UBC Theses and Dissertations

UBC Theses Logo

UBC Theses and Dissertations

NMR-ON studies of europium vanadate and hcp cobalt Willetts, Martin

Abstract

The quadrupole interaction on Eu³⁺ in EuVO₄ was investigated using low temperature nuclear orientation. The interaction strength, P, on the ¹⁵²Eu nuclei was measured as 1±4 MHz, with a total cooling time of 24 hours. This low value is attributed to either the high symmetry of the europium lattice postion, or a very long (greater than one day) spin lattice relaxation time. The NMR frequency of ⁵⁹Co was measured at low temperature, using the first observation of thermometric NMR in a conductor. The motive was to measure the frequency pulling in cobalt metal, and the resonance was observed to be 218.4(4) MHz at 70mK, which is 1.5 MHz below the 1 K value. The frequency pulling effect on the nuclear resonance is due to the Suhl-Nakamura interaction between the nuclear spins.

Item Media

Item Citations and Data

Rights

For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.