppm): pH [acidified]: Permafrost: SAMPLE ID: (UTM NAD 83 Zone 12N) Surficial Material: Sampled Material: Colour: Grain Size:Clast Shape: Clast Lithology: Clast Size: Total Pit Depth (cm): Slurry:East (m): Site Comment: Vegetation:Line: VegetationProfileSite: North (m): Moisture (%): E.C. (mS): In-situ pH: ORP (mV): pH: TDS (ppm): Top of (cm):Elevation(m): TDS [acidified] (ppm): pH [acidified]: Permafrost: Q51569971346594325573755 75Sand38GFp148.30.07 0.000.0Rusty brownSand N/A3.2 3.02695.53.813240N/AN/AHummocky grasslandNone. Soil Classification: HE.SC5None. 5N/AN/AN/AHummocky grasslandEvidence of cryoturbation as organic horizon is observed beneath Bm horizon. Soil Classification: HE.SCQ515700713465143155742476Sand37GFp239.60.08 0.000.0BrownClay-rich sand matrix2.7 3.02585.13.929192330.023.83.1Yes4Om Bm OmBm Horizon: Bm Horizon:Bm Om2308Site Voltage 1 (mV) Moisture 1 (%) Resistance 1 (Ω) Voltage 2 (mV) Moisture 2 (%)48 Base Station Base Station Base Station Base Station Base Station49 -3.90 1.50 29.30 -5.90 1.5050 -15.30 0.00 46.67 -12.50 0.0051 -20.30 7.30 24.33 -22.30 7.4052 -20.50 8.00 23.49 -21.00 8.1053 -7.80 0.00 30.10 -14.60 0.0054 -6.20 8.30 24.42 -7.90 5.6055 -17.30 8.00 23.24 -17.90 7.9056 11.60 0.00 41.21 5.30 0.0057 -14.30 0.00 30.69 -13.90 0.0058 -27.90 0.00 66.80 -26.60 0.0059 -1.30 0.00 33.21 -0.70 0.0064 Base Station Base Station Base Station Base Station Base Station65 -42.50 0.00 54.35 -40.20 0.0066 -37.10 0.00 55.42 -41.80 0.0067 -36.30 0.00 90.50 -33.80 0.0068 -43.50 0.00 59.59 -39.70 0.0069 -8.90 0.00 49.76 -6.80 0.0070 3.90 4.00 34.89 4.60 1.4071 4.40 5.50 32.71 -2.10 2.7072 -9.20 0.00 32.68 -14.10 0.0073 0.00 37.51 -19.50 0.0074 -17.90 0.00 60.38 -6.10 0.0075 -5.90 0.00 48.60 -10.30 0.0076 4.70 0.00 41.23 8.30 0.0077 -12.20 7.10 30.61 -17.60 7.1078 -4.40 5.10 31.65 11.30 6.3079 -20.80 5.00 32.16 -25.80 6.20128 Base Station Base Station Base Station Base Station Base Station129 -12.60 0.00 64.49 -19.60 0.00130 -46.10 0.00 OL -47.10 0.00131 -44.60 0.00 OL -43.80 0.00132 -9.90 0.00 102.70 -23.90 0.00133 -32.30 0.00 OL -18.60 0.00134 -50.30 0.00 OL -51.90 0.00135 -60.90 0.00 OL -56.90 0.00136 -63.90 0.00 63.39 -60.90 0.00137 -48.90 0.00 33.90 -43.10 0.00138 -51.50 0.00 62.80 -66.70 0.00139 -27.60 0.00 75.30 -45.50 0.00140 -45.50 0.00 55.40 -21.30 0.00141 6-52 0.00 124.30 -28.80 0.00142 -18.60 0.00 78.50 -4.90 0.00143 4.50 0.00 64.70 -14.90 0.00C.3 Spontaneous Potential309Site48495051525354555657585964656667686970717273747576777879128129130131132133134135136137138139140141142143Resistance 2 (Ω) Voltage 3 (mV) Moisture 3 (%) Resistance 3 (Ω) Horizon Mean VoltageBase Station Base Station Base Station Base Station Base Station Base Station30.31 -5.50 0.00 30.29 B -5.10oops -8.90 0.00 57.08 B -12.2323.93 -28.50 7.90 23.40 O -23.7023.69 -20.10 8.60 23.62 O -20.5331.10 -10.20 0.00 30.36 B -10.8724.15 -11.20 8.20 23.95 O -8.4323.15 -14.10 8.40 23.48 O -16.4333.10 8.70 0.00 36.05 B 8.5326.48 -18.20 0.00 26.45 B -15.4798.20 -18.30 0.00 115.80 B -24.2735.24 -0.80 0.00 34.28 B -0.93Base Station Base Station Base Station Base Station Base Station Base Station55.40 -28.90 0.00 55.30 B -37.2060.08 -42.70 0.00 56.82 B -40.5396.70 -43.90 0.00 70.40 B -38.0058.15 -49.80 0.00 57.38 B -44.3354.20 -9.90 0.00 46.92 B -8.5334.16 4.30 3.90 35.33 O 4.2733.61 5.90 4.30 33.94 O 2.7333.43 -12.80 0.00 30.57 B -12.0341.30 0.00 0.00 43.41 B -9.7560.20 -7.20 0.00 58.70 B -10.4040.90 -8.70 0.00 49.44 B -8.3041.12 12.50 0.00 42.43 B 8.5030.60 17.30 4.70 30.29 O -4.1731.45 2.50 7.80 32.45 O 3.1332.74 -21.00 5.20 30.33 O -22.53Base Station Base Station Base Station Base Station Base Station Base Station59.91 -21.50 0.00 64.77 B -17.9064.21 -49.30 0.00 OL B -47.5061.92 -48.50 0.00 57.50 B -45.6394.60 -10.30 0.00 104.30 B -14.7064.12 -30.40 0.00 59.00 B -27.10OL -69.20 0.00 OL B -57.13OL -57.10 0.00 OL B -58.30OL -77.10 0.00 OL B -67.3036.80 -45.50 0.00 37.80 B -45.8363.50 -61.20 0.00 OL B -59.8054.30 -34.80 0.00 63.80 B -35.9792.40 -17.60 0.00 100.40 B -28.1374.60 -24.60 0.00 79.20 B -26.7075.90 -4.60 0.00 80.10 B -9.3757.80 -14.90 0.00 68.60 B -8.43C.3 Spontaneous Potential310Site48495051525354555657585964656667686970717273747576777879128129130131132133134135136137138139140141142143STDEV.P Voltage Mean Moisture STDEV.P MoistureBase Station Base Station Base Station0.86 1.00 0.712.62 0.00 0.003.49 7.53 0.260.37 8.23 0.262.82 0.00 0.002.08 7.37 1.251.67 8.10 0.222.57 0.00 0.001.94 0.00 0.004.25 0.00 0.000.26 0.00 0.00Base Station Base Station Base Station5.94 0.00 0.002.46 0.00 0.004.29 0.00 0.004.17 0.00 0.001.29 0.00 0.000.29 3.10 1.203.47 4.17 1.152.07 0.00 0.009.75 0.00 0.005.32 0.00 0.001.82 0.00 0.003.19 0.00 0.0015.34 6.30 1.136.43 6.40 1.102.31 5.47 0.52Base Station Base Station Base Station3.83 0.00 0.001.34 0.00 0.002.05 0.00 0.006.51 0.00 0.006.06 0.00 0.008.56 0.00 0.001.84 0.00 0.007.04 0.00 0.002.38 0.00 0.006.28 0.00 0.007.35 0.00 0.0012.37 0.00 0.002.10 0.00 0.006.53 0.00 0.009.15 0.00 0.00C.3 Spontaneous Potential311312 Appendix D: Raw Geochemical Data Presented in this section is raw geochemical data from each analysis, including:  D.1. Kimberlite Drill Core Lithogeochemical Analysis  D.2. Kimberlitic Clay Sample Lithogeochemical Analysis  D.3. Petrography  D.4. 4-Acid ICP-MS Analysis  D.5. Aqua Regia ICP-MS Analysis  D.6. De-Ionized Water ICP-MS Analysis  D.7. fp-XRF Soil Mode Analysis  D.8. fp-XRF Geochem Mode Analysis  D.9. Sequential Leach Analysis  D.10. X-Ray Diffraction Analysis  D.11. Spatiotemporal Geochemical Hydrocarbon (SGH) Analysis  D.12. AGI. Inc. Goresorber™ Hydrocarbon Collectors Analysis ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06SiO2 Al2O3 Fe2O3 CaO MgO Na2O K2O Cr2O3SAMPLE % % % % % % % %K2P-0018b 56.4 9.65 3.89 2.76 12.6 1.47 3.58 0.05K2P-0027b 52.6 9.7 4.48 3.53 13.2 1.21 3.55 0.06K2P-0067b 50 8.12 4.74 3.34 16.6 0.67 2.9 0.06ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 OA-GRA05 TOT-ICP06 C-IR07TiO2 MnO P2O5 SrO BaO LOI Total CSAMPLE % % % % % % % %K2P-0018b 0.24 0.05 0.23 0.04 0.1 7.96 99.02 0.53K2P-0027b 0.31 0.06 0.23 0.05 0.12 10.7 99.8 1.06K2P-0067b 0.26 0.07 0.23 0.05 0.12 12.55 99.71 0.83S-IR08 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81S Ba Ce Cr Cs Dy Er EuSAMPLE % ppm ppm ppm ppm ppm ppm ppmK2P-0018b 0.15 873 73.6 350 2.1 1.18 0.59 0.62K2P-0027b 0.28 1100 89.6 420 2.36 1.73 0.86 0.96K2P-0067b 0.26 1055 92 440 1.99 1.41 0.55 0.76ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81Ga Gd Ge Hf Ho La Lu NbSAMPLE ppm ppm ppm ppm ppm ppm ppm ppmK2P-0018b 12.5 2.12 <5 2.1 0.21 41 0.07 41.6K2P-0027b 12.8 2.84 <5 2.3 0.33 49.7 0.11 56.3K2P-0067b 11 2.52 <5 1.8 0.27 51.7 0.08 56.3ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81Nd Pr Rb Sm Sn Sr Ta TbSAMPLE ppm ppm ppm ppm ppm ppm ppm ppmK2P-0018b 26.3 7.89 100.5 3.72 1 342 2 0.31K2P-0027b 31.6 9.07 103.5 4.02 1 422 2.6 0.33K2P-0067b 31.9 9.13 84.7 4.03 1 382 2.5 0.3ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81Th Tm U V W Y Yb ZrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppmK2P-0018b 8.86 0.1 3.18 45 <1 6.1 0.46 70K2P-0027b 9.21 0.12 2.85 62 1 8 0.71 86K2P-0067b 9.58 0.1 3.39 59 1 6.7 0.7 65ME-MS42 ME-MS42 ME-MS42 ME-MS42 ME-MS42 ME-MS42 ME-MS42 ME-MS42As Bi Hg In Re Sb Se TeSAMPLE ppm ppm ppm ppm ppm ppm ppm ppmK2P-0018b 1.6 0.12 <0.005 0.015 0.002 0.12 0.7 0.02K2P-0027b 2.9 0.1 0.01 0.018 0.003 0.14 0.7 0.02K2P-0067b 2.9 0.4 0.01 0.016 0.004 0.14 0.9 0.03D.1 Kimberlite Drill Core Lithogeochemistry313ME-MS42 ME-4ACD81 ME-4ACD81 ME-4ACD81 ME-4ACD81 ME-4ACD81 ME-4ACD81Tl Ag Cd Co Cu Li MoSAMPLE ppm ppm ppm ppm ppm ppm ppmK2P-0018b 0.2 <0.5 <0.5 33 21 20 1K2P-0027b 0.24 <0.5 <0.5 35 25 20 <1K2P-0067b 0.25 <0.5 <0.5 46 25 10 <1ME-4ACD81 ME-4ACD81 ME-4ACD81 ME-4ACD81Ni Pb Sc ZnSAMPLE ppm ppm ppm ppmK2P-0018b 532 13 5 43K2P-0027b 557 10 7 51K2P-0067b 789 10 6 53PbIS-RAT61 PbIS-RAT61 PbIS-RAT61 PbIS-RAT61 PbIS-RAT61 PbIS-RAT61206/204 207/204 208/204 208/206 208/207 206/207SAMPLE Unity Unity Unity Unity Unity UnityK2P-0018b 18.63 15.73 38 2.04 2.415 1.19K2P-0027b 18 15.48 37.26 2.07 2.408 1.163K2P-0067b 18.35 15.58 37.61 2.05 2.414 1.18D.1 Kimberlite Drill Core Lithogeochemistry314ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06SiO2 Al2O3 Fe2O3 CaO MgO Na2O% % % % % %NGO-RC15-061-13a 42.7 13.65 6.81 0.97 4.71 0.15ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06 ME-ICP06K2O Cr2O3 TiO2 MnO P2O5 SrO% % % % % %NGO-RC15-061-13a 3.17 0.01 0.51 0.04 0.22 0.01ME-ICP06 OA-GRA05 TOT-ICP06 C-IR07 S-IR08 ME-MS81BaO LOI Total C S Ba% % % % % ppmNGO-RC15-061-13a 0.07 25.7 98.72 3.75 3.79 595ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81Ce Cr Cs Dy Er Euppm ppm ppm ppm ppm ppmNGO-RC15-061-13a 63.5 80 7.43 3.83 2.11 0.99ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81Ga Gd Ge Hf Ho Lappm ppm ppm ppm ppm ppmNGO-RC15-061-13a 18.4 4.38 <5 3 0.81 33.7ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81Lu Nb Nd Pr Rb Smppm ppm ppm ppm ppm ppmNGO-RC15-061-13a 0.31 15.1 27.8 7.39 137.5 5.16ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81Sn Sr Ta Tb Th Tmppm ppm ppm ppm ppm ppmNGO-RC15-061-13a 1 126.5 0.9 0.68 11 0.31ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81 ME-MS81U V W Y Yb Zrppm ppm ppm ppm ppm ppmNGO-RC15-061-13a 11.55 179 3 22.9 2.18 112ME-MS42 ME-MS42 ME-MS42 ME-MS42 ME-MS42 ME-MS42As Bi Hg In Re Sbppm ppm ppm ppm ppm ppmNGO-RC15-061-13a 51.1 0.36 0.089 0.049 0.043 1.51D.2 Clay Sample Lithogeochemistry315ME-MS42 ME-MS42 ME-MS42 ME-4ACD81 ME-4ACD81 ME-4ACD81Se Te Tl Ag Cd Coppm ppm ppm ppm ppm ppmNGO-RC15-061-13a 4.7 0.15 0.71 <0.5 1.8 18ME-4ACD81 ME-4ACD81 ME-4ACD81 ME-4ACD81 ME-4ACD81 ME-4ACD81Cu Li Mo Ni Pb Scppm ppm ppm ppm ppm ppmNGO-RC15-061-13a 47 50 28 80 19 12ME-4ACD81ZnppmNGO-RC15-061-13a 148PbIS-RAT61 PbIS-RAT61 PbIS-RAT61 PbIS-RAT61 PbIS-RAT61 PbIS-RAT61206/204 207/204 208/204 208/206 208/207 206/207Unity Unity Unity Unity Unity UnityNGO-RC15-061-13a 18.93 15.41 38.65 2.042 2.507 1.233D.2 Clay Sample Lithogeochemistry316D.3 Petrography Figure D.1. a) 2x magnification of K2P-0018 under plane polarized light. b) 2x magnification of K2P-0018 under cross polarized light. Minerals present include broken, serpentinized olivine, granitic xenoliths and xenocrysts, and RVK clasts in a serpentine and ash matrix. a) b) 317 Figure D.2. a) 2x magnification of K2P-0027 under plane polarized light. b) 2x magnification of K2P-0027 under cross polarized light. Minerals present include broken, serpentinized olivine, granitic xenoliths and xenocrysts, and RVK clasts, in a serpentine and ash matrix. a) b) 318 Figure D.3. a) 5x magnification of K2P-0067 under plane polarized light. b) 5x magnification of K2P-0067 under cross polarized light. Minerals present include broken, serpentinized olivine, granitic xenoliths and xenocrysts, in a serpentine and ash matrix. a) b) 319ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Sample Ag Al As Ba Be Bi Ca Cd Ce Co Cr Cs CuSAMPLE Site Type ppm % ppm ppm ppm ppm % ppm ppm ppm ppm ppm ppmQ515501 26 Soil 0.11 5.89 5.2 380 1.16 0.2 1.32 0.11 45.8 3.7 25 2.13 16.1Q515502 27 Soil 0.12 6 6 380 1.26 0.24 1.33 0.07 42.9 4.2 29 2.1 12Q515503 28 Soil 0.12 5.92 32.5 400 1.4 0.35 1.38 0.08 52.5 7.8 44 2.24 9Q515504 29 Soil 0.19 1.62 5.9 140 0.55 0.3 0.39 0.32 39.8 2.9 22 0.79 84.1Q515505 30 Soil 0.09 5.99 2.2 400 1.59 0.17 1.3 0.09 47.4 3.5 31 2 15.1Q515506 31 Soil 0.06 6.3 2 440 1.32 0.16 1.37 0.07 46.6 3.5 30 2.1 11.9Q515507 125 Soil 0.07 6.26 6.4 430 1.3 0.17 1.41 0.08 49.7 4.1 30 2.1 13.2Q515508 124 Soil 0.06 6.44 7.4 450 1.4 0.28 1.44 0.07 54.4 4.7 36 2.31 14.3Q515509 123 Soil 0.07 6.06 6.4 420 1.43 0.18 1.34 0.07 59.7 4.1 32 2.15 13Q515510 122 Soil 0.07 5.99 7.4 410 1.33 0.2 1.33 0.08 51.5 4.1 34 2.17 10.8Q515511 121 Soil 0.06 6.05 7.1 410 1.3 0.17 1.32 0.07 49.4 4.3 31 2.22 13.8Q515512 120 Soil 0.08 6.07 6.9 420 1.3 0.18 1.37 0.06 52 4.4 34 2.22 11.2Q515513 119 Soil 0.06 5.93 5.4 400 1.56 0.17 1.32 0.07 43.2 3.7 29 2.12 10.3Q515514 118 Soil 0.06 6.09 7.4 420 1.45 0.17 1.34 0.07 52.7 4.5 32 2.23 16.9Q515515 117 Soil 0.1 5.93 6.1 410 1.26 0.19 1.34 0.07 46.8 4.1 34 2.15 12.4Q515516 116 Soil 0.05 6.27 7 440 1.34 0.18 1.38 0.07 53.9 4.9 35 2.32 15.1Q515516a N/A CRM 0.04 9.25 10.7 160 0.87 0.36 0.32 0.04 46.7 7.4 118 6.34 30.6Q515517 14 Soil 0.06 5.96 3.8 410 1.4 0.17 1.31 0.07 49.9 3.5 29 2 9.3Q515518 15 Soil 0.06 6.25 5.2 440 1.28 0.16 1.37 0.08 50.4 4.1 33 2.2 12.9Q515519 13 Soil 0.05 6.07 6.1 420 1.35 0.25 1.31 0.06 52.7 9.1 36 2.28 10.6Q515520 12 Soil 0.06 5.35 63.4 340 1.31 0.45 1 0.07 45.8 8 44 2.13 14.8Q515521 11 Soil 0.04 6.1 4.4 390 1.58 0.2 1.29 0.06 46.3 3.9 31 2.09 4.6Q515522 10 Soil 0.05 6.19 6.2 430 1.38 0.21 1.37 0.06 58.1 4.9 33 2.3 17.8Q515523 9 Soil 0.06 6.3 6.4 430 1.46 0.18 1.4 0.07 57.2 4.9 36 2.26 14.3Q515524 8 Soil 0.06 6.16 5.7 400 1.79 0.24 1.32 0.07 62.8 4.5 35 2.51 8.2Q515525 7 Soil 0.07 6.22 6.3 420 1.59 0.23 1.27 0.07 57.2 4.4 35 2.3 26.3Q515526 115 Soil 0.05 6.14 6.7 420 1.42 0.17 1.23 0.07 41.4 4.9 31 2.13 13.3Q515527 114 Soil 0.05 6.26 5.6 430 1.56 0.2 1.24 0.08 52.2 5.6 37 2.3 15Q515528 113 Soil 0.05 5.93 1.9 390 1.58 0.16 1.21 0.06 47.8 3.9 29 2.07 6.1Q515529 112 Soil 0.07 6.24 6 460 1.47 0.24 1.24 0.11 62.1 7.2 47 2.76 16.8Q515530 6 Soil 0.07 4.37 1.5 280 1.67 0.1 0.8 0.11 36.7 1.9 23 1.16 21.8Q515531 5 Soil 0.05 5.62 0.7 350 1.3 0.12 1.11 0.07 32.1 2.6 20 1.83 6.9D.4 4-Acid ICP-MS320ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Sample Ag Al As Ba Be Bi Ca Cd Ce Co Cr Cs CuSAMPLE Site Type ppm % ppm ppm ppm ppm % ppm ppm ppm ppm ppm ppmD.4 4-Acid ICP-MSQ515551 77 Soil 0.18 1.14 2.8 80 0.39 0.14 0.26 0.29 37.4 2 13 0.34 99.8Q515551a N/A CRM 0.04 9.53 10.3 160 0.85 0.35 0.31 0.04 50.4 7.5 117 6.41 30.5Q515552 78 Soil 0.14 0.73 3.9 60 0.29 0.16 0.21 0.19 32 1.8 10 0.2 59Q515553 79 Soil 0.09 2.22 5 170 0.6 0.18 0.39 0.11 35.4 2.1 20 0.79 47.5Q515554 95 Soil 0.05 6.16 0.6 400 1.29 0.13 1.22 0.07 41 3 26 2.07 8.2Q515555 94 Soil 0.07 6.21 1.4 420 1.61 0.18 1.3 0.08 58.3 4 29 2.24 26.5Q515556 93 Soil 0.06 5.79 3.9 400 1.4 0.2 1.2 0.07 55.3 3.5 29 2.08 20.6Q515557 92 Soil 0.05 6.18 6.4 400 1.33 0.14 1.27 0.07 53.6 4.3 30 2.15 11Q515558 91 Soil 0.05 6.04 7.4 400 1.37 0.24 1.24 0.07 50 4.1 28 2.03 11.3Q515559 90 Soil 0.05 5.96 7.3 380 1.28 0.15 1.25 0.07 49.8 4.3 27 2.06 10.7Q515560 89 Soil 0.06 6.04 6.5 400 1.17 0.16 1.31 0.07 50.9 3.7 28 1.91 9.6Q515561 88 Soil 0.05 6.18 5.8 430 1.35 0.19 1.21 0.07 47.1 4.6 38 2.79 11.5Q515562 87 Soil 0.03 5.78 7.8 370 1.32 0.24 1.16 0.05 42.2 4.1 33 2.6 6.1Q515563 86 Soil 0.07 6.21 5.4 420 1.33 0.21 1.25 0.1 58.7 5.1 38 2.67 27.8Q515564 85 Soil 0.06 5.92 7.8 380 1.71 0.17 1.23 0.08 48.8 4.8 30 2.2 14.1Q515565 84 Soil 0.06 6.36 8.7 440 1.44 0.21 1.33 0.07 56.3 4.5 33 2.38 17.8Q515566 83 Soil 0.05 6.3 5.3 420 1.33 0.16 1.27 0.07 68.1 5.1 36 2.38 21.2Q515567 82 Soil 0.06 6.27 5.4 420 1.29 0.15 1.29 0.07 58.3 4.6 32 2.11 16.7Q515568 81 Soil 0.06 6.28 12.4 410 1.31 0.19 1.27 0.09 57.1 6.1 41 2.69 21.3Q515569 80 Soil 0.05 6.13 6.2 400 1.47 0.17 1.33 0.07 58.2 4.5 32 2.22 16.6Q515570 96 Soil 0.05 6.25 3.7 420 1.46 0.15 1.34 0.08 71.4 6.9 50 2.41 15Q515571 97 Soil 0.03 5.94 3.1 380 1.28 0.15 1.21 0.07 46 4.1 38 2.33 7.8Q515572 98 Soil 0.04 5.55 3.9 370 1.28 0.15 1.11 0.08 38.4 3.6 24 1.83 10Q515573 99 Soil 0.05 6.28 9.5 450 1.5 0.19 1.3 0.08 64.4 7.3 43 2.56 21.2Q515574 100 Soil 0.05 6.28 10.1 410 1.61 0.2 1.28 0.09 57.6 7.6 46 2.79 26.3Q515575 101 Soil 0.06 5.89 6.1 370 1.35 0.21 1.22 0.07 40.9 4.4 31 2.29 8.6Q515576 102 Soil 0.05 6.31 8.9 440 1.48 0.2 1.26 0.1 56 8 48 2.67 21.1Q515577 103 Soil 0.09 5.98 3.3 430 1.56 0.23 1.2 0.12 81.1 6.5 49 2.53 50.1Q515578 104 Soil 0.04 6.19 7.1 410 1.48 0.27 1.32 0.08 65.6 3.9 35 2.3 17.5Q515579 105 Soil 0.05 6.08 9.5 410 1.37 0.16 1.27 0.08 57.4 4.2 34 2.34 14.9Q515580 106 Soil 0.05 6.14 7.9 400 1.34 0.17 1.3 0.08 49.6 3.9 32 2.18 7.6Q515581 107 Soil 0.05 6.1 6.6 410 1.45 0.15 1.28 0.08 52.9 4.3 33 2.31 13.7321ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Sample Ag Al As Ba Be Bi Ca Cd Ce Co Cr Cs CuSAMPLE Site Type ppm % ppm ppm ppm ppm % ppm ppm ppm ppm ppm ppmD.4 4-Acid ICP-MSQ515582 108 Soil 0.05 5.99 5.4 390 1.69 0.12 1.32 0.08 51.6 4 28 2.05 12.8Q515583 108b Duplicate 0.05 5.92 5.9 390 1.33 0.13 1.3 0.06 52 4.3 28 2.05 12.6Q515583a N/A CRM 0.04 9.23 10.1 150 0.88 0.34 0.31 0.03 50.7 7.6 115 6.49 31.8Q515584 109 Soil 0.05 6.13 6.3 410 1.45 0.17 1.32 0.07 46.8 4.4 31 2.18 12Q515585 110 Soil 0.05 5.91 5.5 390 1.43 0.19 1.27 0.06 47.7 4.1 29 2.12 10.9Q515586 111 Soil 0.05 5.82 7.7 380 1.58 0.15 1.27 0.08 52.7 3.7 30 2.18 9.6Q515587 127 Soil 0.06 5.92 5.4 400 1.73 0.14 1.28 0.06 53.6 4.2 30 2.22 13.3Q515588 126 Soil 0.05 6.01 7.4 380 1.41 0.18 1.26 0.07 53.3 4.6 29 2.19 14.4Q515589 126b Duplicate 0.05 5.9 7 390 1.33 0.17 1.29 0.08 52.2 3.7 29 2.16 9.7Q515590 16 Soil 0.06 5.82 5.5 380 1.61 0.14 1.18 0.08 50.7 4.7 31 2.48 12.8Q515591 17 Soil 0.05 6 6.2 410 1.49 0.15 1.28 0.07 65.1 5.4 33 2.41 15.8Q515592 18 Soil 0.1 6.35 8.1 410 1.25 0.25 1.2 0.07 46.9 5.5 35 2.53 15.7Q515593 18b Duplicate 0.06 6.37 7 440 1.43 0.2 1.28 0.08 57.4 5.9 37 2.65 13.3Q515594 19 Soil 0.05 6.13 5.2 400 1.42 0.18 1.23 0.07 41.6 4.3 33 2.32 9.7Q515595 20 Soil 0.06 6.06 4.5 380 1.49 0.28 1.26 0.06 38.4 3.5 24 1.95 9.5Q515596 21 Soil 0.05 5.78 1.2 370 2.71 0.15 1.22 0.07 41.7 2.4 20 1.87 10.7Q515597 22 Soil 0.06 5.91 1.7 410 1.39 0.15 1.18 0.08 48.5 2.8 30 1.73 19.1Q515598 23 Soil 0.06 6.34 2.3 430 1.35 0.18 1.34 0.08 62.6 3.9 36 2.43 13Q515599 24 Soil 0.05 6.16 6.1 410 1.52 0.17 1.32 0.07 52.7 4 29 2.15 9.2Q515599a N/A CRM 0.04 9.39 9.7 160 0.85 0.35 0.31 0.03 49.3 7.4 120 6.53 31.1Q515600 25 Soil 0.05 5.64 6.6 340 1.21 0.19 1.21 0.06 47.9 3.4 24 1.89 6.2Q515651 32 Soil 0.06 6.37 7.3 440 1.85 0.24 1.32 0.07 61.2 5 35 2.32 17.9Q515652 33 Soil 0.06 6.35 7.7 420 1.36 0.19 1.32 0.08 58.4 4.4 35 2.33 12Q515653 34 Soil 0.06 6.12 5 420 1.63 0.21 1.23 0.07 59.8 4.2 35 2.57 14.6Q515654 35 Soil 0.03 5.48 0.8 360 1.24 0.1 1.08 0.05 33.2 1.9 18 1.47 3Q515655 35b Duplicate 0.04 5.74 1.6 370 1.17 0.11 1.18 0.06 40.4 2.4 19 1.7 3.9Q515657 36 Soil 0.05 4.64 1.7 300 1.18 0.11 0.88 0.09 37.3 1.4 20 1.04 16.6Q515658 37 Soil 0.05 6.23 2.1 430 1.64 0.17 1.26 0.07 51.7 3.5 34 2.32 16.7Q515659 38 Soil 0.06 6 1.4 410 1.35 0.15 1.19 0.08 51.2 3.3 32 2.09 19.6Q515660 39 Soil 0.16 1.05 2.4 80 0.41 0.15 0.21 0.17 30 1.6 13 0.33 71.3Q515661 40 Soil 0.13 1.66 3.7 130 0.68 0.26 0.34 0.32 45.6 2.2 20 0.52 72Q515662 41 Soil 0.05 6.22 3.1 410 1.82 0.21 1.32 0.07 58.8 4.3 33 2.46 8.8322ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Sample Ag Al As Ba Be Bi Ca Cd Ce Co Cr Cs CuSAMPLE Site Type ppm % ppm ppm ppm ppm % ppm ppm ppm ppm ppm ppmD.4 4-Acid ICP-MSQ515663 42 Soil 0.06 6.03 5.2 390 1.53 0.15 1.29 0.06 48.7 3.8 25 1.9 7.6Q515664 43 Soil 0.04 5.97 8.1 390 1.42 0.19 1.28 0.07 52.9 3.5 29 2.06 8.8Q515665 44 Soil 0.05 6.22 2 430 1.35 0.19 1.25 0.08 60.9 4.2 38 2.53 15.4Q515666 45 Soil 0.05 3.87 5.7 320 1.07 0.36 0.53 0.11 43.4 2.4 42 2.5 29.4Q515666a N/A CRM 0.04 9.49 9.4 160 0.88 0.34 0.31 0.03 52 7.3 121 6.56 30.1Q515667 46 Soil 0.08 2 4.8 190 0.61 0.24 0.46 0.24 41.3 3.3 24 1.19 58.6Q515667a N/A CRM 0.03 9.65 9.8 160 0.89 0.35 0.32 0.03 52.5 7.4 125 6.63 30.8Q515668 47 Soil 0.13 1.44 5.9 140 0.55 0.21 0.31 0.38 38.3 2.3 17 0.64 68.8Q515669 63 Soil 0.12 2.16 6.6 200 0.64 0.25 0.48 0.31 48.4 3.4 24 1.09 72.5Q515670 62 Soil 0.05 6.07 1.5 410 1.52 0.14 1.29 0.07 49.8 3.4 29 2.19 11.7Q515671 61 Soil 0.04 5.7 1.2 390 1.48 0.14 1.2 0.07 42.8 2.7 27 1.88 10.4Q515672 60 Soil 0.04 6.29 1.9 450 1.62 0.15 1.3 0.07 50 3.5 30 2.33 10.8Q515673 59 Soil 0.05 6.01 2.1 430 1.36 0.17 1.22 0.06 49.4 3.9 33 2.41 12.8Q515674 58 Soil 0.05 5.72 7.4 370 1.47 0.16 1.24 0.07 45.4 3 25 1.84 8.3Q515675 57 Soil 0.04 5.64 2.8 360 1.27 0.13 1.21 0.06 38.9 2.8 22 1.84 4.7Q515676 56 Soil 0.06 6.07 1.5 400 1.32 0.16 1.25 0.09 57.6 3.3 30 2.19 16.5Q515678 54 Soil 0.12 1.77 3.4 150 0.43 0.2 0.38 0.34 31.5 2.3 19 0.61 115Q515679 54b Duplicate 0.1 1.23 3.7 90 0.38 0.17 0.26 0.43 31.2 2 18 0.36 124.5Q515680 53 Soil 0.05 5.92 1.1 400 1.21 0.13 1.16 0.06 48.6 2.8 27 1.99 10.2Q515681 52 Soil 0.04 6.07 1.1 400 1.25 0.15 1.2 0.08 46.8 3.6 30 2.26 12.6Q515682 51 Soil 0.18 1.85 3.5 140 0.72 0.2 0.37 0.32 51.1 2.5 19 0.6 108Q515683 50 Soil 0.1 6.04 2.3 400 1.41 0.23 1.18 0.09 53.8 3.8 39 2.43 43Q515683a N/A CRM 0.04 9.63 10.8 160 0.92 0.35 0.32 0.05 52 7.5 122 6.72 33.6Q515685 49 Soil 0.06 5.91 6.5 370 1.18 0.24 1.24 0.07 52.4 2.8 24 1.83 8.6Q515686 48 Soil 0.05 7.02 18.5 410 1.65 0.46 1.52 0.08 67.9 9.6 69 4.2 14.8Q515687 64 Soil 0.05 6.37 7.4 430 1.85 0.18 1.31 0.08 61.4 4.9 34 2.39 15.3Q515688 65 Soil 0.06 6.36 6.4 420 1.64 0.17 1.3 0.06 58.8 4.4 31 2.35 15.1Q515689 66 Soil 0.04 5.91 10.1 400 1.15 0.18 1.2 0.06 50 3.4 28 2.16 7.2Q515690 67 Soil 0.06 6.88 9.4 470 1.55 0.21 1.39 0.08 59.4 5 36 2.7 12.2Q515691 68 Soil 0.05 6.32 7.1 430 1.36 0.18 1.29 0.06 55.1 4.7 38 2.53 9.1Q515692 69 Soil 0.06 5.86 3 380 1.38 0.15 1.19 0.06 42.1 3.6 29 2.24 8.3Q515693 70 Soil 0.21 1.5 1.4 90 0.57 0.13 0.22 0.4 47.6 2.2 13 0.43 125.5323ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Sample Ag Al As Ba Be Bi Ca Cd Ce Co Cr Cs CuSAMPLE Site Type ppm % ppm ppm ppm ppm % ppm ppm ppm ppm ppm ppmD.4 4-Acid ICP-MSQ515695 72 Soil 0.06 6.44 5.3 500 1.69 0.18 1.21 0.09 57 6.7 55 3.06 19.1Q515696 72b Duplicate 0.06 6.42 2.7 490 1.54 0.16 1.29 0.09 75.5 5.8 60 2.66 14.9Q515697 73 Soil 0.04 6.32 5.7 430 1.47 0.17 1.29 0.07 52.5 4.3 31 2.34 14.2Q515698 74 Soil 0.04 6.03 2.2 390 1.21 0.24 1.25 0.06 53.2 2.9 25 1.92 6.5Q515699 75 Soil 0.05 6.09 0.7 390 1.47 0.15 1.25 0.07 48.9 2.8 24 2.03 9.7Q515700 76 Soil 0.05 5.88 0.5 400 1.25 0.09 1.17 0.07 38.2 2.3 22 1.75 14.1Q515700a N/A CRM 0.03 9.69 10.6 160 0.93 0.35 0.32 0.03 53.5 7.5 117 6.85 32.[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Fe Ga Ge Hf In K La Li Mg Mn Mo Na Nb Ni% ppm ppm ppm ppm % ppm ppm % ppm ppm % ppm ppm1.09 12.05 0.12 3.3 0.02 1.78 21.8 19.9 0.36 185 0.4 2.29 3.6 11.21.1 12.15 0.16 3.3 0.015 1.74 20.6 21.6 0.38 194 0.57 2.3 3.5 12.44.02 12.9 0.14 3.9 0.019 1.79 25.6 23.2 0.57 309 6.05 2.1 4.4 150.9 3.38 0.1 0.8 0.013 0.36 19.1 3.5 0.09 49 1.09 0.35 1.5 12.50.94 12.35 0.18 3.8 0.015 1.72 23 21.4 0.39 182 0.23 2.25 4.1 11.30.99 12.75 0.18 3.7 0.015 1.92 22.6 21.9 0.39 180 0.23 2.38 4.1 11.31.23 12.55 0.2 3.3 0.015 1.92 23.9 21.3 0.41 208 0.5 2.4 3.9 12.11.38 13.1 0.22 4.3 0.017 1.95 26 23 0.45 220 0.6 2.39 4.6 141.24 12.65 0.21 3.8 0.015 1.83 28.6 22.3 0.41 205 0.51 2.3 4.1 12.51.2 12.6 0.22 3.9 0.017 1.86 24.8 21.5 0.4 198 0.49 2.27 4.2 13.81.25 12.6 0.2 3.6 0.017 1.84 23.7 23 0.42 198 0.53 2.26 4.1 131.32 13.05 0.23 3.9 0.016 1.88 24.8 23.9 0.44 222 0.51 2.25 4.3 13.71.17 12.1 0.21 3.3 0.014 1.79 21 21.2 0.39 197 0.42 2.26 3.7 11.81.28 12.7 0.23 3.6 0.015 1.83 25.7 24.5 0.42 226 0.6 2.26 4.3 13.21.21 12.2 0.21 3.5 0.016 1.8 22.9 22.7 0.43 208 0.52 2.24 4.3 14.91.34 13.1 0.25 4 0.019 1.91 25.8 23.7 0.45 216 0.64 2.33 4.7 15.16.72 27.3 0.16 4.9 0.089 0.5 22 35.7 0.32 487 2.45 0.14 23.4 43.11.01 12 0.2 4 0.015 1.77 24.1 21.7 0.39 201 0.3 2.26 3.9 11.21.25 12.65 0.22 3.6 0.016 1.88 24.4 22.3 0.42 205 0.42 2.32 4.1 12.21.37 13 0.22 4.1 0.017 1.76 25.2 26.2 0.45 207 0.86 2.19 4.3 15.43.97 12.8 0.18 3.2 0.021 1.46 21.8 27.5 0.41 233 9 1.77 4.6 14.91.13 12.45 0.21 3.6 0.015 1.77 22.4 24.3 0.42 201 0.44 2.29 3.8 12.21.3 12.4 0.23 4.1 0.017 1.87 28.3 24.2 0.44 224 0.75 2.27 5.1 15.81.42 12.45 0.23 3.9 0.02 1.92 27.3 23.9 0.46 231 0.69 2.3 4.4 14.81.35 12.65 0.23 3.3 0.016 1.86 30 23.9 0.47 236 0.5 2.27 3.7 13.31.34 12.75 0.14 3.7 0.016 1.88 27.3 26.8 0.44 215 0.78 2.26 4 14.71.19 12.25 0.12 3 0.013 1.82 19.5 25.4 0.4 205 0.47 2.3 3.5 141.28 13.05 0.14 3.6 0.016 1.82 24.5 25 0.47 205 0.49 2.23 4.5 18.60.95 12.3 0.14 3 0.014 1.72 22.3 25.5 0.39 197 0.36 2.28 3.7 11.61.52 13 0.15 3.1 0.016 1.89 29.8 30.4 0.6 222 0.31 2.14 5.8 30.70.43 8.31 0.12 1.9 0.009 1.16 17.6 10 0.18 101 0.65 1.59 2.2 8.40.65 11.25 0.12 2.1 0.01 1.62 15.9 22.2 0.29 134 0.19 2.24 2.2 8.5D.4 4-Acid ICP-[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Fe Ga Ge Hf In K La Li Mg Mn Mo Na Nb Ni% ppm ppm ppm ppm % ppm ppm % ppm ppm % ppm ppmD.4 4-Acid ICP-MS0.21 1.83 0.1 0.5 0.007 0.17 17.7 1.5 0.04 15 0.51 0.18 0.8 8.56.7 25.8 0.12 4.4 0.091 0.49 23 34.6 0.32 484 2.35 0.14 22.9 42.80.2 1.1 <0.05 0.2 0.023 0.07 14.4 0.6 0.03 8 0.5 0.06 0.5 8.10.55 4.4 0.06 1 0.013 0.56 15.9 3.4 0.06 34 0.44 0.55 1.6 9.80.77 11.4 0.08 3.2 0.015 1.76 18.9 20.6 0.34 162 0.14 2.22 3.3 10.80.98 12.3 0.09 3.7 0.017 1.81 25.8 24.9 0.41 222 0.34 2.2 4.4 14.30.99 11.7 0.1 3.9 0.017 1.66 24.7 21 0.36 181 0.4 2.02 3.9 11.71.17 12.25 0.1 3.4 0.014 1.73 24.5 23.5 0.38 187 0.36 2.19 4.1 13.41.11 12.15 0.08 3.5 0.016 1.73 22.7 21.9 0.36 188 0.49 2.15 3.6 12.41.13 12 0.09 3.4 0.015 1.7 22.8 21.5 0.35 192 0.49 2.12 3.4 13.21.07 11.3 0.09 3.3 0.015 1.76 23.3 18.7 0.37 202 0.44 2.2 3.9 131.27 12.85 0.09 3.4 0.017 1.81 21.9 23.3 0.49 207 0.43 2.08 5.1 19.51.38 12.55 0.09 3 0.013 1.59 19.6 20.3 0.43 235 0.76 2.03 3.7 12.51.17 12.55 0.1 3.3 0.018 1.79 27.3 25.6 0.57 211 0.41 2.08 5.4 28.51.12 11.65 0.1 3 0.016 1.74 22.3 22.8 0.42 200 0.58 2.1 3.7 18.51.33 12.8 0.11 3.9 0.017 1.87 26.2 22.5 0.46 212 0.72 2.19 4.9 17.91.23 12.3 0.11 3.5 0.016 1.82 31 24 0.52 204 0.48 2.17 4.7 25.11.15 11.95 0.09 3.5 0.016 1.83 26.6 21.5 0.45 196 0.4 2.19 4 19.41.36 13.15 0.12 3.7 0.019 1.83 27.2 28.8 0.49 198 0.77 2.2 5 22.81.16 12.35 0.15 3.9 0.017 1.83 27.6 24.1 0.42 210 0.47 2.23 4.1 15.31.31 12.7 0.16 4 0.017 1.85 34.4 25.6 0.6 238 0.32 2.22 6.1 29.21.13 12.55 0.14 3.3 0.014 1.76 22.2 21.5 0.49 185 0.33 2.16 5 17.40.98 11.1 0.15 3.1 0.013 1.64 18.6 20.2 0.29 163 0.49 2.04 3.2 10.21.46 13.1 0.18 4.2 0.019 1.9 31.4 28.2 0.55 244 0.68 2.13 6 25.81.52 13.1 0.19 3.7 0.019 1.86 27.3 30.8 0.59 246 0.86 2.14 6 30.31.19 12.2 0.2 3.1 0.014 1.78 19.7 25 0.42 192 0.55 2.18 3.8 14.11.51 13.1 0.21 3.2 0.018 1.85 26.6 31 0.67 235 0.65 2.14 6.8 32.51.19 12.75 0.21 3.6 0.02 1.73 40.4 26.6 0.63 201 0.26 2.02 7.2 28.61.19 12.45 0.22 4.2 0.015 1.84 32.5 23.2 0.42 209 0.6 2.22 4.3 13.21.25 12.65 0.19 3.9 0.018 1.8 27.8 24.3 0.41 186 0.59 2.19 4.3 13.71.22 12.15 0.21 3.5 0.015 1.81 23.7 22.7 0.38 190 0.54 2.24 3.9 121.2 12.4 0.2 3.5 0.015 1.83 25 24.2 0.4 202 0.44 2.25 4 13.[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Fe Ga Ge Hf In K La Li Mg Mn Mo Na Nb Ni% ppm ppm ppm ppm % ppm ppm % ppm ppm % ppm ppmD.4 4-Acid ICP-MS1.08 12.25 0.2 3.5 0.014 1.76 24.5 24 0.37 198 0.45 2.3 3.9 12.11.11 12 0.21 4 0.014 1.77 24.8 24.1 0.37 204 0.46 2.24 3.8 12.36.53 26.2 0.17 4.8 0.089 0.49 23.7 36 0.31 473 2.47 0.13 23.7 44.61.18 12.35 0.21 4.2 0.015 1.83 22.4 27.8 0.39 206 0.53 2.31 3.9 13.21.12 12 0.21 3.3 0.014 1.77 22.7 23.2 0.37 204 0.44 2.25 3.6 12.71.17 11.7 0.2 3.3 0.013 1.71 24.4 24.6 0.36 196 0.49 2.17 3.6 11.61.11 12.35 0.23 3.5 0.017 1.77 25.5 24.8 0.38 198 0.42 2.21 4 12.71.14 12.55 0.2 3.4 0.017 1.77 25.3 25.8 0.38 192 0.49 2.25 4.1 13.61.11 12.05 0.22 3.9 0.012 1.73 24.6 25.9 0.37 197 0.48 2.23 3.7 12.31.16 12.25 0.24 2.9 0.017 1.82 24.2 28.4 0.4 186 0.43 2.08 3.4 14.91.26 13 0.23 4.1 0.016 1.9 30.4 28.3 0.43 205 0.42 2.17 4.4 16.31.54 13 0.12 3 0.02 1.85 22.7 25.3 0.44 217 1.16 2.21 3.6 18.41.44 13.35 0.13 3.7 0.019 2 27.3 27.1 0.48 219 0.57 2.27 4.3 18.41.26 12.3 0.12 3.2 0.015 1.81 20.3 21.6 0.4 197 0.47 2.29 4.3 13.31.07 11.45 0.12 3.1 0.013 1.76 18.7 20 0.34 182 0.41 2.37 2.8 12.30.71 11.2 0.14 2.9 0.013 1.68 20 18.9 0.29 160 0.21 2.31 3 8.20.78 11.6 0.13 3.2 0.014 1.74 23.8 16.8 0.31 151 0.23 2.2 3.5 9.91.15 12.55 0.17 3.9 0.016 1.9 29.7 23.4 0.46 210 0.41 2.3 4.1 13.81.2 12.15 0.16 3.6 0.018 1.86 25.4 21.1 0.4 203 0.43 2.32 3.5 13.56.69 26.2 0.13 5.1 0.091 0.49 23 33.7 0.31 479 2.44 0.14 23 44.41.11 11.1 0.12 3 0.013 1.61 23.3 17.5 0.33 183 0.5 2.16 3 10.41.4 12.7 0.14 4 0.019 1.92 29.1 23.2 0.44 242 0.64 2.33 4.3 15.21.4 12.6 0.14 3.7 0.018 1.95 28 22.9 0.44 229 0.71 2.34 4.1 15.31.19 12.95 0.15 3.4 0.019 1.82 28.8 24 0.42 184 0.4 2.22 3.9 14.60.55 10.75 0.12 2.5 0.01 1.62 16.4 13.7 0.23 122 0.14 2.2 2.5 6.30.72 11 0.11 2.6 0.012 1.67 19.8 17.1 0.29 152 0.2 2.29 2.5 7.80.33 8.71 0.11 2.4 0.009 1.31 18.4 7.6 0.12 84 0.21 1.82 2 5.81.03 12.35 0.12 3.4 0.018 1.75 25.5 22.3 0.39 188 0.17 2.28 3.9 12.60.91 12.25 0.14 3.3 0.016 1.68 24.6 21.4 0.37 172 0.19 2.2 3.8 11.70.12 1.99 0.1 0.5 0.01 0.19 14.4 1.3 0.03 13 0.56 0.18 0.8 7.90.31 3.32 0.1 0.7 0.01 0.32 21.4 2.2 0.06 25 1.18 0.33 1.3 12.41.16 12.65 0.11 3.4 0.021 1.83 29.4 24.6 0.43 211 0.45 2.33 4 15.[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Fe Ga Ge Hf In K La Li Mg Mn Mo Na Nb Ni% ppm ppm ppm ppm % ppm ppm % ppm ppm % ppm ppmD.4 4-Acid ICP-MS1.06 11.8 0.13 3.4 0.015 1.73 23.5 19.8 0.34 189 0.43 2.34 3.3 11.71.2 11.75 0.12 3.7 0.015 1.69 25.7 19.3 0.36 194 0.57 2.27 3.4 11.81.13 12.85 0.13 3.5 0.017 1.8 29.5 24.5 0.44 197 0.24 2.27 4.1 14.30.87 9.86 0.11 2.3 0.019 1.11 21.4 11.9 0.17 150 0.86 1 3.9 10.36.78 25.7 0.14 4.9 0.092 0.5 24.2 34.1 0.31 483 2.4 0.14 23.3 43.80.71 4.49 0.1 1 0.012 0.5 19.9 3.8 0.08 44 0.5 0.47 1.7 12.56.85 26.2 0.12 5.1 0.091 0.49 24.1 34.1 0.32 485 2.39 0.14 24 44.60.48 2.71 0.1 0.7 0.011 0.3 18 2 0.04 23 0.94 0.31 1.1 12.40.91 4.43 0.11 1.1 0.014 0.5 23.4 4.3 0.09 49 0.43 0.52 1.6 13.60.9 12.15 0.13 3.5 0.018 1.75 24 19.5 0.36 183 0.21 2.29 3.8 11.30.76 11.35 0.14 3.2 0.013 1.67 21 17.9 0.3 164 0.23 2.24 3.2 9.21.02 12.85 0.13 3.6 0.018 1.9 24.2 21.2 0.38 178 0.15 2.37 3.9 121.03 12.55 0.12 3.6 0.015 1.77 23.9 24.4 0.39 179 0.17 2.22 3.9 13.51.13 11.3 0.11 3.2 0.012 1.66 22 18.9 0.32 166 0.55 2.26 2.9 10.10.8 11.25 0.11 3.4 0.01 1.67 18.8 18.2 0.31 158 0.25 2.28 2.8 9.50.91 11.9 0.12 3.7 0.017 1.75 27.6 19.5 0.37 199 1.05 2.26 4.1 15.60.22 3.33 0.12 1.1 0.012 0.42 15.4 2.3 0.06 43 1.33 0.53 1.4 12.50.14 2.35 0.1 0.6 0.009 0.21 15.8 1.4 0.04 30 1.09 0.27 1.1 11.70.78 11.6 0.14 2.9 0.015 1.73 23.8 19.3 0.33 161 0.24 2.24 3.6 9.80.89 11.85 0.12 3.2 0.014 1.75 23 21.7 0.37 190 0.35 2.3 3.7 110.27 3.16 0.13 1.1 0.01 0.35 25.9 2.8 0.06 32 0.73 0.45 1.3 14.11.02 11.9 0.12 3.2 0.017 1.73 26.4 23.9 0.43 196 0.31 2.12 4 13.76.84 26.6 0.1 4.8 0.092 0.5 24.1 35.2 0.33 497 2.44 0.14 24 44.91.01 11.35 0.12 2.8 0.012 1.7 25.1 18.1 0.33 193 0.49 2.31 3 9.72.57 15.8 0.11 4 0.025 1.81 33.2 44.6 0.92 446 1.3 2.27 4.8 24.21.28 12.85 0.13 4 0.017 1.92 29.3 23.2 0.45 228 0.55 2.35 4.8 15.31.21 12.5 0.11 3.8 0.017 1.86 27.8 24.1 0.43 206 0.51 2.36 4.2 15.21.14 11.7 0.13 3.6 0.014 1.71 23.9 20.4 0.38 192 0.57 2.23 3.8 111.46 13.7 0.14 3.8 0.016 2.04 28.5 24.8 0.46 239 0.96 2.52 4.3 151.33 12.75 0.12 3.7 0.018 1.85 26.5 23.1 0.48 218 0.61 2.29 4.5 15.51.01 11.35 0.1 3.1 0.01 1.71 20.4 20.1 0.42 196 0.43 2.21 3.9 14.80.18 2 0.1 0.5 0.009 0.18 22.7 1.7 0.04 16 0.37 0.2 0.9 11328SAMPLEQ515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Fe Ga Ge Hf In K La Li Mg Mn Mo Na Nb Ni% ppm ppm ppm ppm % ppm ppm % ppm ppm % ppm ppmD.4 4-Acid ICP-MS1.48 13.45 0.12 3.6 0.018 1.93 27.7 25.9 0.73 214 0.41 2.17 8.9 35.31.33 13.1 0.15 4.1 0.021 1.89 36.8 23.5 0.71 226 0.22 2.27 10.1 33.21.15 12.65 0.12 3.8 0.016 1.88 25.6 23.1 0.41 202 0.4 2.35 4 14.20.88 11.7 0.14 3.5 0.015 1.77 25.9 19.6 0.34 188 0.23 2.31 3.6 9.70.8 11.85 0.13 3.6 0.015 1.77 23.6 19.2 0.33 193 0.2 2.38 3.4 8.90.65 11.05 0.11 2.9 0.011 1.71 18.8 16.7 0.27 151 0.21 2.31 2.8 7.26.84 26.9 0.12 4.9 0.089 0.51 24.8 36.7 0.33 498 2.49 0.15 24.2 45.[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61P Pb Rb Re S Sb Sc Se Sn Sr Ta Te Th Tippm ppm ppm ppm % ppm ppm ppm ppm ppm ppm ppm ppm %650 32 52.5 <0.002 0.01 1.48 4.2 1 0.6 290 0.32 <0.05 5.77 0.172560 28.4 50.6 <0.002 0.01 0.33 4.2 1 0.6 295 0.32 <0.05 6.5 0.183830 30.5 50.6 <0.002 0.01 0.22 5.7 1 0.8 284 0.51 <0.05 7.1 0.2331200 23.3 12 <0.002 0.45 0.27 3.2 1 0.3 53.4 0.13 <0.05 3.82 0.063640 19.7 50.9 <0.002 0.02 0.13 4.8 1 0.7 288 0.44 <0.05 6.02 0.192720 15.2 56.2 <0.002 0.01 0.11 4.8 1 0.7 305 0.41 <0.05 5.66 0.196760 14.8 56.5 <0.002 0.01 0.11 4.6 1 0.7 307 0.37 <0.05 6.38 0.197760 14.1 58.1 <0.002 0.01 0.09 5.2 1 0.8 306 0.41 <0.05 6.62 0.229740 15.1 55.5 <0.002 0.01 0.1 4.9 1 0.7 295 0.37 <0.05 8.55 0.206750 16.2 56 <0.002 0.01 0.17 4.8 1 0.7 286 0.43 <0.05 6.22 0.198670 14.4 55.4 <0.002 0.01 0.1 4.8 1 0.7 290 0.5 <0.05 6.32 0.197760 15.5 57 <0.002 0.01 0.1 5 1 0.8 298 0.4 <0.05 6.82 0.209670 13.7 53.3 <0.002 0.01 0.07 4.5 1 0.7 289 0.33 <0.05 5.37 0.184720 13.8 56.6 <0.002 0.01 0.09 5 1 0.8 290 0.46 <0.05 6.58 0.208700 15 53.5 <0.002 0.01 0.1 4.7 1 0.8 290 0.41 <0.05 5.72 0.199720 14.4 57.8 <0.002 0.01 0.11 5.2 1 0.8 297 0.42 <0.05 6.43 0.222520 24.2 59.6 <0.002 0.06 0.69 14.7 4 3.8 49.6 1.67 <0.05 16.2 1.045690 13.4 52.1 <0.002 0.01 0.09 4.6 1 0.7 291 0.37 <0.05 7.06 0.197760 13.5 54.8 <0.002 0.01 0.1 4.9 1 0.8 299 0.42 <0.05 6.29 0.207730 13.2 52 <0.002 0.01 0.09 5.2 1 0.8 283 0.41 <0.05 7.01 0.213860 14.1 43.2 <0.002 0.05 0.1 5.3 1 0.8 231 0.37 <0.05 6.6 0.212500 13.5 48.8 <0.002 0.01 0.1 4.6 1 0.7 293 0.36 <0.05 5.83 0.207800 14 54.8 <0.002 0.01 0.12 5 1 0.7 291 1.52 <0.05 8.37 0.222840 13.7 54.1 <0.002 0.01 0.09 5.2 1 0.8 301 0.43 <0.05 6.89 0.229680 13.2 53.4 <0.002 0.01 0.09 4.9 1 0.7 294 0.33 <0.05 8.9 0.197750 15.6 55.1 <0.002 0.01 0.1 5.2 1 0.7 277 0.36 <0.05 7.72 0.203610 14.4 55.8 <0.002 0.01 0.09 4.5 <1 0.6 277 0.31 <0.05 5.77 0.174670 14.6 56.6 <0.002 0.01 0.11 4.9 1 0.7 275 0.37 <0.05 6.94 0.193500 14.1 51.2 <0.002 0.01 0.11 4.4 <1 0.7 274 0.32 <0.05 5.84 0.177750 14.7 63 <0.002 0.01 0.14 5.7 1 0.8 264 0.45 <0.05 7.33 0.213570 9.4 33 <0.002 0.13 0.09 3.3 1 0.4 190 0.19 <0.05 4.72 0.114450 12 46.6 <0.002 0.01 0.08 3.3 1 0.5 264 0.18 <0.05 5.11 0.112D.4 4-Acid ICP-[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61P Pb Rb Re S Sb Sc Se Sn Sr Ta Te Th Tippm ppm ppm ppm % ppm ppm ppm ppm ppm ppm ppm ppm %D.4 4-Acid ICP-MS1010 4.7 5.4 <0.002 0.37 0.1 2.7 1 0.2 32.6 0.06 <0.05 3.59 0.034510 25 61.1 <0.002 0.05 0.72 13.3 3 3.9 46.5 1.65 <0.05 17.5 1.015980 3 2.6 <0.002 0.26 0.12 2 1 <0.2 22.6 <0.05 <0.05 2.38 0.0231100 6.1 18.6 <0.002 0.26 0.12 3.1 1 0.4 82.8 0.16 <0.05 3.6 0.069550 13.5 53.7 <0.002 0.02 0.1 4.4 1 0.7 292 0.32 <0.05 5.04 0.157680 14.5 58.9 <0.002 0.01 0.11 5.2 1 0.8 290 0.38 <0.05 7.01 0.195610 13.9 54.9 <0.002 0.02 0.11 5 1 0.7 269 0.39 <0.05 7.57 0.167690 14 57 <0.002 0.01 0.1 4.9 1 0.7 288 0.46 <0.05 6.87 0.163610 13.8 56.4 <0.002 0.01 0.1 4.7 1 0.7 282 0.32 <0.05 6.45 0.163610 14.1 55.1 <0.002 0.01 0.11 4.4 1 0.6 280 0.31 <0.05 6.61 0.163750 13.5 53.6 <0.002 0.01 0.1 4.6 1 0.6 289 0.45 <0.05 6.38 0.174570 13.7 62.4 <0.002 0.01 0.16 5.5 1 0.8 273 0.43 <0.05 6.01 0.19310 12.7 51.6 <0.002 0.01 0.1 4.7 1 0.9 276 0.33 <0.05 6.78 0.191740 14.6 60.9 <0.002 0.01 0.13 5.4 1 0.7 273 0.52 <0.05 7.32 0.182700 14.1 57.5 <0.002 0.01 0.11 4.4 1 0.6 277 0.36 <0.05 6.36 0.161690 14.6 62.6 <0.002 0.01 0.11 5.6 1 0.8 287 1.09 <0.05 7.57 0.193670 15.1 58.5 <0.002 0.01 0.09 5.1 1 0.7 289 0.42 <0.05 8.89 0.182730 14 58.8 <0.002 <0.01 0.09 5 1 0.7 288 0.4 <0.05 7.62 0.182680 14.4 59.3 <0.002 0.01 0.12 5.3 1 0.8 282 0.47 <0.05 7.13 0.198710 14.1 55 <0.002 0.01 0.11 4.7 1 0.7 294 0.36 <0.05 6.78 0.2820 14.6 58.4 <0.002 <0.01 0.12 5.4 1 0.8 291 0.51 <0.05 8.08 0.233540 13 55 <0.002 0.01 0.11 4.5 1 0.7 274 0.39 <0.05 5.3 0.189360 12.8 51.2 <0.002 0.01 0.1 3.8 1 0.6 256 0.25 <0.05 4.97 0.15770 15.1 61.2 <0.002 0.01 0.14 5.5 1 0.9 274 0.56 <0.05 7.83 0.23740 15.4 62.2 <0.002 0.01 0.14 5.6 1 0.9 276 0.5 <0.05 7.01 0.213560 13 54.7 <0.002 0.01 0.13 4.3 1 0.6 274 0.5 <0.05 4.82 0.172680 15.6 62.1 <0.002 0.01 0.18 5.4 1 0.8 276 0.48 <0.05 7.3 0.197710 16.5 58.3 <0.002 0.02 0.15 5.5 1 0.8 263 0.55 <0.05 10.25 0.199700 14.8 56.9 <0.002 0.01 0.12 4.9 1 0.8 285 0.87 <0.05 8.13 0.207670 14.6 56.7 <0.002 0.01 0.11 5.1 1 0.7 282 0.36 <0.05 6.7 0.198730 13.7 55 <0.002 0.01 0.12 4.7 1 0.7 285 1.66 <0.05 5.77 0.182690 13.8 57 <0.002 0.01 0.11 4.8 1 0.8 286 0.36 <0.05 6.11 0.[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61P Pb Rb Re S Sb Sc Se Sn Sr Ta Te Th Tippm ppm ppm ppm % ppm ppm ppm ppm ppm ppm ppm ppm %D.4 4-Acid ICP-MS710 13.9 54.7 <0.002 <0.01 0.11 4.5 1 0.8 290 0.35 <0.05 5.99 0.191680 13.6 54.1 <0.002 0.01 0.11 4.6 1 0.7 284 0.35 <0.05 6.28 0.19500 24.5 61.1 <0.002 0.05 0.73 13.8 4 4 47.9 1.63 0.07 16 1.01700 13.5 55.9 <0.002 <0.01 0.11 4.7 1 0.7 291 0.33 <0.05 5.24 0.194670 13 53.4 <0.002 0.01 0.09 4.4 1 0.7 285 0.31 <0.05 5.52 0.184650 13.9 53.7 <0.002 0.01 0.1 4.5 1 0.6 279 0.31 <0.05 6.94 0.173650 13.6 55.4 <0.002 <0.01 0.11 4.8 1 0.8 282 0.35 <0.05 6.06 0.195690 14.2 57.6 <0.002 <0.01 0.11 4.8 1 0.7 284 0.36 <0.05 6.15 0.184660 13.4 54.3 <0.002 0.01 0.11 4.6 1 0.7 284 0.31 <0.05 6.56 0.181630 14.2 56.8 <0.002 0.01 0.11 4.5 1 0.7 259 0.29 <0.05 6.5 0.164800 14.5 59.7 <0.002 <0.01 0.11 5.3 1 0.8 269 0.42 <0.05 7.95 0.21620 15.6 57.3 <0.002 0.01 0.1 4.6 1 0.7 276 0.33 <0.05 6.55 0.188780 14.3 62.7 <0.002 0.01 0.1 5.3 1 0.8 276 0.42 <0.05 7.06 0.212630 13.2 56.2 <0.002 0.01 0.08 4.3 1 0.6 283 0.56 <0.05 5.26 0.183640 12.7 52.8 <0.002 0.01 0.08 3.6 1 0.6 291 0.3 <0.05 4.88 0.157540 12.5 51 <0.002 0.02 0.08 3.2 1 0.5 282 0.29 <0.05 5.27 0.145540 12.8 52.4 <0.002 0.04 0.08 4.1 1 0.7 272 0.37 <0.05 5.9 0.167780 13.7 55.9 <0.002 0.03 0.08 5.1 1 0.8 287 0.41 <0.05 7.32 0.224790 13.6 56.7 <0.002 <0.01 0.07 4.4 1 0.7 286 0.35 <0.05 7.26 0.192500 24.1 63.1 <0.002 0.05 0.64 13.2 4 3.9 47.2 1.73 <0.05 16.45 1.015600 13.1 48.5 <0.002 0.01 0.06 3.6 1 0.6 272 0.35 <0.05 6.47 0.17770 13.9 59.2 <0.002 0.01 0.07 4.8 1 0.8 289 0.43 <0.05 7.66 0.219810 15 58.4 <0.002 0.01 0.07 4.7 1 0.7 291 0.47 <0.05 7.53 0.202700 13.6 60.6 <0.002 0.01 0.07 4.9 1 0.8 272 0.38 <0.05 8.08 0.185300 12 47.3 <0.002 0.01 0.06 2.7 1 0.5 266 0.22 <0.05 4.02 0.132520 12.5 48.7 <0.002 0.01 0.06 3 1 0.5 278 0.22 <0.05 5.38 0.138450 10.4 38.9 <0.002 0.09 0.06 2.3 1 0.4 224 0.2 <0.05 4.23 0.104660 13 55.2 <0.002 0.04 0.07 4.8 1 0.8 282 0.82 <0.05 5.5 0.191590 13 53.4 <0.002 0.03 0.07 4.6 1 0.7 272 0.37 <0.05 6.08 0.1831020 2.7 6.5 <0.002 0.3 0.07 2.5 1 0.2 32.4 0.08 <0.05 2.61 0.0351330 5.2 11 <0.002 0.4 0.07 3.1 1 0.2 50.9 0.11 <0.05 3.71 0.06680 13.5 60.3 <0.002 0.01 0.09 5 1 0.8 291 0.36 <0.05 6.85 0.[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61P Pb Rb Re S Sb Sc Se Sn Sr Ta Te Th Tippm ppm ppm ppm % ppm ppm ppm ppm ppm ppm ppm ppm %D.4 4-Acid ICP-MS630 13.5 53.4 <0.002 0.01 0.06 3.9 <1 0.6 288 0.31 <0.05 6.17 0.174720 13.5 53.6 <0.002 0.01 0.06 4.2 1 0.6 281 0.36 <0.05 7.92 0.18640 13.7 56.3 <0.002 0.02 0.06 5.1 1 0.8 283 0.4 <0.05 8.31 0.208790 10.5 42 <0.002 0.15 0.09 5.7 1 0.6 126.5 0.39 <0.05 6.57 0.154510 24 62.3 <0.002 0.05 0.65 13.1 3 3.8 46.5 1.68 0.05 16.85 1.0351230 5.5 18.6 <0.002 0.33 0.08 3.2 1 0.3 67.4 0.17 <0.05 3.93 0.073530 26.9 63.2 <0.002 0.06 0.69 13.6 4 3.9 47.8 1.75 <0.05 17.15 1.0751140 4.6 10.7 <0.002 0.44 0.07 2.6 1 0.2 47.2 0.16 <0.05 3.28 0.0471170 6 17.7 <0.002 0.32 0.08 3.2 1 0.3 75.9 0.16 <0.05 3.9 0.071620 13.6 55.4 <0.002 0.03 0.06 4.4 1 0.7 285 0.39 <0.05 5.94 0.189600 12.5 50.7 <0.002 0.02 0.06 3.8 1 0.6 276 0.3 <0.05 5.27 0.163640 13.2 61.6 <0.002 0.01 0.06 4.7 1 0.9 290 0.37 <0.05 6.02 0.192560 13.2 58.9 <0.002 0.01 0.07 4.8 <1 0.8 276 0.39 <0.05 5.81 0.192660 13 51.3 <0.002 0.01 0.05 3.6 1 0.6 277 0.28 <0.05 5.89 0.156530 12.7 51 <0.002 <0.01 0.05 3.5 1 0.6 280 0.28 <0.05 5.08 0.148670 17.3 53.3 0.002 0.02 0.1 4.7 1 0.7 286 0.42 <0.05 7.68 0.196670 5.4 13.7 0.002 0.5 0.13 2.9 1 0.3 77.5 0.11 <0.05 5.23 0.058710 3.2 7.1 0.002 0.62 0.09 2.8 1 0.2 44.1 0.08 <0.05 3.93 0.042570 12.7 51.7 <0.002 0.02 0.08 4.1 1 0.7 278 0.52 <0.05 6.18 0.177520 12.8 51.9 <0.002 0.04 0.08 4.4 <1 0.6 288 0.33 <0.05 5.74 0.1951060 5.3 11.4 <0.002 0.48 0.09 3.4 1 0.2 66.5 0.11 <0.05 5.86 0.059700 13.4 53.4 <0.002 0.07 0.07 5.4 1 0.7 268 0.48 <0.05 7.08 0.198530 24 61.7 <0.002 0.06 0.7 14.1 3 4 48.7 1.71 0.05 16.95 1.07670 13.3 51.6 <0.002 0.01 0.07 3.6 1 0.5 284 0.28 <0.05 8.49 0.165880 15.6 58 <0.002 0.01 0.07 7.6 1 0.9 320 1 <0.05 11.55 0.269780 14 58.9 <0.002 0.01 0.07 5.2 1 0.8 293 0.47 <0.05 7.52 0.219730 13.6 58.4 <0.002 0.01 0.06 4.8 <1 0.7 294 0.42 <0.05 7.78 0.199580 13.2 52.7 <0.002 0.01 0.07 4.4 <1 0.7 283 0.38 <0.05 6.58 0.178730 15.1 64.3 <0.002 0.01 0.08 5.2 1 0.8 319 0.38 <0.05 9.37 0.204690 13.5 58.4 <0.002 0.01 0.07 5.3 1 0.8 289 0.43 <0.05 6.77 0.213580 12.4 52.3 <0.002 0.01 0.06 4.2 <1 0.6 276 0.33 <0.05 5.64 0.1791440 4 6.2 <0.002 0.43 0.08 3.4 1 <0.2 35.5 0.07 <0.05 5.6 0.032333SAMPLEQ515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61P Pb Rb Re S Sb Sc Se Sn Sr Ta Te Th Tippm ppm ppm ppm % ppm ppm ppm ppm ppm ppm ppm ppm %D.4 4-Acid ICP-MS690 13.6 63.5 <0.002 0.01 0.11 5.8 1 0.8 280 0.65 <0.05 6.93 0.212710 14.3 62.6 <0.002 0.01 0.13 5.8 1 0.8 294 0.72 <0.05 9.07 0.229680 13.6 58.4 <0.002 0.01 0.07 4.9 1 0.7 297 0.39 <0.05 6.5 0.197680 13.1 52.9 <0.002 0.01 0.06 4.1 1 0.6 289 0.52 <0.05 6.99 0.18640 13.2 53.1 <0.002 0.01 0.06 4.1 1 0.6 296 0.33 <0.05 6.59 0.177490 12.3 51.3 <0.002 0.02 0.06 3.6 <1 0.5 286 0.25 <0.05 4.76 0.149530 24.4 63.4 <0.002 0.05 0.7 14.7 3 4 50.9 1.73 0.07 17.5 1.[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Tl U V W Y Zn Zrppm ppm ppm ppm ppm ppm ppm0.28 1.5 26 0.4 9.4 36 1220.27 1.4 28 0.4 8.8 21 123.50.27 1.7 66 0.6 10.2 29 1440.11 3.6 30 0.4 8.9 8 29.70.29 1.5 26 0.5 9.3 17 132.50.32 1.6 28 0.7 9.7 18 1370.32 1.6 31 0.5 9.5 18 1250.33 1.8 35 0.6 10.7 20 1580.32 2.1 31 0.5 10.6 19 142.50.31 1.5 31 0.5 9.9 20 139.50.31 1.7 31 0.8 9.5 20 1310.31 1.6 33 0.6 10.2 22 145.50.29 1.3 29 1 8.8 18 1220.31 1.8 33 0.5 9.8 20 1380.3 1.6 31 0.5 9.6 19 1300.32 1.8 34 0.6 10.3 21 153.50.33 2.7 162 2.3 12.8 44 1780.3 1.8 27 0.5 9.6 17 148.50.31 1.8 32 0.5 9.9 19 134.50.32 1.8 38 0.5 10.1 24 1490.32 2 96 1.1 7.8 26 113.50.28 1.5 31 0.4 8.2 18 132.50.3 2.2 33 0.5 10.4 24 151.50.31 1.9 34 0.5 10.7 23 144.50.3 1.9 33 0.7 10.1 23 1250.32 2.5 33 0.6 8.9 23 140.50.33 1.5 29 0.4 7 22 1170.33 1.8 31 0.5 8.3 23 144.50.32 1.5 26 0.4 7.2 17 1210.38 2.3 39 0.6 9.5 30 1280.2 1.8 16 0.3 5.7 9 77.10.27 1.1 18 0.2 5.3 13 83.7D.4 4-Acid ICP-[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Tl U V W Y Zn Zrppm ppm ppm ppm ppm ppm ppmD.4 4-Acid ICP-MS0.07 3.5 10 0.3 6.8 2 18.10.34 3 158 2.3 11.4 45 175.50.03 3.1 13 0.3 6.7 3 8.30.14 2.7 19 0.4 7 6 35.70.3 1.5 24 0.6 7.7 16 113.50.31 2 27 0.5 9.8 23 138.50.31 2.1 29 0.6 9.2 19 1400.32 1.7 29 0.4 9.3 19 1200.31 1.6 27 0.5 8.5 19 1250.29 1.7 27 0.6 8.7 18 1240.29 1.7 27 0.4 9.1 19 1210.35 1.5 35 0.6 8 27 1210.28 1.4 39 0.4 6.5 21 110.50.35 2.3 32 5.9 9.9 29 123.50.31 1.6 28 0.9 8.9 22 1080.33 2.2 33 0.5 9.8 24 1370.31 3.2 32 0.7 10.3 25 127.50.32 2.2 30 0.7 9.7 24 1210.35 2 36 0.7 9.1 26 144.50.3 1.9 31 0.6 9.7 22 1490.33 2.3 36 0.6 11 27 149.50.3 1.4 30 0.4 7.4 21 125.50.3 1.4 23 0.3 6.6 16 118.50.35 2.2 38 0.8 10.5 27 157.50.38 2 37 0.5 9.3 30 1410.31 1.4 31 0.4 7 22 116.50.35 1.8 39 0.5 9.3 32 1250.36 3.7 35 0.9 11.4 32 1350.32 2.3 33 0.5 9.6 21 156.50.33 1.9 33 0.8 9 21 145.50.3 1.6 32 1.5 8.6 20 139.50.31 1.7 32 2 8.8 20 132.[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Tl U V W Y Zn Zrppm ppm ppm ppm ppm ppm ppmD.4 4-Acid ICP-MS0.31 1.7 29 3.4 9 19 1280.31 1.7 29 0.5 8.8 19 152.50.33 2.9 158 2.4 12.3 45 1810.31 1.7 31 0.5 10.3 21 141.50.31 1.4 30 0.5 8.2 19 127.50.31 1.6 27 0.4 8.5 19 1280.32 1.6 30 0.5 9 19 1340.33 1.7 29 0.5 8.8 20 129.50.29 1.6 28 0.5 8.6 19 150.50.32 2.2 30 0.4 8.3 22 1110.34 2.1 34 0.5 10.2 23 152.50.34 1.9 35 0.6 8 26 109.50.36 1.9 36 0.6 9.7 27 1320.32 1.4 31 0.5 7.3 22 114.50.31 1.4 25 0.3 7.1 19 1090.29 1.5 19 0.9 6.7 14 104.50.32 1.8 23 0.4 7.8 15 112.50.34 1.9 34 0.5 9.7 24 136.50.32 1.8 31 0.5 9.1 22 125.50.36 3 157 2.4 12.2 45 1880.28 1.5 25 0.6 7.2 18 105.50.33 2 34 0.8 9.7 24 1430.34 2.1 34 0.5 9.6 25 130.50.38 1.8 31 0.6 8.5 24 1240.28 1.1 16 0.4 4.7 10 92.70.29 1.4 19 0.2 6.3 13 95.60.23 1.7 14 0.3 5.5 5 87.50.35 1.9 29 0.5 8.6 19 118.50.32 1.9 28 0.5 8.7 18 114.50.08 2.7 10 0.2 6.4 4 15.30.1 3.7 13 0.4 8.6 5 260.32 1.8 33 0.5 9.2 25 125.[binary]-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Tl U V W Y Zn Zrppm ppm ppm ppm ppm ppm ppmD.4 4-Acid ICP-MS0.32 1.5 25 1 7.8 18 1200.31 1.7 32 0.4 8.6 18 127.50.34 2 31 0.5 9.1 24 125.50.36 3.5 31 0.9 7.9 12 82.10.35 2.9 157 2.3 12.4 45 178.50.17 3.4 34 0.5 8.5 7 37.60.36 3 160 2.5 14.4 46 180.50.11 3.2 32 0.4 9.1 8 24.20.15 3.5 25 0.4 9 7 37.40.31 1.7 27 0.5 8.2 18 123.50.31 1.5 21 0.4 7.5 14 118.50.36 1.7 29 0.5 8.4 19 1280.34 1.7 29 0.5 8.1 22 128.50.28 1.5 25 0.4 7.4 16 111.50.29 1.3 23 1.1 6.5 15 1180.31 1.9 27 0.4 9.5 23 127.50.11 4.2 8 0.4 5.8 6 38.80.08 4 10 0.4 6.3 4 17.90.31 1.5 23 0.4 7.5 14 1000.3 1.7 25 0.3 7.7 18 1140.1 5 15 0.2 8.1 5 34.30.33 2.5 30 0.4 8.7 26 110.50.34 3.1 164 2.3 13.6 45 1670.29 2.1 25 0.4 8.1 14 94.60.35 2.6 62 0.5 10.4 42 130.50.32 2 33 0.6 10.1 22 139.50.34 2.1 31 0.5 9.5 21 1290.3 1.7 30 0.4 8.1 17 119.50.36 2 36 0.6 9.8 21 132.50.32 1.9 35 0.6 9.1 23 125.50.29 1.5 26 3.1 7.4 19 1060.09 4.9 6 0.2 8.8 3 16.1338SAMPLEQ515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Tl U V W Y Zn Zrppm ppm ppm ppm ppm ppm ppmD.4 4-Acid ICP-MS0.37 2.3 41 0.6 9.6 31 122.50.37 2.7 39 0.7 10.9 29 1410.32 1.8 31 0.5 9 21 1280.29 1.7 23 0.4 8.5 15 117.50.31 1.5 22 0.3 8.3 15 121.50.31 1.3 18 0.5 6.7 11 99.20.34 3.2 164 2.4 14.9 44 172339ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSample Au Ag Al As B Ba Be Bi Ca Cd CeSAMPLE Site Type ppm ppm % ppm ppm ppm ppm ppm % ppm ppmQ515501 26 Soil 0.0011 0.013 0.39 4.52 <10 27 0.2 0.126 0.13 0.017 34.8Q515502 27 Soil 0.0016 0.02 0.49 5.83 <10 27.4 0.24 0.151 0.11 0.027 28.6Q515503 28 Soil 0.0016 0.008 0.59 28.1 <10 27.4 0.56 0.272 0.13 0.022 34.8Q515504 29 Soil 0.003 0.118 0.6 4.58 <10 46.7 0.43 0.248 0.2 0.31 37.6Q515505 30 Soil 0.0034 0.025 0.47 1.26 <10 27.5 0.2 0.119 0.12 0.032 32.5Q515506 31 Soil 0.0016 0.017 0.46 1.9 <10 26 0.24 0.131 0.15 0.032 35.8Q515507 125 Soil 0.0014 0.009 0.41 5.62 <10 27.4 0.2 0.106 0.15 0.022 36Q515508 124 Soil 0.0025 0.016 0.49 6.33 <10 29.2 0.23 0.133 0.15 0.031 43.3Q515509 123 Soil 0.0026 0.015 0.46 5.95 <10 29 0.23 0.126 0.15 0.027 40Q515510 122 Soil 0.0014 0.017 0.44 5.99 <10 29.2 0.19 0.118 0.15 0.029 35.9Q515511 121 Soil 0.0024 0.018 0.52 5.88 <10 30.8 0.23 0.127 0.14 0.022 37.3Q515512 120 Soil 0.002 0.015 0.52 6.19 <10 32 0.25 0.135 0.16 0.028 41Q515513 119 Soil 0.0035 0.013 0.46 5.5 <10 30.7 0.2 0.118 0.14 0.022 35.2Q515514 118 Soil 0.0014 0.014 0.5 5.93 <10 32.2 0.25 0.129 0.14 0.027 38.5Q515515 117 Soil 0.0014 0.015 0.44 5.09 <10 29.8 0.22 0.128 0.13 0.025 34.1Q515516 116 Soil 0.0056 0.014 0.51 5.51 <10 31.7 0.23 0.132 0.14 0.029 39.5Q515516a N/A CRM 0.0006 0.026 5.19 2.83 <10 54.5 0.64 0.279 0.14 0.037 28.9Q515517 14 Soil 0.002 0.019 0.45 3.19 <10 26.2 0.2 0.125 0.15 0.032 39.8Q515518 15 Soil 0.0017 0.018 0.5 4.38 <10 30.2 0.21 0.122 0.15 0.041 41.9Q515519 13 Soil 0.0015 0.016 0.64 5.59 <10 29.2 0.3 0.19 0.14 0.022 38Q515520 12 Soil 0.0022 0.02 0.8 56.9 <10 29.3 0.38 0.425 0.07 0.03 32.1Q515521 11 Soil 0.0034 0.013 0.44 3.22 <10 21.7 0.19 0.11 0.09 0.011 36.8Q515522 10 Soil 0.0015 0.018 0.55 5.1 <10 31.5 0.35 0.157 0.16 0.025 44.3Q515523 9 Soil 0.0017 0.016 0.58 5.45 <10 32.2 0.28 0.154 0.16 0.025 45.6Q515524 8 Soil 0.0019 0.018 0.55 5.04 <10 36.8 0.2 0.137 0.12 0.024 35.4Q515525 7 Soil 0.0035 0.028 0.55 5.64 <10 29.7 0.31 0.159 0.14 0.025 42.1Q515526 115 Soil 0.005 0.019 0.51 5.8 <10 28.6 0.23 0.126 0.12 0.035 31Q515527 114 Soil 0.0009 0.016 0.57 4.67 <10 32.3 0.22 0.131 0.12 0.038 34.9Q515528 113 Soil 0.001 0.018 0.44 1.88 <10 25.3 0.17 0.133 0.1 0.016 33.5Q515529 112 Soil 0.0021 0.026 0.67 5.11 <10 68 0.25 0.15 0.17 0.045 40.9Q515530 6 Soil 0.0016 0.049 0.46 1.29 <10 29.2 0.27 0.098 0.08 0.099 27.1Q515531 5 Soil 0.0011 0.018 0.35 0.48 <10 16.9 0.13 0.059 0.08 0.018 19.85D.5 Aqua-Regia ICP-MS340ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSample Au Ag Al As B Ba Be Bi Ca Cd CeSAMPLE Site Type ppm ppm % ppm ppm ppm ppm ppm % ppm ppmD.5 Aqua-Regia ICP-MSQ515551 77 Soil 0.002 0.17 0.63 2.16 <10 41.6 0.31 0.14 0.18 0.285 33.4Q515551a N/A CRM 0.0006 0.028 5.4 2.8 <10 56.5 0.59 0.272 0.15 0.032 29.5Q515552 78 Soil 0.0008 0.105 0.49 3.18 <10 38.8 0.25 0.14 0.16 0.175 28.6Q515553 79 Soil 0.0041 0.082 0.56 4.22 <10 33.3 0.28 0.179 0.12 0.101 28Q515554 95 Soil 0.0018 0.019 0.45 0.94 <10 24.7 0.14 0.092 0.09 0.02 26.2Q515555 94 Soil 0.0027 0.038 0.46 1.42 <10 28.5 0.18 0.144 0.14 0.039 36.4Q515556 93 Soil 0.0031 0.027 0.51 3.73 <10 28.7 0.23 0.14 0.1 0.026 33.1Q515557 92 Soil 0.0012 0.014 0.5 5.13 <10 28.4 0.23 0.109 0.13 0.026 31.5Q515558 91 Soil 0.0018 0.016 0.47 6 <10 24 0.2 0.109 0.1 0.023 27.1Q515559 90 Soil 0.0017 0.016 0.49 6.17 <10 22.2 0.21 0.115 0.11 0.025 30.2Q515560 89 Soil 0.0077 0.019 0.4 5.38 <10 25.9 0.14 0.114 0.14 0.029 31.2Q515561 88 Soil 0.0024 0.019 0.59 5.31 <10 33.7 0.18 0.14 0.1 0.025 33.2Q515562 87 Soil 0.0016 0.009 0.49 6.04 <10 26.3 0.15 0.189 0.04 0.017 19.9Q515563 86 Soil 0.0026 0.031 0.63 4.78 <10 43.9 0.33 0.166 0.13 0.047 39.3Q515564 85 Soil 0.0175 0.022 0.47 7.01 <10 31.9 0.21 0.124 0.13 0.027 31.6Q515565 84 Soil 0.0016 0.017 0.54 7.47 <10 31.6 0.23 0.144 0.14 0.022 36.3Q515566 83 Soil 0.0015 0.017 0.58 5.06 <10 31.9 0.28 0.132 0.13 0.026 36Q515567 82 Soil 0.002 0.017 0.49 4.83 <10 30 0.22 0.116 0.14 0.023 36.8Q515568 81 Soil 0.0024 0.029 0.65 11.35 <10 34.2 0.32 0.156 0.12 0.031 38.4Q515569 80 Soil 0.002 0.013 0.48 5.64 <10 28.6 0.22 0.123 0.14 0.021 35.7Q515570 96 Soil 0.0023 0.025 0.57 3.77 <10 49.1 0.31 0.123 0.19 0.042 49.7Q515571 97 Soil 0.0022 0.011 0.46 2.76 <10 25.6 0.19 0.119 0.11 0.017 28.8Q515572 98 Soil 0.002 0.017 0.49 3.27 <10 17.1 0.22 0.102 0.07 0.027 25Q515573 99 Soil 0.002 0.016 0.68 8.61 <10 51.2 0.33 0.158 0.16 0.037 44.2Q515574 100 Soil 0.0012 0.024 0.74 9.33 <10 42.4 0.36 0.179 0.15 0.029 42.6Q515575 101 Soil 0.0032 0.028 0.41 5.78 <10 29.5 0.18 0.119 0.1 0.029 30.4Q515576 102 Soil 0.0015 0.025 0.69 7.86 <10 52.4 0.31 0.149 0.13 0.04 35.5Q515577 103 Soil 0.0048 0.067 0.71 2.93 <10 59.9 0.43 0.192 0.13 0.067 46.5Q515578 104 Soil 0.0046 0.014 0.52 6.43 <10 28.7 0.27 0.144 0.13 0.023 42Q515579 105 Soil 0.0048 0.018 0.55 8.23 <10 29.8 0.22 0.134 0.13 0.026 39.2Q515580 106 Soil 0.0012 0.017 0.52 6.59 <10 27.8 0.2 0.122 0.13 0.024 35.3Q515581 107 Soil 0.0016 0.012 0.48 6.07 <10 30.5 0.22 0.109 0.14 0.022 39.5341ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSample Au Ag Al As B Ba Be Bi Ca Cd CeSAMPLE Site Type ppm ppm % ppm ppm ppm ppm ppm % ppm ppmD.5 Aqua-Regia ICP-MSQ515582 108 Soil 0.0016 0.012 0.38 4.08 <10 26.1 0.17 0.094 0.14 0.021 37Q515583 108b Duplicate 0.0014 0.01 0.41 5.29 <10 26.6 0.18 0.098 0.14 0.021 35.5Q515583a N/A CRM 0.0004 0.027 5.42 2.95 <10 56 0.64 0.28 0.15 0.036 31.6Q515584 109 Soil 0.0015 0.012 0.44 5.44 <10 28.9 0.19 0.096 0.15 0.022 38Q515585 110 Soil 0.0015 0.014 0.44 5.33 <10 29.4 0.18 0.1 0.15 0.022 39.3Q515586 111 Soil 0.0019 0.022 0.47 8 <10 28.4 0.18 0.158 0.13 0.028 35Q515587 127 Soil 0.0035 0.014 0.45 4.78 <10 27.6 0.2 0.111 0.15 0.024 37.9Q515588 126 Soil 0.0007 0.013 0.44 6.43 <10 28.4 0.2 0.11 0.15 0.022 38.3Q515589 126b Duplicate 0.0034 0.017 0.38 5.8 <10 26.1 0.15 0.128 0.12 0.019 32.9Q515590 16 Soil 0.001 0.017 0.53 4.62 <10 35.9 0.19 0.12 0.13 0.023 34.1Q515591 17 Soil 0.0052 0.015 0.53 5.32 <10 36.9 0.21 0.124 0.17 0.03 44.4Q515592 18 Soil 0.0017 0.068 0.79 8.04 <10 34.7 0.27 0.201 0.11 0.026 34.1Q515593 18b Duplicate 0.0012 0.022 0.63 6.15 <10 38.8 0.23 0.132 0.16 0.033 41.9Q515594 19 Soil 0.0022 0.018 0.53 4.4 <10 32.6 0.22 0.106 0.12 0.023 33.6Q515595 20 Soil 0.0017 0.016 0.4 4.38 <10 25.1 0.17 0.107 0.12 0.027 31.9Q515596 21 Soil 0.0012 0.024 0.31 0.84 <10 19.6 0.13 0.082 0.1 0.025 28Q515597 22 Soil 0.0029 0.036 0.42 1.04 <10 20.6 0.15 0.096 0.1 0.036 33.6Q515598 23 Soil 0.0025 0.026 0.49 1.81 <10 32.2 0.21 0.117 0.15 0.037 45.1Q515599 24 Soil 0.001 0.012 0.47 5.54 <10 33.8 0.18 0.125 0.15 0.023 39.4Q515599a N/A CRM 0.0009 0.033 5.57 2.71 <10 56.6 0.61 0.258 0.15 0.031 30.5Q515600 25 Soil 0.001 0.015 0.42 6.72 <10 25.3 0.2 0.159 0.13 0.016 35.2Q515651 32 Soil 0.0019 0.018 0.55 7.02 <10 33.2 0.25 0.153 0.16 0.026 44.9Q515652 33 Soil 0.0013 0.022 0.5 6.73 <10 32.4 0.19 0.124 0.15 0.028 42.4Q515653 34 Soil 0.0017 0.029 0.58 4.42 <10 32.2 0.22 0.184 0.13 0.031 37.1Q515654 35 Soil 0.0012 0.012 0.28 0.53 <10 13.8 0.13 0.048 0.05 0.012 28.3Q515655 35b Duplicate 0.0011 0.011 0.34 1.46 <10 18 0.15 0.077 0.09 0.016 27.7Q515657 36 Soil 0.0009 0.032 0.24 0.8 <10 14 0.14 0.057 0.05 0.058 25.5Q515658 37 Soil 0.0016 0.028 0.54 1.52 <10 32.2 0.2 0.118 0.12 0.032 38.9Q515659 38 Soil 0.0118 0.037 0.6 1.29 <10 31.8 0.23 0.138 0.11 0.041 42Q515660 39 Soil 0.0023 0.143 0.51 1.68 <10 31.1 0.28 0.134 0.13 0.165 27.2Q515661 40 Soil 0.0021 0.117 0.72 3.12 <10 47.2 0.41 0.251 0.18 0.29 40.2Q515662 41 Soil 0.001 0.016 0.55 2.9 <10 32.2 0.2 0.171 0.15 0.015 38.2342ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSample Au Ag Al As B Ba Be Bi Ca Cd CeSAMPLE Site Type ppm ppm % ppm ppm ppm ppm ppm % ppm ppmD.5 Aqua-Regia ICP-MSQ515663 42 Soil 0.0059 0.019 0.4 4.9 <10 21 0.16 0.117 0.13 0.016 34.5Q515664 43 Soil 0.0099 0.011 0.44 7.35 <10 24.2 0.17 0.168 0.14 0.014 32.8Q515665 44 Soil 0.002 0.032 0.65 1.71 <10 36.2 0.29 0.161 0.15 0.029 40.6Q515666 45 Soil 0.0023 0.046 0.73 4.64 <10 40 0.3 0.316 0.07 0.079 33.3Q515666a N/A CRM 0.0007 0.03 5.58 2.7 <10 56.2 0.57 0.271 0.14 0.031 30.6Q515667 46 Soil 0.002 0.081 0.56 3.38 <10 62.9 0.35 0.243 0.23 0.226 34Q515667a N/A CRM 0.0005 0.028 5.67 2.72 <10 57.4 0.58 0.284 0.15 0.03 31.3Q515668 47 Soil 0.0039 0.14 0.55 5.18 <10 65 0.49 0.21 0.17 0.371 34.1Q515669 63 Soil 0.0021 0.115 0.64 5.78 <10 71.6 0.38 0.252 0.22 0.273 39.4Q515670 62 Soil 0.0079 0.024 0.46 1.08 <10 26 0.2 0.105 0.14 0.03 38.9Q515671 61 Soil 0.0016 0.022 0.4 1.19 <10 20.4 0.17 0.087 0.12 0.024 35.2Q515672 60 Soil 0.0018 0.02 0.49 1.78 <10 26.1 0.2 0.104 0.13 0.025 37.2Q515673 59 Soil 0.0017 0.024 0.59 1.94 <10 33.4 0.23 0.127 0.13 0.026 38.4Q515674 58 Soil 0.0017 0.015 0.39 7.21 <10 25.4 0.2 0.122 0.14 0.018 33.2Q515675 57 Soil 0.0008 0.01 0.36 2.81 <10 21.5 0.16 0.096 0.12 0.012 31.3Q515676 56 Soil 0.0035 0.024 0.48 1.39 <10 27.2 0.19 0.119 0.14 0.032 40.5Q515678 54 Soil 0.0014 0.103 0.42 2.34 <10 48.7 0.23 0.154 0.14 0.295 20.2Q515679 54b Duplicate 0.0015 0.092 0.53 2.61 <10 42 0.24 0.138 0.13 0.373 26.9Q515680 53 Soil 0.001 0.02 0.46 0.7 <10 22.9 0.16 0.082 0.11 0.016 31.5Q515681 52 Soil 0.0033 0.021 0.45 0.95 <10 37.2 0.14 0.087 0.1 0.029 33.7Q515682 51 Soil 0.0021 0.165 0.66 2.71 <10 46.6 0.38 0.177 0.13 0.257 38.1Q515683 50 Soil 0.0026 0.071 0.72 1.76 <10 40.8 0.29 0.195 0.13 0.036 39.5Q515683a N/A CRM 0.0006 0.043 5.75 2.46 <10 57.4 0.59 0.273 0.15 0.038 30.8Q515685 49 Soil 0.0011 0.017 0.37 5.52 <10 22.3 0.15 0.155 0.13 0.017 29.4Q515686 48 Soil 0.0026 0.028 1.19 16.05 <10 89.6 0.36 0.368 0.17 0.028 34.3Q515687 64 Soil 0.0021 0.016 0.49 5.62 <10 31.8 0.24 0.138 0.16 0.023 42.8Q515688 65 Soil 0.0016 0.02 0.5 5.43 <10 32.1 0.19 0.131 0.16 0.025 40.6Q515689 66 Soil 0.0017 0.015 0.41 8.73 <10 25.2 0.17 0.168 0.12 0.016 32.5Q515690 67 Soil 0.0008 0.019 0.5 6.61 <10 28.7 0.2 0.142 0.13 0.021 33.3Q515691 68 Soil 0.0013 0.021 0.55 6.08 <10 33.9 0.21 0.162 0.15 0.022 42Q515692 69 Soil 0.0012 0.022 0.41 2.86 <10 28.8 0.15 0.121 0.11 0.018 28.7Q515693 70 Soil 0.0029 0.197 0.94 1.33 <10 44.6 0.44 0.12 0.12 0.357 40.3343ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSample Au Ag Al As B Ba Be Bi Ca Cd CeSAMPLE Site Type ppm ppm % ppm ppm ppm ppm ppm % ppm ppmD.5 Aqua-Regia ICP-MSQ515695 72 Soil 0.0018 0.038 0.72 4.56 <10 74.8 0.28 0.139 0.14 0.043 40.9Q515696 72b Duplicate 0.0012 0.025 0.6 2.28 <10 74.6 0.19 0.122 0.15 0.047 44.2Q515697 73 Soil 0.0015 0.014 0.5 4.45 <10 29.1 0.25 0.129 0.14 0.025 35.2Q515698 74 Soil 0.0012 0.013 0.39 1.79 <10 23.1 0.13 0.106 0.13 0.015 31.7Q515699 75 Soil 0.0024 0.02 0.37 0.58 <10 21.8 0.12 0.116 0.11 0.021 31.3Q515700 76 Soil 0.0011 0.023 0.33 0.58 <10 18.1 0.13 0.071 0.09 0.032 27.3Q515700a N/A CRM 0.0007 0.028 5.49 2.85 <10 53.5 0.57 0.261 0.14 0.029 30.[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LCo Cr Cs Cu Fe Ga Ge Hf Hg In K La Lippm ppm ppm ppm % ppm ppm ppm ppm ppm % ppm ppm2.37 14.2 1.145 6.88 0.59 1.88 0.058 0.038 <0.004 <0.005 0.09 17.65 13.53.01 17.2 1.125 11.2 0.63 2.3 0.047 0.027 <0.004 0.008 0.09 13.95 15.85.75 22.4 1.21 8.31 3.02 3.37 0.071 0.026 0.006 0.009 0.08 17.4 17.72.62 14.35 0.463 78.9 0.68 1.545 0.043 0.01 0.078 0.007 0.01 18.9 1.51.915 15.05 0.821 13.05 0.43 2.07 0.047 0.015 0.006 0.005 0.04 16.45 13.82.11 14.55 0.982 11.8 0.48 2.1 0.048 0.014 0.004 <0.005 0.08 17.75 14.12.52 14.6 0.954 12.7 0.64 1.8 0.053 0.086 <0.004 0.005 0.1 17.8 12.33.1 17.6 0.997 14.65 0.73 2.25 0.071 0.038 <0.004 0.005 0.11 21 14.32.66 16.55 1.125 13.4 0.69 2.15 0.054 0.037 <0.004 <0.005 0.1 20.4 14.72.41 15.3 0.977 8 0.66 2.14 0.056 0.036 0.004 <0.005 0.1 18.25 13.42.86 16.75 1.12 13.85 0.72 2.09 0.053 0.028 0.004 0.006 0.1 18.6 15.12.93 17.45 1.165 11.05 0.76 2.3 0.062 0.031 <0.004 <0.005 0.12 20.3 16.22.34 16 1.09 10.5 0.68 2.14 0.046 0.032 <0.004 0.007 0.1 17.45 14.52.84 16.1 1.055 16.2 0.72 2.19 0.051 0.028 <0.004 <0.005 0.11 19.25 15.12.41 16.05 0.99 11.5 0.64 1.98 0.048 0.027 <0.004 <0.005 0.09 17.1 14.43.16 16.4 1.06 14.2 0.72 2.23 0.05 0.028 <0.004 0.007 0.11 19.8 14.85.14 64.2 3.65 22.1 5.52 18.7 0.06 0.304 0.059 0.073 0.12 12.45 18.62.11 14.75 0.965 9.67 0.5 2.08 0.05 0.016 0.004 0.006 0.07 19.85 142.78 16.25 1.095 12.75 0.69 2.18 0.054 0.014 <0.004 0.007 0.1 21 13.77.64 20.2 1.16 10.65 0.81 2.81 0.047 0.019 0.005 0.006 0.06 18.35 18.56.22 28.8 1.02 14.1 3.3 4.58 0.056 0.006 0.017 0.012 0.03 15.6 20.12.34 15.4 0.983 4.16 0.56 2.28 0.042 0.019 0.005 0.006 0.07 18.35 14.73.43 16.5 1.185 18.1 0.73 2.36 0.053 0.027 0.004 0.005 0.1 22.2 15.73.53 18.4 1.21 14.75 0.83 2.49 0.065 0.032 <0.004 0.005 0.12 22.5 15.73.31 20.5 1.49 8.43 0.81 2.65 0.048 0.023 <0.004 0.008 0.13 17.55 15.62.73 17.35 1.11 23.3 0.77 2.28 0.055 0.02 0.005 0.006 0.11 21.4 14.43.06 15.35 0.966 11.6 0.68 2.05 0.04 0.029 0.004 <0.005 0.1 15.6 13.83.43 17.75 1.115 12.75 0.71 2.32 0.045 0.034 0.004 0.007 0.1 17.35 13.42.19 15.25 0.96 4.85 0.51 2.29 0.037 0.015 <0.004 0.006 0.07 16.55 14.25.27 24.1 1.485 16 1.03 2.73 0.05 0.064 0.004 0.01 0.15 20.3 17.61.1 12.75 0.324 25.3 0.17 1.595 0.026 0.006 0.029 0.006 0.01 12.65 41.44 10.85 0.711 6.3 0.32 1.55 0.022 0.01 <0.004 <0.005 0.03 9.45 10.5D.5 Aqua-Regia ICP-[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LCo Cr Cs Cu Fe Ga Ge Hf Hg In K La Lippm ppm ppm ppm % ppm ppm ppm ppm ppm % ppm ppmD.5 Aqua-Regia ICP-MS1.86 8.3 0.147 100 0.152 0.963 0.029 0.008 0.083 0.008 0.01 17.05 0.35.36 67.6 3.51 23.3 5.71 17.95 0.047 0.327 0.054 0.081 0.12 12.8 17.51.695 8.29 0.103 57.8 0.167 0.767 0.047 0.006 0.054 0.009 <0.01 13.2 0.11.9 14.5 0.299 50 0.44 1.505 0.051 0.005 0.081 <0.005 0.01 13 0.61.605 15 0.811 7.28 0.37 1.82 0.038 0.006 <0.004 0.006 0.05 12.65 10.72.27 17.1 0.907 24.7 0.48 1.98 0.058 0.028 <0.004 <0.005 0.11 18.05 12.61.88 17.2 0.926 19.1 0.52 2.01 0.052 0.012 0.013 <0.005 0.09 16.4 11.22.44 16.15 0.83 9.45 0.68 1.885 0.053 0.04 <0.004 <0.005 0.1 15 13.22.27 15.35 0.832 10.25 0.63 1.835 0.038 0.02 <0.004 <0.005 0.08 13.2 122.47 14.8 0.789 8.91 0.64 1.83 0.049 0.038 <0.004 <0.005 0.08 14.55 11.91.985 13.65 0.74 9.01 0.59 1.69 0.047 0.044 <0.004 <0.005 0.09 15.1 11.42.95 22.7 1.365 10.6 0.78 2.86 0.052 0.011 <0.004 0.005 0.11 16.45 15.52.43 21.1 1.365 5.32 0.78 3.18 0.038 0.016 <0.004 <0.005 0.09 9.67 12.13.38 21.8 1.21 25.9 0.67 2.42 0.061 0.023 0.005 0.005 0.12 19.85 16.43.29 17.15 0.974 13 0.69 1.99 0.05 0.033 <0.004 <0.005 0.11 15.2 14.12.76 18.6 1.07 16.25 0.77 2.27 0.057 0.035 <0.004 0.006 0.1 17.75 14.93.62 19.75 1.055 20.5 0.73 2.37 0.055 0.014 0.005 0.007 0.1 18.2 172.97 17.45 0.946 16.05 0.65 2.08 0.057 0.029 <0.004 0.005 0.1 18.35 15.54.46 22.2 1.205 21.2 0.85 2.69 0.064 0.012 <0.004 0.006 0.1 19.1 20.52.79 16.8 0.931 16.1 0.65 2.04 0.062 0.037 <0.004 <0.005 0.1 18 15.95.49 22.8 1.16 15.75 0.82 2.51 0.069 0.105 <0.004 0.008 0.14 24.4 17.22.67 18.55 1 7.73 0.67 2.46 0.049 0.029 <0.004 <0.005 0.08 14 13.52.2 12.25 0.686 9.48 0.56 1.74 0.022 0.02 0.006 0.005 0.05 12.05 11.85.53 21.6 1.18 20.3 0.89 2.5 0.057 0.033 <0.004 0.005 0.12 22 18.45.98 23 1.21 25.3 1 2.52 0.072 0.029 0.004 0.007 0.14 19.75 15.62.85 16.6 0.986 8.28 0.67 1.975 0.06 0.014 <0.004 <0.005 0.11 14.45 11.65.75 22.8 1.15 18.7 0.93 2.5 0.076 0.036 <0.004 0.009 0.12 16.95 16.94.63 22.6 1.065 48.3 0.68 2.51 0.083 0.018 0.011 <0.005 0.11 23.4 15.22.24 16.95 0.998 16.7 0.67 2.27 0.072 0.02 0.008 <0.005 0.1 21 14.52.54 18.55 1.06 14.05 0.77 2.36 0.068 0.017 0.005 <0.005 0.1 18.65 14.22.3 16.3 0.857 7.21 0.73 1.98 0.075 0.04 0.004 <0.005 0.1 16.75 11.62.66 16.8 0.938 13.2 0.71 2.02 0.077 0.04 <0.004 <0.005 0.11 18.1 13.[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LCo Cr Cs Cu Fe Ga Ge Hf Hg In K La Lippm ppm ppm ppm % ppm ppm ppm ppm ppm % ppm ppmD.5 Aqua-Regia ICP-MS2.27 13.9 0.739 11.8 0.6 1.71 0.067 0.052 <0.004 <0.005 0.1 17.3 11.32.77 14.25 0.771 12.3 0.63 1.79 0.062 0.038 <0.004 <0.005 0.1 16.65 11.95.42 72.1 3.51 23.5 5.77 19.7 0.066 0.343 0.068 0.068 0.12 13 18.52.59 15.55 0.862 11.1 0.66 1.775 0.074 0.068 <0.004 <0.005 0.11 17.5 12.12.69 16.15 0.9 10.85 0.68 1.96 0.068 0.043 <0.004 <0.005 0.11 18.5 132.36 16.5 0.951 10.55 0.75 2.11 0.069 0.025 0.004 <0.005 0.1 16.4 12.92.52 15.8 0.878 13.3 0.63 1.965 0.067 0.025 <0.004 <0.005 0.1 17.85 12.92.74 15.05 0.835 13.3 0.67 1.855 0.077 0.041 <0.004 <0.005 0.11 17.75 12.21.995 13.95 0.787 8.81 0.6 1.76 0.072 0.036 <0.004 <0.005 0.09 15.5 10.73.26 18.65 1.205 12 0.76 2.23 0.073 0.027 0.005 <0.005 0.15 15.95 14.73.67 19 1.125 14.55 0.79 2.29 0.07 0.088 <0.004 <0.005 0.15 21.6 14.54.16 22.7 1.305 13.2 1.03 2.99 0.066 0.034 0.01 0.008 0.14 15.95 174.01 20.8 1.21 11.7 0.89 2.51 0.084 0.057 <0.004 <0.005 0.16 19.45 16.62.86 17.55 1.055 9.01 0.74 2.27 0.059 0.027 0.006 <0.005 0.12 15.7 14.22.23 13.15 0.748 9.11 0.59 1.69 0.057 0.026 <0.004 <0.005 0.09 15 11.91.26 9.84 0.662 10.3 0.3 1.425 0.051 0.011 0.005 <0.005 0.05 13.05 8.81.625 13.75 0.499 18.9 0.35 1.855 0.056 0.008 0.014 <0.005 0.03 16.1 8.52.46 18.8 1.12 12.5 0.55 2.33 0.066 0.017 0.008 <0.005 0.1 22.3 13.92.7 16.05 0.938 8.87 0.69 2.05 0.073 0.072 <0.004 <0.005 0.12 18.3 13.15.33 69.8 3.38 22.7 5.81 19.9 0.052 0.334 0.058 0.063 0.13 12.8 18.52.22 13.85 0.816 6.08 0.69 1.965 0.054 0.028 0.005 <0.005 0.09 16.45 11.13.64 19.35 1.035 18.35 0.82 2.28 0.068 0.027 <0.004 <0.005 0.12 21.7 14.42.76 17.9 1.01 10.85 0.78 2.24 0.077 0.051 0.004 <0.005 0.13 20 13.22.73 19.5 1.13 13.8 0.69 2.46 0.062 0.019 0.007 <0.005 0.11 17.75 14.70.997 9.6 0.377 2.84 0.233 1.9 0.048 0.004 0.004 <0.005 0.03 13.55 7.21.37 10.75 0.599 3.63 0.34 1.635 0.052 0.012 <0.004 <0.005 0.04 13 9.30.555 7.38 0.154 15.45 0.074 1.175 0.045 0.003 0.022 <0.005 0.01 11.7 1.52.13 17.2 0.99 15.5 0.52 2.19 0.058 0.009 0.013 <0.005 0.04 18.45 12.42.42 20.6 1.075 22.2 0.51 2.52 0.071 0.008 0.01 0.005 0.05 20.5 14.51.495 8.58 0.124 70.4 0.087 0.946 0.042 0.003 0.084 0.006 0.01 12.15 0.22.02 12.8 0.231 72.1 0.237 1.64 0.058 0.008 0.078 0.008 0.01 18.05 0.72.88 18.65 1.135 8.65 0.64 2.44 0.059 0.017 <0.004 0.005 0.1 18.55 15.[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LCo Cr Cs Cu Fe Ga Ge Hf Hg In K La Lippm ppm ppm ppm % ppm ppm ppm ppm ppm % ppm ppmD.5 Aqua-Regia ICP-MS2.34 11.65 0.698 6.85 0.56 1.63 0.064 0.036 <0.004 <0.005 0.06 16.3 10.72.06 13.7 0.838 8.36 0.66 1.79 0.057 0.036 <0.004 <0.005 0.07 15.6 10.52.95 22.8 1.385 16.8 0.65 2.7 0.067 0.017 0.014 <0.005 0.08 19.35 16.61.71 23 1.11 28.4 0.57 3.3 0.051 0.008 0.069 0.008 0.02 15.85 5.15.39 68.2 3.64 22.7 5.73 18.8 0.069 0.327 0.059 0.058 0.13 12.8 18.33.06 14.25 0.597 61 0.57 1.68 0.048 0.009 0.072 <0.005 0.01 15.85 1.25.77 72 3.7 24.5 5.84 19.65 0.066 0.334 0.062 0.084 0.13 13.25 192.27 10.25 0.307 71.7 0.4 1.095 0.047 0.007 0.083 0.01 0.01 15.3 0.43.24 13.85 0.547 73.3 0.76 1.65 0.06 0.007 0.089 <0.005 0.01 18.5 1.62.14 16.1 1 12.15 0.45 1.955 0.058 0.014 0.005 0.005 0.05 18.75 11.31.54 12.85 0.755 10.55 0.36 1.73 0.057 0.006 0.007 <0.005 0.03 16.8 102.24 15.85 0.973 10.8 0.52 2.15 0.061 0.026 0.004 <0.005 0.07 17.75 12.82.79 19.7 1.2 13.35 0.61 2.49 0.065 0.012 0.004 0.006 0.08 18.35 15.11.895 12.9 0.762 8.18 0.72 1.65 0.058 0.039 0.004 <0.005 0.09 15.6 9.81.61 11.8 0.752 4.41 0.42 1.715 0.056 0.022 <0.004 <0.005 0.07 15.1 9.62.02 15.35 1 10.85 0.45 2.02 0.065 0.012 0.007 <0.005 0.06 19.55 11.52.07 12.45 0.217 106 0.122 0.953 0.036 0.004 0.065 0.012 0.01 9.36 0.41.92 11.8 0.175 119.5 0.09 1.13 0.04 0.009 0.072 <0.005 0.01 13.05 0.31.645 13.3 0.755 9.08 0.39 1.905 0.054 0.01 0.005 <0.005 0.04 15.15 11.32.35 16.35 1.035 11.2 0.43 2.22 0.063 0.01 0.004 <0.005 0.08 15.85 11.92.18 11.9 0.268 97.5 0.168 1.095 0.056 0.007 0.076 0.005 0.01 19.2 0.82.57 22.2 1.225 41.2 0.57 2.59 0.061 0.013 0.021 0.006 0.09 19.05 14.55.57 69.7 3.71 23.6 5.82 19.6 0.069 0.316 0.059 0.064 0.13 13.2 191.595 11.75 0.649 7.7 0.55 1.53 0.044 0.026 0.004 <0.005 0.08 13.75 9.68.21 52.3 3.16 13.95 1.81 5.15 0.083 0.032 0.005 0.012 0.34 16.15 30.13.16 16.7 1.02 13.15 0.7 2.07 0.08 0.044 <0.004 <0.005 0.11 21.2 12.52.99 17.2 1.015 14.6 0.72 2.14 0.072 0.031 <0.004 <0.005 0.11 19.15 13.32.01 13.65 0.935 6.42 0.67 2.02 0.048 0.016 0.004 <0.005 0.07 15.3 11.62.79 16.3 0.977 8.43 0.76 2.09 0.057 0.024 <0.004 <0.005 0.1 15.4 122.95 20 1.185 8.65 0.82 2.53 0.065 0.017 <0.004 0.006 0.12 19.9 14.32.25 14 0.917 7.31 0.53 1.8 0.047 0.012 0.006 <0.005 0.08 13.65 10.42.09 8.75 0.215 119.5 0.122 0.972 0.056 0.014 0.113 0.005 0.01 18.85 0.5348SAMPLEQ515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LCo Cr Cs Cu Fe Ga Ge Hf Hg In K La Lippm ppm ppm ppm % ppm ppm ppm ppm ppm % ppm ppmD.5 Aqua-Regia ICP-MS5.06 25.6 1.445 17.65 0.91 2.71 0.067 0.015 <0.004 0.005 0.11 19.7 173.88 22.1 1.165 12.35 0.74 2.23 0.069 0.053 0.004 0.007 0.1 20.5 14.12.68 15.5 0.961 12.4 0.62 1.93 0.053 0.023 <0.004 0.005 0.09 16 14.71.475 12.15 0.727 5.51 0.41 1.55 0.049 0.015 <0.004 <0.005 0.07 14.7 10.81.32 11.65 0.8 8.27 0.34 1.61 0.053 0.026 <0.004 <0.005 0.07 14.5 10.31.11 9.79 0.568 10.95 0.26 1.37 0.03 0.01 0.004 <0.005 0.03 12.35 8.55.27 68.3 3.57 22.2 5.65 17.55 0.052 0.364 0.06 0.079 0.12 12.5 [binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LMg Mn Mo Na Nb Ni P Pb Pd Pt Rb Re S% ppm ppm % ppm ppm % ppm ppm ppm ppm ppm %0.19 56 0.29 0.006 0.583 7.35 0.049 2.39 <0.001 <0.002 6.96 0.001 0.010.19 55.3 0.51 0.004 0.655 8.9 0.042 2.46 0.001 <0.002 6.68 0.001 <0.010.26 106.5 5.81 0.003 0.882 9.25 0.058 3.27 0.001 <0.002 6.19 0.001 0.010.05 22.7 0.86 0.005 0.438 11.3 0.088 2.86 0.001 0.002 1.28 0.002 0.370.18 47.3 0.11 0.004 0.536 6.66 0.046 2.13 <0.001 <0.002 3.66 0.001 0.020.18 54.1 0.14 0.005 0.498 7.21 0.057 2.3 0.001 <0.002 6.66 0.001 <0.010.18 64.1 0.38 0.006 0.302 7.82 0.056 2.21 <0.001 <0.002 7.59 0.001 <0.010.2 68.6 0.51 0.007 0.593 9.66 0.055 2.56 0.001 0.002 7.4 0.001 <0.010.2 67.5 0.44 0.007 0.538 8.36 0.055 2.46 0.001 <0.002 7.79 0.001 <0.010.19 61.8 0.33 0.005 0.626 8.02 0.056 2.68 0.001 <0.002 7.53 0.001 <0.010.2 66.3 0.44 0.005 0.67 9.03 0.051 2.61 0.001 <0.002 7.96 0.001 <0.010.22 75.4 0.43 0.007 0.679 9.33 0.058 2.83 <0.001 <0.002 8.89 0.001 <0.010.19 60.9 0.35 0.004 0.603 7.97 0.053 2.42 <0.001 <0.002 7.68 0.001 <0.010.2 68.3 0.44 0.004 0.644 8.49 0.055 2.53 <0.001 <0.002 8.03 0.001 <0.010.19 59.9 0.41 0.003 0.535 9 0.05 2.28 <0.001 <0.002 7.16 0.001 <0.010.21 71.7 0.42 0.004 0.569 9.5 0.054 2.52 <0.001 <0.002 8.14 0.001 <0.010.17 386 1.53 0.03 0.645 22.9 0.036 19.25 0.001 <0.002 28.5 0.001 0.040.18 54.1 0.19 0.005 0.584 7.44 0.057 2.39 <0.001 <0.002 6.25 0.001 0.010.2 66 0.37 0.007 0.602 8.36 0.055 2.52 <0.001 <0.002 7.44 0.001 <0.010.24 67.8 0.8 0.005 0.75 11.4 0.056 2.87 <0.001 <0.002 4.76 0.001 0.010.22 100.5 8.92 0.005 0.686 10.2 0.053 4.69 <0.001 <0.002 3.3 0.001 0.050.2 51.5 0.32 0.004 0.562 7.82 0.034 2.65 0.001 <0.002 4.86 0.001 0.010.22 65.8 0.71 0.005 0.647 11.15 0.063 3.5 <0.001 <0.002 7.67 0.001 0.010.23 74.5 0.66 0.006 0.695 10.65 0.064 2.86 <0.001 <0.002 8.74 0.001 0.010.25 73.4 0.44 0.006 0.7 9.61 0.049 2.6 <0.001 <0.002 9.88 0.001 0.010.21 63.3 0.59 0.006 0.646 8.57 0.058 2.86 0.001 <0.002 8.05 0.001 0.010.19 62.4 0.37 0.005 0.61 9.18 0.048 2.64 <0.001 <0.002 7.06 0.001 <0.010.24 62 0.34 0.003 0.939 13.1 0.048 2.54 0.001 <0.002 7.12 0.001 <0.010.2 48.4 0.23 0.004 0.495 6.71 0.035 2.47 <0.001 <0.002 4.88 0.001 <0.010.39 82.6 0.23 0.008 0.965 23.1 0.06 2.88 0.001 <0.002 12.6 0.001 <0.010.06 16.3 0.32 0.005 0.411 6.53 0.042 1.855 <0.001 <0.002 0.886 0.001 0.130.15 35.1 0.09 0.004 0.382 5.25 0.031 1.36 <0.001 <0.002 2.67 0.001 0.01D.5 Aqua-Regia ICP-[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LMg Mn Mo Na Nb Ni P Pb Pd Pt Rb Re S% ppm ppm % ppm ppm % ppm ppm ppm ppm ppm %D.5 Aqua-Regia ICP-MS0.02 3.9 0.5 0.007 0.287 7.53 0.078 2.48 <0.001 <0.002 0.619 0.002 0.340.18 400 1.38 0.033 0.648 24.6 0.038 18.75 0.001 <0.002 27.8 0.001 0.050.02 4.1 0.46 0.005 0.219 7.09 0.069 1.695 0.001 <0.002 0.543 0.001 0.220.02 6.2 0.35 0.008 0.392 9.21 0.078 2.47 <0.001 <0.002 1.065 <0.001 0.220.16 38.4 0.06 0.006 0.467 6.56 0.039 1.87 <0.001 <0.002 3.99 <0.001 0.010.2 54.2 0.2 0.008 0.547 8.94 0.055 2.85 0.001 <0.002 8.04 <0.001 0.010.17 43.8 0.31 0.008 0.54 7.13 0.046 2.71 <0.001 <0.002 6.54 <0.001 0.020.17 52.7 0.25 0.007 0.545 8.14 0.052 2.09 <0.001 <0.002 6.35 <0.001 <0.010.16 46.6 0.35 0.006 0.541 7.32 0.043 2.38 <0.001 <0.002 5.74 <0.001 <0.010.15 46.3 0.34 0.005 0.528 8.08 0.044 2.46 <0.001 <0.002 5.57 <0.001 <0.010.17 48.1 0.31 0.007 0.549 8.04 0.055 2.23 <0.001 <0.002 6.08 <0.001 <0.010.28 61.8 0.36 0.009 0.948 14.2 0.041 2.88 <0.001 <0.002 9.41 <0.001 0.010.22 53.4 0.57 0.005 0.732 8.14 0.014 2.12 <0.001 <0.002 7.32 <0.001 0.010.36 61.6 0.3 0.008 1.06 22.2 0.056 3.1 <0.001 <0.002 9.52 <0.001 0.010.23 61.7 0.47 0.006 0.666 13.6 0.054 2.76 <0.001 <0.002 7.56 <0.001 <0.010.23 61.5 0.65 0.009 0.68 12.6 0.053 2.86 <0.001 <0.002 8.04 <0.001 0.010.31 64.5 0.43 0.008 0.792 20.1 0.05 2.8 0.001 <0.002 7.7 <0.001 0.010.24 58.2 0.32 0.007 0.596 14.15 0.055 2.53 <0.001 <0.002 7.57 <0.001 <0.010.27 64.6 0.63 0.008 0.791 18.35 0.052 3.28 <0.001 <0.002 8.32 <0.001 0.010.21 55.9 0.34 0.007 0.53 11.1 0.054 2.51 <0.001 <0.002 7.04 <0.001 <0.010.4 82.4 0.15 0.008 0.565 26.1 0.066 3.13 <0.001 <0.002 11.6 <0.001 <0.010.3 52.2 0.25 0.007 1.035 14.1 0.04 2.08 <0.001 <0.002 5.52 <0.001 0.010.13 36.7 0.4 0.007 0.559 6.82 0.026 2.37 <0.001 <0.002 4.4 <0.001 0.010.32 88.3 0.57 0.008 0.951 21.2 0.061 3.5 <0.001 <0.002 9.45 <0.001 0.010.38 97.2 0.74 0.006 1.085 24.1 0.059 3.55 0.001 <0.002 9.53 <0.001 0.010.22 59.3 0.44 0.001 0.549 9.85 0.041 2.27 <0.001 <0.002 7.52 <0.001 <0.010.41 91.6 0.5 0.001 1.35 24.7 0.048 3.23 <0.001 <0.002 8.91 <0.001 <0.010.41 62.4 0.18 0.003 1.29 23 0.053 3.61 <0.001 <0.002 8.38 <0.001 0.010.21 55.3 0.51 0.003 0.597 8.79 0.052 2.86 0.001 <0.002 6.78 <0.001 <0.010.22 58.1 0.51 0.002 0.578 9.38 0.053 2.77 <0.001 <0.002 6.57 <0.001 <0.010.18 54.3 0.45 0.001 0.552 7.37 0.054 2.59 <0.001 <0.002 6.52 <0.001 <0.010.21 61.4 0.33 0.002 0.458 8.9 0.054 2.47 <0.001 <0.002 7.17 <0.001 <0.[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LMg Mn Mo Na Nb Ni P Pb Pd Pt Rb Re S% ppm ppm % ppm ppm % ppm ppm ppm ppm ppm %D.5 Aqua-Regia ICP-MS0.18 53.9 0.29 0.003 0.251 7.6 0.052 2.12 <0.001 <0.002 5.9 <0.001 <0.010.18 57.6 0.36 0.003 0.346 8.21 0.053 2.35 0.001 <0.002 6.3 <0.001 <0.010.18 399 1.41 0.028 0.601 25.9 0.037 21.2 0.001 <0.002 27.2 <0.001 0.040.19 59.2 0.32 0.001 0.434 8.71 0.055 2.3 0.001 <0.002 6.77 <0.001 <0.010.2 64.3 0.35 0.003 0.44 8.9 0.056 2.39 <0.001 <0.002 6.87 <0.001 <0.010.19 53 0.5 <0.001 0.558 7.82 0.049 2.87 0.001 <0.002 6.66 <0.001 <0.010.19 57.5 0.35 0.003 0.43 8.68 0.054 2.28 <0.001 <0.002 6.46 <0.001 <0.010.19 60.2 0.35 0.002 0.428 8.76 0.057 2.46 0.001 <0.002 6.63 <0.001 <0.010.16 49.1 0.34 0.002 0.448 7.66 0.049 2.12 0.001 <0.002 5.97 <0.001 <0.010.24 64.9 0.33 0.002 0.594 10.95 0.049 2.47 0.001 <0.002 9.99 <0.001 <0.010.25 74.4 0.3 0.004 0.375 11.75 0.064 2.79 <0.001 <0.002 9.31 <0.001 <0.010.26 70.8 0.55 0.004 0.765 12.6 0.048 3.27 <0.001 <0.002 8.78 <0.001 <0.010.27 78.2 0.35 0.003 0.657 12.85 0.063 3.05 <0.001 <0.002 9.82 <0.001 <0.010.21 59.7 0.3 0.001 0.601 9.16 0.049 2.44 <0.001 <0.002 8.02 <0.001 <0.010.16 48.9 0.32 0.001 0.462 8.88 0.048 2.18 0.001 <0.002 5.9 <0.001 <0.010.13 33.6 0.09 <0.001 0.344 5.05 0.041 1.77 0.001 <0.002 3.88 <0.001 0.010.14 37.5 0.11 0.002 0.42 6.4 0.037 2.06 <0.001 <0.002 2.07 <0.001 0.030.22 60.5 0.22 0.002 0.579 9.19 0.056 3.09 0.001 <0.002 7.54 <0.001 0.010.21 59.9 0.29 0.003 0.508 9.82 0.059 2.51 <0.001 <0.002 8.02 <0.001 <0.010.18 399 1.3 0.029 0.574 25.8 0.037 20.2 0.001 <0.002 27.4 <0.001 0.040.17 49.5 0.38 0.002 0.535 6.97 0.052 2.64 0.001 <0.002 5.51 <0.001 <0.010.22 75.1 0.54 0.004 0.628 11.3 0.058 3.11 0.001 <0.002 8.21 <0.001 <0.010.22 63.6 0.46 0.002 0.626 9.59 0.059 3.02 0.001 <0.002 8.3 <0.001 <0.010.23 58.8 0.23 0.004 0.613 10.15 0.05 2.53 0.001 <0.002 7.97 <0.001 0.010.11 25.2 0.06 <0.001 0.342 4.04 0.018 1.835 <0.001 <0.002 1.75 <0.001 <0.010.14 33.1 0.07 0.001 0.401 5.18 0.037 1.945 0.001 <0.002 2.79 <0.001 <0.010.02 5.8 0.13 <0.001 0.182 3.29 0.028 1.565 <0.001 <0.002 0.543 <0.001 0.070.2 47.2 0.07 0.003 0.555 8.28 0.045 2.33 0.001 <0.002 3.69 <0.001 0.030.22 53 0.13 0.009 0.659 9.57 0.044 2.48 <0.001 <0.002 5.09 <0.001 0.040.02 5.1 0.47 0.011 0.279 7.34 0.075 1.675 0.001 <0.002 0.531 0.001 0.260.04 7.9 1.04 0.009 0.446 11.9 0.102 3.32 <0.001 0.002 1.345 0.001 0.360.24 56.5 0.33 0.009 0.63 11.8 0.053 2.7 0.001 <0.002 7 <0.001 0.[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LMg Mn Mo Na Nb Ni P Pb Pd Pt Rb Re S% ppm ppm % ppm ppm % ppm ppm ppm ppm ppm %D.5 Aqua-Regia ICP-MS0.15 46.7 0.31 0.009 0.496 7.93 0.049 2.11 <0.001 <0.002 4.49 <0.001 0.010.17 45.8 0.46 0.007 0.573 8.09 0.053 2.16 0.001 <0.002 4.98 <0.001 0.020.26 60.6 0.14 0.011 0.731 11.4 0.049 2.71 <0.001 <0.002 7.81 <0.001 0.030.08 18.8 0.63 0.01 0.528 8.07 0.053 4.69 0.001 <0.002 3.47 0.001 0.130.18 399 1.35 0.034 0.65 26.7 0.037 19.5 <0.001 <0.002 28.8 <0.001 0.060.04 16.6 0.43 0.009 0.366 11.5 0.09 2.96 0.001 <0.002 1.9 <0.001 0.290.19 401 1.4 0.034 0.641 28.7 0.037 19.9 0.001 <0.002 30.7 <0.001 0.060.02 6.2 0.88 0.005 0.269 12.3 0.089 3.13 0.001 <0.002 0.972 0.001 0.390.05 18.3 0.34 0.008 0.394 12.65 0.087 3.3 0.001 <0.002 1.345 <0.001 0.280.18 48.9 0.12 0.009 0.566 7.89 0.047 2.35 <0.001 <0.002 5.56 <0.001 0.030.14 37.7 0.09 0.007 0.44 6.22 0.045 1.915 0.001 <0.002 2.64 <0.001 0.030.19 50.5 0.06 0.009 0.597 8.16 0.048 2.19 <0.001 <0.002 7.77 <0.001 0.010.23 56.1 0.1 0.011 0.66 10.55 0.044 2.47 <0.001 <0.002 7.65 <0.001 0.020.16 45.9 0.44 0.008 0.505 7.1 0.052 2.39 <0.001 <0.002 5.47 <0.001 0.010.16 39.8 0.18 0.007 0.448 6.84 0.043 1.94 0.002 <0.002 4.68 <0.001 0.010.19 48 0.12 0.01 0.537 7.8 0.054 2.56 <0.001 <0.002 5.74 <0.001 0.030.02 4.9 0.97 0.007 0.45 10.4 0.045 1.505 0.002 <0.002 0.609 0.003 0.420.02 4.4 0.95 0.006 0.456 10.75 0.05 1.59 0.002 <0.002 0.612 0.002 0.540.17 39.6 0.07 0.008 0.49 6.63 0.042 1.9 <0.001 <0.002 3.51 <0.001 0.020.19 42.2 0.22 0.009 0.574 7.44 0.038 2.25 0.001 <0.002 5.72 <0.001 0.040.03 7.2 0.64 0.006 0.393 12.5 0.07 2.54 0.001 <0.002 0.825 0.001 0.40.25 57.2 0.19 0.011 0.634 10.2 0.054 3.05 0.002 <0.002 7.34 <0.001 0.070.19 399 1.34 0.035 0.626 28.1 0.037 19.9 0.001 <0.002 30.8 <0.001 0.050.15 39.3 0.4 0.009 0.518 6.46 0.05 2.18 <0.001 <0.002 5.23 <0.001 0.020.63 205 1.1 0.017 1.135 20.7 0.07 4.33 0.002 <0.002 19.45 <0.001 0.020.22 61.7 0.39 0.009 0.642 11.1 0.058 2.8 <0.001 <0.002 8.05 <0.001 0.010.23 61 0.39 0.011 0.684 11.65 0.055 2.63 0.001 <0.002 7.97 <0.001 0.010.19 45.4 0.4 0.007 0.597 7.52 0.042 2.54 <0.001 <0.002 5.11 <0.001 0.010.2 57.4 0.68 0.01 0.651 9.08 0.048 2.47 <0.001 <0.002 6.25 <0.001 0.020.26 66.3 0.51 0.011 0.73 10.65 0.057 2.84 0.001 <0.002 7.67 <0.001 0.010.23 46.7 0.25 0.009 0.637 10.85 0.04 2 0.001 <0.002 5.84 <0.001 0.020.02 4.6 0.32 0.007 0.341 10.55 0.116 3.03 <0.001 <0.002 0.799 0.001 0.38353SAMPLEQ515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LMg Mn Mo Na Nb Ni P Pb Pd Pt Rb Re S% ppm ppm % ppm ppm % ppm ppm ppm ppm ppm %D.5 Aqua-Regia ICP-MS0.5 74.2 0.38 0.013 1.76 29.9 0.047 3.03 <0.001 <0.002 10.95 <0.001 0.020.45 62.5 0.12 0.012 1.605 26.6 0.051 3.17 <0.001 <0.002 10.3 <0.001 0.020.2 52.6 0.3 0.01 0.509 9.23 0.05 2.31 <0.001 <0.002 6.55 <0.001 0.020.15 41.8 0.12 0.008 0.511 5.9 0.051 1.955 <0.001 <0.002 5.11 <0.001 0.010.14 38.1 0.09 0.008 0.45 5.13 0.042 1.935 0.001 <0.002 4.65 <0.001 0.020.12 29.2 0.07 0.008 0.364 4.16 0.033 1.47 <0.001 <0.002 2.31 <0.001 0.020.18 396 1.5 0.035 0.615 25.6 0.035 19.05 0.001 <0.002 28.3 <0.001 0.[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSb Sc Se Sn Sr Ta Te Th Ti Tl U V Wppm ppm ppm ppm ppm ppm ppm ppm % ppm ppm ppm ppm0.012 1.3 0.3 0.18 4.29 <0.005 0.01 4.55 0.029 0.049 1.14 13.5 0.2790.017 1.47 0.3 0.18 4.44 <0.005 0.02 3.45 0.035 0.059 0.867 17.7 0.1520.013 1.575 0.3 0.27 4.98 <0.005 0.02 4.19 0.046 0.054 1.02 47.3 0.2660.025 0.623 1.1 0.18 12.5 0.006 0.04 0.137 0.014 0.034 3.52 26.5 0.1610.015 1.595 0.3 0.18 4.48 <0.005 <0.01 4.11 0.029 0.058 0.883 10.9 0.1240.012 1.47 0.3 0.16 5.77 <0.005 0.02 3.34 0.031 0.067 1.115 12.7 0.1260.007 1.355 0.3 0.17 5.01 <0.005 0.01 5.07 0.03 0.069 1.1 13.8 0.2150.008 1.535 0.3 0.17 5.09 <0.005 <0.01 5.2 0.035 0.067 1.25 16.4 0.1750.007 1.53 0.3 0.2 5.79 <0.005 0.01 5 0.033 0.067 1.17 16 0.1850.009 1.46 0.3 0.18 4.96 <0.005 <0.01 4.61 0.033 0.06 0.997 15.3 0.1810.011 1.48 0.3 0.19 5.24 <0.005 0.01 4.59 0.033 0.076 1.15 16.1 0.180.009 1.57 0.3 0.21 5.55 <0.005 <0.01 5.12 0.036 0.078 1.235 17 0.2290.013 1.495 0.3 0.19 4.7 <0.005 0.01 4.4 0.032 0.068 0.992 15.5 0.1840.014 1.52 0.3 0.18 5.59 <0.005 0.01 4.64 0.033 0.073 1.215 15.5 0.2340.009 1.38 0.3 0.17 4.91 <0.005 0.01 4.19 0.031 0.067 0.995 14.5 0.180.009 1.56 0.3 0.23 5.48 <0.005 <0.01 4.58 0.034 0.073 1.21 16 0.1770.22 9.1 0.9 2.58 17.5 <0.005 0.03 9.85 0.049 0.186 1.465 118 0.0340.008 1.4 0.3 0.2 5.23 <0.005 0.01 4.53 0.03 0.06 1.145 12.6 0.1630.005 1.41 0.3 0.19 5.94 <0.005 0.01 3.96 0.033 0.075 1.4 14.9 0.7080.01 1.715 0.4 0.23 4.9 <0.005 <0.01 3.14 0.038 0.095 1.205 21.2 0.8380.021 1.365 0.6 0.36 4.89 <0.005 0.02 0.845 0.044 0.129 1.635 83.9 0.5660.005 1.37 0.3 0.18 3.54 <0.005 <0.01 3.94 0.033 0.05 1.28 14.2 0.1610.007 1.55 0.3 0.21 5.27 <0.005 0.01 5.48 0.035 0.069 1.81 16.6 0.1980.008 1.665 0.3 0.21 5.26 <0.005 0.01 5.59 0.037 0.076 1.39 17.4 0.8470.01 1.73 0.3 0.22 5.29 <0.005 <0.01 3.74 0.039 0.079 1.14 18.9 0.1880.009 1.615 0.3 0.2 4.66 <0.005 0.02 3.97 0.034 0.072 1.725 16.4 0.2230.01 1.36 0.2 0.16 3.92 <0.005 0.01 3.99 0.032 0.057 1 15 0.2750.012 1.475 0.3 0.2 5.05 <0.005 0.02 4.32 0.035 0.058 1.07 16.6 0.415<0.005 1.335 0.2 0.17 3.73 <0.005 <0.01 3.96 0.032 0.057 0.888 13.3 0.4320.041 2.15 0.3 0.25 7.1 <0.005 <0.01 4.93 0.046 0.121 1.525 21.7 0.1420.013 0.561 0.5 0.17 6.02 <0.005 0.01 0.13 0.02 0.027 1.58 8.8 0.084<0.005 1.005 0.2 0.13 2.59 <0.005 <0.01 1.965 0.022 0.036 0.664 8.4 0.083D.5 Aqua-Regia ICP-[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSb Sc Se Sn Sr Ta Te Th Ti Tl U V Wppm ppm ppm ppm ppm ppm ppm ppm % ppm ppm ppm ppmD.5 Aqua-Regia ICP-MS0.03 0.513 0.9 0.15 14 <0.005 0.02 0.157 0.012 0.027 3.16 7.5 0.1020.168 8.72 0.8 2.53 16.8 <0.005 0.01 9.34 0.049 0.181 1.445 121.5 0.0310.08 0.527 0.8 0.11 14 <0.005 <0.01 0.181 0.011 0.013 2.59 12 0.1360.029 0.5 0.9 0.17 12.05 <0.005 <0.01 0.152 0.015 0.033 2.3 13.9 0.1020.006 1.23 0.2 0.15 3.28 <0.005 <0.01 2.78 0.025 0.047 0.716 10.2 0.0930.014 1.33 0.3 0.21 4.61 <0.005 <0.01 5.08 0.033 0.071 1.165 12 1.4450.014 1.375 0.3 0.19 4.03 <0.005 0.01 3.08 0.029 0.065 1.305 15 0.2120.008 1.285 0.2 0.16 4.01 <0.005 <0.01 4.15 0.029 0.054 0.807 14.2 0.32<0.005 1.16 0.3 0.17 3.94 <0.005 <0.01 2.95 0.028 0.056 0.829 13.4 0.13<0.005 1.14 0.2 0.17 3.27 <0.005 <0.01 4.12 0.029 0.047 0.91 13.7 0.362<0.005 1.145 0.3 0.15 4.1 <0.005 <0.01 4.19 0.027 0.048 0.869 12.8 0.2720.031 1.535 0.3 0.22 4.62 <0.005 0.01 3.12 0.04 0.086 1.01 18.5 0.17<0.005 1.465 0.2 0.25 2.93 <0.005 <0.01 2.24 0.048 0.055 0.515 23.5 0.3120.021 1.62 0.3 0.21 4.8 <0.005 <0.01 4.13 0.034 0.087 1.58 16.7 0.1730.01 1.34 0.3 0.16 4.06 <0.005 <0.01 4.87 0.031 0.059 1.14 15 0.155<0.005 1.505 0.3 0.19 4.85 <0.005 <0.01 4.67 0.034 0.076 1.26 16.7 0.5850.006 1.59 0.3 0.18 5.02 <0.005 <0.01 3.77 0.036 0.073 1.605 16.5 0.158<0.005 1.46 0.3 0.16 4.49 <0.005 <0.01 4.51 0.034 0.07 1.375 14.6 0.149<0.005 1.725 0.4 0.2 4.45 <0.005 0.01 3.63 0.036 0.084 1.49 18.6 0.181<0.005 1.37 0.2 0.17 4.39 <0.005 <0.01 4.61 0.033 0.061 1.17 14.4 0.2020.007 1.965 0.3 0.2 6.59 <0.005 <0.01 7.15 0.042 0.094 1.53 18.4 0.494<0.005 1.345 0.2 0.21 3.98 <0.005 <0.01 3.15 0.036 0.046 0.746 14.8 0.134<0.005 0.99 0.2 0.15 3.03 0.008 <0.01 3.38 0.026 0.044 0.859 11.1 0.1520.031 1.665 0.3 0.21 5.61 <0.005 <0.01 5.52 0.039 0.078 1.395 18.7 0.2530.035 1.58 0.3 0.25 5.82 <0.005 <0.01 3.91 0.041 0.096 1.34 19.4 0.1910.023 1.205 0.2 0.21 4.14 <0.005 0.01 3.41 0.03 0.052 1.005 15.3 0.110.051 1.65 0.3 0.19 6.11 <0.005 0.02 3.68 0.038 0.088 1.035 19.9 0.180.039 1.79 0.5 0.23 6.26 <0.005 0.01 2.92 0.034 0.093 2.25 16.5 0.1160.01 1.485 0.3 0.18 4.88 <0.005 <0.01 3.96 0.033 0.064 1.36 14.9 0.3180.011 1.455 0.3 0.18 4.69 <0.005 0.01 3.4 0.035 0.064 1.21 16.8 0.3460.016 1.295 0.2 0.15 4.27 <0.005 0.02 4.25 0.031 0.051 0.991 16.1 0.1620.012 1.42 0.2 0.17 4.29 <0.005 <0.01 4.7 0.034 0.07 1.165 14.4 0.[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSb Sc Se Sn Sr Ta Te Th Ti Tl U V Wppm ppm ppm ppm ppm ppm ppm ppm % ppm ppm ppm ppmD.5 Aqua-Regia ICP-MS0.013 1.24 0.2 0.14 4.59 <0.005 0.01 4.71 0.029 0.057 1.11 12.6 0.1560.01 1.23 0.2 0.16 4.71 <0.005 0.02 4.15 0.029 0.06 1.015 13.1 0.4350.179 9.45 0.8 2.52 17.95 <0.005 0.02 9.88 0.048 0.186 1.555 121.5 0.0330.008 1.275 0.2 0.19 4.82 <0.005 0.01 4.93 0.032 0.061 1.025 13.8 0.1650.013 1.405 0.2 0.17 4.93 <0.005 0.01 5.37 0.032 0.064 1.085 14.2 0.2070.012 1.295 0.3 0.16 4.76 <0.005 0.02 3.66 0.031 0.063 1.075 15.4 0.4940.009 1.365 0.3 0.16 5.05 <0.005 0.01 4.08 0.032 0.062 1.04 13.7 0.2990.009 1.295 0.3 0.17 4.54 <0.005 <0.01 4.77 0.031 0.062 1.175 13.4 0.2020.008 1.165 0.2 0.14 3.78 <0.005 <0.01 3.94 0.028 0.048 0.942 12.8 0.1980.013 1.58 0.3 0.19 3.97 <0.005 0.01 4.06 0.036 0.077 1.215 16.3 0.1250.01 1.7 0.3 0.22 4.91 <0.005 0.01 5.57 0.039 0.083 1.32 16.3 0.3520.009 1.86 0.3 1.03 3.76 0.007 0.01 4.13 0.045 0.071 1.205 20.8 0.3990.015 1.775 0.3 0.21 4.51 <0.005 0.01 5.21 0.042 0.079 1.295 17.6 0.2760.006 1.475 0.2 0.2 3.61 <0.005 0.01 3.82 0.035 0.063 1.08 16.2 0.1250.006 1.09 0.1 0.16 3.86 <0.005 0.01 3.84 0.027 0.049 0.985 12.5 0.1280.005 0.892 0.2 0.14 3.38 <0.005 <0.01 2.83 0.02 0.041 0.861 7.4 0.0650.012 1.225 0.2 0.18 4.35 <0.005 0.01 2.18 0.025 0.042 1.125 9.5 0.1610.007 1.73 0.3 0.19 4.71 <0.005 0.01 4.96 0.034 0.069 1.38 15 0.172<0.005 1.46 0.2 0.18 4.49 <0.005 0.01 5.19 0.034 0.064 1.115 15.2 0.2360.18 9.69 0.8 2.5 17.7 <0.005 0.04 9.22 0.051 0.173 1.455 119.5 0.0270.009 1.175 0.2 0.17 3.97 <0.005 0.01 4.24 0.03 0.047 1.065 13.2 0.1550.011 1.55 0.3 0.25 5.69 <0.005 0.02 5.04 0.038 0.07 1.37 17 0.2180.009 1.52 0.3 0.18 4.72 <0.005 0.02 5.63 0.036 0.064 1.235 16.7 0.2180.012 1.625 0.3 0.23 4.77 <0.005 0.01 3.24 0.036 0.067 1.16 15.3 0.274<0.005 0.782 0.1 0.13 2.53 <0.005 <0.01 2.51 0.021 0.038 0.692 6.2 0.735<0.005 0.973 0.1 0.15 3.27 <0.005 <0.01 2.81 0.023 0.04 0.714 8.4 0.1360.015 0.506 0.4 0.09 4.41 <0.005 <0.01 0.951 0.008 0.016 1.14 5.6 0.0790.015 1.665 0.3 0.18 4.76 <0.005 0.01 3.61 0.031 0.064 1.415 12.2 0.1290.008 1.67 0.4 0.19 5.27 <0.005 0.01 2.86 0.034 0.078 1.44 16 0.1280.031 0.253 0.8 0.15 13.1 <0.005 0.03 0.038 0.01 0.029 2.49 8.1 0.0750.024 0.429 1.1 0.15 15.2 <0.005 0.01 0.112 0.016 0.034 3.39 9.2 0.1330.009 1.455 0.2 0.2 4.92 <0.005 0.01 4.17 0.039 0.071 1.04 18.6 0.[binary]-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSb Sc Se Sn Sr Ta Te Th Ti Tl U V Wppm ppm ppm ppm ppm ppm ppm ppm % ppm ppm ppm ppmD.5 Aqua-Regia ICP-MS0.007 1.015 0.2 0.15 4.15 <0.005 <0.01 4.76 0.026 0.045 0.865 11.9 0.177<0.005 1.135 0.2 0.16 4.79 <0.005 <0.01 3.88 0.029 0.052 0.922 18.3 0.1550.011 1.945 0.3 0.29 5.71 <0.005 0.01 4.8 0.043 0.087 1.21 16.4 0.1930.02 0.758 0.8 0.28 5.39 <0.005 0.05 0.246 0.027 0.101 2.72 18.3 0.2360.173 8.72 0.9 2.53 17.1 <0.005 0.02 9.54 0.056 0.189 1.44 123 0.0330.034 0.395 0.9 0.14 12.95 <0.005 0.01 0.095 0.012 0.059 2.99 28.5 0.1360.174 8.91 0.8 2.62 18.1 <0.005 0.03 9.97 0.053 0.194 1.505 126.5 0.0290.02 0.481 1 0.11 13.65 <0.005 0.01 0.152 0.009 0.034 3.01 29 0.1550.024 0.509 1 0.15 14.2 <0.005 <0.01 0.125 0.013 0.042 3.09 20.3 0.1550.008 1.37 0.3 0.18 5.26 <0.005 0.01 3.78 0.031 0.059 1.15 13.3 0.1890.007 1.16 0.3 0.14 4.67 <0.005 0.01 3.49 0.024 0.043 1.01 10.5 0.1120.009 1.47 0.2 0.21 5.54 <0.005 0.01 4.64 0.033 0.067 1.07 13.7 0.2590.012 1.685 0.3 0.21 6.01 <0.005 <0.01 4.17 0.038 0.074 1.135 15.7 0.1180.008 0.984 0.2 0.15 4.08 <0.005 0.01 4.19 0.028 0.05 0.865 13.6 0.23<0.005 0.943 0.2 0.15 4.52 <0.005 0.01 3.85 0.027 0.049 0.784 11.8 0.3520.007 1.29 0.2 0.19 4.72 <0.005 0.01 3.63 0.031 0.064 1.145 12.7 0.6320.031 0.497 0.9 0.16 15.65 <0.005 <0.01 0.122 0.016 0.032 3.35 5.3 0.1130.043 0.638 0.9 0.18 13.95 0.006 0.01 0.17 0.017 0.03 3.5 7.6 0.1480.009 1.255 0.2 0.19 4.15 <0.005 <0.01 3.14 0.027 0.057 0.855 9.8 0.3230.008 1.335 0.2 0.19 3.84 <0.005 0.01 3.21 0.033 0.064 1.16 11.9 0.090.05 0.266 1 0.15 11.2 <0.005 0.01 0.069 0.01 0.032 3.91 11.3 0.0790.015 1.795 0.4 0.23 4.97 <0.005 <0.01 2.41 0.037 0.091 1.885 16.1 0.1380.204 8.79 0.8 2.54 18.05 <0.005 0.04 9.76 0.055 0.198 1.48 124 0.0280.008 0.92 0.2 0.15 4.03 <0.005 0.01 3.58 0.025 0.048 0.969 12.9 0.9920.017 3.07 0.2 0.41 7.61 <0.005 0.04 4.18 0.087 0.143 1.14 46.5 0.1910.014 1.34 0.2 0.19 5.19 <0.005 <0.01 5.96 0.036 0.065 1.23 15.8 0.2240.007 1.365 0.2 0.18 5.37 <0.005 <0.01 4.76 0.038 0.075 1.26 16.1 0.2090.006 1.05 0.2 0.17 4.35 <0.005 0.01 3.17 0.031 0.067 0.886 15.6 0.1370.013 1.205 0.2 0.16 4.33 <0.005 <0.01 3.8 0.035 0.059 1.04 16.3 0.2780.01 1.475 0.2 0.21 5.27 <0.005 <0.01 4.37 0.041 0.063 1.27 18.3 0.5820.007 1.05 0.2 0.16 4.32 <0.005 <0.01 3.03 0.029 0.054 0.793 12.4 0.1030.031 0.359 1.1 0.09 12.5 <0.005 0.01 0.149 0.007 0.042 4.17 3.7 0.095358SAMPLEQ515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41L ME-MS41LSb Sc Se Sn Sr Ta Te Th Ti Tl U V Wppm ppm ppm ppm ppm ppm ppm ppm % ppm ppm ppm ppmD.5 Aqua-Regia ICP-MS0.05 1.8 0.4 0.26 10.55 <0.005 0.02 3.17 0.04 0.092 1.395 19.7 0.1120.04 1.74 0.3 0.21 7.62 <0.005 0.01 4.92 0.039 0.094 1.32 18 0.0710.01 1.335 0.4 0.19 4.32 <0.005 <0.01 3.92 0.034 0.063 1.095 14 0.1320.01 0.955 0.2 0.16 3.72 <0.005 <0.01 3.21 0.028 0.051 0.831 9 0.20.013 0.997 0.3 0.18 3.3 <0.005 <0.01 3.64 0.026 0.056 0.784 8.3 0.1080.008 0.906 0.2 0.14 3.48 <0.005 0.01 2.79 0.02 0.046 0.682 6.7 0.0950.227 8.51 0.8 2.44 16.45 <0.005 0.03 9.14 0.05 0.182 1.465 118.5 0.[binary]-MS41L ME-MS41L ME-MS41LY Zn Zrppm ppm ppm4.54 10.2 1.583.71 12.5 1.134.17 18.3 0.927.97 5.7 0.494.15 9.3 0.544.93 10.7 0.554.69 10.9 3.415.08 12 1.624.99 12.1 1.734.74 12.1 1.874.58 12.9 1.175.23 14.5 1.54.36 11.8 1.314.64 12.4 1.384.27 10.9 1.244.9 12.5 1.24.32 26.8 13.654.86 11 0.774.99 13.8 0.594.83 16.5 0.643.6 18.5 0.33.72 11 0.755.56 16.1 1.245.52 14.7 1.514.34 15.7 0.765.08 13.7 0.743.91 13.2 1.224.23 13.9 1.163.46 10.3 0.675.2 20.8 3.194.03 5.1 0.182.46 8 0.36D.5 Aqua-Regia ICP-[binary]-MS41L ME-MS41L ME-MS41LY Zn Zrppm ppm ppmD.5 Aqua-Regia ICP-MS6.5 2 0.34.25 27.2 14.955.97 2.3 0.255.55 3.9 0.253.26 9.6 0.264.55 14.9 1.333.9 11 0.374.01 10.9 1.43.3 10.9 0.673.69 10.3 1.593.94 10.8 1.993.37 18.9 0.481.655 13.3 0.544.87 20.4 0.84.19 14.4 1.734.54 15 1.424.65 17 0.794.7 15.2 1.514.76 18 0.584.6 13.5 1.715.88 19.2 4.163.27 13.6 1.082.61 9.1 0.845.28 18.7 1.64.53 21 0.993.49 14.2 0.564.24 23.4 1.35.47 23.7 0.634.61 13.6 0.874.35 14.1 0.744.22 12.4 1.594.43 13.1 2.[binary]-MS41L ME-MS41L ME-MS41LY Zn Zrppm ppm ppmD.5 Aqua-Regia ICP-MS4.32 11.6 2.74.21 11.9 1.894.27 31.5 15.24.36 13.1 2.854.57 12.4 2.424.12 12.8 1.084.58 13.1 1.534.72 12 2.143.97 11.4 1.674.11 16.2 1.325.21 16.2 3.813.92 17.1 1.794.94 18.1 2.513.92 14.8 0.983.84 12.6 1.13.27 7.7 0.43.89 8.5 0.285.16 14.5 0.724.55 14.5 3.084.17 30.9 15.054.34 10.9 1.245.12 15.6 1.444.85 15.7 2.354.22 16.2 0.732.25 5.8 0.273.11 7.5 0.492.84 1.7 0.144.61 11.3 0.465.07 12.5 0.356.01 3.6 0.167.69 3.6 0.334.53 19.7 0.[binary]-MS41L ME-MS41L ME-MS41LY Zn Zrppm ppm ppmD.5 Aqua-Regia ICP-MS4.02 10.1 1.84.35 9.7 1.574.73 17 0.864.24 7 0.334.14 29 14.57.14 4.9 0.274.46 30.4 158.46 5.5 0.377.8 5.1 0.344.84 11.2 0.564.19 7.7 0.364.72 11.1 1.344.49 15.5 0.684.03 9.9 1.83.64 9.1 0.864.73 11.3 0.414.15 3.9 0.345.67 3.3 0.493.63 9.1 0.433.82 10.3 0.476.39 3.5 0.274.84 14.2 0.424.32 30.6 14.63.89 8.3 1.074.41 32.5 1.365.2 13.4 2.314.73 14.4 1.583.5 10.4 0.633.94 11.9 1.054.64 15.1 0.823.15 12.1 0.527.92 2.8 0.43363SAMPLEQ515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS41L ME-MS41L ME-MS41LY Zn Zrppm ppm ppmD.5 Aqua-Regia ICP-MS4.48 23.8 0.564.56 19.6 2.154.14 13.4 0.843.75 9 0.743.35 8.4 0.952.81 5.6 0.344.1 29.2 14.2364ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Sample Ag Al As Au B Ba Be Bi Br Ca Cd Ce CoSAMPLE Site Type ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515501 26 Soil <0.002 5 0.03 0.001 <0.2 0.14 <0.005 <0.003 <1 10 <0.001 0.004 0.019Q515502 27 Soil <0.002 9 0.05 <0.001 <0.2 0.11 <0.005 <0.003 <1 10 0.001 0.0147 0.024Q515503 28 Soil <0.002 14 0.11 <0.001 <0.2 0.28 <0.005 <0.003 <1 20 0.001 0.0159 0.14Q515504 29 Soil <0.002 39 0.41 <0.001 0.4 0.73 <0.005 <0.003 1 80 0.002 0.0958 0.078Q515505 30 Soil <0.002 9 0.06 <0.001 <0.2 0.43 <0.005 <0.003 <1 20 0.001 0.0218 0.017Q515506 31 Soil <0.002 12 0.14 <0.001 <0.2 0.13 <0.005 <0.003 <1 10 <0.001 0.0359 0.01Q515507 125 Soil <0.002 4 0.02 <0.001 <0.2 0.06 <0.005 <0.003 <1 10 <0.001 0.0322 0.014Q515508 124 Soil <0.002 8 0.02 <0.001 <0.2 0.09 <0.005 <0.003 <1 10 0.001 0.0479 0.012Q515509 123 Soil <0.002 6 0.04 <0.001 <0.2 0.08 <0.005 <0.003 <1 10 <0.001 0.0223 0.007Q515510 122 Soil <0.002 8 0.04 <0.001 <0.2 0.1 <0.005 <0.003 <1 10 <0.001 0.0056 0.01Q515511 121 Soil <0.002 11 0.03 <0.001 <0.2 0.13 <0.005 <0.003 <1 10 <0.001 0.0151 0.016Q515512 120 Soil <0.002 7 0.04 <0.001 <0.2 0.12 <0.005 <0.003 <1 10 <0.001 0.0125 0.014Q515513 119 Soil <0.002 9 0.04 <0.001 <0.2 0.19 <0.005 <0.003 <1 10 <0.001 0.0102 0.008Q515514 118 Soil <0.002 11 0.02 <0.001 <0.2 0.15 <0.005 <0.003 <1 10 <0.001 0.0224 0.018Q515515 117 Soil <0.002 8 0.02 <0.001 <0.2 0.15 <0.005 <0.003 <1 10 <0.001 0.0204 0.013Q515516 116 Soil <0.002 7 0.02 <0.001 <0.2 0.17 <0.005 <0.003 <1 10 <0.001 0.0364 0.014Q515516a N/A CRM <0.002 29 0.01 <0.001 1.1 0.18 <0.005 <0.003 2 60 <0.001 0.0049 0.008Q515517 14 Soil <0.002 5 0.12 <0.001 <0.2 0.23 <0.005 <0.003 <1 10 0.001 0.0127 0.008Q515518 15 Soil <0.002 12 0.03 0.001 <0.2 0.19 <0.005 <0.003 <1 10 <0.001 0.0239 0.014Q515519 13 Soil <0.002 11 0.07 <0.001 <0.2 0.31 <0.005 <0.003 <1 10 <0.001 0.0301 0.06Q515520 12 Soil <0.002 10 0.1 0.001 0.2 0.53 <0.005 <0.003 <1 30 <0.001 0.0203 0.064Q515521 11 Soil <0.002 5 0.03 <0.001 <0.2 0.13 <0.005 <0.003 <1 10 <0.001 0.0066 0.011Q515522 10 Soil <0.002 9 0.07 <0.001 <0.2 0.2 <0.005 <0.003 <1 10 <0.001 0.0385 0.019Q515523 9 Soil <0.002 10 0.05 0.001 <0.2 0.14 <0.005 <0.003 <1 10 <0.001 0.0301 0.016Q515524 8 Soil <0.002 8 0.04 <0.001 <0.2 0.13 <0.005 <0.003 <1 10 <0.001 0.0098 0.031Q515525 7 Soil <0.002 9 0.04 <0.001 <0.2 0.12 <0.005 <0.003 <1 10 <0.001 0.0727 0.013Q515526 115 Soil <0.002 7 0.02 <0.001 <0.2 0.19 <0.005 <0.003 <1 10 0.001 0.0091 0.032Q515527 114 Soil <0.002 7 0.02 <0.001 <0.2 0.12 <0.005 <0.003 <1 10 <0.001 0.005 0.021Q515528 113 Soil <0.002 4 0.02 <0.001 <0.2 0.09 <0.005 <0.003 <1 <10 <0.001 0.0136 0.004Q515529 112 Soil <0.002 19 0.11 <0.001 <0.2 0.28 <0.005 <0.003 <1 10 <0.001 0.0581 0.025Q515530 6 Soil <0.002 18 0.13 <0.001 0.3 0.93 <0.005 <0.003 <1 50 0.001 0.0278 0.033Q515531 5 Soil <0.002 4 0.03 <0.001 <0.2 0.12 <0.005 <0.003 <1 <10 <0.001 0.0057 0.004D.6 De-Ionized Water ICP-MS (Rerun)365ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Sample Ag Al As Au B Ba Be Bi Br Ca Cd Ce CoSAMPLE Site Type ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)Q515551 77 Soil <0.002 38 0.18 <0.001 0.4 1.07 <0.005 <0.003 <1 110 0.002 0.0777 0.083Q515551a N/A CRM <0.002 25 0.01 <0.001 1.1 0.18 <0.005 <0.003 2 70 <0.001 0.006 0.007Q515552 78 Soil <0.002 36 0.28 <0.001 0.3 1.02 <0.005 <0.003 <1 90 0.002 0.0701 0.07Q515553 79 Soil <0.002 44 0.29 <0.001 0.2 1.32 <0.005 <0.003 1 110 0.002 0.111 0.119Q515554 95 Soil <0.002 9 0.02 <0.001 <0.2 0.23 <0.005 <0.003 <1 <10 <0.001 0.0234 0.005Q515555 94 Soil <0.002 12 0.14 <0.001 <0.2 0.11 <0.005 <0.003 <1 10 0.001 0.036 0.017Q515556 93 Soil <0.002 13 0.16 <0.001 <0.2 0.19 <0.005 <0.003 <1 10 <0.001 0.0444 0.013Q515557 92 Soil <0.002 10 0.02 <0.001 <0.2 0.16 <0.005 <0.003 <1 10 <0.001 0.0124 0.018Q515558 91 Soil <0.002 12 0.01 <0.001 <0.2 0.14 <0.005 <0.003 <1 10 <0.001 0.0151 0.019Q515559 90 Soil <0.002 13 0.01 <0.001 <0.2 0.14 <0.005 <0.003 <1 10 <0.001 0.0167 0.011Q515560 89 Soil <0.002 8 0.03 <0.001 <0.2 0.1 <0.005 <0.003 <1 10 <0.001 0.006 0.005Q515561 88 Soil <0.002 14 0.11 <0.001 <0.2 0.18 <0.005 <0.003 <1 10 <0.001 0.0604 0.015Q515562 87 Soil <0.002 14 0.03 <0.001 <0.2 0.15 <0.005 <0.003 <1 10 <0.001 0.013 0.016Q515563 86 Soil <0.002 10 0.13 0.001 <0.2 0.31 <0.005 <0.003 <1 10 0.001 0.0628 0.021Q515564 85 Soil <0.002 10 0.05 <0.001 <0.2 0.13 <0.005 <0.003 <1 10 <0.001 0.0087 0.013Q515565 84 Soil <0.002 12 0.05 <0.001 <0.2 0.23 <0.005 <0.003 <1 10 <0.001 0.0255 0.009Q515566 83 Soil <0.002 10 0.15 <0.001 <0.2 0.18 <0.005 <0.003 <1 10 <0.001 0.0417 0.022Q515567 82 Soil <0.002 4 0.09 <0.001 <0.2 0.21 <0.005 <0.003 <1 <10 0.001 0.032 0.016Q515568 81 Soil <0.002 18 0.15 <0.001 <0.2 0.26 <0.005 <0.003 <1 10 <0.001 0.0618 0.019Q515569 80 Soil <0.002 5 0.07 <0.001 <0.2 0.16 <0.005 <0.003 <1 10 <0.001 0.0323 0.008Q515570 96 Soil <0.002 6 0.14 <0.001 <0.2 0.15 <0.005 <0.003 <1 10 <0.001 0.0273 0.027Q515571 97 Soil <0.002 7 0.03 <0.001 <0.2 0.93 <0.005 <0.003 <1 10 <0.001 0.0054 0.011Q515572 98 Soil <0.002 6 0.01 <0.001 <0.2 0.14 <0.005 <0.003 <1 10 <0.001 0.0107 0.015Q515573 99 Soil <0.002 6 0.03 <0.001 <0.2 0.23 <0.005 <0.003 <1 10 <0.001 0.0209 0.009Q515574 100 Soil <0.002 8 0.03 <0.001 <0.2 0.12 <0.005 <0.003 <1 10 <0.001 0.016 0.017Q515575 101 Soil <0.002 8 0.05 <0.001 <0.2 0.09 <0.005 <0.003 <1 <10 <0.001 0.006 0.016Q515576 102 Soil <0.002 10 0.03 <0.001 <0.2 0.18 <0.005 <0.003 <1 10 <0.001 0.0135 0.022Q515577 103 Soil <0.002 15 0.12 <0.001 <0.2 0.31 <0.005 <0.003 <1 10 0.002 0.086 0.059Q515578 104 Soil <0.002 9 0.06 <0.001 <0.2 0.17 <0.005 <0.003 <1 10 0.001 0.0387 0.011Q515579 105 Soil <0.002 9 0.04 <0.001 <0.2 0.14 <0.005 <0.003 <1 10 0.001 0.016 0.013Q515580 106 Soil <0.002 9 0.02 <0.001 <0.2 0.1 <0.005 <0.003 <1 10 <0.001 0.0103 0.015Q515581 107 Soil <0.002 6 0.02 <0.001 <0.2 0.15 <0.005 <0.003 <1 10 <0.001 0.0234 0.015366ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Sample Ag Al As Au B Ba Be Bi Br Ca Cd Ce CoSAMPLE Site Type ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)Q515582 108 Soil <0.002 3 0.05 <0.001 <0.2 0.03 <0.005 <0.003 <1 10 <0.001 0.0192 0.004Q515583 108b Duplicate <0.002 4 0.03 <0.001 <0.2 0.07 <0.005 <0.003 <1 10 <0.001 0.0211 0.01Q515583a N/A CRM <0.002 39 0.02 <0.001 1.1 0.18 <0.005 <0.003 2 70 <0.001 0.0067 0.009Q515584 109 Soil <0.002 4 0.04 <0.001 <0.2 0.09 <0.005 <0.003 <1 <10 <0.001 0.01 0.01Q515585 110 Soil <0.002 5 0.03 <0.001 <0.2 0.17 <0.005 <0.003 <1 10 <0.001 0.0125 0.02Q515586 111 Soil <0.002 7 0.05 <0.001 <0.2 0.08 <0.005 <0.003 <1 10 <0.001 0.0099 0.016Q515587 127 Soil <0.002 4 0.04 <0.001 <0.2 0.11 <0.005 <0.003 <1 10 <0.001 0.0314 0.012Q515588 126 Soil <0.002 4 0.03 <0.001 <0.2 0.1 <0.005 <0.003 <1 10 <0.001 0.0182 0.024Q515589 126b Duplicate <0.002 8 0.05 <0.001 <0.2 0.15 <0.005 <0.003 <1 10 0.001 0.0081 0.008Q515590 16 Soil <0.002 6 0.03 <0.001 <0.2 0.1 <0.005 <0.003 <1 10 <0.001 0.0115 0.01Q515591 17 Soil <0.002 2 0.02 <0.001 <0.2 0.11 <0.005 <0.003 <1 10 <0.001 0.0246 0.008Q515592 18 Soil <0.002 4 0.02 0.001 <0.2 0.18 <0.005 <0.003 <1 10 0.001 0.0059 0.034Q515593 18b Duplicate <0.002 6 0.03 <0.001 <0.2 0.15 <0.005 <0.003 <1 10 <0.001 0.0065 0.02Q515594 19 Soil <0.002 7 0.03 <0.001 <0.2 0.15 <0.005 <0.003 <1 <10 <0.001 0.0077 0.019Q515595 20 Soil <0.002 6 0.02 <0.001 <0.2 0.13 <0.005 <0.003 <1 10 <0.001 0.0076 0.009Q515596 21 Soil <0.002 4 0.05 <0.001 <0.2 0.11 <0.005 <0.003 <1 10 0.001 0.0065 0.004Q515597 22 Soil <0.002 10 0.09 <0.001 <0.2 0.33 <0.005 <0.003 <1 10 0.001 0.0192 0.021Q515598 23 Soil <0.002 7 0.19 <0.001 <0.2 0.33 <0.005 <0.003 <1 10 0.001 0.0134 0.014Q515599 24 Soil <0.002 4 0.05 <0.001 <0.2 0.14 <0.005 <0.003 <1 10 <0.001 0.0039 0.011Q515599a N/A CRM <0.002 49 0.02 <0.001 1 0.19 <0.005 <0.003 2 70 <0.001 0.0076 0.009Q515600 25 Soil <0.002 8 0.04 <0.001 <0.2 0.1 <0.005 <0.003 <1 10 <0.001 0.0071 0.018Q515651 32 Soil <0.002 7 0.03 <0.001 0.2 0.12 <0.005 <0.003 <1 10 <0.001 0.0293 0.017Q515652 33 Soil <0.002 7 0.04 <0.001 <0.2 0.06 <0.005 <0.003 <1 10 <0.001 0.0056 0.013Q515653 34 Soil <0.002 8 0.07 <0.001 <0.2 0.14 <0.005 <0.003 <1 10 0.001 0.0247 0.016Q515654 35 Soil <0.002 4 0.01 <0.001 <0.2 0.09 <0.005 <0.003 <1 <10 <0.001 0.0063 0.003Q515655 35b Duplicate <0.002 4 0.02 <0.001 <0.2 0.12 <0.005 <0.003 <1 10 <0.001 0.0076 0.005Q515657 36 Soil <0.002 14 0.08 <0.001 <0.2 0.39 <0.005 <0.003 <1 30 0.001 0.0304 0.023Q515658 37 Soil <0.002 10 0.09 <0.001 <0.2 0.51 <0.005 <0.003 <1 10 0.001 0.0579 0.02Q515659 38 Soil <0.002 14 0.06 <0.001 <0.2 0.36 <0.005 <0.003 <1 10 0.001 0.0357 0.013Q515660 39 Soil <0.002 29 0.14 <0.001 0.4 0.74 <0.005 <0.003 <1 70 0.001 0.0474 0.053Q515661 40 Soil <0.002 38 0.33 <0.001 0.4 0.83 <0.005 <0.003 <1 80 0.002 0.0711 0.059Q515662 41 Soil <0.002 8 0.09 <0.001 <0.2 0.25 <0.005 <0.003 <1 10 <0.001 0.014 0.011367ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Sample Ag Al As Au B Ba Be Bi Br Ca Cd Ce CoSAMPLE Site Type ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)Q515663 42 Soil <0.002 6 0.03 <0.001 <0.2 0.11 <0.005 <0.003 <1 10 <0.001 0.0061 0.008Q515664 43 Soil <0.002 11 0.11 <0.001 <0.2 0.19 <0.005 <0.003 <1 10 0.001 0.0126 0.012Q515665 44 Soil <0.002 7 0.04 <0.001 <0.2 0.16 <0.005 <0.003 <1 10 <0.001 0.0258 0.008Q515666 45 Soil <0.002 24 0.23 0.001 0.3 1.04 <0.005 <0.003 1 70 0.002 0.0509 0.067Q515666a N/A CRM <0.002 57 0.01 <0.001 1 0.18 <0.005 <0.003 2 70 0.001 0.0194 0.009Q515667 46 Soil <0.002 26 0.3 0.001 0.4 1.48 <0.005 <0.003 1 140 0.003 0.0671 0.109Q515667a N/A CRM <0.002 58 0.01 <0.001 1.1 0.17 <0.005 <0.003 2 70 0.001 0.0088 0.009Q515668 47 Soil <0.002 44 1.09 <0.001 0.4 2.23 0.006 <0.003 1 150 0.008 0.1215 0.136Q515669 63 Soil <0.002 43 0.38 <0.001 0.3 1.71 <0.005 <0.003 1 160 0.004 0.106 0.152Q515670 62 Soil <0.002 5 0.1 <0.001 <0.2 0.14 <0.005 <0.003 <1 10 <0.001 0.0122 0.01Q515671 61 Soil <0.002 7 0.06 <0.001 <0.2 0.21 <0.005 <0.003 <1 20 <0.001 0.0176 0.009Q515672 60 Soil <0.002 9 0.06 <0.001 <0.2 0.12 <0.005 <0.003 <1 10 <0.001 0.0257 0.005Q515673 59 Soil <0.002 7 0.08 <0.001 <0.2 0.1 <0.005 <0.003 <1 10 0.001 0.0153 0.006Q515674 58 Soil <0.002 7 0.03 <0.001 <0.2 0.09 <0.005 <0.003 <1 10 <0.001 0.0051 0.006Q515675 57 Soil <0.002 3 0.09 <0.001 <0.2 0.06 <0.005 <0.003 <1 10 <0.001 0.0033 0.003Q515676 56 Soil <0.002 7 0.1 <0.001 <0.2 0.18 <0.005 <0.003 <1 10 0.001 0.019 0.007Q515678 54 Soil <0.002 30 0.26 0.001 0.4 1.06 <0.005 <0.003 <1 90 0.004 0.0353 0.087Q515679 54b Duplicate <0.002 33 0.29 <0.001 0.4 0.99 <0.005 <0.003 <1 90 0.004 0.0485 0.088Q515680 53 Soil <0.002 6 0.02 <0.001 <0.2 0.17 <0.005 <0.003 <1 10 <0.001 0.0148 0.007Q515681 52 Soil <0.002 6 0.08 <0.001 <0.2 0.28 <0.005 <0.003 <1 20 <0.001 0.0148 0.046Q515682 51 Soil <0.002 31 0.29 <0.001 0.3 1.48 0.005 <0.003 <1 110 0.003 0.0863 0.106Q515683 50 Soil <0.002 12 0.08 <0.001 <0.2 0.39 <0.005 <0.003 <1 20 0.001 0.0315 0.023Q515683a N/A CRM <0.002 55 0.01 <0.001 1.1 0.21 <0.005 <0.003 2 70 0.001 0.012 0.009Q515685 49 Soil <0.002 6 0.07 <0.001 <0.2 0.08 <0.005 <0.003 <1 10 <0.001 0.0115 0.006Q515686 48 Soil <0.002 16 0.08 <0.001 <0.2 0.2 <0.005 <0.003 <1 10 <0.001 0.0103 0.073Q515687 64 Soil <0.002 6 0.07 <0.001 <0.2 0.22 <0.005 <0.003 <1 10 0.001 0.0167 0.014Q515688 65 Soil <0.002 6 0.08 <0.001 <0.2 0.13 <0.005 <0.003 <1 10 0.001 0.0113 0.011Q515689 66 Soil <0.002 6 0.14 <0.001 <0.2 0.18 <0.005 <0.003 <1 10 <0.001 0.009 0.008Q515690 67 Soil <0.002 9 0.02 <0.001 <0.2 0.19 <0.005 <0.003 <1 10 <0.001 0.0118 0.022Q515691 68 Soil <0.002 7 0.04 <0.001 <0.2 0.1 <0.005 <0.003 <1 10 0.001 0.006 0.01Q515692 69 Soil <0.002 7 0.07 <0.001 <0.2 0.11 <0.005 <0.003 <1 10 <0.001 0.0097 0.009Q515693 70 Soil <0.002 43 0.07 <0.001 0.2 1.46 <0.005 <0.003 <1 90 0.007 0.107 0.111368ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Sample Ag Al As Au B Ba Be Bi Br Ca Cd Ce CoSAMPLE Site Type ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)Q515694 72 SoilQ515695 72b Duplicate <0.002 17 0.11 <0.001 <0.2 0.34 <0.005 <0.003 <1 10 <0.001 0.0535 0.017Q515696 73 Soil <0.002 12 0.12 <0.001 <0.2 0.38 <0.005 <0.003 <1 10 <0.001 0.0452 0.019Q515697 74 Soil <0.002 5 0.2 <0.001 <0.2 0.21 <0.005 <0.003 <1 10 <0.001 0.0224 0.022Q515698 75 Soil <0.002 4 0.06 <0.001 <0.2 0.1 <0.005 <0.003 <1 10 <0.001 0.0048 0.004Q515699 76 Soil <0.002 5 0.02 <0.001 <0.2 0.11 <0.005 <0.003 <1 <10 <0.001 0.0033 0.002Q515700 N/A CRM <0.002 7 0.03 <0.001 <0.2 0.24 <0.005 <0.003 <1 10 <0.001 0.012 0.008Q515700a <0.002 60 <0.01 <0.001 1 0.2 <0.005 <0.003 2 70 <0.001 0.0122 0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Cr Cs Cu Dy Er Eu Fe Ga Gd Ge Hf Hg Ho Ippm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm<0.05 0.0025 0.05 0.0005 <0.0005 <0.0005 6 <0.05 <0.0005 <0.005 <0.0005 0.01 0.0001 <0.05<0.05 0.0027 0.08 0.0011 0.001 <0.0005 6 <0.05 0.001 <0.005 <0.0005 0.01 0.0002 <0.05<0.05 0.0056 0.1 0.0015 0.0008 <0.0005 84 <0.05 0.0015 <0.005 0.001 0.01 0.0003 0.050.06 0.0013 0.81 0.0054 0.0036 0.0017 30 <0.05 0.0077 0.005 0.0008 0.01 0.001 0.1<0.05 0.0065 0.35 0.0018 0.0008 0.0005 5 <0.05 0.0023 <0.005 <0.0005 0.01 0.0002 <0.050.05 0.0023 0.2 0.0023 0.0011 0.0008 7 <0.05 0.0043 <0.005 0.0006 0.01 0.0004 <0.05<0.05 0.0014 0.08 0.0019 0.0014 0.0007 6 <0.05 0.002 <0.005 0.0005 0.01 0.0002 <0.05<0.05 0.0014 0.09 0.0026 0.0018 0.0006 6 <0.05 0.0042 <0.005 <0.0005 0.01 0.0004 <0.05<0.05 0.0016 0.09 0.0021 0.0007 0.0029 8 <0.05 0.0022 <0.005 0.0007 0.01 0.0007 <0.05<0.05 0.0014 0.05 <0.0005 <0.0005 <0.0005 7 <0.05 0.001 <0.005 <0.0005 0.01 0.0001 <0.05<0.05 0.0022 0.08 0.0009 <0.0005 <0.0005 8 <0.05 0.001 <0.005 <0.0005 0.01 0.0002 <0.05<0.05 0.0015 0.07 <0.0005 0.0009 <0.0005 7 <0.05 0.0012 <0.005 <0.0005 <0.01 0.0003 <0.05<0.05 0.0016 0.08 0.0005 0.0006 <0.0005 12 <0.05 0.0009 <0.005 <0.0005 0.01 0.0002 <0.05<0.05 0.0014 0.1 0.0006 0.0006 <0.0005 8 <0.05 0.0021 <0.005 <0.0005 0.01 0.0004 <0.05<0.05 0.0013 0.08 0.0012 0.0008 0.0007 6 <0.05 0.0009 <0.005 <0.0005 <0.01 0.0003 <0.05<0.05 0.0014 0.06 0.0013 0.001 0.001 5 <0.05 0.0033 <0.005 0.0005 <0.01 0.0004 <0.05<0.05 0.0042 <0.05 0.001 0.0006 <0.0005 17 <0.05 0.0005 <0.005 0.001 0.01 0.0003 3.97<0.05 0.0019 0.11 0.0009 <0.0005 <0.0005 4 <0.05 0.0006 <0.005 0.0005 0.01 0.0001 0.1<0.05 0.002 0.08 0.0012 0.0008 0.0006 8 <0.05 0.0018 <0.005 <0.0005 0.01 0.0004 0.06<0.05 0.0033 0.13 0.0021 0.0012 <0.0005 8 <0.05 0.0026 <0.005 <0.0005 0.01 0.0004 <0.05<0.05 0.0019 0.14 0.0014 0.0007 <0.0005 27 <0.05 <0.0005 <0.005 0.0006 <0.01 0.0002 0.07<0.05 0.0034 0.05 0.0005 <0.0005 <0.0005 5 <0.05 <0.0005 <0.005 <0.0005 <0.01 0.0002 <0.05<0.05 0.0034 0.15 0.0012 <0.0005 0.0007 10 <0.05 0.0014 <0.005 0.0008 <0.01 0.0004 <0.05<0.05 0.0019 0.11 0.001 <0.0005 0.0006 14 <0.05 0.0029 <0.005 <0.0005 <0.01 0.0004 <0.05<0.05 0.0023 0.07 0.0009 <0.0005 <0.0005 9 <0.05 0.0013 <0.005 <0.0005 0.01 0.0001 <0.05<0.05 0.0017 0.24 0.0026 0.0017 0.0009 13 <0.05 0.0051 <0.005 <0.0005 <0.01 0.0005 <0.05<0.05 0.0016 0.06 0.0005 0.0005 <0.0005 6 <0.05 0.0011 <0.005 <0.0005 <0.01 0.0001 <0.05<0.05 0.0024 <0.05 <0.0005 <0.0005 <0.0005 5 <0.05 <0.0005 <0.005 <0.0005 <0.01 0.0001 <0.05<0.05 0.0028 0.05 0.0013 0.0005 <0.0005 2 <0.05 0.0014 <0.005 <0.0005 <0.01 0.0001 <0.050.06 0.0033 0.26 0.0029 0.002 0.0012 21 <0.05 0.0045 <0.005 0.0013 <0.01 0.0006 <0.050.05 0.0022 0.13 0.0021 0.0012 0.0005 5 <0.05 0.0039 <0.005 <0.0005 <0.01 0.0003 <0.05<0.05 0.0061 0.06 0.0005 0.0005 <0.0005 1 <0.05 0.0011 <0.005 <0.0005 <0.01 <0.0001 <0.05D.6 De-Ionized Water ICP-MS (Rerun)[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Cr Cs Cu Dy Er Eu Fe Ga Gd Ge Hf Hg Ho Ippm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)<0.05 0.0031 0.45 0.0043 0.0019 0.0014 8 <0.05 0.0045 <0.005 0.001 <0.01 0.001 0.06<0.05 0.0033 <0.05 0.0006 0.0014 <0.0005 16 <0.05 <0.0005 <0.005 0.0009 0.01 0.0002 3.67<0.05 0.0028 0.27 0.0043 0.0028 0.001 9 <0.05 0.0061 0.005 0.0012 0.01 0.0007 0.140.07 0.0019 0.53 0.0087 0.0036 0.0018 28 <0.05 0.0099 <0.005 0.0009 <0.01 0.0014 0.17<0.05 0.0048 0.11 0.0018 0.001 <0.0005 2 <0.05 0.0012 <0.005 <0.0005 <0.01 0.0003 <0.05<0.05 0.002 0.41 0.0022 0.0008 0.0005 5 <0.05 0.0028 <0.005 <0.0005 <0.01 0.0003 <0.05<0.05 0.0028 0.22 0.0028 0.0007 0.0011 9 <0.05 0.0034 <0.005 0.0005 0.01 0.0003 <0.05<0.05 0.0015 0.06 0.0017 0.0006 <0.0005 14 <0.05 0.0017 <0.005 <0.0005 <0.01 0.0001 <0.05<0.05 0.0019 0.06 0.0011 <0.0005 <0.0005 11 <0.05 0.0016 <0.005 <0.0005 <0.01 0.0001 <0.05<0.05 0.0019 <0.05 0.0011 <0.0005 <0.0005 8 <0.05 0.0014 <0.005 <0.0005 <0.01 0.0003 <0.05<0.05 0.0009 0.05 0.001 <0.0005 <0.0005 10 <0.05 <0.0005 <0.005 <0.0005 <0.01 0.0001 <0.05<0.05 0.0034 0.09 0.0008 0.0016 <0.0005 17 <0.05 0.0008 <0.005 <0.0005 <0.01 0.0002 <0.05<0.05 0.0037 0.06 0.0009 0.0008 <0.0005 17 <0.05 0.0005 <0.005 0.0009 <0.01 0.0002 <0.05<0.05 0.0029 0.25 0.0029 0.0012 0.0012 5 <0.05 0.005 <0.005 0.0006 <0.01 0.0006 0.06<0.05 0.0028 0.05 0.0007 <0.0005 <0.0005 8 <0.05 0.0011 <0.005 <0.0005 <0.01 <0.0001 0.06<0.05 0.0018 0.1 0.0021 0.0005 0.0006 10 <0.05 0.002 <0.005 <0.0005 <0.01 0.0002 0.06<0.05 0.0025 0.15 0.0022 0.0012 0.0011 6 <0.05 0.005 <0.005 <0.0005 0.01 0.0004 0.06<0.05 0.0016 0.11 0.0016 0.0009 0.0007 4 <0.05 0.0031 <0.005 0.0005 <0.01 0.0001 0.050.05 0.0031 0.15 0.0031 0.0019 0.0015 18 <0.05 0.0036 <0.005 0.0006 <0.01 0.0008 0.05<0.05 0.0016 0.12 0.0017 <0.0005 0.0006 7 <0.05 0.0019 <0.005 <0.0005 <0.01 0.0002 0.050.08 0.0016 0.22 0.0024 0.0009 0.0005 7 <0.05 0.0018 <0.005 0.0177 <0.01 0.0009 0.05<0.05 0.0029 <0.05 <0.0005 <0.0005 <0.0005 5 <0.05 0.0007 <0.005 <0.0005 <0.01 0.0001 0.05<0.05 0.0009 <0.05 <0.0005 <0.0005 <0.0005 5 <0.05 0.0005 <0.005 <0.0005 <0.01 <0.0001 0.06<0.05 0.001 <0.05 0.0012 0.0007 0.0007 2 <0.05 0.0021 <0.005 0.0005 <0.01 0.0002 0.06<0.05 0.0021 0.08 0.0011 0.0008 0.0005 4 <0.05 0.001 <0.005 <0.0005 <0.01 0.0001 0.06<0.05 0.0024 0.05 0.0007 <0.0005 <0.0005 4 <0.05 0.0006 <0.005 <0.0005 <0.01 0.0001 0.05<0.05 0.0024 0.05 0.0005 <0.0005 <0.0005 4 <0.05 0.0012 <0.005 <0.0005 <0.01 0.0001 0.06<0.05 0.0022 0.5 0.0041 0.0014 0.001 7 <0.05 0.0038 <0.005 0.0006 <0.01 0.0006 0.05<0.05 0.002 0.16 0.0021 0.0009 0.0007 10 <0.05 0.0102 <0.005 <0.0005 <0.01 0.0003 0.05<0.05 0.0029 0.08 0.0015 0.0005 <0.0005 10 <0.05 0.0008 <0.005 <0.0005 <0.01 0.0001 0.05<0.05 0.0022 <0.05 0.0009 0.0005 <0.0005 11 <0.05 0.0007 <0.005 <0.0005 <0.01 0.0001 0.05<0.05 0.001 0.08 0.0015 0.0007 <0.0005 5 <0.05 0.0014 <0.005 <0.0005 <0.01 0.0001 0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Cr Cs Cu Dy Er Eu Fe Ga Gd Ge Hf Hg Ho Ippm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)<0.05 0.0008 0.06 0.0014 0.0007 0.0008 2 <0.05 0.0029 <0.005 <0.0005 <0.01 0.0002 0.05<0.05 0.0011 0.05 0.0009 0.0008 0.0006 3 <0.05 0.0021 <0.005 0.0005 <0.01 0.0002 0.05<0.05 0.0043 <0.05 0.0005 <0.0005 <0.0005 24 <0.05 0.0008 <0.005 0.0017 <0.01 0.0004 2.57<0.05 0.0012 <0.05 <0.0005 <0.0005 <0.0005 3 <0.05 0.0011 <0.005 <0.0005 <0.01 0.0001 0.31<0.05 0.0013 <0.05 <0.0005 <0.0005 <0.0005 3 <0.05 0.0015 <0.005 <0.0005 <0.01 0.0001 0.06<0.05 0.0019 0.07 <0.0005 <0.0005 <0.0005 9 <0.05 0.0011 <0.005 <0.0005 <0.01 <0.0001 0.06<0.05 0.0013 0.07 0.0015 0.0008 0.0008 5 <0.05 0.0026 <0.005 <0.0005 <0.01 0.0002 0.06<0.05 0.0012 0.06 0.0016 0.001 <0.0005 2 <0.05 0.0017 <0.005 <0.0005 <0.01 0.0003 0.06<0.05 0.0022 0.06 <0.0005 <0.0005 <0.0005 11 <0.05 0.001 <0.005 <0.0005 <0.01 <0.0001 0.06<0.05 0.0015 0.06 <0.0005 <0.0005 <0.0005 5 <0.05 0.0011 <0.005 <0.0005 <0.01 0.0002 0.06<0.05 0.0015 <0.05 0.0007 <0.0005 0.0006 2 <0.05 0.0012 <0.005 <0.0005 <0.01 0.0002 0.06<0.05 0.0029 <0.05 <0.0005 <0.0005 <0.0005 4 <0.05 0.0005 <0.005 <0.0005 <0.01 0.0001 0.07<0.05 0.0022 <0.05 <0.0005 <0.0005 <0.0005 3 <0.05 0.0257 <0.005 <0.0005 <0.01 0.0001 0.06<0.05 0.0022 <0.05 0.0006 <0.0005 <0.0005 7 <0.05 0.0005 <0.005 <0.0005 <0.01 0.0001 0.06<0.05 0.0015 <0.05 0.0007 <0.0005 <0.0005 7 <0.05 0.0005 <0.005 <0.0005 <0.01 <0.0001 0.06<0.05 0.0042 0.1 <0.0005 <0.0005 <0.0005 2 <0.05 0.0011 <0.005 <0.0005 <0.01 0.0001 0.05<0.05 0.0018 0.24 0.0017 <0.0005 0.0006 4 <0.05 0.0016 <0.005 <0.0005 <0.01 0.0002 0.06<0.05 0.0045 0.17 0.0007 <0.0005 <0.0005 7 <0.05 0.0008 <0.005 <0.0005 <0.01 0.0002 0.06<0.05 0.0009 <0.05 <0.0005 <0.0005 <0.0005 5 <0.05 <0.0005 <0.005 <0.0005 <0.01 <0.0001 0.050.07 0.0061 <0.05 0.0006 0.0005 <0.0005 30 <0.05 0.0005 <0.005 0.0022 <0.01 0.0002 2.47<0.05 0.0027 <0.05 <0.0005 <0.0005 <0.0005 11 <0.05 <0.0005 <0.005 <0.0005 <0.01 <0.0001 0.29<0.05 0.001 0.09 0.0017 0.001 0.0007 4 <0.05 0.0032 <0.005 <0.0005 <0.01 0.0003 0.11<0.05 0.0017 <0.05 0.0005 <0.0005 <0.0005 8 <0.05 0.0006 <0.005 <0.0005 <0.01 0.0001 0.09<0.05 0.0016 0.11 0.0009 0.0007 <0.0005 9 <0.05 0.0015 <0.005 <0.0005 <0.01 0.0001 0.08<0.05 0.0008 <0.05 <0.0005 <0.0005 <0.0005 <1 <0.05 0.0005 <0.005 <0.0005 <0.01 0.0001 0.06<0.05 0.0019 <0.05 <0.0005 <0.0005 <0.0005 2 <0.05 0.0009 <0.005 <0.0005 <0.01 0.0002 0.06<0.05 <0.0005 0.15 0.0023 0.0007 0.001 3 <0.05 0.0027 <0.005 <0.0005 <0.01 0.0003 0.06<0.05 0.0044 0.32 0.0023 0.0017 0.0013 8 <0.05 0.0038 <0.005 0.0005 <0.01 0.0006 0.06<0.05 0.002 0.28 0.0027 0.0013 0.0009 3 <0.05 0.003 <0.005 0.0005 <0.01 0.0003 0.060.08 0.0024 0.25 0.0037 0.0017 0.001 3 <0.05 0.0042 <0.005 0.0006 <0.01 0.0005 0.070.09 0.0012 0.35 0.0053 0.0017 0.0016 9 <0.05 0.0076 0.005 0.0008 <0.01 0.001 0.07<0.05 0.0029 0.07 0.0009 <0.0005 <0.0005 6 <0.05 0.0008 <0.005 0.0005 <0.01 0.0001 0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Cr Cs Cu Dy Er Eu Fe Ga Gd Ge Hf Hg Ho Ippm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)<0.05 0.0017 <0.05 0.0006 <0.0005 <0.0005 9 <0.05 0.0005 <0.005 <0.0005 <0.01 <0.0001 0.06<0.05 0.0035 0.05 0.0005 0.0006 <0.0005 18 <0.05 0.0021 <0.005 0.0005 <0.01 0.0002 0.06<0.05 0.0032 0.19 0.0011 <0.0005 0.0005 4 <0.05 0.0023 <0.005 <0.0005 <0.01 0.0003 0.050.09 0.0024 0.22 0.0037 0.0018 0.0008 10 <0.05 0.0035 <0.005 <0.0005 0.01 0.0007 0.060.1 0.0054 <0.05 <0.0005 <0.0005 <0.0005 31 <0.05 0.0007 <0.005 0.0012 0.01 0.0001 2.330.09 0.0039 0.47 0.0045 0.0023 0.0015 16 <0.05 0.0043 <0.005 <0.0005 0.01 0.0008 0.330.11 0.0062 <0.05 0.0005 0.0008 <0.0005 34 <0.05 0.0008 <0.005 0.0015 0.01 <0.0001 2.250.09 0.002 0.84 0.0079 0.0047 0.003 20 <0.05 0.0086 <0.005 0.0015 0.01 0.0014 0.370.1 0.0038 0.73 0.0066 0.0039 0.0028 33 <0.05 0.0072 <0.005 0.0014 0.01 0.0013 0.180.07 0.0032 0.12 <0.0005 0.0005 <0.0005 4 <0.05 0.0006 <0.005 <0.0005 <0.01 0.0003 0.120.07 0.0028 0.15 0.0008 0.0005 <0.0005 4 <0.05 0.0009 <0.005 <0.0005 <0.01 0.0002 0.070.07 0.0014 0.14 0.0016 0.0008 0.0005 5 <0.05 0.0018 <0.005 <0.0005 <0.01 0.0004 0.070.08 0.001 0.13 0.0011 <0.0005 <0.0005 3 <0.05 0.0009 <0.005 <0.0005 <0.01 0.0002 0.060.06 0.0027 <0.05 0.0006 <0.0005 <0.0005 11 <0.05 0.0007 <0.005 <0.0005 <0.01 0.0001 0.070.06 0.0016 <0.05 <0.0005 <0.0005 <0.0005 3 <0.05 <0.0005 <0.005 <0.0005 <0.01 0.0001 0.060.05 0.0033 0.09 <0.0005 <0.0005 <0.0005 2 <0.05 0.001 <0.005 <0.0005 <0.01 0.0001 0.060.09 0.0054 0.52 0.0021 0.0012 0.0006 6 <0.05 0.0024 <0.005 0.0006 <0.01 0.0002 0.080.09 0.0038 0.43 0.0035 0.0012 0.0011 4 <0.05 0.0032 <0.005 0.0009 <0.01 0.0006 0.070.05 0.0029 0.1 0.0007 0.0007 <0.0005 4 <0.05 0.0008 <0.005 <0.0005 <0.01 0.0002 0.060.06 0.0043 0.14 0.0007 <0.0005 <0.0005 3 <0.05 0.0006 <0.005 <0.0005 <0.01 0.0001 0.060.07 0.002 0.5 0.0045 0.0018 0.0017 8 <0.05 0.0045 0.007 0.0006 <0.01 0.001 0.070.06 0.0036 0.35 0.0018 0.001 0.0006 3 <0.05 0.002 <0.005 <0.0005 <0.01 0.0003 0.050.1 0.006 <0.05 0.0007 <0.0005 <0.0005 38 <0.05 <0.0005 <0.005 0.0014 <0.01 0.0002 2.12<0.05 0.0012 0.05 <0.0005 <0.0005 <0.0005 6 <0.05 0.0009 <0.005 0.0015 <0.01 <0.0001 0.50.07 0.0062 0.06 <0.0005 <0.0005 <0.0005 21 <0.05 0.0005 <0.005 <0.0005 <0.01 0.0001 0.150.06 0.0017 0.08 0.0009 <0.0005 0.0009 7 <0.05 0.0008 <0.005 <0.0005 <0.01 0.0002 0.10.05 0.0007 0.09 0.0007 <0.0005 <0.0005 5 <0.05 0.0007 <0.005 <0.0005 <0.01 0.0001 0.090.11 0.0024 0.05 <0.0005 <0.0005 <0.0005 10 <0.05 0.0006 <0.005 <0.0005 <0.01 <0.0001 0.080.05 0.0025 <0.05 0.0007 0.0007 <0.0005 10 <0.05 0.0008 <0.005 <0.0005 <0.01 0.0001 0.08<0.05 0.002 <0.05 <0.0005 <0.0005 <0.0005 5 <0.05 0.0009 <0.005 <0.0005 <0.01 0.0001 0.06<0.05 0.0021 0.08 <0.0005 <0.0005 <0.0005 6 <0.05 <0.0005 <0.005 <0.0005 <0.01 0.0001 0.060.07 0.0007 0.52 0.0062 0.0036 0.0021 8 <0.05 0.0069 <0.005 0.0009 <0.01 0.0013 0.08373SAMPLEQ515694Q515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Cr Cs Cu Dy Er Eu Fe Ga Gd Ge Hf Hg Ho Ippm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)0.07 0.0036 0.14 0.0029 0.0018 0.0013 11 <0.05 0.0027 <0.005 0.0009 <0.01 0.0006 0.060.09 0.0026 0.2 0.0109 0.0017 0.0006 9 <0.05 0.002 <0.005 0.0013 <0.01 0.0004 0.05<0.05 0.002 0.16 0.0008 <0.0005 0.0005 7 <0.05 0.0012 <0.005 <0.0005 <0.01 0.0015 0.05<0.05 0.0023 <0.05 <0.0005 0.0005 <0.0005 4 <0.05 <0.0005 <0.005 <0.0005 <0.01 0.0001 0.05<0.05 0.0044 <0.05 <0.0005 <0.0005 <0.0005 1 <0.05 <0.0005 <0.005 <0.0005 <0.01 <0.0001 0.05<0.05 0.0031 0.19 0.0008 <0.0005 <0.0005 2 <0.05 <0.0005 <0.005 <0.0005 <0.01 0.0001 0.050.06 0.0049 <0.05 0.0008 0.0005 <0.0005 37 <0.05 0.0006 <0.005 0.0023 <0.01 0.0001 2.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03In K La Li Lu Mg Mn Mo Na Nb Nd Ni P Pbppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm<0.001 5 0.0015 0.07 <0.0001 2 0.06 0.002 5 <0.0005 0.0073 0.08 1 <0.005<0.001 6 0.0047 0.07 <0.0001 2.3 0.06 0.003 5 0.0005 0.0054 0.12 2 <0.005<0.001 7 0.0048 0.08 0.0001 4.6 0.97 0.02 7 0.0016 0.0071 0.17 2 <0.005<0.001 14 0.0358 0.05 0.0006 25.3 0.58 0.035 11 0.0022 0.0469 0.25 10 0.009<0.001 <5 0.0091 0.12 0.0001 3.6 0.12 0.004 6 0.0008 0.0104 0.11 2 <0.005<0.001 12 0.0113 0.09 0.0002 2.6 0.11 0.008 7 0.0013 0.0187 0.09 4 <0.005<0.001 9 0.0114 0.06 0.0004 1.9 0.15 0.006 8 0.0005 0.0175 0.08 1 0.008<0.001 9 0.0193 0.07 <0.0001 3 0.22 0.005 10 0.0012 0.0283 0.09 1 <0.005<0.001 7 0.0088 0.05 0.0001 2.8 0.09 0.005 8 0.001 0.0136 0.09 1 <0.005<0.001 5 0.002 0.08 <0.0001 2.8 <0.05 0.003 6 <0.0005 0.0055 0.08 2 <0.005<0.001 7 0.0064 0.08 0.0001 2.8 0.11 0.004 8 0.0005 0.0068 0.09 2 <0.005<0.001 6 0.0053 0.09 0.0001 2.2 0.11 0.003 8 <0.0005 0.0073 0.09 2 <0.005<0.001 7 0.0039 0.09 <0.0001 2.2 <0.05 0.002 8 <0.0005 0.0048 0.1 2 <0.005<0.001 7 0.0086 0.08 0.0001 3.1 0.25 0.003 5 0.0007 0.0089 0.08 1 <0.005<0.001 6 0.0093 0.09 0.0001 2.1 0.18 0.003 6 0.0007 0.0101 0.06 1 <0.005<0.001 8 0.015 0.05 0.0002 2.2 0.44 0.004 5 0.0008 0.0191 <0.05 1 <0.005<0.001 88 0.0022 0.04 0.0001 20.1 4 <0.001 58 0.0029 0.0026 0.06 1 0.006<0.001 <5 0.0064 0.06 0.0001 1.8 <0.05 0.002 6 <0.0005 0.0088 0.07 2 <0.005<0.001 7 0.0098 0.05 <0.0001 2.3 0.07 0.005 7 0.0006 0.015 0.08 2 <0.005<0.001 <5 0.009 0.11 <0.0001 2.7 0.18 0.004 6 0.0005 0.0165 0.08 2 <0.005<0.001 13 0.0111 0.13 0.0001 14.1 0.25 0.004 9 0.0006 0.0101 0.16 4 0.006<0.001 5 0.0025 0.07 0.0001 1.5 0.05 0.003 6 0.0014 0.0042 0.06 2 <0.005<0.001 6 0.0123 0.09 0.0001 4.1 0.43 0.007 6 0.0053 0.0121 0.08 1 <0.005<0.001 7 0.0117 0.07 <0.0001 2.3 0.14 0.006 6 0.001 0.0141 0.08 1 <0.005<0.001 5 0.0038 0.07 0.0001 3.6 0.15 0.004 5 0.0007 0.0054 0.06 2 <0.005<0.001 6 0.0334 0.05 0.0001 2.6 0.13 0.004 5 0.0007 0.0329 0.07 1 <0.005<0.001 7 0.0041 0.09 <0.0001 1.6 0.43 0.001 6 0.0006 0.006 0.08 1 <0.005<0.001 7 0.0026 0.06 <0.0001 3.5 0.12 0.001 6 <0.0005 0.004 0.08 1 <0.005<0.001 <5 0.0035 0.06 0.0002 2.2 <0.05 0.002 6 <0.0005 0.0051 <0.05 2 <0.005<0.001 24 0.0233 0.09 0.0002 11.8 0.2 0.007 7 0.0205 0.0302 0.19 2 0.005<0.001 10 0.0111 0.06 0.0005 21.4 0.2 0.005 12 0.0013 0.0151 0.14 4 <0.005<0.001 <5 0.0034 0.06 <0.0001 1.6 <0.05 0.006 <5 <0.0005 0.0031 <0.05 1 <0.005D.6 De-Ionized Water ICP-MS (Rerun)[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03In K La Li Lu Mg Mn Mo Na Nb Nd Ni P Pbppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)<0.001 18 0.0312 0.05 0.0002 30.6 0.16 0.001 28 0.002 0.0364 0.19 7 0.005<0.001 91 0.0025 0.04 0.0001 20.2 4 0.001 59 0.0031 0.003 <0.05 <1 0.005<0.001 12 0.0263 0.04 0.0004 28.2 0.18 0.003 16 0.0016 0.0345 0.17 8 <0.005<0.001 24 0.0445 0.03 0.0006 22.6 0.2 0.01 14 0.003 0.0553 0.27 8 0.007<0.001 <5 0.0097 0.09 <0.0001 1.5 <0.05 0.001 5 0.0017 0.0162 <0.05 2 <0.005<0.001 9 0.014 0.13 <0.0001 2.9 0.06 0.018 6 0.001 0.0198 0.05 3 <0.005<0.001 9 0.0196 0.06 0.0001 2.7 0.06 0.014 5 0.0009 0.0187 0.05 2 <0.005<0.001 5 0.0044 0.08 0.0001 2.5 0.12 0.002 6 0.0005 0.0066 0.06 1 <0.005<0.001 7 0.0069 0.05 <0.0001 2.1 0.12 0.003 5 0.0011 0.0071 0.06 1 <0.005<0.001 5 0.0084 0.05 <0.0001 1 0.17 0.001 5 0.0008 0.0115 <0.05 1 <0.005<0.001 <5 0.0022 0.05 <0.0001 3.3 <0.05 0.003 <5 <0.0005 0.0018 <0.05 1 <0.005<0.001 7 0.0174 0.09 <0.0001 3.5 0.11 0.006 7 0.0014 0.0048 0.07 2 <0.005<0.001 11 0.0042 0.06 <0.0001 3.1 0.16 0.003 10 0.0029 0.0062 <0.05 2 <0.005<0.001 8 0.0297 0.13 0.0002 3.8 0.1 0.01 5 0.003 0.0316 <0.05 1 <0.005<0.001 7 0.0045 0.08 <0.0001 1.9 0.19 0.003 <5 0.0012 0.0038 <0.05 1 <0.005<0.001 7 0.01 0.06 0.0002 3.4 0.05 0.005 <5 <0.0005 0.0122 <0.05 <1 0.005<0.001 14 0.0174 0.09 0.0001 4.6 0.37 0.007 7 0.0016 0.0256 <0.05 1 <0.005<0.001 9 0.0108 0.07 0.0001 1.8 0.15 0.006 <5 0.0008 0.013 <0.05 <1 <0.005<0.001 5 0.0248 0.09 0.0003 6.1 0.14 0.007 5 0.0027 0.0302 <0.05 <1 <0.005<0.001 6 0.0155 0.08 0.0001 3.2 0.05 0.007 <5 <0.0005 0.0173 <0.05 <1 <0.005<0.001 17 0.0099 0.12 0.0001 5.4 0.28 0.008 6 0.0049 0.0139 <0.05 1 <0.005<0.001 <5 0.002 0.05 <0.0001 3.8 <0.05 <0.001 8 0.002 0.0021 <0.05 <1 <0.005<0.001 <5 0.005 0.03 0.0001 1.1 0.22 0.004 <5 0.001 0.0044 <0.05 <1 <0.005<0.001 8 0.0104 0.05 0.0001 3.1 0.27 0.002 <5 <0.0005 0.0083 <0.05 <1 <0.005<0.001 7 0.0084 0.04 0.0001 5.9 0.45 0.004 <5 0.0017 0.0114 <0.05 <1 <0.005<0.001 5 0.0026 0.08 <0.0001 2.7 0.17 0.007 <5 0.0009 0.0033 <0.05 1 <0.005<0.001 12 0.0052 0.06 <0.0001 6.8 0.24 0.002 6 0.0222 0.0059 <0.05 <1 <0.005<0.001 19 0.0334 0.12 0.0002 10.9 0.26 0.008 <5 0.0022 0.0306 0.08 1 <0.005<0.001 <5 0.0188 0.08 0.0001 2.8 <0.05 0.008 <5 0.0005 0.0188 <0.05 <1 <0.005<0.001 <5 0.0074 0.07 0.0001 1.6 <0.05 0.004 <5 0.0005 0.0064 <0.05 <1 <0.005<0.001 <5 0.0041 0.06 <0.0001 2.2 0.08 0.003 <5 <0.0005 0.0043 <0.05 <1 <0.005<0.001 6 0.0094 0.07 0.0001 1.5 0.23 0.001 <5 0.0008 0.0114 <0.05 <1 <0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03In K La Li Lu Mg Mn Mo Na Nb Nd Ni P Pbppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)<0.001 8 0.0076 0.05 0.0001 2.3 0.05 0.011 <5 <0.0005 0.0112 <0.05 <1 <0.005<0.001 <5 0.0096 0.05 0.0001 2 0.17 0.007 <5 <0.0005 0.0204 <0.05 <1 <0.005<0.001 87 0.0026 0.05 0.0001 21.6 4.33 0.003 57 0.0048 0.0026 <0.05 <1 0.009<0.001 <5 0.0038 0.06 <0.0001 1.5 0.17 0.003 <5 <0.0005 0.0057 <0.05 <1 <0.005<0.001 <5 0.0048 0.06 <0.0001 1.4 0.42 0.002 <5 <0.0005 0.0052 <0.05 <1 <0.005<0.001 <5 0.0036 0.06 <0.0001 2.9 0.06 0.005 <5 <0.0005 0.0043 <0.05 <1 <0.005<0.001 5 0.013 0.07 0.0001 1.6 0.08 0.005 <5 <0.0005 0.0154 <0.05 <1 <0.005<0.001 <5 0.0084 0.07 <0.0001 1.6 0.36 0.004 <5 <0.0005 0.0092 <0.05 <1 <0.005<0.001 6 0.0037 0.1 <0.0001 1.2 <0.05 0.002 <5 <0.0005 0.0044 <0.05 <1 <0.005<0.001 <5 0.0039 0.07 0.0001 2.7 0.07 0.003 <5 <0.0005 0.0047 <0.05 <1 <0.005<0.001 6 0.009 0.05 <0.0001 2.2 0.2 0.002 <5 <0.0005 0.0074 <0.05 <1 <0.005<0.001 8 0.0022 0.1 <0.0001 1.9 0.46 0.002 7 <0.0005 0.0021 <0.05 <1 <0.005<0.001 6 0.0027 0.09 <0.0001 1.2 0.57 0.002 <5 0.0007 0.0027 <0.05 <1 <0.005<0.001 <5 0.0032 0.07 <0.0001 1.4 0.19 <0.001 <5 <0.0005 0.0033 <0.05 <1 <0.005<0.001 5 0.089 0.08 <0.0001 2 <0.05 0.003 <5 <0.0005 0.0029 <0.05 <1 <0.005<0.001 <5 0.0036 0.07 <0.0001 2 <0.05 0.004 <5 0.0006 0.0022 <0.05 <1 <0.005<0.001 <5 0.0097 0.09 <0.0001 6.3 0.1 0.003 5 0.001 0.01 <0.05 1 <0.005<0.001 7 0.0053 0.11 <0.0001 5.6 0.24 0.023 6 0.0006 0.0064 <0.05 1 <0.005<0.001 <5 0.0014 0.07 <0.0001 1.2 0.09 0.001 <5 <0.0005 0.0015 <0.05 <1 <0.005<0.001 92 0.0033 0.06 <0.0001 21.4 4.44 0.002 58 0.0061 0.003 <0.05 <1 0.01<0.001 <5 0.003 0.06 <0.0001 2.4 0.05 0.006 <5 0.0005 0.0038 <0.05 1 <0.005<0.001 5 0.0118 0.05 0.0002 3.3 0.23 0.007 <5 0.0006 0.0162 <0.05 <1 <0.005<0.001 6 0.0031 0.07 0.0001 3.8 <0.05 0.004 <5 <0.0005 0.0026 <0.05 1 <0.005<0.001 <5 0.0098 0.05 <0.0001 2.7 <0.05 0.006 <5 <0.0005 0.0105 <0.05 <1 <0.005<0.001 <5 0.0026 0.04 <0.0001 1.3 <0.05 0.003 <5 <0.0005 0.003 <0.05 1 <0.005<0.001 <5 0.0041 0.05 <0.0001 2.6 <0.05 0.001 <5 0.0006 0.0038 <0.05 1 <0.005<0.001 5 0.015 0.04 0.0001 11.2 <0.05 0.005 <5 0.0011 0.0172 0.05 3 <0.005<0.001 <5 0.0222 0.1 0.0002 3.4 0.06 0.003 5 0.0008 0.0276 0.06 1 <0.005<0.001 <5 0.0158 0.1 0.0001 5.1 0.07 0.005 6 0.0009 0.0203 <0.05 2 <0.005<0.001 22 0.0204 0.04 0.0002 26.5 0.21 0.004 18 0.0017 0.0273 0.11 8 <0.005<0.001 42 0.0296 0.06 0.0003 33.6 0.28 0.023 18 0.002 0.0348 0.18 13 0.006<0.001 6 0.0082 0.11 <0.0001 2.5 0.07 0.008 <5 0.0006 0.0061 <0.05 <1 <0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03In K La Li Lu Mg Mn Mo Na Nb Nd Ni P Pbppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)<0.001 <5 0.0025 0.06 <0.0001 1.6 <0.05 0.003 <5 0.0024 0.0024 <0.05 <1 <0.005<0.001 <5 0.0054 0.06 <0.0001 2.3 0.18 0.007 <5 0.0006 0.008 <0.05 <1 <0.005<0.001 5 0.0109 0.08 0.0001 2.6 0.05 0.002 <5 0.001 0.0117 <0.05 1 <0.005<0.001 12 0.0231 0.08 0.0002 13.6 0.29 0.019 7 0.0021 0.0278 0.07 5 0.006<0.001 84 0.0029 0.04 <0.0001 21.4 4.19 <0.001 54 0.0074 0.0069 <0.05 <1 0.012<0.001 16 0.0282 0.04 0.0005 38.3 0.73 0.017 9 0.0025 0.0365 0.13 10 0.006<0.001 86 0.0038 0.05 <0.0001 22 4.32 0.002 58 0.0062 0.003 <0.05 <1 0.0120.001 17 0.0509 0.02 0.0006 29 0.31 0.03 5 0.0033 0.066 0.32 14 0.008<0.001 14 0.0446 0.04 0.0006 39.9 0.9 0.007 9 0.0026 0.0573 0.24 9 0.006<0.001 5 0.0042 0.1 0.0001 4.2 0.11 0.003 6 0.0009 0.007 <0.05 1 <0.0050.001 <5 0.0085 0.07 <0.0001 4 0.1 0.003 8 0.001 0.0083 <0.05 2 <0.005<0.001 12 0.0123 0.08 0.0002 1.6 <0.05 0.001 5 0.0016 0.0174 <0.05 4 <0.005<0.001 10 0.0058 0.08 0.0001 2.5 <0.05 <0.001 <5 0.0016 0.0077 <0.05 2 <0.005<0.001 7 0.002 0.06 0.0001 2 <0.05 0.003 <5 0.0009 0.0036 <0.05 1 <0.005<0.001 <5 0.0011 0.03 <0.0001 2.6 <0.05 0.006 <5 0.0009 0.001 <0.05 1 <0.005<0.001 6 0.0068 0.08 <0.0001 2.9 0.05 0.008 6 0.001 0.0058 <0.05 2 <0.0050.001 8 0.014 0.04 0.0002 33.7 0.23 0.006 8 0.0033 0.0191 0.2 9 <0.005<0.001 11 0.0212 0.03 0.0002 32.4 0.22 0.003 14 0.0033 0.0272 0.19 8 <0.005<0.001 <5 0.0068 0.07 <0.0001 3.1 <0.05 0.002 5 0.0008 0.0081 <0.05 2 <0.005<0.001 5 0.0057 0.09 <0.0001 4.4 0.07 0.018 9 0.0008 0.01 0.06 1 <0.0050.001 8 0.0392 0.04 0.0003 33.1 0.33 0.007 10 0.002 0.0452 0.21 5 <0.005<0.001 7 0.0179 0.1 <0.0001 4.7 0.1 0.005 <5 0.0007 0.0171 <0.05 1 <0.005<0.001 92 0.006 0.04 <0.0001 22.4 4.25 0.001 58 0.0102 0.0063 <0.05 <1 0.013<0.001 <5 0.0068 0.05 0.0001 3.3 <0.05 0.005 <5 <0.0005 0.0097 <0.05 1 <0.005<0.001 19 0.0054 0.13 <0.0001 7.5 1.48 0.008 7 0.0017 0.0066 <0.05 3 0.01<0.001 6 0.0059 0.06 0.0001 3.5 0.17 0.007 <5 0.0014 0.0074 <0.05 1 <0.005<0.001 6 0.0042 0.06 <0.0001 3.9 0.08 0.008 8 0.0006 0.0055 <0.05 1 <0.0050.001 <5 0.0032 0.06 <0.0001 3.9 <0.05 0.006 <5 0.0006 0.0035 <0.05 1 <0.005<0.001 6 0.0049 0.06 0.0001 2.5 0.19 0.016 <5 0.0005 0.005 0.05 1 <0.005<0.001 <5 0.0022 0.05 <0.0001 2.5 0.12 0.004 5 0.0005 0.0036 <0.05 1 <0.005<0.001 8 0.0043 0.06 <0.0001 4.1 0.1 0.007 <5 0.0011 0.0047 <0.05 2 <0.0050.001 35 0.0474 0.04 0.0005 29.2 0.23 0.004 19 0.0025 0.0535 0.24 8 0.007378SAMPLEQ515694Q515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03In K La Li Lu Mg Mn Mo Na Nb Nd Ni P Pbppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)<0.001 17 0.0455 0.05 0.0002 15.4 0.12 0.004 <5 0.0129 0.0426 0.17 3 <0.005<0.001 21 0.0175 0.08 0.0002 13.6 0.12 0.005 <5 0.0129 0.0233 0.14 1 0.008<0.001 10 0.0104 0.09 0.0001 2.6 0.26 0.014 <5 0.0006 0.0103 <0.05 1 <0.005<0.001 <5 0.0023 0.05 <0.0001 1.4 <0.05 0.003 <5 0.0005 0.0041 <0.05 2 <0.005<0.001 <5 0.0015 0.06 <0.0001 1.8 <0.05 0.003 <5 0.0006 0.0029 <0.05 2 <0.005<0.001 <5 0.005 0.08 0.0001 3.1 0.25 0.003 <5 0.0007 0.0057 <0.05 1 <0.005<0.001 88 0.0042 0.06 0.0001 22.2 4.14 0.001 57 0.0083 0.004 <0.05 <1 0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Pr Rb Re Sb Se Sm Sn Sr Ta Tb Te Th Ti Tlppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm0.0006 0.053 <0.0002 0.0008 <0.02 0.0009 <0.005 0.065 <0.001 0.0001 <0.005 0.0011 0.21 <0.0010.002 0.06 <0.0002 0.0007 0.02 0.0017 <0.005 0.09 <0.001 0.0002 <0.005 0.0031 0.24 0.0010.0021 0.066 <0.0002 0.0005 <0.02 0.0022 <0.005 0.219 <0.001 0.0003 <0.005 0.0052 0.55 0.0010.0117 0.08 <0.0002 0.0037 <0.02 0.0102 <0.005 0.404 <0.001 0.0008 <0.005 0.0142 0.54 0.0030.0032 0.082 <0.0002 0.0008 <0.02 0.0022 <0.005 0.091 0.001 0.0002 <0.005 0.0029 1.35 0.0020.0047 0.086 <0.0002 0.0014 0.02 0.0049 <0.005 0.098 <0.001 0.0005 <0.005 0.0062 0.37 0.0010.0038 0.037 <0.0002 <0.0005 <0.02 0.0029 <0.005 0.06 <0.001 0.0003 <0.005 0.0035 0.12 0.0010.007 0.048 <0.0002 0.0007 <0.02 0.0045 <0.005 0.095 <0.001 0.001 <0.005 0.0042 0.14 0.0010.0028 0.06 <0.0002 <0.0005 0.05 0.0029 <0.005 0.105 <0.001 0.0002 <0.005 0.0031 0.5 0.0010.0007 0.066 <0.0002 0.0005 <0.02 <0.0005 <0.005 0.054 <0.001 0.0001 <0.005 0.0015 0.06 0.0010.0018 0.06 <0.0002 0.0007 <0.02 0.0021 <0.005 0.085 <0.001 0.0001 <0.005 0.0025 0.09 0.0010.0013 0.072 <0.0002 0.0005 <0.02 0.0019 <0.005 0.06 <0.001 0.0001 <0.005 0.0016 <0.05 0.0010.0013 0.066 <0.0002 0.0007 <0.02 0.0017 <0.005 0.064 <0.001 0.0002 0.005 0.0016 0.07 <0.0010.0025 0.062 <0.0002 0.0013 <0.02 0.0018 <0.005 0.088 <0.001 0.0003 <0.005 0.003 0.11 0.0010.0025 0.065 <0.0002 0.0006 <0.02 0.0029 <0.005 0.057 <0.001 0.0003 <0.005 0.0023 0.18 0.0010.0041 0.066 <0.0002 0.0008 <0.02 0.0043 <0.005 0.096 <0.001 0.0004 <0.005 0.0031 0.34 0.0010.0005 0.367 <0.0002 0.0006 <0.02 0.0013 <0.005 0.431 <0.001 0.0001 <0.005 0.004 1.34 0.0020.0015 0.071 <0.0002 0.0007 <0.02 0.0024 <0.005 0.074 <0.001 0.0002 <0.005 0.0019 0.08 <0.0010.0038 0.068 <0.0002 <0.0005 <0.02 0.0026 <0.005 0.146 <0.001 0.0004 <0.005 0.004 0.53 0.0010.0033 0.038 <0.0002 0.001 <0.02 0.003 <0.005 0.092 <0.001 0.0002 <0.005 0.0042 0.23 0.0020.0025 0.07 <0.0002 0.001 <0.02 0.0032 <0.005 0.268 <0.001 0.0003 0.007 0.0027 0.12 0.0020.0007 0.049 <0.0002 0.0008 <0.02 0.0008 <0.005 0.082 <0.001 <0.0001 <0.005 0.0021 0.11 0.0010.0036 0.086 <0.0002 0.0009 <0.02 0.0026 <0.005 0.101 <0.001 0.0002 <0.005 0.0047 0.32 0.0010.0037 0.077 <0.0002 0.0008 <0.02 0.0029 <0.005 0.073 <0.001 0.0003 <0.005 0.0043 0.21 0.0010.0011 0.072 <0.0002 0.0013 <0.02 0.0012 <0.005 0.145 <0.001 0.0002 <0.005 0.0024 0.17 0.0010.0075 0.082 <0.0002 0.0006 <0.02 0.0288 <0.005 0.091 <0.001 0.0006 <0.005 0.0087 0.14 0.0010.001 0.073 <0.0002 0.001 <0.02 0.0012 <0.005 0.061 <0.001 0.0001 <0.005 0.0018 0.11 <0.0010.0006 0.06 <0.0002 0.0009 0.05 <0.0005 <0.005 0.119 <0.001 0.0002 <0.005 0.0011 0.07 0.0010.0013 0.041 <0.0002 <0.0005 <0.02 0.0015 <0.005 0.033 <0.001 0.0002 <0.005 0.002 0.08 <0.0010.0067 0.099 <0.0002 0.0019 <0.02 0.0044 <0.005 0.092 <0.001 0.0006 <0.005 0.0058 0.82 0.0010.0033 0.055 <0.0002 0.0016 <0.02 0.0024 <0.005 0.4 <0.001 0.0005 <0.005 0.0026 0.38 0.0030.0004 0.042 <0.0002 <0.0005 <0.02 0.0006 <0.005 0.024 <0.001 <0.0001 <0.005 0.0009 0.13 0.001D.6 De-Ionized Water ICP-MS (Rerun)[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Pr Rb Re Sb Se Sm Sn Sr Ta Tb Te Th Ti Tlppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)0.0091 0.079 <0.0002 0.0012 <0.02 0.0099 <0.005 0.861 <0.001 0.001 <0.005 0.0097 0.36 0.0030.0007 0.373 <0.0002 0.0009 <0.02 0.001 <0.005 0.448 <0.001 0.0001 <0.005 0.0024 1.05 0.0020.0085 0.088 <0.0002 0.0008 <0.02 0.01 <0.005 0.784 <0.001 0.0007 <0.005 0.0071 0.25 0.0010.0134 0.084 <0.0002 0.002 <0.02 0.0144 <0.005 1.01 <0.001 0.0017 <0.005 0.0096 0.66 0.0020.0033 0.064 <0.0002 0.0007 <0.02 0.0025 <0.005 0.049 <0.001 0.0002 <0.005 0.0034 0.23 0.0010.0045 0.169 <0.0002 0.0015 <0.02 0.0033 <0.005 0.069 <0.001 0.0003 <0.005 0.0048 0.47 0.0020.0054 0.102 <0.0002 0.0009 0.02 0.0028 <0.005 0.101 <0.001 0.0003 <0.005 0.0058 0.17 0.0020.0016 0.061 <0.0002 <0.0005 <0.02 0.0018 <0.005 0.096 <0.001 0.0002 <0.005 0.0016 0.11 0.0010.0019 0.057 <0.0002 <0.0005 <0.02 0.0016 <0.005 0.089 <0.001 0.0002 <0.005 0.0033 0.23 0.0010.0023 0.054 <0.0002 0.0006 <0.02 0.0023 <0.005 0.034 <0.001 0.0003 <0.005 0.0024 0.23 0.0010.0006 0.055 <0.0002 0.0005 <0.02 0.0006 <0.005 0.06 <0.001 <0.0001 <0.005 0.0008 0.06 <0.0010.0013 0.078 <0.0002 0.0009 <0.02 0.0007 <0.005 0.096 <0.001 0.0001 <0.005 0.002 0.24 0.0010.0011 0.073 <0.0002 <0.0005 <0.02 0.0016 <0.005 0.081 <0.001 0.0002 0.006 0.0112 1.12 0.0010.0073 0.109 <0.0002 0.0011 0.04 0.0059 <0.005 0.066 <0.001 0.0006 <0.005 0.0057 0.12 0.0020.0012 0.074 <0.0002 <0.0005 0.05 0.001 <0.005 0.042 <0.001 0.0001 0.005 0.0023 0.13 0.0010.0032 0.069 <0.0002 <0.0005 0.03 0.003 <0.005 0.093 <0.001 0.0003 <0.005 0.0038 0.23 0.0010.0056 0.066 <0.0002 0.001 0.06 0.0051 <0.005 0.094 <0.001 0.0005 <0.005 0.0036 0.29 0.0010.0039 0.078 <0.0002 0.0005 0.03 0.0044 <0.005 0.049 <0.001 0.0002 <0.005 0.0026 0.1 0.0010.0073 0.092 <0.0002 0.0005 <0.02 0.0079 <0.005 0.083 <0.001 0.0006 <0.005 0.0075 0.46 0.0010.0047 0.066 <0.0002 <0.0005 <0.02 0.0044 <0.005 0.076 <0.001 0.0003 <0.005 0.0034 1.15 0.0010.0027 0.124 <0.0002 0.0007 0.04 0.0036 <0.005 0.042 <0.001 0.0003 <0.005 0.0044 0.25 0.0010.0007 0.032 <0.0002 <0.0005 <0.02 0.0006 <0.005 0.105 <0.001 0.0001 <0.005 0.001 0.09 0.0010.0013 0.054 <0.0002 <0.0005 0.02 0.0012 <0.005 0.074 <0.001 0.0002 <0.005 0.0018 0.13 0.0010.0025 0.069 <0.0002 0.001 0.06 0.0025 <0.005 0.076 <0.001 0.0002 <0.005 0.0023 0.14 0.0010.0023 0.073 <0.0002 <0.0005 <0.02 0.002 <0.005 0.116 <0.001 0.0001 <0.005 0.0067 0.21 0.0020.0007 0.079 <0.0002 <0.0005 <0.02 0.001 <0.005 0.058 <0.001 0.0001 <0.005 0.0014 0.17 0.0010.0014 0.085 <0.0002 <0.0005 0.04 0.0011 <0.005 0.11 <0.001 0.0001 <0.005 0.0022 0.32 0.0010.0078 0.128 <0.0002 0.0027 0.05 0.0071 <0.005 0.117 0.001 0.0006 <0.005 0.0069 0.15 0.0020.0045 0.06 <0.0002 0.0006 <0.02 0.0047 <0.005 0.083 <0.001 0.0003 <0.005 0.0038 0.18 0.0010.0018 0.056 <0.0002 <0.0005 0.04 0.002 <0.005 0.095 <0.001 0.0002 <0.005 0.0014 0.21 0.0010.0012 0.059 <0.0002 0.0009 <0.02 0.002 <0.005 0.073 <0.001 0.0001 <0.005 0.0019 0.05 0.0010.0032 0.058 <0.0002 0.0007 <0.02 0.0016 <0.005 0.054 <0.001 0.0002 <0.005 0.0026 0.23 0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Pr Rb Re Sb Se Sm Sn Sr Ta Tb Te Th Ti Tlppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)0.0038 0.03 <0.0002 <0.0005 0.03 0.0041 <0.005 0.044 <0.001 0.0003 <0.005 0.0026 0.19 0.0010.0028 0.044 <0.0002 0.0007 0.02 0.0023 <0.005 0.058 <0.001 0.0002 <0.005 0.002 0.33 0.0010.0006 0.355 <0.0002 0.0014 0.07 0.0005 <0.005 0.462 <0.001 0.0001 <0.005 0.004 2.05 0.0020.0014 0.046 <0.0002 0.0006 0.03 0.0009 <0.005 0.057 <0.001 0.0001 <0.005 0.0016 <0.05 <0.0010.0013 0.041 <0.0002 <0.0005 0.02 0.0014 <0.005 0.075 <0.001 0.0002 <0.005 0.0016 <0.05 0.0010.0014 0.054 <0.0002 0.001 0.04 0.0015 0.008 0.079 <0.001 0.0002 <0.005 0.001 0.08 0.0020.0041 0.054 <0.0002 <0.0005 0.03 0.0037 <0.005 0.065 <0.001 0.0004 <0.005 0.003 0.07 0.0010.0025 0.046 <0.0002 <0.0005 0.03 0.0015 <0.005 0.073 <0.001 0.0002 <0.005 0.002 <0.05 0.0010.0012 0.072 <0.0002 0.0011 0.09 0.0018 <0.005 0.042 0.001 0.0001 <0.005 0.0013 0.67 0.0010.0011 0.064 <0.0002 0.0006 0.04 0.001 <0.005 0.068 <0.001 0.0002 <0.005 0.0016 0.07 0.0010.0022 0.068 <0.0002 0.0012 0.04 0.001 <0.005 0.057 <0.001 0.0001 0.005 0.0019 0.11 0.0010.0005 0.077 <0.0002 0.0006 0.07 0.0006 <0.005 0.047 <0.001 0.0001 <0.005 <0.0005 <0.05 0.0010.0017 0.068 <0.0002 <0.0005 0.07 0.001 <0.005 0.064 <0.001 0.0001 <0.005 0.0009 0.12 <0.0010.0008 0.066 <0.0002 <0.0005 0.06 0.0007 <0.005 0.066 <0.001 0.0001 <0.005 0.0019 0.05 0.0010.001 0.052 <0.0002 <0.0005 0.03 0.0009 <0.005 0.039 <0.001 0.0001 <0.005 0.0012 0.21 0.0010.0009 0.101 <0.0002 <0.0005 0.02 0.0007 <0.005 0.032 <0.001 0.0001 <0.005 0.0019 <0.05 0.0010.0027 0.034 <0.0002 0.0005 0.05 0.002 <0.005 0.104 <0.001 0.0005 <0.005 0.0026 0.18 0.0020.0016 0.157 <0.0002 0.0015 0.03 0.0013 <0.005 0.085 <0.001 0.0002 <0.005 0.0023 0.15 0.0020.0004 0.053 <0.0002 <0.0005 0.1 0.0007 <0.005 0.04 <0.001 0.0001 <0.005 0.001 0.08 0.0010.001 0.372 <0.0002 0.0006 0.04 <0.0005 <0.005 0.442 <0.001 0.0002 <0.005 0.0041 2.51 0.0020.0009 0.057 <0.0002 <0.0005 0.05 0.0008 <0.005 0.082 <0.001 0.0001 <0.005 0.0011 0.2 0.0010.0037 0.056 <0.0002 <0.0005 0.02 0.0029 <0.005 0.094 <0.001 0.0004 <0.005 0.0031 0.12 0.0010.0007 0.063 <0.0002 <0.0005 <0.02 0.0012 <0.005 0.063 <0.001 0.0001 <0.005 0.0011 0.12 0.0010.0031 0.053 <0.0002 0.0007 0.02 0.0021 <0.005 0.083 <0.001 0.0002 <0.005 0.0025 <0.05 0.0010.0006 0.011 <0.0002 0.0006 <0.02 0.0008 <0.005 0.034 <0.001 0.0001 <0.005 0.0013 0.08 0.0010.0008 0.026 <0.0002 <0.0005 0.04 0.0011 <0.005 0.048 <0.001 0.0002 <0.005 0.0011 0.06 0.0010.0043 0.028 <0.0002 0.0009 <0.02 0.0035 <0.005 0.226 <0.001 0.0004 <0.005 0.0032 0.22 0.0010.0073 0.072 <0.0002 <0.0005 <0.02 0.0052 <0.005 0.11 <0.001 0.0005 <0.005 0.0047 0.23 0.0020.005 0.065 <0.0002 0.0007 0.09 0.0026 <0.005 0.083 <0.001 0.0005 <0.005 0.0043 0.19 0.0020.0066 0.069 <0.0002 0.0013 0.06 0.0067 <0.005 0.641 <0.001 0.0005 <0.005 0.0074 0.27 0.0040.0092 0.166 <0.0002 0.0005 0.04 0.0075 <0.005 0.616 <0.001 0.0011 <0.005 0.0126 0.51 0.0030.0022 0.059 <0.0002 <0.0005 0.04 0.0013 <0.005 0.055 <0.001 0.0005 <0.005 0.0023 0.15 0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Pr Rb Re Sb Se Sm Sn Sr Ta Tb Te Th Ti Tlppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)0.0007 0.034 <0.0002 <0.0005 <0.02 0.0009 <0.005 0.048 <0.001 0.0001 <0.005 0.0018 0.05 0.0010.0017 0.056 <0.0002 <0.0005 0.02 0.0019 <0.005 0.106 <0.001 0.0002 <0.005 0.0025 0.07 0.0020.0036 0.099 <0.0002 0.0006 <0.02 0.0017 <0.005 0.056 <0.001 0.0003 <0.005 0.0048 0.24 0.0010.0066 0.095 <0.0002 0.002 0.06 0.0048 <0.005 0.367 <0.001 0.001 <0.005 0.009 0.57 0.0020.0011 0.354 <0.0002 0.0008 0.09 0.0009 <0.005 0.44 0.001 0.0002 0.005 0.0061 2.59 0.0010.008 0.13 <0.0002 0.0021 <0.02 0.007 <0.005 0.7 <0.001 0.001 0.009 0.0147 0.33 0.0020.0011 0.358 <0.0002 0.0008 0.02 0.0012 <0.005 0.449 0.001 0.0003 <0.005 0.0058 2.78 0.0020.0167 0.042 <0.0002 0.0022 0.02 0.0133 <0.005 1.07 0.002 0.0016 <0.005 0.0202 0.38 0.0030.0127 0.088 0.0002 0.0012 <0.02 0.0108 <0.005 0.877 <0.001 0.0014 0.005 0.0121 0.55 0.0020.0016 0.166 <0.0002 0.0008 0.03 0.0014 <0.005 0.052 <0.001 0.0001 <0.005 0.0034 0.13 0.0010.0022 0.021 <0.0002 0.0008 <0.02 0.0018 <0.005 0.079 <0.001 0.0003 <0.005 0.0027 0.17 0.0010.0042 0.144 <0.0002 0.0005 0.04 0.002 <0.005 0.044 <0.001 0.0002 <0.005 0.0046 0.41 <0.0010.002 0.129 <0.0002 0.0009 0.03 0.0026 <0.005 0.066 <0.001 0.0002 0.005 0.0035 0.15 0.0010.0008 0.054 <0.0002 <0.0005 <0.02 <0.0005 <0.005 0.054 <0.001 0.0001 <0.005 0.0009 0.05 0.0010.0004 0.037 <0.0002 <0.0005 <0.02 0.0006 <0.005 0.094 <0.001 <0.0001 <0.005 0.0019 0.09 <0.0010.0016 0.171 <0.0002 0.0005 <0.02 0.0017 <0.005 0.051 <0.001 0.0002 <0.005 0.0027 0.13 0.0010.0044 0.044 <0.0002 0.001 0.05 0.0031 <0.005 0.788 0.001 0.0007 <0.005 0.027 0.32 0.0050.0061 0.105 <0.0002 0.001 0.04 0.0039 <0.005 0.772 <0.001 0.0007 <0.005 0.0175 0.33 0.0030.0023 0.047 <0.0002 0.0006 <0.02 0.0013 <0.005 0.064 0.001 0.0002 <0.005 0.0025 0.2 0.0010.0035 0.164 0.0002 0.0008 0.02 0.0016 <0.005 0.049 <0.001 0.0002 <0.005 0.0024 0.16 0.0020.0107 0.056 0.0002 0.0013 <0.02 0.007 <0.005 0.746 <0.001 0.0008 <0.005 0.0098 0.29 0.0040.0047 0.156 <0.0002 0.001 <0.02 0.0026 <0.005 0.091 <0.001 0.0003 <0.005 0.0049 0.18 0.0020.0009 0.373 <0.0002 0.0009 0.05 0.0006 <0.005 0.526 <0.001 <0.0001 0.007 0.0068 2.33 0.0020.0015 0.074 <0.0002 <0.0005 0.06 0.0019 <0.005 0.05 <0.001 0.0001 0.005 0.0026 0.08 0.0010.0011 0.106 <0.0002 <0.0005 0.04 0.0013 <0.005 0.126 <0.001 0.0002 <0.005 0.0054 0.53 <0.0010.0017 0.072 <0.0002 0.0008 <0.02 0.0017 <0.005 0.086 <0.001 0.0002 <0.005 0.0035 0.17 <0.0010.0016 0.063 <0.0002 <0.0005 <0.02 0.001 <0.005 0.097 <0.001 0.0001 <0.005 0.0031 0.06 <0.0010.0016 0.049 <0.0002 0.0005 <0.02 0.0015 <0.005 0.08 <0.001 0.0002 <0.005 0.0021 0.08 0.0010.0013 0.066 <0.0002 <0.0005 0.02 0.0014 <0.005 0.096 <0.001 0.0002 <0.005 0.0015 0.14 0.0010.0009 0.051 <0.0002 0.0005 <0.02 0.0019 <0.005 0.072 <0.001 0.0002 <0.005 0.0022 0.14 0.0010.001 0.063 <0.0002 <0.0005 0.04 0.0013 <0.005 0.076 <0.001 0.0001 <0.005 0.0028 0.12 <0.0010.0125 0.054 0.0002 0.0022 <0.02 0.0104 <0.005 0.854 <0.001 0.0012 <0.005 0.0128 0.34 0.004383SAMPLEQ515694Q515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Pr Rb Re Sb Se Sm Sn Sr Ta Tb Te Th Ti Tlppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppmD.6 De-Ionized Water ICP-MS (Rerun)0.0061 0.097 <0.0002 0.0009 0.02 0.0067 <0.005 0.184 0.001 0.0006 <0.005 0.009 0.64 0.0010.0072 0.15 <0.0002 0.0029 <0.02 0.0046 <0.005 0.096 <0.001 0.0005 <0.005 0.0079 0.4 0.0010.0033 0.08 <0.0002 <0.0005 0.02 0.0025 <0.005 0.082 <0.001 0.0003 <0.005 0.0074 0.09 0.0010.0006 0.059 <0.0002 <0.0005 <0.02 0.0008 <0.005 0.035 <0.001 0.0001 <0.005 0.0012 0.06 <0.0010.0004 0.052 <0.0002 0.0006 <0.02 <0.0005 <0.005 0.03 <0.001 0.0001 <0.005 0.0009 0.07 0.0010.0018 0.067 <0.0002 0.0016 0.02 0.0032 <0.005 0.061 <0.001 0.0001 <0.005 0.0015 0.18 0.0020.0012 0.356 <0.0002 0.0008 0.04 <0.0005 <0.005 0.473 <0.001 0.0002 <0.005 0.0059 2.99 0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 pH-MS03 C-IR06aTm U V W Y Yb Zn Zr Final pH C organicppm ppm ppm ppm ppm ppm ppm ppm Unity %<0.0001 0.0016 <0.05 <0.001 0.0022 <0.0005 <0.05 0.002 5 0.15<0.0001 0.0027 0.05 0.001 0.0039 0.0005 <0.05 0.009 5.2 0.270.0001 0.0031 0.11 0.001 0.0062 0.0015 0.06 0.011 4.5 0.260.0005 0.0124 1.17 0.004 0.0326 0.0033 0.05 0.032 4.3 27.30.0001 0.003 0.2 0.001 0.0076 0.0006 <0.05 0.01 4.6 1.590.0002 0.0081 0.56 0.001 0.0118 0.0011 <0.05 0.019 5 0.33<0.0001 0.0242 <0.05 0.001 0.0141 0.0011 <0.05 0.008 5.1 0.060.0001 0.0067 <0.05 <0.001 0.0132 0.0017 <0.05 0.01 5.2 0.14<0.0001 0.0038 <0.05 0.001 0.0065 0.001 <0.05 0.009 5.2 0.11<0.0001 0.0018 <0.05 <0.001 0.003 0.0005 <0.05 0.004 4.8 0.15<0.0001 0.0029 <0.05 0.001 0.0041 <0.0005 <0.05 0.007 5 0.25<0.0001 0.0019 <0.05 <0.001 0.0047 <0.0005 <0.05 0.004 4.4 0.170.0001 0.0024 <0.05 <0.001 0.0037 <0.0005 <0.05 0.003 4.6 0.160.0001 0.0054 <0.05 <0.001 0.0048 0.0008 <0.05 0.005 4.9 0.21<0.0001 0.0048 <0.05 0.001 0.0052 0.0006 <0.05 0.006 5 0.160.0002 0.0056 <0.05 0.001 0.0083 0.0011 <0.05 0.008 5.1 0.1<0.0001 0.0008 <0.05 <0.001 0.0018 0.0006 <0.05 0.033 5 0.82<0.0001 0.0022 0.17 0.001 0.0037 0.0007 <0.05 0.007 5.3 0.350.0001 0.0058 <0.05 <0.001 0.0073 0.001 <0.05 0.008 5.1 0.27<0.0001 0.0045 0.09 0.001 0.0068 0.0006 <0.05 0.01 4.7 0.50.0002 0.0038 <0.05 <0.001 0.0085 0.0013 0.05 0.011 4.4 2.77<0.0001 0.0026 <0.05 0.001 0.0027 0.0008 <0.05 0.004 4.9 0.220.0002 0.0094 0.08 0.001 0.0082 0.0006 <0.05 0.031 5 0.230.0001 0.0057 <0.05 0.001 0.0054 0.0008 <0.05 0.008 5 0.19<0.0001 0.0021 <0.05 <0.001 0.0033 <0.0005 <0.05 0.005 4.9 0.470.0001 0.0106 <0.05 <0.001 0.0116 0.0006 <0.05 0.011 5.1 0.610.0001 0.0022 <0.05 <0.001 0.0019 0.0007 0.05 0.003 5.1 0.190.0001 0.0013 <0.05 <0.001 0.0019 <0.0005 <0.05 0.001 5.3 0.35<0.0001 0.0021 <0.05 0.001 0.0029 <0.0005 <0.05 0.005 5.2 0.20.0002 0.0144 0.14 0.001 0.0178 0.0026 <0.05 0.042 5.1 0.260.0001 0.0023 0.33 0.001 0.0111 0.0009 0.06 0.008 4.4 9.020.0001 0.0012 0.25 0.002 0.0022 <0.0005 <0.05 0.004 4.7 0.58D.6 De-Ionized Water ICP-MS (Rerun)[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 pH-MS03 C-IR06aTm U V W Y Yb Zn Zr Final pH C organicppm ppm ppm ppm ppm ppm ppm ppm Unity %D.6 De-Ionized Water ICP-MS (Rerun)0.0003 0.0088 0.12 0.001 0.0217 0.0027 <0.05 0.028 4 30.40.0002 0.0005 <0.05 0.001 0.0017 <0.0005 <0.05 0.037 4.9 0.920.0004 0.0084 0.23 0.001 0.0215 0.0014 <0.05 0.023 3.9 32.50.0006 0.0082 0.46 0.002 0.0368 0.0037 0.06 0.032 4 230.0001 0.0029 0.46 0.001 0.0076 0.001 <0.05 0.007 4.6 1.110.0001 0.0067 0.43 0.003 0.007 <0.0005 0.05 0.019 4.9 0.280.0001 0.0072 0.69 0.001 0.009 0.001 <0.05 0.011 4.8 1.70.0001 0.0015 <0.05 <0.001 0.0044 0.0005 <0.05 0.004 4.9 0.170.0001 0.0028 <0.05 0.001 0.0045 <0.0005 <0.05 0.004 4.9 0.37<0.0001 0.0019 <0.05 0.001 0.0046 0.0005 <0.05 0.005 5.1 0.18<0.0001 0.0014 <0.05 0.001 0.0019 <0.0005 <0.05 0.002 5.4 0.1<0.0001 0.002 0.1 0.002 0.0034 0.0006 0.07 0.006 4.5 0.55<0.0001 0.0028 0.07 0.001 0.0046 <0.0005 <0.05 0.01 4.8 0.360.0003 0.0097 0.16 0.001 0.0135 0.0009 0.05 0.023 4.8 0.450.0001 0.0023 <0.05 <0.001 0.0026 <0.0005 <0.05 0.008 4.7 0.16<0.0001 0.0068 <0.05 <0.001 0.0069 0.0008 <0.05 0.012 4.7 0.20.0001 0.0145 0.06 0.001 0.0137 0.0013 <0.05 0.013 4.7 0.20.0002 0.0101 0.05 0.001 0.0069 0.0009 <0.05 0.015 4.8 0.120.0003 0.0099 0.09 <0.001 0.0153 0.0019 <0.05 0.021 4.7 0.320.0001 0.0065 <0.05 0.001 0.0073 0.0009 <0.05 0.007 4.8 0.090.0002 0.0115 0.12 <0.001 0.0073 0.0025 <0.05 0.056 4.8 0.07<0.0001 0.0014 <0.05 <0.001 0.0028 <0.0005 <0.05 0.004 4.6 0.11<0.0001 0.002 <0.05 0.001 0.003 0.0005 <0.05 0.003 4.7 0.270.0001 0.0037 <0.05 <0.001 0.0048 0.0009 <0.05 0.004 5.1 0.16<0.0001 0.0039 <0.05 0.001 0.0034 0.0006 <0.05 0.005 5.2 0.40.0001 0.0027 <0.05 <0.001 0.0026 <0.0005 <0.05 0.005 4.8 0.130.0001 0.0025 <0.05 <0.001 0.0035 0.0005 <0.05 0.005 4.8 0.220.0003 0.0118 0.23 0.001 0.0185 0.0019 0.09 0.024 4.7 1.260.0001 0.0066 0.06 0.001 0.0086 0.0008 <0.05 0.008 4.6 0.350.0001 0.0029 <0.05 <0.001 0.0046 <0.0005 <0.05 0.005 5.2 0.370.0001 0.0017 <0.05 <0.001 0.0042 <0.0005 <0.05 0.025 6.1 0.140.0001 0.0054 <0.05 <0.001 0.0058 <0.0005 <0.05 0.005 5.6 0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 pH-MS03 C-IR06aTm U V W Y Yb Zn Zr Final pH C organicppm ppm ppm ppm ppm ppm ppm ppm Unity %D.6 De-Ionized Water ICP-MS (Rerun)0.0001 0.0057 <0.05 0.001 0.0079 0.0006 <0.05 0.007 5.1 0.02<0.0001 0.0045 <0.05 <0.001 0.0053 <0.0005 <0.05 0.017 5.1 0.05<0.0001 0.0011 0.06 0.001 0.0044 <0.0005 <0.05 0.046 4.8 0.83<0.0001 0.0029 <0.05 <0.001 0.0028 <0.0005 <0.05 0.004 5 0.05<0.0001 0.0034 <0.05 <0.001 0.0035 0.0006 <0.05 0.004 4.8 0.69<0.0001 0.0027 <0.05 <0.001 0.0031 <0.0005 <0.05 0.004 4.8 0.340.0002 0.0054 <0.05 0.001 0.0095 0.0013 <0.05 0.006 5 0.10.0001 0.0046 <0.05 <0.001 0.005 0.0007 <0.05 0.004 5 0.130.0001 0.0022 <0.05 <0.001 0.0031 <0.0005 <0.05 0.003 4.8 0.150.0001 0.0022 <0.05 <0.001 0.0028 <0.0005 <0.05 0.003 4.9 0.130.0001 0.0042 <0.05 0.001 0.0047 0.0006 <0.05 0.004 5.1 0.03<0.0001 0.0019 <0.05 <0.001 0.0018 <0.0005 <0.05 0.001 4.7 0.22<0.0001 0.0013 <0.05 0.001 0.0024 <0.0005 <0.05 0.002 4.8 0.09<0.0001 0.0013 <0.05 <0.001 0.0027 <0.0005 <0.05 0.002 4.8 0.190.0001 0.0012 <0.05 0.001 0.0029 <0.0005 <0.05 0.003 4.9 0.10.0001 0.0014 0.26 0.002 0.0019 <0.0005 <0.05 0.005 4.8 0.630.0002 0.0044 0.34 0.001 0.0077 <0.0005 <0.05 0.007 4.5 3.14<0.0001 0.0028 0.57 0.002 0.0033 0.0005 <0.05 0.012 4.5 1.06<0.0001 0.0011 <0.05 0.001 0.0019 <0.0005 <0.05 0.003 4.9 0.10.0001 0.0012 0.08 0.001 0.0025 <0.0005 <0.05 0.059 4.8 0.84<0.0001 0.0016 <0.05 <0.001 0.0026 <0.0005 <0.05 0.004 4.8 0.130.0001 0.0045 <0.05 0.001 0.0079 0.0006 <0.05 0.006 4.9 0.220.0001 0.0016 <0.05 <0.001 0.0024 <0.0005 <0.05 0.002 5 0.130.0001 0.0028 0.08 <0.001 0.005 <0.0005 <0.05 0.005 4.8 0.62<0.0001 0.0007 0.08 0.001 0.0021 <0.0005 <0.05 0.002 4.8 0.45<0.0001 0.001 0.08 0.001 0.0023 0.0005 <0.05 0.003 4.8 0.460.0001 0.0029 0.24 <0.001 0.0118 0.0014 0.05 0.01 4.3 7.780.0003 0.009 0.34 0.001 0.0154 0.0015 <0.05 0.012 4.4 2.610.0001 0.0038 0.53 0.001 0.0102 0.0012 <0.05 0.01 4.5 2.30.0001 0.0065 0.12 0.001 0.017 0.0013 0.06 0.018 4 31.40.0005 0.0086 0.2 0.001 0.0241 0.0025 <0.05 0.027 4.5 27.90.0001 0.0033 0.15 0.001 0.0039 0.0005 <0.05 0.008 4.8 0.[binary]-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 pH-MS03 C-IR06aTm U V W Y Yb Zn Zr Final pH C organicppm ppm ppm ppm ppm ppm ppm ppm Unity %D.6 De-Ionized Water ICP-MS (Rerun)<0.0001 0.0016 <0.05 0.001 0.0019 <0.0005 0.06 0.003 4.8 0.090.0001 0.0018 0.12 0.001 0.004 0.0005 <0.05 0.006 4.8 0.230.0001 0.0053 0.15 0.001 0.0068 0.0006 <0.05 0.011 4.8 1.740.0003 0.008 0.48 0.002 0.0153 0.0011 0.08 0.019 4.3 23.7<0.0001 0.0013 0.09 0.001 0.0036 0.0006 <0.05 0.061 4.7 0.880.0004 0.0067 0.99 0.002 0.025 0.0016 <0.05 0.022 4.3 280.0001 0.0015 0.1 <0.001 0.0043 <0.0005 <0.05 0.063 4.6 0.890.0008 0.0105 0.75 0.003 0.0502 0.0049 0.1 0.04 3.9 33.80.0006 0.013 0.84 0.003 0.0374 0.0028 0.07 0.032 4.2 23.90.0001 0.0034 0.73 0.002 0.0038 <0.0005 <0.05 0.009 4.6 1.76<0.0001 0.0035 0.48 0.001 0.0053 0.0007 <0.05 0.007 4.5 20.0002 0.0063 0.52 0.001 0.0076 0.0007 <0.05 0.013 4.8 0.730.0001 0.0044 0.38 0.001 0.0053 <0.0005 <0.05 0.012 4.8 0.8<0.0001 0.0013 <0.05 <0.001 0.0017 <0.0005 <0.05 0.003 4.6 0.1<0.0001 0.0008 0.26 0.001 0.0009 <0.0005 <0.05 0.003 4.8 0.2<0.0001 0.0027 0.75 0.003 0.005 0.0005 <0.05 0.007 4.6 1.230.0002 0.0111 0.1 <0.001 0.0139 0.0011 0.08 0.03 3.9 26.80.0001 0.0095 0.12 <0.001 0.0174 0.0019 0.05 0.03 3.8 29.70.0001 0.0019 0.21 <0.001 0.0049 0.0005 <0.05 0.004 4.5 1<0.0001 0.0032 0.21 0.002 0.0045 <0.0005 <0.05 0.006 4.4 1.010.0002 0.0096 0.22 0.001 0.0225 0.0026 <0.05 0.025 4 23.20.0001 0.0059 0.3 0.001 0.0071 0.0005 <0.05 0.008 4.3 2.390.0001 0.0021 0.1 0.001 0.011 0.0006 <0.05 0.1 4.5 0.83<0.0001 0.002 <0.05 <0.001 0.0026 <0.0005 <0.05 0.003 4.7 0.19<0.0001 0.0024 0.06 0.001 0.0037 0.0006 0.05 0.012 4.4 0.460.0002 0.0043 0.07 <0.001 0.0041 <0.0005 <0.05 0.007 4.8 0.130.0001 0.0041 0.06 <0.001 0.0028 <0.0005 <0.05 0.007 4.7 0.2<0.0001 0.0024 0.11 <0.001 0.0032 0.0005 <0.05 0.004 4.6 0.32<0.0001 0.0028 <0.05 <0.001 0.0037 0.0005 <0.05 0.005 4.5 0.27<0.0001 0.003 <0.05 <0.001 0.0034 <0.0005 <0.05 0.005 4.6 0.24<0.0001 0.0034 0.09 <0.001 0.0037 <0.0005 <0.05 0.008 4.5 0.360.0005 0.0119 0.08 <0.001 0.0329 0.0035 0.05 0.029 3.9 23.6388SAMPLEQ515694Q515695Q515696Q515697Q515698Q515699Q515700Q515700aME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 pH-MS03 C-IR06aTm U V W Y Yb Zn Zr Final pH C organicppm ppm ppm ppm ppm ppm ppm ppm Unity %D.6 De-Ionized Water ICP-MS (Rerun)0.0001 0.0104 0.11 <0.001 0.0161 0.0014 <0.05 0.033 4.6 0.590.0002 0.0149 0.39 <0.001 0.0092 0.0015 <0.05 0.038 4.6 0.27<0.0001 0.009 0.12 0.001 0.0065 0.0008 <0.05 0.008 4.5 0.23<0.0001 0.0016 <0.05 0.001 0.0016 <0.0005 <0.05 0.002 4.5 0.2<0.0001 0.0006 0.12 0.001 0.0014 <0.0005 <0.05 0.002 4.5 0.330.0001 0.0017 0.27 <0.001 0.0054 0.0012 <0.05 0.004 5.1 1.080.0001 0.0015 0.09 0.001 0.0087 0.0005 <0.05 0.073 4.4 0.82389fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSample ID Sample Type Site Mode Elapsed Time 1 Elapsed Time 2 Elapsed Time 3 Elapsed Time Total Live Time 1 Live Time 2 Live Time 3 Live Time Total Instrument SNQ515501 Soil 26 Soil 3 Beam 29.687 28.936 29.765 88.388 24.925 22.717 26.528 74.17 550271Q515502 Soil 27 Soil 3 Beam 29.712 28.985 29.765 88.462 25.062 22.928 26.502 74.492 550271Q515503 Soil 28 Soil 3 Beam 29.728 29.064 29.602 88.394 25.238 23.138 23.875 72.251 550271Q515504 Soil 29 Soil 3 Beam 29.847 29.23 29.581 88.658 25.542 24.003 24.364 73.909 550271Q515505 Soil 30 Soil 3 Beam 29.731 28.997 29.769 88.497 25.145 22.99 26.606 74.741 550271Q515506 Soil 31 Soil 3 Beam 29.713 28.997 29.776 88.486 25.074 23.005 26.685 74.764 550271Q515507 Soil 125 Soil 3 Beam 29.686 28.948 29.76 88.394 24.998 22.77 26.434 74.202 550271Q515508 Soil 124 Soil 3 Beam 29.69 28.949 29.75 88.389 24.975 22.73 26.297 74.002 550271Q515509 Soil 123 Soil 3 Beam 29.694 28.962 29.76 88.416 25 22.837 26.423 74.26 550271Q515510 Soil 122 Soil 3 Beam 29.709 28.973 29.759 88.441 25.041 22.867 26.42 74.328 550271Q515511 Soil 121 Soil 3 Beam 29.707 28.985 29.758 88.45 25.046 22.925 26.394 74.365 550271Q515512 Soil 120 Soil 3 Beam 29.687 28.939 29.747 88.373 24.966 22.671 26.199 73.836 550271Q515513 Soil 119 Soil 3 Beam 29.718 28.994 29.766 88.478 25.161 22.962 26.44 74.563 550271OREAS25a Standard Soil 3 Beam 29.803 29.2 29.443 88.446 25.762 23.605 21.563 70.93 550271Q515513DUP Duplicate Soil 3 Beam 29.714 28.989 29.761 88.464 25.087 22.931 26.447 74.465 550271Q515514 Soil 118 Soil 3 Beam 29.702 28.961 29.754 88.417 25.059 22.79 26.308 74.157 550271Q515515 Soil 117 Soil 3 Beam 29.7 28.949 29.754 88.403 25.068 22.739 26.3 74.107 550271Q515516 Soil 116 Soil 3 Beam 29.716 28.957 29.748 88.421 25.047 22.771 26.208 74.026 550271Q515517 Soil 14 Soil 3 Beam 29.692 28.942 29.768 88.402 25.026 22.721 26.55 74.297 550271Q515518 Soil 15 Soil 3 Beam 29.702 28.973 29.761 88.436 25.065 22.874 26.45 74.389 550271Q515519 Soil 13 Soil 3 Beam 29.702 28.969 29.746 88.417 25.039 22.826 26.214 74.079 550271Q515520 Soil 12 Soil 3 Beam 29.761 29.104 29.562 88.427 25.458 23.256 23.341 72.055 550271Q515521 Soil 11 Soil 3 Beam 29.7 28.932 29.76 88.392 25.037 22.656 26.436 74.129 550271Q515522 Soil 10 Soil 3 Beam 29.719 28.987 29.753 88.459 25.147 22.887 26.266 74.3 550271Q515523 Soil 9 Soil 3 Beam 29.714 28.998 29.75 88.462 25.107 22.953 26.231 74.291 550271Q515524 Soil 8 Soil 3 Beam 29.723 28.992 29.75 88.465 25.089 22.94 26.237 74.266 550271Q515525 Soil 7 Soil 3 Beam 29.717 28.989 29.752 88.458 25.137 22.912 26.29 74.339 550271Q515526 Soil 115 Soil 3 Beam 29.716 28.964 29.758 88.438 25.024 22.827 26.411 74.262 550271Q515527 Soil 114 Soil 3 Beam 29.722 29.002 29.758 88.482 25.166 22.996 26.374 74.536 550271Q515528 Soil 113 Soil 3 Beam 29.706 28.953 29.776 88.435 25.058 22.769 26.597 74.424 550271Q515529 Soil 112 Soil 3 Beam 29.735 29.041 29.744 88.52 25.211 23.156 26.103 74.47 550271Q515530 Soil 6 Soil 3 Beam 29.829 29.207 29.761 88.797 25.428 23.949 26.638 76.015 550271Q515531 Soil 5 Soil 3 Beam 29.706 28.949 29.787 88.442 25.054 22.768 26.833 74.655 550271Q515551 Soil 77 Soil 3 Beam 29.881 29.383 29.627 88.891 25.442 24.819 25.29 75.551 550271Q515552 Soil 78 Soil 3 Beam 29.878 29.345 29.605 88.828 25.432 24.607 25.041 75.08 550271OREAS25a Standard Soil 3 Beam 29.807 29.2 29.443 88.45 25.752 23.606 21.576 70.934 550271Q515552DUP Duplicate Soil 3 Beam 29.874 29.35 29.606 88.83 25.438 24.66 25.05 75.148 550271Q515553 Soil 79 Soil 3 Beam 29.847 29.243 29.658 88.748 25.495 24.109 25.387 74.991 550271D.7 fp-XRF Soil Mode390fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSample ID Sample Type Site Mode Elapsed Time 1 Elapsed Time 2 Elapsed Time 3 Elapsed Time Total Live Time 1 Live Time 2 Live Time 3 Live Time Total Instrument SND.7 fp-XRF Soil ModeQ515554 Soil 95 Soil 3 Beam 29.745 29.024 29.778 88.547 25.196 23.105 26.71 75.011 550271Q515555 Soil 94 Soil 3 Beam 29.744 29.04 29.772 88.556 25.211 23.163 26.599 74.973 550271Q515556 Soil 93 Soil 3 Beam 29.742 29.017 29.765 88.524 25.226 23.045 26.507 74.778 550271Q515557 Soil 92 Soil 3 Beam 29.718 28.981 29.759 88.458 25.131 22.882 26.324 74.337 550271Q515558 Soil 91 Soil 3 Beam 29.752 29.046 29.761 88.559 25.22 23.172 26.444 74.836 550271Q515559 Soil 90 Soil 3 Beam 29.703 28.97 29.76 88.433 25.011 22.846 26.415 74.272 550271Q515560 Soil 89 Soil 3 Beam 29.704 28.97 29.762 88.436 25.059 22.843 26.449 74.351 550271Q515561 Soil 88 Soil 3 Beam 29.726 29.012 29.75 88.488 25.18 23.048 26.25 74.478 550271Q515562 Soil 87 Soil 3 Beam 29.735 29.004 29.757 88.496 25.158 22.969 26.266 74.393 550271Cal Check Cal Check Cal Check 14.737 0 0 14.737 11.714 0 0 11.714 550271Q515563 Soil 86 Soil 3 Beam 29.724 29 29.759 88.483 25.152 22.973 26.39 74.515 550271Q515564 Soil 85 Soil 3 Beam 29.726 29.008 29.762 88.496 25.116 23.018 26.448 74.582 550271Q515565 Soil 84 Soil 3 Beam 29.714 28.994 29.752 88.46 25.094 22.954 26.274 74.322 550271Q515566 Soil 83 Soil 3 Beam 29.717 28.986 29.754 88.457 25.136 22.902 26.291 74.329 550271Q515567 Soil 82 Soil 3 Beam 29.697 28.956 29.761 88.414 25.054 22.767 26.356 74.177 550271Q515568 Soil 81 Soil 3 Beam 29.741 29.04 29.753 88.534 25.2 23.174 26.254 74.628 550271Q515569 Soil 80 Soil 3 Beam 29.722 29.005 29.761 88.488 25.112 22.989 26.425 74.526 550271Q515570 Soil 96 Soil 3 Beam 29.746 29.061 29.758 88.565 25.183 23.279 26.338 74.8 550271Q515571 Soil 97 Soil 3 Beam 29.737 29.027 29.766 88.53 25.194 23.119 26.502 74.815 550271Q515572 Soil 98 Soil 3 Beam 29.721 28.999 29.772 88.492 25.151 22.992 26.657 74.8 550271OREAS25a Standard Soil 3 Beam 29.806 29.202 29.443 88.451 25.75 23.609 21.574 70.933 550271Q515572DUP Duplicate Soil 3 Beam 29.72 28.997 29.773 88.49 25.092 23.005 26.643 74.74 550271Q515573 Soil 99 Soil 3 Beam 29.73 29.019 29.745 88.494 25.176 23.044 26.159 74.379 550271Q515574 Soil 100 Soil 3 Beam 29.739 29.034 29.738 88.511 25.222 23.115 26.087 74.424 550271Q515575 Soil 101 Soil 3 Beam 29.729 29.027 29.765 88.521 25.156 23.105 26.467 74.728 550271Q515576 Soil 102 Soil 3 Beam 29.754 29.03 29.741 88.525 25.233 23.1 26.116 74.449 550271Q515577 Soil 103 Soil 3 Beam 29.757 29.068 29.757 88.582 25.276 23.278 26.365 74.919 550271Q515578 Soil 104 Soil 3 Beam 29.763 29.074 29.762 88.599 25.287 23.321 26.436 75.044 550271Q515579 Soil 105 Soil 3 Beam 29.735 29.026 29.758 88.519 25.196 23.095 26.375 74.666 550271Q515580 Soil 106 Soil 3 Beam 29.736 29.045 29.765 88.546 25.181 23.193 26.477 74.851 550271Q515581 Soil 107 Soil 3 Beam 29.727 29.013 29.763 88.503 25.143 23.023 26.418 74.584 550271Q515582 Soil 108 Soil 3 Beam 29.74 29.041 29.772 88.553 25.214 23.153 26.587 74.954 550271Q515583 Field Duplicate 108b Soil 3 Beam 29.725 29.017 29.767 88.509 25.152 23.038 26.499 74.689 550271Q515584 Soil 109 Soil 3 Beam 29.749 29.053 29.766 88.568 25.227 23.233 26.528 74.988 550271Q515585 Soil 110 Soil 3 Beam 29.733 28.996 29.76 88.489 25.153 22.973 26.431 74.557 550271Q515586 Soil 111 Soil 3 Beam 29.766 29.044 29.761 88.571 25.272 23.19 26.437 74.899 550271Q515587 Soil 127 Soil 3 Beam 29.73 29.038 29.781 88.549 25.183 23.143 26.552 74.878 550271Q515588 Soil 126 Soil 3 Beam 29.713 28.983 29.761 88.457 25.104 22.919 26.427 74.45 550271391fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSample ID Sample Type Site Mode Elapsed Time 1 Elapsed Time 2 Elapsed Time 3 Elapsed Time Total Live Time 1 Live Time 2 Live Time 3 Live Time Total Instrument SND.7 fp-XRF Soil ModeQ515589 Field Duplicate 126b Soil 3 Beam 29.733 29.017 29.766 88.516 25.136 23.064 26.516 74.716 550271Q515590 Soil 16 Soil 3 Beam 29.716 28.999 29.759 88.474 25.1 22.978 26.372 74.45 550271Q515591 Soil 17 Soil 3 Beam 29.711 28.989 29.756 88.456 25.066 22.931 26.32 74.317 550271Q515592 Soil 18 Soil 3 Beam 29.711 28.993 29.746 88.45 25.07 22.951 26.192 74.213 550271OREAS25a Standard Soil 3 Beam 29.804 29.2 29.442 88.446 25.761 23.586 21.54 70.887 550271Q515592DUP Duplicate Soil 3 Beam 29.71 29.003 29.748 88.461 25.091 22.965 26.206 74.262 550271Q515593 Field Duplicate 18b Soil 3 Beam 29.72 29.001 29.75 88.471 25.129 22.976 26.221 74.326 550271Q515594 Soil 19 Soil 3 Beam 29.716 28.997 29.763 88.476 25.115 22.954 26.466 74.535 550271Q515595 Soil 20 Soil 3 Beam 29.7 28.949 29.769 88.418 25.038 22.743 26.582 74.363 550271Q515596 Soil 21 Soil 3 Beam 29.694 28.978 29.788 88.46 25.045 22.9 26.891 74.836 550271Q515597 Soil 22 Soil 3 Beam 29.758 28.999 29.769 88.526 25.215 23.027 26.671 74.913 550271Q515598 Soil 23 Soil 3 Beam 29.737 29.033 29.767 88.537 25.182 23.127 26.527 74.836 550271Q515599 Soil 24 Soil 3 Beam 29.726 29 29.76 88.486 25.134 22.96 26.38 74.474 550271Q515600 Soil 25 Soil 3 Beam 29.708 28.972 29.761 88.441 25.033 22.868 26.435 74.336 550271Q515651 Soil 32 Soil 3 Beam 29.731 29.024 29.756 88.511 25.188 23.071 26.316 74.575 550271Q515652 Soil 33 Soil 3 Beam 29.741 29.044 29.756 88.541 25.209 23.121 26.314 74.644 550271Q515653 Soil 34 Soil 3 Beam 29.74 29.018 29.756 88.514 25.179 23.047 26.344 74.57 550271Q515654 Soil 35 Soil 3 Beam 29.707 28.955 29.793 88.455 25.041 22.807 26.982 74.83 550271Q515655 Field Duplicate 35b Soil 3 Beam 29.708 28.947 29.783 88.438 25.007 22.763 26.832 74.602 550271Q515657 Soil 36 Soil 3 Beam 29.81 29.152 29.788 88.75 25.389 23.708 27.03 76.127 550271Q515658 Soil 37 Soil 3 Beam 29.756 29.039 29.763 88.558 25.237 23.166 26.528 74.931 550271Q515659 Soil 38 Soil 3 Beam 29.759 29.036 29.775 88.57 25.253 23.169 26.655 75.077 550271Q515660 Soil 39 Soil 3 Beam 29.877 29.36 29.642 88.879 25.426 24.7 25.491 75.617 550271Q515661 Soil 40 Soil 3 Beam 29.865 29.268 29.621 88.754 25.514 24.244 25.118 74.876 550271Q515662 Soil 41 Soil 3 Beam 29.719 28.994 29.764 88.477 25.095 22.952 26.469 74.516 550271Q515663 Soil 42 Soil 3 Beam 29.722 28.983 29.764 88.469 25.113 22.897 26.51 74.52 550271Cal Check Cal Check Cal Check 14.744 0 0 14.744 11.586 0 0 11.586 550271OREAS25a Standard Soil 3 Beam 29.803 29.198 29.444 88.445 25.764 23.579 21.595 70.938 550271Q515663DUP Duplicate Soil 3 Beam 29.72 28.982 29.765 88.467 25.105 22.909 26.476 74.49 550271Q515664 Soil 43 Soil 3 Beam 29.726 28.988 29.754 88.468 25.121 22.935 26.343 74.399 550271Q515665 Soil 44 Soil 3 Beam 29.751 29.058 29.767 88.576 25.229 23.262 26.548 75.039 550271Q515666 Soil 45 Soil 3 Beam 29.85 29.287 29.703 88.84 25.567 24.322 25.811 75.7 550271Q515667 Soil 46 Soil 3 Beam 29.85 29.243 29.624 88.717 25.587 24.091 24.933 74.611 550271Q515668 Soil 47 Soil 3 Beam 29.868 29.319 29.606 88.793 25.55 24.455 24.844 74.849 550271Q515669 Soil 63 Soil 3 Beam 29.858 29.292 29.639 88.789 25.616 24.328 24.833 74.777 550271Q515670 Soil 62 Soil 3 Beam 29.718 28.985 29.775 88.478 25.109 22.921 26.668 74.698 550271Q515671 Soil 61 Soil 3 Beam 29.74 29.004 29.779 88.523 25.203 23.024 26.755 74.982 550271Q515672 Soil 60 Soil 3 Beam 29.717 28.992 29.773 88.482 25.106 22.958 26.636 74.7 550271392fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSample ID Sample Type Site Mode Elapsed Time 1 Elapsed Time 2 Elapsed Time 3 Elapsed Time Total Live Time 1 Live Time 2 Live Time 3 Live Time Total Instrument SND.7 fp-XRF Soil ModeQ515673 Soil 59 Soil 3 Beam 29.726 28.997 29.766 88.489 25.153 22.979 26.513 74.645 550271Q515674 Soil 58 Soil 3 Beam 29.685 28.92 29.755 88.36 24.97 22.604 26.342 73.916 550271Q515675 Soil 57 Soil 3 Beam 29.703 28.947 29.776 88.426 25.015 22.746 26.695 74.456 550271Q515676 Soil 56 Soil 3 Beam 29.718 28.967 29.771 88.456 25.101 22.831 26.652 74.584 550271Q515678 Soil 54 Soil 3 Beam 29.866 29.339 29.686 88.891 25.473 24.603 25.948 76.024 550271Q515679 Field Duplicate 54b Soil 3 Beam 29.874 29.37 29.671 88.915 25.421 24.746 25.823 75.99 550271Q515680 Soil 53 Soil 3 Beam 29.732 29 29.777 88.509 25.171 22.979 26.703 74.853 550271Q515681 Soil 52 Soil 3 Beam 29.72 28.97 29.774 88.464 25.104 22.857 26.681 74.642 550271Q515682 Soil 51 Soil 3 Beam 29.861 29.307 29.67 88.838 25.495 24.423 25.704 75.622 550271Q515683 Soil 50 Soil 3 Beam 29.749 29.027 29.763 88.539 25.267 23.111 26.489 74.867 550271Q515685 Soil 49 Soil 3 Beam 29.695 28.93 29.77 88.395 25.002 22.667 26.6 74.269 550271OREAS25a Standard Soil 3 Beam 29.801 29.192 29.441 88.434 25.738 23.524 21.545 70.807 550271Q515685DUP Duplicate Soil 3 Beam 29.693 28.929 29.769 88.391 25.003 22.681 26.587 74.271 550271Q515686 Soil 48 Soil 3 Beam 29.732 29.055 29.695 88.482 25.203 23.164 25.333 73.7 550271Q515687 Soil 64 Soil 3 Beam 29.716 28.981 29.756 88.453 25.124 22.872 26.342 74.338 550271Q515688 Soil 65 Soil 3 Beam 29.738 29.018 29.756 88.512 25.167 23.06 26.323 74.55 550271Q515689 Soil 66 Soil 3 Beam 29.721 28.985 29.759 88.465 25.106 22.91 26.407 74.423 550271Q515690 Soil 67 Soil 3 Beam 29.726 29.006 29.756 88.488 25.158 22.986 26.342 74.486 550271Q515691 Soil 68 Soil 3 Beam 29.718 28.99 29.752 88.46 25.096 22.933 26.269 74.298 550271Q515692 Soil 69 Soil 3 Beam 29.717 28.976 29.766 88.459 25.074 22.897 26.53 74.501 550271Q515693 Soil 70 Soil 3 Beam 29.871 29.338 29.651 88.86 25.483 24.593 25.621 75.697 550271Q515695 Soil 72 Soil 3 Beam 29.736 29.042 29.749 88.527 25.215 23.177 26.206 74.598 550271Q515696 Field Duplicate 72b Soil 3 Beam 29.726 29.018 29.765 88.509 25.172 23.052 26.31 74.534 550271Q515697 Soil 73 Soil 3 Beam 29.729 29.027 29.768 88.524 25.185 23.11 26.563 74.858 550271Q515698 Soil 74 Soil 3 Beam 29.705 28.951 29.776 88.432 25.055 22.773 26.69 74.518 550271Q515699 Soil 75 Soil 3 Beam 29.697 28.937 29.78 88.414 25.003 22.702 26.759 74.464 550271Q515700 Soil 76 Soil 3 Beam 29.71 28.953 29.783 88.446 25.076 22.792 26.834 74.702 550271Cal Check Cal Check Cal Check 14.753 0 0 14.753 11.705 0 0 11.705 550271393Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFModel Tube Anode Unit LOD Sigma Ag Ag +/- Ag Intercept Ag Slope As As +/- As Intercept As Slope BaDELTA_SDD 47 PPM 3 -0.06592628 1.447477203 0 1 3.571054443 0.81215227 0 1 308.6342159DELTA_SDD 47 PPM 3 0.748796391 1.516179405 0 1 4.005694684 0.828619782 0 1 312.0865046DELTA_SDD 47 PPM 3 1.616880482 1.563509361 0 1 24.99826231 1.203243559 0 1 303.8586216DELTA_SDD 47 PPM 3 -6.333531658 2.575603744 0 1 9.55526998 0.65854264 0 1 83.15411205DELTA_SDD 47 PPM 3 -1.937123705 1.611561353 0 1 0.685780303 0.770958315 0 1 310.253155DELTA_SDD 47 PPM 3 -1.978991761 1.497399316 0 1 0.721592235 0.791127964 0 1 364.5046502DELTA_SDD 47 PPM 3 -0.1012614 1.433412951 0 1 5.875021673 0.862531612 0 1 336.8904629DELTA_SDD 47 PPM 3 1.448528783 1.465191971 0 1 7.385802432 0.869667535 0 1 376.3193159DELTA_SDD 47 PPM 3 1.1774985 1.485557101 0 1 6.693963051 0.854601699 0 1 338.5631204DELTA_SDD 47 PPM 3 2.733593765 1.521637283 0 1 6.567434035 0.848506792 0 1 344.8704169DELTA_SDD 47 PPM 3 -1.259801245 1.491529837 0 1 4.980728885 0.842724758 0 1 359.3537652DELTA_SDD 47 PPM 3 0.888880587 1.416034393 0 1 5.814147196 0.854886374 0 1 329.8309785DELTA_SDD 47 PPM 3 1.028789627 1.558371809 0 1 6.30224966 0.845627832 0 1 333.6527521DELTA_SDD 47 PPM 3 -2.135421431 2.096108047 0 1 8.376612642 1.199937759 0 1 133.3281772DELTA_SDD 47 PPM 3 1.225481947 1.502528847 0 1 6.404846507 0.866053651 0 1 335.5802384DELTA_SDD 47 PPM 3 0.397345824 1.475505641 0 1 6.218310803 0.861899491 0 1 354.2675767DELTA_SDD 47 PPM 3 -0.702459118 1.524944262 0 1 5.670091694 0.840660036 0 1 366.1935469DELTA_SDD 47 PPM 3 -0.031594498 1.492001756 0 1 5.223498376 0.869071244 0 1 356.6007912DELTA_SDD 47 PPM 3 0.157370805 1.502128139 0 1 2.53264825 0.808799277 0 1 353.4615247DELTA_SDD 47 PPM 3 -0.329907301 1.496742599 0 1 3.470566248 0.825748754 0 1 350.0930652DELTA_SDD 47 PPM 3 -0.378825722 1.492107155 0 1 5.825831964 0.859282894 0 1 338.9898635DELTA_SDD 47 PPM 3 1.856878237 1.751135908 0 1 49.14383481 1.41251433 0 1 250.2118053DELTA_SDD 47 PPM 3 -2.428184992 1.497415202 0 1 5.051799585 0.812294647 0 1 311.2900489DELTA_SDD 47 PPM 3 0.502328944 1.536584966 0 1 6.618321136 0.870032753 0 1 323.7568683DELTA_SDD 47 PPM 3 -0.427583749 1.521539399 0 1 6.933726637 0.873362889 0 1 327.187101DELTA_SDD 47 PPM 3 -0.848262022 1.586581209 0 1 3.673288756 0.815197099 0 1 314.8125363DELTA_SDD 47 PPM 3 1.240393502 1.535807518 0 1 5.8083178 0.8395037 0 1 313.6305813DELTA_SDD 47 PPM 3 -2.563330651 1.519604317 0 1 6.733039151 0.854265549 0 1 348.1426433DELTA_SDD 47 PPM 3 -0.465009733 1.572798173 0 1 5.353045829 0.837773195 0 1 322.9382565DELTA_SDD 47 PPM 3 -0.879596263 1.504177729 0 1 1.588714327 0.787201764 0 1 317.1267615DELTA_SDD 47 PPM 3 -2.738599709 1.582996031 0 1 6.951363022 0.886662946 0 1 380.7973063DELTA_SDD 47 PPM 3 -2.648271336 2.426393314 0 1 1.415704827 0.655617769 0 1 181.0028875DELTA_SDD 47 PPM 3 -1.770902723 1.485708869 0 1 2.542050826 0.753532629 0 1 292.8551045DELTA_SDD 47 PPM 3 -2.347096901 3.081595829 0 1 5.177217749 0.567762744 0 1 1.99919543DELTA_SDD 47 PPM 3 -8.578886475 2.92779682 0 1 5.741608746 0.54646101 0 1 34.22529136DELTA_SDD 47 PPM 3 -2.399941505 1.979351103 0 1 9.934005466 1.205093775 0 1 103.9286316DELTA_SDD 47 PPM 3 -4.67528956 2.869059599 0 1 5.931037059 0.54735264 0 1 44.49246024DELTA_SDD 47 PPM 3 0.391767292 2.590122585 0 1 7.777669158 0.63424334 0 1 74.59874439D.7 fp-XRF Soil Mode394Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFModel Tube Anode Unit LOD Sigma Ag Ag +/- Ag Intercept Ag Slope As As +/- As Intercept As Slope BaD.7 fp-XRF Soil ModeDELTA_SDD 47 PPM 3 -0.608827999 1.633288029 0 1 1.019841539 0.754469083 0 1 304.9395831DELTA_SDD 47 PPM 3 1.90150689 1.624057565 0 1 3.825416112 0.787412664 0 1 323.3649409DELTA_SDD 47 PPM 3 -1.96867487 1.654925141 0 1 4.262962417 0.789723002 0 1 318.2001746DELTA_SDD 47 PPM 3 -1.351247697 1.527148321 0 1 5.476746955 0.836691024 0 1 316.0089679DELTA_SDD 47 PPM 3 1.254141365 1.745634124 0 1 6.565982683 0.846439727 0 1 303.1221026DELTA_SDD 47 PPM 3 -1.020576917 1.450154569 0 1 5.589222238 0.857967445 0 1 341.4451903DELTA_SDD 47 PPM 3 -0.931029486 1.494436459 0 1 3.997369334 0.826923312 0 1 301.9910009DELTA_SDD 47 PPM 3 -0.254890172 1.566179972 0 1 3.98378177 0.845794494 0 1 326.5784918DELTA_SDD 47 PPM 3 -1.012623691 1.535545268 0 1 7.345299711 0.860928132 0 1 296.3523399DELTA_SDD 47 PPM NADELTA_SDD 47 PPM 3 0.791588023 1.583704373 0 1 3.40538782 0.816840451 0 1 322.6590622DELTA_SDD 47 PPM 3 -2.64681933 1.568777036 0 1 6.937011757 0.872826424 0 1 297.6160896DELTA_SDD 47 PPM 3 -0.134010165 1.560840972 0 1 7.933377477 0.874751205 0 1 348.0660841DELTA_SDD 47 PPM 3 1.556363828 1.550348499 0 1 6.129674501 0.836867558 0 1 307.3144794DELTA_SDD 47 PPM 3 1.073745554 1.454403534 0 1 5.816173944 0.845613187 0 1 327.2661993DELTA_SDD 47 PPM 3 0.6888892 1.612136625 0 1 9.078302655 0.895351441 0 1 325.7341242DELTA_SDD 47 PPM 3 -1.417218683 1.629347914 0 1 5.756322043 0.85404403 0 1 338.2172875DELTA_SDD 47 PPM 3 1.833504856 1.681566411 0 1 4.362652603 0.848118414 0 1 337.9883964DELTA_SDD 47 PPM 3 0.218555102 1.629071602 0 1 0.655945436 0.796859994 0 1 316.6311921DELTA_SDD 47 PPM 3 -1.548218289 1.524142181 0 1 2.804077353 0.797925344 0 1 300.5683933DELTA_SDD 47 PPM 3 0.822308845 1.999465313 0 1 10.64067593 1.221457263 0 1 88.13163557DELTA_SDD 47 PPM 3 -0.698875504 1.550165398 0 1 4.094690612 0.805372021 0 1 310.9429294DELTA_SDD 47 PPM 3 -0.019706397 1.620596641 0 1 7.528736994 0.879538454 0 1 377.6209163DELTA_SDD 47 PPM 3 -1.959769417 1.6457514 0 1 9.152243265 0.922883067 0 1 314.1872751DELTA_SDD 47 PPM 3 -2.092189853 1.592681191 0 1 5.374998908 0.840502377 0 1 290.398017DELTA_SDD 47 PPM 3 1.254774347 1.643409125 0 1 6.539939421 0.860199571 0 1 318.444889DELTA_SDD 47 PPM 3 3.559298985 1.713753625 0 1 3.280337479 0.831746528 0 1 342.7918583DELTA_SDD 47 PPM 3 -3.950229708 1.728647658 0 1 5.446939492 0.859998983 0 1 315.1583111DELTA_SDD 47 PPM 3 0.028231552 1.595190141 0 1 8.080492966 0.891232341 0 1 345.4459423DELTA_SDD 47 PPM 3 -1.667008194 1.667166658 0 1 7.264632089 0.856347635 0 1 303.8873067DELTA_SDD 47 PPM 3 -0.089494618 1.650141325 0 1 6.656500982 0.860782833 0 1 332.025119DELTA_SDD 47 PPM 3 0.362016573 1.622417715 0 1 5.483910315 0.840021295 0 1 325.2642184DELTA_SDD 47 PPM 3 0.370943054 1.555352995 0 1 5.442175443 0.844362562 0 1 299.0543976DELTA_SDD 47 PPM 3 -1.717792016 1.705839507 0 1 6.866823758 0.844897595 0 1 289.7220461DELTA_SDD 47 PPM 3 -0.76742269 1.581488894 0 1 4.607072185 0.846920291 0 1 321.2953391DELTA_SDD 47 PPM 3 -0.148511693 1.685366195 0 1 6.020113661 0.852432975 0 1 301.9995313DELTA_SDD 47 PPM 3 -0.789792338 1.597044429 0 1 4.560722828 0.84476177 0 1 321.5908711DELTA_SDD 47 PPM 3 -2.412465859 1.515433944 0 1 6.162122022 0.858713618 0 1 333.836052395Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFModel Tube Anode Unit LOD Sigma Ag Ag +/- Ag Intercept Ag Slope As As +/- As Intercept As Slope BaD.7 fp-XRF Soil ModeDELTA_SDD 47 PPM 3 0.195960515 1.650836234 0 1 6.433880145 0.861453613 0 1 319.0534705DELTA_SDD 47 PPM 3 1.195833887 1.533969352 0 1 5.82489567 0.834419356 0 1 323.0885962DELTA_SDD 47 PPM 3 1.52521833 1.514796124 0 1 3.572958404 0.837728643 0 1 343.6177827DELTA_SDD 47 PPM 3 1.553579755 1.50778026 0 1 6.180223191 0.896739649 0 1 340.8022609DELTA_SDD 47 PPM 3 -1.213427418 1.995320287 0 1 8.92322229 1.214252115 0 1 87.0680513DELTA_SDD 47 PPM 3 -0.39875551 1.488939291 0 1 6.552196545 0.868579204 0 1 322.7166411DELTA_SDD 47 PPM 3 3.275899828 1.546764303 0 1 6.325502683 0.868026357 0 1 358.6472758DELTA_SDD 47 PPM 3 1.295679519 1.531901638 0 1 3.805320587 0.821601672 0 1 320.0297677DELTA_SDD 47 PPM 3 -0.28697943 1.469582435 0 1 5.015192445 0.823318641 0 1 278.6166486DELTA_SDD 47 PPM 3 0.500692606 1.559141766 0 1 0.600377508 0.752581427 0 1 254.220397DELTA_SDD 47 PPM 3 -2.493893656 1.609542459 0 1 1.260168347 0.730468297 0 1 305.7798677DELTA_SDD 47 PPM 3 -1.536495748 1.554966381 0 1 0.560071219 0.79907563 0 1 315.9850946DELTA_SDD 47 PPM 3 1.178385102 1.612479543 0 1 3.83267338 0.836447565 0 1 320.1396591DELTA_SDD 47 PPM 3 1.981577928 1.522085327 0 1 5.110599766 0.844701241 0 1 310.6530078DELTA_SDD 47 PPM 3 1.067422825 1.576031144 0 1 6.68408543 0.88030792 0 1 343.0865223DELTA_SDD 47 PPM 3 -2.2007264 1.629018224 0 1 6.876694839 0.867745942 0 1 336.9590992DELTA_SDD 47 PPM 3 -0.530974008 1.696625947 0 1 4.329298049 0.819146826 0 1 343.2241828DELTA_SDD 47 PPM 3 0.84839618 1.43655966 0 1 -0.025632026 0.74341949 0 1 305.9152632DELTA_SDD 47 PPM 3 -3.183282144 1.543033423 0 1 -0.25508967 0.73475317 0 1 296.7155454DELTA_SDD 47 PPM 3 -0.59795401 2.033591684 0 1 1.72999626 0.683893039 0 1 207.2582973DELTA_SDD 47 PPM 3 0.084431444 1.710219189 0 1 0.48088725 0.768502046 0 1 291.6797936DELTA_SDD 47 PPM 3 -0.615084892 1.713786567 0 1 1.124929899 0.743202773 0 1 306.1269047DELTA_SDD 47 PPM 3 -3.542961613 2.953385611 0 1 4.279176735 0.549454959 0 1 22.69184377DELTA_SDD 47 PPM 3 -5.046933673 2.614434037 0 1 6.70492915 0.593310068 0 1 73.00761322DELTA_SDD 47 PPM 3 -1.847138136 1.548676269 0 1 3.328920818 0.811277371 0 1 325.8614392DELTA_SDD 47 PPM 3 1.930151481 1.584089612 0 1 6.561184669 0.824121739 0 1 298.4692533DELTA_SDD 47 PPM NADELTA_SDD 47 PPM 3 1.932080405 1.979698946 0 1 7.067035964 1.195031481 0 1 116.6113754DELTA_SDD 47 PPM 3 -0.076153501 1.596584268 0 1 5.106393063 0.832705295 0 1 336.8537607DELTA_SDD 47 PPM 3 1.419278136 1.548112257 0 1 8.370401627 0.850209281 0 1 283.9925277DELTA_SDD 47 PPM 3 -4.234292513 1.7411755 0 1 0.25268391 0.780541096 0 1 350.9429125DELTA_SDD 47 PPM 3 -0.824634425 2.561875092 0 1 8.114784273 0.801737668 0 1 215.7501147DELTA_SDD 47 PPM 3 -3.226827817 2.501714763 0 1 6.871777121 0.620710259 0 1 111.8410709DELTA_SDD 47 PPM 3 -10.27868808 2.772041432 0 1 9.834690559 0.641112576 0 1 56.05903276DELTA_SDD 47 PPM 3 0.362613829 2.742075415 0 1 9.068258833 0.683623499 0 1 71.75914449DELTA_SDD 47 PPM 3 0.969379344 1.599795868 0 1 0.915632131 0.76110375 0 1 334.7318683DELTA_SDD 47 PPM 3 -2.670824176 1.631668054 0 1 2.275383763 0.749723415 0 1 308.507434DELTA_SDD 47 PPM 3 0.946649514 1.564403716 0 1 2.814895734 0.788360252 0 1 343.3534873396Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFModel Tube Anode Unit LOD Sigma Ag Ag +/- Ag Intercept Ag Slope As As +/- As Intercept As Slope BaD.7 fp-XRF Soil ModeDELTA_SDD 47 PPM 3 1.083223818 1.616150886 0 1 1.847539237 0.798185507 0 1 348.6834436DELTA_SDD 47 PPM 3 -1.473144152 1.428401106 0 1 6.601876842 0.84082125 0 1 306.3635747DELTA_SDD 47 PPM 3 -0.705191043 1.475117758 0 1 3.103421743 0.801246304 0 1 302.3632494DELTA_SDD 47 PPM 3 1.211811574 1.601195286 0 1 1.278068401 0.783398307 0 1 308.9905386DELTA_SDD 47 PPM 3 -7.754893918 2.8279039 0 1 5.800428171 0.601139883 0 1 63.51906171DELTA_SDD 47 PPM 3 -2.699779779 2.967458581 0 1 6.652431694 0.590016145 0 1 34.04056173DELTA_SDD 47 PPM 3 -1.24502734 1.613275968 0 1 1.207870014 0.737275441 0 1 337.109796DELTA_SDD 47 PPM 3 0.811267913 1.53367388 0 1 1.926018332 0.758889218 0 1 315.369184DELTA_SDD 47 PPM 3 -4.129486022 2.66240008 0 1 5.362140192 0.613049352 0 1 54.65616618DELTA_SDD 47 PPM 3 5.168708083 1.610726518 0 1 2.196367194 0.777946791 0 1 258.4971348DELTA_SDD 47 PPM 3 1.569285085 1.503152325 0 1 5.482942318 0.817660791 0 1 320.964939DELTA_SDD 47 PPM 3 4.933653039 2.04171907 0 1 8.999972511 1.231032592 0 1 111.5168362DELTA_SDD 47 PPM 3 -1.879486119 1.46787944 0 1 4.643871668 0.812491639 0 1 307.1519775DELTA_SDD 47 PPM 3 -4.490755615 1.584696088 0 1 15.17516881 1.035174084 0 1 337.2856832DELTA_SDD 47 PPM 3 -1.478762567 1.561954759 0 1 6.955642581 0.847618175 0 1 334.848683DELTA_SDD 47 PPM 3 -0.219814469 1.591062382 0 1 5.280077708 0.865335622 0 1 324.9121454DELTA_SDD 47 PPM 3 -1.093505522 1.572790875 0 1 8.795558559 0.884313312 0 1 319.011371DELTA_SDD 47 PPM 3 -1.807347726 1.596697634 0 1 4.965857029 0.854747797 0 1 337.0579513DELTA_SDD 47 PPM 3 2.875211737 1.572217496 0 1 6.366153563 0.850269696 0 1 330.2921263DELTA_SDD 47 PPM 3 -1.696853261 1.512825522 0 1 2.826021869 0.791532122 0 1 281.2965283DELTA_SDD 47 PPM 3 -3.654109614 2.773615836 0 1 3.506460066 0.542004084 0 1 27.44334407DELTA_SDD 47 PPM 3 -0.730208075 1.65405852 0 1 4.39072595 0.836041608 0 1 363.2146941DELTA_SDD 47 PPM 3 -3.520129917 1.567925763 0 1 2.978360703 0.807087727 0 1 370.9721934DELTA_SDD 47 PPM 3 0.37905973 1.546674965 0 1 3.995593944 0.838665085 0 1 315.4663923DELTA_SDD 47 PPM 3 -0.400839648 1.509018455 0 1 1.825120505 0.77678059 0 1 309.7382869DELTA_SDD 47 PPM 3 -0.790400246 1.506847628 0 1 1.564411426 0.769388735 0 1 316.1261197DELTA_SDD 47 PPM 3 -0.477084168 1.492998136 0 1 0.103771161 0.741041846 0 1 308.5949327DELTA_SDD 47 PPM NA397Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFBa +/- Ba Intercept Ba Slope Bi Bi +/- Bi Intercept Bi Slope Ca Ca +/- Ca Intercept Ca Slope Cd Cd +/-13.85012207 -13 1.1904 0.248464332 2.985540189 0 1 10056.05544 88.04857924 3121 0.9611 -0.542769375 1.83133832714.18054281 -13 1.1904 0.522002806 3.028304714 0 1 9786.995747 88.25366698 3121 0.9611 -0.065210489 1.90540671714.83562688 -13 1.1904 -2.441921608 3.335590291 0 1 10161.47835 106.7523091 3121 0.9611 1.228209688 1.93255893417.58040832 -13 1.1904 -21.63193653 2.608514236 0 1 3397.783203 38.12090829 3121 0.9611 0.553493321 3.32012565114.74128446 -13 1.1904 1.366801738 2.940060243 0 1 9538.538278 85.00108292 3121 0.9611 0.384499813 2.07692754114.33103325 -13 1.1904 -5.776718726 3.065307124 0 1 10267.83673 90.73421721 3121 0.9611 0.133331279 1.90985266514.03946851 -13 1.1904 -3.405315452 3.064119239 0 1 10436.5929 91.53415565 3121 0.9611 -2.119138314 1.81004652114.19972254 -13 1.1904 1.839121735 3.059829641 0 1 10655.67637 92.82410354 3121 0.9611 0.612578059 1.83097966314.09304983 -13 1.1904 -4.559607382 3.086348355 0 1 10474.6905 92.55962052 3121 0.9611 -3.222700839 1.85257928114.56432758 -13 1.1904 -3.49651302 3.066243752 0 1 10075.82837 89.41085887 3121 0.9611 -0.789744139 1.94149315714.43362452 -13 1.1904 -6.058314515 3.088097535 0 1 10218.53864 92.07397374 3121 0.9611 -4.284969417 1.91642198913.99073588 -13 1.1904 0.160259974 3.077744966 0 1 10299.48344 90.45115812 3121 0.9611 1.776181427 1.82638681614.60645544 -13 1.1904 -0.748453642 3.031189024 0 1 10080.59352 90.06621262 3121 0.9611 0.164468031 1.94633002916.90865932 -13 1.1904 5.763891587 3.665478702 0 1 58.77587827 54.10885472 3121 0.9611 -2.857122486 2.62430960114.45733392 -13 1.1904 -6.284660007 3.074079502 0 1 10067.1284 89.95635797 3121 0.9611 -0.061372374 1.94336088214.34451589 -13 1.1904 -6.318697871 3.095969214 0 1 10533.53101 92.55048981 3121 0.9611 0.676110427 1.89137381314.3104119 -13 1.1904 -1.945412419 3.00686644 0 1 10396.21845 91.03811906 3121 0.9611 0.378656342 1.92205223714.169255 -13 1.1904 -0.052101079 3.077030615 0 1 10504.14463 92.33299897 3121 0.9611 -0.819636028 1.87925660914.16146879 -13 1.1904 -1.770730209 3.036203552 0 1 10300.12228 90.48133554 3121 0.9611 -0.508315608 1.88397977214.36615534 -13 1.1904 -0.927744132 3.060237567 0 1 9994.69946 89.83055104 3121 0.9611 0.329479693 1.91089414714.28990591 -13 1.1904 1.044979707 3.063793312 0 1 9747.686493 89.40867263 3121 0.9611 -4.237839136 1.89130281515.57917058 -13 1.1904 -3.70197859 3.187608567 0 1 6447.25678 82.73999584 3121 0.9611 1.187302372 2.21573768913.88361504 -13 1.1904 -6.972642702 3.009731439 0 1 9639.648002 84.90255772 3121 0.9611 -2.241838045 1.93961812314.48866074 -13 1.1904 -5.927584943 3.145926237 0 1 10711.64176 93.59341759 3121 0.9611 -3.605952803 1.92289966414.2500084 -13 1.1904 1.162083451 3.137562316 0 1 10663.49812 95.05968859 3121 0.9611 -3.001362211 1.89945793614.71519102 -13 1.1904 6.266269378 2.935223896 0 1 9620.604505 87.8066993 3121 0.9611 -1.883390988 2.03836100114.36853492 -13 1.1904 -4.622056489 3.094240659 0 1 9983.456811 90.35598649 3121 0.9611 -0.546614222 1.96584040314.40394157 -13 1.1904 -2.525511089 3.03479329 0 1 9739.732861 87.38965933 3121 0.9611 -4.794166759 1.9199397414.58327328 -13 1.1904 -1.162534586 3.037692347 0 1 9952.937742 90.56866076 3121 0.9611 -2.439438651 2.01497620214.103237 -13 1.1904 -3.655887655 3.007667245 0 1 9559.756111 85.31087463 3121 0.9611 -0.907101275 1.93086518715.22815622 -13 1.1904 -2.583736467 3.112396914 0 1 9753.073026 91.63945376 3121 0.9611 -2.516565019 2.0517841417.58125404 -13 1.1904 -6.454813629 2.721183904 0 1 5597.724316 54.05954074 3121 0.9611 1.552199515 3.00035217713.71707278 -13 1.1904 -9.504501003 2.917622276 0 1 9798.213433 84.52897879 3121 0.9611 -2.905960397 1.91925915620.53987641 -13 1.1904 -31.29843971 2.762823585 0 1 3076.903241 32.97957424 3121 0.9611 5.642411492 3.87817528119.44901931 -13 1.1904 -35.95996329 2.683913853 0 1 2602.065255 29.32764331 3121 0.9611 5.512611066 3.8130196416.60191584 -13 1.1904 7.285929316 3.694755697 0 1 119.4903421 54.60067917 3121 0.9611 -3.004631995 2.55990362319.69969925 -13 1.1904 -36.48513844 2.704675018 0 1 2686.05296 29.85844711 3121 0.9611 5.545182282 3.76272487817.97036388 -13 1.1904 -23.67466873 2.643425138 0 1 3320.203896 37.79822871 3121 0.9611 0.758084127 3.322683384D.7 fp-XRF Soil Mode398Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFBa +/- Ba Intercept Ba Slope Bi Bi +/- Bi Intercept Bi Slope Ca Ca +/- Ca Intercept Ca Slope Cd Cd +/-D.7 fp-XRF Soil Mode15.03709044 -13 1.1904 -4.214006084 2.941855376 0 1 9369.448971 83.03431071 3121 0.9611 -0.508565413 2.07359550215.0254488 -13 1.1904 -8.204985798 3.107133111 0 1 10736.15109 94.29373536 3121 0.9611 -1.915566479 2.09339666115.03398464 -13 1.1904 1.848360053 2.983457634 0 1 9047.959105 82.56491564 3121 0.9611 -0.351269386 2.10798975614.35932553 -13 1.1904 -5.101558516 3.042472831 0 1 10286.78128 91.04603278 3121 0.9611 -1.456063282 1.9519511615.41985053 -13 1.1904 -3.623597069 3.022225704 0 1 9627.14235 86.82557584 3121 0.9611 1.111111785 2.19035257214.35581148 -13 1.1904 -5.142034813 3.064079004 0 1 9887.979022 88.81367522 3121 0.9611 0.126075901 1.91398328414.21766306 -13 1.1904 -4.660676731 3.039542044 0 1 10359.14257 91.02378823 3121 0.9611 -1.76541203 1.88258138314.65029872 -13 1.1904 -1.69207784 3.070135658 0 1 9467.325446 88.27617696 3121 0.9611 2.221820118 1.98917351714.24954814 -13 1.1904 -3.082574185 3.033291907 0 1 9161.994758 85.63600751 3121 0.9611 -1.339448176 1.95646060214.78508592 -13 1.1904 -1.480107236 3.046368615 0 1 9566.661561 87.81001422 3121 0.9611 -2.543024838 1.99704844614.800332 -13 1.1904 -6.259659156 3.06169326 0 1 9895.962739 89.04230602 3121 0.9611 -2.079342136 2.03148497314.83945936 -13 1.1904 -3.36540015 3.089926548 0 1 10094.91497 91.95887938 3121 0.9611 -1.87071249 1.98737139514.4537791 -13 1.1904 -4.53265672 3.083015686 0 1 9910.548284 89.03603713 3121 0.9611 2.527909153 1.97090739813.90168534 -13 1.1904 -3.462744833 3.074024307 0 1 10467.11608 92.27340078 3121 0.9611 2.511402501 1.85055456715.07344938 -13 1.1904 -0.699963215 3.088592552 0 1 9896.526627 90.81519513 3121 0.9611 1.218923496 2.08348816814.64610772 -13 1.1904 -3.533018094 3.146340225 0 1 10611.83351 94.03212943 3121 0.9611 -2.477081825 2.01663392315.27329867 -13 1.1904 -2.604246069 3.145802702 0 1 10731.86609 96.36044125 3121 0.9611 -0.632028553 2.10082616814.98346795 -13 1.1904 0.867519737 3.021047841 0 1 9250.264813 86.22166615 3121 0.9611 2.647997547 2.09839410314.4230551 -13 1.1904 -4.252655584 2.98974378 0 1 8808.597971 82.45012707 3121 0.9611 -2.668364656 1.95449288216.11038081 -13 1.1904 6.657768412 3.684948481 0 1 23.33468707 54.49024139 3121 0.9611 -0.285013981 2.52902957614.57054393 -13 1.1904 1.768837284 2.939602871 0 1 8781.970903 82.4133383 3121 0.9611 -0.40712669 1.97428964615.24069845 -13 1.1904 0.67253648 3.070906709 0 1 10214.48212 92.74270761 3121 0.9611 -2.399145761 2.05437242815.02848696 -13 1.1904 -0.623464005 3.075657285 0 1 9891.506891 91.07559231 3121 0.9611 -1.337783962 2.07560946914.7176747 -13 1.1904 -3.313000656 3.040074919 0 1 9655.579553 88.57145639 3121 0.9611 -3.35536689 2.05115745215.12368445 -13 1.1904 -3.539776204 3.060669682 0 1 9619.92236 88.62226005 3121 0.9611 0.020910458 2.09264044815.65560976 -13 1.1904 -3.631382185 3.107475767 0 1 9071.518411 85.43444657 3121 0.9611 2.97655114 2.17775874615.62930263 -13 1.1904 -1.415475663 3.088250769 0 1 10104.64987 90.62111942 3121 0.9611 -2.743996623 2.27376886314.81378919 -13 1.1904 -5.62672331 3.08677856 0 1 10052.18806 90.58545789 3121 0.9611 -2.802140185 2.03196501315.08019384 -13 1.1904 0.131401825 3.071476421 0 1 9973.47887 90.70794071 3121 0.9611 -0.988599748 2.09630461714.99537256 -13 1.1904 -0.134141003 3.032716755 0 1 10708.15887 93.85514476 3121 0.9611 -4.196030542 2.08591114.86403177 -13 1.1904 1.078696462 3.068774261 0 1 10582.33433 93.63107617 3121 0.9611 -2.036016514 2.04472944814.53654811 -13 1.1904 -4.370638902 3.089238833 0 1 10959.52116 95.94057393 3121 0.9611 0.402619576 1.98062998415.40250501 -13 1.1904 -7.527329308 3.085805344 0 1 10412.90053 91.64795689 3121 0.9611 0.614498724 2.17849233314.75370024 -13 1.1904 -4.669360744 3.024332751 0 1 10473.01462 91.62266335 3121 0.9611 -0.546861866 2.04131077914.94783084 -13 1.1904 -1.196027413 3.007516757 0 1 10085.8649 90.18292623 3121 0.9611 -1.724117776 2.14977592114.56056217 -13 1.1904 -3.288830534 3.056835567 0 1 10463.88947 93.27266346 3121 0.9611 -4.272360552 1.96652912514.48064844 -13 1.1904 -3.578463442 3.075839131 0 1 10392.24394 91.8635668 3121 0.9611 -0.767415379 1.965568641399Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFBa +/- Ba Intercept Ba Slope Bi Bi +/- Bi Intercept Bi Slope Ca Ca +/- Ca Intercept Ca Slope Cd Cd +/-D.7 fp-XRF Soil Mode15.00620509 -13 1.1904 -3.278082157 3.078959611 0 1 10221.3303 91.19172183 3121 0.9611 -2.294745614 2.08553797114.43986194 -13 1.1904 -1.968998621 3.002730687 0 1 9610.33435 88.26862822 3121 0.9611 0.683486701 1.95448334914.45043166 -13 1.1904 -1.408512087 3.104095198 0 1 10601.13167 94.88657419 3121 0.9611 3.368573715 1.94976788914.50319655 -13 1.1904 -0.582009327 3.067949634 0 1 9206.401582 86.77207507 3121 0.9611 1.733811351 1.91197444716.77684816 -13 1.1904 7.13871053 3.687720047 0 1 203.5380688 54.80936779 3121 0.9611 3.00244611 2.55605988614.41989438 -13 1.1904 -4.243709463 3.044518464 0 1 9277.614461 87.16047796 3121 0.9611 -4.382221089 1.91473340614.69023913 -13 1.1904 -2.649490463 3.110415038 0 1 10193.83185 91.98108063 3121 0.9611 2.722797441 1.96416771114.27883454 -13 1.1904 1.157417869 2.922971282 0 1 9559.016023 87.25966752 3121 0.9611 -1.538243433 1.94287259813.77821698 -13 1.1904 -1.826846259 3.001930745 0 1 9820.705496 86.74224155 3121 0.9611 -0.382213969 1.88244956114.10705611 -13 1.1904 -4.820491534 2.930305249 0 1 9011.631537 81.01758595 3121 0.9611 -5.747166372 1.96795524414.70814411 -13 1.1904 0.944949063 2.881581479 0 1 8927.999444 79.47756555 3121 0.9611 3.125953299 2.07927377714.63080643 -13 1.1904 -1.212736531 3.05734983 0 1 10193.64618 91.21114031 3121 0.9611 -2.66698825 2.0654511514.63345735 -13 1.1904 -0.179043552 3.027917009 0 1 10540.46474 92.55912879 3121 0.9611 -1.430123844 2.01829583114.21721877 -13 1.1904 1.477378142 2.956964976 0 1 10067.19616 89.53929151 3121 0.9611 0.415288904 1.91646972314.9030581 -13 1.1904 -5.448414816 3.176534189 0 1 10262.05787 92.32927586 3121 0.9611 -0.869137844 2.01448065615.1523769 -13 1.1904 -4.011732534 3.077312763 0 1 10286.99745 92.22267851 3121 0.9611 -0.564889709 2.12351870515.26521906 -13 1.1904 -3.571722217 3.006638004 0 1 9613.36295 86.8980009 3121 0.9611 0.820620611 2.14034103813.83473893 -13 1.1904 -0.875158502 2.896346758 0 1 8588.447 78.00825098 3121 0.9611 -2.807425068 1.85195270414.00699529 -13 1.1904 -1.702662726 2.875264245 0 1 9275.842113 81.94430928 3121 0.9611 -4.443520129 1.9744969716.44715641 -13 1.1904 -9.90870897 2.778620612 0 1 6126.703849 59.25414347 3121 0.9611 4.391404607 2.68286853315.09853763 -13 1.1904 -1.993779362 2.936409069 0 1 8821.124066 80.16285939 3121 0.9611 3.171278477 2.16643715314.96193104 -13 1.1904 0.815621876 2.940447498 0 1 8649.066001 79.74768967 3121 0.9611 -1.638409467 2.13962190319.88677467 -13 1.1904 -34.53348669 2.721753256 0 1 2653.063158 30.32690085 3121 0.9611 4.525806349 3.80715992118.50148151 -13 1.1904 -31.63526423 2.630984106 0 1 3590.643336 35.62963636 3121 0.9611 5.701925822 3.45511655914.44501209 -13 1.1904 5.283438836 3.003105774 0 1 10353.87182 91.11001034 3121 0.9611 0.308688976 1.98840472214.53518558 -13 1.1904 -5.009428195 3.014153798 0 1 10349.78292 90.80449114 3121 0.9611 -1.629500314 1.95821586316.58651632 -13 1.1904 11.2307405 3.667869977 0 1 21.42187591 54.66033003 3121 0.9611 2.158812196 2.50200724114.5571908 -13 1.1904 -0.272519845 3.003173758 0 1 10290.86809 89.6543988 3121 0.9611 -4.451983885 2.01106546814.23232363 -13 1.1904 3.371371249 2.972871374 0 1 9919.748875 87.97453732 3121 0.9611 -3.637042331 1.97506296315.51177281 -13 1.1904 2.939294221 3.000569215 0 1 9585.169455 87.16198521 3121 0.9611 -3.889290091 2.22763479319.20859114 -13 1.1904 -17.55849665 2.920177201 0 1 3970.235995 47.27167993 3121 0.9611 1.915251464 3.31485659718.06172116 -13 1.1904 -21.69318248 2.586073488 0 1 4211.442783 42.15260061 3121 0.9611 3.435937565 3.32608776319.08040591 -13 1.1904 -31.51142397 2.716835943 0 1 3298.149939 35.57956074 3121 0.9611 4.059790834 3.59934434619.11483632 -13 1.1904 -20.10299512 2.700219333 0 1 4461.923396 45.82303639 3121 0.9611 8.475118502 3.59884675514.65330847 -13 1.1904 -1.502298278 2.98353017 0 1 10038.54868 88.07408604 3121 0.9611 -1.556786058 2.01334808614.78117289 -13 1.1904 -4.136280234 2.946342114 0 1 9110.335751 81.36445637 3121 0.9611 3.144394711 2.10605417114.59678434 -13 1.1904 -0.739709707 3.002055217 0 1 9910.230928 88.66771716 3121 0.9611 1.29194718 1.99214726400Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFBa +/- Ba Intercept Ba Slope Bi Bi +/- Bi Intercept Bi Slope Ca Ca +/- Ca Intercept Ca Slope Cd Cd +/-D.7 fp-XRF Soil Mode14.95520574 -13 1.1904 -5.530873545 3.072091998 0 1 9513.591708 85.91937966 3121 0.9611 -3.729649391 2.02051210813.74383189 -13 1.1904 -3.700478 3.0129434 0 1 10483.79348 90.80516333 3121 0.9611 0.768824643 1.86132858113.86565172 -13 1.1904 -0.855000368 2.943175122 0 1 10006.1191 86.79490099 3121 0.9611 -1.128144078 1.89214026914.67421214 -13 1.1904 -6.005701823 2.996218108 0 1 9707.821846 85.28111004 3121 0.9611 2.439673192 2.0022662419.13663509 -13 1.1904 -29.32649622 2.765262627 0 1 3006.413612 33.54917259 3121 0.9611 1.591441169 3.61696889620.39162884 -13 1.1904 -30.67788765 2.749842069 0 1 2372.263333 29.03050567 3121 0.9611 2.735291959 3.80884574914.84699942 -13 1.1904 -0.329450847 2.953614136 0 1 8921.616502 81.23762769 3121 0.9611 -0.231917431 2.05555090414.18840772 -13 1.1904 -5.118088438 2.975096411 0 1 9245.855095 83.04373228 3121 0.9611 1.788220183 1.94881088718.0998915 -13 1.1904 -23.72214121 2.671360485 0 1 2924.180782 32.78265632 3121 0.9611 4.414462229 3.45294722714.59105589 -13 1.1904 -5.923191436 2.992905837 0 1 8943.936926 81.24876279 3121 0.9611 3.094599025 2.1011301713.96326891 -13 1.1904 -2.12019907 2.970952705 0 1 9732.316003 85.9217881 3121 0.9611 -0.915416802 1.88018896916.72518858 -13 1.1904 11.08613333 3.653098229 0 1 11.44502424 53.79249868 3121 0.9611 0.795015795 2.59728307913.82842608 -13 1.1904 3.480789149 2.926433172 0 1 9594.443102 84.83638022 3121 0.9611 -0.268758999 1.85638527215.40636399 -13 1.1904 -11.66019055 3.277687028 0 1 12324.21213 110.7652182 3121 0.9611 -0.103901034 2.05414220814.42937733 -13 1.1904 -3.41373087 3.114293313 0 1 10561.29539 92.98938871 3121 0.9611 -1.559783937 1.94713141215.04307869 -13 1.1904 -0.776865871 3.033647942 0 1 10458.69848 92.12184998 3121 0.9611 3.326688175 2.08177257414.7076238 -13 1.1904 -0.129994968 3.013297316 0 1 10041.54763 89.58188269 3121 0.9611 1.31977956 2.03245685714.92506183 -13 1.1904 -1.841933767 3.061254024 0 1 9989.363289 90.03589748 3121 0.9611 -1.82351968 2.04791112914.65711523 -13 1.1904 -6.074224947 3.077143456 0 1 10198.3941 91.55952464 3121 0.9611 -0.977154604 2.00989629314.16507046 -13 1.1904 -3.139784121 3.018662076 0 1 9515.958155 85.49092401 3121 0.9611 -2.993914528 1.95183400919.11314362 -13 1.1904 -25.83761678 2.717279636 0 1 2051.514131 26.46871162 3121 0.9611 1.854214233 3.60694799415.31553774 -13 1.1904 -2.083333749 3.087562758 0 1 9166.429755 87.54336955 3121 0.9611 -0.368204116 2.07576166714.89484788 -13 1.1904 -0.06568339 3.12069389 0 1 9893.352765 90.59233826 3121 0.9611 -2.080519618 2.01488260714.81879454 -13 1.1904 -3.348897908 3.108027847 0 1 10137.76115 91.45503831 3121 0.9611 -0.867197426 1.97932126614.19986783 -13 1.1904 5.266376868 2.942633063 0 1 10144.95973 88.47625 3121 0.9611 -0.305473246 1.91149056413.95810486 -13 1.1904 -6.857765451 2.991673128 0 1 9829.809216 85.55068521 3121 0.9611 -0.404116938 1.90848094714.1370918 -13 1.1904 -4.325399348 2.916937798 0 1 9060.819714 80.90674026 3121 0.9611 0.247059891 1.943547767401Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCd Intercept Cd Slope Ce Ce +/- Ce Intercept Ce Slope Cl Cl +/- Cl Intercept Cl Slope Co Co +/- Co Intercept0 1 57.3154366 23.93044148 0 1 -23.17870769 38.74587628 0 1 -31.52314417 13.23407549 00 1 62.9114301 24.36146985 0 1 -87.3841296 38.61829597 0 1 -28.34659098 13.88006925 00 1 39.68626227 25.70007111 0 1 -72.10881203 60.47425084 0 1 -339.4062884 31.32369446 00 1 53.29412143 32.02983104 0 1 88.40643733 30.12059412 0 1 -89.73294399 14.87955828 00 1 60.61530277 25.07765116 0 1 9.880296881 39.84256336 0 1 -54.64224612 12.32302117 00 1 96.93074624 24.08059072 0 1 -25.08326699 39.86535498 0 1 -44.10564343 12.60251915 00 1 41.0265559 23.9031115 0 1 -5.056631597 40.82520974 0 1 -60.70697563 14.13822715 00 1 79.74263783 23.95157005 0 1 -40.2896595 40.86339875 0 1 -36.96049132 14.92119996 00 1 74.03135184 24.12967491 0 1 -79.34645457 40.11647265 0 1 -45.45627782 14.42048038 00 1 35.4402721 24.59129951 0 1 -39.22256852 40.37993789 0 1 -75.82826109 14.01223633 00 1 60.39147598 24.36282349 0 1 -84.30486169 41.14290941 0 1 -43.54888689 14.7809317 00 1 31.07767189 23.65639821 0 1 -65.7484483 40.29619557 0 1 -39.4476549 15.12161885 00 1 57.85421742 24.82513495 0 1 -50.40780491 40.14360536 0 1 -58.36530246 14.14361042 00 1 20.73018548 30.65555208 0 1 -84.85358973 91.0704385 0 1 -371.0497956 44.83338608 00 1 12.92001188 24.42198188 0 1 -149.128539 37.48963859 0 1 -64.20707829 14.159567 00 1 -1.080248614 24.23042868 0 1 -100.8413651 39.41622251 0 1 -54.57434533 14.5202592 00 1 61.10867202 24.19515494 0 1 -15.7615262 40.86184937 0 1 -27.78694774 14.42849532 00 1 46.40076319 23.75116437 0 1 17.9721805 42.92801802 0 1 -83.22393403 14.9881606 00 1 59.59581192 24.16987246 0 1 143.9535279 43.85147243 0 1 -42.65807575 12.87069034 00 1 59.75727739 24.35655385 0 1 -42.80010305 40.66592901 0 1 -45.33082077 14.19798412 00 1 24.05283873 24.28197622 0 1 -47.85212238 42.09151036 0 1 -78.41300198 15.38337911 00 1 43.28369846 27.12261062 0 1 -119.038758 58.43911452 0 1 -472.2273014 32.10681947 00 1 23.25879091 23.73390201 0 1 -27.26022085 38.38175832 0 1 -59.97261367 13.17299504 00 1 7.809952002 24.47314339 0 1 4.027660085 42.49315635 0 1 -51.1427105 14.91108717 00 1 70.21436396 24.35182024 0 1 -20.92183651 43.64479526 0 1 -52.91239316 15.88888399 00 1 55.24571379 25.02238151 0 1 -16.59718629 41.62600335 0 1 -73.21429451 14.88736113 00 1 45.2024754 24.42866335 0 1 19.06035998 43.29938256 0 1 -79.3848997 15.0181016 00 1 37.00230521 24.31760497 0 1 -53.15122291 39.55134125 0 1 -57.60839639 13.99323316 00 1 52.07151891 24.71919278 0 1 6.195241379 43.06935568 0 1 -61.58669658 14.94054678 00 1 55.00813927 24.14621642 0 1 -66.14476225 37.67737495 0 1 -47.2463533 12.46111384 00 1 78.06302052 25.51916432 0 1 -63.50780705 44.03360932 0 1 -78.37225837 16.75696181 00 1 -0.559261889 31.07882148 0 1 166.3363092 34.78691382 0 1 -20.32222853 9.057969969 00 1 19.00284089 23.61511199 0 1 3.128038293 36.70472334 0 1 -54.43344258 10.50954715 00 1 45.60467032 37.55174786 0 1 194.8489799 27.42606354 0 1 -72.33354799 8.44358009 00 1 48.48461636 35.66069197 0 1 195.989249 25.80263133 0 1 -68.77857913 8.420382256 00 1 39.60034563 30.31539268 0 1 -228.1780672 89.28230208 0 1 -435.2523909 44.96987355 00 1 2.959697739 35.72756757 0 1 194.8910036 25.87448961 0 1 -58.43770171 8.51138749 00 1 44.0042672 32.8630929 0 1 137.6765035 29.95021317 0 1 -78.47856307 11.73514042 0D.7 fp-XRF Soil Mode402Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCd Intercept Cd Slope Ce Ce +/- Ce Intercept Ce Slope Cl Cl +/- Cl Intercept Cl Slope Co Co +/- Co InterceptD.7 fp-XRF Soil Mode0 1 37.68953755 25.43554661 0 1 -14.5544514 37.42204266 0 1 -29.11526205 11.4692605 00 1 68.83683016 25.27456572 0 1 -59.05853795 40.5120814 0 1 -62.87743715 13.01080915 00 1 77.48798129 25.61823715 0 1 -4.356555192 39.85711378 0 1 -59.84066177 13.05240823 00 1 58.66826813 24.45355569 0 1 -91.66183804 39.25582222 0 1 -67.50957917 14.43235979 00 1 25.67263386 26.30585089 0 1 30.64659991 41.3632474 0 1 -56.65397259 13.87089849 00 1 5.591637372 24.41199751 0 1 45.62398633 42.35731118 0 1 -58.75054829 14.42539582 00 1 55.15539567 24.47278681 0 1 28.7780548 42.06646643 0 1 -58.97317874 13.82455373 00 1 61.38003205 24.73933219 0 1 15.41495924 44.13473588 0 1 -81.3606802 15.14007314 00 1 24.43749255 24.46436101 0 1 -39.84217536 41.90396026 0 1 -57.26339147 15.92251771 00 1 9.233407682 24.79050668 0 1 12.29447344 42.21169942 0 1 -63.66903035 14.23102507 00 1 97.98931762 25.22922914 0 1 -95.91696958 38.91424422 0 1 -57.58325886 14.2784255 00 1 60.39719205 25.00292142 0 1 -22.18309983 43.33713226 0 1 -84.1347082 15.19476 00 1 84.40727239 24.62128647 0 1 -44.08630525 41.09622085 0 1 -47.38170574 14.81697887 00 1 67.29033734 23.6183316 0 1 15.99966539 42.39222282 0 1 -60.59787701 14.16187493 00 1 52.25707063 25.55412969 0 1 -0.425360752 43.58668213 0 1 -63.67398519 15.56238305 00 1 51.91574522 24.934186 0 1 -42.77625933 41.60547213 0 1 -28.92979225 14.56067232 00 1 64.45535134 25.85006309 0 1 17.36698757 45.26175668 0 1 -61.16201002 15.55203881 00 1 52.9641884 25.37032091 0 1 17.67962924 42.37699434 0 1 -38.08041765 14.2450748 00 1 9.44384561 24.59937976 0 1 53.76732957 41.1804744 0 1 -44.67025819 13.23534027 00 1 20.0462958 29.75675964 0 1 -302.8260165 88.9 0 1 -266.4246639 45.10117736 00 1 11.27945914 24.95205886 0 1 8.795658378 40.1132784 0 1 -15.08453704 13.32435766 00 1 104.1513504 25.53876573 0 1 -6.019289179 44.13398371 0 1 -70.75387069 16.14445413 00 1 25.22557675 25.48381763 0 1 -58.84586372 43.37209145 0 1 -89.0490388 16.63028919 00 1 21.27305649 25.30666342 0 1 42.21398008 43.13259257 0 1 -81.36426177 14.69299496 00 1 12.96629147 25.56814911 0 1 -77.88626943 41.26367566 0 1 -40.78921 16.12057637 00 1 104.3042047 26.36382534 0 1 26.40870402 43.34619344 0 1 -60.83436744 14.65082059 00 1 28.27756074 26.56058073 0 1 43.90986212 43.15331913 0 1 -50.59476468 14.37236017 00 1 66.40415885 25.10515173 0 1 6.106145585 42.65003119 0 1 -56.75522628 14.86535273 00 1 32.90172088 25.74739783 0 1 -7.125560396 41.93845122 0 1 -48.14013302 14.48370804 00 1 43.33595205 25.42938386 0 1 -65.22330167 40.58815428 0 1 -69.3116695 14.44400354 00 1 10.98573894 25.38498019 0 1 33.41477153 42.47893471 0 1 -26.4423282 13.6964187 00 1 52.88853424 24.6482507 0 1 -36.62535464 41.28229551 0 1 -44.8746821 14.11859283 00 1 48.35622751 26.16905152 0 1 63.23884876 42.89501099 0 1 -59.08260996 13.81259207 00 1 -20.36958306 24.97167811 0 1 -12.20624431 40.81835948 0 1 -45.44780146 14.03987193 00 1 12.33020691 25.42349459 0 1 43.83326522 42.53983506 0 1 -35.36591752 14.3444011 00 1 69.65122344 24.6797372 0 1 -112.1597649 39.57059588 0 1 -46.8650474 13.91116775 00 1 71.43473061 24.59615369 0 1 64.40433936 43.06525965 0 1 -49.2200276 14.25625635 0403Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCd Intercept Cd Slope Ce Ce +/- Ce Intercept Ce Slope Cl Cl +/- Cl Intercept Cl Slope Co Co +/- Co InterceptD.7 fp-XRF Soil Mode0 1 2.186139023 25.5345379 0 1 3.257663526 41.78256537 0 1 -70.44924921 13.92725613 00 1 39.61517447 24.74429208 0 1 1.403415707 42.12800767 0 1 -55.00983382 14.88171143 00 1 51.90842341 24.54051277 0 1 35.07574301 44.71730933 0 1 -39.09683926 15.37480356 00 1 13.36766902 24.52444303 0 1 -82.76655577 41.31496743 0 1 -54.73585277 16.33802998 00 1 -1.845053659 30.64181573 0 1 -82.43518676 91.29584372 0 1 -322.3529881 45.07684411 00 1 31.71787291 24.54204078 0 1 43.61843751 44.37624605 0 1 -63.60604988 16.0317908 00 1 37.49746292 24.79789672 0 1 -1.422597511 43.38674443 0 1 -66.02541974 15.67001445 00 1 49.41972269 24.48092612 0 1 15.96945812 41.44179107 0 1 -22.6771351 14.14180265 00 1 34.55144824 23.68335283 0 1 -9.687160837 38.84842981 0 1 -52.2699388 12.79900845 00 1 69.01739111 24.44291355 0 1 -22.1587759 36.78512626 0 1 -32.70788911 10.57569226 00 1 69.47174925 24.9180643 0 1 33.84828108 38.31452663 0 1 -49.26677783 11.06264102 00 1 34.52396961 25.07671758 0 1 100.5403479 44.29319862 0 1 -44.01451527 13.76365525 00 1 38.67034235 24.97528441 0 1 -87.88845533 39.4860556 0 1 -64.22999234 14.15998381 00 1 -1.410025735 24.21794066 0 1 -35.04954441 40.03025033 0 1 -71.46643035 13.82405316 00 1 43.22473312 24.92316843 0 1 -8.941161727 43.18250621 0 1 -78.09520745 15.13108266 00 1 60.85168282 25.47601397 0 1 -63.23542746 41.19598998 0 1 -7.663720862 15.26715913 00 1 61.40377433 25.78625223 0 1 16.43293339 41.8315341 0 1 -35.1705796 14.15916489 00 1 -5.102262816 23.51250916 0 1 -39.20896396 34.71110208 0 1 -23.25429813 9.489290248 00 1 -4.90752543 24.03058721 0 1 8.426905041 36.65041771 0 1 -27.3988577 10.55298176 00 1 24.93583368 28.66424918 0 1 51.75218915 32.43735364 0 1 -10.99797261 7.267360358 00 1 29.23338822 25.50896719 0 1 -14.15012744 38.50448505 0 1 -48.46739691 12.42661934 00 1 44.48940546 25.53775645 0 1 -30.70715533 37.95510707 0 1 -28.88067425 12.00180152 00 1 50.63422224 36.43830592 0 1 251.0165581 27.80499291 0 1 -19.53286929 6.801674443 00 1 29.49897214 33.53360388 0 1 123.1267976 26.30767576 0 1 -61.74616103 9.37876861 00 1 12.40488824 24.56007409 0 1 19.09380353 41.89187632 0 1 -26.99132889 13.79511188 00 1 22.76582817 24.92289424 0 1 -31.65962453 39.75997768 0 1 -48.37909468 13.24941521 00 1 23.50910608 30.27987506 0 1 -73.50163483 93.18330397 0 1 -361.4745846 45.00619783 00 1 11.80094891 24.77609603 0 1 35.18791257 40.62604882 0 1 -52.77277067 13.20476806 00 1 24.24583814 24.5260919 0 1 2.415312885 40.50367621 0 1 -53.96717496 14.18050407 00 1 6.448748612 26.06398425 0 1 -76.44383819 39.43041521 0 1 -31.88448222 13.65251729 00 1 34.30728696 33.61914136 0 1 37.26543089 34.45824852 0 1 -76.4829686 13.9922977 00 1 57.19414889 32.20993045 0 1 143.4263994 30.31774642 0 1 -74.86993646 12.8784404 00 1 -37.27243678 34.59668314 0 1 119.100636 27.97620699 0 1 -93.83230336 12.22026619 00 1 6.915941441 34.76940877 0 1 108.961068 32.40868426 0 1 -123.3664337 15.42403493 00 1 20.86262687 24.89943383 0 1 -39.07723225 38.59654138 0 1 -12.16492854 12.12955003 00 1 -0.093599136 25.20590232 0 1 62.36093915 38.7118682 0 1 -39.2295382 10.90757052 00 1 21.91398765 24.57102077 0 1 -127.1032447 37.21274502 0 1 -6.610361185 12.78764651 0404Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCd Intercept Cd Slope Ce Ce +/- Ce Intercept Ce Slope Cl Cl +/- Cl Intercept Cl Slope Co Co +/- Co InterceptD.7 fp-XRF Soil Mode0 1 -23.41733613 25.19841437 0 1 21.56531623 40.90250423 0 1 -28.92184262 13.2219865 00 1 12.86249271 23.61263657 0 1 -40.97661854 39.31985553 0 1 -66.42290801 13.9737207 00 1 30.06419005 23.78558194 0 1 24.18990934 38.53358459 0 1 -35.75315789 11.73835058 00 1 66.37270242 25.11120251 0 1 -8.484199412 38.88453462 0 1 -26.68932588 11.92107625 00 1 84.22873171 34.48792614 0 1 165.8340289 28.63335998 0 1 -32.73106418 7.685150766 00 1 14.51308575 37.16211294 0 1 173.107699 28.13131297 0 1 -39.06849052 6.722558314 00 1 25.21101018 25.12449139 0 1 60.38975348 39.86904703 0 1 -36.82192751 11.29991797 00 1 28.3360942 24.06697013 0 1 -28.09002747 38.11815971 0 1 -56.42710391 11.61532885 00 1 -17.13632833 32.57497854 0 1 213.2575921 28.86607845 0 1 -35.63318871 8.381434293 00 1 18.02422447 24.92602304 0 1 67.31227295 41.24835655 0 1 -50.66447369 12.786068 00 1 19.14145003 23.93514411 0 1 -28.65982548 37.45158408 0 1 -38.84803056 12.57342317 00 1 77.10329239 30.6496531 0 1 -216.0753995 89.30867612 0 1 -304.1360451 45.35117873 00 1 58.7070365 23.86220199 0 1 -22.34735389 37.31554151 0 1 -31.13351436 12.56831591 00 1 25.88727205 26.38627325 0 1 2.881856514 52.2873478 0 1 -129.3985761 22.6487546 00 1 89.16427048 24.39935679 0 1 -38.41149716 41.33947575 0 1 -50.17222307 14.64476777 00 1 17.55002343 25.38688789 0 1 -9.071130944 41.84901782 0 1 -92.90873982 14.37865142 00 1 46.65400059 24.87997468 0 1 33.06198491 42.04722454 0 1 -93.19296625 13.95615137 00 1 30.48017947 25.3127693 0 1 4.670088601 41.89431331 0 1 -59.41071443 14.88349848 00 1 50.72319088 24.8565065 0 1 66.78710137 44.69478735 0 1 -66.60124163 14.99424603 00 1 48.31814495 24.29823156 0 1 75.26928946 41.80290451 0 1 -69.77720963 13.11970224 00 1 41.04361544 35.12708826 0 1 187.057987 26.39329045 0 1 -39.67763092 7.3804889 00 1 59.32322928 25.53667239 0 1 15.56863783 45.21727113 0 1 -59.09448102 16.14625708 00 1 37.8646564 24.81383986 0 1 -8.119621792 43.82108113 0 1 -39.43598274 15.37496625 00 1 12.50493932 25.24022603 0 1 -101.391696 39.75898809 0 1 -49.51721669 14.00589952 00 1 66.44863553 24.34341425 0 1 26.72764179 39.86421679 0 1 -41.76572049 11.80136333 00 1 45.70642002 23.96488944 0 1 0.276644432 37.78748729 0 1 -17.56845551 11.33088318 00 1 31.1641948 24.09324406 0 1 -62.71259206 35.28119006 0 1 -16.4080361 10.34192575 0405Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCo Slope Cr Cr +/- Cr Intercept Cr Slope Cu Cu +/- Cu Intercept Cu Slope Fe Fe +/- Fe Intercept Fe Slope1 34.25127015 2.689123078 4 1.32 -4.196804193 2.584084219 18 1.0893 7809.958819 48.9789949 5290 0.88481 40.08220973 2.832988765 4 1.32 6.995005687 2.728197733 18 1.0893 8454.313928 51.89807565 5290 0.88481 27.55524009 4.268639736 4 1.32 -3.212820243 3.047693988 18 1.0893 39253.58905 174.1701889 5290 0.88481 42.28253175 2.267272174 4 1.32 105.2481806 3.363540184 18 1.0893 12642.02849 60.65375897 5290 0.88481 45.59035017 2.785056726 4 1.32 -0.710606077 2.551531498 18 1.0893 7052.015357 45.49857966 5290 0.88481 35.31659322 2.739465267 4 1.32 -3.37962039 2.711637591 18 1.0893 6979.998278 46.22099117 5290 0.88481 39.44776633 2.832092955 4 1.32 4.243464862 2.815701388 18 1.0893 8898.880665 53.95124871 5290 0.88481 40.76500111 2.907382482 4 1.32 0.778278996 2.759893888 18 1.0893 9802.057449 57.28282247 5290 0.88481 45.25912776 2.954105442 4 1.32 -0.702244925 2.732525452 18 1.0893 9119.08429 54.9045783 5290 0.88481 32.56412609 2.769725154 4 1.32 -5.485154757 2.651281438 18 1.0893 8962.63569 53.84323847 5290 0.88481 42.22534899 2.959563584 4 1.32 -0.952034506 2.709261913 18 1.0893 9593.822374 56.68344689 5290 0.88481 46.77416413 2.944805015 4 1.32 -3.167388498 2.657338885 18 1.0893 10169.38748 58.4531687 5290 0.88481 42.25702181 2.879606848 4 1.32 -0.971478405 2.655498178 18 1.0893 8906.06055 53.93681967 5290 0.88481 86.11022087 6.295284036 4 1.32 7.664067511 3.780563432 18 1.0893 72470.10041 308.2094585 5290 0.88481 39.06711527 2.848475892 4 1.32 -6.420999726 2.650775698 18 1.0893 8978.077768 54.17503543 5290 0.88481 41.7920764 2.904995632 4 1.32 -1.385533547 2.683823378 18 1.0893 9476.67257 55.79174058 5290 0.88481 47.58940684 2.941350851 4 1.32 1.77712711 2.699649126 18 1.0893 9285.011248 54.72472666 5290 0.88481 42.41070872 2.943106303 4 1.32 -0.503057637 2.790339371 18 1.0893 10217.62654 58.86068694 5290 0.88481 41.32180397 2.818222017 4 1.32 -3.005074347 2.612836561 18 1.0893 7463.838192 47.57776479 5290 0.88481 46.20974508 2.943246306 4 1.32 -0.320621793 2.754309447 18 1.0893 8878.202352 53.83593546 5290 0.88481 41.71402318 3.026831066 4 1.32 0.467765203 2.733435741 18 1.0893 10676.58558 60.7285534 5290 0.88481 31.12013792 4.33770627 4 1.32 3.061809579 3.001825557 18 1.0893 44027.47279 186.9902181 5290 0.88481 41.52536205 2.739487128 4 1.32 -6.354552503 2.477949213 18 1.0893 8103.544659 49.60690788 5290 0.88481 48.63761052 3.00359765 4 1.32 11.61038647 2.902792474 18 1.0893 9864.6001 57.58561383 5290 0.88481 43.98298172 3.069374213 4 1.32 -1.782311994 2.811793102 18 1.0893 10984.06749 62.50338112 5290 0.88481 44.74776821 2.971657518 4 1.32 -8.254420096 2.551190864 18 1.0893 10178.30977 58.23302537 5290 0.88481 38.76373039 2.931782363 4 1.32 6.260993584 2.846135922 18 1.0893 10189.60194 58.87717289 5290 0.88481 34.5898435 2.772139596 4 1.32 5.148111867 2.784511547 18 1.0893 8867.755502 53.30240028 5290 0.88481 45.11950518 3.02074502 4 1.32 11.05449941 2.866631801 18 1.0893 9928.238756 57.9804193 5290 0.88481 34.18685882 2.66590574 4 1.32 -10.29428871 2.568097936 18 1.0893 7062.654529 45.83675381 5290 0.88481 50.52592129 3.248740945 4 1.32 -0.052949391 2.891041507 18 1.0893 12250.14219 67.70029879 5290 0.88481 37.76636163 2.215837871 4 1.32 20.17879259 2.609997791 18 1.0893 3995.241176 30.8656656 5290 0.88481 31.84637383 2.46610825 4 1.32 -4.937699554 2.512575664 18 1.0893 5212.910319 37.57609069 5290 0.88481 45.01240327 1.941378154 4 1.32 171.2539609 4.224460882 18 1.0893 3747.433877 30.0251024 5290 0.88481 39.47700343 1.844750077 4 1.32 110.9267677 3.490341431 18 1.0893 3912.978888 29.9046339 5290 0.88481 92.49102374 6.350354519 4 1.32 2.851577287 3.630112879 18 1.0893 73051.91283 311.0756677 5290 0.88481 42.75824596 1.881685851 4 1.32 104.7264323 3.406074903 18 1.0893 3910.111991 29.93902799 5290 0.88481 30.74727587 2.047830617 4 1.32 57.62429978 2.842657857 18 1.0893 7781.87955 44.37567686 5290 0.8848D.7 fp-XRF Soil Mode406Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCo Slope Cr Cr +/- Cr Intercept Cr Slope Cu Cu +/- Cu Intercept Cu Slope Fe Fe +/- Fe Intercept Fe SlopeD.7 fp-XRF Soil Mode1 40.60733013 2.660604956 4 1.32 -7.382785617 2.451881159 18 1.0893 5978.265207 40.96341663 5290 0.88481 44.32552447 2.906722853 4 1.32 6.768903922 2.837614682 18 1.0893 7608.078289 48.67461208 5290 0.88481 40.59394371 2.779583764 4 1.32 2.512640996 2.694935952 18 1.0893 7872.99613 48.97035462 5290 0.88481 44.17764272 2.930544471 4 1.32 -2.071715008 2.666936448 18 1.0893 9538.81158 55.78661901 5290 0.88481 39.20542652 2.81177163 4 1.32 -0.921491477 2.607236927 18 1.0893 8772.77827 52.7509451 5290 0.88481 38.42032219 2.843318611 4 1.32 -2.562416958 2.656049172 18 1.0893 9306.359504 55.36568623 5290 0.88481 41.92131349 2.8608682 4 1.32 -5.993635964 2.648459992 18 1.0893 8618.279361 52.48033728 5290 0.88481 54.4710876 3.149246498 4 1.32 -3.006075218 2.757626386 18 1.0893 10359.49324 59.54652208 5290 0.88481 44.56102324 3.018309481 4 1.32 -7.024036855 2.703268951 18 1.0893 11247.12529 62.978272 5290 0.88481 55.91145831 3.075216783 4 1.32 13.92226533 2.906315495 18 1.0893 9189.798208 54.62433114 5290 0.88481 42.62275215 2.900450726 4 1.32 -0.389814096 2.771181496 18 1.0893 9092.072301 54.59127338 5290 0.88481 40.36387921 3.01513675 4 1.32 -0.263697105 2.803244101 18 1.0893 10373.76698 59.82698047 5290 0.88481 52.70448658 3.029335808 4 1.32 7.17700803 2.850403098 18 1.0893 9763.035447 57.05608524 5290 0.88481 39.7364507 2.888365517 4 1.32 6.279176595 2.808985573 18 1.0893 9047.916533 54.16772848 5290 0.88481 46.83563563 3.074765194 4 1.32 9.214246518 2.870952006 18 1.0893 10702.17305 61.16704246 5290 0.88481 40.44847446 2.952932902 4 1.32 5.125390077 2.807956207 18 1.0893 9134.1948 55.11386779 5290 0.88481 69.11966584 3.341019219 4 1.32 1.385675208 2.804947039 18 1.0893 10437.73362 60.83242036 5290 0.88481 51.25831284 2.989539019 4 1.32 -3.681387683 2.642223267 18 1.0893 8892.791715 53.88990375 5290 0.88481 27.42041092 2.645165478 4 1.32 -4.225418051 2.645527519 18 1.0893 7827.509496 49.29049148 5290 0.88481 77.54269307 6.288192732 4 1.32 5.230215331 3.730450248 18 1.0893 72632.85282 308.7239155 5290 0.88481 36.70051266 2.74964877 4 1.32 -2.728074865 2.592658555 18 1.0893 7749.470707 48.91640927 5290 0.88481 55.93926988 3.210736871 4 1.32 6.732891656 2.906885769 18 1.0893 11578.34675 64.44562552 5290 0.88481 50.15498213 3.170107671 4 1.32 11.13578137 2.980179275 18 1.0893 12361.36707 67.50507989 5290 0.88481 44.24468295 2.950518456 4 1.32 -3.685249095 2.688674361 18 1.0893 9677.450926 57.20667276 5290 0.88481 57.8767473 3.195083057 4 1.32 6.612466992 2.857689112 18 1.0893 11492.19328 63.68776423 5290 0.88481 56.36730293 3.140594808 4 1.32 34.37151043 3.201847527 18 1.0893 9610.166689 56.56071754 5290 0.88481 42.5124652 2.92243136 4 1.32 3.32735381 2.751771185 18 1.0893 9110.620055 54.83220465 5290 0.88481 44.2284586 2.986713534 4 1.32 5.049533121 2.782375009 18 1.0893 9757.405713 57.43404783 5290 0.88481 39.68238499 2.921758455 4 1.32 -4.74172745 2.608412482 18 1.0893 9213.677174 55.29780708 5290 0.88481 37.65018069 2.880127968 4 1.32 -1.484798824 2.706836538 18 1.0893 9371.395351 55.72430346 5290 0.88481 38.8742312 2.850948241 4 1.32 0.789132181 2.761174623 18 1.0893 8043.998625 50.80373332 5290 0.88481 39.20254144 2.889402996 4 1.32 0.235242969 2.688190258 18 1.0893 8713.988461 53.38707933 5290 0.88481 32.35537971 2.754661842 4 1.32 -2.332925502 2.614539292 18 1.0893 8500.434223 52.34381882 5290 0.88481 41.13930406 2.845538497 4 1.32 -2.254226516 2.645472885 18 1.0893 8860.01162 53.23261469 5290 0.88481 35.52583848 2.804731191 4 1.32 -4.753744994 2.563697146 18 1.0893 9091.013372 54.39271645 5290 0.88481 35.75255235 2.859502578 4 1.32 1.509812329 2.71008892 18 1.0893 8477.873941 52.43357132 5290 0.88481 37.28136808 2.849857193 4 1.32 4.686445785 2.746264524 18 1.0893 9005.596052 54.25883961 5290 0.8848407Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCo Slope Cr Cr +/- Cr Intercept Cr Slope Cu Cu +/- Cu Intercept Cu Slope Fe Fe +/- Fe Intercept Fe SlopeD.7 fp-XRF Soil Mode1 37.82866767 2.844642338 4 1.32 -6.232181059 2.713269849 18 1.0893 8679.621041 53.17090944 5290 0.88481 36.4308748 2.882927369 4 1.32 2.112037256 2.745485192 18 1.0893 9781.482919 57.48423673 5290 0.88481 44.53220446 3.042829498 4 1.32 -0.117585582 2.841830912 18 1.0893 10167.92862 59.42658205 5290 0.88481 38.37345659 2.997048641 4 1.32 -0.160689129 2.812579143 18 1.0893 11630.77308 64.95014997 5290 0.88481 86.32349727 6.25600827 4 1.32 0.422733022 3.739626096 18 1.0893 72782.10997 309.6457867 5290 0.88481 43.76410783 3.043681436 4 1.32 -0.552358396 2.763895161 18 1.0893 11396.93531 63.67555902 5290 0.88481 41.98222811 2.99294276 4 1.32 5.445124185 2.854913449 18 1.0893 10847.1935 61.76945678 5290 0.88481 34.77805805 2.796856878 4 1.32 -0.753646981 2.632113177 18 1.0893 8775.368626 53.06730536 5290 0.88481 36.55142956 2.685371096 4 1.32 -0.996894256 2.651157195 18 1.0893 7469.48422 47.52671099 5290 0.88481 33.51615981 2.521072946 4 1.32 -2.032236071 2.491480379 18 1.0893 5078.960919 37.17909702 5290 0.88481 36.00851526 2.565825337 4 1.32 8.184877968 2.661257029 18 1.0893 5896.61108 39.92003526 5290 0.88481 48.41204854 2.966565505 4 1.32 3.026404559 2.719568423 18 1.0893 8344.510043 51.70125358 5290 0.88481 37.6406655 2.844972201 4 1.32 -3.757846252 2.661224589 18 1.0893 9063.336483 54.25725094 5290 0.88481 32.98515206 2.757606341 4 1.32 -3.835789934 2.586542828 18 1.0893 8757.816956 52.86045116 5290 0.88481 40.03475362 2.963885588 4 1.32 5.935424685 2.884965465 18 1.0893 10118.03397 59.23309093 5290 0.88481 41.48204006 2.956388048 4 1.32 -2.358846661 2.663667186 18 1.0893 10004.28113 58.23387937 5290 0.88481 37.67780859 2.841600616 4 1.32 0.212176369 2.600024712 18 1.0893 9031.66795 53.6286111 5290 0.88481 33.59137795 2.447804924 4 1.32 -10.06249139 2.454299829 18 1.0893 4045.751981 32.40221272 5290 0.88481 30.10414302 2.460418651 4 1.32 -6.316646077 2.427669891 18 1.0893 5084.979426 36.97192761 5290 0.88481 26.26325223 2.115642429 4 1.32 5.818195716 2.378247799 18 1.0893 2396.129275 23.44579568 5290 0.88481 47.11654009 2.780164987 4 1.32 5.485266782 2.62367216 18 1.0893 7244.472955 45.89795742 5290 0.88481 38.25899305 2.685431607 4 1.32 2.252739948 2.645915555 18 1.0893 6564.893589 43.35839067 5290 0.88481 45.11056031 1.88933392 4 1.32 130.4616298 3.739067191 18 1.0893 2205.958629 22.09553019 5290 0.88481 41.73787467 1.905711279 4 1.32 110.8615462 3.413119986 18 1.0893 5072.863152 33.68878055 5290 0.88481 47.06521259 2.906455269 4 1.32 -1.407867516 2.643911118 18 1.0893 8335.50282 51.44879982 5290 0.88481 33.94666898 2.747066546 4 1.32 -1.584918705 2.634155092 18 1.0893 7959.393234 49.52514197 5290 0.88481 85.76721414 6.370420428 4 1.32 4.006511815 3.761577467 18 1.0893 72592.55372 309.4631579 5290 0.88481 30.82080267 2.670495698 4 1.32 -4.552380375 2.582250483 18 1.0893 7944.7803 49.44434052 5290 0.88481 34.81958695 2.774860564 4 1.32 -5.94775577 2.539286472 18 1.0893 9197.816602 54.24329357 5290 0.88481 48.1165068 2.939701987 4 1.32 1.453058735 2.6816461 18 1.0893 8193.43418 50.90393961 5290 0.88481 49.45692002 2.564305805 4 1.32 19.06872074 2.753053507 18 1.0893 9628.490499 54.38502884 5290 0.88481 39.0305986 2.16107755 4 1.32 73.96265654 3.069467555 18 1.0893 9433.291389 49.86661068 5290 0.88481 42.4319432 2.070265399 4 1.32 109.7257682 3.517081739 18 1.0893 8183.561977 46.81086069 5290 0.88481 41.63624611 2.366536834 4 1.32 84.17030541 3.326984224 18 1.0893 12805.02947 63.62960112 5290 0.88481 36.67953788 2.695672677 4 1.32 0.168757183 2.638408294 18 1.0893 6499.178719 43.38123181 5290 0.88481 33.52445938 2.538891126 4 1.32 -7.489454458 2.45027453 18 1.0893 5524.577074 38.85217731 5290 0.88481 40.08310979 2.802145851 4 1.32 -3.696439051 2.606902089 18 1.0893 7069.366417 46.14011868 5290 0.8848408Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCo Slope Cr Cr +/- Cr Intercept Cr Slope Cu Cu +/- Cu Intercept Cu Slope Fe Fe +/- Fe Intercept Fe SlopeD.7 fp-XRF Soil Mode1 47.00433719 2.881738138 4 1.32 -4.047765435 2.659324249 18 1.0893 7767.528773 48.83948645 5290 0.88481 35.20378058 2.756727386 4 1.32 -3.090521255 2.628293364 18 1.0893 9010.562901 53.53590069 5290 0.88481 35.82855071 2.615478746 4 1.32 -5.293826963 2.504253661 18 1.0893 6243.52353 42.29162816 5290 0.88481 36.88118297 2.664724267 4 1.32 -3.15687645 2.519528729 18 1.0893 6452.233003 42.91135089 5290 0.88481 35.6159268 1.874012405 4 1.32 180.3151436 4.26159828 18 1.0893 2927.061115 25.86364417 5290 0.88481 42.79142306 1.901068714 4 1.32 200.6886481 4.448791509 18 1.0893 2234.637155 22.48374799 5290 0.88481 33.87737164 2.591439524 4 1.32 -0.968708299 2.539185356 18 1.0893 5831.338491 40.42343186 5290 0.88481 37.00052165 2.657657309 4 1.32 -1.214393046 2.563943472 18 1.0893 6325.386398 42.39052717 5290 0.88481 41.43224894 1.944382697 4 1.32 150.6205668 3.87314733 18 1.0893 3676.32903 28.75578773 5290 0.88481 40.85480928 2.745882692 4 1.32 25.24007551 3.032834493 18 1.0893 7623.482054 47.57460829 5290 0.88481 34.94173581 2.653998444 4 1.32 -1.472744794 2.570023018 18 1.0893 7239.304816 46.21432693 5290 0.88481 74.99484071 6.205693229 4 1.32 -5.375953831 3.65253869 18 1.0893 73135.55463 311.8373393 5290 0.88481 30.55656763 2.59929867 4 1.32 -4.919056433 2.566673615 18 1.0893 7167.206479 45.96377302 5290 0.88481 65.90206972 3.824381318 4 1.32 2.114312813 2.94241225 18 1.0893 21456.53169 104.0617025 5290 0.88481 47.93139545 2.99174833 4 1.32 4.803235549 2.786930936 18 1.0893 9537.908116 56.25035141 5290 0.88481 36.3623949 2.846565427 4 1.32 1.707646547 2.757996732 18 1.0893 9510.874979 56.08319153 5290 0.88481 40.32423222 2.875889186 4 1.32 -3.995717148 2.569296543 18 1.0893 9065.559182 54.08860639 5290 0.88481 44.81927457 2.96057668 4 1.32 -3.265427904 2.5717607 18 1.0893 9927.980264 57.71801177 5290 0.88481 45.36242774 3.005389612 4 1.32 0.782929616 2.668993224 18 1.0893 10111.37217 58.45262988 5290 0.88481 40.82337145 2.790029873 4 1.32 -5.145351853 2.608021826 18 1.0893 7936.389625 49.48738757 5290 0.88481 44.17917169 1.88214902 4 1.32 195.9135737 4.295854592 18 1.0893 2815.254353 24.98790574 5290 0.88481 71.03728033 3.390654452 4 1.32 2.136496449 2.853732225 18 1.0893 11416.23358 64.06471238 5290 0.88481 73.02378947 3.347982455 4 1.32 -0.240470695 2.795968089 18 1.0893 10227.49597 59.49732503 5290 0.88481 44.46521429 2.949959142 4 1.32 1.242088092 2.743848937 18 1.0893 8521.362227 52.88242869 5290 0.88481 35.93357131 2.659501157 4 1.32 -4.663477946 2.590738281 18 1.0893 6344.766015 42.73642976 5290 0.88481 29.49086529 2.506690652 4 1.32 -3.253913922 2.547855941 18 1.0893 5729.58966 39.99484117 5290 0.88481 31.84587375 2.493491149 4 1.32 -1.680049511 2.56877213 18 1.0893 4817.500587 35.76147669 5290 0.8848409Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFHg Hg +/- Hg Intercept Hg Slope K K +/- K Intercept K Slope La La +/- La Intercept La Slope Mn2.686100061 1.521235998 0 1 14806.65447 132.6913874 -1347 1.0707 29.28133642 20.17597732 0 1 129.3001263.63425962 1.501595794 0 1 15012.22472 136.2835337 -1347 1.0707 59.38551264 20.68247056 0 1 138.03541043.405319712 1.669747393 0 1 16916.60128 168.0475519 -1347 1.0707 3.844431626 21.61632226 0 1 263.0223307-2.125232292 1.010337103 0 1 3144.844025 44.7202526 -1347 1.0707 44.71667205 27.4458351 0 1 74.034089320.54476942 1.356284355 0 1 14475.87155 130.5836171 -1347 1.0707 16.57393912 21.20990847 0 1 145.12770844.585154035 1.520441232 0 1 15398.8168 138.4292308 -1347 1.0707 8.912776644 20.33154014 0 1 142.66571565.006640985 1.532747501 0 1 16105.84005 141.8321597 -1347 1.0707 4.318033726 20.17308852 0 1 167.64390294.519101682 1.535904708 0 1 16380.62981 143.2821626 -1347 1.0707 19.05942504 20.12669749 0 1 169.59699861.555199361 1.504777264 0 1 15949.34532 142.1898975 -1347 1.0707 28.1245988 20.28564227 0 1 158.58166554.156760941 1.546119645 0 1 16220.51343 142.1416699 -1347 1.0707 41.82133231 20.6829471 0 1 153.48873832.980430222 1.536196667 0 1 16331.30507 145.651858 -1347 1.0707 39.23224656 20.53834803 0 1 167.30781273.932518121 1.559631926 0 1 16484.54733 143.0752086 -1347 1.0707 17.15195264 20.11036694 0 1 179.01411393.243067423 1.477657198 0 1 15631.98605 139.9544662 -1347 1.0707 34.41603138 20.88085105 0 1 148.89696985.698164921 1.908647232 0 1 5080.750435 96.02538198 -1347 1.0707 74.76230793 26.19155846 0 1 492.27992064.898031916 1.531011927 0 1 15718.68922 140.3717939 -1347 1.0707 63.62158141 20.76304411 0 1 149.2768492.480950713 1.506777376 0 1 16228.82397 143.1050024 -1347 1.0707 10.18160932 20.48700685 0 1 158.45727693.649386784 1.477786482 0 1 15640.1226 138.7422073 -1347 1.0707 42.74767592 20.50830407 0 1 157.98680292.012777943 1.475925519 0 1 16746.04927 145.703611 -1347 1.0707 46.70311623 20.1001583 0 1 184.88694413.893843605 1.514547431 0 1 15992.26926 140.8856823 -1347 1.0707 0.949435673 20.35862287 0 1 159.9208483.165970745 1.488128488 0 1 16296.77589 143.9434115 -1347 1.0707 7.304795147 20.67780352 0 1 157.14824022.377331976 1.45897334 0 1 15985.2828 143.37948 -1347 1.0707 -3.624479468 20.56399647 0 1 169.78876663.445309207 1.662821546 0 1 14316.40282 148.0047945 -1347 1.0707 25.4172918 23.03253327 0 1 180.87138882.636513688 1.477034906 0 1 14893.27999 131.6726867 -1347 1.0707 11.3816761 20.13641015 0 1 132.47485544.575320669 1.522142957 0 1 16283.82092 143.4843127 -1347 1.0707 23.66140743 20.91744808 0 1 158.16890040.857520028 1.490500528 0 1 16875.53838 149.2673052 -1347 1.0707 7.875963701 20.46797419 0 1 171.28414132.386650316 1.455698941 0 1 16455.07589 144.5906791 -1347 1.0707 9.428939562 21.26361082 0 1 159.41796653.70846482 1.555370247 0 1 16286.44013 144.5967086 -1347 1.0707 56.77928806 20.89333704 0 1 169.70604871.018374449 1.457834931 0 1 16118.42352 141.2814317 -1347 1.0707 4.835724321 20.51810547 0 1 142.80888416.319386253 1.594950145 0 1 15910.9758 143.2044042 -1347 1.0707 25.91867829 20.90819533 0 1 165.19606042.58185404 1.477835193 0 1 15159.26919 134.6438154 -1347 1.0707 44.34503939 20.46933046 0 1 138.10542351.390948531 1.467194946 0 1 17870.72871 157.1542774 -1347 1.0707 26.98314515 21.49374113 0 1 179.0262354-1.458586833 1.174980972 0 1 6757.960692 73.808379 -1347 1.0707 -31.11924649 26.28615533 0 1 78.610643152.392841461 1.419447529 0 1 13140.98313 120.8078834 -1347 1.0707 5.561654361 20.03311102 0 1 114.9257867-3.032412609 1.031447789 0 1 1469.287924 29.51879703 -1347 1.0707 19.58733234 32.17825025 0 1 64.57910382-3.093321943 1.01568411 0 1 715.9387715 21.22852589 -1347 1.0707 -9.927242559 30.5066217 0 1 68.909796774.013323978 1.853369683 0 1 5002.620871 95.5923145 -1347 1.0707 10.37620201 25.6908738 0 1 493.0219259-2.671408793 0.995095654 0 1 730.8969459 21.44326449 -1347 1.0707 33.58827559 30.73498468 0 1 65.50267145-0.618387465 1.086055566 0 1 4972.619168 56.89891559 -1347 1.0707 -22.67493809 27.72495093 0 1 52.96297273D.7 fp-XRF Soil Mode410Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFHg Hg +/- Hg Intercept Hg Slope K K +/- K Intercept K Slope La La +/- La Intercept La Slope MnD.7 fp-XRF Soil Mode1.853081113 1.36444826 0 1 14136.71506 127.2887824 -1347 1.0707 17.23329607 21.57855001 0 1 131.17478342.091891073 1.445231675 0 1 16394.12218 145.3387261 -1347 1.0707 21.21197867 21.47917494 0 1 166.09698112.841447359 1.473845251 0 1 14392.40215 130.341915 -1347 1.0707 0.83349753 21.58992076 0 1 143.99957382.456282125 1.486051207 0 1 16150.80117 142.4263929 -1347 1.0707 50.64411219 20.62165647 0 1 179.15092253.749440211 1.487488905 0 1 15229.32451 136.5554403 -1347 1.0707 -25.01942373 22.25614854 0 1 130.76960792.626916707 1.463953102 0 1 15258.5685 137.5212035 -1347 1.0707 -13.5576325 20.77412342 0 1 148.82691461.465031084 1.444370513 0 1 15710.03453 139.540861 -1347 1.0707 9.157687468 20.62403498 0 1 155.05357053.371102318 1.467476211 0 1 17237.60557 150.9690211 -1347 1.0707 55.59640618 21.02708438 0 1 163.38968023.92868682 1.525412068 0 1 14207.44732 132.663697 -1347 1.0707 15.79723375 20.69474101 0 1 159.12473912.772295107 1.487128418 0 1 16238.52113 144.0691768 -1347 1.0707 -11.57659369 20.94697123 0 1 151.98667551.695973662 1.46575482 0 1 15926.75061 141.5124202 -1347 1.0707 31.4699742 21.40506355 0 1 155.85366691.596459768 1.476273992 0 1 17029.95928 150.2262036 -1347 1.0707 4.156705123 21.1676456 0 1 169.28399064.339550058 1.515739904 0 1 16322.6609 143.3641173 -1347 1.0707 3.384578629 20.88462973 0 1 159.42362314.510956195 1.510686804 0 1 16649.66664 145.5890805 -1347 1.0707 37.20955539 19.916386 0 1 160.22169852.527989703 1.478383658 0 1 16331.24749 146.2723064 -1347 1.0707 22.91948069 21.72544886 0 1 158.58851392.463461966 1.491123887 0 1 16443.65812 146.0101072 -1347 1.0707 25.1110654 21.07354193 0 1 175.50962622.708662428 1.497218236 0 1 16999.08889 151.5304846 -1347 1.0707 6.664969641 21.83662061 0 1 181.19064224.323575571 1.53924042 0 1 15789.54429 142.0314485 -1347 1.0707 32.6902975 21.52351182 0 1 149.80843873.273529022 1.513461248 0 1 14117.64063 130.854035 -1347 1.0707 -3.749247136 20.88587393 0 1 148.2998765.31913959 1.895603675 0 1 5090.31724 96.78215676 -1347 1.0707 49.21234007 25.21999391 0 1 498.04292022.735015082 1.467175743 0 1 14367.96966 132.4181756 -1347 1.0707 0.332230786 21.11375163 0 1 138.89773232.881357269 1.505885646 0 1 17337.50419 151.9309879 -1347 1.0707 18.99774026 21.62263173 0 1 194.89128764.476318289 1.513758879 0 1 16937.21286 149.7874119 -1347 1.0707 14.11670157 21.55279586 0 1 201.28020294.612774383 1.598992633 0 1 15731.32063 141.8183289 -1347 1.0707 -2.650022315 21.43691135 0 1 149.97377715.446823788 1.567768399 0 1 16498.27124 145.9251394 -1347 1.0707 20.81996003 21.67311822 0 1 212.87068920.046111417 1.416761227 0 1 15763.78067 142.0112865 -1347 1.0707 37.09635011 22.23095172 0 1 159.58946442.458430342 1.498532125 0 1 15653.123 140.6823273 -1347 1.0707 -23.59394055 22.33445626 0 1 163.06001112.507184143 1.496820424 0 1 15731.06977 141.3907403 -1347 1.0707 59.37278056 21.2443484 0 1 158.78454894.721826835 1.554135646 0 1 15318.71254 140.1066121 -1347 1.0707 30.9574058 21.77867203 0 1 156.60216864.127136167 1.517686568 0 1 16022.28075 142.5925444 -1347 1.0707 -11.00655676 21.61702038 0 1 165.96062812.364902348 1.484859582 0 1 15520.03895 140.7532252 -1347 1.0707 29.6839564 21.38076191 0 1 150.11092630.001704284 1.426713537 0 1 15779.12325 142.4257045 -1347 1.0707 45.97069947 21.07886108 0 1 166.13915231.588944894 1.463981902 0 1 15717.10785 140.145823 -1347 1.0707 -6.76971673 22.19214756 0 1 149.6225822.737075183 1.471552957 0 1 16186.39043 142.0807982 -1347 1.0707 39.49400444 21.22459411 0 1 167.57923531.262265145 1.465957568 0 1 15391.61433 138.7540542 -1347 1.0707 27.02465737 21.6336894 0 1 140.74253124.312384887 1.539035709 0 1 16382.38065 145.8827764 -1347 1.0707 23.03518291 20.83769785 0 1 163.31987612.113796377 1.543048175 0 1 16068.18024 142.4811563 -1347 1.0707 33.57037238 20.84336315 0 1 156.0164466411Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFHg Hg +/- Hg Intercept Hg Slope K K +/- K Intercept K Slope La La +/- La Intercept La Slope MnD.7 fp-XRF Soil Mode2.419084619 1.540435813 0 1 15685.19116 140.8526613 -1347 1.0707 9.682484862 21.65579897 0 1 152.74767053.500548256 1.523489685 0 1 16733.18048 147.0848682 -1347 1.0707 28.98772253 20.88294235 0 1 150.37237782.566926835 1.512556079 0 1 17571.82175 153.5262131 -1347 1.0707 38.3691978 20.68087838 0 1 188.24078972.440145974 1.518274193 0 1 15980.86181 143.8600329 -1347 1.0707 1.239631113 20.6989998 0 1 153.43490865.502067224 1.891403021 0 1 5148.494768 96.35879577 -1347 1.0707 -5.303813343 25.93339596 0 1 490.40819192.656244493 1.476625424 0 1 16138.07152 144.7254439 -1347 1.0707 9.889571602 20.8328606 0 1 154.6766070.985909562 1.482910087 0 1 17796.34916 153.5108502 -1347 1.0707 4.369051607 20.89387888 0 1 175.60685612.958463787 1.510832685 0 1 15935.07533 141.7398988 -1347 1.0707 32.35450262 20.56772051 0 1 150.79410593.506697309 1.528694167 0 1 14751.70506 132.4072583 -1347 1.0707 21.48604869 20.03378367 0 1 122.39718521.748831786 1.429545662 0 1 13662.95942 124.7792368 -1347 1.0707 20.18464538 20.71641858 0 1 115.20271642.646121317 1.4229132 0 1 13938.16124 124.328829 -1347 1.0707 -5.503163217 21.07431136 0 1 149.45228673.144965035 1.456355091 0 1 15884.44832 142.237379 -1347 1.0707 16.83749976 21.16827889 0 1 165.11737412.751165722 1.503595947 0 1 16713.6035 145.8179507 -1347 1.0707 3.187327777 21.10703619 0 1 157.14504495.047815069 1.533075837 0 1 15049.75649 136.0548123 -1347 1.0707 36.6143846 20.64629626 0 1 133.91507932.145565221 1.511099733 0 1 16545.66701 146.7836244 -1347 1.0707 23.42592575 21.27023673 0 1 180.46342782.118208206 1.449105777 0 1 16865.01518 148.1432481 -1347 1.0707 32.15765853 21.59646746 0 1 164.26865724.517389501 1.496658953 0 1 16051.66672 141.142613 -1347 1.0707 12.96029515 21.92613559 0 1 156.31343174.132249089 1.453671513 0 1 13731.51 124.2244245 -1347 1.0707 30.2859706 20.01073394 0 1 98.950990164.342208754 1.464748327 0 1 12969.10432 120.2031266 -1347 1.0707 3.143417206 20.43765889 0 1 108.27599311.220177413 1.239723074 0 1 8890.738463 89.64327194 -1347 1.0707 -15.02409743 24.52298195 0 1 65.867053612.691001124 1.434475923 0 1 14642.61843 129.874077 -1347 1.0707 15.4285559 21.72883008 0 1 150.66988791.270903263 1.400213567 0 1 14339.99103 129.2426019 -1347 1.0707 28.01802656 21.54131258 0 1 130.3566921-3.302802327 1.01540757 0 1 2187.934947 35.0775275 -1347 1.0707 14.8323255 31.15968607 0 1 69.15511475-1.623782851 1.012073573 0 1 2851.677889 39.49587528 -1347 1.0707 -26.87860903 28.79593164 0 1 59.452591262.93813539 1.533947655 0 1 15975.32694 141.1994269 -1347 1.0707 48.50717678 20.84572279 0 1 152.79553586.19905008 1.549863405 0 1 15679.56354 139.205313 -1347 1.0707 20.0200616 21.0144907 0 1 146.37714444.948447345 1.813422823 0 1 5003.354475 96.44768046 -1347 1.0707 21.7097563 25.56904445 0 1 510.68642424.271552805 1.476490133 0 1 15311.63117 135.9234043 -1347 1.0707 33.04244063 20.93577238 0 1 145.03533874.712299392 1.530030917 0 1 15194.17833 135.5544691 -1347 1.0707 42.48268766 20.78036533 0 1 153.96593643.107210374 1.510890627 0 1 15306.63223 137.9717267 -1347 1.0707 -13.61414507 22.04309862 0 1 156.19611052.83235344 1.312419106 0 1 10143.37562 94.15336049 -1347 1.0707 51.99777359 28.57521582 0 1 128.0195888-2.884708827 1.044006002 0 1 4402.71092 52.76497192 -1347 1.0707 47.5861048 27.60560914 0 1 68.07496161-1.710120287 1.056912911 0 1 3126.201007 42.75613495 -1347 1.0707 9.582273829 29.76001294 0 1 61.95278238-2.391513024 1.068781905 0 1 4548.22594 56.3772894 -1347 1.0707 9.654786887 29.77478929 0 1 73.607685983.579077206 1.495746948 0 1 14512.2991 131.4348553 -1347 1.0707 1.119384701 21.08462709 0 1 140.54868923.602525132 1.455605572 0 1 13813.27639 125.210543 -1347 1.0707 18.63396262 21.41953 0 1 119.25423642.346484778 1.47770294 0 1 16167.86681 142.4177446 -1347 1.0707 35.13134865 20.77166652 0 1 130.6095016412Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFHg Hg +/- Hg Intercept Hg Slope K K +/- K Intercept K Slope La La +/- La Intercept La Slope MnD.7 fp-XRF Soil Mode5.87375681 1.536460801 0 1 16128.36752 141.0868203 -1347 1.0707 13.00238836 21.35410867 0 1 134.64208246.289006031 1.585112778 0 1 15151.52022 135.029072 -1347 1.0707 0.00168186 20.00270149 0 1 137.51371162.319579526 1.449295825 0 1 14579.16809 130.1910411 -1347 1.0707 24.24301123 20.12581306 0 1 128.00910852.550764399 1.401559824 0 1 14463.13397 129.6043457 -1347 1.0707 17.4951235 21.1465435 0 1 140.9221485-1.581288161 1.070019559 0 1 2239.613761 36.91615883 -1347 1.0707 85.21563729 29.45497053 0 1 52.56356957-2.568041885 1.073859653 0 1 1347.870988 28.79466258 -1347 1.0707 28.21173543 32.10284602 0 1 56.849593422.845855279 1.440099356 0 1 14722.36261 131.4768773 -1347 1.0707 26.1874382 21.32939739 0 1 128.78826892.519348166 1.458444962 0 1 14416.46535 129.8035768 -1347 1.0707 10.88105463 20.41331658 0 1 141.5804634-1.282567219 1.085005314 0 1 2266.202578 36.58989696 -1347 1.0707 32.90276277 28.28266217 0 1 61.777349966.379725564 1.533310079 0 1 14332.87028 128.8260005 -1347 1.0707 5.302645377 21.42866071 0 1 141.8919232.695367523 1.434506384 0 1 13911.85668 127.315442 -1347 1.0707 7.837124885 20.25850203 0 1 145.12965234.165060451 1.848977924 0 1 5066.023384 95.88558555 -1347 1.0707 35.86706492 25.8776647 0 1 489.9535852.140953321 1.479508191 0 1 13900.90725 126.7544397 -1347 1.0707 11.46155964 20.03941225 0 1 140.33370713.131906079 1.617141392 0 1 15546.49471 149.687063 -1347 1.0707 21.05176591 22.29989712 0 1 372.65861333.361631649 1.532817779 0 1 17018.73015 147.8616962 -1347 1.0707 21.28199083 20.63311989 0 1 193.22550220.630876569 1.444196142 0 1 16446.33039 144.2902504 -1347 1.0707 16.12561838 21.53243032 0 1 153.00764570.110825707 1.428376267 0 1 15392.92878 138.16421 -1347 1.0707 24.40441163 21.16930848 0 1 158.90686610.577332567 1.443243647 0 1 15973.4186 142.389089 -1347 1.0707 45.95278264 21.41944233 0 1 177.64501424.481354623 1.547561611 0 1 16847.94326 147.6956117 -1347 1.0707 7.916345664 21.09111298 0 1 178.41839832.395054043 1.458736042 0 1 14592.32386 132.0448843 -1347 1.0707 41.99515511 20.63705409 0 1 142.135644-3.869354385 0.972993044 0 1 1368.533179 28.19233399 -1347 1.0707 43.42537803 30.09065676 0 1 56.282715092.723537448 1.550673 0 1 16824.87247 150.1506916 -1347 1.0707 18.5145887 21.62824744 0 1 168.90939252.501189754 1.510231243 0 1 16384.59323 146.2718073 -1347 1.0707 18.46870343 20.95608012 0 1 187.78785452.411683417 1.506798508 0 1 16126.03636 144.4652672 -1347 1.0707 -12.14814914 21.31338875 0 1 151.88969361.91366921 1.442226255 0 1 15022.02522 133.9860045 -1347 1.0707 5.934408515 20.64846107 0 1 137.79006081.808797684 1.442052027 0 1 14152.94436 127.5118744 -1347 1.0707 44.0702139 20.42060055 0 1 136.06453422.482675085 1.438557978 0 1 13946.3881 125.7320857 -1347 1.0707 -8.72805687 20.41042299 0 1 115.0154851413Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFMn +/- Mn Intercept Mn Slope Mo Mo +/- Mo Intercept Mo Slope Nb Nb +/- Nb Intercept Nb Slope Nd Nd +/-3.669252928 67 0.9603 3.55238127 1.77287929 0 1 5.181711353 1.121459559 1 0.5528 -46.9773717 75.207330993.833398224 67 0.9603 -1.623022003 1.875032482 0 1 5.717016511 1.194291436 1 0.5528 -43.84758449 76.785515056.041435298 67 0.9603 8.537645913 2.181477944 0 1 5.918601245 1.296623725 1 0.5528 -70.39078286 81.439910522.64352213 67 0.9603 -0.735303141 2.177406072 0 1 -0.084015822 1.503805552 1 0.5528 -49.67056286 98.127801683.774596196 67 0.9603 -0.739656701 1.968448027 0 1 6.791330881 1.283212448 1 0.5528 -99.16396723 78.054366453.821345976 67 0.9603 2.074081287 1.90015726 0 1 4.637347174 1.190005748 1 0.5528 -195.5532083 75.709520934.029703387 67 0.9603 -2.460248357 1.773987499 0 1 5.558877337 1.205291578 1 0.5528 -152.7749872 75.352113514.069044749 67 0.9603 0.875264728 1.886711542 0 1 6.630952866 1.181268506 1 0.5528 -5.323768626 75.101626414.017515874 67 0.9603 -2.227703395 1.85602905 0 1 8.507614239 1.263925833 1 0.5528 -204.7230073 75.488396993.914427368 67 0.9603 -0.060423347 1.932861583 0 1 4.774129036 1.203448028 1 0.5528 -92.75483361 78.134482154.132204749 67 0.9603 -0.835244882 1.897707171 0 1 5.158133618 1.194197352 1 0.5528 47.43120942 76.841511354.122960915 67 0.9603 -2.309899298 1.878874368 0 1 3.538442537 1.154886748 1 0.5528 -152.3348491 75.143653693.927398851 67 0.9603 -2.381403553 1.963409432 0 1 6.583506946 1.29453353 1 0.5528 -86.91433517 77.589100288.76559862 67 0.9603 -10.17378737 3.225037338 0 1 43.80010472 2.929732821 1 0.5528 -46.10235483 95.495400783.926135753 67 0.9603 -4.938827824 1.895803819 0 1 4.884208205 1.230769236 1 0.5528 -128.8964368 76.647498174.006569572 67 0.9603 0.495923473 1.986902887 0 1 6.099579973 1.228444656 1 0.5528 -80.27225103 76.341660323.969142678 67 0.9603 -0.986939645 1.869401771 0 1 5.38729025 1.223326215 1 0.5528 -30.84299814 75.607022134.199581483 67 0.9603 2.103310035 1.93973985 0 1 6.994751451 1.264924482 1 0.5528 -173.6265176 75.325233833.940873865 67 0.9603 -1.848976876 1.836676244 0 1 6.208684019 1.240837043 1 0.5528 -211.9266497 75.830448413.997231492 67 0.9603 -3.133395488 1.868491676 0 1 5.433384692 1.229420163 1 0.5528 -41.41401693 77.230508664.173031973 67 0.9603 1.056169591 1.880332354 0 1 5.221494245 1.200425736 1 0.5528 0.883798345 76.529211075.436705291 67 0.9603 13.27741033 2.370134576 0 1 6.033903997 1.410057896 1 0.5528 11.28283684 85.249738593.662418548 67 0.9603 1.472561144 1.890471235 0 1 4.951201849 1.148949109 1 0.5528 -56.95858605 74.657557064.017684589 67 0.9603 1.018527998 2.083127184 0 1 6.207159425 1.421521068 1 0.5528 -49.93632665 76.987862274.209651516 67 0.9603 -1.627450103 1.944795689 0 1 6.661794393 1.291224896 1 0.5528 -132.8640391 76.554657294.038348204 67 0.9603 0.157681431 2.009070455 0 1 5.388259058 1.278090261 1 0.5528 -43.93600409 78.424068944.138786007 67 0.9603 -0.925590425 1.898574874 0 1 7.172977184 1.286399244 1 0.5528 -151.0010862 77.402534173.828684912 67 0.9603 -0.622114249 1.801156567 0 1 5.47580227 1.167290521 1 0.5528 -7.602469737 76.515173424.125285289 67 0.9603 -2.591233327 2.004989358 0 1 7.420204512 1.313454283 1 0.5528 -116.7359698 77.396527473.713292734 67 0.9603 -4.056951894 1.849639731 0 1 2.225246913 1.122183595 1 0.5528 -141.4952667 76.333188084.371260466 67 0.9603 -0.893937584 2.008961808 0 1 9.043067174 1.439164962 1 0.5528 -53.20260979 79.75938392.773167041 67 0.9603 -3.210080453 2.400229248 0 1 3.204506922 1.65215069 1 0.5528 -79.16497765 95.333388023.414579226 67 0.9603 -0.973607603 1.674237855 0 1 2.075050898 1.03370748 1 0.5528 -152.0018414 73.91102722.287837182 67 0.9603 -1.27814994 2.267018148 0 1 -0.30426038 1.60998899 1 0.5528 26.30919771 115.59880392.259379149 67 0.9603 0.170611122 2.171768231 0 1 -2.718515991 1.372854922 1 0.5528 337.7451834 109.77355348.795703068 67 0.9603 -4.303838671 3.307967832 0 1 45.25369171 2.934139279 1 0.5528 -137.5555371 95.914138682.242808309 67 0.9603 4.351171946 2.127471968 0 1 0.499136207 1.430895926 1 0.5528 -89.17914847 109.64390762.410426255 67 0.9603 -0.998845405 2.305983688 0 1 2.572238193 1.614289723 1 0.5528 7.119573211 100.8197367D.7 fp-XRF Soil Mode414Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFMn +/- Mn Intercept Mn Slope Mo Mo +/- Mo Intercept Mo Slope Nb Nb +/- Nb Intercept Nb Slope Nd Nd +/-D.7 fp-XRF Soil Mode3.596165718 67 0.9603 0.767084102 2.002876213 0 1 8.609294075 1.346790819 1 0.5528 50.63483475 79.415237284.055388072 67 0.9603 -1.434625309 2.099288007 0 1 7.396847936 1.373327296 1 0.5528 -124.1338189 79.261078863.788543716 67 0.9603 -0.18234807 2.172724218 0 1 8.296782324 1.392392551 1 0.5528 -74.78363849 79.486816744.149069132 67 0.9603 0.132100625 1.958937412 0 1 5.889206187 1.230491632 1 0.5528 -188.2800181 76.688151663.754747356 67 0.9603 -4.334788706 2.117807698 0 1 3.661156553 1.315727588 1 0.5528 -1.112471177 81.851291673.923718571 67 0.9603 -2.93945575 1.878391975 0 1 6.67631579 1.244480808 1 0.5528 -127.014202 76.736333813.938551855 67 0.9603 0.22985989 1.86410285 0 1 5.693832267 1.221537249 1 0.5528 -160.6123677 76.59505424.142309867 67 0.9603 0.41656205 1.928742247 0 1 7.8992274 1.298224092 1 0.5528 -72.27448562 77.714905374.089720015 67 0.9603 0.634201767 1.914499621 0 1 5.332244369 1.188973674 1 0.5528 -92.79907959 76.679153683.996992858 67 0.9603 -1.098416323 2.014458063 0 1 8.411154296 1.365805527 1 0.5528 -53.00618964 77.807005913.979040139 67 0.9603 1.556536493 1.953402002 0 1 5.523361268 1.266924345 1 0.5528 -41.24030801 79.216130734.185232782 67 0.9603 -5.855138729 2.009622757 0 1 8.934514102 1.393119876 1 0.5528 -145.8629987 78.6583624.020575191 67 0.9603 -0.746073724 1.95141473 0 1 8.60073161 1.33491171 1 0.5528 3.392845143 76.650488934.010438095 67 0.9603 -1.925020568 1.808535148 0 1 6.192963213 1.192998059 1 0.5528 -105.6663359 74.379111494.122271412 67 0.9603 0.337891339 2.053280017 0 1 6.627247885 1.328594185 1 0.5528 -30.80877453 79.495133814.170985932 67 0.9603 -1.127789864 1.91711132 0 1 7.755441133 1.297806822 1 0.5528 -130.6135826 78.162823534.334547448 67 0.9603 0.683958268 2.132410468 0 1 8.641615205 1.436294292 1 0.5528 -102.4902899 80.282703953.975003696 67 0.9603 -2.684597784 2.044687711 0 1 7.444952087 1.364151776 1 0.5528 -214.482241 79.428827763.871885625 67 0.9603 -0.454308867 1.83724008 0 1 5.154358097 1.193270069 1 0.5528 -72.92531994 76.525000858.864342709 67 0.9603 -3.376767851 3.298902825 0 1 41.01663009 2.809127151 1 0.5528 -180.005325 92.302203843.813154011 67 0.9603 -1.487993333 1.859146586 0 1 6.129738916 1.241526129 1 0.5528 -269.3109923 77.98873714.401411225 67 0.9603 1.155420797 2.172242895 0 1 10.48866534 1.484488793 1 0.5528 -164.8139392 79.756014414.463114393 67 0.9603 0.779570651 2.080718268 0 1 11.38392703 1.497131239 1 0.5528 -196.0321338 79.907767983.982571622 67 0.9603 -0.594981986 1.979413029 0 1 6.188313141 1.303251446 1 0.5528 -60.32993664 78.930407954.491760465 67 0.9603 -2.267128721 2.010854611 0 1 8.293898152 1.381935596 1 0.5528 -102.9647461 79.619436174.079693915 67 0.9603 -8.828768535 2.104103354 0 1 10.08779314 1.566661359 1 0.5528 -88.71474833 82.098257434.056620104 67 0.9603 -0.935396712 2.33806635 0 1 4.594057861 1.469866693 1 0.5528 -23.73866507 82.680911294.052740636 67 0.9603 -2.577144443 2.065417948 0 1 9.653136098 1.426931258 1 0.5528 -66.32306717 78.35292784.050935511 67 0.9603 -0.586592421 2.111250956 0 1 4.360126411 1.263073441 1 0.5528 -232.2067778 80.994657654.069563304 67 0.9603 -0.290645779 2.099510241 0 1 6.829193561 1.333122147 1 0.5528 -140.6942576 80.174091473.95462925 67 0.9603 -1.36809155 2.062355446 0 1 6.247812866 1.336987326 1 0.5528 69.23958149 79.572494964.097512959 67 0.9603 -0.96481935 1.903278102 0 1 4.840337314 1.218473849 1 0.5528 -38.89347746 78.406642973.90023583 67 0.9603 -2.574846784 2.177975814 0 1 5.979202116 1.421620183 1 0.5528 -169.6780396 81.705413424.027396146 67 0.9603 -1.314296601 1.979313022 0 1 5.70808954 1.294782087 1 0.5528 -28.32613049 78.330759383.869034241 67 0.9603 1.276781947 1.995780754 0 1 5.564209461 1.242027619 1 0.5528 -60.42825239 79.865187234.068274605 67 0.9603 -1.043853326 1.980641918 0 1 6.220445328 1.290108602 1 0.5528 -118.9644322 77.807863023.977007737 67 0.9603 1.388878503 1.920966227 0 1 6.614117106 1.24201361 1 0.5528 -111.6819409 77.90829181415Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFMn +/- Mn Intercept Mn Slope Mo Mo +/- Mo Intercept Mo Slope Nb Nb +/- Nb Intercept Nb Slope Nd Nd +/-D.7 fp-XRF Soil Mode3.962374258 67 0.9603 0.334087811 2.05094909 0 1 4.399504907 1.257920697 1 0.5528 -112.2178469 80.458197163.978751979 67 0.9603 1.22885568 1.840632367 0 1 6.394272603 1.227042686 1 0.5528 -176.8836223 77.508311064.315938673 67 0.9603 1.693234444 1.975672196 0 1 7.853911676 1.305862099 1 0.5528 -166.6528031 76.885450194.082341011 67 0.9603 1.627629534 1.840485676 0 1 4.365879312 1.142231003 1 0.5528 -75.02796378 77.24287518.729977495 67 0.9603 2.716938362 3.420817547 0 1 43.27732484 2.916870123 1 0.5528 -5.597621339 95.946220534.093925809 67 0.9603 -1.992946319 1.854416382 0 1 6.68470906 1.260937839 1 0.5528 -67.02652906 77.123063994.199979137 67 0.9603 -2.860589814 1.952825107 0 1 6.323392461 1.278235554 1 0.5528 -115.4540015 77.713322133.931178233 67 0.9603 -2.945725856 1.791178117 0 1 5.735435817 1.221379088 1 0.5528 -118.2048139 76.955397973.608329758 67 0.9603 -1.400390017 1.828314063 0 1 3.921543372 1.074671937 1 0.5528 -80.28106299 74.768580263.448061586 67 0.9603 0.4429242 1.815170327 0 1 5.239259201 1.164857368 1 0.5528 -88.18421382 76.124929873.669033431 67 0.9603 -0.655586996 1.999123148 0 1 6.332528203 1.303211258 1 0.5528 -78.66273458 77.875080384.066091522 67 0.9603 -1.823235133 2.075536342 0 1 7.025046944 1.349413484 1 0.5528 -140.0687562 78.081459743.97404168 67 0.9603 -0.175943099 2.026979204 0 1 8.812437054 1.411148394 1 0.5528 -125.1982995 77.891737553.788632423 67 0.9603 -0.593177136 1.934748278 0 1 3.913528726 1.161959858 1 0.5528 -121.6284164 76.386209314.229715832 67 0.9603 1.112943063 2.088448387 0 1 9.249307673 1.388229421 1 0.5528 -164.3333937 77.815436884.099830083 67 0.9603 -3.610462086 2.032756046 0 1 6.131502613 1.317116608 1 0.5528 -63.36503528 80.431939283.950529308 67 0.9603 -4.311468576 2.00337249 0 1 6.271004872 1.325922276 1 0.5528 84.97585894 81.193761773.263415797 67 0.9603 0.335683733 1.707167349 0 1 2.542524967 1.016323654 1 0.5528 -151.2789479 74.265033353.374611447 67 0.9603 -3.384341664 1.748684751 0 1 2.608668912 1.066158416 1 0.5528 -57.60608841 75.629007322.736325128 67 0.9603 -2.291891102 2.328596475 0 1 1.27907147 1.38659905 1 0.5528 -143.8543323 89.34819433.771497517 67 0.9603 -4.550058663 2.046629293 0 1 5.165882481 1.328949405 1 0.5528 -70.20892235 79.457052053.631643394 67 0.9603 0.825760762 2.096970652 0 1 8.372428165 1.395719376 1 0.5528 -4.734385851 78.695568052.270981574 67 0.9603 0.187439974 2.074525365 0 1 1.779959777 1.618291743 1 0.5528 16.8308386 110.45914582.223096557 67 0.9603 4.445569819 2.149962105 0 1 3.90705564 1.65860985 1 0.5528 -225.2471078 103.29876493.924899608 67 0.9603 -2.758596564 1.925161842 0 1 6.918319265 1.286883939 1 0.5528 -75.23724898 77.399098723.849949502 67 0.9603 2.361208585 2.013771975 0 1 5.508088241 1.216935426 1 0.5528 -107.5692133 77.851773158.988221042 67 0.9603 -1.932810624 3.313868693 0 1 45.10150264 2.907117789 1 0.5528 -76.67409445 94.020048593.799074048 67 0.9603 1.309086485 2.02076976 0 1 5.729740506 1.266776713 1 0.5528 -131.6210926 77.769922283.909894868 67 0.9603 -1.782867666 1.858643 0 1 7.302950011 1.285817395 1 0.5528 59.68081619 76.100226443.966167675 67 0.9603 -0.693680803 2.138072425 0 1 5.155736762 1.326221075 1 0.5528 -56.29383001 81.86092083.283955365 67 0.9603 -2.820515454 2.778036279 0 1 4.154685559 1.814846072 1 0.5528 -109.196304 103.68021832.529822909 67 0.9603 2.791740486 2.049190736 0 1 4.006431594 1.528204514 1 0.5528 62.57083389 99.412163212.367780522 67 0.9603 1.284899262 2.040664487 0 1 0.39014486 1.500263358 1 0.5528 187.9988607 106.26303842.758953099 67 0.9603 0.66359409 2.354234889 0 1 2.983529298 1.775261237 1 0.5528 -39.49079787 107.63838613.739444261 67 0.9603 -1.106218039 1.983604449 0 1 6.612500451 1.321525533 1 0.5528 -130.5775683 78.125109373.480271023 67 0.9603 -3.957813068 1.934799695 0 1 6.790395207 1.322462142 1 0.5528 -138.5423043 79.082259183.729090845 67 0.9603 -2.762220529 1.899858728 0 1 8.808565512 1.333330769 1 0.5528 50.37356419 76.78634446416Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFMn +/- Mn Intercept Mn Slope Mo Mo +/- Mo Intercept Mo Slope Nb Nb +/- Nb Intercept Nb Slope Nd Nd +/-D.7 fp-XRF Soil Mode3.751315811 67 0.9603 0.54507511 2.021695963 0 1 6.325075737 1.313497026 1 0.5528 22.56477297 78.842730333.777323478 67 0.9603 -0.148325342 1.816043847 0 1 3.636006033 1.086419981 1 0.5528 -31.77659122 74.313546693.584830319 67 0.9603 -0.895905321 1.752890238 0 1 5.802193344 1.161882733 1 0.5528 40.92817466 74.515414363.693798451 67 0.9603 0.540183926 2.050743448 0 1 5.67190041 1.293078558 1 0.5528 18.35448297 78.475879872.23785219 67 0.9603 3.198381042 2.26042652 0 1 1.618694715 1.476023328 1 0.5528 -117.2282432 105.72100412.234763738 67 0.9603 1.73636372 2.288548481 0 1 1.025641939 1.668589706 1 0.5528 -220.9220885 114.36392053.595743225 67 0.9603 2.870884628 1.974900672 0 1 5.329316282 1.24234292 1 0.5528 -154.3329834 78.219369543.70904891 67 0.9603 -1.194811373 1.900222836 0 1 4.51780861 1.182523193 1 0.5528 -78.54757919 75.625216372.294760546 67 0.9603 -0.429570625 2.076288434 0 1 2.351536056 1.545513201 1 0.5528 -116.4539723 100.26322543.732410654 67 0.9603 -3.302793335 1.989941217 0 1 9.76532929 1.445480883 1 0.5528 -83.14572419 78.465352233.764401112 67 0.9603 -4.535986751 1.755025747 0 1 6.999015139 1.232583014 1 0.5528 -114.3774143 75.876092888.743555088 67 0.9603 -2.24880119 3.394686286 0 1 45.93847045 2.947704354 1 0.5528 39.41223944 95.230795823.708204956 67 0.9603 0.856787021 1.78534448 0 1 2.837032061 1.054412675 1 0.5528 -52.89523726 75.147172326.094973232 67 0.9603 3.173015587 1.984051495 0 1 6.771372564 1.334936948 1 0.5528 -221.2815752 82.844570984.267471482 67 0.9603 -1.674020033 2.006308953 0 1 6.974328091 1.288128361 1 0.5528 -25.12598233 76.800079073.955178515 67 0.9603 -2.223265184 2.044888779 0 1 8.16338954 1.3949651 1 0.5528 -185.1179099 79.275379613.992647884 67 0.9603 -0.446927869 1.966333076 0 1 8.574173307 1.350531217 1 0.5528 70.4765976 77.853752634.178730763 67 0.9603 1.409745706 2.048439695 0 1 5.422802488 1.299990845 1 0.5528 -176.1407049 79.600821354.199499269 67 0.9603 -1.026322727 2.04033187 0 1 7.380058479 1.361755818 1 0.5528 -51.64335342 77.786420543.793418131 67 0.9603 -3.714341539 1.838910149 0 1 5.448585017 1.243099245 1 0.5528 -106.5999953 76.105848752.18600305 67 0.9603 -3.016154357 2.233471184 0 1 0.299298922 1.703219734 1 0.5528 -89.51291007 108.53204954.268332745 67 0.9603 -2.114986522 2.047275267 0 1 13.42057119 1.564436545 1 0.5528 -3.848783785 79.892245524.33542526 67 0.9603 1.717673273 2.019751636 0 1 13.1562071 1.478138351 1 0.5528 -176.684413 77.735782183.990758034 67 0.9603 -1.790066549 1.939805811 0 1 5.952199926 1.257044023 1 0.5528 -85.3451615 78.801754443.702117394 67 0.9603 0.803815732 1.899748479 0 1 4.920354224 1.202471095 1 0.5528 -86.49989541 76.476412233.616471833 67 0.9603 -5.316944066 1.767137466 0 1 5.4035011 1.198433852 1 0.5528 -149.9157462 75.151936563.421389598 67 0.9603 -2.526613134 1.762731239 0 1 4.743330834 1.15367467 1 0.5528 -140.2864338 75.09683022417Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFNd Intercept Nd Slope Ni Ni +/- Ni Intercept Ni Slope P P +/- P Intercept P Slope Pb Pb +/- Pb Intercept0 1 19.32010207 5.265024709 0 1 158.9626697 980.3511877 0 1 12.12574646 1.103314986 00 1 14.77046107 5.265237507 0 1 2509.369362 1043.27912 0 1 12.08373659 1.120729149 00 1 14.60816768 6.109351092 0 1 6695.475571 1384.18865 0 1 11.40503072 1.276338185 00 1 -6.922838019 4.215530063 0 1 -3054.306034 625.6796769 0 1 1.693715371 0.745842026 00 1 5.178720814 5.005858718 0 1 928.895017 984.689119 0 1 13.16802902 1.101746224 00 1 15.86487194 5.30832462 0 1 1570.765444 1028.714891 0 1 13.42858201 1.144246291 00 1 26.51058824 5.456853655 0 1 2560.427029 1052.154922 0 1 12.58270424 1.135831737 00 1 18.22716697 5.333396749 0 1 4320.81792 1093.47308 0 1 10.80452313 1.10911194 00 1 9.837401636 5.266762653 0 1 2167.313039 1056.015333 0 1 10.71664633 1.104407867 00 1 13.32009933 5.243780896 0 1 3417.297942 1062.089059 0 1 10.88068905 1.098171599 00 1 3.564610839 5.178733674 0 1 885.5820765 1039.937978 0 1 12.16523767 1.124599993 00 1 9.224203928 5.196771423 0 1 1305.710835 1025.658269 0 1 11.93393852 1.121872794 00 1 14.06742491 5.294627916 0 1 930.2107661 1021.097693 0 1 10.60922012 1.093408582 00 1 31.75766338 6.896894989 0 1 11359.98157 1522.428131 0 1 21.66247668 1.658524245 00 1 14.14915001 5.290150053 0 1 -111.1663797 999.14203 0 1 12.55778594 1.130959162 00 1 25.36894477 5.390487172 0 1 3217.584779 1074.61813 0 1 12.48399604 1.136304985 00 1 12.65360368 5.184215824 0 1 2533.261744 1049.802916 0 1 11.9419793 1.104537707 00 1 18.28404056 5.335874088 0 1 3289.474477 1075.939229 0 1 13.78155486 1.155820837 00 1 25.00919216 5.325906975 0 1 2325.808547 1040.400084 0 1 13.08860878 1.127666605 00 1 17.89604862 5.346516385 0 1 3454.000664 1072.402031 0 1 12.25578319 1.1273962 00 1 8.356757958 5.228201177 0 1 2213.177471 1059.370543 0 1 12.15589726 1.125410268 00 1 10.72017884 5.872162783 0 1 8974.749092 1344.973395 0 1 9.409647078 1.196042677 00 1 12.59372487 5.10082595 0 1 1054.019026 980.2940723 0 1 11.43489427 1.080964059 00 1 16.50764253 5.32118766 0 1 1816.609549 1052.933876 0 1 12.02012748 1.139031938 00 1 20.62822277 5.462163496 0 1 1409.070696 1065.688398 0 1 10.70437764 1.121858856 00 1 8.970055122 5.155737098 0 1 1067.70531 1020.547553 0 1 11.73990305 1.098718771 00 1 9.611959121 5.244387766 0 1 185.0641271 1016.486662 0 1 10.91938124 1.097018639 00 1 15.50828461 5.248832423 0 1 2874.869178 1043.326804 0 1 11.41078762 1.102311934 00 1 10.33639818 5.265662137 0 1 4202.240739 1100.100969 0 1 11.10654444 1.101662276 00 1 15.08004252 5.181448207 0 1 -691.4781439 952.0329415 0 1 12.95109814 1.115554837 00 1 23.12459053 5.545149301 0 1 1458.815551 1074.198219 0 1 12.13156627 1.143614004 00 1 -14.80931785 4.365419722 0 1 -1191.786157 753.7667529 0 1 8.088469889 0.915535093 00 1 12.41884155 5.032160455 0 1 866.1131045 960.4489215 0 1 10.85297832 1.044119422 00 1 -11.60931924 4.450313272 0 1 -5223.930506 513.3177066 0 1 -0.528520995 0.688907899 00 1 -19.03015442 4.166888258 0 1 -5249.454261 481.8698166 0 1 -1.324824216 0.653332073 00 1 20.37471322 6.779179204 0 1 6106.935227 1418.820608 0 1 19.92226611 1.631501147 00 1 -16.22316654 4.213135393 0 1 -5359.62047 482.2286447 0 1 -1.504509327 0.65062267 00 1 -15.09972797 4.134298863 0 1 -3599.551835 598.6012008 0 1 1.843900646 0.748331874 0D.7 fp-XRF Soil Mode418Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFNd Intercept Nd Slope Ni Ni +/- Ni Intercept Ni Slope P P +/- P Intercept P Slope Pb Pb +/- Pb InterceptD.7 fp-XRF Soil Mode0 1 2.709120046 4.941020819 0 1 1115.637198 968.133256 0 1 12.26287075 1.076296364 00 1 5.881087452 5.167265819 0 1 1968.183004 1058.77228 0 1 9.150412519 1.072217792 00 1 9.85208313 5.10413907 0 1 2445.853351 1011.872639 0 1 9.76975311 1.04831987 00 1 11.30750963 5.181707669 0 1 2621.982873 1057.491369 0 1 12.07713127 1.103916246 00 1 -0.120093494 5.017653493 0 1 728.6594448 999.1027591 0 1 11.6696191 1.092252258 00 1 14.61764069 5.288397043 0 1 2676.406333 1050.275989 0 1 12.78739617 1.135249033 00 1 10.21995772 5.19914305 0 1 169.6575127 1004.424833 0 1 12.54531369 1.121463466 00 1 19.65182393 5.37136472 0 1 1899.907307 1053.099899 0 1 13.32173636 1.149899318 00 1 5.928166428 5.211251281 0 1 2519.896999 1048.825332 0 1 10.88033615 1.094661155 00 1 19.92875097 5.312126484 0 1 1495.690655 1030.347462 0 1 12.05010042 1.119403236 00 1 12.02167095 5.261948769 0 1 1279.552408 1024.496634 0 1 12.75813344 1.126708994 00 1 17.24134521 5.374303078 0 1 1858.169799 1065.622129 0 1 10.64245319 1.107707311 00 1 23.64505853 5.390909166 0 1 1318.849127 1025.933766 0 1 10.30314036 1.087357271 00 1 17.11843066 5.288504248 0 1 2937.382596 1068.150964 0 1 11.58890407 1.111299369 00 1 17.07238784 5.381550763 0 1 1634.484231 1056.937332 0 1 10.76276825 1.115917115 00 1 14.44219714 5.342776276 0 1 1602.62688 1055.946184 0 1 11.20138713 1.127524297 00 1 34.35125968 5.6802933 0 1 1910.300005 1087.446834 0 1 11.85651076 1.14329552 00 1 15.46167667 5.314068573 0 1 1581.452821 1027.909043 0 1 13.60420777 1.145137022 00 1 0.38930341 5.060050599 0 1 1491.254147 999.8212991 0 1 12.15555869 1.09656081 00 1 17.63362542 6.719018839 0 1 12181.81051 1551.670175 0 1 20.80301303 1.650170612 00 1 7.321292218 5.13856271 0 1 2077.265635 1012.747958 0 1 10.76953782 1.074785145 00 1 24.96336269 5.477740433 0 1 2725.564779 1087.060082 0 1 11.4168519 1.118384334 00 1 22.76064635 5.466770134 0 1 4193.662207 1111.898262 0 1 13.23065507 1.157520205 00 1 7.561102519 5.256867742 0 1 207.1446333 1008.91928 0 1 11.35205418 1.103856262 00 1 27.84182583 5.458792274 0 1 1910.18465 1049.88849 0 1 11.78741987 1.117913261 00 1 25.28698372 5.422136883 0 1 1095.832845 1018.916798 0 1 12.92346845 1.152721653 00 1 8.12672454 5.235006854 0 1 1933.426731 1047.357381 0 1 12.66076292 1.138229731 00 1 2.799678764 5.183768135 0 1 796.2443056 1027.010746 0 1 12.23757117 1.132229861 00 1 5.965034156 5.215961502 0 1 3569.83049 1086.909321 0 1 10.01593923 1.083271937 00 1 18.73578237 5.350718649 0 1 1455.705004 1046.845684 0 1 11.63158716 1.107068912 00 1 6.132845212 5.232432889 0 1 801.5610812 1034.117499 0 1 10.53570486 1.09825414 00 1 11.01233591 5.285379932 0 1 2092.458866 1071.819168 0 1 11.65135875 1.113349992 00 1 6.747984712 5.201242984 0 1 1835.336906 1040.707977 0 1 10.4958174 1.083792399 00 1 18.7102233 5.278703987 0 1 1199.747966 1025.419592 0 1 13.76800844 1.141337759 00 1 8.608495803 5.190265659 0 1 1592.436861 1036.480245 0 1 12.43823432 1.109342244 00 1 -5.975914201 5.06361772 0 1 1915.13885 1059.782076 0 1 12.66962345 1.130844468 00 1 15.29338726 5.30841201 0 1 1076.573587 1030.274644 0 1 12.19368726 1.119697404 0419Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFNd Intercept Nd Slope Ni Ni +/- Ni Intercept Ni Slope P P +/- P Intercept P Slope Pb Pb +/- Pb InterceptD.7 fp-XRF Soil Mode0 1 4.018340527 5.189527552 0 1 1897.538735 1046.018436 0 1 11.4674661 1.119135928 00 1 13.42667578 5.312536146 0 1 1323.453089 1030.530879 0 1 10.49661895 1.080409641 00 1 6.670250313 5.290671597 0 1 3033.787639 1096.177954 0 1 12.27236173 1.143409682 00 1 16.56357315 5.414344425 0 1 911.1870043 1027.375088 0 1 14.31614701 1.1774699 00 1 35.87090718 6.954870633 0 1 9198.685875 1476.660808 0 1 21.98473464 1.674467776 00 1 16.58978657 5.363620715 0 1 -208.7102675 1005.715856 0 1 12.12508885 1.130323962 00 1 13.86080251 5.350650458 0 1 3021.233175 1081.910142 0 1 11.55826621 1.137887755 00 1 9.706822801 5.190551623 0 1 258.2325101 996.8606322 0 1 12.6466774 1.101972918 00 1 3.375520089 5.046763247 0 1 2116.668756 1013.560392 0 1 11.53689619 1.091033805 00 1 5.933967196 4.985958916 0 1 -300.9939203 932.9556736 0 1 12.43776537 1.0835387 00 1 2.745443185 4.81947782 0 1 -816.4864565 910.9518887 0 1 10.74067245 1.029280715 00 1 11.40441631 5.253934976 0 1 1696.718519 1044.582365 0 1 13.92204205 1.152044871 00 1 26.45134749 5.409129216 0 1 2521.530297 1060.595837 0 1 13.08059898 1.135770473 00 1 4.637028774 5.106129838 0 1 2441.714874 1045.498124 0 1 12.84186495 1.113475888 00 1 8.091078777 5.307742238 0 1 2115.652875 1064.887834 0 1 11.90509624 1.152601997 00 1 14.00030408 5.303503217 0 1 3306.841677 1085.179407 0 1 12.01461878 1.119554394 00 1 6.753520296 5.089500481 0 1 596.310219 999.4078104 0 1 12.05252351 1.105873304 00 1 -0.265885255 4.859938621 0 1 34.21116655 918.749215 0 1 12.66460571 1.078718285 00 1 -0.169724562 4.862233986 0 1 -332.6762099 928.1393542 0 1 12.42787139 1.070583954 00 1 -14.43585498 4.416211834 0 1 -4490.084985 707.5775159 0 1 9.469982351 0.956906981 00 1 7.546923959 4.977252558 0 1 446.6158276 951.0399136 0 1 13.95213823 1.108946917 00 1 5.816608087 4.982884803 0 1 1212.953917 967.695545 0 1 10.62182579 1.053209219 00 1 -23.14510542 4.181263843 0 1 -4553.557832 509.0327326 0 1 0.280656036 0.700015549 00 1 -4.6787122 4.164931799 0 1 -3465.713254 558.93019 0 1 1.525455985 0.717822376 00 1 2.306629829 5.11001163 0 1 2225.950109 1044.909387 0 1 11.29837037 1.100968688 00 1 12.37526468 5.168630037 0 1 667.2173577 1010.270799 0 1 9.734716596 1.057861964 00 1 31.28539858 6.913957314 0 1 6296.951989 1433.670419 0 1 21.77457901 1.679302743 00 1 6.417982023 5.089755045 0 1 521.6510418 995.5875768 0 1 12.03224989 1.101620926 00 1 4.313655666 5.060737925 0 1 3379.65298 1051.859807 0 1 9.318139141 1.049773018 00 1 2.526601643 5.11139127 0 1 1455.710032 1020.338131 0 1 13.16285998 1.125414796 00 1 -20.48734075 4.506854878 0 1 -1703.852059 733.0526802 0 1 9.808248496 1.010933896 00 1 -8.298648876 4.186642338 0 1 -3379.29649 620.6007712 0 1 2.300349627 0.747337645 00 1 -10.51271411 4.325420717 0 1 -3599.29874 578.2667052 0 1 -0.573250696 0.699214548 00 1 -3.708564246 4.506552354 0 1 -2135.972897 690.5277358 0 1 1.896615577 0.784417383 00 1 1.720760279 4.981947935 0 1 167.8159263 980.4337644 0 1 11.90182707 1.088909249 00 1 1.162832484 4.881450078 0 1 -1614.315371 904.4409969 0 1 10.52015533 1.041613344 00 1 -6.82853546 4.947207595 0 1 -332.5504837 982.6305186 0 1 10.99113947 1.082477973 0420Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFNd Intercept Nd Slope Ni Ni +/- Ni Intercept Ni Slope P P +/- P Intercept P Slope Pb Pb +/- Pb InterceptD.7 fp-XRF Soil Mode0 1 9.32122027 5.140969746 0 1 1647.456541 1010.245909 0 1 13.20977932 1.12897865 00 1 9.471929212 5.125986393 0 1 3349.593305 1058.091575 0 1 10.79282621 1.088125694 00 1 5.271279632 5.019713381 0 1 113.7923135 964.1350741 0 1 12.6072202 1.094481579 00 1 14.71981304 5.09500522 0 1 2239.683333 1005.060793 0 1 13.95749927 1.122379828 00 1 -9.086781962 4.40933046 0 1 -6064.334745 513.7687433 0 1 0.685045899 0.73747884 00 1 -11.28654863 4.415449461 0 1 -5476.871366 510.1348774 0 1 -0.78773109 0.686707089 00 1 -1.388468138 4.90143704 0 1 789.663882 962.6616785 0 1 10.14370183 1.042609033 00 1 1.722930004 4.933521526 0 1 -14.04062418 955.4272002 0 1 10.83935365 1.068537494 00 1 -4.812818788 4.332059116 0 1 -4464.314226 539.6421627 0 1 2.774330504 0.770472527 00 1 14.57353735 5.097955595 0 1 1625.134539 985.571654 0 1 12.34642712 1.089139423 00 1 6.702022831 5.021212696 0 1 2035.624329 1006.133011 0 1 10.96633002 1.077014383 00 1 19.28465395 6.777397354 0 1 8320.632252 1459.402189 0 1 22.99496144 1.693329042 00 1 8.297357903 5.052216718 0 1 -374.6534356 951.0713837 0 1 11.49553707 1.073601831 00 1 17.98964502 5.746017221 0 1 4386.686206 1247.314768 0 1 12.77353292 1.218279341 00 1 10.16212322 5.231867841 0 1 1906.932181 1053.140944 0 1 9.829333133 1.087097755 00 1 21.20801169 5.360075747 0 1 1788.497768 1045.004029 0 1 13.8558099 1.151389762 00 1 15.48693186 5.2483777 0 1 751.1239937 1013.411606 0 1 11.56320067 1.102409715 00 1 7.956974616 5.198207169 0 1 1392.239663 1035.631663 0 1 13.14954686 1.144061072 00 1 21.16928349 5.372106092 0 1 4160.699906 1099.181058 0 1 11.09667591 1.108844562 00 1 16.81095155 5.233014925 0 1 1824.53118 1009.908729 0 1 11.66546305 1.089810118 00 1 -10.97962174 4.29804972 0 1 -3897.258231 515.2115645 0 1 -0.131976676 0.710911246 00 1 16.99487501 5.410665232 0 1 1330.316765 1047.989772 0 1 11.42409872 1.123408309 00 1 38.50406249 5.662255611 0 1 1789.699938 1057.69208 0 1 10.39950271 1.111193767 00 1 11.0953013 5.325760133 0 1 921.1674276 1033.174775 0 1 12.26144741 1.139604998 00 1 4.272690299 5.012566721 0 1 1873.02227 1012.452847 0 1 11.38492279 1.083945223 00 1 13.94521538 5.096693784 0 1 24.74938102 954.9354034 0 1 12.45150122 1.093298362 00 1 -1.448536302 4.832141753 0 1 721.3955614 949.4102389 0 1 12.685071 1.077728113 0421Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFPb Slope Pr Pr +/- Pr Intercept Pr Slope Rb Rb +/- Rb Intercept Rb Slope S S +/- S Intercept S Slope1 -106.3805315 45.63411054 0 1 51.15730954 0.938933969 -2 0.9644 113.8249405 117.357046 0 11 -107.5253454 46.5048144 0 1 49.76195084 0.940027817 -2 0.9644 -29.56370223 116.3206792 0 11 -157.9449918 48.98169739 0 1 49.60575616 1.017861471 -2 0.9644 -45.37703153 185.8534202 0 11 -151.3537574 60.65202717 0 1 15.41524993 0.520532819 -2 0.9644 6324.857526 202.5708018 0 11 -125.4622782 47.63018842 0 1 49.43147508 0.919336252 -2 0.9644 547.2146438 129.9732114 0 11 -152.5507939 45.9525453 0 1 56.36926186 0.988424451 -2 0.9644 51.7632597 117.0775644 0 11 -135.3932844 45.61943114 0 1 54.94593564 0.980004473 -2 0.9644 -262.2962501 108.3418608 0 11 -145.0749928 45.76829698 0 1 55.98161507 0.992230031 -2 0.9644 112.8640811 124.2486569 0 11 -122.1931693 45.71385413 0 1 56.26883004 0.993130495 -2 0.9644 -14.85640432 119.7102422 0 11 -92.65823563 47.04653969 0 1 55.59082032 0.981910015 -2 0.9644 220.7966407 125.4126704 0 11 -117.8038731 46.77530178 0 1 55.99845954 0.989386683 -2 0.9644 277.4999728 131.8718566 0 11 -145.1510289 45.5828513 0 1 55.29477601 0.982884838 -2 0.9644 254.4978971 127.9812687 0 11 -212.5199227 47.27969229 0 1 54.45341206 0.977415611 -2 0.9644 209.8412529 125.6923797 0 11 89.72693115 58.6511813 0 1 61.36286187 1.158453831 -2 0.9644 416.7691125 249.6987695 0 11 -69.12412446 47.04512731 0 1 55.7942132 0.987302725 -2 0.9644 321.5531292 129.1855683 0 11 -161.0183372 46.03188176 0 1 56.62493038 0.988715199 -2 0.9644 3.193238261 120.7986102 0 11 -150.9056939 45.86414315 0 1 54.88978428 0.968995063 -2 0.9644 125.7189941 122.83182 0 11 -153.9240748 45.44845308 0 1 58.0435741 1.007089679 -2 0.9644 -111.2865434 117.9099937 0 11 -150.9821412 45.86644228 0 1 54.29531058 0.96198533 -2 0.9644 64.85469194 118.5320236 0 11 -115.4366062 46.39354726 0 1 55.29477631 0.986474626 -2 0.9644 136.4813846 123.7847465 0 11 -188.5452372 46.32401674 0 1 51.65050483 0.954253454 -2 0.9644 485.4325805 139.1193862 0 11 -102.7894228 51.50280393 0 1 42.03056631 0.921854125 -2 0.9644 1245.367962 214.2509454 0 11 -95.4633362 45.35137462 0 1 49.70604589 0.917718211 -2 0.9644 76.84963853 114.8468004 0 11 -215.8261556 46.61106474 0 1 56.13691844 0.993105537 -2 0.9644 312.4985502 131.5510105 0 11 -95.49444353 46.50972363 0 1 55.86933719 1.004318671 -2 0.9644 92.07828035 129.0392892 0 11 -160.357737 47.48290176 0 1 53.10011816 0.958240219 -2 0.9644 139.0138548 125.4917922 0 11 -71.46598315 46.81654067 0 1 54.68570848 0.977572283 -2 0.9644 165.5571789 127.9101909 0 11 -143.8516809 46.50449771 0 1 54.78961571 0.975233276 -2 0.9644 231.4089145 124.4037606 0 11 -163.821502 47.023565 0 1 52.34683666 0.959007715 -2 0.9644 305.8032928 132.5315645 0 11 -116.9222039 46.2789833 0 1 51.40480725 0.937210662 -2 0.9644 191.9293453 118.4546233 0 11 -112.2993772 48.51025402 0 1 62.9068597 1.056122033 -2 0.9644 270.9147828 138.6693706 0 11 -79.51746952 58.43375968 0 1 29.70411454 0.699379145 -2 0.9644 4555.403368 191.7341881 0 11 -99.17879956 45.1301347 0 1 47.07679643 0.890842726 -2 0.9644 274.6651805 114.6790609 0 11 -68.43076372 70.04014176 0 1 5.927842918 0.411132899 -2 0.9644 5812.882903 182.8187764 0 11 40.75860895 66.98450788 0 1 3.741425443 0.367595092 -2 0.9644 4026.849774 151.7144083 0 11 -60.99011297 57.32779544 0 1 63.85637875 1.181940035 -2 0.9644 814.3887659 259.8911098 0 11 -4.962722905 67.2763997 0 1 4.321840059 0.373422157 -2 0.9644 4073.248514 152.740269 0 11 -51.55363081 61.61433007 0 1 22.62860344 0.597079626 -2 0.9644 3883.048061 164.7310689 0 1D.7 fp-XRF Soil Mode422Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFPb Slope Pr Pr +/- Pr Intercept Pr Slope Rb Rb +/- Rb Intercept Rb Slope S S +/- S Intercept S SlopeD.7 fp-XRF Soil Mode1 -80.75448593 48.46839859 0 1 51.19862969 0.924609213 -2 0.9644 397.0020739 121.2317971 0 11 -147.1803736 48.16515704 0 1 55.90364475 0.988611971 -2 0.9644 115.0354747 122.8891471 0 11 -179.3946116 48.2810505 0 1 52.73573761 0.945864839 -2 0.9644 955.0181886 142.6449813 0 11 -230.3896039 46.38232429 0 1 56.17575823 0.97786341 -2 0.9644 144.3792107 124.788177 0 11 -204.9922862 49.51684037 0 1 54.05166929 0.96357562 -2 0.9644 4.62316598 116.5604355 0 11 -60.43176972 46.75485585 0 1 53.12760861 0.968729887 -2 0.9644 109.875002 122.0755756 0 11 -178.036137 46.19496253 0 1 52.09231673 0.954810696 -2 0.9644 109.0622798 121.679382 0 11 -114.010548 47.2933875 0 1 59.6593641 1.0178944 -2 0.9644 349.7169304 135.1604774 0 11 -120.3869971 46.70895576 0 1 50.50537927 0.941842785 -2 0.9644 9.067471685 122.4142991 0 11 -153.3811736 47.40336799 0 1 55.98798795 0.985308844 -2 0.9644 3.773942916 119.9709504 0 11 -147.6363504 48.09006414 0 1 55.137728 0.981485194 -2 0.9644 19.38864507 119.2316687 0 11 -136.7578869 47.83410918 0 1 56.80725813 0.999784195 -2 0.9644 314.531317 135.1319629 0 11 -141.4366597 46.85493466 0 1 56.60369231 0.993707429 -2 0.9644 117.2921423 123.7326911 0 11 -80.88387666 45.09303216 0 1 57.06897536 0.991443756 -2 0.9644 -71.94280642 117.5958645 0 11 -126.3005988 48.42103255 0 1 56.56889704 0.998421849 -2 0.9644 192.3114329 130.9489159 0 11 -129.5826685 47.74510213 0 1 55.40382092 0.99405189 -2 0.9644 -72.91048916 119.3729764 0 11 -130.5918657 49.01132332 0 1 58.24815081 1.024417847 -2 0.9644 39.76582728 127.8997849 0 11 -110.9478279 48.3166547 0 1 52.39613951 0.958677213 -2 0.9644 -23.72558052 117.9158601 0 11 -142.3029566 47.08649747 0 1 51.2899233 0.944585099 -2 0.9644 224.7598314 121.3633846 0 11 -30.47649139 56.48826881 0 1 62.31872295 1.162619218 -2 0.9644 813.2765504 261.8690656 0 11 -176.1054346 47.44406694 0 1 52.96046674 0.958111922 -2 0.9644 133.1304523 118.9442392 0 11 -142.9989257 48.25105414 0 1 60.29789905 1.02554821 -2 0.9644 245.0374548 134.5272869 0 11 -63.86684838 48.99856671 0 1 59.3247799 1.018877112 -2 0.9644 -60.41172931 125.9288885 0 11 -168.484428 48.01570889 0 1 55.08482426 0.98568896 -2 0.9644 77.64047062 122.422464 0 11 -224.035317 48.47231655 0 1 58.77546609 1.006197967 -2 0.9644 48.49430166 125.8653921 0 11 -15.23208418 49.83403503 0 1 54.8366118 0.983284347 -2 0.9644 291.7006197 130.1973209 0 11 -142.1236169 50.38550338 0 1 54.23431914 0.979543606 -2 0.9644 -17.48132421 119.4663774 0 11 -153.0410864 47.77793358 0 1 54.77053492 0.985879419 -2 0.9644 120.5042111 125.1435507 0 11 -195.8193381 48.9700508 0 1 53.83315561 0.977942173 -2 0.9644 183.7642357 127.2368122 0 11 -154.3030458 48.45357305 0 1 57.04251253 0.995472611 -2 0.9644 69.42721558 123.1645206 0 11 -38.49918206 48.37027799 0 1 53.60043561 0.980087888 -2 0.9644 38.31637222 120.1941551 0 11 -22.94468201 47.72439216 0 1 53.88165646 0.975208861 -2 0.9644 112.7735385 125.1684577 0 11 -92.97537639 49.75724865 0 1 53.20267676 0.96606126 -2 0.9644 21.12227782 118.4854115 0 11 -143.3689389 47.60398012 0 1 53.94182831 0.967222408 -2 0.9644 115.9629704 121.8584685 0 11 -66.7073798 48.70294895 0 1 52.63176532 0.954306002 -2 0.9644 232.6624975 126.8181882 0 11 -145.2773866 47.27415306 0 1 52.7209464 0.969925207 -2 0.9644 173.1820033 126.3680573 0 11 -148.577642 46.88040309 0 1 55.23573446 0.98190453 -2 0.9644 8.107750913 119.8303434 0 1423Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFPb Slope Pr Pr +/- Pr Intercept Pr Slope Rb Rb +/- Rb Intercept Rb Slope S S +/- S Intercept S SlopeD.7 fp-XRF Soil Mode1 -157.5907873 48.81823327 0 1 52.01021678 0.965525313 -2 0.9644 170.710998 124.6330613 0 11 -125.6925723 47.23598488 0 1 57.08490361 0.998646216 -2 0.9644 226.0367477 128.2358445 0 11 -122.1118288 46.49849158 0 1 59.25508278 1.026503938 -2 0.9644 -79.11696613 122.2120123 0 11 -153.3839856 47.07147078 0 1 56.43007732 1.002177091 -2 0.9644 289.70097 133.4757711 0 11 -169.637922 57.99652922 0 1 63.71607134 1.174591146 -2 0.9644 230.2800783 244.2159132 0 11 -99.71666528 46.63247013 0 1 55.08071755 0.984514722 -2 0.9644 280.8069807 133.2896292 0 11 -147.5107995 47.21709946 0 1 62.06359803 1.043422885 -2 0.9644 38.77078022 125.4118723 0 11 -141.2935026 46.67873739 0 1 53.74328586 0.966308372 -2 0.9644 -97.30176365 114.0939571 0 11 -165.6825164 45.1776486 0 1 51.04032061 0.934734884 -2 0.9644 50.13807839 114.2042161 0 11 -170.8186354 46.62223301 0 1 48.48265359 0.908284612 -2 0.9644 755.7896272 130.4475629 0 11 -69.43117826 47.23845815 0 1 47.85912321 0.883626863 -2 0.9644 1322.180496 145.5922753 0 11 -100.4461937 47.41772657 0 1 55.29410752 0.985506418 -2 0.9644 392.2049662 131.9260469 0 11 -135.6784744 47.70055775 0 1 53.92702073 0.972774413 -2 0.9644 176.1711412 125.4423679 0 11 -53.16340927 46.5793055 0 1 49.02174799 0.927486129 -2 0.9644 205.2525374 124.453164 0 11 -94.82892071 47.83615947 0 1 56.0610321 1.000719018 -2 0.9644 -28.30878047 121.86102 0 11 -177.7389814 48.92908182 0 1 55.69550239 0.985956758 -2 0.9644 -28.94440712 121.4408348 0 11 -63.38947651 48.93336716 0 1 56.7087475 0.979604874 -2 0.9644 278.1327704 126.8802961 0 11 -146.7039622 45.0957795 0 1 48.32161625 0.900415832 -2 0.9644 187.6656754 108.39259 0 11 -125.9622035 45.93564918 0 1 47.48948344 0.893871653 -2 0.9644 151.8835507 109.9471153 0 11 -71.69014272 54.63169542 0 1 37.4854628 0.775853195 -2 0.9644 2176.11025 150.0158483 0 11 -143.706585 48.50245591 0 1 52.97522975 0.937896428 -2 0.9644 930.7410475 138.7024124 0 11 -139.7692293 48.16413162 0 1 50.36973739 0.92084212 -2 0.9644 609.1967275 129.3733186 0 11 59.17523698 67.99328926 0 1 8.998823987 0.44503099 -2 0.9644 4614.252002 162.8619756 0 11 -22.59571069 62.64456544 0 1 12.725196 0.478884751 -2 0.9644 5913.837761 181.3183206 0 11 -126.8984216 47.10262789 0 1 53.72074211 0.97032819 -2 0.9644 168.1526673 123.6588831 0 11 -136.9735335 47.4704754 0 1 51.45529425 0.942649608 -2 0.9644 96.58290656 119.7260949 0 11 -31.23903661 56.86132647 0 1 61.88162375 1.165624289 -2 0.9644 188.8707848 247.6044523 0 11 -139.5048764 47.03562511 0 1 52.31251985 0.948977724 -2 0.9644 50.73486728 116.4603851 0 11 -69.07163058 46.62069771 0 1 51.89322514 0.946470727 -2 0.9644 155.1343267 122.1836082 0 11 -168.5195211 49.67986909 0 1 55.22180237 0.976733155 -2 0.9644 401.6025494 130.2639464 0 11 -34.39006238 63.68175675 0 1 42.45784312 0.828864119 -2 0.9644 2359.002589 154.909075 0 11 -56.91726265 60.52673431 0 1 20.65915448 0.571213316 -2 0.9644 4679.90085 177.091862 0 11 -13.33082098 64.50755767 0 1 13.08675589 0.498818499 -2 0.9644 6834.522895 200.1026689 0 11 -57.96670342 65.44055553 0 1 18.01695539 0.574466648 -2 0.9644 4671.743038 187.125295 0 11 -109.5350757 47.53189802 0 1 51.48760509 0.933710582 -2 0.9644 419.1715951 126.1978842 0 11 -106.4822707 48.41058408 0 1 49.30435605 0.904725445 -2 0.9644 366.2447968 118.7039087 0 11 -189.1625418 46.64930368 0 1 56.70280368 0.986551946 -2 0.9644 251.2677709 123.412983 0 1424Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFPb Slope Pr Pr +/- Pr Intercept Pr Slope Rb Rb +/- Rb Intercept Rb Slope S S +/- S Intercept S SlopeD.7 fp-XRF Soil Mode1 -207.3324128 47.86717368 0 1 57.04620506 0.985313722 -2 0.9644 33.6150066 116.1367852 0 11 -101.779368 45.12357731 0 1 50.6646852 0.937078753 -2 0.9644 209.1857436 123.9502267 0 11 -129.8390369 45.53177303 0 1 48.11999648 0.912860291 -2 0.9644 68.1770937 111.7541684 0 11 -202.0959364 47.76700149 0 1 54.01504797 0.945695884 -2 0.9644 669.111638 131.8729648 0 11 9.185913304 64.58840023 0 1 12.79991098 0.511559962 -2 0.9644 8030.543782 217.13011 0 11 32.60203674 69.42954986 0 1 7.793024591 0.433637447 -2 0.9644 9580.780827 232.707332 0 11 -36.94892385 47.7730696 0 1 49.92602749 0.916196952 -2 0.9644 517.5755027 125.6916964 0 11 -216.7581428 45.72147287 0 1 48.00638187 0.905893669 -2 0.9644 1108.150915 144.1600428 0 11 -115.6193533 60.99776295 0 1 12.57911727 0.496232124 -2 0.9644 6487.985696 194.4467627 0 11 -118.2511038 47.4423717 0 1 51.37209255 0.928201253 -2 0.9644 1458.488668 154.44248 0 11 -166.2944802 45.90068752 0 1 50.55264442 0.925577941 -2 0.9644 103.8046505 114.8005633 0 11 -103.8404244 57.89032205 0 1 64.03905486 1.182158634 -2 0.9644 374.5796277 248.3195575 0 11 -65.38276048 45.39251292 0 1 50.68412172 0.927185576 -2 0.9644 14.85625353 110.9300482 0 11 -208.444855 50.55890294 0 1 55.84020574 1.031576885 -2 0.9644 181.3264681 158.4764404 0 11 -131.4010164 46.54233559 0 1 57.95181951 1.005265848 -2 0.9644 -69.28039939 118.7145151 0 11 -203.5243708 48.66007953 0 1 55.60932412 0.982531485 -2 0.9644 46.52013975 121.3681984 0 11 -130.4636698 47.39067117 0 1 53.63868522 0.963766942 -2 0.9644 107.0183926 121.9132629 0 11 -138.5401843 48.22863393 0 1 54.46035713 0.976908981 -2 0.9644 181.3055206 127.0717676 0 11 -92.2193438 47.26926548 0 1 56.95355862 0.996792492 -2 0.9644 208.7655327 129.776868 0 11 -189.2766681 46.30083621 0 1 49.96737115 0.928556927 -2 0.9644 295.6389197 124.1605476 0 11 -59.29197074 66.09897798 0 1 8.955475844 0.451388234 -2 0.9644 5902.159121 181.3232649 0 11 -172.0953989 48.80324423 0 1 63.35957628 1.053100173 -2 0.9644 -82.33782597 123.4706628 0 11 -148.3006407 47.26371783 0 1 60.57776571 1.035374752 -2 0.9644 349.4384889 135.3309521 0 11 -180.2458735 47.87917939 0 1 53.94232711 0.981492971 -2 0.9644 -2.911682871 119.5053498 0 11 -149.1703719 46.18344819 0 1 47.98186459 0.913131306 -2 0.9644 10.75579816 111.6250189 0 11 -162.1130621 46.03328062 0 1 49.97351603 0.916944659 -2 0.9644 435.520593 122.2817739 0 11 -113.8147473 45.79958257 0 1 49.69854603 0.906818449 -2 0.9644 766.9434147 130.0013835 0 1425Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSb Sb +/- Sb Intercept Sb Slope Se Se +/- Se Intercept Se Slope Sn Sn +/- Sn Intercept Sn Slope Sr3.140352937 3.458863895 0 1 -0.276342828 0.513408093 0 1 -0.270225069 3.187947504 0 1 298.71668311.888264342 3.615658036 0 1 0.044123731 0.517258843 0 1 0.902862669 3.340602802 0 1 311.2472143-1.854812326 3.710643559 0 1 -0.079645957 0.586559714 0 1 2.408775992 3.464864531 0 1 273.5819378-0.252152588 5.476903684 0 1 -2.277159535 0.364675479 0 1 -4.336421673 5.146256587 0 1 114.9218284-2.185904659 3.776997025 0 1 -1.164938078 0.471563165 0 1 -2.48626523 3.530057395 0 1 331.16664121.242911544 3.537375447 0 1 -0.069457084 0.520822647 0 1 -2.43335063 3.283405065 0 1 312.195582-0.58603828 3.422421093 0 1 -0.00345428 0.523133919 0 1 5.51839184 3.199593581 0 1 286.58450162.551100702 3.490218208 0 1 0.151598707 0.528253039 0 1 2.16275139 3.215475718 0 1 298.11798250.936924692 3.519860376 0 1 0.058405688 0.533444134 0 1 -5.174675353 3.27959722 0 1 289.6016487-1.626040401 3.592067437 0 1 -0.632217638 0.511117412 0 1 1.208432885 3.385951609 0 1 309.8996398-2.232640244 3.539720135 0 1 -1.401715402 0.497096959 0 1 -0.286541471 3.32821941 0 1 300.21091513.616182955 3.471919347 0 1 -1.264427223 0.498928137 0 1 2.857022144 3.225077689 0 1 313.1036837-0.664813844 3.669519807 0 1 0.038468376 0.517858277 0 1 5.073165339 3.366793864 0 1 317.7062779-1.595057326 4.7028458 0 1 0.294488656 0.669716158 0 1 10.19533323 4.470841196 0 1 58.337725230.279371864 3.659153627 0 1 -0.891120163 0.502212782 0 1 5.6619741 3.414198077 0 1 309.92389750.440075121 3.557765826 0 1 -0.165089724 0.523252559 0 1 1.069221524 3.313557909 0 1 308.75494760.349086247 3.545804827 0 1 -0.421011219 0.503789906 0 1 4.159562134 3.309117089 0 1 315.26027694.961900801 3.500714255 0 1 -1.876973633 0.483045805 0 1 6.264434228 3.248528768 0 1 294.77900696.033368157 3.506374776 0 1 -0.4411683 0.507666061 0 1 7.383408274 3.247070414 0 1 302.32382032.865970631 3.570029516 0 1 -0.71138505 0.506584073 0 1 6.650128142 3.342577911 0 1 295.56720243.142109315 3.566064671 0 1 -1.014419089 0.49777824 0 1 1.811126188 3.305977189 0 1 289.85913620.933724469 4.077738087 0 1 -1.559662624 0.535501046 0 1 -3.027225374 3.783675801 0 1 263.88268089.221865038 3.503193644 0 1 -0.706419206 0.49576663 0 1 3.364277389 3.28048455 0 1 309.3664356.429446616 3.67189346 0 1 -0.574541358 0.512378657 0 1 5.741027496 3.421624215 0 1 307.8269395-0.332452759 3.576454358 0 1 -1.116563911 0.512175738 0 1 -0.688305385 3.332764693 0 1 291.15129890.850680138 3.762514863 0 1 0.082700471 0.513835757 0 1 -0.799331636 3.487405279 0 1 326.6609591-0.978443222 3.672752712 0 1 -2.203068055 0.477848429 0 1 -0.11832694 3.426599213 0 1 293.5331712-7.079952746 3.586526448 0 1 -0.834303305 0.502895531 0 1 -1.609678638 3.362548963 0 1 305.29250276.13205539 3.648020273 0 1 -0.180269365 0.519219949 0 1 1.734059747 3.387117305 0 1 303.24058390.671890696 3.553581011 0 1 -0.280115979 0.511526879 0 1 2.969823904 3.297437 0 1 312.78531315.400323311 3.817646298 0 1 -1.023210012 0.510551087 0 1 -1.916811856 3.540269857 0 1 303.4733668-8.287814413 5.135678378 0 1 -1.889668427 0.409192014 0 1 -5.269907085 4.785872645 0 1 327.4902483-0.97490265 3.503372814 0 1 -0.771047244 0.481622081 0 1 -2.934355931 3.243113849 0 1 298.2812338-9.971048512 6.583357485 0 1 -3.212771664 0.355282433 0 1 -5.445128926 5.943730987 0 1 69.06920460.629757517 6.136830705 0 1 -2.32729917 0.369708286 0 1 -0.275524633 5.612521774 0 1 52.25039371-1.546937347 4.650830485 0 1 -0.666932322 0.644049813 0 1 1.480093918 4.400102315 0 1 54.623515763.266681628 6.187751238 0 1 -2.496470317 0.360410188 0 1 -7.852169095 5.705381068 0 1 47.75480332-5.512299457 5.600191346 0 1 -1.795505075 0.381210571 0 1 -4.351504444 5.106231457 0 1 172.3783546D.7 fp-XRF Soil Mode426Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSb Sb +/- Sb Intercept Sb Slope Se Se +/- Se Intercept Se Slope Sn Sn +/- Sn Intercept Sn Slope SrD.7 fp-XRF Soil Mode-0.63394949 3.954986856 0 1 -0.947603253 0.472853334 0 1 -1.544590647 3.644412613 0 1 351.3967077-2.872815468 3.869571074 0 1 0.219424444 0.526718481 0 1 1.844114904 3.600508804 0 1 326.7612808-0.17503372 3.917570722 0 1 -0.903240629 0.491053033 0 1 -0.322464257 3.5896578 0 1 329.41697582.411402054 3.631853839 0 1 -1.579971049 0.483401722 0 1 -0.325686699 3.350030836 0 1 321.1445299-5.697523909 3.98623091 0 1 -1.554963878 0.474501478 0 1 -1.586844166 3.718537329 0 1 351.3864525-0.46607671 3.598984737 0 1 -0.937620493 0.498003706 0 1 2.078997486 3.32844586 0 1 310.7287782.131196442 3.547564008 0 1 -0.520571181 0.509294053 0 1 2.971924702 3.309174672 0 1 297.2034657-1.86292735 3.670164705 0 1 -1.093556208 0.495878092 0 1 8.11499231 3.446203077 0 1 294.9992883-5.189980241 3.636164162 0 1 -0.543736809 0.514075551 0 1 2.105960105 3.38185165 0 1 296.05902381.931573186 3.713941703 0 1 -0.551062112 0.507109898 0 1 0.043330636 3.458640564 0 1 313.9744379-0.721003876 3.770384327 0 1 -1.756522141 0.483268885 0 1 2.044425255 3.50786922 0 1 312.7792006-1.591330713 3.71093093 0 1 -0.222827676 0.5259286 0 1 4.100428956 3.453033763 0 1 289.91076310.08567249 3.674428927 0 1 -1.382991738 0.488964439 0 1 -1.439320338 3.3823573 0 1 303.6560807-5.302525477 3.449009308 0 1 -0.892114033 0.499109366 0 1 2.492167078 3.224904081 0 1 283.7847371-2.238336306 3.85052925 0 1 0.392880993 0.534163899 0 1 5.167159079 3.61601471 0 1 309.94778891.030717489 3.699671904 0 1 -0.516860626 0.516876449 0 1 8.58084601 3.478623536 0 1 328.36338940.544840326 3.881728165 0 1 -0.791443902 0.511707175 0 1 0.762527168 3.620471776 0 1 338.45527933.435476486 3.827038626 0 1 -0.36942807 0.51239521 0 1 -0.388557664 3.564354859 0 1 311.27048391.328103766 3.656829785 0 1 -1.617819645 0.481162595 0 1 -0.916763578 3.391260008 0 1 300.72939040.61850102 4.576314953 0 1 0.133728664 0.666519518 0 1 1.530840044 4.262008344 0 1 67.751744051.597583704 3.771960798 0 1 -0.08726133 0.508852567 0 1 4.696550593 3.494152603 0 1 297.3083828-2.547231649 3.840709123 0 1 -0.694593993 0.512616661 0 1 4.684034079 3.579364993 0 1 310.29599980.722005314 3.909970657 0 1 -0.362955905 0.517310464 0 1 -1.169192375 3.558026157 0 1 308.9294588-0.353985183 3.746929692 0 1 -1.226659942 0.501713631 0 1 1.251023078 3.515025451 0 1 318.8051566-0.062197738 3.908828239 0 1 -0.767350715 0.506403452 0 1 -0.723215017 3.624637115 0 1 312.28903831.830895187 4.027467584 0 1 -0.037328441 0.522218133 0 1 2.73561784 3.723280711 0 1 322.4127284-0.04836138 4.074801372 0 1 -0.899786596 0.50399459 0 1 1.519734968 3.779682129 0 1 365.5994607-6.302462795 3.745644215 0 1 -0.78554831 0.508132083 0 1 0.205961412 3.557391437 0 1 317.8343421-1.946531793 3.861847681 0 1 -1.45423633 0.488351248 0 1 1.995055592 3.644647132 0 1 331.15264573.609432422 3.815770463 0 1 -0.716889184 0.503600259 0 1 -1.747164293 3.536477625 0 1 329.74405281.998195449 3.799002686 0 1 -0.463442536 0.514586361 0 1 1.421813065 3.553449699 0 1 326.56811021.167408668 3.722202365 0 1 -1.337180772 0.492237963 0 1 1.947961637 3.429595452 0 1 310.27683691.627434969 4.028146967 0 1 -1.075309211 0.495422325 0 1 -1.485139869 3.757932898 0 1 363.9365936-1.316948315 3.769062426 0 1 -0.659731353 0.500815778 0 1 2.68120879 3.509300502 0 1 339.0200492-5.011568226 3.893449344 0 1 -1.280297793 0.487557372 0 1 -0.266615202 3.6332017 0 1 333.71789917.862198714 3.669453426 0 1 -0.966396812 0.500122868 0 1 4.352328953 3.439615978 0 1 314.9797142.1724565 3.629185113 0 1 -1.610574726 0.492317781 0 1 7.216839414 3.4120546 0 1 321.1360689427Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSb Sb +/- Sb Intercept Sb Slope Se Se +/- Se Intercept Se Slope Sn Sn +/- Sn Intercept Sn Slope SrD.7 fp-XRF Soil Mode-1.649780716 3.846229269 0 1 -0.410138013 0.525671362 0 1 -3.101566946 3.59075796 0 1 341.2967985-5.148982807 3.655685811 0 1 -1.138432585 0.494291486 0 1 4.177609427 3.44013774 0 1 285.3917258-1.609325259 3.586714303 0 1 -0.820922056 0.51599408 0 1 8.211829974 3.347352829 0 1 304.0795875-1.124432934 3.591541467 0 1 -1.073884446 0.508503786 0 1 3.594764046 3.393537941 0 1 285.8526561-0.122018419 4.736374682 0 1 0.721036448 0.681837323 0 1 -1.659916085 4.381715714 0 1 61.29659416-4.669438367 3.613363843 0 1 -0.202074762 0.519858152 0 1 8.716314486 3.394313726 0 1 282.98311130.920958522 3.668690036 0 1 0.174584333 0.537673364 0 1 4.22697036 3.417834133 0 1 301.8604744-2.1448517 3.624929531 0 1 -1.451809696 0.479672539 0 1 1.340065805 3.385220649 0 1 302.3910296-2.197886852 3.501920545 0 1 -0.302908803 0.513074376 0 1 -1.625930278 3.219334978 0 1 284.48262554.526893296 3.726880986 0 1 -0.632657918 0.487131287 0 1 -0.128605442 3.444895945 0 1 313.49277642.386165323 3.841262001 0 1 -1.442380502 0.460468658 0 1 3.202608795 3.565010065 0 1 326.0782148-2.11658608 3.770876105 0 1 -1.180755814 0.48682133 0 1 1.532069515 3.483905324 0 1 323.7809169-2.50833817 3.754894218 0 1 -0.795146118 0.503435021 0 1 1.545942546 3.481496863 0 1 323.6559821-6.033449074 3.567868613 0 1 -0.782106203 0.494501915 0 1 -4.581036192 3.305891148 0 1 298.34592981.358967466 3.741338299 0 1 0.047432708 0.539447152 0 1 -1.207674992 3.506706352 0 1 318.2456278-2.191194673 3.882559418 0 1 -1.282193745 0.489385426 0 1 5.264169513 3.664617962 0 1 323.22331531.757301316 3.92085497 0 1 -0.189501529 0.504612584 0 1 2.344618704 3.592701687 0 1 330.40020882.981798825 3.544425849 0 1 -0.8015814 0.480212157 0 1 -3.730991866 3.263099274 0 1 304.7106155-1.504996323 3.607330812 0 1 -0.80809516 0.476484223 0 1 -0.460790992 3.32836184 0 1 318.5775253-0.390514384 4.68427804 0 1 -1.467984348 0.421454736 0 1 -3.597853982 4.384795822 0 1 361.93905854.73937542 3.933808889 0 1 -1.3027231 0.468213298 0 1 0.261768516 3.68869541 0 1 334.8917832-7.896866473 3.92300537 0 1 -0.658066465 0.487350059 0 1 -4.054940981 3.628928016 0 1 324.0034891-2.431940657 6.305626037 0 1 -2.533163134 0.368041462 0 1 -12.34258334 5.767658424 0 1 79.65440266-0.837186366 5.819410343 0 1 -2.330177524 0.360330851 0 1 0.848190703 5.330942271 0 1 122.60763-4.265926775 3.63436314 0 1 -0.252220443 0.516996606 0 1 4.771691447 3.402178429 0 1 310.4764339-3.900940461 3.729766847 0 1 -0.325508132 0.50580262 0 1 -5.838768478 3.423745717 0 1 324.48196190.473830196 4.625690344 0 1 1.467129241 0.690787492 0 1 12.50271064 4.342129298 0 1 54.496089881.269804868 3.71626077 0 1 -0.711933434 0.493480855 0 1 1.369464011 3.430320624 0 1 330.2106802-0.796646605 3.674368305 0 1 -0.778183003 0.494961147 0 1 0.538331794 3.422733106 0 1 308.7556894-3.112543979 4.01455732 0 1 -1.001454605 0.493896095 0 1 -0.921618678 3.662758479 0 1 334.1677313-0.999919302 5.667184458 0 1 -1.584385878 0.438971677 0 1 -2.149074081 5.326664243 0 1 262.81831892.247788477 5.496088213 0 1 -2.064820647 0.377065543 0 1 -7.126063987 5.047998066 0 1 140.0534173-19.19666434 5.888420083 0 1 -1.953233274 0.384701778 0 1 -9.400018973 5.522641107 0 1 108.2453152-6.547817394 5.966561229 0 1 -1.672249307 0.401414659 0 1 -16.02600532 5.515730782 0 1 157.5318393-4.000288454 3.742074918 0 1 -0.465249988 0.501352308 0 1 -0.813869522 3.47119773 0 1 330.2443991-3.072528368 3.841940882 0 1 -1.033712333 0.476177691 0 1 -3.833341447 3.55737748 0 1 327.553323-1.714548679 3.673785422 0 1 -0.836353039 0.497352771 0 1 4.722803805 3.402953366 0 1 310.0220686428Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSb Sb +/- Sb Intercept Sb Slope Se Se +/- Se Intercept Se Slope Sn Sn +/- Sn Intercept Sn Slope SrD.7 fp-XRF Soil Mode5.17922023 3.771726835 0 1 -1.414076293 0.483892842 0 1 3.600762852 3.537788594 0 1 332.69648834.985999041 3.404136496 0 1 0.077953415 0.52141168 0 1 3.401830615 3.183024254 0 1 292.3528349-3.566737044 3.531045072 0 1 -1.192232367 0.478700354 0 1 -3.115987057 3.275508699 0 1 310.71995692.303570965 3.771796716 0 1 -0.335317348 0.493471731 0 1 -1.592522336 3.479861727 0 1 330.627117512.24515755 5.979257288 0 1 -2.060919813 0.386882995 0 1 -7.479495022 5.489588158 0 1 150.36031248.427477341 6.440359004 0 1 -2.104316782 0.388142484 0 1 -6.878219247 5.959040312 0 1 93.441223631.552831201 3.830928629 0 1 -0.856494828 0.481586359 0 1 -6.705092496 3.533547134 0 1 329.4434946-1.340370617 3.617535133 0 1 0.015739474 0.508150131 0 1 0.880778507 3.343198533 0 1 301.4721967-3.114683929 5.612639135 0 1 -1.84626304 0.383975401 0 1 -7.794348078 5.207938282 0 1 118.60791994.241312668 3.881056797 0 1 -1.292959749 0.477690931 0 1 1.712939502 3.615449247 0 1 318.658991-3.757925756 3.521167773 0 1 0.410722754 0.515488669 0 1 8.761609023 3.303591101 0 1 304.93404455.924598499 4.637464893 0 1 0.79809979 0.683229913 0 1 14.00764352 4.418947889 0 1 60.160558673.042697748 3.481479165 0 1 -0.94315223 0.491026879 0 1 6.37224324 3.231210549 0 1 287.99466593.99393662 3.817676267 0 1 -0.426355077 0.550601109 0 1 1.541665494 3.601189269 0 1 337.30617440.823294392 3.624341635 0 1 -1.291783229 0.49836915 0 1 5.862833845 3.380096813 0 1 308.61324240.034628037 3.876337167 0 1 -0.362692495 0.514697116 0 1 2.839129683 3.5965475 0 1 344.00247632.321895372 3.714192644 0 1 -0.354836726 0.509865364 0 1 7.097778367 3.487121367 0 1 319.1813305-3.931971073 3.761220825 0 1 -0.827779622 0.50141721 0 1 0.883650041 3.540047275 0 1 310.1914979-1.732078318 3.739232953 0 1 -0.526050982 0.510443357 0 1 -2.825425985 3.449014083 0 1 305.77758282.749643161 3.678520729 0 1 -1.456455089 0.480591593 0 1 2.862624279 3.392931203 0 1 311.223308-1.294485681 6.127887033 0 1 -1.697859415 0.386267547 0 1 -9.642547811 5.57812606 0 1 74.22478540.219834912 3.821096772 0 1 -0.787829349 0.517217773 0 1 1.527876739 3.547108594 0 1 307.9952469-1.426057824 3.731108121 0 1 -0.464422952 0.520527224 0 1 1.682363404 3.442923009 0 1 317.52834481.481255192 3.750424805 0 1 -0.028987159 0.528743567 0 1 -1.609780364 3.491302281 0 1 308.27433853.384364435 3.586109655 0 1 0.177273772 0.514689339 0 1 1.008897393 3.364354621 0 1 300.94538570.697023775 3.551156633 0 1 -0.554102302 0.496482672 0 1 3.072893396 3.29776712 0 1 306.25231170.064725918 3.595133538 0 1 -0.99886502 0.47909677 0 1 1.010534231 3.340148124 0 1 311.1933638429Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSr +/- Sr Intercept Sr Slope Te Te +/- Te Intercept Te Slope Th Th +/- Th Intercept Th Slope Ti Ti +/-5.807960838 19 0.7838 2.141134653 3.799438281 0 1 13.39521117 3.931771638 0 1 1586.504925 18.514789916.155643467 19 0.7838 3.839835922 3.906233804 0 1 8.018837646 3.972842589 0 1 1703.948575 19.660616345.957439342 19 0.7838 3.022923795 4.02845888 0 1 6.13511726 4.082559735 0 1 2615.262041 30.402529574.775041489 19 0.7838 -5.996324168 5.778247534 0 1 2.4187846 4.399901963 0 1 754.5023604 10.540528686.58466594 19 0.7838 8.140002453 4.083344163 0 1 12.13659346 4.300617649 0 1 1878.17841 20.291102816.128275404 19 0.7838 3.606553149 3.837879644 0 1 13.51975564 4.12467608 0 1 1780.253636 20.033010745.652292732 19 0.7838 -1.303132473 3.737672428 0 1 12.75874378 3.949805283 0 1 1805.960035 20.209526695.823401303 19 0.7838 -3.788823515 3.779799563 0 1 15.75605689 4.097453406 0 1 1952.557225 21.181872465.75350133 19 0.7838 3.125401845 3.781484916 0 1 19.00176345 4.22785681 0 1 1979.946911 21.511355166.156888967 19 0.7838 -0.716256554 3.920906128 0 1 13.27804561 4.182064406 0 1 1975.650272 21.232161875.997611503 19 0.7838 2.765459586 3.884544151 0 1 15.94578678 4.208169207 0 1 2115.753646 22.585586175.969903568 19 0.7838 -1.788368337 3.729010524 0 1 11.8093699 4.006191988 0 1 2072.347539 21.819355526.291644533 19 0.7838 -8.379049821 3.959547512 0 1 16.41369168 4.380022596 0 1 1788.534744 20.236370063.216553186 19 0.7838 -2.882688945 5.091197491 0 1 25.40228068 6.138106445 0 1 13317.07837 104.19957176.1709818 19 0.7838 -4.073491235 3.922034514 0 1 13.27381636 4.213404815 0 1 1715.169166 19.758418136.047440669 19 0.7838 3.81143463 3.876361659 0 1 12.49428298 4.129065867 0 1 1915.030804 21.040524756.102410156 19 0.7838 1.280821378 3.847459871 0 1 16.03381723 4.195823494 0 1 1889.863058 20.716712435.83418445 19 0.7838 -2.024756406 3.805574411 0 1 6.330709771 3.851225209 0 1 2175.549252 22.628977765.894204095 19 0.7838 2.426378806 3.838411661 0 1 15.96097711 4.144818933 0 1 1821.700738 20.199491515.900557088 19 0.7838 -4.339593883 3.900789478 0 1 16.32888907 4.213813745 0 1 1877.744871 20.823222985.829225549 19 0.7838 -2.391773682 3.82089262 0 1 12.51348185 4.029123686 0 1 1982.895894 21.795419476.209623172 19 0.7838 -7.258144002 4.427338095 0 1 15.8240657 4.708292896 0 1 2527.614371 29.426704015.993322243 19 0.7838 0.824055765 3.832601477 0 1 15.09880112 4.107210382 0 1 1713.876677 19.135133396.158549058 19 0.7838 -2.460404339 3.914153384 0 1 18.09018529 4.443597148 0 1 2069.411484 22.019962795.904662258 19 0.7838 -1.95807994 3.867207492 0 1 12.4363633 4.125796846 0 1 2202.419321 23.271159166.491385127 19 0.7838 -4.164763378 4.079929909 0 1 11.53824118 4.279338562 0 1 1847.603315 20.686162745.991281189 19 0.7838 -5.450864948 3.961298589 0 1 21.85073049 4.448164376 0 1 2028.600319 21.964028256.042101079 19 0.7838 -1.050050497 3.949276822 0 1 7.808859654 3.883651535 0 1 1831.986373 20.293045946.149376511 19 0.7838 2.728535715 4.020022757 0 1 10.98225134 4.206172311 0 1 1998.818609 21.867150456.108080445 19 0.7838 3.124022705 3.90552104 0 1 15.7659525 4.196566957 0 1 1741.364138 19.442857686.330929825 19 0.7838 -2.181988918 4.168923003 0 1 13.98738658 4.417216723 0 1 2155.55967 23.381902778.23942901 19 0.7838 2.177619288 5.452021025 0 1 10.03528619 5.36680735 0 1 1274.584938 14.39245135.853808291 19 0.7838 6.104214624 3.778029868 0 1 15.65013993 4.007131461 0 1 1418.191889 16.905771744.29388684 19 0.7838 -0.153347426 6.810340416 0 1 3.350628003 4.836982595 0 1 511.5703896 7.8521573053.599331418 19 0.7838 -7.833528813 6.542401489 0 1 -0.004334976 4.268349129 0 1 383.6337716 6.7439818453.103076312 19 0.7838 1.79409189 5.04966757 0 1 17.64802159 5.832186967 0 1 13461.80523 105.34317163.482537157 19 0.7838 6.347713572 6.532902478 0 1 -6.918652429 3.577240988 0 1 394.4448918 6.838746586.004134994 19 0.7838 -0.82674995 5.865878202 0 1 3.991263252 4.797570407 0 1 858.2236716 10.94532663D.7 fp-XRF Soil Mode430Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSr +/- Sr Intercept Sr Slope Te Te +/- Te Intercept Te Slope Th Th +/- Th Intercept Th Slope Ti Ti +/-D.7 fp-XRF Soil Mode7.004366368 19 0.7838 2.9384705 4.19555043 0 1 16.33780112 4.588806825 0 1 1550.424196 17.943901766.664641157 19 0.7838 3.984018622 4.125285079 0 1 13.91591118 4.498819329 0 1 2029.961481 21.823968916.700865725 19 0.7838 -1.853750833 4.194985649 0 1 14.26042364 4.542892229 0 1 1834.318458 20.10106566.309313878 19 0.7838 -0.861314762 3.931562108 0 1 8.200535438 4.050127196 0 1 1778.056059 20.140643467.151665008 19 0.7838 6.667518553 4.349573387 0 1 23.85817668 5.003698085 0 1 1756.602117 19.873395036.10357467 19 0.7838 3.1353933 3.951049448 0 1 12.8016346 4.144109088 0 1 1785.103697 20.197709495.924706783 19 0.7838 4.42181766 3.91018002 0 1 17.40418258 4.207983084 0 1 1999.785673 21.417379056.066263446 19 0.7838 2.512711752 3.988374859 0 1 7.56067166 4.014238017 0 1 2176.316116 23.031514386.038789172 19 0.7838 -1.659795457 3.943320531 0 1 8.160124253 3.986428365 0 1 2078.247407 22.349011336.312461601 19 0.7838 -1.548962867 4.051877678 0 1 12.37976957 4.294099332 0 1 1826.591174 20.609574196.358233496 19 0.7838 -5.641700826 4.104079411 0 1 11.90275988 4.226255766 0 1 1742.802107 19.942149715.989202803 19 0.7838 1.799291813 4.071198968 0 1 11.04250747 4.24192456 0 1 2099.004496 22.624833636.11117646 19 0.7838 4.626010032 4.013176613 0 1 14.49498911 4.26531394 0 1 2047.212886 21.839575735.64041612 19 0.7838 -1.200694055 3.780965961 0 1 10.39030502 3.883100135 0 1 2012.380216 21.63821726.448552032 19 0.7838 -2.213958766 4.152197755 0 1 20.93041519 4.65695017 0 1 1984.496925 21.940981556.488217963 19 0.7838 -1.63044468 4.060858147 0 1 10.81565218 4.197723098 0 1 1995.457322 21.768037916.888137666 19 0.7838 0.068832225 4.198575357 0 1 17.1664508 4.690017109 0 1 2349.657859 24.387561786.422275541 19 0.7838 3.827398825 4.130262204 0 1 15.13277467 4.489022611 0 1 1913.984465 21.200730346.082735841 19 0.7838 5.198003689 3.979855672 0 1 19.30656237 4.344098198 0 1 1506.652855 18.295664793.395175324 19 0.7838 7.779005784 4.96839463 0 1 27.1976727 6.108646025 0 1 13500.94429 106.03999736.083473589 19 0.7838 3.069554852 4.042380577 0 1 10.55318285 4.096061028 0 1 1510.118612 18.330845796.386143143 19 0.7838 -1.193207747 4.108566959 0 1 16.24483611 4.56784117 0 1 2139.26248 22.920064046.436819955 19 0.7838 -4.32431451 4.246951519 0 1 4.970151287 4.160177715 0 1 2279.68398 23.853068226.451336049 19 0.7838 2.911678352 4.094255272 0 1 15.3357979 4.421541059 0 1 1864.842209 20.928652756.505927476 19 0.7838 -5.883675188 4.103921108 0 1 17.24952602 4.572216928 0 1 1902.207889 21.276612286.827088016 19 0.7838 -3.547855507 4.342062557 0 1 16.2776941 4.821857454 0 1 2056.30152 22.173342487.449730062 19 0.7838 7.796805715 4.389860446 0 1 20.50795233 5.072534146 0 1 1985.217273 21.589425516.461605889 19 0.7838 1.052910792 4.065794361 0 1 4.834364197 4.13692088 0 1 1965.304623 21.546846346.746716714 19 0.7838 0.846725536 4.214722789 0 1 18.96321226 4.676691574 0 1 1702.225672 19.986601416.612445197 19 0.7838 1.488199486 4.1096461 0 1 8.687131466 4.286509627 0 1 1957.886533 21.389506336.627344651 19 0.7838 -4.375360399 4.147771975 0 1 16.04549997 4.53269619 0 1 1801.689132 20.472185376.273286147 19 0.7838 -2.135029425 4.029672301 0 1 27.9032743 4.701591358 0 1 1809.075983 20.591548847.301141995 19 0.7838 -0.511366783 4.303608401 0 1 17.04074855 4.843687595 0 1 1944.489183 21.145808466.664094289 19 0.7838 -2.746356099 4.079350613 0 1 8.116717462 4.194264354 0 1 1818.678459 20.273802616.791912012 19 0.7838 1.041089118 4.199614542 0 1 11.99604291 4.371061303 0 1 1789.806403 20.28551276.336151445 19 0.7838 7.239668771 4.007108927 0 1 14.36957917 4.329730703 0 1 1925.005581 21.313130666.292550954 19 0.7838 0.797197623 3.920169198 0 1 16.08036425 4.278962169 0 1 1833.816507 20.53373272431Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSr +/- Sr Intercept Sr Slope Te Te +/- Te Intercept Te Slope Th Th +/- Th Intercept Th Slope Ti Ti +/-D.7 fp-XRF Soil Mode6.784515577 19 0.7838 -1.966513523 4.165606677 0 1 9.00860479 4.27925454 0 1 1862.997682 20.779550415.890920001 19 0.7838 7.005006323 3.967855905 0 1 10.57119821 4.008472393 0 1 1756.80561 20.205038296.059606666 19 0.7838 -5.347295965 3.906107996 0 1 15.70895453 4.263924147 0 1 2193.911578 23.201234075.849246742 19 0.7838 2.844104254 3.921630282 0 1 9.083480034 3.90405936 0 1 1848.870742 21.0733073.273270804 19 0.7838 1.241241802 4.970492937 0 1 30.70138961 6.307934357 0 1 13507.14855 105.23062575.812858083 19 0.7838 -2.055365538 3.904058609 0 1 7.740611152 3.937354308 0 1 1867.413844 21.181259566.116792771 19 0.7838 3.179869802 4.002627045 0 1 10.98854626 4.170989329 0 1 2072.852508 22.301213736.0694496 19 0.7838 -4.942746071 3.918276979 0 1 11.89873334 4.081174051 0 1 1703.99917 19.693294355.680152061 19 0.7838 -2.175600471 3.82561363 0 1 8.752361545 3.808065049 0 1 1576.559788 18.428631986.222183939 19 0.7838 4.511143727 4.008197847 0 1 13.1024152 4.119747805 0 1 1480.591615 17.45183646.576486066 19 0.7838 3.713086999 4.128139095 0 1 3.802188238 4.041040032 0 1 1682.207958 18.524060786.520042627 19 0.7838 -4.977267164 4.05433574 0 1 14.43364706 4.454614827 0 1 1902.959305 21.057010036.458399115 19 0.7838 -1.244424983 4.048675809 0 1 13.80248853 4.388347905 0 1 1859.692391 20.642911935.971330767 19 0.7838 2.206207027 3.9129527 0 1 8.142257082 3.956039632 0 1 1710.708038 19.664193036.434627476 19 0.7838 -1.757884328 4.039138509 0 1 15.41534558 4.442873323 0 1 2202.58931 23.131469056.630100706 19 0.7838 -0.016404211 4.163612481 0 1 19.91889858 4.679340154 0 1 1926.160779 21.338243556.745578552 19 0.7838 0.630681161 4.218168767 0 1 13.47903883 4.496470279 0 1 1957.906784 21.154897525.934027161 19 0.7838 -2.428024952 3.831820809 0 1 6.98538296 3.713685936 0 1 1247.509401 15.685070186.165834217 19 0.7838 5.349604005 3.900844727 0 1 6.463827572 3.832099923 0 1 1293.443456 16.133688488.181148949 19 0.7838 1.552399938 5.008057605 0 1 16.8757956 5.3297977 0 1 1027.434519 13.172017316.893240026 19 0.7838 -0.582532965 4.27067738 0 1 4.542545454 4.242287887 0 1 1764.880631 19.359983416.686652542 19 0.7838 -1.531137169 4.244557034 0 1 12.8999493 4.478564249 0 1 1676.372323 18.919759474.462457352 19 0.7838 -3.72826894 6.494812988 0 1 1.542898871 4.496045717 0 1 563.8017985 8.0506807455.140808821 19 0.7838 -3.262430468 5.962556308 0 1 6.813747065 4.72518384 0 1 776.8683373 9.5303379646.209129142 19 0.7838 0.027433412 3.966809715 0 1 1.837965845 3.846385525 0 1 2005.802276 21.465701366.428132685 19 0.7838 -1.443419894 4.057259033 0 1 8.127546627 4.089600758 0 1 1724.810049 19.636782883.073712715 19 0.7838 6.805097049 4.972879018 0 1 20.47824412 5.887398408 0 1 13658.93033 107.45470226.476085817 19 0.7838 3.375087018 4.003161252 0 1 16.66729153 4.407920742 0 1 1662.492568 19.069113866.213278272 19 0.7838 -0.724147928 4.012051764 0 1 20.63938816 4.445298752 0 1 1694.148978 19.40355056.912381538 19 0.7838 0.466111518 4.311933503 0 1 12.4663872 4.547045052 0 1 1915.311283 20.984383037.835491045 19 0.7838 1.840348638 5.936300435 0 1 10.75983378 5.777400319 0 1 1720.492284 17.474377795.339083707 19 0.7838 -0.272248762 5.8289781 0 1 2.570462919 4.374024 0 1 849.147228 10.887709935.012145213 19 0.7838 -1.611434799 6.208950385 0 1 1.082004599 4.392760315 0 1 647.359565 9.1660551656.032887509 19 0.7838 5.757370633 6.22444269 0 1 4.920217277 5.055897234 0 1 916.9790386 12.005310666.478995271 19 0.7838 -0.708734379 4.04325086 0 1 13.25653952 4.318107501 0 1 1798.622487 19.859062796.602876154 19 0.7838 -2.586775612 4.13434528 0 1 7.147526765 4.186770043 0 1 1438.65899 17.15653766.185140917 19 0.7838 3.833042181 3.929895029 0 1 13.6283181 4.240235538 0 1 1729.455043 19.66668954432Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSr +/- Sr Intercept Sr Slope Te Te +/- Te Intercept Te Slope Th Th +/- Th Intercept Th Slope Ti Ti +/-D.7 fp-XRF Soil Mode6.601499757 19 0.7838 7.757947327 4.080458052 0 1 19.68219051 4.579769568 0 1 1831.507589 20.207171345.685948725 19 0.7838 3.296143752 3.712440821 0 1 11.9576259 3.885606479 0 1 1666.558275 19.177675776.011753133 19 0.7838 -4.598250933 3.846901507 0 1 13.24858363 4.01769297 0 1 1471.49989 17.500104386.503372195 19 0.7838 2.32245738 4.081552823 0 1 7.231065061 4.135036591 0 1 1864.557775 20.037619225.926231328 19 0.7838 1.766368922 6.195970595 0 1 6.759051599 4.952675938 0 1 701.9286717 9.3345749144.895958627 19 0.7838 -1.39357999 6.739372141 0 1 9.420224847 5.207583578 0 1 564.9674542 8.2290041396.588731017 19 0.7838 -0.302041387 4.157497359 0 1 15.88773634 4.391745677 0 1 1640.743558 18.642460686.004442405 19 0.7838 5.232155717 3.898412218 0 1 11.64856958 4.06467392 0 1 1647.596277 18.727615235.028922028 19 0.7838 -11.80214381 5.827621801 0 1 7.13782009 4.709585172 0 1 657.3813912 8.9755900196.558350006 19 0.7838 -2.711559442 4.156610503 0 1 18.11596358 4.612299787 0 1 1884.623104 20.230163565.921994124 19 0.7838 1.59192214 3.831275516 0 1 5.296797693 3.787232852 0 1 1305.0007 16.587160393.222214885 19 0.7838 -6.437627766 5.045464786 0 1 26.67156455 6.194649815 0 1 13429.4714 104.93327365.696024983 19 0.7838 -1.661329468 3.835917572 0 1 7.307410032 3.720121591 0 1 1296.542664 16.464212276.848618002 19 0.7838 -0.859536801 4.209142392 0 1 19.01772376 4.655761474 0 1 2630.331295 27.86916146.144751923 19 0.7838 -5.031058943 3.955894729 0 1 20.0432716 4.454489576 0 1 1991.720701 21.554730636.859992323 19 0.7838 0.194494396 4.198271976 0 1 13.75075897 4.516698338 0 1 2035.117497 21.770313316.369105113 19 0.7838 5.910878119 4.030945125 0 1 4.284508253 3.990567258 0 1 1796.182054 20.248393336.333140617 19 0.7838 -2.557022606 4.090282696 0 1 21.07642018 4.593587778 0 1 1657.988836 19.540128976.173021956 19 0.7838 -0.409590558 3.979277126 0 1 5.291506956 4.052022253 0 1 2145.68668 22.665991766.145250725 19 0.7838 5.154119444 3.939390006 0 1 15.57931435 4.248399347 0 1 1778.348204 19.839418414.186171692 19 0.7838 -1.452159921 6.378333536 0 1 5.025581983 4.803632309 0 1 405.5727815 6.9034869736.405115872 19 0.7838 1.178316841 4.214481919 0 1 12.45229823 4.456894702 0 1 2276.53698 23.956707446.361884707 19 0.7838 -3.417561069 3.988136078 0 1 10.90925597 4.258259069 0 1 2294.853377 23.791762776.294517099 19 0.7838 -1.880597678 4.090768413 0 1 15.16322592 4.339523877 0 1 1946.610703 21.452219375.957749307 19 0.7838 -5.073753115 3.921909561 0 1 15.62898981 4.156239026 0 1 1750.790351 19.487982815.950245287 19 0.7838 -1.943162949 3.83649063 0 1 16.23466094 4.154743461 0 1 1550.198297 17.936406666.083666232 19 0.7838 3.074341707 3.902325224 0 1 13.24718484 4.066781597 0 1 1415.384836 16.9212008433Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFTi Intercept Ti Slope U U +/- U Intercept U Slope V V +/- V Intercept V Slope W W +/- W Intercept654 0.8292 -2.746742994 3.393037256 0 1 37.41659856 1.936350813 -18 1.2795 1.025614601 3.941800615 0654 0.8292 0.074027945 3.658668867 0 1 35.846821 2.001792838 -18 1.2795 -7.468585298 3.750361712 0654 0.8292 2.27396979 3.831905701 0 1 56.65406673 3.065051877 -18 1.2795 -13.84696042 4.165214534 0654 0.8292 17.74598469 5.216522755 0 1 34.77262818 1.378564121 -18 1.2795 -17.54936721 2.596070964 0654 0.8292 -1.093313142 3.780953975 0 1 36.60179145 1.996936332 -18 1.2795 -10.12434051 3.516396477 0654 0.8292 3.151805209 3.763499776 0 1 39.99944742 2.035396207 -18 1.2795 -10.43630569 3.755411659 0654 0.8292 4.868469228 3.643881636 0 1 40.16615024 2.055161194 -18 1.2795 -11.56582661 3.736793009 0654 0.8292 -2.127064628 3.477920505 0 1 46.15205593 2.153118199 -18 1.2795 -8.736583482 3.814893933 0654 0.8292 -1.964935857 3.467153366 0 1 44.57061266 2.159530092 -18 1.2795 -1.875848353 3.956667894 0654 0.8292 3.028205697 3.786197092 0 1 42.94944206 2.118236464 -18 1.2795 -4.024169976 3.910667929 0654 0.8292 0.758395574 3.661737243 0 1 39.63729811 2.18254162 -18 1.2795 -2.369505637 3.955749786 0654 0.8292 6.190985388 3.799519407 0 1 40.86301113 2.133803082 -18 1.2795 -1.671187537 3.973570377 0654 0.8292 7.706633827 4.03291002 0 1 37.5096887 2.0442057 -18 1.2795 -11.08567697 3.684985626 0654 0.8292 5.524158177 4.490756095 0 1 120.2279477 5.846072653 -18 1.2795 -12.00930298 4.870888372 0654 0.8292 4.266191919 3.82058532 0 1 38.59877292 2.032964643 -18 1.2795 -10.62992021 3.759776759 0654 0.8292 3.444790246 3.745682141 0 1 39.75262782 2.101383216 -18 1.2795 -2.925584868 3.902460481 0654 0.8292 0.978698327 3.702285431 0 1 43.42967571 2.104808645 -18 1.2795 -10.3560913 3.688784186 0654 0.8292 6.119564001 3.768950907 0 1 43.62371252 2.200219034 -18 1.2795 -7.340624759 3.824784114 0654 0.8292 4.194688532 3.727889117 0 1 42.9895296 2.064552876 -18 1.2795 -4.850367235 3.801586169 0654 0.8292 5.236582959 3.795335004 0 1 42.07791348 2.108508025 -18 1.2795 -10.12409379 3.742203727 0654 0.8292 -0.311988804 3.573200735 0 1 50.21097806 2.243354907 -18 1.2795 -11.21519735 3.707102812 0654 0.8292 3.663380367 4.209779403 0 1 72.67029995 3.126206651 -18 1.2795 -8.300868534 4.167174026 0654 0.8292 0.215805303 3.588127665 0 1 35.52399875 1.937386334 -18 1.2795 -2.269860797 3.785160159 0654 0.8292 6.714955654 3.950475827 0 1 44.64274976 2.183038529 -18 1.2795 -11.12079866 3.766391061 0654 0.8292 0.601540345 3.630504256 0 1 48.97324185 2.300238547 -18 1.2795 -3.704976151 3.980185762 0654 0.8292 6.313173077 4.057417501 0 1 42.58973429 2.117905137 -18 1.2795 -8.344431433 3.719451679 0654 0.8292 -0.202148727 3.715579668 0 1 40.81887658 2.16629677 -18 1.2795 -2.300728706 3.976698788 0654 0.8292 -2.271023178 3.539016423 0 1 40.69462412 2.058887069 -18 1.2795 -2.977759671 3.850691368 0654 0.8292 5.13042923 3.890076164 0 1 47.1880395 2.215144147 -18 1.2795 -7.283409946 3.876424973 0654 0.8292 6.560692753 3.879069105 0 1 38.27931989 1.975143353 -18 1.2795 -4.784398711 3.822100778 0654 0.8292 0.954276687 3.921085167 0 1 53.22118755 2.372334389 -18 1.2795 -10.97139079 3.853799442 0654 0.8292 10.42518538 5.383725541 0 1 28.46235834 1.515992663 -18 1.2795 -8.969107082 3.130951438 0654 0.8292 4.418180258 3.701307706 0 1 28.17214669 1.736601719 -18 1.2795 -6.801330723 3.61208441 0654 0.8292 11.85471053 5.597717019 0 1 24.8081071 1.075685694 -18 1.2795 -15.76511127 2.73357549 0654 0.8292 18.52759662 5.523918852 0 1 24.27895133 1.009351818 -18 1.2795 -12.5344072 2.709086708 0654 0.8292 5.602462325 4.399881736 0 1 114.5070221 5.852323514 -18 1.2795 -12.93584451 4.77077246 0654 0.8292 5.834966607 4.877247708 0 1 25.23175673 1.023161073 -18 1.2795 -16.49371803 2.561616645 0654 0.8292 14.33212608 5.385075379 0 1 30.4052066 1.331947096 -18 1.2795 -14.33496233 2.712295941 0D.7 fp-XRF Soil Mode434Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFTi Intercept Ti Slope U U +/- U Intercept U Slope V V +/- V Intercept V Slope W W +/- W InterceptD.7 fp-XRF Soil Mode654 0.8292 -4.700016944 3.813821244 0 1 38.35503836 1.887881602 -18 1.2795 -12.90145819 3.425618982 0654 0.8292 1.171235782 3.989847733 0 1 43.59637879 2.156701494 -18 1.2795 -10.06307894 3.706281313 0654 0.8292 -1.21036264 3.893717645 0 1 40.98184453 2.034278743 -18 1.2795 -5.12985723 3.774902247 0654 0.8292 0.766200776 3.729445315 0 1 42.48249782 2.083867533 -18 1.2795 -4.181075693 3.825595269 0654 0.8292 7.53000961 4.426941005 0 1 36.10705393 2.006852015 -18 1.2795 -7.445577714 3.704162728 0654 0.8292 3.109023723 3.752139253 0 1 37.30330935 2.042278329 -18 1.2795 -10.49609285 3.693690313 0654 0.8292 -1.611353608 3.545418132 0 1 40.89520349 2.11102868 -18 1.2795 -7.48686772 3.755055245 0654 0.8292 0.274396973 3.738449818 0 1 47.52495549 2.273038649 -18 1.2795 -14.38465216 3.678607512 0654 0.8292 2.900483031 3.753070794 0 1 40.90393862 2.190409299 -18 1.2795 -8.682044863 3.845239516 0654 0.8292 3.424118177 3.895239232 0 1 43.20992865 2.115776303 -18 1.2795 -6.062296262 3.814708575 0654 0.8292 -1.146862743 3.780421746 0 1 42.05617914 2.066880685 -18 1.2795 -6.759029551 3.824065268 0654 0.8292 10.38945906 4.110906359 0 1 48.19261189 2.262280483 -18 1.2795 -6.972783656 3.855460002 0654 0.8292 1.297564921 3.775690091 0 1 42.64907884 2.15425859 -18 1.2795 -10.15367494 3.7690284 0654 0.8292 3.727341175 3.607296566 0 1 44.36794433 2.156404862 -18 1.2795 -10.95959179 3.729739795 0654 0.8292 -0.235958472 3.946017517 0 1 43.4917076 2.200617492 -18 1.2795 -9.602355915 3.74836976 0654 0.8292 -5.664646579 3.603898393 0 1 50.22194756 2.223291384 -18 1.2795 -7.750656257 3.813678213 0654 0.8292 -1.260056064 3.962256495 0 1 50.60207625 2.362772591 -18 1.2795 -10.41609836 3.79011286 0654 0.8292 7.129280917 4.112568794 0 1 34.72924932 2.068745144 -18 1.2795 -6.07795422 3.840833135 0654 0.8292 3.486324951 3.827153024 0 1 33.21834095 1.907308718 -18 1.2795 -3.433004365 3.857118547 0654 0.8292 6.228496404 4.473945678 0 1 119.6630841 5.897391964 -18 1.2795 -12.24064131 4.846792379 0654 0.8292 4.693499484 3.885342492 0 1 32.7555734 1.906141974 -18 1.2795 -7.080008256 3.699229953 0654 0.8292 4.070711811 3.995774544 0 1 49.71481108 2.294169611 -18 1.2795 -8.507542674 3.860019317 0654 0.8292 -0.199645163 3.900232639 0 1 45.83455792 2.310076417 -18 1.2795 -14.50620612 3.732103103 0654 0.8292 6.585267017 4.082874787 0 1 40.68893118 2.110708484 -18 1.2795 -0.108001296 4.051048199 0654 0.8292 -0.693847152 3.937778127 0 1 48.59945736 2.209519855 -18 1.2795 -7.251706828 3.894801276 0654 0.8292 11.96513163 4.55247225 0 1 53.23046072 2.266529439 -18 1.2795 -5.736889609 3.816304822 0654 0.8292 6.264863148 4.436369611 0 1 41.56562025 2.138883117 -18 1.2795 -4.789910739 3.851362471 0654 0.8292 2.756322561 3.923528868 0 1 45.90247065 2.181289521 -18 1.2795 -6.34795436 3.821935598 0654 0.8292 4.040072439 4.112589277 0 1 41.75669546 2.087212281 -18 1.2795 -6.217297516 3.843075096 0654 0.8292 5.822517698 4.127353957 0 1 44.33933515 2.152463557 -18 1.2795 -9.228210331 3.773793398 0654 0.8292 2.215353427 3.994345335 0 1 39.65233266 2.073136758 -18 1.2795 -7.659708716 3.794966621 0654 0.8292 -0.688374077 3.771320131 0 1 40.47162438 2.093989285 -18 1.2795 -5.24634415 3.789932123 0654 0.8292 9.954931371 4.564551213 0 1 39.23023496 2.08581744 -18 1.2795 -5.109656098 3.792805106 0654 0.8292 4.778464059 4.072033486 0 1 39.09596597 2.046054271 -18 1.2795 -7.272874681 3.736836462 0654 0.8292 -3.825496589 3.845587229 0 1 34.71379688 2.023034184 -18 1.2795 -2.081340576 3.834006779 0654 0.8292 3.276630589 3.896511733 0 1 43.73810113 2.148642893 -18 1.2795 -7.141437972 3.830745631 0654 0.8292 -3.63474342 3.586974694 0 1 43.2388867 2.101476582 -18 1.2795 3.538162939 4.04309536 0435Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFTi Intercept Ti Slope U U +/- U Intercept U Slope V V +/- V Intercept V Slope W W +/- W InterceptD.7 fp-XRF Soil Mode654 0.8292 2.036168638 4.001455946 0 1 40.07835412 2.087970515 -18 1.2795 0.05440294 4.035985686 0654 0.8292 0.603533539 3.680832823 0 1 42.11424284 2.093914769 -18 1.2795 -6.351630838 3.853777794 0654 0.8292 1.894962176 3.755085794 0 1 47.75542202 2.278705432 -18 1.2795 -7.82214171 3.900063771 0654 0.8292 -2.241830758 3.505075022 0 1 42.86901284 2.163481442 -18 1.2795 -5.875836201 3.92350195 0654 0.8292 2.9015224 4.306547345 0 1 111.2206621 5.807044981 -18 1.2795 -14.66831058 4.829179935 0654 0.8292 6.91456787 3.832714582 0 1 40.62789893 2.149427515 -18 1.2795 -10.64195895 3.752890498 0654 0.8292 5.728751628 3.925747174 0 1 43.09423875 2.200263131 -18 1.2795 -3.777839917 3.940850212 0654 0.8292 1.434685741 3.734015203 0 1 38.88467709 2.028751112 -18 1.2795 -2.736723468 3.864108523 0654 0.8292 0.143388565 3.507722534 0 1 34.1374717 1.898235123 -18 1.2795 -1.0480151 3.913445846 0654 0.8292 -2.174662642 3.577848569 0 1 31.54627777 1.797437997 -18 1.2795 -2.927728996 3.67575852 0654 0.8292 2.936027095 3.979167577 0 1 37.40654443 1.885952271 -18 1.2795 -3.607418103 3.637926179 0654 0.8292 5.419173183 4.038523728 0 1 42.64018105 2.120883822 -18 1.2795 -13.15601499 3.624388191 0654 0.8292 5.303162548 4.048803283 0 1 43.18561733 2.102122917 -18 1.2795 -4.172031124 3.866197348 0654 0.8292 6.729546953 3.888731916 0 1 36.35334629 2.001704229 -18 1.2795 -8.110696533 3.764431537 0654 0.8292 -4.310837611 3.672657015 0 1 44.56133077 2.242832483 -18 1.2795 -5.625142799 3.925511401 0654 0.8292 0.356579085 3.963599477 0 1 42.37116551 2.14803309 -18 1.2795 -10.62719725 3.682909491 0654 0.8292 3.168088916 4.086587946 0 1 43.58883159 2.12178695 -18 1.2795 -8.927583013 3.689192532 0654 0.8292 -1.366133149 3.46617691 0 1 29.57539583 1.68197759 -18 1.2795 -8.933336277 3.589110722 0654 0.8292 4.064100037 3.730514309 0 1 29.83198336 1.719036804 -18 1.2795 -7.47381045 3.596881641 0654 0.8292 8.818278529 5.068665966 0 1 26.45432873 1.460955706 -18 1.2795 -13.39923551 3.05850213 0654 0.8292 6.255258982 4.233448178 0 1 39.68222809 1.968010775 -18 1.2795 -5.036111868 3.639384601 0654 0.8292 1.347497717 4.019063091 0 1 39.31482783 1.949520717 -18 1.2795 -5.659500548 3.648674364 0654 0.8292 4.300962892 5.063908372 0 1 23.98291666 1.058324285 -18 1.2795 -13.75718346 2.740126281 0654 0.8292 3.565818186 4.670128383 0 1 25.59374249 1.14802317 -18 1.2795 -16.34642184 2.593846104 0654 0.8292 5.652044641 3.934155356 0 1 40.00167775 2.10209044 -18 1.2795 -0.094546715 3.959598379 0654 0.8292 -1.358044377 3.754861959 0 1 40.69158805 2.025413283 -18 1.2795 -8.89582395 3.737807157 0654 0.8292 7.455022305 4.444851495 0 1 115.2280788 5.921569803 -18 1.2795 -23.59813627 4.543298163 0654 0.8292 1.716306012 3.866890049 0 1 37.49887676 1.964103406 -18 1.2795 -12.05007755 3.622319443 0654 0.8292 -2.079183635 3.671071896 0 1 39.05022612 2.006374939 -18 1.2795 -5.330968701 3.791346429 0654 0.8292 2.269490268 4.186003048 0 1 44.59213743 2.122959404 -18 1.2795 -3.571601899 3.877288993 0654 0.8292 8.968469352 5.779739743 0 1 41.31196395 1.80380394 -18 1.2795 -15.77826137 3.217317185 0654 0.8292 -0.762267385 4.368706009 0 1 36.02556326 1.374900816 -18 1.2795 -9.807247718 2.825622158 0654 0.8292 0.068940426 4.626034858 0 1 36.96844917 1.268471338 -18 1.2795 -16.44595963 2.711807814 0654 0.8292 7.134405715 5.250470056 0 1 35.71638313 1.484103611 -18 1.2795 -16.03954401 2.801166319 0654 0.8292 4.906793237 3.990368082 0 1 39.90993228 2.004543864 -18 1.2795 -3.90638961 3.788713993 0654 0.8292 6.75769425 4.083001201 0 1 33.21129944 1.801166169 -18 1.2795 -5.761492277 3.650022139 0654 0.8292 1.37335563 3.787646841 0 1 43.29000235 2.044266751 -18 1.2795 -4.534789093 3.816502022 0436Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFTi Intercept Ti Slope U U +/- U Intercept U Slope V V +/- V Intercept V Slope W W +/- W InterceptD.7 fp-XRF Soil Mode654 0.8292 2.004394803 3.974012516 0 1 44.96957975 2.076726593 -18 1.2795 -10.52136441 3.744719829 0654 0.8292 2.669749509 3.571269525 0 1 36.3517912 1.970606935 -18 1.2795 -4.367068349 3.884916038 0654 0.8292 0.47399695 3.607358468 0 1 36.18448908 1.854313037 -18 1.2795 -5.090081472 3.69557706 0654 0.8292 5.313741151 4.023922519 0 1 40.62528196 2.003193506 -18 1.2795 -11.44055827 3.501849466 0654 0.8292 -0.505803358 4.680237576 0 1 22.33479363 1.128592813 -18 1.2795 -16.83017031 2.740331816 0654 0.8292 4.396235327 5.220637089 0 1 21.75803687 1.060138093 -18 1.2795 -11.96727367 2.848036736 0654 0.8292 -3.935895284 3.712876493 0 1 34.62698269 1.891479536 -18 1.2795 -6.664610337 3.628123257 0654 0.8292 4.236333301 3.78946421 0 1 38.25221219 1.931139799 -18 1.2795 -2.948357512 3.749762317 0654 0.8292 8.537330058 4.918941681 0 1 28.18468602 1.161453436 -18 1.2795 -12.49287283 2.779322189 0654 0.8292 2.481333113 4.00448635 0 1 40.3131994 2.019364422 -18 1.2795 -8.242526511 3.731404033 0654 0.8292 5.669007861 3.724397857 0 1 35.04844556 1.822752524 -18 1.2795 -8.631290828 3.607678964 0654 0.8292 8.808518081 4.562427883 0 1 116.8154291 5.836562627 -18 1.2795 -16.36080084 4.774593898 0654 0.8292 2.1043997 3.58069856 0 1 36.83259179 1.82828844 -18 1.2795 -0.399977975 3.849736657 0654 0.8292 -3.472703516 3.918825405 0 1 49.16174885 2.65356801 -18 1.2795 -6.448491786 4.156189401 0654 0.8292 2.04094784 3.768728346 0 1 44.22089425 2.158105685 -18 1.2795 -3.838787413 3.919043558 0654 0.8292 0.852084806 3.977353177 0 1 41.32894113 2.139171864 -18 1.2795 -4.490876307 3.832499302 0654 0.8292 1.062526434 3.828159464 0 1 42.64971814 2.083075642 -18 1.2795 -2.62069474 3.794549535 0654 0.8292 4.486823764 3.989446529 0 1 39.74132218 2.046082573 -18 1.2795 -3.568402748 3.806408098 0654 0.8292 13.66664251 4.204462484 0 1 43.98949923 2.214248466 -18 1.2795 -5.443337972 3.858674661 0654 0.8292 7.88262597 3.948100948 0 1 39.41372632 2.014000449 -18 1.2795 -6.991493738 3.738909914 0654 0.8292 22.11791277 5.7844306 0 1 22.94294647 1.002221531 -18 1.2795 -15.1800629 2.624829117 0654 0.8292 4.615252456 4.101025198 0 1 50.30000816 2.352173954 -18 1.2795 -1.878430444 4.068818452 0654 0.8292 -4.91350619 3.591924061 0 1 52.83641677 2.341326986 -18 1.2795 -6.353531119 3.906359425 0654 0.8292 -0.17847224 3.829074823 0 1 43.80421951 2.155073347 -18 1.2795 -5.442348492 3.866806363 0654 0.8292 0.971822414 3.695056193 0 1 36.30456064 1.953996842 -18 1.2795 -5.405320114 3.725428182 0654 0.8292 6.195154466 3.797203637 0 1 33.12392877 1.838648549 -18 1.2795 -3.118411521 3.742151109 0654 0.8292 3.457582387 3.761183411 0 1 34.78652508 1.795654861 -18 1.2795 -3.56876206 3.688355073 0437Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFW Slope Y Y +/- Y Intercept Y Slope Zn Zn +/- Zn Intercept Zn Slope Zr Zr +/- Zr Intercept Zr Slope1 9.278979942 1.361439412 3 0.8801 16.85450499 1.51814827 2 1.0984 194.8039859 4.909401348 31 0.58281 9.283836009 1.415490753 3 0.8801 20.83796049 1.597387956 2 1.0984 239.8207309 5.607044709 31 0.58281 11.08509993 1.509972682 3 0.8801 23.97967521 1.835527396 2 1.0984 247.9406184 5.912854947 31 0.58281 15.25625459 1.959254072 3 0.8801 9.024836789 1.208123298 2 1.0984 76.36915511 4.310324563 31 0.58281 10.76096599 1.518086849 3 0.8801 17.94418726 1.492881231 2 1.0984 248.463144 5.909415187 31 0.58281 12.12396414 1.47579971 3 0.8801 16.60215296 1.509739422 2 1.0984 213.612129 5.281225635 31 0.58281 14.14084633 1.471671697 3 0.8801 17.09789764 1.528660339 2 1.0984 215.1284324 5.113563508 31 0.58281 7.57809252 1.369820258 3 0.8801 19.08668743 1.568103878 2 1.0984 257.4040828 5.635993883 31 0.58281 9.482486267 1.400972938 3 0.8801 17.93152851 1.565323317 2 1.0984 264.1739356 5.737392257 31 0.58281 11.12665207 1.47777825 3 0.8801 18.21053026 1.547770238 2 1.0984 236.801624 5.59737078 31 0.58281 10.47917852 1.467165154 3 0.8801 18.63660851 1.574957416 2 1.0984 243.2872469 5.622690215 31 0.58281 14.40150518 1.483394936 3 0.8801 19.70800473 1.586085532 2 1.0984 248.1224619 5.519199451 31 0.58281 9.708632577 1.459575682 3 0.8801 21.23871436 1.600550406 2 1.0984 240.841584 5.695349622 31 0.58281 25.25752227 2.462505878 3 0.8801 37.94434249 2.249728308 2 1.0984 634.7798887 12.23183711 31 0.58281 13.21194938 1.548680521 3 0.8801 17.76738974 1.531961953 2 1.0984 253.2637041 5.801640794 31 0.58281 10.32965677 1.430308731 3 0.8801 21.02188344 1.60626468 2 1.0984 269.3618318 5.873424005 31 0.58281 15.38880531 1.541055044 3 0.8801 21.03190719 1.58081261 2 1.0984 237.155112 5.50305147 31 0.58281 12.57272677 1.469115597 3 0.8801 17.74793365 1.541833839 2 1.0984 235.4700244 5.421341493 31 0.58281 13.70211413 1.494711805 3 0.8801 15.3391811 1.476017572 2 1.0984 227.7485957 5.333338972 31 0.58281 11.95751205 1.495135506 3 0.8801 16.16933262 1.506949719 2 1.0984 236.557681 5.505818565 31 0.58281 14.13947217 1.498500635 3 0.8801 21.6495178 1.611227879 2 1.0984 233.1041912 5.447054199 31 0.58281 10.42267163 1.600373688 3 0.8801 22.72669224 1.778912841 2 1.0984 218.3591073 5.917651274 31 0.58281 9.267768181 1.381247768 3 0.8801 15.8904486 1.471456196 2 1.0984 240.1539146 5.492472367 31 0.58281 31.55288638 1.938837794 3 0.8801 24.90708026 1.681351223 2 1.0984 275.7777883 6.073466496 31 0.58281 17.05096712 1.635853273 3 0.8801 22.79197883 1.667528408 2 1.0984 270.5431507 5.93476517 31 0.58281 12.10964407 1.549127149 3 0.8801 19.89943877 1.556882481 2 1.0984 233.3707498 5.692990871 31 0.58281 11.17285744 1.505804615 3 0.8801 18.27841871 1.571903791 2 1.0984 234.986011 5.597979964 31 0.58281 9.927010358 1.446431071 3 0.8801 17.59378267 1.53694273 2 1.0984 216.0240492 5.286328889 31 0.58281 10.11052704 1.482430323 3 0.8801 20.24007472 1.607210529 2 1.0984 271.0869157 6.049680154 31 0.58281 12.37200562 1.4643527 3 0.8801 18.09019453 1.519615753 2 1.0984 228.7456762 5.435923008 31 0.58281 16.95548781 1.730731979 3 0.8801 28.73382751 1.773230576 2 1.0984 245.7587124 5.929074545 31 0.58281 22.28653926 2.256710263 3 0.8801 7.601309034 1.194615842 2 1.0984 185.772281 6.495767682 31 0.58281 7.352958803 1.285023148 3 0.8801 13.13604519 1.387623202 2 1.0984 155.1167769 4.487172608 31 0.58281 9.934521442 1.898758837 3 0.8801 0.959679315 1.151783118 2 1.0984 45.14610256 3.994595515 31 0.58281 6.817033436 1.551879736 3 0.8801 0.36680082 1.051248724 2 1.0984 19.0780178 2.94028754 31 0.58281 22.27086288 2.378175079 3 0.8801 36.47812747 2.221408949 2 1.0984 638.5546981 12.22365854 31 0.58281 5.200369765 1.496987306 3 0.8801 0.804619199 1.045529493 2 1.0984 22.52899069 2.984465121 31 0.58281 11.8911547 1.968400191 3 0.8801 4.536316005 1.087558876 2 1.0984 107.0950942 5.143532469 31 0.5828D.7 fp-XRF Soil Mode438Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFW Slope Y Y +/- Y Intercept Y Slope Zn Zn +/- Zn Intercept Zn Slope Zr Zr +/- Zr Intercept Zr SlopeD.7 fp-XRF Soil Mode1 7.50697629 1.507294664 3 0.8801 12.9894329 1.372900004 2 1.0984 239.1710883 5.982358104 31 0.58281 13.52036717 1.670633783 3 0.8801 18.39857185 1.547614469 2 1.0984 280.3397711 6.405801379 31 0.58281 13.02072412 1.641220598 3 0.8801 18.44220045 1.531272332 2 1.0984 311.6907498 6.779490666 31 0.58281 11.36218384 1.49677783 3 0.8801 14.66656203 1.468800236 2 1.0984 253.3718124 5.808224918 31 0.58281 12.36818061 1.676724708 3 0.8801 14.48871548 1.450951582 2 1.0984 255.3761874 6.31906749 31 0.58281 9.607991297 1.425882582 3 0.8801 19.09322235 1.55694476 2 1.0984 244.155063 5.623592891 31 0.58281 14.69426251 1.549058118 3 0.8801 15.90587894 1.489524166 2 1.0984 235.0049657 5.49351522 31 0.58281 9.435796176 1.493651046 3 0.8801 24.14800924 1.649989779 2 1.0984 230.9342753 5.583629184 31 0.58281 6.883385691 1.354505062 3 0.8801 18.8576613 1.562020494 2 1.0984 221.9496022 5.442731802 31 0.58281 12.91999019 1.555991474 3 0.8801 22.314991 1.629842535 2 1.0984 262.727329 5.998223258 31 0.58281 14.71340164 1.623205704 3 0.8801 19.47126041 1.574404824 2 1.0984 224.4003595 5.599940242 31 0.58281 10.06912477 1.49857374 3 0.8801 19.3903274 1.585681146 2 1.0984 275.4479994 6.087918741 31 0.58281 11.17214434 1.512658993 3 0.8801 22.08063349 1.622387711 2 1.0984 251.2886514 5.784958535 31 0.58281 9.697031172 1.387874312 3 0.8801 21.61004556 1.606520988 2 1.0984 228.9031525 5.282006274 31 0.58281 11.23936548 1.596435442 3 0.8801 19.05137644 1.579476276 2 1.0984 251.6920662 6.050652081 31 0.58281 13.16153893 1.567408958 3 0.8801 21.01345334 1.618737566 2 1.0984 253.9830832 5.91058898 31 0.58281 15.26669232 1.699935419 3 0.8801 21.78030488 1.645494646 2 1.0984 274.7896767 6.432896926 31 0.58281 9.573412784 1.516891061 3 0.8801 17.44123353 1.536353428 2 1.0984 253.500324 6.028314146 31 0.58281 6.582550227 1.367890495 3 0.8801 11.51187444 1.404886381 2 1.0984 193.0403195 5.113977865 31 0.58281 21.7984817 2.353158201 3 0.8801 36.01171028 2.212686682 2 1.0984 635.2986689 12.08937926 31 0.58281 7.519934805 1.405800817 3 0.8801 12.37357631 1.410784899 2 1.0984 201.4997752 5.230228632 31 0.58281 14.21922038 1.672135828 3 0.8801 24.57736737 1.688811058 2 1.0984 293.5979637 6.477276263 31 0.58281 14.89068145 1.716925699 3 0.8801 25.43419814 1.6983918 2 1.0984 263.7060588 6.16910481 31 0.58281 9.790960799 1.491505739 3 0.8801 16.65533051 1.54481929 2 1.0984 218.7750598 5.565432748 31 0.58281 10.78000513 1.601619781 3 0.8801 26.48123157 1.711646893 2 1.0984 253.2374335 6.093417016 31 0.58281 13.09226827 1.713210532 3 0.8801 30.20686234 1.791083872 2 1.0984 266.0957091 6.444767754 31 0.58281 26.0356628 2.031524456 3 0.8801 17.78369483 1.553498126 2 1.0984 312.6280906 7.131258799 31 0.58281 14.23281987 1.599257427 3 0.8801 16.68900867 1.534368677 2 1.0984 286.0291162 6.358859206 31 0.58281 9.808250368 1.531526264 3 0.8801 16.08510238 1.513071545 2 1.0984 262.9977544 6.24012384 31 0.58281 10.23230516 1.559279851 3 0.8801 18.5878779 1.554704438 2 1.0984 264.9068095 6.137807544 31 0.58281 14.244758 1.652977306 3 0.8801 14.9664042 1.493693177 2 1.0984 264.8005334 6.193977129 31 0.58281 10.27469069 1.498578899 3 0.8801 18.46206355 1.563427981 2 1.0984 226.3846625 5.599688544 31 0.58281 14.40030289 1.73176787 3 0.8801 18.27116108 1.551343805 2 1.0984 255.9049208 6.323992395 31 0.58281 14.02138493 1.585423338 3 0.8801 16.65895517 1.500973412 2 1.0984 232.5149177 5.711100819 31 0.58281 8.476979273 1.512111827 3 0.8801 15.3029977 1.487728341 2 1.0984 229.3822758 5.837084136 31 0.58281 12.47625046 1.539815681 3 0.8801 18.47137981 1.564023315 2 1.0984 246.7208456 5.826488865 31 0.58281 11.61386116 1.513809116 3 0.8801 15.26848417 1.520132735 2 1.0984 243.2705431 5.688943832 31 0.5828439Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFW Slope Y Y +/- Y Intercept Y Slope Zn Zn +/- Zn Intercept Zn Slope Zr Zr +/- Zr Intercept Zr SlopeD.7 fp-XRF Soil Mode1 14.38592217 1.621827328 3 0.8801 14.30187376 1.491175768 2 1.0984 249.6569307 5.999311929 31 0.58281 8.640828729 1.42889988 3 0.8801 21.31229688 1.620061205 2 1.0984 196.0242391 5.10735865 31 0.58281 11.49560358 1.516246824 3 0.8801 19.84882504 1.606530408 2 1.0984 248.8578371 5.707013385 31 0.58281 10.71750181 1.46476397 3 0.8801 19.97409752 1.609980322 2 1.0984 212.0577833 5.256106154 31 0.58281 27.95399522 2.520060856 3 0.8801 37.2309043 2.230530273 2 1.0984 644.6210923 12.32826721 31 0.58281 9.363226187 1.405289936 3 0.8801 21.18323497 1.609370725 2 1.0984 211.2364644 5.241994296 31 0.58281 10.32688044 1.514052263 3 0.8801 24.34361853 1.692699207 2 1.0984 248.808279 5.777110627 31 0.58281 11.19763686 1.481214498 3 0.8801 18.25723113 1.548078609 2 1.0984 206.4810985 5.232836723 31 0.58281 6.537910099 1.300242855 3 0.8801 16.57636989 1.508636661 2 1.0984 243.2134685 5.46818109 31 0.58281 8.450516431 1.391998279 3 0.8801 10.58604747 1.351288367 2 1.0984 203.3372014 5.229079291 31 0.58281 12.69107282 1.59161115 3 0.8801 11.49163909 1.351325493 2 1.0984 238.8380593 5.82493947 31 0.58281 12.55179466 1.564412628 3 0.8801 22.55078042 1.621948001 2 1.0984 273.8780187 6.226688409 31 0.58281 14.94947353 1.637763337 3 0.8801 19.22246457 1.566774389 2 1.0984 245.7218936 5.840769851 31 0.58281 9.39942655 1.393344869 3 0.8801 19.34030237 1.554065443 2 1.0984 235.6407611 5.517160804 31 0.58281 14.22240519 1.64486344 3 0.8801 20.67358206 1.630100123 2 1.0984 296.2598924 6.460700968 31 0.58281 11.26738072 1.605905647 3 0.8801 19.35442548 1.565038871 2 1.0984 269.8443658 6.297339852 31 0.58281 10.31547134 1.575015131 3 0.8801 21.89182483 1.590573373 2 1.0984 249.4179623 6.076391363 31 0.58281 8.313281184 1.321169255 3 0.8801 9.773158073 1.307108391 2 1.0984 182.7564249 4.810403065 31 0.58281 8.197255062 1.323877511 3 0.8801 11.77121507 1.355482375 2 1.0984 197.1430555 5.054129287 31 0.58281 13.80450363 1.895564454 3 0.8801 5.318907601 1.132460978 2 1.0984 212.6743023 6.509210194 31 0.58281 13.45505181 1.676204394 3 0.8801 13.68404133 1.411016036 2 1.0984 248.8961971 6.142058306 31 0.58281 10.87861529 1.591558561 3 0.8801 14.18928506 1.423489914 2 1.0984 254.4509727 6.146555219 31 0.58281 11.01331866 1.915678411 3 0.8801 6.109317688 1.211353932 2 1.0984 36.60882156 3.660837193 31 0.58281 14.93284326 1.995507117 3 0.8801 5.344619424 1.121938828 2 1.0984 59.56061722 4.146839786 31 0.58281 11.08703092 1.498052127 3 0.8801 18.08108198 1.555237383 2 1.0984 238.6950813 5.641591672 31 0.58281 10.30034634 1.497261278 3 0.8801 15.6668903 1.47512677 2 1.0984 254.3380511 5.892791509 31 0.58281 20.80900204 2.30262308 3 0.8801 36.30168305 2.20057144 2 1.0984 629.0940441 12.0000501 31 0.58281 13.09463794 1.534139404 3 0.8801 18.58065836 1.520478637 2 1.0984 254.6067167 5.899617799 31 0.58281 11.45595059 1.512040866 3 0.8801 15.26415625 1.46760447 2 1.0984 227.7638406 5.564421049 31 0.58281 12.73394804 1.687798998 3 0.8801 23.36293173 1.647473192 2 1.0984 262.5353387 6.344625104 31 0.58281 17.16775052 2.447804797 3 0.8801 15.0914741 1.389008291 2 1.0984 238.730947 7.805900247 31 0.58281 10.13919798 1.857969121 3 0.8801 4.16606652 1.097088065 2 1.0984 79.80509256 4.480608551 31 0.58281 15.85453405 2.089701532 3 0.8801 8.300312671 1.232984713 2 1.0984 53.91330856 4.091739571 31 0.58281 20.76875718 2.345191341 3 0.8801 6.562413784 1.19888987 2 1.0984 99.69716042 5.24858517 31 0.58281 14.83228609 1.594962665 3 0.8801 14.35398101 1.446462884 2 1.0984 244.0449052 5.775890245 31 0.58281 10.03934667 1.505608404 3 0.8801 12.69720731 1.377546464 2 1.0984 223.1968225 5.653590326 31 0.58281 10.44190841 1.486657677 3 0.8801 18.61546195 1.543137906 2 1.0984 244.5027809 5.710640311 31 0.5828440Sample IDQ515673Q515674Q515675Q515676Q515678Q515679Q515680Q515681Q515682Q515683Q515685OREAS25aQ515685DUPQ515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515696Q515697Q515698Q515699Q515700Cal Checkfp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFW Slope Y Y +/- Y Intercept Y Slope Zn Zn +/- Zn Intercept Zn Slope Zr Zr +/- Zr Intercept Zr SlopeD.7 fp-XRF Soil Mode1 12.99097102 1.595648654 3 0.8801 20.31683091 1.563445474 2 1.0984 243.850936 5.869373482 31 0.58281 8.989830984 1.353731982 3 0.8801 16.78306369 1.507706303 2 1.0984 228.1156915 5.233040838 31 0.58281 7.80086494 1.35418333 3 0.8801 12.93128069 1.405556148 2 1.0984 197.8170896 5.012516328 31 0.58281 14.96757961 1.595287528 3 0.8801 15.73387101 1.441013035 2 1.0984 256.8672313 5.931352765 31 0.58281 7.273608075 1.808185406 3 0.8801 5.667367347 1.250109399 2 1.0984 89.1939392 5.042500527 31 0.58281 14.25625638 2.131442685 3 0.8801 2.432991377 1.213903198 2 1.0984 57.69346367 4.389481609 31 0.58281 13.1808683 1.599048145 3 0.8801 13.17592854 1.401743132 2 1.0984 229.0983081 5.70554457 31 0.58281 11.01341595 1.448764976 3 0.8801 15.40320572 1.455449748 2 1.0984 235.773496 5.524966277 31 0.58281 9.720255523 1.775426184 3 0.8801 4.621535862 1.184763469 2 1.0984 64.82377875 4.232441517 31 0.58281 12.16158633 1.613553819 3 0.8801 17.36445594 1.507158746 2 1.0984 246.151286 5.99345824 31 0.58281 10.29390592 1.373179821 3 0.8801 14.10038932 1.422071063 2 1.0984 212.8805394 5.147792331 31 0.58281 21.00374127 2.337485178 3 0.8801 37.21514763 2.229179192 2 1.0984 659.7974873 12.43420357 31 0.58281 8.865468047 1.34376657 3 0.8801 13.07262864 1.420965005 2 1.0984 201.7842846 4.975579422 31 0.58281 12.17514975 1.596426974 3 0.8801 35.01009719 1.957160969 2 1.0984 201.5198145 5.525325881 31 0.58281 11.15915232 1.513507985 3 0.8801 21.12426788 1.618410107 2 1.0984 283.7527837 6.143248486 31 0.58281 13.96951654 1.652378759 3 0.8801 19.54410451 1.577801436 2 1.0984 265.845852 6.240074175 31 0.58281 13.22533855 1.554024352 3 0.8801 16.16826694 1.500241562 2 1.0984 246.6225403 5.796987794 31 0.58281 13.27566036 1.607756156 3 0.8801 20.01161226 1.583295899 2 1.0984 241.8870389 5.829331578 31 0.58281 12.27027154 1.522565966 3 0.8801 22.14229242 1.629814916 2 1.0984 241.4444249 5.696703717 31 0.58281 11.25456135 1.437766018 3 0.8801 17.97094331 1.519909623 2 1.0984 209.903478 5.266685663 31 0.58281 15.93593154 2.085512116 3 0.8801 4.574879403 1.219016548 2 1.0984 44.99470535 3.803220498 31 0.58281 11.61531001 1.617366666 3 0.8801 28.12973697 1.768436059 2 1.0984 253.1976275 6.037870948 31 0.58281 12.89147891 1.582338538 3 0.8801 24.93850158 1.698637726 2 1.0984 274.2434452 6.13821202 31 0.58281 10.19034684 1.517655803 3 0.8801 18.11857591 1.568961959 2 1.0984 241.3992131 5.79272908 31 0.58281 14.16445984 1.528014277 3 0.8801 12.79978966 1.406283757 2 1.0984 234.8841413 5.480234909 31 0.58281 10.26294628 1.396254435 3 0.8801 15.54746448 1.458821342 2 1.0984 216.4897312 5.219872883 31 0.58281 8.040048482 1.357443409 3 0.8801 9.142142443 1.309297302 2 1.0984 194.5764301 5.029253854 31 0.5828441fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSample ID Sample Type Site Mode Elapsed Time 1 Elapsed Time 2 Elapsed Time Total Live Time 1 Live Time 2 Live Time Total Instrument SN Model Tube Anode UnitCal Check Cal Check Cal Check 14.74 0 14.74 11.68 0 11.68 550271 DELTA_SDD 47 PPMOREAS25a Standard Geochem 29.807 29.495 59.302 25.704 20.189 45.893 550271 DELTA_SDD 47 PPMQ515501 Soil 26 Geochem 29.678 29.762 59.44 24.847 23.276 48.123 550271 DELTA_SDD 47 PPMQ515502 Soil 27 Geochem 29.708 29.764 59.472 24.975 23.456 48.431 550271 DELTA_SDD 47 PPMQ515503 Soil 28 Geochem 29.726 29.634 59.36 25.167 21.863 47.03 550271 DELTA_SDD 47 PPMQ515504 Soil 29 Geochem 29.842 29.672 59.514 25.485 22.803 48.288 550271 DELTA_SDD 47 PPMQ515505 Soil 30 Geochem 29.725 29.767 59.492 25.037 23.459 48.496 550271 DELTA_SDD 47 PPMQ515506 Soil 31 Geochem 29.708 29.771 59.479 24.945 23.47 48.415 550271 DELTA_SDD 47 PPMQ515507 Soil 125 Geochem 29.684 29.759 59.443 24.89 23.286 48.176 550271 DELTA_SDD 47 PPMQ515508 Soil 124 Geochem 29.688 29.745 59.433 24.91 22.99 47.9 550271 DELTA_SDD 47 PPMQ515509 Soil 123 Geochem 29.661 29.754 59.415 24.851 23.146 47.997 550271 DELTA_SDD 47 PPMQ515510 Soil 122 Geochem 29.704 29.757 59.461 24.932 23.241 48.173 550271 DELTA_SDD 47 PPMQ515511 Soil 121 Geochem 29.705 29.756 59.461 24.971 23.321 48.292 550271 DELTA_SDD 47 PPMQ515512 Soil 120 Geochem 29.683 29.743 59.426 24.88 22.956 47.836 550271 DELTA_SDD 47 PPMQ515513 Soil 119 Geochem 29.715 29.761 59.476 25.015 23.411 48.426 550271 DELTA_SDD 47 PPMQ515514 Soil 118 Geochem 29.7 29.752 59.452 24.952 23.148 48.1 550271 DELTA_SDD 47 PPMQ515515 Soil 117 Geochem 29.695 29.753 59.448 24.925 23.199 48.124 550271 DELTA_SDD 47 PPMQ515516 Soil 116 Geochem 29.699 29.743 59.442 24.911 22.975 47.886 550271 DELTA_SDD 47 PPMQ515517 Soil 14 Geochem 29.691 29.763 59.454 24.923 23.349 48.272 550271 DELTA_SDD 47 PPMQ515518 Soil 15 Geochem 29.697 29.758 59.455 24.927 23.306 48.233 550271 DELTA_SDD 47 PPMQ515519 Soil 13 Geochem 29.698 29.749 59.447 24.941 23.182 48.123 550271 DELTA_SDD 47 PPMQ515520 Soil 12 Geochem 29.763 29.62 59.383 25.373 21.816 47.189 550271 DELTA_SDD 47 PPMOREAS25a Standard Geochem 29.799 29.5 59.299 25.647 20.248 45.895 550271 DELTA_SDD 47 PPMQ515520DUP Duplicate Geochem 29.764 29.617 59.381 25.33 21.763 47.093 550271 DELTA_SDD 47 PPMCal Check Cal Check Cal Check 14.721 0 14.721 11.506 0 11.506 550271 DELTA_SDD 47 PPMOREAS25a Standard Geochem 29.813 29.493 59.306 25.558 20.243 45.801 550271 DELTA_SDD 47 PPMQ515521 Soil 11 Geochem 29.696 29.758 59.454 24.862 23.266 48.128 550271 DELTA_SDD 47 PPMQ515522 Soil 10 Geochem 29.709 29.748 59.457 24.978 23.157 48.135 550271 DELTA_SDD 47 PPMQ515523 Soil 9 Geochem 29.705 29.745 59.45 24.935 23.155 48.09 550271 DELTA_SDD 47 PPMQ515524 Soil 8 Geochem 29.716 29.748 59.464 24.976 23.201 48.177 550271 DELTA_SDD 47 PPMQ515525 Soil 7 Geochem 29.71 29.746 59.456 24.971 23.193 48.164 550271 DELTA_SDD 47 PPMQ515526 Soil 115 Geochem 29.699 29.755 59.454 24.928 23.271 48.199 550271 DELTA_SDD 47 PPMQ515527 Soil 114 Geochem 29.716 29.755 59.471 24.999 23.339 48.338 550271 DELTA_SDD 47 PPMQ515528 Soil 113 Geochem 29.699 29.767 59.466 24.926 23.42 48.346 550271 DELTA_SDD 47 PPMQ515529 Soil 112 Geochem 29.729 29.74 59.469 25.07 23.113 48.183 550271 DELTA_SDD 47 PPMQ515530 Soil 6 Geochem 29.828 29.787 59.615 25.38 24.38 49.76 550271 DELTA_SDD 47 PPMQ515531 Soil 5 Geochem 29.7 29.785 59.485 24.973 23.751 48.724 550271 DELTA_SDD 47 PPMQ515551 Soil 77 Geochem 29.878 29.722 59.6 25.313 23.72 49.033 550271 DELTA_SDD 47 PPMD.8 fp-XRF Geochem Mode442fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSample ID Sample Type Site Mode Elapsed Time 1 Elapsed Time 2 Elapsed Time Total Live Time 1 Live Time 2 Live Time Total Instrument SN Model Tube Anode UnitD.8 fp-XRF Geochem ModeQ515552 Soil 78 Geochem 29.84 29.713 59.553 25.279 23.652 48.931 550271 DELTA_SDD 47 PPMQ515553 Soil 79 Geochem 29.846 29.73 59.576 25.475 23.638 49.113 550271 DELTA_SDD 47 PPMQ515554 Soil 95 Geochem 29.742 29.773 59.515 25.124 23.515 48.639 550271 DELTA_SDD 47 PPMQ515555 Soil 94 Geochem 29.74 29.768 59.508 25.115 23.458 48.573 550271 DELTA_SDD 47 PPMQ515556 Soil 93 Geochem 29.739 29.767 59.506 25.117 23.492 48.609 550271 DELTA_SDD 47 PPMQ515557 Soil 92 Geochem 29.712 29.752 59.464 25.048 23.182 48.23 550271 DELTA_SDD 47 PPMQ515558 Soil 91 Geochem 29.748 29.758 59.506 25.173 23.33 48.503 550271 DELTA_SDD 47 PPMQ515559 Soil 90 Geochem 29.699 29.758 59.457 24.966 23.301 48.267 550271 DELTA_SDD 47 PPMOREAS25a Standard Geochem 29.802 29.501 59.303 25.658 20.282 45.94 550271 DELTA_SDD 47 PPMQ515559DUP Duplicate Geochem 29.7 29.758 59.458 24.952 23.304 48.256 550271 DELTA_SDD 47 PPMQ515560 Soil 89 Geochem 29.697 29.757 59.454 24.973 23.275 48.248 550271 DELTA_SDD 47 PPMQ515561 Soil 88 Geochem 29.718 29.748 59.466 25.082 23.221 48.303 550271 DELTA_SDD 47 PPMQ515562 Soil 87 Geochem 29.72 29.753 59.473 25.069 23.336 48.405 550271 DELTA_SDD 47 PPMQ515563 Soil 86 Geochem 29.723 29.756 59.479 25.083 23.288 48.371 550271 DELTA_SDD 47 PPMQ515564 Soil 85 Geochem 29.72 29.759 59.479 25.061 23.343 48.404 550271 DELTA_SDD 47 PPMQ515565 Soil 84 Geochem 29.733 29.749 59.482 25.096 23.158 48.254 550271 DELTA_SDD 47 PPMQ515566 Soil 83 Geochem 29.715 29.749 59.464 25.047 23.144 48.191 550271 DELTA_SDD 47 PPMQ515567 Soil 82 Geochem 29.694 29.753 59.447 25.007 23.165 48.172 550271 DELTA_SDD 47 PPMQ515568 Soil 81 Geochem 29.756 29.752 59.508 25.173 23.263 48.436 550271 DELTA_SDD 47 PPMQ515569 Soil 80 Geochem 29.718 29.758 59.476 25.048 23.308 48.356 550271 DELTA_SDD 47 PPMQ515570 Soil 96 Geochem 29.745 29.753 59.498 25.203 23.301 48.504 550271 DELTA_SDD 47 PPMQ515571 Soil 97 Geochem 29.734 29.765 59.499 25.156 23.47 48.626 550271 DELTA_SDD 47 PPMQ515572 Soil 98 Geochem 29.722 29.772 59.494 25.049 23.603 48.652 550271 DELTA_SDD 47 PPMQ515573 Soil 99 Geochem 29.728 29.743 59.471 25.174 23.021 48.195 550271 DELTA_SDD 47 PPMQ515574 Soil 100 Geochem 29.738 29.739 59.477 25.157 23.05 48.207 550271 DELTA_SDD 47 PPMQ515575 Soil 101 Geochem 29.727 29.765 59.492 25.076 23.505 48.581 550271 DELTA_SDD 47 PPMQ515576 Soil 102 Geochem 29.736 29.741 59.477 25.153 23.046 48.199 550271 DELTA_SDD 47 PPMQ515577 Soil 103 Geochem 29.753 29.76 59.513 25.211 23.414 48.625 550271 DELTA_SDD 47 PPMQ515578 Soil 104 Geochem 29.753 29.758 59.511 25.167 23.344 48.511 550271 DELTA_SDD 47 PPMQ515579 Soil 105 Geochem 29.729 29.753 59.482 25.099 23.289 48.388 550271 DELTA_SDD 47 PPMOREAS25a Standard Geochem 29.803 29.501 59.304 25.691 20.241 45.932 550271 DELTA_SDD 47 PPMQ515579DUP Duplicate Geochem 29.729 29.754 59.483 25.114 23.295 48.409 550271 DELTA_SDD 47 PPMQ515580 Soil 106 Geochem 29.741 29.764 59.505 25.131 23.503 48.634 550271 DELTA_SDD 47 PPMQ515581 Soil 107 Geochem 29.726 29.757 59.483 25.111 23.264 48.375 550271 DELTA_SDD 47 PPMQ515582 Soil 108 Geochem 29.736 29.768 59.504 25.135 23.459 48.594 550271 DELTA_SDD 47 PPMQ515583 Field Duplicate 108b Geochem 29.723 29.763 59.486 25.06 23.395 48.455 550271 DELTA_SDD 47 PPMQ515584 Soil 109 Geochem 29.746 29.761 59.507 25.187 23.334 48.521 550271 DELTA_SDD 47 PPMQ515585 Soil 110 Geochem 29.727 29.756 59.483 25.121 23.199 48.32 550271 DELTA_SDD 47 PPM443fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSample ID Sample Type Site Mode Elapsed Time 1 Elapsed Time 2 Elapsed Time Total Live Time 1 Live Time 2 Live Time Total Instrument SN Model Tube Anode UnitD.8 fp-XRF Geochem ModeQ515586 Soil 111 Geochem 29.765 29.761 59.526 25.154 23.394 48.548 550271 DELTA_SDD 47 PPMQ515587 Soil 127 Geochem 29.726 29.763 59.489 25.108 23.39 48.498 550271 DELTA_SDD 47 PPMQ515588 Soil 126 Geochem 29.731 29.758 59.489 25.066 23.269 48.335 550271 DELTA_SDD 47 PPMQ515589 Field Duplicate 126b Geochem 29.728 29.762 59.49 25.092 23.398 48.49 550271 DELTA_SDD 47 PPMCal Check Cal Check Cal Check 0 0 0 0 0 0 550271 DELTA_SDD 47 PPMQ515590 Soil 16 Geochem 29.712 29.757 59.469 25.011 23.355 48.366 550271 DELTA_SDD 47 PPMQ515591 Soil 17 Geochem 29.706 29.75 59.456 24.99 23.145 48.135 550271 DELTA_SDD 47 PPMQ515592 Soil 18 Geochem 29.707 29.747 59.454 25.065 23.224 48.289 550271 DELTA_SDD 47 PPMQ515593 Field Duplicate 18b Geochem 29.715 29.746 59.461 25.055 23.098 48.153 550271 DELTA_SDD 47 PPMQ515594 Soil 19 Geochem 29.714 29.763 59.477 25.054 23.437 48.491 550271 DELTA_SDD 47 PPMQ515595 Soil 20 Geochem 29.698 29.771 59.469 24.953 23.514 48.467 550271 DELTA_SDD 47 PPMQ515596 Soil 21 Geochem 29.717 29.787 59.504 25.049 23.766 48.815 550271 DELTA_SDD 47 PPMQ515597 Soil 22 Geochem 29.735 29.771 59.506 25.185 23.507 48.692 550271 DELTA_SDD 47 PPMQ515598 Soil 23 Geochem 29.754 29.758 59.512 25.164 23.318 48.482 550271 DELTA_SDD 47 PPMQ515599 Soil 24 Geochem 29.724 29.758 59.482 25.106 23.298 48.404 550271 DELTA_SDD 47 PPMOREAS25a Standard Geochem 29.802 29.503 59.305 25.694 20.265 45.959 550271 DELTA_SDD 47 PPMQ515599DUP Duplicate Geochem 29.723 29.757 59.48 25.056 23.265 48.321 550271 DELTA_SDD 47 PPMQ515600 Soil 25 Geochem 29.706 29.771 59.477 25.021 23.383 48.404 550271 DELTA_SDD 47 PPMQ515651 Soil 32 Geochem 29.729 29.75 59.479 25.155 23.179 48.334 550271 DELTA_SDD 47 PPMQ515652 Soil 33 Geochem 29.741 29.752 59.493 25.146 23.253 48.399 550271 DELTA_SDD 47 PPMQ515653 Soil 34 Geochem 29.735 29.75 59.485 25.107 23.151 48.258 550271 DELTA_SDD 47 PPMQ515654 Soil 35 Geochem 29.703 29.792 59.495 24.958 23.809 48.767 550271 DELTA_SDD 47 PPMQ515655 Field Duplicate 35b Geochem 29.708 29.784 59.492 25.054 23.692 48.746 550271 DELTA_SDD 47 PPMQ515657 Soil 36 Geochem 29.802 29.807 59.609 25.321 24.459 49.78 550271 DELTA_SDD 47 PPMQ515658 Soil 37 Geochem 29.755 29.765 59.52 25.165 23.453 48.618 550271 DELTA_SDD 47 PPMQ515659 Soil 38 Geochem 29.747 29.774 59.521 25.156 23.624 48.78 550271 DELTA_SDD 47 PPMQ515660 Soil 39 Geochem 29.885 29.736 59.621 25.327 23.892 49.219 550271 DELTA_SDD 47 PPMQ515661 Soil 40 Geochem 29.856 29.718 59.574 25.417 23.506 48.923 550271 DELTA_SDD 47 PPMQ515662 Soil 41 Geochem 29.718 29.759 59.477 25.077 23.288 48.365 550271 DELTA_SDD 47 PPMQ515663 Soil 42 Geochem 29.721 29.762 59.483 25.096 23.311 48.407 550271 DELTA_SDD 47 PPMQ515664 Soil 43 Geochem 29.724 29.754 59.478 25.108 23.205 48.313 550271 DELTA_SDD 47 PPMQ515665 Soil 44 Geochem 29.771 29.767 59.538 25.207 23.525 48.732 550271 DELTA_SDD 47 PPMQ515666 Soil 45 Geochem 29.85 29.744 59.594 25.49 23.594 49.084 550271 DELTA_SDD 47 PPMQ515667 Soil 46 Geochem 29.847 29.704 59.551 25.54 23.201 48.741 550271 DELTA_SDD 47 PPMQ515668 Soil 47 Geochem 29.866 29.702 59.568 25.413 23.262 48.675 550271 DELTA_SDD 47 PPMQ515669 Soil 63 Geochem 29.858 29.695 59.553 25.564 23.037 48.601 550271 DELTA_SDD 47 PPMQ515670 Soil 62 Geochem 29.713 29.77 59.483 25.074 23.466 48.54 550271 DELTA_SDD 47 PPMOREAS25a Standard Geochem 29.801 29.502 59.303 25.678 20.246 45.924 550271 DELTA_SDD 47 PPM444fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSample ID Sample Type Site Mode Elapsed Time 1 Elapsed Time 2 Elapsed Time Total Live Time 1 Live Time 2 Live Time Total Instrument SN Model Tube Anode UnitD.8 fp-XRF Geochem ModeQ515670DUP Duplicate Geochem 29.719 29.769 59.488 25.078 23.432 48.51 550271 DELTA_SDD 47 PPMQ515671 Soil 61 Geochem 29.737 29.781 59.518 25.117 23.66 48.777 550271 DELTA_SDD 47 PPMQ515672 Soil 60 Geochem 29.718 29.766 59.484 25.056 23.399 48.455 550271 DELTA_SDD 47 PPMQ515673 Soil 59 Geochem 29.726 29.761 59.487 25.084 23.293 48.377 550271 DELTA_SDD 47 PPMQ515674 Soil 58 Geochem 29.689 29.755 59.444 24.983 23.225 48.208 550271 DELTA_SDD 47 PPMQ515675 Soil 57 Geochem 29.701 29.774 59.475 24.985 23.468 48.453 550271 DELTA_SDD 47 PPMQ515676 Soil 56 Geochem 29.714 29.768 59.482 25.05 23.399 48.449 550271 DELTA_SDD 47 PPMQ515678 Soil 54 Geochem 29.865 29.773 59.638 25.432 23.98 49.412 550271 DELTA_SDD 47 PPMQ515679 Field Duplicate 54b Geochem 29.873 29.752 59.625 25.42 23.928 49.348 550271 DELTA_SDD 47 PPMQ515680 Soil 53 Geochem 29.732 29.776 59.508 25.112 23.535 48.647 550271 DELTA_SDD 47 PPMQ515681 Soil 52 Geochem 29.713 29.775 59.488 25.044 23.579 48.623 550271 DELTA_SDD 47 PPMQ515682 Soil 51 Geochem 29.859 29.751 59.61 25.463 23.887 49.35 550271 DELTA_SDD 47 PPMQ515683 Soil 50 Geochem 29.747 29.766 59.513 25.21 23.52 48.73 550271 DELTA_SDD 47 PPMQ515685 Soil 49 Geochem 29.695 29.772 59.467 25.008 23.479 48.487 550271 DELTA_SDD 47 PPMQ515686 Soil 48 Geochem 29.73 29.709 59.439 25.185 22.83 48.015 550271 DELTA_SDD 47 PPMQ515687 Soil 64 Geochem 29.713 29.749 59.462 25.055 23.081 48.136 550271 DELTA_SDD 47 PPMQ515688 Soil 65 Geochem 29.736 29.753 59.489 25.175 23.171 48.346 550271 DELTA_SDD 47 PPMQ515689 Soil 66 Geochem 29.719 29.758 59.477 25.075 23.298 48.373 550271 DELTA_SDD 47 PPMQ515690 Soil 67 Geochem 29.728 29.756 59.484 25.15 23.297 48.447 550271 DELTA_SDD 47 PPMQ515691 Soil 68 Geochem 29.713 29.747 59.46 25.077 23.068 48.145 550271 DELTA_SDD 47 PPMQ515692 Soil 69 Geochem 29.712 29.767 59.479 25.051 23.486 48.537 550271 DELTA_SDD 47 PPMCal Check Cal Check 70 Cal Check 0 0 0 0 0 0 550271 DELTA_SDD 47 PPMOREAS25a Standard Geochem 29.803 29.505 59.308 25.75 20.262 46.012 550271 DELTA_SDD 47 PPMQ515692DUP Duplicate Geochem 29.709 29.765 59.474 25.034 23.403 48.437 550271 DELTA_SDD 47 PPMQ515693 Soil 71 Geochem 29.868 29.749 59.617 25.37 23.956 49.326 550271 DELTA_SDD 47 PPMQ515695 Soil 72 Geochem 29.734 29.75 59.484 25.197 23.222 48.419 550271 DELTA_SDD 47 PPMQ515696 Field Duplicate 72b Geochem 29.725 29.753 59.478 25.119 23.243 48.362 550271 DELTA_SDD 47 PPMQ515697 Soil 73 Geochem 29.726 29.766 59.492 25.079 23.419 48.498 550271 DELTA_SDD 47 PPMQ515698 Soil 74 Geochem 29.699 29.77 59.469 25.013 23.414 48.427 550271 DELTA_SDD 47 PPMQ515699 Soil 75 Geochem 29.694 29.776 59.47 24.975 23.538 48.513 550271 DELTA_SDD 47 PPMQ515700 Soil 76 Geochem 29.709 29.785 59.494 25.029 23.706 48.735 550271 DELTA_SDD 47 PPM445Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFLOD Sigma Al Al +/- Al Intercept Al Slope As As +/- As Intercept As Slope Ba Ba +/- Ba Intercept Ba Slope BiNA3 118045.8081 1093.801238 25162 0.5959 0 33.01281696 0 1 0 86.63222088 73 0.8961 03 55297.05819 696.0992097 25162 0.5959 0 35.89645898 0 1 514.7821891 21.95878392 73 0.8961 03 56833.93854 735.2291456 25162 0.5959 0 39.31181527 0 1 452.2684214 22.26667723 73 0.8961 03 48628.13466 714.6058843 25162 0.5959 20.68011123 4.439391816 0 1 323.1110322 16.33831836 73 0.8961 03 30139.49527 890.664001 25162 0.5959 0 49.60889381 0 1 0 142.8768175 73 0.8961 03 57979.78634 755.2372515 25162 0.5959 0 39.72124672 0 1 491.6841481 23.47460147 73 0.8961 03 57399.57198 735.5689636 25162 0.5959 0 36.37647591 0 1 590.0952033 23.67686694 73 0.8961 03 56582.89223 711.803969 25162 0.5959 0 35.60666059 0 1 560.0774991 22.19507238 73 0.8961 03 62277.41895 729.5769945 25162 0.5959 0 37.0094075 0 1 577.6556242 22.04732528 73 0.8961 03 59854.15199 727.4122932 25162 0.5959 0 38.04880053 0 1 538.8833498 22.28307031 73 0.8961 03 58890.09887 738.448217 25162 0.5959 0 38.84395507 0 1 563.8748075 22.51539169 73 0.8961 03 57375.15199 733.1662249 25162 0.5959 0 37.21040616 0 1 521.4458559 21.7993042 73 0.8961 03 62159.01553 725.2231637 25162 0.5959 12.18632169 3.644079742 0 1 567.5214817 21.88472209 73 0.8961 03 56692.9104 742.5863688 25162 0.5959 0 39.47219004 0 1 511.99043 22.86264638 73 0.8961 03 61088.35979 739.4960929 25162 0.5959 0 37.40925296 0 1 489.4601131 22.05487476 73 0.8961 03 59557.43779 726.7206744 25162 0.5959 0 36.6789175 0 1 501.5889059 21.83229542 73 0.8961 03 64175.07797 744.2836976 25162 0.5959 0 37.79822529 0 1 537.2610485 22.14192158 73 0.8961 03 58815.35286 726.5274032 25162 0.5959 11.4358048 3.498000354 0 1 584.3071244 22.7044861 73 0.8961 03 60892.14597 743.4306066 25162 0.5959 0 36.9153549 0 1 577.8873897 22.68224054 73 0.8961 03 58415.99894 736.7392743 25162 0.5959 0 38.12693437 0 1 552.674833 22.20638573 73 0.8961 03 47569.43194 745.6239916 25162 0.5959 59.41694186 5.812368377 0 1 247.6663741 15.04883085 73 0.8961 03 112139.2715 1061.685018 25162 0.5959 0 32.36365306 0 1 0 86.27221744 73 0.8961 03 47938.42676 751.9839145 25162 0.5959 54.10137795 5.884993597 0 1 276.7829749 15.4410992 73 0.8961 0NA3 115405.5151 1103.790659 25162 0.5959 0 32.0370548 0 1 95.14381152 13.18275053 73 0.8961 03 59812.04194 736.67695 25162 0.5959 14.22009001 3.553492247 0 1 445.5765998 21.774235 73 0.8961 03 64059.06786 777.8020552 25162 0.5959 0 38.67301656 0 1 510.09169 22.25417194 73 0.8961 03 61879.71891 771.2931579 25162 0.5959 0 38.52653448 0 1 560.4038708 21.49437379 73 0.8961 03 61408.27629 772.2433905 25162 0.5959 0 36.10852306 0 1 495.0175726 21.07339674 73 0.8961 03 60434.03195 762.6027958 25162 0.5959 0 35.93099216 0 1 482.7185384 21.31013904 73 0.8961 03 61146.56783 755.7427225 25162 0.5959 0 38.4093828 0 1 474.6271195 22.25588296 73 0.8961 03 60453.28431 769.4268853 25162 0.5959 0 37.32947227 0 1 528.0399517 21.97268757 73 0.8961 03 59036.92492 736.3758457 25162 0.5959 0 35.91440328 0 1 511.6973122 22.54995591 73 0.8961 03 61397.1467 783.5046356 25162 0.5959 0 38.54653793 0 1 498.0828107 21.70983271 73 0.8961 03 47226.00567 986.0382207 25162 0.5959 0 49.88323261 0 1 238.7512643 26.56022932 73 0.8961 03 56031.63275 726.4729415 25162 0.5959 0 36.83775528 0 1 493.7750326 23.25703705 73 0.8961 03 36340.0382 1265.547675 25162 0.5959 0 56.84129109 0 1 0 190.8204492 73 0.8961 0D.8 fp-XRF Geochem Mode446Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFLOD Sigma Al Al +/- Al Intercept Al Slope As As +/- As Intercept As Slope Ba Ba +/- Ba Intercept Ba Slope BiD.8 fp-XRF Geochem Mode3 26308.30154 1185.774432 25162 0.5959 0 59.1036957 0 1 0 187.5968848 73 0.8961 03 40032.59672 1002.072216 25162 0.5959 0 51.36686093 0 1 0 160.2281536 73 0.8961 03 62911.1772 788.5324885 25162 0.5959 0 42.36703516 0 1 500.8247025 24.61045531 73 0.8961 03 63266.86524 791.224452 25162 0.5959 0 40.37232009 0 1 483.5403982 23.02412782 73 0.8961 03 58757.14144 771.6865436 25162 0.5959 0 40.44473268 0 1 485.0321209 23.17103301 73 0.8961 03 63049.16749 756.0211024 25162 0.5959 0 37.48000521 0 1 519.4940347 21.90303587 73 0.8961 03 63949.28608 787.1321778 25162 0.5959 13.1098483 4.129047603 0 1 498.1899185 23.35943901 73 0.8961 03 59827.45312 731.7324042 25162 0.5959 0 37.83880571 0 1 492.2016761 21.67959203 73 0.8961 03 114181.9574 1070.197188 25162 0.5959 0 32.65445331 0 1 0 88.0850427 73 0.8961 03 59184.85434 731.8003453 25162 0.5959 0 39.29919064 0 1 528.5231346 21.96653763 73 0.8961 03 57960.37046 721.384208 25162 0.5959 0 36.43889636 0 1 510.0278705 21.39147023 73 0.8961 03 62177.03249 766.0034125 25162 0.5959 0 38.54277329 0 1 548.3978238 21.83560258 73 0.8961 03 56339.02595 734.7731843 25162 0.5959 12.20425269 3.838942643 0 1 436.2516911 21.47804588 73 0.8961 03 63782.71445 778.3256698 25162 0.5959 0 41.45138863 0 1 520.1687852 22.46871324 73 0.8961 03 59419.03339 745.9399579 25162 0.5959 0 38.18114528 0 1 506.7641505 22.01455911 73 0.8961 03 61070.78437 751.17653 25162 0.5959 0 40.63620571 0 1 535.165915 22.22504038 73 0.8961 03 62723.10639 753.3480439 25162 0.5959 0 39.74401759 0 1 528.2939008 22.2201543 73 0.8961 03 60048.43127 723.7353004 25162 0.5959 0 34.50006512 0 1 524.7803186 21.55684453 73 0.8961 03 62320.75404 777.9098167 25162 0.5959 0 40.19683676 0 1 471.7602303 21.87781861 73 0.8961 03 61298.60201 752.1658244 25162 0.5959 0 39.19502724 0 1 492.0820037 22.42349406 73 0.8961 03 60703.14078 775.4463037 25162 0.5959 0 39.51150835 0 1 506.5149983 22.43683919 73 0.8961 03 59136.57992 760.4898246 25162 0.5959 0 40.41907306 0 1 501.9566087 22.78795622 73 0.8961 03 55884.02712 729.0793089 25162 0.5959 0 37.67056092 0 1 525.7650735 22.46852512 73 0.8961 03 65642.32766 770.675272 25162 0.5959 0 41.06155543 0 1 545.3392154 21.6944109 73 0.8961 03 65811.06393 785.8175232 25162 0.5959 0 41.80832613 0 1 462.8985727 21.38974159 73 0.8961 03 57363.63295 748.4634033 25162 0.5959 0 38.31009247 0 1 470.8049905 21.93812295 73 0.8961 03 64904.46647 777.6848672 25162 0.5959 15.4685865 4.119001988 0 1 516.2710519 22.13714242 73 0.8961 03 65287.30521 815.7428835 25162 0.5959 0 42.45812363 0 1 519.6959578 22.91335475 73 0.8961 03 65718.4538 802.7345346 25162 0.5959 13.00889931 4.264087745 0 1 495.2855198 22.98598843 73 0.8961 03 63175.92891 770.5195545 25162 0.5959 12.47845065 3.989070857 0 1 514.9579633 22.19323969 73 0.8961 03 114342.6762 1062.468657 25162 0.5959 0 32.0522867 0 1 0 86.21682224 73 0.8961 03 62632.29117 765.9615297 25162 0.5959 0 39.19063938 0 1 504.2597641 21.98715857 73 0.8961 03 57607.75252 762.7094794 25162 0.5959 0 42.09568617 0 1 436.322348 22.78175386 73 0.8961 03 62173.26424 756.5208546 25162 0.5959 0 40.27981252 0 1 495.1935692 22.45873018 73 0.8961 03 59606.31702 754.1249971 25162 0.5959 0 39.46342027 0 1 523.2120922 23.27345855 73 0.8961 03 57440.13568 734.2371123 25162 0.5959 0 40.6400655 0 1 511.9690548 22.5323558 73 0.8961 03 64315.81038 778.7296191 25162 0.5959 0 38.33173854 0 1 488.323522 23.23306679 73 0.8961 03 62000.97077 742.653622 25162 0.5959 0 39.92835279 0 1 498.2923583 22.49605751 73 0.8961 0447Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFLOD Sigma Al Al +/- Al Intercept Al Slope As As +/- As Intercept As Slope Ba Ba +/- Ba Intercept Ba Slope BiD.8 fp-XRF Geochem Mode3 58309.77834 757.359221 25162 0.5959 0 43.6022739 0 1 472.429202 22.84419646 73 0.8961 03 59109.08497 747.6662309 25162 0.5959 0 40.33560608 0 1 489.238199 22.86452998 73 0.8961 03 59576.32462 731.3051662 25162 0.5959 0 38.06029277 0 1 548.3115437 22.04680503 73 0.8961 03 59940.13617 748.7808487 25162 0.5959 0 39.70656871 0 1 492.0386485 22.70764539 73 0.8961 0NA3 61792.65338 753.1584196 25162 0.5959 0 37.77114619 0 1 512.3475723 21.8224387 73 0.8961 03 63205.18052 745.9259714 25162 0.5959 0 37.55912002 0 1 568.1774582 21.96856784 73 0.8961 03 64961.14342 758.4982103 25162 0.5959 0 37.60529546 0 1 437.9901628 20.65488082 73 0.8961 03 66030.7967 760.6658247 25162 0.5959 0 37.48161745 0 1 513.0755852 21.77777823 73 0.8961 03 58752.08587 737.3986191 25162 0.5959 0 38.40320152 0 1 505.9991496 22.2660406 73 0.8961 03 55740.04077 704.262679 25162 0.5959 0 34.34539043 0 1 455.2415607 21.59746473 73 0.8961 03 52260.87881 709.5959609 25162 0.5959 0 36.38477603 0 1 475.7885048 23.12195564 73 0.8961 03 59015.85735 753.5092182 25162 0.5959 0 37.39076005 0 1 475.3916408 23.650731 73 0.8961 03 61894.98784 764.1241665 25162 0.5959 0 39.79907126 0 1 534.9232084 23.0833749 73 0.8961 03 60179.34294 740.5776601 25162 0.5959 0 40.23305565 0 1 459.6732185 22.29768702 73 0.8961 03 112891.6294 1056.872203 25162 0.5959 0 33.3749847 0 1 0 87.08606766 73 0.8961 03 60441.49831 740.0100256 25162 0.5959 13.01611575 3.825625734 0 1 494.5194057 22.57926735 73 0.8961 03 57539.75872 724.0240209 25162 0.5959 12.96427708 3.782325917 0 1 465.0136674 22.13263554 73 0.8961 03 63390.45252 761.2427527 25162 0.5959 0 37.8968762 0 1 515.8203349 21.79506972 73 0.8961 03 61626.51056 767.4834155 25162 0.5959 0 39.81914929 0 1 488.3309715 22.41756042 73 0.8961 03 66658.83846 776.6907706 25162 0.5959 0 41.04881261 0 1 533.1646577 22.57674693 73 0.8961 03 52824.3024 701.0621938 25162 0.5959 0 37.37705045 0 1 519.4892565 23.67454538 73 0.8961 03 52842.44999 696.4548873 25162 0.5959 0 36.7624377 0 1 507.310222 22.76143698 73 0.8961 03 45582.94825 845.9197093 25162 0.5959 0 47.18253107 0 1 293.1267999 27.22902255 73 0.8961 03 62621.35216 788.7997006 25162 0.5959 0 43.32837506 0 1 487.3700392 23.89847054 73 0.8961 03 59554.13057 775.7883223 25162 0.5959 0 39.58313438 0 1 489.4567537 23.36672167 73 0.8961 03 35793.87793 1176.645401 25162 0.5959 0 57.59961119 0 1 0 190.0760757 73 0.8961 03 41744.2445 1103.123526 25162 0.5959 0 56.61940907 0 1 0 171.9840554 73 0.8961 03 62653.15298 752.6220272 25162 0.5959 0 38.67581317 0 1 527.9009828 23.03495207 73 0.8961 03 60693.96414 736.3032408 25162 0.5959 0 39.34024967 0 1 473.1119879 22.08294797 73 0.8961 03 61104.7722 739.5240826 25162 0.5959 13.58505436 3.995739886 0 1 478.8496306 21.87049528 73 0.8961 03 61029.45482 782.881761 25162 0.5959 0 38.24637235 0 1 460.5231401 22.89305813 73 0.8961 03 59673.23978 1032.508714 25162 0.5959 19.77191676 5.976099494 0 1 248.4574828 25.6613517 73 0.8961 03 35341.92909 926.7263302 25162 0.5959 0 49.29152492 0 1 165.1196944 22.11157704 73 0.8961 03 36392.55732 1060.950952 25162 0.5959 26.32017074 5.857087869 0 1 0 168.1190067 73 0.8961 03 37179.35964 936.1038791 25162 0.5959 0 50.82075857 0 1 0 151.7114731 73 0.8961 03 57927.52554 728.7322381 25162 0.5959 0 38.29048316 0 1 545.6298434 23.07419516 73 0.8961 03 111380.131 1049.472492 25162 0.5959 18.30738062 5.583052981 0 1 94.83080919 13.03027978 73 0.8961 0448Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFLOD Sigma Al Al +/- Al Intercept Al Slope As As +/- As Intercept As Slope Ba Ba +/- Ba Intercept Ba Slope BiD.8 fp-XRF Geochem Mode3 56334.33949 722.8050016 25162 0.5959 0 37.43394161 0 1 535.3205618 22.91816251 73 0.8961 03 56312.50484 744.371424 25162 0.5959 0 39.85256242 0 1 509.4085912 24.07998015 73 0.8961 03 59323.3573 737.2752443 25162 0.5959 0 38.69158254 0 1 561.3191798 22.93778189 73 0.8961 03 62326.30952 750.1326622 25162 0.5959 0 38.14061236 0 1 585.0047519 23.15496239 73 0.8961 03 55246.64213 691.8185718 25162 0.5959 0 38.11428114 0 1 538.5868348 21.60144618 73 0.8961 03 58093.00853 708.554178 25162 0.5959 0 37.40676621 0 1 515.5811118 22.75687023 73 0.8961 03 59585.06187 731.6367168 25162 0.5959 0 39.37651092 0 1 505.0313469 23.22858088 73 0.8961 03 25556.70342 943.1821805 25162 0.5959 0 63.24241443 0 1 0 187.645746 73 0.8961 03 26620.95647 998.8066996 25162 0.5959 0 60.57635211 0 1 0 196.6760899 73 0.8961 03 61120.59409 757.6415042 25162 0.5959 0 38.74824378 0 1 505.1616258 24.24858471 73 0.8961 03 55722.15882 725.3463227 25162 0.5959 0 35.35393662 0 1 508.5770342 23.27500552 73 0.8961 03 35734.02516 972.9769562 25162 0.5959 0 56.31650249 0 1 0 176.4281386 73 0.8961 03 61946.07775 790.9855341 25162 0.5959 0 39.77578062 0 1 475.2493381 23.27109456 73 0.8961 03 53769.17019 686.7594367 25162 0.5959 0 34.92073612 0 1 446.2687385 21.66752904 73 0.8961 03 55887.37977 741.5842506 25162 0.5959 18.96207117 4.323136999 0 1 410.8878946 18.87584827 73 0.8961 03 64279.91848 742.1268403 25162 0.5959 0 40.58368165 0 1 540.0292009 22.21559022 73 0.8961 03 64191.3648 763.1838594 25162 0.5959 0 42.44891799 0 1 476.6993738 22.70056474 73 0.8961 03 58327.35592 730.1793945 25162 0.5959 12.19183508 3.929547247 0 1 512.8593567 22.62787402 73 0.8961 03 59927.0105 744.6724107 25162 0.5959 12.04356505 3.87064018 0 1 463.4229048 21.92954586 73 0.8961 03 62865.08908 739.131711 25162 0.5959 16.97532878 3.95314266 0 1 509.920289 22.03451294 73 0.8961 03 57296.49183 727.0268642 25162 0.5959 0 36.50645593 0 1 473.5795259 22.29072498 73 0.8961 0NA3 112903.1447 1052.785095 25162 0.5959 0 34.50029505 0 1 0 87.88724838 73 0.8961 03 57780.82104 718.8943864 25162 0.5959 0 39.36643625 0 1 501.9619778 22.19595566 73 0.8961 03 40761.97956 1109.436576 25162 0.5959 0 58.23506787 0 1 0 188.5682664 73 0.8961 03 60455.03249 760.6295152 25162 0.5959 0 38.36045935 0 1 548.3703959 22.01359313 73 0.8961 03 58677.25978 743.9566654 25162 0.5959 0 38.5028143 0 1 595.8181029 22.86808893 73 0.8961 03 58366.17936 739.1235034 25162 0.5959 0 39.33807556 0 1 559.74885 22.89131729 73 0.8961 03 57549.13039 706.2041433 25162 0.5959 0 38.40555101 0 1 528.9095017 22.65763093 73 0.8961 03 57016.71048 698.8622035 25162 0.5959 0 36.51165584 0 1 488.2027787 22.6515326 73 0.8961 03 53462.52355 700.4482467 25162 0.5959 0 37.56853436 0 1 532.3359792 23.52158762 73 0.8961 0449Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFBi +/- Bi Intercept Bi Slope Ca Ca +/- Ca Intercept Ca Slope Cd Cd +/- Cd Intercept Cd Slope Ce Ce +/- Ce Intercept159.3446319 0 1 0 341.358682 7090 0.5042 0 75.92711658 0 1 0 273.5214131 0178.1661966 0 1 13580.45259 101.3383056 7090 0.5042 0 95.88068874 0 1 0 393.6241035 0190.5315955 0 1 13918.47734 106.4882182 7090 0.5042 0 100.1954958 0 1 0 396.0129651 0157.9392048 0 1 12381.17151 99.61279637 7090 0.5042 0 84.51782657 0 1 0 337.9279747 0181.4964164 0 1 17597.27499 199.5526347 7090 0.5042 0 143.8879809 0 1 0 441.4940257 0197.0117658 0 1 15308.79706 116.3447304 7090 0.5042 0 106.7417572 0 1 0 408.3587291 0183.5340701 0 1 15245.13292 113.7091311 7090 0.5042 0 103.1261364 0 1 0 405.1620684 0176.476977 0 1 14293.45168 105.5791587 7090 0.5042 0 97.44204945 0 1 0 390.7172754 0188.2163579 0 1 14594.9374 105.6173659 7090 0.5042 0 94.57446154 0 1 0 389.4087224 0188.1347686 0 1 14428.11315 106.334471 7090 0.5042 0 96.72211172 0 1 0 400.97979 0178.2031509 0 1 15022.25159 111.4446466 7090 0.5042 0 102.4822002 0 1 0 401.5716441 0181.5739615 0 1 14060.07595 106.0590239 7090 0.5042 0 98.22189663 0 1 0 392.1577564 0180.7650361 0 1 14622.79292 106.2859976 7090 0.5042 0 95.33869486 0 1 0 388.8080988 0185.6288071 0 1 15232.50517 114.7731747 7090 0.5042 0 102.9760442 0 1 0 409.5508427 0193.5325746 0 1 14974.0486 109.6288175 7090 0.5042 0 101.0389146 0 1 0 392.3699777 0185.4998936 0 1 14846.4379 108.7032189 7090 0.5042 0 98.20098572 0 1 0 391.9763463 0178.3279903 0 1 14963.49706 109.1634648 7090 0.5042 0 98.75879195 0 1 0 391.4997984 0185.2508653 0 1 14581.98177 107.1679427 7090 0.5042 0 96.67272886 0 1 0 391.9137281 0186.0169011 0 1 14237.34267 107.3454955 7090 0.5042 0 96.75546317 0 1 0 395.4914784 0180.4999088 0 1 13714.19742 105.3158919 7090 0.5042 0 100.2168021 0 1 0 395.9282341 0151.9372695 0 1 9033.398046 85.12640974 7090 0.5042 0 86.96373955 0 1 0 324.4098865 0153.5814422 0 1 0 349.3271156 7090 0.5042 0 74.20253848 0 1 0 274.0988681 0157.8912763 0 1 9330.680717 88.3081213 7090 0.5042 0 86.19528033 0 1 0 330.6826426 0152.3877693 0 1 0 329.9471116 7090 0.5042 0 73.4836117 0 1 0 270.3997445 0181.7197337 0 1 13325.59668 99.6845117 7090 0.5042 0 98.07219254 0 1 0 387.8940502 0202.9606056 0 1 15707.72481 113.4265392 7090 0.5042 0 104.2493291 0 1 0 403.3405501 0181.3863426 0 1 15181.6262 111.7033466 7090 0.5042 0 98.93999038 0 1 0 396.5539778 0177.2605621 0 1 14145.38791 107.5999664 7090 0.5042 0 101.1704638 0 1 0 392.2531313 0189.317485 0 1 14269.83046 106.8505669 7090 0.5042 0 99.86802689 0 1 0 395.0870928 0186.3782877 0 1 14144.65048 106.3022898 7090 0.5042 0 101.868862 0 1 0 400.6631686 0186.4115999 0 1 14140.0721 108.4782213 7090 0.5042 0 102.1265726 0 1 0 401.3368287 0183.4244023 0 1 13789.65875 104.5874174 7090 0.5042 0 102.9145649 0 1 0 401.2567413 0190.8936287 0 1 14683.03882 112.5637677 7090 0.5042 0 103.0159512 0 1 0 396.0152384 0243.6182157 0 1 19577.02827 195.2510147 7090 0.5042 0 161.1122594 0 1 0 513.3068488 0176.0429608 0 1 13997.88053 106.8275648 7090 0.5042 0 105.4551063 0 1 0 410.3743051 0236.2857817 0 1 25846.22814 329.0074187 7090 0.5042 0 202.0009631 0 1 0 601.8558141 0D.8 fp-XRF Geochem Mode450Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFBi +/- Bi Intercept Bi Slope Ca Ca +/- Ca Intercept Ca Slope Cd Cd +/- Cd Intercept Cd Slope Ce Ce +/- Ce InterceptD.8 fp-XRF Geochem Mode236.4342218 0 1 23456.51895 302.6544098 7090 0.5042 0 196.274708 0 1 0 581.5380279 0216.453284 0 1 17704.19867 197.7356386 7090 0.5042 0 161.6105465 0 1 0 497.0582352 0206.5056063 0 1 15917.55481 122.2329423 7090 0.5042 0 116.7524476 0 1 0 433.7223851 0208.1764798 0 1 17014.75704 125.3387187 7090 0.5042 0 106.642176 0 1 0 418.4630148 0212.9878989 0 1 14648.38229 114.5959516 7090 0.5042 0 112.2161081 0 1 0 417.6985693 0181.5783304 0 1 15119.63845 111.4761342 7090 0.5042 0 100.9998293 0 1 0 396.898234 0206.2115776 0 1 15241.11773 116.7180048 7090 0.5042 0 112.5758083 0 1 0 414.9737927 0181.1988507 0 1 13331.4852 101.7090097 7090 0.5042 0 97.99494066 0 1 0 389.403644 0157.2753801 0 1 0 348.2947246 7090 0.5042 0 73.91010593 0 1 0 275.4810556 0188.4871673 0 1 13807.0234 105.1759495 7090 0.5042 0 97.82912894 0 1 0 400.531087 0179.4705592 0 1 14696.07119 107.3093732 7090 0.5042 0 100.5149116 0 1 0 391.1692345 0192.4356731 0 1 13338.83498 104.0568493 7090 0.5042 0 102.3834583 0 1 0 394.1932086 0180.6623952 0 1 12815.11479 103.0187797 7090 0.5042 0 105.0401859 0 1 0 397.69569 0193.150527 0 1 14566.96764 112.5818845 7090 0.5042 0 106.3375168 0 1 0 408.3762937 0194.57593 0 1 14458.09465 109.773937 7090 0.5042 0 101.9801964 0 1 0 400.4786656 0194.7989532 0 1 14502.38515 109.7312265 7090 0.5042 0 102.8026866 0 1 0 402.728326 0195.0508865 0 1 14358.34816 107.7994891 7090 0.5042 0 103.4649892 0 1 0 400.1842535 0188.9947736 0 1 13898.85683 103.1711119 7090 0.5042 0 96.83058581 0 1 0 390.3371095 0198.7935712 0 1 14462.14705 112.0330508 7090 0.5042 0 104.6111422 0 1 0 399.9706518 0198.6733377 0 1 15123.56812 112.0801622 7090 0.5042 0 99.2287044 0 1 0 402.3399194 0199.6658928 0 1 16318.90188 121.9682896 7090 0.5042 0 105.3113712 0 1 0 409.6411277 0194.9224851 0 1 13671.98334 109.2562833 7090 0.5042 0 107.8755497 0 1 0 410.1852819 0188.9607563 0 1 12513.59135 101.5613255 7090 0.5042 0 103.5401808 0 1 0 401.4027178 0198.7488996 0 1 14530.17477 109.5823381 7090 0.5042 0 100.3405993 0 1 0 397.3968325 0193.7751552 0 1 14693.03166 112.3421698 7090 0.5042 0 104.7937733 0 1 0 399.023547 0196.9023065 0 1 13633.66828 107.0252358 7090 0.5042 0 105.8931171 0 1 0 405.8650925 0187.3176291 0 1 14852.08057 113.3191628 7090 0.5042 0 105.57076 0 1 0 402.7821387 0200.1788541 0 1 14966.8285 118.8825761 7090 0.5042 0 112.2903523 0 1 0 415.9433688 0212.4191214 0 1 16525.19318 124.1177644 7090 0.5042 0 111.5242273 0 1 0 416.6602287 0193.9765454 0 1 15117.26924 114.4687245 7090 0.5042 0 103.8002438 0 1 0 403.2354038 0156.3211191 0 1 0 350.1876428 7090 0.5042 0 74.75860872 0 1 0 272.1369805 0193.4616936 0 1 15152.06626 113.8613677 7090 0.5042 0 101.6409449 0 1 0 401.7622803 0194.8708173 0 1 15597.08242 119.4512513 7090 0.5042 0 109.0999789 0 1 0 412.6053762 0189.9532199 0 1 16076.62357 117.7354136 7090 0.5042 0 105.6425271 0 1 0 405.9090541 0193.4313834 0 1 16103.34296 120.0121092 7090 0.5042 0 107.2132452 0 1 0 414.0255435 0190.4263437 0 1 15590.61142 114.7538122 7090 0.5042 0 101.6357837 0 1 0 407.1497857 0210.7770958 0 1 16586.04909 122.6079064 7090 0.5042 0 112.3816211 0 1 0 421.9131007 0194.3893974 0 1 15532.42512 114.6160587 7090 0.5042 0 106.1741033 0 1 0 402.5266954 0451Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFBi +/- Bi Intercept Bi Slope Ca Ca +/- Ca Intercept Ca Slope Cd Cd +/- Cd Intercept Cd Slope Ce Ce +/- Ce InterceptD.8 fp-XRF Geochem Mode193.5958539 0 1 15827.96624 120.0997748 7090 0.5042 0 110.1674559 0 1 0 414.5218127 0192.9537846 0 1 15427.70564 115.2964981 7090 0.5042 0 105.4149308 0 1 0 410.6707669 0185.5931555 0 1 14533.52042 107.6939019 7090 0.5042 0 101.4213046 0 1 0 396.4355141 0194.7649382 0 1 15242.04286 114.8909816 7090 0.5042 0 106.1585138 0 1 0 410.9780619 0180.3368723 0 1 13279.90704 103.9928006 7090 0.5042 0 100.8673176 0 1 0 396.1273433 0190.0257722 0 1 14450.88209 107.4639541 7090 0.5042 0 100.9460458 0 1 0 396.3631996 0174.6029175 0 1 11873.11646 96.75559268 7090 0.5042 0 97.85535781 0 1 0 390.8397627 0195.4231863 0 1 14124.09276 107.0590487 7090 0.5042 0 100.8710554 0 1 0 397.2135032 0184.5685588 0 1 13567.30389 106.2102512 7090 0.5042 0 102.5920871 0 1 0 406.6227035 0174.042352 0 1 13208.92512 101.5018614 7090 0.5042 0 99.72570199 0 1 0 397.6439707 0182.8251408 0 1 13023.16856 104.5068426 7090 0.5042 0 104.8635818 0 1 0 411.467708 0195.0138848 0 1 14965.93164 115.8627679 7090 0.5042 0 111.9783926 0 1 0 413.5012809 0202.6922373 0 1 16046.56613 119.087869 7090 0.5042 0 107.4267094 0 1 0 412.2832487 0184.2677577 0 1 15470.53459 114.795798 7090 0.5042 0 104.2712263 0 1 0 404.7208502 0154.0752048 0 1 0 355.0934473 7090 0.5042 0 74.59031588 0 1 0 275.458716 0186.412644 0 1 15773.39604 116.0917102 7090 0.5042 0 103.9710261 0 1 0 404.6918657 0187.208555 0 1 13999.89074 106.1048052 7090 0.5042 0 100.1446935 0 1 0 398.1902274 0196.2573791 0 1 15484.76403 115.6954982 7090 0.5042 0 105.1583272 0 1 0 405.7101786 0192.2991242 0 1 15933.47459 119.7210703 7090 0.5042 0 108.7038959 0 1 0 405.0019442 0184.9032515 0 1 14936.23324 114.2139503 7090 0.5042 0 108.282975 0 1 0 405.4300881 0187.8603521 0 1 12344.33856 100.505505 7090 0.5042 0 105.281567 0 1 0 409.0047065 0182.7637352 0 1 12896.42567 101.6863764 7090 0.5042 0 105.1873604 0 1 0 399.7484496 0238.3548143 0 1 16540.35112 151.196116 7090 0.5042 0 142.675408 0 1 0 478.8738034 0206.6967954 0 1 14839.6775 118.0021734 7090 0.5042 0 119.3214272 0 1 0 426.8247948 0199.1274398 0 1 14438.15496 116.0998157 7090 0.5042 0 112.7909298 0 1 0 422.7040221 0248.941684 0 1 22871.28062 277.1124883 7090 0.5042 0 199.6096992 0 1 0 593.4626347 0242.9828087 0 1 24371.05398 289.5367476 7090 0.5042 0 178.6801114 0 1 0 533.8924602 0194.5706383 0 1 15226.96176 112.887948 7090 0.5042 0 105.7416626 0 1 0 410.9224656 0187.4798085 0 1 15032.88422 111.6575951 7090 0.5042 0 105.3574787 0 1 0 400.8243146 0187.8467083 0 1 14467.17668 108.8975789 7090 0.5042 0 105.070741 0 1 0 396.5939715 0208.339714 0 1 14740.69613 116.4411077 7090 0.5042 0 111.8563158 0 1 0 417.22575 0248.5966826 0 1 15776.88302 161.4956211 7090 0.5042 10.24925329 3.342892871 0 1 0 504.0599288 0222.368163 0 1 22244.76011 237.736437 7090 0.5042 0 160.6349143 0 1 0 482.3715584 0247.1124357 0 1 22610.77599 280.1043066 7090 0.5042 0 173.4852377 0 1 0 521.6264819 0180.7052309 0 1 21662.94771 230.0830223 7090 0.5042 0 153.8103315 0 1 0 469.6197878 0186.3091352 0 1 14925.55173 112.7306667 7090 0.5042 0 104.8470341 0 1 0 405.2374379 0152.4154359 0 1 0 357.2759473 7090 0.5042 0 74.44325749 0 1 0 273.7368223 0452Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFBi +/- Bi Intercept Bi Slope Ca Ca +/- Ca Intercept Ca Slope Cd Cd +/- Cd Intercept Cd Slope Ce Ce +/- Ce InterceptD.8 fp-XRF Geochem Mode207.7884167 0 1 15031.66949 112.8305064 7090 0.5042 0 106.3723241 0 1 0 413.0238682 0200.5495901 0 1 14884.54026 116.2577216 7090 0.5042 0 111.8626788 0 1 0 423.4291077 0202.072405 0 1 14302.63496 108.6673873 7090 0.5042 0 105.1309143 0 1 0 410.1204797 0177.3627813 0 1 14461.60417 111.0489756 7090 0.5042 0 107.2772626 0 1 0 408.6267832 0184.6744766 0 1 14054.9024 102.8997689 7090 0.5042 0 97.2440285 0 1 0 391.3344453 0184.858323 0 1 13905.58505 105.7664365 7090 0.5042 0 102.5990222 0 1 0 402.4824297 0201.3779584 0 1 14660.00082 110.4962528 7090 0.5042 0 106.2974819 0 1 0 411.4667859 0257.5948412 0 1 20458.14066 242.567358 7090 0.5042 0 194.1533551 0 1 0 586.1751132 0277.8940022 0 1 18534.00298 236.8181171 7090 0.5042 0 210.3181436 0 1 0 615.8404946 0188.6529669 0 1 14056.75582 112.7391007 7090 0.5042 0 111.2882164 0 1 0 423.6473611 0195.6339696 0 1 13475.78993 105.7909647 7090 0.5042 0 104.8243846 0 1 0 407.9547924 0236.4538888 0 1 17916.77172 204.7977458 7090 0.5042 0 181.991184 0 1 0 551.7479596 0210.1487974 0 1 14864.54029 117.8376974 7090 0.5042 0 113.2418275 0 1 0 421.3067325 0177.8811484 0 1 12800.02112 99.34453017 7090 0.5042 0 99.71130892 0 1 0 393.9340849 0178.1586897 0 1 16198.74572 120.6944358 7090 0.5042 0 93.50285793 0 1 0 377.2901134 0185.1587141 0 1 15345.91887 112.1377094 7090 0.5042 0 104.364129 0 1 0 405.2290564 0208.9923272 0 1 16093.8107 118.7067967 7090 0.5042 0 106.6019502 0 1 0 411.1561507 0195.8706761 0 1 14317.15578 109.0290867 7090 0.5042 0 103.0553341 0 1 0 403.7646969 0194.0307038 0 1 14342.28602 109.9988215 7090 0.5042 0 101.928148 0 1 0 399.6157483 0190.8241266 0 1 14559.2026 108.3030303 7090 0.5042 0 100.1380489 0 1 0 395.9200257 0186.8293418 0 1 13588.37739 105.3879478 7090 0.5042 0 104.3127325 0 1 0 407.4877506 0153.2520788 0 1 0 356.017426 7090 0.5042 0 74.29292423 0 1 0 276.5038493 0182.3538201 0 1 13454.54842 104.5117674 7090 0.5042 0 103.224914 0 1 0 396.0833033 0267.7805163 0 1 16005.47697 207.4296718 7090 0.5042 0 198.5642071 0 1 0 589.9511597 0191.8994222 0 1 13578.61344 108.6263754 7090 0.5042 0 102.5018814 0 1 0 399.4270717 0204.8362465 0 1 14489.41748 111.3674718 7090 0.5042 0 107.6900331 0 1 0 412.4711245 0200.5232418 0 1 14741.18412 112.6865395 7090 0.5042 0 105.2136461 0 1 0 408.9724216 0187.9643448 0 1 14280.71961 105.9927188 7090 0.5042 0 98.19797992 0 1 0 400.3090925 0186.0368318 0 1 13493.22156 102.5860415 7090 0.5042 0 101.3660904 0 1 0 398.6489417 0182.9318955 0 1 13261.31761 104.6729816 7090 0.5042 0 104.9537494 0 1 0 405.8179702 0453Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCe Slope Cl Cl +/- Cl Intercept Cl Slope Co Co +/- Co Intercept Co Slope Cr Cr +/- Cr Intercept Cr Slope Cu1 0 110.9669025 0 1 0 464.7727305 0 1 866.649118 115.9873309 0 1 01 0 76.55598009 0 1 0 219.8951394 0 1 0 518.8406587 0 1 01 0 83.00684616 0 1 0 237.6211529 0 1 0 519.6282584 0 1 01 0 99.49314423 0 1 0 356.2042595 0 1 0 445.622939 0 1 01 0 225.6912474 0 1 0 440.4375294 0 1 868.2813253 164.1377279 0 1 632.05796361 0 84.24008155 0 1 0 241.1002357 0 1 0 542.7150288 0 1 01 0 81.75200561 0 1 0 223.966334 0 1 0 538.1459789 0 1 01 0 80.27082583 0 1 0 225.4246244 0 1 0 515.0846942 0 1 01 0 77.66534634 0 1 0 238.2594168 0 1 0 515.4006243 0 1 01 0 78.62087522 0 1 0 239.8491684 0 1 0 534.4674784 0 1 01 0 80.71967738 0 1 0 239.5169532 0 1 0 532.2823396 0 1 01 0 83.63946516 0 1 0 239.9427768 0 1 0 523.5045982 0 1 01 0 77.83354563 0 1 0 239.2021773 0 1 0 509.5168784 0 1 01 0 83.81302628 0 1 0 246.6714783 0 1 0 541.3804343 0 1 01 0 80.76885422 0 1 0 247.7806693 0 1 0 518.6042846 0 1 01 0 79.87217454 0 1 0 238.4073337 0 1 0 508.4621662 0 1 01 0 78.48406905 0 1 0 246.8923944 0 1 0 522.4419535 0 1 01 0 81.2362951 0 1 0 223.7832577 0 1 0 516.1270091 0 1 01 0 82.07098718 0 1 0 236.3500871 0 1 0 532.2039482 0 1 01 0 83.54961262 0 1 0 255.9462393 0 1 0 522.513028 0 1 01 0 114.2961828 0 1 0 393.7747536 0 1 663.0659084 121.2577912 0 1 01 0 114.034559 0 1 0 444.9355066 0 1 936.0334007 115.5569689 0 1 01 0 115.1206727 0 1 0 406.9830949 0 1 375.8932974 122.1387406 0 1 01 0 107.1925843 0 1 0 445.359442 0 1 1064.053053 117.1282906 0 1 01 0 74.86958137 0 1 0 230.7034582 0 1 0 513.795594 0 1 01 0 78.78176413 0 1 0 253.0900714 0 1 0 525.6754566 0 1 01 0 82.30857974 0 1 0 255.5070481 0 1 0 514.3533276 0 1 01 0 82.23977014 0 1 0 250.0376567 0 1 842.9416197 175.3220551 0 1 01 0 82.15865897 0 1 0 257.0664403 0 1 0 535.6846161 0 1 01 0 79.93539206 0 1 0 239.6227819 0 1 0 528.2626589 0 1 01 0 83.79334545 0 1 0 251.013376 0 1 0 531.4094033 0 1 01 0 78.14517679 0 1 0 224.6816692 0 1 0 529.7947197 0 1 01 0 85.59056595 0 1 0 273.4439632 0 1 648.5710967 177.9555684 0 1 01 0 160.6784037 0 1 0 289.5217217 0 1 803.1979295 227.361145 0 1 303.03105031 0 79.70494709 0 1 0 209.5906173 0 1 0 542.9811634 0 1 01 276.6249344 69.98168526 0 1 0 395.8278686 0 1 912.4113717 251.8063474 0 1 1466.156627D.8 fp-XRF Geochem Mode454Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCe Slope Cl Cl +/- Cl Intercept Cl Slope Co Co +/- Co Intercept Co Slope Cr Cr +/- Cr Intercept Cr Slope CuD.8 fp-XRF Geochem Mode1 1088.313091 66.43553178 0 1 0 379.1551731 0 1 870.6894417 239.8169659 0 1 1004.5245571 0 200.7622151 0 1 0 406.1263203 0 1 757.7627155 202.5015342 0 1 575.6358451 0 82.05169506 0 1 0 239.1632098 0 1 613.3915325 203.9997792 0 1 01 0 84.25136302 0 1 0 255.3549635 0 1 0 559.5825993 0 1 01 0 85.85418304 0 1 0 255.7693542 0 1 610.515248 190.2164114 0 1 01 0 81.99778241 0 1 0 247.7628801 0 1 0 531.8021266 0 1 01 0 81.83624615 0 1 0 270.8474593 0 1 0 558.3875404 0 1 01 0 81.66814005 0 1 0 235.2823595 0 1 0 514.3067183 0 1 01 0 113.444529 0 1 0 454.5282818 0 1 898.3260322 116.8850187 0 1 01 0 81.45819045 0 1 0 240.6721731 0 1 0 529.4178957 0 1 01 0 81.1640395 0 1 0 229.7156683 0 1 0 525.1634268 0 1 01 0 86.18605961 0 1 0 257.7003146 0 1 0 521.7946026 0 1 01 0 84.90110691 0 1 0 267.2600272 0 1 0 525.376257 0 1 01 0 86.26080611 0 1 0 262.0870094 0 1 0 537.6666652 0 1 117.88048451 0 83.63176085 0 1 0 251.2476489 0 1 0 530.2270033 0 1 01 0 83.12469036 0 1 0 262.0042609 0 1 0 527.0884835 0 1 01 0 81.06844154 0 1 0 254.0083613 0 1 0 533.4897857 0 1 01 0 80.8358256 0 1 0 235.3679517 0 1 0 516.7715908 0 1 01 0 87.53595841 0 1 0 270.9021639 0 1 596.6515755 177.3493244 0 1 01 0 82.96825041 0 1 0 247.050331 0 1 0 537.4802986 0 1 01 0 86.63776786 0 1 0 273.2537161 0 1 719.508782 185.5280313 0 1 01 0 85.53103925 0 1 0 259.2560431 0 1 0 551.5541241 0 1 01 0 84.66995014 0 1 0 236.8570497 0 1 0 529.0292339 0 1 01 0 83.59207211 0 1 0 266.4503379 0 1 556.9178063 177.0959638 0 1 01 0 86.69250636 0 1 0 279.1343484 0 1 557.8771556 176.4174295 0 1 01 0 87.16951663 0 1 0 257.3932459 0 1 0 545.3084919 0 1 01 0 83.11831617 0 1 0 284.8945797 0 1 570.6079889 182.0089927 0 1 01 0 90.69804825 0 1 0 275.3565031 0 1 0 544.2384218 0 1 120.07103451 0 85.90555953 0 1 0 274.7421959 0 1 744.1785444 188.1233047 0 1 01 0 85.71866608 0 1 0 265.0102479 0 1 554.938597 181.4145586 0 1 01 0 114.1667354 0 1 0 450.2952704 0 1 925.5503288 114.1308887 0 1 01 0 85.25788232 0 1 0 260.2446813 0 1 577.0564908 180.6902326 0 1 01 0 86.77486886 0 1 0 265.2159117 0 1 0 556.4550995 0 1 01 0 82.47005165 0 1 0 250.1514106 0 1 0 537.2043273 0 1 01 0 81.60133218 0 1 0 251.531069 0 1 0 557.2663979 0 1 01 0 82.97501672 0 1 0 246.4118957 0 1 0 538.7186195 0 1 01 0 81.80526212 0 1 0 262.8169335 0 1 0 552.2386492 0 1 01 0 79.52588714 0 1 0 254.9351844 0 1 0 531.0613765 0 1 0455Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCe Slope Cl Cl +/- Cl Intercept Cl Slope Co Co +/- Co Intercept Co Slope Cr Cr +/- Cr Intercept Cr Slope CuD.8 fp-XRF Geochem Mode1 0 84.98619013 0 1 0 266.4212953 0 1 0 546.2380822 0 1 01 0 84.37401134 0 1 0 251.3391184 0 1 0 541.698436 0 1 01 0 81.75197146 0 1 0 236.832885 0 1 0 531.6590081 0 1 01 0 83.44085394 0 1 0 248.5464519 0 1 0 544.2856831 0 1 01 0 87.42102569 0 1 0 246.9038106 0 1 0 523.5919891 0 1 01 0 83.99450548 0 1 0 247.6023493 0 1 0 528.1536615 0 1 01 0 89.3162821 0 1 0 254.3123016 0 1 0 512.4878409 0 1 01 0 83.29140427 0 1 0 265.9139681 0 1 0 534.8896302 0 1 01 0 85.75735616 0 1 0 244.8185383 0 1 0 536.7641672 0 1 01 0 82.64781534 0 1 0 224.6499682 0 1 0 528.3715168 0 1 01 0 83.85781501 0 1 0 210.0529385 0 1 0 537.6356406 0 1 01 0 85.8147138 0 1 0 231.1927708 0 1 0 553.298092 0 1 01 0 85.12995148 0 1 0 257.1005101 0 1 0 555.5011199 0 1 01 0 83.10389899 0 1 0 254.4635734 0 1 0 539.8771401 0 1 01 0 115.9308101 0 1 0 454.8075274 0 1 751.3556487 115.4979923 0 1 01 0 81.7664963 0 1 0 251.2921948 0 1 0 537.4409083 0 1 01 0 85.10270343 0 1 0 237.6404244 0 1 0 532.1636057 0 1 01 0 84.27248816 0 1 0 260.2405274 0 1 0 537.2297493 0 1 01 0 86.19636522 0 1 0 268.8278767 0 1 0 544.0346557 0 1 01 0 84.28210753 0 1 0 259.0874103 0 1 0 537.3558743 0 1 01 0 80.87338299 0 1 0 198.1766358 0 1 0 546.3368872 0 1 01 0 80.56722193 0 1 0 207.5554508 0 1 0 530.6349844 0 1 01 0 123.5054899 0 1 0 229.7804313 0 1 734.8485655 227.8378845 0 1 148.10654181 0 86.81489682 0 1 0 250.2263293 0 1 0 567.3876568 0 1 01 0 88.29623768 0 1 0 249.0782293 0 1 0 566.6035305 0 1 161.87880351 0 283.8926849 0 1 0 322.4749618 0 1 0 815.6091023 0 1 1042.071511 0 246.6276478 0 1 0 373.7785405 0 1 0 727.5201349 0 1 898.67695441 0 81.66354128 0 1 0 246.655388 0 1 0 542.5816258 0 1 01 0 81.0962888 0 1 0 239.4901975 0 1 0 534.2290127 0 1 01 0 81.73229113 0 1 0 251.407984 0 1 0 526.5349809 0 1 01 0 89.09876935 0 1 0 264.2413604 0 1 0 554.8112552 0 1 01 0 136.2904635 0 1 0 418.4145072 0 1 666.5725138 221.4046716 0 1 405.82555441 0 194.9238436 0 1 0 424.2223331 0 1 0 663.9419235 0 1 632.58190271 0 258.0120491 0 1 0 443.4315288 0 1 0 725.1958573 0 1 938.41801861 0 186.6136365 0 1 0 466.86048 0 1 912.6323102 190.5248643 0 1 725.92617581 0 84.16543799 0 1 0 222.3618531 0 1 0 538.846011 0 1 01 0 116.0879216 0 1 0 450.2946672 0 1 945.4817963 115.4518152 0 1 0456Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCe Slope Cl Cl +/- Cl Intercept Cl Slope Co Co +/- Co Intercept Co Slope Cr Cr +/- Cr Intercept Cr Slope CuD.8 fp-XRF Geochem Mode1 0 81.96606796 0 1 0 225.321851 0 1 0 542.4725346 0 1 01 0 84.7213038 0 1 0 229.178929 0 1 0 565.1354222 0 1 01 0 81.69737319 0 1 0 235.8371846 0 1 0 544.158243 0 1 01 0 81.63786912 0 1 0 239.3606828 0 1 0 545.5315044 0 1 01 0 79.78693619 0 1 0 234.5448826 0 1 0 520.7434984 0 1 01 0 79.31316858 0 1 0 212.5493824 0 1 0 534.5380339 0 1 01 0 81.55212669 0 1 0 227.6178527 0 1 0 541.9222535 0 1 01 0 215.5153175 0 1 0 343.0719592 0 1 0 802.1470913 0 1 1025.2590861 0 237.0214611 0 1 0 345.088722 0 1 0 845.2705868 0 1 1294.8309751 0 83.48540289 0 1 0 236.9164584 0 1 0 561.0276753 0 1 01 0 86.06525388 0 1 0 225.8964064 0 1 0 538.2341533 0 1 01 0 204.8682011 0 1 0 345.7211938 0 1 0 760.9356009 0 1 1010.949781 0 93.2306601 0 1 0 261.9950998 0 1 0 567.424729 0 1 01 0 81.44850698 0 1 0 215.3680058 0 1 0 525.9948839 0 1 01 0 97.17467819 0 1 0 321.496235 0 1 0 504.4428394 0 1 01 0 80.96536044 0 1 0 256.7257837 0 1 0 527.9183553 0 1 01 0 83.39341493 0 1 0 266.9986248 0 1 0 548.9070752 0 1 01 0 83.61561459 0 1 0 246.5235063 0 1 0 540.4326311 0 1 01 0 86.54061998 0 1 0 254.6342691 0 1 0 535.288948 0 1 01 0 83.00376438 0 1 0 253.1112798 0 1 0 528.2597721 0 1 01 0 86.49037867 0 1 0 239.5116029 0 1 0 544.2441187 0 1 01 0 116.3124407 0 1 0 455.0415025 0 1 759.3357124 115.5434221 0 1 172.50439561 0 84.99035737 0 1 0 234.7920011 0 1 0 523.1753917 0 1 01 0 253.8515688 0 1 0 349.8557546 0 1 0 823.7344599 0 1 1384.2266471 0 90.31133127 0 1 0 267.9812545 0 1 0 532.6683787 0 1 01 0 87.16752698 0 1 0 263.9418561 0 1 0 537.9947214 0 1 01 0 85.47683247 0 1 0 245.8172232 0 1 0 541.8596979 0 1 01 0 81.10153458 0 1 0 213.4508345 0 1 0 528.6554758 0 1 01 0 82.20603141 0 1 0 205.2217293 0 1 0 527.6332248 0 1 01 0 83.50045101 0 1 0 206.7841184 0 1 0 541.0820489 0 1 0457Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCu +/- Cu Intercept Cu Slope Fe Fe +/- Fe Intercept Fe Slope Hg Hg +/- Hg Intercept Hg Slope LE LE +/- LE Intercept150.4352368 33 0.371 125178.056 921.3117573 -2308 0.6309 0 171.1147251 0 1 374587.4756 3142.605106 0175.9411615 33 0.371 16441.08025 274.787107 -2308 0.6309 0 227.834715 0 1 490383.7842 2522.481865 0180.1377799 33 0.371 19311.33426 307.9169562 -2308 0.6309 0 227.6483389 0 1 495518.7104 2641.577458 0151.7893581 33 0.371 61122.93059 567.9076285 -2308 0.6309 0 196.1405249 0 1 547909.6831 2833.491665 056.57785558 33 0.371 46050.75718 677.5818881 -2308 0.6309 0 280.0378388 0 1 691838.2387 4272.64139 0194.5220996 33 0.371 17554.92539 304.9533059 -2308 0.6309 0 243.9476537 0 1 483451.0884 2708.288555 0183.677716 33 0.371 15937.54016 285.6977185 -2308 0.6309 0 227.5829527 0 1 489263.1074 2636.173701 0175.2514936 33 0.371 18921.81449 297.1781927 -2308 0.6309 0 219.5267954 0 1 499693.4805 2559.539617 0173.3485117 33 0.371 21107.61098 312.1459193 -2308 0.6309 0 231.3653797 0 1 470293.1627 2543.822003 0177.3455543 33 0.371 19703.61465 304.5134689 -2308 0.6309 0 236.8359415 0 1 479825.9185 2583.034032 0184.0163126 33 0.371 19715.16837 309.2899356 -2308 0.6309 0 234.2652834 0 1 480470.9898 2637.138991 0178.3027253 33 0.371 20435.19545 311.496326 -2308 0.6309 0 215.0304925 0 1 499959.0642 2638.245256 0178.3105656 33 0.371 21842.41016 315.9458827 -2308 0.6309 0 225.6558053 0 1 472968.0573 2527.698061 0184.7009684 33 0.371 20470.7644 322.612079 -2308 0.6309 0 235.6595803 0 1 491912.7839 2695.265202 0184.3002645 33 0.371 21311.84578 318.6332384 -2308 0.6309 0 228.2558408 0 1 479019.48 2601.005741 0175.2265946 33 0.371 19768.70882 303.5605509 -2308 0.6309 0 224.4752917 0 1 487222.5324 2585.572829 0178.2500121 33 0.371 22352.71875 324.0148417 -2308 0.6309 0 221.6549741 0 1 466510.0635 2575.214606 0175.7362154 33 0.371 16711.93544 284.2159953 -2308 0.6309 0 226.8420789 0 1 496522.1774 2569.847139 0182.6191669 33 0.371 19569.79028 307.3446275 -2308 0.6309 0 234.9974517 0 1 487433.2818 2609.025592 0179.0593684 33 0.371 23259.42512 333.5512776 -2308 0.6309 0 237.0161203 0 1 494310.3611 2639.880257 0157.2799022 33 0.371 74491.89248 683.9523613 -2308 0.6309 0 188.6611774 0 1 560596.4609 3040.647119 0149.4856682 33 0.371 116596.4395 884.5505814 -2308 0.6309 0 180.2092032 0 1 412114.5505 3161.004245 0165.5525793 33 0.371 75828.1033 696.8300086 -2308 0.6309 0 190.8988733 0 1 555175.8536 3074.907755 0146.3494045 33 0.371 120269.8051 900.3014368 -2308 0.6309 0 188.1874665 0 1 391392.9306 3136.337271 0175.4141237 33 0.371 18849.29733 301.3522478 -2308 0.6309 0 211.0574204 0 1 467293.0415 2549.586484 0189.228916 33 0.371 23489.55732 343.820977 -2308 0.6309 0 224.6696386 0 1 456760.3927 2658.404653 0186.6609316 33 0.371 24467.02272 346.1624135 -2308 0.6309 0 230.8684246 0 1 480832.2814 2668.86679 0179.7405504 33 0.371 23673.27407 340.3193747 -2308 0.6309 0 228.6176673 0 1 479263.099 2684.883205 0190.511853 33 0.371 23022.77781 334.8732341 -2308 0.6309 0 243.6913243 0 1 484016.9599 2671.213817 0182.9387712 33 0.371 20432.66341 318.6304282 -2308 0.6309 0 234.7333515 0 1 474321.6378 2622.333154 0188.1095321 33 0.371 23087.44193 341.90374 -2308 0.6309 0 230.188291 0 1 482888.2175 2702.488689 0181.9451396 33 0.371 16812.46665 290.8875774 -2308 0.6309 0 245.9748609 0 1 474593.729 2589.188731 0187.7283672 33 0.371 28419.53052 382.3197803 -2308 0.6309 0 222.9700978 0 1 475494.8162 2752.262753 049.92089984 33 0.371 16142.03355 376.0509462 -2308 0.6309 0 306.7935683 0 1 588324.1305 3900.93888 0184.1157267 33 0.371 13298.12237 266.565981 -2308 0.6309 0 233.395173 0 1 487402.614 2611.560627 085.6296977 33 0.371 18120.74741 473.284772 -2308 0.6309 0 393.8313177 0 1 766961.7854 2980.711804 0D.8 fp-XRF Geochem Mode458Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCu +/- Cu Intercept Cu Slope Fe Fe +/- Fe Intercept Fe Slope Hg Hg +/- Hg Intercept Hg Slope LE LE +/- LE InterceptD.8 fp-XRF Geochem Mode75.20856336 33 0.371 19354.82706 479.7485802 -2308 0.6309 0 364.1735893 0 1 799176.2971 2663.546511 059.36736259 33 0.371 33755.13879 572.4041144 -2308 0.6309 0 313.5535284 0 1 637453.4005 4303.808471 0203.78989 33 0.371 16620.67228 313.6687948 -2308 0.6309 0 265.0400702 0 1 442720.4905 2752.753312 0202.7455177 33 0.371 19293.9097 324.9383894 -2308 0.6309 0 254.6956597 0 1 459508.0713 2758.961451 0199.4309156 33 0.371 20183.30693 334.1468242 -2308 0.6309 0 245.9878651 0 1 472308.9914 2772.886672 0187.5087774 33 0.371 21965.563 330.6064879 -2308 0.6309 0 226.2758799 0 1 472164.5674 2636.528055 0200.6946647 33 0.371 23345.05364 361.2265238 -2308 0.6309 0 235.8810057 0 1 435455.108 2746.283178 0179.7244388 33 0.371 21099.63659 318.0219159 -2308 0.6309 0 218.1853109 0 1 486905.2854 2591.773169 0148.3832156 33 0.371 119652.8914 898.5119352 -2308 0.6309 0 172.457356 0 1 399123.099 3151.075495 0173.9554913 33 0.371 20933.03308 320.3793867 -2308 0.6309 0 203.8259424 0 1 482683.2635 2610.40574 0176.3676187 33 0.371 18953.16962 299.9942301 -2308 0.6309 0 243.9330117 0 1 493367.0933 2586.251991 0187.8492062 33 0.371 23971.87844 345.9242404 -2308 0.6309 0 230.697951 0 1 484819.8903 2678.361883 0182.4284545 33 0.371 26767.01732 368.179632 -2308 0.6309 0 217.2133881 0 1 489850.559 2702.679789 035.22086464 33 0.371 21823.31865 336.9977806 -2308 0.6309 0 220.611509 0 1 471907.5518 2701.139017 0182.7743547 33 0.371 21561.99995 330.9599799 -2308 0.6309 0 249.7049122 0 1 482006.5302 2667.069156 0180.5634767 33 0.371 23756.25986 345.7809646 -2308 0.6309 0 235.7822468 0 1 472630.0564 2664.495766 0190.9123567 33 0.371 22212.32674 334.2893636 -2308 0.6309 0 242.4056241 0 1 460753.59 2640.233971 0180.4700759 33 0.371 19903.83818 307.2557477 -2308 0.6309 0 229.1388598 0 1 485997.846 2557.05494 0195.4219677 33 0.371 25543.85527 365.929968 -2308 0.6309 0 256.3418769 0 1 474952.3683 2757.376342 0188.5035189 33 0.371 21585.80807 331.4344254 -2308 0.6309 0 238.9561064 0 1 472727.5992 2658.065694 0198.5725598 33 0.371 24891.65874 367.0215079 -2308 0.6309 0 232.0500581 0 1 469105.7418 2784.967137 0191.6322788 33 0.371 21621.45169 340.3851133 -2308 0.6309 0 240.8468984 0 1 473645.7135 2733.301777 0183.1177489 33 0.371 18980.52468 312.5863753 -2308 0.6309 0 242.5863673 0 1 494884.8854 2667.202039 0189.1719258 33 0.371 27049.75398 368.9130644 -2308 0.6309 0 237.2892708 0 1 458732.5083 2677.077699 0192.4025789 33 0.371 29335.2596 389.6337535 -2308 0.6309 0 218.7805877 0 1 460924.0833 2741.059087 0186.2733872 33 0.371 21886.80456 335.7810133 -2308 0.6309 0 241.1730012 0 1 492966.5837 2729.413847 0199.2504308 33 0.371 28098.74666 383.6897003 -2308 0.6309 0 229.1698394 0 1 449923.8448 2716.218386 037.98804576 33 0.371 23880.71754 364.970882 -2308 0.6309 0 220.0601392 0 1 464769.6493 2824.186159 0196.8584876 33 0.371 23820.78234 365.659919 -2308 0.6309 0 258.7441311 0 1 445967.1478 2794.010466 0186.2650351 33 0.371 23339.42903 348.1859629 -2308 0.6309 0 229.8398627 0 1 473160.4869 2709.113596 0147.3562339 33 0.371 120365.0466 901.4129101 -2308 0.6309 0 178.5920845 0 1 400039.5108 3148.87701 0189.3254656 33 0.371 22755.07157 343.0785323 -2308 0.6309 0 241.2275146 0 1 472404.1247 2701.603659 0199.2923443 33 0.371 22498.92317 351.9211379 -2308 0.6309 0 243.5705596 0 1 478815.2048 2791.770814 0192.9724984 33 0.371 21927.8134 337.7267609 -2308 0.6309 0 223.812138 0 1 465590.5243 2681.151894 0189.2407352 33 0.371 19622.25649 327.6532433 -2308 0.6309 0 265.0049906 0 1 455550.5396 2713.804566 0191.2159583 33 0.371 20457.35335 326.2783731 -2308 0.6309 0 255.280699 0 1 480221.9493 2681.975167 0201.2904123 33 0.371 21882.46903 346.8906266 -2308 0.6309 0 253.9187294 0 1 436679.7958 2736.872735 0188.8694586 33 0.371 20990.34731 330.3388549 -2308 0.6309 0 247.0528151 0 1 450950.4804 2634.753408 0459Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCu +/- Cu Intercept Cu Slope Fe Fe +/- Fe Intercept Fe Slope Hg Hg +/- Hg Intercept Hg Slope LE LE +/- LE InterceptD.8 fp-XRF Geochem Mode200.3240658 33 0.371 22911.71069 354.7111929 -2308 0.6309 0 267.5401621 0 1 466806.8017 2770.347427 0191.5280356 33 0.371 20555.22095 329.7328458 -2308 0.6309 0 237.5620488 0 1 478752.8456 2697.64371 0183.4107154 33 0.371 20916.38376 321.896083 -2308 0.6309 0 216.3107592 0 1 478593.8141 2621.550638 0192.9026104 33 0.371 20412.75975 328.568663 -2308 0.6309 0 231.694782 0 1 470621.9146 2693.780214 0176.7301919 33 0.371 22241.64916 332.3953569 -2308 0.6309 0 239.6954085 0 1 493592.5789 2658.143217 0180.4988838 33 0.371 22797.33406 333.8647571 -2308 0.6309 0 225.7298517 0 1 483446.3112 2616.11451 0172.394059 33 0.371 25322.19245 345.5159578 -2308 0.6309 0 242.9634331 0 1 500597.3266 2631.366199 0193.1088763 33 0.371 24940.60573 351.2002399 -2308 0.6309 0 239.2799557 0 1 463514.1563 2636.811259 0186.7295197 33 0.371 20796.30115 325.3505913 -2308 0.6309 0 233.4766374 0 1 492608.5098 2659.707442 0172.9913911 33 0.371 17234.98116 288.6829542 -2308 0.6309 0 232.187188 0 1 503257.6679 2586.457935 0180.2628709 33 0.371 12683.45979 262.8275205 -2308 0.6309 0 232.2302402 0 1 496318.8758 2657.037607 0203.5520432 33 0.371 15959.45847 298.731959 -2308 0.6309 0 229.6193937 0 1 474151.6034 2707.122639 0198.6446997 33 0.371 20744.38395 333.6225089 -2308 0.6309 0 232.193018 0 1 464966.1847 2714.122442 0190.5254586 33 0.371 21343.86682 331.6355146 -2308 0.6309 0 229.1063933 0 1 473881.4844 2662.62914 0148.6392438 33 0.371 119214.3025 898.6716352 -2308 0.6309 0 174.3544113 0 1 404272.7193 3159.265969 0184.5992292 33 0.371 21516.27272 333.9016572 -2308 0.6309 0 236.7813859 0 1 466446.8519 2654.335176 0181.9865665 33 0.371 20166.10279 317.5539912 -2308 0.6309 0 237.4762048 0 1 499574.2057 2629.476496 0193.3744829 33 0.371 23555.22938 346.240159 -2308 0.6309 0 237.9715284 0 1 465239.5003 2693.274969 0189.8802949 33 0.371 24725.72691 362.8314372 -2308 0.6309 0 233.32312 0 1 465470.737 2743.87095 0193.4583889 33 0.371 23004.22751 347.9646584 -2308 0.6309 0 240.5486514 0 1 453742.4189 2683.973473 0189.5530627 33 0.371 10704.02474 244.5547972 -2308 0.6309 0 236.1880385 0 1 489771.3291 2599.362224 0180.9575524 33 0.371 12784.92508 259.7412468 -2308 0.6309 0 220.9600291 0 1 491966.5305 2589.941679 044.11561445 33 0.371 8740.601578 274.1118439 -2308 0.6309 0 279.9604166 0 1 539268.2501 3335.266883 0208.6962989 33 0.371 20078.5189 342.3522597 -2308 0.6309 0 255.2817247 0 1 449903.3111 2799.973374 036.83970599 33 0.371 17534.68829 315.0867324 -2308 0.6309 0 242.6390616 0 1 470020.8895 2788.611556 075.29431455 33 0.371 11593.42715 379.1679935 -2308 0.6309 0 384.4996725 0 1 734989.5637 3067.845044 066.89416524 33 0.371 24401.84969 506.8214492 -2308 0.6309 0 340.5963852 0 1 689538.7046 4758.830611 0188.9097794 33 0.371 20067.55638 322.988385 -2308 0.6309 0 242.3317315 0 1 457081.1313 2646.373288 0183.7874631 33 0.371 18715.46533 307.388606 -2308 0.6309 0 234.0669512 0 1 469089.9867 2631.713648 0177.4573344 33 0.371 22467.33483 336.5828047 -2308 0.6309 0 238.1344639 0 1 466436.7585 2643.866968 0202.973561 33 0.371 21372.12282 344.812711 -2308 0.6309 0 237.2865969 0 1 475704.8182 2815.246038 061.25195729 33 0.371 39105.4388 601.5625177 -2308 0.6309 0 308.0783132 0 1 473855.0076 3852.773101 059.4459464 33 0.371 39910.31088 627.5628921 -2308 0.6309 0 280.356188 0 1 640610.7361 4176.060271 072.44000952 33 0.371 36793.88079 664.5500785 -2308 0.6309 0 315.857254 0 1 695032.7595 4865.845808 065.34327664 33 0.371 50216.76323 730.8085427 -2308 0.6309 0 308.5689549 0 1 610099.2565 4234.299198 0192.3010104 33 0.371 16004.67538 290.0147979 -2308 0.6309 0 243.1891552 0 1 487348.9914 2633.131341 0144.9923311 33 0.371 118007.9379 894.7279991 -2308 0.6309 0 177.5202629 0 1 413531.7873 3164.773228 0460Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFCu +/- Cu Intercept Cu Slope Fe Fe +/- Fe Intercept Fe Slope Hg Hg +/- Hg Intercept Hg Slope LE LE +/- LE InterceptD.8 fp-XRF Geochem Mode190.9937383 33 0.371 15983.10978 290.1389446 -2308 0.6309 0 225.0520998 0 1 477635.524 2653.009121 0206.8787732 33 0.371 15316.1576 296.6600863 -2308 0.6309 0 255.46391 0 1 473479.315 2731.444743 0190.2116591 33 0.371 17041.27388 297.4595836 -2308 0.6309 0 226.1792205 0 1 471542.3206 2646.808604 0187.8922564 33 0.371 19454.76019 320.1776936 -2308 0.6309 0 240.878501 0 1 456567.19 2655.131312 0173.6531506 33 0.371 19941.01086 306.5826976 -2308 0.6309 0 227.0658858 0 1 494716.1481 2547.056236 0184.1824463 33 0.371 15106.72685 277.7238865 -2308 0.6309 0 229.872385 0 1 476201.4223 2560.086084 0188.5621596 33 0.371 16274.61297 293.3395168 -2308 0.6309 0 218.6832198 0 1 468336.7931 2622.728513 073.85228944 33 0.371 14617.41883 411.371019 -2308 0.6309 0 357.3316536 0 1 620893.8474 4691.827734 081.7247085 33 0.371 11919.65268 391.4035279 -2308 0.6309 0 367.2174259 0 1 628539.105 4984.456824 0196.2918234 33 0.371 15830.06332 300.1354089 -2308 0.6309 0 243.2060132 0 1 454900.1307 2695.089946 0187.5433766 33 0.371 15434.48873 286.8278396 -2308 0.6309 0 242.6820479 0 1 496768.8196 2649.43396 069.49476448 33 0.371 18353.01469 435.5562642 -2308 0.6309 0 357.8911647 0 1 607016.2495 4389.648722 0209.2770943 33 0.371 21056.05415 344.9814876 -2308 0.6309 0 244.295089 0 1 485799.9481 2818.269898 0178.7024197 33 0.371 16503.60553 282.018495 -2308 0.6309 0 216.2996542 0 1 503170.2129 2556.30654 0174.1814336 33 0.371 41974.43287 463.4675053 -2308 0.6309 0 218.6801641 0 1 531347.1414 2793.082487 0185.9235566 33 0.371 22629.01787 335.4674139 -2308 0.6309 0 237.0263202 0 1 460090.0849 2607.105655 0192.7468362 33 0.371 23375.32994 353.326895 -2308 0.6309 0 254.0841153 0 1 450291.0683 2700.339235 0184.1653964 33 0.371 21267.33007 332.0438418 -2308 0.6309 0 232.7302459 0 1 478359.5896 2661.844434 0183.6990607 33 0.371 23363.58688 345.6700737 -2308 0.6309 0 236.3306642 0 1 484457.4646 2687.224056 0178.9211338 33 0.371 23927.21174 344.5835661 -2308 0.6309 0 216.914229 0 1 470307.7157 2619.14487 0188.2803647 33 0.371 18056.62432 302.896375 -2308 0.6309 0 244.2068857 0 1 495812.2062 2656.045125 046.00806 33 0.371 120976.5083 908.8702425 -2308 0.6309 0 177.9953339 0 1 401303.5859 3167.203743 0179.7778197 33 0.371 18405.94086 303.786914 -2308 0.6309 0 202.7858709 0 1 497109.1308 2611.094132 081.08770092 33 0.371 14559.71301 415.7182956 -2308 0.6309 0 366.6684264 0 1 639221.8443 4875.837318 0184.7257924 33 0.371 26621.13614 370.9871904 -2308 0.6309 0 215.7660137 0 1 488152.7267 2740.200027 0195.8362564 33 0.371 23525.46405 351.1071713 -2308 0.6309 0 243.9054921 0 1 481803.8804 2722.615956 0193.7816257 33 0.371 20480.94378 328.8477801 -2308 0.6309 0 223.1832591 0 1 483401.031 2695.765332 0181.5075417 33 0.371 15427.08727 279.1126244 -2308 0.6309 0 231.8641906 0 1 487435.0665 2561.947706 0181.5720799 33 0.371 13162.88254 259.4954331 -2308 0.6309 0 220.5214753 0 1 498898.6053 2537.410765 0189.9877923 33 0.371 11717.47983 253.8546196 -2308 0.6309 0 223.153768 0 1 494824.6121 2603.339246 0461Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFLE Slope La La +/- La Intercept La Slope Mg Mg +/- Mg Intercept Mg Slope Mn Mn +/- Mn Intercept Mn Slope Mo1 0 192.4927281 0 1 74144.95086 2063.138715 -7958 0.2851 1135.961474 121.9482804 -82 0.7346 01 0 275.1034736 0 1 62225.22736 1654.819924 -7958 0.2851 0 583.3052809 -82 0.7346 01 0 277.9474093 0 1 62706.13296 1807.960668 -7958 0.2851 0 623.2659502 -82 0.7346 01 0 238.5826225 0 1 53582.18282 1939.222045 -7958 0.2851 722.4271861 119.7399292 -82 0.7346 4.7449727511 0 317.1308076 0 1 22513.02861 4376.128456 -7958 0.2851 734.8188051 147.2199558 -82 0.7346 01 0 288.0849263 0 1 59509.96043 1826.022316 -7958 0.2851 650.4823275 151.6905563 -82 0.7346 01 0 284.8463137 0 1 60741.0594 1765.967535 -7958 0.2851 0 617.1682187 -82 0.7346 01 0 275.0061354 0 1 61706.76555 1695.63445 -7958 0.2851 0 610.0350295 -82 0.7346 01 0 274.0840542 0 1 66573.69292 1647.386573 -7958 0.2851 472.5901716 143.3693438 -82 0.7346 01 0 279.9873686 0 1 62521.05275 1671.813961 -7958 0.2851 0 603.0744754 -82 0.7346 01 0 284.331564 0 1 64878.6233 1766.694956 -7958 0.2851 0 613.2752847 -82 0.7346 01 0 276.5930182 0 1 62376.08921 1784.499852 -7958 0.2851 478.0964884 141.444576 -82 0.7346 01 0 271.4324711 0 1 64785.56835 1620.665828 -7958 0.2851 464.3424019 141.8145984 -82 0.7346 01 0 286.3479538 0 1 61536.42005 1822.971834 -7958 0.2851 455.7604634 148.3129104 -82 0.7346 01 0 276.9950051 0 1 63940.3655 1697.326059 -7958 0.2851 463.9758664 142.4674234 -82 0.7346 01 0 275.6813782 0 1 61868.75658 1681.777664 -7958 0.2851 540.7800166 139.7027684 -82 0.7346 01 0 275.8673613 0 1 66231.06082 1666.093507 -7958 0.2851 552.8374353 143.8075771 -82 0.7346 01 0 275.3458307 0 1 61923.94913 1716.420818 -7958 0.2851 518.5930298 145.2332683 -82 0.7346 01 0 278.9559869 0 1 65353.83543 1755.558195 -7958 0.2851 0 625.4695461 -82 0.7346 01 0 279.2021219 0 1 63850.20528 1778.172864 -7958 0.2851 0 632.2616612 -82 0.7346 01 0 229.9593696 0 1 50404.43182 2157.978298 -7958 0.2851 593.4794861 112.7750553 -82 0.7346 7.1050054521 0 191.9341549 0 1 65534.77173 1975.740571 -7958 0.2851 1051.306951 118.6622319 -82 0.7346 01 0 233.2376478 0 1 51002.7394 2174.418807 -7958 0.2851 642.2654401 116.7195029 -82 0.7346 6.4873070971 0 191.5039962 0 1 71630.46267 2207.786044 -7958 0.2851 1167.279038 119.9789441 -82 0.7346 01 0 274.8338361 0 1 67301.63127 1745.533979 -7958 0.2851 0 575.7259662 -82 0.7346 01 0 283.6902659 0 1 65175.24253 1815.790247 -7958 0.2851 0 600.8518923 -82 0.7346 01 0 275.9840768 0 1 63804.01064 1856.999061 -7958 0.2851 658.2513945 146.8371502 -82 0.7346 01 0 275.5406682 0 1 62869.14157 1851.783167 -7958 0.2851 665.1640819 144.6375325 -82 0.7346 01 0 278.2921906 0 1 62702.79818 1835.514464 -7958 0.2851 510.0703845 144.9303523 -82 0.7346 01 0 283.0402193 0 1 62242.91309 1768.74325 -7958 0.2851 0 610.4254172 -82 0.7346 01 0 282.3145931 0 1 63761.78263 1881.411065 -7958 0.2851 468.6096945 147.251337 -82 0.7346 01 0 281.1822063 0 1 63663.07014 1740.012347 -7958 0.2851 0 595.8235044 -82 0.7346 01 0 281.9032829 0 1 63133.70508 1891.000313 -7958 0.2851 0 643.5505997 -82 0.7346 01 0 364.4212435 0 1 41415.09582 3723.198779 -7958 0.2851 0 988.3227596 -82 0.7346 01 0 288.3876125 0 1 60530.4765 1752.728371 -7958 0.2851 0 601.4246718 -82 0.7346 01 0 429.7755367 0 1 0 13898.88831 -7958 0.2851 0 1710.133161 -82 0.7346 0D.8 fp-XRF Geochem Mode462Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFLE Slope La La +/- La Intercept La Slope Mg Mg +/- Mg Intercept Mg Slope Mn Mn +/- Mn Intercept Mn Slope MoD.8 fp-XRF Geochem Mode1 0 415.0766375 0 1 0 18025.35886 -7958 0.2851 0 1848.299996 -82 0.7346 01 0 354.2771984 0 1 28892.44223 4327.214527 -7958 0.2851 0 1194.117893 -82 0.7346 01 0 305.214554 0 1 61748.51569 1833.520241 -7958 0.2851 0 621.5027964 -82 0.7346 01 0 294.988446 0 1 64486.87002 1880.765631 -7958 0.2851 781.9962508 156.3376898 -82 0.7346 01 0 294.1030437 0 1 61933.44081 1891.591054 -7958 0.2851 0 642.0419058 -82 0.7346 01 0 279.6758716 0 1 63436.92382 1724.726709 -7958 0.2851 671.401522 149.339794 -82 0.7346 01 0 294.835961 0 1 67565.36534 1822.663579 -7958 0.2851 536.8893753 155.7268684 -82 0.7346 01 0 274.9168413 0 1 64867.41816 1723.570626 -7958 0.2851 0 621.1013538 -82 0.7346 01 0 194.4152662 0 1 69213.61938 1995.293209 -7958 0.2851 1025.167886 120.4114004 -82 0.7346 01 0 282.4040712 0 1 62482.01789 1708.307648 -7958 0.2851 0 620.9364438 -82 0.7346 01 0 275.3382105 0 1 62544.82272 1704.291791 -7958 0.2851 494.3972565 143.4548655 -82 0.7346 01 0 277.7508252 0 1 64792.98918 1805.612915 -7958 0.2851 0 653.0150468 -82 0.7346 01 0 281.2157248 0 1 59699.05688 1792.15706 -7958 0.2851 0 638.8774806 -82 0.7346 01 0 288.1262333 0 1 64306.74151 1807.573701 -7958 0.2851 0 653.8406773 -82 0.7346 01 0 280.4716881 0 1 63194.45569 1762.386361 -7958 0.2851 0 634.4877462 -82 0.7346 01 0 284.118327 0 1 64284.68272 1756.054643 -7958 0.2851 0 631.4317075 -82 0.7346 01 0 283.3638939 0 1 67926.91163 1730.511349 -7958 0.2851 619.0995889 150.1329799 -82 0.7346 01 0 272.5785659 0 1 61472.18288 1635.918109 -7958 0.2851 617.979898 146.1750492 -82 0.7346 01 0 282.8582885 0 1 63011.39693 1854.001225 -7958 0.2851 754.7773663 149.0516547 -82 0.7346 01 0 283.5759676 0 1 64009.40383 1741.658774 -7958 0.2851 0 629.5623412 -82 0.7346 01 0 288.0199217 0 1 66076.78907 1868.315492 -7958 0.2851 491.1211373 151.2109104 -82 0.7346 01 0 288.2205244 0 1 63562.99518 1826.715354 -7958 0.2851 0 641.7120622 -82 0.7346 01 0 282.2403116 0 1 60322.70591 1790.012988 -7958 0.2851 0 635.3126689 -82 0.7346 01 0 279.2700566 0 1 64374.09071 1715.999116 -7958 0.2851 0 639.2758061 -82 0.7346 01 0 281.4438921 0 1 65259.19184 1777.511727 -7958 0.2851 585.6691352 146.8814088 -82 0.7346 01 0 286.367024 0 1 62411.21902 1830.353114 -7958 0.2851 0 651.8516784 -82 0.7346 01 0 283.8734954 0 1 65751.98881 1763.911148 -7958 0.2851 0 636.9504009 -82 0.7346 01 0 292.6895339 0 1 65070.9388 1940.550047 -7958 0.2851 529.5986014 151.9779945 -82 0.7346 01 0 296.0318292 0 1 65634.83293 1848.182378 -7958 0.2851 691.1512881 155.5578217 -82 0.7346 01 0 282.8270321 0 1 63135.20172 1776.755303 -7958 0.2851 0 650.0483819 -82 0.7346 01 0 191.9877396 0 1 66706.1991 1939.520413 -7958 0.2851 1186.139893 118.9317529 -82 0.7346 01 0 284.6980027 0 1 62505.46715 1766.025534 -7958 0.2851 805.8232437 151.2443715 -82 0.7346 01 0 293.2633046 0 1 61579.36558 1874.149669 -7958 0.2851 714.9757083 157.0690934 -82 0.7346 01 0 286.3812578 0 1 62342.01333 1723.781829 -7958 0.2851 836.016979 154.9396446 -82 0.7346 01 0 291.4510271 0 1 64907.08655 1783.084018 -7958 0.2851 512.5547599 156.7079719 -82 0.7346 01 0 286.8307574 0 1 61676.64588 1735.735268 -7958 0.2851 615.2291024 151.8581131 -82 0.7346 01 0 299.1503424 0 1 65086.82615 1753.559228 -7958 0.2851 0 624.8644013 -82 0.7346 01 0 284.9110506 0 1 64137.68935 1663.665212 -7958 0.2851 796.6038949 154.126309 -82 0.7346 0463Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFLE Slope La La +/- La Intercept La Slope Mg Mg +/- Mg Intercept Mg Slope Mn Mn +/- Mn Intercept Mn Slope MoD.8 fp-XRF Geochem Mode1 0 294.5870708 0 1 61358.09039 1805.132519 -7958 0.2851 502.0649114 152.4374633 -82 0.7346 01 0 290.5769321 0 1 59062.71706 1740.7842 -7958 0.2851 0 637.1919706 -82 0.7346 01 0 279.0802244 0 1 64845.69237 1698.060276 -7958 0.2851 451.9018734 146.8578427 -82 0.7346 01 0 289.0249223 0 1 62319.9113 1745.624136 -7958 0.2851 513.2954259 151.5970772 -82 0.7346 01 0 277.6203907 0 1 64986.13428 1762.907249 -7958 0.2851 554.9297813 146.7679679 -82 0.7346 01 0 279.1602207 0 1 61163.22646 1647.973216 -7958 0.2851 0 645.632393 -82 0.7346 01 0 273.2220934 0 1 60337.49094 1687.673049 -7958 0.2851 0 680.2050764 -82 0.7346 01 0 278.811729 0 1 65187.95548 1661.975216 -7958 0.2851 504.7966123 149.2880781 -82 0.7346 01 0 284.708816 0 1 59289.1491 1712.270044 -7958 0.2851 0 649.6022885 -82 0.7346 01 0 278.0952117 0 1 59693.73507 1674.020758 -7958 0.2851 454.6507158 143.8717938 -82 0.7346 01 0 290.7479078 0 1 60249.08301 1769.706954 -7958 0.2851 0 623.7351868 -82 0.7346 01 0 292.7536191 0 1 60855.88039 1773.697521 -7958 0.2851 0 643.6990415 -82 0.7346 01 0 291.545413 0 1 63447.52616 1765.23528 -7958 0.2851 486.0369563 153.9594352 -82 0.7346 01 0 283.7769842 0 1 60709.18395 1689.275519 -7958 0.2851 0 632.815255 -82 0.7346 01 0 193.3601716 0 1 67770.29629 1940.48515 -7958 0.2851 949.6865646 118.5896011 -82 0.7346 01 0 285.9289165 0 1 62125.70202 1671.698017 -7958 0.2851 566.2119233 151.2268316 -82 0.7346 01 0 280.7879269 0 1 59806.53073 1706.338083 -7958 0.2851 679.5229608 150.7178172 -82 0.7346 01 0 284.286061 0 1 62616.86699 1714.899538 -7958 0.2851 625.1088069 148.4334673 -82 0.7346 01 0 286.2216971 0 1 63917.74144 1780.21853 -7958 0.2851 0 650.6050341 -82 0.7346 01 0 286.5732968 0 1 61740.79466 1679.363519 -7958 0.2851 0 644.4830355 -82 0.7346 01 0 287.9106105 0 1 61291.35736 1720.807482 -7958 0.2851 0 607.5010792 -82 0.7346 01 0 281.1303914 0 1 61659.53128 1708.601325 -7958 0.2851 487.0050083 149.4318655 -82 0.7346 01 0 343.6231894 0 1 48348.84102 2744.475628 -7958 0.2851 636.7260778 183.6903795 -82 0.7346 01 0 299.8222332 0 1 62487.98398 1832.457892 -7958 0.2851 641.8725392 160.5577808 -82 0.7346 01 0 301.2458477 0 1 63197.72689 1873.720885 -7958 0.2851 495.0565831 155.4967216 -82 0.7346 01 0 426.2008523 0 1 0 11887.52116 -7958 0.2851 0 1640.252957 -82 0.7346 01 0 383.221538 0 1 25695.27957 5071.38223 -7958 0.2851 0 1421.436643 -82 0.7346 01 0 289.9903354 0 1 68268.83211 1723.279078 -7958 0.2851 0 623.2891447 -82 0.7346 01 0 282.8897937 0 1 63268.27351 1671.210967 -7958 0.2851 473.2987136 145.2478647 -82 0.7346 01 0 280.3643662 0 1 63207.84432 1677.74725 -7958 0.2851 524.6479254 146.4093839 -82 0.7346 01 0 295.7360546 0 1 59637.60854 1857.011723 -7958 0.2851 632.3605527 153.8245062 -82 0.7346 01 0 360.0759984 0 1 56425.76901 3113.072255 -7958 0.2851 0 923.7490668 -82 0.7346 01 0 343.0252215 0 1 28451.06268 4013.289485 -7958 0.2851 0 1163.991039 -82 0.7346 01 0 374.1972149 0 1 16461.95875 5154.258619 -7958 0.2851 0 1463.931072 -82 0.7346 01 0 333.576552 0 1 33404.84064 3909.506227 -7958 0.2851 0 1124.837293 -82 0.7346 01 0 284.6386615 0 1 57900.0993 1692.076313 -7958 0.2851 0 634.9646609 -82 0.7346 01 0 192.7548374 0 1 64457.34441 1908.152205 -7958 0.2851 1073.905178 118.8068472 -82 0.7346 0464Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFLE Slope La La +/- La Intercept La Slope Mg Mg +/- Mg Intercept Mg Slope Mn Mn +/- Mn Intercept Mn Slope MoD.8 fp-XRF Geochem Mode1 0 291.457354 0 1 60751.0253 1702.228748 -7958 0.2851 689.0730948 154.4617524 -82 0.7346 01 0 297.6378061 0 1 60419.84944 1798.594455 -7958 0.2851 0 632.4311697 -82 0.7346 01 0 290.402256 0 1 64553.46191 1719.13538 -7958 0.2851 0 622.0761106 -82 0.7346 01 0 287.1060093 0 1 64722.63408 1700.044005 -7958 0.2851 475.5680063 151.1481024 -82 0.7346 01 0 274.5951207 0 1 61205.10283 1618.187229 -7958 0.2851 0 609.1576777 -82 0.7346 01 0 283.3044235 0 1 61242.38452 1600.511382 -7958 0.2851 0 608.4114503 -82 0.7346 01 0 290.4104539 0 1 63057.32222 1672.070354 -7958 0.2851 0 620.3673495 -82 0.7346 01 0 419.5525116 0 1 32086.91443 4840.868789 -7958 0.2851 0 1156.529704 -82 0.7346 01 0 439.2545923 0 1 27767.22062 5295.062869 -7958 0.2851 0 1259.692268 -82 0.7346 01 0 301.06651 0 1 63451.92171 1747.893891 -7958 0.2851 0 632.0041895 -82 0.7346 01 0 288.0278417 0 1 60777.09093 1760.733986 -7958 0.2851 0 643.4103831 -82 0.7346 01 0 391.5985395 0 1 37522.04316 4358.26341 -7958 0.2851 0 1153.337215 -82 0.7346 01 0 297.8335455 0 1 59047.82027 1874.733489 -7958 0.2851 0 692.3527476 -82 0.7346 01 0 278.2625897 0 1 56997.82871 1608.674507 -7958 0.2851 0 616.5686488 -82 0.7346 01 0 266.2666728 0 1 56230.51674 1836.016273 -7958 0.2851 622.5111867 136.7970404 -82 0.7346 01 0 283.2188689 0 1 65451.92959 1616.18068 -7958 0.2851 0 627.3717584 -82 0.7346 01 0 292.3608924 0 1 63021.74466 1681.358996 -7958 0.2851 0 636.6318509 -82 0.7346 01 0 284.604634 0 1 61648.85416 1698.53867 -7958 0.2851 0 635.0771148 -82 0.7346 01 0 281.5507462 0 1 59995.38219 1715.205321 -7958 0.2851 0 656.6084882 -82 0.7346 01 0 279.1264094 0 1 63360.88914 1630.534904 -7958 0.2851 0 637.3466442 -82 0.7346 01 0 287.9926476 0 1 61573.39415 1730.089303 -7958 0.2851 0 648.0373005 -82 0.7346 01 0 196.1230156 0 1 64918.41782 1894.036041 -7958 0.2851 1130.556296 120.8547391 -82 0.7346 01 0 281.6956656 0 1 58952.23192 1666.80321 -7958 0.2851 0 644.2202056 -82 0.7346 01 0 421.4678216 0 1 26188.98598 5161.558057 -7958 0.2851 0 1429.192943 -82 0.7346 01 0 281.8411082 0 1 61015.24963 1779.36314 -7958 0.2851 477.5441923 147.1533422 -82 0.7346 01 0 290.2211007 0 1 62688.04365 1745.205891 -7958 0.2851 525.9321921 150.9640789 -82 0.7346 01 0 287.6557561 0 1 58763.14231 1714.934303 -7958 0.2851 0 648.0472697 -82 0.7346 01 0 280.2447322 0 1 60839.40569 1613.079323 -7958 0.2851 0 619.3512843 -82 0.7346 01 0 282.9109875 0 1 56346.23374 1572.792399 -7958 0.2851 0 627.057149 -82 0.7346 01 0 287.6942444 0 1 60540.39084 1686.40041 -7958 0.2851 0 624.232385 -82 0.7346 0465Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFMo +/- Mo Intercept Mo Slope Nb Nb +/- Nb Intercept Nb Slope Nd Nd +/- Nd Intercept Nd Slope Ni Ni +/- Ni Intercept44.4962001 0 1 52.50444717 3.53089355 0.76 0.5027 0 62.47507774 0 1 0 207.2560746 042.11067738 0 1 7.368349588 1.382246305 0.76 0.5027 0 90.68024783 0 1 0 247.3868626 042.04606291 0 1 5.521879846 1.465199914 0.76 0.5027 0 90.77875924 0 1 0 255.9018673 01.561399303 0 1 8.694241299 1.66445606 0.76 0.5027 0 78.33025144 0 1 0 230.5693285 040.94826346 0 1 0 50.32236882 0.76 0.5027 0 99.19397258 0 1 0 358.9848475 045.95577232 0 1 5.75137061 1.521870843 0.76 0.5027 0 93.80910775 0 1 0 274.0740954 046.56247402 0 1 9.214199459 1.611022491 0.76 0.5027 0 93.24942868 0 1 0 269.7412268 042.78279666 0 1 4.359429598 1.399365892 0.76 0.5027 0 90.42770324 0 1 0 251.7904825 044.76240779 0 1 7.845193136 1.549147489 0.76 0.5027 0 90.48846487 0 1 0 250.8180099 046.02241587 0 1 9.830904425 1.540959708 0.76 0.5027 0 92.16253977 0 1 0 254.0975403 043.46786373 0 1 8.989290628 1.565756689 0.76 0.5027 0 93.09377406 0 1 0 262.8188913 044.80840925 0 1 7.38904092 1.484389564 0.76 0.5027 0 90.93689787 0 1 0 253.4866066 044.04721444 0 1 7.35761252 1.522668817 0.76 0.5027 0 89.36286141 0 1 0 255.3722273 046.87765832 0 1 8.767826335 1.639098309 0.76 0.5027 0 93.98377079 0 1 0 265.6163981 045.60201775 0 1 7.11514053 1.49436774 0.76 0.5027 0 90.74240049 0 1 0 260.2237035 044.70469196 0 1 8.352056528 1.544512324 0.76 0.5027 0 90.53073867 0 1 0 244.8564589 043.37055555 0 1 9.477506615 1.548790897 0.76 0.5027 0 90.43726427 0 1 0 255.3694379 042.59348175 0 1 10.15877604 1.534921385 0.76 0.5027 0 90.66537779 0 1 0 248.5859254 044.45732715 0 1 6.300732132 1.487484117 0.76 0.5027 0 91.58701504 0 1 0 252.2961255 044.62468795 0 1 6.806828297 1.544416384 0.76 0.5027 0 91.52473606 0 1 0 261.3462694 01.524023764 0 1 9.762006014 1.79387316 0.76 0.5027 0 74.79101856 0 1 0 223.3765695 043.42044106 0 1 43.45344504 3.223995004 0.76 0.5027 0 62.88844459 0 1 0 207.8752359 01.649570733 0 1 9.191383584 1.804939184 0.76 0.5027 0 76.33935391 0 1 0 236.6490816 041.57145955 0 1 50.68015985 3.378039636 0.76 0.5027 0 61.89120929 0 1 0 199.9464428 045.06819262 0 1 6.842419607 1.47276229 0.76 0.5027 0 89.35605324 0 1 0 254.2996778 049.91632644 0 1 9.210411066 1.83811228 0.76 0.5027 0 92.47496676 0 1 0 265.4380441 045.64582837 0 1 11.73176166 1.667472088 0.76 0.5027 0 91.25991248 0 1 0 252.2059718 044.45388367 0 1 7.237595875 1.53304585 0.76 0.5027 0 90.47951539 0 1 0 256.8089342 045.01502818 0 1 7.687950864 1.572782217 0.76 0.5027 0 90.82541885 0 1 0 255.3077459 044.02205498 0 1 9.008592662 1.595516292 0.76 0.5027 0 92.74443031 0 1 0 258.6717517 047.18535629 0 1 12.05715548 1.729504049 0.76 0.5027 0 92.34786686 0 1 0 264.4410887 042.87501689 0 1 5.819162172 1.406035375 0.76 0.5027 0 91.7271692 0 1 0 263.3728826 047.17250864 0 1 8.288589468 1.716302034 0.76 0.5027 0 91.64446665 0 1 0 273.7710356 055.32635779 0 1 7.415247489 2.141591764 0.76 0.5027 0 115.8814657 0 1 0 408.8685908 040.76827937 0 1 5.958138146 1.374175982 0.76 0.5027 0 94.1041855 0 1 0 268.6214282 053.79728298 0 1 0 57.19438852 0.76 0.5027 0 135.150566 0 1 0 538.2810399 0D.8 fp-XRF Geochem Mode466Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFMo +/- Mo Intercept Mo Slope Nb Nb +/- Nb Intercept Nb Slope Nd Nd +/- Nd Intercept Nd Slope Ni Ni +/- Ni InterceptD.8 fp-XRF Geochem Mode47.14815337 0 1 0 55.57533652 0.76 0.5027 0 130.7438315 0 1 0 539.1061371 046.51800171 0 1 8.742986756 2.07284476 0.76 0.5027 0 111.789205 0 1 0 401.9811969 049.74483922 0 1 6.56272476 1.634720219 0.76 0.5027 0 98.76966018 0 1 0 287.8937622 051.53312696 0 1 6.029014933 1.69905522 0.76 0.5027 0 95.19014307 0 1 0 279.2908232 050.49223643 0 1 8.407604032 1.686936474 0.76 0.5027 0 95.46619489 0 1 0 276.7543728 045.00361791 0 1 7.096715984 1.545616427 0.76 0.5027 0 91.37961222 0 1 0 255.0601336 049.96977112 0 1 10.05040888 1.815320279 0.76 0.5027 0 95.60510228 0 1 0 284.510024 043.603192 0 1 6.001360784 1.431896262 0.76 0.5027 0 90.5396109 0 1 0 249.4404322 044.30472304 0 1 53.80058985 3.477349573 0.76 0.5027 0 63.59488578 0 1 0 208.5830172 045.07043635 0 1 6.970287389 1.549867281 0.76 0.5027 0 92.31749053 0 1 0 252.743228 043.57148068 0 1 5.873974567 1.454075462 0.76 0.5027 0 90.51198211 0 1 0 251.5092173 044.2740534 0 1 9.980694777 1.602958137 0.76 0.5027 0 91.54994482 0 1 0 267.1800137 044.72494051 0 1 7.027556034 1.528248531 0.76 0.5027 0 91.56075623 0 1 0 259.0106965 048.53305337 0 1 9.215497688 1.675633389 0.76 0.5027 0 94.08481486 0 1 0 266.0214729 043.10655906 0 1 8.224661279 1.575959013 0.76 0.5027 0 92.43151114 0 1 0 267.0682429 047.24432438 0 1 7.25055438 1.593748454 0.76 0.5027 0 94.05078655 0 1 0 266.2607889 045.59676908 0 1 9.353527648 1.647575728 0.76 0.5027 0 92.68791868 0 1 0 271.464294 043.58960044 0 1 7.438849498 1.502954966 0.76 0.5027 0 89.83376041 0 1 0 252.518403 047.08765107 0 1 10.32697404 1.730562242 0.76 0.5027 0 92.16014519 0 1 0 269.8416927 046.03574288 0 1 8.461616944 1.583314101 0.76 0.5027 0 92.64655365 0 1 0 261.0094527 049.67472825 0 1 7.771290668 1.697095336 0.76 0.5027 0 94.11455506 0 1 0 276.7811828 046.91232897 0 1 8.585644163 1.592063498 0.76 0.5027 0 94.42561459 0 1 0 271.2633562 043.4330821 0 1 7.063320182 1.477027923 0.76 0.5027 0 92.06446968 0 1 0 255.7103068 048.19101919 0 1 8.760721097 1.670585542 0.76 0.5027 0 90.77223394 0 1 0 271.1028992 045.65512823 0 1 12.40041429 1.788904606 0.76 0.5027 0 91.69548036 0 1 0 277.8169337 045.44040865 0 1 7.629653075 1.566937791 0.76 0.5027 0 93.31553609 0 1 0 263.8006568 046.02105956 0 1 15.8658866 1.852189534 0.76 0.5027 0 92.52355768 0 1 0 276.6495583 049.52830956 0 1 11.18137491 1.836413491 0.76 0.5027 0 95.0038907 0 1 0 289.0477206 051.25601961 0 1 9.30633685 1.939226125 0.76 0.5027 0 95.38171694 0 1 0 281.1897549 048.65711583 0 1 7.876625776 1.651654405 0.76 0.5027 0 92.50859326 0 1 0 263.1035958 043.22487275 0 1 48.40649469 3.361406485 0.76 0.5027 0 61.55177728 0 1 0 203.1759806 048.65063315 0 1 6.654353559 1.612442922 0.76 0.5027 0 92.29080915 0 1 0 273.4452841 047.89835727 0 1 8.857295412 1.664017112 0.76 0.5027 0 95.32453549 0 1 0 272.6305053 047.55268394 0 1 9.591025015 1.655176124 0.76 0.5027 0 93.29463941 0 1 0 269.4935024 049.49483655 0 1 7.628713639 1.612961178 0.76 0.5027 0 95.38207705 0 1 0 271.8411252 045.51306676 0 1 9.71029089 1.652868989 0.76 0.5027 0 93.54613741 0 1 0 262.9317966 049.62866518 0 1 7.908091989 1.69504932 0.76 0.5027 0 96.38766424 0 1 0 285.7004455 045.60277243 0 1 7.262922269 1.549760588 0.76 0.5027 0 92.48809736 0 1 0 264.6387305 0467Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFMo +/- Mo Intercept Mo Slope Nb Nb +/- Nb Intercept Nb Slope Nd Nd +/- Nd Intercept Nd Slope Ni Ni +/- Ni InterceptD.8 fp-XRF Geochem Mode47.08763726 0 1 5.853668854 1.534878207 0.76 0.5027 0 95.24764597 0 1 0 276.314265 047.65099518 0 1 6.770393169 1.607552075 0.76 0.5027 0 94.53219937 0 1 0 271.2289686 044.95792634 0 1 9.271334377 1.576761145 0.76 0.5027 0 91.84704928 0 1 0 257.795076 045.60700335 0 1 6.203089416 1.568909762 0.76 0.5027 0 94.14562842 0 1 0 269.2800595 042.47920498 0 1 7.192839975 1.517021806 0.76 0.5027 0 92.06660296 0 1 0 259.2788085 045.54561831 0 1 8.207084833 1.578795458 0.76 0.5027 0 91.79641935 0 1 0 255.5259451 042.21463332 0 1 7.05923156 1.475571086 0.76 0.5027 0 89.51886299 0 1 0 253.3052445 045.0868437 0 1 7.274813221 1.552360354 0.76 0.5027 0 92.06148894 0 1 0 257.4957128 043.65160412 0 1 0 43.57089202 0.76 0.5027 0 93.00787976 0 1 0 258.8846618 044.33667202 0 1 7.959523411 1.483446731 0.76 0.5027 0 91.25628026 0 1 0 251.3790463 044.33066388 0 1 6.112098715 1.469140782 0.76 0.5027 0 94.41658195 0 1 0 259.9885881 048.26480047 0 1 6.815927933 1.592849178 0.76 0.5027 0 95.34568474 0 1 0 274.3558927 048.76654133 0 1 7.055131787 1.618911051 0.76 0.5027 0 95.35729388 0 1 0 278.2908938 045.65656965 0 1 6.128087135 1.53102335 0.76 0.5027 0 92.41087912 0 1 0 262.6430783 043.4316349 0 1 52.79354694 3.443340083 0.76 0.5027 0 63.40722365 0 1 0 201.0253122 046.06052126 0 1 6.60938365 1.562532676 0.76 0.5027 0 92.90352793 0 1 0 264.5029682 044.01655609 0 1 4.326199449 1.43330764 0.76 0.5027 0 91.41975085 0 1 0 259.7227248 049.18804871 0 1 7.533644636 1.676794619 0.76 0.5027 0 92.82184327 0 1 0 271.0383243 049.59303368 0 1 7.306422256 1.66330803 0.76 0.5027 0 93.49802711 0 1 0 277.3771315 044.58142922 0 1 8.531315737 1.630004262 0.76 0.5027 0 93.29166335 0 1 0 268.7158366 042.49363624 0 1 5.013664893 1.352164381 0.76 0.5027 0 94.40921242 0 1 0 270.3014544 042.71716078 0 1 0 40.39513903 0.76 0.5027 0 91.82772392 0 1 0 253.2964366 055.47003579 0 1 0 54.2178583 0.76 0.5027 0 109.4863393 0 1 0 343.876332 050.32441685 0 1 8.434639062 1.776402183 0.76 0.5027 0 97.35154748 0 1 0 291.8912614 048.83713859 0 1 13.4615687 1.892982612 0.76 0.5027 0 97.28779737 0 1 0 282.3901699 048.70802238 0 1 0 62.71669366 0.76 0.5027 0 134.7484854 0 1 0 522.7064377 047.76271096 0 1 0 57.41350217 0.76 0.5027 0 121.3589356 0 1 0 457.9024821 046.27652237 0 1 8.301631567 1.576398478 0.76 0.5027 0 95.03723237 0 1 0 266.0166632 045.67166542 0 1 7.247019982 1.543811504 0.76 0.5027 0 92.12457589 0 1 0 264.3948836 044.93213883 0 1 7.321581905 1.565110005 0.76 0.5027 0 91.51266796 0 1 0 258.128029 048.79774992 0 1 12.00043897 1.78584425 0.76 0.5027 0 96.37955927 0 1 0 283.1668752 059.31094515 0 1 10.66350636 2.425090867 0.76 0.5027 0 113.2730906 0 1 0 424.5563615 046.66807401 0 1 0 52.18934552 0.76 0.5027 0 109.4803296 0 1 0 392.4405455 046.47784453 0 1 0 54.96404421 0.76 0.5027 0 117.7014833 0 1 0 449.3047486 047.04103876 0 1 0 55.31618621 0.76 0.5027 0 106.6925661 0 1 0 398.0316341 046.99206259 0 1 9.019643013 1.63038679 0.76 0.5027 0 93.45596819 0 1 0 267.9672034 043.74521061 0 1 56.53889578 3.514863136 0.76 0.5027 0 62.86272351 0 1 0 204.8056075 0468Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFMo +/- Mo Intercept Mo Slope Nb Nb +/- Nb Intercept Nb Slope Nd Nd +/- Nd Intercept Nd Slope Ni Ni +/- Ni InterceptD.8 fp-XRF Geochem Mode47.48894778 0 1 8.522823477 1.641685021 0.76 0.5027 0 94.91198078 0 1 0 268.5955837 048.09285622 0 1 8.152464191 1.659071956 0.76 0.5027 0 96.86288048 0 1 0 278.14834 043.7047404 0 1 8.820045685 1.602665659 0.76 0.5027 0 94.49218842 0 1 0 269.6238496 047.73889556 0 1 8.778429871 1.638199064 0.76 0.5027 0 93.35803668 0 1 0 276.5457803 041.78212 0 1 5.986360253 1.383905912 0.76 0.5027 0 90.20173922 0 1 0 247.8397177 042.93408362 0 1 6.770346606 1.441761113 0.76 0.5027 0 92.87736848 0 1 0 265.9520834 047.29984879 0 1 8.997590668 1.676960952 0.76 0.5027 0 94.25936627 0 1 0 269.7866722 054.960035 0 1 0 61.93998997 0.76 0.5027 0 133.6247501 0 1 0 502.8594595 055.17925082 0 1 0 65.90053501 0.76 0.5027 0 138.8574768 0 1 0 569.1426696 047.09908529 0 1 10.3361475 1.711161128 0.76 0.5027 0 97.69220486 0 1 0 274.5733123 045.32272827 0 1 5.405610357 1.418249993 0.76 0.5027 0 93.693641 0 1 0 269.5780655 052.07202461 0 1 0 55.13018916 0.76 0.5027 0 123.6801364 0 1 0 464.4467699 049.24435981 0 1 8.454016249 1.698031448 0.76 0.5027 0 96.75001121 0 1 0 283.4858282 042.70739539 0 1 9.333982472 1.486138838 0.76 0.5027 0 91.6628256 0 1 0 253.1790822 040.56470877 0 1 7.239464845 1.608717797 0.76 0.5027 0 87.4788373 0 1 0 252.592735 046.67314153 0 1 8.252284144 1.60160302 0.76 0.5027 0 92.70801744 0 1 0 266.0446578 048.65484214 0 1 7.356384635 1.737077469 0.76 0.5027 0 95.03793981 0 1 0 276.1137239 047.1002071 0 1 8.383149039 1.631753836 0.76 0.5027 0 93.18603548 0 1 0 263.1022814 045.65043467 0 1 10.29070875 1.65163416 0.76 0.5027 0 91.89535478 0 1 0 265.9672146 044.17612642 0 1 9.418274867 1.611802207 0.76 0.5027 0 91.35787104 0 1 0 257.1346641 044.56615382 0 1 8.617541729 1.601648218 0.76 0.5027 0 94.17561179 0 1 0 260.9918214 043.87599196 0 1 53.95801431 3.495010601 0.76 0.5027 0 62.89172995 0 1 0 215.5629653 043.08082755 0 1 9.902083988 1.581183024 0.76 0.5027 0 91.6349365 0 1 0 265.7916337 051.36798351 0 1 0 66.60102195 0.76 0.5027 0 134.2139997 0 1 0 516.9280862 045.52587011 0 1 15.14959922 1.875199957 0.76 0.5027 0 92.67534321 0 1 0 262.6981551 049.39017771 0 1 20.42616915 2.035969481 0.76 0.5027 0 94.49498263 0 1 0 271.6727136 045.66293616 0 1 8.061434673 1.585877313 0.76 0.5027 0 94.8595719 0 1 0 268.172891 043.46910469 0 1 8.613276931 1.467253505 0.76 0.5027 0 93.13594076 0 1 0 254.4606962 042.9814498 0 1 5.451917287 1.409593687 0.76 0.5027 0 91.76151541 0 1 0 253.4043031 043.86696829 0 1 5.237763087 1.385594104 0.76 0.5027 0 93.69978337 0 1 0 261.8754123 0469Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFNi Slope P P +/- P Intercept P Slope Pb Pb +/- Pb Intercept Pb Slope Pr Pr +/- Pr Intercept Pr Slope Rb1 0 106.1176164 0 1 42.33534422 8.174288234 6.4 0.2667 0 44.20824622 0 1 95.472835411 0 87.91842179 0 1 0 148.0051767 6.4 0.2667 0 63.42562702 0 1 54.666938831 0 93.94999497 0 1 16.19083391 5.035779754 6.4 0.2667 0 64.06456197 0 1 60.639914591 593.7347773 63.44320526 0 1 19.27862065 5.543219884 6.4 0.2667 0 55.29339635 0 1 57.673537861 5833.113206 134.1564447 0 1 0 190.6778403 6.4 0.2667 0 70.53643029 0 1 33.989368691 0 94.89033212 0 1 20.00781063 5.32387459 6.4 0.2667 0 66.56185872 0 1 66.00395551 270.8468502 75.18114478 0 1 18.41241614 5.111087634 6.4 0.2667 0 65.75744706 0 1 63.568218761 223.4185247 69.65835072 0 1 18.09442311 4.982099955 6.4 0.2667 0 63.9324741 0 1 59.329117771 274.8540592 71.91223252 0 1 16.697573 4.980273641 6.4 0.2667 0 63.52280993 0 1 62.326495881 235.32147 72.50537028 0 1 0 154.9683669 6.4 0.2667 0 64.9205502 0 1 62.707778581 288.7015837 74.19535054 0 1 0 157.9365666 6.4 0.2667 0 65.18236334 0 1 67.974972751 0 94.24752543 0 1 0 149.1119621 6.4 0.2667 0 63.55009736 0 1 66.823764091 274.5605973 71.3496901 0 1 0 148.3267553 6.4 0.2667 0 62.98206078 0 1 60.230761131 0 94.94828272 0 1 23.24649953 5.448593838 6.4 0.2667 0 66.13342223 0 1 62.546764121 483.0979182 74.69677349 0 1 18.93971221 5.168535813 6.4 0.2667 0 64.15190089 0 1 64.511147991 294.0307482 71.90510511 0 1 0 152.8332495 6.4 0.2667 0 63.60506022 0 1 62.665912921 279.3629364 72.99621594 0 1 21.32980604 5.173321219 6.4 0.2667 0 63.68836295 0 1 65.296787121 463.1526586 72.98633549 0 1 0 145.2575725 6.4 0.2667 0 63.80619073 0 1 66.065747211 0 92.22147783 0 1 18.03156015 5.112514145 6.4 0.2667 0 64.60345334 0 1 61.242460261 386.6731678 72.30964509 0 1 28.40664058 5.521408401 6.4 0.2667 0 64.23853874 0 1 54.297771361 2376.091242 78.61225253 0 1 23.65659051 5.968287333 6.4 0.2667 0 52.36918846 0 1 55.255840831 0 107.472217 0 1 35.81904446 7.54555102 6.4 0.2667 0 44.12784554 0 1 78.047194071 2290.33576 78.9099186 0 1 26.9474353 6.319189051 6.4 0.2667 0 53.58345648 0 1 58.692817351 0 101.643689 0 1 33.02668795 7.382761982 6.4 0.2667 0 43.64226883 0 1 78.63297521 0 89.06823523 0 1 0 141.8895631 6.4 0.2667 0 63.07021976 0 1 63.918094211 871.5378933 80.89327655 0 1 17.56560212 5.296022446 6.4 0.2667 0 65.43051452 0 1 68.123332931 505.5022293 74.42348661 0 1 17.80741233 5.114109091 6.4 0.2667 0 64.18941361 0 1 68.657546271 352.3049351 73.95642427 0 1 0 154.3989891 6.4 0.2667 0 63.52063046 0 1 66.405834321 676.203425 75.84332143 0 1 0 152.1252391 6.4 0.2667 0 64.2868593 0 1 61.297178161 0 93.6179729 0 1 15.32586668 5.008822377 6.4 0.2667 0 65.16357707 0 1 65.854733021 472.6088179 75.16692859 0 1 27.73218638 5.635974595 6.4 0.2667 0 64.88312492 0 1 62.692150061 0 89.36644966 0 1 19.15285798 5.056193779 6.4 0.2667 0 64.75795123 0 1 54.498413741 0 96.48280775 0 1 18.24335979 5.41162392 6.4 0.2667 0 64.10518646 0 1 74.974860641 5165.450733 140.1634714 0 1 0 208.2575184 6.4 0.2667 0 82.04699381 0 1 58.11594661 323.8272483 75.09979397 0 1 17.80773625 4.981151599 6.4 0.2667 0 66.36731034 0 1 56.048233261 8105.218314 191.1189842 0 1 0 241.7752705 6.4 0.2667 0 95.32857495 0 1 13.96762393D.8 fp-XRF Geochem Mode470Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFNi Slope P P +/- P Intercept P Slope Pb Pb +/- Pb Intercept Pb Slope Pr Pr +/- Pr Intercept Pr Slope RbD.8 fp-XRF Geochem Mode1 8126.304206 188.5742296 0 1 0 234.9811815 6.4 0.2667 0 93.41940697 0 1 10.084801621 6378.016928 150.559767 0 1 0 207.2702375 6.4 0.2667 0 78.66501402 0 1 61.306324791 0 96.32448697 0 1 31.0282885 6.073899408 6.4 0.2667 0 69.82214667 0 1 70.458262911 544.4366085 82.04112866 0 1 0 173.6294276 6.4 0.2667 0 67.56768183 0 1 72.436740741 787.7199454 83.05974894 0 1 19.9945476 5.578799051 6.4 0.2667 0 67.15197829 0 1 65.678044621 347.7477614 73.82426258 0 1 15.31005074 5.049380242 6.4 0.2667 0 64.30154405 0 1 63.410975791 653.4817429 84.94348214 0 1 0 169.8630593 6.4 0.2667 0 67.81516482 0 1 67.745642631 0 90.61953931 0 1 21.96421086 5.194933348 6.4 0.2667 0 63.04138345 0 1 61.55703441 0 103.8634972 0 1 41.33513875 7.780257738 6.4 0.2667 0 44.4981422 0 1 86.721038331 0 90.34945153 0 1 17.29613875 5.159501504 6.4 0.2667 0 64.89022564 0 1 58.771101441 486.043467 71.44794026 0 1 0 148.7627068 6.4 0.2667 0 64.0530465 0 1 61.549288651 367.5760132 72.8654817 0 1 23.49247781 5.437923483 6.4 0.2667 0 64.12209762 0 1 74.762973741 0 98.68807473 0 1 0 152.8722043 6.4 0.2667 0 64.49856352 0 1 66.478082951 823.1557598 80.06234265 0 1 22.06308828 5.480314789 6.4 0.2667 0 66.28096847 0 1 71.335128261 251.3299973 73.00679875 0 1 16.84312431 5.182617299 6.4 0.2667 0 64.69424407 0 1 66.816525461 0 91.67929061 0 1 22.79543473 5.510948901 6.4 0.2667 0 65.46628219 0 1 65.634449871 266.1364672 74.17553932 0 1 22.08885797 5.414022661 6.4 0.2667 0 65.12437128 0 1 67.607324741 254.1389348 70.03298169 0 1 15.51487215 4.957511484 6.4 0.2667 0 63.12512377 0 1 65.80876211 494.8204144 77.04077063 0 1 27.0135075 5.729468336 6.4 0.2667 0 64.55129473 0 1 67.972870241 0 91.30813044 0 1 17.85880524 5.226392893 6.4 0.2667 0 65.41751613 0 1 70.041847461 562.2638123 78.86400725 0 1 22.10869836 5.685390064 6.4 0.2667 0 66.40709826 0 1 71.828813881 0 93.36631786 0 1 15.77254281 5.233212944 6.4 0.2667 0 66.51044891 0 1 64.806166241 0 96.34360462 0 1 20.79545157 5.287128845 6.4 0.2667 0 65.47293978 0 1 62.339357381 433.8983122 75.82188662 0 1 22.01962412 5.525384134 6.4 0.2667 0 64.05701094 0 1 72.898343291 558.724974 77.49304283 0 1 25.68085784 5.724257421 6.4 0.2667 0 65.3582333 0 1 72.181172141 0 96.96153704 0 1 0 163.5744754 6.4 0.2667 0 65.99691251 0 1 64.60590231 393.3636817 77.71861373 0 1 0 160.2046169 6.4 0.2667 0 65.31949492 0 1 69.684894471 790.7209949 83.92914616 0 1 21.3916731 5.738135728 6.4 0.2667 0 66.70528594 0 1 72.507545461 537.2209441 83.46183562 0 1 18.86834805 5.655070373 6.4 0.2667 0 67.12946499 0 1 67.410404551 561.5868402 77.26116378 0 1 15.99982724 5.280956296 6.4 0.2667 0 65.43002655 0 1 65.564933021 0 107.0493742 0 1 34.13640378 7.423416908 6.4 0.2667 0 43.71260101 0 1 84.229042991 518.7156038 77.01038213 0 1 19.51157137 5.376062688 6.4 0.2667 0 65.10097818 0 1 70.08439511 367.3167772 77.85665586 0 1 17.88182884 5.406359212 6.4 0.2667 0 66.84097933 0 1 66.993402211 389.8865683 76.51189035 0 1 26.83762306 5.653901292 6.4 0.2667 0 65.49196022 0 1 66.69732231 0 91.45153566 0 1 18.54061724 5.371256622 6.4 0.2667 0 67.06576388 0 1 65.651872881 439.9808055 75.5119261 0 1 28.58107058 5.646124084 6.4 0.2667 0 65.72973304 0 1 66.401406251 424.5345509 83.15647272 0 1 0 167.0297762 6.4 0.2667 0 68.38788332 0 1 78.788704311 267.1943501 76.56551037 0 1 0 163.1860338 6.4 0.2667 0 65.24924857 0 1 66.0372062471Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFNi Slope P P +/- P Intercept P Slope Pb Pb +/- Pb Intercept Pb Slope Pr Pr +/- Pr Intercept Pr Slope RbD.8 fp-XRF Geochem Mode1 462.2621288 79.72501927 0 1 29.46443039 5.930460798 6.4 0.2667 0 67.13732888 0 1 67.886667541 310.9776421 75.87501049 0 1 19.17262492 5.355408862 6.4 0.2667 0 66.51657526 0 1 65.280929211 447.0946587 73.31253386 0 1 16.77112686 5.073462961 6.4 0.2667 0 64.62996894 0 1 63.310817371 548.4198589 78.02484778 0 1 20.61736246 5.423871015 6.4 0.2667 0 66.68959232 0 1 60.783385111 417.8738802 71.38519047 0 1 21.49815681 5.273517269 6.4 0.2667 0 64.76051869 0 1 65.525760411 441.1765515 72.31541113 0 1 15.63527675 5.055117682 6.4 0.2667 0 64.49761012 0 1 64.657622561 359.969706 68.99498048 0 1 0 149.324663 6.4 0.2667 0 63.36518956 0 1 65.70595281 326.4134579 73.45221414 0 1 21.21008193 5.361480124 6.4 0.2667 0 64.41293778 0 1 74.942534061 0 94.50253579 0 1 18.17934022 5.204050538 6.4 0.2667 0 65.45132355 0 1 64.37498731 578.4702114 71.63860606 0 1 0 150.5569737 6.4 0.2667 0 64.4309185 0 1 63.435407161 273.223031 74.498954 0 1 0 157.2734493 6.4 0.2667 0 67.14604251 0 1 63.412405411 325.7682559 78.68793098 0 1 19.54635902 5.377703103 6.4 0.2667 0 66.93535388 0 1 65.773000961 769.172352 81.25330097 0 1 19.18004982 5.432754713 6.4 0.2667 0 66.97493679 0 1 69.591863891 524.7979094 76.42658105 0 1 18.50783354 5.220708081 6.4 0.2667 0 65.02063908 0 1 66.361854711 0 110.0901406 0 1 36.42212259 7.541523008 6.4 0.2667 0 44.95252435 0 1 87.900303561 526.4616737 77.02758995 0 1 0 154.752221 6.4 0.2667 0 65.67732419 0 1 66.548891191 563.8239261 72.76913077 0 1 0 155.0921305 6.4 0.2667 0 64.66722701 0 1 61.023736391 413.0958936 76.35825013 0 1 0 164.8305416 6.4 0.2667 0 65.97408872 0 1 64.000060571 793.7000137 80.79712234 0 1 19.36099058 5.458922673 6.4 0.2667 0 65.8117585 0 1 77.553088111 568.3758448 79.81797918 0 1 23.6785403 5.601222585 6.4 0.2667 0 66.29426711 0 1 72.591939951 0 94.30746681 0 1 16.26381893 4.964109306 6.4 0.2667 0 66.26491039 0 1 59.679346651 259.6556407 72.58376213 0 1 22.89243607 5.224790383 6.4 0.2667 0 64.56395421 0 1 53.218146421 2118.583966 108.9940104 0 1 30.97235368 6.789932885 6.4 0.2667 0 77.37223964 0 1 68.970507461 0 94.88130682 0 1 26.51354216 5.978555043 6.4 0.2667 0 68.83822182 0 1 67.247577591 0 103.0176732 0 1 0 171.9752424 6.4 0.2667 0 68.52674848 0 1 70.739008831 9579.03168 206.1323019 0 1 0 231.7874831 6.4 0.2667 0 95.80105167 0 1 22.065856161 9113.131243 184.2008307 0 1 0 237.6394076 6.4 0.2667 0 85.64936416 0 1 36.314471961 381.4801971 76.87582242 0 1 17.19437319 5.207948106 6.4 0.2667 0 66.91376328 0 1 70.759332681 315.7264298 74.7528704 0 1 0 162.5734138 6.4 0.2667 0 64.97331121 0 1 61.420703191 542.39695 76.37521838 0 1 19.09096884 5.247263093 6.4 0.2667 0 64.25109379 0 1 61.891188791 0 104.3319956 0 1 0 160.8675606 6.4 0.2667 0 67.97008614 0 1 75.462021531 3430.339641 133.2765066 0 1 0 221.8807875 6.4 0.2667 0 80.63781851 0 1 93.972016121 6431.761196 146.0203799 0 1 0 198.1504441 6.4 0.2667 0 77.7053549 0 1 49.558789791 8140.003915 174.6254284 0 1 0 198.9397704 6.4 0.2667 0 83.41955882 0 1 31.157895941 6274.974441 145.8749508 0 1 23.8468792 7.682599254 6.4 0.2667 0 75.29516953 0 1 40.870432661 0 92.58513108 0 1 20.44330602 5.225393523 6.4 0.2667 0 65.80120635 0 1 64.274373631 0 111.0871429 0 1 33.03108325 7.361426058 6.4 0.2667 0 43.93398981 0 1 92.69334604472Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFNi Slope P P +/- P Intercept P Slope Pb Pb +/- Pb Intercept Pb Slope Pr Pr +/- Pr Intercept Pr Slope RbD.8 fp-XRF Geochem Mode1 0 90.60163846 0 1 0 170.5909583 6.4 0.2667 0 67.05406533 0 1 68.632749241 0 93.91008361 0 1 17.84813664 5.377597608 6.4 0.2667 0 68.21972628 0 1 60.260750461 0 90.81235889 0 1 0 155.5326229 6.4 0.2667 0 66.41554463 0 1 66.037370061 0 95.21301302 0 1 19.03825186 5.261135771 6.4 0.2667 0 66.47824208 0 1 70.566807531 512.4043514 70.47161032 0 1 21.22048796 5.095896995 6.4 0.2667 0 63.56247612 0 1 61.457878791 0 93.4752618 0 1 17.0604549 5.009354185 6.4 0.2667 0 65.0753401 0 1 59.105119251 0 90.21486561 0 1 29.26810604 5.663057781 6.4 0.2667 0 66.39965298 0 1 61.057677341 5122.254216 156.2542202 0 1 0 244.316041 6.4 0.2667 0 94.68077273 0 1 36.130518261 5499.818417 166.7357242 0 1 0 244.0970468 6.4 0.2667 0 98.6816143 0 1 20.165446231 0 89.84531041 0 1 17.81538415 5.358492993 6.4 0.2667 0 68.7534586 0 1 73.087614761 0 94.32151015 0 1 0 163.3579431 6.4 0.2667 0 65.87377922 0 1 54.550637031 7391.866227 170.829651 0 1 0 212.6340451 6.4 0.2667 0 87.28160906 0 1 22.07772811 1016.826247 84.07889003 0 1 17.27851508 5.52222814 6.4 0.2667 0 68.17633432 0 1 75.705188341 540.3059503 71.51852165 0 1 0 148.7756885 6.4 0.2667 0 64.40649627 0 1 56.567634051 1767.64194 76.89579918 0 1 21.3403619 5.564199869 6.4 0.2667 0 61.53834032 0 1 70.088612641 435.804214 74.5528986 0 1 29.06372167 5.645169675 6.4 0.2667 0 65.1660856 0 1 67.29771 433.2999936 79.37944544 0 1 21.51346887 5.686995806 6.4 0.2667 0 67.0761716 0 1 76.470699711 368.7200494 74.50991728 0 1 0 163.4479207 6.4 0.2667 0 65.6024258 0 1 63.880109491 549.1417129 75.45850211 0 1 15.76482221 5.140029178 6.4 0.2667 0 65.255852 0 1 71.215916241 586.321795 74.72931719 0 1 0 153.6060345 6.4 0.2667 0 64.32675353 0 1 71.097273671 470.3472521 73.61109561 0 1 0 161.4717011 6.4 0.2667 0 66.00166612 0 1 64.864174831 0 101.4547801 0 1 39.05592103 7.837277267 6.4 0.2667 0 44.29665106 0 1 89.172461331 497.4837646 72.75541972 0 1 20.87610659 5.171575463 6.4 0.2667 0 64.51002909 0 1 64.513750981 11357.07273 224.8375813 0 1 0 229.9110428 6.4 0.2667 0 94.74568216 0 1 21.399028541 286.9398938 73.0241331 0 1 26.28920743 5.747523447 6.4 0.2667 0 64.70685078 0 1 72.294368451 379.8585139 74.67843869 0 1 18.48980457 5.406061973 6.4 0.2667 0 66.61437504 0 1 68.866119251 278.537057 74.88794798 0 1 20.82322678 5.44454842 6.4 0.2667 0 66.62784558 0 1 74.497427161 401.3227931 72.51947316 0 1 19.27600365 5.032530012 6.4 0.2667 0 64.74789277 0 1 60.189706681 0 89.52949108 0 1 20.94520542 5.090683423 6.4 0.2667 0 65.04127081 0 1 55.986137781 0 90.49692767 0 1 17.07440165 5.015491766 6.4 0.2667 0 66.04368625 0 1 57.80350885473Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFRb +/- Rb Intercept Rb Slope S S +/- S Intercept S Slope Sb Sb +/- Sb Intercept Sb Slope Se Se +/- Se Intercept4.722121242 8.5 0.6356 0 71.1224427 0 1 0 177.6626542 0 1 0 26.82631361 02.836221614 8.5 0.6356 0 47.9629031 0 1 0 236.252047 0 1 0 28.83067336 03.124750821 8.5 0.6356 0 53.45756592 0 1 0 242.4741974 0 1 0 31.79877222 03.254612792 8.5 0.6356 0 70.41103904 0 1 0 200.630492 0 1 0 25.46229321 03.443255629 8.5 0.6356 23766.51863 266.9788958 0 1 0 313.5235509 0 1 0 37.68447397 03.308928078 8.5 0.6356 0 62.83906412 0 1 0 257.7954143 0 1 0 32.306729 03.201147232 8.5 0.6356 0 51.83164393 0 1 0 249.158125 0 1 0 32.33466083 03.025818327 8.5 0.6356 0 49.44838111 0 1 0 233.2797631 0 1 0 30.4967823 03.11178967 8.5 0.6356 0 46.49351071 0 1 0 233.4405833 0 1 0 30.32010995 03.090589008 8.5 0.6356 0 48.48050946 0 1 0 243.1438259 0 1 0 30.89979451 03.279339802 8.5 0.6356 0 50.53641149 0 1 0 249.2931464 0 1 0 31.61264456 03.209462333 8.5 0.6356 0 53.1190977 0 1 0 238.4264241 0 1 0 31.74890413 03.062466164 8.5 0.6356 0 47.68014697 0 1 0 231.8556686 0 1 0 30.39929737 03.287129257 8.5 0.6356 0 54.06506553 0 1 0 253.1353302 0 1 0 31.62429647 03.177672966 8.5 0.6356 0 50.22199735 0 1 0 243.1653539 0 1 0 29.51222099 03.14015998 8.5 0.6356 0 49.57326811 0 1 0 239.8822698 0 1 0 29.47000749 03.169961625 8.5 0.6356 0 47.36982683 0 1 0 239.3265007 0 1 0 29.85949227 03.098679858 8.5 0.6356 0 51.96500642 0 1 0 238.7854772 0 1 0 30.81973582 03.119299635 8.5 0.6356 0 51.06464895 0 1 0 241.4476393 0 1 0 31.42801666 03.022705399 8.5 0.6356 0 55.06322759 0 1 0 240.5424059 0 1 0 31.3110726 03.342717411 8.5 0.6356 1078.668951 36.05791594 0 1 0 207.3941096 0 1 0 26.42818338 04.282943445 8.5 0.6356 0 72.96682991 0 1 0 174.2199261 0 1 0 23.82992817 03.50805218 8.5 0.6356 1135.126828 36.91629682 0 1 0 207.7142071 0 1 0 25.09813819 04.244321106 8.5 0.6356 0 69.4161083 0 1 0 174.8037235 0 1 0 25.47201442 03.121567687 8.5 0.6356 0 48.90899084 0 1 0 239.5825718 0 1 0 31.75678266 03.388981933 8.5 0.6356 0 50.72027724 0 1 0 249.2907784 0 1 0 27.93466782 03.270042497 8.5 0.6356 0 52.89912307 0 1 0 243.0580143 0 1 0 32.45197597 03.282927743 8.5 0.6356 0 55.13782242 0 1 0 246.4244923 0 1 0 30.27022858 03.176727465 8.5 0.6356 0 54.92418261 0 1 0 246.6064017 0 1 0 28.78019108 03.239984497 8.5 0.6356 0 50.89000275 0 1 0 244.3287009 0 1 0 32.02409045 03.263834552 8.5 0.6356 0 54.98909822 0 1 0 246.0909316 0 1 0 33.27354159 02.941926741 8.5 0.6356 0 50.53176448 0 1 0 242.5445829 0 1 0 30.12129192 03.587898014 8.5 0.6356 0 54.3279467 0 1 0 248.739062 0 1 0 31.31447549 04.005998578 8.5 0.6356 15236.79574 164.915786 0 1 0 358.1123872 0 1 0 40.97309549 02.985336764 8.5 0.6356 0 57.75086546 0 1 0 255.7783726 0 1 0 30.77598255 03.080959832 8.5 0.6356 33855.55392 429.9478257 0 1 0 435.6961736 0 1 0 53.62535025 0D.8 fp-XRF Geochem Mode474Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFRb +/- Rb Intercept Rb Slope S S +/- S Intercept S Slope Sb Sb +/- Sb Intercept Sb Slope Se Se +/- Se InterceptD.8 fp-XRF Geochem Mode2.7607571 8.5 0.6356 24418.17868 322.0511047 0 1 0 418.1697913 0 1 0 45.95625216 04.23678519 8.5 0.6356 17254.60068 198.9796949 0 1 0 355.9402839 0 1 0 44.37241493 03.570692857 8.5 0.6356 0 56.59239434 0 1 0 275.7515725 0 1 0 35.11939281 03.62558472 8.5 0.6356 0 56.30082119 0 1 0 264.2402536 0 1 0 32.97056507 03.431857342 8.5 0.6356 0 65.79740692 0 1 0 263.3449923 0 1 0 32.35250983 03.206283917 8.5 0.6356 0 51.69693322 0 1 0 246.758127 0 1 0 32.29646134 03.558570779 8.5 0.6356 0 52.58156427 0 1 0 264.7464034 0 1 0 35.310021 03.099663023 8.5 0.6356 0 51.09239055 0 1 0 237.8826524 0 1 0 30.47417271 04.416496005 8.5 0.6356 0 72.81288083 0 1 0 178.2498979 0 1 0 24.21119051 03.139444405 8.5 0.6356 0 51.05729302 0 1 0 246.1022504 0 1 0 31.82611166 03.104504152 8.5 0.6356 0 51.98897159 0 1 0 239.7926198 0 1 0 29.79694045 03.436760655 8.5 0.6356 0 55.23770272 0 1 0 246.6104468 0 1 0 29.44686474 03.33591636 8.5 0.6356 0 55.73327662 0 1 0 247.5270174 0 1 0 31.46391194 03.462054873 8.5 0.6356 0 57.42414179 0 1 0 255.2802295 0 1 0 32.15896996 03.266537748 8.5 0.6356 0 53.40573139 0 1 0 249.4929138 0 1 0 29.95634931 03.324339245 8.5 0.6356 0 52.76802392 0 1 0 249.7397099 0 1 0 32.60171176 03.314672759 8.5 0.6356 0 49.91988623 0 1 0 247.9242679 0 1 0 31.54885532 03.173690965 8.5 0.6356 0 49.61259082 0 1 0 237.3724298 0 1 0 30.95444453 03.416799844 8.5 0.6356 0 56.2981656 0 1 0 251.5310282 0 1 0 31.19098668 03.358636906 8.5 0.6356 0 52.10233902 0 1 0 249.4420878 0 1 0 31.66818038 03.572947846 8.5 0.6356 0 55.36511477 0 1 0 258.5427411 0 1 0 32.2032599 03.331679842 8.5 0.6356 0 54.47332994 0 1 0 258.6124341 0 1 0 30.33664584 03.180963496 8.5 0.6356 0 54.55655606 0 1 0 252.4828512 0 1 0 29.83014535 03.49471829 8.5 0.6356 0 50.70202815 0 1 0 247.6058339 0 1 0 31.28057614 03.517252023 8.5 0.6356 0 54.81439672 0 1 0 251.2420136 0 1 0 30.73737993 03.324119257 8.5 0.6356 0 57.29012762 0 1 0 254.6474849 0 1 0 33.46315657 03.442828083 8.5 0.6356 0 52.97453923 0 1 0 256.3171293 0 1 0 32.02978027 03.636074819 8.5 0.6356 0 65.72859921 0 1 0 265.1791524 0 1 0 33.57203035 03.586439728 8.5 0.6356 0 56.41228964 0 1 0 267.2962836 0 1 0 33.0395969 03.365918119 8.5 0.6356 0 55.35590062 0 1 0 253.3800497 0 1 0 33.70052868 04.399040109 8.5 0.6356 0 72.65704254 0 1 0 176.295909 0 1 0 24.53483268 03.461012695 8.5 0.6356 0 54.29757508 0 1 0 252.0873459 0 1 0 31.74290864 03.430883863 8.5 0.6356 0 56.96512095 0 1 0 264.410499 0 1 0 31.44269731 03.336808747 8.5 0.6356 0 51.00332368 0 1 0 252.6977004 0 1 0 32.10823656 03.383647093 8.5 0.6356 0 50.68327532 0 1 0 262.914302 0 1 0 34.46536138 03.319463149 8.5 0.6356 0 51.50236529 0 1 0 251.8567854 0 1 0 33.82792933 03.733966016 8.5 0.6356 0 50.06270883 0 1 0 271.0676539 0 1 0 35.75800289 03.314715096 8.5 0.6356 0 48.83996619 0 1 0 250.5642793 0 1 0 30.7159462 0475Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFRb +/- Rb Intercept Rb Slope S S +/- S Intercept S Slope Sb Sb +/- Sb Intercept Sb Slope Se Se +/- Se InterceptD.8 fp-XRF Geochem Mode3.464180844 8.5 0.6356 0 56.44677766 0 1 0 264.9073832 0 1 0 32.29395869 03.372454547 8.5 0.6356 0 52.40825045 0 1 0 253.6408884 0 1 0 32.98843228 03.163882165 8.5 0.6356 0 51.2981243 0 1 0 244.7725405 0 1 0 33.48577636 03.269699141 8.5 0.6356 0 52.79865934 0 1 0 258.4532067 0 1 0 31.73973519 03.254583201 8.5 0.6356 0 55.62927481 0 1 0 244.5191146 0 1 0 29.46607671 03.226062174 8.5 0.6356 0 50.84514663 0 1 0 244.2081646 0 1 0 31.98083864 03.222591821 8.5 0.6356 0 56.42702171 0 1 0 237.4941133 0 1 0 30.89059039 03.44773873 8.5 0.6356 0 50.48370627 0 1 0 247.4377367 0 1 0 29.95267469 03.257770448 8.5 0.6356 0 55.11700473 0 1 0 251.382749 0 1 0 32.16535997 03.125451799 8.5 0.6356 0 53.00332679 0 1 0 244.4064302 0 1 0 32.05220699 03.207780743 8.5 0.6356 0 63.86777142 0 1 0 259.5783675 0 1 0 31.80924027 03.403372819 8.5 0.6356 539.4459866 41.99210909 0 1 0 262.9578292 0 1 0 31.63581345 03.458467177 8.5 0.6356 0 62.29510699 0 1 0 260.7364621 0 1 0 30.72557678 03.289428961 8.5 0.6356 0 51.70810328 0 1 0 251.4900226 0 1 0 32.83552924 04.467795878 8.5 0.6356 0 74.42214916 0 1 0 177.0435305 0 1 0 23.54005969 03.296452013 8.5 0.6356 0 50.31693023 0 1 0 251.137843 0 1 0 32.52652768 03.145893472 8.5 0.6356 0 56.20563712 0 1 0 246.2289911 0 1 0 29.89393076 03.360832131 8.5 0.6356 0 52.38938058 0 1 0 250.6954025 0 1 0 31.13555993 03.678816974 8.5 0.6356 0 55.22386297 0 1 0 256.3242594 0 1 0 31.95993011 03.497241645 8.5 0.6356 0 55.028588 0 1 0 257.3204606 0 1 0 34.48170999 03.053627822 8.5 0.6356 0 55.39936774 0 1 0 255.9126052 0 1 0 33.56250857 02.982650551 8.5 0.6356 0 55.09420728 0 1 0 251.1224152 0 1 0 29.60703806 03.936528794 8.5 0.6356 6599.438797 87.62066791 0 1 0 324.8956329 0 1 0 39.93167172 03.609319764 8.5 0.6356 0 64.3656094 0 1 0 277.297933 0 1 0 34.14878992 03.603212242 8.5 0.6356 0 68.67263342 0 1 0 273.6382051 0 1 0 33.10665918 03.223833855 8.5 0.6356 30095.84737 361.646141 0 1 0 431.7611281 0 1 0 51.72570172 03.565151543 8.5 0.6356 30509.49373 361.8601832 0 1 0 385.0203982 0 1 0 47.00453032 03.3738052 8.5 0.6356 0 52.62553976 0 1 0 259.5891279 0 1 0 33.48417186 03.197362297 8.5 0.6356 0 50.89933953 0 1 0 252.9347785 0 1 0 31.23643263 03.22664933 8.5 0.6356 0 53.03281683 0 1 12.90748904 4.167648932 0 1 0 30.59934835 03.62915488 8.5 0.6356 0 64.77322447 0 1 0 265.9212263 0 1 0 32.90852635 05.316743582 8.5 0.6356 7449.088082 102.5585874 0 1 0 353.4922798 0 1 0 47.3275742 04.028407974 8.5 0.6356 19415.14928 216.5962077 0 1 0 348.0677888 0 1 0 45.20316794 03.558249347 8.5 0.6356 33193.55641 405.1549202 0 1 0 374.412523 0 1 0 49.97843299 03.957648711 8.5 0.6356 18359.72264 205.0007345 0 1 0 336.6541027 0 1 0 33.65711313 03.246489655 8.5 0.6356 0 61.54712114 0 1 0 255.6565144 0 1 0 30.13428035 04.539361818 8.5 0.6356 0 74.32022933 0 1 0 176.3491859 0 1 0 25.21516261 0476Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFRb +/- Rb Intercept Rb Slope S S +/- S Intercept S Slope Sb Sb +/- Sb Intercept Sb Slope Se Se +/- Se InterceptD.8 fp-XRF Geochem Mode3.391026896 8.5 0.6356 0 60.09722678 0 1 0 256.5017774 0 1 0 34.7475594 03.276728479 8.5 0.6356 0 63.43151998 0 1 0 266.7017833 0 1 0 33.41664472 03.269906843 8.5 0.6356 0 51.05154904 0 1 0 256.6538095 0 1 0 33.31856275 03.455780089 8.5 0.6356 0 52.6558828 0 1 0 257.6276244 0 1 0 33.18365364 03.029991784 8.5 0.6356 0 51.01620566 0 1 0 237.3615132 0 1 0 28.51284142 03.054906209 8.5 0.6356 0 49.5673555 0 1 0 250.1551595 0 1 0 31.64185163 03.212646247 8.5 0.6356 0 57.46407965 0 1 0 256.7488816 0 1 0 33.0819109 03.743350239 8.5 0.6356 45976.15412 508.2056055 0 1 0 421.2466159 0 1 0 50.0873164 03.312515891 8.5 0.6356 57823.99325 666.0085412 0 1 0 450.0181171 0 1 0 54.40794191 03.539148853 8.5 0.6356 0 58.95506542 0 1 0 267.337424 0 1 0 33.66665915 02.992578964 8.5 0.6356 993.6743384 41.73571446 0 1 0 253.8622501 0 1 0 32.82950145 03.215883137 8.5 0.6356 36209.54963 382.3170889 0 1 0 393.4598118 0 1 0 48.53800698 03.681715827 8.5 0.6356 2175.907723 50.42472743 0 1 0 266.8092298 0 1 0 31.89186667 02.9579687 8.5 0.6356 0 53.62146905 0 1 0 243.4832349 0 1 0 30.87390209 03.470371232 8.5 0.6356 0 68.20188766 0 1 0 230.3420847 0 1 0 31.81247321 03.308384651 8.5 0.6356 0 49.3594298 0 1 0 248.2586971 0 1 0 31.74217862 03.677043605 8.5 0.6356 0 51.11221018 0 1 0 261.0507392 0 1 0 32.20165272 03.289943277 8.5 0.6356 0 53.91448838 0 1 0 252.8257833 0 1 0 31.97896689 03.384863736 8.5 0.6356 0 54.7471524 0 1 0 249.6761919 0 1 0 33.45705298 03.337898979 8.5 0.6356 0 51.59029763 0 1 0 244.5110354 0 1 0 28.157311 03.260884093 8.5 0.6356 0 58.68658884 0 1 0 253.6497183 0 1 0 31.70714146 04.544855624 8.5 0.6356 0 74.08984907 0 1 0 179.8470615 0 1 0 25.80593263 03.175472135 8.5 0.6356 0 57.56372069 0 1 0 245.4244902 0 1 0 31.99633599 03.316846298 8.5 0.6356 35854.90228 421.5435431 0 1 0 429.8348915 0 1 0 53.09749598 03.51588143 8.5 0.6356 0 59.16478393 0 1 0 248.5461404 0 1 0 30.27889268 03.435057586 8.5 0.6356 0 56.35385245 0 1 0 256.518576 0 1 0 30.51135689 03.489161722 8.5 0.6356 0 54.17853767 0 1 0 254.2789993 0 1 0 33.02245604 03.022411564 8.5 0.6356 0 51.19517721 0 1 0 245.3473997 0 1 0 32.56501836 02.94720992 8.5 0.6356 0 55.57417007 0 1 0 247.3446521 0 1 0 32.70690971 03.038067061 8.5 0.6356 0 63.52757141 0 1 0 256.6009309 0 1 0 32.58565185 0477Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSe Slope Si Si +/- Si Intercept Si Slope Sn Sn +/- Sn Intercept Sn Slope Sr Sr +/- Sr Intercept Sr Slope Te Te +/-1 290085.5414 1676.696217 121552 0.5762 0 144.5596657 0 1 60.12445157 3.187655485 25.5 0.788 0 7.2052855031 361037.3801 1834.726002 121552 0.5762 0 193.231217 0 1 285.6135004 5.108709023 25.5 0.788 0 9.3143830581 350636.946 1882.208046 121552 0.5762 0 198.5528204 0 1 303.429158 5.480663745 25.5 0.788 0 9.5248650091 274159.3623 1717.500389 121552 0.5762 0 163.8270284 0 1 261.0890606 5.390166326 25.5 0.788 0 8.0056942261 159720.5808 1722.842864 121552 0.5762 0 256.211195 0 1 107.5116551 4.406524974 25.5 0.788 0 11.63902411 364372.0344 1969.414472 121552 0.5762 0 209.5320759 0 1 335.8989892 5.958473889 25.5 0.788 0 10.21523131 359968.6443 1909.417048 121552 0.5762 0 201.6571676 0 1 305.6857258 5.518769251 25.5 0.788 0 9.6623206011 347468.8186 1818.160693 121552 0.5762 0 189.9746771 0 1 289.4012199 5.202103451 25.5 0.788 0 9.1303177831 363227.9634 1814.625089 121552 0.5762 0 190.8403857 0 1 289.6797517 5.22490195 25.5 0.788 0 9.2777440971 362294.7856 1858.967012 121552 0.5762 0 195.3623954 0 1 305.1196391 5.432867456 25.5 0.788 0 9.637668081 359595.8299 1887.158467 121552 0.5762 0 201.6498019 0 1 301.0016219 5.481563177 25.5 0.788 0 9.5494590821 344234.7041 1857.653954 121552 0.5762 0 195.8460927 0 1 287.2436753 5.313955795 25.5 0.788 0 9.3006132691 361683.564 1801.612354 121552 0.5762 0 186.9635128 0 1 304.4094769 5.323873091 25.5 0.788 0 9.2314089151 352586.7391 1920.515625 121552 0.5762 0 203.0264438 0 1 311.4573682 5.681615015 25.5 0.788 0 9.8054197491 357540.8468 1847.931979 121552 0.5762 0 197.212133 0 1 315.172337 5.558587578 25.5 0.788 0 9.4753403511 354820.5902 1842.307675 121552 0.5762 0 195.2237413 0 1 303.3698822 5.405055053 25.5 0.788 0 9.2731079531 363809.0022 1831.07365 121552 0.5762 0 193.5907671 0 1 303.3954676 5.425415108 25.5 0.788 0 9.3015677171 349301.3724 1827.32667 121552 0.5762 0 190.74943 0 1 290.0389745 5.216460417 25.5 0.788 0 9.3408372711 351350.9419 1843.831431 121552 0.5762 0 193.7720077 0 1 298.6630725 5.391398594 25.5 0.788 0 9.4860453411 344930.1751 1849.000582 121552 0.5762 0 196.5798344 0 1 300.2057199 5.457445359 25.5 0.788 0 9.5112327291 252344.7391 1731.092499 121552 0.5762 0 168.4371898 0 1 257.0257509 5.688381447 25.5 0.788 0 8.0778645531 273582.1308 1637.508957 121552 0.5762 0 142.166209 0 1 58.80756807 3.057850009 25.5 0.788 0 7.1952180971 255326.6762 1755.955099 121552 0.5762 0 168.6343519 0 1 257.3442846 5.754599639 25.5 0.788 0 8.019017531 280532.7606 1657.037073 121552 0.5762 0 142.8520792 0 1 58.99507497 3.074214578 25.5 0.788 0 7.3062788471 372373.6658 1858.85533 121552 0.5762 0 193.9572959 0 1 312.9882746 5.425415163 25.5 0.788 0 9.3168334411 372750.8472 1915.465044 121552 0.5762 0 203.4621107 0 1 316.6807714 5.717941549 25.5 0.788 0 9.6068179671 351436.3135 1872.795386 121552 0.5762 0 196.049121 0 1 315.2201017 5.651942085 25.5 0.788 0 9.6447963751 355657.5248 1900.930708 121552 0.5762 0 198.6704156 0 1 318.0172654 5.715893119 25.5 0.788 0 9.6125301561 353308.5478 1889.999432 121552 0.5762 0 197.8428665 0 1 303.0585683 5.543870455 25.5 0.788 0 9.4834139241 366619.7031 1898.176352 121552 0.5762 0 201.4738862 0 1 302.9173717 5.483857736 25.5 0.788 0 9.6719925291 353567.135 1911.07182 121552 0.5762 0 201.4074166 0 1 305.8627537 5.629964264 25.5 0.788 0 9.7438928261 371019.7022 1895.530302 121552 0.5762 0 199.7683743 0 1 314.4582269 5.530499431 25.5 0.788 0 9.759297911 355054.0278 1935.689441 121552 0.5762 0 201.4216893 0 1 299.7392348 5.69474354 25.5 0.788 0 9.70868181 265029.6601 2322.317083 121552 0.5762 0 285.4523759 0 1 304.1931194 7.246563162 25.5 0.788 0 13.030019471 367390.4418 1924.179026 121552 0.5762 0 208.2115803 0 1 317.2921761 5.58609863 25.5 0.788 0 9.8629431151 107871.3981 1412.667083 121552 0.5762 0 357.0414213 0 1 57.1239987 3.753087361 25.5 0.788 0 15.81869453D.8 fp-XRF Geochem Mode478Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSe Slope Si Si +/- Si Intercept Si Slope Sn Sn +/- Sn Intercept Sn Slope Sr Sr +/- Sr Intercept Sr Slope Te Te +/-D.8 fp-XRF Geochem Mode1 96029.02498 1290.266234 121552 0.5762 0 340.7156715 0 1 51.56114227 3.509307428 25.5 0.788 0 15.067870281 216854.9493 2198.719172 121552 0.5762 0 288.7475062 0 1 177.8703207 5.808048772 25.5 0.788 0 13.016156381 398291.0641 2072.650859 121552 0.5762 0 224.8062137 0 1 360.7401628 6.414351209 25.5 0.788 0 10.715331551 373924.0346 1998.340065 121552 0.5762 0 214.6995129 0 1 339.0058102 6.14023379 25.5 0.788 0 10.224234791 369537.2227 2015.798924 121552 0.5762 0 215.4482668 0 1 327.9108846 6.03175411 25.5 0.788 0 10.240751631 362113.5884 1879.541713 121552 0.5762 0 198.8916919 0 1 323.9684991 5.732367346 25.5 0.788 0 9.749522231 392104.8316 2021.217749 121552 0.5762 0 214.6601666 0 1 338.0132933 6.197569877 25.5 0.788 0 10.297843561 352903.4244 1837.718655 121552 0.5762 0 194.156045 0 1 284.4701565 5.232833438 25.5 0.788 0 9.3132215131 280694.3122 1655.241037 121552 0.5762 0 146.2595159 0 1 60.174967 3.117227914 25.5 0.788 0 7.2895461 359754.9549 1873.646405 121552 0.5762 0 196.0999167 0 1 310.7162446 5.540275071 25.5 0.788 0 9.288686131 350439.2473 1836.372105 121552 0.5762 0 195.3112319 0 1 299.4019973 5.358336192 25.5 0.788 0 9.4065183971 349385.8726 1876.480691 121552 0.5762 0 199.2119143 0 1 288.9940993 5.437541363 25.5 0.788 0 9.7229214791 353455.5231 1924.403328 121552 0.5762 0 200.2724041 0 1 312.3703426 5.720744181 25.5 0.788 0 9.548135881 361476.4602 1922.824622 121552 0.5762 0 206.7479705 0 1 319.3970338 5.811588795 25.5 0.788 0 9.8846690231 358015.231 1903.809328 121552 0.5762 0 201.0442805 0 1 308.6274823 5.632820587 25.5 0.788 0 9.6197634651 362591.2868 1902.375141 121552 0.5762 0 198.5542231 0 1 312.6428039 5.682738243 25.5 0.788 0 9.612684631 369989.5349 1894.179234 121552 0.5762 0 199.7454092 0 1 303.8718483 5.575797236 25.5 0.788 0 9.7027871261 356640.6241 1828.279437 121552 0.5762 0 191.8839049 0 1 286.5813833 5.207312586 25.5 0.788 0 9.3509336831 356671.6268 1944.709276 121552 0.5762 0 206.4134306 0 1 312.9831288 5.852984187 25.5 0.788 0 9.8833852531 364092.5775 1905.405057 121552 0.5762 0 201.3220561 0 1 308.0152195 5.628935997 25.5 0.788 0 9.8783570131 359968.2685 1966.692051 121552 0.5762 0 209.9384652 0 1 327.1620796 6.065828344 25.5 0.788 0 9.9081595981 367256.4403 1977.467486 121552 0.5762 0 210.6640817 0 1 311.2469366 5.803759832 25.5 0.788 0 9.9371043581 356343.1711 1926.760737 121552 0.5762 0 202.7808734 0 1 294.8118053 5.473381109 25.5 0.788 0 9.7979437341 367468.4966 1901.888934 121552 0.5762 0 199.0578762 0 1 306.8422711 5.692711071 25.5 0.788 0 9.7290270781 361101.1814 1921.286508 121552 0.5762 0 203.2512451 0 1 317.0991236 5.910723809 25.5 0.788 0 9.7169795281 350706.6005 1937.106631 121552 0.5762 0 205.8684882 0 1 311.5628136 5.758941732 25.5 0.788 0 9.9546781351 374366.5381 1943.949447 121552 0.5762 0 204.2298748 0 1 318.1653502 5.898168137 25.5 0.788 0 9.9476586621 363367.6774 2004.260227 121552 0.5762 0 213.053759 0 1 328.3256118 6.153848825 25.5 0.788 0 10.189160241 379077.3787 2015.589883 121552 0.5762 0 216.3179684 0 1 351.0757968 6.39410327 25.5 0.788 0 10.489409041 359790.8095 1921.372258 121552 0.5762 0 204.5392524 0 1 311.9848251 5.765572406 25.5 0.788 0 9.865345151 278294.3725 1637.950316 121552 0.5762 0 144.7509837 0 1 56.05735177 3.025946649 25.5 0.788 0 7.1715259951 361397.7532 1922.291068 121552 0.5762 0 205.8443273 0 1 308.7179628 5.719615267 25.5 0.788 0 9.8652831771 361747.2587 2003.314545 121552 0.5762 0 214.2451061 0 1 327.6336748 6.071735914 25.5 0.788 0 10.136999441 369524.9378 1930.228795 121552 0.5762 0 204.0174389 0 1 323.6085939 5.851814076 25.5 0.788 0 9.8028017271 382443.3865 1994.51228 121552 0.5762 0 212.0921366 0 1 332.9679146 6.031539576 25.5 0.788 0 10.262542371 362419.8185 1930.637965 121552 0.5762 0 204.2617647 0 1 321.4402883 5.802583248 25.5 0.788 0 10.127860811 393818.2014 2019.997767 121552 0.5762 0 218.6346987 0 1 362.17811 6.42757601 25.5 0.788 0 10.47737751 384158.6866 1931.546605 121552 0.5762 0 204.4746359 0 1 335.2833986 5.907267651 25.5 0.788 0 9.862149514479Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSe Slope Si Si +/- Si Intercept Si Slope Sn Sn +/- Sn Intercept Sn Slope Sr Sr +/- Sr Intercept Sr Slope Te Te +/-D.8 fp-XRF Geochem Mode1 372706.649 2012.766357 121552 0.5762 0 211.346904 0 1 335.3012034 6.15050439 25.5 0.788 0 10.313982861 365681.6606 1954.490656 121552 0.5762 0 206.7538819 0 1 311.9018957 5.750475509 25.5 0.788 0 10.013198591 359482.9015 1869.992491 121552 0.5762 0 196.8740192 0 1 307.7859532 5.544558245 25.5 0.788 0 9.4939797551 369293.974 1950.221279 121552 0.5762 0 211.231185 0 1 327.0223109 5.898347064 25.5 0.788 0 9.7909559791 342078.8184 1845.601678 121552 0.5762 0 198.2648623 0 1 287.1686346 5.38095047 25.5 0.788 0 9.5504267891 353323.3704 1846.853048 121552 0.5762 0 196.1268811 0 1 297.4847892 5.44428241 25.5 0.788 0 9.4701084181 335598.5325 1811.147197 121552 0.5762 0 195.4990057 0 1 276.8893982 5.236547043 25.5 0.788 0 9.4973942891 364158.941 1867.546964 121552 0.5762 0 198.7024375 0 1 313.678006 5.675807833 25.5 0.788 0 9.5125272941 353919.9535 1902.997688 121552 0.5762 0 204.0023268 0 1 312.112092 5.65487867 25.5 0.788 0 9.6502185531 348824.5457 1851.889257 121552 0.5762 0 197.206707 0 1 287.5116403 5.250469067 25.5 0.788 0 9.4888778591 364159.5046 1962.260583 121552 0.5762 0 209.5699358 0 1 316.1167963 5.663010032 25.5 0.788 0 9.8722027091 373101.4403 1988.177353 121552 0.5762 0 217.0408569 0 1 327.00867 5.916903793 25.5 0.788 0 10.183793551 370398.1175 1957.405009 121552 0.5762 0 210.9337546 0 1 317.7825822 5.85965755 25.5 0.788 0 9.9258399991 366818.1669 1922.304928 121552 0.5762 0 202.8208139 0 1 312.1845817 5.698283353 25.5 0.788 0 9.7906976641 277512.784 1644.238216 121552 0.5762 0 143.582656 0 1 55.5772699 3.011002458 25.5 0.788 0 7.2460439331 371455.0259 1921.023183 121552 0.5762 0 205.9029259 0 1 316.9646576 5.737920504 25.5 0.788 0 9.8013297891 346553.1197 1862.099531 121552 0.5762 0 197.3775146 0 1 306.6482683 5.517983664 25.5 0.788 0 9.4800287081 367477.1787 1927.205482 121552 0.5762 0 204.7879259 0 1 329.5959524 5.935240836 25.5 0.788 0 9.9698537081 366314.2561 1958.835344 121552 0.5762 0 208.0428453 0 1 322.7142844 5.971187849 25.5 0.788 0 9.7952277891 378189.7792 1944.793708 121552 0.5762 0 210.1452235 0 1 316.6792114 5.836920957 25.5 0.788 0 9.8243612861 371999.3315 1942.368409 121552 0.5762 0 206.5310513 0 1 305.7684683 5.465066527 25.5 0.788 0 9.9230636511 366060.8817 1911.75709 121552 0.5762 0 202.254692 0 1 308.0730809 5.4601658 25.5 0.788 0 9.583336451 330285.6594 2356.669984 121552 0.5762 0 261.433467 0 1 356.5001077 7.202980934 25.5 0.788 0 12.108269811 388280.4986 2072.524309 121552 0.5762 0 221.127175 0 1 348.0285572 6.38400048 25.5 0.788 0 10.521991331 373508.0835 2040.73491 121552 0.5762 0 220.2480743 0 1 316.0606194 5.967718931 25.5 0.788 0 10.417382621 153824.6696 1799.507485 121552 0.5762 0 350.980022 0 1 78.99585628 4.204928318 25.5 0.788 0 15.378706791 153423.2431 1786.650327 121552 0.5762 0 313.2939002 0 1 115.9995366 4.814916313 25.5 0.788 0 13.886120751 375112.8258 1914.035866 121552 0.5762 0 205.6795656 0 1 328.2788989 5.837802492 25.5 0.788 0 9.9584208761 371357.1317 1911.053166 121552 0.5762 0 204.7225594 0 1 313.9894139 5.654138792 25.5 0.788 0 9.7271898031 370141.6817 1907.662102 121552 0.5762 0 202.7608829 0 1 318.846794 5.733502545 25.5 0.788 0 9.729945641 365789.7101 2032.596457 121552 0.5762 0 218.6840999 0 1 331.405302 6.173251015 25.5 0.788 0 10.329583581 342195.0416 2613.59028 121552 0.5762 0 286.4188066 0 1 246.0521875 6.917751194 25.5 0.788 0 12.860760271 206543.0237 2083.549003 121552 0.5762 0 280.6005732 0 1 124.0398613 4.847640453 25.5 0.788 0 12.470607571 150112.0301 1815.787738 121552 0.5762 0 304.5526436 0 1 104.1083975 4.744897306 25.5 0.788 0 13.431153651 220835.8628 2189.243271 121552 0.5762 0 272.5658993 0 1 153.8308867 5.56375829 25.5 0.788 0 12.443230671 364677.1866 1924.563715 121552 0.5762 0 205.5984154 0 1 310.3283302 5.594452751 25.5 0.788 0 9.8365637491 273714.868 1636.81779 121552 0.5762 0 144.8165204 0 1 56.74448032 3.019690705 25.5 0.788 0 7.260768268480Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFSe Slope Si Si +/- Si Intercept Si Slope Sn Sn +/- Sn Intercept Sn Slope Sr Sr +/- Sr Intercept Sr Slope Te Te +/-D.8 fp-XRF Geochem Mode1 372434.4888 1952.412533 121552 0.5762 0 207.2416417 0 1 329.1648263 5.825594982 25.5 0.788 0 9.8970270821 378461.93 2030.754889 121552 0.5762 0 217.2862501 0 1 339.3663299 6.092323255 25.5 0.788 0 10.357205421 372099.8569 1932.4623 121552 0.5762 0 207.6702329 0 1 299.3757421 5.531365727 25.5 0.788 0 10.032307221 380785.451 1944.413837 121552 0.5762 0 206.5073109 0 1 332.1939332 5.906762694 25.5 0.788 0 10.132166091 353204.9312 1824.321821 121552 0.5762 0 193.2784572 0 1 305.8510094 5.367992452 25.5 0.788 0 9.3069801731 374313.7508 1889.466863 121552 0.5762 0 200.569443 0 1 311.3272323 5.486771799 25.5 0.788 0 9.4729730231 376855.8219 1929.419672 121552 0.5762 0 207.2463593 0 1 331.8772204 5.811077907 25.5 0.788 0 9.916115431 233931.8204 2509.259503 121552 0.5762 0 344.1232383 0 1 144.9564047 5.55123748 25.5 0.788 0 15.120321671 221749.3211 2523.670307 121552 0.5762 0 360.5276146 0 1 80.94328065 4.295736098 25.5 0.788 0 15.900395781 389455.2283 2012.240592 121552 0.5762 0 215.9888705 0 1 338.6734004 6.058971604 25.5 0.788 0 10.430541721 355689.7153 1915.651244 121552 0.5762 0 205.2895071 0 1 297.4776027 5.46180488 25.5 0.788 0 9.9875097411 238638.7767 2389.183348 121552 0.5762 0 318.5478865 0 1 114.8349376 4.754323964 25.5 0.788 0 14.129992851 352974.7804 1993.75727 121552 0.5762 0 217.9989335 0 1 332.5097938 6.163938758 25.5 0.788 0 10.38951671 355235.9908 1861.741436 121552 0.5762 0 197.7974466 0 1 295.4355086 5.28820385 25.5 0.788 0 9.4599713821 294906.6513 1774.029004 121552 0.5762 0 187.9263613 0 1 320.3496029 5.963859266 25.5 0.788 0 9.0062048941 370586.4789 1867.453262 121552 0.5762 0 200.1141805 0 1 308.1736268 5.583675055 25.5 0.788 0 9.8304508191 381444.3101 1962.803701 121552 0.5762 0 211.2753235 0 1 331.6112365 6.032093325 25.5 0.788 0 10.134011251 364589.0379 1921.763307 121552 0.5762 0 205.3528069 0 1 309.5975301 5.65545298 25.5 0.788 0 9.9528563231 356218.5323 1913.378584 121552 0.5762 0 203.452311 0 1 309.2338076 5.696266269 25.5 0.788 0 9.6308496171 363270.7283 1865.099776 121552 0.5762 0 201.4983116 0 1 299.6167196 5.494997301 25.5 0.788 0 9.6776916631 352177.3373 1899.564314 121552 0.5762 0 208.0636901 0 1 301.4950753 5.53084369 25.5 0.788 0 9.8288411721 280918.728 1658.504342 121552 0.5762 0 142.9744693 0 1 57.66928935 3.085055984 25.5 0.788 0 7.2712574641 352722.9522 1873.603947 121552 0.5762 0 200.023585 0 1 303.9110853 5.477285053 25.5 0.788 0 9.3679421251 214454.1035 2417.069895 121552 0.5762 0 350.287194 0 1 71.5331384 3.982950631 25.5 0.788 0 15.62841281 348222.644 1919.349906 121552 0.5762 0 201.5230662 0 1 289.087506 5.583442052 25.5 0.788 0 9.6558148721 356641.9953 1933.67004 121552 0.5762 0 206.4928421 0 1 318.9069443 5.864508743 25.5 0.788 0 9.8925715181 362727.2262 1949.210899 121552 0.5762 0 206.1839804 0 1 316.2872625 5.790903689 25.5 0.788 0 9.7888981791 362958.6501 1864.310572 121552 0.5762 0 201.6771902 0 1 299.112948 5.352575505 25.5 0.788 0 9.6532354491 360019.4746 1860.925779 121552 0.5762 0 197.8451807 0 1 309.7276507 5.402368737 25.5 0.788 0 9.2896747371 365121.6145 1923.780607 121552 0.5762 0 207.6550521 0 1 304.0138505 5.464835699 25.5 0.788 0 9.706348608481Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFTe Intercept Te Slope Th Th +/- Th Intercept Th Slope Ti Ti +/- Ti Intercept Ti Slope U U +/- U Intercept U Slope0 1 17.52302202 4.215343646 0 1 15091.7085 1255.473833 0 1 0 104.7611839 0 10 1 0 130.6046264 0 1 0 218.1176046 0 1 0 149.1566056 0 10 1 11.14187614 2.890358476 0 1 0 236.0091692 0 1 0 171.3583453 0 10 1 0 111.5824113 0 1 0 295.0905088 0 1 0 143.5746291 0 10 1 0 120.3848984 0 1 0 546.5865925 0 1 0 194.3439902 0 10 1 10.66790949 3.024047713 0 1 0 243.1604102 0 1 0 173.4645961 0 10 1 0 139.4181672 0 1 0 233.2336668 0 1 0 177.3147723 0 10 1 0 127.7811179 0 1 0 230.6645206 0 1 0 168.8595604 0 10 1 11.70547244 2.884171634 0 1 0 226.418525 0 1 0 171.1628999 0 10 1 11.0151129 2.889212323 0 1 0 229.4510473 0 1 0 155.8151032 0 10 1 0 136.7027991 0 1 0 235.1224404 0 1 0 170.2648537 0 10 1 9.662171841 2.819426171 0 1 0 243.2692308 0 1 0 161.2656789 0 10 1 0 130.4417794 0 1 0 228.5042165 0 1 0 171.2692733 0 10 1 0 142.2130574 0 1 0 240.2838049 0 1 0 188.8790708 0 10 1 9.222820729 2.87106283 0 1 0 233.7502015 0 1 0 166.8000031 0 10 1 0 133.9816877 0 1 0 231.375679 0 1 0 171.0203349 0 10 1 0 133.0045598 0 1 0 233.0426024 0 1 0 161.5521556 0 10 1 12.89985278 2.851738628 0 1 0 234.2747818 0 1 0 153.6586691 0 10 1 0 134.3573087 0 1 0 237.0882793 0 1 0 170.415673 0 10 1 0 136.7604674 0 1 0 242.7909653 0 1 0 173.610009 0 10 1 9.513649534 3.164741603 0 1 0 338.6028462 0 1 0 129.7427387 0 10 1 11.96805275 3.829475361 0 1 17239.50193 1233.41067 0 1 0 117.2014864 0 10 1 0 113.1609789 0 1 0 340.5637844 0 1 0 139.4680198 0 10 1 17.55908901 4.036810006 0 1 17706.14778 1241.469849 0 1 0 107.5241553 0 10 1 9.264639909 2.80335687 0 1 0 216.4223554 0 1 0 170.5010309 0 10 1 12.59652859 3.133836792 0 1 0 230.2576088 0 1 0 184.7171541 0 10 1 0 136.465636 0 1 0 241.7066993 0 1 0 157.8444415 0 10 1 0 137.8362844 0 1 0 238.6796802 0 1 0 168.0081 0 10 1 9.260161413 2.895171141 0 1 0 240.6400813 0 1 0 169.7285644 0 10 1 9.256312478 2.862244194 0 1 0 231.1881267 0 1 0 172.5838725 0 10 1 0 141.0718503 0 1 0 242.9752664 0 1 0 179.7198377 0 10 1 0 137.8896696 0 1 0 225.8709738 0 1 0 162.727947 0 10 1 0 144.2122252 0 1 0 250.0306132 0 1 0 181.9504991 0 10 1 0 182.6401625 0 1 0 415.6545648 0 1 0 236.4070507 0 10 1 0 133.1575371 0 1 0 223.3253622 0 1 0 165.8749867 0 10 1 0 134.9953207 0 1 0 707.4029659 0 1 0 241.4356858 0 1D.8 fp-XRF Geochem Mode482Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFTe Intercept Te Slope Th Th +/- Th Intercept Th Slope Ti Ti +/- Ti Intercept Ti Slope U U +/- U Intercept U SlopeD.8 fp-XRF Geochem Mode0 1 0 152.2489334 0 1 0 760.2494668 0 1 0 223.0387768 0 10 1 0 151.9340014 0 1 0 503.9160084 0 1 0 196.0806668 0 10 1 0 157.3500691 0 1 0 233.1734398 0 1 0 192.4516673 0 10 1 0 153.7941683 0 1 0 244.0716937 0 1 0 203.1240425 0 10 1 12.39552176 3.230178115 0 1 0 247.1002029 0 1 0 187.7510644 0 10 1 0 133.5883295 0 1 0 236.2065721 0 1 0 168.7284808 0 10 1 13.81522438 3.345446607 0 1 0 234.8385976 0 1 0 195.8153426 0 10 1 0 133.684772 0 1 0 233.2146893 0 1 0 166.2473743 0 10 1 15.65854793 4.003552071 0 1 14307.90858 1223.247202 0 1 0 101.5046723 0 10 1 0 137.5106404 0 1 0 234.365161 0 1 0 183.2730395 0 10 1 0 136.7911591 0 1 0 237.0581695 0 1 0 171.9585168 0 10 1 10.67520063 2.936434613 0 1 0 253.9938283 0 1 0 166.706059 0 10 1 0 134.3034652 0 1 0 249.398043 0 1 0 173.1866725 0 10 1 0 145.8758322 0 1 0 248.5379353 0 1 0 182.5504693 0 10 1 0 140.8757128 0 1 0 239.9284969 0 1 0 162.5788846 0 10 1 0 143.4701797 0 1 0 242.2175326 0 1 0 180.1836866 0 10 1 9.879052118 2.9492335 0 1 0 237.7420571 0 1 0 170.8594536 0 10 1 10.02566871 2.801517891 0 1 0 235.9527167 0 1 0 170.8030578 0 10 1 14.50778147 3.206078533 0 1 0 254.5382849 0 1 0 171.457759 0 10 1 14.63530045 3.094402738 0 1 0 240.2157002 0 1 0 168.7523327 0 10 1 0 148.2680015 0 1 0 256.8074637 0 1 0 184.0916562 0 10 1 0 147.3228208 0 1 0 246.7616007 0 1 0 171.3943004 0 10 1 0 138.0989604 0 1 0 238.2053601 0 1 0 168.5357308 0 10 1 11.86077451 3.114888829 0 1 0 242.9677118 0 1 0 176.8141176 0 10 1 10.22457067 3.110947969 0 1 0 255.7037668 0 1 0 168.9803131 0 10 1 8.850664 2.947843439 0 1 0 249.5894493 0 1 0 177.2910185 0 10 1 0 143.8567806 0 1 0 241.0429264 0 1 0 164.408591 0 10 1 0 146.4276113 0 1 0 262.4853094 0 1 0 187.4878389 0 10 1 12.72752381 3.391115574 0 1 0 249.8433567 0 1 0 198.5581895 0 10 1 0 144.4151854 0 1 0 250.0065285 0 1 0 181.5915424 0 10 1 23.5634168 4.280219102 0 1 17271.26146 1228.36366 0 1 0 107.8052818 0 10 1 9.776867963 3.038955232 0 1 0 248.5313025 0 1 0 185.6979813 0 10 1 0 148.1662859 0 1 0 246.4032121 0 1 0 173.5667696 0 10 1 0 140.8390654 0 1 0 238.6806675 0 1 0 170.865087 0 10 1 0 150.8410783 0 1 0 233.3010862 0 1 0 180.6694604 0 10 1 10.01492597 2.991224068 0 1 0 238.4426205 0 1 0 174.2751024 0 10 1 13.81130576 3.349227597 0 1 0 237.2158722 0 1 0 187.2275267 0 10 1 0 144.5649102 0 1 0 229.5098838 0 1 0 174.93191 0 1483Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFTe Intercept Te Slope Th Th +/- Th Intercept Th Slope Ti Ti +/- Ti Intercept Ti Slope U U +/- U Intercept U SlopeD.8 fp-XRF Geochem Mode0 1 0 144.3277591 0 1 0 241.4561594 0 1 0 177.8335196 0 10 1 9.311241814 3.004487647 0 1 0 243.1718011 0 1 0 189.0682106 0 10 1 9.693161681 2.885052255 0 1 0 235.3445628 0 1 0 162.9400141 0 10 1 0 148.1886589 0 1 0 238.9903853 0 1 0 184.5790812 0 10 1 0 135.554887 0 1 0 248.762173 0 1 0 171.9261347 0 10 1 10.8848359 2.936472013 0 1 0 247.5568658 0 1 0 171.8618584 0 10 1 0 127.771493 0 1 0 256.2342361 0 1 0 165.1846293 0 10 1 14.06395054 3.083234488 0 1 0 242.8274805 0 1 0 166.4367857 0 10 1 0 137.4396671 0 1 0 244.5029267 0 1 0 176.0744368 0 10 1 0 133.6178265 0 1 0 234.0019988 0 1 0 168.6990748 0 10 1 0 144.6998073 0 1 0 234.9374752 0 1 0 177.2101959 0 10 1 0 151.1166475 0 1 0 244.3166891 0 1 0 195.8151176 0 10 1 11.36401873 3.112674237 0 1 0 247.4215005 0 1 0 181.4957107 0 10 1 0 138.9327723 0 1 0 238.8674173 0 1 0 166.3942803 0 10 1 15.78830384 4.014585126 0 1 15732.29748 1227.617373 0 1 0 107.4750973 0 10 1 0 142.189869 0 1 0 236.1159007 0 1 0 166.8868822 0 10 1 13.09268972 2.965051488 0 1 0 243.5271432 0 1 0 173.8008121 0 10 1 0 146.0795387 0 1 0 247.9860657 0 1 0 185.9271611 0 10 1 0 150.5514845 0 1 0 248.1359886 0 1 0 190.0050192 0 10 1 0 138.6997684 0 1 0 244.6058744 0 1 0 175.84774 0 10 1 0 141.0552476 0 1 0 223.6899105 0 1 0 167.4270892 0 10 1 0 136.3087597 0 1 0 222.7693176 0 1 0 184.7628273 0 10 1 0 175.3649142 0 1 0 315.6299262 0 1 0 223.147198 0 10 1 9.804654939 3.257130082 0 1 0 248.705157 0 1 0 206.1085895 0 10 1 0 152.4331588 0 1 0 251.3351143 0 1 0 201.3350424 0 10 1 0 158.2472281 0 1 0 681.6155948 0 1 0 224.2617925 0 10 1 0 156.2692102 0 1 0 604.0684434 0 1 0 200.8217226 0 10 1 9.639931883 2.97000959 0 1 0 237.3398408 0 1 0 168.2678829 0 10 1 0 136.4511558 0 1 0 231.898844 0 1 0 175.2057185 0 10 1 0 143.5542662 0 1 0 233.9974819 0 1 0 175.5756899 0 10 1 11.70680531 3.218029604 0 1 0 257.3992719 0 1 0 172.8873405 0 10 1 0 170.5535257 0 1 0 387.9318688 0 1 0 239.8383451 0 10 1 0 147.8505345 0 1 0 490.9928721 0 1 0 212.3964765 0 10 1 0 160.2981821 0 1 0 609.5880745 0 1 0 202.8196486 0 10 1 0 126.4183056 0 1 0 469.6033212 0 1 15.63794393 4.745335525 0 10 1 0 142.3779711 0 1 0 240.770389 0 1 0 182.1070297 0 10 1 12.84405723 3.905123197 0 1 15922.80612 1217.548981 0 1 0 107.2892508 0 1484Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFTe Intercept Te Slope Th Th +/- Th Intercept Th Slope Ti Ti +/- Ti Intercept Ti Slope U U +/- U Intercept U SlopeD.8 fp-XRF Geochem Mode0 1 0 148.109953 0 1 0 234.5919669 0 1 0 188.0734572 0 10 1 0 150.4450658 0 1 0 236.4257057 0 1 0 185.4281888 0 10 1 10.73702649 2.946426597 0 1 0 234.4471811 0 1 0 169.6581705 0 10 1 0 139.0424208 0 1 0 235.923823 0 1 0 188.9171941 0 10 1 8.568223475 2.71959844 0 1 0 226.3637812 0 1 0 157.884232 0 10 1 0 136.4043519 0 1 0 223.3965558 0 1 0 170.6714991 0 10 1 12.38158961 3.083303307 0 1 0 236.1577751 0 1 0 185.8804912 0 10 1 0 165.2513466 0 1 0 490.8639702 0 1 0 237.0604488 0 10 1 0 174.839836 0 1 0 524.8508301 0 1 0 258.359066 0 10 1 0 139.8407745 0 1 0 236.6217001 0 1 0 189.3868929 0 10 1 9.445547749 2.835405942 0 1 0 243.9848199 0 1 0 166.5392567 0 10 1 0 162.6058804 0 1 0 473.1420765 0 1 0 246.525956 0 10 1 10.82788237 3.195290376 0 1 0 267.3554327 0 1 0 193.1013476 0 10 1 0 125.8399884 0 1 0 225.4356474 0 1 0 161.704084 0 10 1 0 134.4932386 0 1 0 289.4542286 0 1 0 160.9965653 0 10 1 0 136.9773216 0 1 0 236.0935802 0 1 0 174.494532 0 10 1 10.4430562 3.170251199 0 1 0 242.3788329 0 1 0 198.5610759 0 10 1 10.65071642 3.016680289 0 1 0 239.7339654 0 1 0 181.4645895 0 10 1 12.89289489 3.052198576 0 1 0 245.5713771 0 1 0 162.2259183 0 10 1 13.75939909 3.036367948 0 1 0 243.4166027 0 1 0 162.2382071 0 10 1 8.629787693 2.862609974 0 1 0 246.0672403 0 1 0 178.179176 0 10 1 0 107.0351386 0 1 16120.73195 1236.971432 0 1 0 108.9010173 0 10 1 0 137.6752505 0 1 0 243.7257383 0 1 0 166.9420232 0 10 1 0 170.5340389 0 1 0 560.816161 0 1 0 250.808742 0 10 1 0 139.4295856 0 1 0 266.2229898 0 1 0 177.7482582 0 10 1 12.00114309 3.207795683 0 1 0 257.335213 0 1 0 179.1200087 0 10 1 10.85211228 3.014767032 0 1 0 246.4837703 0 1 0 173.2162531 0 10 1 10.88138036 2.822241546 0 1 0 232.7547163 0 1 0 158.1273655 0 10 1 8.58339505 2.730809019 0 1 0 231.7205812 0 1 0 169.0215612 0 10 1 0 134.3765983 0 1 0 231.9367667 0 1 0 170.9339833 0 1485Sample IDCal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFW W +/- W Intercept W Slope Y Y +/- Y Intercept Y Slope Zn Zn +/- Zn Intercept Zn Slope Zr Zr +/-0 310.8576862 0 1 29.63967003 3.025189749 0.74 0.8334 58.09608252 17.07264745 6 0.7788 508.153131 7.866127070 416.9071057 0 1 11.4655831 1.605001691 0.74 0.8334 0 76.75657754 6 0.7788 161.1207892 3.581665560 418.103258 0 1 14.4442614 1.784774185 0.74 0.8334 48.39773784 12.1563101 6 0.7788 162.4263762 3.7705681930 337.7037133 0 1 11.93045336 1.828918748 0.74 0.8334 0 67.26033197 6 0.7788 193.1711023 4.248017370 490.9506307 0 1 14.816237 2.183019177 0.74 0.8334 90.74620055 18.44143932 6 0.7788 58.77101992 3.1275474930 463.9480069 0 1 17.45289961 1.947956993 0.74 0.8334 40.47692048 12.51775083 6 0.7788 184.9816664 4.1336557890 398.2952918 0 1 16.44514443 1.851573356 0.74 0.8334 0 74.92283223 6 0.7788 170.6759997 3.8398043310 399.1701754 0 1 16.63619994 1.777025579 0.74 0.8334 0 74.74008386 6 0.7788 161.4605256 3.6204281030 409.4115409 0 1 15.65021535 1.798549626 0.74 0.8334 0 76.9624465 6 0.7788 196.209079 3.9779299040 443.3281922 0 1 11.92804283 1.723191876 0.74 0.8334 0 76.10691765 6 0.7788 197.5570681 4.0532113360 404.7752415 0 1 12.78708365 1.790230429 0.74 0.8334 0 74.92740633 6 0.7788 183.7087699 3.9658086850 378.4742437 0 1 11.81848784 1.740028933 0.74 0.8334 0 71.45331165 6 0.7788 177.2395612 3.8847147730 401.1097412 0 1 17.31322854 1.804825947 0.74 0.8334 40.30032191 11.67306922 6 0.7788 190.3695452 3.8924014130 436.9813456 0 1 10.83061498 1.757091072 0.74 0.8334 0 79.91783058 6 0.7788 183.277019 4.0414902440 402.9255544 0 1 12.71022922 1.769275101 0.74 0.8334 0 76.24485288 6 0.7788 203.0927555 4.128957920 402.0693963 0 1 14.19879814 1.769460383 0.74 0.8334 0 76.2687008 6 0.7788 190.5499551 3.9585934150 395.7445226 0 1 13.0706327 1.76388948 0.74 0.8334 0 76.50992214 6 0.7788 176.548133 3.8454635070 420.9894636 0 1 14.39400546 1.752870421 0.74 0.8334 0 74.03286889 6 0.7788 172.1850064 3.7567770860 426.6987318 0 1 15.78774047 1.811981906 0.74 0.8334 0 77.34721521 6 0.7788 184.7489872 3.919587430 420.92182 0 1 16.62429573 1.82583268 0.74 0.8334 0 74.38380006 6 0.7788 173.9478062 3.8613701480 364.3841068 0 1 14.69336528 2.001812649 0.74 0.8334 0 67.31550806 6 0.7788 164.2445265 4.2295762190 324.1060094 0 1 27.98449677 2.80013493 0.74 0.8334 0 62.26724211 6 0.7788 472.300893 7.3788044460 349.8221544 0 1 11.22615462 1.958341533 0.74 0.8334 0 70.41408008 6 0.7788 168.8729295 4.31013620 333.1456275 0 1 28.52521689 2.818139296 0.74 0.8334 0 62.09531083 6 0.7788 468.4830161 7.3659110420 394.7915715 0 1 12.51641499 1.706584199 0.74 0.8334 0 69.35663966 6 0.7788 179.3990051 3.8457778050 401.7312192 0 1 38.14438317 2.392435892 0.74 0.8334 0 79.36577945 6 0.7788 213.2169913 4.3444833390 440.5654429 0 1 17.62574196 1.92072207 0.74 0.8334 39.09456738 12.15995696 6 0.7788 204.7319478 4.1974132380 401.1836224 0 1 14.5486063 1.84619912 0.74 0.8334 43.00303312 11.8878885 6 0.7788 178.655825 3.9953866260 412.3223941 0 1 16.55207595 1.863692075 0.74 0.8334 0 73.96414286 6 0.7788 178.2056501 3.9732663630 421.0961965 0 1 15.08047654 1.828105817 0.74 0.8334 36.46802631 11.81222516 6 0.7788 163.3258379 3.7904757440 430.7707967 0 1 11.62067579 1.790037425 0.74 0.8334 0 78.47950112 6 0.7788 212.8431742 4.3135432090 442.8974355 0 1 13.30909727 1.711472288 0.74 0.8334 0 76.53427832 6 0.7788 165.5132512 3.7613183140 433.7482823 0 1 19.22907691 2.061373876 0.74 0.8334 0 79.76433508 6 0.7788 187.1175508 4.1731092480 549.2872566 0 1 30.53127315 2.747323873 0.74 0.8334 0 106.9092333 6 0.7788 138.5637586 4.611643490 437.7417912 0 1 9.395217046 1.604489025 0.74 0.8334 0 75.96587826 6 0.7788 124.7282488 3.3795056460 771.7002173 0 1 7.623165381 1.986856054 0.74 0.8334 122.4383515 23.94036352 6 0.7788 42.68450658 3.051569595D.8 fp-XRF Geochem Mode486Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFW W +/- W Intercept W Slope Y Y +/- Y Intercept Y Slope Zn Zn +/- Zn Intercept Zn Slope Zr Zr +/-D.8 fp-XRF Geochem Mode0 717.2028391 0 1 6.145840356 1.82089842 0.74 0.8334 86.73059638 21.60022705 6 0.7788 12.49803421 2.1387258580 570.5051143 0 1 12.11979829 2.323862698 0.74 0.8334 0 113.9376937 6 0.7788 81.21824965 3.7852844640 488.7401381 0 1 16.1646834 2.033751342 0.74 0.8334 0 88.96574613 6 0.7788 191.3551182 4.368745360 444.0188287 0 1 20.71719243 2.120828691 0.74 0.8334 46.37792457 12.76871299 6 0.7788 210.9521804 4.4827196540 441.6629418 0 1 13.53133264 1.924573575 0.74 0.8334 0 85.01265341 6 0.7788 234.4227249 4.6979591950 423.8609605 0 1 18.84203933 1.924328812 0.74 0.8334 0 78.57628332 6 0.7788 183.2798515 4.0088053550 432.1068413 0 1 16.26886809 2.022110617 0.74 0.8334 0 78.87288686 6 0.7788 191.6732929 4.3825115250 389.9772481 0 1 10.85860229 1.687347317 0.74 0.8334 0 74.87088232 6 0.7788 188.2440611 3.9276450110 300.9601469 0 1 33.36523592 2.984769359 0.74 0.8334 51.23725529 16.06322127 6 0.7788 467.0273501 7.3983055560 368.2931385 0 1 12.85027365 1.745559795 0.74 0.8334 36.77422606 11.52869356 6 0.7788 182.9514549 3.9491898580 439.2175471 0 1 13.53625841 1.734276882 0.74 0.8334 0 77.04100271 6 0.7788 168.3952758 3.7545912710 437.6305981 0 1 9.343785387 1.76591701 0.74 0.8334 0 77.91570027 6 0.7788 180.2789875 4.0004954210 398.8522219 0 1 9.857045962 1.74305419 0.74 0.8334 52.90736203 12.60209293 6 0.7788 176.6066699 4.0082779540 432.2705371 0 1 14.75579058 1.917483783 0.74 0.8334 45.62080397 12.62701444 6 0.7788 192.6533669 4.186556660 433.5904697 0 1 20.01661496 1.974144794 0.74 0.8334 0 78.73528803 6 0.7788 166.0326227 3.8706043840 413.8253769 0 1 14.42923205 1.871787288 0.74 0.8334 0 76.4306716 6 0.7788 206.6263146 4.2606143550 418.1637428 0 1 18.36188647 1.958923403 0.74 0.8334 0 76.4995267 6 0.7788 191.4896981 4.1148615590 423.9651108 0 1 12.03728289 1.716668992 0.74 0.8334 0 73.05672432 6 0.7788 174.203017 3.7896719320 453.489104 0 1 17.88863206 2.016713965 0.74 0.8334 0 80.61640029 6 0.7788 185.8992719 4.2161301420 436.1831368 0 1 12.59812029 1.831963685 0.74 0.8334 0 78.28594195 6 0.7788 179.9337939 4.0304955640 424.8060646 0 1 18.41578571 2.074514166 0.74 0.8334 0 82.11546552 6 0.7788 208.8038116 4.4739644030 420.8381626 0 1 10.55487671 1.796198032 0.74 0.8334 0 79.1758778 6 0.7788 191.9132946 4.2232102530 447.6676315 0 1 9.86122894 1.695123244 0.74 0.8334 0 77.64591899 6 0.7788 150.458248 3.6833163620 433.8651163 0 1 14.75838328 1.945339064 0.74 0.8334 0 80.55367555 6 0.7788 229.3526262 4.5286711220 420.6784494 0 1 15.50899222 1.987132909 0.74 0.8334 0 78.68097282 6 0.7788 192.4029121 4.2916037090 451.2203312 0 1 10.13748496 1.755826857 0.74 0.8334 0 81.7173452 6 0.7788 157.8994963 3.8800735560 427.9341351 0 1 13.10571408 1.896527188 0.74 0.8334 0 82.86953288 6 0.7788 189.8014725 4.2372300150 429.1614396 0 1 19.20640914 2.11757115 0.74 0.8334 43.13646754 13.09727005 6 0.7788 201.0476207 4.4537729010 478.9276948 0 1 35.61491767 2.490200799 0.74 0.8334 53.00181987 13.6156737 6 0.7788 227.3608462 4.7675064670 436.8205492 0 1 16.54722184 1.946612409 0.74 0.8334 0 80.0053959 6 0.7788 218.9393504 4.4349991080 318.0140785 0 1 28.17175615 2.867967744 0.74 0.8334 0 61.39655133 6 0.7788 490.2519779 7.6032598190 427.5124678 0 1 14.64626071 1.920743361 0.74 0.8334 39.4211976 12.32220949 6 0.7788 218.2722355 4.433520380 424.4591905 0 1 16.06999957 1.982149301 0.74 0.8334 0 81.27043858 6 0.7788 198.3617675 4.3744269520 406.9631359 0 1 16.90076476 1.952236274 0.74 0.8334 0 80.61346721 6 0.7788 200.0908965 4.2545444040 457.9959137 0 1 14.20200988 1.912563275 0.74 0.8334 0 81.82393386 6 0.7788 203.4615314 4.3647172680 477.2579902 0 1 15.60035495 1.904256129 0.74 0.8334 0 79.91360055 6 0.7788 174.5585758 4.0153664690 477.2391264 0 1 15.77435532 2.05970231 0.74 0.8334 40.03609228 12.89777373 6 0.7788 199.4933896 4.4805986050 435.5291518 0 1 13.95411664 1.852173233 0.74 0.8334 0 78.08756624 6 0.7788 173.76587 3.998435746487Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFW W +/- W Intercept W Slope Y Y +/- Y Intercept Y Slope Zn Zn +/- Zn Intercept Zn Slope Zr Zr +/-D.8 fp-XRF Geochem Mode0 460.5619612 0 1 13.05889066 1.921067064 0.74 0.8334 0 84.05015295 6 0.7788 190.6825066 4.3096112480 439.3200469 0 1 13.62382855 1.862080165 0.74 0.8334 0 79.37653745 6 0.7788 184.4885001 4.126769820 390.8961722 0 1 14.77963987 1.817750397 0.74 0.8334 0 71.85640418 6 0.7788 182.4430773 3.9829351970 385.6158456 0 1 14.88547704 1.877480597 0.74 0.8334 0 76.99574151 6 0.7788 185.9957542 4.143901880 424.5409639 0 1 12.0161441 1.760931362 0.74 0.8334 0 76.70664353 6 0.7788 149.7060553 3.6555285380 401.305841 0 1 14.03642019 1.81355352 0.74 0.8334 0 76.33590057 6 0.7788 193.4352623 4.074301440 447.6442178 0 1 10.13933883 1.689812166 0.74 0.8334 0 77.74352277 6 0.7788 152.4438446 3.6405547780 408.3671788 0 1 14.85373646 1.912783317 0.74 0.8334 0 78.86782644 6 0.7788 187.9531825 4.1052924840 416.2081447 0 1 12.61403855 1.781792222 0.74 0.8334 0 76.67951193 6 0.7788 153.4170382 3.7398716340 408.8478217 0 1 9.98424581 1.654834416 0.74 0.8334 0 76.67079406 6 0.7788 182.8509682 3.8725879410 428.6131869 0 1 12.05640868 1.747384753 0.74 0.8334 0 81.6365542 6 0.7788 158.3201552 3.7752994890 439.2239048 0 1 9.955733603 1.775582414 0.74 0.8334 0 84.99373208 6 0.7788 180.1229033 4.1003248570 414.1117188 0 1 15.46210888 1.956116422 0.74 0.8334 0 79.23897811 6 0.7788 206.8421432 4.3827085730 443.0980502 0 1 19.78977568 1.988497209 0.74 0.8334 0 77.24776949 6 0.7788 189.9771006 4.1174093950 302.6342386 0 1 27.23022619 2.849321428 0.74 0.8334 50.60612487 16.06052566 6 0.7788 475.5728058 7.4698465190 424.8666613 0 1 21.84315411 2.034425475 0.74 0.8334 37.54997622 12.25570235 6 0.7788 191.5278847 4.1405006120 412.9884278 0 1 13.6141183 1.770862712 0.74 0.8334 0 75.40923156 6 0.7788 166.6936369 3.8319448620 445.4602587 0 1 19.3155027 2.014943678 0.74 0.8334 37.68066615 12.2950909 6 0.7788 223.8571335 4.5023156220 387.5004855 0 1 13.98059737 1.973360715 0.74 0.8334 0 77.76666641 6 0.7788 199.6920275 4.3514866250 415.9188158 0 1 15.85749045 1.965978502 0.74 0.8334 0 81.74632809 6 0.7788 188.8290668 4.1798512360 432.5805246 0 1 9.455722619 1.630807239 0.74 0.8334 0 80.78082197 6 0.7788 149.6460415 3.6116151450 407.501565 0 1 8.215085642 1.564613626 0.74 0.8334 0 74.80911471 6 0.7788 142.8861486 3.5282501290 524.5300252 0 1 11.21498212 2.091363781 0.74 0.8334 0 101.0204634 6 0.7788 155.5713484 4.4927071420 428.6559079 0 1 14.99188561 2.014927094 0.74 0.8334 0 81.83605947 6 0.7788 184.3943409 4.3699432740 454.8587565 0 1 14.01340979 1.952701292 0.74 0.8334 0 82.57195457 6 0.7788 185.6595575 4.2555351060 711.6364747 0 1 14.21199092 2.271389527 0.74 0.8334 67.45974572 20.66121703 6 0.7788 27.49698424 2.646792260 605.4617978 0 1 13.89925822 2.272243613 0.74 0.8334 90.58910829 19.83599241 6 0.7788 47.52028148 3.0968672840 435.0391141 0 1 15.49408929 1.907683048 0.74 0.8334 46.21484902 12.49688288 6 0.7788 184.2753554 4.0953208810 417.4617308 0 1 15.21965511 1.838224671 0.74 0.8334 0 80.85610043 6 0.7788 182.2804504 4.0068358210 425.7950244 0 1 14.41609365 1.838637761 0.74 0.8334 0 77.50581911 6 0.7788 180.478117 4.0237600020 451.0404856 0 1 15.3902223 2.017491993 0.74 0.8334 0 85.15897017 6 0.7788 186.7409639 4.343204460 519.0234081 0 1 17.3132 2.820699715 0.74 0.8334 101.596673 20.3983703 6 0.7788 169.8874244 5.3091648440 541.0443475 0 1 15.60305696 2.378490565 0.74 0.8334 0 115.2000706 6 0.7788 64.36375649 3.392655910 561.2182486 0 1 18.63181395 2.50001079 0.74 0.8334 100.6011833 21.41642611 6 0.7788 43.23972825 3.1106763240 588.6343085 0 1 17.00354075 2.458820201 0.74 0.8334 0 114.3764327 6 0.7788 76.52418165 3.7518624970 447.8747381 0 1 16.53038874 1.874290799 0.74 0.8334 0 77.5640383 6 0.7788 183.3684938 3.9925691580 324.61185 0 1 29.03128607 2.887186687 0.74 0.8334 0 63.31489866 6 0.7788 474.7848404 7.430452625488Sample [binary]-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRF fp-XRFW W +/- W Intercept W Slope Y Y +/- Y Intercept Y Slope Zn Zn +/- Zn Intercept Zn Slope Zr Zr +/-D.8 fp-XRF Geochem Mode0 416.0014396 0 1 15.19140746 1.888063558 0.74 0.8334 0 79.21477495 6 0.7788 183.937713 4.0667035520 460.0583933 0 1 19.01040221 1.989655429 0.74 0.8334 0 80.00987287 6 0.7788 171.6561697 4.0688182880 444.0317171 0 1 16.29017456 1.885802684 0.74 0.8334 0 79.73879826 6 0.7788 174.5148958 3.9579582980 451.6023997 0 1 12.03866279 1.830411206 0.74 0.8334 0 81.55725769 6 0.7788 178.8621775 4.0460857660 394.3038186 0 1 12.05326467 1.685806301 0.74 0.8334 0 72.07596473 6 0.7788 165.134072 3.706185980 391.9679463 0 1 10.92184514 1.663940349 0.74 0.8334 0 78.05287633 6 0.7788 148.9383992 3.5925282120 416.1797405 0 1 18.73944607 1.941371304 0.74 0.8334 0 73.74029654 6 0.7788 193.2811334 4.1437154990 657.9696327 0 1 11.39317064 2.249991175 0.74 0.8334 75.85967069 20.41766789 6 0.7788 63.14773135 3.5839147790 685.2918661 0 1 11.90041746 2.199649033 0.74 0.8334 96.89909221 22.15260319 6 0.7788 41.19025034 3.0472645340 471.8203728 0 1 15.3737787 1.949522466 0.74 0.8334 51.49299536 13.09597359 6 0.7788 173.3651157 4.05947940 441.8029705 0 1 11.9884605 1.707498561 0.74 0.8334 0 79.55367376 6 0.7788 177.4600971 3.9377668180 638.3812254 0 1 16.41373725 2.254379725 0.74 0.8334 0 135.5473689 6 0.7788 53.42699674 3.2026312480 442.0169156 0 1 11.78906552 1.931352574 0.74 0.8334 0 84.18053717 6 0.7788 186.2312328 4.3175499380 405.9086556 0 1 9.830936415 1.597750317 0.74 0.8334 0 77.35830871 6 0.7788 165.4280723 3.6879989190 376.7413606 0 1 15.90536432 1.965667403 0.74 0.8334 44.16947473 12.49122956 6 0.7788 156.0361858 3.9269843660 444.6597652 0 1 16.11478733 1.904142247 0.74 0.8334 0 81.25757318 6 0.7788 211.9157979 4.2547637220 442.589611 0 1 20.95160967 2.137148866 0.74 0.8334 0 83.74376204 6 0.7788 204.0256118 4.4029393360 451.9684868 0 1 13.57981035 1.83377261 0.74 0.8334 0 76.51605954 6 0.7788 190.8139349 4.1385202060 431.377459 0 1 16.12241364 1.926130323 0.74 0.8334 0 80.82953926 6 0.7788 169.8034515 3.9701773710 443.9072533 0 1 15.37270014 1.882481733 0.74 0.8334 0 77.70615606 6 0.7788 186.6816638 4.0491304810 444.2964874 0 1 14.65886918 1.827062525 0.74 0.8334 0 77.68243789 6 0.7788 153.3765741 3.7344756780 297.6181493 0 1 27.4295206 2.882764705 0.74 0.8334 55.01773629 16.46786155 6 0.7788 474.1840303 7.4801966890 375.1328356 0 1 13.55364204 1.77473946 0.74 0.8334 0 72.66807153 6 0.7788 162.172359 3.748514660 689.1415897 0 1 16.18730409 2.344953059 0.74 0.8334 66.68974334 20.80784372 6 0.7788 35.88585338 2.844000940 412.1056949 0 1 14.92628404 1.945315061 0.74 0.8334 41.09882493 12.413654 6 0.7788 182.897276 4.1118450750 435.1234877 0 1 16.07318519 1.968022196 0.74 0.8334 0 82.06398373 6 0.7788 217.5671165 4.4786091850 387.1740567 0 1 13.354919 1.890352379 0.74 0.8334 0 79.15017659 6 0.7788 169.8319265 3.9933222330 434.7443147 0 1 9.471729325 1.631319442 0.74 0.8334 0 76.33043195 6 0.7788 172.1630755 3.8015308160 374.8838898 0 1 14.87512637 1.728284552 0.74 0.8334 0 75.20126041 6 0.7788 159.0995118 3.652308080 414.1332333 0 1 10.78011994 1.657876801 0.74 0.8334 0 74.2310277 6 0.7788 144.8158711 3.566339495489Sample IDCal [binary]-XRF fp-XRFZr Intercept Zr Slope24.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.8159D.8 fp-XRF Geochem Mode490Sample [binary]-XRF fp-XRFZr Intercept Zr SlopeD.8 fp-XRF Geochem Mode24.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.8159491Sample IDQ515586Q515587Q515588Q515589Cal [binary]-XRF fp-XRFZr Intercept Zr SlopeD.8 fp-XRF Geochem Mode24.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.8159492Sample [binary]-XRF fp-XRFZr Intercept Zr SlopeD.8 fp-XRF Geochem Mode24.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.815924.9 0.8159493ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Ag Al As Au B Ba Be Bi BrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 <0.002 10 0.02 0.001 <0.2 0.18 <0.005 <0.003 <1Q515695 <0.002 16 0.11 0.001 <0.2 0.34 <0.005 <0.003 <1Q515572 <0.002 7 <0.01 0.001 <0.2 0.13 <0.005 <0.003 <1Q515581 <0.002 6 0.02 <0.001 <0.2 0.15 <0.005 <0.003 <1Q515653 <0.002 11 0.07 <0.001 <0.2 0.17 <0.005 <0.003 <1Q515501 <0.002 5 0.03 <0.001 <0.2 0.12 <0.005 <0.003 <1Q515665 <0.002 7 0.05 <0.001 <0.2 0.2 <0.005 <0.003 <1ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Ca Cd Ce Co Cr Cs Cu Dy ErSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 10 0.001 0.0116 0.023 <0.05 0.0026 0.07 0.001 0.0005Q515695 10 0.001 0.0584 0.016 0.06 0.0031 0.17 0.0032 0.0013Q515572 10 0.001 0.0111 0.015 <0.05 0.002 <0.05 0.0006 <0.0005Q515581 10 <0.001 0.0238 0.016 <0.05 0.0008 0.08 0.0017 0.0006Q515653 10 0.001 0.0267 0.02 <0.05 0.0013 0.16 0.0018 <0.0005Q515501 10 0.001 0.004 0.018 <0.05 0.002 <0.05 <0.0005 <0.0005Q515665 10 0.001 0.0299 0.009 <0.05 0.002 0.29 0.0023 0.0006ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Eu Fe Ga Gd Ge Hf Hg Ho ISAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 <0.0005 5 <0.05 0.0008 <0.005 <0.0005 <0.01 0.0001 <0.05Q515695 0.0013 11 <0.05 0.0027 <0.005 0.0009 <0.01 0.0005 <0.05Q515572 0.0012 3 <0.05 0.0009 <0.005 <0.0005 <0.01 0.0001 <0.05Q515581 0.0005 4 <0.05 0.0023 <0.005 0.0015 <0.01 0.0001 <0.05Q515653 0.0005 11 <0.05 0.0016 <0.005 <0.0005 <0.01 0.0004 <0.05Q515501 <0.0005 6 <0.05 0.0008 <0.005 <0.0005 <0.01 0.0001 <0.05Q515665 <0.0005 3 <0.05 0.002 <0.005 <0.0005 <0.01 0.0004 <0.05ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03In K La Li Lu Mg Mn Mo NaSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 <0.001 7 0.0046 0.06 0.0002 6.6 0.28 0.002 5Q515695 <0.001 20 0.0241 0.05 0.0003 15 0.14 0.006 6Q515572 <0.001 <5 0.0065 0.03 0.0001 1.4 0.23 0.001 5Q515581 <0.001 6 0.0102 0.05 0.0002 1.5 0.41 0.002 5Q515653 <0.001 <5 0.0122 0.06 0.0002 3.6 0.05 0.006 5Q515501 <0.001 <5 0.0029 0.05 0.0001 2.1 0.08 0.002 <5Q515665 <0.001 7 0.0105 0.08 0.0001 2.9 0.07 0.003 8D.9 Sequential Leach 494ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Nb Nd Ni P Pb Pr Rb Re SbSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.0015 0.0049 0.05 1 <0.005 0.0012 0.094 <0.0002 <0.0005Q515695 0.013 0.0289 0.14 4 <0.005 0.0083 0.123 <0.0002 0.0008Q515572 <0.0005 0.0056 0.05 <1 <0.005 0.0019 0.055 <0.0002 <0.0005Q515581 <0.0005 0.0124 <0.05 1 <0.005 0.0028 0.061 <0.0002 <0.0005Q515653 0.0005 0.014 0.06 1 <0.005 0.0035 0.07 <0.0002 <0.0005Q515501 <0.0005 0.003 <0.05 1 <0.005 0.0004 0.06 <0.0002 0.001Q515665 0.0005 0.0126 <0.05 2 <0.005 0.0038 0.109 <0.0002 0.0007ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Se Sm Sn Sr Ta Tb Te Th TiSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 <0.02 <0.0005 <0.005 0.126 0.001 0.0002 <0.005 0.0021 0.09Q515695 <0.02 0.0045 <0.005 0.191 0.001 0.0004 <0.005 0.0083 0.37Q515572 <0.02 0.0016 <0.005 0.075 <0.001 0.0001 <0.005 0.0016 0.08Q515581 <0.02 0.0028 <0.005 0.051 <0.001 0.0003 <0.005 0.0024 0.05Q515653 <0.02 0.0029 <0.005 0.11 <0.001 0.0004 <0.005 0.0026 0.07Q515501 <0.02 0.0005 <0.005 0.067 <0.001 0.0001 <0.005 0.001 0.06Q515665 <0.02 0.0028 <0.005 0.068 <0.001 0.0003 <0.005 0.0062 0.28ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03 ME-MS03Tl Tm U V W Y Yb Zn ZrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.002 0.0002 0.0026 <0.05 0.001 0.0039 <0.0005 <0.05 0.005Q515695 0.001 0.0003 0.0128 0.12 0.002 0.0147 0.0019 <0.05 0.029Q515572 0.001 <0.0001 0.0029 <0.05 0.001 0.0036 <0.0005 0.08 0.002Q515581 0.001 0.0001 0.0058 <0.05 0.001 0.0063 <0.0005 <0.05 0.005Q515653 0.001 0.0001 0.0037 0.1 0.001 0.0062 <0.0005 0.05 0.005Q515501 0.001 0.0001 0.0014 <0.05 <0.001 0.0019 <0.0005 <0.05 0.002Q515665 0.002 0.0001 0.0057 0.19 0.001 0.0075 <0.0005 <0.05 0.012pH-MS03Final pHSAMPLE UnityQ515576 5.2Q515695 6.3Q515572 6Q515581 5.1Q515653 4.8Q515501 5Q515665 4.9D.9 Sequential Leach 495ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04Ag Al As Au B Ba Be Bi BrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 <0.002 405 0.05 <0.001 <0.2 7.28 0.032 0.003 <1Q515695 <0.002 115 0.15 <0.001 <0.2 29.1 0.035 0.008 <1Q515572 <0.002 170 0.02 <0.001 <0.2 2.05 0.014 <0.003 <1Q515581 <0.002 102 0.08 0.001 <0.2 3.5 0.015 <0.003 <1Q515653 <0.002 212 0.27 <0.001 <0.2 3.98 0.02 0.012 <1Q515501 <0.002 102 0.06 <0.001 <0.2 4.17 0.009 0.003 <1Q515665 <0.002 86 0.02 <0.001 <0.2 6.65 0.011 0.005 <1ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04Ca Cd Ce Co Cr Cs Cu Dy ErSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 60 0.004 0.575 0.094 2.41 0.0861 0.76 0.0249 0.0089Q515695 270 0.012 2.41 0.187 2.58 0.0764 1.01 0.0822 0.038Q515572 10 0.002 0.417 0.016 2.45 0.0382 0.41 0.0146 0.0068Q515581 20 <0.001 0.543 0.026 2.34 0.0244 0.57 0.023 0.0079Q515653 40 0.004 1 0.058 2.53 0.0472 1.67 0.0417 0.014Q515501 30 <0.001 0.171 0.06 2.65 0.0512 0.24 0.0066 0.0033Q515665 50 0.004 1.08 0.048 2.49 0.0752 1.69 0.0419 0.0144ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04Eu Fe Ga Gd Ge Hf Hg Ho ISAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.0113 59 <0.05 0.0365 <0.005 0.0025 <0.01 0.003 0.07Q515695 0.04 96 <0.05 0.126 <0.005 0.0014 <0.01 0.0133 <0.05Q515572 0.0083 22 <0.05 0.0278 <0.005 0.0014 <0.01 0.0018 0.07Q515581 0.0099 33 <0.05 0.0338 <0.005 0.0022 <0.01 0.0035 <0.05Q515653 0.0192 182 <0.05 0.0663 <0.005 0.0018 <0.01 0.006 0.07Q515501 0.0046 79 <0.05 0.0154 <0.005 0.0012 <0.01 0.0013 <0.05Q515665 0.0194 18 <0.05 0.0688 <0.005 0.0008 <0.01 0.0071 <0.05ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04In K La Li Lu Mg Mn Mo NaSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.001 5 0.271 0.04 0.0009 13.9 0.93 0.004 8Q515695 0.001 19 1.23 0.02 0.003 180 1.67 0.003 13Q515572 <0.001 <5 0.199 0.01 0.0004 0.6 0.19 0.004 6Q515581 <0.001 <5 0.24 0.02 0.0008 1.2 0.46 0.003 8Q515653 0.001 <5 0.49 0.02 0.0013 4 0.11 0.006 8Q515501 0.001 <5 0.0791 0.01 0.0004 2.8 0.18 0.002 8Q515665 <0.001 6 0.54 0.03 0.0011 10.1 0.32 <0.001 10D.9 Sequential Leach 496ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04Nb Nd Ni P Pb Pr Rb Re SbSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.0048 0.245 0.29 4 0.222 0.0691 0.336 0.0004 <0.0005Q515695 0.0037 0.964 1.73 9 0.27 0.293 0.487 <0.0002 <0.0005Q515572 0.0014 0.1765 0.12 2 0.45 0.0509 0.185 0.0005 <0.0005Q515581 <0.0005 0.213 0.08 2 0.084 0.0676 0.168 <0.0002 <0.0005Q515653 0.0037 0.414 0.33 7 0.17 0.126 0.207 <0.0002 <0.0005Q515501 0.0012 0.0759 0.19 4 0.129 0.0206 0.138 <0.0002 <0.0005Q515665 0.0006 0.436 0.31 4 0.165 0.131 0.379 0.0004 <0.0005ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04Se Sm Sn Sr Ta Tb Te Th TiSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 <0.02 0.046 <0.005 0.755 0.002 0.0049 <0.005 0.0678 0.39Q515695 <0.02 0.167 <0.005 4.64 0.001 0.0166 <0.005 0.0905 0.28Q515572 <0.02 0.0306 <0.005 0.109 0.002 0.0042 <0.005 0.0421 0.22Q515581 <0.02 0.0422 <0.005 0.128 <0.001 0.0048 <0.005 0.0433 0.12Q515653 <0.02 0.0802 <0.005 0.398 <0.001 0.009 <0.005 0.0693 0.63Q515501 <0.02 0.0141 <0.005 0.28 <0.001 0.0024 <0.005 0.0287 0.25Q515665 <0.02 0.0838 0.033 0.436 <0.001 0.0087 <0.005 0.0449 0.33ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04 ME-MS04Tl Tm U V W Y Yb Zn ZrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.012 0.0008 0.0555 0.65 <0.001 0.105 0.0077 0.22 0.067Q515695 0.01 0.0039 0.211 0.73 <0.001 0.41 0.0223 0.33 0.054Q515572 0.004 0.0007 0.061 0.67 0.001 0.0659 0.0039 0.06 0.031Q515581 0.004 0.0007 0.0675 0.65 <0.001 0.0892 0.0074 0.07 0.039Q515653 0.006 0.0012 0.107 0.81 0.001 0.154 0.0081 0.22 0.069Q515501 0.003 0.0005 0.0226 0.73 <0.001 0.0457 0.0045 0.28 0.03Q515665 0.008 0.0019 0.1005 0.72 0.001 0.181 0.0099 0.13 0.024pH-MS04Final pHSAMPLE UnityQ515576 5.3Q515695 5.3Q515572 5.3Q515581 5.3Q515653 5.3Q515501 5.3Q515665 5.3D.9 Sequential Leach 497ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05Ag Al As Au B Ba Be Bi BrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.004 633 0.23 <0.001 <0.2 3.49 0.029 0.003 1Q515695 0.005 158 0.39 <0.001 <0.2 6.79 0.021 <0.003 <1Q515572 0.005 364 0.04 <0.001 <0.2 0.59 0.019 <0.003 <1Q515581 0.002 187 0.41 <0.001 <0.2 0.77 0.017 0.003 <1Q515653 0.002 230 0.45 <0.001 <0.2 0.93 0.014 0.003 <1Q515501 0.002 125 0.22 <0.001 <0.2 0.84 0.009 <0.003 <1Q515665 0.003 119 0.06 <0.001 <0.2 1.25 0.013 0.003 <1ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05Ca Cd Ce Co Cr Cs Cu Dy ErSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 610 0.006 0.671 0.29 0.22 0.0233 0.5 0.125 0.0695Q515695 610 0.008 0.688 0.131 0.13 0.0166 0.92 0.0876 0.0445Q515572 260 0.003 0.569 0.024 0.16 0.0126 0.35 0.0794 0.0351Q515581 910 0.007 0.998 0.04 0.1 0.0125 0.46 0.246 0.117Q515653 500 0.004 0.751 0.02 0.19 0.0193 0.75 0.0956 0.0478Q515501 620 0.005 0.473 0.021 0.14 0.0191 0.16 0.138 0.0683Q515665 650 0.006 0.714 0.018 0.08 0.0303 0.94 0.122 0.0594ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05Eu Fe Ga Gd Ge Hf Hg Ho ISAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.0185 148 <0.05 0.138 <0.005 0.0049 <0.01 0.0232 <0.05Q515695 0.0115 227 <0.05 0.08 <0.005 0.001 <0.01 0.0158 <0.05Q515572 0.0127 53 <0.05 0.0892 <0.005 0.0026 <0.01 0.0146 <0.05Q515581 0.0337 85 <0.05 0.252 <0.005 0.0018 <0.01 0.0439 <0.05Q515653 0.0136 212 <0.05 0.101 <0.005 0.0023 0.01 0.0171 <0.05Q515501 0.0166 129 <0.05 0.137 <0.005 0.0011 <0.01 0.0251 <0.05Q515665 0.0145 45 <0.05 0.121 <0.005 0.001 0.01 0.0213 <0.05ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05In K La Li Lu Mg Mn Mo NaSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 <0.001 5 0.296 0.06 0.0061 2.9 5.34 0.002 8Q515695 <0.001 7 0.375 0.03 0.0034 15 3.62 0.001 9Q515572 <0.001 <5 0.273 0.03 0.0031 0.6 1.39 0.001 7Q515581 <0.001 5 0.381 0.03 0.0107 0.8 4.12 0.002 8Q515653 <0.001 <5 0.398 0.03 0.004 1.1 1.99 0.003 7Q515501 <0.001 <5 0.187 0.02 0.006 0.9 2.56 0.001 7Q515665 <0.001 <5 0.36 0.04 0.0054 4.5 2.46 0.002 14D.9 Sequential Leach 498ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05Nb Nd Ni P Pb Pr Rb Re SbSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.0108 0.382 0.23 213 0.163 0.0878 0.082 0.0003 0.0009Q515695 0.0094 0.289 0.61 245 0.123 0.0772 0.086 <0.0002 0.0013Q515572 0.002 0.307 0.07 61 0.133 0.0742 0.055 <0.0002 0.001Q515581 0.0014 0.699 0.05 354 0.119 0.146 0.067 <0.0002 <0.0005Q515653 0.0064 0.358 0.16 202 0.105 0.0876 0.055 <0.0002 0.001Q515501 0.0019 0.341 0.08 236 0.101 0.0702 0.039 <0.0002 <0.0005Q515665 0.0018 0.346 0.14 266 0.107 0.0856 0.104 <0.0002 0.0007ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05Se Sm Sn Sr Ta Tb Te Th TiSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 <0.02 0.107 <0.005 0.881 0.001 0.0218 <0.005 0.0358 0.42Q515695 <0.02 0.0601 <0.005 1.175 <0.001 0.0141 <0.005 0.0025 0.28Q515572 <0.02 0.0767 <0.005 0.312 <0.001 0.0137 <0.005 0.0156 0.22Q515581 0.03 0.199 <0.005 1.04 <0.001 0.0418 <0.005 0.0077 0.26Q515653 <0.02 0.0803 <0.005 0.599 <0.001 0.0159 <0.005 0.0164 0.44Q515501 <0.02 0.0979 <0.005 0.698 <0.001 0.0221 <0.005 0.0065 0.26Q515665 <0.02 0.0853 <0.005 0.735 <0.001 0.0202 <0.005 0.0023 0.39ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05 ME-MS05Tl Tm U V W Y Yb Zn ZrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.002 0.0087 0.0271 0.08 0.001 0.686 0.0466 0.1 0.118Q515695 0.002 0.0056 0.0244 0.48 0.001 0.505 0.0329 0.13 0.029Q515572 0.002 0.0052 0.0217 <0.05 0.001 0.422 0.0304 <0.05 0.035Q515581 0.001 0.0166 0.0366 0.1 0.001 1.28 0.0879 <0.05 0.037Q515653 0.001 0.0065 0.0224 0.35 0.001 0.573 0.0381 <0.05 0.067Q515501 <0.001 0.0097 0.019 0.11 0.001 0.769 0.0543 <0.05 0.029Q515665 0.001 0.0079 0.0143 0.14 0.001 0.7 0.0398 <0.05 0.016pH-MS05Final pHSAMPLE UnityQ515576 2.7Q515695 2.6Q515572 2.6Q515581 2.5Q515653 2.6Q515501 2.6Q515665 2.6D.9 Sequential Leach 499ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06Ag Al As Au B Ba Be Bi BrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.011 1570 3.68 <0.001 <0.2 9.38 0.102 0.116 2Q515695 0.021 1500 1.94 <0.001 <0.2 12.6 0.071 0.097 1Q515572 0.006 1310 0.71 <0.001 <0.2 3.68 0.058 0.057 2Q515581 0.005 607 2.71 <0.001 <0.2 3.41 0.054 0.087 2Q515653 0.016 836 1.58 <0.001 <0.2 5.61 0.054 0.09 2Q515501 0.006 514 2.2 <0.001 <0.2 3.28 0.08 0.071 2Q515665 0.014 1140 0.25 <0.001 <0.2 8.21 0.057 0.072 1ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06Ca Cd Ce Co Cr Cs Cu Dy ErSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 260 0.025 3.51 2.44 3.96 0.195 9.01 0.245 0.115Q515695 210 0.016 4.46 1.36 4.93 0.191 7.22 0.263 0.131Q515572 100 0.013 1.76 0.414 1.6 0.134 2.74 0.102 0.0451Q515581 160 0.01 2.64 0.396 1.33 0.111 4.41 0.154 0.0693Q515653 260 0.019 2.95 0.346 1.94 0.207 4.35 0.234 0.106Q515501 250 0.006 2.03 0.312 1.28 0.139 1.94 0.187 0.0923Q515665 170 0.01 3.19 0.502 3.5 0.236 5.16 0.215 0.0993ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06Eu Fe Ga Gd Ge Hf Hg Ho ISAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.0604 2350 0.46 0.333 <0.005 0.0054 0.01 0.042 0.11Q515695 0.0718 2380 0.51 0.373 0.005 0.002 <0.01 0.0491 0.11Q515572 0.0351 950 0.3 0.157 <0.005 0.0036 <0.01 0.0167 0.23Q515581 0.045 1050 0.23 0.239 <0.005 0.0028 <0.01 0.0269 0.14Q515653 0.0592 1050 0.32 0.335 <0.005 0.0027 <0.01 0.0405 0.23Q515501 0.0436 1120 0.24 0.264 <0.005 0.0012 <0.01 0.0352 0.14Q515665 0.0591 1040 0.39 0.338 <0.005 0.0021 <0.01 0.0401 0.06ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06In K La Li Lu Mg Mn Mo NaSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.001 69 1.535 3.33 0.0116 1280 27.7 0.087 17Q515695 0.002 68 2.11 2.93 0.0129 1340 13.7 0.04 18Q515572 0.001 28 0.809 1.44 0.0044 139 4.01 0.034 13Q515581 0.001 67 1.22 1.57 0.0079 157 6.29 0.065 20Q515653 0.001 76 1.26 1.6 0.0116 207 4.96 0.031 19Q515501 0.001 51 0.882 1.35 0.0103 144 4.17 0.04 15Q515665 0.001 49 1.43 2.69 0.0119 419 7.43 0.004 17D.9 Sequential Leach 500ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06Nb Nd Ni P Pb Pr Rb Re SbSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.105 1.635 10.25 164 1.455 0.412 0.959 <0.0002 0.0077Q515695 0.0944 1.995 8.86 116 1.175 0.521 1.17 <0.0002 0.0062Q515572 0.0383 0.879 1.16 87 0.824 0.22 0.612 <0.0002 0.004Q515581 0.0241 1.3 1.27 106 0.829 0.327 0.67 <0.0002 0.005Q515653 0.0212 1.595 1.25 147 0.725 0.381 0.92 <0.0002 0.0037Q515501 0.0175 1.13 1.1 140 0.822 0.263 0.496 <0.0002 0.0047Q515665 0.0167 1.665 1.66 67 0.632 0.405 0.903 0.0003 0.0038ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06Se Sm Sn Sr Ta Tb Te Th TiSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.03 0.359 0.015 0.916 0.004 0.0493 0.005 0.0084 31.3Q515695 <0.02 0.412 0.01 1.22 0.005 0.0562 <0.005 0.0053 28Q515572 0.02 0.188 0.014 0.428 0.002 0.0234 <0.005 0.0213 27.5Q515581 <0.02 0.27 0.012 0.594 0.001 0.0354 <0.005 0.0102 19.25Q515653 <0.02 0.365 0.008 0.739 0.001 0.0494 <0.005 0.0134 19.25Q515501 0.04 0.277 0.011 0.618 0.001 0.0418 <0.005 0.0111 14.95Q515665 <0.02 0.365 0.021 0.681 0.001 0.0481 <0.005 0.0084 30.6ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06 ME-MS06Tl Tm U V W Y Yb Zn ZrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.016 0.0154 0.18 3.77 0.017 1.06 0.084 7.84 0.159Q515695 0.012 0.0178 0.31 5.04 0.007 1.22 0.101 7.42 0.075Q515572 0.007 0.0051 0.171 1.57 0.008 0.411 0.034 1.52 0.107Q515581 0.008 0.0092 0.165 1.63 0.023 0.65 0.058 1.75 0.067Q515653 0.011 0.0143 0.182 3.09 0.008 1.04 0.0837 2.49 0.065Q515501 0.005 0.0122 0.0994 2.23 0.017 0.844 0.0748 1.58 0.049Q515665 0.008 0.0142 0.21 3.02 0.003 0.98 0.0782 3.43 0.026pH-MS06Final pHSAMPLE UnityQ515576 1.6Q515695 1.6Q515572 1.6Q515581 1.6Q515653 1.6Q515501 1.6Q515665 1.7D.9 Sequential Leach 501ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07Ag Al As Au B Ba Be Bi BrSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 <0.002 71 0.92 0.001 <0.2 1.17 <0.005 <0.003 <1Q515695 <0.002 95 0.34 0.001 <0.2 1.11 <0.005 <0.003 <1Q515572 <0.002 116 0.64 <0.001 <0.2 0.85 0.007 0.004 <1Q515581 <0.002 93 0.37 <0.001 <0.2 1 0.005 <0.003 <1Q515653 <0.002 143 0.2 0.001 <0.2 1.36 0.006 0.003 <1Q515501 <0.002 76 0.51 <0.001 <0.2 0.81 0.009 <0.003 <1Q515665 <0.002 51 0.07 <0.001 <0.2 0.56 <0.005 <0.003 <1ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07Ca Cd Ce Co Cr Cs Cu Dy ErSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 10 <0.001 0.165 0.039 0.48 0.0193 0.98 0.0093 0.0034Q515695 10 <0.001 0.283 0.047 1.45 0.0264 0.97 0.0145 0.0067Q515572 10 <0.001 0.106 0.039 0.44 0.0231 0.43 0.0055 0.0024Q515581 10 <0.001 0.105 0.024 0.22 0.019 0.46 0.0049 0.0016Q515653 10 0.001 0.183 0.03 0.86 0.0316 0.63 0.0112 0.005Q515501 10 <0.001 0.124 0.029 0.34 0.0202 0.36 0.0066 0.0036Q515665 10 <0.001 0.161 0.01 0.72 0.0222 0.52 0.0078 0.0024ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07Eu Fe Ga Gd Ge Hf Hg Ho ISAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.0027 166 <0.05 0.0125 <0.005 0.0272 0.02 0.0016 0.13Q515695 0.0048 147 <0.05 0.0215 <0.005 0.0475 0.02 0.0024 0.13Q515572 0.002 205 <0.05 0.0071 <0.005 0.0162 0.02 0.0009 0.12Q515581 0.0014 78 <0.05 0.0058 <0.005 0.0202 0.02 0.0007 <0.05Q515653 0.0034 98 <0.05 0.016 <0.005 0.0251 0.01 0.0021 0.15Q515501 0.002 126 <0.05 0.0086 <0.005 0.0154 0.01 0.0012 0.07Q515665 0.0031 43 <0.05 0.0115 <0.005 0.0182 0.02 0.001 0.06ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07In K La Li Lu Mg Mn Mo NbSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.001 50 0.0842 0.12 0.0005 34.2 0.3 0.162 0.401Q515695 <0.001 48 0.136 0.09 0.0009 43.4 0.28 0.088 0.759Q515572 0.001 38 0.055 0.19 0.0005 13.4 0.47 0.13 0.11Q515581 <0.001 56 0.0499 0.15 0.0003 6.9 0.22 0.091 0.0577Q515653 <0.001 74 0.0805 0.21 0.0006 14.6 0.32 0.071 0.104Q515501 <0.001 51 0.0739 0.12 0.0004 9.6 0.24 0.1 0.0565Q515665 0.001 32 0.0751 0.07 0.0004 6.6 0.12 0.01 0.123D.9 Sequential Leach 502ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07Nd Ni Pb Pr Rb Re Sb Se SmSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.0743 0.44 0.014 0.0203 0.207 0.0002 0.0468 0.03 0.0147Q515695 0.124 0.5 0.017 0.0334 0.247 <0.0002 0.0388 <0.02 0.0237Q515572 0.043 0.23 0.016 0.0113 0.192 <0.0002 0.0372 <0.02 0.0103Q515581 0.0418 0.28 0.007 0.0111 0.214 <0.0002 0.0364 <0.02 0.0086Q515653 0.0963 0.28 0.018 0.0234 0.329 <0.0002 0.0376 <0.02 0.0216Q515501 0.0574 0.26 0.009 0.0153 0.18 <0.0002 0.0384 <0.02 0.0122Q515665 0.0739 0.13 0.006 0.021 0.155 <0.0002 0.0372 <0.02 0.0177ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07Sn Sr Ta Tb Te Th Ti Tl TmSAMPLE ppm ppm ppm ppm ppm ppm ppm ppm ppmQ515576 0.021 0.071 0.025 0.0017 <0.005 0.486 25.5 0.004 0.0006Q515695 0.034 0.09 0.037 0.003 <0.005 0.738 39.7 0.004 0.001Q515572 0.021 0.154 0.009 0.001 <0.005 0.347 26.9 0.002 0.0006Q515581 0.011 0.063 0.007 0.0007 <0.005 0.427 9.19 0.003 0.0003Q515653 0.027 0.098 0.009 0.0025 <0.005 0.392 25.5 0.004 0.0007Q515501 0.014 0.064 0.007 0.0014 <0.005 0.309 11.35 0.002 0.0005Q515665 0.053 0.047 0.007 0.0014 <0.005 0.448 27.1 0.002 0.0005ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 ME-MS07 pH-MS07U V W Y Yb Zn Zr Final pHSAMPLE ppm ppm ppm ppm ppm ppm ppm UnityQ515576 0.0226 0.29 0.061 0.0325 0.0042 0.28 0.918 10.8Q515695 0.0527 0.33 0.043 0.055 0.0053 0.23 1.565 10.7Q515572 0.0188 0.33 0.038 0.0204 0.0026 0.18 0.582 10.7Q515581 0.0105 0.14 0.057 0.0156 0.0019 0.11 0.621 11.2Q515653 0.0406 0.23 0.036 0.0434 0.004 0.2 0.828 10.9Q515501 0.0202 0.25 0.049 0.0262 0.0022 0.16 0.535 11.1Q515665 0.0327 0.13 0.026 0.0257 0.0032 0.07 0.528 10.8D.9 Sequential Leach 503ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41Ag Al As Au B Ba Be Bi CaSAMPLE ppm % ppm ppm ppm ppm ppm ppm %Q515576 0.01 0.39 2.1 <0.2 <10 30 0.11 0.03 0.03Q515695 0.02 0.5 1.2 <0.2 <10 30 0.13 0.04 0.04Q515572 0.01 0.21 1.2 <0.2 <10 10 0.07 0.04 0.02Q515581 0.02 0.3 1 <0.2 <10 20 0.1 0.02 0.03Q515653 0.02 0.39 1 <0.2 <10 20 0.12 0.04 0.03Q515501 0.01 0.26 0.8 <0.2 <10 20 0.13 0.03 0.02Q515665 0.01 0.38 0.9 <0.2 <10 20 0.12 0.05 0.03ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41Cd Ce Co Cr Cs Cu Fe Ga GeSAMPLE ppm ppm ppm ppm ppm ppm % ppm ppmQ515576 0.01 22.7 2.2 17 0.73 6.1 0.61 1.75 0.06Q515695 0.01 29 2.8 18 0.94 6.4 0.62 2.2 0.06Q515572 <0.01 21 1.4 9 0.4 4 0.37 1.17 <0.05Q515581 <0.01 29.6 1.6 13 0.61 4.5 0.47 1.4 0.05Q515653 <0.01 29 1.9 15 0.74 3.9 0.48 1.8 0.05Q515501 <0.01 26.3 1.4 10 0.54 2.8 0.36 1.19 <0.05Q515665 0.01 27.5 1.7 14 0.64 3.4 0.42 1.79 0.05ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41Hf Hg In K La Li Mg Mn MoSAMPLE ppm ppm ppm % ppm ppm % ppm ppmQ515576 0.06 <0.01 <0.005 0.1 11.2 13.1 0.28 50 0.21Q515695 0.04 <0.01 <0.005 0.1 14.3 13.5 0.35 54 0.15Q515572 0.05 <0.01 <0.005 0.04 10.6 8.7 0.11 27 0.13Q515581 0.08 <0.01 <0.005 0.09 14.4 10.7 0.16 40 0.11Q515653 0.04 <0.01 <0.005 0.09 14.3 13.1 0.2 45 0.13Q515501 0.07 <0.01 <0.005 0.08 12.9 9.4 0.14 33 0.09Q515665 0.03 <0.01 <0.005 0.06 13.6 12.7 0.18 40 0.1ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41Na Nb Ni P Pb Rb Re S SbSAMPLE % ppm ppm ppm ppm ppm ppm % ppmQ515576 0.08 0.36 12.1 90 1 7.2 <0.001 <0.01 <0.05Q515695 0.14 0.65 16.9 190 1.3 8.7 <0.001 0.01 <0.05Q515572 0.05 0.14 5 110 1 3.1 <0.001 <0.01 <0.05Q515581 0.04 0.13 5.8 90 1.1 5.2 <0.001 <0.01 <0.05Q515653 0.08 0.27 7.5 210 1.3 6.5 <0.001 0.01 <0.05Q515501 0.04 0.12 5.1 60 1.7 4.4 <0.001 <0.01 <0.05Q515665 0.11 0.37 6.9 160 1.3 4.5 <0.001 0.01 <0.05D.9 Sequential Leach 504ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41Sc Se Sn Sr Ta Te Th Ti TlSAMPLE ppm ppm ppm ppm ppm ppm ppm % ppmQ515576 1.2 0.2 0.2 2.6 <0.01 0.01 2.9 0.034 0.04Q515695 1.3 <0.2 0.2 3.6 <0.01 <0.01 4.2 0.037 0.07Q515572 0.6 <0.2 <0.2 2.3 <0.01 <0.01 2.9 0.02 0.03Q515581 0.9 0.2 <0.2 2.4 <0.01 <0.01 4.1 0.028 0.04Q515653 1.2 0.2 0.2 2.6 <0.01 <0.01 3.8 0.032 0.04Q515501 0.8 <0.2 <0.2 1.8 <0.01 <0.01 3.7 0.024 0.03Q515665 1 0.2 0.2 2.7 <0.01 <0.01 3.5 0.032 0.04ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41 ME-MS41U V W Y Zn ZrSAMPLE ppm ppm ppm ppm ppm ppmQ515576 0.52 15 0.1 1.62 12 2.5Q515695 0.7 13 0.09 1.96 15 1.8Q515572 0.53 9 0.15 1.48 6 1.8Q515581 0.65 11 0.06 2 8 2.6Q515653 0.68 11 0.08 1.93 11 1.7Q515501 0.77 8 0.14 1.83 7 2.3Q515665 0.57 10 0.33 1.83 10 1.2D.9 Sequential Leach 505ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Ag Al As Ba Be Bi Ca Cd CeSAMPLE ppm % ppm ppm ppm ppm % ppm ppmQ515576 0.04 5.78 <0.2 390 1.06 0.05 1.12 0.04 13.3Q515695 0.02 6.24 1 510 1.15 0.05 1.08 0.04 17.95Q515572 0.03 5.48 <0.2 410 1.03 0.06 1.07 0.04 15.65Q515581 0.03 5.92 0.2 400 1.19 0.05 1.17 0.05 17.25Q515653 0.03 6.17 0.5 480 1.38 0.04 1.15 0.03 20.5Q515501 0.03 5.77 0.2 390 1.22 0.04 1.14 0.04 15.85Q515665 0.02 5.91 0.2 420 1.25 0.04 1.15 0.04 19.15ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Co Cr Cs Cu Fe Ga Ge Hf InSAMPLE ppm ppm ppm ppm % ppm ppm ppm ppmQ515576 1.5 24 1.45 4.5 0.49 10.15 0.14 2.5 0.011Q515695 1.9 46 2.3 2 0.58 11.95 0.15 3.6 0.017Q515572 1.4 13 1.18 2.3 0.42 9.75 0.14 2.2 0.012Q515581 1.4 15 1.24 1.1 0.45 10.35 0.2 2.7 0.008Q515653 1.6 21 1.48 1.1 0.5 11.05 0.18 3.2 0.014Q515501 1.3 14 1.2 1 0.41 9.85 0.19 2.1 0.012Q515665 1.5 20 1.34 1.1 0.47 10.45 0.19 3.1 0.012ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61K La Li Mg Mn Mo Na Nb NiSAMPLE % ppm ppm % ppm ppm % ppm ppmQ515576 1.76 6.2 8.7 0.21 147 0.65 2.23 5.3 6.8Q515695 2.13 8.3 10.7 0.26 143 0.2 2.18 11.7 6.1Q515572 1.75 7.2 8.7 0.17 118 0.2 2.18 2.9 3.5Q515581 1.76 8 8.7 0.19 134 0.11 2.4 2.9 3.6Q515653 2.07 9.6 10.9 0.22 134 0.09 2.33 4.4 4.3Q515501 1.77 7.3 8.9 0.18 132 0.13 2.33 2.3 3.5Q515665 1.79 8.8 11.3 0.21 135 0.11 2.3 3.8 4ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61P Pb Rb Re S Sb Sc Se SnSAMPLE ppm ppm ppm ppm % ppm ppm ppm ppmQ515576 120 12.8 52.2 0.002 <0.01 0.11 3.3 <1 0.6Q515695 130 10.5 68.4 <0.002 <0.01 0.13 5 1 1Q515572 120 10.6 52.9 <0.002 <0.01 0.09 2.7 <1 0.4Q515581 130 11.1 50.2 <0.002 <0.01 0.08 3 <1 0.5Q515653 140 10.9 60.2 <0.002 <0.01 0.09 4.1 <1 0.8Q515501 130 11 49.9 <0.002 <0.01 0.08 2.7 <1 0.5Q515665 130 10.8 52.7 <0.002 0.01 0.08 3.6 1 0.6D.9 Sequential Leach 506ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61 ME-MS61Sr Ta Te Th Ti Tl U V WSAMPLE ppm ppm ppm ppm % ppm ppm ppm ppmQ515576 278 0.4 <0.05 1.25 0.142 0.27 0.6 19 0.3Q515695 268 0.89 <0.05 1.95 0.218 0.36 0.8 32 0.7Q515572 268 0.25 <0.05 1.43 0.112 0.28 0.5 13 0.3Q515581 298 0.26 <0.05 1.59 0.126 0.27 0.6 15 0.2Q515653 282 0.45 <0.05 2.18 0.169 0.32 0.7 21 0.4Q515501 288 0.21 <0.05 1.43 0.106 0.24 0.5 13 0.2Q515665 289 0.39 <0.05 1.8 0.163 0.28 0.7 18 0.5ME-MS61 ME-MS61 ME-MS61Y Zn ZrSAMPLE ppm ppm ppmQ515576 3.9 11 94.1Q515695 4.9 11 138.5Q515572 3.7 7 86.2Q515581 3.9 7 103.5Q515653 4.5 9 118Q515501 3.6 7 74.4Q515665 4.3 8 116.5D.9 Sequential Leach 507D.10 X-ray Diffraction Raw Data 010003000600010000200003000040000Counts (Square Root)10 20 30 40 50 60 70 802Theta (Coupled TwoTheta/Theta) WL=1.78897Q515501Quartz, syn - Si O2Biotite-1M, synK ( Fe2.554 Al0.446 ) ( ( Al1.55 Si2.45 ) O10 ) ( O H )2Albite, calcian, ordered( Na , Ca ) Al ( Si , Al )3 O8OrthoclaseK Al Si3 O8Tetraferriphlogopite, synK Mg3 Fe Si3 O10 ( O H )2Vermiculite-2MMgx ( Mg , Fe )3 ( Si , Al )4 O10 ( O H )2 ·4 H2 OClinochlore-1MIIb, ferroan( Mg , Fe )6 ( Si , Al )4 O10 ( O H )8Magnesio-hornblende, ferroanCa2 ( Mg , Fe +2 )4 Al ( Si7 Al ) O22 ( O H , F )2Illite-1MK0.78 Mg0.34 Al2.34 Si3.35 O10 ( O H )2 ( H2 O )0.15508 010003000600010000200003000040000Counts (Square Root)10 20 30 40 50 60 70 802Theta (Coupled TwoTheta/Theta) WL=1.78897Q515572Quartz, synSi O2Biotite-1M, synK ( Fe2.554 Al0.446 ) ( ( Al1.55 Si2.45 ) O10 ) ( O H )2Albite, calcian, ordered( Na , Ca ) Al ( Si , Al )3 O8OrthoclaseK Al Si3 O8Tetraferriphlogopite, synK Mg3 Fe Si3 O10 ( O H )2Vermiculite-2MMgx ( Mg , Fe )3 ( Si , Al )4 O10 ( O H )2 ·4 H2 OClinochlore-1MIIb, ferroan( Mg , Fe )6 ( Si , Al )4 O10 ( O H )8Magnesio-hornblende, ferroanCa2 ( Mg , Fe +2 )4 Al ( Si7 Al ) O22 ( O H , F )2Illite-1MK0.78 Mg0.34 Al2.34 Si3.35 O10 ( O H )2 ( H2 O )0.15509 010003000600010000200003000040000Counts (Square Root)10 20 30 40 50 60 70 802Theta (Coupled TwoTheta/Theta) WL=1.78897Q515576Quartz, synSi O2Biotite-1M, synK ( Fe2.554 Al0.446 ) ( ( Al1.55 Si2.45 ) O10 ) ( O H )2Albite, calcian, ordered( Na , Ca ) Al ( Si , Al )3 O8OrthoclaseK Al Si3 O8Tetraferriphlogopite, synK Mg3 Fe Si3 O10 ( O H )2Vermiculite-2MMgx ( Mg , Fe )3 ( Si , Al )4 O10 ( O H )2 ·4 H2 OClinochlore-1MIIb, ferroan( Mg , Fe )6 ( Si , Al )4 O10 ( O H )8Magnesio-hornblende, ferroanCa2 ( Mg , Fe +2 )4 Al ( Si7 Al ) O22 ( O H , F )2Nontronite-15ACa0.1 Fe2 ( Si , Al )4 O10 ( O H )2 ·4 H2 OIllite-1MK0.78 Mg0.34 Al2.34 Si3.35 O10 ( O H )2 ( H2 O )0.15510 010003000600010000200003000040000Counts (Square Root)10 20 30 40 50 60 70 802Theta (Coupled TwoTheta/Theta) WL=1.78897Q515581Quartz, synSi O2Biotite-1M, synK ( Fe2.554 Al0.446 ) ( ( Al1.55 Si2.45 ) O10 ) ( O H )2Albite, calcian, ordered( Na , Ca ) Al ( Si , Al )3 O8OrthoclaseK Al Si3 O8Tetraferriphlogopite, synK Mg3 Fe Si3 O10 ( O H )2Vermiculite-2MMgx ( Mg , Fe )3 ( Si , Al )4 O10 ( O H )2 ·4 H2 OClinochlore-1MIIb, ferroan( Mg , Fe )6 ( Si , Al )4 O10 ( O H )8Magnesio-hornblende, ferroanCa2 ( Mg , Fe +2 )4 Al ( Si7 Al ) O22 ( O H , F )2Nontronite-15ACa0.1 Fe2 ( Si , Al )4 O10 ( O H )2 ·4 H2 OandalusiteAl2 ( Si O4 ) OIllite-1MK0.78 Mg0.34 Al2.34 Si3.35 O10 ( O H )2 ( H2 O )0.15511 010003000600010000200003000040000Counts (Square Root)10 20 30 40 50 60 70 802Theta (Coupled TwoTheta/Theta) WL=1.78897Q515653Quartz, synSi O2Biotite-1M, synK ( Fe2.554 Al0.446 ) ( ( Al1.55 Si2.45 ) O10 ) ( O H )2Albite, calcian, ordered( Na , Ca ) Al ( Si , Al )3 O8OrthoclaseK Al Si3 O8Tetraferriphlogopite, synK Mg3 Fe Si3 O10 ( O H )2Vermiculite-2MMgx ( Mg , Fe )3 ( Si , Al )4 O10 ( O H )2 ·4 H2 OClinochlore-1MIIb, ferroan( Mg , Fe )6 ( Si , Al )4 O10 ( O H )8Magnesio-hornblende, ferroanCa2 ( Mg , Fe +2 )4 Al ( Si7 Al ) O22 ( O H , F )2Nontronite-15ACa0.1 Fe2 ( Si , Al )4 O10 ( O H )2 ·4 H2 OandalusiteAl2 ( Si O4 ) OIllite-1MK0.78 Mg0.34 Al2.34 Si3.35 O10 ( O H )2 ( H2 O )0.15512 010003000600010000200003000040000Counts (Square Root)10 20 30 40 50 60 70 802Theta (Coupled TwoTheta/Theta) WL=1.78897Q515665Quartz, synSi O2Biotite-1M, synK ( Fe2.554 Al0.446 ) ( ( Al1.55 Si2.45 ) O10 ) ( O H )2Albite, calcian, ordered( Na , Ca ) Al ( Si , Al )3 O8OrthoclaseK Al Si3 O8Tetraferriphlogopite, synK Mg3 Fe Si3 O10 ( O H )2Vermiculite-2MMgx ( Mg , Fe )3 ( Si , Al )4 O10 ( O H )2 ·4 H2 OClinochlore-1MIIb, ferroan( Mg , Fe )6 ( Si , Al )4 O10 ( O H )8Magnesio-hornblende, ferroanCa2 ( Mg , Fe +2 )4 Al ( Si7 Al ) O22 ( O H , F )2Nontronite-15ACa0.1 Fe2 ( Si , Al )4 O10 ( O H )2 ·4 H2 OandalusiteAl2 Si O5Illite-1MK0.78 Mg0.34 Al2.34 Si3.35 O10 ( O H )2 ( H2 O )0.15513 010003000600010000200003000040000Counts (Square Root)10 20 30 40 50 60 70 802Theta (Coupled TwoTheta/Theta) WL=1.78897Q515695Quartz, synSi O2Biotite-1M, synK ( Fe2.554 Al0.446 ) ( ( Al1.55 Si2.45 ) O10 ) ( O H )2Albite, calcian, ordered( Na , Ca ) Al ( Si , Al )3 O8OrthoclaseK Al Si3 O8Tetraferriphlogopite, synK Mg3 Fe Si3 O10 ( O H )2Clinochlore-1MIIb, ferroan( Mg , Fe )6 ( Si , Al )4 O10 ( O H )8Magnesio-hornblende, ferroanCa2 ( Mg , Fe +2 )4 Al ( Si7 Al ) O22 ( O H , F )2Nontronite-15ACa0.1 Fe2 ( Si , Al )4 O10 ( O H )2 ·4 H2 OandalusiteAl2 ( Si O4 ) OIllite-1MK0.78 Mg0.34 Al2.34 Si3.35 O10 ( O H )2 ( H2 O )0.15514Sample ID Sample Type Site C001 LA C002 LA C003 LB C004 LA C005 LB C006 LB C007 LA C008 LB C009 LB C010 LB C011 LA C012 LB C013 LBA C014 LB C015 LAR C016 LB C017 LBQ515501 Soil 26 46 341 26 4 17 15 2 70 8 21 4 10 13 14 -1 14 17Q515502 Soil 27 44 337 27 3 16 14 1 47 6 17 3 7 12 8 -1 8 7Q515503 Soil 28 60 444 84 8 16 17 16 828 118 59 64 103 17 170 3 170 165Q515504 Soil 29 101 996 128 11 38 17 4 78 8 17 7 8 2 6 -1 6 7Q515505 Soil 30 40 350 38 3 13 12 2 31 4 14 2 4 1 3 -1 3 3Q515505-R Duplicate 50 385 41 3 17 13 2 31 4 11 2 4 8 3 -1 3 3Q515506 Soil 31 43 42 18 4 9 8 2 32 4 11 4 5 20 8 -1 8 7Q515507 Soil 125 48 282 14 3 8 9 3 63 9 17 13 12 23 27 -1 27 25Q515508 Soil 124 48 369 22 3 10 12 3 58 8 16 6 10 6 15 -1 15 14Q515509 Soil 123 50 393 21 4 12 11 3 56 8 15 7 10 13 16 -1 16 14Q515510 Soil 122 46 398 38 3 14 13 2 47 6 13 4 7 6 9 -1 9 9Q515511 Soil 121 46 378 34 3 14 12 2 40 5 13 3 5 3 6 -1 6 6Q515512 Soil 120 45 347 29 3 12 11 2 38 5 12 3 5 2 7 -1 7 7Q515513 Soil 119 46 432 33 5 12 10 2 32 4 13 2 4 15 5 -1 5 4Q515514 Soil 118 45 361 35 3 16 15 2 49 6 17 3 7 13 7 -1 7 7Q515515 Soil 117 45 346 36 3 19 13 2 63 7 18 4 8 6 8 -1 8 8Q515516 Soil 116 42 372 28 3 14 13 2 54 7 14 5 9 4 11 -1 11 10Q515517 Soil 14 40 258 23 2 7 6 1 17 2 9 1 2 1 2 -1 2 2Q515518 Soil 15 45 288 30 2 10 10 2 30 4 14 3 4 3 5 -1 5 5Q515519 Soil 13 46 371 31 5 13 9 2 25 3 11 3 3 9 3 -1 3 3Q515520 Soil 12 56 432 69 5 26 21 4 82 11 18 7 12 11 10 -1 10 9Q515520-R Duplicate 65 452 67 5 30 19 4 90 12 23 6 13 4 12 -1 12 11Q515521 Soil 11 41 313 25 3 10 8 2 28 4 11 3 4 2 5 -1 5 4Q515522 Soil 10 44 321 32 3 14 14 2 46 6 16 5 7 4 8 -1 8 7Q515523 Soil 9 48 309 33 2 16 15 2 52 7 12 5 8 4 9 -1 9 8Q515524 Soil 8 45 322 33 3 12 11 2 31 4 13 2 4 2 4 -1 4 4Q515525 Soil 7 41 274 27 2 10 8 1 20 2 10 2 3 1 3 -1 3 2Q515526 Soil 115 44 337 32 3 12 9 2 28 4 12 2 4 2 5 -1 5 4Q515527 Soil 114 51 440 119 4 40 15 2 76 8 15 3 7 12 6 -1 6 5Q515528 Soil 113 42 286 24 3 11 6 1 17 2 8 9 2 14 2 -1 2 2Q515529 Soil 112 75 1600 126 52 100 20 90 500 60 36 186 53 172 61 12 61 49Q515530 Soil 6 50 396 145 4 24 16 2 36 4 15 2 3 2 2 -1 2 2Q515531 Soil 5 40 271 32 4 9 7 2 19 2 8 2 2 7 2 -1 2 2Q515551 Soil 77 117 984 167 14 30 11 4 50 5 14 5 5 5 3 -1 3 4Q515552 Soil 78 100 944 247 11 40 15 4 81 8 16 6 7 5 6 -1 6 6Q515553 Soil 79 78 668 127 7 28 15 3 57 6 18 4 6 1 4 -1 4 5Q515554 Soil 95 40 263 37 3 11 8 1 17 2 8 2 2 7 2 -1 2 2Q515554-R Duplicate 37 241 25 2 9 6 1 16 2 9 2 2 2 2 -1 2 2Q515555 Soil 94 36 264 29 2 9 8 2 22 3 12 2 3 2 3 -1 3 3D.11 Spatiotemporal Geochemical Hydrocarbons515Sample ID Sample Type Site C001 LA C002 LA C003 LB C004 LA C005 LB C006 LB C007 LA C008 LB C009 LB C010 LB C011 LA C012 LB C013 LBA C014 LB C015 LAR C016 LB C017 LBD.11 Spatiotemporal Geochemical HydrocarbonsQ515556 Soil 93 48 408 51 4 19 16 3 40 5 10 4 6 4 5 -1 5 5Q515557 Soil 92 33 199 7 -1 3 2 -1 2 -1 2 -1 -1 -1 -1 -1 -1 -1Q515558 Soil 91 39 305 33 3 12 10 2 28 4 10 2 4 2 4 -1 4 4Q515559 Soil 90 43 334 29 3 10 9 2 34 4 12 3 5 2 6 -1 6 6Q515560 Soil 89 44 400 67 5 21 13 1 55 6 13 4 6 4 6 -1 6 6Q515561 Soil 88 48 412 96 4 36 12 2 73 8 16 3 7 3 6 -1 6 5Q515562 Soil 87 45 318 34 3 14 11 2 54 7 15 4 8 3 10 -1 10 9Q515563 Soil 86 69 357 188 10 16 17 4 258 19 31 10 20 8 11 -1 11 13Q515564 Soil 85 46 460 106 5 60 16 2 154 13 19 3 14 3 9 -1 9 10Q515565 Soil 84 48 536 72 7 33 13 3 81 10 18 6 9 5 9 -1 9 8Q515566 Soil 83 60 800 153 10 17 18 8 229 24 28 16 22 4 16 -1 16 13Q515567 Soil 82 50 664 113 10 15 16 7 212 21 27 16 20 5 13 -1 13 13Q515568 Soil 81 47 460 77 5 36 17 4 79 8 16 6 8 5 6 -1 6 5Q515569 Soil 80 43 350 42 5 25 25 3 88 11 20 5 11 3 10 -1 10 9Q515569-R Duplicate 40 34 33 3 16 15 2 54 7 13 2 8 2 7 -1 7 6Q515570 Soil 96 75 2190 134 103 141 26 150 708 90 65 212 91 190 92 20 92 74Q515571 Soil 97 56 652 286 7 126 19 3 220 23 22 6 17 4 10 -1 10 8Q515572 Soil 98 38 303 33 3 11 8 1 19 3 9 1 3 1 2 -1 2 2Q515573 Soil 99 54 856 295 9 25 26 5 292 29 34 9 24 13 13 -1 13 11Q515574 Soil 100 53 796 235 9 75 15 3 103 10 17 7 8 6 5 -1 5 4Q515575 Soil 101 51 464 90 6 40 18 3 106 13 24 5 12 6 10 -1 10 9Q515576 Soil 102 64 936 388 11 21 2 6 372 32 38 11 28 10 15 -1 15 14Q515577 Soil 103 47 396 82 3 19 14 2 30 3 14 3 3 2 2 -1 2 2Q515578 Soil 104 36 208 12 2 5 3 -1 9 1 6 -1 2 -1 1 -1 1 1Q515579 Soil 105 41 263 39 2 9 9 1 22 3 11 2 3 4 2 -1 2 2Q515580 Soil 106 37 214 18 2 6 5 -1 13 2 8 -1 2 -1 2 -1 2 2Q515581 Soil 107 39 295 27 3 12 14 2 56 8 16 4 9 3 10 -1 10 10Q515582 Soil 108 37 203 7 1 2 1 -1 6 4 3 -1 1 -1 2 -1 2 2Q515583 Field Duplicate 108b 39 258 24 3 9 8 2 35 5 14 5 6 4 7 -1 7 6Q515584 Soil 109 41 301 32 3 12 13 2 49 7 18 4 7 4 9 -1 9 8Q515584-R Duplicate 40 290 34 3 12 12 2 46 6 14 4 7 3 7 -1 7 7Q515585 Soil 110 38 302 25 3 12 11 2 54 7 17 5 9 4 13 -1 13 12Q515586 Soil 111 41 296 53 3 15 12 1 28 3 11 2 4 2 3 -1 3 3Q515587 Soil 127 38 269 26 3 13 11 3 51 7 15 5 8 5 9 -1 9 9Q515588 Soil 126 39 226 19 2 7 6 1 21 3 14 1 4 1 4 -1 4 4Q515589 Field Duplicate 126b 43 295 37 2 12 9 2 27 3 13 2 3 1 3 -1 3 3Q515590 Soil 16 41 304 38 3 12 11 2 32 4 13 2 4 2 4 -1 4 4Q515591 Soil 17 40 382 24 3 12 12 3 73 9 15 7 11 6 14 -1 14 14Q515592 Soil 18 42 334 29 3 12 13 2 47 6 13 4 8 4 8 -1 8 7516Sample ID Sample Type Site C001 LA C002 LA C003 LB C004 LA C005 LB C006 LB C007 LA C008 LB C009 LB C010 LB C011 LA C012 LB C013 LBA C014 LB C015 LAR C016 LB C017 LBD.11 Spatiotemporal Geochemical HydrocarbonsQ515593 Field Duplicate 18b 40 345 38 3 16 15 2 50 6 13 3 7 5 7 -1 7 6Q515594 Soil 19 39 313 39 3 14 11 1 28 3 14 2 4 4 3 -1 3 3Q515595 Soil 20 40 281 47 2 20 17 2 45 6 16 2 6 3 5 -1 5 4Q515596 Soil 21 33 202 15 1 6 5 -1 9 1 5 -1 2 2 -1 -1 -1 -1Q515597 Soil 22 42 412 98 4 27 16 3 44 5 14 4 5 2 3 -1 3 3Q515598 Soil 23 38 286 37 3 12 10 2 22 2 11 4 3 2 2 -1 2 2Q515599 Soil 24 35 238 42 2 18 18 2 44 6 15 2 6 2 4 -1 4 4Q515599-R Duplicate 39 261 42 2 20 15 2 52 7 18 3 7 2 5 -1 5 4Q515600 Soil 25 37 254 40 2 16 15 1 42 5 15 2 6 2 5 -1 5 5Q515651 Soil 32 39 324 31 3 14 13 2 38 5 14 4 5 3 5 -1 5 5Q515652 Soil 33 40 360 58 3 20 16 2 46 5 11 3 6 2 6 -1 6 5Q515653 Soil 34 31 195 10 1 6 2 -1 5 -1 3 -1 1 -1 -1 -1 -1 -1Q515654 Soil 35 38 250 39 2 12 10 1 21 2 10 2 2 -1 2 -1 2 2Q515655 Field Duplicate 35b 39 273 40 3 13 9 1 18 2 9 3 2 2 1 -1 1 1Q515657 Soil 36 50 379 84 9 21 14 1 27 3 13 2 3 1 1 -1 1 1Q515658 Soil 37 38 337 43 4 13 10 2 25 3 9 3 3 2 2 -1 2 2Q515659 Soil 38 42 367 74 4 20 17 2 38 5 12 3 5 1 3 -1 3 3Q515660 Soil 39 97 1070 188 14 51 15 4 95 9 18 5 8 4 5 -1 5 5Q515661 Soil 40 134 135 116 19 38 21 4 69 6 15 5 6 4 4 -1 4 4Q515662 Soil 41 39 258 34 2 12 10 2 24 3 10 2 3 2 3 -1 3 2Q515663 Soil 42 43 286 35 3 14 13 2 48 6 12 2 6 2 7 -1 7 6Q515664 Soil 43 54 311 64 3 25 13 2 41 5 16 2 4 17 4 -1 4 4Q515664-R Duplicate 55 325 64 3 27 21 2 54 6 17 2 6 9 5 -1 5 5Q515665 Soil 44 48 311 33 3 12 11 2 28 3 10 3 4 2 3 -1 3 3Q515666 Soil 45 68 620 61 6 28 28 5 72 9 12 10 10 3 8 -1 8 7Q515667 Soil 46 73 720 93 7 33 13 3 60 7 13 5 6 2 4 -1 4 4Q515668 Soil 47 84 816 83 8 31 17 3 55 6 14 4 6 1 4 -1 4 4Q515669 Soil 63 69 768 100 6 38 16 3 71 8 17 5 7 4 5 -1 5 5Q515670 Soil 62 59 444 48 5 20 16 3 40 5 11 3 5 5 4 -1 4 4Q515671 Soil 61 49 374 60 4 21 18 2 36 4 13 4 5 3 3 -1 3 3Q515672 Soil 60 52 340 23 4 9 8 2 30 4 14 5 5 7 5 -1 5 5Q515673 Soil 59 36 234 23 2 8 8 1 20 3 13 2 3 4 2 -1 2 3Q515674 Soil 58 58 420 58 5 31 13 2 80 9 20 4 9 14 10 -1 10 10Q515675 Soil 57 58 334 35 4 16 16 3 56 7 14 6 7 9 8 -1 8 7Q515676 Soil 56 64 368 48 4 13 11 1 21 2 10 1 2 1 1 -1 1 2Q515678 Soil 54 108 676 173 6 38 18 3 64 7 13 3 6 3 4 -1 4 4Q515679 Field Duplicate 54b 111 868 196 11 54 14 4 104 10 21 7 9 1 6 -1 6 6Q515679-R Duplicate 111 872 198 12 16 17 4 106 10 22 5 9 5 6 -1 6 7Q515680 Soil 53 60 416 57 4 20 18 2 37 5 13 3 5 6 3 -1 3 4517Sample ID Sample Type Site C001 LA C002 LA C003 LB C004 LA C005 LB C006 LB C007 LA C008 LB C009 LB C010 LB C011 LA C012 LB C013 LBA C014 LB C015 LAR C016 LB C017 LBD.11 Spatiotemporal Geochemical HydrocarbonsQ515681 Soil 52 60 354 58 4 18 15 2 31 4 10 3 4 7 3 -1 3 3Q515682 Soil 51 58 480 135 5 30 13 2 44 5 14 2 4 3 3 -1 3 3Q515683 Soil 50 54 364 64 3 16 13 1 24 3 11 1 3 5 2 -1 2 2Q515685 Soil 49b 54 351 44 4 13 10 1 21 2 10 1 2 9 2 -1 2 2Q515686 Soil 48 56 416 46 5 23 21 3 58 8 17 5 9 1 7 -1 7 6Q515687 Soil 64 45 349 44 4 30 13 3 111 12 16 7 13 6 13 -1 13 12Q515688 Soil 65 54 468 70 5 28 14 3 60 7 12 5 6 4 5 -1 5 4Q515689 Soil 66 54 343 52 3 17 13 2 27 3 12 2 3 9 3 -1 3 2Q515690 Soil 67 64 516 52 6 17 13 2 28 3 14 3 3 21 3 -1 3 3Q515691 Soil 68 54 488 55 6 23 18 2 56 7 12 5 7 4 6 -1 6 6Q515692 Soil 69 54 404 78 4 23 17 2 33 4 11 2 3 4 2 -1 2 2Q515693 Soil 70 70 712 112 13 25 17 2 41 4 12 2 4 2 3 -1 3 3Q515695 Soil 72 106 4240 235 66 142 23 37 282 31 28 29 24 26 15 3 15 11Q515695-R Duplicate 108 4280 245 66 26 27 36 277 31 28 36 22 13 14 3 14 10Q515696 Field Duplicate 72b 116 6240 226 202 31 33 208 904 102 63 206 87 175 76 12 76 62Q515697 Soil 73 49 297 38 3 15 15 2 42 6 10 4 7 4 6 -1 6 6Q515698 Soil 74 46 311 43 3 14 12 2 30 3 10 2 4 5 3 -1 3 3Q515699 Soil 75 52 300 52 3 24 18 2 48 5 10 2 5 8 4 -1 4 5Q515700 Soil 76 51 316 43 4 16 12 2 27 3 12 2 4 2 2 -1 2 3LMB-QA 40 223 7 2 1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1LMB-QA 40 221 10 2 1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1LMB-QA 37 213 13 2 1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1LMB-QA 36 208 11 2 1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1518Sample IDQ515501Q515502Q515503Q515504Q515505Q515505-RQ515506Q515507Q515508Q515509Q515510Q515511Q515512Q515513Q515514Q515515Q515516Q515517Q515518Q515519Q515520Q515520-RQ515521Q515522Q515523Q515524Q515525Q515526Q515527Q515528Q515529Q515530Q515531Q515551Q515552Q515553Q515554Q515554-RQ515555C018 LB C019 LB C020 LA C021 LPH C022 LBA C023 LAR C024 LB C025 LAR C026 LBA C027 LB C028 ALK C029 HB C030 HB C031 HB C032 HB C033 HB C034 HB C035 LAR34 35 5 -1 3 -1 1 5 2 19 3 -1 5 4 -1 -1 -1 -115 15 3 -1 2 -1 -1 2 1 8 2 -1 2 1 -1 -1 -1 -1307 308 60 3 63 6 4 36 10 145 15 1 7 21 10 5 1 114 14 9 -1 9 -1 -1 3 1 6 2 1 1 1 -1 -1 -1 -17 7 2 -1 -1 -1 -1 2 -1 4 -1 -1 -1 1 -1 -1 -1 -17 7 2 -1 -1 -1 -1 2 -1 4 1 1 -1 1 -1 -1 -1 -114 14 6 -1 5 -1 -1 2 2 9 4 -1 2 2 -1 -1 -1 -148 48 28 2 6 2 2 6 6 28 9 -1 9 5 3 2 1 -127 27 12 -1 3 1 2 4 3 15 4 -1 4 3 2 1 -1 -128 28 12 -1 4 1 2 4 3 16 5 -1 4 3 2 1 -1 -117 17 6 -1 3 -1 -1 3 2 9 -1 -1 -1 2 1 -1 -1 -112 12 5 -1 2 -1 -1 2 1 6 4 -1 2 2 -1 -1 -1 -113 13 4 -1 3 -1 -1 2 2 7 6 -1 2 1 -1 -1 -1 -19 9 3 -1 2 -1 -1 2 1 5 2 -1 1 1 -1 -1 -1 -113 13 6 -1 2 -1 -1 2 2 7 2 -1 2 1 -1 -1 -1 -116 17 6 -1 3 -1 -1 3 2 8 2 -1 2 1 -1 -1 -1 -119 20 10 -1 2 -1 1 3 2 11 3 -1 3 -1 1 -1 -1 -14 4 2 -1 2 -1 -1 -1 -1 3 1 -1 -1 -1 -1 -1 -1 -19 9 6 -1 2 -1 -1 2 2 5 2 1 1 1 -1 -1 -1 -15 5 7 -1 -1 -1 -1 1 1 3 2 -1 -1 -1 -1 -1 -1 -116 17 12 -1 13 1 -1 3 2 8 3 -1 2 2 -1 -1 -1 -122 22 10 -1 2 1 -1 4 2 11 3 -1 -1 2 -1 -1 -1 -19 9 6 -1 2 -1 -1 2 1 5 2 -1 1 1 -1 -1 -1 -114 14 10 -1 3 1 -1 2 2 8 6 -1 2 1 -1 -1 -1 -116 17 10 -1 3 -1 -1 3 3 9 9 2 2 1 -1 -1 -1 -17 7 4 -1 1 -1 -1 1 1 4 -1 1 -1 1 -1 -1 -1 -15 5 2 -1 1 -1 -1 1 1 3 4 -1 -1 -1 -1 -1 -1 -18 9 3 -1 2 -1 -1 1 1 5 4 -1 1 1 -1 -1 -1 -111 11 3 -1 2 -1 -1 2 1 5 4 1 1 1 -1 -1 -1 -14 4 2 -1 2 -1 -1 -1 1 2 3 -1 -1 -1 -1 -1 -1 -191 91 226 15 230 18 3 11 10 39 56 -1 9 6 3 2 1 45 5 2 -1 -1 -1 -1 1 -1 2 -1 -1 -1 -1 -1 -1 -1 -14 4 2 -1 1 -1 -1 -1 1 2 1 -1 -1 -1 -1 -1 -1 -17 7 10 -1 11 -1 -1 1 1 3 2 -1 -1 -1 -1 -1 -1 -112 12 11 -1 11 -1 -1 2 1 6 3 -1 1 1 -1 -1 -1 -19 10 7 -1 8 -1 -1 2 1 5 1 1 -1 1 -1 -1 -1 -13 3 3 -1 3 -1 -1 -1 -1 2 1 -1 -1 -1 -1 -1 -1 -14 4 3 -1 4 -1 -1 1 -1 3 1 -1 -1 -1 -1 -1 -1 -15 6 5 -1 1 -1 -1 1 1 4 2 -1 -1 -1 -1 -1 -1 -1D.11 Spatiotemporal Geochemical Hydrocarbons519Sample IDQ515556Q515557Q515558Q515559Q515560Q515561Q515562Q515563Q515564Q515565Q515566Q515567Q515568Q515569Q515569-RQ515570Q515571Q515572Q515573Q515574Q515575Q515576Q515577Q515578Q515579Q515580Q515581Q515582Q515583Q515584Q515584-RQ515585Q515586Q515587Q515588Q515589Q515590Q515591Q515592C018 LB C019 LB C020 LA C021 LPH C022 LBA C023 LAR C024 LB C025 LAR C026 LBA C027 LB C028 ALK C029 HB C030 HB C031 HB C032 HB C033 HB C034 HB C035 LARD.11 Spatiotemporal Geochemical Hydrocarbons10 10 6 -1 6 -1 -1 2 1 6 2 1 1 1 -1 -1 -1 -11 1 2 -1 2 -1 -1 -1 -1 1 2 -1 -1 -1 -1 -1 -1 -17 7 3 -1 1 -1 -1 1 1 4 4 -1 -1 1 -1 -1 -1 -111 11 6 -1 2 -1 -1 2 1 6 4 -1 2 2 -1 -1 -1 -112 12 9 -1 2 -1 -1 2 2 7 2 -1 1 2 -1 -1 -1 -110 11 4 -1 1 -1 -1 2 1 5 2 1 1 1 -1 -1 -1 -117 17 8 -1 2 1 -1 3 2 10 7 2 2 -1 1 -1 -1 -129 29 20 1 2 -1 -1 6 2 13 3 3 -1 3 1 -1 -1 -123 23 4 -1 1 -1 -1 5 1 11 4 -1 -1 3 1 -1 -1 -115 15 8 -1 9 -1 -1 3 2 7 -1 -1 2 2 -1 -1 -1 -126 26 13 -1 14 1 -1 5 2 10 4 -1 2 2 -1 -1 -1 -127 27 12 -1 11 1 -1 5 2 12 3 3 -1 2 -1 -1 -1 -111 11 8 -1 9 -1 -1 2 2 6 2 -1 1 1 -1 -1 -1 -119 19 6 -1 1 -1 -1 4 2 9 2 -1 2 2 1 -1 -1 -113 13 3 -1 -1 -1 -1 3 1 7 -1 2 2 2 -1 -1 -1 -1134 134 194 12 198 26 2 20 12 61 67 -1 2 10 4 2 1 515 15 4 -1 -1 -1 -1 3 -1 5 2 -1 1 1 -1 -1 -1 -14 4 3 -1 -1 -1 -1 -1 -1 2 2 -1 -1 -1 -1 -1 -1 -123 23 9 -1 2 1 -1 4 2 8 4 -1 -1 2 -1 -1 -1 -18 8 12 -1 13 -1 -1 2 2 4 3 -1 -1 1 -1 -1 -1 -116 17 6 -1 7 1 -1 3 1 8 4 2 -1 2 -1 -1 -1 -130 30 14 -1 14 -1 -1 6 2 11 4 3 -1 2 -1 -1 -1 -14 4 4 -1 4 -1 -1 1 -1 2 1 -1 -1 -1 -1 -1 -1 -13 3 1 -1 -1 -1 -1 -1 -1 2 -1 -1 -1 -1 -1 -1 -1 -14 4 4 -1 -1 -1 -1 1 -1 3 1 -1 -1 -1 -1 -1 -1 -14 4 1 -1 -1 -1 -1 1 -1 3 2 1 -1 -1 -1 -1 -1 -119 19 7 -1 8 -1 -1 3 2 10 5 -1 -1 -1 -1 -1 -1 -14 4 2 -1 2 -1 -1 1 -1 4 -1 1 -1 1 -1 -1 -1 -112 13 10 -1 10 -1 -1 2 2 7 3 -1 2 2 -1 -1 -1 -116 16 9 -1 1 -1 -1 3 2 8 2 -1 2 2 -1 -1 -1 -114 14 8 -1 9 -1 -1 2 2 7 2 -1 -1 1 -1 -1 -1 -124 24 10 -1 11 -1 -1 4 2 14 3 -1 -1 -1 1 -1 -1 -15 5 4 -1 -1 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -117 17 9 -1 2 -1 -1 3 2 10 3 -1 2 2 -1 -1 -1 -18 8 3 -1 3 -1 -1 2 1 5 3 1 1 1 -1 -1 -1 -16 7 3 -1 -1 -1 -1 1 -1 4 3 1 -1 1 -1 -1 -1 -18 9 4 -1 1 -1 -1 2 1 5 4 1 -1 2 -1 -1 -1 -128 28 9 -1 8 -1 -1 4 2 16 3 -1 -1 3 1 -1 -1 -114 14 3 -1 -1 -1 -1 2 1 8 3 -1 -1 1 -1 -1 -1 -1520Sample IDQ515593Q515594Q515595Q515596Q515597Q515598Q515599Q515599-RQ515600Q515651Q515652Q515653Q515654Q515655Q515657Q515658Q515659Q515660Q515661Q515662Q515663Q515664Q515664-RQ515665Q515666Q515667Q515668Q515669Q515670Q515671Q515672Q515673Q515674Q515675Q515676Q515678Q515679Q515679-RQ515680C018 LB C019 LB C020 LA C021 LPH C022 LBA C023 LAR C024 LB C025 LAR C026 LBA C027 LB C028 ALK C029 HB C030 HB C031 HB C032 HB C033 HB C034 HB C035 LARD.11 Spatiotemporal Geochemical Hydrocarbons13 13 3 -1 3 -1 -1 2 1 6 1 1 1 2 -1 -1 -1 -15 5 1 -1 1 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -18 8 2 -1 -1 -1 -1 1 -1 4 -1 -1 -1 1 -1 -1 -1 -12 2 -1 -1 -1 -1 -1 -1 -1 1 -1 -1 -1 -1 -1 -1 -1 -16 6 3 -1 4 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -13 4 2 -1 3 -1 -1 -1 -1 2 -1 -1 -1 -1 -1 -1 -1 -17 7 3 -1 -1 -1 -1 1 -1 3 3 -1 -1 -1 -1 -1 -1 -18 8 3 -1 3 -1 -1 1 -1 4 -1 -1 -1 -1 -1 -1 -1 -19 9 3 -1 -1 -1 -1 2 1 5 3 -1 -1 1 -1 -1 -1 -19 9 6 -1 7 -1 -1 2 2 5 2 1 -1 1 -1 -1 -1 -110 10 4 -1 5 -1 -1 2 1 5 3 -1 1 1 -1 -1 -1 -12 2 1 -1 1 -1 -1 -1 -1 1 1 -1 -1 -1 -1 -1 -1 -13 3 2 -1 2 -1 -1 -1 -1 2 -1 -1 -1 -1 -1 -1 -1 -13 3 2 -1 -1 -1 -1 -1 -1 2 -1 -1 -1 -1 -1 -1 -1 -13 3 1 -1 -1 -1 -1 -1 -1 2 -1 -1 -1 -1 -1 -1 -1 -15 5 3 -1 3 -1 -1 -1 -1 2 -1 -1 -1 -1 -1 -1 -1 -16 6 2 -1 3 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -111 11 5 -1 5 -1 -1 2 -1 4 1 -1 -1 1 -1 -1 -1 -18 8 5 -1 5 -1 -1 2 -1 4 -1 -1 -1 -1 -1 -1 -1 -14 5 2 -1 -1 -1 -1 -1 -1 2 -1 -1 -1 -1 -1 -1 -1 -113 13 4 -1 4 -1 -1 2 1 7 4 2 -1 2 -1 -1 -1 -18 8 1 -1 1 -1 -1 1 1 4 3 -1 -1 1 -1 -1 -1 -110 10 3 -1 3 -1 -1 2 1 5 2 -1 -1 1 -1 -1 -1 -15 5 3 -1 3 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -113 14 8 -1 9 -1 -1 2 1 6 2 -1 -1 1 -1 -1 -1 -18 8 3 -1 3 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -17 8 3 -1 4 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -110 10 4 -1 4 -1 -1 2 -1 4 -1 -1 -1 -1 -1 -1 -1 -18 8 3 -1 -1 -1 -1 2 -1 5 -1 -1 -1 1 -1 -1 -1 -16 6 3 -1 3 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -110 10 6 -1 -1 -1 -1 2 2 6 2 1 -1 2 -1 -1 -1 -15 5 2 -1 -1 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -120 20 3 -1 1 -1 -1 3 1 10 4 -1 -1 2 -1 -1 -1 -114 14 6 -1 1 -1 -1 2 1 8 2 2 2 2 -1 -1 -1 -13 3 1 -1 1 -1 -1 -1 -1 2 1 -1 -1 -1 -1 -1 -1 -18 8 3 -1 3 -1 -1 2 -1 4 -1 -1 -1 -1 -1 -1 -1 -113 13 6 -1 7 -1 -1 2 -1 5 1 -1 1 1 -1 -1 -1 -113 13 6 -1 7 -1 -1 2 -1 5 1 -1 1 1 -1 -1 -1 -17 7 3 -1 -1 -1 -1 2 1 4 -1 -1 -1 1 -1 -1 -1 -1521Sample IDQ515681Q515682Q515683Q515685Q515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515695-RQ515696Q515697Q515698Q515699Q515700LMB-QALMB-QALMB-QALMB-QAC018 LB C019 LB C020 LA C021 LPH C022 LBA C023 LAR C024 LB C025 LAR C026 LBA C027 LB C028 ALK C029 HB C030 HB C031 HB C032 HB C033 HB C034 HB C035 LARD.11 Spatiotemporal Geochemical Hydrocarbons5 5 3 -1 4 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -16 6 2 -1 2 -1 -1 1 -1 3 -1 -1 -1 -1 -1 -1 -1 -13 3 1 -1 1 -1 -1 -1 -1 2 -1 -1 -1 -1 -1 -1 -1 -13 4 2 -1 1 -1 -1 -1 -1 2 -1 -1 -1 -1 -1 -1 -1 -112 12 5 -1 4 1 -1 2 1 6 4 1 1 1 -1 -1 -1 -123 24 8 -1 2 -1 -1 4 2 12 3 -1 -1 2 1 -1 -1 -18 9 6 -1 -1 -1 -1 2 1 4 4 1 -1 1 -1 -1 -1 -14 4 3 -1 3 -1 -1 -1 1 2 3 -1 -1 -1 -1 -1 -1 -16 6 3 -1 3 -1 -1 1 2 3 4 -1 -1 -1 -1 -1 -1 -111 11 6 -1 1 -1 -1 2 2 5 -1 1 1 1 -1 -1 -1 -14 4 2 -1 -1 -1 -1 1 -1 2 -1 -1 -1 -1 -1 -1 -1 -15 5 3 -1 3 -1 -1 1 -1 2 -1 -1 -1 -1 -1 -1 -1 -122 22 18 1 19 2 -1 3 2 8 5 -1 -1 2 -1 -1 -1 -119 19 20 1 21 3 -1 3 3 7 5 -1 -1 2 -1 -1 -1 -1117 117 97 6 100 10 2 18 10 46 29 -1 1 8 3 2 -1 111 12 4 -1 -1 -1 -1 2 1 6 4 2 -1 2 -1 -1 -1 -16 7 3 -1 -1 -1 -1 1 -1 4 2 -1 -1 1 -1 -1 -1 -19 10 2 -1 1 -1 -1 2 1 5 1 -1 -1 2 -1 -1 -1 -16 6 2 -1 2 -1 -1 2 -1 4 -1 1 -1 1 -1 -1 -1 -1-1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1-1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1-1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1-1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1522Sample IDQ515501Q515502Q515503Q515504Q515505Q515505-RQ515506Q515507Q515508Q515509Q515510Q515511Q515512Q515513Q515514Q515515Q515516Q515517Q515518Q515519Q515520Q515520-RQ515521Q515522Q515523Q515524Q515525Q515526Q515527Q515528Q515529Q515530Q515531Q515551Q515552Q515553Q515554Q515554-RQ515555C036 LBA C037 HB C038 LBA C039 LAR C040 LPB C041 LBA C042 LPB C043 HB C044 HB C045 LA C046 LPH C047 LBA C048 HB C049 -HB C050 LBA C051 LBI C052 LPB3 2 2 5 5 13 3 -1 3 13 1 6 2 -1 4 -1 11 -1 1 2 2 9 2 2 2 9 1 6 1 -1 5 -1 118 2 8 21 23 146 9 6 8 156 10 35 1 2 24 2 33 2 1 2 2 24 1 1 2 25 2 3 1 1 4 -1 -12 2 -1 2 2 6 1 1 2 6 1 3 1 1 2 -1 -12 -1 -1 2 2 7 1 -1 2 7 1 3 1 1 2 -1 -15 -1 3 2 3 23 2 2 3 23 2 8 2 -1 6 -1 112 1 9 -1 8 91 3 4 4 96 6 24 2 -1 18 1 28 -1 2 4 4 44 2 2 3 47 3 16 2 -1 11 1 18 2 3 -1 4 48 2 1 3 52 4 9 2 -1 12 1 11 1 2 3 3 25 2 2 2 27 2 10 2 -1 8 1 15 3 1 2 2 21 2 2 3 22 2 9 1 -1 7 -1 12 3 2 2 2 25 2 2 3 26 2 13 2 -1 9 -1 14 2 4 2 2 17 1 2 2 18 2 4 1 -1 5 -1 14 2 1 2 2 23 2 2 2 25 2 8 1 -1 5 -1 14 2 1 2 2 26 2 2 2 27 2 7 1 -1 5 1 16 -1 2 3 3 35 2 2 2 37 3 9 2 -1 8 1 13 2 -1 1 1 10 1 1 2 10 1 4 1 1 4 -1 -11 -1 2 2 2 22 1 2 2 24 2 8 1 -1 7 -1 -13 2 1 1 1 23 1 -1 2 24 2 3 1 1 4 -1 -14 2 2 2 2 38 1 -1 2 41 3 4 1 1 6 1 15 3 2 3 3 31 2 2 2 33 3 11 2 2 7 -1 14 2 2 2 2 19 1 2 2 19 2 7 1 1 5 -1 -12 1 2 2 2 36 2 2 2 39 3 13 2 -1 9 1 13 2 2 3 3 38 2 2 3 41 3 21 2 -1 14 1 14 2 1 2 2 19 1 2 2 19 2 3 1 1 5 -1 -11 2 1 1 1 11 1 -1 -1 12 1 8 1 1 7 -1 -11 3 2 2 2 18 1 -1 2 20 2 9 1 1 7 -1 -11 2 1 2 2 11 1 2 2 11 1 6 1 1 5 -1 -13 2 1 1 1 9 1 1 2 9 1 6 1 1 4 -1 -124 1 17 6 7 266 3 1 3 286 18 22 3 3 29 2 22 -1 -1 1 1 7 1 1 1 6 1 3 1 1 2 -1 -13 2 -1 1 1 9 1 1 2 9 1 5 1 1 4 -1 -13 2 3 1 1 39 1 -1 2 42 3 4 1 1 5 -1 -13 2 4 2 2 42 1 1 2 45 4 5 1 1 6 -1 -13 2 3 2 2 33 1 1 2 34 3 4 1 1 5 -1 -12 2 2 1 1 12 1 -1 2 13 2 3 1 1 3 -1 -12 2 2 1 1 17 1 1 2 18 2 2 1 1 3 -1 -13 2 1 1 2 23 1 1 2 24 2 3 1 1 5 -1 -1D.11 Spatiotemporal Geochemical Hydrocarbons523Sample IDQ515556Q515557Q515558Q515559Q515560Q515561Q515562Q515563Q515564Q515565Q515566Q515567Q515568Q515569Q515569-RQ515570Q515571Q515572Q515573Q515574Q515575Q515576Q515577Q515578Q515579Q515580Q515581Q515582Q515583Q515584Q515584-RQ515585Q515586Q515587Q515588Q515589Q515590Q515591Q515592C036 LBA C037 HB C038 LBA C039 LAR C040 LPB C041 LBA C042 LPB C043 HB C044 HB C045 LA C046 LPH C047 LBA C048 HB C049 -HB C050 LBA C051 LBI C052 LPBD.11 Spatiotemporal Geochemical Hydrocarbons3 2 1 2 2 21 2 1 2 22 2 3 1 1 4 -1 -11 1 -1 1 1 4 1 -1 -1 3 -1 5 1 1 5 -1 -11 2 1 2 2 14 1 2 2 15 2 9 1 1 6 -1 -11 -1 1 2 2 24 2 2 2 26 2 10 1 -1 8 -1 14 -1 1 2 2 21 2 2 2 23 2 8 1 1 6 -1 -13 2 1 2 2 13 1 2 2 13 2 5 1 1 4 -1 -16 -1 2 3 3 28 2 2 3 30 3 11 2 -1 8 -1 14 -1 2 3 3 48 2 2 2 51 4 3 1 -1 5 -1 14 -1 1 3 3 11 2 -1 -1 11 1 5 1 -1 5 -1 14 2 2 2 2 24 2 2 2 25 2 8 1 -1 6 -1 -14 -1 5 3 3 21 2 2 2 22 2 8 2 -1 6 1 14 -1 4 3 3 21 2 2 3 22 2 7 1 -1 4 -1 -14 2 1 2 2 16 1 -1 2 16 2 8 1 1 5 -1 -14 -1 2 3 3 14 2 2 2 14 2 7 1 -1 5 -1 13 2 1 2 3 8 2 1 2 8 1 5 1 -1 4 -1 -124 3 17 9 9 226 4 2 3 242 15 22 3 3 29 3 22 2 -1 2 2 10 1 2 2 10 1 2 1 1 3 -1 -12 2 -1 1 1 9 1 1 2 9 1 4 1 1 3 -1 -15 -1 5 3 3 25 2 2 -1 26 2 5 2 2 7 1 14 2 1 2 2 38 1 2 2 40 3 4 1 1 5 -1 -13 -1 1 2 2 16 1 2 2 17 2 3 1 1 3 -1 -14 2 2 3 3 30 2 -1 2 32 3 6 2 2 7 1 12 2 -1 1 1 12 1 -1 2 13 1 2 1 1 3 -1 -1-1 2 -1 1 1 4 1 -1 -1 3 -1 4 1 1 4 -1 -13 2 -1 1 1 23 1 -1 2 24 2 3 1 1 3 -1 -1-1 2 -1 2 1 4 1 1 2 4 -1 4 1 1 3 -1 -11 2 2 3 3 25 2 2 2 27 2 9 1 -1 7 -1 1-1 -1 -1 2 2 4 1 1 2 3 -1 4 1 -1 -1 -1 -15 2 2 2 2 42 2 -1 2 45 3 5 1 -1 7 1 15 2 1 2 3 34 2 2 2 36 3 10 1 -1 6 -1 14 2 1 2 2 34 2 2 2 37 3 4 1 -1 6 -1 16 2 2 4 4 41 2 2 3 44 3 11 2 -1 7 1 12 -1 -1 1 1 13 1 1 2 13 2 3 1 1 3 -1 -15 3 6 3 3 30 2 2 3 32 3 6 1 -1 8 -1 11 -1 1 2 2 12 1 2 2 13 1 6 1 -1 6 -1 -1-1 -1 1 2 2 9 1 1 2 9 1 5 1 -1 4 -1 -11 -1 1 2 2 11 1 1 2 12 1 6 1 1 5 -1 -16 -1 2 4 4 17 2 2 2 18 2 9 1 -1 7 1 14 2 1 2 2 12 1 1 2 12 1 6 1 -1 5 -1 -1524Sample IDQ515593Q515594Q515595Q515596Q515597Q515598Q515599Q515599-RQ515600Q515651Q515652Q515653Q515654Q515655Q515657Q515658Q515659Q515660Q515661Q515662Q515663Q515664Q515664-RQ515665Q515666Q515667Q515668Q515669Q515670Q515671Q515672Q515673Q515674Q515675Q515676Q515678Q515679Q515679-RQ515680C036 LBA C037 HB C038 LBA C039 LAR C040 LPB C041 LBA C042 LPB C043 HB C044 HB C045 LA C046 LPH C047 LBA C048 HB C049 -HB C050 LBA C051 LBI C052 LPBD.11 Spatiotemporal Geochemical Hydrocarbons3 -1 3 2 2 10 1 1 2 10 1 5 1 1 4 -1 -12 2 2 1 1 6 1 1 2 5 1 3 1 1 3 -1 -12 -1 3 2 1 6 1 1 2 6 1 3 1 1 3 -1 -11 1 -1 1 1 2 -1 1 1 2 -1 2 -1 -1 1 -1 -12 2 2 1 1 7 1 -1 2 7 1 3 1 -1 2 -1 -12 2 2 1 1 6 1 2 2 6 1 3 -1 -1 2 -1 -13 -1 -1 1 1 7 1 1 2 7 1 4 1 1 3 -1 -12 2 3 1 1 8 1 1 2 8 1 4 1 1 3 -1 -13 -1 1 2 2 10 1 1 2 11 1 5 1 1 4 -1 -14 -1 1 2 2 17 1 1 2 18 2 7 1 1 6 -1 -14 -1 1 2 2 10 1 1 2 11 1 6 1 1 6 -1 -1-1 1 -1 1 1 3 1 -1 1 3 -1 3 -1 -1 2 -1 -12 2 2 1 1 6 1 -1 1 6 1 3 -1 -1 2 -1 -12 1 2 1 1 5 1 -1 1 5 1 2 -1 -1 2 -1 -12 1 2 1 1 3 1 -1 1 3 -1 2 -1 -1 1 -1 -12 1 2 -1 1 7 1 -1 1 7 1 3 -1 -1 2 -1 -12 1 2 1 1 5 1 -1 1 5 1 3 1 1 2 -1 -12 2 2 2 2 10 1 -1 2 10 1 4 1 1 3 -1 -12 2 2 2 2 10 1 -1 2 10 1 3 1 1 3 -1 -12 2 -1 1 1 6 1 -1 -1 6 1 4 1 1 3 -1 -12 2 1 2 2 12 2 1 2 12 1 9 1 2 9 -1 -13 2 -1 2 1 6 1 1 2 7 1 4 1 1 4 -1 -13 -1 1 2 2 9 1 1 2 9 1 4 1 1 3 -1 -12 2 2 1 1 7 1 -1 2 6 1 3 1 1 2 -1 -13 2 4 2 2 21 1 1 2 21 2 5 1 1 4 -1 -12 -1 2 1 1 8 1 -1 2 8 1 3 1 1 3 -1 -12 2 2 1 1 7 1 1 1 7 1 4 1 1 3 -1 -13 2 3 1 2 9 1 -1 2 9 1 4 1 1 3 -1 -12 -1 -1 2 2 5 1 1 2 5 1 3 1 1 2 -1 -12 -1 2 1 1 6 1 1 2 6 1 2 -1 -1 2 -1 -14 -1 4 2 2 17 1 1 2 17 2 6 1 1 5 -1 -12 -1 2 2 1 7 1 -1 2 7 1 3 1 1 2 -1 -14 -1 1 3 3 9 2 2 2 10 1 6 1 -1 5 -1 13 -1 1 2 2 15 1 2 2 16 2 6 1 1 4 -1 -12 -1 2 1 1 3 1 -1 1 3 -1 2 -1 -1 2 -1 -12 2 2 1 1 6 1 1 2 6 1 2 1 1 2 -1 -13 -1 3 2 2 15 1 1 2 16 2 5 1 1 4 -1 -13 -1 3 2 2 17 1 1 2 17 2 5 1 1 4 -1 -13 2 3 2 2 10 1 1 2 10 1 4 1 1 3 -1 -1525Sample IDQ515681Q515682Q515683Q515685Q515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515695-RQ515696Q515697Q515698Q515699Q515700LMB-QALMB-QALMB-QALMB-QAC036 LBA C037 HB C038 LBA C039 LAR C040 LPB C041 LBA C042 LPB C043 HB C044 HB C045 LA C046 LPH C047 LBA C048 HB C049 -HB C050 LBA C051 LBI C052 LPBD.11 Spatiotemporal Geochemical Hydrocarbons2 2 3 1 1 9 1 1 2 9 1 4 1 1 3 -1 -12 2 2 1 1 5 1 -1 1 5 1 3 -1 -1 2 -1 -12 2 -1 1 1 4 1 2 2 4 -1 2 -1 -1 2 -1 -12 2 -1 1 1 5 1 -1 -1 5 1 4 1 1 3 -1 -13 -1 3 2 2 14 1 1 2 14 2 5 1 1 4 -1 -15 -1 2 3 3 20 2 2 3 21 2 9 1 -1 8 1 14 2 1 2 2 15 1 1 2 16 2 6 1 1 5 -1 -13 2 -1 1 1 10 1 -1 2 10 1 5 1 1 4 -1 -11 2 1 1 1 11 1 1 2 11 1 8 1 1 7 -1 -14 2 1 -1 2 18 1 1 2 18 2 8 1 1 5 -1 -12 2 -1 1 1 5 1 -1 1 5 1 3 -1 -1 2 -1 -12 2 2 1 1 7 1 -1 1 7 1 3 -1 1 3 -1 -14 2 2 2 2 27 1 2 2 28 3 3 1 1 5 -1 -14 -1 4 2 2 34 1 2 2 36 3 6 1 1 5 1 -113 2 13 6 7 102 3 3 3 109 7 21 2 2 14 2 13 -1 3 2 2 16 1 2 2 16 2 5 1 1 4 -1 -13 2 3 2 2 9 1 -1 2 9 1 4 1 1 3 -1 -13 2 -1 2 2 7 1 -1 2 7 1 4 1 1 4 -1 -12 2 2 2 2 6 1 -1 1 6 1 2 1 1 2 -1 -11 1 2 -1 -1 2 -1 -1 1 1 -1 2 -1 -1 2 -1 -1-1 1 2 -1 -1 2 -1 1 1 2 -1 2 -1 -1 1 -1 -11 -1 2 -1 -1 2 -1 -1 -1 1 -1 2 -1 -1 1 -1 -1-1 1 -1 -1 -1 2 -1 1 1 1 -1 2 -1 -1 1 -1 -1526Sample IDQ515501Q515502Q515503Q515504Q515505Q515505-RQ515506Q515507Q515508Q515509Q515510Q515511Q515512Q515513Q515514Q515515Q515516Q515517Q515518Q515519Q515520Q515520-RQ515521Q515522Q515523Q515524Q515525Q515526Q515527Q515528Q515529Q515530Q515531Q515551Q515552Q515553Q515554Q515554-RQ515555C053 LPB C054 HB C055 LPB C056 LBI C057 ALK C058 LPB C059 LPB C060 LPH C061 LBI C062 LBA C063 LPH C064 LBA C065 HPB C066 LBA C067 LBI C068 HPB C069 LA3 2 1 1 2 2 4 26 2 23 14 26 4 35 3 7 362 2 1 1 3 1 2 7 2 15 5 16 2 24 2 4 259 2 3 3 7 8 11 27 10 46 16 45 10 170 10 21 1762 1 -1 -1 2 1 2 5 3 1 3 7 2 32 3 3 331 1 -1 -1 -1 1 1 4 -1 5 3 5 2 12 2 3 121 1 -1 -1 1 1 1 4 -1 6 3 6 2 14 2 3 142 2 1 1 6 1 2 6 3 24 4 26 3 60 4 6 603 2 2 2 13 3 5 13 8 40 9 42 7 158 9 22 1642 2 1 2 8 2 3 8 5 26 6 28 4 94 -1 11 972 2 1 2 8 2 3 11 5 30 7 33 5 106 5 12 1092 2 1 2 4 2 2 6 4 23 5 25 3 70 4 9 722 2 1 2 5 1 2 5 3 21 4 23 3 60 3 7 622 2 1 2 7 1 2 7 3 24 5 27 3 72 4 8 751 1 1 1 2 1 2 4 3 18 3 21 3 53 3 6 542 2 1 1 3 1 2 4 3 21 3 23 3 65 4 8 672 2 1 1 3 1 2 4 3 22 3 23 3 56 4 8 572 2 1 1 5 2 2 6 4 21 4 22 4 77 5 9 791 1 -1 1 -1 1 1 3 2 12 3 13 2 28 2 4 291 1 -1 2 1 1 2 4 3 18 3 19 2 43 3 4 441 1 -1 1 2 1 1 3 3 8 3 9 2 30 3 3 311 1 1 1 4 1 2 4 3 14 3 16 2 44 3 4 452 2 1 1 5 1 2 6 3 17 4 20 3 43 3 5 451 1 -1 1 3 1 1 4 2 12 3 13 2 30 3 4 312 2 1 2 6 1 2 6 4 21 4 22 3 72 4 6 742 2 1 4 7 1 2 7 4 28 5 30 3 73 4 6 741 1 -1 1 2 1 2 4 3 14 3 16 2 42 3 4 431 1 -1 2 -1 1 1 5 2 14 3 16 2 27 3 3 281 2 -1 2 4 1 2 4 3 22 3 24 3 50 3 5 521 1 -1 2 4 1 2 4 3 20 3 22 2 34 3 4 36-1 1 -1 1 2 -1 1 2 -1 11 3 14 2 21 2 1 223 2 2 4 14 2 4 6 12 43 5 44 5 156 13 11 1641 1 -1 -1 -1 -1 1 3 -1 5 2 5 2 12 2 3 121 1 -1 -1 -1 -1 1 3 -1 11 2 14 2 24 2 3 251 1 -1 -1 2 1 1 3 3 7 2 1 2 46 3 3 471 1 -1 1 -1 1 1 4 3 8 3 2 2 54 -1 3 561 1 -1 -1 2 1 2 3 3 9 3 10 2 56 3 4 57-1 1 -1 -1 -1 -1 1 1 -1 7 2 10 2 25 2 1 261 1 -1 -1 1 1 -1 2 2 6 3 8 2 35 3 4 361 1 -1 1 3 1 -1 2 3 9 3 12 2 42 3 3 43D.11 Spatiotemporal Geochemical Hydrocarbons527Sample IDQ515556Q515557Q515558Q515559Q515560Q515561Q515562Q515563Q515564Q515565Q515566Q515567Q515568Q515569Q515569-RQ515570Q515571Q515572Q515573Q515574Q515575Q515576Q515577Q515578Q515579Q515580Q515581Q515582Q515583Q515584Q515584-RQ515585Q515586Q515587Q515588Q515589Q515590Q515591Q515592C053 LPB C054 HB C055 LPB C056 LBI C057 ALK C058 LPB C059 LPB C060 LPH C061 LBI C062 LBA C063 LPH C064 LBA C065 HPB C066 LBA C067 LBI C068 HPB C069 LAD.11 Spatiotemporal Geochemical Hydrocarbons2 1 -1 1 -1 1 2 8 3 9 5 9 2 40 3 5 41-1 1 -1 2 4 -1 1 4 2 4 3 7 2 8 2 3 91 1 -1 2 4 1 -1 4 3 11 3 14 2 32 3 4 332 2 1 2 5 1 2 6 3 16 4 17 3 61 3 6 632 1 -1 1 -1 1 2 6 3 16 4 17 3 47 3 6 481 1 -1 1 2 1 1 4 2 11 3 12 2 27 3 4 282 2 1 2 5 2 2 9 4 24 6 26 3 68 4 7 702 2 1 1 -1 2 3 14 3 15 7 16 3 69 3 7 712 2 1 1 2 1 2 15 2 15 8 16 2 28 2 4 291 2 -1 1 3 1 2 5 2 14 4 16 2 53 3 3 542 2 1 1 3 1 2 4 3 13 3 14 2 32 3 4 342 2 1 -1 2 1 2 6 3 11 4 12 3 32 3 6 321 1 -1 1 3 1 2 5 -1 8 4 9 2 24 2 3 252 2 1 1 -1 1 2 10 2 12 7 12 3 29 2 4 302 1 -1 1 -1 1 1 8 -1 8 6 9 2 19 2 3 194 3 2 4 19 4 5 12 10 30 8 32 5 157 11 12 1641 1 -1 -1 1 1 -1 1 -1 7 2 9 -1 17 2 2 171 1 -1 -1 1 -1 1 3 2 8 3 9 2 24 2 1 252 2 1 1 4 1 1 4 3 18 3 33 3 48 -1 4 501 1 -1 1 3 1 1 3 3 10 3 11 2 60 3 3 621 1 -1 -1 2 1 2 4 2 8 3 10 2 27 2 4 282 2 1 1 4 1 2 5 3 13 4 15 2 48 3 5 50-1 1 -1 1 -1 -1 -1 2 -1 6 3 7 2 21 2 1 221 1 -1 2 -1 -1 1 4 -1 6 3 6 2 10 -1 3 101 1 -1 -1 2 -1 1 3 3 11 2 13 2 50 3 4 521 1 -1 -1 2 1 1 6 -1 2 4 7 2 13 2 3 132 2 1 1 4 1 2 8 3 16 6 16 3 58 3 8 601 1 -1 -1 2 1 2 9 -1 1 6 5 3 12 2 6 132 2 1 1 4 1 2 5 4 14 4 17 3 74 -1 8 772 2 1 1 3 1 2 5 3 19 4 20 3 75 4 10 772 2 1 2 4 1 2 5 3 13 4 14 3 65 -1 9 672 2 1 1 4 2 3 11 4 8 7 17 4 105 5 11 109-1 1 -1 -1 1 -1 1 2 -1 6 3 8 2 23 2 2 242 2 1 2 5 2 2 7 3 15 5 20 3 57 3 7 591 1 -1 2 4 1 2 6 2 10 4 10 3 38 3 6 401 1 -1 1 2 1 1 6 -1 8 4 9 2 25 2 4 252 1 -1 2 -1 1 2 11 2 7 7 10 2 26 2 5 272 2 1 2 4 2 3 11 2 13 7 13 3 32 3 6 331 1 -1 1 3 1 2 5 2 12 4 13 2 31 2 3 32528Sample IDQ515593Q515594Q515595Q515596Q515597Q515598Q515599Q515599-RQ515600Q515651Q515652Q515653Q515654Q515655Q515657Q515658Q515659Q515660Q515661Q515662Q515663Q515664Q515664-RQ515665Q515666Q515667Q515668Q515669Q515670Q515671Q515672Q515673Q515674Q515675Q515676Q515678Q515679Q515679-RQ515680C053 LPB C054 HB C055 LPB C056 LBI C057 ALK C058 LPB C059 LPB C060 LPH C061 LBI C062 LBA C063 LPH C064 LBA C065 HPB C066 LBA C067 LBI C068 HPB C069 LAD.11 Spatiotemporal Geochemical Hydrocarbons1 1 -1 -1 2 1 1 4 2 13 3 14 2 28 2 3 291 1 -1 -1 -1 -1 -1 3 -1 8 2 9 2 14 -1 -1 151 1 -1 -1 1 -1 1 3 -1 9 2 10 2 18 2 -1 19-1 -1 -1 -1 -1 -1 -1 -1 -1 4 -1 4 -1 6 -1 -1 61 1 -1 -1 -1 -1 -1 2 -1 5 -1 6 2 14 2 -1 15-1 1 -1 -1 -1 -1 -1 -1 -1 5 -1 6 -1 14 -1 -1 141 1 -1 1 2 -1 -1 3 -1 9 2 9 2 17 2 -1 181 1 -1 -1 1 -1 -1 1 -1 6 2 7 -1 16 2 -1 161 1 -1 1 2 1 -1 4 -1 10 3 10 2 29 2 3 301 1 -1 1 -1 1 1 3 2 9 3 9 2 35 2 3 361 1 -1 2 3 1 2 5 2 9 3 9 2 22 2 3 23-1 -1 -1 1 1 -1 -1 3 -1 4 2 4 2 7 -1 -1 7-1 1 -1 -1 -1 -1 -1 1 -1 6 2 6 -1 16 2 -1 17-1 -1 -1 -1 -1 -1 -1 -1 -1 5 -1 5 -1 13 -1 -1 13-1 -1 -1 -1 -1 -1 -1 2 -1 4 2 4 -1 7 -1 -1 7-1 1 -1 -1 -1 -1 1 -1 -1 4 2 4 2 13 2 -1 141 1 -1 -1 -1 -1 -1 4 -1 5 3 5 2 12 -1 -1 121 1 -1 -1 1 -1 -1 3 -1 1 2 4 2 14 2 2 141 1 -1 -1 -1 1 -1 4 -1 -1 3 4 2 16 2 -1 161 1 -1 -1 1 -1 -1 3 -1 6 2 6 2 13 -1 -1 132 2 1 3 7 1 2 8 2 13 5 13 2 30 2 4 301 1 -1 1 2 1 -1 4 -1 19 3 21 2 24 -1 -1 241 1 -1 1 1 1 -1 4 -1 15 3 16 2 29 2 3 291 1 -1 -1 -1 -1 -1 3 -1 5 2 5 2 16 2 2 161 1 -1 -1 1 1 -1 2 2 9 2 9 2 34 2 2 351 1 -1 -1 -1 -1 -1 2 -1 5 2 5 2 16 2 -1 171 1 -1 -1 -1 -1 -1 2 -1 -1 2 4 2 12 2 -1 131 1 -1 -1 1 1 1 3 -1 5 2 6 2 16 2 2 161 1 -1 -1 -1 1 1 6 -1 6 4 6 2 11 -1 3 121 1 -1 -1 -1 -1 -1 3 -1 6 2 6 2 15 2 -1 151 1 -1 -1 2 1 1 5 2 13 3 14 2 49 3 3 501 1 -1 -1 -1 1 -1 3 -1 6 3 6 2 24 2 3 242 2 1 2 3 1 2 9 2 12 6 12 2 22 2 4 221 1 1 -1 2 1 2 4 2 12 3 13 2 25 2 3 25-1 -1 -1 -1 -1 -1 -1 2 -1 7 2 8 2 10 -1 -1 111 1 -1 -1 -1 -1 -1 3 -1 4 2 4 2 10 -1 3 101 1 -1 -1 1 1 1 3 2 3 3 5 2 24 2 3 251 1 -1 -1 1 1 1 4 2 3 3 5 2 28 2 3 291 1 -1 -1 1 1 -1 3 -1 9 3 9 2 25 2 3 25529Sample IDQ515681Q515682Q515683Q515685Q515686Q515687Q515688Q515689Q515690Q515691Q515692Q515693Q515695Q515695-RQ515696Q515697Q515698Q515699Q515700LMB-QALMB-QALMB-QALMB-QAC053 LPB C054 HB C055 LPB C056 LBI C057 ALK C058 LPB C059 LPB C060 LPH C061 LBI C062 LBA C063 LPH C064 LBA C065 HPB C066 LBA C067 LBI C068 HPB C069 LAD.11 Spatiotemporal Geochemical Hydrocarbons1 1 -1 -1 -1 -1 1 3 -1 6 2 6 2 19 2 -1 20-1 1 -1 -1 -1 -1 1 2 -1 5 -1 5 2 12 -1 -1 131 1 -1 -1 -1 -1 -1 3 -1 8 2 9 2 13 -1 -1 141 1 -1 1 2 -1 -1 3 -1 9 3 10 2 14 -1 -1 151 1 -1 -1 2 1 1 3 2 11 3 12 2 34 2 4 352 2 1 1 -1 2 2 6 3 17 5 18 3 49 3 5 501 1 -1 1 -1 1 1 3 2 11 3 12 2 33 2 3 331 1 -1 1 2 -1 1 3 2 14 2 16 2 30 2 -1 311 1 -1 2 4 -1 1 3 2 24 3 29 2 38 2 3 401 1 -1 1 -1 1 2 4 2 10 3 12 2 33 2 3 34-1 1 -1 -1 -1 -1 1 1 -1 5 2 6 2 10 -1 -1 101 1 -1 -1 -1 -1 -1 3 -1 4 3 4 2 12 2 -1 131 1 -1 1 -1 1 1 3 -1 7 2 7 2 35 2 3 361 1 -1 1 3 1 1 3 2 10 2 11 2 62 2 3 643 2 1 2 5 2 3 7 4 16 5 16 3 99 4 6 1021 1 -1 -1 2 1 2 5 2 10 4 11 2 39 3 4 401 1 -1 -1 1 1 1 5 -1 8 4 9 2 23 2 3 241 1 -1 1 2 1 2 9 -1 9 5 9 2 18 2 4 181 1 -1 -1 -1 1 1 7 -1 14 5 15 2 28 2 3 27-1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 3 -1 4 -1 -1 4-1 -1 -1 -1 -1 -1 -1 -1 -1 6 -1 7 -1 2 -1 -1 4-1 -1 -1 -1 -1 -1 -1 -1 -1 3 -1 4 -1 1 -1 -1 1-1 -1 -1 -1 -1 -1 -1 -1 -1 3 -1 4 -1 4 -1 -1 1530Sample IDQ515501Q515502Q515503Q515504Q515505Q515505-RQ515506Q515507Q515508Q515509Q515510Q515511Q515512Q515513Q515514Q515515Q515516Q515517Q515518Q515519Q515520Q515520-RQ515521Q515522Q515523Q515524Q515525Q515526Q515527Q515528Q515529Q515530Q515531Q515551Q515552Q515553Q515554Q515554-RQ515555C070 HPB C071 HPB C072 HPB C073 HBA C074 HBA C075 HPB C076 LPH C077 MAR C078 ALK C079 LBI C080 LPH C081 MAR C082 LPH C083 HBA C084 HBA C085 LPH11 13 7 25 16 11 4 3 5 -1 3 5 4 31 1 325 6 1 19 11 5 3 3 3 -1 3 3 3 17 -1 2136 46 48 31 68 35 45 26 62 6 22 10 26 164 17 1155 6 -1 10 11 5 5 3 8 -1 3 3 4 38 2 314 4 -1 8 8 4 3 2 -1 -1 2 2 3 11 1 134 5 1 9 9 4 3 2 1 -1 2 2 3 7 -1 1410 12 6 40 30 9 8 6 10 3 5 4 6 52 2 5039 50 58 30 73 43 35 25 32 7 20 15 24 206 18 15219 24 27 20 44 21 16 12 17 4 10 7 12 110 8 8822 28 33 24 50 26 15 12 16 5 9 9 11 6 9 11215 20 21 19 37 15 10 9 15 3 7 7 8 113 2 812 16 18 37 32 14 7 6 11 3 5 5 6 89 2 814 17 21 20 40 16 8 7 13 4 6 6 7 129 2 10510 12 15 36 29 12 6 5 8 3 4 4 5 75 2 913 17 18 38 32 14 9 7 13 3 6 5 7 104 2 712 17 17 32 30 14 10 7 12 3 6 4 7 73 2 5914 20 20 17 41 16 14 11 19 4 9 5 10 100 2 736 7 7 17 14 6 4 3 4 -1 3 3 3 25 1 267 9 9 23 21 7 7 5 7 3 5 3 5 32 2 355 5 1 13 15 5 5 4 4 -1 3 2 4 4 2 305 7 8 20 20 6 8 5 6 -1 4 3 5 39 2 298 9 11 28 21 9 7 5 6 -1 4 3 5 34 2 306 7 7 18 18 6 5 4 4 -1 3 3 4 35 1 2911 13 15 34 39 12 11 8 13 3 7 5 8 10 2 729 12 14 37 35 12 9 7 11 3 6 4 7 80 3 587 8 5 24 21 8 6 4 6 -1 4 3 4 58 1 465 6 4 21 18 6 4 3 3 2 3 3 3 31 1 267 9 11 31 26 8 6 5 8 3 4 4 5 80 2 607 9 10 30 23 8 5 5 6 2 4 4 4 54 1 454 4 5 20 18 4 3 3 4 -1 3 3 3 27 1 2819 26 27 35 70 20 67 32 42 7 28 6 32 129 19 963 4 -1 7 8 4 3 2 -1 -1 2 2 3 13 1 144 5 1 20 14 4 3 3 3 -1 3 2 3 23 1 33 4 -1 11 11 4 4 4 5 -1 4 2 4 39 2 355 6 -1 13 3 1 2 4 5 -1 4 3 5 51 3 466 7 1 16 16 6 5 4 2 1 4 3 4 60 2 524 4 1 1 14 5 3 3 3 -1 3 2 3 24 2 45 7 2 14 14 7 4 4 4 -1 3 3 4 7 2 314 6 2 2 25 7 1 4 4 -1 3 3 4 56 2 43D.11 Spatiotemporal Geochemical Hydrocarbons531Sample IDQ515556Q515557Q515558Q515559Q515560Q515561Q515562Q515563Q515564Q515565Q515566Q515567Q515568Q515569Q515569-RQ515570Q515571Q515572Q515573Q515574Q515575Q515576Q515577Q515578Q515579Q515580Q515581Q515582Q515583Q515584Q515584-RQ515585Q515586Q515587Q515588Q515589Q515590Q515591Q515592C070 HPB C071 HPB C072 HPB C073 HBA C074 HBA C075 HPB C076 LPH C077 MAR C078 ALK C079 LBI C080 LPH C081 MAR C082 LPH C083 HBA C084 HBA C085 LPHD.11 Spatiotemporal Geochemical Hydrocarbons9 11 3 4 17 10 5 4 6 1 4 4 4 55 2 454 4 5 9 10 4 -1 -1 1 -1 -1 2 -1 5 5 26 7 5 2 19 8 4 4 3 2 3 3 4 48 2 511 13 8 28 26 12 6 5 8 3 4 5 5 81 2 6611 14 2 27 23 11 5 4 6 3 4 5 4 58 2 556 8 8 19 18 6 5 4 5 -1 3 3 4 43 1 3712 16 17 37 34 13 8 7 13 3 6 6 7 11 2 716 19 20 21 17 14 5 4 6 1 3 4 4 56 2 446 6 6 19 6 4 3 2 3 -1 2 3 2 21 5 244 5 5 20 20 5 4 4 4 -1 3 3 3 46 1 365 7 8 19 23 7 7 7 8 -1 5 3 5 8 2 3712 15 8 19 21 12 5 4 5 -1 4 4 4 45 2 394 5 2 13 16 5 4 3 2 -1 3 3 3 31 1 256 8 8 16 18 7 4 4 4 -1 3 3 3 45 1 365 6 7 14 14 6 3 3 2 -1 3 3 3 35 1 2820 25 37 8 47 30 40 28 38 6 25 6 30 116 16 104 5 8 2 14 7 -1 4 2 -1 3 3 3 30 2 243 4 5 15 16 4 4 3 2 -1 3 3 3 38 1 346 8 13 23 40 11 6 9 25 3 6 4 7 65 4 595 6 7 4 20 6 6 5 7 -1 4 3 5 47 2 405 6 8 15 15 7 4 3 2 -1 3 3 3 30 2 228 10 12 25 27 9 8 8 10 3 5 3 6 2 2 644 5 1 13 13 5 3 3 2 -1 3 2 3 31 2 244 5 5 7 7 4 2 2 -1 -1 -1 2 2 11 -1 116 7 8 22 19 6 5 4 5 -1 3 3 4 50 2 385 6 7 10 10 6 2 2 1 -1 2 3 2 19 5 1814 18 11 26 26 15 6 5 7 3 4 5 5 65 2 5612 15 19 8 8 16 2 2 -1 -1 2 6 2 28 1 2615 19 13 30 32 21 11 8 12 4 7 6 8 87 4 7418 23 26 16 36 19 9 7 12 3 6 6 7 98 2 915 20 13 27 29 21 9 7 12 3 6 6 7 88 3 7621 30 32 34 37 24 12 10 26 4 8 9 9 154 8 1285 6 2 1 16 6 3 3 2 -1 3 3 3 28 1 2411 15 11 21 28 17 7 5 6 3 5 5 5 71 2 549 12 7 17 19 11 4 4 5 -1 3 5 4 55 1 496 7 -1 15 14 7 3 3 2 -1 2 3 3 5 1 49 11 12 14 13 8 3 2 1 -1 2 4 3 33 -1 310 12 2 18 21 10 4 4 2 -1 3 4 4 40 1 315 7 7 18 18 6 3 3 4 -1 3 3 3 5 1 35532Sample IDQ515593Q515594Q515595Q515596Q515597Q515598Q515599Q515599-RQ515600Q515651Q515652Q515653Q515654Q515655Q515657Q515658Q515659Q515660Q515661Q515662Q515663Q515664Q515664-RQ515665Q515666Q515667Q515668Q515669Q515670Q515671Q515672Q515673Q515674Q515675Q515676Q515678Q515679Q515679-RQ515680C070 HPB C071 HPB C072 HPB C073 HBA C074 HBA C075 HPB C076 LPH C077 MAR C078 ALK C079 LBI C080 LPH C081 MAR C082 LPH C083 HBA C084 HBA C085 LPHD.11 Spatiotemporal Geochemical Hydrocarbons4 5 5 18 15 4 3 3 3 -1 2 2 3 25 -1 243 3 3 12 10 3 2 2 2 -1 -1 2 2 13 -1 143 3 3 12 10 3 3 2 1 -1 2 2 2 19 5 17-1 2 -1 6 6 2 -1 -1 1 -1 -1 -1 -1 9 -1 83 4 -1 7 7 3 2 2 -1 -1 2 2 2 17 5 143 3 -1 8 8 2 2 2 1 -1 -1 2 2 14 5 123 3 4 13 11 3 3 2 1 -1 2 2 2 2 5 173 3 3 9 12 3 3 3 1 -1 2 2 2 3 -1 165 6 1 15 12 5 3 3 2 -1 2 2 3 27 5 244 4 4 12 14 4 3 3 1 -1 3 2 3 5 -1 225 5 -1 12 13 4 3 3 1 -1 2 2 2 4 5 223 3 3 5 6 3 -1 -1 -1 -1 -1 2 2 11 -1 93 3 -1 8 10 2 2 2 1 -1 -1 2 2 17 5 142 2 -1 7 7 2 2 -1 -1 -1 -1 -1 2 3 -1 10-1 2 2 5 5 2 -1 -1 -1 -1 -1 -1 -1 7 -1 73 3 -1 5 5 3 2 2 -1 -1 2 -1 2 14 1 123 3 3 7 9 3 2 2 -1 -1 -1 2 2 12 -1 113 3 3 4 4 3 3 2 2 -1 2 2 2 14 5 133 4 3 5 5 3 2 2 3 -1 2 2 2 17 5 153 3 3 7 8 3 2 2 -1 -1 -1 2 2 12 5 126 7 1 16 17 5 3 3 1 2 2 3 3 33 6 273 4 3 17 6 3 2 2 2 -1 -1 2 2 11 -1 144 5 -1 16 13 4 3 3 3 -1 2 2 3 5 6 273 4 -1 6 7 3 2 2 -1 -1 2 2 2 16 5 143 3 -1 9 9 3 3 3 -1 -1 2 2 3 24 -1 223 3 -1 6 6 2 2 2 -1 -1 2 2 2 18 5 153 3 -1 5 5 2 2 2 -1 -1 -1 2 2 14 5 133 3 3 6 6 2 2 2 -1 -1 2 2 2 18 5 164 4 4 7 7 3 2 2 -1 -1 -1 2 2 18 5 154 4 -1 7 6 3 2 2 -1 -1 2 2 2 15 -1 135 6 1 17 15 4 3 3 4 -1 3 2 3 36 1 293 4 4 9 9 3 3 2 -1 -1 2 2 2 3 5 156 8 7 13 14 6 3 3 1 -1 2 3 3 27 5 225 6 1 12 12 5 3 3 2 -1 3 2 3 23 1 193 3 3 9 7 3 -1 2 1 -1 -1 2 2 10 -1 103 4 -1 5 5 3 2 2 -1 -1 2 2 2 13 5 114 4 4 7 7 3 3 2 4 -1 2 2 3 24 6 225 5 5 7 7 4 3 2 4 -1 3 2 3 26 -1 254 5 -1 10 9 3 3 2 1 -1 2 2 3 -1 6 20533Sample 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IDQ515556Q515557Q515558Q515559Q515560Q515561Q515562Q515563Q515564Q515565Q515566Q515567Q515568Q515569Q515569-RQ515570Q515571Q515572Q515573Q515574Q515575Q515576Q515577Q515578Q515579Q515580Q515581Q515582Q515583Q515584Q515584-RQ515585Q515586Q515587Q515588Q515589Q515590Q515591Q515592C152 HPH C153 HPH C154 HPH C155 HPH C156 HBI C157 HAR C158 HBA C159 HBA C160 HBI C161 HA C162 HPHD.11 Spatiotemporal Geochemical Hydrocarbons29 45 -1 -1 -1 47 128 44 46 164 -1-1 -1 -1 -1 -1 46 94 -1 -1 121 -1-1 45 -1 -1 -1 -1 92 -1 -1 116 -1-1 -1 -1 -1 -1 46 111 44 46 145 -1-1 45 -1 -1 -1 46 123 43 -1 159 -1-1 -1 -1 -1 -1 -1 86 -1 -1 110 -129 45 -1 -1 -1 46 118 43 46 149 -1-1 45 -1 -1 -1 46 113 44 -1 149 -1-1 -1 -1 -1 -1 46 113 43 -1 145 -1-1 -1 -1 -1 -1 -1 104 -1 -1 135 -1-1 -1 -1 -1 -1 -1 77 -1 -1 97 -1-1 -1 -1 -1 -1 -1 81 -1 -1 105 -1-1 -1 -1 -1 -1 -1 86 -1 -1 105 -1-1 -1 -1 -1 -1 -1 91 -1 -1 111 -1-1 -1 -1 -1 -1 -1 84 -1 -1 109 -1-1 -1 -1 -1 -1 -1 74 -1 -1 97 -1-1 -1 -1 -1 -1 -1 74 -1 -1 97 -1-1 -1 -1 -1 -1 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IDQ515593Q515594Q515595Q515596Q515597Q515598Q515599Q515599-RQ515600Q515651Q515652Q515653Q515654Q515655Q515657Q515658Q515659Q515660Q515661Q515662Q515663Q515664Q515664-RQ515665Q515666Q515667Q515668Q515669Q515670Q515671Q515672Q515673Q515674Q515675Q515676Q515678Q515679Q515679-RQ515680C152 HPH C153 HPH C154 HPH C155 HPH C156 HBI C157 HAR C158 HBA C159 HBA C160 HBI C161 HA C162 HPHD.11 Spatiotemporal Geochemical Hydrocarbons-1 -1 -1 -1 -1 -1 78 -1 -1 101 -1-1 -1 -1 -1 -1 -1 70 -1 -1 90 -1-1 -1 -1 -1 -1 -1 71 -1 -1 92 -1-1 -1 -1 -1 -1 -1 60 -1 -1 78 -1-1 -1 -1 -1 -1 -1 67 -1 -1 81 -1-1 -1 -1 -1 -1 -1 67 -1 -1 86 -1-1 -1 -1 -1 -1 -1 72 -1 -1 92 -1-1 -1 -1 -1 -1 -1 72 -1 -1 87 -1-1 -1 -1 -1 -1 -1 76 -1 -1 98 -1-1 -1 -1 -1 -1 -1 74 -1 -1 96 -1-1 -1 -1 -1 -1 -1 74 -1 -1 95 -1-1 -1 -1 -1 -1 -1 69 -1 -1 90 -1-1 -1 -1 -1 -1 -1 64 -1 -1 80 -1-1 -1 -1 -1 -1 -1 62 -1 -1 80 -1-1 -1 -1 -1 -1 -1 60 -1 -1 78 -1-1 -1 -1 -1 -1 -1 63 -1 -1 81 -1-1 -1 -1 -1 -1 -1 63 -1 -1 82 -1-1 -1 -1 -1 -1 -1 70 -1 -1 89 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-1 -1 80 -1 -1 102 -1-1 -1 -1 -1 -1 -1 77 -1 -1 98 -1-1 -1 -1 -1 -1 -1 82 -1 -1 104 -1-1 -1 -1 -1 -1 -1 73 -1 -1 89 -1-1 -1 -1 -1 -1 -1 74 -1 -1 96 -1-1 -1 -1 -1 -1 -1 100 -1 -1 130 -1-1 -1 -1 -1 -1 -1 82 -1 -1 107 -1-1 -1 -1 -1 -1 -1 78 -1 -1 101 -1-1 -1 -1 -1 -1 -1 90 -1 -1 116 -1-1 -1 -1 -1 -1 -1 85 -1 -1 110 -1-1 -1 -1 -1 -1 -1 70 -1 -1 91 -1-1 -1 -1 -1 -1 -1 72 -1 -1 93 -1-1 -1 -1 -1 -1 -1 70 -1 -1 90 -1-1 -1 -1 -1 -1 -1 77 -1 -1 100 -1-1 -1 -1 -1 -1 -1 78 -1 -1 101 -1-1 -1 -1 -1 -1 -1 76 -1 -1 96 -1-1 -1 -1 -1 -1 -1 82 -1 -1 106 -1-1 -1 -1 -1 -1 -1 87 -1 -1 112 -130 -1 -1 -1 -1 -1 90 -1 -1 113 -1-1 -1 -1 -1 -1 -1 82 -1 -1 105 -1-1 -1 -1 -1 -1 -1 73 -1 -1 93 -1-1 -1 -1 -1 -1 -1 63 -1 -1 82 -1-1 -1 -1 -1 -1 -1 68 -1 -1 87 -1554D.12 AGI Goresorber Hydrocarbon CollectorsModule ID Site Sample Type Carbon Dioxide Carbonyl Sulfide Dimethyl Sulfide Dimethyl Disulfide Ethene/Ethane Ethane Propene Propane 1-Butene Butane00760884.D 5 Field 5591536 56.80 4.89 4.94 7.02 42.82 7.20 13.58 105.68 58.0300760783.D 6 Field 4532614 5.99 0.59 1.57 1.87 46.20 4.38 13.56 29.84 7.8200760754.D 7 Field 5438440 56.83 146.54 5.47 17.15 47.60 44.95 77.97 158.67 187.3000760829.D 8 Field 4650633 43.40 1.84 4.42 13.47 40.89 34.93 32.04 163.36 241.6500760847.D 9 Field 5076931 59.41 7.71 0.02 12.92 46.79 33.49 54.32 136.70 76.0400760730.D 10 Field 5142463 83.57 28.51 4.11 18.91 47.82 29.04 78.01 152.10 155.2300760753.D 11 Field 5593483 61.89 33.43 195.91 18.76 49.29 85.98 79.57 286.35 215.9100760836.D 12 Field 4135064 23.95 1.39 3.68 2.04 60.56 2.21 3.36 33.26 1.3000760831.D 13 Field 5436702 35.65 3.33 1.81 10.87 36.68 21.40 68.07 122.40 111.2900760802.D 14 Field 5408321 72.02 7.57 9.53 18.28 40.20 62.56 69.97 247.42 233.4100760717.D 15 Field 4331507 32.36 2.70 6.01 12.67 33.01 26.62 45.44 143.71 169.9600760815.D 16 Field 6481208 67.43 1.54 11.13 4.93 58.02 8.50 14.39 90.14 39.5000760906.D 17 Field 5330050 25.56 0.17 0.01 8.10 36.32 7.45 9.20 64.24 58.1600760785.D 18 Field 5563599 39.38 13.67 25.62 18.01 40.95 46.25 46.52 178.08 284.0100760752.D 18b Duplicate 5450019 59.14 2.96 0.57 19.91 42.12 87.85 46.21 357.43 320.4100760823.D 19 Field 4868885 61.87 3.22 5.87 20.97 41.41 67.86 29.84 436.97 394.4400760888.D 20 Field 5907615 54.77 3.55 0.50 18.67 41.10 79.76 65.23 289.97 247.9000760792.D 21 Field 5476922 52.28 7.77 3.09 19.29 40.43 18.51 37.71 194.62 242.3500760756.D 22 Field 6082799 48.45 3.01 15.20 3.99 53.72 6.09 7.77 83.33 23.5900760744.D 23 Field 4777217 42.39 35.75 41.14 19.67 36.46 34.84 34.75 205.59 330.5900760759.D 24 Field 4499754 40.28 1.37 0.01 13.16 35.16 58.23 51.73 259.38 209.4300760905.D 25 Field 5275823 21.81 0.23 0.01 6.58 39.51 7.10 11.01 51.31 28.9100760846.D 26 Field 5838733 25.26 4.49 0.66 13.12 47.49 16.99 35.12 103.21 80.5300760773.D 27 Field 6073957 52.03 10.06 0.89 19.69 46.84 73.56 76.05 295.08 231.7500760825.D 28 Field 4799319 27.13 1.43 0.27 10.86 34.14 22.29 61.98 99.87 105.5000760778.D 29 Field 6021830 21.27 17.43 2457.44 2.88 81.44 3.65 5.05 31.27 8.3100760791.D 30 Field 5286130 21.55 0.08 8.59 3.60 44.71 6.04 12.05 51.55 14.7400760871.D 31 Field 4598633 38.18 0.98 1.71 13.87 37.97 32.28 50.36 147.85 189.1300760874.D 32 Field 5952063 30.66 0.28 0.01 13.16 44.75 31.09 67.76 107.75 119.3100760839.D 33 Field 5041237 40.21 2.12 0.28 13.02 37.31 51.18 51.06 236.98 239.6900760803.D 34 Field 4982786 53.43 13.97 5.62 21.46 41.24 71.55 27.00 317.44 325.1400760856.D 35 Field 4829071 30.17 6.07 0.01 14.36 39.35 41.37 80.81 133.46 162.3900760812.D 35b Duplicate 5443361 61.51 2.39 0.92 23.86 41.33 106.33 47.54 413.40 350.1000760838.D 36 Field 6844959 41.09 7.38 274.87 3.10 54.09 6.85 9.92 65.89 28.84555D.12 AGI Goresorber Hydrocarbon CollectorsModule ID Site Sample Type Carbon Dioxide Carbonyl Sulfide Dimethyl Sulfide Dimethyl Disulfide Ethene/Ethane Ethane Propene Propane 1-Butene Butane00760901.D 37 Field 5845649 56.23 4.75 2.37 18.64 46.34 23.23 61.22 126.43 185.6400760834.D 38 Field 5597193 39.65 0.94 0.01 14.91 38.44 41.58 74.19 126.42 158.8600760826.D 39 Field 6560569 43.34 4.68 5.67 3.54 61.00 5.02 7.60 69.62 44.3600760721.D 40 Field 6070035 91.09 3.79 9.20 4.80 53.51 10.17 10.76 128.07 22.1300760806.D 41 Field 4963441 59.59 5.76 14.94 32.10 41.01 110.82 38.86 552.21 617.8400760883.D 42 Field 4771391 57.95 5.80 13.92 34.76 42.41 97.37 29.86 585.04 596.3100760749.D 43 Field 4615232 62.86 7.53 5.99 29.60 40.83 82.71 22.38 473.28 492.4300760876.D 44 Field 5366183 78.91 5.21 0.97 18.53 39.58 66.39 65.87 302.61 269.7300760862.D 45 Field 5523969 58.91 4.07 4.81 18.33 37.57 105.02 47.09 331.55 286.3400760781.D 46 Field 7086529 20.94 19.61 204.73 3.51 54.53 5.42 8.08 40.98 13.9200760775.D 47 Field 5370400 49.80 0.72 0.67 16.24 36.51 19.86 48.40 132.87 169.2100760824.D 48 Field 4644566 35.88 0.81 2.11 7.63 38.23 10.13 26.78 76.19 41.3200760832.D 49 Field 5539141 36.37 10.23 36.84 46.67 44.22 19.75 27.50 457.95 772.8400760729.D 50 Field 5491235 57.05 7.32 37.95 20.49 42.70 52.58 71.94 282.40 306.8300760767.D 51 Field 4781990 37.41 50.82 15.76 62.19 41.87 28.03 51.58 336.78 393.0700760898.D 52 Field 5922637 44.82 5.59 20.07 40.67 46.63 58.23 19.37 544.74 729.6400760800.D 53 Field 5488940 31.88 4.00 24.05 31.78 42.33 14.42 20.27 257.12 567.0800760840.D 54 Field 6779644 36.38 4.06 6.40 2.95 49.37 5.39 6.19 67.25 23.5000760886.D 54b Duplicate 5526923 34.91 11.50 19.50 42.40 45.87 18.04 27.75 369.71 712.3900760855.D 55 Field 5421958 31.44 1.17 1.77 7.56 43.29 7.23 15.24 53.25 27.3600760907.D 57 Field 6001692 21.20 4.85 73.29 3.49 56.98 5.10 8.50 34.46 19.0800760745.D 58 Field 5723118 28.99 1.03 0.37 12.86 43.19 28.15 62.19 95.81 122.9300760818.D 59 Field 4038257 30.58 4.86 4.81 11.34 33.07 22.22 32.20 131.97 196.4300760795.D 60 Field 5186235 40.98 3.10 3.40 15.03 40.22 37.80 61.86 185.13 209.3000760735.D 61 Field 5504226 62.47 2.24 0.48 19.11 44.35 51.38 58.82 278.66 286.6200760738.D 62 Field 5782594 37.68 1.36 0.77 21.35 49.05 14.46 27.71 160.91 206.9000760788.D 63 Field 6453266 26.02 0.88 2.23 3.69 45.42 6.23 8.98 57.39 19.6700760885.D 64 Field 4860144 35.23 0.79 0.01 20.78 42.04 54.50 62.21 321.22 395.2900760736.D 65 Field 5017873 46.65 1.94 1.87 36.26 44.18 48.86 64.24 260.02 371.9900760817.D 66 Field 5069802 52.81 4.39 1.32 37.13 44.73 68.58 49.84 472.62 500.4600760734.D 67 Field 5030675 43.13 19.42 1.49 20.22 43.02 62.90 70.93 320.79 292.6000760784.D 68 Field 5696083 82.44 3.37 1.57 38.34 51.43 139.91 58.79 579.04 499.4300760833.D 69 Field 5923494 42.65 1.62 1.02 23.98 43.90 19.52 57.77 144.52 208.3300760790.D 70 Field 6246139 50.18 2.56 6.10 4.16 52.07 7.59 7.96 66.76 24.05556D.12 AGI Goresorber Hydrocarbon CollectorsModule ID Site Sample Type Carbon Dioxide Carbonyl Sulfide Dimethyl Sulfide Dimethyl Disulfide Ethene/Ethane Ethane Propene Propane 1-Butene Butane00760887.D 71 Field 5551065 56.48 6.89 6.49 24.39 43.11 11.52 18.64 175.81 239.7700760794.D 72 Field 3974913 38.34 2.00 12.04 30.30 35.17 26.09 41.03 295.06 425.8800760890.D 72b Duplicate 4854488 66.73 2.78 4.61 24.03 39.51 20.20 38.81 188.98 268.9700760771.D 73 Field 6591011 33.06 0.13 4.58 3.51 49.82 5.12 7.31 48.69 13.5000760731.D 74 Field 4179757 34.17 3.94 9.01 15.10 35.74 30.92 44.00 134.35 187.3400760892.D 75 Field 5060021 53.98 2.30 3.51 20.93 45.40 15.77 36.98 183.78 189.6400760820.D 76 Field 6540959 48.07 5.22 21.11 3.11 55.18 6.67 8.50 139.35 88.3900760805.D 77 Field 4814100 47.55 6.34 17.67 26.16 36.61 33.10 36.80 308.22 428.8400760880.D 78 Field 6968826 27.52 15.97 25.16 3.05 75.74 4.95 5.58 50.72 24.5700760760.D 79 Field 7092684 32.62 1.80 7.25 2.87 55.40 5.28 7.49 51.15 19.2200760873.D 80 Field 5468572 57.33 12.16 0.04 15.29 42.64 45.35 71.53 186.52 197.3600760758.D 81 Field 5439986 63.35 3.98 3.22 28.10 48.56 30.13 60.06 227.54 311.1500760910.D 82 Field 5372310 44.67 3.62 12.62 29.53 42.75 18.68 30.22 228.93 466.6800760845.D 83 Field 4926049 35.04 0.74 0.25 10.93 35.38 31.13 58.70 114.33 147.8300760740.D 84 Field 5152708 35.36 16.58 0.89 11.74 40.77 24.94 70.22 94.71 101.9200760902.D 85 Field 5206901 51.02 18.46 1.61 16.83 40.19 48.41 81.17 233.94 215.3200760801.D 86 Field 4792716 30.91 0.38 0.01 13.04 39.47 34.52 75.63 135.54 131.1700760747.D 87 Field 5507450 36.29 1.05 0.61 14.81 37.94 33.36 80.72 147.32 187.2400760893.D 88 Field 5303681 36.06 20.65 6.06 13.94 37.55 19.58 54.11 106.62 152.7200760718.D 89 Field 5224852 59.38 26.85 2.72 29.71 47.84 77.13 50.55 302.42 405.9900760861.D 90 Field 4354160 56.45 3.07 1.18 33.05 55.39 79.65 48.39 601.10 597.2000760816.D 91 Field 5891840 24.41 0.02 0.97 9.56 44.15 9.49 26.57 55.91 37.4800760843.D 92 Field 5026056 47.73 1.55 1.81 18.95 45.51 71.53 60.03 338.14 307.9700760733.D 93 Field 5467057 38.83 1.39 1.71 21.89 36.35 18.63 57.33 141.34 222.3200760764.D 94 Field 6138729 24.12 1.75 9.23 3.16 59.60 7.39 7.98 107.15 27.1800760796.D 95 Field 6867917 57.11 0.90 6.22 4.42 60.11 7.36 12.86 98.73 36.7400760859.D 96 Field 5025852 67.95 23.04 6.07 33.04 45.93 114.16 36.98 573.29 622.9900760881.D 97 Field 5648045 39.24 1.23 0.21 13.96 37.81 38.97 66.34 124.64 170.1700760808.D 98 Field 6116610 33.15 3.34 1.33 8.36 45.23 9.01 17.46 67.59 20.8700760866.D 99 Field 6166524 31.27 0.63 0.90 8.21 51.27 10.04 27.78 52.72 24.0300760813.D 100 Field 4867536 40.93 0.89 1.16 23.00 41.35 60.97 73.77 312.48 339.5000760737.D 101 Field 4901022 80.10 7.00 9.79 88.89 49.53 165.23 28.87 791.26 845.7600760765.D 102 Field 4917462 31.70 1.17 6.18 30.66 42.24 39.63 48.17 252.69 387.5900760728.D 103 Field 7183409 39.97 5.71 18.53 3.00 90.27 4.82 3.58 66.92 14.10557D.12 AGI Goresorber Hydrocarbon CollectorsModule ID Site Sample Type Carbon Dioxide Carbonyl Sulfide Dimethyl Sulfide Dimethyl Disulfide Ethene/Ethane Ethane Propene Propane 1-Butene Butane00760830.D 104 Field 2502477 2.49 0.00 0.01 5.00 20.68 5.00 20.70 7.45 30.1800760810.D 105 Field 5338386 47.57 1.26 0.01 18.36 43.27 62.68 71.17 274.98 291.3400760895.D 106 Field 5043820 34.51 0.56 0.01 14.29 35.86 44.44 54.74 184.50 209.4200760755.D 107 Field 5309975 66.98 2.28 7.77 42.41 46.31 125.52 38.15 637.12 588.3800760743.D 108 Field 5388131 45.72 2.09 19.78 17.50 40.32 44.43 35.32 251.59 364.1800760882.D 108b Duplicate 4854956 39.50 1.21 1.50 21.83 38.15 90.37 52.44 412.98 433.4300760842.D 109 Field 5068098 35.38 0.11 0.21 15.33 32.21 58.34 56.40 192.35 202.6500760889.D 110 Field 4166886 30.38 0.64 10.68 14.79 33.23 32.27 39.66 154.52 203.0900760867.D 111 Field 4261328 49.28 2.55 5.62 31.65 36.58 68.22 42.71 317.49 514.7900760903.D 112 Field 3945703 32.63 6.03 5.08 23.89 34.53 59.62 52.30 293.30 362.4200760766.D 113 Field 5193085 46.88 3.12 1.41 28.70 46.45 97.41 61.82 445.91 434.3000760748.D 114 Field 3297414 34.46 1.42 6.38 16.31 28.57 47.46 30.82 280.92 267.4700760811.D 115 Field 4323217 40.57 1.19 9.71 24.70 36.41 76.23 51.16 421.98 375.2700760741.D 116 Field 5602928 47.56 3.07 0.93 19.38 43.36 34.05 81.79 144.54 168.0900760768.D 117 Field 4660892 39.93 2.74 4.96 24.13 41.14 48.40 34.90 348.07 425.1700760865.D 118 Field 4131651 29.23 0.39 0.01 12.86 33.32 38.56 76.75 178.76 184.0100760809.D 119 Field 5923814 45.32 3.65 1.22 26.08 44.85 94.19 67.42 390.25 351.3500760720.D 120 Field 5190323 43.90 4.06 0.37 20.02 46.87 76.29 84.46 310.85 276.5300760770.D 121 Field 4365556 41.61 0.69 4.94 22.37 36.43 59.32 59.44 251.78 302.7400760793.D 122 Field 5183287 58.00 0.99 0.66 23.53 48.84 63.37 93.07 215.07 229.4900760868.D 123 Field 4990346 44.93 1.57 1.20 23.04 45.19 79.49 68.26 334.68 342.1700760897.D 124 Field 4170375 34.02 2.47 12.81 23.50 34.27 56.15 38.29 305.08 338.1100760837.D 125 Field 5889800 47.68 1.09 1.82 26.41 44.78 97.58 59.60 421.97 384.6500760776.D 126 Field 5148109 41.98 0.43 0.80 16.49 37.02 50.13 55.53 229.75 239.3600760780.D 126b Duplicate 4753363 52.65 1.19 0.02 21.81 43.80 84.94 70.21 274.08 223.3400760782.D 127 Field 5747989 41.52 1.78 0.04 14.79 42.85 28.08 73.16 97.47 119.6600760875.D 128 Field 5403839 36.49 1.29 0.22 23.17 40.28 62.90 65.58 260.48 275.0100760742.D 129 Field 5158737 61.89 14.98 2.77 28.79 44.03 76.45 52.95 474.92 409.4200760835.D 130 Field 4879007 49.09 3.61 4.42 18.57 42.12 61.89 49.95 321.67 320.7400760899.D 131 Field 5452738 69.38 4.03 1.15 23.64 42.57 96.60 54.20 486.24 388.8200760896.D 132 Field 5248259 41.27 0.31 0.27 19.13 41.35 53.40 54.72 314.55 278.5500760719.D 133 Field 5291999 64.92 1.81 1.62 35.57 47.42 112.67 60.79 454.24 442.1300760844.D 134 Field 5427908 38.13 0.43 0.46 25.57 49.66 62.76 62.84 379.69 412.9200760798.D 135 Field 4262618 33.11 1.32 10.93 29.08 37.82 59.43 46.68 430.15 425.58558D.12 AGI Goresorber Hydrocarbon CollectorsModule ID Site Sample Type Carbon Dioxide Carbonyl Sulfide Dimethyl Sulfide Dimethyl Disulfide Ethene/Ethane Ethane Propene Propane 1-Butene Butane00760804.D 136 Field 5443251 41.51 0.66 0.42 25.80 39.34 68.39 57.12 332.71 341.9600760762.D 137 Field 3898135 35.09 4.52 3.00 25.35 40.39 45.91 44.69 414.61 442.6000760787.D 138 Field 5114657 33.89 0.43 0.46 28.79 46.14 66.06 69.35 334.27 393.0100760860.D 139 Field 4910931 35.49 0.50 0.01 18.92 42.80 45.41 61.53 264.58 308.9400760732.D 140 Field 5938545 62.28 3.30 1.00 33.82 50.06 81.24 62.14 401.44 438.5000760746.D 141 Field 5349719 26.30 0.43 0.01 17.11 38.98 32.66 79.78 112.61 164.9600760819.D 142 Field 6027392 64.64 1.95 2.08 30.37 46.20 101.62 54.12 424.67 393.8800760821.D 143 Field 4744136 33.50 1.00 0.36 22.57 39.63 54.68 68.60 325.18 298.9700760904.D N/A Handling Blank 4384375 28.37 0.01 0.01 16.87 34.28 46.23 110.43 206.00 246.6000760739.D N/A TripBlank1 2707343 5.06 0.00 0.01 6.74 26.19 10.44 39.27 6.57 18.2300760769.D N/A TripBlank2 1832789 6.61 0.01 0.02 6.64 28.00 11.30 42.31 10.63 41.1300760777.D N/A TripBlank3 2977224 5.20 0.00 0.01 4.94 21.14 8.74 31.71 6.70 17.4000760799.D N/A TripBlank4 1598957 6.40 0.01 0.02 6.02 21.23 7.65 26.06 3.83 17.8100760807.D N/A TripBlank5 2928823 7.19 0.02 0.04 7.22 29.23 10.28 34.87 4.94 19.8600760814.D N/A TripBlank6 2897759 7.10 0.02 0.04 5.32 23.24 5.39 18.18 3.89 10.1500760841.D N/A TripBlank7 3050215 8.21 0.02 0.04 6.49 25.97 9.02 32.79 6.70 16.5700760854.D N/A TripBlank8 2995844 7.99 0.02 0.04 4.63 18.87 7.16 23.74 4.63 14.7800760863.D N/A TripBlank9 2695533 6.83 0.02 0.04 5.79 21.98 6.13 19.26 4.49 10.6500760864.D N/A TripBlank10 2915740 4.66 0.00 0.01 4.71 21.25 6.15 19.14 3.61 12.69559Module ID00760884.D00760783.D00760754.D00760829.D00760847.D00760730.D00760753.D00760836.D00760831.D00760802.D00760717.D00760815.D00760906.D00760785.D00760752.D00760823.D00760888.D00760792.D00760756.D00760744.D00760759.D00760905.D00760846.D00760773.D00760825.D00760778.D00760791.D00760871.D00760874.D00760839.D00760803.D00760856.D00760812.D00760838.DD.12 AGI Goresorber Hydrocarbon Collectors2-Methylbutane 1-Pentene Pentane Furan Carbon Disulfide Cyclopentane 2-Methylpentane 3-Methylpentane 1-Hexene Hexane 2-Methylfuran290.73 20.02 499.67 24.35 147.70 1360.44 60.04 1.45 1.49 9.34 0.391.98 3.12 28.12 14.61 0.34 52.40 340.68 0.26 0.47 0.33 0.091058.17 23.62 742.98 75.37 346.54 3820.56 427.40 1.98 2.70 9.84 0.791236.32 28.89 614.93 106.44 215.66 4167.73 1968.88 2.38 2.56 8.82 0.71594.67 10.07 487.64 78.96 118.75 3308.46 1623.99 0.77 0.87 2.09 0.19800.77 21.06 640.95 31.50 313.38 3369.91 130.09 8.26 4.17 18.16 0.923302.84 32.40 1128.79 117.79 407.45 6217.03 1289.98 4.29 3.21 12.66 1.2152.63 1.10 129.71 20.67 55.66 931.28 495.21 0.55 0.61 0.49 0.02515.12 15.75 451.69 27.79 177.41 2500.09 69.18 2.86 3.09 11.74 1.272195.60 37.10 1697.91 114.52 470.93 4762.05 178.92 10.86 6.19 29.44 1.74823.93 24.64 674.60 104.90 142.37 4113.29 259.69 3.12 2.43 8.56 0.45246.38 11.09 254.71 24.77 114.31 1272.59 38.89 3.26 1.86 7.99 0.79231.85 8.25 154.49 13.56 35.02 1775.59 38.46 0.59 0.48 1.82 0.181471.49 38.02 582.53 57.22 187.70 4195.54 206.02 4.92 1.98 7.86 0.654512.16 47.28 2377.48 146.21 799.72 5501.08 655.94 19.57 13.78 53.61 3.774401.45 906.23 1812.21 158.92 586.50 6249.63 2731.90 10.58 6.38 23.60 2.133722.54 33.21 1584.62 112.42 519.81 5808.13 718.92 10.56 7.03 32.53 1.761228.34 26.82 1399.25 37.37 407.85 1629.94 155.14 14.95 11.36 61.22 2.51255.72 9.73 317.03 20.03 90.42 1593.61 63.10 2.20 1.61 7.80 0.791229.27 550.44 988.73 90.00 323.96 3807.51 189.35 6.50 3.94 14.58 1.012658.38 26.70 1045.03 77.31 363.75 5284.11 589.31 7.71 6.33 25.73 1.71193.98 5.05 138.10 33.10 19.73 1590.59 86.72 0.19 0.31 0.37 0.05326.89 11.50 364.52 61.78 34.65 2096.80 61.76 0.47 0.62 1.80 0.273130.13 29.18 1317.41 94.62 449.59 5694.88 435.84 8.10 5.53 21.65 1.59513.95 12.36 503.78 49.62 145.60 2567.14 115.15 1.83 2.55 10.72 0.76124.24 4.63 89.53 9.05 10.97 1247.90 26.37 0.89 0.32 2.03 0.2382.12 2.38 43.16 9.34 6.09 1171.12 826.10 0.26 0.44 0.14 0.11766.49 20.84 730.27 119.71 140.95 3763.39 415.74 3.01 1.80 9.52 0.531265.68 14.10 457.30 27.83 107.22 815.19 39.00 4.30 1.87 9.32 0.292990.23 23.35 1083.81 82.14 408.86 5577.79 577.82 7.74 5.76 21.90 1.452900.00 877.65 1145.02 121.84 455.36 5940.95 688.39 11.73 5.83 21.99 1.92868.64 18.96 656.01 72.11 184.42 3367.39 201.53 2.22 2.49 9.77 0.694561.02 54.88 2419.05 179.70 854.61 4699.31 2772.25 13.04 12.07 46.45 3.69261.35 6.16 236.80 21.86 68.23 1629.02 36.41 1.64 1.10 4.19 0.73560Module ID00760901.D00760834.D00760826.D00760721.D00760806.D00760883.D00760749.D00760876.D00760862.D00760781.D00760775.D00760824.D00760832.D00760729.D00760767.D00760898.D00760800.D00760840.D00760886.D00760855.D00760907.D00760745.D00760818.D00760795.D00760735.D00760738.D00760788.D00760885.D00760736.D00760817.D00760734.D00760784.D00760833.D00760790.DD.12 AGI Goresorber Hydrocarbon Collectors2-Methylbutane 1-Pentene Pentane Furan Carbon Disulfide Cyclopentane 2-Methylpentane 3-Methylpentane 1-Hexene Hexane 2-Methylfuran701.93 22.56 664.86 46.71 187.24 2520.65 66.83 4.50 2.51 12.65 0.53992.01 18.92 729.90 73.77 247.40 3309.46 566.41 2.42 2.87 13.77 0.98328.52 20.81 950.29 27.35 116.71 1225.36 66.05 4.52 2.97 17.45 1.17420.69 26.52 969.87 52.70 160.33 1467.35 98.78 5.20 4.26 31.90 1.604583.04 1558.95 4955.73 227.20 949.64 4803.61 479.75 24.06 17.94 79.16 5.424710.24 963.29 3114.11 222.50 836.81 3899.49 6983.81 11.06 10.45 28.43 2.274213.35 985.90 3462.54 184.19 894.50 6226.71 417.59 23.83 15.14 57.80 4.924049.37 37.11 1447.41 84.49 525.48 5762.91 253.10 9.23 5.16 21.49 1.393474.69 43.86 2453.75 151.93 744.99 5549.02 404.25 21.33 16.98 85.77 5.05207.21 5.46 136.23 10.42 30.56 1777.84 31.00 0.74 1.06 3.37 1.10725.40 20.05 789.25 21.78 292.02 1841.17 78.32 8.32 5.57 26.80 1.27171.52 6.45 123.48 16.50 38.25 1442.62 492.16 0.30 0.47 0.54 0.131977.42 1483.31 4176.66 80.69 436.45 1771.82 112.64 21.04 17.22 72.55 3.722593.49 38.23 1130.17 71.04 356.62 5392.59 159.76 7.86 5.30 18.55 1.141010.47 1002.10 2367.81 70.54 517.27 2967.03 214.66 10.90 11.24 27.18 3.124250.40 1551.36 4043.22 163.06 709.82 5440.15 369.24 14.04 13.76 28.49 2.57797.04 1436.38 2807.09 43.78 293.05 2535.02 116.78 5.90 3.77 12.54 1.16275.50 7.07 366.72 28.65 80.05 1473.37 125.04 0.80 1.52 5.24 0.781096.24 1466.55 3606.19 59.32 455.84 1660.55 128.93 12.69 10.71 38.05 2.48311.80 5.55 267.00 22.45 40.62 1759.10 95.23 0.41 0.56 1.63 0.1268.72 4.05 26.07 5.20 5.59 740.23 167.47 0.52 0.50 0.44 0.17814.55 14.14 319.66 29.91 98.98 3508.75 168.27 1.85 1.58 6.40 0.78993.18 23.84 355.31 45.24 125.08 3834.51 1088.59 1.85 1.90 4.81 0.381519.25 45.69 1162.17 65.60 261.35 4325.47 596.26 4.87 4.10 20.52 0.933169.30 35.47 1354.27 102.02 490.44 5290.80 1615.22 3.86 4.06 17.22 1.11558.50 23.63 521.28 26.08 131.58 1982.71 111.83 1.06 1.85 9.08 0.48175.91 5.47 144.85 14.24 33.95 1567.01 85.22 0.43 0.70 1.78 0.783415.26 54.38 1063.56 117.08 383.33 6063.28 1063.19 6.19 4.28 18.68 1.271690.33 203.98 1075.83 75.25 473.95 4201.83 479.73 5.69 4.43 19.99 1.015292.36 1165.87 1835.14 123.68 773.70 5907.79 2078.93 11.40 9.02 34.11 2.203507.32 40.40 1137.59 76.73 387.57 5904.77 824.53 8.81 7.02 32.41 1.896169.38 924.74 3182.43 207.24 1033.08 6099.87 1196.66 26.72 16.05 67.98 3.81861.98 26.17 847.63 44.03 207.97 1388.94 608.91 0.78 2.47 10.89 0.52244.03 7.70 329.16 27.16 114.99 1247.68 45.54 1.36 1.56 6.89 0.74561Module ID00760887.D00760794.D00760890.D00760771.D00760731.D00760892.D00760820.D00760805.D00760880.D00760760.D00760873.D00760758.D00760910.D00760845.D00760740.D00760902.D00760801.D00760747.D00760893.D00760718.D00760861.D00760816.D00760843.D00760733.D00760764.D00760796.D00760859.D00760881.D00760808.D00760866.D00760813.D00760737.D00760765.D00760728.DD.12 AGI Goresorber Hydrocarbon Collectors2-Methylbutane 1-Pentene Pentane Furan Carbon Disulfide Cyclopentane 2-Methylpentane 3-Methylpentane 1-Hexene Hexane 2-Methylfuran1001.74 30.66 964.86 25.71 298.75 1139.02 57.65 7.98 4.77 25.05 1.221095.89 900.65 2488.85 74.85 416.43 1849.32 1791.38 5.49 7.44 21.96 0.961281.27 23.24 1004.39 36.30 399.07 1871.42 96.03 13.81 8.25 44.46 1.93217.60 3.19 188.51 22.56 33.94 1519.14 561.42 0.33 0.56 0.77 0.241055.25 23.71 344.89 49.39 142.60 4248.85 1028.07 1.43 1.16 4.75 0.21572.35 41.63 503.47 20.69 204.18 1620.37 52.97 7.91 5.19 17.96 0.99251.29 36.26 276.62 20.34 50.31 1484.11 33.45 2.92 2.25 3.24 0.451545.82 1498.54 3987.49 80.74 573.19 2106.98 114.76 19.36 13.36 64.74 3.50329.12 2.36 347.68 21.58 17.35 1479.85 39.53 1.97 0.83 2.04 0.50165.54 3.19 145.13 20.28 24.63 1313.84 932.49 0.29 0.55 0.54 0.222287.17 29.93 877.50 50.66 260.17 4980.45 167.32 7.85 4.27 20.57 1.041411.05 41.02 1258.52 49.83 595.41 2536.71 231.29 11.64 7.32 38.32 1.67758.54 1423.58 3065.19 63.20 372.94 1765.86 130.69 10.16 5.41 24.48 1.421163.72 16.91 473.41 59.69 148.55 3006.50 2791.83 0.51 1.11 3.34 0.26460.18 12.85 339.96 32.08 90.00 2462.95 118.00 0.92 1.41 8.78 0.412887.20 30.01 1070.78 56.46 324.29 5640.98 174.43 7.64 4.14 18.55 0.841256.48 15.58 363.35 32.33 115.81 4258.69 314.91 1.94 1.23 6.08 0.531643.82 18.71 565.93 38.33 216.55 4372.31 680.13 3.05 2.61 11.62 0.72539.83 16.64 565.93 51.75 186.97 2176.52 112.61 2.55 2.69 12.98 0.803578.20 51.12 1891.76 136.91 639.53 4534.16 1607.02 8.36 7.83 31.22 2.415247.29 1070.89 3582.65 214.87 1012.99 6643.73 440.75 25.43 14.33 53.54 3.72191.51 6.61 84.59 4.83 15.94 1563.67 14.28 0.72 0.40 1.36 0.184182.62 40.05 1608.92 108.78 457.69 5524.17 1949.18 8.92 7.58 42.07 2.58852.47 24.30 784.82 26.12 321.72 1788.00 103.02 8.98 5.23 24.90 1.33224.26 15.06 117.52 14.53 22.28 1899.94 45.57 0.59 0.94 1.63 0.43278.20 13.61 449.07 35.43 219.19 1491.06 50.50 4.18 3.10 14.19 1.715581.73 1020.80 4067.59 249.31 1064.41 6091.50 2665.95 29.32 20.59 84.75 6.51994.34 21.95 575.68 50.93 193.78 3320.83 967.92 1.41 2.62 9.06 0.93225.27 5.13 109.13 6.49 23.10 1599.11 14.84 0.91 0.77 1.20 0.40186.98 5.89 111.76 9.38 16.77 1540.92 25.50 0.73 0.46 0.95 0.053112.92 37.25 956.33 70.14 426.78 5687.62 1018.04 5.69 5.07 24.93 1.515383.64 1112.09 4747.72 301.47 1574.55 5943.61 641.16 39.43 32.37 88.09 7.691433.12 940.07 1830.33 65.06 257.91 5352.55 469.39 7.44 3.66 15.48 1.26276.07 5.74 341.82 14.39 75.94 1679.30 29.77 2.88 1.34 4.78 0.80562Module ID00760830.D00760810.D00760895.D00760755.D00760743.D00760882.D00760842.D00760889.D00760867.D00760903.D00760766.D00760748.D00760811.D00760741.D00760768.D00760865.D00760809.D00760720.D00760770.D00760793.D00760868.D00760897.D00760837.D00760776.D00760780.D00760782.D00760875.D00760742.D00760835.D00760899.D00760896.D00760719.D00760844.D00760798.DD.12 AGI Goresorber Hydrocarbon Collectors2-Methylbutane 1-Pentene Pentane Furan Carbon Disulfide Cyclopentane 2-Methylpentane 3-Methylpentane 1-Hexene Hexane 2-Methylfuran81.93 4.83 25.63 2.73 27.78 172.91 9.07 0.33 0.38 0.75 0.292818.34 33.58 1015.35 83.28 397.63 5710.67 1322.66 7.49 4.86 18.15 1.232105.85 25.07 718.58 73.97 208.66 2950.26 5544.33 0.75 1.83 3.11 0.415934.46 1083.09 3622.07 217.55 971.89 7050.62 1651.70 22.57 12.09 45.79 3.382935.55 354.81 1009.51 77.53 306.63 5316.68 384.09 7.79 3.60 13.53 1.273982.17 1097.47 3155.63 165.50 727.10 5737.32 991.17 14.81 10.00 39.52 2.442422.06 23.61 734.15 70.97 246.88 3348.60 4651.80 1.07 2.13 6.75 0.47949.72 38.09 318.25 45.46 146.43 4006.37 443.39 2.85 2.01 7.73 0.551525.51 1055.01 2994.95 142.71 773.85 3833.15 376.22 24.04 14.42 63.93 3.721845.78 926.28 1859.90 93.03 326.71 4717.75 3222.41 4.85 3.46 13.56 1.334757.66 520.67 1821.30 135.05 649.98 5691.12 2081.56 12.04 10.97 46.58 3.152395.25 740.87 666.86 86.18 269.45 4018.30 5356.69 2.18 2.72 7.24 0.483475.78 923.76 2050.56 123.06 443.83 5543.66 3872.68 7.78 5.38 19.61 1.541143.72 25.69 579.52 39.08 179.92 3916.04 110.51 4.26 2.09 9.52 0.682861.65 928.34 2114.02 101.29 399.07 5232.39 3264.74 7.71 5.12 19.36 1.751797.41 18.07 368.96 39.20 210.89 5444.23 510.14 2.30 1.59 3.99 0.413876.44 116.84 1258.62 111.93 544.54 5057.73 2804.57 7.27 6.36 24.32 1.993151.27 35.06 1236.19 98.53 434.93 5741.05 1179.97 6.45 5.21 22.44 1.341578.39 321.38 668.22 88.16 320.67 5386.94 441.23 6.96 3.80 15.73 1.281882.42 22.67 656.70 62.64 312.27 6041.82 450.27 6.55 3.83 15.23 0.773673.30 41.59 1285.34 103.45 482.43 5417.42 1914.69 6.44 7.49 30.62 2.462240.59 904.46 689.83 77.26 270.99 5326.59 2458.84 4.83 4.06 16.36 1.294748.76 634.67 1889.55 153.86 770.95 6130.39 948.17 15.70 11.73 41.57 3.042504.40 28.15 1027.10 100.58 415.18 4132.61 2946.94 3.23 4.52 14.42 1.442858.32 23.56 930.45 84.24 391.84 6538.99 428.54 9.98 5.15 20.13 1.14696.29 16.61 311.84 25.36 94.61 3054.55 39.69 2.94 1.29 5.78 0.542869.07 31.66 831.55 75.91 347.39 4414.04 3949.01 2.93 3.22 10.75 1.024969.65 75.09 2191.67 139.28 805.72 6245.15 1629.50 16.44 11.31 46.28 3.494067.67 39.80 1410.92 103.54 457.03 5004.81 2814.56 4.39 6.34 21.40 1.745325.21 58.83 2306.76 136.71 690.35 6268.72 331.73 15.67 11.04 48.07 3.013342.18 35.37 1166.89 109.98 347.71 3324.51 6332.01 2.27 4.58 14.85 1.605083.16 613.74 2486.79 179.47 792.08 5946.48 2189.47 19.64 11.58 58.23 3.524062.32 568.41 1240.99 104.98 418.58 5641.43 3031.69 5.56 6.79 25.68 1.953604.15 938.09 2235.29 106.47 390.20 5800.22 3985.81 8.14 5.10 18.37 1.27563Module ID00760804.D00760762.D00760787.D00760860.D00760732.D00760746.D00760819.D00760821.D00760904.D00760739.D00760769.D00760777.D00760799.D00760807.D00760814.D00760841.D00760854.D00760863.D00760864.DD.12 AGI Goresorber Hydrocarbon Collectors2-Methylbutane 1-Pentene Pentane Furan Carbon Disulfide Cyclopentane 2-Methylpentane 3-Methylpentane 1-Hexene Hexane 2-Methylfuran3392.78 37.32 1185.63 81.31 441.77 5952.39 1035.73 10.20 8.44 36.76 2.052812.77 914.63 2235.18 96.75 363.13 4729.13 5160.06 6.33 5.79 18.92 1.273229.21 316.00 959.09 81.29 340.13 5338.28 2136.70 4.22 4.67 16.66 1.143005.89 30.57 756.43 62.58 285.32 5457.07 1484.75 2.59 2.82 10.13 0.565075.91 321.95 1564.65 99.98 506.71 5858.95 944.59 11.48 5.05 21.52 1.16986.99 14.70 357.35 30.09 138.43 3914.95 155.32 2.82 1.91 6.88 0.335272.65 60.21 2627.82 154.88 887.35 5876.52 887.91 20.66 13.49 55.81 3.363052.72 42.24 930.80 69.98 318.70 6320.68 1093.01 7.26 4.46 19.45 1.252174.51 21.97 412.36 48.04 202.13 5805.02 1145.01 2.08 1.46 4.64 0.489.23 0.92 5.73 2.50 1.45 74.74 7.68 0.47 0.39 0.61 0.189.89 3.66 4.36 3.96 0.69 125.62 233.41 0.15 0.38 0.16 0.0044.90 1.84 8.61 1.96 2.60 539.21 141.61 0.19 0.30 0.20 0.062.21 2.32 1.89 0.75 0.52 37.24 63.39 0.11 0.29 0.19 0.031.90 5.21 6.82 1.04 0.75 29.16 6.11 0.29 0.46 0.24 0.062.03 3.26 3.49 0.64 0.83 56.48 6.45 0.26 0.28 0.15 0.0426.96 2.88 11.37 1.37 2.53 258.64 6.50 0.53 0.42 0.44 0.2221.29 3.41 7.11 1.25 2.22 245.69 5.68 0.25 0.41 0.26 0.097.23 2.92 3.75 0.76 1.34 104.04 2.94 0.30 0.45 0.36 0.122.28 2.61 4.03 0.72 0.73 75.48 73.94 0.25 0.27 0.31 0.05564Module ID00760884.D00760783.D00760754.D00760829.D00760847.D00760730.D00760753.D00760836.D00760831.D00760802.D00760717.D00760815.D00760906.D00760785.D00760752.D00760823.D00760888.D00760792.D00760756.D00760744.D00760759.D00760905.D00760846.D00760773.D00760825.D00760778.D00760791.D00760871.D00760874.D00760839.D00760803.D00760856.D00760812.D00760838.DD.12 AGI Goresorber Hydrocarbon CollectorsMethylcyclopentane 2,4-Dimethylpentane Cyclohexane Benzene 2-Methylhexane 3-Methylhexane cis-1,3-Dimethylcyclopentane7.98 1.68 7.66 1.30 1.16 1.29 0.150.17 1.14 0.20 0.17 0.40 1.09 0.4511.99 2.93 15.55 1.30 1.01 1.54 0.279.63 3.24 15.44 1.37 1.45 2.20 0.232.82 4.21 9.21 0.74 0.44 0.79 0.0412.08 1.61 16.17 1.68 1.36 2.37 0.3911.89 2.88 18.89 1.47 1.18 2.00 0.240.52 5.10 0.45 0.24 0.98 0.86 0.888.31 2.69 8.69 1.52 0.84 1.63 0.3519.28 2.99 19.13 2.09 1.80 3.12 0.466.30 1.33 10.83 1.17 1.15 1.46 0.205.70 1.38 9.76 1.31 0.80 1.22 0.272.99 1.11 3.45 0.45 0.32 0.34 0.017.65 1.57 10.84 1.75 0.89 1.57 0.3141.04 4.14 41.07 3.60 3.83 6.36 0.7819.51 4.29 31.93 1.99 2.21 3.20 0.4022.91 2.88 22.38 2.05 1.92 3.64 0.6741.17 3.88 25.25 3.17 3.76 6.68 0.656.11 1.27 7.07 0.91 1.71 1.27 0.3211.91 3.47 13.91 1.62 1.54 2.16 0.4116.23 3.23 16.85 1.63 1.98 2.95 0.351.60 2.64 2.03 0.31 0.23 0.13 0.003.18 1.82 4.37 0.51 0.33 0.33 0.0517.19 2.30 18.92 1.62 1.52 2.36 0.488.50 5.02 9.11 0.97 0.74 1.31 0.110.93 0.99 2.78 0.59 0.73 0.79 0.300.62 15.58 1.90 0.40 0.35 0.34 0.288.01 1.94 13.18 1.36 0.98 1.52 0.252.34 0.16 2.88 0.58 0.52 0.65 0.4417.06 2.94 22.37 1.60 1.63 2.70 0.3517.55 2.49 27.42 2.24 2.08 3.57 0.389.11 5.79 9.02 0.96 0.88 1.44 0.1538.64 6.53 39.46 3.27 3.76 7.24 0.614.44 0.91 6.92 0.78 1.01 1.13 0.28565Module ID00760901.D00760834.D00760826.D00760721.D00760806.D00760883.D00760749.D00760876.D00760862.D00760781.D00760775.D00760824.D00760832.D00760729.D00760767.D00760898.D00760800.D00760840.D00760886.D00760855.D00760907.D00760745.D00760818.D00760795.D00760735.D00760738.D00760788.D00760885.D00760736.D00760817.D00760734.D00760784.D00760833.D00760790.DD.12 AGI Goresorber Hydrocarbon CollectorsMethylcyclopentane 2,4-Dimethylpentane Cyclohexane Benzene 2-Methylhexane 3-Methylhexane cis-1,3-Dimethylcyclopentane9.52 4.57 9.53 1.20 0.94 1.64 0.1712.97 2.79 12.85 1.17 1.33 1.91 0.1710.18 1.32 10.49 1.13 1.69 2.05 0.4020.44 3.51 17.24 2.41 2.91 4.09 0.4237.72 6.32 37.16 5.25 6.81 10.76 0.6932.21 7.03 46.91 2.86 2.74 5.38 0.5334.76 4.02 44.81 4.29 5.02 8.01 0.9315.37 2.17 20.23 2.49 1.98 2.59 0.4437.22 4.27 29.97 5.15 6.66 10.91 0.971.82 1.97 3.00 0.85 0.65 0.89 0.3617.68 2.87 14.26 1.70 1.91 2.71 0.411.97 7.11 4.70 0.66 0.67 0.82 0.1545.47 4.33 34.42 3.85 5.03 7.97 0.7713.37 1.60 15.30 1.70 1.31 1.92 0.3317.99 2.35 19.79 3.21 2.44 3.59 0.4521.39 3.67 31.65 2.70 2.58 4.18 0.459.82 4.65 12.84 1.38 1.52 2.25 0.406.73 1.35 7.84 0.95 1.45 1.74 0.1622.12 3.15 21.93 2.28 4.40 4.97 0.543.11 4.61 3.96 0.43 0.57 0.46 0.040.57 0.58 2.37 0.61 0.36 0.49 0.235.00 2.47 7.08 0.72 0.57 1.02 0.316.39 2.40 12.30 1.09 0.80 1.35 0.2512.50 2.60 16.51 1.51 2.98 2.65 0.2919.20 5.18 24.66 1.50 2.26 2.82 0.209.14 2.78 9.06 1.04 1.25 1.19 0.172.40 1.47 3.56 0.69 0.82 0.80 0.2515.44 2.70 23.13 1.40 1.50 2.73 0.3817.45 3.35 18.06 1.69 1.69 2.31 0.2226.67 4.83 32.32 2.54 2.93 3.83 0.3718.98 8.35 21.69 2.30 2.70 3.95 0.3651.88 5.85 57.16 4.24 5.24 8.35 0.9218.29 4.78 14.34 1.38 1.26 2.76 0.278.37 1.06 8.95 1.19 0.97 1.66 0.33566Module ID00760887.D00760794.D00760890.D00760771.D00760731.D00760892.D00760820.D00760805.D00760880.D00760760.D00760873.D00760758.D00760910.D00760845.D00760740.D00760902.D00760801.D00760747.D00760893.D00760718.D00760861.D00760816.D00760843.D00760733.D00760764.D00760796.D00760859.D00760881.D00760808.D00760866.D00760813.D00760737.D00760765.D00760728.DD.12 AGI Goresorber Hydrocarbon CollectorsMethylcyclopentane 2,4-Dimethylpentane Cyclohexane Benzene 2-Methylhexane 3-Methylhexane cis-1,3-Dimethylcyclopentane18.06 1.66 12.49 1.68 1.70 2.68 0.2722.73 5.81 23.71 2.59 2.80 5.00 0.2928.65 2.34 21.31 2.50 2.54 5.03 0.523.53 1.12 5.09 0.89 0.40 0.89 0.205.88 2.06 10.61 0.97 0.72 1.16 0.3311.12 1.45 11.29 2.03 1.20 1.96 0.393.06 0.77 3.70 1.10 0.59 1.02 0.2132.31 3.42 26.67 3.99 4.86 7.68 0.904.41 0.48 5.41 0.99 0.39 0.65 0.232.12 1.36 3.74 0.58 0.36 0.98 0.2010.72 1.48 11.01 1.55 1.35 2.20 0.3032.13 4.15 29.81 2.61 2.51 4.41 0.6017.69 2.77 16.71 1.95 1.73 3.21 0.386.98 2.90 8.50 0.77 0.59 1.26 0.095.76 1.52 5.62 0.91 0.73 1.19 0.2112.63 2.19 12.71 1.36 1.14 1.82 0.365.56 1.83 9.81 0.95 0.59 0.89 0.1311.04 3.60 10.99 1.08 0.83 1.34 0.2311.47 2.47 12.00 1.16 0.99 1.76 0.3034.51 7.42 32.83 2.59 2.61 4.04 0.3037.13 4.21 43.15 3.87 4.52 7.25 0.841.22 1.76 2.11 0.49 0.20 0.35 0.0722.97 9.13 26.41 3.57 3.87 6.13 0.3320.30 2.99 17.21 1.60 1.69 3.21 0.401.72 0.72 2.71 1.23 0.59 0.79 0.1510.46 1.06 11.63 1.84 1.17 2.34 0.2445.03 5.63 54.15 5.75 7.07 11.70 1.0010.90 5.34 12.48 1.23 0.91 1.75 0.231.75 2.08 2.14 0.52 0.20 0.31 0.111.67 1.90 2.81 0.49 0.15 0.21 0.0214.77 3.03 15.95 1.69 2.03 3.09 0.2855.64 8.94 61.99 5.89 7.89 12.47 1.4410.14 1.69 16.10 1.77 1.37 2.49 0.354.27 0.70 5.13 0.69 0.16 0.44 0.23567Module ID00760830.D00760810.D00760895.D00760755.D00760743.D00760882.D00760842.D00760889.D00760867.D00760903.D00760766.D00760748.D00760811.D00760741.D00760768.D00760865.D00760809.D00760720.D00760770.D00760793.D00760868.D00760897.D00760837.D00760776.D00760780.D00760782.D00760875.D00760742.D00760835.D00760899.D00760896.D00760719.D00760844.D00760798.DD.12 AGI Goresorber Hydrocarbon CollectorsMethylcyclopentane 2,4-Dimethylpentane Cyclohexane Benzene 2-Methylhexane 3-Methylhexane cis-1,3-Dimethylcyclopentane0.91 0.87 1.39 0.14 0.08 0.18 0.0616.68 2.56 19.20 1.53 1.57 2.42 0.229.35 9.41 11.45 0.81 0.56 1.50 0.2034.34 3.87 48.08 3.45 3.80 6.47 0.9412.07 2.36 16.55 1.62 1.25 2.01 0.4427.96 3.27 35.45 3.04 2.93 5.53 0.5812.11 4.01 15.45 1.08 1.07 1.95 0.136.86 0.90 10.64 0.98 0.99 1.52 0.3439.05 4.17 34.64 4.17 5.20 7.37 1.0611.15 2.77 18.83 1.93 1.97 2.75 0.3027.97 5.86 30.88 3.22 3.70 6.01 0.419.64 4.94 18.39 1.44 1.38 2.32 0.2415.60 3.23 23.72 1.86 2.21 3.37 0.357.96 1.82 8.43 0.90 0.65 1.11 0.0615.07 5.70 22.51 1.79 2.23 3.20 0.325.76 2.60 9.17 0.86 0.65 0.97 0.2421.72 4.27 26.76 2.04 2.15 3.34 0.3817.54 4.72 19.10 1.77 1.66 2.75 0.3111.06 2.62 15.51 1.66 1.68 2.61 0.3510.79 1.59 14.60 1.21 1.11 1.88 0.3720.30 5.97 23.04 2.33 2.55 3.88 0.3010.23 3.11 16.03 1.75 1.79 2.91 0.3830.57 3.64 33.00 2.93 2.93 5.34 0.6517.65 4.90 19.77 1.47 1.39 2.93 0.2515.69 1.78 19.02 1.50 1.28 2.43 0.464.32 0.89 5.70 0.68 0.42 0.58 0.1013.79 3.68 17.35 1.22 1.16 2.15 0.2432.28 6.60 39.97 3.29 3.79 6.56 0.5121.01 6.02 25.49 2.02 2.03 3.45 0.2423.81 2.86 27.05 3.34 3.32 6.01 0.6417.07 6.50 21.78 1.72 1.74 3.80 0.3035.14 7.34 38.57 4.04 5.01 7.08 0.6619.33 5.99 23.67 2.14 2.34 4.27 0.2714.88 2.36 23.28 1.92 1.74 2.72 0.48568Module ID00760804.D00760762.D00760787.D00760860.D00760732.D00760746.D00760819.D00760821.D00760904.D00760739.D00760769.D00760777.D00760799.D00760807.D00760814.D00760841.D00760854.D00760863.D00760864.DD.12 AGI Goresorber Hydrocarbon CollectorsMethylcyclopentane 2,4-Dimethylpentane Cyclohexane Benzene 2-Methylhexane 3-Methylhexane cis-1,3-Dimethylcyclopentane19.68 2.34 21.02 2.36 3.09 4.54 0.5716.07 3.69 23.49 2.17 1.70 3.32 0.3115.56 4.38 18.87 1.60 1.48 2.25 0.1810.99 4.15 15.23 1.22 0.99 1.49 0.1518.98 3.94 22.13 1.72 1.35 2.68 0.306.66 0.98 7.80 0.72 0.42 0.72 0.1740.68 4.57 46.64 4.04 4.02 7.10 0.9316.25 3.42 20.25 1.66 1.58 2.55 0.386.47 1.40 9.16 0.98 0.62 0.95 0.150.35 0.11 3.38 0.27 0.16 0.17 0.080.23 0.56 2.34 0.37 0.16 0.41 0.040.25 0.20 0.90 0.11 0.04 0.09 0.000.18 0.00 0.37 0.07 0.00 0.00 0.000.27 0.00 0.93 0.14 0.00 0.00 0.060.20 0.12 0.13 0.10 0.00 0.04 0.000.39 0.02 1.24 0.23 0.03 0.09 0.000.31 0.17 0.28 0.15 0.00 0.00 0.030.15 0.06 0.36 0.18 0.00 0.00 0.000.33 0.21 0.41 0.11 0.00 0.00 0.01569Module ID00760884.D00760783.D00760754.D00760829.D00760847.D00760730.D00760753.D00760836.D00760831.D00760802.D00760717.D00760815.D00760906.D00760785.D00760752.D00760823.D00760888.D00760792.D00760756.D00760744.D00760759.D00760905.D00760846.D00760773.D00760825.D00760778.D00760791.D00760871.D00760874.D00760839.D00760803.D00760856.D00760812.D00760838.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,3-Dimethylcyclopentane trans-1,2-Dimethylcyclopentane 1-Heptene Heptane Methylcyclohexane 2,5-Dimethylhexane Toluene 3-Methylheptane0.36 0.70 1.89 3.39 3.44 0.79 13.88 0.800.17 0.49 1.66 0.48 0.71 1.66 0.21 0.740.39 0.88 12.13 2.92 2.88 0.45 13.77 0.600.47 0.67 1.81 2.79 3.09 0.66 13.88 1.110.21 0.91 3.59 2.47 1.36 0.35 7.56 0.420.70 1.00 1.24 3.33 3.46 1.13 18.62 0.890.46 0.83 8.97 3.25 3.04 0.68 15.96 0.610.24 0.30 10.26 1.97 0.20 0.26 0.22 0.490.47 0.66 3.35 2.05 2.42 0.96 12.35 0.510.91 0.91 0.77 4.06 5.06 0.85 25.87 0.710.35 0.36 1.51 1.89 1.88 0.43 9.94 0.590.39 0.40 0.90 1.49 2.03 0.48 8.80 0.580.08 0.40 0.97 0.49 0.71 0.15 3.31 0.170.46 0.43 0.45 1.54 2.06 0.40 8.34 0.461.52 1.99 23.66 6.51 9.22 1.66 42.31 1.750.71 1.30 1.37 3.70 4.81 0.92 23.47 0.940.98 1.80 15.72 4.19 4.88 0.70 28.01 0.741.43 2.25 2.71 5.79 8.34 1.62 46.60 1.190.25 0.35 0.82 3.05 2.30 0.46 5.98 0.970.57 0.54 0.73 3.33 3.26 0.88 17.83 1.110.68 0.89 14.99 3.69 4.74 0.83 21.36 0.650.00 0.30 1.09 1.33 0.47 0.10 2.71 0.130.12 0.33 9.32 1.89 0.72 0.18 3.94 0.410.85 1.23 2.47 3.34 3.52 0.94 20.96 0.750.28 0.80 6.85 2.30 2.13 0.48 11.40 0.550.34 0.50 6.99 1.25 0.98 0.25 1.10 0.410.23 0.16 1.34 1.88 0.62 0.28 1.96 0.360.47 0.56 1.83 2.54 2.40 0.61 10.96 1.000.29 0.25 0.72 0.62 0.77 0.31 8.28 0.310.91 1.39 5.74 3.16 4.17 0.78 28.56 0.770.76 1.01 0.65 2.89 4.82 1.01 22.78 0.860.34 0.46 9.66 2.41 2.26 0.39 11.63 0.331.28 2.15 3.00 7.29 8.94 1.33 49.38 1.540.20 0.21 0.66 1.33 1.42 0.32 159.54 0.70570Module ID00760901.D00760834.D00760826.D00760721.D00760806.D00760883.D00760749.D00760876.D00760862.D00760781.D00760775.D00760824.D00760832.D00760729.D00760767.D00760898.D00760800.D00760840.D00760886.D00760855.D00760907.D00760745.D00760818.D00760795.D00760735.D00760738.D00760788.D00760885.D00760736.D00760817.D00760734.D00760784.D00760833.D00760790.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,3-Dimethylcyclopentane trans-1,2-Dimethylcyclopentane 1-Heptene Heptane Methylcyclohexane 2,5-Dimethylhexane Toluene 3-Methylheptane0.37 0.83 11.62 2.97 2.60 0.65 14.95 0.810.44 1.45 5.24 3.21 3.03 0.44 21.22 0.700.74 0.68 0.60 3.13 3.08 0.69 10.15 0.691.10 1.37 0.51 3.73 7.73 1.59 11.69 0.931.88 3.67 2.01 10.23 13.79 2.58 73.07 3.781.16 2.21 1.12 5.01 8.41 1.15 32.79 1.032.03 2.01 1.84 7.77 10.50 2.03 50.51 1.760.78 0.80 1.00 3.32 4.17 0.68 23.66 0.802.40 2.34 43.92 12.98 12.85 2.92 111.37 2.250.27 0.15 1.23 1.02 0.77 0.38 2.32 0.770.89 1.15 4.23 3.04 4.23 0.83 23.92 0.680.15 0.31 1.33 1.13 1.26 0.92 5.72 0.531.70 2.09 1.09 7.23 10.97 2.10 51.17 1.550.63 0.73 0.48 2.40 3.43 0.58 14.30 0.420.70 1.34 2.59 4.18 3.78 0.79 11.92 2.490.93 1.64 0.88 4.35 5.84 1.23 25.60 1.180.55 0.66 0.45 2.05 2.87 0.81 15.61 1.090.29 0.48 0.82 2.24 2.39 0.47 1.67 0.761.00 1.77 1.93 6.43 7.11 1.48 33.83 1.240.14 0.34 0.98 0.98 1.07 0.32 5.30 0.460.19 0.24 0.39 0.70 0.66 0.23 1.17 0.300.35 0.44 1.07 1.75 1.22 0.33 7.99 0.380.28 0.45 0.55 1.69 1.97 0.53 8.70 0.830.31 0.69 15.47 4.65 3.74 0.65 15.99 7.790.61 1.86 12.41 4.11 5.40 0.59 25.66 0.830.27 0.68 2.59 3.43 2.76 0.40 13.99 0.500.24 0.28 1.73 1.78 1.34 0.57 3.96 0.560.50 1.13 1.12 3.66 4.19 0.70 19.53 0.750.56 1.27 16.60 3.63 4.50 0.84 25.44 1.000.94 2.10 23.21 4.65 6.10 1.11 33.96 1.240.67 1.43 11.29 5.38 5.48 0.88 27.80 0.991.72 2.82 3.59 8.68 12.18 1.94 52.69 1.390.64 1.36 1.57 4.21 4.65 0.70 25.86 0.670.43 0.42 0.55 1.24 2.89 0.76 9.62 0.54571Module ID00760887.D00760794.D00760890.D00760771.D00760731.D00760892.D00760820.D00760805.D00760880.D00760760.D00760873.D00760758.D00760910.D00760845.D00760740.D00760902.D00760801.D00760747.D00760893.D00760718.D00760861.D00760816.D00760843.D00760733.D00760764.D00760796.D00760859.D00760881.D00760808.D00760866.D00760813.D00760737.D00760765.D00760728.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,3-Dimethylcyclopentane trans-1,2-Dimethylcyclopentane 1-Heptene Heptane Methylcyclohexane 2,5-Dimethylhexane Toluene 3-Methylheptane0.77 1.21 1.43 2.42 4.38 0.83 18.20 0.780.82 1.86 1.11 4.68 7.06 1.78 33.12 1.790.97 1.47 0.42 4.93 6.26 1.68 34.56 1.590.25 0.26 0.48 1.62 1.27 0.23 5.28 0.430.42 0.43 0.36 1.67 1.97 0.56 7.07 0.830.50 0.68 1.34 2.35 2.75 0.61 12.90 0.460.24 0.19 0.56 1.74 1.11 0.44 2.60 0.681.77 1.89 1.16 7.17 10.68 1.87 56.08 1.320.25 0.19 0.36 1.44 1.66 0.29 13.00 0.340.20 0.23 0.42 2.11 1.21 0.23 11.40 0.960.67 1.16 4.53 2.42 3.37 0.60 20.69 0.540.93 1.54 4.46 4.18 6.81 1.04 34.19 1.120.74 1.16 0.86 2.97 5.25 0.83 26.76 0.750.34 0.76 9.95 2.18 2.34 0.33 13.72 0.550.29 0.40 0.63 2.27 1.88 0.39 12.05 0.330.57 0.67 1.99 2.03 3.26 0.57 16.56 0.530.25 0.53 0.63 1.55 1.38 0.43 8.71 0.580.40 0.69 15.07 2.05 2.12 0.43 12.71 0.520.57 0.73 6.28 2.80 2.65 0.52 15.78 0.500.91 2.17 16.58 5.06 8.29 0.93 36.10 0.991.75 1.95 1.26 5.71 9.77 1.77 38.12 1.450.08 0.21 0.90 0.41 0.42 0.18 2.63 0.341.02 2.38 10.53 8.05 7.86 1.23 55.03 1.430.70 0.64 1.28 3.78 4.28 0.90 25.40 0.810.14 0.20 1.01 1.70 0.69 0.22 2.87 0.960.69 0.54 0.82 2.41 3.11 0.93 26.50 0.942.32 3.30 3.19 11.42 14.47 3.84 86.07 2.580.39 0.76 14.00 2.35 2.95 0.40 14.55 0.460.17 0.29 1.78 0.80 0.41 0.29 3.54 0.140.04 0.32 0.54 0.46 0.48 0.13 2.81 0.100.59 1.16 2.52 4.20 4.13 0.77 25.09 0.933.26 3.02 3.85 11.17 17.11 3.43 68.11 2.000.54 0.85 0.88 2.20 3.07 0.53 16.37 0.760.28 0.43 1.82 1.49 0.98 0.19 2.48 0.39572Module ID00760830.D00760810.D00760895.D00760755.D00760743.D00760882.D00760842.D00760889.D00760867.D00760903.D00760766.D00760748.D00760811.D00760741.D00760768.D00760865.D00760809.D00760720.D00760770.D00760793.D00760868.D00760897.D00760837.D00760776.D00760780.D00760782.D00760875.D00760742.D00760835.D00760899.D00760896.D00760719.D00760844.D00760798.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,3-Dimethylcyclopentane trans-1,2-Dimethylcyclopentane 1-Heptene Heptane Methylcyclohexane 2,5-Dimethylhexane Toluene 3-Methylheptane0.16 0.27 0.37 0.34 0.31 0.41 2.37 0.520.39 1.19 17.78 3.10 4.03 0.65 22.88 0.630.38 0.74 6.48 2.00 2.20 0.39 13.22 0.551.67 1.79 0.90 6.34 8.47 1.71 40.67 1.720.67 0.92 0.80 2.24 3.27 0.58 13.77 0.641.23 1.66 1.76 4.70 7.49 1.30 37.35 1.090.46 1.16 16.26 2.42 3.41 0.67 19.61 0.690.44 0.38 0.50 1.68 2.12 0.50 9.28 0.851.75 2.54 1.28 6.95 11.03 1.59 46.64 1.630.54 1.34 1.08 3.19 3.61 0.65 16.39 0.611.14 2.08 2.61 7.30 8.66 1.25 51.78 1.220.43 1.01 0.80 3.06 3.26 0.61 18.92 0.500.55 1.18 1.11 2.77 4.57 0.73 18.59 1.190.34 0.85 12.57 1.48 1.80 0.42 9.07 0.390.74 1.04 0.98 3.76 4.47 0.82 20.74 0.810.21 0.33 0.32 1.03 1.17 0.44 6.33 0.490.77 1.46 27.51 3.82 4.92 0.76 26.53 0.730.67 1.08 4.65 3.55 4.55 0.61 24.14 0.540.57 0.97 0.74 2.87 3.20 0.94 15.06 0.720.50 1.02 1.52 2.45 2.84 1.21 14.62 0.690.75 1.67 3.54 5.29 6.49 0.81 32.07 0.580.63 0.98 1.19 3.69 3.84 0.90 24.00 1.041.24 1.30 13.49 5.80 7.34 0.96 36.65 0.630.62 1.36 15.35 3.63 4.12 0.74 22.59 0.860.82 0.94 1.98 2.25 3.57 1.12 16.59 0.540.25 0.62 1.35 1.20 0.98 0.29 5.44 0.250.48 0.83 9.24 3.19 3.03 0.53 15.02 0.461.18 1.89 2.85 6.44 8.71 1.65 38.29 1.070.67 1.72 24.18 4.48 5.61 0.84 27.85 0.871.30 1.69 13.92 5.80 8.00 1.59 43.42 1.030.67 1.69 8.79 4.63 5.13 0.69 33.02 0.831.15 3.15 23.67 10.08 10.41 1.81 47.97 1.230.70 2.08 30.17 4.84 6.28 0.72 31.25 0.900.69 1.04 0.57 3.50 3.89 1.05 17.75 1.11573Module ID00760804.D00760762.D00760787.D00760860.D00760732.D00760746.D00760819.D00760821.D00760904.D00760739.D00760769.D00760777.D00760799.D00760807.D00760814.D00760841.D00760854.D00760863.D00760864.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,3-Dimethylcyclopentane trans-1,2-Dimethylcyclopentane 1-Heptene Heptane Methylcyclohexane 2,5-Dimethylhexane Toluene 3-Methylheptane1.07 1.38 28.60 5.95 5.49 1.15 37.22 1.410.66 1.42 1.13 3.48 4.36 0.82 18.75 0.470.50 0.98 13.31 3.13 3.96 0.66 18.06 0.550.46 1.23 4.47 2.14 2.63 0.52 15.78 0.910.54 1.28 14.10 3.11 4.55 0.67 18.15 0.670.31 0.54 1.55 1.04 1.19 0.29 5.99 0.351.77 2.33 38.14 6.70 9.62 1.70 49.51 1.210.59 0.92 2.15 3.00 3.41 0.70 17.79 0.480.31 0.92 7.24 1.39 1.71 0.61 9.58 0.760.06 0.30 0.41 0.25 0.10 0.06 1.28 0.110.05 0.27 0.37 0.29 0.12 0.10 0.99 0.010.02 0.20 0.37 0.10 0.08 0.07 0.72 0.050.00 0.06 0.54 0.04 0.00 0.00 0.29 0.010.00 0.23 0.43 0.16 0.06 0.00 0.54 0.070.00 0.07 0.30 0.00 0.00 0.00 0.17 0.030.01 0.20 0.44 0.17 0.09 0.04 0.69 0.040.03 0.05 0.21 0.04 0.02 0.00 0.36 0.030.04 0.15 0.33 0.04 0.03 0.07 0.30 0.120.02 0.20 0.44 0.04 0.05 0.08 0.41 0.03574Module ID00760884.D00760783.D00760754.D00760829.D00760847.D00760730.D00760753.D00760836.D00760831.D00760802.D00760717.D00760815.D00760906.D00760785.D00760752.D00760823.D00760888.D00760792.D00760756.D00760744.D00760759.D00760905.D00760846.D00760773.D00760825.D00760778.D00760791.D00760871.D00760874.D00760839.D00760803.D00760856.D00760812.D00760838.DD.12 AGI Goresorber Hydrocarbon Collectorscis-1,3/1,4-Dimethylcyclohexane 1-Octene Cycloheptane cis-1,2-Dimethylcyclohexane Octane trans-1,3/1,4-Dimethylcyclohexane 2,6-Dimethylheptane1.89 3.94 0.00 0.35 2.18 0.51 0.630.17 0.49 0.36 0.27 0.62 0.19 0.962.89 1.89 0.00 0.23 1.90 0.32 0.433.72 1.95 1.46 1.24 3.12 0.51 0.762.19 1.91 0.00 0.11 1.24 0.18 0.272.56 2.02 0.06 0.23 2.56 0.35 0.544.24 2.28 0.04 0.32 1.94 0.31 0.471.18 0.64 0.00 0.18 0.21 0.25 2.333.26 40.14 0.05 0.15 1.70 0.29 0.433.35 2.23 0.00 0.36 3.43 0.54 0.640.90 2.42 0.10 0.00 1.39 0.39 1.804.31 1.52 0.37 0.36 1.36 0.69 0.482.43 1.00 0.00 0.01 0.54 0.03 0.212.77 2.22 0.01 0.09 1.32 0.21 0.374.84 6.35 0.15 0.60 7.73 0.99 0.924.00 3.93 1.28 0.42 2.85 0.88 0.382.91 3.51 0.00 0.31 3.25 0.40 0.554.25 3.55 0.05 0.65 2.51 0.91 0.774.81 1.93 0.72 0.29 2.38 0.40 0.852.94 3.55 0.42 0.30 3.09 0.75 0.574.74 2.32 0.05 0.27 2.37 0.35 0.411.12 1.30 0.00 0.03 0.46 0.06 0.363.46 1.28 0.00 0.04 1.16 0.13 0.345.13 4.90 0.00 0.30 3.78 0.50 0.533.48 8.65 0.00 0.16 1.68 0.17 0.332.61 0.97 0.40 0.20 1.06 0.31 0.363.59 28.37 0.47 0.18 1.23 0.20 0.301.86 1.32 0.00 0.00 1.41 0.13 0.332.42 1.19 0.05 0.00 1.17 0.13 0.123.30 3.11 0.00 0.23 4.53 0.51 0.714.26 2.90 0.87 0.65 3.07 0.50 0.512.29 17.02 0.03 0.14 1.32 0.18 0.314.89 13.72 0.29 0.62 5.01 0.88 0.584.05 1.59 0.54 0.22 1.11 0.25 0.60575Module ID00760901.D00760834.D00760826.D00760721.D00760806.D00760883.D00760749.D00760876.D00760862.D00760781.D00760775.D00760824.D00760832.D00760729.D00760767.D00760898.D00760800.D00760840.D00760886.D00760855.D00760907.D00760745.D00760818.D00760795.D00760735.D00760738.D00760788.D00760885.D00760736.D00760817.D00760734.D00760784.D00760833.D00760790.DD.12 AGI Goresorber Hydrocarbon Collectorscis-1,3/1,4-Dimethylcyclohexane 1-Octene Cycloheptane cis-1,2-Dimethylcyclohexane Octane trans-1,3/1,4-Dimethylcyclohexane 2,6-Dimethylheptane1.10 12.46 0.00 0.24 2.40 0.30 0.712.78 7.05 0.00 0.18 2.33 0.30 0.384.24 2.18 0.46 0.30 2.32 0.46 0.712.05 2.45 0.84 0.53 2.44 0.97 0.754.58 10.32 0.38 0.90 7.29 1.44 0.742.28 3.78 1.12 0.77 5.30 1.06 0.764.53 8.33 1.24 1.00 5.87 1.35 2.172.25 5.94 0.00 0.25 1.90 0.38 0.373.51 10.46 0.17 0.86 9.73 1.25 0.823.97 4.61 0.40 0.32 1.65 0.28 0.313.18 2.63 0.05 0.30 1.62 0.43 0.382.22 0.86 0.00 0.01 0.66 0.11 0.395.10 3.45 0.40 0.65 4.21 1.13 0.972.85 1.10 0.06 0.14 1.43 0.20 0.413.78 8.26 0.00 0.36 1.92 0.47 0.442.80 25.40 0.36 0.44 4.51 0.65 0.684.52 3.68 1.05 0.25 2.40 0.51 0.553.93 1.86 0.31 0.42 1.65 0.47 0.692.12 7.20 0.60 1.62 8.51 0.68 1.822.56 2.10 0.05 0.09 1.28 0.18 0.321.83 0.78 0.77 0.28 0.65 0.19 0.423.88 1.33 0.21 0.65 1.12 0.68 0.242.89 3.07 0.01 0.08 1.39 0.66 0.372.94 4.62 0.13 0.46 7.88 0.39 1.993.24 4.64 0.17 0.35 2.84 0.52 0.622.81 1.22 0.00 0.11 1.35 0.27 0.503.91 5.51 0.64 0.34 1.37 0.29 0.342.68 2.96 0.00 0.22 3.83 0.35 0.542.57 3.32 0.04 0.30 3.36 0.42 0.632.75 9.49 0.00 0.37 3.63 0.62 0.523.28 2.44 0.00 0.47 2.48 0.47 0.394.62 4.40 0.18 0.60 11.01 0.90 0.653.31 1.58 0.00 0.44 2.08 0.52 0.674.63 1.27 0.48 0.37 1.26 0.48 0.54576Module ID00760887.D00760794.D00760890.D00760771.D00760731.D00760892.D00760820.D00760805.D00760880.D00760760.D00760873.D00760758.D00760910.D00760845.D00760740.D00760902.D00760801.D00760747.D00760893.D00760718.D00760861.D00760816.D00760843.D00760733.D00760764.D00760796.D00760859.D00760881.D00760808.D00760866.D00760813.D00760737.D00760765.D00760728.DD.12 AGI Goresorber Hydrocarbon Collectorscis-1,3/1,4-Dimethylcyclohexane 1-Octene Cycloheptane cis-1,2-Dimethylcyclohexane Octane trans-1,3/1,4-Dimethylcyclohexane 2,6-Dimethylheptane1.68 2.76 0.00 0.41 1.84 0.62 0.702.71 8.71 0.24 0.51 5.30 2.00 1.132.87 4.80 0.00 0.65 5.80 0.64 1.473.54 1.52 0.32 0.30 1.65 0.22 0.452.27 1.92 0.00 0.02 1.97 0.22 0.591.73 2.25 0.00 0.16 1.59 0.27 0.253.90 1.19 0.42 0.17 1.29 0.32 0.434.02 4.75 0.16 0.52 5.23 0.78 1.111.00 2.21 0.36 0.56 1.18 0.17 0.554.60 1.62 0.51 0.19 1.79 0.32 0.512.39 1.61 0.00 0.16 1.47 0.25 0.334.53 2.27 0.05 0.44 3.55 0.65 0.702.28 2.67 0.85 0.39 2.39 0.67 0.713.27 1.23 0.00 0.10 1.89 0.14 0.412.42 0.87 0.00 0.00 0.80 0.08 0.281.33 1.01 0.00 0.07 1.22 0.20 0.283.48 1.01 0.00 0.04 1.60 0.10 0.343.76 1.52 0.00 0.21 1.96 0.22 0.402.63 1.10 0.00 0.22 1.37 0.26 0.261.11 2.44 0.05 0.36 4.00 0.73 0.783.29 3.31 0.00 0.65 7.30 0.89 0.893.22 0.67 0.00 0.03 0.76 0.13 0.243.47 4.03 0.07 0.53 4.04 0.73 0.453.01 1.78 0.20 0.46 3.15 0.50 0.783.39 1.46 0.66 0.45 1.58 0.25 0.514.07 2.61 0.46 0.42 3.03 0.71 0.605.26 9.37 0.74 1.29 7.27 1.42 2.192.11 1.76 0.00 0.13 1.19 0.22 0.252.89 0.76 0.00 0.03 0.38 0.03 0.292.85 0.85 0.00 0.00 0.45 0.05 0.143.07 2.14 0.00 0.21 2.07 0.38 0.505.91 8.96 0.96 0.87 8.21 1.59 0.994.12 1.90 0.16 0.23 2.03 0.34 0.421.25 1.97 0.66 0.27 1.99 0.54 0.53577Module ID00760830.D00760810.D00760895.D00760755.D00760743.D00760882.D00760842.D00760889.D00760867.D00760903.D00760766.D00760748.D00760811.D00760741.D00760768.D00760865.D00760809.D00760720.D00760770.D00760793.D00760868.D00760897.D00760837.D00760776.D00760780.D00760782.D00760875.D00760742.D00760835.D00760899.D00760896.D00760719.D00760844.D00760798.DD.12 AGI Goresorber Hydrocarbon Collectorscis-1,3/1,4-Dimethylcyclohexane 1-Octene Cycloheptane cis-1,2-Dimethylcyclohexane Octane trans-1,3/1,4-Dimethylcyclohexane 2,6-Dimethylheptane2.93 0.98 0.01 0.22 1.41 0.39 0.452.87 1.94 0.00 0.25 2.03 0.30 0.371.30 1.34 0.00 0.14 1.19 0.20 0.274.91 5.62 0.65 0.93 7.69 1.23 1.621.68 3.04 0.09 0.09 1.82 1.89 0.333.02 6.70 0.20 0.52 6.09 0.59 0.462.88 2.01 0.00 0.19 3.06 0.34 0.501.22 0.93 0.00 0.03 1.25 0.27 0.393.19 3.40 0.20 0.67 6.98 0.75 1.111.41 2.15 0.00 0.23 2.21 0.23 1.094.59 4.56 0.14 0.50 5.34 0.75 0.513.43 2.22 0.41 0.24 3.97 0.53 0.583.07 1.80 0.10 0.27 2.39 0.38 0.403.49 0.98 0.00 0.16 1.27 0.21 0.303.21 8.54 0.80 0.63 3.88 0.91 0.743.24 1.32 0.00 0.07 1.67 0.12 0.452.89 2.45 0.10 0.22 2.57 0.46 0.460.81 2.24 0.00 0.30 1.55 0.25 0.414.40 1.94 0.00 0.21 2.95 0.31 0.423.52 1.53 0.00 0.20 2.80 0.31 0.603.27 2.38 0.05 0.36 2.27 0.46 0.452.06 3.28 0.20 0.29 2.45 0.49 3.703.39 2.50 0.36 0.55 3.02 0.70 0.363.69 1.69 0.00 0.30 3.37 0.33 0.503.65 1.39 0.00 0.00 1.70 0.27 0.454.46 0.92 0.05 0.03 1.01 0.07 0.332.75 2.67 0.00 0.22 2.62 0.36 0.544.49 4.03 0.09 0.63 6.98 0.84 0.683.81 2.27 0.05 0.38 5.02 0.49 0.492.34 2.16 0.05 0.51 3.34 0.69 0.492.22 2.31 0.00 0.36 2.28 0.44 0.401.80 4.06 0.17 0.55 4.43 0.73 1.013.29 3.30 0.00 0.32 3.18 0.55 0.802.90 2.78 0.06 0.40 5.29 0.41 0.52578Module ID00760804.D00760762.D00760787.D00760860.D00760732.D00760746.D00760819.D00760821.D00760904.D00760739.D00760769.D00760777.D00760799.D00760807.D00760814.D00760841.D00760854.D00760863.D00760864.DD.12 AGI Goresorber Hydrocarbon Collectorscis-1,3/1,4-Dimethylcyclohexane 1-Octene Cycloheptane cis-1,2-Dimethylcyclohexane Octane trans-1,3/1,4-Dimethylcyclohexane 2,6-Dimethylheptane3.33 4.00 0.09 0.59 3.54 0.54 0.582.83 2.14 0.05 0.24 2.45 0.43 0.613.84 1.66 0.05 0.20 1.93 0.35 0.232.99 2.68 0.00 0.17 4.08 0.28 0.633.80 1.34 0.07 0.17 1.72 0.34 0.372.82 0.91 0.00 0.00 1.14 0.16 0.314.68 4.19 0.20 0.65 5.60 0.84 0.612.76 1.58 0.00 0.23 1.15 0.26 0.461.60 2.25 0.00 0.29 3.25 0.34 0.593.31 0.71 0.00 0.03 0.23 0.00 0.042.01 0.79 0.00 0.00 0.22 0.00 0.123.11 0.36 0.00 0.00 0.09 0.02 0.062.66 0.17 0.00 0.00 0.00 0.01 0.003.27 0.38 0.00 0.00 0.35 0.00 0.093.50 0.34 0.00 0.00 0.14 0.00 0.063.85 0.41 0.00 0.00 0.09 0.00 0.093.26 0.35 0.00 0.03 0.11 0.00 0.032.68 0.48 0.00 0.03 0.37 0.00 0.082.64 0.42 0.00 0.00 0.13 0.00 0.05579Module ID00760884.D00760783.D00760754.D00760829.D00760847.D00760730.D00760753.D00760836.D00760831.D00760802.D00760717.D00760815.D00760906.D00760785.D00760752.D00760823.D00760888.D00760792.D00760756.D00760744.D00760759.D00760905.D00760846.D00760773.D00760825.D00760778.D00760791.D00760871.D00760874.D00760839.D00760803.D00760856.D00760812.D00760838.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,2-Dimethylcyclohexane Ethylcyclohexane Ethylbenzene m,p-Xylene 1-Nonene o-Xylene Nonane Cyclooctane Propylcyclohexane alpha-Pinene0.69 1.42 2.59 5.88 2.87 2.77 4.00 2.58 1.12 13.840.48 0.22 0.26 0.71 1.05 0.52 1.79 0.46 0.27 0.230.42 0.70 1.70 3.68 2.52 1.77 3.39 2.02 0.72 9.991.35 0.75 1.85 3.88 3.57 1.78 3.44 2.18 0.62 33.840.34 0.41 0.99 2.09 1.03 0.98 1.38 0.70 0.23 3.250.62 1.83 3.84 8.31 2.61 4.18 5.31 3.47 1.57 5.850.58 0.86 2.22 5.03 3.74 2.16 3.60 1.46 0.59 1.400.29 0.52 0.48 1.69 0.57 1.02 0.88 0.77 0.54 0.240.64 1.13 1.90 3.51 4.90 1.91 3.74 3.14 0.75 1.540.63 1.70 2.71 5.78 5.08 3.30 6.84 3.55 1.20 3.630.33 0.56 1.67 2.49 4.27 1.47 2.04 0.67 0.34 0.800.46 0.40 2.73 0.39 0.74 0.22 1.34 0.98 0.44 1.100.31 0.40 0.51 1.14 0.63 0.52 0.89 0.30 0.21 0.880.28 0.49 1.07 2.65 1.25 1.17 1.93 0.77 0.26 1.041.45 2.10 6.88 14.43 6.46 6.87 15.86 8.23 2.13 6.001.24 0.90 3.69 5.23 5.79 3.21 6.83 3.13 0.77 2.960.94 1.81 2.94 6.30 2.79 2.79 5.04 5.27 0.81 15.520.83 2.64 4.27 9.49 1.09 4.65 3.40 3.60 1.69 2.420.86 0.46 2.66 0.43 2.34 0.25 4.67 2.23 0.58 0.661.20 1.07 3.33 8.44 5.53 3.96 5.24 3.86 0.89 8.790.59 0.86 1.84 3.73 2.26 1.58 3.30 2.00 0.57 3.840.26 0.31 0.49 1.09 3.97 0.56 0.96 0.53 0.20 0.730.31 0.23 0.47 1.01 3.84 0.52 1.89 1.23 0.26 0.530.90 1.98 4.51 11.01 7.37 4.89 8.39 3.53 1.16 2.410.49 0.53 1.21 2.63 6.31 1.35 3.03 1.71 0.51 11.580.73 0.28 0.16 0.47 0.86 0.41 0.84 0.59 0.33 0.410.56 0.55 0.42 0.77 2.83 0.48 1.32 0.75 0.23 3.450.43 0.40 1.47 3.02 2.97 1.47 2.29 0.89 0.40 0.980.40 0.22 0.93 1.48 0.71 0.80 2.05 0.83 0.33 0.871.25 1.48 5.49 12.62 4.85 5.98 12.07 8.46 1.65 3.931.02 0.55 2.58 2.29 2.03 1.93 5.20 1.44 0.73 2.630.45 0.40 1.17 2.48 2.15 1.13 2.11 2.75 0.40 13.660.99 2.24 5.57 11.61 3.25 5.18 7.01 5.03 1.17 28.560.27 0.39 0.78 0.91 1.27 0.10 0.54 1.35 0.21 0.17580Module ID00760901.D00760834.D00760826.D00760721.D00760806.D00760883.D00760749.D00760876.D00760862.D00760781.D00760775.D00760824.D00760832.D00760729.D00760767.D00760898.D00760800.D00760840.D00760886.D00760855.D00760907.D00760745.D00760818.D00760795.D00760735.D00760738.D00760788.D00760885.D00760736.D00760817.D00760734.D00760784.D00760833.D00760790.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,2-Dimethylcyclohexane Ethylcyclohexane Ethylbenzene m,p-Xylene 1-Nonene o-Xylene Nonane Cyclooctane Propylcyclohexane alpha-Pinene0.68 0.73 3.09 7.55 6.56 3.89 6.22 4.20 1.12 6.500.71 0.75 1.83 4.02 2.31 1.98 2.92 2.10 0.54 5.500.58 0.61 2.33 0.44 4.89 0.13 3.40 2.36 0.41 0.840.74 1.82 5.03 0.65 1.43 0.28 1.46 3.64 0.78 0.323.53 3.17 6.86 15.18 2.88 6.56 5.46 3.97 1.23 11.160.85 1.47 3.92 6.15 2.83 3.49 6.85 2.85 1.11 4.391.54 1.59 4.07 5.06 1.99 3.17 5.12 2.54 0.87 8.290.51 0.98 2.02 4.33 2.22 2.51 3.21 3.66 0.65 11.761.95 3.37 9.27 18.83 4.22 8.22 8.40 7.85 1.71 11.720.71 0.22 0.83 0.31 0.86 0.31 2.05 2.47 0.31 10.470.58 0.97 1.89 3.78 0.93 1.66 1.78 1.83 0.63 6.880.18 0.41 0.83 1.81 0.44 0.91 0.71 0.58 0.21 0.730.90 2.95 4.84 10.48 1.72 5.72 4.61 3.83 1.64 3.020.39 0.48 1.15 2.40 1.05 1.33 1.79 1.34 0.34 1.350.88 0.69 1.32 2.56 0.87 1.48 13.80 2.74 0.49 19.181.95 1.22 5.09 11.87 6.39 6.54 10.39 6.69 1.55 4.191.59 1.31 3.82 8.17 1.83 4.59 4.36 2.90 1.12 2.040.47 0.35 2.25 0.66 0.90 0.37 2.53 1.60 0.49 0.532.04 1.46 5.53 19.45 2.67 9.60 14.97 5.10 2.17 4.360.38 0.77 1.51 4.01 1.46 1.80 1.92 1.13 0.51 4.240.34 0.20 0.79 0.37 0.66 0.21 0.75 0.99 0.18 1.350.64 0.50 0.99 2.26 1.37 1.15 2.08 2.56 0.42 8.880.61 0.40 0.93 1.92 0.92 0.97 1.86 0.96 0.27 1.141.59 2.00 5.37 13.68 14.67 5.92 30.00 4.50 1.99 2.681.09 1.53 3.70 8.27 3.24 3.98 5.39 4.08 1.03 5.220.62 0.54 0.95 2.01 1.85 0.98 2.07 0.78 0.45 1.830.70 0.40 0.49 0.82 1.09 0.44 1.36 2.49 0.31 34.850.77 1.48 4.38 10.90 4.10 4.62 6.96 12.97 1.21 499.190.72 2.29 4.77 11.27 3.93 5.33 6.46 3.37 1.47 2.570.85 2.04 4.82 10.19 3.27 4.77 6.92 5.41 1.18 3.450.62 1.08 2.20 4.59 1.00 2.00 2.20 2.95 0.52 2.691.86 2.19 6.89 15.91 5.16 7.35 15.61 12.89 1.98 6.720.44 1.31 2.42 5.07 1.61 2.62 2.96 2.77 1.13 3.500.40 0.50 2.26 0.60 0.74 0.33 2.83 1.72 0.57 1.90581Module ID00760887.D00760794.D00760890.D00760771.D00760731.D00760892.D00760820.D00760805.D00760880.D00760760.D00760873.D00760758.D00760910.D00760845.D00760740.D00760902.D00760801.D00760747.D00760893.D00760718.D00760861.D00760816.D00760843.D00760733.D00760764.D00760796.D00760859.D00760881.D00760808.D00760866.D00760813.D00760737.D00760765.D00760728.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,2-Dimethylcyclohexane Ethylcyclohexane Ethylbenzene m,p-Xylene 1-Nonene o-Xylene Nonane Cyclooctane Propylcyclohexane alpha-Pinene0.67 1.94 2.11 5.44 1.88 3.06 3.80 2.34 1.09 10.011.18 3.40 9.76 23.56 2.95 11.75 7.78 5.42 2.18 3.711.31 6.68 10.20 19.72 5.64 10.95 12.15 6.96 2.89 4.670.63 0.31 1.68 0.82 0.69 0.48 1.98 1.26 0.43 0.900.53 0.61 2.24 4.61 1.66 2.45 3.61 2.92 0.62 2.100.34 0.71 1.29 2.64 1.00 1.30 1.74 0.77 0.42 2.520.34 0.24 1.42 0.58 1.06 0.35 1.84 0.63 0.34 0.851.16 1.90 4.26 8.80 3.65 5.05 17.00 4.33 1.91 6.070.76 0.30 0.76 0.13 1.44 0.80 0.70 0.96 0.23 0.110.39 0.34 1.31 1.27 0.89 0.29 4.11 2.50 0.48 0.550.42 0.46 1.47 2.83 0.98 1.50 1.72 1.46 0.42 2.220.73 2.19 4.23 9.65 4.03 4.78 7.24 3.55 1.91 3.651.27 0.87 2.22 5.28 1.06 2.63 1.67 0.80 0.62 2.320.45 0.71 1.26 3.11 1.26 1.59 2.59 1.31 0.49 1.290.24 0.25 0.81 1.77 0.83 0.81 1.12 1.04 0.16 1.040.36 0.51 1.15 2.44 0.63 1.15 1.31 0.57 0.30 1.270.51 0.54 1.28 2.84 1.08 1.26 2.38 1.47 0.37 0.930.43 0.86 1.68 3.91 1.35 1.98 2.91 2.87 0.56 1.710.43 0.64 1.72 4.67 3.98 2.03 2.33 2.09 0.58 2.910.92 2.22 4.63 10.33 4.62 5.23 7.26 9.69 1.51 4.761.53 2.31 5.00 8.59 3.81 5.04 9.84 8.66 1.34 6.150.31 0.22 0.53 1.21 1.17 0.63 1.26 0.93 0.35 0.940.92 1.73 4.22 8.63 1.77 3.91 3.17 4.50 0.89 5.120.60 2.02 4.07 9.64 3.37 4.78 6.15 2.72 1.43 3.020.65 0.13 0.90 0.54 1.55 0.14 1.58 1.05 0.26 2.610.72 0.75 5.45 0.73 1.04 0.40 2.35 1.49 0.57 1.711.94 2.60 7.64 10.22 2.78 6.46 8.05 2.83 1.17 9.990.38 0.62 1.20 2.47 0.97 1.15 1.15 0.94 0.32 2.780.30 0.21 0.30 0.89 0.37 0.41 0.64 0.81 0.15 1.540.19 0.23 0.45 1.15 0.47 0.59 0.82 0.48 0.17 0.820.49 0.83 2.20 4.96 0.99 2.25 1.95 1.68 0.41 2.311.90 1.83 5.77 5.57 5.72 4.83 12.43 4.46 1.78 18.100.87 0.51 1.48 2.63 1.04 1.41 1.79 0.73 0.30 1.820.57 0.37 0.55 1.43 0.80 0.95 1.67 0.40 0.28 0.55582Module ID00760830.D00760810.D00760895.D00760755.D00760743.D00760882.D00760842.D00760889.D00760867.D00760903.D00760766.D00760748.D00760811.D00760741.D00760768.D00760865.D00760809.D00760720.D00760770.D00760793.D00760868.D00760897.D00760837.D00760776.D00760780.D00760782.D00760875.D00760742.D00760835.D00760899.D00760896.D00760719.D00760844.D00760798.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,2-Dimethylcyclohexane Ethylcyclohexane Ethylbenzene m,p-Xylene 1-Nonene o-Xylene Nonane Cyclooctane Propylcyclohexane alpha-Pinene0.38 0.83 1.42 3.73 1.78 2.03 2.87 1.16 0.80 1.340.54 0.80 2.08 4.47 1.39 2.10 2.02 1.61 0.52 2.100.43 0.39 1.18 2.78 0.87 1.23 0.98 0.87 0.29 1.222.23 1.38 6.37 7.43 4.31 5.92 14.87 4.58 2.00 4.490.71 0.58 1.27 3.11 1.10 1.42 1.41 0.79 0.36 1.541.50 1.10 3.59 7.69 2.32 3.73 6.09 3.47 1.07 5.000.64 0.83 2.74 6.55 2.34 3.13 4.61 3.36 0.90 2.270.58 0.27 0.92 1.80 0.72 0.98 0.96 0.76 0.14 0.941.48 1.99 5.85 11.37 5.77 6.20 12.61 6.96 2.13 6.201.03 0.74 1.85 3.81 1.98 1.70 2.32 0.76 0.43 1.631.08 1.88 4.91 10.65 2.52 4.78 4.91 3.86 0.84 4.701.05 0.72 2.37 5.33 3.09 2.83 5.01 2.90 0.70 1.791.79 0.72 2.04 3.42 1.39 1.84 2.35 1.40 0.43 1.960.38 0.51 1.44 3.26 2.76 1.81 3.27 2.89 0.63 0.981.49 0.80 2.42 4.59 3.77 2.46 5.29 3.95 0.81 2.470.45 0.55 2.09 5.43 5.89 2.62 4.02 2.23 0.54 1.160.69 1.00 2.41 5.32 2.59 2.48 3.08 2.70 0.56 2.270.38 0.66 1.83 3.56 1.24 1.66 1.28 1.36 0.32 2.080.42 1.02 2.52 5.38 3.83 2.91 4.71 1.35 0.84 2.030.61 1.12 2.35 4.89 4.16 2.58 5.12 3.16 0.87 1.520.48 0.88 2.34 4.84 1.28 2.23 2.04 2.21 0.44 3.960.44 0.75 2.19 4.49 3.10 2.31 2.24 1.49 0.42 1.760.63 1.27 2.92 6.11 1.42 2.86 3.00 2.59 0.52 4.180.73 1.05 2.60 5.70 3.00 2.95 4.85 3.66 0.85 2.470.54 0.60 1.37 2.53 0.97 1.28 2.34 0.82 0.37 1.580.32 0.24 0.62 1.31 1.02 0.81 1.81 0.87 0.30 0.600.58 1.04 2.35 5.51 3.86 2.47 4.45 4.52 0.80 2.591.32 1.75 5.14 11.31 5.65 5.50 10.56 6.91 1.65 4.990.79 1.33 3.88 9.18 5.77 4.30 6.72 5.61 1.19 3.540.76 1.47 2.93 5.80 1.37 3.10 2.68 2.42 0.65 3.860.55 0.98 2.58 5.11 1.05 2.43 1.72 2.06 0.48 3.070.87 1.99 4.10 8.34 2.22 3.76 5.48 4.51 0.98 5.280.75 1.26 2.79 5.57 1.94 2.51 2.50 3.05 0.63 4.521.16 2.46 5.80 10.94 7.31 6.03 12.75 6.52 1.67 3.23583Module ID00760804.D00760762.D00760787.D00760860.D00760732.D00760746.D00760819.D00760821.D00760904.D00760739.D00760769.D00760777.D00760799.D00760807.D00760814.D00760841.D00760854.D00760863.D00760864.DD.12 AGI Goresorber Hydrocarbon Collectorstrans-1,2-Dimethylcyclohexane Ethylcyclohexane Ethylbenzene m,p-Xylene 1-Nonene o-Xylene Nonane Cyclooctane Propylcyclohexane alpha-Pinene0.94 1.34 3.38 7.04 2.17 2.99 3.00 3.86 0.59 3.660.42 0.79 1.92 4.05 2.35 2.02 3.48 4.42 0.71 17.200.39 0.65 1.58 3.26 1.32 1.53 1.96 1.81 0.41 2.410.68 1.49 4.56 11.19 6.00 4.87 7.11 5.03 1.10 2.500.41 0.60 1.34 3.13 1.78 1.46 1.70 1.20 0.37 1.950.33 0.49 0.98 2.07 2.91 1.17 2.22 2.13 0.41 0.761.33 3.36 6.21 12.86 4.48 5.91 9.66 8.57 1.75 5.500.38 0.70 1.61 3.10 1.44 1.31 1.94 1.97 0.32 1.940.78 1.10 3.75 9.66 3.30 4.35 6.34 4.44 1.51 2.490.23 0.03 0.23 0.64 0.27 0.29 0.47 0.51 0.04 0.270.25 0.00 0.18 0.53 0.22 0.25 0.46 0.46 0.00 0.280.14 0.02 0.10 0.17 0.13 0.11 0.36 0.34 0.00 0.120.08 0.00 0.08 0.24 0.00 0.08 0.17 0.52 0.00 0.030.18 0.02 0.17 0.47 0.30 0.21 0.60 0.38 0.01 0.150.09 0.03 0.04 0.12 0.11 0.02 0.42 0.46 0.00 0.050.13 0.00 0.14 0.35 0.18 0.15 0.39 0.47 0.00 0.160.17 0.00 0.06 0.13 0.15 0.07 0.33 0.47 0.00 0.030.17 0.00 0.06 0.14 0.33 0.05 0.64 0.72 0.02 0.090.16 0.00 0.06 0.15 0.13 0.04 0.25 0.39 0.00 0.09584Module ID00760884.D00760783.D00760754.D00760829.D00760847.D00760730.D00760753.D00760836.D00760831.D00760802.D00760717.D00760815.D00760906.D00760785.D00760752.D00760823.D00760888.D00760792.D00760756.D00760744.D00760759.D00760905.D00760846.D00760773.D00760825.D00760778.D00760791.D00760871.D00760874.D00760839.D00760803.D00760856.D00760812.D00760838.DD.12 AGI Goresorber Hydrocarbon CollectorsPropylbenzene 1-Ethyl-2/3-methylbenzene 1,3,5-Trimethylbenzene beta-Pinene 1-Ethyl-4-methylbenzene 1-Decene Decane 1,2,4-Trimethylbenzene1.82 3.80 1.75 6.03 1.40 37.11 15.84 4.210.26 0.48 1.10 0.44 0.43 8.80 3.79 1.290.79 1.92 1.34 1.49 0.83 39.47 16.55 2.200.97 1.65 1.76 1.54 0.75 27.71 11.29 2.140.65 0.65 0.83 1.58 0.35 13.37 4.96 0.832.11 5.91 3.01 2.73 2.20 40.64 19.16 7.090.71 1.85 1.33 0.87 0.69 26.23 10.50 2.240.35 1.18 1.72 0.13 0.76 3.29 2.00 1.480.97 2.80 1.64 1.48 1.12 70.56 26.54 3.901.57 5.04 2.39 2.97 1.73 79.79 36.40 5.690.47 1.16 1.15 0.50 0.53 17.85 6.04 1.610.27 0.98 0.50 0.63 0.44 4.91 2.71 1.070.21 0.41 0.64 0.48 0.25 8.01 3.44 0.480.41 0.94 1.79 0.46 0.51 17.68 7.67 1.203.21 9.68 4.33 4.74 3.32 117.15 71.92 10.391.20 3.15 1.75 1.51 1.14 30.95 13.76 3.332.75 4.05 2.16 9.73 1.70 82.32 40.49 4.911.66 4.50 2.67 0.94 1.67 15.03 11.73 4.920.34 1.34 0.57 1.36 0.53 6.93 2.80 2.782.00 3.44 2.76 12.75 1.43 37.08 16.25 3.750.80 1.49 0.93 1.27 0.61 24.94 12.02 1.640.21 0.47 0.61 0.52 0.25 11.10 3.50 0.750.26 0.56 0.74 0.41 0.27 18.57 6.02 0.731.48 4.16 2.18 1.73 1.42 45.83 21.70 4.151.40 1.71 1.16 3.95 0.66 38.39 14.18 1.990.21 0.51 0.54 0.67 0.42 4.96 0.92 1.040.53 0.57 0.82 1.75 0.42 20.29 5.08 1.070.57 1.68 1.61 0.61 0.65 28.24 10.50 2.070.45 1.17 0.87 0.70 0.44 16.75 8.50 1.262.50 8.65 3.88 3.72 2.78 99.71 50.08 9.100.96 2.82 1.61 1.42 1.09 35.96 19.11 2.971.68 0.99 0.94 26.24 0.86 20.34 8.79 1.194.43 4.85 2.94 10.64 2.06 66.46 37.36 5.620.18 0.70 0.31 0.55 0.24 2.05 2.43 0.53585Module ID00760901.D00760834.D00760826.D00760721.D00760806.D00760883.D00760749.D00760876.D00760862.D00760781.D00760775.D00760824.D00760832.D00760729.D00760767.D00760898.D00760800.D00760840.D00760886.D00760855.D00760907.D00760745.D00760818.D00760795.D00760735.D00760738.D00760788.D00760885.D00760736.D00760817.D00760734.D00760784.D00760833.D00760790.DD.12 AGI Goresorber Hydrocarbon CollectorsPropylbenzene 1-Ethyl-2/3-methylbenzene 1,3,5-Trimethylbenzene beta-Pinene 1-Ethyl-4-methylbenzene 1-Decene Decane 1,2,4-Trimethylbenzene1.93 4.85 3.32 4.76 1.82 77.17 33.34 5.561.18 2.21 1.58 3.21 0.89 32.16 15.87 2.550.30 1.15 0.56 4.24 0.46 2.79 3.36 1.421.14 4.49 1.16 1.35 1.50 6.99 7.08 2.691.87 2.99 3.07 1.97 1.25 31.13 17.30 3.001.38 3.62 2.03 1.91 1.37 40.75 25.02 3.761.28 2.62 1.66 2.08 0.99 30.03 14.66 2.751.63 2.02 1.40 7.36 0.94 32.47 13.77 2.282.80 5.60 3.04 3.40 2.26 91.29 46.62 6.400.28 0.85 0.45 8.61 0.35 6.89 5.14 1.050.79 1.18 1.03 3.18 0.56 11.56 5.61 1.680.20 0.39 1.05 0.24 0.23 2.35 1.41 0.571.32 3.70 4.34 0.79 1.81 9.93 8.75 3.660.35 0.78 0.98 0.64 0.65 10.32 4.29 1.093.05 1.35 1.58 59.71 1.45 7.57 5.24 1.561.97 6.35 3.79 2.08 2.43 52.71 21.49 6.521.35 4.18 2.78 1.18 1.57 17.50 10.82 5.090.40 1.22 0.71 0.60 0.48 3.29 3.35 1.792.40 7.58 4.12 1.97 2.65 14.46 15.90 8.210.72 1.43 1.06 9.89 0.68 16.87 5.86 2.250.19 0.57 0.40 0.84 0.30 7.18 3.05 0.720.95 1.34 1.04 5.74 0.50 16.69 6.91 1.390.36 0.76 1.30 0.44 0.43 11.47 4.45 0.961.61 4.74 2.53 1.84 1.68 43.38 24.40 5.371.52 3.66 2.55 4.71 1.32 35.05 13.82 4.990.33 0.67 1.09 0.74 0.37 12.33 4.41 1.011.08 0.64 0.77 14.84 0.55 13.96 4.69 1.1319.77 4.43 2.20 8.77 1.52 40.08 16.27 4.501.40 4.75 2.32 1.26 1.51 41.76 17.06 4.721.60 4.04 2.11 1.39 1.36 44.83 17.40 4.020.65 1.05 0.97 0.68 0.47 14.18 6.46 1.213.24 10.03 4.57 3.99 3.33 131.94 60.88 11.461.14 3.26 2.15 1.46 1.32 19.90 11.92 3.970.71 2.40 0.80 4.05 0.88 7.50 4.11 2.63586Module ID00760887.D00760794.D00760890.D00760771.D00760731.D00760892.D00760820.D00760805.D00760880.D00760760.D00760873.D00760758.D00760910.D00760845.D00760740.D00760902.D00760801.D00760747.D00760893.D00760718.D00760861.D00760816.D00760843.D00760733.D00760764.D00760796.D00760859.D00760881.D00760808.D00760866.D00760813.D00760737.D00760765.D00760728.DD.12 AGI Goresorber Hydrocarbon CollectorsPropylbenzene 1-Ethyl-2/3-methylbenzene 1,3,5-Trimethylbenzene beta-Pinene 1-Ethyl-4-methylbenzene 1-Decene Decane 1,2,4-Trimethylbenzene1.05 2.26 1.09 12.97 0.97 9.84 5.18 2.542.48 8.44 4.81 1.69 3.02 26.11 17.54 8.903.24 10.42 4.35 2.52 3.38 64.24 35.50 11.480.53 1.74 0.85 0.82 0.60 14.11 5.67 1.800.68 2.20 1.54 1.16 0.84 22.79 9.14 2.370.44 0.97 0.82 1.88 0.45 12.57 4.61 1.060.35 1.09 0.74 0.71 0.42 5.29 2.84 1.331.84 5.84 2.63 3.23 1.90 51.42 27.43 6.060.17 0.61 0.28 0.46 0.30 2.21 1.93 0.870.44 1.52 0.77 1.02 0.55 9.61 5.81 1.850.37 0.85 0.84 0.92 0.40 10.62 4.60 0.901.89 5.90 2.92 1.85 2.16 67.78 33.11 6.780.55 1.35 1.68 0.61 0.60 7.45 3.98 1.330.63 1.72 1.45 0.78 0.68 27.26 11.49 2.090.23 0.44 0.60 0.50 0.23 8.28 3.37 0.550.32 0.79 0.88 0.42 0.32 13.42 5.28 0.900.64 1.98 1.30 0.80 0.76 31.35 12.86 2.230.83 2.52 1.54 1.11 0.89 43.83 16.23 2.890.63 1.95 1.40 1.47 0.76 30.33 11.08 2.332.33 7.19 4.21 2.54 2.52 92.79 42.69 8.642.10 6.17 3.00 2.64 2.08 82.76 35.44 7.020.36 1.03 1.20 0.90 0.50 27.52 8.67 1.351.12 1.99 1.83 1.02 0.84 27.58 11.89 2.081.90 6.38 2.91 1.82 2.12 59.23 28.39 6.900.20 0.53 0.41 7.56 0.38 4.31 2.89 0.770.40 1.53 0.62 1.95 0.54 13.42 5.55 1.531.93 3.83 2.28 2.19 1.53 37.80 15.93 4.030.43 0.74 1.15 1.92 0.35 11.84 4.48 0.990.17 0.22 0.48 2.16 0.22 4.07 1.72 0.310.31 0.50 0.77 0.68 0.25 6.18 2.59 0.720.59 0.87 1.01 0.65 0.47 11.45 5.74 0.983.70 7.90 3.74 5.48 2.80 93.88 44.70 8.580.42 0.87 1.03 0.98 0.51 12.82 5.05 1.040.25 0.65 0.92 0.47 0.33 1.84 1.37 0.80587Module ID00760830.D00760810.D00760895.D00760755.D00760743.D00760882.D00760842.D00760889.D00760867.D00760903.D00760766.D00760748.D00760811.D00760741.D00760768.D00760865.D00760809.D00760720.D00760770.D00760793.D00760868.D00760897.D00760837.D00760776.D00760780.D00760782.D00760875.D00760742.D00760835.D00760899.D00760896.D00760719.D00760844.D00760798.DD.12 AGI Goresorber Hydrocarbon CollectorsPropylbenzene 1-Ethyl-2/3-methylbenzene 1,3,5-Trimethylbenzene beta-Pinene 1-Ethyl-4-methylbenzene 1-Decene Decane 1,2,4-Trimethylbenzene0.72 2.15 1.21 0.69 0.77 13.91 8.44 2.110.54 1.13 1.15 0.55 0.50 10.17 5.43 1.190.31 0.64 1.07 0.44 0.29 7.59 3.79 0.732.79 8.88 3.86 3.69 3.16 86.67 41.84 9.110.43 0.80 2.39 0.53 0.51 10.25 4.42 1.011.54 4.74 2.89 2.82 1.74 48.90 25.84 5.331.24 3.63 2.43 1.73 1.33 40.29 19.33 4.060.24 0.56 0.91 0.34 0.34 6.63 2.91 0.703.11 9.04 4.40 3.09 3.07 83.00 44.86 9.450.44 1.01 1.21 0.64 0.47 11.28 4.86 1.171.24 2.32 1.81 1.54 0.98 27.65 12.98 2.581.09 3.63 2.44 1.15 1.49 50.20 22.92 4.380.48 1.04 1.07 0.48 0.48 10.32 5.10 1.120.75 2.81 1.46 1.04 0.99 41.33 15.56 2.931.07 3.12 2.23 2.12 1.33 65.24 27.66 3.940.72 2.04 1.35 0.83 0.75 21.75 8.55 2.130.75 1.63 1.54 1.56 0.79 27.50 11.48 2.130.50 0.83 1.00 0.62 0.40 14.82 5.61 0.931.09 3.03 2.30 1.23 1.31 42.59 17.92 3.801.00 3.46 1.99 1.47 1.35 61.93 21.50 4.000.66 0.77 1.15 1.42 0.41 10.21 4.90 0.810.57 1.41 1.66 0.93 0.69 23.87 8.38 1.800.77 1.60 1.21 1.57 0.75 17.02 8.94 1.841.29 3.91 2.39 1.65 1.44 49.72 23.11 4.560.39 0.82 0.88 0.43 0.40 12.34 5.62 0.970.37 1.07 0.91 0.58 0.45 16.81 6.91 1.291.08 3.05 2.15 2.14 1.24 49.06 21.75 3.632.31 7.09 3.56 2.71 2.56 98.84 42.09 7.961.76 4.92 3.05 1.86 1.88 68.08 29.30 5.830.73 1.58 1.25 0.82 0.57 15.28 6.44 1.490.56 1.08 1.30 0.67 0.51 12.04 5.60 1.191.13 2.60 2.04 1.38 1.02 43.30 17.58 2.920.82 1.51 1.76 1.95 0.69 22.20 9.30 1.742.40 7.63 3.81 2.51 2.54 99.08 40.42 8.41588Module ID00760804.D00760762.D00760787.D00760860.D00760732.D00760746.D00760819.D00760821.D00760904.D00760739.D00760769.D00760777.D00760799.D00760807.D00760814.D00760841.D00760854.D00760863.D00760864.DD.12 AGI Goresorber Hydrocarbon CollectorsPropylbenzene 1-Ethyl-2/3-methylbenzene 1,3,5-Trimethylbenzene beta-Pinene 1-Ethyl-4-methylbenzene 1-Decene Decane 1,2,4-Trimethylbenzene0.86 1.84 1.26 1.00 0.64 23.42 9.04 1.881.73 2.80 1.94 8.08 1.16 50.65 20.63 3.310.53 0.94 1.23 0.95 0.48 17.02 6.94 1.211.42 4.39 2.61 1.53 1.46 52.75 22.00 4.650.47 0.92 1.24 0.50 0.42 13.67 5.08 1.060.50 1.56 1.14 0.73 0.59 30.11 11.00 1.922.39 7.21 3.44 3.63 2.59 110.25 48.08 8.220.40 0.80 0.71 1.07 0.44 18.05 8.25 1.051.48 4.48 2.33 1.23 1.48 26.91 11.55 4.010.08 0.24 0.64 0.06 0.12 0.73 0.95 0.260.04 0.07 0.85 0.02 0.16 0.55 0.59 0.210.03 0.00 0.44 0.00 0.09 0.60 0.51 0.110.01 0.00 0.31 0.00 0.05 0.17 0.31 0.080.07 0.06 0.75 0.02 0.12 0.56 0.77 0.190.01 0.02 0.34 0.00 0.08 0.28 0.32 0.050.06 0.07 0.53 0.05 0.13 1.12 0.76 0.220.03 0.03 0.35 0.00 0.09 0.76 0.52 0.070.02 0.00 0.34 0.00 0.07 0.71 0.53 0.050.04 0.00 0.42 0.02 0.08 0.44 0.37 0.08589Module ID00760884.D00760783.D00760754.D00760829.D00760847.D00760730.D00760753.D00760836.D00760831.D00760802.D00760717.D00760815.D00760906.D00760785.D00760752.D00760823.D00760888.D00760792.D00760756.D00760744.D00760759.D00760905.D00760846.D00760773.D00760825.D00760778.D00760791.D00760871.D00760874.D00760839.D00760803.D00760856.D00760812.D00760838.DD.12 AGI Goresorber Hydrocarbon CollectorsOctanal Benzofuran Indane Indene Butylbenzene 1-Undecene Undecane Nonanal 1,2,4,5-Tetramethylbenzene Camphor Dodecane Naphthalene21.81 0.16 0.92 0.27 2.67 128.25 40.69 152.79 1.73 1.18 18.27 5.3413.31 0.12 0.16 0.18 0.56 49.28 12.69 93.76 0.56 0.38 5.42 1.8331.77 0.09 0.47 0.22 1.20 49.55 21.58 146.19 0.74 0.45 16.67 2.7134.25 0.09 0.35 0.20 1.08 56.72 21.88 167.02 0.64 0.27 12.76 2.4512.90 0.04 0.13 0.09 0.73 21.54 10.93 61.29 0.35 0.50 7.37 1.3437.52 0.25 1.57 0.41 3.45 37.41 44.61 247.97 2.43 1.10 26.34 5.8136.81 0.08 0.45 0.21 0.74 41.80 14.65 144.73 0.49 0.99 8.48 1.981.95 0.00 0.19 0.17 0.77 10.28 6.55 15.11 1.15 0.53 2.08 1.6257.66 0.15 0.76 0.25 1.80 418.44 89.74 285.18 1.94 0.37 38.11 7.0965.16 0.18 0.97 0.31 3.21 226.22 53.35 370.77 2.39 0.74 40.22 5.9616.02 0.03 0.28 0.36 0.61 66.44 18.16 79.66 0.61 0.53 6.06 1.2815.45 0.04 0.17 0.25 0.48 5.62 14.72 78.75 0.64 0.46 6.36 2.3410.57 0.00 0.09 0.07 0.33 5.74 14.78 56.22 0.21 0.39 10.05 1.5729.27 0.15 0.21 0.17 0.68 4.68 15.28 130.52 0.34 0.30 17.45 2.32220.57 0.44 2.10 0.58 5.01 21.38 73.72 1061.47 2.88 0.99 106.52 10.9348.45 0.13 0.60 0.19 1.37 36.67 21.40 148.67 0.75 0.49 11.50 2.04103.09 0.31 1.00 0.33 8.54 103.43 54.87 548.09 2.08 1.69 57.58 7.0411.46 0.21 1.00 0.33 2.46 23.58 23.14 96.44 1.78 0.59 10.94 4.1311.10 0.03 0.22 0.29 0.55 22.95 13.10 48.64 0.86 0.58 3.99 1.5741.18 0.19 0.68 0.21 2.47 70.55 28.25 187.31 0.78 0.67 9.84 2.5639.20 0.04 0.31 0.17 1.11 39.82 16.17 188.79 0.70 0.53 12.16 2.3111.37 0.00 0.11 0.05 0.38 57.66 27.36 66.14 0.28 0.45 4.12 1.2958.21 0.03 0.15 0.14 0.52 163.84 27.51 204.55 0.51 0.39 11.97 2.5799.62 0.23 0.81 0.21 1.36 94.55 35.77 388.08 0.86 3.92 14.79 3.5848.68 0.08 0.42 0.20 1.45 399.45 73.85 243.96 1.17 0.89 24.30 4.503.29 0.06 0.11 0.17 0.61 82.26 8.67 34.37 1.00 0.61 2.47 2.0923.86 0.02 0.22 0.25 1.09 74.95 20.88 70.91 0.61 1.06 4.86 1.8029.34 0.09 0.41 0.13 1.12 136.23 41.87 181.98 0.91 0.54 19.49 3.0325.30 0.08 0.30 0.20 0.70 10.78 26.52 132.12 0.58 0.41 29.84 2.93160.97 0.28 1.63 0.47 3.97 27.74 85.53 748.33 2.43 0.91 112.03 10.1848.05 0.12 0.52 0.23 2.41 17.96 32.93 281.17 1.07 0.58 35.53 3.8126.52 0.00 0.27 0.13 3.05 79.63 31.35 135.00 0.44 1.37 26.15 3.29112.22 0.26 1.25 0.38 18.45 10.03 48.38 589.50 1.98 5.33 66.71 7.286.91 0.03 0.09 0.14 0.52 76.12 6.35 26.51 0.56 0.42 3.73 1.42590Module ID00760901.D00760834.D00760826.D00760721.D00760806.D00760883.D00760749.D00760876.D00760862.D00760781.D00760775.D00760824.D00760832.D00760729.D00760767.D00760898.D00760800.D00760840.D00760886.D00760855.D00760907.D00760745.D00760818.D00760795.D00760735.D00760738.D00760788.D00760885.D00760736.D00760817.D00760734.D00760784.D00760833.D00760790.DD.12 AGI Goresorber Hydrocarbon CollectorsOctanal Benzofuran Indane Indene Butylbenzene 1-Undecene Undecane Nonanal 1,2,4,5-Tetramethylbenzene Camphor Dodecane Naphthalene65.60 0.24 1.00 0.25 3.74 187.38 99.72 497.18 1.45 1.29 97.07 10.9540.63 0.07 0.49 0.24 2.28 82.72 43.60 232.76 0.81 0.69 45.95 4.697.08 0.06 0.19 0.19 0.70 22.73 9.53 27.92 0.71 1.05 4.32 1.745.44 0.11 0.60 0.44 1.60 14.99 25.25 47.92 2.46 1.19 8.75 4.5647.70 0.18 0.53 0.15 1.25 12.32 21.79 241.68 0.67 0.90 22.27 2.8468.28 0.13 0.62 0.27 2.68 5.81 30.30 366.70 1.01 1.42 38.06 4.0143.76 0.11 0.45 0.17 1.76 4.45 18.35 218.03 0.70 0.74 22.54 2.7139.77 0.11 0.49 0.15 14.93 10.99 24.19 147.17 0.71 2.07 20.46 2.71114.27 0.25 1.23 0.34 3.37 82.17 65.81 671.10 1.91 4.16 76.59 8.5847.36 0.04 0.27 0.13 1.84 16.10 20.18 132.81 0.93 1.80 9.57 3.8610.87 0.04 0.27 0.17 1.33 2.69 13.60 58.12 0.43 1.10 11.54 2.098.10 0.00 0.09 0.08 0.32 3.55 6.00 31.61 0.16 0.34 2.98 0.9919.73 0.28 0.68 0.16 1.01 9.15 11.96 96.48 0.88 0.51 7.91 1.5317.06 0.07 0.17 0.09 0.41 40.90 14.02 89.84 0.33 0.44 14.17 1.7229.30 0.09 0.23 0.17 1.31 12.24 11.64 129.50 0.46 3.28 7.62 1.9769.32 0.36 1.17 0.32 3.22 33.80 36.36 336.83 0.99 0.45 36.15 4.3027.48 0.18 0.84 0.24 1.77 7.78 23.94 183.34 1.06 0.56 27.17 4.459.16 0.07 0.24 0.21 0.43 9.28 11.06 36.23 0.57 0.38 5.01 1.6927.95 0.32 1.51 0.32 2.09 18.46 27.08 219.61 1.36 0.71 27.10 4.1515.73 0.07 0.33 0.10 0.95 23.80 27.81 129.67 0.50 0.49 17.63 3.829.37 0.00 0.15 0.11 0.54 15.16 14.34 39.11 0.75 0.55 9.50 3.3741.08 0.03 0.32 0.17 4.95 38.15 31.25 159.42 0.40 2.45 23.98 2.6542.52 0.05 0.14 0.17 0.63 5.50 13.82 147.09 0.35 0.48 16.48 2.0264.38 0.40 1.04 0.30 1.43 40.84 56.80 310.45 1.27 0.85 50.11 5.6126.40 0.19 0.85 0.21 1.53 12.30 21.13 178.63 0.52 0.88 19.96 2.6116.50 0.01 0.18 0.08 0.60 47.26 25.99 98.89 0.32 0.36 20.07 2.2733.66 0.00 0.17 0.12 1.93 34.10 30.15 111.89 0.58 1.55 25.18 3.6059.52 0.23 0.97 0.24 1.58 32.36 37.04 310.41 0.73 0.53 50.55 3.7931.01 0.21 0.96 0.25 1.39 31.63 37.20 221.48 0.87 0.77 30.46 3.6441.67 0.23 0.80 0.23 1.12 4.95 20.51 233.36 0.69 0.52 21.20 2.5326.34 0.07 0.25 0.11 0.55 2.59 11.62 123.90 0.32 1.27 14.91 1.49187.53 0.58 2.10 0.64 4.67 16.76 70.10 1359.20 3.06 2.01 168.72 8.7722.58 0.16 0.85 0.26 1.99 76.62 36.04 170.88 1.41 0.70 35.39 5.3616.28 0.09 0.46 0.26 1.94 38.37 15.01 66.61 1.45 0.92 9.59 4.71591Module ID00760887.D00760794.D00760890.D00760771.D00760731.D00760892.D00760820.D00760805.D00760880.D00760760.D00760873.D00760758.D00760910.D00760845.D00760740.D00760902.D00760801.D00760747.D00760893.D00760718.D00760861.D00760816.D00760843.D00760733.D00760764.D00760796.D00760859.D00760881.D00760808.D00760866.D00760813.D00760737.D00760765.D00760728.DD.12 AGI Goresorber Hydrocarbon CollectorsOctanal Benzofuran Indane Indene Butylbenzene 1-Undecene Undecane Nonanal 1,2,4,5-Tetramethylbenzene Camphor Dodecane Naphthalene9.41 0.09 0.45 0.15 5.67 17.56 11.97 51.98 0.44 0.51 4.67 1.5644.15 0.47 1.55 0.31 2.47 16.79 39.99 293.07 1.60 0.84 41.52 5.5225.02 0.58 2.23 0.53 3.39 49.99 65.24 203.22 2.84 1.11 56.59 9.5530.06 0.09 0.34 0.16 1.08 24.29 37.11 147.64 0.98 0.36 25.69 4.6630.30 0.09 0.38 0.19 1.18 11.11 23.85 136.30 0.66 0.34 26.57 2.6618.28 0.00 0.25 0.18 1.50 14.89 17.31 69.60 0.42 0.88 14.03 2.4917.70 0.08 0.26 0.19 0.86 22.99 17.64 76.00 0.71 0.36 10.22 3.5864.91 0.25 1.07 0.30 2.14 36.00 45.66 339.70 2.08 0.59 67.14 5.667.12 0.04 0.07 0.10 0.45 6.54 4.90 22.94 0.55 0.35 3.03 1.4222.13 0.09 0.31 0.11 0.74 25.49 20.87 85.40 0.97 0.59 11.28 4.2023.24 0.00 0.19 0.10 0.91 2.32 13.23 93.07 0.33 0.50 13.53 1.4541.18 0.26 1.51 0.40 3.40 16.11 49.81 275.80 1.84 0.85 72.07 6.3910.89 0.07 0.27 0.10 0.93 4.76 8.52 61.00 0.31 0.42 6.95 1.6433.91 0.02 0.48 0.17 1.28 22.76 38.25 229.79 0.78 0.35 50.03 4.0812.22 0.00 0.11 0.10 0.63 12.01 12.54 65.41 0.24 0.57 12.69 1.3515.39 0.02 0.17 0.09 0.54 6.39 18.97 100.02 0.51 0.32 21.25 2.1839.38 0.01 0.38 0.18 1.07 19.24 52.50 263.43 1.08 0.72 61.48 4.6352.06 0.07 0.58 0.20 1.32 26.10 51.64 306.16 1.09 1.27 64.32 5.2924.18 0.08 0.50 0.23 1.55 197.80 54.12 169.23 0.96 0.37 50.92 4.98103.21 0.41 1.58 0.46 3.94 163.67 88.08 738.45 1.84 1.20 152.98 8.8894.17 0.28 1.23 0.40 3.32 7.51 48.86 623.58 1.86 0.93 101.44 6.0835.08 0.00 0.24 0.16 1.25 45.31 61.19 206.41 1.05 0.52 71.66 6.1330.02 0.12 0.41 0.24 0.84 13.99 20.47 187.28 0.48 0.88 25.40 2.3041.32 0.29 1.36 0.44 2.79 48.89 63.74 304.48 2.21 0.77 73.29 8.5310.63 0.05 0.09 0.17 1.58 15.70 10.16 36.76 0.41 1.41 6.37 1.7511.80 0.11 0.34 0.26 0.94 11.57 14.19 40.60 0.59 0.62 17.34 1.8069.46 0.20 0.80 0.23 2.20 6.71 27.59 329.07 0.93 0.92 34.48 3.0419.02 0.05 0.18 0.16 1.54 8.37 15.15 85.06 0.30 0.98 15.45 2.238.76 0.01 0.11 0.10 3.17 2.05 6.65 34.42 0.21 0.26 5.28 1.0110.30 0.03 0.15 0.09 1.25 8.81 13.96 89.67 0.32 0.37 11.84 2.4719.24 0.01 0.21 0.17 0.64 4.65 11.65 101.17 0.28 0.70 13.90 1.57153.77 0.32 1.81 0.48 6.41 36.63 77.32 917.27 2.92 1.86 115.55 8.0226.30 0.03 0.21 0.20 5.05 3.89 18.25 95.04 0.34 0.88 17.39 1.987.11 0.08 0.11 0.08 0.33 4.36 4.07 36.23 0.28 0.42 3.02 1.14592Module ID00760830.D00760810.D00760895.D00760755.D00760743.D00760882.D00760842.D00760889.D00760867.D00760903.D00760766.D00760748.D00760811.D00760741.D00760768.D00760865.D00760809.D00760720.D00760770.D00760793.D00760868.D00760897.D00760837.D00760776.D00760780.D00760782.D00760875.D00760742.D00760835.D00760899.D00760896.D00760719.D00760844.D00760798.DD.12 AGI Goresorber Hydrocarbon CollectorsOctanal Benzofuran Indane Indene Butylbenzene 1-Undecene Undecane Nonanal 1,2,4,5-Tetramethylbenzene Camphor Dodecane Naphthalene10.12 0.06 0.45 0.17 0.69 4.41 12.88 64.66 0.44 0.27 8.66 1.3318.55 0.05 0.24 0.16 0.53 5.70 13.37 100.44 0.33 0.30 15.06 1.5920.85 0.02 0.16 0.08 0.35 4.57 12.43 84.72 0.21 0.49 13.91 1.60181.45 0.39 1.79 0.56 5.25 18.82 80.19 924.48 2.58 4.52 108.83 8.6718.83 0.01 0.14 0.12 0.54 3.35 11.14 100.25 0.25 0.27 13.36 1.4888.85 0.23 1.07 0.35 3.16 9.40 49.62 598.14 1.50 0.96 73.98 4.8572.57 0.14 0.83 0.31 1.93 12.26 46.29 449.93 1.11 0.69 63.66 4.5010.98 0.02 0.13 0.03 0.52 5.95 10.39 51.87 0.25 0.36 9.82 1.26110.77 0.44 2.04 0.49 4.30 14.21 58.55 632.45 2.37 0.66 106.76 7.6827.90 0.07 0.18 0.17 0.61 18.03 10.22 87.06 0.34 0.69 6.07 1.3460.23 0.10 0.47 0.26 1.26 16.60 17.53 271.65 0.59 0.89 18.92 1.9379.31 0.14 0.79 0.30 2.07 68.18 52.73 481.79 1.41 0.88 43.83 4.5831.98 0.00 0.18 0.18 0.63 9.16 9.77 118.24 0.46 0.42 7.52 1.3924.45 0.12 0.49 0.16 1.28 193.72 40.22 191.36 1.26 0.76 25.93 3.46117.04 0.13 0.77 0.30 2.35 63.73 47.19 494.20 1.49 0.81 51.08 4.8847.12 0.07 0.45 0.29 0.85 38.00 17.05 157.83 0.50 0.55 10.41 1.6953.06 0.12 0.45 0.19 1.02 42.53 23.38 256.82 0.81 0.68 21.15 2.6023.96 0.00 0.19 0.21 0.50 18.06 11.60 99.00 0.32 0.56 8.32 1.0574.19 0.16 0.70 0.29 1.84 107.28 50.51 346.32 1.24 0.45 33.58 4.0781.02 0.08 0.77 0.30 1.90 187.91 77.98 442.88 1.65 0.96 43.99 5.7124.56 0.03 0.18 0.11 0.74 9.03 7.87 95.36 0.26 0.38 6.74 1.1349.33 0.10 0.27 0.14 0.84 53.34 25.61 196.00 0.67 0.43 17.14 2.3746.09 0.12 0.41 0.24 0.79 11.23 12.07 200.18 0.58 0.59 14.20 1.6093.83 0.16 0.85 0.29 3.47 145.65 55.42 541.78 1.39 0.86 47.73 4.5440.58 0.03 0.22 0.15 0.67 6.05 23.70 172.21 0.48 0.92 27.46 2.7749.45 0.02 0.27 0.15 0.70 73.18 33.54 222.76 0.76 0.54 37.70 4.0888.34 0.10 0.77 0.22 2.38 101.24 43.59 431.26 1.25 0.92 39.34 4.00141.34 0.33 1.64 0.40 3.38 74.79 67.10 902.60 2.23 1.71 71.05 7.3891.57 0.24 1.08 0.31 2.57 105.73 59.14 589.61 1.27 0.83 50.16 4.8120.51 0.06 0.27 0.13 0.55 8.23 10.26 110.31 0.54 0.55 8.06 1.2721.43 0.02 0.26 0.12 0.45 2.85 9.41 108.43 0.36 0.24 8.07 1.3840.90 0.11 0.51 0.24 1.16 6.77 14.53 194.44 0.64 0.40 17.16 1.9628.00 0.04 0.34 0.17 2.88 10.50 12.68 147.25 0.44 0.60 11.72 1.62139.65 0.44 1.66 0.43 3.01 88.97 62.19 786.20 2.98 1.01 59.95 6.92593Module ID00760804.D00760762.D00760787.D00760860.D00760732.D00760746.D00760819.D00760821.D00760904.D00760739.D00760769.D00760777.D00760799.D00760807.D00760814.D00760841.D00760854.D00760863.D00760864.DD.12 AGI Goresorber Hydrocarbon CollectorsOctanal Benzofuran Indane Indene Butylbenzene 1-Undecene Undecane Nonanal 1,2,4,5-Tetramethylbenzene Camphor Dodecane Naphthalene34.89 0.08 0.31 0.19 0.67 21.51 14.80 155.64 0.58 0.51 13.40 1.7358.65 0.19 0.66 0.27 11.08 101.21 43.65 350.18 1.52 0.80 41.95 3.6319.84 0.04 0.26 0.19 1.50 19.97 13.17 110.57 0.38 0.74 8.64 1.3069.03 0.23 0.91 0.28 1.68 72.64 38.82 379.56 1.00 0.60 25.55 3.5720.06 0.06 0.22 0.13 0.50 30.46 12.66 101.51 0.36 0.72 8.14 1.2839.07 0.07 0.37 0.18 0.95 124.37 34.68 216.32 0.94 0.43 21.02 2.72146.67 0.31 1.68 0.48 3.51 45.87 52.26 799.81 2.72 1.05 78.61 6.3437.71 0.01 0.17 0.14 0.55 23.88 8.92 124.02 0.40 0.49 7.49 1.4830.03 0.38 0.97 0.24 1.16 1.51 7.16 126.66 0.49 0.36 9.52 1.396.27 0.00 0.00 0.09 0.15 0.33 1.57 21.96 0.10 0.44 2.45 0.418.35 0.00 0.00 0.05 0.20 0.31 1.04 27.66 0.04 0.44 1.25 0.444.37 0.00 0.00 0.14 0.10 0.23 0.86 12.41 0.02 0.39 1.27 0.432.29 0.00 0.00 0.03 0.06 0.33 0.75 8.31 0.01 0.59 1.11 0.294.95 0.00 0.03 0.08 0.21 0.41 1.20 27.41 0.02 0.40 1.84 0.453.14 0.00 0.00 0.13 0.09 0.21 0.56 12.24 0.01 0.47 1.07 0.354.84 0.00 0.01 0.07 0.14 0.33 1.26 16.34 0.03 0.33 1.76 0.473.66 0.00 0.00 0.05 0.12 0.25 0.88 10.83 0.02 0.33 2.05 0.5015.60 0.00 0.00 0.05 0.12 0.45 0.94 36.06 0.01 0.28 1.47 0.513.49 0.00 0.01 0.04 0.08 0.25 0.80 8.10 0.00 0.44 0.92 0.33594Module ID00760884.D00760783.D00760754.D00760829.D00760847.D00760730.D00760753.D00760836.D00760831.D00760802.D00760717.D00760815.D00760906.D00760785.D00760752.D00760823.D00760888.D00760792.D00760756.D00760744.D00760759.D00760905.D00760846.D00760773.D00760825.D00760778.D00760791.D00760871.D00760874.D00760839.D00760803.D00760856.D00760812.D00760838.DD.12 AGI Goresorber Hydrocarbon CollectorsDecanal Benzothiazole Tridecane 2-Methylnaphthalene Tetradecane Caryophyllene Acenaphthylene Pentadecane Hexadecane Heptadecane Pristane58.33 3.16 38.57 2.98 20.55 265.39 0.64 115.31 29.06 19.47 11.8390.69 1.08 13.85 0.72 7.68 2.32 0.16 61.43 8.75 55.49 3.6283.26 1.46 49.43 1.30 22.85 38.94 0.35 124.49 18.21 57.94 11.8686.43 1.17 22.06 0.99 18.95 2.19 0.25 48.42 12.87 15.65 6.6733.39 1.10 15.58 0.56 14.02 11.08 0.22 65.26 9.99 28.36 7.3379.04 2.98 32.97 2.89 21.46 31.96 0.56 81.74 20.63 11.09 9.8981.37 1.65 12.58 0.68 10.58 3.01 0.23 27.67 8.10 14.20 3.115.22 0.57 5.98 0.71 2.78 1.36 0.35 8.08 3.70 0.73 0.50130.11 5.64 162.22 3.71 56.43 13.02 0.79 160.69 42.35 41.28 14.49104.04 2.89 154.14 2.57 41.48 7.88 0.39 80.26 23.81 9.92 6.9728.10 1.24 24.13 0.57 7.73 3.78 0.22 26.38 4.10 11.80 1.7459.56 1.27 11.66 1.01 8.30 1.14 0.22 36.53 12.89 30.55 8.9619.34 1.07 18.35 0.69 18.39 10.61 0.18 27.54 11.93 9.95 8.2572.27 0.96 32.46 1.00 44.10 21.41 0.23 60.50 31.29 19.63 18.05345.57 4.04 118.50 5.54 241.30 2.58 0.83 311.32 498.81 397.37 262.1387.77 1.25 21.39 0.73 19.99 3.03 0.23 56.04 24.15 14.17 8.03237.33 3.65 67.55 3.45 74.37 83.34 0.66 165.16 89.20 32.18 19.7235.15 1.70 18.19 1.98 10.19 44.17 0.36 66.16 12.56 13.91 3.8841.95 1.06 12.00 0.68 5.39 2.75 0.14 29.72 6.63 13.51 2.7636.46 0.91 20.37 0.84 10.98 9.39 0.20 42.75 7.36 12.82 4.3091.69 1.43 23.51 1.02 18.85 2.78 0.26 60.55 18.05 20.45 6.0721.96 0.77 16.26 0.41 6.20 12.04 0.16 26.98 5.86 8.54 2.65192.08 1.95 48.34 1.01 26.13 5.12 0.32 72.74 32.20 27.20 11.35207.28 1.76 67.52 0.99 15.98 35.69 0.25 69.09 12.89 56.69 5.20185.21 3.12 375.77 2.28 38.70 6.39 0.54 113.39 29.84 63.03 9.7730.34 1.74 6.46 1.03 3.65 5.49 0.38 14.71 8.33 9.03 1.9130.73 1.13 23.50 0.73 9.69 3.33 0.24 102.93 9.22 53.46 8.8471.19 1.91 101.29 1.73 30.40 2.77 0.59 73.08 17.31 12.08 6.2148.09 1.62 68.77 1.89 92.79 4.95 0.56 109.51 108.81 56.34 55.30214.02 4.86 139.01 5.71 297.99 7.72 1.17 370.79 618.55 445.34 311.1562.73 1.81 70.00 2.18 90.84 5.74 0.36 112.30 116.81 73.38 54.3154.83 2.33 64.59 1.78 68.19 9.47 0.43 92.13 46.77 34.92 24.70189.87 3.88 72.81 3.71 137.33 47.13 0.55 157.87 177.38 120.73 80.0216.78 0.89 5.67 0.64 5.19 3.09 0.13 13.60 4.11 10.31 3.25595Module ID00760901.D00760834.D00760826.D00760721.D00760806.D00760883.D00760749.D00760876.D00760862.D00760781.D00760775.D00760824.D00760832.D00760729.D00760767.D00760898.D00760800.D00760840.D00760886.D00760855.D00760907.D00760745.D00760818.D00760795.D00760735.D00760738.D00760788.D00760885.D00760736.D00760817.D00760734.D00760784.D00760833.D00760790.DD.12 AGI Goresorber Hydrocarbon CollectorsDecanal Benzothiazole Tridecane 2-Methylnaphthalene Tetradecane Caryophyllene Acenaphthylene Pentadecane Hexadecane Heptadecane Pristane89.19 4.40 156.41 5.56 310.00 12.59 1.01 409.94 573.04 295.89 347.4073.18 2.75 74.47 2.93 117.75 4.62 0.57 126.56 117.03 57.55 48.5619.56 1.03 12.16 0.87 6.54 8.13 0.33 19.30 4.48 6.26 3.4022.05 1.02 13.10 1.99 6.03 4.33 0.33 37.43 5.53 25.67 3.6667.51 1.16 33.50 1.17 47.50 1.36 0.15 58.03 41.77 16.82 22.4997.76 1.42 42.62 2.01 74.33 3.96 0.37 84.32 75.97 31.93 36.3972.62 0.99 26.36 1.37 44.87 2.64 0.25 53.02 49.50 23.22 21.2150.31 1.52 38.20 1.30 57.54 14.77 0.23 69.04 74.51 31.14 31.35176.63 3.96 120.96 4.75 206.72 4.99 1.00 240.32 418.64 281.86 179.2362.84 1.55 19.27 1.86 11.42 32.42 0.43 60.90 5.93 22.75 10.0234.83 1.14 17.15 1.02 24.11 6.25 0.17 31.83 17.56 8.19 9.1621.18 0.64 6.81 0.30 6.05 14.08 0.11 30.56 5.40 29.81 5.1425.16 0.50 10.45 0.42 7.56 2.64 0.10 25.09 4.48 19.67 5.0837.63 1.25 25.59 0.74 46.64 10.58 0.18 80.91 100.38 104.34 44.37119.29 1.01 10.46 0.60 9.76 51.37 0.14 28.05 8.34 33.96 4.2356.62 1.52 47.07 1.61 81.90 8.33 0.32 132.62 107.56 45.17 45.2942.67 1.23 30.69 1.55 25.58 4.27 0.22 45.76 15.21 8.79 7.6123.91 1.32 8.67 0.69 7.63 9.18 0.11 17.01 4.91 11.68 4.3239.60 0.65 28.65 1.53 34.05 2.10 0.15 64.52 25.81 16.14 17.1945.94 1.75 43.59 1.90 42.60 31.79 0.44 148.00 51.64 90.53 40.3722.36 1.31 15.14 2.18 11.87 5.22 0.49 53.80 9.88 13.72 7.7580.57 1.91 85.51 1.27 62.52 16.35 0.28 133.66 90.26 106.17 31.03121.25 1.00 30.97 0.84 45.72 9.97 0.22 96.66 35.72 71.79 23.2988.20 2.42 85.68 2.51 105.14 15.03 0.38 139.44 99.06 62.27 44.8344.98 1.43 23.18 1.00 25.20 4.26 0.20 89.91 13.70 112.58 16.1543.65 1.28 40.16 1.23 69.45 2.34 0.30 219.37 113.29 159.37 63.0965.77 2.42 42.42 2.20 53.59 3.93 0.51 162.84 40.72 126.03 31.8266.98 1.65 51.63 1.59 64.68 11.15 0.32 103.72 80.60 69.22 31.2258.68 1.72 42.46 1.65 61.31 2.78 0.47 101.44 59.13 45.94 26.8152.92 1.36 25.23 0.85 31.34 1.56 0.23 71.35 34.86 48.83 12.4945.35 1.19 21.09 0.72 35.11 2.78 0.21 65.94 52.06 51.52 17.94256.85 2.68 87.71 4.01 168.35 4.67 0.61 219.23 388.59 234.67 143.8281.18 1.64 38.97 2.78 52.40 2.17 0.53 101.07 71.14 56.23 34.9838.72 2.07 16.04 2.41 10.93 4.56 0.39 36.91 9.33 11.45 7.19596Module ID00760887.D00760794.D00760890.D00760771.D00760731.D00760892.D00760820.D00760805.D00760880.D00760760.D00760873.D00760758.D00760910.D00760845.D00760740.D00760902.D00760801.D00760747.D00760893.D00760718.D00760861.D00760816.D00760843.D00760733.D00760764.D00760796.D00760859.D00760881.D00760808.D00760866.D00760813.D00760737.D00760765.D00760728.DD.12 AGI Goresorber Hydrocarbon CollectorsDecanal Benzothiazole Tridecane 2-Methylnaphthalene Tetradecane Caryophyllene Acenaphthylene Pentadecane Hexadecane Heptadecane Pristane22.15 0.76 7.11 0.50 4.60 4.75 0.13 10.80 3.37 6.97 1.9272.70 1.49 46.16 2.64 50.36 4.82 0.35 86.38 77.84 37.97 30.7445.49 3.18 74.30 4.67 88.86 6.92 0.72 130.23 83.57 49.27 44.23101.84 2.23 50.61 2.91 79.08 3.62 0.55 196.81 159.87 139.29 85.3235.09 1.02 35.94 1.25 41.75 4.22 0.27 58.73 20.65 24.90 9.0830.81 1.25 42.31 1.19 41.87 10.25 0.30 85.31 54.35 69.25 26.3946.85 1.65 21.71 2.08 33.31 3.89 0.34 68.04 45.35 27.59 27.6299.62 2.48 61.89 2.97 116.74 2.13 0.44 132.85 154.91 71.88 43.6819.44 1.12 5.54 0.62 4.76 0.68 0.14 8.28 3.88 3.70 5.0278.29 2.18 30.22 2.43 19.26 2.36 0.31 42.27 17.36 16.84 10.7244.53 1.09 24.40 0.70 47.17 12.36 0.20 69.35 104.96 44.68 26.8967.93 1.82 59.66 3.86 106.51 1.29 0.65 125.37 83.66 32.29 29.9016.25 0.37 10.24 0.61 12.28 4.32 0.14 26.40 8.86 6.20 5.0372.00 1.60 89.17 2.46 152.47 3.00 0.52 160.04 140.87 51.85 42.8730.23 0.73 25.77 0.74 41.50 7.80 0.25 67.40 49.15 39.82 16.3321.34 0.89 45.70 1.30 81.02 2.41 0.32 128.03 91.22 52.16 28.9253.99 1.92 125.08 3.10 225.16 3.66 0.79 247.78 298.46 119.36 80.2879.15 2.74 116.57 3.27 210.83 23.97 0.87 242.96 373.36 168.10 95.9137.23 2.37 206.59 2.93 161.88 5.32 0.60 171.37 215.54 93.53 61.03163.00 3.60 592.79 4.66 219.12 4.26 0.93 259.11 410.44 166.78 130.10141.18 2.02 72.78 2.78 124.63 9.33 0.48 133.28 188.73 83.21 60.3473.72 3.02 217.60 3.83 272.15 6.09 0.85 327.37 499.35 236.49 154.5332.35 1.49 37.66 1.07 55.55 13.77 0.26 58.09 37.98 13.05 13.7095.59 3.36 86.24 4.47 168.22 3.47 0.72 227.94 355.94 210.33 127.0530.78 1.33 11.68 0.92 9.58 2.85 0.22 18.58 4.88 10.36 3.5523.07 0.95 17.94 1.01 30.64 1.64 0.22 41.53 26.97 18.25 10.7297.19 1.18 40.74 1.31 76.08 4.00 0.26 100.40 93.94 47.91 27.9728.70 1.14 24.60 1.06 46.58 5.96 0.29 66.32 47.74 29.23 16.9817.96 1.06 8.98 0.53 11.67 0.94 0.17 20.85 7.77 9.93 5.7829.95 0.91 23.99 1.25 32.10 3.88 0.31 76.91 56.35 32.50 32.2139.81 1.14 23.79 0.72 43.31 21.28 0.32 54.97 84.44 42.83 23.53197.58 1.93 228.65 4.09 174.73 4.92 0.51 177.66 227.51 68.32 53.6653.77 0.91 29.75 1.05 67.67 8.39 0.28 111.05 70.39 59.11 23.7315.37 1.22 6.74 0.67 9.25 1.47 0.25 23.03 10.56 13.29 6.09597Module ID00760830.D00760810.D00760895.D00760755.D00760743.D00760882.D00760842.D00760889.D00760867.D00760903.D00760766.D00760748.D00760811.D00760741.D00760768.D00760865.D00760809.D00760720.D00760770.D00760793.D00760868.D00760897.D00760837.D00760776.D00760780.D00760782.D00760875.D00760742.D00760835.D00760899.D00760896.D00760719.D00760844.D00760798.DD.12 AGI Goresorber Hydrocarbon CollectorsDecanal Benzothiazole Tridecane 2-Methylnaphthalene Tetradecane Caryophyllene Acenaphthylene Pentadecane Hexadecane Heptadecane Pristane20.41 0.45 9.60 0.50 8.58 1.63 0.11 28.14 5.96 8.61 5.7234.25 0.97 20.83 0.83 39.98 4.22 0.25 52.59 24.48 14.59 12.2426.70 0.80 27.99 0.76 53.32 2.68 0.27 73.33 123.91 54.81 32.01214.25 2.93 144.37 4.81 326.34 4.01 1.23 380.11 713.70 299.75 174.7426.79 0.73 25.77 0.77 44.92 8.40 0.22 54.10 32.31 11.97 13.58116.79 1.55 83.53 2.58 160.96 7.20 0.52 180.71 295.85 114.67 76.5293.76 1.71 93.94 2.55 188.47 2.94 0.55 208.40 309.53 130.28 80.1015.24 0.51 17.97 0.58 27.71 2.46 0.17 31.34 16.95 7.79 7.44179.79 1.94 68.26 3.84 117.95 3.55 0.49 136.63 126.12 49.31 41.2139.23 0.55 14.50 0.41 6.96 11.09 0.14 14.47 3.88 2.24 1.4196.60 1.17 17.49 0.79 13.39 3.43 0.24 33.62 8.80 2.96 2.28121.46 1.57 71.24 2.01 38.10 10.62 0.39 71.74 28.30 6.76 6.7260.68 0.84 14.27 0.46 10.03 13.78 0.17 21.47 7.62 4.58 3.5252.84 1.60 71.00 1.75 31.07 2.93 0.36 79.23 21.33 5.74 6.35206.73 2.47 77.01 2.66 61.15 5.62 0.57 129.61 57.71 16.16 13.2763.83 1.22 25.51 0.76 12.07 4.67 0.24 34.34 9.36 2.90 2.66127.13 1.92 53.97 1.24 29.84 1.62 0.38 68.91 31.42 9.97 6.8141.77 1.97 16.27 0.63 12.06 2.05 0.22 33.12 15.89 7.83 5.80140.49 2.25 98.15 1.99 44.99 3.27 0.42 104.81 42.73 19.37 13.34212.66 3.23 229.01 2.81 64.02 2.39 0.67 138.44 57.30 17.23 15.9658.50 1.03 12.08 0.39 10.16 6.40 0.18 28.81 8.61 8.02 3.6477.06 1.28 45.81 1.20 22.59 5.81 0.30 49.52 20.99 11.24 7.3587.29 1.36 17.64 0.64 14.73 3.11 0.16 36.38 13.75 10.08 5.58173.84 2.56 144.70 2.23 44.69 6.85 0.43 96.29 40.51 17.55 10.99145.75 1.23 57.44 1.45 112.44 3.21 0.58 139.11 179.49 92.37 46.40103.80 1.73 160.16 2.33 144.81 4.06 0.46 153.28 143.80 48.32 37.39145.88 2.37 75.16 2.02 36.80 4.62 0.42 85.92 21.51 4.62 5.02222.16 3.66 101.73 3.10 53.41 12.64 0.70 118.15 37.72 6.68 7.85126.78 2.31 106.01 2.13 44.17 5.59 0.52 95.10 33.97 8.11 7.5138.03 0.80 11.10 0.47 7.13 1.94 0.14 14.30 4.77 1.69 0.9134.81 0.89 8.54 0.54 8.46 1.43 0.17 19.68 4.44 1.47 1.4454.79 1.65 11.36 0.89 7.79 16.19 0.21 17.79 4.32 1.91 1.1044.62 1.17 17.06 0.68 13.15 3.40 0.22 30.97 9.56 2.42 2.56236.06 2.69 111.79 3.01 65.41 8.02 0.64 146.67 66.53 22.33 12.58598Module ID00760804.D00760762.D00760787.D00760860.D00760732.D00760746.D00760819.D00760821.D00760904.D00760739.D00760769.D00760777.D00760799.D00760807.D00760814.D00760841.D00760854.D00760863.D00760864.DD.12 AGI Goresorber Hydrocarbon CollectorsDecanal Benzothiazole Tridecane 2-Methylnaphthalene Tetradecane Caryophyllene Acenaphthylene Pentadecane Hexadecane Heptadecane Pristane52.75 1.40 19.11 0.75 13.29 5.61 0.25 33.47 9.35 2.47 1.94153.00 1.92 81.76 1.93 46.29 3.54 0.37 111.85 61.80 25.15 11.9246.67 0.94 21.69 0.58 10.05 3.61 0.23 24.00 5.52 1.75 2.03139.48 1.76 84.04 1.40 24.44 2.13 0.36 59.22 16.69 4.40 3.8040.04 0.64 15.16 0.57 10.30 2.48 0.16 27.36 7.54 1.75 2.36101.50 1.58 91.24 1.65 39.64 1.93 0.43 103.99 52.91 21.33 11.99235.98 2.51 47.89 2.89 46.49 5.85 0.52 108.99 52.68 17.83 11.51101.47 0.92 24.34 0.48 12.95 9.77 0.16 30.16 15.69 6.83 4.7424.90 0.74 3.47 0.25 2.22 0.69 0.06 2.46 1.43 0.87 0.8218.09 0.65 2.97 0.10 2.56 0.22 0.02 1.81 1.04 0.75 0.9319.34 0.37 2.06 0.06 1.51 0.07 0.01 0.81 0.53 0.41 0.4320.60 0.46 2.25 0.07 2.35 0.30 0.02 1.98 2.54 1.88 1.079.46 0.33 2.01 0.02 2.06 0.00 0.00 1.53 1.49 0.57 1.1633.76 0.40 2.32 0.08 2.76 0.21 0.01 2.88 5.01 3.79 2.3920.52 0.39 2.01 0.04 2.96 0.71 0.01 2.54 5.32 3.20 2.1214.55 0.71 3.40 0.08 2.62 0.22 0.01 1.39 0.65 0.55 0.5417.55 0.85 3.08 0.12 3.60 0.21 0.01 1.81 1.98 0.60 0.6557.89 0.70 1.79 0.07 1.55 0.39 0.02 1.01 1.55 0.54 0.4011.54 0.54 1.34 0.04 1.27 0.15 0.01 0.75 0.73 0.52 0.48599Module ID00760884.D00760783.D00760754.D00760829.D00760847.D00760730.D00760753.D00760836.D00760831.D00760802.D00760717.D00760815.D00760906.D00760785.D00760752.D00760823.D00760888.D00760792.D00760756.D00760744.D00760759.D00760905.D00760846.D00760773.D00760825.D00760778.D00760791.D00760871.D00760874.D00760839.D00760803.D00760856.D00760812.D00760838.DD.12 AGI Goresorber Hydrocarbon CollectorsOctadecane Phytane24.05 19.512.62 3.7614.89 13.219.61 8.287.19 4.9622.55 17.255.25 4.220.74 0.8237.59 26.5611.94 11.242.71 1.9314.86 7.416.42 5.2210.84 9.35472.13 225.4624.76 15.7298.23 53.2312.75 7.933.68 4.843.83 2.8318.38 10.804.76 2.8634.59 21.408.66 4.1423.47 14.334.76 2.547.31 4.8815.76 10.0241.01 34.21479.90 253.1457.30 34.6714.68 13.63105.14 61.123.10 3.83600Module ID00760901.D00760834.D00760826.D00760721.D00760806.D00760883.D00760749.D00760876.D00760862.D00760781.D00760775.D00760824.D00760832.D00760729.D00760767.D00760898.D00760800.D00760840.D00760886.D00760855.D00760907.D00760745.D00760818.D00760795.D00760735.D00760738.D00760788.D00760885.D00760736.D00760817.D00760734.D00760784.D00760833.D00760790.DD.12 AGI Goresorber Hydrocarbon CollectorsOctadecane Phytane331.92 216.3444.76 32.575.06 4.444.01 3.0114.20 14.4622.40 19.2516.61 12.7616.79 19.29305.91 145.3713.61 7.818.42 7.024.41 2.040.98 0.9241.07 29.735.23 3.2120.77 22.056.38 5.302.55 5.1611.10 10.7832.91 23.2011.79 7.8934.30 19.0410.41 7.8432.13 25.443.63 2.8241.73 31.6823.00 18.0028.20 18.5514.93 13.648.89 7.7615.54 10.49217.12 103.8542.57 24.818.83 6.57601Module ID00760887.D00760794.D00760890.D00760771.D00760731.D00760892.D00760820.D00760805.D00760880.D00760760.D00760873.D00760758.D00760910.D00760845.D00760740.D00760902.D00760801.D00760747.D00760893.D00760718.D00760861.D00760816.D00760843.D00760733.D00760764.D00760796.D00760859.D00760881.D00760808.D00760866.D00760813.D00760737.D00760765.D00760728.DD.12 AGI Goresorber Hydrocarbon CollectorsOctadecane Phytane1.41 1.1538.19 23.2840.02 27.76106.44 60.485.56 4.0223.92 14.8125.99 21.3243.71 25.391.77 6.8812.20 7.8726.73 15.7724.94 16.085.32 3.2939.60 24.5916.30 9.1524.15 16.4786.21 45.19185.60 69.9479.80 34.46184.24 77.8467.81 36.08204.98 103.3311.94 7.70222.21 96.264.28 2.4612.69 6.4825.92 15.2718.27 9.794.87 3.3334.93 23.4238.38 16.9155.04 33.2822.28 11.695.51 5.15602Module ID00760830.D00760810.D00760895.D00760755.D00760743.D00760882.D00760842.D00760889.D00760867.D00760903.D00760766.D00760748.D00760811.D00760741.D00760768.D00760865.D00760809.D00760720.D00760770.D00760793.D00760868.D00760897.D00760837.D00760776.D00760780.D00760782.D00760875.D00760742.D00760835.D00760899.D00760896.D00760719.D00760844.D00760798.DD.12 AGI Goresorber Hydrocarbon CollectorsOctadecane Phytane5.54 3.558.29 6.2352.81 24.83342.16 124.0710.61 8.60132.23 59.72150.88 65.116.84 3.5247.29 27.352.34 1.437.33 4.0021.22 11.626.86 4.1919.55 14.6445.77 24.517.38 4.4928.48 15.1621.43 13.7440.31 24.6052.48 31.847.66 5.0618.96 11.3212.37 8.0837.33 22.4174.32 27.8127.45 19.6916.76 9.3628.21 16.3127.63 14.532.75 1.754.23 2.432.54 1.797.47 4.6155.83 29.56603Module ID00760804.D00760762.D00760787.D00760860.D00760732.D00760746.D00760819.D00760821.D00760904.D00760739.D00760769.D00760777.D00760799.D00760807.D00760814.D00760841.D00760854.D00760863.D00760864.DD.12 AGI Goresorber Hydrocarbon CollectorsOctadecane Phytane9.69 5.1958.42 26.534.80 2.7314.50 8.806.11 4.1761.50 30.8756.88 30.1416.60 11.070.83 1.001.03 0.930.54 0.482.65 1.510.92 1.154.73 2.444.08 2.860.35 0.630.52 0.610.52 0.550.84 0.50604605 Appendix E: Data Interpretation from Activation Laboratories and AGI. Inc. Data interpretation given by Activation Laboratories upon completion of the SGH analysis is included in this section as Appendix E.1. Data interpretation given by AGI. Inc. upon completion of hydrocarbon analysis from the Goresorber™ Hydrocarbon Collectors is included herein as Appendix E.2. Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 1 of 52 3D - SGH “A SPATIOTEMPORAL GEOCHEMICAL HYDROCARBON INTERPRETATION” AURORA GEOSCIENCES LTD. SGH TEST SURVEY 606Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 2 of 52 (this page purposely left blank) 607Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 3 of 52 SGH – SPATIOTEMPORAL GEOCHEMICAL HYDROCARBON PREDICTIVE GEOCHEMISTRY for AURORA GEOSCIENCES LTD. SGH TEST SURVEY November 27, 2015 * Dale Sutherland, Activation Laboratories Ltd (* - author, originator) EVALUATION OF SAMPLE DATA - EXPLORATION FOR: “KIMBERLITE” TARGETS THE SGH KIMBERLITE INTERPRETATION TEMPLATE IS USED FOR THIS REPORT Workorder: A15-09729 608Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 4 of 52 Table of Contents PREFACE .............................................................................................................................................................. 6 DISCLAIMER ......................................................................................................................................................... 7 CAUTIONARY NOTE REGARDING ASSUMPTIONS AND FORWARD LOOKING STATEMENTS ...................................... 8 SPATIOTEMPORAL GEOCHEMICAL HYDROCARBON (SGH) GEOCHEMISTRY – OVERVIEW ...................................... 10 SGH DATA QUALITY............................................................................................................................................ 13 SGH DATA INTERPRETATION .............................................................................................................................. 14 SGH CHARACTERISTICS ....................................................................................................................................... 15 INTERPRETATION OF SGH RESULTS - A15-09729 – AURORA GEOSCIENCES LTD. – SGH TEST SURVEY ................... 16 SGH TEST SURVEY SGH SURVEY - SAMPLE LOCATION MAP ........................................................................................... 16 GH SURVEY INTERPRETATION - A15-09729 – AURORA GEOSCIENCES LTD. - QUALITY ASSURANCE SGH TEST SURVEY ............................................................................................................................................................ 17 A15-09729 – AURORA GEOSCIENCES LTD. - SGH TEST SURVEY - SGH TARGET PATHFINDER CLASS MAPS ..................... 18 A15-09729 – AURORA GEOSCIENCES LTD - SGH TEST SURVEY- SGH INTERPRETATION RATING AND CLARIFICATION ... 20 A15-09729 – AURORA GEOSCIENCES LTD. - SGH TEST SURVEY - SGH “REDOX” INTERPRETATION ................................ 21 A15-09729 – AURORA GEOSCIENCES LTD. - SGH TEST SURVEY - SGH “KIMBERLITE” INTERPRETATION ....................... 22 A15-09729 – AURORA GEOSCIENCES LTD. - SGH TEST SURVEY - SGH “KIMBERLITE” PATHFINDER CLASS .................... 24 A15-09729 – AURORA GEOSCIENCES LTD. - SGH TEST SURVEY - SGH INTERPRETATION GOALS .................................. 26 A15-09729 – AURORA GEOSCIENCES LTD. - SGH TEST SURVEY - SGH INTERPRETATION FOR “KIMBERLITE” FORMATIONS .................................................................................................................................................................. 27 A15-09729 – AURORA GEOSCIENCES LTD. - SGH TEST SURVEY - SGH SURVEY RECOMMENDATIONS .......................... 29 GENERAL RECOMMENDATIONS FOR ADDITIONAL OR IN-FILL SAMPLING FOR SGH ANALYSIS ....................................... 29 CERTIFICATE OF ANALYSIS .................................................................................................................................. 30 APPENDIX “B” .................................................................................................................................................... 35 EXAMPLE OF AN SGH FORENSIC GEOCHEMICAL SIGNATURE EXAMPLE SHOWN FOR A VMS TARGET .................. 35 APPENDIX “C” .................................................................................................................................................... 40 APPENDIX “D” .................................................................................................................................................... 41 609Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 5 of 52 APPENDIX “E” .................................................................................................................................................... 42 SGH DATA QUALITY............................................................................................................................................ 42 REPORTING LIMIT ................................................................................................................................................................ 42 LABORATORY REPLICATE ANALYSIS ......................................................................................................................................... 42 HISTORICAL SGH PRECISION ................................................................................................................................................. 43 LABORATORY MATERIALS BLANK – QUALITY ASSURANCE (LMB-QA) .......................................................................................... 43 APPENDIX “F” .................................................................................................................................................... 45 SGH DATA INTERPRETATION .............................................................................................................................. 45 SGH INTERPRETATION REPORT .............................................................................................................................................. 45 SGH PATHFINDER CLASS MAGNITUDE ............................................................................................................................ 45 GEOCHEMICAL ANOMALY THRESHOLD VALUE ............................................................................................................... 45 MOBILIZED INORGANIC GEOCHEMICAL ANOMALIES .................................................................................................................. 46 THE NUGGET EFFECT ............................................................................................................................................................ 46 SGH DATA LEVELING ........................................................................................................................................................ 47 APPENDIX “G”.................................................................................................................................................... 48 SGH RATING SYSTEM DESCRIPTION .................................................................................................................... 48 HISTORY & UNDERSTANDING ......................................................................................................................................... 49 APPENDIX “H” .................................................................................................................................................... 52 610Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 6 of 52 PREFACE THIS “STANDARD” SGH INTERPRETATION REPORT: The purpose of this Spatiotemporal Geochemical Hydrocarbon interpretation (SGH), previously called Soil Gas Hydrocarbon; “Standard Report” is to ensure that clients and other potential reviewers of the results have a good understanding of this organic, deep penetrating geochemistry. As SGH provides such a large data set and is not interpreted in the same way as an inorganic geochemical method, this interpretation and report enables the user to realize the results in a timely fashion and capitalizes on years of research and development since the inception of SGH in 1976 combined with the knowledge obtained by Activation Laboratories through the interpretation of SGH data from over hundreds of surveys for a wide variety of target types in various lithologies from many geographical locations. Although referenced today as a “nano-technology”, the analysis of SGH has not changed since inception. The report is compulsory as it is the only known organic geochemistry that, in spite of the name, uses non-gaseous semi-volatile organic compounds interpreted using a forensic signature approach. It is typically based solely on SGH data and does not include the consideration or interpretation from any other geochemistry (inorganic), geology, or geophysics that may exist related to this survey area(s). This report can also provide evidence of project maintenance. To keep the price to a minimum and to provide as short a turnaround time as practically possible, usually only one SGH Pathfinder Class map is illustrated in a “Standard Report” with an applied interpretation although several other SGH Pathfinder Class maps are used and referenced. Definitions of certain terms or phrases used in this report can be found in Appendix A. A Supplemental Report, GIS package, and/or interpretations for other target types are available. (See Appendix H). The interpretation in this report has used the results from some of the research with SGH in recent years which has focused on the potential that the SGH data might be able to further dissect and understand the relationships between the chemical Redox conditions in the overburden the development of an electrochemical cell and its affect in shaping geochemical anomalies. This research has resulted in the development by Activation Laboratories of a new enhanced model of the Electrochemical/ Redox Cell theory originated by Govett (1976) that was further developed to the model by Hamilton (2004, 2009). The new enhanced model developed by Sutherland (2011) takes the general anomalies expected by the Hamilton model to a higher level of detail and specificity. This has resulted in a more confident level of interpretation which has been referenced as 3D-SGH or 3D-“Spatiotemporal Geochemical Hydrocarbons. This model has been formally introduced at the International Applied Geochemistry Symposium (IAGS) organized by The Association of Applied Geochemists that took place in Rovaniemi, Finland, in August 2011. This new level of understanding of the expected anomaly types that can be observed with SGH provides a new level of quality control in the interpretation process as the symmetry of SGH anomalies can assure the interpreter which anomalies are as a result of a buried target. With the enhanced 3D-SGH interpretation that was introduced in 2012, we also mark the beginning of the ability to make some statements regarding the possible depth to mineralization for some projects as we dissect the Redox cell relative to the new Electrochemical Cell theory. The cover of this report is an artist’s rendering of the pathways of different classes of Spatiotemporal Geochemical Hydrocarbons which migrate through the overburden. This model is used as the new 3D-SGH interpretation approach. 611Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 7 of 52 DISCLAIMER This “SGH Interpretation Report” has been prepared to assist the user in understanding the development and capabilities of this Organic based Geochemistry. The interpretation of the Spatiotemporal Geochemical Hydrocarbon (SGH) data is in reference to a template or group of SGH classes of compounds specific to a type of mineralization or target that is chosen by the client (i.e. the template for gold, copper, VMS, uranium, etc.). The various templates of SGH Pathfinder Classes that together define the forensic identification signature for a wide range of commodity target types; Gold, Nickel, VMS, SEDEX, Uranium, Cu-Ni-PGE, IOCG, Base Metal, Tungsten, Lithium, Polymetallic, and Copper, as well as for Kimberlites, Coal Seam, Wet Gas and Oil Play, have been developed through years of research and have been further refined from review of case studies and orientation studies has proven to be able to also address a wide range of lithologies. Even with 15+ years of development and experience with SGH, Activation Laboratories Ltd. cannot guarantee that the templates used are applicable to every type of target in every type of environment. The interpretation in this report attempts to identify an anomaly that has the best SGH signature in the survey for the type of mineralization or target chosen by the client. However, this interpretation is not exhaustive and there may be additional SGH anomalies that may warrant interest. It should not be viewed due to the generation of this SGH report, that Activation Laboratories Ltd. has the expertise or is in the business of interpreting any type of geochemical data as a general service. As the author is the originator of the SGH geochemistry, has researched and developed this exploration tool since 1996, and has produced similar interpretations using SGH data for close to 1,000 surveys, he is perhaps the best qualified to prepare this interpretation as assistance to clients wishing to use this SGH geochemistry. Activation Laboratories Ltd. can offer assistance in general suggestions for sampling protocols and in sample grid design; however we accept no responsibility to the appropriateness of the samples taken. Activation Laboratories Ltd. has made every attempt to ensure the accuracy and reliability of the information provided in this report. Activation Laboratories Ltd. or its employees do not accept any responsibility or liability for the accuracy, content, completeness, legality, or reliability of the information or description of processes contained in this report. The information is provided “as is” without a guarantee of any kind in the interpretation or use of the results of the SGH geochemistry. The client or user accepts all risks and responsibility for losses, damages, costs and other consequences resulting directly or indirectly from using any information or material contained in this report or using data from the associated spreadsheet of results. 612Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 8 of 52 Cautionary Note Regarding Assumptions and Forward Looking Statements The statements and target rating made in the Spatiotemporal Geochemical Hydrocarbon (SGH) interpretive report or in other communications may contain or imply certain forward-looking information related to the quality of a target or SGH anomaly. Statements related to the rating of a target are based on comparison of the SGH signatures derived by Activation Laboratories Ltd. through previous research on known case studies. The rating is not derived from any statistics or other formula. The rating is a subjective value on a scale of 0 to 6 relative to the similarity of the SGH signature reviewed compared to the results of previous scientific research and case studies based on the analysis of surficial samples over known ore bodies. No information on the results from other geochemical methods, geophysics, or geology is usually available as additional information for the interpretation and assignment of a rating value unless otherwise stated. The rating does not imply ore grade and is not to be used in mineral resource estimate calculations. References to the rating should be viewed as forward-looking statements to the extent that it involves a subjective comparison to known SGH case studies. As with other geochemical methods, an implied rating and associated anticipated target characteristics may be different than that actually encountered if the target is drilled tested or the property developed. Activation Laboratories Ltd. may also make a scientifically based reference in this interpretive report to an area that might be used as a drill target. Usually the nearest sample is identified as an approximation to a “possible drill target” location. This is based only on SGH results and is to be regarded as a guide based on the current state of this science. Unless otherwise stated, Activation Laboratories Ltd. has not physically observed the exploration site and has no prior knowledge of any site description or details or previous test results. Actlabs makes general recommendations for sampling and shipping of samples. Unless stated, the laboratory does not witness sampling, does not take into consideration the specific sampling procedures used, or factors such as the season of sampling, samples handling, packaging, or shipping methods. The majority of the time, Activation Laboratories Ltd. has had no input into sampling survey design. Where specified Activation Laboratories Ltd. may not have conducted sample preparation procedures as it may have been conducted at the client’s assigned laboratory external to Actlabs. Although Actlabs has attempted to identify important factors that could cause actual actions, events or results to differ scientifically which may impact the associated interpretation and target rating from those described in forward-looking statements, there may be other factors that cause actions, events or results that are not anticipated, estimated or intended. In general, any statements that express or involve discussions with respect to predictions, expectations, beliefs, plans, projections, objectives, assumptions, future events or performance are not statements of historical fact. These “scientifically based educated theories” should be viewed as "forward-looking statements". 613Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 9 of 52 Readers of this interpretive report are cautioned not to place undue reliance on forward-looking information. Forward looking statements are made based on scientific beliefs, estimates and opinions on the date the statements are made and the interpretive report issued. The Company undertakes no obligation to update forward-looking statements or otherwise revise previous reports if these beliefs, estimates and opinions, future scientific developments, other new information, or other circumstances should change that may affect the analytical results, rating, or interpretation. Actlabs nor its employees shall be liable for any claims or damages as a result of this report, any interpretation, omissions in preparation, or in the test conducted. This report is to be reproduced in full, unless approved in writing. The unauthorized reproduction, translation, adaptation, or reverse engineering of the analytical method or interpretational protocols of SGH as Spatiotemporal Geochemical Hydrocarbons (SGH), Soil Gas Hydrocarbons (SGH) as it pertains to the analysis and use of hydrocarbons in the C5 through to C17 carbon series range, or the Organo-Sulphur Geochemistry (OSG) constitutes an infringement of Copywright and the exclusive rights of the author. 614Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 10 of 52 SPATIOTEMPORAL GEOCHEMICAL HYDROCARBON (SGH) GEOCHEMISTRY – OVERVIEW In the search for minerals and elements, geology requires tools to assess the location and potential quantity of minerals and ores. In the past people looked at the landscape to find the deposit. Similar landscapes indicate similar mineral and metal deposits. This is searching on a macro level, while geochemistry is searching on a micro level. Organic material requires many minerals and elements, so organic materials can be biomarker of the present of the minerals and elements. SGH is a deep penetrating geochemistry that involves the analysis of surficial samples from over potential mineral or petroleum targets. The analysis involves the testing for 162 hydrocarbon compounds in the C5-C17 carbon series range applicable to a wide variety of sample types. The hydrocarbons are residues from the decomposition of bacteria and microbe that feed on the target commodity as they require inorganic metallic’s to catalyze the reactions necessary to develop hydrocarbons and grow in their life cycle. Specific classes of hydrocarbons (SGH) have been successful for delineating targets found at over 900 metres in depth. Samples of various media have been successfully analyzed such as soil (any horizon), sand, till, drill core, rock, peat, humus, lake-bottom sediments and even snow. After preparation in the laboratory, the SGH analysis incorporates a very weak leach, essentially aqueous, that only extracts the surficial bound hydrocarbon compounds and those compounds in interstitial spaces around the sample particles. These are the hydrocarbons that have been mobilized from the target depth. SGH is unique and should not be confused with other hydrocarbon tests or traditional analyses that measure C1 (Methane) to C5 (Pentane) or other gases. Thus, in spite of the previous name as Soil Gas Hydrocarbons, SGH does not analyze for any hydrocarbons that are actually gaseous at room temperature and can be used to analyze for hydrocarbons in sample types other than soil. SGH is also different from soil hydrocarbon tests that thermally extracts or desorbs all of the hydrocarbons from the whole soil sample. This test is less specific as it does not separate the hydrocarbons and thus does not identify or measure the responses as precisely. These tests also do not use a forensic approach to identification. The hydrocarbons in the SGH extract are separated by high resolution capillary column gas chromatography and then detected by mass spectrometry to isolate, confirm, and measure the presence of only the individual hydrocarbons that have been found to be of interest from initial research and development and from performance testing especially from the two Canadian Mining Industry Research Organization (CAMIRO) projects (97E04 and 01E02). Over the past 15+ years of research, Activation Laboratories Ltd. has developed an in-depth understanding of the unique SGH signatures associated with different commodity targets. Using a forensic approach we have developed target signatures or templates for identification, and the understanding of the expected geochromatography that is exhibited by each class of SGH compounds. In 2004 we began to include an SGH interpretation report delivered with the data to enable our clients to realize the complete value and understanding of the SGH results in the shortest time frame and provide the benefit from past research sponsored by Actlabs, CAMIRO, OMET and other industrial sponsors. In 2011, a new model of Electrochemical/Redox Cell theory was proposed and the new 3D-SGH interpretation approach based on this theory was incorporated in 2012 on a routine basis for SGH interpretation reports. 615Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 11 of 52 SGH has attracted the attention of a large number of Exploration companies. In the above mentioned research projects the sponsors have included (in no order): Western Mining Corporation, BHP-Billiton, Inco, Noranda, Outokumpu, Xstrata, Cameco, Cominco, Rio Algom, Alberta Geological Survey, Ontario Geological Survey, Manitoba Geological Survey and OMET. Further, beyond this research, Activation Laboratories Ltd. has interpreted the SGH data for over 700 targets from clients since January of 2004. In both CAMIRO research projects over known mineralization and in exploration projects over unknown targets, SGH has performed exceptionally well. As an example, in the first CAMIRO research project that commenced in 1997 (Project 97E04), there were 10 study areas that were submitted blindly to Actlabs. These study sites were selected since other inorganic geochemical methods were unsuccessful at illustrating anomalies related to the target. Although Actlabs was only provided with the samples and their coordinates, SGH was able to locate the blind mineralization with exceptional accuracy in 9 of the 10 surveys. In 2007, SGH has recently been very successful in exploration and discovery of unknown targets e.g. Golden Band Resources drilled an SGH anomaly and discovered a significant vein containing “visible” gold. (www.goldenbandresources.com) 616Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 12 of 52 SPATIOTEMPORAL GEOCHEMICAL HYDROCARBON SURVEY DESIGN AND SAMPLING Summary: See Appendix C for more details In summary, the best conditions for the sample type and survey design include:  Fist sized samples are usually retrieved from a shallow dug hole in the 15 to 40 cm range of depth.  Different sample types can be taken even “within” the same survey or transect, data leveling is rarely ever required. SGH is highly effective in areas of very difficult terrain. The Golden Rule is to always take a sample.  Samples should be evenly spaced in a grid or a series of transects with sample lines spaced at a ratio of up to 4:1 (line spacing: sample spacing).  A minimum of 50 sample “locations” is recommended with one-third over the target and one-third on each side of the target into background if this can be predicted. This provides the opportunity of optimal data contrast.  If very wet, samples can be drip dried in the field. No special preservation is required for shipping.  Relative or UTM sample location coordinates are required to allow interpretation. SAMPLE PREPARATION AND SGH ANALYSIS Summary: See Appendix D for more details Upon receipt at Activation Laboratories:  The samples are air-dried at a relatively low temperature of 40°C.  The samples are then sieved and the -60 mesh sieve fraction (<250 microns, although different mesh sizes can be used at the preference of the exploration geologist) is collected.  The collected “pulp” is packaged in a Kraft paper envelope and transported from our sample preparation department to our analytical building also located in the industrial park in Ancaster Ontario.  Each sample is then extracted, compounds separated by gas chromatography and detected by mass spectrometry at a Reporting Limit of one part-per-trillion (ppt).  The results of the SGH analysis is reported in raw data form in an Excel spreadsheet as “semi-quantitative” concentrations without any additional statistical modification. 617Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 13 of 52 SGH DATA QUALITY Summary: See Appendix E for more details Reporting Limit:  The Excel spreadsheet of concentrations for each of the 162 compounds monitored is in units of ppt as “parts-per-trillion” which is equivalent to nanograms/kilogram (ng/Kg). The reporting limit of 1 ppt represents a value of approximately 5 times the standard deviation of low level analysis. Essentially all background noise has already been eliminated. All data reported should be used in geochemical mapping. Actual detectable levels can be significantly < 1 ppt. Laboratory Replicate Analysis:  An equal aliquot of a random sample is analyzed as a laboratory replicate.  Due to the large amount of data, the estimate of method variability is reported as the percent coefficient of Variation (%CV).  A laboratory replicate analysis is reported at a frequency of 1 for every 15 samples analyzed.  The variability of field duplicate samples are similarly reported if identified. Historical SGH Precision:  Although the SGH analysis reports results at such trace ppt concentration levels, the average %CV for laboratory replicates is 8% within a range of ±4%.  Field duplicates have historically been 5% higher than laboratory replicates. Laboratory Materials Blank (LMB-QA):  The LMB-QA values are only an early warning as a quality assurance procedure to indicate the relative cleanliness of laboratory glassware, vials, caps, and the laboratory water supply at the ppt concentration level.  The LMB-QA values should not be subtracted from any SGH data as any background or noise characteristics have already been removed through the use of a Reporting Limit. 618Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 14 of 52 SGH DATA INTERPRETATION Summary: See Appendix F for more details SGH Interpretation and Report:  Due to the very large data set provided by the SGH analysis, this interpretation report is provide to offer guidance in regard to the results of this geochemistry for their survey.  In our interpretation procedure, we separate the 162 compound results into 19 SGH sub-classes. These classes include specific alkanes, alkenes, Thiophenes, aromatic, and polyaromatic compounds. The concentrations of the individual hydrocarbons within a class are simply summed. None of these compounds are gaseous at room temperature.  At this time the magnitude of the hydrocarbon class data has not been proven to imply a higher grade or quantity of the mineralization if present.  A “geochemical anomaly threshold value” should not be calculated for SGH data as any background or noise has already been filtered out through the use of a Reporting Limit instead of some type of detection limit.  SGH hydrocarbons data should never be interpreted individually. Interpretation must always be by compound class.  Multiple SGH Classes are compared. Multiple SGH Classes that have been associated with the presence of specific mineralization are called SGH Pathfinder Classes that together represent the forensic signature or fingerprint identification for a specific type of mineralization or petroleum play.  The anomalies of each class are compared as to their geochromatographic dispersion and ability to vector to a common location that may be referenced as a potential drill target.  The agreement and behaviour between SGH Pathfinder Classes for a type of target, as a template of Classes, is compared against SGH research and orientation studies. The quality of agreement is expressed as an SGH Rating of confidence that the SGH anomalies of the survey being interpreted are similar to the behaviour of these classes over known mineralization.  The interpretation is customized for the project survey by the Author. The SGH Rating and Interpretation is thus subjective and based on the experience of close to 1,000 SGH survey interpretations. The interpretation is not conducted by any computerized process. 619Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 15 of 52 SGH CHARACTERISTICS Summary: See Appendix G for more details SGH Characteristics:  The pattern of SGH anomalies are usually of high contrast and easily observed.  SGH is able to illustrate exceptionally symmetrical anomalies in spite of exotic overburden and barriers such as permafrost, shale and basalt caps, previously thought to be impenetrable.  Inorganic geochemistry can illustrate anomalies of metals that have been mobilized by surficial physical processes. As SGH is essentially “blind” to the inorganic content of a sample, SGH anomalies illustrate the true source of mineralization as it does not detect trace mobilized (by glacial action or down slope) mineralization.  AS SGH hydrocarbons are essentially non-polar, highly symmetrical anomalies are observed. As such symmetry is rare this provides a quality control to the interpretation resulting in higher confidence that is reflected by a higher SGH Rating Score in comparison to known case studies.  SGH can be analyzed on samples collected in different seasons or adjacent years. The combined data rarely require any data leveling. 620Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 16 of 52 INTERPRETATION OF SGH RESULTS A15-09729 – AURORA GEOSCIENCES LTD. – SGH TEST SURVEY This report is based on the SGH results from the analysis of a total of 127 soil based samples. The SGH TEST SURVEY Area is described by a rectangular grid with samples spaced at approximately 50 metres. These samples were received on November 11th and prepared at Actlabs Global Headquarters in Ancaster Ontario Canada. The prepared samples were then analyzed from November 24th to 25th. Sample coordinates were provided for mapping of the SGH results for these samples as GPS X-Y coordinates. A sample location map is shown below SGH TEST SURVEY SGH SURVEY - SAMPLE LOCATION MAP 621Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 17 of 52 GH SURVEY INTERPRETATION A15-09729 – AURORA GEOSCIENCES LTD. - QUALITY ASSURANCE SGH TEST SURVEY Note that the associated SGH results are presented in a separate Excel spreadsheet. This data is semi-quantitative and is presented in units of pg/g or parts-per-trillion (ppt) as the concentration of specific hydrocarbons in the sample. The number of samples submitted for this survey is adequate to use SGH as an exploration tool. As SGH is an organic geochemistry it is essentially “blind” to the elemental presence of any inorganic species as actual VMS, gold, silver, uranium, etc. content in the each sample analyzed. SGH has been proven to discriminate between false or mobilized anomalies and is able to actually locate the source target deposition. SGH is a deep-penetrating geochemistry and has been proven to locate Copper, Gold, VMS, and other types of mineralization at several hundred metres below the surface irrespective of the type of overburden. Note that the SGH data is only reviewed for the particular target deposit type requested, in this case for the presence of a Kimberlite target. It is usually assumed that there is only one potential target, however in this survey, with samples spaced at 50 metres and the fact that Kimberlite pipes/dykes etc. are of a small size the majority of the time, this survey was reviewed for the possible presence of multiple targets. If known, in surveys with several complex geophysical targets, to obtain the best interpretation the client should indicate that there are possibly multiple targets. The possibility of multiple geophysical targets should be known due to potential overlap and increased complexity of the resulting geochromatographic spatial anomalies, which could alter the interpretation as to which targets are mineralized or not. The overall precision of the SGH analysis for the samples at the SGH Test Survey was excellent as demonstrated by 9 different samples taken from this survey which were used for laboratory replicate analysis and were randomized within the analytical run list. The average Coefficient of Variation (%CV) of the replicate results for the survey samples in this submission was 8.4% which represents an excellent level of analytical performance especially at such low parts-per-trillion concentrations. Six samples were identified as Field Duplicate samples that resulted in an average Coefficient of Variation (%CV) of these duplicates at 19.8%CV. It is typically observed that the variability of field duplicates are 5% to 8% CV higher than for laboratory duplicates of random samples taken from the survey which generally have a variability in the range of 6% to 12%CV. Thus these field duplicates have a bit more variability than the average found but is still within the acceptable range. Note that the SGH geochemistry does not detect all organic hydrocarbons present in the samples. No other statistics were used on the data for this report for mapping or interpretation purposes aside from the use of a Kriging trending algorithm in the GeoSoft Oasis Montaj mapping software. This interpretation is based only on the analytical results provided by the SGH Nano-Geochemistry from this submission of samples for the SGH Test Survey. A template or group of SGH Pathfinder Classes that have been found to be associated with buried Kimberlite targets was used as the basis for the interpretation of the SGH Test Survey. The final interpretation is customized and conducted by the author. Although the term “template” or “signature” often appears in an SGH Interpretation Report, a computerized interpretation is not used. 622Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 18 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH INTERPRETATION SGH TARGET PATHFINDER CLASS MAPS The maps shown in plan and in 3D views in this report are SGH “Pathfinder Class maps” for targeting various chemical classes of hydrocarbon flux signatures related and Kimberlitic type targets and frequently to Redox conditions. The maps shown represent the simple summation of several individual hydrocarbon compound concentrations that are grouped from within the same organic chemical class. SGH Pathfinder Class maps have been shown to be robust as they are each described using from 4 to 14 chemically related SGH compounds (unless otherwise stated) which are simply summed to create each chemical class map. Thus each map has a higher level of confidence as it is not illustrating just one compound measurement. A legend of the compound classes appears at the bottom of the SGH data spreadsheet. The Kimberlite template of SGH Pathfinder Classes uses primarily medium and high molecular weight classes of hydrocarbon compounds. At least three Pathfinder Class maps, associated with the SGH signature developed for Kimberlite must be present to begin to be considered for assignment of a good rating relative to the SGH performance in case studies over known Kimberlite type mineralization (some of these maps might not be shown in this report). These SGH classes must also concur and support a consistent interpretation in relation to the expected geochromatographic characteristics of the Pathfinder Class. The overall SGH interpretation Rating has even a higher level of confidence as it further implies the consensus between at least the three pathfinder classes. A combination of these SGH Pathfinder Classes potentially defines the signature of a target at depth if present. Each of the SGH Pathfinder Class maps shown in this report is a specific portion of the SGH signature relative to the presence of Kimberlite as described. Each pathfinder class map is still just one of the Pathfinder Class maps used in the interpretation template for Kimberlite. Additional interpretation information which may contain additional SGH Pathfinder Class maps is available as a Supplementary Report at an additional price (see Appendix H). 623Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 19 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH INTERPRETATION SGH TARGET PATHFINDER CLASS MAPS Note that any concentration value in the accompanying Excel spreadsheet greater than the “Reporting Limit” of 1 ppt (part-per-trillion) is important data and has been able to depict mineralization at depth. The majority of the variability or noise has already been eliminated; additional filtering will adversely affect any interpretation. Note again that a Kriging trending algorithm has been applied to the mapping routine in the Geosoft Oasis Montaj software in the development of the SGH Class maps. SGH concentrations are in some way probably related to the amount of mineralization present and the grade of mineralization, which probably defines the characteristics of the biofilm(s) in contact with mineralization (in this case for kimberlite), as well as being related to the depth to mineralization. SGH results have also been shown to correlate well with geophysical measurements such as magnetic anomalies and those of CSAMT. The SGH Class maps are the plot of the sums of the particular hydrocarbon class in parts-per-trillion concentration. The dark blue represents very low or non-detect values. For plotting purposes the values at the Reporting Limit are plotted as one-half of this filtering, or one-half of 1.0 ppt. The hotter colours represent higher concentrations of the sum of the class with the highest values being purple in colour. Potential anomalous signatures at the edges of the SGH survey are not typically interpreted as there is a significantly lower number of samples to base a “confident” interpretation on. SGH is a “deep penetrating” geochemistry but also works well for relatively shallow targets. Targets shallower than about 3 to 5 metres will have a reduced SGH signal due to interaction with atmospheric conditions and samples taken right at surface outcrops will have even weaker signals due to a higher degree of weathering from various environmental processes on these volatile and semi-volatile organic hydrocarbons. 624Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 20 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY SGH| INTERPRETATION RATING AND CLARIFICATION Often a geochemistry such as SGH is used as an economical exploration investigation tool to provide more information on an exploration target as some geological body or help prioritize some geophysical target. Such occurrences are in general expected to change the chemistry of the immediate overburden which in turn is expected to result in a chemical anomaly as detected in surficial samples. The author believes that it is important to convey to the client of an anomaly even if there is only part of the SGH signature present that may be related to the mineral signature or template requested. In other words, the anomaly illustrated in the report may not be representative of the feature or mineralization sought as only a part of the SGH signature is present, but the anomaly may confirm the presence of some geological or geophysical target which may be valuable to the client for comparison with other data. In addition it would confirm the ability and sensitivity of SGH to show geological or geophysical occurrences. Example: A well defined rabbit-ear anomaly on an SGH Pathfinder Class map in a report, even though it may have a lower rating of 2.0 or 3.0, may illustrate to the exploration geologist that SGH does agree that there is some geological body at depth that is changing the chemistry and forming a Redox cell in the overburden. However the SGH forensic signature Rating indicates that there is a lower confidence that the “identification” of that body is likely to be say Gold (if the SGH Gold template is requested). This information would provide a confirmation that a target does exist, however if the SGH Rating indicates that the target has a lower level of confidence then the target does not have the forensic signature of the mineralization sought. SGH would thus provide a savings to the exploration program and divert focus to potentially other targets having a higher confidence in the SGH identification Rating. Thus, the SGH rating must always be considered in conjunction with the SGH Pathfinder Class map shown in the report. It is this rating that provides an insight into the authors’ complete interpretation and is a measure of the confidence and to what degree the complete SGH signature compares with the SGH results from over case studies of similar known deposits. Unfortunately, the interpretation of a visual, as the SGH map provided, is so ingrained in humans that the reader may erroneously disregard the author’s subjective rating to a large degree. As of November 25, 2011, the author now highlights the rating directly on the page having the plan view of the SGH Pathfinder Class map chosen to be illustrated. Thus to the reader of the report, the authors Rating is actually MORE IMPORTANT than the readers instinctive interpretation of just the one map provided. Again, SGH should not be used in isolation from other site information, and that a Rating of 4.0 is when, in the authors’ estimation, a signature only starts to have a good identification relative to that type of mineralization, and that the survey may warrant further study although it is not a specific recommendation to drill test the anomaly. As the SGH interpretation is represented by a signature, the SGH Pathfinder Class map(s) illustrated in reports is always only “PART” of the specific SGH signature or template that the client requests (i.e. for Gold, Kimberlite, etc.). No one SGH map can represent the complete signature due to the different amounts of spatial dispersion expected for the variety of SGH chemical classes within each signature. Thus the author selects the one SGH Class Map relative to the mineralization requested that best represents an anomaly that estimates the overall signature found in the survey. 625Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 21 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH “REDOX” INTERPRETATION As a general comment in regard to the SGH results at this SGH Test Survey, the SGH data in general had a moderate signal strength as expected from peat and peat like samples, and the SGH Class maps in this report are quite good in contrast. Its important to not think of contrast with SGH as Signal:Noise as by using a reporting limit tihe noise has already been nearly completely removed. One of the first steps in the interpretation of SGH data is to locate potential Redox conditions in the overburden. Redox conditions have been well known to be related to blind mineral targets; however, Redox conditions can also be attributed to other geological bodies that are of no particular interest. SGH signatures are able to differentiate between these targets. SGH has been described by the Ontario Geological Survey of Canada (OGS) as a “Redox Cell locator”. Redox Cells can be related to the presence of bacteriological activity related to mineralization but also may be related to the presence of geological bodies such as Granite Gneiss, Dunite, etc. Recently SGH has been shown to be far more sensitive to depicting Redox conditions than even measurements using pH or ORP tests. Note that the presence of a Redox cell is not necessarily require in order for SGH to delineate mineralization if present. It is also important to understand that; not only is SGH a Redox cell locator, but due to the forensic signature of mineralization used in the interpretation process, SGH can discriminate mineral targets and other target types from geological bodies, other magnetically detected targets, mineralized versus non-mineralized conductors, cultural effects, etc. even in surveys over highly difficult or exotic terrain that often requires the collection of multiple sample types. In the interpretation it is again not necessary to detect a Redox cell if the feature or mineralization is within approximately 20 metres of the surface and does not extend to a significant depth, as this would be insufficient depth to develop a dispersion halo anomaly. Many SGH surveys for Kimberlite, and other mineral targets can result in multiple types of anomalies, depending on the class of SGH compounds, even over the same target and in the same set of samples. Thus “Apical”, “Segmented-Nested-Halo”, and “Rabbit-Ear” or “Segmented Halo” type anomalies are all typically observed within the SGH data set from the effect of Redox cells that have developed over mineralization and their interaction with Redox conditions and the electromotive forces produced by the subsequent Electrochemical Cell. Typically halo, segmented-halo, or nested-halo anomalies are associated with Kimberlites due to the dyke or pipe like shape. Different types of anomalies have also been associated with the depth to the target. The types of anomalies developed have been recently explained by the use of the 3D-SGH model of interpretation. The highly symmetrical anomalies illustrated by SGH data closely follow the expected self-organizing patterns of neutral species within an electrochemical cell in recent experiments in physics Laboratories. The highly symmetrical anomalies are also able to be observed as the Nano-sized dimensions of these organic hydrocarbons are much smaller than inorganic oxides and sulphides. Note that the presence of sulphides is not required to develop SGH anomalies. Thus the SGH hydrocarbons can migrate through the Nano-sized fissures of even clay, basalt, and permafrost caps by means of Nano-capillary action. The simple fact that the SGH anomalies are geometrically symmetrical and not random further improves the confidence of SGH interpretations. 626Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 22 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH “KIMBERLITE” INTERPRETATION This report illustrates an SGH Kimberlite Pathfinder Class map on page 24 in plan view and on page 25 in 3D view that has been very reliable in its association with the presence of Kimberlite pipes or diatremes. This SGH Class map is only a portion of the SGH Kimberlite signature used in the interpretation. There is not any one SGH Class map that can, as a single map, be reliably used to interpret the presence of Kimberlite or any other type of mineralization, thus a rating relative to the performance of SGH over known case studies is determined. It should also be noted that some SGH Classes can be used as a portion of other SGH mineral signatures, i.e. some portions of SGH signatures overlap in their use. The SGH Kimberlite Pathfinder Classes are often expected to illustrate a halo, segmented-halo, or nested-halo type of response as a vertical projection over the pipe feature, especially for crater and diatreme facies kimberlites. The response for these SGH Pathfinder Classes for Kimberlite at this SGH Test Survey has some halo anomalies as will be discussed. The SGH hydrocarbon signatures are predicted to be associated with Kimberlite targets as the detection of those hydrocarbon residues produced by the decomposition of microbes and bacteria from the life cycle death phase that have been feeding on Kimberlite mineralization. These residues have subsequently migrated to the surface as a flux of different classes of hydrocarbons or decomposition products. During migration to the surface, dispersion away from the mineralization is expected. The distance of dispersion is dependent on the principle of geochromatography that is in generally related to the average molecular weight of the class. It has been found that the complexity of the overburden does not affect the geochromatographic dispersion of the SGH classes of this Nano-Geochemistry, unless a situation is encountered such as that of a “major” fault that may result is a very slight deflection of this path. This is the basis of the 3D-SGH interpretation as the relatively neutral hydrocarbons that SGH detects are spatially observed as very symmetrical anomalies (as presented by the author at the IAGS conference in Finland in 2011 and further at the IAGS conference in New Zealand in November of 2013 and IAGS conference in Arizona in 2015). SGH has been researched and tested many times and in many projects over Kimberlite targets. It has been successfully tested over false anomalies such as Granite Gneiss and Dunite as well as many types of kimberlite. Most of this testing has been over kimberlitic formations having crater facies and diatreme facies. There has been less focus on hypabyssal facies kimberlites during these tests and thus there is a lower level of interpretational experience. There is no doubt that SGH will show anomalies over hypabyssal facies, which it has already been proven to do. 627Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 23 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH “KIMBERLITE” INTERPRETATION The SGH Class map illustrated in plan view on page 24 and in 3D view on page 25 is diagnostic for depicting Kimberlite mineralization. SGH has typically been used to study one magnetic anomaly to determine whether the geophysical anomaly is associated with a Kimberlite. In these studies, since Kimberlite targets are relatively small, the sample spacing has typically been 20m or 25m. As this SGH Test Survey uses 50 metre spacing it is closer to sub-regional with respect to this type of target. Thus a large Kimberlite might not be more that 100 metres in diameter, with 50 metre sampling a target will be described by only a few samples. The plan map on page 24 illustrates the possible presence of several features. Through the centre of this survey, as a general wide East-West trend, there appears to be a significant fault zone. Specific SGH Classes have been shown to reliably display faults and shear zones. This fault zone is shown as the area within the black dashed elongated shapes. Just North of the fault trend are four halo type anomalies, within the four dotted ovals on page 25, of similar size based on the spacing of this survey. This SGH Pathfinder Class map for Kimberlites is the most reliable SGH Class that is specific to illustrating the presence of Kimberlite formations. It is highly sensitive with previous case studies illustrating strong results for Kimberlite features. These four anomalies are well supported in other classes also associated with Kimberlite formations. Thus these anomalies are interpreted as reliable and are expected to be real. The dotted yellow interpretation ovals are placed to indicate the general extent of the kimberlite material. With the spacing used in this survey, this data implies that these potential Kimberlites are in the 50 to 100 metre diameter range. The shape and size of these features imply that these are most likely crater facies kimberlites with relatively little glacial abrasion. These SGH findings appear to comply with the theory that “Kimberlite intrusions tend to occur in clusters or fields, with the large scale distribution possibly controlled by deep seated structureal features and local emplacement controlled by shallow zones of weakness such as faults…” (M. Power and D. Hildes, Aurora Geosciences Ltd., Geophysical strategies for kimberlite exploration in northern Canada, Proceedings of Exploration 07). . 628Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 24 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH “KIMBERLITE” PATHFINDER CLASS KIMBERLITE FORMATIONS DETECTED BY SGH WITHIN DOTTED YELLOW OUTLINES ADJACENT AND NORTH OF A SIGNIFICANT FAULT ZONE SGH SIGNATURE RATING RELATIVE TO “KIMBERLITE” = 4.5 OF 6.0 Results represent only the material tested. Actlabs is not liable for any claim/damage from the use of this report in excess of the test cost. Samples are discarded in 90 days unless requested otherwise. This report is only to be reproduced in full. 629Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 25 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH “KIMBERLITE” PATHFINDER CLASS Results represent only the material tested. Actlabs is not liable for any claim/damage from the use of this report in excess of the test cost. Samples are discarded in 90 days unless requested otherwise. This report is only to be reproduced in full. 630Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 26 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH INTERPRETATION GOALS As a reminder, in the interpretation of SGH data there are several goals. In order of importance they are:  Vector to the location of a mineral target  Delineate the mineral target  Identify the type of mineral target  Describe the features of the possible mineral target  See if there is information on the basement structure  Predict the possible depth to the mineral target Not every goal is expected to be able to be achieved with each SGH data set although most are observed at this SGH Test Survey. 631Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 27 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH INTERPRETATION FOR “KIMBERLITE” FORMATIONS The interpretation of the SGH data relative to the presence of Kimberlite at the Aurora Geosciences Ltd. SGH TEST Survey is described by what appears to be the presence of a significant and wide East-West trending fault zone. Most likely associated with this fault zone are four halo anomalies to the North of the fault zone that are predicted to be Kimberlite formations as supported by other SGH Pathfinder Class maps for Kimberlites (not shown). The SGH confidence rating, relative to other SGH studies over known Kimberlites, was 4.5 of 6.0. This confidence rating was reduced by 0.5 as the survey spacing of 50 metres is twice as wide as previous research studies although this spacing may be a good design to cover a larger geographic area. The confidence rating was also reduced by another 0.5 as we have not had very much experience at interpreting the presence of a Kimberlitic cluster field. Aside from these two aspects, the SGH Confidence Rating could have been as high as 5.5 of 6.0. NOTE: The depths to mineralization as estimates has not been used for these relatively small targets. For other types of mineral targets, statements on predicted depth are very approximate and are a result of the development of the 3D-SGH interpretation process that recognizes the importance of symmetrical anomalies. Such estimates cannot be calibrated except from the responses from those SGH clients that have offered feedback from actual drilling results or prior site knowledge. The feedback obtained regarding depth since the use of 3D-SGH has been quite encouraging, e.g. Aura Silver mentioned in their recent press release (November 24th, 2015) on a successful drill intersection of significant Gold mineralization at 196 metres which is consistent with the 200 metres that Activation Laboratories Ltd. made in their report using SGH. SGH is the only geochemistry to our knowledge that is able to make some statement with regards to the depth to blind mineralization. The SGH Ratings shown in this and all SGH reports are based on a scale of 6.0, in 0.5 increments, with a value of 6.0 being the best. The SGH Ratings discussed in relation to the presence of Kimberlite pipes represents the similarity of these SGH results with other SGH case studies over known mineralization. Theses SGH signatures or templates have been constantly refined and enhanced since inception and has been proven to be effective and reliable. SGH is very reliable at differentiating Kimberlite pipes from barren areas or other circular features that may give rise to geophysical responses. High ratings for SGH Responses relative to Kimberlites is not an indication that a Kimbelite may be diamondiferous. The SGH templates are based on the interpretation from over 1,000 interpretations for many other surveys, including for a large number of Kimberlites in Canada, in many different geographical regions and for a wide variety of lithologies. The degree of confidence in the SGH Rating only starts to be “good” at a level of 4.0. A Rating of 4.0 is an indication that this SGH Nano-Geochemistry predicts that the zone(s) described may warrant more work or more consideration. 632Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 28 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH INTERPRETATION FOR MINERALIZATION Deeper mineralization is often expected to be centrally located within Redox zones. In areas predicted to have shallower mineralization the SGH anomalies are very reliable at showing vertical projections of mineralization and Kimberlite features, and thus in directly illustrating the location of possible drill targets. From client feedback in recent years, a few grass roots exploration surveys that have been interpreted with an SGH Confidence Rating of 4.0 (±0.5) have been drill tested and have had successful Gold intersections. However the frequency of success is much more prevalent for those targets that have associated SGH Rating Scores of ≥5.0. Any identification of a drill target would be shown as a white star on the plan view map and is not an explicit recommendation by Activation Laboratories Ltd. to drill test the associated location or SGH anomaly. A drill target is implied to ensure that the reader is aware of the location having the highest confidence of being the location of the vertical projection of possibly the shallowest mineralization, based only on SGH data. This is also not a recommendation for vertical drilling. Vertical drilling may not be the best approach to test the SGH anomaly in this area. Activation Laboratories Ltd. has no experience in actual exploration drilling techniques. Other geological, geochemical and/or geophysical information should also be considered. It must be remembered that many other SGH Class maps not shown in this report have also been reviewed to support the interpretation shown. To deduce the most scientifically sound interpretation of the SGH Test Survey, the client should use a combination of the SGH results shown in this report with additional geochemical, geophysical, and geological information to possibly obtain a more confident and precise target location. This is not a statement to convey some lower level of confidence in SGH results. This statement is made to recognize the proper use and interpretation of any scientific data. Whenever possible, multiple methods should always be employed so that any decisions do not rely on any one technique. 633Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 29 of 52 A15-09729 – AURORA GEOSCIENCES LTD. SGH TEST SURVEY - SGH SURVEY RECOMMENDATIONS The sample survey design using 50 metre sample spacing in this approx. 0.7 x 0.5 km grid was appropriate and nicely illustrated fault zones and Kimberlitic features at the SGH Test Survey. Should more accurate drill targets be considered, infill sampling to create a 25m spaced grid over the four predicted kimberlite pipes may be beneficial. Any additional infill sampling may be added to the current SGH data and interpretation, even if sampled at a later time, and may provide information with greater accuracy. This would further improve confidence in the interpretation. Should additional sampling be considered, please refer to the general recommendations for additional or in-fill sampling for SGH in the next section of this report. GENERAL RECOMMENDATIONS FOR ADDITIONAL OR IN-FILL SAMPLING FOR SGH ANALYSIS Based on the results of this report and/or other information, the client may decide that in-fill sampling may be warranted. To obtain the best results from additional sampling for SGH it is recommended that sample locations from the original survey within, or bordering, the area of interest be re-sampled rather than just combining new sample results with the sample data from the initial survey. Although several SGH surveys have previously been easily and directly, combined without data leveling, it cannot be guaranteed that data leveling will not be required. It has been found that data leveling is more apt to be required should the new samples be collected under significantly different environmental conditions than during the initial sample survey, i.e. summer collection versus winter collection. The process of data leveling adds a minimum of 3 to 5 days of work to conduct the additional data evaluation, develop additional plots of the results, conduct new interpretations, and in additional report descriptions. Results from data leveling is also always considered “an approximation”, thus the confidence in a combined interpretation will be lower that the interpretation from samples collected during one excursion to the field and submitted as one survey. An additional cost will be invoiced should data leveling operations be required if the client requests that two SGH data sets be interpreted and reported together. Thus re-sampling a few of the original sample locations will provide a faster turnaround time for results and provide more accurate and confident surveys for evaluation and aid in deciding specific drill targets. 634Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 30 of 52 Date Received at Actlabs Ancaster: November 11th, 2015 Date Analyzed: November 24th and 25th, 2015 Interpretation Report: November 27, 2015 AURORA GEOSCIENCES LTD. Attention: Mr. Gabe Fortin, Aurora Geosciences Ltd. 3506 McDonald Dr. Yellowknife, NT X1A2H1 RE: Your Reference: SGH TEST SURVEY Activation Laboratories Workorder: A15-09729 CERTIFICATE OF ANALYSIS This Certificate applies to the associated Excel Spreadsheet of Hydrocarbon results combined with the discussion and SGH Pathfinder Class maps of the data shown in this report. 127 Samples were analyzed for this submission. Sample preparation –Actlabs Asia - S4: Drying at 40°C and maceration of vegetation like samples Interpretation relative to Kimberlite targets was requested. The following analytical package was requested and analyzed at Actlabs Ancaster Canada: Analysis Code SGH – Spatiotemporal Geochemical Hydrocarbon Geochemistry using High Resolution Gas Chromatography/Mass Spectrometry (HRGC/MS) 635Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 31 of 52 REPORT/WORKORDER: A15-09729 This report may be reproduced in whole without our consent. If only selected portions of the report are reproduced, permission must be obtained. If no instructions were given at the time of sample submittal regarding excess material, it will be discarded within 90 days of this report. Our liability is limited solely to the analytical cost of these analyses. Test results are representative only of the material submitted for analysis. Notes: The SGH – Spatiotemporal Geochemical Hydrocarbon Geochemistry is a semi-quantitative analytical procedure to detect and measure 162 hydrocarbon compounds as the organic signature in the sample material collected from a survey area. It is not an assay of mineralization but is a predictive geochemical tool used for exploration. This certificate pertains only to the SGH data presented in the associated Microsoft Excel spreadsheet of results. The author of this SGH Interpretation Report, Mr. Dale Sutherland, is the creator of the SGH and OSG organic geochemical methods. He is a Chartered Chemist (C.Chem.) and Forensic Scientist specializing in organic chemistry. He is a member of the Association of the Chemical Profession of Ontario, the Association of Applied Geochemists, the International Association of GeoChemistry, the Ontario Prospectors Association, the Association for Mineral Exploration British Columbia, the Geochemical Society Association, the Ontario Petroleum institute, the Chemical Institute of Canada, and the Canadian Society for Chemistry, as well as having memberships in several national and international Forensic associations. He is not a professional geologist. 636Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 32 of 52 APPENDIX “A” List of terms 1. SGH – “SPATIOTEMPORAL GEOCHEMICAL HYDROCARBON” GEOCHEMISTRY – a Predictive Geochemistry, used for delineate buried inorganic mineral deposits and organic petroleum plays. This is the original name used to describe this geochemistry since inception in 1996. Code SGH is still used when submitting samples. 2. 3D-SGH- “3D- SPATIAL TEMPORAL GEOCHEMICAL HYDROCARBONS - the method of interpreting SGH and OSG results based on the Redox/Electrochemical Cell model developed by Activation Laboratories Ltd. in 2011. 3. Redox cell- an area of oxidation-reduction reactions or exchange of electrons that is produced over geological bodies, mineralization and petroleum based plays. 4. Electrochemical cell- the effect of adjacent chemically reduced areas and chemically oxidized areas as a Redox cell produces a electrical gradient that obeys the physics of a typical Electrochemical cell. 5. Anthropogenic contamination- the introduction of impurities/compounds of the same type as those that are being analyzed by human actions that could lead to erroneous results. 6. Background areas- the area around a mineral deposit that is beyond the effect of the Redox cell formed over geological bodies or exploration targets. Sampling is required into background areas to produce data that has sufficient contrast to illustrate and differentiate anomalies associated with exploration targets. 7. Background subtracted- A sample taken some distances away as to not contain any elements of the target being analyzed. 8. Biofilm- a layer of microorganisms and microbe and their related secretions and decomposition products, in this case found to inhabit mineral deposits . 9. Biomarker- a compound used as an indicator of a biological state. In this case a biological substance used to indicate the presence of a mineral deposit. 10. Blind mineralization – buried mineralization that shows no physical indication of its existence at the surface 11. Compound – used synonymously with the term hydrocarbon in this report 12. Compound chemical class – a group of hydrocarbons that are similar in size, structure, and molecular weight such that their chemical characteristics, such as water solubility, partition coefficients, vapour pressures, etc. are similar 13. Cultural activities – human initiated processes that may affect the physical and chemical characteristics at the earth’s surface 14. Delineating targets- indicate the position or outlines of an exploration target as a vertical projection of the target at depth. 637Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 33 of 52 15. Geochemical anomalies – inorganic element or organic hydrocarbon measurements that are significantly different than the average low level measurements or background in a survey i.e. the needle in a haystack is an anomaly 16. Dispersion patterns – the movement/ spreading of something. In this context the spatial arrangements of hydrocarbons caused by their movements to the surface from some depth. 17. Exploration tool – a geological, geophysical or geochemical method that attempts to illustrate data in exploration activities that may indicate the presence of mineralization or petroleum plays. 18. Fit for purpose- this method is ideal for its intended use. 19. Forensic signature- a grouping or pattern found to identify a substance having multiple characteristics with a high degree of specificity. 20. High specificity- as in being very specific to the mineralization. 21. Anomalies- this is the spatial representation of data that illustrates a high or low response as well as the combined spatial shape of anomalous data from several neighbouring samples in a survey that can form anomalies described as Rabbit-Ear, Halo, Segmented-halo, nested-halo, etc. 22. Inorganic geochemistry – the measurement of inorganic elements in a survey of near surface samples as a tool for exploration 23. Data leveling – a technique that attempts to normalize the data sets obtained between two or more sampling programs. The results of data leveling is always considered as an approximation. 24. Lithologies- the characteristics and classifications of rock. 25. Locations- the physical/ geographical position or coordinates of samples in a survey. 26. Noise- interference in a measurement which is independent of the data signal. 27. Nugget effect- Anomalously high precious metal assays resulting from the analysis of samples that may not adequately represent the composition of the bulk material tested due to non-uniform distribution of high-grade nuggets in the material to be sampled. (Webster’s online dictionary) 28. Organic geochemistry- the Soil Gas Hydrocarbon geochemistry (SGH), or now more accurately named as Spatiotemporal Geochemical Hydrocarbons, is the analysis to detect specific organic, or carbon based, hydrocarbon compounds in a sample. The Organo-Sulphur Geochemistry (OSG) is the analysis to detect specific organic compounds that have sulphur joined to carbon in its molecular structure. 29. Percent Coefficient of Variation (%CV) – a measure of data variability 30. Project maintenance – an activity where the associated cost is applied to the exploration, advancement, and/or operation of activities associated with a particular claim 31. Rating- a value given to the overall confidence in the SGH results 32. Real (in relation to data)- any rational or irrational number 33. Reporting Limit – minimum concentration of an analyte that can be accurately measured for a given analytical method. 34. Sample matrix- the components of a sample other than the analyte. 35. Sample type – soil, till, humus, lake bottom sediment, sand, snow, etc. 638Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 34 of 52 36. Semi-quantitative- yielding an approximation of the quantity or amount of a substance 37. SGH anomalies (“Apical”, “Nested-Halo”, and “Rabbit-Ear” or “Halo”) 38. SGH Pathfinder (class map/compounds) 39. SGH template – a set of hydrocarbon classes that together form a geochemical signature that has been associated with the presence of a particular type of mineralization the majority of the time 40. Surficial bound hydrocarbons – 41. Surficial samples- a sample from near the earth’s surface. 42. Survey- the area, position, or boundaries of a region to be analyzed, as set out by the client. 43. Project- a planned undertaking 44. Transect- A straight line or narrow section through an object or across a section of land. 45. Target- Target refers to the ore body of interest Target signature: the unique characteristics that identify the target. Target type: i.e. Gold, Nickel, Copper, Uranium, SEDEX, VMS, Lithium Pegmatites, IOCG, Silver, Ni-Cu-PGE, Tungsten, Polymetallic, Kimberlite as well as Coal, Oil and Gas. 46. Threshold- level or point at which data is accepted as significant or true. 47. Total measurement error- An estimate of the error in a measurement. Based on either limitation of the measuring instruments or from statistical fluctuations in the quantity being measured. 48. Visible (in terms of signature)- the portion shown in a chart or map 639Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 35 of 52 APPENDIX “B” EXAMPLE OF AN SGH FORENSIC GEOCHEMICAL SIGNATURE EXAMPLE SHOWN FOR A VMS TARGET The following analyses examine the Volcanic Massive Sulphide (VMS) deposit in various known locations. These analyses show how the gas chromatography indicates the reality of deposits. For all the profiles in this section, the red arrows indicate the signature of the VMS, which have all been found by organic geochemistry. These forensic geochemical signatures are shown to be consistent for similar target areas; therefore, the analyses are reliable indicators for the presence of VMS. One of the first experiments in 1996 in the development of the SGH analysis was to observe if an SGH response could be obtained directly from an ore sample. From office shelf specimens, small rock chips were obtained which were then crushed and milled. The fine pulp obtained was then subjected to the SGH analysis. These shelf specimen samples were from well known VMS deposits of the Mattabi deposit from the Archean Sturgeon Lake Camp in Northwestern Ontario and from the Kidd Creek Archean volcanic-hosted copper-zinc deposit. Even these specimen samples contain a geochemical record of the hydrocarbons produced by the bacteria that had been feeding on these deposits at depth. As a comparison, SGH analysis were similarly conducted on modern-day VMS ore samples taken from a “black smoker” hydrothermal volcanic vent from the deep sea bed of the Juan de Fuca Ridge where high concentrations of microbial growth was also known to exist. The raw data profiles as GC/MS Total Ion Chromatograms are shown below to illustrate the “visible” portion of the VMS signature obtained from the SGH analysis. The above profiles are: 01 02 03 0k C o u n ts01 02 03 0k C o u n ts01 02 03 0k C o u n ts01 02 03 0k C o u n tsf ile 6 1 0 3 .m sf ile 6 1 0 4 .m sf ile 6 1 2 4 .m sf ile 6 1 2 5 .m s" M o d e r n " Z n - C u D e p o s i t # 3" M o d e r n " Z n - C u D e p o s i t # 6" P r e - C a m b r ia n " Z n - C u D e p o s i t K id d - C r e e k" P r e - C a m b r ia n " Z n - C u D e p o s i t M a t t a b i640Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 36 of 52  First profile: Samples from modern day “black smokers”  Second profile: Samples from modern day “black smokers”  Third profile: Samples from Pre-Cambrian Zn-Cu Kidd Creek deposit  Fourth profile: Samples from Mattabi deposit The red arrows point to three compounds that are a portion of the SGH signature for VMS type deposits. This visible portion of the VMS signature of hydrocarbons can easily be seen in the analysis of each of these four samples. The next question in our early objectives was to see if this SGH signature could also be observed in surficial soil samples that had been taken over VMS deposits. Through our research projects, soil samples were obtained from over the Ruttan Cu-Zn VMS deposit near Leaf Rapids, Manitoba and located in the Paleoproterozoic Rusty Lake greenstone belt. The profile obtained, as observed in the raw GC/MS chromatogram, is shown in this next image below: The three compounds indicated by the red arrows represent the same visible portion of the VMS signature observed from the modern day black smoker samples and the ore samples taken from the Mattabi and Kidd Creek, even though this soil was taken from over a different VMS deposit in a geographically different area. Is this coincidence? Another soil sample was obtained from Noranda’s Gilmour South base-metal occurrence in the Bathurst Mining camp in northern New Brunswick. As shown below, this sample contained a very complex SGH signature, however the visible portion of the VMS signature as indicated by the red arrows is still observed as in the black smoker, Mattabi and Kidd Creek ore samples. 641Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 37 of 52 In research conducted by the Ontario Geological Survey, this same portion of the SGH signature was also observed over the VMS deposit at Cross Lake in Ontario. Note that the visible signature shown as the three compounds indicated by the red arrows is only a small portion of the complete SGH VMS signature. The full VMS signature is made up of at least three groups, as three organic chemical classes, that together contain at least 35 of the individual SGH hydrocarbons. The chromatograms shown on the preceding page from the GC/MS analysis are not used directly in the interpretation of SGH data. As we are only interested in a specific list of 162 hydrocarbons, the mass spectrometer and associated software programs specifically identifies the hydrocarbons of interest, runs calculations using relative responses to a short list of hydrocarbons used as standards, and develops an Excel spreadsheet of semi-quantitative concentration data to represent the sample. Thus the SGH results for a sample, like that observed in ore from the Ruttan, are filtered to obtain the concentrations for the specific 162 hydrocarbons. A simple bar graph drawn from the Excel spreadsheet of the hydrocarbons and their concentrations results in a DNA like forensic SGH signature as shown below. The portion discussed hear as the “visible” SGH VMS signature in the GC/MS chromatograms, is again shown by the red arrows. 642Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 38 of 52 Through the work done in the SGH CAMIRO research projects, it was observed that the hydrocarbon signature produced by the SGH technique appeared to also be able to be used to differentiate barren from ore-bearing conductors. This was explored further through the submission and analysis of specific specimen samples that represented a barren pyritic conductor and a barren graphitic conductor. The GC/MS chromatograms from these two specimens are compared to that obtained from the Kidd-Creek ore as shown below. This diagram conclusively shows that the SGH signatures obtained from the two types of barren conductors are completely different than that obtained by SGH over VMS type ore. SGH is thus able to differentiate between ore-bearing conductors and barren conductors as the Forensic SGH Geochemical signature is different. 643Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 39 of 52 SGH has been described by the Ontario Geological Survey of Canada (OGS) as a “REDOX cell locator”. Many SGH surveys for Gold and other mineral targets can result in multiple types of anomalies, depending on the class of SGH compounds, even over the same target and in the same set of samples. Thus “Apical”, “Nested-Halo”, and “Rabbit-Ear” or “Halo” type SGH anomalies are all typically observed from the effect of REDOX cells that have developed over deposits. REDOX cells are also related to the presence of bacteriological activity. The VMS template of SGH Pathfinder Classes uses low and medium weight classes of hydrocarbon compounds. Again, at least three Pathfinder Class group maps, associated with the SGH signature for VMS, must be present to begin to be considered for assignment of a good rating. The Pathfinder Class anomalies in these maps must logically concur and support a consistent interpretation in relation to the expected geochromatographic characteristics of the Pathfinder Class, for a specific area. The interpretation development history for VMS SGH Pathfinder Class map(s) shown in this report is similar to the development history for other target types. The reader should not draw a conclusion that SGH is used only for sulphide based mineralization as some of the most intense SGH anomaly has been associated with Kimberlites where sulphides are essentially not present. 010 20 30 40 kCounts010 20 30 40 kCounts010 20 30 40 kCountsfile6124.ms file6128.ms file6127.ms Pre-Cambrian -Zn-Cu Deposit “Kidd-Creek” Barren Graphitic Conductor Barren Pyritic Conductor 644Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 40 of 52 APPENDIX “C” SPATIOTEMPORAL GEOCHEMICAL HYDROCARBON SURVEY DESIGN AND SAMPLING Sample Type and Survey Design: It is highly recommended that a minimum of 50 sample “locations” is preferred to obtain enough samples into background areas on both sides of small suspected targets (wet gas plays, Kimberlite pipes, Uranium Breccia pipes, veins, etc.). SGH is not interpreted in the same way as inorganic based geochemical method. SGH must have enough samples over both the target and background areas in order to fully study the dispersion patterns or geochromatography of the SGH classes of compounds. Based on our minimum recommendation of at least 50 sample locations we further suggest that all samples be evenly spaced with about one-third of the samples over the target and one-third on each side of the target in order for SGH to be used for exploration. Targets other than gas plays, pipes, dykes or veins usually require additional samples to represent both the target and background areas. SGH has been shown to be very robust to the use of different sample types even “within” the same survey or transect. Research has illustrated that it is far more important to the ultimate interpretation of the results to take a complete sample transect or grid than to skip samples due to different sample media. The most ideal natural sample is still believed to be soil from the “Upper B-Horizon”, however excellent results can also be obtained from other soil horizons, humus, peat, lake-bottom sediments, and even snow. The sampling design is suggested to use evenly spaced samples from 15 metres to 200 metres and line spacing from 50 metres to 500 metres depending on the size and type of target. A 4:1 ratio is suggested, however, larger orientation surveys have also been successful. Ideally even large grids should have one-third of the samples over the target and two-thirds of the samples into anticipated background areas. This will allow the proper assessment of the SGH geochromatographic vectoring and background site signature levels with minimal bias. Individual samples taken at significant distances from the main survey area to represent background are not of value in the SGH interpretation as SGH results are not background subtracted. Samples can be drip dried in the field and do not need special preservation for shipping and has been specifically designed to avoid common contaminants from sample handling and shipping. SGH has also been shown to be robust to cultural activities even to the point that successful results and interpretation has been obtained from roadside right-of-ways. In conclusion, the conditions for the sample type and survey design include:  Fist sized samples are usually retrieved from a shallow dug hole in the 15 to 40 cm range of depth.  Different sample types can be taken even “within” the same survey or transect, data leveling is rarely ever required. SGH is highly effective is areas of very difficult terrain. The Golden Rule is to always take a sample.  Samples should be evenly spaced in a grid or a series of transects with sample lines spaced at a ratio of up to 4:1 (line spacing: sample spacing). 645Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 41 of 52  A minimum of 50 sample “locations” is recommended with one-third over the target and one-third on each side of the target into background if this can be predicted. This provides the opportunity of optimal data contrast.  If very wet, samples can be drip dried in the field.  No special preservation is required for shipping. APPENDIX “D” SAMPLE PREPARATION AND ANALYSIS Upon receipt at Activation Laboratories the samples are air-dried in isolated and dedicated environmentally controlled rooms set to 40°C. The dried samples are then sieved. In the sieving process, it is important that compressed air is not used to clean the sieves between samples as trace amounts of compressor oils “may” poison the samples and significantly affect some target signatures. At Activation Laboratories a vacuum is used to clean the sieve between each sample. The -60 mesh sieve fraction (<250 microns, although different mesh sizes can be used at the preference of the exploration geologist) is collected and packaged in a Kraft paper envelope and transported from our sample preparation building to our analytical building on the same street in Ancaster Ontario. Each sample is then extracted, separated by gas chromatography and analyzed by mass spectrometry using customized parameters enabling the highly specific detection of the 162 targeted hydrocarbons at a reporting limit of one part-per-trillion (ppt). This trace level limit of reporting is critical to the detection of these hydrocarbons that, through research, have been found to be related at least in part to the breakdown and release of hydrocarbons from the death phase of microbes directly interacting with a deposit at depth. The hydrocarbon signatures are directly linked to the deposit type, which is used as a food source. The hydrocarbons that are mobilized and metabolized by the microbes are released in the death phase of each successive generation. Very few of the hydrocarbons measured are actually due to microbe cell structure, or hydrocarbons present or formed in the genesis of the deposit or from anthropogenic contamination. The results of the SGH analysis is reported in raw data form in an Excel spreadsheet as “semi-quantitative” concentrations without any additional statistical modification. 646Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 42 of 52 APPENDIX “E” SGH DATA QUALITY Reporting Limit The SGH Excel spreadsheet of results contains the raw unaltered concentrations of the individual SGH compounds in units of “part-per-trillion” (ppt). The reporting of these ultra low levels is vital to the measurement of the small amounts of hydrocarbons now known to be leached/metabolized and subsequently released by dead bacteria that have been interacting with the ore at depth. To ensure that the data has a high level of confidence, a “reporting limit” is used. The reporting limit of 1 ppt actually represents a level of confidence of approximately 5 standard deviations where SGH data is assured to be “real” and non-zero. Thus in SGH the use of a reporting limit automatically removes site variability, and there is no need to further background subtract any data as the reporting limit has already filtered out any site background effects. Thus we recommend that all data that is equal to or greater than 2 ppt should be used in any data review. It is important to review all SGH data as low values that may be the centre of halo anomalies and higher values as apical anomalies or as halo ridges are all important. Laboratory Replicate Analysis A laboratory replicate is a sample taken randomly from the submitted survey being analyzed and are not unrelated samples taken from some large stockpile of bulk material. In the Organics laboratory an equal portion of this sieved sample, or pulp, is taken and analyzed in the same manner using the Gas Chromatography/Mass Spectrometer. The comparison of laboratory replicate and field duplicate results for chemical tests in the parts-per-million or even parts-per-billion range has typically been done using an absolute “relative percent difference (RPD)” statistic which is an easy proxy for error estimation rather than a more complete analysis of precision as specified by Thompson and Howarth. An RPD statistic is not appropriate for SGH results as the reporting limit for SGH is 1 part-per-trillion. Further, SGH is a semi-quantitative technique and was not designed to have the same level of precision as other less sensitive geochemistry’s as it is only used as an exploration tool and not for any assay work. SGH is also designed to cover a wide range of organic compounds with an unprecedented 162 compounds being measured for each sample. In order to analyze such a wide molecular weight range of compounds, sacrifices were made to the variability especially in the low molecular weight range of the SGH analysis. The result is that the first fifteen SGH compounds in the Excel spreadsheet is expected to exhibit more imprecision than the other 147 compounds. An SGH laboratory replicate is a large set of data for comparison even for just a few pairs of analyses. Precision calculations using a Thompson and Howarth approach should only be used for estimating error in individual measurements, and not for describing the average error in a larger data set. In geochemical exploration geochemists seek concentration patterns to interpret and thus rigorous precision in individual samples is not required because the concentrations of many samples are interpreted collectively. For these reasons recent and independent research at Acadia University in Canada promote that a percent Coefficient of Variation (%CV) should be used as a universal measurement of relative error in all geochemical applications. As SGH results are a relatively large data set for nearly all submissions, %CV is a better statistic for use with SGH. By using %CV, the concentration of duplicate pairs is irrelevant because the units of concentration cancel out in the formation of the coefficient of variation ratio. For SGH, the 647Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 43 of 52 %CV is calculated on all values ≥ 2 ppt. These values are averaged and represent a value for each pair of replicate analysis of the sample. All of the %CV values for the replicates are then averaged to report one %CV value to represent the overall estimate of the relative error in the laboratory sub-sampling from the prepared samples, and any instrumental variability, in the SGH data set for the survey. Actlabs' has successfully addressed the analytical challenge to minimize analytical variability for such a large list of compounds. Thus as SGH is also interpreted as a signature and is solely used for exploration and not assay measurement, the data from SGH is “fit for purpose” as a geochemical exploration tool. Historical SGH Precision In the general history of geochemistry, studies indicate that a large component of total measurement error is introduced during the collection of the initial sample and in sub-sampling, and that only a subordinate amount of error in the result is introduced during preparation and analysis. A historical record encompassing many projects for SGH, including a wide variety of sample types, geology and geography, shows that the consistency and precision for the analysis of SGH is excellent with an overall precision of 6.8% Coefficient of Variation (%CV). When last calculated, this number had a range of a maximum of 12.4% CV, a minimum of 3.0% CV, with a standard deviation of 1.6%, in a population made up of over 400 targets (over 45,000 samples) interpreted since June of 2004. Again the precision of 6.8% CV included all of the sample types as soil from different horizons, peat, till, humus, lake-bottom sediments, ocean-bottom sediments, and even snow. When field duplicates have been revealed to us, we have found that the precision of the field duplicates are in the range of about 9 to 12 %CV. As SGH is interpreted using a combination of compounds as a chemical “class” or signature, the affect of a few concentrations that may be imprecise in a direct comparison of duplicates is not significant. Further, projects that have been re-sampled at different times or seasons are expected to have different SGH concentrations. The SGH anomalies may not be in exactly the same position or of the same intensity due to variable conditions that may have affected the dispersion of different pathfinder classes. However, the SGH “signature” as to the presence of the specific mix of SGH pathfinder classes will definitely still exist, and will retain the ability to identify the deposit type and vector to the same target location. Laboratory Materials Blank – Quality Assurance (LMB-QA) The Laboratory Materials Blank Quality Assurance measurements (LMB-QA) shown in the SGH spreadsheet of results are matrix free blanks analyzed for SGH. These blanks are not standard laboratory blanks as they do not accurately reflect an amount expected to be from laboratory handling or laboratory conditions that may be present and affect the sample analysis result. The LMB-QA measurements are a pre-warning system to only detect any contamination originating from laboratory glassware, vials or caps. As there is no substrate to emulate the sample matrix, the full solvating power of the SGH leaching solution, effectively a water leach, is fully directed at the small surface area of the glassware, vials or caps. In a sample analysis the solvating power of the SGH leaching solution is distributed between the large sample surface area (from soil, humus, sediments, peat, till, etc.) and the relatively small contribution from the laboratory materials surfaces. The sample matrix also buffers the solvating or leaching effect in the sample versus the more vigorous leaching of the laboratory materials which do not experience this buffering effect. Thus the level of the LMB-QA reported is 648Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 44 of 52 biased high relative to the sample concentration and the actual contribution of the laboratory reagents, equipment, handling, etc. to the values in samples is significantly lower. This situation in organic laboratory analysis only occurs at such extremely low part-per-trillion (ppt) measurement levels. This is one of the reasons that SGH uses a reporting limit and not a detection limit. The 1 ppt reporting limit used in the SGH spreadsheet of raw concentration data is 3 to 5 times greater than a detection limit. The reporting limit automatically filters out analytical noise, the actual LMB-QA, and most of the sample survey site background. This has been proven as SGH values of 1 to 3 parts-per-trillion (ppt) have very often illustrated the outline of anomalies directly related to mineral targets. Thus all SGH values greater than or equal to 1 or 2 ppt should be used as reliable values for interpretations. The LMB-QA values thus should not be used to background subtract any SGH data. The LMB-QA values are only an early warning as a quality assurance procedure to indicate the relative cleanliness of laboratory glassware, vials, caps, and the laboratory water supply at the ppt concentration level. Do not subtract the LMB-QA values from SGH sample data. 649Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 45 of 52 APPENDIX “F” SGH DATA INTERPRETATION SGH Interpretation Report All SGH submissions must be accompanied by relative or UTM coordinates so that we may ensure that the sample survey design is appropriate for use with SGH, and to provide an SGH interpretation with the results. In our interpretation procedure, we separate the results into 19 SGH sub-classes. These classes include specific alkanes, alkenes, thiophenes, aromatic, and polyaromatic compounds. Note that none of the SGH hydrocarbons are “gaseous” at room temperature and pressure. The classes are then evaluated in terms of their geochromatography and for coincident compound class anomalies that are unique to different types of mineralization. Actlabs uses a six point scale in assigning a subjective rating of similarity of the SGH signatures found in the submitted survey to signatures previously reviewed and researched from known case studies over the same commodity type. Also factored into this rating is the appropriateness of the survey and amount of data/sample locations that is available for interpretation. This rating scale is described in detail in the following section. SGH PATHFINDER CLASS MAGNITUDE The magnitude of any individual concentration or that of a hydrocarbon class does not imply that the data is of more importance or that mineralization is of higher quantity or grade. SGH interpretation must use the review of the combination of specific hydrocarbon classes to make any interpretation. GEOCHEMICAL ANOMALY THRESHOLD VALUE In the interpretation of “inorganic” geochemical data one of the determinations to be made is to calculate a “Threshold” value above which data is considered anomalous. This is done on an element by element basis. In the interpretation of this “organic” geochemical data this determination is done differently. The determination of a threshold value is not calculated for each hydrocarbon compound. The determination of a threshold value is also a concentration below which geochemical data is considered as “noise” for the purposes of geochemical interpretation. As discussed, SGH uses a “Reporting Limit” instead of some type of Detection Limit. The amount of noise that is already eliminated in the data, as below the Reporting Limit of 1 part-per-trillion (shown in the data spreadsheet as “-1” as “not-detected at a Reporting Limit of 1 ppt”) is equivalent to approximately 5 standard deviations of variability. To thus calculate an additional Threshold Value is a loss of real and valuable data. Further, in the interpretation of SGH data, individual compounds are not considered (unless explicitly mentioned in the report). The interpretation of SGH data is exclusively conducted by “compound chemical class” which is the sum of four to fourteen individual hydrocarbons in the same organic chemical class as these compounds naturally have the same chemical properties that ultimately define their spatial dispersion characteristics in their rise from a mineral target through the overburden. This combined class is more reliable than the measurement of any one compound. SGH also eliminates the need for a Threshold value determination above the Reporting Limit due to the “high specificity” of the specific hydrocarbons and the classes they form. Each of the hydrocarbons has been 650Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 46 of 52 hand selected due to their lower probability of being found in general surface soils. Further, only those classes where the majority of the compounds are detected above the Reporting Limit are considered in the interpretation. This defines the SGH geochemistry as having less geochemical noise due to the use of a reporting limit and as having higher confidence in the use of groups (classes) of data instead of individual compounds. However the most important aspect of interpretation is the use of a forensic signature. At least three specific “Pathfinder” classes, based on the combinations or template of classes we have developed, must be present to define the hydrocarbon signature to confidently predict the presence of a specific type of mineral target. Do not calculate another Threshold value. Fact: It has been proven many times that important SGH anomalies that depict mineralization at depth can exist even with data at 3 ppt. Mobilized Inorganic Geochemical Anomalies It is important to note that SGH is essentially “blind” to any inorganic content in samples as only organic compounds as hydrocarbons are measured. Thus inorganic geochemical surface anomalies that have migrated away from the mineral source, and thus may be interpreted and found to be a false target location, is not detected and does not affect SGH results. This fact is of great advantage when comparing the SGH results to inorganic geochemical results. If there is agreement in the location of the anomalies between the organic and inorganic technique, such as Actlabs’ Enzyme Leach, a significant increase in confidence in the target location can be realized. If there is no agreement or a shift in the location of the anomalies between the techniques, the inorganic anomaly may have been mobilized in the surficial environment. The Nugget Effect As SGH is “blind” to the inorganic content in the survey samples, any concern of a “nugget effect” will not be encountered with SGH data. A “nugget effect” may be of a concern for other inorganic geochemical methods from surveys over copper, gold, lead, nickel, etc. type targets. 651Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 47 of 52 SGH DATA LEVELING The combination of SGH data from different field sampling events has rarely required leveling in order to combine survey grids. The only circumstances that have occasionally required leveling has been the combination of samples that are very fine in texture, thus having a combined large surface area to samples of peat that may be in nearby areas. Even after maceration of the peat and in using the maximum size of sample amenable to this test method, peat samples have a significantly lower surface area. Peat samples have only required leveling in one survey in the last 500 SGH interpretations. In only the last year it has been observed that SGH data may require leveling when different field sampling events have significantly different soil temperature. It has been documented that only when “soil” samples are taken from “frozen” ground that data leveling may be required as frozen sample act as a frozen cap to the hydrocarbon flux and may collect a higher concentration of hydrocarbon compounds compared to sampling during seasons where the samples are not frozen. Only two surveys have required leveling in the last 500 SGH interpretations. The author has taken introductory training in the leveling of geochemical data. If leveling is required, both data sets are reviewed in terms of maximum, minimum and average values for each SGH Pathfinder Class intended for use in the interpretation. Data in sectioned into quartiles and each section is assigned specific leveling factors that is then applied to one data set. It should be noted that any type of data leveling is an approximation. 652Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 48 of 52 APPENDIX “G” SGH RATING SYSTEM DESCRIPTION To date SGH has been found to be successful in the depiction of buried mineralization for Gold, Nickel, VMS, SEDEX, Uranium, Cu-Ni-PGE, IOCG, Base Metal, Tungsten, Lithium, Polymetallic, and Copper, as well as for Kimberlites, Coal Seam, Wet Gas and Oil Plays. SGH data has developed into a dual exploration tool. From the interpretation, a vertical projection of the predicted location of the target can be made as well as a statement on the rating of the comparability of the identification of the anticipated target type to that from known case studies, as an example: if the client anticipates the target to be a Gold deposit, what is the rating or comparability that the target is similar to the SGH results over a Gold deposit in Nunavut, shear hosted and sediment hosted deposits in Nevada, or Paleochannel Gold mineralization in Western Australia.  A rating of “6” is the highest or best rating, and means that the SGH classes most important to describing a Gold related hydrocarbon signature are all present and consistently vector to the same location with well defined anomalies. To obtain this rating there also needs to be other SGH classes that when mapped lend support to the predicted location.  A rating of “5” means that the SGH classes most important to describing a Gold signature are all present and consistently describe the same location with well defined anomalies. The SGH signatures may not be strong enough to also develop additional supporting classes.  A rating of “4” means that the SGH classes most important to describing a Gold signature are mostly present describing the location with well defined anomalies. Supporting classes may also be present.  A rating of “3” means that the SGH classes most important to describing a Gold signature are mostly present and describe the same location with fairly well defined anomalies. Some supporting classes may or may not be present.  A rating of “2” means that some of the SGH classes most important to describing a Gold signature are present but a predicted location is difficult to determine. Some supporting classes may be present  A rating of “1” is the lowest rating, and means that one of the SGH classes most important to describing a Gold signature is present but a predicted location is difficult to determine. Supporting classes are also not helpful. The SGH rating is directly and significantly affected by the survey design. Small data sets, especially if significantly <50 sample locations, or transects/surveys that are geographically too short will automatically receive a lower rating no matter how impressive an SGH anomaly might be. When there is not enough sample locations to adequately review the SGH class geochromatography, or when the sample spacing is inadequate, or if the spacing is highly variable such that it biases the interpretation of the results, then the confidence in the interpretation of any geochemistry is adversely 653Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 49 of 52 affected. The SGH rating is not just a rating of the agreement between the SGH pathfinder classes for a particular target type; it is a rating of the overall confidence in the SGH results from this particular survey. The interpretation is only based on the SGH results without any information from other geochemical, geological or geophysical information unless otherwise specified. HISTORY & UNDERSTANDING The subjective SGH rating system has been used since 2004 when Activation Laboratories started providing an SGH Interpretation Report with ever submission for SGH analysis to aid our clients in understanding this organic geochemistry and ensuring that they obtain the best results for their surveys. As explained in the previous section, the SGH rating is not just a rating of how definitive an SGH anomaly is, and it is not based just on the map(s) provided in this report. It is a rating of “confidence in the interpreted anomaly” from the combination of:  (i) are the expected SGH Pathfinder Classes of compounds present from the template for this target type (one Pathfinder Class map is shown in the report, at least three must be present to adequately describe the correct signature for a particular target),  (ii) how well do these SGH Pathfinder Classes agree in describing an particular area,  (iii) how well does this agreement compare to SGH case studies over known targets of that type,  (iv) how well is the interpreted anomaly defined by the survey (i.e. a single transect does not provide the same confidence as a complete grid of samples), and  (v) is there at least a minimum of 50 sample locations in the survey so that there may be an adequate amount of data to observe the geochromatography of the different SGH Pathfinder Class of compounds. The question often arises by clients as to the frequency of a rating, e.g. “how often is a rating of 5.0 given in an interpretation”. To better understand this we present this review of the history of the SGH rating program since 2004 and some of the underlying situations that can affect the historical rating charts. Originally it was recommended that a minimum of 35 sample location be used for small target exploration, however it was quite quickly realized that this is often insufficient and at least 50 sample locations were required. In 2007 the rating scale was refined to include increments of 0.5 units rather than just integer values from 0 to 6. A rating frequency may be biased high as most clients conduct an orientation study over a known target, thus several of these projects result in high ratings. Note that, at this time, the rating is not said to be linked to grade of a deposit or depth to the target. Even in exploration surveys clients tend to submit samples over more promising targets due to knowledge of the geology and prior geochemical or geophysical results. As shown in the following chart, projects with SGH data from 200 or more sample locations have a higher level of confidence in the interpretation as the 654Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 50 of 52 geochromatography of the SGH Pathfinder Classes of compounds can be more completely observed and reviewed. The rating frequency may be biased low as research projects often include a bare minimum of samples to reduce costs. Research projects may also be over targets known to be difficult to depict with geochemistry. Multiple targets in close vicinity in a survey may result in a low bias as the Pathfinder Class geochromatography is more difficult to deconvelute. Ratings may also be biased low if less than the recommended 50 sample locations are submitted as indicated by the following chart. This chart also illustrates that there is no interpretation bias to a particular rating value. 01002003004005006007008009000 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5 6Number of Samples per Target for ≥50 Samples SGH Ratings 2004-2009SGH Ratings vs Number of Samples per Target for ≥ 50 Samples1520253035400 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5 6Number of Samples per Target for Project Sizes <50 SamplesSGH Ratings 2004-2009SGH Ratings vs Number of Samples per Target for < 50 Samples655Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 51 of 52 The overall rating frequency for over 400 targets from January 2004 to December 2009 is shown in the chart below illustrating that surveys over more promising targets are most often submitted for best use of research or exploration dollars. It also indicates that the 0.5 increments were less frequent as they started in 2007. More specific for SGH interpretation for Gold targets, the overall rating frequency for 97 targets from January 2004 to December 2009 is shown in the chart below that also illustrates that surveys over more promising Gold targets are most often submitted for best use of research or exploration dollars. 14128339442961347829 330204060801000.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0FrequencySGH Ratings 2004-2009SGH Rating History0 13 2411151917 1897051015200.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0FrequencyRatingTotal Gold656Quality Analysis ... Innovative Technologies November 27, 2015 Activation Laboratories Ltd. A14-05812 1336 Sandhill Drive ● Ancaster, ON ● L9G 4V5 ● CANADA ● Tel: (905) 648-9611 ● Fax: (905) 648-9613 ● Toll Free: 1-888-ACTLABS E-mail: dalesutherland@actlabsint.com ● Web Site: www.actlabs.com Page 52 of 52 APPENDIX “H” NOTE: THERE IS NEW PRICING FOR THE SGH AND OSG GEOCHEMISTRIES AS OF 2014 SAMPLE PREPARATION: CODE S4 - $4.20 CDN per sample INTERPRETATION FOR ONE COMMODITY TARGETS: Included in the price of analysis of $48.00 CDN per sample INTERPRETATION FOR MULTI-COMMODITY TARGETS: i.e. VMS, SEDEX, Polymetallic, IOCG, IOCGU, Cu-Au-Porphyry, etc. – add additional price of $500 is applied to cover the additional time in interpretation. “SUPPLEMENTAL REPORT”: ($ 1,200.00) Those clients who have determined that these SGH results will add an important aspect to their exploration effort can request a “Supplemental Report”. This report contains the additional SGH Pathfinder Classes and an explanation of their use in the SGH interpretation that supports the initial applied “Rating” for the survey as a relative comparison to the results previously obtained in case studies that were used to create the SGH template for the general target type. “ADDITIONAL INTERPRETATIONS”: ($ 1,200.00) - if 30 days after delivery of the report. The SGH data can be interpreted multiple times in comparison to a variety of SGH templates developed for exploration for different mineral targets or petroleum plays. The samples do not have to be reanalyzed. This can be addressed as a separate section of a report or as a separate report based on the client’s wishes. The price is per survey area, e.g. if there are two projects in a submission, perhaps a North area and South area, and both survey areas are to be interpreted for say Gold and Copper, the first interpretation is included in the SGH analysis price, the second interpretation for each area would be priced at $1,200 per area, thus a total of $2,400. “BASIC OR SUPPLEMENTAL REPORT GIS PACKAGE”: ($ 300.00) Those clients that wish to import the SGH results into their GIS software can request a “GIS Package”, which will include the geo-referenced image files that reflect the mapped SGH Pathfinder Class or Classes contained in the Standard or Supplemental Report and an Excel CSV file(s) containing the associated Class Sum data. 657658659660661662663664665666667668669670671672673674675676677678679680681682
Thesis/Dissertation
eng
Geological Sciences
Vancouver : University of British Columbia Library
Attribution-NoDerivatives 4.0 International
Graduate
The development of surface geochemical technologies for the detection of kimberlites concealed by glacial drift in the Northwest Territories, Canada
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