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Cationic carbonyl derivatives of electron-rich metals-syntheses, structures, and spectroscopic properties Wang, Changqing
Abstract
The range of thermally stable, predominantly a-bonded metal carbonyl derivatives has been expanded to include Pd(I), Pd(II), Ir(III), Os(II), and Ru(II). The new compounds, [Pd(CO)₄][Sb₂F₁₁]₂, cis-Pd(CO)₂(SO₃F)₂, [Pd₂(µ-CO)₂](SO₃F)₂, [Pd₂(µ -CO) ₂][Sb₂₁₁]₂, mer- Ir(CO)₃(SO₃F)₃, [Ir(CO)₅Cl][Sb₂ F₁₁]₂, [Ru(CO)₆][Sb₂F₁₁]₂, [Os(CO)₆][Sb₂F₁₁]₂, and cis- Pt(CO)₂(Sb₂Fn)₂ have been synthesized. The compounds have been characterized using a variety of physico-chemical techniques: elemental analysis, FT-IR and Raman spectroscopy, and ¹³C NMR spectroscopy. For cis-Pd(CO)₂(SO₃F)₂, [Pd₂(µ-CO)₂](SO₃F)₂, mer- Ir(CO)₃(SO₃F)₃, and [Ir(CO)₅Cl][Sb₂F₁₁]₂, the molecular structures have been determined by single crystal X-ray diffraction. [More abstract follows; please see pp.3+ of the accompanying pdf file]
Item Metadata
| Title |
Cationic carbonyl derivatives of electron-rich metals-syntheses, structures, and spectroscopic properties
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| Creator | |
| Publisher |
University of British Columbia
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| Date Issued |
1996
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| Description |
The range of thermally stable, predominantly a-bonded metal carbonyl derivatives has
been expanded to include Pd(I), Pd(II), Ir(III), Os(II), and Ru(II). The new compounds,
[Pd(CO)₄][Sb₂F₁₁]₂, cis-Pd(CO)₂(SO₃F)₂, [Pd₂(µ-CO)₂](SO₃F)₂, [Pd₂(µ -CO) ₂][Sb₂₁₁]₂, mer-
Ir(CO)₃(SO₃F)₃, [Ir(CO)₅Cl][Sb₂ F₁₁]₂, [Ru(CO)₆][Sb₂F₁₁]₂, [Os(CO)₆][Sb₂F₁₁]₂, and cis-
Pt(CO)₂(Sb₂Fn)₂ have been synthesized. The compounds have been characterized using a
variety of physico-chemical techniques: elemental analysis, FT-IR and Raman spectroscopy,
and ¹³C NMR spectroscopy. For cis-Pd(CO)₂(SO₃F)₂, [Pd₂(µ-CO)₂](SO₃F)₂, mer-
Ir(CO)₃(SO₃F)₃, and [Ir(CO)₅Cl][Sb₂F₁₁]₂, the molecular structures have been determined by
single crystal X-ray diffraction.
[More abstract follows; please see pp.3+ of the accompanying pdf file]
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| Extent |
9140332 bytes
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| Genre | |
| Type | |
| File Format |
application/pdf
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| Language |
eng
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| Date Available |
2009-03-17
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| Provider |
Vancouver : University of British Columbia Library
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| Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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| DOI |
10.14288/1.0059520
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| URI | |
| Degree | |
| Program | |
| Affiliation | |
| Degree Grantor |
University of British Columbia
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| Graduation Date |
1996-11
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| Campus | |
| Scholarly Level |
Graduate
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| Aggregated Source Repository |
DSpace
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Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.