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UBC Theses and Dissertations
Applications of hypervalent iodine reagents in organic synthesis : the development of iodonium metathesis reaction and effort towards himandrine Kasahara, Takahito
Abstract
This thesis discloses two different applications of hypervalent iodine(III) reagents in organic synthesis. In the first part, a novel reactivity of diaryliodonium triflates towards aryl iodides will be discussed. The new mode of reactivity allows various diaryliodonium triflates to be accessed, simply by heating a mixture of electron deficient diaryliodonium triflate with a moderately electron rich aryliodide. In the second part of the thesis, the use of (diacetoxyiodo) benzene in oxidative amidation in the context of total synthesis will be made.
Item Metadata
Title |
Applications of hypervalent iodine reagents in organic synthesis : the development of iodonium metathesis reaction and effort towards himandrine
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Creator | |
Publisher |
University of British Columbia
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Date Issued |
2015
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Description |
This thesis discloses two different applications of hypervalent iodine(III) reagents in organic synthesis. In the first part, a novel reactivity of diaryliodonium triflates towards aryl iodides will be discussed. The new mode of reactivity allows various diaryliodonium triflates to be accessed, simply by heating a mixture of electron deficient diaryliodonium triflate with a moderately electron rich aryliodide. In the second part of the thesis, the use of (diacetoxyiodo) benzene in oxidative amidation in the context of total synthesis will be made.
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Genre | |
Type | |
Language |
eng
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Date Available |
2015-10-24
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Provider |
Vancouver : University of British Columbia Library
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Rights |
Attribution-NonCommercial-NoDerivs 2.5 Canada
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DOI |
10.14288/1.0166790
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URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
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Graduation Date |
2015-11
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Campus | |
Scholarly Level |
Graduate
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Rights URI | |
Aggregated Source Repository |
DSpace
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Rights
Attribution-NonCommercial-NoDerivs 2.5 Canada