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The structure determination of three inorganic and two organic compounds by x-ray diffraction 1977

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THE STRUCTURE DETERMISATION OF THREE INORGANIC AND TWO ORGANIC COMPOUNDS BY X-RAY DIFFRACTION. By ANTHONY MERCER. .Sc., U n i v e r s i t y o f B r i s t o l , England, 1972. A THESIS SUBMITTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY i n the department of CHEMISTRY. We accept t h i s t h e s i s as conforming t o the r e g u i r e d standard. THE UNIVERSITY OF BRITISH COLUMBIA JUNE 1977. (c) Anthony Mercer, 1977 In presenting th i s thes i s in pa r t i a l fu l f i lment of the requirements for an advanced degree at the Univers i ty of B r i t i s h Columbia, I agree that the L ibrary sha l l make it f ree ly ava i l ab le for reference and study. I fur ther agree that permission for extensive copying of th is thesis for scho lar ly purposes may be granted by the Head of my Department or by his representat ives. It is understood that copying or pub l i cat ion of this thes is fo r f inanc ia l gain sha l l not be allowed without my writ ten permission. Department of C m CWwSTft^f The Un ivers i ty o f B r i t i s h Columbia 2075 Wesbrook Place Vancouver, Canada V6T 1W5 Date 4 a b s t r a c t This thesis deals with the current methods avail a b l e f o r X-ray structure determination and with the c r y s t a l and molecular structure determination of f i v e compounds using these methods. The f i v e compounds are 1) [ 2,3-Bis (dimethylarsino)- 1, 1, 1,4, 4, 4-hexaf luorobut- 2~ene-As,As3tricarbonyldiiodotungsten(II), Me^AsC (CF3 j~:C (CF^) AsBe*WXx (CO)3 2) Dimethylammonium trichlorotris(dimethylsulphoxide}- ruthenate(II) , [ ( (CE%)t SQ)% RuCl a r [ (CH^i NHa J+ 3) Dichlorotetrakis{dimethylsulphoxide)ruthenium(II), (Me 1SO)v fRuCl x 4) 1,3,7-Triraethyl-2,6-dioxypuriae hydrochloride dihydrate (caffeine hydrochloride dihydrate), C 8H n ClN l f0 1.lH 10 .5) 1-Acetyl-3-benzamido-2-keto-4- (2,3, 4, 6-tetra-O-acetyl- P-D-glucopyranosyloxy)-k 3-pyrroline, The structures of compounds 1), 2), and 3) were determined by Patterson syntheses, compound 4) by centrosymmetric d i r e c t methods and compound 5) by non- centrosymmetric direct methods. A l l structures were then refined using f u l l - m a t r i x least-sguares procedures. The relevant c r y s t a l data for a l l f i v e compounds can be found i n Table A In the tungsten compound [ 1 ) ] the tungsten atom i s seven-coordinate with a distorted capped octahedral environment, the capping group being a carbonyl. The capped face consists of the two remaining carbonyl groups and one of the arsenic atoms from the bidentate ligand. The uncapped face contains the two iodine atoms and the remaining arsenic i i i Table.A Crystal data for the f i v e compounds examined Space Group Unit C e l l Dimensions Fi n a l R Factor 2) 3) 4) £2,/c ££2, a £2 4/n £2,/c a = 15.37 (2) 90.0 b 9.52 9(1) I 112.03 (2) 0. 067 c = 15. 967(3) I — 90.0 a 27.45 9(5) 90.0 b 9.925(1) = 90.0 0. 045 c 14.266(3) — 90.0 a = 8.9 39(3) 90.0 b 18.045(7) 1 91.52 (2) 0. 041 c 1 1.363(3) 90.0 a — 12.391 (4) 90.0 b 6.52 4(1) I = 118.82 (3) 0. 064 c = 17. 167(6) 90.0 a 19.629(5) = 90.0 b = 7.504(2) 1 = 90.53(2) 0. 079 c 9.830(2) tt = 90.0 5) P24 atom. The structure of the ruthenium compound [ 2) ] consists of two c r y s t a l l c g r a p h i c a l l y non-equivalent anions i n the asymmetric unit linked by hydrogen bonding v i a dimethylammonium cations. The coordination geometry about the s t r u c t u r a l l y s i m i l a r anions i s e s s e n t i a l l y that of an octahedron with the DHSO ligands being bonded to Ru via the sulphur atoms. The co-ordination geometry about the ruthenium atom f o r compound 3) i s e s s e n t i a l l y octahedral with c i s chlorine atoms; Of the four DMSO ligands three are S-bonded and one i s O-bonded, the O-bonded ligand being trans to a S-bonded ligand. For c a f f e i n e h y d r o c h l o r i d e [ 4) ] the fused r i n g system i s e s s e n t i a l l y planar and protonated a t the 9 - p o s i t i o h . The c r y s t a l c o n t a i n s two types of hydrogen bonding i n v o l v i n g 0- H...C1 and N-H...0 i n t e r a c t i o n s . The s t r u c t u r e of compound 5) c o n s i s t s of a pyranose r i n g i n the c h a i r conformation with t h e f o u r 0 - a c e t y l s u b s t i t u e n t s i n e q u a t o r i a l p o s i t i o n s ; the pyranose r i n g i s connected to a p l a n a r p y r r o l i n e r i n g v i a a £-oxygen bridge. V TABLE OF CONTENTS Pag e TITLE PAGE .............................................. i ABSTRACT i i TftBLE OF CONTENTS ....................................... v LIST OF TABLES ., v i i i LIST OF FIGURES .......................... ............ x i ACKNOWLEDGEMENTS x i i i GENERAL INTRODUCTION 1 CHAPTER 1. AN INTRODUCTION TO X-RAY CRYSTALLOGRAPHY ..... 4 k) A p r a c t i c a l viewpoint ........................ 5 B) A t h e o r e t i c a l viewpoint ...................... 14 CHAPTER 2. CRYSTAL AND MOLECULAR STRUCTURE OF [2,3- BIS(DIHETHYLARSINO)-1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE- AS, AS]TRICARBONYL DIIODOTUNGSTEN(II) ..................... 16 Introduction .................................... 17 Experimental 17 Structure aaalysis .............................. 18 Results and discussion .......................... 26 v i CHS.PTES 3. CRYSTAL AND MOLECULAR STRUCTURE OF DIMETHYL- AMMONIUM TRICHLO 80TRIS (DIMETHYLS ULPH OXIDE) BOTH EN AT E (II) . 39 Introduction 40 Experimental 40 Structure analysis .............................. 41 Results and discussion .......................... 46 CHAPTER 4. CRYSTAL AND MOLECULAR STRUCTURE OF DICHLOROTETRAKIS(DIM ETHYLSULPHOXIDE) ROTH ENIUM (II) ...... . 53 Introduction 54 Experimental .................................... 54 Structure analysis .............................. 55 Results and discussion 59 CHAPTER 5. CRYSTAL AND MOLECULAR STRUCTURE OF 1,3,7- TRIMETHYL-2,6-DIOXYPURIN E HYDROCHLORIDE DIHYDRATE (CAFFEINE HYDROCHLORIDE DIHYDRATE) 69 Introduction .................................... 70 Experimental 70 Structure analysis 71 Analysis of thermal motion ...................... 77 Results and discussion 84 v i i CHAPTER 6. CRYSTAL AND MOLECULAR STRUCTURE OF 1—ACETYL-3- BENZAMIDO-2-KETO-4- (2,4, 4, 6-TETRA-O-ACETYL-p-D- GLUCOPYRANOSYLOXY)-&3—PYRROLINE 92 Introduction .................................... 93 Experimental 93 Structure analysis .............................. 94 Results and discussion .......................... 100 SUMMARY 113 REFERENCES ................................. ..117 v i i i LIST OF TABLES Table Page [2, 3-Bis (dimethylarsino)- 1,1, 1, 4, 4, 4-hexaf luorobut-2-ene- As, As]tricarbonyldiiodotungsten (II) 1 The interatomic vectors and the solution to the Patterson function »•••• • 22 2 C r y s t a l dimensions and face indices for the absorption correction 24 3 F i n a l atomic coordinates 28 4 Fi n a l thermal parameters ......................... 29 5 Bond lengths 32 6 Bond angles ...................................... 3 3 7 Mean planes ...................................... 36 Dimethylammonium trichlorotris{dimethylsulphoxide)- ruthenate (II) 8 F i n a l atomic coordinates ......................... 44 9 F i n a l thernal parameters 45 10 Bond lengths ..................................... 48 11 Bond angles 49 12 Non-bonded contacts 51 i x Dichlorotetrakis (dimethylsulphoxide) ruthenium (II) 13 F i n a l atomic coordinates 57 14 F i n a l thermal parameters ......................... 5 8 15 Bond lengths 61 16 Bond angles 62 17 Mean planes ...................................... 63 18 Comparison of the s t r u c t u r a l data for some dimethylsulphoxide complexes ..................... 66 1,3,7-Trimethy1-2,6-dioxypurine hydrochloride dihydrate (Caffeine hydrochloride dihydrate) 19 Starting set of r e f l e c t i o n s 74 20 Results of the phase determination procedure ..... 76 21 F i n a l atomic coordinates 78 22 F i n a l thermal parameters ......................... 79 23 Bigid body thermal parameters .................... 8 1 2 4 Bond lengths 82 25 Bond angles 83 26 Structural data for some purine derivatives 87 27 Mean planes 89 28 Non-bonded contacts .............................. 90 X 1-Acetyl -3-benzamido -2 - keto - 4 - ( 2 , 4 , a , 6-tetra-O-acetyl-^-D- glticopyranosyloxy) pyrroline 2 9 Starting set of r e f l e c t i o n s . 9 6 3 0 Results of the phase determination procedure ..... 9 7 31 F i n a l atomic coordinates ......................... 1 0 2 3 2 F i n a l thermal parameters ......................... 10 4 3 3 Bond lengths 1 0 5 3 4 Bond angles ...................................... 1 0 6 3 5 Mean planes 1 0 7 36 Structural data for some pyranose rings .......... 10 9 3 7 Non-bonded contacts .............................. 1 11 x i LIST OF FIGURES F i g u r e Page I n t r o d u c t i o n 1 The sphere of r e f l e c t i o n 8 2 Flow c h a r t of p r a c t i c a l c r y s t a l l o g r a p h y .......... 13 [2,3-Bis{dimethylarsino)~1,1,1,4,4,4-hexafluorobut-2-ene- A s , A s ] t r i c a r b o n y l d i i o d o t u n g s t e n (II) 3 Schematic diagram of compounds |1) and (2) 26 4 View of the molecule down the capping c a r b o n y l group with the c a r b o n y l group removed .................. 27 5 A stereoview of the molecule ..................... 31 6 The s t r u c t u r e viewed down b ...................... 37 Dimethylammonium t r i c h l o r o t r i s ( d i m e t h y l s u l p h o x i d e ) - r uthenate (II) 7 A g e n e r a l view of the s t r u c t u r e .................. 47 8 The s t r u c t u r e viewed down c ...................... 52 D i c h l o r o t e t r a k i s (dimethylsulphoxide) ruthenium(II) 9 A g e n e r a l view of the s t r u c t u r e 60 10 The s t r u c t u r e viewed down b ...................... 67 x i i 1,3,7-Trimethyl-2,6-dioxypurine hydrochloride dihydrate (Caffeine hydrochloride dihydrate) 11 A general view of the structure .................. 80 12 Comparison of several imidazole ring compounds ... 8 5 13 The structure viewed down b ...................... 91 1-Acetyl-3-benzamido-2-keto-4-(2,4,4,6-tetra-O-acetyl-p-D- glucopyranosyloxy )-A 3-pyrroline 14 (A) A stereoview of the structure 101 (B) The conventional chemical structure ..........101 15 The structure viewed down b ...................... 112 ACKNOWLEDGEMENTS I wish to express my gratitude to Professor James Trotter for his help and guidance throughout a l l stages of t h i s work. I am also indebted to my fellow graduate students and postdoctoral fellows who have aided me at a l l times, and i n par t i c u l a r to Dr. Steven Rettig, for his assistance in the l a t e r stages of the work and i n the preparation of t h i s thesis. I would also l i k e to thank Dr. L. Mihichuk for the tungsten c r y s t a l s (Chapter 2), Dr. R. McMillan for the two ruthenium compounds (Chapters 3 and 4), Dr. D. Lenard f o r the caffeine compound (Chapter 5), and Dr. A. Brink for the pyrroline c r y s t a l s . I am grateful to the Killam Foundation for f i n a n c i a l support i n the form of a postgraduate scholarship in the years 1973-1974 and 1974-1975. F i n a l l y , I am very grateful to a l l the Canadian people I have met who have made the past five years such happy ones. 1 GENES AL INTRODUCTION 2 This thesis deals p r i n c i p a l l y with the structure determination by single c r y s t a l X-ray d i f f r a c t i o n of f i v e compounds i n t h e i r c r y s t a l l i n e state. I t i l l u s t r a t e s by both t h e o r e t i c a l and p r a c t i c a l discussion the three major methods presently available for structure determination v i z . the Patterson heavy atom synthesis, centrosymmetric d i r e c t methods, and non-centrosyrametric dir e c t methods, and also contains a brief description of the p r a c t i c a l aspects of X- ray crystallography. Chapter 1 deals with the p r a c t i c a l aspects and i s designed to explain some of the terms used in the experimental sections of Chapters 2-6, and also give the non- crystallographie reader of t h i s thesis a l i m i t e d background to crystallography. A l l crystallographic symbols and nomenclature appearing throughout t h i s thesis have t h e i r conventional meanings described i n the "International Tables for X-ray Crystallography" (1). Chapters 2-6 contain the description of the methods of structure analysis used, with a discussion of the r e s u l t i n g molecular and c r y s t a l structures found, f o r the f i v e compounds examined. [2,3-bis (dimethylarsino)-1,1,1,4,4,4- hexafluoro-but-2-ene-As,Js]tricarbonyldiiodotungsten(II), d i - methylammonium trichlorotris(dimethy lsulphoxide)ruthenate(II), and d i c h l o r o t e t r a k i s (dimethylsulphoxide) ruthenium (II) were a l l solved using Patterson syntheses, 1,3,7-trimethyl-2,6- dioxypurine hydrochloride dihydrate was solved by centrosymmetric dir e c t methods, and 1-acetyl-3-benzamido-2- keto-4- (2,3, 4,6-tetr a-O-acetyl-p-D-glucopyranosyloxy) 3 p y r r o l i n e was s o l v e d using non-centrosymmetric d i r e c t methods. These methods are discussed i n d e t a i l f o r the tungsten, p u r i n e and p y r r o l i n e compounds r e p e c t i v e l y . For each o f the f i v e c r y s t a l s t r u c t u r e s the l e a s t - squares refinement was based on the minimization of ^ w(Fo- Fc) z where Fo and Fc are t h e observed and c a l c u l a t e d s t r u c t u r e f a c t o r s and w i s the assigned weighting f a c t o r . The a n i s o t r o p i c thermal f a c t o r s employed i n the refinement a r e U;; i n the e x p r e s s i o n : f = f°exp [ - 2 T t 2 (U M h 2 a * 2 + U i x ] c 2 b * 2 • U ^ ^ c * 2 + 2U, thka*b* + 2U u h f a * c * * + 20^k4b*c*) ] o where £ i s the t a b u l a t e d s c a t t e r i n g f a c t o r and f xs t h a t c o r r e c t e d f o r thermal motion. The i s o t r o p i c thermal parameters have the form: t = f°exp [-B (sine/A) 2 ] where B i s r e l a t e d t o the mean-square displacement, [ j 2 , of the atom from i t s mean p o s i t i o n by the e x p r e s s i o n : B = 8W2U2. CHAPTER 1 I N T R O D U C T I O N TO X-RAY C R Y S T A L L O G R A P H Y 5 A) A PRACTICAL VIEWPOINT X-ray crystallography has grown from i t s infancy some 60 years ago to become what many would f e e l i s the present day d e f i n i t i v e means of structure determination. From the complex pattern of d i f f r a c t e d X-ray i n t e n s i t i e s a crystallographer i s usually able to piece together the i n t e r n a l structure of the s i n g l e c r y s t a l chcsen f o r study. The end results contain information valuable to both t h e o r e t i c a l and p r a c t i c a l s c i e n t i s t s and as such are rarely equalled in terms of accuracy and r e l i a b i l i t y . Although the p r i n c i p l e s of X-ray crystallography are well established and are discussed i n several standard texts (2-6), the b r i e f synopsis of crystallographic terms and ideas given i n t h i s chapter, and the outline of the p r a c t i c a l aspects of obtaining the necessary data, should be very useful to the non- crystallographer reading t h i s thesis. Often a good X-ray crystallographic structure determination w i l l depend upon the s k i l l of the synthetic chemist to produce a suitable c r y s t a l . A s a t i s f a c t o r y c r y s t a l would be uniform i n i n t e r n a l structure, single ( i . e . not twinned), with a reasonable size and shape. The perfect s i z e and shape are d i f f i c u l t to define since they depend on a balance of contradictory factors (e.g. a larger size produces more i n t e n s i t y but introduces absorption effects that must be corrected); one equation f o r the optimum thickness i s that 1 0 f t = 2//*. where i s the l i n e a r absorption c o e f f i c i e n t . For organic compounds yuc<10cm-1 (for CuKa radiation) giving a t0pfc = 0.2cm which i s a large c r y s t a l indeed. A more general 6 r u l e i s that a uniform cross-section c r y s t a l of s i z e 0.1 to 0.3 mm i s preferred. Obviously i t i s easier to work with room temperature and a i r stable c r y s t a l s though techniques have been developed so that the structures of thermal- and a i r - unstable c r y s t a l s can s t i l l be determined. Once suit a b l e c r y s t a l s have been found, one i s attached to the end of a glass f i b r e , with a l i t t l e non-reactive adhesive, and mounted on a goniometer head. The goniometer head i s s p e c i a l l y designed to enable simple alignment of the c r y s t a l . It has two arcs which allow the c r y s t a l to be tipped by i 20° in each of two perpendicular planes, and two perpendicular s l i d e s which allow for l a t e r a l movement of the c r y s t a l . The crysta llcgrapher must now complete two d i s t i n c t operations on the c r y s t a l . F i r s t l y i t i s necessary to determine the s i z e and shape of the unit c e l l which also provides additional information on the i n t e r n a l symmetry of the c r y s t a l . Without t h i s 'geometry' information i t would be impossible to undertake the second part which e n t a i l s knowing the position of a l l d i f f r a c t e d X-rays and measuring the in t e n s i t y of these ' r e f l e c t i o n s ' , since i t i s these i n t e n s i t i e s that can be ultimately related to the d i s t r i b u t i o n of d i f f r a c t i n g electrons in the unit c e l l , i n other words the c r y s t a l structure. Bragg*s Law (7) f o r X-ray d i f f r a c t i o n from a c r y s t a l i s given by: n X = 2dsinG where n i s an integer, X i s the wavelength of X-ray 7 r a d i a t i o n , d i s the i n t e r p l a n a r s p a c i n g , and 8- i s the angle between the i n c i d e n t beam and the p a r t i c u l a r c r y s t a l plane being c o n s i d e r e d . The planes t h a t are , r e f l e c t i n g , the X-rays are named by M i l l e r i n d i c e s , which r e l a t e t o the i n t e r c e p t s any plane makes on a s e t of r e f e r e n c e axes a, b, and c. I f these i n t e r c e p t s are 1/k, V * ( f r a c t i o n s of the u n i t c e l l edge) then the plane i s s a i d to have M i l l e r i n d i c e s of ( h , k , i ) . Rearranging Bragg«s law g i v e s sin© = nX . 1 2 d and a s i m p l i f i e d view of d i f f r a c t i o n can be obtained by c o n s i d e r i n g a d i r e c t r e l a t i o n s h i p between sin§ and 1/d which i s the c o n s t r u c t of Ewald (8) , i n h i s r e c i p r o c a l l a t t i c e . A r e c i p r o c a l l a t t i c e can be d e f i n e d by c o n s i d e r i n g the normals to a l l p o s s i b l e d i r e c t l a t t i c e planes (h,k,£) drawn from the o r i g i n . Each normal i s t e r m i n a t e d at a p o i n t a d i s t a n c e 1/d^kJl from the o r i g i n , where d K K 1 i s the p e r p e n d i c u l a r d i s t a n c e between planes of the s e t (h,k,4). Now the d i f f r a c t i n g planes have been r e p l a c e d by p o i n t s and a r e c i p r o c a l l a t t i c e with axes a*, b* and c*, compared to the r e a l axes a, b and c, has been produced. Combining the r e c i p r o c a l l a t t i c e with the sphere o f r e f l e c t i o n a llows f o r a simple v i s u a l i z a t i o n of the d i f f r a c t i o n process ( f i g . 1). Whenever a r e c i p r o c a l l a t t i c e p o i n t c o i n c i d e s with the s u r f a c e of t h e sphere the c o n d i t i o n s f o r Bragg r e f l e c t i o n are f u l f i l l e d f o r the c o r r e s p o n d i n g s e t of planes i n d i r e c t space and a d i f f r a c t e d ray passes from the c e n t r e of the sphere through t h i s p o i n t of c o n t a c t . B F i g u r e 1 Schematic drawing of a r e c i p r o c a l l a t t i c e l e v e l (n) i n t e r s e c t i n g the sphere of r e f l e c t i o n . D i f f r a c t e d r a y s Fass f r c n the c e n t r e of t h e s p h e r e through the i n t e r s e c t i n g p o i n t s . As the c r y s t a l r o t a t e s o t h e r p o i n t s i n the r e c i p r o c a l l a t t i c e l e v e l c o n t a c t the sphere but always on the c i r c l e . Extended r a y s w i l l s e e t the c y l i n d r i c a l f i l m at the same h e i g h t i f the c r y s t a l i s c o r r e c t l y a l i g n e d . 9 The a p p l i c a t i o n of these concepts can be seen i n the methods used f o r determining the geometry of the u n i t c e l l . For t h i s e i t h e r a Weissenberg or a P r e c e s s i o n camera, but u s u a l l y both as they are complementary, can be used. In a Weissenberg camera a c y l i n d e r of f i l m i s c o - a x i a l with a r e a l r o t a t i o n a x i s (e.g. c ) , the r o t a t i o n a x i s being p e r p e n d i c u l a r t o the X-ray beam. By the r e c i p r o c a l l a t t i c e d e f i n i t i o n , the a*b* planes ( i . e . hkO, hk1, hk2f etc.) o f r e c i p r o c a l l a t t i c e p o i n t s must be p e r p e n d i c u l a r to the r o t a t i o n a x i s and p a r a l l e l to t h e beam ( f i g . 1) . On o s c i l l a t i o n these p o i n t s w i l l c ut the sphere i n a c i r c l e , and should, when the d i f f r a c t e d rays through these i n t e r s e c t i n g p o i n t s are extended, meet the f i l m a t the same h e i g h t . Then on u n r o l l i n g and developing the d i f f r a c t e d spots w i l l l i e on s t r a i g h t l i n e s or rows on the f i l m . E r r o r s i n alignment o f the r e a l a x i s w i l l appear and can be c o r r e c t e d , and as the s e p a r a t i o n o f the rows on the f i l m i s a f u n c t i o n o f the i d e n t i t y p e r i o d o f the l a t t i c e t h i s repeat d i s t a n c e can be determined. . A plane o f r e f l e c t i o n s (e.g. hkO) c o n t a i n s i n f o r m a t i o n about the axes a* and b* but i n a compressed unseparable form and as p r e v i o u s l y s t a t e d appears as a row on the f i l m . I f , however, t h i s or any s i m i l a r row i s i s o l a t e d (using a screen) and the f i l m i s moved while the c r y s t a l i s r o t a t i n g the a* and b* axes w i l l i n t e r s e c t the sphere of r e f l e c t i o n a t d i f f e r e n t times and should appear on the f i l m i n d i f f e r e n t p l a c e s . T h i s i s the b a s i s o f the Weissenberg technique and i t provi d e s the necessary a d d i t i o n a l u n i t c e l l i n f o r m a t i o n ; 1 0 e.g. as the d i s t a n c e t r a v e l l e d by the f i l m i s l i n e a r l y r e l a t e d to the angle r o t a t e d by the c r y s t a l {1mm = 2°), by a measurement of the d i s t a n c e apart of the axes a* and b* on the f i l m the a n g l e d * can be determined. The disadvantage of the Heissenberg method i s t h a t i t produces a d i s t o r t e d view of the r e c i p r o c a l l a t t i c e . The Buerger p r e c e s s i o n camera overcomes t h i s by a complex machining which d u p l i c a t e s the motion of one r e c i p r o c a l l a t t i c e plane (again i s o l a t e d , by the placement of a screen and the f i l m ) by the motion of the f i l m , producing an u n d i s t o r t e d view of the r e c i p r o c a l l a t t i c e . Obviously t h i s produces s i m i l a r *geometric* i n f o r m a t i o n , though the e x t e n t of r e c i p r o c a l space a v a i l a b l e i s l e s s than t h a t of the Weissenberg camera. The Heissenberg and p r e c e s s i o n photographs a l s o p r ovide symmetry i n f o r m a t i o n i n the form o f 'systematic absences* which o f t e n allows f o r the d e t e r m i n a t i o n of the c r y s t a l l o g r a p h i c space group. The 230 space groups a r i s e from the d i s t i n c t combinations of the p o s s i b l e symmetry elements i . e . , r o t a t i o n axes ( e.g. a two f o l d r o t a t i o n designated by the symbol 2), mirror planes (m) , r o t a t i o n - i n v e r s i o n axes (e. g. 2), screw axes (e.g. 2j, a r o t a t i o n plus t r a n s l a t i o n ) , and g l i d e p l a n e s (e.g. a, a m i r r o r p l u s t r a n s l a t i o n ) with the 14 B r a v a i s l a t t i c e s . The presence of screw axes, g l i d e planes, and centered l a t t i c e s l e a d to s y s t e m a t i c absences, i . e . r e f l e c t i o n s t h at are s y s t e m a t i c a l l y missing on the f i l m . The combination o f s y s t e m a t i c absences and symmetry on the photograph p r o v i d e the i n f o r m a t i o n from which the space 11 group can be determined.. Sometimes i t i s not possible to uniquely define the space group from the photographs e.g. P2, and P2, /m have the same systematic absences i . e . on the 3k0 row every odd numbered k r e f l e c t i o n i s missing. This absence i s related to the presence of the two screw axis (2,) i n the group. The addi t i o n a l symmetry element m in P2,/m produces no absences and hence the two groups are in d i s t i n g u i s h a b l e . Fortunately t h i s causes few problems in the f i n a l structure determination process. Another important piece of information i s Z the number of molecules per unit c e l l , which i s usually found by measuring the density of the c r y s t a l s by f l o t a t i o n methods. Using the density, the t o t a l molecular weight of the c e l l contents can be calculated and then compared with the molecular weight of the compound. This comparison should produce close to an integer r a t i o , even i f the molecular weight i s only known approximately, which corresponds to the number of molecules in the c e l l . Each space group has a c h a r a c t e r i s t i c number of asymmetric units which generally contain one molecule, so that Z may assist i n determining or confirming the space group. Unfortunately, asymmetric units can contain more (Chapter 3) or less than one molecule. In practice i f the space group i s s t i l l i n question, the usual approach i s to attempt the solution i n each of the possible space groups and see which one succeeds. The f i l m techniques have produced the following data about the c r y s t a l : the three a x i a l lengths a, b, and c 1 2 (reciprocal dimensions can be easily transformed into r e a l l a t t i c e dimensions by the use of standard equations), the three angles and "6 , and the probable space group. With a l l t h i s information i t i s now possible to proceed with the second stage which involves measuring the intensity of every independent r e f l e c t i o n . From the l a t t i c e parameters and the space group a computer can e a s i l y calculate settings f o r the c r y s t a l and detector, with respect to the incident beam, such that the i n t e n s i t y of a l l the desired r e f l e c t i o n s can be measured. The c r y s t a l i s transfered to the diffTactometer and accurately aligned using the intensity of a x i a l r e f l e c t i o n s . Then the maximum position of several prominent r e f l e c t i o n s (chosen from the previously taken photographs) i s c a r e f u l l y determined so that the c e l l dimensions can be more accurately refined. A new set of values for the r e l a t i v e positions of c r y s t a l and detector can then be determined. To measure the int e n s i t y of each r e f l e c t i o n the detector i s i n i t i a l l y positioned to one side of the maximum so that the background can be measured. The detector then scans through the r e f l e c t i o n peak, recording the in t e n s i t y , and f i n a l l y measures the background on the other side. Usually from the int e n s i t y data based on a l l the measured r e f l e c t i o n s i t i s possible to determine the structure of the c r y s t a l . A b r i e f summary of these p r a c t i c a l procedures i s i l l u s t r a t e d i n the flow diagram Figure 2. 1 3 A) Geometry of d i f f r a c t i o n measurements Choose c r y s t a l , attach to f i b r e on goniometer head I C r y s t a l mounted i Take o s c i l l a t i o n photographs , I C r y s t a l c o r r e c t l y aligned a x i a l repeat distance determined I Take Seissenberg and precession photographs Unit c e l l constants and space group determined B) Intensity of d i f f r a c t i o n data Mount on diffractometer, more accurately determine c e l l constants, measure i n t e n s i t i e s of a l l necessary r e f l e c t i o n s I Structure factor amplitudes |Fobs| determined Figure 2 Flow chart i l l u s t r a t i n g the important steps in the p r a c t i c a l aspects of X-ray crystallography 1 4 B) A THEORETICAL VIEWPOINT An atom (n) with f r a c t i o n a l co-ordinates x , y , z referred to uni t c e l l axes a, b, and c w i l l scatter X- radiation with an amplitude f n , and a phase constant, r e l a t i v e to the o r i g i n , dependent on i t s position i n the c e l l , The atomic scattering factor varies with the type of atom and i t s value i s dependent upon s i n 8 / X for the r e f l e c t i o n being considered (values can be obtained from t a b l e s ) . Further corrections are made for the thermal motion of the atom (f i s tabulated for stationary atoms) as mentioned i n the general introduction. I f there i s more than one atom then the resultant from a combination of these d i f f r a c t e d waves i s c a l l e d the structure factor and can be expressed for a general plane (h,k,t) as F(hkl) = ^ f-exp[ 2lti (hx-• ky. + I z- ) 3 where the summation i s over a l l atoms i n the unit c e l l . An equivalent expression i s n F (hkft) = [cos2U(hx j* ky.. + Azp • i s in2ir (hx, * ky^* ^2^)3 i . e . F(hkl) can be represented as a complex number F(hkt) = A + iB or F (hk|) = 1F K % t t 1 (cos ci + i s i n * ) hence the complex resultant i s characterised by an amplitude jF| and a phase constant V given by If I = J A 2 + £ 2 and ^ = tan- 1 B/A. The measured in t e n s i t y I v w t unfortunately only t e l l s us about | F V < U | and not about « since generally 1 5 This l a c k of knowledge about phases i s c a l l e d *the phase problem* and i t s a f f e c t only becomes apparent when i t i s r e a l i z e d t h a t i f the s t r u c t u r e f a c t o r s a r e F o u r i e r transforms of the p e r i o d i c e l e c t r o n d e n s i t y of the c r y s t a l l a t t i c e then the e l e c t r o n d e n s i t y must be the F o u r i e r transform o f the s t r u c t u r e f a c t o r s . The gen e r a l e x p r e s s i o n i s £ ( x y z ) = i £ £ £ F ( h k $ ) exp [-2*1 (hx + ky_ + Az) J y Vv * t hence once the s t r u c t u r e f a c t o r s F ( h k l ) are known the above s e r i e s can be summed to gi v e a r e p r e s e n t a t i o n of the e n t i r e c r y s t a l s t r u c t u r e . Three major methods are p r e s e n t l y used t o overcome the f a c t t h a t 1 ^ g i v e s i n f o r m a t i o n on J F V W I | and not and they are di s c u s s e d i n the f o l l o w i n g c h a p t e r s ; P a t t e r s o n heavy atom methods are d i s c u s s e d i n Chapter 2, centrosymmetric d i r e c t methods i n Chapter 5, and noncentrosymmetric d i r e c t methods i n Chapter 6. 1 6 CHAPTER 2 CRYSTAL AND MOLECULAR STRUCTURE OF [ 2,3-BIS(DIMETHYL ARSINQ) — 1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE- AS,AS]TRICARBO»YLDIIODOTONGSTEN (II) 1 7 INTRODUCTION Preliminary n. m. r. data on [ 2,3-bis(dimethylarsino)- I r l t l * 4, 4,4-hexaf luorobut-2-ene- As,As ")tricarbonyldiiodo- tungsten(II) seemed consistent with stereochemical nonrigidity (9), the existence of which has also been observed for seven-coordinate tantalum (10)., The X-ray c r y s t a l structure of HejAsC (CFS ) :C ( C F 3 ) AsMe^HIa, ( C 0W w a s undertaken to provide information, which could indicate the geometry of the most probable t r a n s i t i o n state, f o r the exchange processes occuring in solution.. EXPERIMENTAL [ 2 ,3-bis (diraethylarsino)- 1, 1, 1, 4, 4, 4-hexaf luorobut- 2- ene-As, As ]tricarbonyldiiodotungsten (II) was prepared by the dropwise addition of iodine to MexAsC (CF 3) :C (CF3) AsMe^W (CO)H. , in CH^Cl^, with vigorous s t i r r i n g under a N a atmosphere. flecrystallization from methylene chloride/faexane gave yellow plates. The c r y s t a l chosen for study was mounted with b p a r a l l e l to the goniostat axis and was ca. 0.2 mm i n length with a cross section of 0.2 x 0.0 4 mm. U n i t - c e l l and space group data were obtained from f i l m and d i f fT a c t o m e t e r measurements. U n i t - c e l l parameters were refined by a l e a s t - squares treatment of s i n 2 6 values for 24 r e f l e c t i o n s measured on a diffTactometer with MoK«t radiation. C r y s t a l Data. C M H »a A s 1 F f c I z 0 3 w, M = 893.40 o Monoclinic, a = 15.37(2), b = 9.529(1], c = 15. 967 (3) A, £ = 112.03(2)°, 0 = 2168(2) A 3 , Dm= 2.737 (3) gem-3 , Z = 4, 1 8 &c = 2.735 (4) gcra-3, F(QOO) = 1608 (20°C, HoK*, >\ = 0.71069 o A, /x = 118 cm - 1). Absent r e f l e c t i o n s : hOl, l#2n and OkO , k#2n define uniquely the space group P2^/c ( C | , No. 14). In t e n s i t i e s were measured on a Datex-automated General E l e c t r i c XRD 6 diffTactometer, with a s c i n t i l l a t i o n counter, Ho K<* (zirconium f i l t e r and pulse height analyser) , and a 9- 2B scan at 2° min-* over a range of (1.80 * 0. 86 tan 0) degrees i n 26, with 20 s background counts being measured at each end of the scan. Data were measured to 2€ = 45° (minimum e interplanar spacing 0.93 ft). A check r e f l e c t i o n was monitored every 50 r e f l e c t i o n s throughout the data c o l l e c t i o n . The greatest deviation from the i n i t i a l value was +10.1% and the f i n a l i n t e n s i t y was 1.007 times the i n i t i a l value. Lorentz and po l a r i z a t i o n corrections were applied, and the structure amplitudes were derived. Of the 2778 independent r e f l e c t i o n s measured, 942 had i n t e n s i t i e s less than 3<r(l) above background where <r2 (I) = S + B * . (0.05S) 2 with S = scan count and B = time averaged background count. These r e f l e c t i o n s were c l a s s i f i e d as unobserved and given zero weight i n the refinement. Structure analysis As previously stated in Chapter 1 the electron density at a point <x,y,z) can be represented by a three dimensional Fourier s e r i e s with the structure factors a s c o e f f i c i e n t s C&,.2,z) = i ! S £ F(h,k,<)exp[-2Tti(hx * ky + *z) ]. K U t F ^ t contains both an amplitude JF^ W 4 | and a phase * ^ t but the i n t e n s i t y information only gives data on the 1 9 ! F ^ w t | ' s , hence the phase information i s unknown. Patterson (11) solved t h i s problem by use of a Fourier series with the phaseless quantities I I ^ v . * ' 2 a s c o e f f i c i e n t s i . e . f(x,!,z) =1 JF k J 2 c o s 2 n ( h x + ky. + I z). y v u. <. This summation produced a map which contained peaks at positions corresponding to the interatomic vectors i . e . f o r co-ordinates u ,v ,w on the Patterson aap there ex i s t atoms x " , 2 ^ 2 , and xx,2.x,z% such that u = x,-x t v = y_, -y_1 and w = z 4-z a where Xj_,y. t,z a may be a symmetry related position of At f i r s t glance the Patterson synthesis appears to provide a simple solution to the phase problem. However, i f there are N atoms i n the c e l l , there w i l l be N{N-1)/2 d i s t i n c t Patterson vectors contained in a c e l l of the same s i z e . This leads to a great deal of overlap and makes interpretation v i r t u a l l y impossible e s p e c i a l l y f o r structures involving many atoms of the same weight because i n addition the height of the vector peak i s proportional to the product of the atomic numbers of the atoms to which i t corresponds. A consequence of this i s that vectors between r e l a t i v e l y •heavy* atoms w i l l appear larger than vectors between the l i g h t e r atoms, and here l i e s the key to the solution of the phase problem f o r certa i n molecules. I f a molecule contains a few *heavy' atoms the Patterson function w i l l give information on t h i s part of the molecule. 20 I f the heavy atom(s) comprise the larger share of the structure f a c t o r , a f i r s t approximation to the phases may be obtained i . e . a n a l y t i c a l l y Efc„ = ̂ f M . ^ i e x p [ 2 « i ( h x H . * ki H.+ <z M.)] + t £ u « T i exp[ 2 * i (hxL. • k I u. * i z u. ) ] i f £«,»£ui then I ^ A exp[2TTi (hx W i+ JSI H i + I z„- ) ]. I f t h i s f i r s t approximation i s used in the Fouriar summation the difference map produced may provide the positions of another part of the molecule. These positions of new atoms can be added to the old ones and used to improve the phases. The process i s then repeated and i t i s hoped that t h i s i t e r a t i v e procedure w i l l r e s u l t i n the determination of the complete structure. This process of finding successive pieces of the structure i s e s s e n t i a l l y the basis for a l l structure determinations including the direct methods described i n Chapters .5 and 6. For t h i s compound and the two ruthenium compounds (discussed i n Chapters 3 and 4) the largest peaks on the Patterson ' syntheses would be expected to be between the singl e heavy atoms and t h e i r symmetry related positions i n a l l three cases. Once the tungsten and ruthenium positions were determined the i t e r a t i v e procedure was used to f i n d the rest of the molecules. Even the process of finding the heavy atoms i s somewhat si m p l i f i e d by the phenomenon f i r s t pointed out by Harker ( 1 2 ) . He showed that useful information i s contained i n certain planes and l i n e s i n the Patterson map which give r i s e 2 1 to vectors with one or two constant co-ordinates due to the presence of symmetry (other than centres) in the c r y s t a l . For example the tungsten compound's space group was P2t/c which has four molecules in the unit c e l l . Due to the symmetry elements of the group any atom that occurs at the general position x,y,z (I) w i l l also occur at the symmetry related positions x,y,z (II); x, 1/2+y_, 1/2-z (III); and x,1/2- y,1/2+z (IV), The Patterson function contains peaks which correspond to the vectors between these symmetry related positions. e.g. the vector between p o s i t i o n (I) and (III) i s either (x # 1/2-y, 1/2+z) " <**Y.»z) = (0,1/2-2y,1/2) or (£,I#z) " (S,1/2-y,1/2 + z) = (0,-1/2+2y,-1/2) as 1/2 i s eguivalent to -1/2 the two vectors become 0, 1/2-2y, 1/2 and 0, 1/2*-2y_, 1/2 i . e . 0,1/2 ± 2y,1/2 {note that these two vectors were rel a t e d by a centre of symmetry hence a l l Patterson functions must be centrosymmetric). Table 1 gives the general vectors between a l l the four symmetry related positions (I), (II), ( I I I ) , and (IV) in i t s f i r s t column. A search of the Patterson map was then undertaken to see i f any of the peaks corresponded to these vectors which would be expected to be between the symmetry rel a t e d tungsten atoms. The second column of t h i s table indicates the respective peaks found on the map. Column three gives the possible values for the co-ordinates x,y_,z of the tungsten atcm. The map was also examined for the presence of W-I vectors and I-I vectors and from an o v e r a l l 22 Table 1 Vectors between the symmetry related positions f o r the Space Group P2, /c and the possible solutions to the Patterson function for the tungsten compound 'General vectors for i Space Group P2l(/c Peak on Patterson ] Possible solution] function ' ' ' 0, 1/2t2y, 1/2 #2* ; 1/2t2y =0.28 | 0.00, 0.28, 0.50 J 2y = 0.22 or 0.78! ! ±2x, 1/2, 1/2±2z ; | 4. 2x = 0. 35 I #3 l 2x = 0.35 or 0.65 0.35, 0.50, 0.27 ! 1/2i2z=,0.27 ! 2z = 0.23 or 0. 77 • i.2x, ±2y, i-2z i #16 J 2x = 0.65 or 0. 35 0.65, 0.22, 0. 23 J,2y = 0.23 or 0.78 I 2z = 0.23 or 0.77 Peaks were ordered by s i z e , i . e . #2 was the second highest 23 examination i t was deduced that 2x = 1.35, 2y. = 0.78, and 2z = 0.77 or x = 0.68, 2 = 0.39, and z = 0.38 would be the values for the co-ordinates of the tungsten atom. One cycle of f u l l - m a t r i x least-squares refinement varying the i s o t r o p i c thermal parameters and position of the tungsten atom produced an B factor of 0.54. A difference Fourier revealed the positions of the two iodine and the two arsenic atoms and a further two cycles varying the p o s i t i o n a l and anisotropic thermal parameters reduced R to 0.20. A difference map at t h i s stage revealed the positions of the remaining 20 atoms, but two further cycles with anisotropic thermal parameters for the f i v e * heavy* atoms and i s o t r o p i c thermal parameters for the remaining atoms reduced B to only 0.16. Due to the high value of JLK (118cm-3) and the size of the c r y s t a l i t was believed that such a high discrepency at t h i s stage was probably due to neglecting the effects of absorption when c a l c u l a t i n g the structure amplitudes. An absorption correction using the computer program BICABS was therefore attempted (13). The faces of the c r y s t a l were c a r e f u l l y indexed and the dimensions measured. The values used i n the correction are given in Table 2. Two cycles of refinement with the same atom parameters used i n the l a s t cycles, but the new structure amplitudes corrected f o r absorption, produced an H factor of 0.076. Convergence was f i n a l l y reached a f t e r two more c y c l e s , using an anomalous dispersion correction and anisotropic thermal parameters for the W, I, and As atoms, and i s o t r o p i c Table 2 C r y s t a l dimensions and indices of the faces used i n absorption correction ' - ! k • 1 Distance to Centroid (cm.) ' • o ! 1 0 0 . 0 2 2 8 I i -4 j -12 11 0 . 0 1 9 7 ! i - i 0 0 0 . 0 0 4 5 | • -1 • 0 0 0 .0045 i • _-j • 0 1 0 . 0 2 0 7 J ! i - i 0 -1 0 .0207 2 5 thermal parameters for the remaining atoms, at 8 = 0.067 for the 1823 observed r e f l e c t i o n s . {The thirteen highest i n t e n s i t y r e f l e c t i o n s 102, 106, 204, 202, 204, 306, 504, 502, 604, 114, 514, 025, and 225 were not included i n the B f a c t o r c a l c u l a t i o n due to probable instrumental error.) The scattering factors were taken from ref. 14 and anomalous scattering corrections from r e f . 15. The weighting scheme: /]T= 1 i f - 7 ^« 3 ; Jw~= 74.3/JFoJ i f |Fo| > 74.3 and yj w = 0.0 for unobserved r e f l e c t i o n s gave constant average values of W(Fo-Fc) 2 over ranges of |Fo| and was employed i n the f i n a l stages of refinement. The two CF groups on the chelate ring had high i s o t r o p i c temperature factors; however an Fo electron density map calculated using the phases from a l l the other found atoms did not reveal any evidence of disorder i n the groups or i n d i v i d u a l atoms. The f i n a l p o s i t i o n a l and thermal parameters are given i n Tables 3 and 4 respectively. Measured and calculated structure f a c t o r s are available from the U.B.C. Library. 26 RESULTS AND DISCUSSION CO X^Mv\CO A-A 1 2 M = W M = M o X = I X = Br Y = As Y = P R. == CH3 R = CftHs A—A = r=C A—A = CH2—CH2 CFj CF3 Figure 3 Schematic diagram cf compounds (1) and (2) from text The seven-coordinate geometry about the tungsteD atcm i n (1), [2,3-bis(dimethylarsinc)-1,1,1,4,a ,4-hexafluorobut-2- ene-Aj,AsJtricarbonyldiiodotungsten(II) i s s i m i l a r to that found for (2) dibrcmctricarbcnyl[1,2-bis (diphenylphosphino) ethanejmclybdenum(II)-1-acetone (16) (Figure 3), t h i s type of geometry being described as a considerably d i s t o r t e d capped octahedron. In t h i s mclecule the capping group i s cne cf the carbonyls [C(3)-0(3) ], the three a t o i s defining the capped face are C(1), C (2) and As(1), while the uncapped face consists of the two iodine atoms 1(1) and 1(2) and the regaining arsenic atcm As (2). Figure 4 shows a projection down the W-C(3) bond. Although i t would also be possible to describe the tungsten environment in terms of various distorted capped t r i g c n a l prisms (17), a d e t a i l e d a n a l y s i s of C(4) 1(1)/ 1.17(A)J '0(1) ^ V - 2 9 ( 4 ) 1.98(3)/ [ N ^ C © As(1) 2.556(3) J>.> 2.856(2) 2.00(3) |As(2) VC(2) J.19C4) Figure 4 Projection of the coordination sphere of the molecule viewed dcwc the vector from the cartonyl grcup i n the capping p o s i t i o n (ctritted from the diagrair) to the tungsten atcm. Table 3 F i n a l p o s i t i o n a l parameters ( f r a c t i o n a l X 10 4) with standard deviations i n parentheses atom X 2 z w 6733 (1) 39 32 (1) 3840(1) I{1) 8344(1} 3338 (2) 3427 (1) 1(2) 5627 (1) 2858 (3) 2094(1) As (1) 805 3(2) 4102 (3) 5 396(2) As (2) 6956(2) 1347 (3) 4439(2) F (1) 9743 (20) 3296 (32) 7073( 19) F(2) 10241 (19) 2691 (29) 6121 (18) F{3) 9903 (23) 1333 (36) 7008(23) F(4) 7815(25) -1202 (36) 5435(22) F(5) 9209 (26) -663 (39) 5574(24) F{6) 8701 (23) -530 (37) 6578(24) 0(1) 6742(20) 6410 (31) 2526(19) 0(2) 4737(21) 3648 (31) 3926(19) 0(3) 6362(17) 65 56 (26) 4800(16) C(1) 6688 (24) 5473 (39) 297 8(23) C (2) 5494 (22) 3788 (33) 3893 (20) C (3) 6485(25) 5613 (40) 4431 (24) C (4) 8686(18) 2270 (28) 5757 (17) C(5) 8218 (19) 1142 (30) 5422(18) C (6) 9677(23) 2355 (36) 6418(21) C(7) 8525(40) -394 (58) 5735(36) C(8) 8997(22) 5506 (34) 5546(21) C{9) 7715 (23) 4521 (37) 6430(21} C(10) 6 981 (25) -73 (40) 3550(24} C<11) 6092 (24) 535 (38) 4927(22) 29 Table 4 F i n a l thermal parameters and t h e i r estimated standard deviations 0 a) Anisotropic thermal parameters (U-- (A2) X 102) atom U u D t x 0 „ UiX 0^ J J a a w 4.18( 6} 6.27( 7) 4. 15 ( 6) 0.16< 5) 1.49 ( 4) 0.17( 5) 1(1) 5.68(11) 9.35(15) 6. 56 (1 2)-1 . 14 (10) 3.27 ( 9)-1.43(10) 1 (2) 6.39(12) 14. 10(22) 5. 15 (11) -0. 22 (13) 0 .57 ( 9) - 1. 10 (12 ) As(1) 5. 12 (14) 4.59 (15) 4. 62 (1 4)-0. 18 ( 12) 1. 50 (11)-0. 11 (1 1) As(2) 6.37(17) 5.87(18) 5. 61 (1 6)-1. 83 (14) 2 . 21 (1 3)-0.7 4 (1 3) lb) Isotropic thermal parameters (U x 10 3) Atom U (A 2) Atom U(A 2) F(1) 11.7 (7) C(2) 5.8 (6) F(2) 11.0 (7) C{3) 7.0 (8) F(3) 13.6 (9) C(4) 4.5(5) F(4) 13.5 (9) C(5) 4.9(6) F(5) 15 (1) C{6) 5.9(7) F(6) 13.6 (9) C (7) 11 (1) 0(1) 9.3 (7) C(8) 6.1 (7) 0(2) 9.5(7) C(9) 6.5(7) 0(3) 7.4(5) C(10) 7.4 (8) C(1) 6.9 (8) C(11) 6.9(7) 30 differences between the basic polyhedra available for seven- coordinate molecules (18), indicates that i n t h i s type of molecule the i d e a l angle between the two larger coordinated atoms i s 180° for a pentagonal bipyramid, ca. 90° for a capped octahedron, and 81.5° for a capped t r i g o n a l prism. From the I-B-I angle of 87.3° the choice of the capped octahedron would appear to describe the observed geometry most exactly. Figure 5 shows a general stereoscopic view of the molecule, with the atom l a b e l l i n g scheme. Individual bond lengths and angles, with standard deviations are given i n Tables 5 and 6 respectively. The angles subtended at the tungsten atom between the unique carbon atom C(3) and the atoms i n the capped face, and those between C(3) and the atoms in the uncapped face, average to 74 and 128° respectively. These angles are very si m i l a r to those found i n other capped octahedral structures, i . e . 73.6 and 125.5° in (2), and 73 and 128° for [ b i s - (diphenylarsino) methane Jdibromodicarbonylmolybdenum (II) (19) . S i m i l a r l y the angles subtended at the central metal atom by pairs of atoms i n the capped, and pairs in the uncapped faces for both molecules (1) and (2) are comparable. In (1) they are an average of 112 and 86° respectively, while i n (2) the mean values are 112.3 and 89.7°. another feature of a distorted capped octahedron (17) demonstrated by t h i s molecule, i s the close non-bonded contacts made between the capping group and the three atoms i n the capped face. Hence in (1), C{3) i s 2.46, 2.26, and o 2.73 A away from C (1) , C (2) , and A s p ) , compared to 2.29, Figure 5 general stereoscopic view of the molecule show the c r y s t a l l o g r a p h i c numbering scheme. - fable 5 © Bond lengths (A) with standard deviations i n parentheses © o Bond Length (A) Bond Length (A) W-I(1) 2.848 (2) W-I(2) 2.856 (2) W-As(1) 2.556 (3) W-As (2) 2.618 (3) W-C(1) 2.00 (4) H-C(2) 1.97 (4) S-C (3) 1.94 (3) As(1)-C(4) 1.98{3) As (1) -C(8) 1.92 (3) As(1)-C(9) 1.95 (3) As (2) -C (5) 2.00 (3) As (2) -C(10) 1.97 (4) As (2) -C(11) 1-93(3) C(1) -0(1) 1. 17(4) C(2) -0(2) 1. 19(4) C (3) -0(3) 1. 13(4) C(4) -C(5) 1. 29(4) C (4) -C (6) 1. 50 (4) C (5) -C (7) 1. 56 (6) C (6) -F{1) 1. 35(4) C (6) -F(2) 1. 31 (4) C (6) -F{3) 1. 18(4) C(7) -F{4) 1. 27(5) C (7) -F(5) 1. 20 (5) C(7) -F(6) 1. 28(5) 33 Table 6 Bond a n g l e s (deg.) with s t a n d a r d d e v i a t i o n s i n parentheses. Bonds Angle Bonds Angle I(1)-W-I(2) 87.3 (D W-As(2)-C (5) 110| 1) I (1)-W-As (1) 78.2 (1) W-As(2)-C (10) 115 j 1) I (1) -W-As (2) 83.8 [1) W-As(2) -C (11) 120| 1) I(1)-W-C(1) 78 (1) C (5)-As (2)-C (10) 103( 1) I (1)-W-C (2) 161 (1) C (5)-As (2) -C (11) 105i 1) I(1)-W-C(3) 128 (1) C (10) -As(2) -C (11) 10 3 [ 1) I (2)-W-As (1) 159.4 (D As(1)-C(4)-C(5) 119 (2) I (2) -W-As (2) 88.2 (1) As (1) -C (4) -C (6) 115| [2) I (2)-W-C(1) 75 (1) C (5)-C(4)-C (6) 127 | 3) I (2) -W-C (2) 77 <1) As (2) -C (5) -C (4) 118| [2) I (2) -W-C (3) 128{1) As (2) -C(5)-C(7) 116| [3) As(1) -W-As(2) 75.9 (1) C (4)-C(5)-C (7) 126 (3) As(1)-W-C(1) 116 (1) W-C (1) -0(1) 174| 3) As(1) -W-C (2) 113 (1) W-C (2)-0(2) 178 ( 3) As (1) -W-C (3) 73 (1) W-C (3) -0(3) 177 3) As (2) -W-C{1) 155 (1) C (4)-C(6)-F(1) 1 10 ;3) As (2) — W-C {2) 85 (1) C (4)-C (6)-.P(2) 1 16 (3) As (2) -W-C (3) 128 (1) C (4)-C(6) -F(3) 1 13 3) C(1)-W-C(2) 108 (1) F (1)-C(6)-F(2) 106 3) C(1)-W-C(3) 77 (1; F (1)-C{6) -F{3) 91 3) C{2) -W-C (3) 71 (1) F (2)-C (6)-F(3) 1 17 [3) W-As (1)-C (4) 111(1] C (5)-C(7)-F(4) 109 W-As (1)-C (8) 117 (1) C (5)-C(7) -F(5) 108 ;5) W-As(1)-C(9) 118(1; C (5)-C (7)-F(6) 111 4) C (4)-As(1)-C (8) 108 (1 F (4)-C(7) -F{5) 1 19 ;5) C(4)-As(1)-C(9) 101 (1| F (4)-C (7) -F (6) 99 [5) C (8)-As(1)-C(9) 100 (1) F (5)-C (7)-F(6) 1 10 (5) 34 2.29, and 2.70 A for the respective C{1) to C (2) , C (3) , and P(1) distances in molecule (2). The angle subtended at the central tungsten atom by the bidentate ligand i s 75.9(1)°. This i s s i m i l a r to those subtended by the mutually c i s atoms of the capped and uncapped faces (the mean value of the six such angles being 78°). The ligand therefore seems i d e a l l y suited to occupy an edge of the capped octahedron. The three angles mutually tj:aa§ are also very s i m i l a r being 155, 159, and 161°, giving the geometry around the tungsten (see Figure 4) a reasonable C j v symmetry. © The tungsten-iodine distances of 2.848 (2) and 2,856 (2} A would appear to be the f i r s t determinations of W-I bond lengths in a seven-coordinate environment. Tungsten-bromine distances i n s i m i l a r environments (20 and 21) have already been found to have a mean value of 2.65 A. Using a bromine o covalent 1 radius of 1.14 A (22) we can estimate a W single o e bond radius of 1.51 A for t h i s compound. With use of 1.33 A (22) for the iodine covalent radius, a predicted H-I bond c length would be 2.84 A, in reasonable agreement with the o value found (mean value 2.852 (2) A). Assuming the r a d i i of o Mo(II) and H(II) are s i m i l a r the value of 2.862 A found f o r the Mo-I distance i n Mo(CNfi)bI*- (23) i s also very close to these measured and predicted values., A s i m i l a r argument e predicts a W-As bond length of 2.73 A, compared to the o 2.556 (3) and 2.618(3) A found experimentally. This s i g n i f i c a n t shortening i s thought to be due to some double bond character in the K-As bonds caused by (dir-dir) back 35 donation from the central metal atom. The two W-As bonds are also s i g n i f i c a n t l y d i f f e r e n t from each other, which can be explained by consideration of the respective trans ligands. A t £ M § ligand can a f f e c t the extent of back donation from the metal, hence the 1(2) atom trans to As(1), i s not as strong a dir accepting group as the C(1)-0{1) group trans to As(2) which should r e s u l t i n a greater back donation to As(1). This w i l l cause a shortening of the H-As(1) bond with respect to © the W-As{2) bond, the difference found being 0.062 A. The H-C and C-0 distances (mean values 1.97(4) and © 1.16(4) A) and the W-C-0 angles (mean value 176(3)°) are s i m i l a r to those found i n ether compounds with carbonyls joined to tungsten (24). The f i v e membered ring i s i n a 'puckered' conformation. Table 7 gives the eguation of a weighted least-squares mean plane, with deviations of the atoms from the plane, and values for the dihedral angles i n the r i n g . This type of •puckered* conformation, with both carbon atoms on the same side of the weighted least-squares mean plane f o r tha f i v e membered ri n g , has been found i n other compounds (25). The bend in the ri n g i s probably to increase contacts between the methyl groups on the arsenic atoms and the adjacent carbonyl groups rather than the methyl-iodine contacts (26) . Neither the carbon-carbon double bond length of 1.29(4) A (expected 1.34 A } (27) , nor the H-As-C bond angle mean value of 110.5° (expected tetrahedral value of 109.5°) and the As-C-C bond angles, mean value of 118.5° (expected f o r s p 2 hybridized carbons of 120.0°) are s i g n i f i c a n t l y d i f f e r e n t 36 Table 7 a) Equation of weighted least-squares mean plane* for the f i v e membered ring atom A (A) A/<r B 0.0015 1.404 As{2) -0.0105 3.822 As(2) -0.0127 3.970 C(4) 0.7055 24.447 C(5) 0.6139 20.574 * plane: 0.894X - 0.151Y - 0.421Z = 4.240, where X,Y, and 2 are orthogonal angstrom coordinates derived as follows i-Xn r a 0 ccos P n rx-, I I I = I 0 b 0 i H I *-Z-« «- o 0 csin p -» «-z-« b) Dihedral angles i n the f i v e membered ring Atom 1 Atom 2 Atom 3 Atom 4 Angle (deg.) As (2) H As{1) C(4) 23(1) As (1) SJ As (2) C (5) -20 (1) W &s(1) C(4) C(5) -26(2) W As (2) C (5) C (4) 12 (2) As(1) C(4) C{5) As (2) 8 (2) Figure 6 & p r o j e c t i o n of the structure down the h a x i s . 38 £rom t h e i r stated expected values. Both the As (1)-C(4) and o As(2)-C(5) bond distances of 1.98(3) and 2.00(3) A are s i m i l a r to the AS-CH3 bond lengths (mean, 1.98(3) A) as i s found i n other si m i l a r ligands (28). From the r e l a t i v e uncertainty of the positions of the two CF 3 groups, i t seems unreasonable to attempt any meaningful discussion of their bond lengths and angles. The intermolecular packing appears to be governed s o l e l y by van der Kaals interactions. A projection of the structure down the b axis i s shown i n Figure 6. The n.m.r. data for t h i s compound (9) indicated that molecular rearrangement must be occuring in solution. The c r y s t a l structure would suggest that the process involves rapid scrambling of the carbonyl groups and the iodine atoms, and simultaneous migration of the capping group over the faces of the [AstCxI^] octahedron; The sharpness of the spectra at -70°C indicates that the l i m i t i n g spectrum corresponding to the s o l i d state structure would be reached only at a much lower temperature. CHAPTER 3 CRYSTAL AND MOLECULAR STRUCTURE OF DIMETHYLAMMONIUM TRICHLOROTRIS (DIMETHYLSULPHOXIDE) RUTHENATE (II) . 40 INTRODUCTION From the r e s u l t s of the i n f r a r e d and lH n.m.r. s p e c t r a l data on dimethylammonium t r i c h l o r o t r i s - ( d i m e t h y l s u l p h o x i d e ) r u t h e n a t e ( I I ) (29) i f was thought t h a t a l l t h r e e d i m e t h y l s u l p h o x i d e l i g a n d s were S-bonded and t h a t the anion was i n the f a c - c o n f i g u r a t i o n . The X-ray c r y s t a l l o g r a p h i c study was undertaken t o v e r i f y t h i s assignment and determine s t r u c t u r a l parameters which c o u l d be u s e f u l i n e x p l a i n i n g the c a t a l y t i c p r o p e r t i e s of these m a t e r i a l s . , EXPERIMENTAL Ruthenium t r i c h l o r i d e t r i h y d r a t e (1g# 39% Ru) and dim e t h y l s u l p h o x i d e (1ml) were heated a t 80°C i n NN' - dimethylacetamide (20ml) under 1 atm hydrogen f o r 4h. The r e s u l t i n g red s o l u t i o n was set aside at room temperature (or con c e n t r a t e d to 10ml and cooled) and gave a b r i g h t yellow product which was washed with e t h e r , and vacuum d r i e d . R e c r y s t a l l i z a t i o n o f [ ( ( C H 3 ) z SO) a R u C l 3 ] [ (CHjJ^NH^] from dimethylacetamide gave yellow cubes. The c r y s t a l chosen f o r study was mounted with c p a r a l l e l t o the g o n i o s t a t a x i s and was ca. 0.3 mm i n l e n g t h with a c r o s s s e c t i o n of 0.25 x 0 . 2 5 mm. U n i t c e l l and space group data were obtained from f i l m and d i f f T a c t o m e t e r measurements. The u n i t - c e l l parameters were r e f i n e d by a l e a s t - s q u a r e s treatment of sin 2© val u e s f o r 20 r e f l e c t i o n s measured on a d i f f r actometer with MoK«*. 41 r a d i a t i o n . C r y s t a l Data. CgH a bCl<3NO sRuS 3, M = 487.9 Orthorhombic, © o a = 27.459(5), b = 9.925 (1), c = 14. 266 (3) A, 0 = 3887(1) A 3, D m = 1.67(1) gem- 3, 1 = 8 , D c = 1. 667 (5) gcm~ 3 , o F(000) = 1984 (20 °C, HoK<* , X = 0.71069 A, /x = 15.036 cm-* ) . Absent r e f l e c t i o n s : Okl, k+1 * 2n, hkO, h # 2n d e f i n e the space group as e i t h e r Pnma (D** , No. 62) or Pn2, a (C|v , No. ,33) . I n t e n s i t i e s were measured on a Datex-automated General E l e c t r i c XBD 6 diffTactometer, with a s c i n t i l l a t i o n c o u nter, Mo K<* (zirconium f i l t e r and p u l s e height analyser) , and a 8— 29 scan a t 2° min" 1 over a range of (1.80 + 0.86 tan 9) degrees i n 2©, with 10 s background counts being measured a t each end of the scan. Data were measured to 29 = 45° (minimum © i n t e r p l a n a r spacing 0.93 A) . A check r e f l e c t i o n was monitored every 50 r e f l e c t i o n s throughout the data c o l l e c t i o n . The g r e a t e s t d e v i a t i o n from the i n i t i a l v a l u e was +11.1% and the f i n a l i n t e n s i t y was 1.067 times the i n i t i a l v a l u e . L o r e n t z and p o l a r i z a t i o n c o r r e c t i o n s were a p p l i e d , and the s t r u c t u r e amplitudes were d e r i v e d . No a b s o r p t i o n c o r r e c t i o n was a p p l i e d due to the low value of /*., and the f a i r l y uniform shape o f the c r y s t a l . Of the 2637 independent r e f l e c t i o n s measured, 676 had i n t e n s i t i e s l e s s than 3«-(I) above background where «"2 (I) = S * B + (0.05S)2 with S = scan count and B = time averaged background count. These r e f l e c t i o n s were c l a s s i f i e d as unobserved and given z e r o weight i n the refinement. STRUCTURE ANALYSIS In a s i m i l a r manner to that d e s c r i b e d i n the p r e v i o u s chapter a P a t t e r s o n f u n c t i o n was used t o s o l v e the s t r u c t u r e of the compound. However, the i n i t i a l attempt t o s o l v e the s t r u c t u r e i n the space group Pnma r e q u i r e d a maximum a t 0,0.5-2y,0 i n the P a t t e r s o n f u n c t i o n . The th r e e - d i m e n s i o n a l P a t t e r s o n map reve a l e d no such peak other than the o r i g i n . I f t h i s was the case the y c o o r d i n a t e f o r the Ru atom would have to be 0.25, l o c a t i n g the atom on the c r y s t a l l o g r a p h i c m i r r o r plane. Although the anion c o u l d possess m i r r o r symmetry, an attempt was then made to s o l v e the s t r u c t u r e i n the non- c e n t r i c space group, Pn2 la. Since t h i s space group has only four e g u i v a l e n t p o s i t i o n s , there must be two c r y s t a l l o g r a p h i c a l l y non-equivalent molecules i n the asymmetric u n i t . In Pn2,a the heavy atom v e c t o r s on the Pa t t e r s o n map are to be found on the Harker plane 2x, 1/2, 2y. Examination of the map gave the x and z c o o r d i n a t e s o f Ru(1) and Ru(2), but l e f t t h e i r y values u n s p e c i f i e d . In t h i s space group, however, there i s no unique o r i g i n p o i n t along the b a x i s so Ru (2) was a r b i t r a r i l y a ssigned the y c o o r d i n a t e 0.000, which was kept c o n s t a n t throughout the l a t e r r e f i n e m e n t s . One c y c l e o f f u l l - m a t r i x l e a s t - s q u a r e s refinement of the p o s i t i o n a l and i s o t r o p i c thermal parameters f o r these two ruthenium atoms produced an R f a c t o r of 0.45. A d i f f e r e n c e F o u r i e r r e v e a l e d the p o s i t i o n s of the s i x c h l o r i n e and s i x sulphur atoms. Two f u r t h e r c y c l e s f o r these f o u r t e e n atoms s t i l l v a r y i n g the p o s i t i o n a l and i s o t r o p i c thermal parameters gave an R va l u e o f 0.19. The d i f f e r e n c e map a t t h i s stage r e v e a l e d the p o s i t i o n s of the remaining 24 oxygen, n i t r o g e n and carbon atoms. A f t e r s e v e r a l more c y c l e s convergence was f i n a l l y reached, using an anomalous scattering correction for the Ru, C l , and S atoms, and varying the po s i t i o n a l and anisotropic thermal parameters f o r a l l the atoms, at R ~ 0.045 for 1943 observed r e f l e c t i o n s (the following r e f l e c t i o n s were removed from the data set i n the f i n a l stages of refinement due to suspected errors r e s u l t i n g from extinction, absorption, and instrument malfunction: 4 0 0, 2 4 0, 19 0 1, 21 0 1, 2 1 1, 10 0 2, 17 1 2, 14 0 3, 4 0 4, 9 0 4, 12 0 4, 3 0 5, 2 3 5, 8 0 7, 10 6 7, 19 0 8, 0 1 9, and 1 0 14.) Due to the a d d i t i o n a l expense involved i n further refinement for a structure with so many variables, bearing i n mind the reason behind the investigation, and the inherent d i f f i c u l t y with so many heavy atoms present, no attempt was made to determine or r e f i n e the positions of the hydrogen atoms i n the RuCl 3 (MezS0)^ molecules. The positions of the hydrogen atoms bonded d i r e c t l y to the nitrogen atoms in the e cations were calculated (assuming a N-H bond length of 0.99 A and a H-N-H angle of 108°.) to give an idea of the i n t e r i o n i c bonding. These atoms were not included i n the structure refinement. The scattering factors were taken from ref. 14 and anomalous scattering corrections (15) were applied for the Ru, Cl and S atoms. The weighting scheme: /~w = 1 i f |Fo| < 65; /w = 65/1 Foi i f |Fo| > 65 and J~v = 0-0 f o r unobserved r e f l e c t i o n s gave constant average values of w (Fo-Fc) 2 over ranges of |Foj and was used in the f i n a l stages of refinement. The f i n a l p o s i t i o n a l and thermal Table 8 F i n a l p o s i t i o n a l parameters ( f r a c t i o n a l x 10*) with estimated standard deviations i n parentheses Atom X I z Ru(1) 2560 (0) 4849 (2) 3945 ( 1) Ru (2) 283(0) 0 2858 ( 1) Cl (11) 1670(1) 4795(6) 3851 ( 3) Cl(12) 2489(2) 3399(5) 5299 { 3) Cl(13) 2563(2) 2834 (5) 2997 j [3) C l (21) 1094 (2) 10090 (8) 2176 \ ,3) Cl{22) 469 (2) 2095(6) 3640 { A ) Cl (23) 640 (2) 8823 (7) 4181| «0 S(11) 3381 (1) 4766 (6) 3943 < [3) S(12) 2556 (2) 6598 (5) 4961 | [3) S(13) 254 8(2) 6206 (5) 2680 | [3) S(21) 9543 (1) 10104(7) 3 556 | (3) S (22) 16(2) 1123 (6) 1567 (3) S (23) 128 (2) 7954(6) 2231 i [*») 0(111) 3657(5) 5966 (14) 4246 (11) 0 (121) 2672(5) 7981 (14) 4620 (9) 0(131) 3 026 (5) 6846 (13) 2425 (9) 0(211) 9154 (4) 9221(15) 3 198 (10) 0 (221) 948 7 (6) 1271 (18) 1434 (10) 0(231) 9823 (7) 7888 (17) 1401 (11) C(111) 3606(8) 3435 (22) 4669 (18) C(112) 3638 (8) 4336(23) 2772 (15) C(121) 2948(7) 6334 (20) 5956 (12) C (122) 1970(8) 6759(27) 5528 (16) C(131) 2 335(9) 5372 (22) 1655 (13) C(132) 2105(8) 7535(20) 2752 (14) C(211) 9575(7) -125 (37) 4788 (11) C (212) 9299 (6) 1795(26) 3530 (17) C(221) 293 (13) 2769 (24) 15 10 (21) C (222) 233 (9) 491(27) 499 (15) C{231) 9 857 (9) 6784 (28) 3017 (20) C(232) 675(11) 7074 (24) 2026 (26) N ( 1) 3646 (6) 880 9(18) 3556 (13) N(2) 1569 (6) 1629(15) 4378 (12) C(11) 3 297 (8) 9802 (28) 3173 (17) C(12) 3790(10) 9068 (28) 4564 (17) C(21) 1870 (7) 413 (19) 4212 (16) C (22) 1378 (9) 1719(22) 5336 (14) H(11) 3944 8818 3163 H(12) 3500 7900 3513 H(21) 1768 2438 4248 H (22) 1292 1624 3934 Table 9 F i n a l thermal parameters and t h e i r estimated standard deviations anisotropic thermal pa ra me te r s (U ^ x 10 2 o A*} atom Ru(1) 3.28 (8) 2.10(6) 1. 82 (5) -0. 1 1 (8) -0.07(4) 0.04(6) Ru (2) 2.82(8) 3.56(7) 2.81 (6) -0.40 (6) -0.12 (6) 0.37 (9) Cl(11) 3.5(2) 4.1 (3) 4. 2(2) -0.5 (3) -0.2 I (2) 0.5 ( 3) C l (12) 6.5 (3) 3.2 (3) 2.7 (2) -1. 1 (2) -0.9 [2) 1.4( 2) Cl(13) 6.5 (3) 2.7 (2) 3.4(2) 0.1 (2) -1.2 [2) -0.5 { 2) Cl (21) 3.4(2) 7.5 (3) 5.3(2) -0.4(3) 0.9 [2) 0.5( 3) Cl{22) 4.6(3) 4.5 (3) 6.4(3) -0.8 (2) -1.4 (3) - 1.3 ( 3) C l (23) 5.5 (3) 6.9 (4) 4. 9(3) 0.1 (3) -1.3 [3) 2-0 | 3) S(11) 3.2(2) 3.4 (3) 3.7(2) 0.8 (2) 0. 1 (3) -0.9 | 2) S (12) 3.0 (2) 3.2 (2) 1.9(2) -0.2(2) 0.3( [2) -0.0( 2) S(13) 4.3 (3) 2. 1 (2) 1.9(2) 0.1 (2) 0.4 (2) 0. 1 ( 2) S(21) 3.4 (2) 5.1 (3) 3.0(2) -0.4 (3) 0.2 (2) 0.5 | 2) S (22) 4.7(3) 4.5 (3) 3.6(3} 0.3 (2) -0.7 (2) 1.3( 2) S(23) 5.7 (3) 3.8 (3) 5.6(3) -0.4 (2) -1.3 (3) 0.3| 3) 0(111) 2.5(7) 4.4(9) 9(1) -1.0 (6) 0.6 (?) -0.8 i 8) 0 (121) 5.5(8) 3.4 (7) 4.5(7) -0.7(6) 0.3 (6) 0.0j 7) 0(131) 4.8(8) 3.9(8) 4. 1 (7) -1.2 (7) 0.5 (6) 1.0i 6) 0 (211) 2. 1 (7) 7.2 (9) 6. 0(8) -1.6 (7) 0.4 (6) 0.4j 8) 0(221) 7(1) 9 (1) 4. 3 (8) 3 (1) -1.6 (8) 0.0 9) 0 (231) 13(1) 5(1) 5. 8(9) -0(1) -3(1) -0.2i 8) C{111) 4(1) 5(1) 9(2) 2(1) -2(1) 1 (1) C (112) 5(1) 6(1) 6(1) 2(1) -1(1) -3 (1) C (121) 5(1) 4 (1) 3(1) -1(1) -1. 1 (9) -0.3 | [9) C(122) 4(1) 9 (2) 5(1) -3 (1 ) 3(1) "2 (1) C (131) 9(2) 5 (1) 2.5 (9) 2(1) -2(1) - 0.6 | 9} C (132) 6(1) 4(1) 5(1) 1 (1) -0(1) 2 (D C(211) 6 (1) 11(2) 2.7 (9) 1(2) 1.6 (8) 1 (2) C (212) 1.2(9) 9 (2) 9(2) 2(1) 1(1) -4 (1) C (221) 16 (3) 4 (2) 10(2) -3(2) -2(2) 3 (1) C (222) 7(1) 10(2) 3(1) 1 (1) -0(1) 0 (1) C (231) 7 (2) 8 (2) 10 (2) -3(1} -3(2) 5(2) C (232) 9(2) 3(1) 18(3} 0(1) -2 (2) -0 (2) W(1) 5(1) 3.4 (9) 8(1) 1.0(9) 2(1] 0.6 [9) H(2) 3. 9(9) 2.4(9} 6(1) 0.7(7) 0.8 (8) -0.6 [8) C(11) 6(1) 6 (2) 9(1) 1(1) 3(1) 2 (2) C(21) 3(1) 4(1) 9(2} 0.6 (8) -0(1) -1 (D C(12) 10(2) 8 (2) 6(1) -3(2) -0(1] 0 (1) C (22) 7(2) 6 (2) 3(1) -1(1) -1(1) -0 (1) 46 parameters are given i n Tables 8 and 9 respectively. Measured and calculated structure factors are available from the U.B.C. Library. RESULTS AND DISCUSSION The structure consists of two cr y s t a l l o g r a p h i c a l l y non- equivalent anions i n the asymmetric unit, linked by two non- eguivalent dimethylammonium cations. The atom l a b e l l i n g scheme i s i l l u s t r a t e d i n Figure 7. Most corresponding bond lengths and angles are not s i g n i f i c a n t l y d i f f e r e n t between the two independent formula units, as can be seen from Tables 10 and 11. A l l three DMSO ligands are coordinated through the sulphur atoms, the coordination geometry about the ruthenium atoms being e s s e n t i a l l y that of an octahedron, with each DMSO ligand having a chlorine atom i n a trans position. Slight d i s t o r t i o n does occur, presumably due to s t e r i c interference between the DMSO groups, the Cl-Ru-Cl angles being s l i g h t l y smaller than 90° [87.1-88.3(2)°, mean 87.6°] while those f o r S-Ru-S are s l i g h t l y larger [ 92.0-93.4(2)°, mean 92.6°]. o o The Ru-S bond lengths [ 2.25 2-2. 273 (5) A, mean 2.261 A] are s i g n i f i c a n t l y longer while the S-0 distances [ 1.45- o o 1.50(1) A, mean 1.48 A] are shorter than those found i n o o [ Ru (NH3 )s DMSO2* 2PF b-J (30) i . e . 2.188(3) A and 1.527 (8) A respectively. These changes i n bond length indicate a decrease i n the possible dir-jr«r back donation from the c e n t r a l metal to the sulphur atom caused by the competition from the other DMSO ligands for the available "W-donor o r b i t a l s . Similar e f f e c t s are seen for trans-PdClj{DMS0) a [Pd-S o © 2.299 (2) A, and S-0 1.476(5) AJ (31) and c i s - A general view of the structure showing the c r y s t a l l o g r a p h i c numbering scheme. 48 Table J.0 o Bond Lengths (A) with standard d e v i a t i o n s i n parentheses. o o Bond Length (A) Bond Length (A) Bu (1) - C l ( 1 1) 2. 450 (4) Ru (2) - C l (21) 2. 430(4) Ru (1) - C l (12) 2. 417(4) Ru (2) - C l (22) 2. 414(5) Ru (1.) - C l (13) 2. 415 (5) Ru (2) - C l (23) 2. 427(5) Ru (1) -S(11) 2. 256 (4) Ru (2) -S (21) 2. 267(4) Ru (1) -S(12) 2. 261 (5) Ru (2) -S(22) 2. 273 (5) Ru (1) -S(13) 2. 252 (4) Bu(2) -S (23) 2. 260(5) S (11) -0(111) 1. 48(1) S (21) -0 (21 1) 1. 47 (1) S{12) -0 (121) 1. 49 (1) S (22) -0 (221) 1. 47(2) S {13) -0(131) 1. 50(1) S (23) -0 (231) 1. 45 (2) S (11) -C(111) 1. 79 (2) S (21) -C (21 1} 1. 77 (2) S (11) -C (112) 1. 86 (2) S (21) -C (212) 1. 8 1 (2) S (12) -C(121) 1. 80 (2) S (22) -C (221) 1. 80 (2) S (12) -C (122) 1. 81 (2) S (22) -C (222) 1. 75(2) S { 13) -C (131) 1. 78 (2) S (23) -C (231) 1. 78 (3) S (13) -C(132) 1. 80 (2) S (23) -C (232) 1. 7 6 (3) N(1) -C(11) 1. 48 (3) N(2) -C(21) 1. 48(2) N(1) -C(12) 1. 51 (3) N{2) -C (22) 1. 47(3) 4 9 Table jn Bond angles (deg) with standard d e v i a t i o n s i n parentheses. Bonds Angle (deg) Bonds Angle (deg) Cl(11) -Ru (1) - C l (12) 87.1(2) C l (21) -Ru (2) -Cl(22) 87.7 (2) Cl(11) -Ru( 1) -Cl(13) 87.4(2) Cl(21) -Ru (2) -Cl{2 3) 87.7 (2) C l (1 1) -Ru(1) -s ( 11) 175.4 (2) C l (21) -Ru (2) -S (21) 174.7 (2) C l (11) -Ru (1) -s j 12) 92.7 (2) C l (21 j -Ru(2) -S (22) 87.3(2) Cl(11) -Ru(1) -S ( 13} 87.4(2} Cl(21) -Ru (2) -S (23) 92.7 (2) C l (12) -Ru (1) - C l (13) 87.4 (2) C l (22) -Ru (2) -Cl(23) 88.3 (2) Cl(12) -Ru{1) -s { 11) 93.4(2) Cl(22) -Ru (2) -S (21) 86. 9(2) Cl{12) -Ru{ 1) -S ( 12) 86.8(2) C l (22; -Ru (2) -S (22) 91.2 (2) C l (12) -Ru{1) -S | 13) 174.5 (2) C l (22) -Ru (2) -S (23) 175.4 (2) Cl(13) -Ru(1) -s | 11) 88.0(2) C l (23] -Ru (2) -S (21) 92.4 (2) Cl(13) -Ru (1) -S i 12) 174.2(2) Cl(23; -Ru (2) -S (22) 175.0 (2) Cl(13) -Ru (1) -s | 13) 92.6 (2) C l (23] -Ru (2) -S (23) 87.2 (2) S(11) -Ru(1) -s I 12) 92.0(2) S (21) -Su (2) -S (22) 92.5 (2) S(11) -Ru (1) -s \ 13) 92. 0 (2) S (21) -Ru (2) -S (23) 92.6 (2) S(12) -Ru{ 1) -s | 13) 93. 1 (2) S (22) -Ru (2) -S (23) 9 3.4 (2) Eu(1) -S (11) -0 i 1 11) 118.9 (6) Su (2) -S(21) -0 (211) 118. 1 (6) Ru{1) -S (12) -0 i 121) 119.8 (5) Ru (2) -5(22) -0 (221) 118.2 (7) Ru(1) -S(13) -0 | 131) 115.7 (5) Ru (2) -S(23) -0 (231) 118. 2 (7) Ru(1) -S (11) -C I 1 11) 111.8 (8) Ru (2) -S(21) -C (2 11) 112. 6 (6) Ru(1) -S (11) -c 1 1 12) 1 12.8 (7) Ru(2) -S(21) -C (212) 111.4 (7) Ru(1) -S (12) -c 121) 113.0 (7) Ru (2) -S (22j -C (221) 110(1} Ru(1) -S (12) -C i 122) 111.1 (8) Ru (2) -S(22) -C (222) 114.8 (8) RU(1) -S{13) -C \ 131) 112.7(8) Ru (2) -S(23, -C (231) 115(1) Ru(1) -S (13) -C | 132) 113.8 (7) Ru (2) -S(23) -C (232) 110(1) 0(111) -S(11) -C i 1 11} 104.4 (9) 0 (211] |-S(21] -C (211) 108(1) 0(111) -S (1 1) -c [1 12) 104.6(9) 0 (211 -S{21) -C (212) 106(1) 0(121) -S{12) -c | 121) 105.3(8) 0 (221 i-S (22] -C (221) 109(1) 0(121) -S (12) -c 122) 105 (1) 0 (221 -S{22; -C (222) 105(1) 0(131) -S (13) ~C ! 131} 107 (1) 0 (231 i-S (23' -C (23 1) 104(1) 0(131) -S (13) -C [132) 107.1 (9) 0 (231 -S(23; -C (232) 110(1) C(11 1) -S(11) -c | [112) 103 (1) C (211 |-S(21] |-C (212) 99(1) C(121) -S (12) -c 1 122) 101 (1) C (221 -S(22) -C (222) 98 (1) C(131) -S{13) -c ;132) 100 (1) C (231 I -S(23] -C (232) 98(1) C(11) -13(1) -c { 12) 114 (2) C (21) -N (2) -C (22) 113(2) 50 o o Pa (N03 ) x (DMS0)2 [ Pd-S 2.231(3) A, and S-0 1.463 (7) A] (32). The strong trans e f f e c t of sulphur-bonded DMSO ligands (33) i s i l l u s t r a t e d i n the 8 u-Cl bond distances [2.414- 2.450 (4) A, mean 2.426 A] which are s i g n i f i c a n t l y longer than © those f o r the mutually trans chlorine atoms [mean 2.390(7) A] i n the octahedral complex RuClj(K zC bH^(CHj)) (P ( C b H s ) a ) 2 . (CH 3) l0 (34) . The' geometry about the sulphur atoms i s the expected distorted tetrahedron with values of 115.7-119.8(5)°, mean 118.2°, for the 8u-S-0 angles, and 110-115(1)°, mean 112°, for the Hu-S-C angles. The values of the O-S-C angles [104- 110(1)°, mean 106°], the C-S-C angles [ 98-103 (1)°, mean o o 100°], and the S-C bond lengths [1.7 5-1.86(2) A, mean 1.79 A] are very s i m i l a r to those found for free DMSO [107°, 98° and e 1.80-1.82(1) A respectively] (35). The hydrogen atoms attached to the nitrogen atoms i n the dimethylammonium cations are involved i n hydrogen bonding to both non-eguivalent anions, forming a chain-like structure throughout the c r y s t a l l a t t i c e . H (11) and H(12) take part i n N-H ..... 0 hydrogen bonding, while H(21) and H(22) are involved i n N-H . . . Cl hydrogen bonding. Although heavy atom separations do not uniquely define the presence of hydrogen bonding, they can give a reasonable i n d i c a t i o n , values of t y p i c a l heavy atom contact distances being 2.9 A o and 3.3 A for N . . . . 0. and N . . . C l hydrogen bonded atoms (36 and 37). From Table 12 i t can be seen that several of the separations are well above these values, tending to 5 1 Table 12 Values o f O . . . , N, 0 . . . H, Cl . . . N and Cl . . . H intermolecular contacts. -- . -- Atoms Distance (A) Atoms Distance (A) 0 (111)-N (1) 2.99 (2) 0(111] -H(12) 2.2 0 (121) - K (1) 3.18(2) 0(121) -H (1 2) 2.8 0(131)-N{1) 3.05 (3) 0 (131 ] -H(12) 2.3 0 (21 1)-H{1). 2.89 (2) 0 (211) -H ( 11) 2.1 0 (221)-N (1) 3.36 (3) 0(221] -H(11) 2.9 0(231)-N (1) 3.36(3) 0(231) -H(11) 2.7 Cl(1 1)-N(2) 3.24(3) c i (11) -H(21) 2.4 Cl(12)-N (2) 3.35 (3) Cl(12) -H(21) 2.7 Cl (13)-N (2) 3.57 (4) Cl(13) -H(21) 2.8 Cl (21)-N (2) 3.73(4) C l (21) -H (22) 3.0 Cl(22) —N (2) 3. 23 (3) C l (22) -H (22) 2.3 Cl(23) -N{2) 3.79(4) Cl(23) -H (22) 3.3 Due to the hydrogen positions being calculated the errors i n the 0 ....... H, and C l . . . H distances are subject to speculation. Fiqure 8 A stereoscopic diagram of the u n i t c e l l viewed down c; hydroqen bonds are i n d i c a t e d by dotted l i n e s . r u l e out the presence of hydroqen bonding for these c h l o r i n e and oxygen atoms. Unfortunately the hydroqen positions must be somewhat s p e c u l a t i v e , but the trends indicated from the 0 . . . H and C l . . . H separations support the f i n d i n g s f o r the heavy atom contacts. T y p i c a l observed H . - . 0 and o * e H . . . C l distances are 2.0 A and 2.4 A compared to 2.6 A and 3.0 A f o r van der Haals contact only. The o v e r a l l r e s u l t s would i n d i c a t e the presence of at l e a s t six hydroqen bonds N(1)-H{12) . . . 0(111), N(1)-H(12) . . . 0(131), N(1)-H(11) . . . 0(211), N(2)-H(21) . . . Cl(11), N(2)-H(21) . . . Cl(12) and N(2)-H(22) . . . Cl(22). Fiqure 8 shows the contents of the unit c e l l viewed along c-with these hydrogen bonds i n d i c a t e d by the dotted l i n e s . CHAPTER 4 CRYSTAL AND MOLECULAR STRUCTURE OF DXCHLOROTETRAKIS (DIMETHYLSULPHOXIDE) RUTHENIUM (II) 54 INTRODUCTION Infrared and *H n. m. r. ,spectral data on dic h l o r o t e t r a k i s (dimethylsulphoxide) ruthenium (II) indicated the p o s s i b i l i t y of a mixture of S-bonded and O-bonded dimethylsulphoxide ligands (38). The X-ray crystallographic study of [ (MejSO)i^RuCla, ] was undertaken to ver i f y t h i s unusual assignment, and provide a d d i t i o n a l information to that gained from the structure presented in Chapter 3 (29) on ruthenium dimethylsulphoxide complexes. EXPERIMENTAL 1g of ruthenium t r i c h l o r i d e was refluxed i n methanol (20ml) under hydrogen (1 atm) for approximately 8hr producing a blue solution. 4ml of dimethylsulphoxide were then added and the re f l u x i n g continued for a further 2 hours f i n a l l y producing a red solut i o n . Cooling and r e c r y s t a l l i z a t i o n of (MeiSO)H.RuCli from methanol gave yellow cubes. The c r y s t a l chosen for study was mounted with c* p a r a l l e l to the goniostat axis and had dimensions of ca 0.20 x 0.20 x 0.2 5 mm. U n i t - c e l l and space group data were obtained from f i l m and diffractometer measurements. The u n i t - c e l l parameters were refined by a least-squares treatment of sin 2© values f o r 21 r e f l e c t i o n s measured on a diffractometer with Mo K«t radiation.. Crystal ' Data. CfHi* C l j O ^ u S ^ , M = 484.54 , monoclinic, a = 8.939 (3), b = 18.045(7), c = 11.363(3) A, P= 91.52(2)° U = 1832 (1) A 3, 0^= 1.74(1) gcm-3 Z = 4, 0 t= 1.76(1) gcm-3, © F(000) = 984 (20°C, Mo K*, X= 0.71069 A, A = 15.66 cr>) . 55 Absent r e f l e c t i o n s : hOl, h>l # 2n, QkO, k # 2n define uniquely the space group P2,/n (C|^, No. 14). I n t e n s i t i e s were measured on a Datex-automated General E l e c t r i c XRD 6 diffractometer, with a s c i n t i l l a t i o n counter, Mo K« (zirconium f i l t e r and pulse height analyser), and a 9- 29 scan at 2° min-* over a range of {1.80 + 0.86 tan 9) degrees i n 29, with 20 s background counts being measured at each end of the scan. Data were measured to 29 = 45° (minimum e inter planar spacing 0.93 A) . A check r e f l e x i o n was monitored every 50 r e f l e c t i o n s throughout the data c o l l e c t i o n . The greatest deviation from the i n i t i a l value was +7.8% and the f i n a l i n t e n s i t y was 0.962 times the i n i t i a l value. Lorentz and p o l a r i z a t i o n corrections were applied, and the structure amplitudes were derived. No absorption correction was applied due to the low value of/* , and the f a i r l y uniform shape of the c r y s t a l . Of the 3231 independent r e f l e c t i o n s measured, 511 had i n t e n s i t i e s less than 3«-(I) above background where <rz(D = S + B * (0.05S) 2 with S = scan count and B = time averaged background count. These r e f l e c t i o n s were c l a s s i f i e d as unobserved and given zero weight in the refinement. STRUCTURE ANALYSIS The p o s i t i o n of the ruthenium atom was again determined from the three-dimensional Patterson function. One cycle of full-matrix least-squares refinement of the p o s i t i o n a l and i s o t r o p i c thermal parameters for the ruthenium atom gave a R value of 0.48. The positions of the two chlorine atoms and the four sulphur atoms were revealed from a difference 56 Fourier, and two further i s o t r o p i c cycles lowered R to 0.20. another difference map then revealed the positions of the remaining non-hydrogen atoms, a further three cycles using an anomalous scattering correction for the Ru, C l , and S atoms, and r e f i n i n g the p o s i t i o n a l and anisotropic thermal parameters for a l l the atoms, lowered R to 0.047. a f i n a l difference Fourier performed at t h i s stage indicated the positions of eleven of the twenty-four hydrogens, and the remaining thirteen positions were calculated allowing f o r minimum intramolecular interactions (see Table 13). The f i n a l conventional R factor for the 2720 observed r e f l e c t i o n s was R = 0.041. (15 r e f l e c t i o n s were given zero weight i n the f i n a l stages of refinement due to suspected errors r e s u l t i n g from e x t i n c t i o n , absorption, or instrument malfunction: 1 2 4, 3 0 1, 4 2 1, 3 4 1, 2 0 0, 4 0 0, 3 2 0, 1 6 0, 0 8 0 , 1 8 1 , 4 0 2, 1 0 3, 0 2 3 , 0 0 4 , 0 2 5). The scattering factors of r e f . 14 were used for the non- hydrogen atoms and those of ref. 39 f o r the hydrogen atoms, anomalous scattering corrections (15) were applied f o r the Ru, C l , and S atoms. The weighting scheme: fit ~ I £ ° 1/12.8 i f JFo| < 12.8, J~i = 1 i f 22.6 < |Fo| > 12.8, / T = 22.6/|FoJ i f |Fo| > 22.6 and - 0.0 f o r unobserved r e f l e c t i o n s gave constant average values of w (Fo-Fc) 2 over ranges of IFoj and was employed i n the f i n a l stages of refinement. The f i n a l p o s i t i o n a l and thermal parameters are given i n Tables 13 and 14 respectively. Measured and calculated structure amplitudes are a v a i l a b l e from U.B.C. Library. Table 13 F i n a l p o s i t i o n a l parameters {fractional x 10*) with estimated standard deviations i n parentheses atom X I z EU 2484.2(4) 1 217.5 (2) 2654.5 (3) Cl{1) 5001 (1) 701 (1) 2652(1) Cl(2) 1570 (1) 9972 (1) 3040 (1) S(1) 2361 (2) 1051 (1) 690 (1) S (2) 3332 (1) 2403 ( 1) 2507(1) S{3) 63(1) 1591 (1) 2791 (1) S (4) 3528 (1) 766 (1) 5290(1) 0(1) 1036 (6) 1302 (3) 9984 (4) 0 (2) 30 41 (6) 2800(2) 1379(4) 0(3) 9657(5) 2378 (2) 2577 (4) 0(4) 27 65 (4) 1377(2) 4515(3) C{11) 3980(8) 1413 (4) 9964 (5) C (12) 2596 (9) 96 (4) 349(6) C(21) 5292(7) 2486 (4) 2867 (8) C (22) 2660 (7) 2982(3) 3649(6) C(31) 9396 (7) 1365 (4) 4216 (6) C{32) 8809 (6) 1047 (4) 1886(6) C (41) 2524(8) 843 (5) 6619(6) C{42) 5262(8) 1176 (4) 5778(7) H {11 1) 36 00 1851 10 H (112) * 48 19 1075 77 H(113) * 3739 1460 -887 H (121)* 20 55 -219 896 H(122) 2488 95 -500 H (123)* 36 86 -39 420 H{211) 6027 2329 2347 H (212) 5577 3058 3184 H (213) * 5432 2480 3753 H (221) * 1597 2888 3775 H (222) 2950 3004 4 429 H(223) 3081 3456 3520 H(311) -47 1638 4969 H (312) * -1516 1654 4370 H(313)* -869 832 4241 H (321) * -754 959 1111 H (322) -1170 490 2150 H{323)* -2150 1307 1770 H{41 1) 2392 1321 7080 H (412) 1447 1197 6664 H (413) * 2915 490 721 1 H (421) 4397 1421 6023 H{422) * 5795 829 6304 H (423)* 5867 1287 5100 •calculated positions 5 8 Table J J F i n a l thermal parameters and t h e i r estimated standard deviations (a) Anisotropic thermal parameters (U>- x 1Q2 A2) Atom 0 fi 21 fi S3 u 0 va fi 2.Z Hu 2. 08 ( 2) 2.59 ( 2) 3. 21 { 2) 0. 00 ( 1) 0 .09 ( 1) 0. 10 ( 1) Cl(1) 2. 33 ( 6) 4.3 8 ( 7) 5. 74 ( 8) 0. 62 ( 5) 0 .20 ( 5) 0. 09 ( 5) Cl(2) 3. 72 ( 6) 2.96 ( 6) 5. 42 ( 7) -0. 58 ( 5) -0 .01 ( 5) 0. 39 ( 5) S(1) 3. 82 ( 7) 5.23 { 7) 3. 34 ( 6) 0. 03 ( 6) -0 .03 ( 5} 0. 16 ( 5) S{2) 4. 00 ( 7) 2.75 ( 6) 5. 49 { 7) -0. 28 { 5) 1 .06 ( 5) 0.20 ( 5) S(3) 2. 39 ( 6) 3.84 { 7) 4. 92 ( 7) 0. 39 ( 5) 0 .28 ( 5) 0. 19 ( 5) S (4) 4. 00 ( 7) 3.51 ( 6) 3. 75 ( 6) 0. 19 ( 5) -0 .62 ( 5) -0.22 ( 5) 0(1) 5. 62 (29) 12.78 (51) 4. 73 (24) 1. 51 (26) -1 .56 (21) 1.8 6 (26) 0(2) 10. 47 (39) 4. 19 (24) 6. 45 (28) 0. 83 (25) 2 .49 (26) 1.74 (21) 0(3) 4. 18 (21) 4.0 8 (22) 9. 27 (32) 1. 78 (18) 0 .15 (20) 0.7 5 (21) 0(4) 4. 09 (20) 3.95 (19) 3. 39 (16) 0. 52 (15) -0 .27 (14) -0. 11 (14) C(11) 6. 89 (42) 5.7 8 (36) 4. 93 (32) 0. 76 (31) 2 .52 (29) 1.01 (28) C(12) 9. 73 (54) 6.32 (43) 5. 34 (3 5] -1. 56 (39) 1 .23 (34) -2.07 (32) C(21) 3. 82 (34) 5.88 (41) 13. 62 (7 0] -2. 27 (31) 1 .04 (38) -2. 00 (43) C (22) 6. 14 (38) 3.79 (31) 7. 86 (4 1) -1 . 15 (26) 1 .54 (31) -1. 85 (28) C (31) 4. 18 (33) 7.34 (43) 6. 08 (3 6] 0. 69 (29) 1 .93 (27) 0.14 (31) C (32) 2. 44 (26) 7.20 (40) 7. 31 (4 0) -0. 2 0 (26) -0 .81 (24) -0.78 (32) C (41) 7. 67 (46) 8.00 (48) 4. 62 (3 3] 2. 60 (38) 0 .90 (31) 1.65 (32) C (42) 4. 35 (34) 6.2 2 (41) 7. 42 (4 2) 0. 14 (27) -2 .56 (30) -0.10 (30) (b) Isotropic thermal parameters (U x 100) o Atom fi(A2) A l l Hydrogens 6.3 RESULTS AND DISCUSSION The co-ordination geometry about the ruthenium atom i s es s e n t i a l l y octahedral with c i s chlorine atoms. Of the four DMSO ligands, three are sulphur-bonded and one i s oxygen- bonded, the O-bonded ligand being trans to one of the S-- bonded ligands <S(1}). The atom l a b e l l i n g scheme and a general view of the molecule are i l l u s t r a t e d i n Figure 9. Individual bond lengths and angles, with standard deviations, are given i n Tables 15 and 16 respectively. S l i g h t d i s t o r t i o n does occur, the angles subtended at the central ruthenium atom between the three mutually c i s S- bonded ligands being larger than 90°[92.6- 94.9°, mean 94{1)°], while the values for the Cl-Ru-Cl, and the two Cl-Ru-0 angles are s l i g h t l y l e s s than 90°[87.8- 88 - 7° , mean 88.2(5)°]. Equations of selected least-squares mean-planes with deviations of the atoms from these planes are given i n Table 17. This d i s t o r t i o n appears to be governed primarily by s t e r i c factors associated with the S-bonded DMSO groups. The Ru-Cl bond lengths, 2.435(1) A, are s i g n i f i c a n t l y longer than would be expected for a purely ©"-donor ligand. Typical values of mean Ru-Cl bond lengths i n octahedral © complexes with trans chlorine atoms are 2. 390 (7) A i n RuCl 5(N iC vH v(CH 1) ) (P( C f c H s ) x ) a . (CH 3) z0 (34) and 2.398 (7) A i n RuCl 3 (NO) (PMePha.)^ (40). This lengthening i s an indicatio n of the strong trans e f f e c t of a S-bonded DMSO ligand (33). A g e n e r a l view of the s t r u c t u r e showing the c r y s t a l l o g r a p h i c numbering scheme. 6 1 Table 15 o Bond lengths <A) with standard deviations i n parentheses Bond Length (&) Bond Length (&) Ru -Cl(1) 2.435(1) S(1)-C(11) 1.779(8) Ru -Cl(2) 2.435(1) S(1)-C(12) 1.808(6) Eu -S(1) 2. 252(1) S (2)-C (21) 1. 795(7) Eu -S (2) 2. 277(1) S(2)-C(21) 1.783(6) Ru -S(3) 2.276(1) S (3)-C (31) 1.787 (6) Ru -0(4) 2. 142 (3) S (3)-C (32) 1.794(6) S{1)-0 (1) 1.483(5) 0(4)-S(4) 1.557(4) S(2)-0(2) 1.485(5) S(4)-C(41) 1.783(6) S(3)-0{3) 1. 485 (5) S (4) -C (42) 1.793(6) 6 2 Table J6 Bond angles (deg) with standard deviations i n parentheses. Bonds Angle Bonds Angle Cl (1) -Bu - C l (2) 87.78 (5) Bu -S (2) -C(22) 112. 2(2) Cl (1) -Bu -S(1) 88.22 (5) Hu -S(3) -C (31) 109. 6(2) Cl(1) -Bu -S(2) 92.90(5) Bu -S (3) -C (32) 112. 3(2) Cl (1) -Bu -S (3) 173.49 (5) Bu -S(1) -0(1) 120.9(2) Cl{1) -Bu -0(4) 88.2(1) Bu -S{2) -0(2} 117. 7(2) Cl(2) -Bu -S(1) 92.69 (5) Bu -S (3) -0(3} 120. 1(2) Cl <2) -Bu -S(2) 173.85 (5) C (11) -S(1) -C{12) 98.6 (3) Cl{2) -Bu -S{3) 86.38(5) C(21) -S (2) -C(22) 97.5 (3) Cl (2) -Bu -0(4) 88.7 (1) C{31) -S(2) -C {32} 100. 1 (3) S (1) -Bu -S{2) 9 3. 44 (5) C(11) -S{ 1) -0(1) 106. 3(3) S{1) -Bu -S(3) 94.91 (5) C{12) -S{1) -0(1) 106. 0(4) S(1) t-Bu -0 (4) 176.1 (1) C(21) - S (2) -0(2) 107. 7(4) S(2) -Bu -S<3) 92.61 (5) C (22) -S (2) -0(2) 106. 9 (3) S(2) -Bu -0(4) 85.2 (1) C{31) - S (3) -0 (3) 106.3 (3) S(3) -Hu -0 (4) 88. 8(1) C (32) -S{3) -0(3) 106. 4(3) Bu -S(1) -C(11) 112.6(2) BU -0(4) -S (4) 120. 0(2) Su -S(1) -C(12) 110.0 (2) 0(4) -S(4) -C(41) 101 . 6(3) Hu -S (2) -C(21) 112.7 (2) 0(4) -S(4) -C (42) 104. 2(3) C{41) - S (4) -C {42} 99.0 (4) Table V7 Selected Weighted Least-Squares mean planes for RuClj {flea,SO)H. Plane through Ru, C l (2) , S(1), S (2) , and 0(4) 0.999X + 0.049Y - 0.013Z = 2.249 Atom Ru Cl(2) S<1) S(2) 0(4) Distance (A) -0.042(1) -0. 100(1) -0. 079 (1) 0. 826 (1) 0. 139(4) Plane through Ru, Cl ( 1 ) , S(1), S (3) , and 0(4) 0.335X + 0.933Y - 0. 129Z = 2.365 Atom Ru Cl(1) S(1) S (3) O (4) Distance (A) 0.013 (1) -0. 102(1) 0.003 (1) -0. 104( 1) 0.075(4) Plane through Ru, Cl (1) , Cl (2) , S (2) , and S(3) -0.043X * 0.024Y - 0.999Z = -3.0537 Atom Ru Cl(1) Cl(2) S(3) S (3) Distance (A) 0. 0009 (3) -0. 166(1) -0.027(1) 0.186 (1) -0.042( 1) In the inter a c t i o n between the Ru and S atoms, the sulphur atom appears to be behaving as a weak "^-acceptor, as a shortening of the bond between a metal atom and a tf"-donor ligand should be observed i f the «"-donor i s trans to a strong T-acceptor. For example i n £ Ru (N0)C1 S ] 2 ~ the equatorial Ru-Cl distances average 2.376(2) A while the chlorine atom trans to © the n i t r o s y l group i s s i g n i f i c a n t l y shorter at 2. 357 (1) A <«••). However evidence supporting some TT-acceptor nature can be obtained from the Ru-S distances i n the S-bonded DMSO ligands, which are trans to the two chlorine atoms. The mean © value of 2.277(1) A found for the Ru-S bond lengths indicates the presence of some dtr-£TT back donation from the c e n t r a l metal to the sulphur atom, assuming the single bond covalent e r a d i i f o r ruthenium and sulphur are 1-33 and 1.04 A respectively., (22). However, t h i s back donation i s considerably less than that found i n [ Ru (NHj) s (Me2SO) ] 2 * (30), where the Ru-S distance i s © 2.188(3) A. The increased back donation found i n the mono- sulphoxide i s due to the lack of competition for the available tr-donor o r b i t a l s from other TT-acceptor ligands i n the co-ordination sphere. A comparison of simi l a r bond lengths and angles f o r [ RUCI3 (Me aS0)3 ]-. (Chapter 3, ref . 29), f Eu (NH 3) S (MeaSO) ]2*„ (30)j and free DMSO (35) with those of RuCl 2.(MexS0)4. can be found i n Table 18. Examples of the change in co-ordinating atom with the variation of the number of DMSO ligands attached are somewhat li m i t e d . In four-co-ordinate palladium complexes s t e r i c 65 influences appear to be of most importance (42) . [Pd(Ke^SO^d^] has exclusively sulphur-bonding, [ Pd (MejSO) ̂ .32+ has both sulphur and oxygen-bonded ligands i n a c i s configuration. as the s i z e of the ligand increases mixed trans structures are produced, i . e . i n the propyl and butyl c a t i o n i c species, while only oxygen-bonded ligands occur i n the iso-pentyl complex [Pd(Pe^SO)^ ] 2 + . This change i n co-ordination i s paralleled i n these octahedral systems. [ BuClj (HeaSOJ-j j - (Chapter 3) has an a l l S-bonded c i s structure, while the inclus i o n of another DMSO ligand approaches the [ Pd (-He 2. SO) ̂  ] 2 + s i t u a t i o n , such that s t e r i c influences prohibit the formation of an a l l sulphur-bonded complex, but el e c t r o n i c e f f e c t s keep the S-bonded ligands i n a c i s configuration. The decrease i n central metal si z e i n going from ruthenium to iron increases the s t e r i c i n t e r a c t i o n s considerably, i . e . , [ FeCla (MezS0)a ] + has a trans configuration in which a l l the DMSO ligands are oxygen-bonded (43) . The fiu-S bond length for the S-bonded dimethylsulphoxide o ligand trans to the O-bonded sulphoxide i s 2.252 (1) .&. This © s l i g h t yet s i g n i f i c a n t shortening (compared to 2.277(1) A) i s due to the di f f e r e n t atoms i n the trans positions. The Eu-0 o distance i s 2.142(3) A and i s s i m i l a r to the value of o 2.007 (6) A found for Fe-0 (43), considering the difference of o covalent r a d i i of the two metals to be approximately 0.12 A (22). 66 Table J.8 Mean bond lengths and angles for (I) [ RuCl a(He xSO) i ]- (II) RuCl a(Me xS0) % (III) [Ru (NH3)S (MexSO) j 2 * (IV) Free DMSO A) Bond o Lengths (A) (I) (II) (III) (IV) Ru-S 2.261 (8) 2. 277 (1) 2. 188 (3) - S-0 1.48(2) 1.485 (5) 1.527 (7) 1.471-1.531 S-C 1.79 (3) 1.790 (6) 1. 840(8) 1.80- 1.82 (1) BU-C1 2.43 (1) 2.435 (1 ) - - B) Bond Angles (deg) Bu-S-0 118(1) 119(1) 114.9(3) - Ru-S-C 112 (2) 112(1) 116(1) - O-S-C 106(2) 106.8(6) 104.2 (8) 107 C-S-C 100 (2) 99(1) 99.4(6) 98 67 Figure 10 A stereoscopic diagram of the un i t c e l l viewed down b. There i s considerable v a r i a t i o n i n the sulphur-oxyqen distances for the two types of d i f f e r e n t l y co-ordinated dimethylsulphoxide ligands. In the sulphur-bonded ligands the mean value i s 1.484(5) A, while i n the oxygen-bonded liqa n d the distance i s 1.557(4) A. This represents a considerable decrease -in the multiple bond character of the sulphur-oxygen linkeage caused i y the differences i n co-ordination, though t h i s i s s t i l l somewhat short of the estimated S-0 s i n g l e bond o length of 1.70 A (43). The molecular geometry of the r- S-bonded dimethylsulphoxide ligands i s very s i m i l a r to that found i n free dimethylsulphoxide (41). The 0-S-C angles (mean value 106.6(6)°), C-S-C angles (mean value 99(1)°), and the S-C 68 bona lengths (mean value 1.79(1) A) compare with 107°, 98° and 1.80-1.82(1) A respectively. The corresponding mean values for the O-bonded ligand are also s i m i l a r being 103 (1)°, 99.0(4)° and 1.788 (5) A. The other angles i n the distorted tetrahedron have mean values of 112(2)° f o r Ru-S-C, 120(2)° for Ru-S-0 and 120.0(2)° for Bu-O-S. Figure 10 shows a stereoscopic view of the contents of the unit c e l l viewed down b. The c r y s t a l structures of t h i s compound and the t r i c h l o r o t r i s (dimethylsulphoxide) complex (Chapter 3) were consistent with the infrared and *H n.m.r. spectral data (29) f o r these compounds. 5 9 CHAPTER 5 CRYSTAL AND MOLECULAR STRUCTURE OF 1 , 3,7—TRIMETHYL-2,6-DIOXY PURINE HYDROCHLORIDE DIHYDRATE (CAFFEINE HYDROCHLORIDE DIHYDRATE) 70 INTRODUCTION The c r y s t a l structure determination of caffeine hydrochloride dihydrate was undertaken primarily to provide the necessary information to complement an ENDOR study on t h i s compound. The renewed inter e s t i n t h i s area i s due to the discovery that caffeine w i l l i n h i b i t the post-radiation repair of chromosomal aberrations in i r r a d i a t e d DNA (44). EXP ERI MENTAL The white nearly t r i g o n a l prismatic c r y s t a l s were grown by evaporation from a saturated sol u t i o n of caffeine i n hydrochloric acid. The c r y s t a l chosen for study (ca 0.4 X 0.3 X 0.2 mm.) was mounted with b p a r a l l e l to the gbniostat axis. U n i t - c e l l and space group data were obtained from f i l m and diffractometer measurements. The u n i t - c e l l parameters were refined by a least-squares treatment of s i n 2 8 values for 22 r e f l e c t i o n s measured on a diffractometer with Cu K* r a d i a t i o n . C r y s t a l Data. C $H„ ClN^O,..2H1>0, M = 266.7, monoclinic, a = 12.391(4), b = 6. 524 (1), c = 17.167(6) A, o P = 118.82(3)°, U= 1215.9(8) A 3 , D m = 1.46, D e = 1.457 g cm-3, z = 4, F(000) = 560. Space group P2,/c (C^ , No 14) from absent r e f l e c t i o n s hOl, 1 * 2n and OkO, k * 2n. /*(CuKo( radiation) = 29.19 cm - 1. I n t e n s i t i e s were measured on a Datex-automated General E l e c t r i c XRD 6 diffractometer, with a s c i n t i l l a t i o n counter, Cu K ot (nickel f i l t e r and pulse height analyser), and a -6-29 scan at 2° min - 1 over a range of (1.80 * 0.86 tan 8) degrees 7 1 in 29, with 10 s background counts being measured at each end of the scan. Data were measured to 29 = 140° {minimum interplanar spacing 0.82 ft). A check r e f l e c t i o n was monitored every 40 r e f l e c t i o n s throughout the data c o l l e c t i o n . The greatest deviation from the i n i t i a l value was +21.1% and the f i n a l i n t e n s i t y was 0.85 times the i n i t i a l value. Lorentz and p o l a r i z a t i o n corrections were applied, and the structure amplitudes were derived. No absorption correction was applied due to the low value of /* and the f a i r l y uniform shape of the c r y s t a l . Of the 2208 independent r e f l e c t i o n s measured, 451 had i n t e n s i t i e s l e s s than 3 o-(I) above background where <fz{I) = S + B * (0.05S) 2 with S = scan count and B = time averaged background count. These r e f l e c t i o n s were c l a s s i f i e d as unobserved and given zero weight i n the refinement. STSDCTURE ANALYSIS Although the Patterson synthesis i s very useful f o r compounds with one or a few 'heavy atoms', i t i s unsuitable for molecules in which many atoms have the same or s i m i l a r atomic numbers, because no vectors w i l l stand out on the Patterson Fourier map. Fortunately alternate 'direct methods' have been developed which r e l y on p r o b a b i l i t y relationships between the phases of the 'stronger' r e f l e c t i o n s . In direct methods, normalized fac t o r s H Hj are used which are e s s e n t i a l l y geometrical structure factors only, rather than containing, as does |F B|, the e f f e c t s of atomic scattering factors and atomic thermal motion. They can be calculated as follows where S i s an integer symmetry factor which depends upon the space group extinctions, flauptman and Karle (45) developed probability r e l a t i o n s h i p s , based on Sayre's work, which could be used to determine the phases of r e f l e c t i o n s . B a s i c a l l y , as seen i n the eguation one estimate of the phase of H can be obtained from the phase addition of two r e f l e c t i o n s whose indices when added together give the indices of H. The weight to be given to t h i s indication i s equal to the product of the two normalised structure factors |EK1 and | E H |; the best estimate of the phase $ M w i l l be the weighted sum of a l l the i n d i c a t i o n s . Obviously relationships between large J E KJ and | E M M J * s w i l l dominate the summations due to t h e i r weight and should produce a phase value somewhere near that f o r the whole summation. For a centrosymmetric space group (e.g. P2,/c, t h i s compound) the phases can only be 0 or it, corresponding to the sign of + or -. Sayres equations then become where S means * the sign o f , ^ means 'probably equal to*, and the r e l a t i o n s h i p i s known as a £-2 (referred to as a Sigma Two) r e l a t i o n s h i p . That i s the £-2 relationship f o r the r e f l e c t i o n 4,2,1 i s made up of the sum of a l l the pairs of r e f l e c t i o n s whose indices add to 4,2,1 e.g. 4,1,0, and 0,1,1; 8,6,4 and -4,-4,-3; 1,1,1 and 3,1,0; etc. 7 3 The p r o b a b i l i t y , P, o f the s i g n S being c o r r e c t i s given f o r each r e f l e c t i o n by P = 0.5 + 0.5tanhl ^ ^ l ^ i l ^ I J where ^/°\ 3'x i s a constant dependent on the co n t e n t s of the u n i t c e l l . A computer program developed by Long (46) was used t o determine the s t r u c t u r e of c a f f e i n e h y d r o c h l o r i d e using these i d e a s . The program prepared a l i s t of C""2 r e l a t i o n s h i p s between the 297 r e f l e c t i o n s with JE| > 1.50. Three of the l a r g e s t IJM's were chosen with i n d i c e s conforming t o the p a r i t y r u l e s d e r i v e d from the space group {for P2,/c the suras of i n d i c e s o f any p a i r , and the sum of i n d i c e s of a l l three could not produce the p a r i t y even,even,even) and by a s s i g n i n g p o s i t i v e s i g n s t o these r e f l e c t i o n s the o r i g i n was s p e c i f i e d . Four more r e f l e c t i o n s (see Ta b l e 19 f o r the complete l i s t ) , each having a l a r g e |EJ and many ^ - 2 r e l a t i o n s h i p s , were then s e l e c t e d and allowed t o take on both + and - signs i n tur n producing s i x t e e n (2 4) s t a r t i n g s e t s of signs. When Sayre's eguation i s a p p l i e d to any s t a r t i n g s e t , a d d i t i o n a l s i g n s are determined, which i n t u r n are used t o determine more s i g n s , and to redetermine those already p r e d i c t e d . I n t h i s case newly determined s i g n s were not used to determine s i g n s o f a d d i t i o n a l r e f l e c t i o n s u n t i l the next c y c l e . T h i s process i s r e i t e r a t e d u n t i l t h e r e are no new a d d i t i o n s o r changes to the l i s t . A c o n s i s t e n c y index 0 i s def i n e d as <IIH-«M,c-l«-*l> 0 = <ISMI- S l I J I IH - « 1 > 7 4 Table _19 Basic s t a r t i n g set of r e f l e c t i o n s for C1C€NH.02.HU .2H^0 h k 1 |EI 1) -3 1 1 2.70 ^ 2) -7 2 2 3.33 > o r i g i n determining 3) -4 1 2 2.42 J 4) 2 5 3 3.08 5) -2 5 11 3,17 6) -7 2 4 2.29 7) -9 3 1 2.82 7 5 where < > means the average value over a l l H. The t r u e s o l u t i o n w i l l u s u a l l y have the h i g h e s t c o n s i s t e n c y index, r e g u i r e the l e a s t number of c y c l e s and converge t o a set o f s i g n s which are approximately e q u a l l y d i s t r i b u t e d between p o s i t i v e and n e g a t i v e . The r e s u l t s of the 1 6 s t a r t i n g s e t s are given i n Table 2 0 , and set 1 5 i s ou t s t a n d i n g i n that i t converged i n 5 c y c l e s with a very h i g h c o n s i s t e n c y index of 0 . 9 2 and had 1 5 6 p o s i t i v e and 1 4 1 n e g a t i v e s i g n s . An E map was computed using the 2 9 7 assigned values of E from t h i s s e t . The p o s i t i o n s of the 1 7 non- hydrogen atoms were i n d i c a t e d from the 1 7 h i g h e s t peaks on the map. Two c y c l e s of f u l l - m a t r i x l e a s t - s q u a r e s refinement produced an B f a c t o r of 0 . 1 2 9 with i s o t r o p i c temperature f a c t o r s , w h i l e a f u r t h e r c y c l e using a n i s o t r o p i c temperature f a c t o r s lowered the B f a c t o r t o 0 . 0 8 8 . A d i f f e r e n c e F o u r i e r computed a t t h i s stage r e v e a l e d the p o s i t i o n s of the 1 5 hydrogen atoms. F u r t h e r refinement with an anomalous s c a t t e r i n g c o r r e c t i o n f o r the c h l o r i n e atom, a n i s o t r o p i c temperature f a c t o r s f o r the non-hydrogen atoms, i s o t r o p i c temperature f a c t o r s f o r the hydrogen atoms and an o v e r a l l e x t i n c t i o n c o e f f i c i e n t c o r r e c t i o n produced convergence a t B = 0 . 0 6 4 f o r 1 7 5 2 r e f l e c t i o n s with I > 3 cr ( I ) ( 5 r e f l e c t i o n s were given z e r o weight i n the f i n a l stages of refinement due to suspected i n s t r u m e n t a l e r r o r s , - 1 0 2 , 1 2 1 6 , - 1 4 2 , 3 6 1 2 , - 7 5 4 ) . The atomic s c a t t e r i n g f a c t o r s f o r C l , O, N, and C were taken from r e f . 1 4 , anomalous s c a t t e r i n g c o r r e c t i o n from r e f . 1 5 , and s c a t t e r i n g f a c t o r s f o r the hydrogen atoms frcm r e f . 3 9 . The weighting Table 20 Comparison of the 16 solutions from Long's sign determination program. Set Signs of 7 Number of Number of Number of Consiste r e f l e c t i o n s cycles pluses minuses index 1 +++++++ 7 267 30 0. 850 2 -*+ + •+ + - 10 142 155 0. 608 3 +++•+-* 10 182 115 0. 685 4 — 7 147 150 0. 684 5 +++*-++ 6 143 154 0.717 6 «•+++—+- 7 140 157 0. 534 7 + — • 9 156 141 0. 598 8 8 142 155 0. 522 9 10 150 147 0.658 10 ++*-+*- 8 148 149 0. 523 11 + + +—#•-* 9 139 158 0. 713 12 +++-*— 7 140 157 0. 510 13 + + +-— + • 12 149 148 0.752 14 + + +—+- 7 150 147 0. 641 15 + + + + 5 156 141 0. 917 16 + + +- 12 144 153 0. 532 77 scheme w = 1/o-2 (F) where o-2 (F) i s derived from the previously defined a 2 (I) , gave constant average values of w(Fo-Fc) 2 over ranges of |Fo| and was employed i n the f i n a l stages of refinement. The f i n a l p o s i t i o n a l and thermal parameters appear in Tables 21 and 22 respectively. Measured and calculated structure factors are a v a i l a b l e from the U.B.C. Library. THERMAL MOTION AND CORRECTION OF MOLECULAR GEOMETRY Tbe e l l i p s o i d s of thermal motion f o r the non-hydrogen atoms (excluding the chloride ion and the water molecules) are shown i n F i g . 11. The thermal motion has been analysed i n terms of the rigid-body modes of translation (T) , l i b r a t i o n (L) , and screw (S) motion (47) using the computer program MGTLS. The r.m.s., standard deviation i n the temperature o f a c t o r s D-tj i s 0 . 0 0 1 7 A 2 i n d i c a t i n g that the whole molecule o (r.m.s. A U j ^ = 0 . 0 0 2 2 A 2 ) i s a reasonable rigid-body and that the thermal motion of the 9-membered fused ring system i s remarkably well described by the rigid-body thermal parameters given in Table 23 (r.m.s. A U ^ = 0 . 0 0 1 5 A 2 ) . The bond distances i n the fused r i n g system have been corrected for l i b r a t i o n (48 and 49) using shape parameters q 2 of 0.08 for a l l the atoms involved. Independent motion corrections based on the &U:: (50 and 51) have been applied to the bond lengths for the non-hydrogen atoms attached to the fused r i n g system. The corrected and uncorrected bond lengths appear i n Table 2 4 . Bond angles, given i n Table 2 5 , changed by no more than 0 . 0 5 ° , thus the corrected angles are not reported. T a b l e 21 F i n a l p o s i t i o n a l parameters ( f r a c t i o n a l x 10*, C l x 10 s, H 103) with estimated standard d e v i a t i o n s i n parentheses Atom X I 2 C l 9 8 3 8 8 ( 8 ) 4 8 8 4 7 ( 1 5 ) 3 5 3 7 0 { 6 ) 0 ( 1 1 ) 6 6 2 0 ( [ 2 ) 2 3 3 2 ( 4) 1 2 7 5 { 2 ) 0 ( 1 3 ) 5 7 4 8 [ 2 ) 6 9 9 2 ( 4} 2 8 8 5 { 2) 0 ( 1 ) ' 9 1 0 1 | [ 3 ) 7 6 3 3 { 5 ) 4 6 9 5 ( 2) 0 ( 2 ) » 8 5 9 2 [ 3 ) 5 8 8 4 ( 6 ) 1 4 2 0 ( 2) N ( 1 ) 6 2 4 1 | [ 2 ) 4 6 7 0 ( 4) 2 0 9 5 { 2) N ( 3 ) 7 3 5 9 [ 2 ) 1 6 3 0 { 4) 2 7 4 0 ( 2) N ( 7 ) 7 0 6 3 < t 2 ) 4 0 3 3 { 4) 4 4 5 9 ( 2 ) N ( 9 ) 7 9 0 5 ( 3 ) 1 2 3 2 ( 5 ) 4 3 0 6 ( 2) C ( 2 ) 6 7 3 3 [ 3 ) 2 8 2 7 ( 5 ) 1 9 9 4 { 2 ) C ( f t ) 7 3 8 1 [ 3 ) 2 2 1 9 ( 5 ) 3 5 0 3 { 2) C ( 5 ) 6 8 5 H [ 3 ) 3 9 7 1 { 5 ) 3 5 8 6 ( 2) C ( 6 ) 6 2 2 8 ( 3 ) 5 3 7 6 { 5 ) 2 8 6 5 ( 2) C ( 8 ) 7 6 9 3 | ( 3 ) 2 3 6 7 ( 5 ) 4 8 7 2 { 2} C ( 1 0 ) 5 5 9 1 ( ft) 5 9 1 6 { 8) 1 2 7 9 { 3) C { 1 2 ) 8 0 6 7 < ( 5 ) - 1 5 0 ( 7) 2 7 0 5 { 3 ) C ( 1 4 ) 6 6 4 7 ( ft) 5 6 5 3 ( 6 ) 4 8 4 8 ( 3 ) H ( 1 1) * 9 3 7 ( ft) 7 2 1 ( 7) 5 2 2 ( 3) H ( 1 2 ) • 9 27 ( 5 ) 692 ( 9 ) 4 3 2 { 4) H ( 2 1 ) * 8 8 8 ( ft) 5 4 0 ( 8 ) 1 9 8 { 3 ) H { 2 2 ) « 9 0 5 ( 7} 7 2 4 ( 1 3 ) 1 4 9 ( 4) H(D 7 9 2 { 2 ) 2 0 5 ( 4) 547 ( 2 ) H ( 2 ) 8 3 2 ( ft) 4 ( 7 ) 4 4 2 { 3 ) H ( 3 ) 5 4 3 ( ft) 7 2 7 ( 8) 1 4 9 ( 3 ) H (4) 4 7 9 ( 6 ) 5 2 0 ( 1 0 ) 8 7 ( 4) a ( 5 ) 6 1 0 ( 5) 6 0 9 ( 9) 9 6 { 4) H ( 6 ) 8 0 6 ( 5 ) - 1 8 ( 9 ) 2 1 8 ( 4) H{7) 7 7 9 ( 6 ) - 1 3 7 ( 1 2 ) 2 8 2 ( 5 ) H ( 8 ) 8 8 5 ( 5) -16 ( 8) 3 2 9 ( 4) H (9) 6 96 ( ft) 548 ( 7) 545 ( 3 ) H ( 1 0 ) 5 8 4 ( 5 ) 5 8 4 ( 8 ) 4 4 9 ( 3 ) H { 1 1 ) 700 ( ft) 7 0 4 ( 8 ) 473 ( 3 ) * i n d i c a t e s water molecule Table 22 F i n a l thermal parameters and th e i r estimated standard deviations (a) Anisotropic thermal parameters (tJ ̂  x 10 3, x 10* for Cl A2) ~ - Atom 2„ D 2»v 2.1. U 2x* Cl 606 ( 6) 468 ( 6) 479 ( 5) 72 ( 4) 27' I ( 4) 22 ( 0(11) 73 ( 2) 53 ( 2) 43 ( D -1( 1) 35 ( D -5( 1 0(13) 62( 2) 44 ( 2) 56 ( 2) 25( 1) 32 I 1) 11( 1 0(1) • 75 ( 2) 43 ( 2) 56 ( 2) 22 ( 1} 37 ( 2) 10 ( 1 0(2) • 72 ( 2) 63 ( 2) 50 ( 2) -13( 2) 20 ( 2) 2( 1 N(1) 37 ( D 40 ( 2) 36 { 1) 2( 1) 19 ( 1.) 5{ 1 N(3) 39 ( 1) 33 ( 1) 43 ( 2) M D 24 ( 1) -5( 1 N(7) 37 ( 1) 30 ( D 38 ( 1) 1( 1) 21 ( 1) -1( 1 N(9) "0 ( 1) 33 ( 2} 41 ( 2) 3{ 1) 20 ( 1) 3{ 1 C{2) 38( 2) 43 ( 2) 39 { 2) -7( 1) 22 ( 1) -4( 1 C(4) 31 ( 1) 31 ( 2) 39 ( 2) -2{ 1) 18 ( D - 1 ( 1 C(5) 34 ( 2) 27 ( 2) 37 { 2) 0{ 1) 20 ( D 2( 1 C{6) 34 ( 2) 38 ( 2) 42 ( 2) 2( D 21 ( 1) 5( 1 C (8) 38 ( 2) 38 ( 2) 32 ( 2) -1( 1) 14 ( 1) 2( 1 C(10) 64 ( 3) 62 ( 3) 42 ( 2) 16( 2) 24 ( 2) 12 ( 2 C(12) 68 ( 3) 41 ( 2) 65 ( 3) 18 ( 2) 40 ( 2) -2( 2 C(14) 59 ( 2) 42 ( 2} 45 ( 2) 6 ( 2) 32 ( 2) -3( 2 (b) Isotropic thermal parameters (0 x 10 3) Atom fi(A2) Atom 2(* 2) H(11) » 59 (12) H (5) 103 (17) H(12)* 97 (18) H(6) 99(19) H(21) * 74 (14) H(7) 133(27) H (22) « 152(26) H (8) 89 (16) H (1) 17 ( 7) H{9) 69(13) H(2) 60 (13) H (10) 79(15) H(3) 79 (14) H(11) 79(14) H(4) 122 (23) 80 81 Table 23 Rigid-body thermal parameters for the 9-membered fused ring system L(x 10 deg 2) J J-8-1 (11) 22{ 9) 58(12) -37 d3h; -6 (11) | 96 (35)Ji P r i n c i p a l axes of L i r.m.s. amplitude i • 3.6° J • 2,6 i ! 2-0 ; Direction 643 389 659 cosines 247 709 660 ( X 1 0 3 ) -725 58 8 36 0 [ P r i n c i p a l axes of T ' • r.m.s. amplitude ] ' 0.19(A) . ; o.i7 ; . 0.17 ! Direction 18 355 935 cosines -82 931 355 ( X 1 Q 3 ) 996 -83 12 o , ; r.m.s. A Uii (A*) • 0.0015 *Axes of reference are orthogonal Angstrom axes. E.s.d.*s of components of L are given i n parentheses i n units of the l a s t places shown. Table 24 Bond Lengths (A) with standard deviations i n parentheses Bond uncorr, corr. Bond uncorr. N{1) -C{2) 1. 396 (4) 1 .400 C{8)- H{1) 0.95(3) C (2) -N (3) 1. 376 (4) 1 .379 N(9) -H (2) 0. 9 2 (5) N (3) -C(4) 1. 351 (4) 1 .354 C(10) -H(3) 1.01 (5) C (4) -C<5) 1. 360 (4) 1 .363 C{10) -H(4) 1.02(7) C(5) -C{6) 1. 431 (5) 1 .434 C{10) -H{5) 1.02 (6) C (6) -N{1) 1. 4 07 (4) 1 .410 C{12) -H{6) 0.89 (6) C (4) -N (9) 1. 369 (4) 1 .372 C{12) -H(7) 0.92(8) N (9) -C{8) 1. 343(4) 1 .346 C{12) -H{8) 1.00 (6) C (8) -M(7) 1. 327 (4) 1 .330 C(14) -H(9) 0.92 (5) N (7] -C(5) 1. 392 (4) 1 .394 C(14) -H (10) 0. 89 (5) M (D -G{10) 1. 477 (5) 1 .477 C(14) -H(11) 1.07 (5) B (3) -C(12) 1. 474 (5) 1 .476 0(1). • -H(11) • 0.84 (4) -C(14) 1. 469 (5) 1 .471 0(1) * -H (12) ' 0.89 (6) C (2) -0(11) 1. 217 (4) 1 .218 0(2) * -H(21) « 0.90 (5) C (6' -0(13) 1. 218 (4) 1 .220 0(2) * -H (22) » 1.03 (8) 8 3 Table 25 Bond angles (deg.) with standard deviations i n parentheses a) Angles for the non-hydrogen atoms and H(1) and H(2) Bond Angle Bond Angle N (1) -C (2) -N(3) 117. 2(3) C (2) - N (3) -C(12) 119. 2(3) c (2; -N (3) -C(4) 118. 6(3} C (4) -N (3) -C(12) 121. 9(3) N 13) -C (4] -C(5) 123. 8(3) N (3) -C (4) -N(9) 128.4(3) C(4) -C (5) -C(6) 122. 3(3) N (7) -C (5) -C(6) 131.0(3) C(5) -C (6] -N(1) 111. 0(3) C(5) -C(6) -0(13) 126.7(3) C(6) — N (1] -C(2) 127. 0(3) N{1) -C (6) -0(13) 122. 4(3) c(u; -c (5; -N(7) 106. 8(3) C{6) -N (1) -C(10) 117. 6(3) C (5) -N (7] -C(8) 107. 9(3) C (2) -N(1) -C(10) 115. 3 (3) N (7) -C(8) -N(9) 109. 6(3) C(5) -N (7) -C(14) 125. 8(3) C{8] - H (9) -C(4) 107. 8(3) C (8) -N (7) -C(14) 126. 3(3) N (9j -C(4] -C(5) 107. 9(3} N (7) -C (8) -H{1) 123 (2) N {1) -C{2] -0(11} 120. 7(3) N (9) -C (8) -H(1) 127 (2) N (3) -C (2) -0 (11) 122. 0(3) C (8) -N (9) -H (2) 128 (2) C (4) -N (9) -H (2) 124 (2) b) Angles involving hydrogen atoms not attached d i r e c t l y to the fused r i n g system Bond Angle Bond Angle N(1)-C(10)-H (3) 105(3) H(6)-C(12)-H(8) 122(5) N ( 1) —C (1 0) — H (4) 108(4) H (7) -C (12) —H (8) 94(5) N(1)-C(10)-H(5) 112(3) N (7)-C (14)-H (9) 112(3) H (3)-C (10)-H (4) 111(4) N (7) -C (1 4) -H (10) 108(3) H(3)-C(10)-H(5) 111(4) N(7)-C (14)-H (11) 105(2} H(4)-C(10)-H(5) 109(5) H(9) -C (14) -H (10) 121(4) N (3) -C (12) —H (6) 110(4) H (9)-C (14)-H (11) 109(4) N(3)-C(12)-H(7) 113(5) H (10)-C (14)-H (1 1) 100(4} N(3)-C(12)-H(8) 106(3) H (11) • -0 ( 1) « - H (12) • 119(4) H(6) -C(12)-fl(7) 111(6) H(21) »-0 (2)'-H(22) » 105(5) RESULTS AND DISCUSSION 1,3,7-Trimethyl-2,6-dioxypurine hydrochloride dihydra te (caffeine hydrochloride dihydrate) contains a caffeine molecule protonated at N{9). The caffeine molecule i s hydrogen bonded to only one of the water molecules, by a strong N-H.,,0 hydrogen bond. Both water molecules are, however, hydrogen bonded to the chloride ion (0-H...C1). The atom numbering scheme can be seen in F i g . 11, except for the chloride ion C l and the water molecules, H (11) »-0 (1) *-H (12) ' and H (21) *-0 (2) »-H (22) *. The e f f e c t of protonation on the bond lengths between atoms i n the fused r i n g system i s somewhat d i f f i c u l t to determine. The i n i t i a l structure determination f o r caffeine (52) has f a i r l y inaccurate bond lengths, and modifications to the structure may have resulted i n the N (9) adduct studied by Shefter (53). Even so i t can be said that, i n terms of bond distances, a d i r e c t comparison indicates l i t t l e s i g n i f i c a n t difference between the protonated and non-protonated species. This might have been expected as Taylor (54) and Kistenmacher and Shigematsu (55) found p a r a l l e l r e s u l t s for adenine compounds. Fig. 12 does however i l l u s t r a t e one in t e r e s t i n g anomaly. An affect of protonation on compound (I) , i s o c a f f e i n e (56) , would be expected to be a lengthening of the C-N double bond. This i s indeed found i n (I I ) , methylguanine hydrobromide (59), but t h i s bond i s s t i l l shorter than the other C-N bonds. Protonation i n the caffeine system, i . e . from (III), c a f f e i n e : 5 - c h l o r o s a l i c y l i c acid adduct (53), also results i n 85 H / Ztf V1.299 (A) C ^1.34 C 8 — H || C — H CL /1.376 ^ C \ K / 1 - 3 9 \ \ CH3 CH3 (I, (II) CH, CH, . /. x / C - " " \1.343 ^ c ^ \ l . 3 2 7 II \ II \ .C H .C H V H (III) 'IV) F i g u r e 12 Bond lengths and representation of the imidazole r i n g for (I) I s o c a f f e i n e , (II) Methylguanine hydrobromide, (III) C a f f e i n e : S - c h l o r o s a l i c y l i c a c i d adduct, • and (IV) Caffeine hydrochloride dihydrate 86 (a, lengthening of the C-N double bond, but now, as shown i n (IV), t h i s study, a shortening of the N(7)-C(8) bond also occurs. , A s i m i l a r r e s u l t can be found i n another protonated [also at N (9) ] c a f f e i n e - l i k e derivative, 7-methylxanthine hydrochloride monohydrate (58) which has a N(7)-C{8) distance of 1.325 A and a C(8)-N(9) distance of 1.338 A. Such findings indicate that the simple pictures drawn in F i g . 12 are inadequate in representing the protonated species, and that considerable el e c t r o n i c rearrangement must be occurring close to the protonated centre. This rearrangement does not seem to transfer to the rest of the molecule judging by the s i m i l a r i t y between the remaining corresponding bond lengths i n the protonated and non-protonated species. For the angles, s i g n i f i c a n t changes do occur but only i n the imidazole r i n g , a s i t u a t i o n p a r a l l e l to that found by Kistenmacher and S o r r e l l (58) . Table 26 i l l u s t r a t e s the endocyclic imidazole bond angles f o r several purine derivatives. ( I l l ) caf eine adduct (53) , (V) theobromine (59) , (VI) 7-methyladenine dihydrochloride (60) , (VII) 7- methylxanthine hydrochloride (58) and (IV) t h i s study. Compounds (III) and (V) are unprotonated, while (IV) , (VI) , and (VII) are protonated at N(9) . The changes i n angles found on protonation are quite large, being up to 7.6° [ comparing N (9)-C (4)-C (5) i n (IV) and (V) J. Compounds (IV) and (VII) are very s i m i l a r , as i s to be expected since there should be l i t t l e e f f e c t on the imidazole ring due to the d i f f e r e n t substituents at N(1) and N(3) [hydrogen atoms f o r (VII) , methyl groups for (IV)] in the pyrimidine ring. 87 Table 26 A comparison o f the e n d o c y c l i c imidazole bond an g l e s f o r s e v e r a l p u r i n e d e r i v a t i v e s Atoms Angles (IJI) (V) (VI) (VII) (IV) C(4)-C{5)-N(7) 106.0 106. 1 105.9 106.6 106.8 C(5)-N(7)-C(8) 105.4 105.0 107.3 107.5 107.9 N(7)-C(8)-N(9) 113.6 114. 2 110.7 110.3 109.6 C(8) -N (?) -C{4) 103.4 103.2 108.1 107.5 107.8 N(9) -C(4)-C(5) 111.6 1 15.5 108. 1 108.2 107.9 (III) C a f f e i n e : 5 - c h l o r o s a l i c y l i c a c i d adduct (V) Theobromine (VI) 7-Hethyladenine d i h y d r o c h l o r i d e (VII) 7-Methylxanthine h y d r o c h l o r i d e (IV) C a f f e i n e h y d r o c h l o r i d e d i h y d r a t e , t h i s study. 88 The mean planes c a l c u l a t e d f o r c a f f e i n e h y d r o c h l o r i d e i n d i c a t e t h a t the protonated c a f f e i n e molecule i s e s s e n t i a l l y p l a n a r . a plane c a l c u l a t e d u s i n g a l l the non-hydrogen atoms i n the c a f f e i n e molecule, and H{1) and H(2), i n d i c a t e s a © maximum d e v i a t i o n of only 0.19 a £ f or C(12) ]. For the fused r i n g atoms on l y , a comparison of the d e v i a t i o n s found with t h e i r standard d e v i a t i o n s shows the six-membered r i n g to be puckered, and the five-membered r i n g to be planar w i t h i n experimental e r r o r . Table 27 gives the mean pla n e s and dis t a n c e s ' f r o m the atoms to these planes. C a f f e i n e h y d r o c h l o r i d e , l i k e s e v e r a l other purine type d e r i v a t i v e s (61) e.g. hypoxanthine h y d r o c h l o r i d e monohydrate (Table 27), i s a l s o bent along the C(4)-C{5) bond, the angle between the i m i d a z o l e and the p y r i m i d i n e r i n g f o r c a f f e i n e h y d r o c h l o r i d e b e ing about 0.85°. The c r y s t a l c o n t a i n s two types of hydrogen bonds. 0- H. ..C1 hydrogen bonds occur between the water molecules and the c h l o r i d e i o n , and N-H...0 hydrogen bonds occur between the r i n g hydrogen H(2) and the water oxygen atom 0 ( 1 ) ' . The hydrogen bond between H(2) and 0 ( 1 ) ' i s very s t r o n g H...0, I . 76(5} a, N-H.,,0 an g l e , 176(4)°, and i s probably due t o the very a c i d i c nature of t h i s proton. The p r o p o s i t i o n t h a t N- H...0 hydrogen bonding e x i s t s between the c a f f e i n e molecule and one of the water molecules i s f u r t h e r supported by the water H-O-H angles. For water 1, s t r o n g l y hydrogen bonded, the angle i s d i s t o r t e d , being 119(5)°, whereas f o r water 2 the angle i s c l o s e to normal, being 105(5)°. Table 28 gives the d i s t a n c e s and angles f o r the p o s t u l a t e d i n t e r m o l e c u l a r 89 f a b l e 27 Equations of s e l e c t e d weighted l e a s t - s q u a r e s mean planes with d e v i a t i o n s (A) of the atoms from the planes 1) C a l c u l a t e d using N ( 1 ) ,8 (3) ,C (2) ,C (4) ,C (5) , and C (6) 0.833X + 0.487Y * 0.264Z = 7.296.* Hypoxanthine C a f f e i n e h y d r o c h l o r i d e monohydrate h y d r o c h l o r i d e d i h y d r a t e N(1) 0.0013 -0. 0148(32) N(3) -0.0006 -0.0145(32) C(2) -0.001 1 0.0334(38) C{4) 0.0020 -0.0020 (35) C(5) -0.0017 0.0123 (36) C(6) 0.0001 -0.0015 (38) other atoms N(7) -0.0183 0. 0288 (31) C{8) -0.0297 0.0279 (38) 8(9) -0.0111 0.0051 (33) 2) C a l c u l a t e d using N (7) ,N (9) ,C(4) ,C (5) ,C (8) . 0.825X + 0.493Y • 0.275Z = 7.318 N(7) -0.0010(30) N(9) -0.0013(33) C(4) 0.0006(35) C(5) 0.0004(36) C(8) 0.0020(37) Angle between planes 1) and 2) f o r the c a f f e i n e molecule i s o equal t o 0.85 o * X,Y, and 2 are orthogonal c o o r d i n a t e s i n A w.r.t. a,b,c*. 9 0 Table 28 Distances and angles i n the interatomic contacts of the type D-H...A o © © D H A D-H (A) H. ..A (A) D. . .A (A) D-H...A (*) 0(1) • H(11) Cl 0,. 84 (8) 2 .32 (5) 3. 12(1) 162 (4) 0(1} • B{12) Cl 0. 89 (6) 2 .23(6} 3. 12(1} 172 (5) 0(2) ». H(21) C l 0. 90(5) 2 .37(5) 3. 24(1) 167(4) 0(2)' H (22) Cl 1. 0 3(9) 2 .22 (8) 3. 24(1) 169 (6) N(9) H{2) 0(1) « 0. 92(5} 1 .76(5) 2. 684(4) 176 (4) * indicates water molecules 91 Fiqure 13 A stereoscopic diaqram of the u n i t - c e l l viewed down b, showinq the postulated hydroqen bondinq as dashed l i n e s . bonding for t h i s compound. A stereoview of the packing of the molecules i n the c r y s t a l l a t t i c e , and . the postulated intermolecular hydrogen bonding can be seen i n F i g . 13. In t h e s e - . c r y s t a l s , unlike many other purine type d e r i v a t i v e s , there appears to be no s i g n i f i c a n t stacking of layers of molecules and hence no s i g n i f i c a n t dipole overlap of hetero C-0 and C-N bonds contributing to the s t a b i l i t y of the c r y s t a l - The c r y s t a l s t r u c t u r e determination was useful because i t allowed for a c o r r e l a t i o n between the proton and nitroqen hyperfine couplinq tensors, determined from the ENDOR spectroscopy on the X - i r r a d i a t e d c r y s t a l , and the molecular structure (62) . 92 CHAPTER 6 CRYSTAL AND MOLECULAR STRUCTURE OF 1-ACETYL-3-BENZAflIDG-2-KET0-4-(2,3,4,6-TETRA-O-ACETYL- £-D-GLUC0PYRAN0SYL0XY ) -a 3-PYRR0LINE INTRODUCTION From reactions of glycosyl bromide with 2-phenyloxazol- 5-one (63) a P-glycoside considered to be 3-benzamido-1- benzoyl-2-keto-4~ (2, 3,4,6-tetr a-O-acetyl-P-D-glucopyranosyl- oxy)-A 3-pyrroline was produced. On refluxing with acetic anhydride and sodium acetate in pyridine, one benzoate group was exchanged for an acetate group giving 1-acetyl-3-benzamido-2-keto-4-(2,3,4,6-tetra-0-acetyl-p-D- glucopyranosyloxy)-£ 3-pyrroline.,The c r y s t a l structure was undertaken to v e r i f y the i n i t i a l assignment of structure based upon mass spectrum, n.m.r., and chemical data. EXPERIMENTAL Re c r y s t a l l i z a t i o n of 1-acetyl-3-benzamido-2-keto-4- (2,3, 4, 6-tetr a- O-acet yl-fi-D-gl ucopyranosyloxy)-^ 3- pyrroline from hexane-acetone gave colourless rectangular c r y s t a l s . The c r y s t a l chosen for study was mounted with b p a r a l l e l to the goniostat axis and had dimensions of ca 0.20 X 0.20 X 0.07 mm. U n i t - c e l l and space group data were obtained from f i l m and diffractometer measurements. The u n i t - c e l l parameters were refined by a least-squares treatment of sin 2© values f o r 19 r e f l e c t i o n s measured on a diffractometer with Cu KoC r a d i a t i o n . Crystal Data Ca^,H3©N10ii , M = 590.54 , monoclinic, © a = 19.629(5), b = 7. 504 (2), c = 9.830 (2) A, £= 90.53 (2)°, 0 = 1447.8 (6) A 3, Z = 2, O c = 1.35(1) gem-3, F{000) = 620 © (20°C, Cu K « , A= 1.5418 A, /x= 9.4 cm"1) . Absent r e f l e c t i o n s OkO, k * 2n define the space group £2^ (C|, No. 4). I n t e n s i t i e s were measured on a Datex-automated General E l e c t r i c XED 6 diffractometer, with a s c i n t i l l a t i o n counter, Cu Kot (nickel f i l t e r and pulse height analyser) , and a 9-29 scan at 2° min - 1 over a range of (1.80 * 0.86 tan 9) degrees i n 29, with 10 s background counts being measured at each end of the scan. Data were measured to 29 = 120° (minimum o interplanar spacing 0.89 A) . A check r e f l e c t i o n was monitored every 40 r e f l e c t i o n s throughout the data c o l l e c t i o n . The greatest deviation from the i n i t i a l value was -4.5% and the f i n a l i n t e n s i t y was 1.04 times the i n i t i a l value. Lorentz and po l a r i z a t i o n corrections were applied, and the structure amplitudes were derived. No absorption correction was applied due to the low value of /*.. Of the 2336 independent r e f l e c t i o n s measured, 49 8 had i n t e n s i t i e s less than 3«-(I) above background where o*2 (I) = S + B * (0.05S) 2 with S = scan count and B = time averaged background count. These r e f l e c t i o n s were c l a s s i f i e d as unobserved and given zero weight i n the refinement. STBOCTURE ANALYSIS As previously demonstrated i n chapter 5, methods are available f o r the s t a t i s t i c a l determination of the phases of the structure factors d i r e c t l y from the structure amplitudes. The basis f o r these d i r e c t methods was discussed i n chapter 5 for the centrosymmetric case i n which the phases could only have values of 0 or IT (corresponding to • or - signs). When the space group i s non-centrosymmetric the phases can have general values and cannot always be added together numerically. Fortunately J. Karle and I. Karle (64) have been 95 able to generalise the procedure already i l l u s t r a t e d i n the previous structure, to include the acentric structure. The procedure i s very s i m i l a r to that for c e n t r i c structures; normalised structure factors were calculated and the 37 3 r e f l e c t i o n s with JEJ > 1.35 were chosen as the basis f o r the s o l u t i o n . Of these the 70 r e f l e c t i o n s with the l a r g e s t J E j's were' searched f o r ,̂-2 relationships and a manual expansion was attempted. The o r i g i n i n P2 ( could be defined by the r e f l e c t i o n s 13 0 -6, 1 0 - 9 and 3 11 which were given phases of zero. The manual expansion indicated that i f any three r e f l e c t i o n s cut of a group of s i x prominent r e f l e c t i o n s were given symbols then the phases of the majority of the 70 largest r e f l e c t i o n s could be determined i n terms of these assigned symbols. After several unsuccessful runs using a l l 373 r e f l e c t i o n s the combination of o r i g i n , enantimorph f i x i n g , and symbol r e f l e c t i o n s given in Table 29 produced sa t i s f a c t o r y r e s u l t s . That i s the solution involved using the previously mentioned o r i g i n r e f l e c t i o n s , f i x i n g the enantimorph by allowing the phase of r e f l e c t i o n 1 4 4 to only vary between 0 and 500 mc, and giving the r e f l e c t i o n s 5 6-1 and 4 1 1 various combinations of the phases 0, 250, 500, and 750 mc, leading to sixteen (2*) sets as indicated i n Table 30. These sets were used as input to a computer program which determines phases using the tangent formula (given on page 98) of Karle and Hauptman (ref 65 and 66) , as the simple Sayre relationship cannot be used for non-centrosymmetric structures. , 96 Table 29 Basic s t a r t i n g set of r e f l e c t i o n s for 1-Acetyl-3-benzamido-2-keto-4-(2,3,4,6-tetra-O-acetyl- P-D-glucopyranosyloxy) - & 3-pyrroline h k * i n phase(mc) 13 0 -6 3. 3 0 0 ' 1 0 -9 2.85 0 * o r i g i n 3 1 1 2.72 0 - 1 4 4 2. 49 2 50 5 6 -1 2. 47 a 4 1 1 2.67 b 97 Table 30 Besults for the sixteen s t a r t i n g sets i n the phase determining procedure Set a (me) b (mc) t ©* Ek N* 1 0 0 0.52 116 0. 33 328 2 0 250 0.78 226 0.28 349 3 0 500 0.80 227 0.27 348 4 0 750 0.65 166 0.31 343 5 250 0 0.80 224 0.30 344 6 250 250 0.56 121 0.32 340 7 2 50 500 0.65 152 0.32 343 8 250 750 0.55 119 0.32 326 9 500 0 0.79 223 0. 29 345 10 500 250 0.60 141 0.31 336 1 1 500 500 0.59 169 0. 24 358 12 50 0 750 0.56 115 0.37 324 13 750 0 0.64 159 0. 32 339 14 750 250 0.56 125 0.33 333 15 750 50 0 0.72 200 0. 29 343 16 750 750 0.58 1 60 0.24 349 * Total N = 373 98 . § l E K E H . K l s i n ( ^ < t > H . K ) tan Each r e f l e c t i o n i s examined i n descending order of |E|, and a phase i s determined for i t from the previously known phases of pairs of ̂ -2 related r e f l e c t i o n s . The phases calculated i n the f i r s t cycle can then be used i n the second cycle to give more and better approximations to the correct phases. This process i s continued u n t i l most of the phases have been determined and there i s l i t t l e change i n the values of the calculated phases from cycle to c y c l e . Before a new phase was accepted various c r i t e r i a must be s a t i s f i e d ; the consistencies t H and o< of the new phase had to exceed the a r b i t r a r y values 0.25 and 4.0 respectively, where J&2 * B2 t„ = ol = JE I .V f l 2 + B2 H J i K I . I I u . K l I f a new phase angle s a t i s f i e s these c r i t e r i a , i t i s used i n the determination of the phases of other r e f l e c t i o n s i n the following c y c l e * : I f the phase angle i n two successive cycles i s di f f e r e n t by 250 mc, then the phase i s considered to be unknown i n the following cycle and therefore cannot be used i n the determination of other phases, but i t i s then recalculated in the next cycle. The f i n a l values of t, and the r e l i a b i l i t y index RKarle (Rk), given by £ | |E H| obs-|EM1 calc | Rk = — I 1 |E M|obs where l E M j c a l c are derived from use of the tangent formula, f o r the sixteen s t a r t i n g sets, are given i n Table 30. Both sets 11 and 16 looked promising but the E map was 99 calculated from set 11 as t h i s had the greater number of phases determined (N). The E map based on set 11 gave positions for 36 of the 42 heavy atoms i n i t s top 50 peaks. Fixing the y co-ordinate of atom 0(1) at 0.8300 to define the o r i g i n in the space group JP2t , and r e f i n i n g the remaining p o s i t i o n a l and i s o t r o p i c thermal parameters f o r these 3 6 atoms, gave an B factor of 0.230. A difference Fourier revealed the positions of the remaining heavy atoms and two further cycles of fu l l - m a t r i x least-squares refinement with anisotropic thermal parameters for a l l the non-hydrogen atoms reduced B to 0.090. A difference Fourier at t h i s stage p o s i t i v e l y revealed the positions of only 17 of the 30 hydrogen atoms. The remaining hydrogen atoms were given calculated positions. Due to the excessive expense and the nature of the problem, the refinement was concluded a f t e r two more cycles, varying only the heavy atom p o s i t i o n a l parameters and anisotropic temperature f a c t o r s , but including the hydrogen atom positions and i s o t r o p i c temperature o factors, 0 = 63 X 10~ 3 A z, i n the refinement. The f i n a l E value was 0.079 for 1838 r e f l e c t i o n s with I > 3«-(i) . The atomic scattering factors and anomalous scattering correction for the C, N, and O atoms were taken from ref 14 and ref 15 respectively, and the scattering f a c t o r s f o r the hydrogen atoms from ref 39. The weighting scheme: w = 1/o-2(F) where tr2 (F) i s derived from the previously defined <r2 (I) gave uniform average values of w(Fo-Fc) 2 over ranges of i£oj and was employed in the f i n a l stages of refinement. 100 An attempt was made to determine the absolute configuration of the molecule through anomalous scattering of the non-hydrogen atoms. The enantimorph i n Table 31, (A), and that generated by changing y to -y, (B), were both refined and Hamilton's test (67) applied to the r e s u l t i n g R factor r a t i o s . Unfortunately neither (A) nor (B) was proved to be s i g n i f i c a n t l y more correct. (A) was therefore chosen i n view of the chemical evidence. The f i n a l p o s i t i o n a l and thermal parameters appear i n Tables 31 and 32 respectively. Measured and calculated structure factors are available from the U.B.C. Library. RESULTS AMD DISCUSSION Fi g . 14 shows a general stereoview of 1-acetyl-3-benz- amido-2-keto-4-(2,3,4,6-tetra-O-acety1-P-D-glucopyranosyl- oxy)-& 3-pyrroline, with the crystallographic numbering scheme. Complete l i s t s of bond lengths and angles are given i n Tables 33 and 34 respectively. As expected the s i x - membered rin g i s in tbe chair conformation with equatorial substituents at positions 2, 3, 4, and 5. Table 35 gives a weighted least-squares mean plane for t h i s r i n g and i t s molecular geometry i s compared with s i m i l a r compounds, 2,3,4,6- tetra-O-acetyl- l-cyano-p-fi-galactopyranose (68) and tetra-0-acetyl-<*-D-mann6pyranosyl chloride (69) , in Table 36. The average values f o r the bond lengths [C-C, 1.53(2) ; C-0, o 1.45(2) A], bond angles [112(3)°] and range of torsion angles [ 51.7 (7)-69.8 (7) ° ] are very close to those given by Kim and Jeffrey (70) as t y p i c a l of other pyranose rings. The 0-acetyl groups attached to C(2), C (3) , C(4), and 10 1 Figure 1 4 (A) A general stereoview of the molecule showing the c r y s t a l l o g r a p h i c numbering scheme OAc H BzN A c O N—Ac Figure 14(B) Diagram of the conventional chemical structure 102 Table 3J F i n a l p o s i t i o n a l parameters ( f r a c t i o n a l x 10*, H x 10 3) with estimated standard deviations i n parentheses Atom X 1 2 0 (1) 2462 ( 3) 830 0 6742 [ 5) 0 (2) 24 38< 3) 8305 (10) 3 798 ( 5) 0 (3) 3746 ( 3) 6996 (11) 2761 I 5) 0 (4) 4063( 3) 3691 (12) 3854 ( 6) 0 (5) 3194 ( 3) 5947 (10) 6654 ( 5} 0 (6) 3368 ( 3) 2618 (11) 7897 ( [ 6) 0 (7) 2739 ( **) 11172 (13) 4098< [ 9) 0 (8) 3049 { 5) 5920 (16) 1173 i [ 7) 0 (9) 5138{ 4) 420 3 (16) 4410 [ 8) 0 (10) 4195( 5) 2094 (28) 9253 (10) 0 (2») 742 ( 3) 8638 (10) 10065 [ 5) 0 (3') 1556 ( 3) 3482 (11) 100671 [ 5) 0 (4») 1241 ( 3) 10214 (10} 5670 j [ 5) » d') 1500 ( 3) 6368 (11) 9479 | [ 6) N (2«) 1378 ( 3) 10750 (11) 7937| [ 6) c (1) 2696 ( 4) 6858 (13) 5925 1 [ 7) c (2) 3000 ( 4) 7716 (12) 4623< [ 7) c (3) 3336 ( *») 6195 (14) 3829 | [ 8) c (4) 3818 ( <0 5135 (13) 4 7061 [ 8) c (5) 3423 ( *») 4384 (14) 5914 ( 8) c (6) 3842 ( 4) 3291 (15) 6881 | [ 8) c (7) 2370( 5) 10137 (16) 3593 [ 9) c (8) 1794 ( 5) 10462 (15) 2640| [ 9) c (9) 3557 { 6) 663 9 (16) 1459 | [ 8) c (10) 4101 ( 6) 7327 (21) 504 | [10) c (11) 4714 ( 5) 3471 (18) 3740 | [ 8) c (12) 4883 ( 6) 2091 (23) 2708( [ 8) c (13) 3622 ( 5) 2117 (19) 9044 i [11) c (14) 3068 { 5) 1436 (20) 9977 JO) c (2') 1204 ( 4) 8038 (13) 93 77 L 7) c (3») 1570 ( **) 8985 (13) 8274 | 7) c (4») 2019 ( <0 7866 (13) 7753 | 7) c (5») 2012 ( 4) 6 118 (13) 8459i 7) c [6«) 1296 ( <*) 492 9 (15) 10268 i [ 7) c ( 7 f ) 802 ( 5} 5234 (16) 11396i 8) Ci [8') 1183( 4) 11165 (15) 6638 8) c [9*) 900 ( ") 13067 (13) 6494 1 8) c [10') 1083 ( 5) 14088 (15) 5355 < 8) c (11».) 820 ( 5) 1580 5 (16) 52 14 ( 10) c (12«) 369 ( 5) 16449 (16) 6158 < 11) c (13*) 174 ( 5) 15410 (16) 72 85< 9) c (14») 445( <*) 13764 (14) 74 39 i 9) H (1) 229 615 555 H (2) 341 844 486 H (3) 293 544 324 H (4) 425 590 502 103 Table 31 (continued) Atom X Y Z H(5) 302 357 543 H(6A) 431 326 707 H (6B) * 409 216 633 H(8A) * 164 924 212 H (8B) * 135 1101 316 H(8C) * 195 1142 185 H (10A) 449 780 127 H(10B) * 432 619 -4 H (10C) * 387 820 -24 fl (12A) * 442 127 248 H (12B) 474 217 190 H(12C) 544 172 269 H (14A) 260 111 905 H (1 4B) * 317 2 1025 R (14C) * 306 218 1092 H(5'A) 246 551 858 H(5«B) * 188 503 776 H{7»A) 51 600 1147 H(7'B) 32 537 1074 H (7»C) 105 525 221 H(10*)* 142 1354 459 H (11«) 99 1613 424 H (12') * 16 1782 604 H (13«) -12 1600 826 H(14')* 31 1293 832 H (N2*) 106 1000 795 * calculated positions 1 0 4 Table 32 F i n a l thermal parameters and t h e i r standard d e v i a t i o n s i n parentheses A n i s o t r o p i c thermal parameters (U;\ x 10 3 A 2) Atom I n . £* 0 (1) 71 [ 3) 35{ 3) 48 ( 3) 1 I 3) 101 [ 2) -4( 3 0 (2) 71 [ ft) 40 { ft) 43 ( 3) 3 [ 3) -3 ( 2) 1 ( 3 0 (3) 71 ( 4) 68 { ft) 50 ( 3) -3 | 3) 4 [ 3) 1( 3 0 ;ft) 64| [ ft) 77( 5) 67 [ 3) 13 ( ft) 0 ( 3) -14( 4 0 (5) 62 ( 3) 51 { ft) 40 ( 3) 104 [ 3) -2 ( 2) -5( 3 0 [6) 69 [ ft) 68 ( 5) 78 ( ft) -1 [ ft) -11 ( 3) 17 ( 4 0 (7) 123 ( 6) 44 ( ft) 127 ( 6} -211 [ 5) -2 ft ( 5) 14( 5 0 (8) 133| [ 7) 147( 9) 49 [ ft) -8 ( 7) -13 ( ft) -10 { 5 0 (9) 75 ( 5) 145( 9) 109 ( 6) 29 | [ 5) 7 ( 4) - 17( 6 0 (10) 86 [ 6) 414 ( 25) 127 ( 7) -6 ( 9) -10 ( 5) 136( 12 0 (2«) 85 [ ft) 45 ( ft) 54 ( 3) IT j [ 3) 18 [ 3) 3( 3 0 ( 3 « ) 85| [ ft) 35 { ft) 62 ( 3) 15 ( 3) 5 ( 3) 6( 3 0 («*•) 106 ( 5) 44 { ft) 43 ( 3) 3j [ 4) -2 ( 3) 3( 3 N (1*) 67| [ ft) 29( ft) 50 ( ft) 12 ( 3) 2 ( 3) 0 ( 3 N (2*) 73 ( ft) 34 ( ft) 49 ( ft) 2| [• ft) -3 ( 3) 6( 3 C (1) 50 [ ft) 50{ 5) 40 ( 4) 0 ( ft) -5 ( 3) ft( 4 C (2) 45 ( ft) 41 ( 5) 46 ( 4) -9 [ ft) -2 ( 3) 5( 4 c (3) 55 ( 5) 48 | 5) 55 ( ft) -3 [ ft) 6 [ ft) 6( 4 c (4) 54 [ 5) 40 { 5) 55 ( ft) 3 ( ft) 2 ( ft) -9 ( 4 c (5) 56 ( 5) 50 i 5) 55 ( ft) 114 [ ft) 4 ( ft) 1 ( 4 c (6) 55| [ 5) 68 { 7) 71 ( 5) 15 ( 5) 5 ( ft) 12( 5 c (7) 96 ( 7) 45 { °) 52 ( 5) -1\ [ 6) 7, ( 5) 20( 5 c (8) 103 i [ 7) 55 ( 6) 61 ( 5) 15 ( 6) -8 ( 5) 10{ 5 c (9) 87 ( 7) 73 { 8) 45 ( 5) 6 [ 6) -9 ( 5) -8{ 5 c (10) 106 4 ( 8) 125( 11) 64 (•• 6) 26 ( 8) 19 ( 6) 14( 7 c (11) 74 ( 7) 94 | 8) 45 ( 5) 261 [ 7) -5 ( ft) ~ 1 ( 5 c (12) 114 [ 9 ) 181 ( 13) 41 ( 5) 69 ( 9) -7 ( 5) -27( 7 c (13) 48 ( 6) 110 { 9) 92 ( 7) 15^ [ 6) -18 ( 5) 24( 7 c (14) 90 [ 7) 109 ( 10) 84 ( 7) 4 ( 7) 0 ( 6) 34( 7 c (2«) 60 ( 5) 42 | 5) 43 (ft) -9 j [ ft) -1 [ ft) - ft( 4 c (3*) 68 t 5} 38 ( 5) 37 ( ft) 15 ( ft) -14 ( ft) 2{ 4 c (4») 54 ( ft) 31 { 5) 48 ( ft) 0 [ ft) 2 ( ft) ft( 4 c (5*) 58j [ 5) 38 ( 5) 48 ( 4) 8 ( ft) 3 ( ft) -5( 4 c (6«) 77 ( 6) 43 | 5) 39 ( 4) Oi [ 5) -5 ( ft) 8( 4 c (7') 971 [ 7) 65( 6) 49 ( 5) 7 ( 6) 14 ( 5) 10{ 5 c (8«) 76 ( 6) 49 | 5) 43 ( 5) -11^ ( 5) -6 (ft) 7( 5 c (9') 61 j i 5) 38 ( 5) 61 ( 5) -5 ( ft) -14 ( ft) 8 ( 4 c (10*) 76 ( 6) 5.5 { 6) 49 ( 4) -9 < [ 5) -14 ( ft) 2( 4 c (11*) 91 ( 7) 48 j 6) 76 ( 6) -2 ( 6) -16 ( 6) 12{ 5 c (12*) 86 ( 7) 42 ( 6) 99 ( 8) 0 ( 5) -36 ( 6) 6( 6 c (13») 76 i [ 6) 55( 7) 74 ( 6) 5 ( 5) -13 ( 5) -1 < 5 c (14*) 60 ( 5) 45 j 6) 66 { 5) 8* [ 5) -4 ( ft) -4* 5 ° z * A l l H atoms had i s o t r o p i c thermal parameters U = 63 X 10- 3 A 105 Table 33 o Bond l e n g t h s (A) »ith standard d e v i a t i o n s i n parentheses Bond Length (A) Bond Length (A) C { 1 ) - C { 2 ) 1 . 5 5 ( 1 ) C ( 1 ) - 0 ( 1 ) 1 . 4 3 ( 1 ) C ( 2 ) - C ( 3 ) 1 . 5 4 ( 1 ) 0 ( 1 ) - C ( 4 * ) 1 . 3 7 ( 1 ) C ( 3 ) - c m 1 . 5 0 ( 1 ) C ( 4 » ) -C ( 5 » ) 1 . 4 8 ( 1 ) C ( 4 ) - C { 5 ) 1 . 5 3 ( 1 ) C ( 5 « ) - N ( 1 » ) 1 . 4 4 ( 1 ) C ( 5 ) - 0 ( 5 ) 1 . 4 5 ( 1 ) N ( T ) - C ( 2 » ) 1 . 3 9 ( 1 ) 0 ( 5 ) - C ( 1 ) 1 . 3 9 ( 1 ) C (2») - C { 3 ' ) 1 . 4 9 ( 1 ) C ( 5 ) - C { 6 ) 1 . 5 0 ( 1 ) c ( 3 « ) -C ( 4 » ) 1 - 3 2 ( 1 ) C ( 2 ) - 0 ( 2 ) 1 . 4 3 ( 1 ) N ( 1 *) -C ( 6 » ) 1 . 3 9 ( 1) C ( 3 ) - 0 ( 3 ) 1 . 4 6 ( 1 ) C ( 6 » ) - 0 ( 3 ») 1 . 2 2 ( 1 ) c ( 4 ) - 0 ( 4 ) 1 . 4 5 ( 1 ) c ( 6 « ) -C ( 7 « ) 1 . 5 0 ( 1 ) C ( 6 ) - 0 ( 6 ) 1 . 4 6 ( 1 ) c ( 2 « ) - 0 { 2 » ) 1 . 2 2 ( 1 } 0 ( 2 ) - C ( 7 ) 1 . 4 0 ( 1 ) c ( 3 « ) - N { 2 « ) 1 . 4 2 ( 1 ) 0 ( 3 ) - C ( 9 ) 1 . 3 6 ( 1 ) N ( 2 « ) - C ( 8 « ) 1 . 3 7 ( 1 ) 0 ( 4 ) - C ( 1 1 ) 1 . 2 9 ( 1 ) c ( 8 » ) - 0 ( 4 * ) 1 . 2 0 ( 1 ) 0 ( 5 ) - C ( 1 3 ) 1 . 2 9 ( 1 ) c ( 8 » ) -C ( 9 » ) 1 . 5 4 ( 1 ) C { 7 ) - 0 ( 7 ) 1 . 1 7 ( 1 ) c ( 9 » ) -C ( 1 0 » ) 1 . 4 1 ( 1 ) C ( 9 ) - 0 ( 8 ) 1 . 1 7 ( 1 ) c ( 1 0 ' ) - C ( 1 1 » ) 1 - 3 9 ( 1 ) C ( V I) - 0 ( 9 ) 1 . .19 (1) c ( 1 1 ' ) - C ( 1 2 » ) 1 . 3 8 ( 1 ) C ( 1 3 ) - 0 ( 1 0 ) 1 . 1 4 ( 1 ) c ( 1 2 ' ) - C { 1 3 » ) 1 . 4 1 ( 1 ) C ( 7 ) - C ( 8 ) 1 . 4 8 ( 1 ) c < 1 3 « ) - C ( 1 4 « ) 1 . 3 5 ( 1 ) C ( 9 ] - C { 1 0 ) 1 . 52 ( 1 ) c ( 1 4 « ) - C { 9 * ) 1 . 4 0 ( 1 ) C ( 1 1 ) - C ( 1 2 ) 1 . 4 9 ( 1 ) c ( 1 3 ) -C ( 1 4 ) 1- 5 2 ( 1 ) 106 T a b l e 34 Bond angles (deg.) with standard d e v i a t i o n s i n parentheses Bonds Angles Bonds Angle C ( 1 ) - C ( 2 ) - C { 3 ) 1 0 6 . 3 ( 6 ) 0 ( 1 ) - C ( 1 ) - C { 2 ) 1 0 6 . 1 ( 6 ) C { 2 ) - C ( 3 ) - C { 4 ) 1 1 1 . 9 ( 6 ) 0 ( 1 ) - C ( 1 } - 0 ( 5 ) 1 0 8 . 2 | 5 ) C ( 3 ) - C ( 4 ) - C { 5 ) 1 0 8 . 5 ( 6 ) C ( 1 ) - 0 ( 1 ) - C ( 4 « ) 1 1 6 . 1 | 6 ) C ( 4 ) - C ( 5 ) - 0 ( 5 ) 1 1 4 . 4 ( 6 ) 0 ( 1 ) - C ( 4 « ) - C ( 5 » ) 1 2 4 . 0 < 7 ) C ( 5 ) - 0 ( 5 } - C ( 1 ) 1 1 1 . 0 ( 5 ) 0 ( 1 ) - C ( 4 » ) - C ( 3 * ) 1 2 4 . 1 I 7 ) 0 ( 5 ) - C ( 1 ) - C { 2 ) 1 1 0 . 8 [ 6 ) c ( 4 ' ) - C { 5 ' ) - N ( 1 « ) 1 0 2 . 7 { 6 ) C { 1 ) - C ( 2 ) - 0 ( 2 ) 1 0 7 . 2 ( 5 ) c ( 5 « ) - N ( 1 » ) - C { 2 » ) 1 1 1 . 3 ( 6 ) C ( 3 ) - C ( 2 ) - 0 ( 2 ) 1 0 5 . 9 ( 6 ) N ( 1 ' ) - C ( 2 » ) - C ( 3 » ) 1 0 6 . 2 < 7 ) C ( 2 ) - C ( 3 ) - 0 ( 3 ) 1 0 7 . 6 1 7 ) c ( 2 « ) - C ( 3 » ) - C ( 4 « ) 1 0 7 . 9 { 7 ) C ( 4 ] - C { 3 ) - 0 ( 3 ) 1 0 6 . 3 [ 6 ) c ( 3 ' ) - C ( 4 » ) - C ( 5 » ) 1 1 1 . 8 | 6 ) C ( 3 ) - C ( 4 ) - 0 ( 4 ) 1 0 5 . 9 [ 6 ) c ( 5 « ) - N ( 1 ' ) - C ( 6 ' } 1 1 9 . 6 ( 7 ) C { 5 ) - C ( 4 ) - 0 ( 4 ) 1 1 0 . 2 ( 7 ) c ( 2 » ) - N ( 1 » ) - C ( 6 ' } 1 2 8 . 3 ( 7 ) C ( 4 ) - C ( 5 ) - C ( 6 ) 1 1 4 . 4 ( 6 ) N ( 1 » ) - C ( 6 » ) - 0 ( 3 * ) 1 1 8 . 6 ( 7 ) 0 ( 5 ] - C ( 5 ) - C { 6 ) 1 0 7 . 1 ( 6 ) ( 1 * ) - C ( 6 « ) - C ( 7 » ) 1 1 9 . 1 { 8 ) C ( 5 ) - C ( 6 ) - 0 ( 6 ) 1 0 5 . 9 [ 6 ) 0 ( 3 * ) - C ( 6 * ) - C ( 7 » ) 1 2 2 . 1 | 8 ) C ( 2 ) - 0 ( 2 ) - C ( 7 ) 1 1 7 . 2 ( 7 ) N ( 1 * ) - C ( 2 * ) - 0 ( 2 « ) 1 2 7 . 4 ( 7 ) C ( 3 ) - 0 ( 3 ) - C ( 9 ) 1 1 6 . 7 ( 7 ) C ( 3 » ) - C ( 2 » ) - 0 { 2 » ) 1 2 6 . 4 ^ 8) C ( 4 ) - 0 ( 4 ) - C ( 1 1 ) 1 1 8 . 5 ( 8 ) c ( 2 « ) - C ( 3 « ) - M ( 2 » ) 1 1 9 . 2 ( 7 ) c ( 6 ; - 0 ( 6 ) - C ( 1 3 ) 1 1 7 . 2 ( 7 ) c ( 4 « ) - C { 3 * } - N ( 2 « ) 1 3 2 . 8 { 8 ) 0 ( 2 ] - C ( 7 ) - C ( 8 ) 1 0 8 . 9 ( 8 ) c ( 3 * ) - N ( 2 , ) - C ( 8 « ) 1 2 0 . 3 { 7 ) 0 ( 3 ] - C { 9 ) - C { 1 0 ) 1 0 9 . 2 ( 9 ) H ( 2 » ) - C ( 8 > ) - 0 ( 4 » ) 1 2 5 . 4 ( 9 ) o ( 4 ; - C ( 1 1 ) - C { 1 2 ) 1 1 2 ( 1 ) N ( 2 » ) - C ( 8 F ) - C ( 9 » ) 1 1 3 . 3 ( 8 ) 0 ( 5 ] - C ( 1 3 ) - C { 1 4 ) 1 1 0 . 7 ( 8 ) 0 ( 4 « ) - C ( 8 « } - C ( 9 « ) 1 2 1 . 2 ) 7 ) o ( 2 ; - C ( 7 ) - 0 ( 7 ) 1 2 2 . 4 [ 9 ) C ( 8 » ) - C { 9 » ) - C { 1 0 » ) 1 1 9 . 0 ( 8 ) 0 ( 3 ) - C ( 9 ) - 0 ( 8 ) 1 2 3 . 0 ( 9 ) c ( 8 » ) - C ( 9 * ) - C ( 1 4 » ) 1 2 1 . 2 { 8) 0 ( 4 ] - C ( 1 1 ) - 0 ( 9 ) 1 2 5 ( 1 ) c ( 9 » ) - C (1 0' ) - C (1 1 • ) 1 1 9 . 0 ( 9 ) 0 ( 6 ) - C ( 1 3 ) - 0 ( 1 0 ) 1 2 2 ( 1 ) c ( 1 0 • ) - C ( 1 1 « ) - C ( 1 2 « ) 1 2 0 ( 1 ) 0 ( 7 ) - C { 7 ) - C { 8 ) 1 2 8 . 7 ( 9 ) c ( 1 1 ' ) - C ( 1 2 « ) - C ( 1 3 « ) 1 2 1 ( 1 ) 0 ( 8 ) - C ( 9 ) - C ( 1 0 ) 1 2 7 . 8 [ 9 ) c ( 1 2 » ) - T C ( 1 3 ' ) - C ( 1 4 « ) 1 1 9 ( 1 ) o ( 9 ; - C { 1 1 ) - C ( 1 2 ) 1 2 2 . 6 ( 9 ) c ( 1 3 * ) - C ( 1 4 » ) - C ( 9 » ) 1 2 1 . 4 { 9 ) 0 ( 1 0 ) - C { 1 3 ) - C ( 1 4 ) 1 2 7 ( 1 ) c ( 1 4 , } - C ( 9 » ) - C ( 1 0 ' ) 1 1 9 . 7 ( 8 ) 107 Table 35 Weighted least-sguares mean planes a) Distances (A) of relevant atoms from the planes with standard deviations i n parentheses Plane 1: Calculated using 0 (5) ,C (2), C (3) and C{5) Atom 0(5) C{5) Plane 0(2) C(8) Plane 0 (3) C{10) Plane 0(4) C(12) Plane 0(6) C(13) Plane N(1») C{4») 0{2») Plane 0(4') C(9») Plane C(9«) C (12«) C(8«) Distance -0.030{ 0.061 ( (A) 6) 8) A torn C(2) C (1) Distance 0. 050 { 0.700{ 8) 8) 2: 0(2) ,0(7) ,C (7) and 0.001 ( 5) 0 (7) 0.003( 9) C(2) 0(3) ,0(8) ,C(9) and 0.000 ( 8) 0 (8) 0.001(15) C(3) 0 (4) ,0 (9) ,C{11} and -0.002{ 7) 0(9) -0.007 (14) C(4) C(8) 0. 003 ( 8) 0.081( 7) C{10) 0.001(11) -0.205(10) C(12) -0.005(10) 0. 172 ( 9) Atom C(3) C(4) C (7) C{9) C(11) 5: 0(6) ,0 (10) ,C{6) ,C (13) and C(14) 0.005{ 8) 0(10) 0.017(20) C(6) -0.025(14) C(14) 0.004(14} C(5) N{1*),C(2«) ,C(3») ,C{4«) and C(5») •0.014( 6) C(2») 0.022( 8) C{3') 0.002( 8) C{5») 0.011( 8) 0(1) 0.050( 6) N(2») 0.007( 7) C(6») 7: 8: 0(4») ,N{2») ,C(8») 0.003( 7) N(2») 0.004( 8) C(3») and C (9') 0.003{ -0. 178{ 7) 8) Distance (A) -0.060 { 8) -0.740 ( 8) -0.010 ( 9) -0.002 (12) 0.0 18 (11) -0.003 (11) •0.479 (10) •0.013 ( 8) •0.062 ( 4) 0. 128 ( 8) C{8 •) -0.016 ( 9) C(9») ,C(10' ) ,C{11*) -0.004( 8} C (10«) -0.002(11) C(13 f) 0-041 ( 9) ,C (12*) ,C(13») and C{14») 0.013( 9) C (11*) -0.011 (11) 0.010(10) C{14«) -0.005 ( 9) b) Dihedral angles between selected planes Plane Plane Angle (deg.) Plane Plane 1 2 118 1 6 1 3 83 6 7 1 4 103 6 8 1 5 39 7 8 Angle (deg.) 34 130 9 138 108 Table _35 (continued) c) Equations of planes: IX + mY •* nZ = £ where X, Y and Z are orthogonal angstrom coordinates derived as follows rXi r §. 0 ccos p -j rx-| I I I = | 0 b 0 | H J *-Z-* i - O O csin p J *-z-" Plane 1 m n £ 1 0.924 0.365 0.115 8.086 2 -0.624 0.063 0.779 0.335 3 -0.466 0.883 -0.052 1.076 4 -0.048 -0.719 0.694 0.258 5 -0.091 0.923 0.374 4.122 6 0.681 0.340 0.649 9.603 7 0.920 0.354 -0. 166 3.979 8 0.761 0.379 0.526 8.375 109 Table 36 Comparison of s t r u c t u r a l data for the pyranose ring Distance Bond I *>. II III C(1)-C{2) 1.55(1) 1.528(7) 1 .529 (9) C (2)-C(3) 1.54(1) 1.50 0(7) 1 .56(1) C(3)-C(4) 1.50 (1) 1.523(6) 1 .476 (9) C(4)-C(5) 1.53 (1) 1.503 (7) 1 .524 (9) C{5)-0(5) 1. 45 (1) 1.441 (6) 1 . 443 (9) 0(5) -C(1) 1.39(1) 1.413 (5) 1 .366 (9) Angle (deg.) Bond I I I III ** «fc 0{5)-C(1) -C(2) 110. 8 (6) 108.9(3) 1 16(1) C(1)-C(2) -C{3) 106.3(6) 1 10. 9 (4) 109(1) C(2)-C<3) -C{4) 111.9 (6) 112. 2 (4) 110(1) C(3)-C(4) -C{5) 10 8.5 (6) 109.4(4) 111(1) C(4)-C{5) -0(5) 114. 4 (6) 110.9 (4) 109( 1) C(5)-0<5) -C(1) 111.0 (5) 111.0(4) 117(1) Torsion Angles (deg.) Bond I II III C(1)-C(2) -C{3) -C{4) -51.7(7) -50.5 49 C(2)-C{3) -C{4) -C{5) 58.3(8) 49. 3 57 C(3)-C(4) -C(5) -0(5) -63.0(7) -55.3 57 C(4)-C{5) -0(5) -C(1) 69.8(7) 65.0 53 C(5) -0(5) -C(1) -C(2) -68.0(7) -64. 1 49 0{5)-C{1) -C(2) -C(3) 55.6 (7) 56. 8 45 I 1-Acetyl-3-benzamido-2-keto-4-(2,3,4,6-tetra-0 -acetyl-p-D-glycopyranosyloxy) -& 3-pyrr o l i n e . II 2,3,4,6-Tetra-O-acetyl-l-cyano-p-D- galactopyranose. ~ III Tetra-0-acetyl-*-p-mannopyranosyl chloride 110 C{6) are planar {fable 35). The average values f o r the bond l e n g t h s [ C r i n g - 0 , 1.45(2); 0-C, 1.33(2); OO, 1.17(2); and C- e Cmethyl, 1.50(2) A] and angles [Cring-O-C, 117(1); Q-C*0 , 123(1); O-C-Cmethyl, 110(1); and 0*C-Cmethyl, 127(2)°] are c l o s e to the values expected f o r such groups. I t should a l s o be mentioned t h a t the t e r m i n a l atoms on these O - a c e t y l groups e x h i b i t e x t e n s i v e thermal motion (see Table 32), i n p a r t i c u l a r atom 0(10)., This i s somewhat expected due to the l e n g t h of these c h a i n s , and the lac k o f very strong i n t e r - o r i n t r a m o l e c u l a r bonding which might help to c o n s t r a i n these atoms. The mean plane c a l c u l a t e d f o r the 5-membered p y r r o l i n e r i n g ( l i n k e d to the pyranose r i n g by a p-oxygen bridge) shows i t t o be planar w i t h i n experimental e r r o r (Table 35). Other s t u d i e s on p y r r o l i n e r i n g s (71 and 72) found mean values f o r H (1 •)-C (2 •) , N(1')-C(5«), and C ^ ' J - O ^ ' ) of o 1.343 (5), 1.456 (8) and 1.2 30 (3) A r e s p e c t i v e l y . The corr e s p o n d i n g values f o r t h i s compound are 1.39(1), 1.44(1) and 1.22(1) A. Any s h o r t e n i n g i n t h e f i r s t two d i s t a n c e s i s probably due to t h e a c e t y l s u b s t i t u e n t on N(1'). The values f o r the C(2«)-C{3*), C(4*)-C{5»), and C(3»)-C(4') bond o d i s t a n c e s of 1.48 (1), 1.49 (1) and 1.32(1) A are very s i m i l a r t o those found by Boeyens and Kruger (73) [1.52, 1.52, and 1.31 A], The range of i n t r a - a n n u l a r angles f o r the p y r r o l i n e r i n g i s from 102.7 t o 111.8°. Weighted l e a s t - s q u a r e s mean planes c a l c u l a t e d f o r the benzamido group, the a c e t y l group attached to N(1*), and the benzene r i n g show them to be planar (Table 35). Again the I S M e 37 A) Intermolecular C-H...0 interactions (distances i n A angles in deg.) D-H...A H. ..A D. ..A D-H. ..A C{7«)-H(7»B) ...0<2«) i 2.57(1) 3.53 (1) 142(1) C(8)-H(8C) ...0(3»)2 2.46(1) 3.42 (1) 146 (1) C (5)-H (5)...0(7 )3 2.29(1) 3.28 (1) 148(1) C(10)-H(10A) . . .0(10) * 2.68(1) 3.36 (1) 117 (1) B) Intramolecular 0...H contacts 0(2*)- 0(2*) . 0(3»). 0(4») . 0{4»). 0(7)., 0(8).. 0(9) ., 0(10) . . , H (N2*) ..H(7'A) . . H(14A) ,.H (8B) ..H (10») ?H(2) .H{3) -H(4) . . H (6 A) 2.41 (1) 2. 46 (1) 2.91 (1) 2.55 (1) 2.47 (1) 2.55(1) 2.08 (1) 2.25 (1) 2.33 (1) -x, -1/2*y, 1-z x, 1 + y# -1 +z x, -1+y, z 1-x, 1/2+y, 1-z 112 Figure 15 A stereoscopic diagram of the u n i t - c e l l viewed down b bond lengths and angles are as expected f o r these groups. In the c r y s t a l there are extensive numbers of close H. ..0 i n t r a - and intermolecular contacts which are summarized i n Table 37. Of p a r t i c u l a r note i s the s i g n i f i c a n t l y longer H(2)..-0(7) contact compared to the other a x i a l hydrogen, ac e t y l oxygen contacts. This d i f f e r e n c e i s probably due to s t e r i c c o n s t r a i n t s induced by a postulated intermolecular hydrogen bond between 0(7) and H(5). A stereoview of the packing of the molecules i n the c r y s t a l l a t t i c e can be seen in F i g . 15. The c r y s t a l structure determination for t h i s compound indi c a t e d that the structure suggested by the mass spectrum, n.m.r., and other chemical data was i n f a c t correct. 1 1 3 SOMMA BY 1 1 n The aim of this research has been to determine the structures of the f i v e molecules previously described. The structure determinations themselves involved the u t i l i z a t i o n of the three major methods currently available in X-ray crystallography for overcoming the phase problem and thereby deducing the c r y s t a l and molecular structure. For any compound the choice of the most suit a b l e method fo r structure determination i s e s s e n t i a l l y determined by the nature of the compound i t s e l f . Patterson methods, described i n Chapter 2, involve a process i n which i t i s e s s e n t i a l that the molecule contain one or more 'heavy' atoms. The tungsten and the two ruthenium compounds (Chapters 2, 3, and 4) with their heavy metal atoms were therefore i d e a l for t h i s method. I f , however, a molecule contains only atoms which have the same or s i m i l a r atomic numbers, e.g. most organic molecules, the Patterson synthesis i s unsuitable. Although i t may be possible to produce heavy atom derivatives of these molecules and hence use the Patterson method, alternate 'd i r e c t methods* have fortunately been developed which make i t possible to determine the structures d i r e c t l y . The structure of the caffeine and pyrroline derivatives described i n Chapters 5 and 6 were determined by use of these d i r e c t methods. The actual method used depends upon the space group of the compound. The caff e i n e structure was therefore determined by centrosymmetric direct methods ( i t c r y s t a l l i z e d i n the centrosymmetric space group P2,/c) while the structure of the pyrroline compound was solved by non-centrosymmetric d i r e c t methods ( i t c r y s t a l l i z e d in the non-centrosymmetric 115 space group P2 |). Although the f i v e compounds sere e s s e n t i a l l y unrelated; and any meaningful c o r r e l a t i o n i n terms of bonding, intermolecular i n t e r a c t i o n s , etc., was impossible, the re s u l t s for the i n d i v i d u a l molecules were both i n t e r e s t i n g and useful. The analysis of the seven-coordinate tungsten compound (Chapter 2) showed i t to have a distorted capped octahedral geometry. The tungsten-iodine distances of 2.848(2) and o 2.856(2) A appeared to be the f i r s t determinations of 1-1 bond lengths i n a seven-coordinate environment. The two ruthenium compounds had very s i m i l a r octahedral structures. The t r i s complex (Chapter 3) had a l l three DMSO ligands sulphur-bonded i n a c i s configuration. In the t e t r a k i s compound (Chapter 4) the extra ligand replaced one of the chlorine atoms but was coordinated through the oxygen atom. I t i s thought that s t e r i c influences prohibit the formation of an a l l sulphur-bonded complex, but e l e c t r o n i c e f f e c t s keep the S-bonded ligands in the c i s configuration. Caffeine hydrochloride dihydrate (Chapter 5) contained a planar caffeine molecule protonated at N (9) . Of p a r t i c u l a r i n t e r e s t was the e f f e c t of protonation on the bond lengths between atoms in the fused ring system. I t i s believed that considerable rearrangement must be occuring close to the protonated centre, but that this rearrangement does not seem to be transferred to the r e s t of the molecule. The molecular geometry i n the pyrroline compound (Chapter 6) was very s i m i l a r to that found f o r other related 116 compounds. This compound did, however, exhibit extensive numbers of close C-H..,0 i n t r a - and intermolecular contacts. Some degree of hydrogen bonding was also shown by another two of the compounds studied. The ruthenium anions i n Chapter 3 were linked in a chain l i k e structure throughout the l a t t i c e to the dimethylammonium cations via N-H...0 and N-H...C1 hydrogen bonds, while the caffeine c r y s t a l s contained 0- H...C1 and N-H...0 hydrogen bonds. 117 Eef erences I . International Tables for X-ray Crystallography, vols. I - I I I , Kynoch Press, Birmingham. Vol..1, 1952; vol. II, 1959; and v o l . I l l , 1962. 2., G. H. Stout and L.H. Jensen. 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Nucleosides. Nucleotides, 19 75, 2(4S5), 343. 64. J.,Karle and I.L. Karle. Acta C r i s t . , 1966, 21, 849. 65. J.,Karle and a. Hauptman. Acta Cryst., 1956, 9, 635. 66. M.G.B. Drew, D.H. Templeton, and A. Zalkin. Acta Cryst., 1969, B25, 261; M.G.B. Drew. private communication.*' 67. 8.C. Hamilton, Acta Cr^st., 1965, 18, 502. 68. C. ,Foces-foces, F.H. Cano, and S. Garcia-blanco. Acta Cryst., 1976, B32, 964. 69. P. Herpin, R. Famery, J . Auge, S. David, and L. Guibe. Acta Cryst., 1976, B32, 209. _ _ _ _ _ n n <• 70. S.H. Kim and G.A. Jeffrey. Acta Cryst., 1967, 22, 537. 71. L. Fanfani, A. Nunzi, P.F. Zanazzi, and A.R. Zanzari. Acta Cryst., 1974, B30, 127. 72. L. Dupont, 0. Dideberg, and A. Welter. Acta Cryst., 1975, B31, 1018. 0\ *. * 73. J.C.A. Boeyens and G.J. Kruger. Acta Cryst., 1970, B26, 668. James Trotter Additional data THE STRUCTURE DETERMINATION OF THREE INORGANIC AND TWO ORGANIC COMPOUNDS B l X-RAY DIFFRACTION• By ANTHONY MERCER. B . S c , U n i v e r s i t y o f B r i s t o l , E n g l a n d , 1972. A THESIS SUBMITTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS POR THE DEGREE OF DOCTOR OF PHILOSOPHY i n t h e department of CHEMISTBY. He a c c e p t t h i s t h e s i s as c o n f o r m i n g t o t h e r e g u i r e d s t a n d a r d . THE ONIVERSITY OF BRITISH COLUMBIA JUNE 1977. @ Anthony Mercer, 1977 (2,3-Bis(dimethylarsino)-1,1,1,4,4,4-hexafluorobut-2-ene-As,As)tricarbonyl- diiodotungsten(II) j- Anthony Mercer and James Trotter Observed and calculated structure factor amplitudes (reflections with intensity < 3a(I) are marked with an asterisk). H K L FO FC H K L FO FC 0 0 2 83. 31 50.20 4 0 12 55.09 49. 16 0 0 4 252. 25 209.28 . 5 0 -14 56.04 57.08 0 0 6 22.58* 5.70 5 0 -12 29.03 25.80 0 0 8 16.39* 10.12 5 ' 0 -10 154.55 152.81 0 0 10 23.99 24.91 5 0 -8 47.16 50.26 0 0 12 186.74 179.12 5 0 -6 265.36 224.45 0 0 14 25.29* 27.56 5 0 0 0.00* 12.07 1 0 -14 34.70 40.04 5 0 2 248.26 272.36 1 0 -12 118.35 113.40 5 0 4 14.93* 13.86 1 0 -10 130.59 137.38 5 0 6 93.35 94.57 1 0 -8 46.69 52.02 5 0 8 125.78 116.24 1 0 -6 188.65 189.89 5 0 10 55.72 46.89 1 0 -4 91.47 86. 3 2 5 0 12 10.82* 23.48 1 0 2 287.92 229. 15 6 0 -14 50.92 48.43 1 0 4 16.05 10.96 6 0 -12 24.35* 19.60 1 0 8 56. 22 55.28 6 0 -10 112.57 112.05 1 0 10 158.41 156.61 6 0 -8 5.71* 13.09 1 0 12 95. 10 96.58 6 0 -6 30.70 31.27 1 0 14 20.24* 15.08 6 0 -2 17.01* 17.49 2 0 -14 183.92 182.45 6 0 0 413. 13 388.03 2 0 -12 42.07 45.19 6 0 2 149.64 161. 14 2 0 -10 41.61 45.01 6 0 4 95.40 86.08 2 0 -8 36.41 39.37 6 0 6 12.74* 4.23 2 0 -6 31.74 34.02 6 0 8 174.00 176.67 2 0 0 244. 11 249.09 6 0 10 27.74* 34.88 2 0 2 33.09 40.46 6 0 12 36.11 22.93 2 0 6 68.05 67. 13 7 0 -14 50.81 54.71 2 0 8 41.20 42.63 7 0 -12 15.62* 19.52 2 u 10 219.83 209.24 7 0 -10 25.7*4 2 1. 72 2 0 12 81.56 83.18 7 0 -8 81.67 79.39 2 0 14 22.47* 7.08 7 . 0 -6 257.23 226.89 3 0 -14 25. 17 18.29 7 0 -4 19.71* 9.6 1 3 0 -12 72.46 69.94 7 0 -2 128.63 119.22 3 0 -10 122.45 130.59 7 0 0 138.46 126. 18 3 0 -8 368.61 317.23 7 0 2 404.91 392.64 3 0 -4 38.02 22.62 7 0 4 11.99* 1.64 3 0 -2 108.28 103.01 7 0 6 211.37 196.32 3 0 0 46.31* 75.08 7 0 8 57.47 53.07 3 0 2 186.19 201.41 7 0 10 18.97* 8.38 3 0 4 275.08 238.99 8 0 -14 108.19 110.64 3 0 6 89. 80 85.67 8 0 -12 55.52 55.81 3 0 8 21.21* 27.37 8 0 -10 86.02 84.01 3 0 10 117.85 113.78 8 0 -8 176.99 171.76 3 0 12 84.81 80.70 8 0 -6 126.82 129.94 3 0 14 66. 17 71.10 8 0 -4 39.83 40.33 4 0 -14 151.54 157.32 8 0 -2 17.84* 19.90 4 0 -12 50.08 53.08 8 0 0 395.37 382.12 4 0 -10 239.08 234.94 8 ' 0 2 0.00* 7.03 4 0 -8 230.99 223.48 8 0 4 61.64 66.46 4 0 -6 90.77 94.54 8 0 6 41.87 46.63 4 0 -4 326.81 312.41 8 0 8 " -86.44 77.77 4 0 -2 367.98 311.76 8 0 10 32.86 31.28 4 0 0 115. 12 146.76 9 0 -14 19.08* 13.80 4 0 2 335. 17 315.37 9 0 -12 152.58 154.91 4 0 4 96.34 79.59 9 0 -10 204.41 201.03 4 0 6 140.24 147.29 9 0 -8 151.98 142.45 4 0 8 82.78 82.45 9 0 -6 65.23 49.23 4 0 10 161.64 162.37 9 0 -4 67.73 59. 12 H K L FO FC H 9 0 -2 86.22 92.11 15 9 0 0 163.55 153.83 15 9 0 2 13.03* 13.68 15 9 0 4 18.43* 15.97 15 9 0 6 145. 10 154.32 15 9 0 8 30.00* 28.05 15 10 0 -14 141.62 142.81 15 10 0 -12 60. 94 59.03 0 10 0 -10 48.09 45.77 0 10 0 -8 145. 17 139.78 0 10 0 -6 205.83 186.70 0 10 0 -4 259.76 243.68 0 10 0 -2 215.31 203.77 0 10 0 0 16.68* 21.11 0 10 0 2 60.92 65.39 0 10 0 4 84.76 74.07 0 10 0 6 77.87 66.42 0 10 0 8 13.44* 1.30 0 11 0 -14 0. 00* 8.52 0 11 0 -12 24.20* 22.97 0 11 0 -10 89.24 88.74 0 11 0 -8 197.83 192.37 0 11 0 -6 222.89 213.49 11 0 -4 104.56 110.40 11 0 -2 133.31 131.31 11 0 0 31.70* 43.80 11 0 2 62.53 60.69 11 0 4 116.72 106.46 11 0 6 39. 01 39.31 12 0 -14 35.09 29.77 12 0 -12 17.89* 6.97 12 0 -10 49.62 48.79 12 0 -8 114.59 113.39 12 0 -6 32.01 24.94 12 0 -4 162.50 166.4 6 12 0 -2 156.34 167.87 12 0 0 103.67 103.78 12 0 2 56.96 54.01 12 0 4 103.87 89.19 12 0 6 60. 17 46.35 13 0 -14 14.71* 8.22 13 0 -12 73.70 73.09 13 0 -10 35.62 33.73 13 0 -8 25.21* 24.53 13 0 -6 65.47 63. 17 13 0 -4 108.94 103.64 13 0 -2 150.63 147.27 13 0 0 0.00* 6.61 13 0 2 136.59 124.02 13 0 4 0.00* 2.27 14 0 --12 31.91 28.26 14 0 --10 60.71 52. 18 14 0 -8 37.97 37.73 14 0 -6 48.44 48. 15 14 0 -4 135.36 133.00 14 0 -2 3.36* 7.22 14 0 0 80.99 70.52 14 0 2 39.23 32.87 K L FO FC 0 -12 81.72 80.94 0 -10 44.66 36.78 0 -8 105.68 101.18 0 -6 20.60* 3.89 0 -4 42.94 50.58 0 -2 24.88* 13.52 0 0 22.55* 6.07 1 236.54 192. 10 2 242.78 204.34 3 188.28 164.27 4 144.52 137.36 5 161,72 148.28 6 372.87 311.87 7 . 150.98 146.34 8 129.68 121.6 1 9 87.28 87.73 10 44.37 40.68 11 36.05 30.62 12 0.00* 9.32 13 88. 58 82.66 14 0.00* 5.03 15 45.88 45.80 -15 14.58* 18.41 -14 44.74 44.03 -13 62.13 60.79 -12 38.71 38.84 -11 51.06 51.07 -10 24.39 25.46 -9 93.29 8 8.28 -8 0.00* 9.4 1 -7 219.26 194.37 -6 133.23 122.01 -5 66.74 72.61 -4 34.22 34.40 -3 84.86 89.89 -2 53.87 54.47 -1 187.36 160.05 0 451.01 475.80 1 266.44 256. 1 1 2 38.71 29.31 3 8.28* 5.07 5 375.95 324.34 6 172.78 166.94 7 129.58 127.62 8 15.44* 16.24 9 73.42 74.71 10 52.30 43.33 11 79.65 80.63 12 104.59 103.81 13 12.03* 9.74 14 14.65* 7.22 15 12.03* 18.37 15 83.46 82.54 14 30.63 30.37 . -13 65.68 64.70 — 12 98.96 99. 10 — 11 137.62 134.20 — 10 104.78 103.35 H K L FO 2 _! -9 90.04 2 - 1 -8 110.14 2 -1 -7 67.20 . 2 - 1 -6 183.82 2 - 1 -5 41.85 2 - 1 -4 135. 14 2 -1 -3 57.34 2 - 1 -2 353.49 2 - 1 -1 210.03 2 - 1 0 98.22 2 - 1 1 37. 84 2 -1 2 251.86 2 -1 3 190.32 2 - 1 4 151.20 2 - 1 5 39.73 2 -1 6 110.81 2 -1 7 162.50 2 - i 8 40.46 2 - 1 9 31.11 2 - 1 10 164.57 2 -1 11 154.36 2 - 1 12 111.26 2 - 1 13 38.90 2 - 1 14 28.45 3 - 1 -15 26.30* 3 - 1 -14 165.14 3 - 1 -13 102.52 3 - 1 -12 83. 03 3 - i -11 34.85 3 - r -10 21.58 3 -1 -9 254.95 3 - 1 -8 97.87 3 - 1 -7 95.05 3 -1 -6 50. 80 3 - 1 -5 101.19 3 - 1 -4 147.50 3 - 1 -3 43.94 3 - 1 -2 276.93 3 - 1 -1 73.99 3 -1 0 56. 14 3 - 1 1 75. 34 3 -1 2 170.07 3 - 1 3 122.39 3 - 1 4 265.66 3 - 1 5 190.06 3 - 1 6 52.72 3 - 1 7 39.49 3 - 1 8 122.70 3 - i 9 173.80 3 - 1 10 163.94 3 - -j 11 32.98 3 - 1 12 19.79* 3 - 1 13 34.62 3 - 1 14 32.71 4 - 1 -15 73. 13 4 - 1 -14 52. 29 4 -1 -13 41.95 4 - 1 -12 25.75 FC H 86.60 4 98.08 4 73.06 4 181.65 4 41.05 4 127.51 4 59.03 4 303.61 4 175.93 4 90.87 4 40.94 4 234.57 4 164.00 4 143.23 4 27.12 4 112. 15 4 161.03 4 40.38 4 32.92 4 152.67 4 145.81 4 112.17 4 39.94 4 25.03 4 23.16 4 160.40 5 104.43 5 81.35 5 31.31 5 22.82 5 235.06 5 101.33 5 93.16 5 41.18 5 95. 81 5 142.24 5 50.62 5 244.42 5 79.51 5 74.83 5 74.36 5 163.85 5 131.31 5 243.20 5 183.19 5 57.58 5 39.71 5 119.34 5 168.77 5 161.85 5 27.26 5 10.95 5 36.08 5 29.24 6 73.55 6 56.87 6 36.93 6 23.80 6 L FO FC -11 165.78 165.43 -10 54. 30 51.60 -9 62.28 59.43 -8 140. 16 133.37 -7 168.15 166.82 -6 261.08 227.45 -5 43.23 29.60 -4 297.31 263.10 -3 216.60 181.25 -2 380.37 335.74 -1 12.50* 21.43 0 138.25 145.48 1 79.45 87.38 2 48. 42 54.85 3 69.71 75.24 4 55. 65 67.39 5 38. 18 34.47 6 50. 46 49.00 7 93.39 92.47 8 65. 12 63.82 9 70.54 66.28 10 13.21* 9.92 11 97.78 92.17 12 0.00* 5. 10 13 0.00* 3.25 -15 24. 63 16.30 -14 25.22 27.44 -13 22.23* 23.43 -12 o ~> r\ ft i. . V H 19. 14 -11 81.04 79.31 -10 195.27 190.29 -9 272.89 247.94 -8 158.27 155.44 -7 42. 84 45.88 -6 36.09 38.46 -5 264.25 230.90 -3 40. 44 33.21 -2 62.68 48.83 -1 102.54 102.56 0 79.09 81.76 1 173.80 186.28 2 267.75 276.07 3 201.31 195.41 4 121.30 114.79 5 21.95* 23.97 6 85.32 81.91 7 97.03 93.51 8 30.26 30.47 9 86.76 83.97 10 19.37* 7.80 11 21. 12* 11.35 12 46.62 40.26 13 33.70 30.47 -15 20.14* 19.37 -14 20.79* 19.42 -13 84.85 84. 12 -12 48.62 53.56 -11 85.34 89.29 H K L FO 6 _-| -10 85. 31 6 -1 -9 59.77 6 -1 -8 46.45 6 -1 -7 97. 18 6 -1 -6 161.78 6 -1 -5 41.82 6 -1 -4 139.06 6 -1 -3 149.97 6 -1 -2 224.96 6 -1 -1 125.84 6 -1 0 136.54 6 -1 1 202.59 6 -1 2 228.54 6 -1 3 111.49 6 -1 4 81.66 6 -1 5 75. 13 6 -1 6 0.00* 6 -1 7 48.56 6 -1 8 11.95* 6 -1 9 81. 26 6 -1 10 18.00* 6 -1 11 27.35* 6 -1 12 32.41 7 -1 -15 35. 10 7 -1 -14 56. 15 7 -1 -13 73.75 7 -1 -12 30.00 7 -1 -11 116.51 7 -1 -10 21.76* 7 -1 -9 17.16* 7 -1 -8 167.21 7 -1 -7 95.03 7 -1 -6 75. 88 7 -1 -5 184.21 7 -1 -4 219.75 7 -1 -3 33. 11 7 -1 -2 11.43* 7 -1 -1 33. 1 1 7 -1 0 301.70 7 -1 1 225.94 7 -1 2 24.86* 7 -1 3 71.68 7 -1 4 0.02* 7 -1 5 122.85 7 -1 6 11.69* 7 -1 7 139. 19 7 -1 8 119.27 7 -1 9 12.21* 7 -1 10 41.57 7 -1 11 29.52 8 -1 -15 99.52 8 -1 -14 43.74 8 -1 -13 87. 83 8 -1 -12 66.67 8 -1 -11 70.51 8 -1 -10 116.92 8 -1 -9 52. 56 8 -1 -8 42.07 FC H 88.38 8 60.25 8 48. 13 8 100.09 8 154.18 8 40.73 8 129.98 8 141.10 8 232.04 8 127.43 8 138.88 8 217.90 8 259.24 8 116.39 8 94.97 8 70.04 8 19.15 8 45.59 8 12.68 9 81.25 9 7.52 9 25.45 9 28.68 9 37.91 9 52.47 9 72.72 9 32.09 9 117.42 9 19.15 9 13. 14 9 158.54 9 96.01 9 87.30 9 173.21 9 214.60 9 35.59 9 6.09 9 28.95 9 31 1.99 9 227.71 9 3.52 9 68.40 9 12.48 9 122.71 10 17.23 10 130.78 10 115.88 10 10.85 10 40.32 10 20.42 10 96.18 10 40.20 10 85.77 10 68.76 10 72.53 10 120.52 10 54.28 10 29.31 10 L FC FC -7 24. 54 14.05 -6 80.75 70.90 -5 52.38 49.44 -4 123.38 113.72 -3 17.94* 9.34 -2 63.29 62.54 -1 113.95 119.37 0 48. 89 51.01 1 61.90 62.89 2 123.54 108.71 3 93.66 91.88 4 34.96 52.77 5 51.83 55.48 6 168.21 168.09 7 1 12.30 115.48 8 69. 42 70.63 9 38.25 37.18 10 14.68* 22.79 15 11.29* 7.31 14 84.01 86.05 13 109.73 115.26 12 14.88* 8.69 11 56.24 60.97 10 57.90 58.90 -9 151.00 150.33 -8 72.00 74.50 -7 133.50 128.09 -6 170.48 158.04 -5 26.04 3 1.18 -4 160.20 165.80 -3 46. 25 48.01 -2 32.36 31.34 -1 64.48 69.14 0 130.04 128.88 1 78.74 77.29 2 63.48 57.40 3 48.44 38.47 4 104.02 96.58 5 160.54 155.58 6 69.72 72.23 7 46. 26 44.75 8 0.00* 5.19 9 37.09 38.89 15 84.75 82.02 14 28.89 22.58 13 38.07 39.08 12 85.26 89.56 11 115.02 117.51 10 112.55 112.93 -9 13.54* 21.32 -8 127.98 123.60 -7 140.42 137.48 -6 182.42 173.37 -5 25.26* 20.95 -4 30.40 33.31 -3 117.02 114.18 -2 17.35* 5.08 -1 45.98 44.75 H K L FO FC H K L FO FC 10 0 88.54 84.68 13 -V -10 18.29* 23. 14 10 -1 1 66.56 67. 13 13 -1 -9 68.75 65.93 10 -1 2 32.01 20.35 13 -1 -8 30.27* 29. 18 10 -1 3 27.93* 33.26 13 -7 13.48* 14.55 10 - 1 4 32.82* 31. 19 13 - 1 -6 0.00* 7.67 10 -1 5 31.07* 33.07 13 - 1 -5 59.13 58.71 10 -1 6 0.00* 1.60 13 - 1 -4 111.44 110.59 10 -1 7 52.06 47.72 13 - 1 -3 25.96* 24. 10 10 -1 8 26.30* 16.91 13 -1 -2 50.22 41.82 11 -1 -15 11.72* 21.63 13 - 1 -1 31.93 25.76 11 -1 -1" 72.28 75.26 13 -1 0 35.30 42.65 11 -1 -13 66.28 70.25 13 - 1 1 85. 87 86.22 11 -1 -12 29.09* 37.72 13 - 1 2 70.85 66.09 11 -1 -11 30.48* 33.44 13 - 1 3 92. 86 91.00 11 -1 -10 21.73* 35.65 13 - 1 4 64.87 64.98 11 -1 -9 158.29 158.65 14 - 1 -13 61.14 58.30 11 -1 -8 93.88 91.16 14 - 1 -12 48. 30 43.85 11 -1 -7 43.55 45.24 14 - 1 -11 16.00* 10.33 11 -1 -6 40.34 38.95 14 - 1 -10 17.18* 3.76 11 -1 -5 72. 1 1 70.73 14 - 1 -9 36.97 28.93 11 -1 -4 137.29 133.54 14 - 1 -8 67.40 63.75 11 -1 -3 41.28 26.53 14 - 1 -7 32.44* 31.33 11 -1 -2 150. 10 159.90 14 - 1 -6 0.00* 8.72 11 -1 -1 95.79 103.10 14 - 1 -5 49.33 49.91 11 -1 0 104.09 101.94 14 - 1 -4 15.08* 17.73 11 -1 1 79.07 77.27 14 -1 -3 39.06 30.17 11 -1 2 36.07 25. 14 14 - 1 -2 34.83 30.99 11 -1 3 115.40 114.93 14 - 1 -1 51.54 51.31 11 — i 4 0.00* 14.30 14 - 1 0 40. 83 32. 12 11 -1 5 53. 13 50.67 14 - 1 1 59.00 44.31 11 - 1 6 31.97* 20.34 14 - 1 2 92.12 88.23 11 - 1 7 21.85* 10.75 15 - 1 -12 25.12* 15.42 12 - 1 -15 14.09* 25.62 15 - 1 -11 57.36 61.50 12 - 1 -14 0.00* 4.12 15 - 1 -10 77.03 71.80 12 - 1 -13 32.33 31.52 15 - 1 -9 49. 15 43.90 12 - 1 -12 30.68 25.21 15 - 1 -8 77. 52 73.03 12 -1 -11 50. 28 49.38 15 - 1 -7 23.54* 28.26 12 - i -10 0.00* 9.76 15 - 1 -6 42. 50 44.03 12 -1 -9 0.00* 4.16 15 - 1 -5 21.80* 8.26 12 -1 -8 76.49 73.69 15 - 1 -4 17.90* 25.66 12 -1 -7 68.53 73.44 15 -1 -3 15.09* 10.30 12 -1 -6 96.89 99.04 15 -1 -2 33. 33 17.32 12 - 1 -5 51.89 56.25 15 - 1 -1 42.04 28.36 12 - 1 -4 94. 35 99. 17 15 - 1 0 44.81 43. 11 12 -1 -3 120.25 123.70 0 -2 0 76.85 96.57 12 - 1 -2 152.26 158.96 0 -2 1 317. 16 258.97 12 - 1 -1 49. 40 52.24 0 -2 2 274.32 229.66 12 -1 0 25.31* 12.37 0 -2 3 41.47 29. 19 12 -1 1 70.27 72.25 0 -2 4 42.83 35.48 12 - 1 2 48.24 39.92 0 -2 6 31.67 34.52 12 -1 3 24.19* 26.24 0 -2 7 248.81 224.42 12 -1 4 41.32 36.73 0 -2 8 41.84 48.31 12 -1 5 44.09 47.97 0 -2 9 19.02* 11.73 12 -1 6 39.78 32.06 0 -2 10 29.79 31.97 13 -1 -14 26.14* 31.79 0 -2 11 110.51 105.78 13 - 1 -13 32.07 31.30 0 -2 12 17.09* 2.63 13 - 1 -12 4 3.12 39.60 0 -2 13 16.38* 18.56 13 -1 -11 58. 68 64.84 0 -2 14 67.88 68.04 H K L FO FC 0 -r2 15 13.64* 13.64 1 -2 -15 85.10 85.53 1 -2 -14 0.00* 2.53 1 -2 -13 89.94 89.83 1 -2 -12 20.55* 22.25 1 -2-11 98.33 101.64 1 -2 -10 80.71 80.04 1 -2 -9 64.89 58.66 1 -2 -8 200.23 198.35 1 -2 -7 88.77 80.55 1 -2 -6 38.41 41.69 1 -2 -5 158.27 142.45 1 -2 -4 92.10 98.90 1 -2 -3 185.03 165.98 1 -2 -2 92.35 94.75 1 -2 -1 367.83 307.57 1 - 2 0 41.30* 50.99 1 -2 1 131.57 122.06 1 -2 2 33.34 38.59 1 - 2 3 323.04 288.39 1 -2 4 174.89 179.60 1 -2 5 122.19 123.32 1 -2 6 16.95* 19.88 1 -2 7 309.91 277.26 1 - 2 8 52.20 48.01 1 -2 9 94.27 87.37 1 -2 10 9.98* 9.80 1 -2 11 141.39 140.65 1 -2 12 72.66 76.89 1 -2 13 45.91 51.55 1 -2 14 44.74 46.43 1.-2 15 27.04 18.34 2 -2 -15 21.49* 19.43 2 -2 -14 8.39* 6.67 2 -2 -13 129.60 131.51 2 -2 -12 79.65 83.65 2 -2 -11 4.37* 12.80 2 -2 -10 102.29 106.79 2 -2 -9 205.12 196.69 2 - 2 - 8 16.68* 1.14 2 -2 -7 224.40 214.33 2 -2 -6 13.69* 25.40 , 2 -2 -5 5.65* 4.59 2 -2 -4 77.04 76.19 2 -2 -3 66.25 57.42 2 -2 -2 163.64 156.27 2 -2 -1 128.20 122.72 2 - 2 0 165.49 206.49 2 -2 1 104.37 108.80 2 - 2 2 293.23 280.32 2 - 2 3 31.46 29.89 2 -2 4 106.23 101.78 2 - 2 6 64.19 63.77 2 -2 7 78.53 78.47 2 - 2 8 0.00* 3.62 2 - 2 9 207.51 198.91 2 -2 10 12.80* 1.55 2 -2 11 52.38 52.58 fl K L FO FC 2 -2 12 58.80 59.46 2 -2 13 24.06* 29.46 2 -2 14 24.51* 15.87 3 -2 -15 91.49 96.90 3 -2 -14 8.83* 7.13 3 -2 -13 15.41* 21. 38 3 -2 -12 11.73* 7.26 3 -2 -11 191.74 191.54 3 -2 -10 68.63 67.03 3 -2 -9 100.97 101.21 3 -2 -8 37.76 36.66 3 -2 -7 213.99 197.26 3 -2 -6 167.19 160.77 3 -2 -5 20.99 23.49 3 -2 -4 197.24 170.90 3 -2 -3 134.45 122.49 3 -2 -2 46.56 51.18 3 -2 -1 37.90 29.51 3 -2 0 91.34 95. 19 3 -2 1 80. 10 94.66 3 -2 2 126.68 142.29 3 -2 3 158.43 154.99 3 -2 4 8.21* 14.49 3 -2 5 84. 28 80.93 3 -2 6 78. 35 78.26 3 -2 7 158.77 155.41 3 -2 8 76.44 77.04 3 -2 9 0.00* 3. 17 3 -2 10 8.70* 8.29 3 -2 .11 156.59 156.08 3 -2 12 7.81* 1.86 3 -2 13 31.11 33.94 3 -2 14 28.84* 25.74 4 -2-15 19.51* 11.58 4 -2 -14 22.42* 24.82 4 -2 -13 102.41 105.86 4 -2-12 17.98* 23.07 4 -2 -11 54.78 56.99 4 -2 -10 44.00 37.75 4 -2 -9 379.25 356.75 4 - 2 -8 127.80 128.06 4 -2 -7 20.69 13.22 4 -2 -6 99.77 103.34 4 -2 -5 232.80 207.13 4 -2 -4 28.42* 54.28 4 -2 -3 56.46 53.18 4 - 2 -2 54.64 63.34 4 -2 -1 17.06* 18.53 4 - 2 0 0.00* 26.50 * 4 -2 1 123.35 151.41 4 -2 2 61.93 73.13 4 - 2 3 219.20 221.50 4 -2 4 64.17 59.68 4 - 2 5 74.64 70.83 4 - 2 6 133.94 136.81 4 - 2 7 30.57 24.82 4 - 2 8 112.96 108.96 4 -2 9 203.09 191.68 H K L FO FC 4 -2 10 26.41 15.37 4 -2 11 27.76 25.80 4 -2 12 20.07* 2.28 4 -2 13 61.01 55.48 5 -2 -15 31.89 39.44 5 -2 -14 0.00* 2.73 5 -2 -13 67.85 69.49 5 -2 -12 26.65 28.58 5 -2 -11 174.98 175.95 5 -2 -10 23.67 26.83 5 -2 -9 11.48* 5.73 5 -2 -8 21.57 14.28 5 -2 -7 236.01 220.44 5 -2 -6 91.36 82.36 5 -2 -5 50. 17 51.67 5 -2 -4 85. 54 73.53 5 -2 -3 416.29 387.36 5 -2 -2 164. 19 172.93 5 -2 -1 143.13 144.41 5 -2 0 90.44 99.39 5 -2 1 143.51 146.14 5 -2 2 26.52 22.07 5 -2 3 85.09 96.77 5 -2 4 154.02 163.21 5 -2 5 71.78 73.05 5 -2 6 97.53 93.05 5 -2 7 27.84 30.05 5 -2 8 23.06* 7.57 5 -2 9 110.92 105.37 5 -2 10 36. 14 38.98 5 -2 1 1 69.78 71.67 5 -2 12 34.64 31.83 6 -2 -15 33.41 41.58 6 -2 -14 6.25* 2. 83 6 -2 -13 52.72 53.94 6 -2 -12 91.51 91.75 6 -2 -11 110.02 109.74 6 -2 -10 35.93 38.35 6 -2 -9 177.84 173.08 6 -2 -8 30.76 37.39 6 -2 -7 32.74 19.53 6 -2 -6 125.42 123.68 6 -2 -5 392.85 341.93 6 -2 -4 71.56 71.90 6 -2 -3 92.03 81.00 6 -2 -2 105.44 96. 17 6 -2 -1 63.54 62.96 6 -2 0 39.54 40.01 6 -2 1 229.92 225.61 6 — 2 2 24.13* 15.77 6 -2 3 175.95 193.79 6 -2 4 24. 14* 17.47 6 -2 5 124.64 129.63 6 -2 6 0.00* 16.02 6 -2 7 187.09 180.35 6 -2 8 32.27 31.40 6 -2 9 13.40* 14.23 6 -2 10 87.25 81.56 H K L FO FC 6 -2 11 0.00* 5.84 6 -2 12 41.45 41.47 7 -2 -15 97.35 96.02 7 -2 -14 58.61 56.74 7 -2 -13 83.65 84.04 7 -2 -12 71.73 72.86 7 -2 -11 14.52* 17.26 7 -2 -10 33. 12 31.78 7 -2 -9 58.14 59.47 7 -2 -8 49.35 46.75 7 -2 -7 72.39 61.12 7 -2 -6 15.75* 17.45 7 -2 -5 107.89 103.73 7 -2 -4 62.96 54.58 7 -2 -3 96.06 100.52 7 -2 -2 69.36 74.42 7 -2 -1 98.20 100.55 7 -2 0 158.92 162.31 7 -2 1 204.38 208.82 7 -2 2 49.03 42.04 7 -2 3 156.17 161.20 7 -2 4 15.21* 6.73 7 -2 5 82.69 87.61 7 -2 6 19.32* 5.81 7 -2 7 149. 17 149.25 7 -2 8 79.06 75. 18 7 -2 9 57.79 60.89 7 -2 10 39.78 38.75 7 -2 11 8.99* 9.25 8 -2 - 15 19.64* 19.86 8 -2 -14 37.60 41.90 8 -2 -13 128.66 134.95 8 -2 -12 0.00* 4.42 8 -2 -11 121.20 127.04 8 -2 -10 27.54 24. 38 8 -2 -9 106.50 104.06 8 -2 -8 53.07 52.39 8 -2 -7 116.37 107.33 8 -2 -6 90.82 80. 16 8 -2 -5 103.58 93.63 8 -2 -4 80.98 77.85 8 -2 -3 49.20 43.51 8 -2 -2 159.56 155.90 8 -2 -1 32.92 35.30 8 -2 0 39.57 43. 10 8 -2 1 181.33 183.86 8 -2 2 43.54 43.82 8 -2 3 34.26 34.40 8 -2 4 18.32* 16.66 8 -2 5 196.06 204.21 8 -2 6 27.91* 21.12 8 -2 7 98. 19 99.60 8 -2 8 23.77* 26.57 8 -2 9 47.19 43.80 8 -2 10 16.96* 21.76 9 -2 -15 120.19 119.86 9 -2 -14 26.15* 27.93 9 -2 -13 87.59 89.56 H K L FO FC 9 -2 -12 22.18* 21.98 9 -2 -11 161.26 167.93 9 -2 -10 69.88 70.10 9 -2 -9 35.21 31.96 9 -2 -8 80. 18 81.40 9 -2 -7 104.32 100.51 9 -2 -6 80. 16 75.93 9 -2 -5 20.35* 19.93 9 -2 -4 49.66 41.46 9 -2 -3 84. 18 85.46 9 -2 -2 21.24* 16.98 9 -2 -1 97. 29 95.06 9 -2 0 17.20* 8.57 9 -2 1 15.89* 9. 17 9 -2 2 46. 20 47.92 9 -2 3 68.44 66.95 9 -2 4 109. 12 116.41 9 -2 5 0.00* 25.61 9 -2 6 13.84* 4.68 9 -2 7 120.86 117.66 9 -2 8 8.33* 5.55 9 -2 9 37.26 31.04 10 -2 -15 14.25* 7.68 10 -2 -14 15.46* 11.17 10 -2 -13 131.03 135.25 10 -2 -12 22.48* 23.32 10 -2 -11 0.00* 10.36 10 -2 -10 0.00* 17.18 10 -2 -9 204.26 203. 15 10 -2 -8 18.92* 25.01 10 -2 -7 112.65 107.20 10 -2 -6 46.57 44.65 .10 -2 -5 115.42 106.42 10 -2 -4 47. 43 33.35 10 -2 -3 55.56 63.67 10 -2 -2 50.46 54.57 10 -2 -1 112.10 125.28 10 -2 0 85.83 83.10 10 -2 1 35.51 30.56 10 -2 2 88.43 88.2 8 10 -2 3 82.95 71.40 10 -2 4 55.60 50.35 10 -2 5 123.66 128.00 10 -2 6 30.04* 3.72 10 -2 7 28.10* 7.46 10 -2 8 0.00* 5.66 11 -2 -15 57.77 53.68 11 -2 -14 35.81 32.73 11 -2 -13 24.02* 5.62 11 -2 -12 9.30* 19.42 11 -2 -11 114.96 114.51 11 -2 -10 66.37 69.66 11 -2 -9 40.38 40. 1 1 11 -2 -8 34.16 33.52 11 -2 -7 165.56 165.51 11 -2 -6 75.72 76.87 11 -2 -5 78. 31 68.59 11 -2 -4 28.65* 23.90 fi K L FO FC 11 -2 -3 161.60 161.55 11 -2 -2 36.70 25. 10 11 -2 -1 51.48 52.69 11 -2 0 28.49* 29.83 11 -2 1 83.96 82.69 11 -2 2 42.28 44.98 11 -2 3 18.32* 7.22 11 -2 4 14.39* 12.84 11 -2 5 77. 36 74.6 1 11 -2 6 40.78 35.51 11 -2 7 0.00* 14.99 12 -2 -15 35. 54 34.25 12 -2 -14 5. 11* 10.72 12 -2 -13 14.77* 19.74 12 -2 -12 41.07 42.59 12 -2 -11 42.94 45.18 12 -2 -10 44. 32 39. 18 12 -2 -9 144.09 146.76 12 -2 -8 16.46* 12.84 12 -2 -7 23.99* 22. 19 12 -2 -6 10.89* 5.33 12 -2 -5 85.73 87.73 12 -2 -4 60.83 56.51 12 -2 -3 31.92* 38. 13 12 -2 -2 21.68* 18. 38 12 -2 -1 92.92 100.35 12 -2 0 0.00* 10. 30 12 -2 1 97.64 97.0 1 12 -2 2 11.54* 4.60 12 -2 3 136.84 139.80 12 -2 4 41.99 31.51 12 -2 5 18. 53* 13.68 13 -2 -14 10.05* 5.55 13 -2 - 13 59.73 59.4 1 13 -2 -12 23.29* 23.62 13 -2 -11 10.19* 16.96 13 -2 -10 53.24 51.00 13 -2 -9 19.06* 16.81 13 -2 -8 0.00* 6.4 1 13 -2 -7 31.28 28.64 13 -2 -6 52.02 52.64 13 -2 -5 27.89* 30.08 13 -2 -4 48.66 43.85 13 -2 -3 90. 12 104.80 13 -2 -2 38.67 33.89 13 -2 -1 66.57 71.07 13 -2 0 0.00* 11.14 13 -2 1 87.67 84.31 13 -2 2 O.OC* 8.44 13 -2 3 63.90 63.71 13 -2 4 26.00* 22.76 14 -2 -13 82.31 81.67 14 -2 -12 36.08 37.96 14 -2 -11 74.87 74.50 14 -2 -10 0.00* 12.22 14 -2 -9 0.00* 1.58 14 -2 -8 23.56* 29.48 14 -2 -7 20.42* 12.96 H K L FO FC 14 -2 -6 56.48 53. 15 14 -2 -5 28.27* 32.67 14 -2 -4 16.82* 3.24 14 -2 -3 23.03* 31.73 14 -2 -2 0. 00* 3.71 14 -2 -1 0.00* 4.06 14 -2 0 14.97* 28.02 14 -2 1 85. 13 88. 19 14 -2 2 24.78* 20.86 15 -2 -11 49.00 54.50 15 -2 -10 0.00* 11.93 15 -2 -9 33.94 28.96 15 -2 -8 25.69* 13.12 15 -2 -7 69.79 63.65 15 -2 -6 31.64* 29.63 15 -2 -5 39.95 35.82 15 -2 -4 18.20* 6.54 15 -2 -3 37.49 33.69 15 -2 -2 33.50 30.40 15 -2 -1 29.68* 31.94 15 -2 0 59.41 51.95 0 -3 1 99.71 99.94 0 -3 2 335.62 306. 17 0 -3 3 197.85 171.71 0 -3 4 26.84 20.23 0 -3 5 103.79 100.85 0 -3 6 122.60 126.62 0 -3 7 221.62 217.05 0 -3 8 176.37 165.5.0 0 -3 9 17.62* 19.02 0 -3 10 77.07 74.80 0 -3 1 1 18.46* 15.27 0 -3 12 24.59* 31.13 0 -3 13 10.36* 7.61 0 -3 14 45.62 54.4 5 0 -3 15 45.79 43.08 1 -3 -15 19.13* 21.48 1 -3 -14 123.22 122.35 1 -3 -13 48.69 49.22 1 -3 -12 67.92 68. 10 1 -3 -11 19.02* 10.15 1 -3 -10 70.81 73.73 1 -3 -9 4.51* 3.26 1 -3 -8 13.92* 11.53 1 -3 -7 94. 13 90.25 1 -3 -6 10.25* 11.90 1 -3 -5 75.60 73.54 1 -3 -4 169.39 162.69 1 -3 -3 82.44 87.51 1 -3 -2 311.86 280.99 1 -3 -1 237.59 212.00 1 -3 0 205.64 229.00 1 -3 1 170.72 160.30 1 -3 2 36.28 45.92 1 -3 3 98.93 100.19 1 -3 4 82.41 91.14 1 -3 5 308.56 279.61 1 -3 6 66.71 66.68 H K L FO FC 1 -3 7 20. 19* 15.41 1 -3 8 123.66 130.58 1 -3 9 99.26 91.36 1 -3 10 95.67 98.85 1 -3 11 4 1.15 41.17 1 -3 12 104.32 103.18 1 -3 13 14.02* 5.36 1 -3 14 38.41 42.47 2 -3 -15 34. 87 32.91 2 -3 -14 0.00* 10.27 2 -3 -13 14.54* 13.21 2 -3 -12 34. 52 32.69 2 -3 -11 131.56 135.30 2 -3 -10 4 3.74 39.72 2 -3 -9 21.51 17.32 2 -3 -8 149.73 148.27 2 -3 -7 58.52 55.75 2 -3 -6 98.67 86.03 2 -3 -5 84.94 88.94 2 -3 -4 295.52 269.39 2 -3 -3 225. 1 1 205.70 2 -3 -2 80.61 74.81 2 -3 -1 26.98 18.25 2 -3 0 98.47 95.40 2 -3 1 17.12* 5.25 2 -3 2 114.76 97.69 2 -3 3 101.56 97.94 2 -3 4 171.71 166.69 2 -3 5 .0.00* 4..2 2 2 -3 . 6 189.02 186.83 2 -3 7 133.52 138.99 2 -3 8 87.27 83.40 2 -3 9 65.95 63.89 2 -3 10 18.27* 18.69 2 -3 11 109.67 108. 12 2 -3 12 24.19* 13.45 2 -3 13 14.61* 2.43 2 -3 14 47.39 46.26 3 -3 -15 32.75 23.49 3 -3 -14 55.08 61.51 3 -3 -13 106.10 110.43 3 -3 -12 27.99 23.20 3 -3 -11 39.35 34.64 3 -3 -10 115.10 115. 13 3 -3 -9 151.76 150. 13 3 -3 -8 22.29 23.31 3 -3 -7 20.28 18.04 3 -3 -6 125.19 140. 16 3 -3 -5 23.16 15.58 3 -3 -4 223.74 203.20 3 -3 -3 39.16 33.41 3 -3 -2 223.05 206.21 3 -3 -1 17.67* 3.71 3 -3 0 206.92 226.72 3 -3 1 84.28 109.00 3 -3 2 189.97 206.64 3 -3 3 56.51 56.55 3 -3 4 110.23 117.76 H K L FO FC 3 -3 5 90.78 90.38 3 -3 6 73.52 75.24 3 -3 7 49. 17 51.91 3 -3 8 57.03 68.92 3 -3 9 168.00 161.98 3 -3 10 98.80 94.40 3 -3 11 4.06* 5.59 3 -3 12 90.21 93.04 3 -3 13 15.38* 24.87 4 -3 -15 41.96 39.52 4 -3 -14 13.53* 5.74 4 -3 -13 21.71* 25. 18 4 -3 -12 50.53 51. 13 4 -3 -11 92.58 96.61 4 -3 -10 143.64 148.88 4 -3 -9 54.87 57.82 4 -3 -8 87. 12 84.81 4 -3 -7 239.03 237. 17 4 -3 -6 129.68 119.67 4 -3 -5 27.59 26.57 4 -3 -4 165.46 160.44 4 -3 -3 99.31 100.34 4 -3 -2 31.30 39.95 4 -3 -1 191.84 206. 10 4 -3 0 149.74 175.24 4 -3 1 38.21 38.54 4 -3 2 145.74 148.79 4 -3 3 0.00* 16.53 4 -3 .4 137.91 142.71 4 -3 5 17.99* 15. 14 4 -3 6 33.80 40.44 4 -3 7 77.63 76.02 4 -3 8 81.62 83.94 4 -3 9 13.90* 17.66 4 -3 10 68.03 67.65 4 -3 11 39.36 40.32 4 -3 12 71.44 73.30 4 -3 13 33. 1 1 30.38 5 -3 -15 9.05* 2.89 5 -3 -14 33.90 32.3 1 5 -3 -13 10.82* 4.91 5 -3 -12 114. 17 117.17 5 -3 -11 21.34* 24.89 5 -3 -10 0.00* 3.65 5 -3 -9 209.61 205.70 5 -3 -8 12.81* 12.94 5 -3 -7 20.09* 4.55 5 -3 -6 29.91 25.90 5 -3 -5 174.67 166.22 5 -3 -4 253.89 233.31 5 -3 -3 38.88 34.05 5 -3 -2 222.55 206.00 5 -3 -1 19.55* 21.05 5 -3 0 162.89 181.22 5 -3 1 91.99 100.88 5 -3 2 118.08 127. 17 5 -3 3 110.04 119.64 5 -3 4 87.53 95.83 H K L FO FC 5 -3 5 80.25 72.64 5 -3 6 40.20 38.50 5 -3 7 36.79 30.35 5 -3 8 81.39 76.78 5 -3 9 33.32 25.83 5 -3 10 98. 13 101.60 5 -3 11 28.94* 31.62 5 -3 12 43.24 43.00 6 -3 -15 22.31* 33.42 6 -3 -14 38.62 43.29 6 -3 -13 7.06* 6.65 6 -3 -12 74.48 79.06 6 -3 -11 56.74 59.72 6 -3 -10 47.80 50. 15 6 -3 -9 40.45 4 0.70 6 -3 -8 16.52* 11.89 6 -3 -7 128.56 130.14 6 -3 -6 275.96 267.67 6 -3 -5 37.36 40.82 6 -3 -4 40.80 36.35 6 -3 -3 135.52 127.97 6 -3 -2 129.12 141.06 6 -3 -1 70.96 69.58 6 -3 0 56. 62 67.24 6 -3 1 142.68 141.09 6 -3 2 73.27 82.98 6 -3 3 187.86 210.20 6 -3 4 102.92 108.09 6 -3 5 2 7-. 9 6 29. 5 1 6 -3 6 138.92 142.43 6 -3 7 35.31 32.92 6 -3 8 64. 21 57.59 6 -3 9 4.70* 16.51 6 -3 10 33.06 26.98 6 -3 11 22.91* 22.02 7 -3 -15 12.21* 18.50 7 -3 -14 72.40 75.84 7 -3 -13 65.56 68.01 7 -3 -12 64.22 66.09 7 -3 -11 30.10 27.47 7 -3 -10 12.92* 10.94 7 -3 -9 6.32* 2.29 7 -3 -8 58.49 55.92 7 -3 -7 51.99 55.75 7 -3 -6 210.19 196.30 7 -3 -5 183.33 181.59 7 -3 -4 137.07 137.86 7 -3 -3 32.82 34.96 7 -3 -2 73.66 66.54 7 -3 -1 81.36 92.35 7 -3 0 182. 19 195.99 7 -3 1 128.20 136.95 7 -3 2 132.29 137.97 7 -3 3 19.30* 35.25 7 -3 4 80.25 92.36 7 -3 5 79.07 83.87 7 -3 6 70.44 67.93 7 -3 7 90.00 89.08 H K L FO FC 7 -3 8 45.31 45.45 7 -3 9 46.67 43.84 7 -3 10 15.34* 1 1.07 8 -3 -15 78.60 81.48 8 -3 -14 8.88* 11.61 8 -3 -13 20.74* 20.82 8 -3 -12 63.73 70.69 8 -3 -11 75.68 85.08 8 -3 -10 27.87 24.48 8 -3 -9 18.34* 8.87 8 -3 -8 194.60 200.24 8 -3 -7 36. 26 41.16 8 -3 -6 71.51 67.44 8 -3 -5 0.02* 12. 36 8 -3 -4 43.76 43.65 8 -3 -3 39.98 39.63 8 -3 -2 111.51 118.34 8 -3 -1 22.67* 23.93 8 -3 0 65.80 73.31 8 -3 1 27.51* 29.96 8 -3 2 107.89 106.42 8 -3 3 67.00 66.59 8 -3 4 109.76 116.21 8 -3 5 93. 10 96.57 8 -3 6 60.77 58.44 8 -3 7 98.58 106.02 8 -3 8 20. 19* 22. 18 8 -3 9 17.80* 14.76 8 -.3 1.0 46.77 .51.61 9 -3 -15 18.87* 4. 15 9 -3 -14 91.74 93.72 9 -3 -13 78.48 87. 13 9 -3 -12 15.84* 6.24 9 -3 -11 30.89 35.78 9 -3 -10 48.94 49.91 9 -3 -9 93.63 99.25 9 -3 -8 82.74 81.91 9 -3 -7 36.51 37.34 9 -3 -6 88.89 89.58 9 -3 -5 61.84 58.37 9 -3 -4 34.42 29.73 9 -3 -3 100.87 111.73 9 -3 -2 212.82 226.53 9 -3 -1 36.75 38.31 9 -3 0 113.20 114.07 9 -3 1 0.00* 5.17 9 -3 2 34.20 32.95 9 -3 3 30.62* 22.05 9 -3 4 19.31* 13.62 9 -3 5 90.63 102.02 9 -3 6 33.79* 31.90 9 -3 7 6.59* 13.96 9 -3 8 51.44 52.71 9 -3 9 13.71* 27.03 10 -3 -15 21.02* 31.09 10 -3 -14 45. 10 51.27 10 -3 -13 41.78 37.72 10 -3 -12 7.77* 14.49 H K L FO FC 10 -3 -11 109.62 114.85 10 -3 -10 89.48 92.54 10 -3 -9 29.35 38.55 10 -3 -8 107.99 108.70 10 -3 -7 1 16.66 118.87 10 -3 -6 12.56* 10.27 10 -3 -5 52.78 55. 19 10 -3 -4 143.69 149.82 10 -3 -3 32.04* 21.23 10 -3 -2 56.76 57.20 10 -3 -1 43.33 38.48 10 -3 0 45.56 48. 18 10 -3 1 52. 18 53.80 10 -3 2 17.36* 0.38 10 -3 3 27.93* 5. 15 10 -3 4 91.92 93.42 10 -3 5 21.92* 14.47 10 -3 6 50.95 50.09 10 -3 7 24.22* 25.45 11 -3 -15 8.01* 10.95 1 1 -3 -14 0.00* 18.53 11 -3 -13 53.24 56.71 11 -3 -12 22. 14* 19.21 11 -3 -11 16.63* 12.18 11 -3 -10 33.76 23.58 11 -3 -9 94.98 96.67 11 -3 -8 87.23 83.96 11 -3 -7 11.96* 24.20 11 _ 2 -6 38.57 40.. ,7 6 11 -3 -5 64.30 64.61 11 -3 -4 155.59 166.58 11 -3 -3 24.59* 15.48 11 -3 -2 87.92 98.33 11 -3 -1 75.77 85.33 11 -3 0 37.88 33.56 11 -3 1 89.33 89.68 11 -3 2 65. 25 70.78 1 1 -3 3 41.45 37.35 11 -3 4 22.55* 19.83 11 -3 5 0.00* 2.72 11 -3 6 51.39 40.22 12 -3 -14 14.20* 15.59 12 -3 -13 0.00* 8.80 12 -3 -12 21.27* 24.30 12 -3 -11 23.47* 23.65 12 -3 -10 103.49 111.95 12 -3 -9 52.89 52.51 12 _3 -8 0.00* 8.56 12 -3 -7 74.69 80.31 12 -3 -6 79.31 87.65 12 -3 -5 " 23.94* 14.91 12 -3 -4 0.00* 18.62 12 -3 -3 73.25 79.48 12 -3 -2 29.62* 32. 13 12 -3 -1 70.16 71.31 12 -3 0 50.25 4 4. 13 12 -3 1 37.97 37.47 12 -3 2 91.06 89.52 H K L FO FC 12 -3 3 39.74 33.20 12 -3 4 39.69 34.24 12 -3 5 35.95* 40.91 13 -3 -13 26.68* 35.27 13 -3 -12 44.21 49. 80 13 -3 -11 18.76* 11.92 13 -3 -10 56.04 50.02 13 -3 -9 51.48 43.79 13 -3 -8 34.09 31.82 13 -3 -7 27.52* 24.25 13 -3 -6 67.68 59.49 13 -3 -5 34.81* 42.44 13 -3 -4 124.78 124.47 13 -3 -3 19.18* 6.70 13 -3 -2 38.07 33.26 13 -3 -1 32.31 29.24 13 -3 0 85.45 83.44 13 -3 1 37.01 31.84 13 -3 2 18.06* 6.46 13 -3 3 72. 38 65.30 14 -3 -12 73. 28 75.03 14 -3 -11 26.30* 22.62 14 -3 -10 32.85 27.51 14 -3 -9 27.26* 7.38 14 -3 -8 36.43 39.29 14 -3 -7 32.68* 14.53 14 -3 -6 75.26 82.78 14 -3 -5 36.92* 34.64 '14 -3 -4 26.20* 24.66 14 -3 -3 26.36* 18.84 14 -3 -2 51.82 49.37 14 -3 -1 26.83* 3.75 14 -3 0 51.39 48.94 14 -3 1 48.42 44.75 15 -3 -10 19.66* 26.78 15 -3 -9 49. 48 45.98 15 -3 -8 29.47* 3.57 15 -3 -7 0.00* 18. 32 15 -3 -6 99. 19 97.51 15 -3 -5 29.47* 10.43 15 -3 -4 25.60* 33. 18 15 -3 -3 0.00* 16.57 15 -3 -2 34.17* 42.79 15 -3 -1 22.50* 5.62 0 -4 0 368.82 341.67 0 -4 1 147.33 134.08 0 -4 2 181.35 157.81 0 -4 3 46.87 45.82 0 -4 4 140.06 135.62 0 -4 5 17.27* 5.40 0 -4 6 20.75* 31.33 0 -4 7 160.17 157.40 0 -4 8 53.95 48. 19 0 -4 9 0.00* 15.83 0 -4 10 42.70 47.77 0 -4 11 30. 12 31.18 0 -4 12 62.73 57.72 0 -4 13 22.58* 18.52 H F L FO FC 0 -4 14 77.68 77.81 1 -4 -15 18.68* 16.25 1 -4 -14 7.34* 9.27 1 -4 -13 47.43 50.78 1 -4 -12 22.46* 17.87 1 -4 -11 74.39 67.28 1 -4 -10 21.47* 21.93 1 -4 -9 134.50 128.20 1 -4 -8 121.71 124.64 1 -4 -7 63.75 61.18 1 -4 -6 36.55 39.53 1 -4 -5 99.80 100.34 1 -4 -4 115.56 129.02 1 -4 -3 176.97 178.46 1 -4 -2 146.24 129.47 1 -4 -1 123.81 113.42 1 -4 0 36.42* 39.47 1 -4 1 97.77 102.62 1 -4 2 319.79 314.07 1 -4 3 62.17 60.95 1 -4 4 109.03 117.49 1 -4 5 13.57* 8.08 1 -4 6 169.82 158.82 1 -4 7 47.20 50.73 1 -4 8 23.09 20. 12 1 -4 9 19.57* 6.07 1 -4 10 35.87 40.40 1 -4 11 16.20* 5.16 1 -4 12 4.0 0* 3.17 1 -4 13 85.43 88.92 1 -4 14 59.55 61.61 2 -4 -15 27.22* 16.61 2 -4 -14 97.22 94.65 2 -4 -13 27.98 25.99 2 -4 -12 32.40 35.44 2 -4 -11 61.57 58. 15 2 -4 -10 92.83 89.09 2 -4 -9 91.91 90.80 2 -4 -8 58.17 64.74 2 -4 -7 1 12.96 112.28 2 -4 -6 35.48 27.84 2 -4 -5 17.40* 13.01 2 -4 -4 92.62 76. 13 2 -4 -3 144.19 141.42 2 -4 -2 240.62 217.67 2 -4 -1 35.21 39.87 2 -4 0 243.77 268.59 2 -4 1 74.96 79.58 2 -4 2 78.79 84.96 2 -4 3 179.62 184.56 2 -4 4 131.30 134.86 2 -4 5 9.74* 8.69 2 -4 6 38.34 32.23 2 -4 7 45.78... 41.79 2 -4 8 54.06 55.74 2 -4 9 12.20* 13.79 2 -4 10 114. 14 112.47 2 -4 11 38.37 39.51 H K L FO FC 2 -4 12 88. 19 89.28 2 -4 13 15.68* 16.48 3 -4 -15 34.87 30.28 3 -4 -14 11.45* 6.72 3 -4 -13 23.90 16.46 3 -4 -12 74.08 75.80 3 -4 -1 1 11.58* 4.54 3 -4 -10 99.49 102.54 3 -4 -9 28.83 24.93 3 -4 -8 63.20 64.24 3 -4 -7 70.26 73.44 3 -4 -6 71.12 69. 18 3 -4 -5 116.85 104.26 3 -4 -4 146. 10 122.56 3 -4 -3 195.24 185.25 3 -4 -2 13.62* 13.73 3 -4 -1 228.64 225.76 3 -4 0 113.48 134.79 3 -4 1 151.73 167. 14 3 -4 2 15.52* 8.23 3 -4 3 52. 15 49.39 3 -4 4 51.92 38.47 3 -4 5 9.96* 3.54 3 -4 6 152.68 155.37 3 -4 7 24.84 24. 15 3 -4 8 71. 14 79.91 3 -4 9 77.84 76.73 3 -4 10 39.22 36.61 3 -4 1 1 31.49 29.00 3 -4 12 50.99 58.60 3 -4 13 17.77* 3.77 4 -4 -15 32.66 32.92 4 -4 -14 65.81 68.6 1 4 -4 -13 29.90 26. 13 4 -4 -12 42.60 43.01 4 -4 -1 1 58. 46 63.22 4 -4 -10 69. 22 71.33 4 -4 -9 9.74* 5.06 4 -4 -8 50.16 51.74 4 -4 -7 94.56 96.66 4 -4 -6 69.05 74.33 4 -4 -5 82. 11 .89.87 4 -4 -4 320.43 306.85 4 -4 -3 76. 65 73. 16 4 -4 -2 177.93 159.28 4 -4 -1 18.47* 5.68 4 -4 0 38.99* 37.38 4 -4 1 67. 26 68.63 4 -4 2 111.88 109.05 4 -4 3 84. 13 90.84 4 -4 4 134.36 130.21 4 -4 5 148.40 144.07 4 -4 6 43.73 35. 10 4 -4 7 121.66 117.79 4 -4 8 63.78 58.75 4 -4 9 0.00* 5.40 4 -4 10 61.91 68.94 4 -4 11 14.92* 10.53 H K L FO FC 4 -4 12 32.29 20.97 5 -4 -15 7.08* 13.75 5 -4 - 14 21.21* 19.16 5 -4 -13 33. 17 36.63 5 -4 -12 20.25* 18.96 5 -4 -11 24.96 13.75 5 -4 -10 62. 34 67.54 5 -4 -9 0.00* 1.74 5 -4 -8 66.60 71.53 5 -4 -7 29. 86 3 5.68 5 -4 -6 247.39 230.85 5 -4 -5 109.95 110.08 5 -4 -4 59.63 54.36 5 -4 -3 22.28* 18.94 5 -4 -2 138.38 145.88 5 -4 -1 100.38 104.88 5 -4 0 83.36 93.79 5 -4 1 82.85 88.71 5 -4 2 99. 12 115.08 5 -4 3 144.37 151.81 5 -4 4 105.89 108.5 3 5 -4 5 64. 96 72.24 5 -4 6 29.35 38.34 5 -4 7 32.42 31.54 5 -4 8 31.77 29.22 5 -4 9 52.73 50.87 5 -4 10 0.00* 18.45 5 -4 11 27.32* 26.28 6 -4 -15 6. 10* 11.15 6 -4 - 14 0.00* 2.39 6 -4 -13 7.47* 14.01 6 -4 -12 64.88 62.42 6 -4 -11 113.65 120.39 6 -4 -10 13.84* 21.21 6 -4 -9 0.00* 1.90 6 -4 -8 66.09 61.78 6 -4 -7 137.57 140.28 6 -4 -6 105.52 101.61 6 -4 -5 50.97 48.87 6 -4 -4 205.87 189.87 6 -4 -3 62.80 63.92 6 -4 -2 101.57 107.33 6 -4 -1 18.89* 8.03 6 -4 0 240.72 265.91 6 -4 1 22.16* 29.20 6 -4 2 82.89 92. 17 6 -4 3 57.66 58.69 6 -4 4 23.24* 24.70 6 -4 5 15.22* 17.57 6 -4 6 43.31 44.85 6 -4 7 28.94 34.96 6 -4 8 30.74 34.06 6 -4 9 63. 88 62.77 6 -4 10 31.30 37.00 6 -4 11 46. 13 41.59 7 -4 -15 28.55 30.69 7 -4 -14 27.91 29.32 7 -4 -13 85.01 89.63 H K L FO FC 7 -4 -12 53.22 57.36 7 -4 -11 15.13* 22.81 7 -4 -10 18.47* 4.96 7 -4 -9 55.04 50.98 7 -4 -8 73.86 74.55 7 -4 -7 56.73 56.46 7 -4 -6 91.05 96.94 7 -4 -5 116.02 1 17.32 7 -4 -4 1 1.86* 15.63 7 -4 -3 22.24* 14.94 7 -4 -2 185.71 176.70 7 -4 -1 130.90 145.04 7 -4 0 43. 47 52.39 7 -4 1 7. 11* 6.48 7 -4 2 132.86 127.00 7 -4 3 61.07 68.37 7 -4 4 19.45* 2.13 7 -4 5 10.50* 12.0 1 7 -4 6 90.87 85.21 7 -4 7 31.09 21.72 7 -4 8 19.93* 9.96 7 -4 9 59.57 54.64 7 -4 10 54.62 57.55 8 -4 -15 14.40* 11.88 8 -4 -14 92. 06 92.53 8 -4 -13 0.00* 8.66 8 -4 -12 15.25* 6.68 8 -4 -11 26. 14 22.36 8 -4 -TO 26.41 24.03 8 -4 -9 10.77* 7.08 8 -4 -8 45. 22 44.29 8 -4 -7 165.10 158.65 8 -4 -6 132.50 126.59 8 -4 -5 23.41* 25.03 8 -4 -4 86.84 88. 63 8 -4 -3 110.54 1 17.96 8 -4 -2 122.29 129.33 8 -4 -1 103.47 110.51 8 -4 0 140.98 151.75 8 -4 1 33.89 36.24 8 -4 2 59.94 58.32 8 -4 3 0.00* 2.63 8 -4 4 73.36 82.22 8 -4 5 32.25 36.38 8 -4 6 .36.20 40. 82 8 -4 7 22.28* 26.42 8 -4 8 64.13 56.84 •8 -4 9 0.00* 2.00 9 -4 -15 23.23* 22.74 9 -4 -14 15.39* 20.3 4 9 -4 -13 6.35* 12.59 9 -4 -12 45.48 49.94 9 -4 -11 68. 30 65.26 9 -4 -10 47.89 51.42 9 -4 -9 53.06 48.31 9 -4 -8' 146.61 150.96 9 -4 -7 42.29 40.92 9 -4 -6 43.89 41.33 H K L FO FC 9 -4 -5 72.99 68.92 9 -4 -4 98. 59 97. 16 9 -4 -3 87.88 87.07 9 -4 -2 11.23* 13.56 9 -4 -1 97.06 101.95 9 -4 0 39.97 35.42 9 -4 1 3.70* 21.80 9 -4 2 78. 14 82.93 9 -4 3 66.74 64.85 9 -4 4 74.03 72.30 9 -4 5 60.64 52.91 9 -4 6 44.55 48.02 9 -4 7 0.00* 7.98 9 -4 8 37.75 35.09 10 -4 -14 52.41 59. 10 10 -4 -13 20.89* 1G.45 10 -4 -12 0.00* 3.74 10 -4 -11 24.51* 18.68 10 -4 -10 59.52 58.66 10 -4 34.39 37.74 10 -4 -8 121.83 126. 13 10 -4 -7 34.94 31.82 10 -4 -6 73.91 82.00 10 -4 -5 15.21* 21.25 10 -4 -4 94.98 102.36 10 -4 -3 68.98 67.94 10 -4 -2 120.89 129.9 1 10 -4 -1 11.04* 20. 37 TO -4 0 54.30 52.42 10 -4 1 93.07 98.76 10 -4 2 52.98 53.97 10 -4 3 82.25 86.35 10 -4 4 22.31* 4.72 10 -4 5 39.40 39.08 10 -4 6 23.91* 17.64 10 -4 7 17.13* 5. 13 11 -4 -14 22.76* 18.09 11 -4 -13 19.23* 23.89 11 -4 -12 22.50* 16.71 11 -4 -11 18.02* 2.92 11 -4 -10 96.84 95.05 11 -4 -9 61.26 61.43 11 -4 -8 39.02 42.15 11 -4 -7 41.50 42.20 11 -4 -6 90.53 94.01 11 -4 -5 0.00* 4.42 11 -4 -4 84.03 90.95 11 -4 -3 44.06 44.73 11 -4 -2 68.65 74. 12 11 -4 -1 68.75 72.21 11 -4 0 54.64 48.03 11 -4 1 27.45* 26.72 11 -4 2 52.71 57.86 11 -4 3 22.13* 21.50 11 -4 4 4.29* 20.04 11 -4 5 13.20* 2.53 12 -4 -13 19.04* 6.49 12 -4 -12 14.57* 17.22 H K L FO FC 12 -4 -11 68. 38 69.64 12 -4 -10 12.88* 8.69 12 -4 -9 16.52* 5.16 12 -4 -8 57.24 56.00 12 -4 -7 41.51 29.42 12 -4 -6 24.79* 19.25 12 -4 -5 0.00* 14.03 12 -4 -4 153.80 156.62 12 -4 -3 32.92* 29.99 12 -4 -2 52.63 68.30 12 -4 -1 24.61* 9.53 12 -4 0 60. 14 60. 15 12 -4 1 0.00* 1 .87 12 -4 2 24.98* 18.30 12 -4 3 33.13 24.96 12 -4 4 24.20* 17.23 13 -4 -12 37.23 37. 10 13 -4 -11 25.40* 22.40 13 -4 -10 38.75 30.66 13 -4 -9 50.59 46.66 13 -4 -8 12.13* 11.23 13 -4 -7 20.36* 7.63 13 -4 -6 92.61 96.39 13 -4 -5 110.00 109. 10 13 -4 -4 17.27* 8.46 13 "4 -3 0.00* 5.57 13 -4 -2 55.66 59.91 13 -4 -1 13.87* 3.24 .13 -4 .0 23.89* 16.81 13 -4 1 17.50* 3.71 13 -4 2 62.25 62.44 14 -4 -11 48.47 48.00 14 -4 -10 43.87 40.91 14 -4 -9 11.62* 17.27 14 -4 -8 15.66* 2.85 14 -4 -7 63.15 64.92 14 -4 -6 68.67 71.64 14 -4 -5 34.12* 15.32 14 -4 -4 58.32 60.95 14 -4 -3 27.15* 31.18 14 -4 -2 18.59* 12.25 14 -4 -1 25.36* - 8.29 14 -4 0 70.70 69.47 15 -4 -8 66.04 71.23 15 -4 -7 28.25* 18.88 15 -4 -6 0.00* 9.49 15 -4 -5 59.54 58.96 15 -4 -4 40.05 27.68 0 -5 1 128. 16 139.97 0 -5 2 180.36 184.42 0 -5 3 75.80 67.41 0 -5 4 0.00* 5.28 0 -5 5 57.08 64.73 0 -5 6 0.00* 9.53 0 -5 7 22.62* 17.48 0 -5 8 37.52 36.59 0 -5 9 123.81 129.89 0 -5 10 15.00* 5.63 H K L FO FC 0 -5 11 20.31* 27. 16 0 -5 12 35.30 32.79 0 -5 13 101.92 98.39 1 -5 -14 29.34 21.19 1 -5 -13 36.72 39.87 1 -5 -12 14.25* 7.00 1 -5 -11 73.30 75.45 1 -5 -10 27.10 22. 19 1 -5 -9 79.49 88.63 1 -5 -8 83. 16 87.00 1 -5 -7 178.41 171.09 1 -5 -6 51.26 58.22 1 -5 -5 96.81 92.46 1 -5 -4 71.75 70.38 1 -5 -3 187.98 186.39 1 -5 -2 25.61 26.06 1 -5 -1 48.29 46.92 1 -5 0 1 16.40 121.48 1 -5 1 83.39 88.44 1 -5 2 25.37 14.95 1 -5 3 70.09 77.91 1 -5 4 112.23 103.31 1 -5 5 111.97 115.58 1 -5 6 .11.52* 22.61 1 -5 7 159.50 162.95 1 -5 8 15.71* 25.03 1 -5 9 65.72 66.03 1 -5 10 50.87 56.59 1 -5 11 52.0.9 ..59.4 3 1 -5 12 20.00* 9.11 1 -5 13 5. 19* 3.87 2 -5 -14 6.46* 4.88 2 -5 -13 41.86 41.23 2 -5 -12 26. 11 21.59 2 -5 -11 26.38 30.6 1 2 -5 -10 27.63 23.63 2 -5 -9 1 12.91 119. 19 2 -5 -8 62.51 66.28 2 -5 -7 22.21 27.51 2 -5 -6 94.54 105.82 2 -5 -5 171.16 165.71 2 -5 -4 42. 11 35.54 2 -5 -3 163.31 170.32 2 -5 -2 17.45* 3.36 2 -5 -1 151.10 148.33 2 -5 0 28.78* 40.61 2 -5 1 12.23* 19.69 2 -5 2 152.55 150.78 2 -5 3 132.73 139.58 2 -5 4 37.49 29.75 2 -5 5 7.23* 4.51 2 -5 6 44.28 43.27 2 -5 7 104.81 110.91 2 -5 8 42.19 42.83 2 -5 9 35.69 32.94 2 -5 10 17.18* 10.74 2 -5 11 41.51 44.04 2 -5 12 37.06 41.61 H K L FO FC 2 -5 13 59.41 57.58 3 -5 -14 36.77 34.26 3 -5 -13 19.44* 11.73 3 -5 -12 17.70* 6.07 3 -5 -11 20.21* 20.05 3 -5 -10 14. 19* 21.86 3 -5 -9 132.57 134.10 3 -5 -8 57.28 61. 14 3 -5 -7 158.51 157.30 3 -5 -6 17.76* 13.69 3 -5 -5 102.01 100.66 3 -5 -4 112.04 120.16 3 -5 -3 106.73 101.34 3 -5 -2 34.76 20.98 3 -5 -1 0.00* 10.71 3 -5 0 5.97* 27.69 3 -5 1 99.48 104.52 3 -5 2 9.65* 3.4 3 3 -5 3 182.58 188.14 3 -5 4 71.15 69.08 3 -5 5 170.60 166.78 3 -5 6 5.72* 8.03 3 -5 7 71.72 67.92 3 -5 8 28.09 28.62 3 -5 9 47.68 52.58 3 -5 10 6.47* 3.05 3 -5 11 37.19 35.99 3 -5 12 16.42* 8.32 4 -5 -14 23,31* 8.76 4 -5 -13 0.00* 10.85 4 -5 -12 71.67 75.70 4 -5 -11 94.42 104.27 4 -5 -10 9.56* 2.53 4 -5 -9 13.51* 3.46 4 -5 -8 31.21 29.30 4 -5 -7 31.05 31.28 4 -5 -6 103. 15 102.09 4 -5 -5 12.71* 4.21 4 -5 -4 0.00* 7.00 4 -5 -3 101.49 96.97 4 -5 -2 96.88 84.90 4 -5 -1 150.00 151.89 4 -5 0 70.95 82.46 4 -5 1 172.43 198.76 4 -5 2 45.92 48.07 4 -5 3 68.05 71.78 4 -5 4 70.84 73.41 4 -5 6 45.46 50.69 4 -5 7 48.36 49.90 4 -5 8 26.35 22.33 4 -5 9 52.89 60.05 4 -5 10 12.48* 14.28 4 -5 11 82.67 83.68 5 -5 -15 25.01* 35.32 5 -5 -14 40.09 42.43 5 -5 -13 32.49 27.60 5 -5 -12 8.39* 0.21 5 -5 -11 129.87 132.89 H K L FO FC 5 -5 -9 64.44 74.36 5 -5 -8 24.89 29.90 5 -5 -7 14.63* 12.35 5 -5 -6 35.27 28.87 5 -5 -5 1 19.45 116.20 5 -5 -4 129.15 123.34 5 -5 -3 88.69 78.22 5 -5 -2 48.01 39.94 5 -5 -1 80.66 83.39 5 -5 0 97.94 109.59 5 -5 1 71.91 76.04 5 -5 2 29.95* 33.27 5 -5 3 1 15.28 122.67 5 -5 4 14.31* 5.08 5 -5 5 69.78 77.81 5 -5 6 32.52 28.79 5 -5 7 118. 10 120.73 5 -5 8 26.47* 2 1.14 5 -5 9 81.79 79.66 5 -5 10 23.87* 13.65 5 -5 11 46.72 45.66 6 -5 -15 15.73* 9.28 6 -5 -14 0.00* 5.89 6 -5 -12 24.28* 31.99 6 -5 -11 34.80 38.35 6 -5 -10 57.73 61.11 6 -5 -9 34. 10 32.80 6 -5 -8 43.59 43.95 6 -5 -7 50.03 54.92 6 -5 -6 26.65* 26.43 6 -5 ' -5 118.16 120.83 6 -5 -3 54.56 52.82 6 -5 -2 166.57 173.31 6 -5 -1 93.36 97.51 6 -5 0 48.02 53.26 6 -5 1 66.13 67.94 6 -5 2 25.02* 28. 12 6 -5 3 51.93 52.66 6 -5 4 4.43* 10.30 6 -5 5 105.36 108.89 6 -5 6 25.49* 18.85 6 -5 7 20.83* 22.57 6 -5 8 42.57 48.73 6 -5 9 89.02 84.52 6 -5 10 22.06* 14.49 7 -5 -14 8.63* 4.75 7 -5 -13 29.66 33. 12 7 -5 -12 34.22 39.23 7 -5 -11 106.76 111.18 7 -5 -10 19.21* 12.99 7 -5 -9 29.66 33.87 7 -5 -8 27.58 20.20 7 -5 -7 193.64 184.79 7 -5 -6 14.30* 7.55 7 -5 -5 35.87 29.30 7 -5 -4 47.30 49.41 7 -5 -3 45.20 41.61 7 -5 -2 27.1 1* 27.30 H K L FO FC 7 -5 -1 33.68* 33.49 7 -5 0 80.41 93.59 7 -5 1 82.28 93. 17 7 -5 2 36. 11 35.54 7 -5 3 62.58 78.45 7 -5 4 53. 36 55.43 7 -5 5 91.96 95.47 7 -5 6 21.16* 32.70 7 -5 7 59.95 68.08 7 -5 8 23.94* 3.59 7 -5 9 20.51* 23.75 8 -5 -14 17.86* 6.93 8 -5 -13 86.87 88.45 8 -5 -12 4.07* 6.74 8 -5 -11 15.49* 8.65 8 -5 -10 40.76 35.71 8 -5 -9 100.08 109.76 8 -5 -8 21.87* 4.45 8 -5 -7 52. 38 56.07 8 -5 -4 23.64* 5.61 8 -5 -3 27.75* 23.89 8 -5 -2 65.54 70.28 8 -5 -1 147.63 163.08 8 -5 0 41.58 43.83 8 -5 2 66.82 75.31 8 -5 3 101.12 102.30 8 -5 4 20.28* 12.18 8 -5 5 34. 37 28.86 8 -5 .6 15.64* 3.47 8 -5 7 31.84* 35.26 8 -5 8 7.04* 22.00 9 -5 -14 28.32* 26.86 9 -5 -13 59. 10 62.89 9 -5 -12 24.63* 22.3 1 9 -5 -11 36.88 37.09 9 -5 -10 29.93 25.57 9 -5 -9 69.58 73.91 9 -5 -8 74. 11 76.34 9 -5 -7 104.03 104.59 9 -5 -6 0.00* 6.49 9 -5 -5 1 27.35* 28.00 9 -5 -4 13.72* 21.62 9 -5 -3 99.05 99.84 9 -5 -2 27.86* 19.89 9 -5 -1 81.34 94.01 9 -5 0 28.22* 23.76 9 -5 1 99.95 100.15 9 -5 2 27.03* 26.46 9 -5 3 60.30 68.65 9 -5 4 40.28 31.50 9 -5 5 82.33 91.50 9 -5 6 0.00* 15.01 9 -5 7 40.55 39. 89 10 -5 -13 6.72* 8.04 10 -5 -12 24.02* 31.44 10 -5 -11 31.43 33.64 10 -5 -10 27.36* 30.72 10 -5 -9 20.05* 15.56 H K L FO FC 10 -5 -8 0.00* 6.36 10 -5 -7 30.03 28. 13 10 -5 -6 76.93 74.59 10 -5 -5 40.91 44.60 10 -5 -4 49.20 50. 19 10 -5 -3 110.55 113.83 10 -5 -2 32.79* 46.00 10 -5 -1 59.82 66.28 10 -5 0 28.28* 11.39 10 -5 1 31.85* 38.55 10 -5 2 35.28 24.28 10 -5 3 54.30 62.02 10 -5 4 45.71 36.89 10 -5 5 28.97* 35.29 10 -5 6 0.00* 2.30 11 -5 -13 19.32* 26.53 11 -5 -12 24.62* 18.34 11 -5 -11 37.00 44.18 11 -5 -10 32.00 24.49 11 -5 -9 82.24 86.4 1 11 -5 -8 34.71 38.07 11 -5 -7 22.37* 15.40 11 -5 -6 38.44 39.22 11 -5 -5 35.28 39. 10 11 -5 -4 73.69 73.63 11 -5 -3 39.41 29.42 11 -5 -2 24.92* 12.37 11 -5 -1 40.24 32.81 11 -5 0 30.73* 22.7 1 11 -5 1 20.10* 25.39 11 -5 2 8.80* 5.97 11 -5 3 100.56 99.40 11 -5 4 10.43* 2.64 12 -5 -12 6.77* 20.20 12 -5 -11 47.45 51.86 12 -5 -10 11.79* 14.79 12 -5 -9 50.97 54.53 12 -5 -8 13.72* 5.23 12 -5 -6 40.62 45. 15 12 -5 -5 66.93 70.47 12 -5 -4 31.59* 33.70 12 -5 -3 46.77 45.24 12 -5 -2 38. 10 41.88 12 -5 -1 19.20* 9.36 12 -5 0 20.59* 31.26 12 -5 1 59.16 64.09 12 -5 2 14.16* 15.69 12 -5 3 0.00* 3.63 13 -5 -11 89.12 94.34 13 -5 -10 25.47* 8.40 13 -5 -9 • 34.04 31.45 13 -5 -8 0.00* 13.19 13 -5 -7 48.68 44. 17 13 -5 -6 34.73* 20.99 13 -5 -5 34.55* 16.79 13 -5 -4 27.55* 26.85 13 -5 -3 37.35 43.96 13 -5 -2 28.55* 28.21 H K L FO FC 13 -5 -1 17.99* 16.86 13 -5 0 33.75* 42.80 13 -5 1 78.79 78.23 14 -5 -8 8.50* 11.32 14 -5 -7 22.81* 3.70 14 -5 - 6 23.90* 5. 18 14 -5 -5 91. 38 88.75 14 -5 -4 0.00* 8.10 14 -5 -3 25.49* 9.30 14 -5 -2 37. 11 33.49 0 -6 0 78.57 71.71 0 -6 1 17.46* 20.58 0 -6 2 78.48 78.62 0 -6 3 59.40 61.77 0 - 6 4 15. 11* 6.82 0 - 6 5 122.47 117.76 0 -6 6 64.77 66.50 0 - 6 7 100.57 106.49 0 -6 8 45.52 45.83 0 - 6 9 24.54* 22. 17 0 -6 10 36. 36 36.88 0 - 6 1 1 44.82 47.70 0 - 6 12 75. 22 74.61 1 - 6 -13 25.18* 27.71 1 -6 -12 47.49 42.93 1 - 6 -11 21.44* 20.88 1 -6 -10 11.26* 16.68 1 - 6 -9 115.48 114.44 -6 -8 131. 15 132.28 1 -6 -7 24.71 23.46 1 -6 -6 111.13 116.05 1 - 6 -5 75.05 76.23 1 -6 -4 47.87 42.65 1 -6 -3 0.00* 3.71 1 -6 -2 7.63* 20.07 1 -6 -1 28.68 23.67 1 - 6 0 0.00* 36.49 1 -6 1 60.32 54.29 1 -6 2 81.33 82.81 1 -6 3 135.31 136.24 1 -6 4 54. 17 55.35 1 - 6 5 15.98* - 6.09 1 -6 6 85.59 83.76 1 -6 7 75. 17 75.47 1 - 6 8 63.05 63. 13 1 - 6 9 49.23 49.00 1 - 6 10 36. 18 43.94 1 -6 1 1 15.67* 3.98 1 - 6 12 40. 39 39.92 2 -6 -13 33.55 35.22 2 - 6 -12 30.83 30. 14 2 - 6 -11 59.75 54.08 2 - 6 -10 47.44 47.98 2 -6 -9 102.44 103.62 2 - 6 -8 69.48 66.32 2 - 6 -7 77.28 78.23 2 - 6 - 6 83.29 76.35 2 -6 -5 33.73 33.38 H K L FO FC 2 -6 -4 10.48* 9.03 2 -6 -3 74.07 67.7 1 2 -6 -2 202.02 182.14 2 -6 -1 16.85* 8.61 2 -6 0 33.65* 35.05 2 -6 1 75.79 80.55 2 -6 2 74. 18 74.64 2 -6 3 1 17.41 109.94 2 -6 4 20.40* 5.08 2 -6 5 89.76 90.23 2 -6 6 21.41* 22.40 2 -6 7 19.60* 21.50 2 -6 8 18.87* 19.10 2 -6 9 70.01 75. 17 2 -6 10 18.91* 13.07 2 -6 11 40.55 40.68 2 -6 12 52.94 51.85 3 -6 -13 9. 86* 6.92 3 -6 -12 19.49* 16.78 3 -6 -11 93.43 93.00 3 -6 -10 23.15* 26. 17 3 -6 -9 13.33* 17.22 3 -6 -8 100.75 106.87 3 -6 -7 32.64 34.46 3 -6 -6 63. 53 61.01 3 -6 -5 90.05 91.34 3 -6 -4 134.85 127.05 3 -6 -3 58.73 47.05 3 D -2 / J. Oo 6 3.57 3 -6 -1 41.28 35.79 3 -6 0 47.41 59.14 3 -6 1 73. 30 87.90 3 -6 2 60.69 66.07 3 -6 3 32.45 25.81 3 -6 4 154.58 159.53 3 -6 5 15.12* 23.08 3 -6 6 0.00* 4.79 3 -6 7 107.92 109.91 3 -6 8 41.93 41.57 3 -6 9 12.37* 12.71 3 -6 10 33.83 27.98 3 -6 11 55.04 51.25 4 -6 -13 29.25 33. 19 4 . -6 -12 33.38 35.95 4 -6 -11 24.11* 27.87 4 -6 -10 19.88* 24.07 4 -6 -9 80.05 84.24 4 -6 -8 19.39* 24.56 4 -6 -7 86.84 80.56 4 -6 -6 9.56* 12.96 4 -6 -5 109.06 105.78 4 -6 -4 20.83* 6.22 4 -6 -3 27.09 22.68 4 -6 -2 128.55 128.83 4 -6 -1 17.11* 18.91 4 -6 0 21.51* 13.38 4 -6 1 33.26 15.09 4 -6 2 117.58 123.28 H K L FO FC 4 -6 3 75.03 73.82 1 -6 4 0.00* 5.97 4 . -6 5 85.99 92.28 4 -6 6 56.90 50.77 4 -6 7 80. 19 80.55 4 -6 8 33.61 36.74 4 -6 9 51.86 51.68 4 -6 10 65.98 67.69 5 -6 -13 37. 32 38.28 5 -6 -12 48.78 52. 18 5 -6 -11 63.59 61.03 5 -6 -10 82.83 87.78 5 -6 -9 19.90* 16.28 5 -6 -8 12. 1 1* 17.85 5 -6 -7 105.52 102.92 5 -6 -6 26. 34 25.97 5 -6 -5 13.98* 20.59 5 -6 -4 61.43 60.70 5 -6 -3 0.00* 22.26 5 -6 -2 56.72 64.31 5 -6 -1 21.12* 4.48 5 -6 0 17.81* 3.32 5 -6 1 53.83 62.96 5 -6 2 40.37 47.62 5 -6 3 17.60* 6.55 5 -6 4 89. 66 93. 34 5 -6 5 106.47 106.68 5 -6 6 37. 12 38.46 5 -6 7 11.86* 12.43 5 -6 8 86.76 88.25 5 -6 9 30.30* 25.56 5 -6 10 9.36* 4.00 6 -6 -13 14.08* 9.30 6 -6 -12 82.98 83.76 6 -6 -11 88.60 87.70 6 -6 -10 14.54* 19.88 6 -6 -9 56.63 52.33 6 -6 -8 21.52* 20.66 6 -6 -7 53.01 56. 10 6 -6 -6 73.86 69.00 6 -6 -5 40.97 40.08 6 -6 -4 62. 50 57.23 6 -6 -3 24.76* 15. 1 1 6 -6 -2 9.89* 24.65 6 -6 -1 45.00 46.71 6 -6 0 23.91* 11.45 6 -6 1 96.23 96.98 6 -6 2 61. 20 62.78 6 -6 3 65.93 67.34 6 -6 4 20.19* 6.23 6 -6 5 36.21 41.23 6 -6 6 31.76* 29.52 6 -6 7 45. 20 45.95 6 -6 8 52.96 54.82 6 -6 9 45.46 43.64 7 -6 --13 82.72 76.99 7 -6 --12 57.27 59.70 7 -6 --11 7.47* 12.24 H K L FO FC 7 -6 - 10 75.80 75.41 7 -6 -9 66.82 66.89 7 -6 -8 82. 35 84.42 7 -6 -7 39. 20 35.56 7 -6 -6 103.29 102.92 7 -6 -5 31.23 31.67 7 -6 -4 39.54 28. 17 7 -6 -3 59.21 55. 19 7 -6 -2 5.35* 23.72 7 -6 -1 86. 21 91.01 7 -6 0 49.28 62. 18 7 -6 1 16.97* 11.78 7 -6 2 4.44* 21.14 7 -6 3 68. 45 75.05 7 -6 4 13. 48* 14.85 7 -6 5 42.49 40.88 7 -6 6 43.95 46.69 7 -6 7 26.12* 22.08 7 -6 8 63. 33 54. 16 8 -6 -13 59.56 60.48 8 -6 -12 62.07 62. 11 8 -6 -11 54.88 54.94 8 -6 -10 30.75 27.28 8 -6 -9 4.06* 3.53 8 -6 -8 42.60 46.29 8 -6 -7 65.21 69.29 8 -6 -6 96.59 89.67 8 -6 -5 28.70* 26.28 8 -6 -4 46.08 37* 56 8 -6 -3 48.00 52.82 8 -6 -2 100.79 99.93 8 -6 -1 52.53 55.07 8 -6 0 36.82 49.60 8 -6 1 51.42 52.28 8 -6 2 36.87* ' 31.08 8 -6 3 19.81* 17.35 8 -6 4 22.12* 21.49 8 -6 5 69.36 82. 14 8 -6 6 31.62* 27.80 8 -6 7 46.71 41.43 9 -6 -13 13.38* 17.60 9 -6 -12 23.61* 19.00 9 -6 -11 34.43 40.42 9 -6 -10 0.00* 2.7 1 9 -6 -9 70.58 69.77 9 -6 -8 73.37 72.99 9 -6 -7 35.08 35.29 9 -6 -6 87.30 89.43 9 -6 -5 43. 89 38.93 9 -6 -4 34.18 41.23 9 -6 -3 • 37.02 35.10 9 -6 -2 18.74* 13.63 9 -6 -1 33.02* 24.74 9 -6 0 79.17 83. 12 9 -6 1 26.07* 17.26 9 -6 2 18.03* 18.72 9 -6 3 77.27 86. 19 9 -6 4 81.52 79.06 H K L FO FC 9 -6 5 38.31 27.43 9 -6 6 36.55 34.98 10 -6 -12 13.79* 15.70 10 -6 -11 29.27 22.06 10 -6 -10 7.03* 2.97 10 -6 -9 77.68 75.39 10 -6 -8 25.47* 11.12 10 -6 -7 22.12* 19.48 10 -6 -6 25.27* 22.31 10 -6 -5 0.00* 13.11 10 -6 -4 23.81* 3.98 10 -6 -3 0.00* 4.4 1 10 -6 -2 86.38 87.80 10 -6 -1 43.21 42.03 10 -6 0 34. 39 32. 14 10 -6 1 4 4.33 40.20 10 -6 2 34.94* 42.4 1 10 -6 3 71.93 70.65 10 -6 4 27.64* 9.99 11 -6 -11 58. 54 58.59 11 -6 -10 55.40 59.21 11 -6 -9 18.64* 9.89 11 -6 -8 35.92 31.50 11 -6 -7 30. 60 21.50 11 -6 -6 27.49* 16. 82 11 -6 -5 0.00* 9.40 11 -6 -4 0.00* 7.38 11 -6 -3 38.71* 45.45 11 -6 -2 10.7 8* 14.24 11 -6 -1 21.99* 10.27 11 -6 0 0.00* 21.18 11 -6 1 64.74- 56.64 11 -6 2 28.25* 27.79 11 -6 3 0. 00* 3.31 12 -6 -10 0.00* 16.48 12 -6 -9 36.80 40. 15 12 -6 -8 35.90 31.71 12 -6 -7 25. 19* 7.51 12 -6 -6 38. 19 37.52 12 -6 -5 28.84* 32. 12 12 -6 -4 22.88* 30.38 12 -6 -3 36.37* 43.79 12 -6 -2 18.80* 17.76 12 -6 -1 24.31* 22.97 12 -6 0 24.06* 6. 65 12 -6 1 47.25 39.93 13 -6 -8 27.84* 20. 17 13 -6 -7 32.09* 30.26 13 -6 -6 30.07* 33.64 13 -6 -5 33.99* 37.59 13 -6 -4 21.03* 18.49 13 -6 -3 8.76* 5.12 13 -6 -2 25.38* 2.36 0 -7 1 52.93 48.38 0 -7 2 49.36 52.21 0 -7 3 87. 14 82. 38 0 -7 4 25.54 21.80 0 -7 5 36.45 31.48 H K L FO FC 0 -7 6 79.01 83.67 0 -7 7 13.99* 21.05 0 -7 8 78. 16 75.97 0 -7 9 35.74 38.31 0 -7 10 47.49 44.17 0 -7 11 22.64* 29.71 1 -7 -12 54. 38 55.25 1 -7 -11 17.24* 11.79 1 -7 -10 43.87 44.50 1 -7 -9 14.60* 2.50 1 -7 -8 46.04 45.18 1 -7 -7 38.32 36.47 1 -7 -6 85.17 89.78 1 -7 -5 46.01 46.41 1 -7 -4 29.09 19.24 1 -7 -3 10.63* 7.06 1 -7 -2 165.21 158.59 1 -7 -1 17.30* 2.88 1 -7 0 1 11.67 113.86 1 -7 1 21.84* 3.61 1 -7 2 22.06* 20.71 1 -7 3 0.00* 10.46 1 -7 4 46.37 48.73 1 -7 5 20.40* 3.38 1 -7 6 27.47 22.90 1 -7 7 12.82* 6.03 1 -7 8 22.70* 22.89 1 -7 9 58.28 55.59 1 -7 10 0.00* 2.88 1 -7 11 2.59* 2.25 2 -7 -12 36.06 31.40 2 -7 -11 35.49 34.42 2 -7 -10 13.26* 8.48 2 -7 -9 17.01* 8.97 2 -7 -8 108.64 107.40 2 -7 -7 3.69* 6.60 2 -7 -6 51.17 55.27 2 -7 -5 46.77 36.92 2 -7 -4 123.34 121.84 2 -7 -3 52.87 53.30 2 -7 -2 69.75 62.85 2 -7 -1 122.51 110.52 2 -7 0 81.40 97.47 2 -7 1 11.96* 12.31 2 -7 2 20.46* 12.60 2 -7 3 13.00* 4.54 2 -7 4 83.58 88.94 2 -7 5 16.20* 16.55 2 -7 6 46.23 50.71 2 -7 7 77. 16 78.06 2 -7 8 28.96 21.22 2 -7 9 0.00* 8.98 2 -7 10 36.92 38.22 3 -7 -12 20.68* 2.37 3 -7 -11 21.66* 27.23 3 -7 -10 51.08 50.03 3 -7 -9 24.01* 22.14 3 -7 -8 10.40* 17.06 H K L FO FC 3 -7 -7 0.00* 11.40 3 -7 -6 49.42 48.03 3 -7 -5 0.00* 3.45 3 -7 -4 38.86 34.55 3 -7 -3 69.53 64.30 3 -7 -2 185.20 175.59 3 -7 -1 52.88 52.92 3 -7 0 34.18* 33.34 3 -7 1 17.12* 2.86 3 -7 2 120.09 124.90 3 -7 3 25.68* 21. 10 3 -7 4 35.55 29.07 3 -7 5 17.26* 8. 14 3 -7 6 39.54 42.22 3 -7 7 32.76 26. 30 3 -7 8 16.93* 20. 18 3 -7 9 3.49* 11.99 3 -7 10 54.78 52.27 4 -7 -12 2.92* 8.20 4 -7 -11 36.77 30.77 4 -7 -10 50.54 50.29 4 -7 -9 11.62* 17.44 4 -7 -8 36.53 38.47 4 -7 -7 61.74 57.76 4 -7 -6 18.35* 22.61 4 -7 -5 43. 16 39.68 4 -7 -4 108.19 105.40 4 -7 -3 88.58 80.23 •4 — / — 18.50* 1 8.0 0 4 -7 -1 47. 32 40. 86 4 -7 0 89.06 99.23 4 -7 1 11.54* 4.48 4 -7 2 22.12* 23.90 4 -7 3 63.75 72. 31 4 -7 4 107.40 116.00 4 -7 5 19.77* 20.60 4 -7 6 11.90* 17.55 4 -7 7 4 0.40 38. 12 4 -7 8 63.9 1 68.74 4 -7 9 31.02 31.16 5 -7 -12 55. 10 58.53 5 -7 -11 17.06* 3.29 5 -7 -10 17.94* 2.11 5 -7 -9 22.62* 15.68 5 -7 -8 16.75* 22.72 5 -7 -7 31.46 30.96 5 -7 -6 29. 16 23.90 .5 -7 -5 10.86* 12.67 5 -7 -4 74.84 75. 16 5 -7 -3 22.19* 2.22 5 -7 -2 72.39 71.90 5 -7 -1 22.38* 21.30 5 -7 0 37. 17 45.46 5 -7 1 37.92* 46.54 5 -7 2 98.81 110.08 5 -7 3 37.28 41.88 5 -7 4 12.99* 3.48 5 -7 5 11.14* 8.70 H K L FO FC 5 -7 6 44.89 45.31 5 -7 7 27.95* 1.01 5 -7 8 37.51 41.75 6 -7 -12 43.73 43.33 6 -7 -11 26.14* 21.92 6 -7 -10 72. 31 69.38 6 -7 -9 0.00* 1.38 6 -7 -8 56.91 55.91 6 -7 -7 87. 32 81.64 6 -7 -6 88.98 87.89 6 -7 -5 47.90 42.26 6 -7 -4 15.53* 3.33 6 -7 -3 17.83* 7.21 6 -7 -2 29.76* 32.95 6 -7 -1 0.00* 12.17 6 -7 0 0.00* 12.31 6 -7 1 65.60 58.27 6 -7 2 31.84* 43.41 6 -7 3 . 43.03 50.89 6 -7 4 38.20 43.16 6 -7 5 41.84 44. 36 6 -7 6 42. 59 38.86 6 -7 7 0.00* 0.51 7 -7 -12 61.63 64.77 7 -7 -11 20.23* 7.10 7 -7 -10 31.20 35.43 7 -7 -9 29.93 25.04 7 -7 -8 43.91 44.30 —* i -T — / -7 20.91* 10.35 1 -7 -6 92. 31 90.78 7 -7 -5 0.00* 6.29 7 -7 -4 75.79 77.26 7 -7 -3 25.79* 22.06 7 -7 -2 63.02 64.54 7 -7 -1 22.02* 9.66 7 -7 0 67.26 78.57 7 -7 1 22.28* 6.45 7 -7 2 25.04* 15.14 7 -7 3 21.64* 8.09 7 -7 4 19.74* 12.92 7 -7 5 36.73 35.06 7 -7 6 13.22* 6.65 8 -7 -11 20.48* 28.95 8 -7 -10 31.95 18.33 8 -7 -9 34. 83 36.87 8 -7 -8 93.37 92.33 8 -7 -7 23.29* 14.54 8 -7 -6 83.78 76.32 8 -7 -5 45.71 44.84 8 -7 -4 61.66 65.48 8 -7 -3 36.31* 40.37 8 -7 -2 59.50 46.24 8 -7 -1 35.49* 41.32 8 -7 0 58.83 68. 12 8 -7 1 33.39* 34.38 8 -7 2 37.78* 32.97 3 -7 3 55.52 55.70 8 -7 4 33.69* 43.59 H K L FO FC 8 -7 5 25.15* 1. 16 9 -7 -11 14.94* 14.19 9 -7 -10 28.50* 26. 15 9 -7 -9 0.00* 5.93 9 -7 -8 0. 00* 4.72 9 -7 -7 35.55 26.82 9 -7 -6 83.28 80. 19 9 -7 -5 9.83* 10.08 9 -7 -4 24.08* 24.36 9 -7 -3 0.00* 4.06 9 -7 , -2 103.50 1 10.42 9 -7 -1 33.09* 4.38 9 -7 0 49.63 56.31 9 -7 1 17.53* 12.04 9 -7 2 49.00 49.90 9 -7 3 0.00* 1.70 9 -7 4 0.00* 2.57 10 -7 -10 38.06 40.58 10 -7 -9 27.83* 23.87 10 -7 -8 56.90 52.87 10 -7 -7 23.03* 1.49 10 -7 -6 26. 16* 9.65 10 -7 -5 0.00* 12.26 10 -7 -4 61.13 58.74 10 -7 -3 26.53* 19.27 10 -7 -2 0.00* 14.65 10 -7 -1 66.56 68.91 10 -7 0 60.24 61.03 10 -7 i 1.2.9 0* 14.08 10 -7 2 5.56* 8.25 11 -7 -9 0.00* 6.46 11 -7 -8 46.98 39. 32 11 -7 -7 19.77* 0.68 11 -7 -6 0.00* 7.00 11 -7 -5 24.87* 14.89 11 -7 -4 22.25* 36.02 11 -7 -3 30.83* 28.32 11 -7 -2 58.58 62. 13 11 -7 -1 26.81* 8.04 11 -7 0 0.00* 8.68 12 -7 -6 51.52 47.64 12 -7 -5 37.51 26. 14 12 -7 -4 0.00* 8.99 0 -8 0 47.83 53.74 0 -8 1 42.74 35.52 0 -8 2 36.22 27.08 0 -8 3 22.26* 22.57 0 -8 4 31.84 35.70 0 -8 5 15.62* 13.88 0 -8 6 41.43 39.33 0 -8 7 83.50 •78.92 0 -8 8 24.07* 17.53 0 -8 9 24.95* 24. 10 1 -8 -10 31.12 27.30 1 -8 -9 36.72 34.54 1 -8 -8 29.70 24.11 1 -8 -7 12.04* 6. 19 1 -8 -6 12.88* 3.50 H K L FO FC ! -8 -5 49. 89 45.45 1 -8 -4 70.50 68.22 1 -8 -3 57. 19 60.20 1 -8 -2 41.22 4 1.14 1 -8 -1 135.47 124.29 1 -8 0 44.29* 39.79 1 -8 1 21.29* 23.06 1 -8 2 62.74 60.93 1 -8 3 18.43* 8.94 1 -8 4 5.87* 12.77 1 -8 5 47.70 42.26 1 -8 6 19.02* 12.18 1 -8 7 0.00* 8.76 1 -8 8 0.00* 5.25 1 -8 9 8.93* 15.80 2 -8 -10 22.52* 20.22 2 -8 -9 25.07* 27.78 2 -8 -8 9.93* 3.72 2 -8 -7 90.32 88.22 2 -8 -6 54.43 51.81 2 -8 -5 34. 87 32.02 2 -8 -4 0.00* 1.66 2 -8 -3 88.72 81.60 2 -8 -2 95.12 78.86 2 -8 -1 53.08 45.19 2 -8 0 47.81* 36.86 2 -8 1 36. 24 40.73 2 -8 2 27. 29* 43.00 2 -8 3 3.1.56 27.46 2 -8 4 7. 25* 18.92 2 -8 5 62.21 67.99 2 -8 6 18.82* 10.95 2 -8 7 16.30* 21.13 2 -8 8 3.44* 2.42 2 -8 9 0.00* 7.45 3 -8 -10 13.39* 14.80 3 -8 -9 44.53 38.73 3 -8 -8 24.41* 11.90 3 -8 -7 21.98* 16.86 3 -8 -6 8.93* 1 1.46 3 -8 -5 16.01* 3.01 3 -8 -4 77. 12 67.65 3 -8 -3 87.4-1 83.43 3 -8 -2 26.71* 1.39 3 -8 -1 101.87 101.65 3 -8 0 76.85 87.66 3 -8 1 32.48* 40.72 3 -8 2 12.79* 31.86 3 -8 3 85.26 79.13 3 -8 4 31.48 28. 10 3 -8 5 22.19* 15.83 3 -8 6 6.86* 2.26 3 -8 7 21.58* 15.85 3 -8 8 27.77* 26.24 4 -8 -10 16.54* 2.64 4 -8 -9 40.48 37.44 4 -8 -8 0.00* 12.66 4 -8 -7 0.00* 5.71 H K L FO F C 4 - 8 -6 1 6 . 3 3 * 1 8 . 3 2 4 - 8 - 5 1 8 . 7 7 * 2 3 . 6 2 4 -8 -4 4 7 . 31 3 5 . 2 7 4 - 8 - 3 6 2 . 0 5 5 6 . 9 5 4 -8 -2 6 5 . 8 6 6 6 . 13 4 - 8 - 1 4 8 . 5 2 4 3 . 9 0 4 - 8 0 2 8 . 7 9 * 8. 17 4 -8 1 4 5 . 6 8 3 0 . 0 5 4 - 8 2 5 7 . 5 9 5 5 . 0 9 4 -8 3 8 3 . 30 9 3 . 6 7 4 -8 4 3 0 . 0 4 * 1 8 . 6 8 4 - 8 5 4 4 . 4 6 4 3 . 2 5 4 - 8 6 2 8 . 2 3 * 3 0 . 3 3 4 - 8 7 8 . 8 7 * 1 9 . 5 0 5 -8 - 1 0 0 . 0 0 * 9.99 5 - 8 -9 2 4 . 7 3 * 1 9 . 84 5 - 8 -8 2 0 . 8 7 * 1 3 . 0 3 5 - 8 -7 8 . 6 0 * 2 0 . 4 7 5 -8 -6 3 7 . 3 1 3 7 . 5 5 5 - 8 -5 3 1 . 3 2 3 5 . 7 3 5 - 8 -4 9 . 5 3 * 6.70 5 -8 -3 7 0 . 8 9 7 1 . 8 1 5 - 8 -2 3 2 . 1 5 * 3 8 . 19 5 - 8 - 1 3 0 . 9 5 * 9.40 5 -8 0 4 6.11 6 2 . 2 6 5 - 8 1 7 9 . 38 7 4 . 3 4 5 - 8 2 2 7 . 8 1 * 1 1.28 5 -8 3 4 8 . 5 7 5 5 . 2 0 5 - 8 4 3 0 . 7 6 * 3 1 . 4 7 5 - 8 5 2 2 . 4 1* 9.90 5 - 8 6 6 . 5 1 * 9.61 6 - 8 - 1 0 2 8 . 39 1 9 . 16 6 - 8 - 9 7 . 7 1 * 8.41 6 - 8 -8 3 2 . 10 2 1 . 7 8 6 -8 -7 5 7 . 9 6 5 2 . 6 7 6 -8 -6 3 8 . 0 3 3 2 . 7 6 6 - 8 -5 3 6 . 6 9 3 3 . 7 6 6 - 8 -4 5 0 . 34 4 6 . 80 6 - 8 - 3 3 4 . 4 7 1 9 . 3 5 6 - 8 -2 0 . 0 0 * 8.71 6 - 8 - 1 0 . 0 0 * 7 . 2 0 6 - 8 0 4 4 . 5 0 3 7 . 8 0 6 - 8 1 3 9 . 5 3 * " 1 7 . 8 8 6 - 8 2 3 4 . 8 8 * 3 0 . 8 8 6 - 8 3 5 3 . 9 3 5 8 . 7 7 6 - 8 4 2 2 . 6 4 * 6.52 6 - 8 5 3 1 . 3 0 * 2 0 . 17 7 - 8 - 1 0 1 7 . 3 8 * 8. 85 7 - 8 - 9 3 6 . 4 3 3 3 . 3 7 7 - 8 -8 3 1 . 7 1 3 8 . 6 5 7 -8 -7 2 4 . 0 3 * 2 9 . 5 2 7 -8 -6 3 0 . 3 6 * 2 8 . 0 0 7 - 8 -5 9 5 . 0 3 8 7 . 9 3 7 - 8 -4 5 1 . 2 5 4 6 . 3 6 7 -8 - 3 1 9 . 0 7 * 1 5 . 4 6 7 - 8 -2 5 2 . 3 0 5 9 . 5 6 7 - 8 -1 4 5 . 4 0 5 3 . 18 7 -8 0 1 6 . 2 1 * 5.04 H K L FO FC 7 -8 1 3 7 . 4 3 * 5 3 . 4 1 7 -8 2 1 5 . 4 5 * 1 4 . 0 2 7 -8 3 0 . 0 0 * 1 2 . 2 0 7 -8 4 0 . 0 0 * 3. 8 6 8 -8 -9 3 1 . 1 0 2 2 . 16 8 -8 -8 8 . 4 2 * 1 3 . 9 8 8 -8 -7 7 4 . 9 0 7 0 . 2 7 8 -8 -6 5 1 . 8 5 5 2 . 4 2 8 -8 -5 2 4 . 6 6 * 3. 11 8 -8 -4 3 4 . 4 3 * 3 3 . 3 4 8 -8 - 3 4 0 . 0 1 3 7 . 4 0 8 -8 -2 3 2 . 9 0 * 4 5 . 6 9 8 -8 - 1 . 0 . 0 0 * 2 3 . 6 4 8 -8 0 3 7 . 2 2 * 3 6 . 5 3 8 -8 1 5 9 . 2 2 6 2 . 4 3 8 -8 2 2 4 . 4 2 * 1 3 . 3 2 8 -8 3 2 3 . 7 9 * 1 1 . 7 5 9 -8 -8 2 1 . 0 2 * 2 6 . 8 4 9 -8 -7 3 3 . 5 2 2 4 . 8 1 9 -8 -6 1 7 . 7 1 * 8.36 9 -8 - 5 5 0 . 89 4 4 . 8 5 9 -8 -4 6 6 . 4 2 6 0 . 0 7 9 -8 - 3 4 8 . 1 1 4 6 . 15 9 -8 -2 2 7 . 4 5 * 3 3 . 3 7 9 - 8 -1 9 5 . 12 9 4 . 7 3 9 -8 0 1 6 . 6 6 * 2 9 . 15 9 -8 1 0 . 0 0 * 7.53 10 -8 -6 2 4 . 3 9 * 2 7 . 6 5 10 -8 -5 2 6 . 9 8 * 1 4 . 8 7 10 -8 -4 0 . 0 0 * 2 . 3 3 10 -8 - 3 2 6 . 4 6 * 2 5 . 9 4 10 -8 -2 3 8 . 4 5 * 3 7 . 9 0 0 -9 1 2 2 . 8 6 * 2 5 . 1 2 0 - 9 2 1 6 . 7 6 * 1 7 . 0 9 0 -9 3 0 . 0 0 * 3. 12 0 -9 4 3 1 . 7 1 3 7 . 16 0 - 9 5 5 6 . 5 0 5 4 . 2 8 0 - 9 6 6 5 . 92 5 7 . 5 9 0 - 9 7 1 8 . 9 2 * 1 3 . 4 3 1 - 9 -7 8 5 . 0 8 7 8 . 4 3 1 - 9 -6 1 8 . 1 4 * 4.75 1 - 9 -5 0 . 0 0 * 1 0 . 7 5 1 - 9 -4 1 6 . 3 9 * 5.04 1 -9 - 3 5 2 . 40 4 9 . 4 8 1 - 9 -2 2 0 . 7 2 * 7 .07 1 - 9 -1 0 . 0 0 * 6.69 1 - 9 0 1 9 . 2 5 * 1 9 . 6 4 1 - 9 1 3 0 . 0 4 * 3 9 . 0 5 1 - 9 2 1 6 . 3 4 * 9.03 1 - 9 3 0 . 0 0 * 2 . 6 9 1 - 9 4 0 . 0 0 * 3 . 0 3 1 -9 5 4 3 . 5 5 4 3 . 4 6 1 - 9 6 0 . 0 0 * 7 . 1 2 1 - 9 7 1 5 . 8 9 * 3 3 . 9 5 2 - 9 -8 4 9 . 8 7 4 3 . 6 4 2 -9 -7 2 5 . 3 5 * 2 6 . 1 1 2 - 9 -6 4 3 . 0 9 4 1 . 7 4 2 - 9 -5 6 6 . 0 1 5 4 . 5 4 H K L FO FC H K L FO FC 2 -9 -4 15.20* 14.95 5 -9 2 19.22* 12.36 2 -9 -3 24.70* 24.98 5 -9 3 60.16 66.81 2 -9 -2 24.28* 18.27 •5 -9 4 20.27* 9.21 2 -9 -1 71.33 65.82 6 -.9 -7 7.97* 5.47 2 -9 0 14.41* 17.75 6 -9 -6 30.78 19.18 2 -9 1 40.49 31.99 6 -9 -5 41.32 42.20 2 -9 2 45.33 41.75 6 -9 -4 33.91* 36.73 2 -9 3 43.49 41.34 6 -9 -3 10.77* 16.11 2 -9 4 42.83 47.40 6 -9 -2 49. 75 34.4 5 2 -9 5 20.15* 14.23 6 -9 -1 0.00* 19.94 2 -9 6 40.33 30.53 6 -9 0 38.73 26.57 3 -9 -8 21.21* 13.57 6 -9 1 46.57 38.51 3 -9 -7 42.68 42.03 6 -9 2 35.19* 32.49 3 -9 -6 0.00* 2.21 7 -9 -6 22.26* 0.68 3 -9 -5 26.12* 25. 84 7 -9 -5 27.60* 10.74 3 -9 -4 0.00* 2.55 7 -9 -4 0.00* 4.63 3 -9 -3 70.94 58.42 7 -9 -3 42. 35 39.44 3 -9 -2 34.42 23.03 7 -9 -2 6.36* 5.22 3 -9 -1 40.90* 47.90 7 -9 -1 30.56* 7.14 3 -9 0 19.23* 0.37 7 -9 0 24.07* 12.42 3 -9 1 43.09 32.22 0 -10 0 39.57 36.42 3 -9 2 0.00* 7.54 0 -10 1 9. 26* 7.40 3 -9 3 45.41 52.72 0 -10 2 10.14* 13.92 3 -9 4 11.87* 3.40 0 -10 3 13.54* 9.37 3 -9 5 52. 36 51.76 1 -10 -3 15.48* 16.65 4 -9 -8 43.72 34.89 1 -10 -2 31.31 24.97 4 -9 -7 35.59 29. 18 1 -10 -1 13.59* 11.83 4 -9 -6 0.00* 7.27 1 -10 0 43.85* 12.98 4 -9 -5 28.87 21.56 1 -10 1 41.34 33. 19 4 -9 -4' 29.39* 18. 80 1 -TO 2 0.00* 2.'60 4 -9 -3 54. 10 50.68 1 -10 3 5. 37* 14.76 4 -9 -2 28.48* 28. 18 2 -10 -3 28.47 18.96 4 -9 -1 23.97* 30.20 2 -10 -2 58.91 48.51 4 -9 0 41.86* 35.86 2 -10 -1 32.68* 24.89 4 -9 1 41.08* 45.08 2 -10 0 44.73* 23.56 4 -9 2 50.70 44.50 2 -10 1 31.55* 16.95 4 -9 3 39.94 43.55 2 -10 2 18.78* 17.26 4 -9 4 35.46 33. 1 1 3 -10 -3 30.62* 17.20 4 -9 5 41.88 44.80 3 -10 -2 30.59* 18.62 5 -9 -7 16.73* 18.49 3 -10 -1 3.02* 0.37 5 -9 -6 19.96* 3.30 3 -10 0 37.16* 13.33 5 -9 -5 23.09* 24.64 4 -5 5 77.04 76.62 5 -9 -4 19.44* 8.65 5 -5 -10 35.38 27.66 5 -9 -3 0.00* 7.4 0 6 -5 -13 107.56 109.68 5 -9 -2 24.37* 5.06 6 -5 -4 17.39* 12. 33 5 -9 -1 20.73* 16.35 8 -5 -6 75.60 79.70 5 -9 0 0.00* 8.38 8 -5 -5 86.74 83.54 5 -9 1 20.79* 12.34 8 -5 1 28.35* 19.79 i Dimethylammonium trichlorotris(dimethylsulphoxide)ruthenate(II) Anthony Mercer and James Trotter. Observed and calculated structure amplitudes ( r e f l e c t i o n s with i n t e n s i t y < 3 (I) are marked with an as t e r i s k ) . The following planes which had |Fo-Fc| > 3 (F) were given zero weight i n the f i n a l stages of refinement due to suspected errors r e s u l t i n g from extinction, absorption, or instrument malfunction: h k 1 Fo Fc h k 1 Fo Fc 4 0 0 367.5 544.8 9 0 4 64. 8 92.0 2 4 0 45.8 6 0.4 12 0 4 54. 4 70.2 1 9 0 1 50. 0 66.3 3 0 5 96. 3 72.6 21 0 1 52.4 66.0 2 3 5 63.0 44.3 2 1 1 303.9 494. 4 8 0 7 37. 9 18.6 10 0 2 113.6 142.5 10 6 7 28. 2 11.2 17 1 2 26.2 8.7 19 0 8 74. 9 90. 8 14 0 3 77.4 94.4 0 1 9 61.4 42. 1 4 0 4 43.8 62. 2 1 0 14 38. 4 4, 1 H K L FO FC H K L FO FC 6 0 0 0. 00* 1 10.09 8 4 0 131.65 133.23 8 0 0 292.18 309.19 10 4 0 115.25 117.86 10 0 0 35 7. 89 400.62 12 4 0 17.30* 13. 80 12 0 0 164.03 172.55 14 4 0 236.08 227.54 14 0 0 252. 85 262.08 16 4 0 13 8. 41 131. 62 16 0 0 116.78 116. 14 18 4 0 40. 71 33* 32 18 0 0 137.67 144.95 20 4 0 47. 00 46, 67 20 0 0 102.57 93.97 22 4 0 82. 17 79. 88 22 0 0 146. 10 143. 18 24 4 0 47. 84 46. 87 24 0 0 96.27 94.51 26 4 0 9. 70* 2. 52 26 0 0 59.84 56. 50 2 5 0 65.76 57. 87 28 0 0 44. 54 46.22 4 5 0 97. 16 91.92 2 1 0 140.02 150.64 6 5 0 62. 21 5 2- 25 4 1 0 54. 74 55. 32 8 5 0 62. 97 60. 92 6 1 0 73. 35 67.32 10 5 0 172.78 157.77 8 1 0 91.36 79.80 12 5 0 103.32 105. 58 10 1 0 257.53 242.48 14 5 0 110.74 105.40 12 1 0 63. 03 63. 43 16 5 0 37. 13 38.44 14 1 0 134.59 122-02 18 5 0 31. 78 26. 18 16 1 0 38.09 38. 47 20 5 0 59. 76 62.20 18 1 0 88.24 87.76 22 5 0 53. 83 50.66 20 1 0 70. 99 73.78 24 5 0 97.50 96. 92 22 1 0 65.45 64.81 0 6 0 361. 13 328. 04 24 1 0 145.46 142. 13 2 6 0 151.22 137.90 26 1 0 44. 64 46.54 4 6 0 232,35 213.43 28 1 0 105.82 102.62 6 6 0 38. 81 43.09 0 2 0 279.75 285.41 8 6 0 196.51 185.64 2 2 0 10.37* 10. 17 10 6 0 166.85 165.58 4 2 0 114.75 91.52 12 6 0 179.29 172.33 6 2 0 78. 07 64.51 14 6 0 188. 81 188. 30 8 2 0 56.75 48. 25 16 6 0 35.28 34. 23 10 2 0 129.18 132-94 18 6 0 83-81 84- 63 12 2 0 52. 38 55.30 20 6 0 45. 45 41-39 14 2 0 215.50 213.85 22 6 0 113-77 11 1. 54 16 2 0 90.67 91.94 24 6 0 66. 05 64.72 18 2 0 43.02 44.01 2 7 0 36. 45 35.72 20 2 0 77. 98 79.82 4 7 0 22. 99* 21- 19 22 2 0 88.23 82-33 6 7 0 38. 03 3 5-37 24 2 0 34. 42 37. 87 8 7 0 0. 00* 2. 40 26 2 0 16.41* 24.22 10 7 0 86.30 87- 34 28 2 0 26.86* 26. 45 12 7 0 36. 32 39. 05 2 3 0 40.60 31.19 14 7 0 93. 13 92-75 4 3 0 114.48 1 15.34 16 7 0 0.00* 7. 15 6 3 0 65.86 78. 88 18 7 0 39. 41 43-87 8 3 0 49.02 51.73 20 7 0 51. 49 45. 09 10 3 0 124.48 141.70 0 8 0 173-56 170. 81 12 3 0 118.97 127.58 2 8 0 48.31 50.66 14 3 0 99.49 107.51 4 8 0 90. 15 96. 66 16 3 0 52. 22 50.01 6 8 0 28. 87 25. 12 18 3 0 49. 97 51.29 8 8 0 61.40 62. 85 20 3 0 38. 53 34. 62 10 8 0 106.07 103.22 22 3 0 28.89 24.92 12 8 0 50. 41 50. 24 24 3 0 125.42 120.27 14 8 0 97. 74 91.09 26 3 0 76.50 76.89 16 8 0 0. 00* 18. 24 28 3 0 66. 03 61. 56 18 8 0 37. 85 40-71 0 4 0 284.46 271.97 2 9 0 24.02* 19.53 4 4 0 211.21 205.48 4 9 0 47.77 44- 88 6 4 0 48. 24 59.07 6 9 0 63. 52 59.39 H K L FO FC H K L FO FC 8 9 0 19.56* 13.50 24 •j 1 71.84 66.55 10 9 0 66.79 65. 47 25 1 1 85.04 83. 46 12 9 0 40. 60 44.61 26 1 1 50.78 4 7. 98 14 9 0 50.58 47.37 27 1 1 2.84* 14, 11 0 10 0 145.77 137.79 28 1 1 23.71* 21. 83 2 10 0 87. 15 87.78 29 1 1 26.18* 29.38 4 10 0 76. 94 74.93 1 2 1 39.19 42. 00 6 10 0 6.59* 9. 11 2 2 1 31.80 36.09 8 10 0 42.59 41.70 3 2 1 140.17 129.51 2 0 1 12.29* 26.69 4 2 1 38.57 29- 47 3 0 1 64.43 77. 13 5 2 1 42. 33 38. 44 4 0 168.74 174.69 6 2 1 59.64 55. 91 5 0 0.00* 47.73 7 2 1 74.94 63.93 6 0 1 138.63 127. 14 8 2 1 40.63 37. 71 7 0 1 102.01 106.93 9 2 1 37.81 37.60 8 0 1 114. 11 142-65 10 2 1 101.01 102.72 9 0 1 247.89 246.95 11 2 1 31.99 31. 09 10 0 1 61.21* 89.66 12 2 1 160.54 164. 32 11 0 1 0. 00* 44.38 13 2 1 62.77 58. 46 12 0 1 212.09 213.91 14 2 1 55.43 58- 24 13 0 1 125.26 127.32 15 2 1 25.54 27.27 14 0 1 0. 00* 27-39 16 2 1 31.04 35. 09 15 0 1 32.04* 35.45 17 2 1 51.28 52- 09 16 0 1 44.04 47. 13 18 2 1 25.77 19.66 17 0 1 73.46 77. 51 19 2 1 11.35* 5- 89 18 0 1 5.24* 42- 14 20 2 1 22.64* 21. 29 20 0 1 103.73 101-38 21 2 1 32.28 30.42 22 0 1 65.75 71. 92 22 2 1 63. 43 56. 76 23 0 1 51.68 53. 28 23 2 1 35.07 34.93 24 0 1 0. 00* 10. 15 24 2 1 75.67 71. 90 25 0 1 46. 88 50.09 25 2 1 33.72 33. 35 26 0 1 1 17.61 116.36 26 2 1 117.75 111.64 27 0 1 0. 00* 51. 17 27 2 1 16.35* 25- 80 28 0 1 0. 00* 0.92 28 2 1 48.37 45. 83 29 0 1 46.93 48-95 0 3 1 50,16 3 6. 05 0 1 1 193.85 192.75 1 3 1 84.12 84.90 1 1 1 221.24 255.31 2 3 1 166-07 144.54 3 1 1 170. 99 185.76 3 3 1 137.12 125,81 4 1 1 28. 19 29.28 4 3 1 20.88 32.61 5 1 1 114.80 103.90 5 3 1 17-56* 14. 64 6 1 1 120.08 128. 19 6 3 1 155.04 160.77 7 1 1 1 14.27 123.66 7 3 1 61.37 56- 83 8 1 1 117.49 100.72 8 3 1 17.37* 29-34 9 1 1 161.64 162.22 9 3 1 58.84 49.34 10 1 1 163.26 160.74 10 3 1 118.53 11 7. 10 11 1 1 160.31 158-22 11 3 1 99.48 100.63 12 1 1 199.66 193.65 12 3 1 156.86 160.54 13 1 1 149.13 142.71 13 3 1 67.78 67. 40 14 1 1 49. 02 47.33 14 3 1 118.70 121. 61 15 1 1 88. 17 87.97 15 3 1 39.76 38.71 16 1 1 120.08 114.65 16 3 1 99.61 10 0.40 17 1 1 47.56 45. 47 17 3 1 77.78 79.90 18 1 1 38.7 5 35.38 18 3 1 92.84 94- 75 19 1 1 82.87 77.04 19 3 1 19.86* 16. 18 20 1 1 78. 80 77.76 20 3 1 68.11 63. 27 21 1 1 66.64 63. 60 21 3 1 22. 88* 20. 90 22 1 1 34.02 27.97 22 3 1 23.43* 22. 62 23 1 1 66. 16 65.66 23 3 1 12.07* 1 8. 42 H K L F O F C 2 4 3 1 5 7 . 0 1 5 4 . 7 8 2 5 3 1 3 3 . 8 7 3 0 . 5 6 2 6 3 1 2 3 . 7 8 * 1 7 . 9 1 2 7 3 1 4 1 . 2 1 3 2 . 3 3 1 4 1 1 2 6 . 2 7 1 0 1 . 8 8 2 4 1 1 1 0 . 0 4 9 7 . 4 5 3 4 1 4 5 . 5 4 4 6 . 1 8 4 4 1 9 4 . 7 9 8 9 . 9 5 5 4 1 3 3 . 5 8 3 3 . 3 5 6 4 1 4 7 . 9 1 4 6 . 0 3 7 4 1 6 6 . 4 7 6 2 - 2 2 8 4 1 9 0 . 1 9 8 9 - 9 4 9 4 1 2 4 . 6 2 2 1 - 2 6 1 0 4 1 1 1 2 . 9 3 1 1 0 . 0 3 1 1 4 1 1 6 . 2 4 * 1 3 . 3 9 1 2 4 1 1 3 9 . 7 9 1 3 1 - 3 6 1 3 . 4 1 9 0 . 9 6 8 7 . 3 8 1 4 4 1 4 8 . 7 4 3 7 . 7 4 1 5 4 1 3 2 - 9 0 3 4 - 7 7 1 6 4 1 7 0 . 4 9 6 0 . 0 7 1 7 4 1 4 2 - 0 8 4 3 - 1 4 1 8 4 1 3 3 . 4 4 3 1 - 6 4 1 9 4 1 2 6 . 6 0 2 3 - 5 6 2 0 4 1 6 . 8 1 * 8 . 3 4 2 1 4 1 0 . 0 0 * 4 . 8 9 2 2 4 1 6 3 . 4 3 6 1 . 6 0 2 3 4 1 7 7 . 1 1 7 3 . 7 5 2 4 4 1 2 6 . 6 9 * 2 9 . 1 8 2 5 4 1 2 5 . 9 0 * 2 4 - 4 0 2 6 4 1 7 8 . 4 7 7 4 . 7 0 0 5 1 1 1 7 . 3 0 1 0 6 . 9 7 1 5 1 1 6 0 . 5 2 1 4 1 . 6 9 2 5 1 2 3 6 . 3 5 2 3 1 . 1 8 3 5 1 9 9 . 6 9 9 1 . 5 2 4 5 1 5 1 . 3 7 4 6 . 2 5 5 5 1 7 8 . 5 7 7 8 . 9 1 6 5 1 9 0 . 0 5 9 9 . 7 3 7 5 1 8 5 . 2 6 7 8 . 6 6 8 5 1 4 8 . 4 4 4 1 . 3 0 9 5 1 5 1 . 0 4 5 1 . 9 0 1 0 5 1 9 3 . 3 9 9 4 - 8 1 1 1 5 1 1 4 6 . 2 3 1 4 0 . 8 4 1 2 5 1 1 5 9 . 7 3 1 4 9 . 6 2 1 3 5 1 7 6 . 6 1 7 9 . 2 9 1 4 5 1 1 0 3 . 5 3 1 0 5 . 3 8 1 5 5 1 8 8 . 8 3 8 6 . 3 4 1 6 5 1 1 1 0 . 1 4 1 0 7 . 1 7 1 7 5 1 3 0 . 6 8 3 4 . 2 3 1 8 5 1 3 9 . 2 4 4 0 . 7 9 1 9 5 1 2 0 . 3 5 * 2 0 . 0 9 2 0 5 1 6 6 . 5 2 6 5 . 4 4 2 1 5 1 7 6 - 7 1 7 4 . 3 4 2 2 5 1 3 3 . 3 3 2 9 . 7 6 2 3 5 1 5 1 . 2 6 5 0 . 6 6 2 4 5 1 5 2 . 7 8 5 2 - 7 7 2 5 5 1 3 7 . 8 5 3 7 . 6 9 1 6 1 1 0 1 . 0 7 8 5 . 8 7 2 6 1 5 3 . 1 8 5 2 . 2 1 H K L F O F C 3 6 1 4 2 . 2 7 3 3 . 6 9 4 6 1 6 6 . 1 5 6 7 . 2 1 5 6 1 5 5 . 7 0 4 9 - 4 7 6 6 1 2 0 . 2 6 * 2 6 . 8 8 7 6 1 6 4 . 7 3 6 0 - 0 6 8 6 1 7 7 . 1 5 7 3 . 7 1 9 6 1 4 0 . 7 8 3 8 . 3 3 1 0 6 1 6 5 . 1 6 6 8 . 0 1 1 1 6 1 3 9 . 0 3 3 7 . 5 0 1 2 6 1 1 0 6 . 1 6 1 0 6 . 4 3 1 3 6 1 6 1 . 9 0 6 3 . 0 6 1 4 6 1 4 0 . 8 3 4 8 . 0 9 1 5 6 1 3 3 . 1 8 2 9 . 0 3 1 6 6 1 7 2 . 3 1 7 2 . 2 7 1 7 6 1 6 3 . 8 2 6 2 . 5 7 1 8 6 1 2 1 . 7 7 * 2 2 . 0 2 1 9 6 1 2 5 . 1 2 * 2 4 - 4 6 2 0 6 1 3 7 . 9 6 3 5 . 6 0 2 1 6 1 5 1 . 8 9 5 3 - 5 6 2 2 6 1 5 6 . 8 2 5 4 . 4 5 2 3 6 1 4 8 . 4 2 4 9 - 9 7 0 7 1 8 7 . 6 6 8 5 . 4 5 1 7 1 1 5 8 . 2 0 1 4 6 - 0 0 2 7 1 1 2 4 . 0 1 1 0 8 . 5 7 3 7 1 1 0 1 . 3 9 9 0 . 2 3 4 7 1 1 5 . 6 2 * 7 . 4 6 5 7 1 8 8 . 9 9 8 4 . 1 1 6 7 1 6 6 . 1 1 5 7 . 2 2 7 7 1 6 7 . 8 8 6 4 . 1 6 8 7 1 2 6 . 2 2 2 6 . 0 3 9 7 1 9 3 . 0 9 8 6 . 9 9 1 0 7 1 8 2 . 2 2 7 7 . 3 1 1 1 7 1 1 0 5 . 8 2 1 0 0 . 7 7 1 2 7 1 9 5 . 2 5 9 5 . 0 8 1 3 7 1 6 0 . 7 5 5 8 . 8 1 1 4 7 1 5 5 . 2 9 5 2 - 0 8 1 5 7 1 7 6 . 3 8 7 5 . 1 7 1 6 7 1 5 9 . 2 0 5 5 - 4 5 1 7 7 1 2 2 . 9 5 * 2 0 . 8 6 1 8 7 1 3 7 . 2 5 i 3 2 . 9 2 1 9 7 1 4 4 . 4 3 4 3 . 1 0 2 0 7 1 4 9 . 6 2 4 5 . 6 3 2 1 7 1 4 6 . 9 2 4 5 . 5 0 1 8 1 1 8 . 6 0 * 1 5 . 0 8 2 8 1 2 7 . 5 1 2 7 . 3 2 3 8 1 4 1 . 1 0 3 7 . 8 0 4 8 1 4 2 . 4 1 3 5 . 5 3 5 8 1 0 . 0 0 * 3 - 8 4 6 8 1 3 6 . 9 3 3 1 . 2 0 7 8 1 2 0 . 6 2 * 1 4 . 9 2 8 8 1 3 3 . 7 7 3 1 . 6 1 9 8 1 2 8 . 1 3 2 5 . 2 2 1 0 8 1 3 7 . 3 2 3 4 . 8 4 1 1 8 1 2 1 . 1 8 * 3 . 9 8 1 2 8 1 7 5 . 4 7 7 1 . 8 1 1 3 8 1 3 1 . 8 4 3 0 . 3 8 1 4 8 1 3 2 . 9 8 3 1 . 6 3 1 5 8 1 1 5 . 0 6 * 1 7 - 0 8 H K L FO FC H K L FO FC 16 8 1 43.56 39.94 2 ! 2 47. 90 43.27 17 8 1 18.00* 17.28 3 1 2 45.72 47.69 18 8 1 29. 98 29.47 4 1 2 102.73 94. 27 19 8 1 0.00* 0. 78 5 1 2 17.63* 17.91 0 9 1 68.21 64.56 6 1 2 64. 10 59.76 1 9 1 62. 16 60.64 7 1 2 134.22 128. 19 2 9 1 155.77 149.54 8 1 2 77.55 72. 46 3 9 1 53.56 53. 15 9 1 2 78.95 77. 94 4 9 1 22.26* 10.73 10 1 2 184. 34 175.46 5 9 1 31. 33 25.35 11 1 2 164.60 161.03 6 9 1 94. 14 91.56 12 1 2 172.26 163.01 7 9 1 27.88* 28.98 13 1 2 43. 17 42- 04 8 9 1 37.54 36.46 14 1 2 74.62 64. 15 9 9 1 39.21 37.60 15 1 2 93. 33 9 2. 27 10 9 1 55.43 52. 53 16 1 2 13.63* 1 4. 50 11 9 1 48.76 48.62 18 1 2 41.79 40. 66 12 9 1 90.28 89. 13 19 1 2 101.68 99. 13 13 9 1 45.90 46.68 20 1 2 16.22* 2. 48 14 9 1 21.05* 17. 28 21 1 2 53.32 4 7. 03 15 9 1 24.01* 15.75 22 1 2 36.46 39.01 1 10 1 12.40* 9. 19 23 1 2 71. 09 68. 08 2 10 1 12.27* 17.35 24 1 2 56.37 54. 47 3 10 1 21.75* 18.61 25 1 2 49. 90 48. 69 4 10 1 49.95 49.99 26 1 2 67.49 65. 99 5 10 1 15.53* 8. 22 27 1 2 41.61 40. 95 6 10 1 24.00* 25.51 28 1 2 25. 05* 23. 84 7 10 1 0. 00* 10.61 0 2 2 92. 74 80.68 8 10 1 59.22 53.78 1 2 2 217.23 205.98 9 10 1 31. 23 29. 92 2 2 2 67. 14 76, 86 0 0 2 202.12 187.70 3 2 2 128.25 136,10 1 0 2 300.48 348.79 4 2 2 85. 81 74-59 2 0 2 268.97 306.24 5 2 2 31.69 3 6.49 3 0 2 106.50 104.01 6 2 2 86. 41 94. 00 4 0 2 136.94 135.31 7 2 2 7. 72* 9.77 5 0 2 0. 00* 55.72 8 2 2 46. 67 37. 77 6 0 2 101.62 105.74 9 2 2 102.01 108. 29 7 0 2 0. 00* 17.04 10 2 2 37. 77 3 9.05 8 0 2 0.00* 20.33 11 2 2 113.43 114.29 9 0 2 252.84 253.45 12 2 2 79.01 79. 96 11 0 2 224.22 218.21 13 2 2 173.45 172.47 12 0 2 9.39* 71. 13 14 2 2 101.27 95. 23 13 0 2 124.27 121.63 15 2 2 13.21* 9.74 14 0 2 6. 65* 50.32 16 2 2 107. 12 105.60 15 0 2 88.28 93.83 17 2 2 97.51 95. 44 16 0 2 93. 53 95. 28 18 2 2 56. 13 52.70 17 0 2 7.21* 35.58 19 2 2 39.87 36. 96 18 0 2 18.33* 25.99 20 2 2 63. 17 61. 66 19 0 2 21.91* 31.61 21 2 2 47. 98 44. 59 20 0 2 60.55 61.22 22 2 2 34. 29 32.73 21 0 2 23.06* 34. 35 23 2 2 105.26 97.38 22 0 2 0.00* 28. 16 24 2 2 36. 15 34.90 23 0 2 86.35 82.63 25 2 2 22.43* 10. 83 24 0 2 0. 00* 34. 14 26 2 2 10.29* 13- 17 25 0 2 21.94* 32.53 27 2 2 69.92 62. 66 26 0 2 0.00* 16. 11 28 2 2 34. 10 30.27 27 0 2 57. 92 55.47 1 3 2 146.47 129.72 28 0 2 0.00* 14. 88 2 3 2 1 13.62 98-91 1 1 2 121.56 116.84 3 3 2 158.00 140. 47 H K L FO 4 3 2 151.98 5 3 2 144.25 6 3 2 50. 26 7 3 2 53.88 8 3 2 123.37 9 3 2 84.30 10 3 2 78. 83 11 3 2 71.64 12 3 2 58. 97 13 3 2 45.52 14 3 2 55.55 15 3 2 70.50 16 3 2 11.28* 17 3 2 29.43 18 3 2 52.29 19 3 2 70.92 20 3 2 17.98* 21 3 2 58.87 22 3 2 66.37 23 3 2 27.60* 24 3 2 55.54 25 3 2 54. 10 26 3 2 85.33 27 3 2 26.18* 0 4 2 2 10.64 1 4 2 192.66 2 4 2 103.83 3 4 2 208.94 4 4 2 73. 38 5 4 2 77.28 6 4 2 22.48* 7 4 2 44. 50 8 4 2 73.22 9 4 2 133.87 10 4 2 24. 71 11 4 2 101. 12 12 4 2 96. 17 13 4 2 195.25 14 4 2 73. 14 15 4 2 53.26 16 4 2 63.04 17 4 2 57. 35 18 4 2 53. 49 19 4 2 38. 41 20 4 2 55. 93 21 4 2 42. 46 22 4 2 64.36 23 4 2 97.43 24 4 2 39.56 25 4 2 44.75 26 4 2 7. 95* 1 5 2 106.19 2 5 2 75.56 3 5 2 90. 43 4 5 2 87.60 5 5 2 85.62 6 5 2 102.82 7 5 2 21.33* FC H 140.51 8 120.48 9 37.92 10 51. 85 11 126.51 12 79.93 13 84.99 14 71.87 15 63.81 16 43.40 17 54. 02 18 69. 15 19 21. 48 20 30.43 21 43.27 22 68.59 23 12.62 24 56.20 25 60.30 0 27. 45 1 49.74 2 51.49 3 81.45 4 25.67 5 207.61 6 171. 45 7 112.56 8 191.47 9 78.73 10 77.78 11 27. 13 12 45.30 13 75.78 14 133.83 15 15.70 16 95.95 17 93.31 18 187.89 19 66.09 20 47.91 21 61.34 22 54.47 23 48.21 1 39,73 2 52.95 3 41.85 4 64.08 5 94.95 6 38.80 7 42. 87 8 14.92 9 104.09 10 65. 81 11 85.33 12 76.69 13 84. 10 14 93. 15 15 19.35 16 K L FO FC 5 2 65.44 59. 81 5 2 27. 44 30. 11 5 2 102. 30 92- 62 5 2 99. 84 90. 57 5 2 102.54 97. 97 5 2 37. 11 38. 11 5 2 41. 57 43. 27 5 2 75.40 67. 82 5 2 4 3. 81 41. 05 5 2 10.76* 17- 49 5 2 14.53* 1- 98 5 2 33.50 31. 58 5 2 12.03* 8. 43 5 2 70.68 63. 19 5 2 25.98* 24. 57 5 2 40.45 39. 16 5 2 31. 41 29. 08 5 2 70. 16 6 2. 70 6 2 57. 30 56. 99 6 2 149.48 133- 08 6 2 196.24 172. 04 6 2 130.88 123. 13 6 2 77.82 75. 02 6 2 49.76 45. 95 6 2 106.32 91. 87 6 2 62.95 65. 37 6 2 80.71 82. 46 6 2 113.29 107. 73 6 2 79. 05 74. 25 6 2 1 15.92 115. 14 6 2 122.46 121. 51 6 2 146. 19 144. 87 6 2 6. 91* 20, 48 6 2 38. 62 38. 23 6 2 92.79 9 2. 48 6 2 18.55* 19. 46 6 2 17,05* 19. 71 6 2 25.78* 22. 76 6 2 86. 22 81. 29 6 2 26.97* 29. 93 6 2 0. 00* 7. 72 6 2 75.40 71. 74 7 2 55. 04 54- 60 7 2 21.69* 15. 84 7 2 61. 65 57. 83 7 2 72. 55 68. 58 7 2 50. 13 48. 67 7 2 33. 90 33. 10 7 2 20. 97* 13. 44 7 2 50. 67 47. 64 7 2 33. 11 33. 10 7 2 30. 05 31. 60 7 2 52. 88 50. 97 7 2 84.73 80- 75 7 2 23.55* 19- 78 7 2 23.28* 20. 50 7 2 58. 45 57. 23 7 2 24.20* 15. 57 ( H K L FO FC H K L FO FC 17 7 2 0.00* 1 1. 77 12 0 3 45.42 61. 89 18 7 2 28.29* 31. 13 13 0 3 95. 86 10 2- 55 19 7 2 60. 82 57-81 15 0 3 70.33 67. 17 20 7 2 21.28* 8. 96 16 0 3 0- 00* 14. 87 21 7 2 16.55* 13.82 17 0 3 99. 64 100.97 0 8 2 79. 06 81.00 18 0 3 0. 00* 25. 69 1 8 2 1 10.97 100.89 19 0 3 46. 50 49. 05 2 8 2 30.06 28.66 20 0 3 39.96 42. 38 3 8 2 43.-47 39.32 21 0 3 46. 04 50. 51 4 8 2 54.92 56.56 22 0 3 0. 00* 3. 66 5 8 2 52. 84 52.96 23 0 3 0. 00* 23. 52 6 8 2 11.54* 9-26 24 0 3 7 0. 44 67. 95 7 8 2 29. 57 32. 44 25 0 3 0. 00* 15. 57 8 8 2 51.85 54. 21 ' 26 0 3 0. 00* 9.80 9 8 2 80- 35 77-44 27 0 3 0. 00* 1- 18 10 8 2 23.62* 21.78 28 0 3 42.31 42. 08 11 8 2 72.70 68. 81 0 1 3 195.60 208. 83 12 8 2 36. 98 28.24 1 1 3 77. 36 89.91 13 8 2 74.93 70. 12 2 1 3 54. 44 54. 40 14 8 2 60.51 60. 23 3 1 3 27.34 24. 48 15 8 2 29. 86 25. 19 4 1 3 81.89 78. 56 16 8 2 38. 48 33.37 5 1 3 160.63 148.98 17 8 2 50.28 50-36 6 1 3 113.86 117-24 18 8 2 38.47 37.25 7 1 3 128.78 109.38 1 9 2 25.59* 33.23 8 1 3 183.44 170. 18 2 9 2 29.99 27. 00 9 1 3 87.86 76. 15 3 9 2 27.23* 28. 48 10 1 3 99.90 91.98 4 9 2 23.43* 21.34 11 1 3 1 10.21 102.76 5 9 2 15.33* 12. 63 12 1 3 96.58 90. 69 6 9 2 42. 80 37-63 13 1 3 20.98* 29. 04 7 9 2 40. 41 38-31 14 1 3 160.64 153. 21 8 9 2 31. 20 35.51 15 1 3 70.27 64,73 9 9 2 15.57* 23. 27 16 1 3 86.21 81.56 10 9 2 67.74 65. 44 17 1 3 38. 26 32- 02 11 9 2 70.73 66.59 18 1 3 60. 29 55, 84 12 9 2 27.80* 30. 42 19 1 3 21.43* 17.20 13 9 2 29.95 24. 17 20 1 3 57. 15 54. 10 14 9 2 54.63 54-44 21 1 3 51. 00 48. 42 0 10 2 92. 13 90-78 22 1 3 98.64 92. 81 1 10 2 101.46 97.99 23 1 3 0. 00* 10. 43 2 10 2 37. 46 31. 18 24 1 3 37.77 31. 88 3 10 2 58. 62 55.76 25 1 3 58. 35 53. 84 4 10 2 62. 39 59-91 26 1 3 17.84* 25. 81 5 10 2 60.66 59.65 27 1 3 52.48 49. 84 6 10 2 14.96* 20-08 28 1 3 6.47* 18. 89 7 10 2 41.82 39. 19 1 2 3 110.58 105. 54 8 10 2 34.44 38. 26 2 2 3 73.40 84- 14 1 0 3 0.00* 29.38 3 2 3 145. 15 133.60 2 0 3 82.54 80. 40 4 2 3 133.54 131. 22 3 0 3 85.86 82.08 ' 5 2 3 66.46 65.71 4 0 3 90.57 85.26 6 2 3 85.64 85. 39 5 0 3 0. 00* 26. 58 7 2 3 74. 56 66.39 6 0 3 0.00* 6.48 8 2 3 60. 85 59. 04 7 0 3 81.54 89.95 9 2 3 48. 32 51.39 8 0 3 0- 00* 66. 84 10 2 3 165.23 155.51 9 0 3 0.00* 119. 14 11 2 3 52. 80 58- 06 10 0 3 244.73 239.60 12 2 3 42.53 41. 23 11 0 3 0.00* 69. 57 13 2 3 71.86 69. 21 H K 1 FO FC EI K L FO FC 14 2 3 72.02 73.02 16 4 3 38.01 39. 56 15 2 3 40. 15 42.77 17 4 3 51-30 52.79 16 2 3 95. 97 88. 57 18 4 3 23. 45* 29. 83 17 2 3 98.26 95.71 19 4 3 14. 31* 18. 90 18 2 3 19.92* 15. 34 20 4 3 30.34 26. 98 19 2 3 61.65 57.98 21 4 3 0. 00* 17. 94 20 2 3 77. 47 69.77 22 4 3 34.68 32. 70 21 2 3 62.05 56. 16 23 4 3 41. 65 44.93 22 2 3 30. 04 25.65 24 4 3 96.32 101. 37 23 2 3 34. 26 31.77 25 4 3 13.88* 22.26 24 2 3 118.06 108.38 26 4 3 13.86* 6. 58 25 2 3 28.59* 25.62 0 5 3 228.38 236.92 26 2 3 41. 86 37. 45 1 5 3 90.58 87. 72 27 2 3 25.73* 26.87 2 5 3 29. 06 20.90 28 2 3 52. 56 49.66 3 5 3 69. 62 66-39 0 3 3 434.78 440.67 4 5 3 106,31 117. 17 1 3 3 137.48 133.09 5 5 3 45.91 42.82 2 3 3 198.28 208.75 6 5 3 13.26* 11- 69 3 3 3 50.96 58.97 7 5 3 100.34 95.51 4 3 3 201.21 197.81 8 5 3 112.32 117.60 5 3 3 56.80 55.30 9 5 3 47. 22 48. 70 6 3 3 103.78 116.40 10 5 3 88.68 88. 18 7 3 3 88.67 99.83 11 5 3 93.36 91. 6 6 8 . 3 3 96.73 97.72 12 5 3 102.84 107.08 9 3 3 49.04 42.40 13 5 3 31.74 33.21 10 3 3 160.55 177.37 14 5 3 103. 28 102-98 11 3 3 119.96 135.02 15 5 3 42. 21 4 3. 27 12 3 3 142.58 148.56 16 5 3 0. 00* 10. 63 13 3 3 8. 04* 4.29 17 5 3 28- 00 29. 08 14 3 3 180.90 196.05 18 5 3 44. 36 47. 16 15 3 3 128.55 137.43 19 5 3 3. 57* 14. 58 16 3 3 0.00* 8.83 20 5 3 2.66* 12- 02 17 3 3 6.64* 14.24 21 5 3 33. 09 39.67 18 3 3 70.56 73.21 22 5 3 104. 05 106. 91 19 3 3 51.93 56.98 23 5 3 21.79* 18. 72 20 3 3 33.47 35.01 24 5 3 23.21* 23. 68 21 3 3 65. 12 66. 14 25 5 3 34.98 31. 84 22 3 3 137.01 143.78 1 6 3 105. 04 97. 20 23 3 3 16.25* 18.65 2 6 3 46.54 45. 84 24 3 3 40. 74 50.55 3 6 3 111. 53 108. 09 25 3 3 74.70 73.52 4 6 3 76. 14 78. 55 26 3 3 26.01* 22.31 5 6 3 72. 51 71.53 27 3 3 19.48* 21.42 6 6 3 84. 19 86. 62 1 4 3 125.46 126. 15 7 6 3 27. 42 23.62 2 4 3 86. 04 86.69 8 6 3 41.04 45. 55 3 4 3 127.25 130.83 9 6 3 18. 64* 22- 72 4 4 3 76. 43 80. 10 10 6 3 88.40 9 4. 23 5 4 3 76. 68 87. 19 11 6 3 27. 88 31. 81 6 4 3 127.40 129.78 12 6 3 21.22* 22.25 7 4 3 44. 28 48. 03 13 6 3 2 0 . 0 8 * 27- 39 8 4 3 39.77 39.47 14 6 3 58. 12 62- 87 9 4 3 55. 89 52.37 15 6 3 24. 76* 20.97 10 4 3 100.59 100.82 16 6 3 31. 84 28.89 11 4 3 42.28 37.70 17 6 3 30.96 32. 09 12 4 3 24.60 23.82 18 6 3 27.29* 29. 26 13 4 3 59.74 58. 12 19 6 3 33.55 32-97 14 4 3 85.64 84.06 20 6 3 45. 47 45. 17 15 4 3 3.08* 10.54 21 6 3 26.30* 27- 57 H K L FO FC H K L FO FC 22 6 3 29.30 27.79 2 10 3 15.76* 21- 43 23 6 3 0.00* 3. 43 3 10 3 14.50* 17. 93 0 7 3 160.59 154.57 4 10 3 9. 24* 2 4- 36 1 7 3 46. 05 44. 73 5 10 3 19. 76* 2. 28 2 7 3 36. 52 34.59 6 10 3 20.24* 24. 22 3 7 3 51.01 54. 83 7 10 3 14.79* 7. 66 4 7 3 60.64 61.89 0 0 4 61. 50 61.92 5 7 3 34. 94 38.90 1 0 4 66. 14 66. 81 6 7 3 24.76* 30.72 2 0 4 20,19* 43. 32 7 7 3 21.12* 19.40 3 0 4 98. 05 94. 92 8 7 3 53.55 58.09 5 0 4 76.69 84. 89 9 7 3 52.87 54.02 6 0 4 24.64* 3 8. 90 10 7 3 71. 24 8 1. 23 7 0 4 93. 59 97- 84 11 7 3 18.95* 30. 14 8 0 4 144.03 148.69 12 7 3 35.69 36.29 10 0 4 101.52 121.77 13 7 3 49. 03 56.52 11 0 4 99. 20 110.92 14 7 3 81. 24 90.78 13 0 4 9,06* 34. 20 15 7 3 23.57* 31. 44 14 0 4 38. 98 41.36 16 7 3 13,03* 24.75 15 0 4 0. 00* 13. 07 17 7 3 47. 06 53. 87 16 0 4 39. 37 38. 81 18 7 3 38. 87 45.63 17 0 4 0. 00* 10. 62 19 7 3 17.60* 7.81 18 0 4 117.98 118.92 20 7 3 22.9 7* 9.88 19 0 4 30.45* 64.49 21 7 3 24.68* 22.96 20 0 4 45.97 56. 12 1 8 3 20.20* 24. 24 21 0 4 45. 26 52. 84 2 8 3 30.46 33.85 22 0 4 42.67 51. 05 3 8 3 30. 90 37.03 23 0 4 0. 00* 43. 53 4 8 3 30. 23 31.75 24 0 4 71. 19 78. 16 5 8 3 14.68* 21.59 25 0 4 0. 00* 28. 66 6 8 3 30.34 36.42 26 0 4 0. 00* 5. 80 7 8 3 11.75* 19.89 27 0 4 54. 81 5 1. 04 8 8 3 33.00 33.60 28 0 4 0. 00* 27. 75 9 8 3 29.93 30. 84 1 1 4 43. 54 43. 32 10 8 3 59.29 63.01 2 1 4 100. 10 101. 44 11 8 3 1. 11* 11. 49 3 1 4 142.58 146.00 12 8 3 48.45 49. 20 4 1 4 91.95 95. 18 13 8 3 43. 05 52. 19 5 1 4 60. 00 61. 98 14 8 3 22.00* 27. 4 2 6 1 4 50. 19 50. 12 15 8 3 24.25* 18.76 7 1 4 22. 19 17.77 16 8 3 23.95* 22-56 8 1 4 139.49 139.13 17 8 3 50.43 52. 42 9 1 4 63. 63 60.39 18 8 3 0.00* 20.43 10 1 4 84.62 85.51 0 9 3 91. 79 98. 47 11 1 4 54. 14 51. 62 1 9 3 64.92 66.96 12 1 4 109.92 110.69 2 9 3 83.58 86.98 13 1 4 76. 29 76. 69 3 9 3 86. 80 93. 98 14 1 4 0. 00* 7.36 4 9 3 38.60 44.00 15 1 4 71. 75 75- 88 5 9 3 41.38 40.98 16 1 4 32.85 35. 15 6 9 3 32.20 34.58 17 1 4 113.20 120.51 7 9 3 86. 00 92.30 18 1 4 45.75 44. 43 8 9 3 48.21 50. 63 19 1 4 78. 27 75. 44 9 9 3 34. 16 31.41 20 1 4 20.31* 19. 17 10 9 3 60. 57 65.86 21 1 4 63.03 6 2. 43 11 9 3 71.96 76.29 22 1 4 50.70 56. 55 12 9 3 46. 40 49.09 23 1 4 24.99* 17.88 13 9 3 42.34 48.89 24 1 4 48.93 4 9. 93 14 9 3 56.85 60.24 25 1 4 32. 15 32. 66 1 10 3 16.80* 19. 03 26 1 4 47.71 50. 19 H K L FO FC H K L FO FC 27 1 4 13.82* 7.84 2 4 4 245.72 252. 13 28 1 4 32. 59 29.66 3 4 4 125. 89 120.33 0 2 4 173.00 182-37 4 4 4 95. 25 88. 06 1 2 4 156. 13 155.70 5 4 4 62. 17 59. 42 2 2 4 349.27 352-35 6 4 4 116. 41 127.70 3 2 4 144.01 144. 15 7 4 4 130.08 136. 14 4 2 4 98.40 107, 18 8 4 4 74. 67 73- 30 5 2 4 44. 17 57. 54 9 4 4 26. 14 20. 04 6 2 4 100.39 100.94 10 4 4 199.87 205.99 7 2 4 193.52 206.62 11 4 4 107.78 114.88 8 2 4 85. 12 91.66 12 4 4 156.89 16 4- 44 9 2 4 53. 8 2 50.6 2 13 4 4 60. 84 59. 34 10 2 4 132.77 135.63 14 4 4 115.34 120.03 11 2 4 141.75 150.40 15 4 4 74. 54 72. 47 12 2 4 215.81 225.53 16 4 4 76. 13 77. 19 13 2 4 17.56* 15.57 17 4 4 24.30* 15. 00 14 2 4 57. 49 59.78 18 4 4 27. 47 30. 52 15 2 4 126.70 132.81 19 4 4 25.23* 24. 12 16 2 4 108.4 1 1 12.32 20 4 4 91. 82 96.90 17 2 4 16.72* 7.71 21 4 4 64.51 64. 58 18 2 4 51.91 48.28 22 4 4 33.74 33. 30 19 2 4 44.43 48.77 23 4 4 46. 43 5 0. 59 20 2 4 90. 18 93-35 24 4 4 87.43 88. 69 21 2 4 68. 89 66.08 25 4 4 45. 48 46. 82 22 2 4 60.77 62.63 1 5 4 86. 33 97.99 23 2 4 0. 00* 3.04 2 5 4 46.73 47.72 24 2 4 83.94 85.35 3 5 4 105.07 109.08 25 2 4 57. 63 60. 92 4 5 4 52. 50 51.64 26 2 4 42. 63 41. 68 5 5 4 56.33 57. 93 27 2 4 24.42* 29.20 6 5 4 54.66 52. 85 1 3 4 147.81 133.31 7 5 4 29. 21 20.73 2 3 4 49.48 50. 45 8 5 4 74.67 75. 10 3 3 4 156.79 144.87 9 5 4 39. 15 38.37 4 3 4 129. 11 138.34 10 5 4 44. 01 42.71 5 3 4 102.08 97.53 11 5 4 56.71 . 60. 09 6 3 4 98.46 101.85 12 5 4 109.99 112.23 7 3 4 105.78 96. 10 13 5 4 27. 56 25.72 8 3 4 89, 03 92.65 14 5 4 4. 64* 10. 41 9 3 4 37. 37 4 2.43 15 5 4 16.90* 23. 49 10 3 4 32.70 35.09 16 5 4 54.76 56. 07 11 3 4 50.81 50.36 17 5 4 32. 52 30. 93 12 3 4 91.95 96. 31 18 5 4 21. 84* 15.46 13 3 4 49.22 53.32 19 5 4 36.07 37.21 14 3 4 64-69 60.39 20 5 4 44.97 45. 15 15 3 4 46.79 45. 43 21 5 4 19.73* 26- 47 16 3 4 47.99 48. 37 22 5 4 45. 45 43. 71 17 3 4 94. 36 93.60 23 5 4 16.21* 10. 78 18 3 4 80.45 83.39 24 5 4 7. 86* 4. 63 19 3 4 31.82 29.43 0 6 4 18.41* 14.64 20 3 4 41.56 44. 17 1 6 4 41. 95 39.79 21 3 4 48.76 46.75 2 6 4 98. 38 97.21 22 3 4 98.54 96.92 3 6 4 56. 95 61- 98 2 3 3 4 45.05 45.70 4 6 4 32. 46 24. 48 24 3 4 37. 51 38.25 5 6 4 39.98 37-91 25 3 4 35.94 32.44 6 6 4 55. 92 57. 97 26 3 4 76.82 75.58 7 6 4 74. 92 76. 92 0 4 4 132.40 122.97 8 6 4 22.94* 2 1. 90 1 4 4 79. 19 78.08 9 6 4 33.50 41.28 H K L FO FC H K L FO FC 10 6 4 65.26 66.55 8 9 4 40. 26 41- 56 11 6 4 68.51 78.06 9 9 4 10.19* 2 0. 59 12 6 4 69.06 71.77 10 9 4 33. 92 34. 44 13 6 4 29. 15 31.73 1 1 9 4 34. 01 37. 43 14 6 4 0. 00* 7. 17 12 9 4 54. 54 55. 61 15 6 4 51. 24 57. 60 13 9 4 34. 45 36. 16 16 6 4 18.04* 25. 53 0 10 4 59. 85 66. 86 17 6 4 9.49* 20.25 1 10 4 27.28* 31. 14 18 6 4 44.79 43.95 2 10 4 81.93 82. 22 19 6 4 0. 00* 4.80 3 10 4 26.30* 24. 21 20 6 4 31.09 33.34 4 10 4 27.47* 26. 67 21 6 4 48.03 47. 48 5 10 4 19.45* 18.77 22 6 4 31. 30 28.91 1 0 5 0. 00* 22. 48 1 7 4 32.95 36.80 2 0 5 37. 86 46. 40 2 7 4 40.66 40.95 4 0 5 150. 15 153-05 3 7 4 68.65 69.26 5 0 5 98.58 88. 92 4 7 4 53.99 55.27 6 0 5 77.55 75.61 5 7 4 45. 42 49.93 7 0 5 26. 55 36. 54 6 7 4 35. 87 33.88 8 0 5 91.39 82- 80 7 7 4 46. 84 50. 34 9 0 5 11.60* 17, 04 8 7 4 58. 01 61.14 10 0 5 0. 00* 10. 11 9 7 4 24.93* 30. 12 11 0 5 47.31 55. 74 10 7 4 38.76 37.03 12 0 5 54. 41 61. 95 11 7 4 0. 00* 6.53 13 0 5 16.65* 39.71 12 7 4 36.80 34. 42 14 0 5 0. 00* 35. 10 13 7 4 64. 04 66.09 15 0 5 73.39 75- 13 14 7 4 32. 61 30.77 16 0 5 0. 00* 19. 43 15 7 4 12.88* 13.59 17 0 5 128.18 129.02 16 7 4 26.76 28.52 18 0 5 0. 00* 9. 17 17 7 4 62.09 65.36 19 0 5 93. 04 93. 11 18 7 4 35.68 40. 49 20 0 5 0. 00* 39.21 19 7 4 21.45* 20.94 21 0 5 21.16* 30. 88 20 7 4 28. 13 24. 68 22 0 5 0. 00* 18, 47 0 8 4 1 13.29 109.67 23 0 5 21. 51* 24. 95 1 8 4 20.19* 21. 85 24 0 5 0. 00* 22. 13 2 8 4 77. 82 78.94 25 0 5 16.71* 2 0. 27 3 8 4 38. 10 35.26 26 0 5 35. 41 36. 29 4 8 4 53. 06 45.67 27 0 5 7.75* 23- 30 5 8 4 23.35* 19. 10 0 1 5 210. 91 207.60 6 8 4 19.98* • 18.30 1 1 5 139.50 133.82 7 8 4 58.27 60.02 2 1 5 45. 35 46. 12 8 8 4 58.40 52-89 3 1 5 105. 28 103- 93 9 8 4 34. 45 32.59 4 1 5 149.00 147.20 10 8 4 57.54 56.70 5 1 5 65. 31 61. 77 11 8 4 60.91 57. 40 6 1 5 73. 23 69. 04 12 8 4 87. 94 87-70 7 1 5 1 13-75 115.08 13 8 4 24.34* 23. 38 8 1 5 3 8.59 37. 44 14 8 4 35. 06 39-28 9 1 5 174.42 175.30 15 8 4 44. 44 42. 21 10 1 5 51.74 57. 03 16 8 4 51.99 54.21 11 1 5 29.89 33. 02 17 8 4 7. 71* 14.28 12 1 5 27. 11 29. 76 1 9 4 31.52 23. 61 13 1 5 129.56 135.20 2 9 4 14.59* 16.52 14 1 5 82. 01 81. 76 3 9 4 25.59* 28.03 15 1 5 43. 38 44.58 4 9 4 23.55* 34.97 16 1 5 88. 12 88.. 43 5 9 4 26.97* 30.52 17 1 5 54. 17 54. 61 6 9 4 24.57* 29.08 18 1 5 28.60 25. 68 7 9 4 0. 00* 12.23 19 1 5 36. 44 37. 15 H K L FO FC H K L FO FC 20 1 5 78. 67 7 4.54 24 3 5 0.00* 17. 45 21 1 5 0- 00* 21.35 25 3 5 44. 10 40. 62 22 1 5 84.42 84. 19 26 3 5 14.50* 6. 04 23 1 5 97. 96 98. 12 1 4 5 88.64 87.91 24 1 5 46. 84 48. 00 2 4 5 31. 34 32.38 25 1 5 6.61* 4. 34 3 4 5 88. 68 99.59 26 1 5 12.21* 10.33 4 4 5 17.70* 15.65 27 1 5 39. 85 41.84 5 4 5 77. 98 87. 17 1 2 5 129.97 119.02 6 4 5 48. 48 47. 64 2 2 5 84.20 78.77 7 4 5 0. 00* 10.32 3 2 5 132.26 131.89 8 4 5 50. 61 49. 71 4 2 5 87. 31 81.73 9 4 5 44. 93 39. 00 5 2 5 106.05 106.04 10 4 5 89.87 88. 62 6 2 5 102.27 106,59 11 4 5 75. 17 74.62 7 2 5 20.29* 14.21 12 4 5 78. 07 75.78 8 2 5 44.30 44.36 13 4 5 43. 92 43. 46 9 2 5 18.14* 26.60 14 4 5 48.00 47. 67 10 2 5 60. 08 61. 44 15 4 5 73. 93 74, 24 11 2 5 108.75 1 13.77 16 4 5 14.09* 6. 09 12 2 5 35.27 22.61 17 4 5 18. 85* 21.70 13 2 5 46. 32 43. 92 18 4 5 18.37* 17. 52 14 2 5 27. 87 25.20 19 4 5 94. 16 9 1. 86 15 2 5 129.58 132.41 20 4 5 20.77* 2 5. 50 16 2 5 63.4 3 60.34 21 4 5 7.83* 18. 44 17 2 5 38. 41 37.81 22 4 5 0. 00* 14. 03 18 2 5 39. 14 38.77 23 4 5 80.78 80. 52 19 2 5 129.63 125.80 24 4 5 37. 29 35.53 20 2 5 47.30 51.04 25 4 5 34. 91 35. 22 21 2 5 42. 28 39.67 0 5 5 107.60 107. 24 22 2 5 18.23* 21. 07 1 5 5 118.43 119.41 23 2 5 79.29 79.74 2 5 5 33. 43 32.75 24 2 5 29. 60 32.49 3 5 5 24. 19 2 6.. 12 25 2 5 67. 21 67. 22 4 5 5 86. 96 84. 16 26 2 5 0. 00* 18.71 5 5 5 99. 70 97. 19 27 2 5 51.06 52. 00 6 5 5 51. 66 54. 95 0 3 5 150.73 131.77 7 5 5 58. 53 50. 51 1 3 5 272.46 269.23 8 5 5 130.66 128.83 3 3 5 182.74 172.46 9 5 5 99.02 97. 23 4 3 5 45.45 34.52 10 5 5 11. 10* 13. 61 5 3 5 237.75 249.6 2 11 5 5 66.67 72.20 6 3 5 0.00* 33.33 12 5 5 87. 80 88, 42 7 3 5 41.51 37.09 13 5 5 84.20 82. 97 8 3 5 52.37 48.68 14 5 5 31. 00 28.76 9 3 5 280.92 298.85 15 5 5 20.63* 11.21 10 3 5 21.68* 20.53 16 5 5 36. 25 40. 23 11 3 5 167.24 160.70 17 5 5 32. 45 26. 78 12 3 5 51.10 48. 18 18 5 5 38. 40 41.36 13 3 5 238.51 247.81 19 .5 5 29. 16 28. 08 14 3 5 37.76 33.68 20 5 5 17.05* 18.73 15 3 5 77. 11 69.21 2.1 5 5 14. 11* 16.45 16 3 5 51. 47 49.06 22 5 5 37.44 34. 39 17 3 5 80. 84 87.73 23 5 5 82. 14 80. 51 18 3 5 36.49 33.68 1 6 5 52. 58 47.96 19 3 5 68.26 66. 14 2 6 5 29. 55 28. 10 20 3 5 30.63 28.72 3 6 5 67.52 61. 39 21 3 5 64.37 63.64 4 6 5 46. 94 49.77 22 3 5 27.40* 27.30 5 6 5 74. 42 64. 10 23 3 5 1 18.61 114.63 6 6 5 33.69 31. 87 H K L FO , FC 7 6 5 36. 23 38.48 8 6 5 54. 55 56. 14 9 6 5 36. 14 34.75 10 6 5 41. 53 46.62 11 6 5 52. 71 58. 81 12 6 5 24. 92* 27. 28 13 6 5 8. 55* 15.35 in 6 5 9. 91* 15.37 15 6 5 52. 09 58. 16 16 6 5 29. 86 25. 11 17 6 5 33. 29 35.93 18 6 5 22. 42* 18.28 19 6 5 71. 85 72.50 20 6 5 13. 97* 10.26 21 6 5 12. 92* 10.38 22 6 5 15. 76* 11.70 0 7 5 40. 65 42. 13 1 7 5 112. 73 1 12.02 2 7 5 16. 78* 18.76 3 7 5 37. 94 35. 65 4 7 5 5. 85* 9.75 5 7 5 76. 75 83.64 6 7 5 0. 00* 10.56 7 7 5 47. 76 49.72 8 7 5 21. 79* 20. 54 9 7 5 107. 25 112-61 10 7 5 27. 45 28. 16 11 7 5 71. 30 70. 68 12 7 5 12. 27* 9. 68 13 7 5 93. 29 101.94 14 7 5 35. 91 36.04 15 7 5 33. 81 34.58 16 7 5 27. 31 25. 23 17 7 5 14. 20* 25. 19 18 7 5 17. 54* 19. 37 19 7 5 29. 85 30. 49 1 8 5 48. 40 50. 74 2 8 5 43. 26 46.75 3 8 5 41. 23 44. 65 4 8 5 30. 50 31.23 5 8 5 52. 41 62. 90 6 8 5 35. 32 35.51 7 8 5 14. 05* 14.66 8 8 5 34. 28 39. 14 9 8 5 21. 58* 33. 25 10 8 5 26. 59 24. 84 11 8 5 54. 20 54.31 12 8 5 0. 00* 1.96 13 8 5 36. 06 39.51 14 8 5 24. 93* 24.77 15 8 5 61. 44 59. 80 16 8 5 12. 24* 9.48 0 9 5 22. 08* 19.02 1 9 5 96. 46 100.26 2 9 5 22. 17* 26.54 3 9 5 56. 90 62.81 4 9 5 26. 97* 30-91 5 9 5 52. 84 53. 82 H K L FO FC 6 9 5 18. 46* 22.78 7 9 5 37. 21 38-38 8 9 5 17. 58* 13.71 9 9 5 90. 86 89.28 10 9 5 28. 57 3 2. 72 11 9 5 56. 73 61.61 0 0 6 83. 97 86-33 1 0 6 89. 35 93. 46 2 0 6 136. 93 130. 41 3 0 6 31. 12 30, 01 4 0 6 24. 83* 24. 62 5 0 6 45, 41 44. 82 6 0 6 15- 88* 8. 68 7 0 6 75. 73 83- 41 8 0 6 8. 59* 5.90 9 0 6 31. 63 37. 21 10 0 6 0. 00* 18. 84 11 0 6 108, 73 117.53 12 0 6 12. 58* 25. 03 13 0 6 42. 85 50. 70 14 0 6 0. 00* 32.32 15 0 6 67. 68 67. 93 16 0 6 0. 00* 8. 92 17 0 6 0. 00* 1.33 18 0 6 34. 48 35.68 19 0 6 8. 39* 19. 16 20 0 6 0. 00* 14. 58 21 0 6 78. 90 94. 92 22 0 6 77. 48 91. 45 23 0 6 0. 00* 9.51 24 0 6 0. 00* 16. 90 25 0 6 68. 75 74. 06 26 0 6 0. 00* 24. 08 1 1 6 75. 09 82. 17 2 1 6 148. 32 142. 57 3 1 6 69. 92 83. 64 4 1 6 69. 97 72. 44 5 1 6 86. 49 93. 17 6 1 6 79. 97 90. 07 7 1 6 52. 20 58. 51 8 1 6 37. 93 33. 46 9 1 6 46. 49 49. 81 10 1 6 39. 52 45. 09 11 1 6 33. 27 40. 32 12 1 6 39. 16 38. 13 13 1 6 49. 13 46. 14 14 1 6 29. 69 30.63 15 1 6 14- 58* 13- 25 16 1 6 33. 91 33. 86 17 1 6 99. 05 105. 07 18 1 6 30. 31 31.93 19 1 6 62. 91 64, 82 20 1 6 29. 98 34. 46 21 1 6 70. 69 73. 18 22 1 6 24. 89* 25.62 23 1 6 25. 22* 24. 14 24 1 6 39. 99 41. 65 25 1 6 41. 66 39.22 FO FC 14. 41* 23. 36 144. 55 155. 89 150. 52 153. 87 135. 36 133. 03 191. 25 200. 66 88. 96 87. 62 71. 81 80. 80 68. 01 71. 10 217. 17 239. 42 96. 63 103. 02 57. 36 60. 67 1 15. 08 119. 82 191. 66 203. 96 96. 95 96. 36 96. 15 97. 27 102. 19 100, 47 76. 38 76. 80 56. 34 56. 92 38. 99 42. 08 78. 34 81. 73 14. 91* 9. 66 i 2 . 35* 16. 76 84. 34 85. 70 66. 75 72. 61 41. 59 41. 31 25. 79* 16. 23 45. 92 48. 87 31. 19 29. 12 73. 07 69. 61 14. 25* 20. 70 122. 69 119. 82 14. 83* 12. 35 79. 57 72- 24 33. 98 31. 04 50. 02 50. 07 19. 9 1* 23. 81 42. 91 49. 21 76. 28 77. 18 29. 83 26. 50 17. 10* 31. 27 65. 76 71. 71 41. 61 43. 25 17. 22* 16. 70 73. 50 78- 37 102. 48 104- 57 18. 01* 11. 20 42. 19 43. 19 52. 69 55. 13 93. 95 95. 84 13. 02* 21. 61 25. 26* 26. 92 43. 64 42. 78 63. 43 62- 11 80. 25 85. 94 101. 93 107. 03 69. 54 68. 84 75. 47 76. 53 64. 13 68. 97 H K L FO FC 5 4 6 77.47 73. 23 6 4 6 20. 97* 18. 44 7 4 6 118. 04 119. 24 8 4 6 106.77 110. 89 9 4 6 30.75 23. 89 10 4 6 23.95* 21. 58 11 4 6 126.56 128. 10 12 4 6 87.23 90. 44 13 4 6 32. 56 36. 62 14 4 6 39.79 39. 30 15 4 6 63. 08 65. 40 16 4 6 17.67* 17. 62 17 4 6 18.85* 24. 07 18 4 6 30.39 24. 10 19 4 6 32.60 38. 48 20 4 6 17.53* 2 0. 60 21 4 6 75. 96 84. 15 22 4 6 35.46 36. 07 23 4 6 5. 94* 10. 58 24 4 6 30. 10 28. 71 1 5 6 16.42* 24. 91 2 5 6 14.13* 17, 03 3 5 6 39. 63 45. 73 4 5 6 18.46* 16. 07 5 5 6 35. 56 3 9, 68 6 5 6 38. 50 42. 94 7 5 6 37.91 37. 06 8 5 6 24.90* 31- 55 9 5 6 38.13 31. 66 10 5 6 45.34 51. 31 11 5 6 20.60* 24. 88 12 5 6 42. 37 38. 14 13 5 6 53.52 55. 35 14 5 6 39, 89 46. 85 15 5 6 26.62* 31. 72 16 5 6 15.86* 20. 78 17 5 6 91. 30 94- 33 18 5 6 11.66* 18. 93 19 5 6 56.35 58. 36 20 5 6 15.84* 8. 37 21 5 6 85. 64 88. 19 22 5 6 18.47* 10. 99 23 5 6 19.28* 15. 99 0 6 6 56. 27 56. 85 1 6 6 107. 65 104. 01 2 6 6 59.73 65. 30 3 6 6 109.29 110. 07 4 6 6 26. 43 22. 98 5 6 6 39. 41 39. 02 6 6 6 12.91* 30. 19 7 6 6 133. 15 144. 89 8 6 6 39. 84 41. 49 9 6 6 16.41* 2. 29 10 6 6 59.96 63. 74 11 6 6 106.05 111. 58 12 6 6 33. 46 37. 40 13 6 6 38. 64 37. 76 14 6 6 37,66 37. 52 H K L FO FC H K L FO FC 15 6 6 72. 00 77. 45 9 0 7 11.36* 5.41 16 6 6 20.18* 1 1 - 2 3 10 0 7 34. 18 33. 61 17 6 6 32. 10 26.58 11 0 7 24.12* 19. 23 18 6 6 23.38* 21. 50 12 0 7 34. 46 30. 24 19 6 6 28. 14 29- 84 13 0 7 0. 00* 4.35 20 6 6 18.85* 11.49 14 0 7 44. 41 49. 88 21 6 6 73-28 73- 17 15 0 7 0. 00* 4. 68 1 7 6 62. 88 63.07 16 0 7 0. 00* 33- 73 2 7 6 28.20 22. 47 17 0 7 76. 14 79.64 3 7 6 66.30 68.52 18 0 7 0. 00* 22. 86 4 7 6 26.68* 25. 15 19 0 7 63. 15 68. 83 5 7 6 59.45 59. 91 20 0 7 0. 00* 33. 09 6 7 6 32. 28 32. 58 21 0 7 54. 39 55.37 7 7 6 34.50 36.66 22 0 7 41. 92 50. 48 8 7 6 18. 11* 8.92 23 0 7 29.56* 42. 22 9 7 6 20.72* 27.04 24 0 7 43. 52 51. 34 10 7 6 32.46 30-54 25 0 7 0. 00* 18.60 11 7 6 0. 00* 12.79 0 1 7 235.61 243.23 12 7 6 29-84 28.40 1 1 7 24.59* 17.55 13 7 6 47. 35 54. 16 2 1 7 154.68 154.87 14 7 6 33.99 34.47 3 1 7 79. 53 7 5. 13 15 7 6 26.84* 29. 14 4 1 7 1 12.51 111.44 16 7 6 39. 15 44.57 5 1 7 116. 18 115-23 17 7 6 56. 17 61. 43 6 1 7 64. 35 62. 52 18 7 6 15.39* 17. 47 7 1 7 174.27 179. 13 0 8 6 80.44 80.07 8 1 7 100. 90 103. 47 1 8 6 96- 50 99. 11 9 1 7 84. 01 83. 79 2 8 6 91.21 90.05 10 1 7 137.33 137.52 3 8 6 80.22 81. 24 11 1 7 28. 50 34. 58 4 8 6 54.78 55.02 12 1 7 165.46 165- 53 5 8 6 79. 89 82.82 13 1 7 86. 29 87.88 6 8 6 80.73 87. 29 14 1 7 107.84 109.21 7 8 6 91.72 95. 27 15 1 7 49.23 45. 51 8 8 6 56. 59 56.49 16 1 7 47. 94 51. 17 9 8 6 64. 13 63.38 17 1 7 48.72 53. 64 10 8 6 83.41 85.67 18 1 7 27.32* 34. 22 11 8 6 116.62 119. 10 19 1 7 8.22* 18. 98 12 8 6 54. 51 55.54 20 1 7 55.90 56. 22 13 8 6 44. 17 44.64 21 1 7 50. 20 48. 69 14 8 6 59.28 63.47 22 1 7 57.61 56.56 15 8 6 61.64 63.46 23 1 7 36. 99 43. 46 1 9 6 22.93* 30.59 24 1 7 73. 30 74. 90 2 9 6 12.15* 16.91 25 1 7 25.32* 35. 10 3 9 6 35.26 36.43 1 2 7 61. 81 62. 49 4 9 6 15.95* 23.04 2 2 7 28. 27 30. 49 5 9 6 24.16* 30. 40 3 2 7 121. 03 122.85 6 9 6 25.93* 24. 10 4 2 7 30. 79 27. 47 7 9 6 17.06* 22. 70 5 2 7 107. 16 102. 94 8 9 6 0. 00* 4.63 6 2 7 34.64 35. 00 9 9 6 17.88* 5.91 7 2 7 51. 95 50. 40 10 9 6 24.04* 31.98 8 2 7 25. 87 27. 52 1 0 7 63.38 63.42 9 2 7 53. 28 4 8. 22 2 0 7 59. 38 57.29 10 2 7 74. 90 77. 53 3 0 7 91. 47 97.81 11 2 7 47. 92 46. 37 4 0 7 50. 53 42. 38 12 2 7 62. 89 65. 96 5 0 7 1 18.72 115.80 13 2 7 24.72* 27. 00 6 0 7 0. 00* 2.72 14 2 7 65. 73 67. 84 7 0 7 22.41* 30.99 15 2 7 29. 20 35-64 fl K 1 FO FC H K L FO FC 16 2 7 32.04 32.32 0 5 7 107.17 110.80 17 2 7 59.79 60. 17 1 5 7 23.27* 24-58 18 2 7 50. 09 52. 68 2 5 7 123. 95 115. 04 19 2 7 80.66 81.25 3 5 7 18. 25* 1 4. 37 20 2 7 45. 13 45.53 4 5 7 32.56 38. 18 21 2 7 44.35 43. 26 5 5 7 36. 61 42. 94 22 2 7 59. 78 59.93 6 5 7 40- 85 36. 53 23 2 7 25.12* 29. 26 7 5 7 74. 70 73. 06 24 2 7 40. 07 44.69 8 5 7 0. 00* 4. 40 25 2 7 32. 53 34. 27 9 5 7 75.71 73. 09 0 3 7 153.09 145.53 10 5 7 78.78 78. 00 1 3 7 41. 84 38. 18 11 5 7 28. 37 25- 84 2 3 7 72.77 83.78 12 5 7 69. 90 74.78 3 3 7 72.32 74. 13 13 5 7 32. 15 24. 71 4 3 7 24.56 22. 99 14 5 7 54.47 55. 11 5 3 7 105.37 112.90 15 5 7 16.68* 14. 13 6 3 7 10.89* 18.09 16 5 7 0. 00* 11.83 7 3 7 187.54 189.33 17 5 7 21.93* 11. 86 8 3 7 37.68 32. 05 18 5 7 9. 81* 21^25 9 3 7 106.79 113.62 19 5 7 45.24 46- 69 10 3 7 104.60 114.56 20 5 7 23.31* 14.79 11 3 7 99.80 104.24 21 5 7 55. 78 55. 07 12 3 7 82.75 84. 83 1 6 7 29. 67 27. 52 13 3 7 39.94 45. 13 2 6 7 0. 00* 12. 84 14 3 7 59.21 57. 13 3 6 7 44. 46 48.61 15 3 7 31.96 30.51 4 6 7 7. 45* 12. 56 16 3 7 17.70* 8. 16 5 6 7 49.40 44. 00 17 3 7 36. 1 1 40-23 6 6 7 13.00* 16. 82 18 3 7 18.35* 1 1.08 7 6 7 31.70 26. 45 19 3 7 38.53 37.32 8 6 7 29. 17 30. 34 20 3 7 13.37* 20.21 9 6 7 15. 46* 12. 12 21 3 7 66. 97 68. 59 11 6 7 31.34 35. 85 22 3 7 46.69 41.30 12 6 7 34. 82 36. 22 23 3 7 20.64* 14. 00 13 6 7 37. 62 36.24 24 3 7 44. 83 46.23 14 6 7 33.29 34.22 1 4 7 25.35 18-91 15 6 7 47.85 52. 85 2 4 7 18.53* 15.72 16 6 7 28. 01 24. 31 3 4 7 31. 17 37. 18 17 6 7 59. 00 59. 12 4 4 7 34.57 31.34 18 6 7 14.79* 25. 78 5 4 7 54.64 57.31 19 6 7 85.36 86. 29 6 4 7 2. 05* 9. 12 0 7 7 157.48 155. 16 7 4 7 38.66 36. 11 1 7 7 49. 05 5 0. 37 8 4 7 38.92 37.47 2 7 7 111.71 1 14. 62 9 4 7 38. 64 38. 29 3 7 7 42. 15 38. 06 10 4 7 26. 04 23.72 4 7 7 108.20 107.49 11 4 7 15.31* 6. 23 5 7 7 101. 10 101.69 12 4 7 48.97 51.75 6 7 7 60. 34 63. 98 13 4 7 44. 83 42.75 7 7 7 80. 01 86. 22 14 4 7 26.82* 31.72 8 7 7 100.09 101.36 15 4 7 48.40 46. 94 9 7 7 103.55 104.85 16 4 7 16.07* 12.41 10 7 7 112.05 118.80 17 4 7 105.24 108.29 11 7 7 35. 32 39-26 18 4 7 29. 10 34. 19 12 7 7 123.21 123.52 19 4 7 95. 30 92.93 13 7 7 48. 38 47. 58 20 4 7 21.21* 27. 40 14 7 7 8 5. 83 86-97 21 4 7 67.03 69.65 15 7 7 14.37* 17-21 22 4 7 46.01 48.06 16 7 7 57. 88 57. 47 23 4 7 36. 97 3 4.09 17 7 7 25. 07* 25.70 H K L FO 1 8 7 64. 99 2 8 7 6. 85* 3 8 7 59.70 4 8 7 13.21* 5 8 7 36.61 6 8 7 9. 90* 7 8 7 32. 07 8 8 7 13.35* 9 . 8 7 25.19* 10 8 7 31-33 11 8 7 20.44* 12 8 7 25.76* 13 8 7 19.75* 0 9 7 72. 84 1 9 7 48. 15 2 9 7 71. 38 3 9 7 59. 37 4 9 7 37, 87 5 9 7 6.07* 6 9 7 4. 57* 7 9 7 74. 12 0 0 8 105.64 1 0 8 210.05 2 0 8 93. 99 3 0 8 101.86 4 0 8 105. 12 5 0 8 214.33 6 0 8 41. 57 7 0 8 7. 28* 8 0 8 44. 04 9 0 8 209- 51 10 0 8 106-89 11 0 8 127.26 12 0 8 51.70 13 0 8 138.57 14 0 8 74. 90 15 0 8 57.78 16 0 8 24.30* 17 0 8 71.54 18 0 8 0. 00* 20 0 8 69.45 21 0 8 0. 00* 22 0 8 0. 00* 23 0 8 103.30 24 0 8 62.67 1 1 8 109. 15 2 1 8 35.67 3 1 8 77. 55 4 1 8 55.91 5 1 8 96.23 6 1 8 54.35 7 1 8 96.61 8 1 8 86,99 9 1 8 31. 86 10 1 8 12.88* 1 1 1 8 63.89 12 1 8 37. 62 13 1 8 47.00 FC H 69.51 14 7.06 15 67.60 16 10. 48 17 41.00 18 2. 17 19 30.71 20 24.71 21 26.55 22 29.63 23 18.74 24 31.05 0 7.27 1 73. 18 2 43.71 3 71.02 4 61.04 5 38.78 6 2. 36 7 17.23 8 78.76 9 109.85 10 206.24 11 90.28 12 95.39 13 90.23 14 216.31 15 41.86 16 8.38 17 40.94 18 208.04 19 1 10.34 20 124.00 21 59. 23 22 142.07 23 79.33 24 54, 57 1 46. 93 2 70.92 3 3.73 4 73. 46 5 0.52 6 16.32 7 106.73 8 71. 13 9 101.35 10 28.76 11 81. 48 12 51.57 13 98. 43 14 49.80 15 94.38 16 82.92 17 30.59 18 13-51 19 64. 09 20 38.09 21 49.64 22 K L FO FC 8 35. 49 41. 95 1 8 54. 33 55. 66 1 8 31. 72 30. 50 1 8 16,16* 21. 98 1 8 32. 00 33. 15 1 8 107. 83 106. 20 1 8 34. 03 36, 56 1 8 17.59* 14. 26 1 8 45. 07 46. 28 1 8 63.54 63. 30 1 8 31. 43 33. 94 2 8 76. 78 77. 07 2 8 125.09 122. 51 2 8 113. 73 109. 39 2 8 19. 64* 1 1. 04 2 8 53. 04 60. 66 2 8 173.44 171. 26 2 8 107. 13 99- 18 2 8 115.41 116. 88 2 8 43. 34 41. 86 2 8 180.25 182. 82 2 8 92.57 92. 52 2 8 57. 46 56. 17 2 8 78. 51 79. 66 2 8 106.63 107. 97 2 8 48. 20 49. 25 2 8 29. 09 36. 39 2 8 50.35 48. 09 2 8 29.25 26. 42 2 8 16. 03* 19. 58 2 8 47. 53 43. 33 2 8 41. 27 40. 95 2 8 27.54* 24. 25 2 8 28. 05 27. 67 2 8 58. 00 55. 88 2 8 38. 18 40. 23 3 8 43. 15 42. 96 3 8 24. 89 2 8. 37 3 8 58. 27 55. 81 3 8 29. 63 28. 33 3 8 105,48 104. 38 3 8 55. 13 5 8. 17 3 8 31. 81 29. 62 3 8 28.58 32. 11 3 8 14.49* 22. 37 3 8 2 2. 17* 18- 59 3 8 14.79* 18. 41 3 8 42.05 4 5. 69 3 8 6.61* 12. 15 3 8 2 5.90* 15. 95 3 8 65.27 66. 96 3 8 21.90* 7. 78 3 8 67. 86 7 0. 99 3 8 21.37* 24. 07 3 8 87. 15 92. 02 3 8 24.83* ^ 29. 47 3 8 45.21 42. 56 3 8 15.23* 12. 28 H K L FO FC H K I FO FC 23 3 8 58.36 60.39 14 6 8 44. 57 42. 45 0 4 8 88.89 86.05 15 6 8 50. 93 48. 44 1 4 8 84. 27 82. 15 16 6 8 45. 82 48. 16 2 4 8 69.77 63.67 17 6 8 16.19* 22.90 3 4 8 36. 46 35.03 18 6 8 7, 30* 15. 52 4 4 8 54. 59 56.28 1 7 8 64.44 61. 94 5 4 8 89.07 90.58 2 7 8 9. 05* 19.62 6 4 8 37.64 33.38 3 7 8 6 5. 85 68- 80 7 4 8 77.75 78.62 4 7 8 38. 56 39.38 8 4 8 38.49 38.64 5 7 8 53. 49 52. 80 9 4 8 114.52 116. 17 6 7 8 0. 00* 17.46 10 4 8 63. 85 65.68 7 7 8 20.76* 19. 52 1 1 4 8 14.60* 9. 17 8 7 8 38. 08 4 2- 37 12 4 8 19.93* 21. 45 9 7 8 23. 18* 19. 80 13 4 8 68.74 67.75 10 7 8 5.79* 12-97 14 4 8 49. 36 51. 34 11 7 8 14. 32* 17. 84 15 4 8 32.44 33.63 12 7 8 28.15* 30.65 16 4 8 10.43* 18.42 13 7 8 26.35* 28.76 17 4 8 8. 13* 6.82 14 7 8 25.19* 27.75 18 4 8 41.43 42.91 15 7 8 48.74 4 5. 03 19 4 8 53.48 59.21 0 8 8 65. 93 64. 48 20 4 8 18.35* 22.66 1 8 8 84. 18 84. 48 21 4 8 20.88* 27.05 2 8 8 49.71 54.60 22 4 8 12.86* 16. 14 3 8 8 50. 70 54. 48 1 5 8 25.51* 26-89 4 8 8 23.78* 22. 16 2 5 8 8.37* 12.84 5 8 8 97. 39 104.36 3 5 8 18.80* 11. 25 6 8 8 17.63* 26. 01 4 5 8 14.63* 10.32 7 8 8 42. 34 44.77 5 5 8 45. 80 48. 22 8 8 8 29.64* 24. 32 6 5 8 21.74* 17.84 9 8 8 95. 28 98. 95 7 5 8 10.21* 14. 37 10 8 8 40. 96 46. 12 8 5 8 21.73* 26.62 11 8 8 38. 43 39.08 9 5 8 18.38* 24. 23 1 0 9 63.63 56. 88 10 5 8 20.24* 19.58 2 0 9 67.30 62. 35 11 5 8 56.32 57.63 3 0 9 108.75 107- 30 12 5 8 40. 57 39.37 4 0 9 62.75 61. 61 13 5 8 24.63* 26.30 5 0 9 55. 11 63.31 14 5 8 12.29* 19. 93 6 0 9 63. 62 67- 23 15 5 8 97.87 102.01 7 0 9 66. 80 66. 12 16 5 8 16.53* 9.90 8 0 9 37.3 6 36- 19 17 5 8 63.01 63.67 9 0 9 50.24 44.98 18 5 8 23.24* 25.62 10 0 9 30.14* 30. 60 19 5 8 94.58 94. 80 1 1 0 9 26.08* 25. 47 20 5 8 16.84* 23. 11 12 0 9 26.15* 12.91 0 6 8 90. 95 93. 14 13 0 9 82. 17 87. 16 1 6 8 98. 94 96. 68 14 0 9 32.10* 38. 84 2 6 8 74. 84 74.48 15 0 9 12.81* 13.78 3 6 8 58.40 53. 96 16 0 9 0. 00* 20.24 4 6 8 40. 07 45. 24 17 0 9 98.37 104.30 5 6 8 1 11.05 1 13.74 18 0 9 4. 00* 10.53 6 6 8 63.73 62.63 19 0 9 9. 77* 2.77 7 6 8 63.76 61.96 20 0 9 0. 00* 3. 66 8 6 8 38.91 38.95 21 0 9 91.93 91. 11 9 6 8 130.92 134.60 22 0 9 0.00* 3.47 10 6 8 74. 87 72.45 23 0 9 68. 35 65. 95 11 6 8 63. 62 6 0. 90 1 1 9 197.07 185- 37 12 6 8 76.46 76.87 2 1 9 143.41 137.25 13 6 8 90. 54 91.99 3 1 9 161. 81 158.74 H K L FO FC 4 1 9 73.10 71.01 5 1 9 0.00* 16. 01 6 1 9 51.31 54.20 7 1 9 179.29 181.65 8 1 9 107. 14 103. 32 9 1 9 51. 53 50.05 10 1 9 61.54 60.99 11 1 9 188.25 189.04 12 1 9 49, 30 52. 27 13 1 9 74.51 73.93 14 1 9 48.67 46.76 15 1 9 109.04 109.51 16 1 9 48.11 47.63 17 1 9 0. 00* 16.97 18 1 9 58.82 57. 45 19 1 9 24.31* 27.97 20 1 9 59.00 57.67 21 1 9 100.24 98.49 22 1 9 46. 93 46.90 23 1 9 35.67 34.15 1 2 9 80.92 78.51 2 2 9 19.93* 17.89 3 2 9 115.31 109.56 4 2 9 92.38 9 2,48 5 2 9 79.00 79.95 6 2 9 69.47 67.02 7 2 9 67.79 67.41 8 2 9 52.84 56.15 9 2 9 28.47 29.98 10 2 9 44. 29 45. 56 11 2 9 29.75 30.50 12 2 9 32.50 32-58 13 2 9 42-21 42.43 14 2 9 30.98 32.10 15 2 9 26.96* 29-56 16 2 9 25.88* 24.02 17 2 9 73.69 72-38 18 2 9 38. 13 35.62 19 2 9 49.69 44-56 20 2 9 21.74* 21.70 21 2 9 70.33 67.89 22 2 9 0-00* 11-20 0 3 9 36.48 32.75 1 3 9 77.94 74.15 2 3 9 44. 73 37.40 3 3 9 70.19 67.28 4 3 9 31.83 28,01 5 3 9 77.64 78.93 6 3 9 19.15* 17.79 7 3 9 95.96 94.92 8 3 9 28.51 27.30 9 3 9 49. 19 51-46 10 3 9 24.22* 21.18 11 3 9 104.17 106-32 12 3 9 20-37* 20.74 13 3 9 14.06* 16.12 14 3 9 37. 13 41. 18 15 3 9 60.56 60-74 H K L FO FC 16 3 9 23.82* 23- 52 17 3 9 26. 74 24. 89 18 3 9 15.96* 17. 75 19 3 9 12-89* 13. 93 20 3 9 31.64 33- 07 21 3 9 47.40 44. 34 22 3 9 8. 66* 8. 71 1 4 9 27.24 27. 17 2 4 9 17.88* 14. 24 3 4 9 39. 58 42- 61 4 4 9 33. 32 33. 60 5 4 9 44. 57 44. 99 6 4 9 20.59* 24. 33 7 4 9 16.26* 16. 91 8 4 9 44. 63 40. 79 9 4 9 41. 15 40. 93 10 4 9 30. 46 32. 34 11 4 9 34. 08 33- 94 12 4 9 63. 03 62. 35 13 4 9 56. 39 60. 89 14 4 9 20.03* 9. 50 15 4 9 42. 81 43. 39 16 4 9 30- 28 30. 11 17 4 9 81. 34 85. 40 18 4 9 35. 45 36. 13 19 4 9 52. 79 50. 76 20 4 9 0. 00* 4. 86 0 5 9 58. 55 53. 56 1 5 9 125. 46 125. 52 2 5 9 51.78 53. 58 3 5 9 107. 13 106. 70 4 5 9 58. 53 57. 81 5 5 9 43- 95 44. 29 6 5 9 97.31 100. 55 7 5 9 108.09 112. 11 8 5 9 20.81* 14. 07 9 5 9 78. 30 80. 69 10 5 9 78. 03 84. 15 11 5 9 132.63 131. 22 12 5 9 40- 87 36. 62 13 5 9 90.95 86. 42 14 5 9 33. 08 34. 72 15 5 9 54.35 54- 52 16 5 9 49.75 47. 35 17 5 9 35.37 34. 49 18 5 9 0. 00* 13. 94 19 5 9 15.82* 19. 19 1 6 9 38. 06 32. 16 2 6 9 40.39 39. 86 3 6 9 59. 22 56- 63 4 6 9 33. 52 33. 37 5 6 9 27. 48 24- 31 6 6 9 36.21 35. 78 7 6 9 24. 28* 21. 00 8 6 9 33. 19 36- 93 9 6 9 45. 62 50. 44 10 6 9 36.49 37. '20 11 6 9 28.51* 31. 47 H K L FO FC H K L FO FC 12 6 9 22.27* 23. 24 9 10 9, 45* 3. 46 13 6 9 57.27 59.71 10 1 10 83.50 82. 06 14 6 9 15.35* 11.97 11 1 10 54.79 54. 80 15 6 9 31.73 31.54 12 1 10 21.04* 23.25 16 6 9 20.50* 8.27 13 1 10 24.34* 24.75 0 7 9 51.64 53. 11 14 1 10 53. 24 46. 84 1 7 9 96.06 95. 55 15 1 10 64.63 59.25 2 7 9 28.11* 24.48 16 1 10 52. 44 52, 51 3 7 9 90.55 90.90 17 1 10 49. 36 47, 99 4 7 9 23.49* 28.61 18 1 10 23.35* 23. 07 5 7 9 28.06* 28.57 19 1 10 57. 45 54.77 6 7 9 19.43* 14.76 20 1 10 47. 03 46.23 7 7 9 96.43 96.47 21 1 10 15.59* 12. 80 8 7 9 23.25* 18.55 0 2 10 157.10 149.66 9 7 9 23.77* 29.42 1 2 10 58.39 56. 99 10 7 9 3. 16* 6.70 2 2 10 47. 96 47. 99 11 7 9 108.69 109.02 3 2 10 51. 74 4 7, 79 12 7 9 29.28 27.26 4 2 10 54. 65 52.30 13 7 9 48. 49 49.21 5 2 10 105. 23 101. 25 1 8 9 51.00 52. 20 6 2 10 19.61* 17. 68 2 8 9 27.75* 30. 43 7 2 10 40. 22 39. 26 3 8 9 50.72 50.76 8 2 10 43. 49 39. 48 4 8 9 40.65 39. 26 9 2 10 90. 05 91. 92 5 8 9 35.38 33.25 10 2 10 50. 81 49. 34 6 8 9 39.00 31.79 11 2 10 40.39 40. 73 7 8 9 38. 42 43.01 12 2 10 50. 59 52.29 8 8 9 28.83* 29.94 13 2 10 96. 81 92. 79 0 0 10 124.64 114.87 14 2 10 70. 61 72- 50 1 0 10 63. 12 60.90 15 2 10 49. 46 52. 34 2 0 10 125.57 126.05 16 2 10 28.78 27. 88 3 0 10 47. 31 45.64 17 2 10 51.30 49.71 4 0 10 83 . 96 83. 11 18 2 10 49. 44 44.71 5 0 10 70. 24 68.80 19 2 10 15.85* 14. 48 6 0 10 75.51 79.01 20 2 10 20.05* 16. 92 7 0 10 34. 06 29.65 21 2 10 40.30 37. 68 8 0 10 93.72 90. 46 1 3 10 70. 10 70.35 9 0 10 84.56 87.00 2 3 10 38.89 35. 32 10 0 10 88. 90 90.62 3 3 10 68.68 69.37 11 0 10 22.41* 4.30 4 3 10 34.09 32- 46 12 0 10 1 11.72 110.74 5 3 10 50.06 53. 23 13 0 10 68.36 71.64 6 3 10 50. 13 50. 48 14 0 10 1 14.81 1 14.90 7 3 10 34. 72 31.77 15 0 10 19.35* 14.80 8 3 10 48. 14 49. 74 16 0 10 12.33* 8.92 9 3 10 0. 00* 16. 60 17 0 10 0.00* 2.34 10 3 10 51. 12 52. 45 18 0 10 82.41 80.93 11 3 10 37. 49 38. 99 19 0 10 38. 52 38.71 12 3 10 18.30* 15. 43 20 0 10 14. 1 1* 16.26 13 3 10 24.15* 2 5. 15 21 0 10 0.00* 38.46 14 3 10 27.76* 29. 82 22 0 10 110.41 108.04 15 3 10 25. 17* 26. 08 1 1 10 58.54 59. 12 16 3 10 30.69 32.81 2 1 10 68.59 66.07 17 3 10 49.96 52. 42 3 1 10 107.95 99.04 18 3 10 24.77* 20. 42 4 1 10 40.74 39.21 19 3 10 46. 10 45. 48 5 1 10 74. 92 70.94 20 3 10 30. 79 26. 69 6 1 10 80, 97 78.63 0 4 10 153.40 155,62 7 1 10 22.13* 15.47 1 4 10 57. 63 50. 96 8 1 10 22.34* 24. 60 2 4 10 74. 74 66-46 H K L FO 3 4 10 21. 01* n 4 10 92. 77 5 4 10 55. 12 6 4 10 25. 84* 7 4 10 57. 16 8 4 10 1 16. 59 9 4 10 59. 23 10 4 10 66. 4 3 11 4 10 5. 72* 12 4 10 106. 36 13 4 10 48. 43 14 4 10 76. 31 15 4 10 33. 42 16 4 10 21. 75* 17 4 10 26. 35* 18 4 10 47. 51 19 4 10 22. 79* 1 5 10 46. 96 2 5 10 24. 64* 3 5 10 49. 14 4 5 10 28. 51 5 5 10 0. 00* 6 5 10 64. 43 7 5 10 28. 77 8 5 10 20. 72* 9 5 10 53. 82 10 5 10 80- 78 11 5 10 61. 24 12 5 10 8. 33* 13 5 10 29. 93* 14 5 10 73. 03 15 5 10 34. 12 16 5 10 47. 70 17 5 10 42. 71 0 6 10 129. 32 1 6 10 53. 36 2 6 10 83. 18 3 6 10 34. 58 4 6 10 88. 42 5 6 10 35. 42 6 6 10 45. 95 7 6 10 52. 35 8 6 10 76. 22 9 6 10 48. 04 10 6 10 78. 39 11 6 10 . 40. 31 12 6 10 65. 73 13 6 10 38. 31 14 6 10 80. 20 1 7 10 44. 30 2 7 10 18. 73* 3 7 10 47. 19 4 7 10 39. 68 5 7 10 48. 24 6 7 10 52. 38 7 7 10 23. 23* 8 7 10 22. 59* 9 7 10 26. 85* FC H 6.64 10 95.95 1 51.44 2 19.20 3 57.78 4 120.03 5 59.01 6 65.32 7 13. 47 8 104.94 9 44. 45 10 77.86 11 34.44 12 20.03 13 13.23 14 48. 14 15 14.02 16 45.39 17 21. 19 18 44.61 19 25.68 20 7.23 0 61.33 1 29.85 2 21-23 3 52. 58 4 75.98 5 56.79 6 18.53 7 36.74 8 71.29 9 33.36 10 43.96 11 42. 06 12 125-48 13 54. 52 14 82-52 15 32.61 16 85. 12 17 39-34 18 44- 46 19 54. 33 1 77. 61 2 44.39 3 78. 83 4 43. 72 5 62.65 6 39.88 7 80.06 8 46.73 9 29-54 10 47. 23 11 39.91 12 47. 37 13 48.89 14 19.06 15 19-31 16 22. 56 17 K L FO PC 7 10 36. 13 34- 88 0 11 19.69* 20. 42 0 11 25.87* 22. 67 0 11 7. 41* 1. 25 0 11 55.56 53. 74 0 11 58. 81 60. 61 0 11 23.15* 30. 93 0 11 21. 25* 24. 26 0 11 69. 83 68. 06 0 11 39. 83 42. 52 0 11 20.38* 20. 62 0 11 65.74 63. 92 0 11 10 4. 19 10 3. 26 0 11 28.48* 27. 32 0 11 29.44* 22. 97 0 11 66. 55 69. 62 0 11 37. 82 42. 67 0 11 20.04* 24. 61 0 11 50.26 49. 35 0 11 24.73* 24. 30 0 11 6. 16* 23. 02 1 11 66.61 60. 65 1 11 41. 89 37. 48 1 11 106.57 101. 89 1 11 44. 97 39. 81 1 11 20.30* 18. 47 1 11 43.26 42. 43 1 11 31. 40 32- 48 1 11 26-71 21. 06 1 11 21.05* 23. 90 1 11 65. 25 65. 47 1 11 69. 16 70. 54 1 11 8. 10* 10. 24 1 11 110.40 109. 68 1 11 53. 5 1 53. 23 1 11 5.54* 20. 21 1 11 21.39* 16. 59 1 11 75.07 72. 68 1 11 18- 58* 22. 54 1 11 46.62 43. 03 1 11 38.34 35. 75 2 11 64. 56 62. 83 2 11 26.78* 31. 11 2 11 49. 59 51. 82 2 11 51. 32 48. 69 2 11 63- 97 61. 46 2 11 29- 19 29. 51 2 11 27. 41 24. 47 2 11 62. 13 64- 67 2 11 0. 00* 10. 97 2 11 38.34 33. 22 2 11 31. 83 29. 44 2 11 59.47 59- 73 2 11 8.96* 10. 30 2 11 19,20* 13. 74 2 11 64.38 64. 07 2 11 0. 00* 13, 90 2 11 20.15* 15. 90 H K L FO FC H K L FO FC 18 2 1 1 25.97* 27.05 7 6 1 1 14.74* 4. 39 19 2 11 40.22 37.29 8 6 1 1 42. 50 43. 83 0 3 11 39.99 39.35 9 6 1 1 15.13* 1 1. 98 1 3 11 29.16 26. 42 10 6 1 1 27. 97 25. 16 ' 2 3 11 141.77 140.43 11 6 11 32.76 32.63 3 3 11 31.06 32.55 0 7 11 32. 09 30. 90 4 3 11 33.14 28.77 1 7 11 10.67* 11. 56 5 3 11 51.89 51.67 2 7 11 49.40 49. 25 6 3 11 63.41 59. 19 3 7 11 31. 09 27. 54 7 3 11 15.09* 7. 17 4 7 11 11.93* 18. 94 8 3 11 26.34* 23. 18 5 7 1 1 16.62* 8. 52 9 3 11 59.60 58. 14 0 0 12 88.21 89.30 10 3 11 79.15 74.45 1 0 12 70. 03 70. 34 11 3 11 24.41* 18.32 2 0 12 43. 68 42. 48 12 3 11 85.95 85.58 3 0 12 66. 44 6 4. 27 13 3 11 70.33 70.32 4 0 12 34. 50 32.61 14 3 11 38.51 36.28 5 0 12 18.26* 11.77 15 3 11 31.88 25.78 6 0 12 18.87* 33. 37 16 3 11 57.64 54. 28 7 0 12 48. 22 49. 22 17 3 11 52.91 51. 37 8 0 12 32. 10 30.30 18 3 11 10.94* 8. 17 9 0 12 30.88* 26. 55 1 4 11 72.03 74.36 10 0 12 31.67* 29. 10 2 4 11 20.09* 27.53 11 0 12 70. 94 68.46 3 4 11 36.47 37.70 12 0 12 40. 88 37. 62 4 4 11 57.65 56.35 13 0 12 60.68 61. 34 5 4 11 47.17 48. 98 14 0 12 78. 70 79.78 6 4 11 27.81 26.41 15 0 12 40. 48 42- 06 7 4 11 22.70* 20. 28 16 0 12 69. 87 65.79 8 4 11 70.45 67.82 17 0 12 22.83* 10.65 9 4 11 37.59 38.02 1 1 12 23,61* 26. 30 10 4 11 0.00* 16.83 2 1 12 19.53* 14. 09 11 4 11 50,68 51.12 3 1 12 26.25* 26. 28 12 4 11 69.60 63.79 4 1 12 50. 87 54. 19 13 4 11 14.75* 13.48 5 1 12 17.65* 7.27 14 4 11 19.91* 10.04 6 1 12 31. 41 32. 27 15 4 11 47.00 42.01 7 1 12 11. 56* 4. 12 16 4 11 27.71* 26.31 8 1 12 42.95 44. 74 0 5 11 80.84 74. 30 9 1 12 52. 54 52. 29 1 5 11 83.08 84.49 10 1 12 79. 88 76. 40 2 5 11 144.67 144.67 1 1 1 12 21.85* 19. 19 3 5 11 57.16 57.08 12 1 12 57. 61 56. 60 4 5 11 46.18 42. 22 13 1 12 54.97 58.87 5 5 11 92.07 97.47 14 1 12 40. 04 39. 92 6 5 11 66.43 70.04 15 1 12 15.31* 7- 67 7 5 11 31.83 26.73 16 1 12 16.85* 13-36 8 5 11 60.61 58. 28 17 1 12 46. 62 46. 90 9 5 11 82.46 85.33 0 2 12 77.73 75. 96 10 5 11 87.87 91. 44 1 2 12 98. 98 98.66 11 5 11 51.34 50.83 2 2 12 79. 41 78- 45 12 5 11 96.48 98.50 3 2 12 62. 60 60.74 13 5 11 58.12 61.08 4 2 12 58. 87 58- 06 14 5 11 37.14 43.58 5 2 12 32.70 31.21 1 6 11 48.52 52.43 6 2 12 40. 40 38. 82 2 6 11 20.99* 20. 11 7 2 12 55. 41 50.56 3 6 11 38.45 41.20 8 2 12 72.35 73.33 4 6 11 44.26 46. 30 9 2 12 51.70 50. 91 5 6 11 37.07. 39. 51 10 2 12 20. 47* 10-71 6 6 11 38.86 39.13 11 2 12 94.30 95. 10 H K L FO 12 2 12 49. 06 13 2 12 41. 90 14 2 12 53. 01 15 2 12 68. 89 16 2 12 58. 11 17 2 12 23. 51* 1 3 12 41. 74 2 3 12 33. 5 8 3 3 12 72. 59 4 3 12 33. 58 5 3 12 26. 99 6 3 12 53. 74 7 3 12 35. 66 8 3 12 8. 36* 9 3 12 28. 14* 10 3 12 57. 51 11 3 12 27. 70* 12 3 12 30. 84 13 3 12 46. 65 14 3 12 28. 72* 15 3 12 20. 19* 0 4 12 125. 23 1 4 12 126. 89 2 4 12 51. 70 3 4 12 101. 46 4 4 12 75. 76 5 4 12 57. 12 6 4 12 39. 29 7 4 12 87. 71 8 4 12 40. 69 9 4 12 77. 19 10 4 12 22. 68* 1 1 4 12 1 15. 31 12 4 12 22. 37* 13 4 12 71. 80 14 4 12 47. 00 1 5 12 36. 49 2 5 12 31. 96 3 5 12 45. 66 4 5 12 55. 62 5 5 12 19. 91* 6 5 12 46. 69 7 5 12 18. 98* 8 5 12 37. 44 9 5 12 39. 34 10 5 12 56. 51 11 5 12 0. 00* 0 6 12 60. 14 1 6 12 69. 38 2 6 12 50. 65 3 6 12 39. 34 4 6 12 16. 13* 5 6 12 29. 11 6 6 12 24. 96* 1 0 13 0. 00* 2 0 13 40. 36 3 0 13 18. 92* 4 0 13 28. 41* F C H 49.47 5 40. 41 6 55.87 7 68.70 8 56. 41 9 14. 07 10 45.93 11 29.27 12 73.49 13 35. 56 14 24.45 15 52. 47 0 37.33 1 12.63 2 25. 47 3 57.77 4 26. 10 5 31.41 6 45.95 7 31. 15 8 28.61 9 124.80 10 125.94 11 53. 52 12 100. 10 13 77. 50 14 56. 42 1 35.82 2 90.73 3 37. 96 4 73. 56 5 21.72 6 115.36 7 28.56 8 69.04 9 42.79 10 30.50 11 33.26 12 40.04 13 54.03 14 7.39 0 42. 92 1 12. 52 2 39. 16 3 41.59 4 55. 85 5 9.49 6 55. 80 7 68.89 8 50.29 9 38. 11 10 16.02 11 24. 54 12 27.36 1 0. 46 2 42. 40 3 0.80 4 25.74 5 K L FO FC 0 13 21.97* 6. 37 0 13 47.39 42. 72 0 13 51.61 51. 75 0 13 60. 03 59. 06 0 13 35. 46 35. 91 0 13 57.32 59. 35 0 13 45. 83 43. 61 0 13 46. 06 45. 84 0 13 23.08* 17. 30 0 13 64.60 64. 08 0 13 23.92* 20. 93 1 13 142.19 147. 71 1 13 84. 18 84. 00 1 13 31.28 25. 22 1 13 58. 47 54. 64 1 13 80.31 81. 12 1 13 59.21 61. 28 1 13 37.39 39. 56 1 13 50. 30 52. 91 1 13 52. 03 4 9- 78 1 13 55.42 56. 96 1 13 73.99 74. 72 1 13 76. 95 75. 19 1 13 16.29* 4. 13 1 13 54.51 56. 77 1 13 91.76 90. 10 2 13 36.69 36. 63 2 13 31. 96 30. 57 2 13 38.64 32. 10 2 13 21.46* 16. 28 2 13 23.70* 26- 59 2 13 30.78 31. 96 2 13 0.00* 6. 59 2 13 28. 18 25. 79 2 13 24. 85* 17- 36 2 13 52.78 55. 71 2 13 32.57 31. 04 2 13 30. 68 30. 36 2 13 31.00 26. 47 2 13 65.37 66. 38 3 13 118. 76 119. 58 3 13 79.55 77. 46 3 13 22.45* 31. 25 3 13 66. 54 66. 79 3 13 83. 02 82- 29 3 13 40.33 41- 59 3 13 36. 98 36- 36 3 13 36. 18 33- 74 3 13 56.92 59. 57 3 13 64.04 65. 10 3 13 56. 48 56. 15 3 13 56.65 57. 64 3 13 25-77* 25. 10 4 13 33. 86 28. 10 4 13 46.20 44. 62 4 13 16.90* 21- 65 4 13 21.37* 26. 94 4 13 43. 56 37. 97 H K L FO FC H K L FO FC 6 4 13 50. 60 47.09 9 1 14 28.22* 26. 08 7 4 13 0.00* 11.01 10 1 14 35. 12 29. 92 8 4 13 37. 43 32-68 1 1 1 14 13.81* 22. 60 9 4 13 25.69* 27.71 0 2 1.4 55.99 55. 33 10 4 13 52.71 50.34 1 2 14 35. 82 32.38 0 5 13 1 13.69 116.85 2 2 14 120.59 124-71 1 5 13 63. 51 63.77 3 2 14 43. 18 48. 58 2 5 13 53. 83 49.73 4 2 14 41. 13 43- 67 3 5 13 66. 36 67.94 5 2 14 42. 78 38. 00 4 5 13 60. 37 60. 41 6 2 14 57. 05 61.03 5 5 13 29.02* 33.03 7 2 14 35. 48 42. 21 6 5 13 17.24* 23- 15 8 2 14 48. 92 53. 94 0 0 14 30,83* 22. 21 9 2 14 41. 1 1 43. 21 2 0 14 . 159. 19 162-28 1 3 14 33.45 31.37 3 0 14 12.20* 9.24 2 3 14 15.22* 13. 50 4 0 14 0. 00* 1 1.85 3 3 14 8.52* 8.90 5 0 14 25.83* 13.78 4 3 14 41.00 37. 37 6 0 14 53. 70 50-84 5 3 14 34.22 31.76 7 0 14 8. 19* 21. 71 6 3 14 0. 00* 6. 17 8 0 14 36. 25 38-02 7 3 14 10.46* 17. 52 9 0 14 19.50* 2.47 0 4 14 26.05* 24- 77 10 0 14 32.53* 33.07 1 4 14 40. 09 35. 15 11 0 14 21.29* 20. 11 2 4 14 107. 89 109-38 1 1 14 22.09* 18.64 1 0 15 37. 48 38. 85 2 1 14 30.56 21.43 2 0 15 28. 89* 24. 62 3 1 14 7.68* 13-42 3 0 15 15. 94* 13. 05 4 1 14 37.62 37-02 4 0 15 26.90* 24. 33 5 1 14 17.61* 5.94 0 1 15 1 18,59 122. 43 6 1 14 20.73* 17.88 1 1 15 67. 28 67.44 7 1 14 8. 38* 14.98 2 1 15 40. 12 3 8. 59 8 1 14 41. 38 37. 11 3 1 15 50.36 47.71 * DENOTES AN UNOBSERVED REFLECTION 20 1,3,7-Trimethyl-2,6-dioxypurine Hydrochloride Dihydrate (Caffeine Hydrochloride Dihydrate) Anthony Mercer and James Trotter. Observed and calculated structure amplitudes ( r e f l e c t i o n s with i n t e n s i t y < 3«sr(T) are marked with an asterisk) . The following planes which had |Fo-Fc|> 3 (F) were given zero weight i n the f i n a l stages of refinement due to suspected instrumental errors. Fo Fc Fo Fc 1 0 2 70.72 91.91 • 1 4 2 6. 87 0. 36 7 5 4 4.78 0. 20 1 2 16 3. 87 0.93 3 6 12 4. 22 1. 2C ) H K L FO FC WEIGHT -13 0 2 10.05 9.88 5.67 -13 0 4 8. 14 8.34 5,44 -13 0 6 7.66 7.79 5.72 -13 0 8 12.23 12.89 4.92 -13 0 10 11. 23 12.00 5. 11 -13 0 12 9.62 10.06 6. 05 -13 0 14 13.42 14.30 4. 15 -13 0 16 8. 44 8.62 5.92 -12 0 2 6. 99 6.94 6. 37 -12 0 4 15. 55 15.51 3. 75 -12 0 6 16.58 16.18 3.68 -12 0 8 14. 4 2 15.75 4. 20 -12 0 10 3. 51* 4.77 0.23 -12 0 12 13. 95 13.85 4. 35 -12 0 14 7. 32 7. 40 5. 42 -12 0 16 0.95* 1.17 0.03 -12 0 18 18.60 20.11 2.79 -11 0 2 8. 13 7.29 6.24 -11 0 4 6.23 5.64 7.01 -11 0 6 16. 67 16.79 3. 50 -11 0 8 10.88 11.57 4.50 -11 0 10 10. 36 10.67 4. 89 -11 0 12 24.26 24. 19 2.04 -11 0 14 10. 93 11. 23 5. 95 -11 0 16 9. 92 9.40 6.57 -11 0 18 6. 14 6.11 6. 01 -10 0 2 11.10 10.69 5.01 -10 0 4 3.35* 1.53 0. 33 -10 0 6 12.68 13.33 4. 97 -10 0 8 4. 34 5.0 2 3. 46 -10 0 10 16.47 17. 06 3. 99 -10 0 12 4.51 4.07 5.50 -10 0 14 11. 32 11. 54 5. 80 -10 0 16 12.93 13.85 4. 59 -10 0 18 4.91 4.70 4. 18 -9 0 2 10.63 10.46 6.22 -9 0 4 31. 79 32. 17 1. 34 -9 0 6 3.25 2. 43 3. 95 -9 0 8 28. 52 2 8.51 1.60 -9 0 10 7. 23 6.82 7.41 -9 0 12 4.37 3. 23 3. 33 -9 0 14 19.88 2 0.48 2.94 -9 0 16 14.73 15.51 3.86 -9 0 18 20.02 19.78 2. 83 -8 0 2 3. 41 4. 10 3.91 -8 0 4 34. 93 36. 94 1. 13 -8 0 6 3.54 3. 96 6. 21 -8 0 8 6.02 5.97 7.71 -8 0 10 3. 69 1.95 6. 87 -8 0 12 19.78 20.08 2.92 -8 0 14 2.66* 1.83 0.15 -8 0 16 18.53 19.29 3.20 -8 0 18 12.39 12.30 4.87 -7 0 2 19. 17 19.88 3. 18 -7 0 4 38.70 39.06 0. 95 -7 0 6 1. 34* 0.82 0. 10 -7 0 8 24.63 24.35 2.13 -7 0 10 53. 74 54.29 0.50 H K L FO FC WEIGHT -7 0 12 22.77 23. 75 2. 43 -7 0 14 21.90 22. 56 2.41 -7 0 16 2. 11* 1. 24 0. 12 -7 0 18 8.15 7. 54 6.53 -6 0 2 14.14 14. 63 5.24 -6 0 4 64.77 66. 43 0. 35 -6 0 6 4.34 4. 81 5.94 -6 0 8 32.95 33. 54 1.30 -6 0 10 22.36 22. 22 2. 54 -6 0 12 11.79 11. 80 4. 82 -6 0 14 24.37 24.45 2.08 -6 0 16 22.89 23. 11 2. 38 -6 0 18 6.79 6. 58 6.04 -5 0 2 20.45 20. 14 3. 06 -5 0 4 41.05 41. 75 0. 86 -5 0 6 6.11 6. 05 8. 19 -5 0 8 3.86 4. 33 6. 30 -5 0 10 32.63 30. 23 1. 23 -5 0 12 20.41 20. 09 2.94 -5 0 14 27.16 27. 61 1.72 -5 0 16 4.12 5.05 3.26 -5 0 18 6.75 6. 65 5.06 -4 0 2 44.36 45.75 0.74 -4 0 4 4.31 4.57 11. 84 -4 0 6 34.72 35.47 1.18 -4 0 8 86.04 87. 24 0. 20 -4 0 10 33.24 33. 44 1.27 -4 0 12 18. 81 19. 16 3. 39 -4 0 14 19.34 19. 09 3. 13 -4 0 16 3.26* 0. 70 0.36 -4 0 18 5,48 4. 86 5. 35 -3 0 2 72.30 73. 10 0. 28 -3 0 4 37.51 36. 99 1.03 -3 0 6 78.09 79. 28 0. 24 -3 0 8 20.26 20.56 3. 04 -3 0 10 15.46 14. 86 4. 63 -3 0 12 1.50* 1. 61 0. 09 -3 0 14 21 .49 21. 09 2.75 -3 0 16 6.28 6. 45 4. 33 -3 0 18 17.82 17. 52 3.55 -2 0 2 1. 84* 0. 72 0. 60 -2 0 4 47 . 36 52. 90 0.59 -2 0 6 32.74 32. 20 1.33 -2 0 8 6.31 6. 91 8. 53 -2 0 10 2.80* 2.42 0. 39 -2 0 12 7.64 7. 10 7.14 -2 0 14 8.78 8. 85 6.55 -2 0 16 10.30 9. 58 6. 93 -2 0 18 4.12 4. 09 3.49 -1 0 4 3.55 3. 61 10.71 -1 0 6 112.12 117.39 0. 12 -1 0 8 24.86 25. 11 2. 16 -1 0 10 39. 15 39. 24 0. 94 -1 0 12 4.20 3. 73 5. 01 -1 0 14 22.83 23. 73 2. 28 0 16 8.24 7. 30 6.29 -1 0 18 5.36 4. 56 5.6 3 0 0 2 52.74 50. 94 0.52 H K L FO FC WEIGHT H K L 0 0 4 15. 5 8 14.94 3. 55 7 0 4 0 0 6 50.51 51.12 0.55 7 0 6 0 0 8 34. 36 32.73 1.16 7 0 8 0 0 10 34. 33 3 2.48 1.18 7 0 10 0 0 12 36.91 35.04 1.02 8 0 0 0 0 14 45. 24 44.42 0.69 8 0 2 0 0 16 8.74 8.01 4. 47 8 0 4 0 0 18 7.71 7.10 7.41 8 0 6 1 0 0 9.31 9.95 2. 10 8 0 8 1 0 2 8. 85 6.89 4.91 8 0 10 1 0 4 74. 64 74.39 0.27 9 0 0 1 0 6 30.66 29.44 1.48 9 0 2 1 0 8 3.64 3.97 5.47 9 0 4 1 0 10 46. 32 45. 92 0.68 9 0 6 1 0 12 33. 14 32. 58 1. 25 9 0 8 1 0 14 15.49 15.48 3. 89 10 0 0 1 0 16 7.70 7.46 6. 22 10 0 2 2 0 0 72.67 72.05 0. 27 10 0 4 2 0 2 36. 94 36.31 1.05 10 0 6 2 0 4 63.60 62.55 0.36 11 0 0 2 0 6 23. 62 2 5. 28 2.34 11 0 2 2 0 8 12.50 11.91 5. 58 11 0 4 2 0 10 8.64 8.43 5.76 12 0 0 2 0 12 9.98 9. 93 5.39 12 0 2 2 0 14 5.86 4.06 6. 88 13 0 0 2 0 16 6.74 6.00 7.05 -13 1 1 3 0 0 108. 82 96.59 0.13 -13 1 2 3 0 2 20. 69 18.99 2. 95 - 13 1 3 3 0 4 19. 82 19.22 3.17 -13 1 4 3 0 6 17.44 17. 65 3.76 -13 1 5 3 0 8 9.57 8.62 7. 18 -13 1 6 3 0 10 5.51 5. 34 3.59 - 13 1 7 3 0 12 23. 13 21.02 2. 34 -13 1 8 3 0 14 12.97 12. 28 5. 25 -13 1 9 4 0 0 6. 49 7.70 3.03 -13 1 10 0 2 8. 25 8. 30 8.75 - 13 1 11 4 0 4 31. 39 30. 74 1.40 -13 1 12 4 0 6 26.59 26. 33 1.85 -13 1 13 4 0 8 24.63 24. 11 2. 12 -13 1 14 4 0 10 28.99 28.21 1. 53 -13 1 15 4 0 12 21. 67 20. 56 2.46 -13 1 16 4 0 14 4. 84 3.49 6.25 -13 1 17 5 0 0 21.88 20. 92 2. 61 -12 1 1 5 0 2 89.93 83.51 0. 18 -12 1 2 5 0 4 20. 84 19.48 2. 86 -12 - 1 3 5 0 6 6. 06 5. 83 6.02 -12 1 4 5 0 8 3. 44* 2. 87 0.23 -12 1 5 5 0 10 4.91 4.74 4.00 -12 1 6 5 0 12 10. 53 10.70 5.39 -12 1 7 6 0 0 14.09 14.36 4.90 -12 1 8 6 0 2 20.34 20.03 2.96 -12 1 9 6 0 4 27. 68 26.86 1.76 -12 1 10 6 0 6 23.32 24.00 2. 20 -12 1 11 6 0 8 2. 49* 1.52 0.15 -12 1 12 6 0 10 9. 30 8.76 6.37 -12 1 13 6 0 12 2. 61* 1.02 0. 22 -12 1 14 7 0 0 14. 37 14.52 4. 98 -12 1 15 7̂ 0 2 21. 09 19.26 2.75 -12 1 16 FO FC WEIGHT 27.69 26. 79 1.72 16.17 16.77 3.56 0.00* 0. 92 0. 00 11.62 10. 73 5.55 7.03 6.02 6.69 29.22 28.45 1.53 12. 26 12. 64 4.28 13.65 12. 86 4. 64 4. 11 4. 09 3. 12 3.14* 2.65 0.33 19.54 19. 39 2. 97 10.11 10.14 5.36 1.91* 0. 23 0.09 15.44 14.60 4.11 2.46* 2. 32 0. 18 6. 19 6. 29 4. 21 0.00* 0. 88 0. 00 3.16* 0.43 0.40 2.49* 0.59 0.28 4.34 4.09 2.70 19. 14 18. 24 2.98 1.98* 1.63 0.11 2.32* 1.23 0.18 6.39 6. 72 7. 10 2.88* 2. 63 0. 26 2.17* 2.49 0.14 7.90 7.89 6.10 1.55* 0.18 0.07 6.05 6. 57 4.28 7.97 8. 50 4.46 6.04 5. 47 5.79 3.62 0.57 4.28 4.09 3. 59 3. 54 6.66 6.83 4.93 3.33* 0.70 0.29 15.72 17. 03 3.46 7.75 7. 85 5.73 9.65 9.77 6.13 8.67 9.06 5.65 5.52 6.35 4.46 4.60 4. 90 4.03 6.91 7,06 6.16 4.84 3.69 6.50 1 .37* 0.03 0.06 2. 18* 1. 74 0. 10 2.72* 0.52 0.19 8.24 8. 05 5. 17 4.84 3.49 3.96 7.95 9.39 3.63 3.65 1. 66 3.75 7.07 6. 61 5.66 6.61 6.19 6.98 3.29* 2. 34 0.25 7.30 6. 53 5. 92 5.87 5. 08 6. 85 8.18 8. 27 5.48 8.56 7.80 8.14 3.44 0. 70 4. 64 H K I FO FC WEIGHT 12 1 17 3. 06* 1.87 0.26 12 1 18 6. 05 6.03 5. 96 11 1 1 11.79 11. 13 6. 21 11 1 2 4. 80 4.14 3.83 11 1 3 2.44* 0.99 0.14 11 1 4 11.12 11.22 4. 64 11 1 5 11.31 11.97 4.72 11 1 6 4. 56 5.94 2.42 11 1 7 9.06 9.12 5.39 11 1 8 3. 34 1.82 3. 47 11 1 9 3.78 1.23 4. 15 11 1 10 2.51* 1.14 0. 16 11 1 11 4.68 2.82 5.29 11 1 12 5. 82 5.44 4. 89 11 1 13 13.32 13. 33 4.71 11 1 14 5. 92 5.76 3. 38 11 1 15 9. 94 10.51 4.94 11 1 16 5. 21 3.59 6.75 11 1 17 10.53 10.88 5.06 11 1 18 5. 14 4.25 6.50 10 1 1 16.20 15.74 3.55 10 1 2 9.70 9.49 6.26 10 1 3 5.19 5.32 4.83 10 1 4 8.79 8.70 5.07 10 1 5 26. 04 25. 17 1.85 10 1 6 8. 30 8.81 5.16 10 1 7 14. 96 13.90 4. 23 10 1 8 6.77 5.52 6. 37 10 1 9 18.72 18.84 3.13 10 1 10 12.00 12.08 4. 86 10 1 11 24. 72 25.78 2.01 10 1 12 2.24* 1.11 0.14 10 113 3. 30* 1.98 0.26 10 1 14 8. 25 7. 84 5,14 10 1 15 16.71 16.53 3.79 10 1 16 7.81 7.22 4. 30 10 1 17 2. 38* 0.86 0. 16 10 1 18 11. 40 11. 55 5. 82 -9 1 1 19. 66 19.49 2.84 -9 1 2 2. 59* 3.59 0. 13 -9 1 3 13. 97 13. 34 4. 64 -9 1 4 2. 50* 1. 96 0. 18 -9 1 5 4.00 3.23 3.55 -9 1 6 13. 20 12.40 5.34 -9 1 7 17.55 17.55 3.55 -9 1 8 8.50 7.27 6. 46 -9 1 9 12. 57 14. 17 5.08 -9 1 10 16. 01 16. 20 3. 80 -9 1 11 11.61 1 1. 09 5.42 -9 1 12 7.41 7.46 5. 17 -9 1 13 4. 32 4.35 2.71 -9 1 14 5. 28 4.66 4.26 -9 1 15 15.65 15.38 4.23 -9 1 16 12.32 12.33 5. 33 -9 1 17 10.98 10.94 5.29 -9 1 18 3. 38* 2.31 0.31 -8 1 1 16. 66 15.84 3. 85 -8 1 2 4. 48 3.80 4.88 H K L FO FC WEIGHT -8 1 3 8.08 8. 66 6.78 -8 1 4 26.71 25. 01 1. 86 -8 1 5 18.40 18. 75 3. 37 -8 1 6 10.89 10. 26 5.70 -8 1 7 12.72 12. 84 6.00 -8 1 8 0. 74* 2. 17 0.02 -8 1 9 8,04 8. 25 6.37 -8 1 10 28. 12 27. 37 1.65 -8 1 11 23.64 23. 50 2. 26 -8 1 12 1.44* 3. 37 0. 04 -8 1 13 8.87 9. 51 4. 92 -8 1 14 16.74 16. 91 3.57 -8 1 15 5.57 4.53 4. 48 -8 1 16 16.63 16. 90 3.54 -8 1 17 4. 14 1. 94 3.76 -8 1 18 3, 88 4. 29 2.64 -7 1 1 24.72 23.64 2. 11 -7 1 2 18. 80 18. 56 3. 32 -7 1 3 13.86 13. 97 4. 86 -7 1 4 9.18 8. 89 7. 45 -7 1 5 27 . 93 28. 80 1.74 -7 1 6 12.56 12. 40 5.98 -7 1 7 4.93 5. 09 6. 10 -7 1 8 29.21 29. 05 1.60 -7 1 9 13.58 13. 05 5.55 -7 1 10 18.00 18. 22 3.55 -7 1 11 25.24 25. 89 2.00 -7 1 12 8.04 8. 14 6.62 -7 1 13 9.43 9.59 6.10 -7 1 14 3,81 2. 51 3.26 -7 1 15 13.33 12. 93 4.75 -7 1 16 7. 85 8. 19 5.04 -7 1 17 2.46* 1. 09 0. 16 -7 1 18 6.45 6. 05 6. 04 -6 1 1 34.05 32.91 1. 20 -6 1 2 27.72 27. 49 1.75 -6 1 3 48.63 46. 29 0.61 -6 1 4 15.84 15.81 4.28 -6 1 5 16.17 16. 21 4. 39 -6 1 6 11. 17 11. 60 6.83 -6 1 7 44.28 46. 90 0.73 -6 1 8 2. 13* 1. 60 0. 23 -6 1 9 11.41 10. 53 6. 68 -6 1 10 13.46 11.94 5.41 -6 1 11 3.61 3. 76 4. 11 -6 1 12 1.83* 0. 49 0.12 -6 1 13 14.39 13. 97 4.54 -6 1 14 3.34* 1. 22 0. 35 -6 1 15 21.53 22. 11 2.68 -6 1 16 7.38 6. 75 7. 29 -6 1 17 16.63 17. 04 3.65 -6 1 18 6.67 6. 37 6. 14 -5 1 1 23.27 22. 58 2.42 -5 1 2 12.00 11. 88 6. 40 -5 1 3 23.86 24.50 2.30 -5 1 4 16. 12 15. 28 4.48 -5 1 5 16. 10 16. 32 4. 43 -5 1 6 6.28 6. 11 8. 25 H K I FO FC WEIGHT 5 1 7 31.71 3 2.24 1.38 5 1 8 13.06 13. 11 5.74 5 1 9 7.70 6.73 8.34 5 1 10 15. 24 15. 16 4.61 5 1 11 19.93 20.23 3. 08 5 1 12 4.54 4.55 4.65 5 1 13 7. 90 7.79 6.16 5 1 14 3. 26* 3.35 0.22 5 1 15 10. 28 10.45 5.96 5 1 16 14.10 13.58 4.73 5 1 17 15.37 15.00 4.11 5 1 18 4. 64 2.84 5.70 4 1 1 48. 32 48.82 0.63 4 1 2 116.47 115.24 0.11 4 1 3 39.41 3 8.98 0.94 4 1 4 39. 68 3 7.42 0.93 4 1 5 7. 19 7.71 10.56 4 1 6 33.43 33.31 1.26 4 1 7 54. 85 56.98 0.49 4 1 8 6.40 6.72 8.63 4 1 9 14.67 14.83 5.07 4 1 10 28. 00 26. 18 1.77 4 1 11 36. 66 37.75 1.04 4 1 12 20.59 20.87 2.93 4 1 13 3. 00* 3. 47 0. 23 4 1 14 11.61 10.88 5. 90 4 1 15 17. 15 17.50 3. 49 4 1 16 2.68* 3.02 0.13 4 1 17 12. 61 11.72 5. 38 4 1 18 1.75* 2. 80 0.07 3 1 1 176.28 177.91 0.05 3 1 2 25.74 23. 28 2. 11 3 1 3 75. 86 73. 93 0. 26 3 1 4 37.51 38.48 1.02 3 1 5 18.74 18. 1 1 3.79 3 1 6 25. 19 25.02 2. 15 3 1 7 41.41 42.89 0. 84 3 1 8 8. 82 8.28 7.46 3 1 9 14. 82 13.61 5. 01 3 1 10 20.95 19.77 2.88 3 1 11 29. 82 30.73 1. 53 3 1 12 20.75 20.47 2.87 3 1 13 7. 56 7.73 5.95 3 1 14 21. 57 21.51 2.49 3 1 15 26. 04 26.40 1.87 3 1 16 16.43 15.99 4.02 3 1 17 9.56 8. 96 5.45 3 1 18 7.22 6.70 5.68 2 1 1 45.08 4 2.71 0.71 2 1 2 25. 67 25.46 1.81 2 1 3 37. 12 38. 85 1.07 2 1 4 40. 01 41.41 0.91 2 1 5 43.00 44.63 0.78 2 1 6 20.76 19.59 3.06 2 1 7 4. 12 2.86 6.23 2 1 8 8.53 9.73 7.41 2 1 9 15.24 13.76 5.05 2 1 10 22.4 2 21.51 2.53 H K L FO FC WEIGHT -2 1 11 38.37 38. 72 0. 97 -2 1 12 2.38* 0. 17 0.23 -2 1 13 34.38 34. 34 1.18 -2 1 14 14. 10 14.53 4. 52 -2 1 15 4.89 4.56 3.04 -2 1 16 1.84* 1. 28 0. 09 -2 1 17 9.51 9.73 5. 66 • -2 1 18 5.73 5. 35 6.48 -1 1 1 48.57 42. 93 0.61 -1 1 2 28.53 29.52 1.41 -1 1 3 28.89 31. 86 1.63 -1 1 4 22.08 24. 75 2.74 -1 1 5 47.80 53. 23 0.63 -1 1 6 8. 55 8. 21 9. 79 -1 1 7 51.29 56. 06 0. 55 -1 1 8 24.70 24. 91 •2 • 2 2 -1 1 9 5.21 4. 29 8.49 -1 1 10 10,87 10. 51 7.04 -1 1 11 2.14* 1.94 0. 19 -1 1 12 3.61 2. 04 5. 65 -1 1 13 4. 54 6. 17 2. 93 -1 1 14 15.13 15.75 4. 30 -1 1 15 9.51 9. 52 5. 51 -1 1 16 1.94* 0. 28 0.11 -1 1 17 7.25 7. 05 7. 28 -1 1 18 3.50 2. 04 4.64 0 1 1 27.60 30. 18 1. 75 0 1 2 21 .13 24. 22 2.96 0 1 3 6.63 7. 25 1 3.99 0 1 4 14.79 16.73 5. 12 0 1 5 3.03 2.72 6.29 0 1 6 37.51 40. 34 1.02 0 1 7 41.99 43. 75 0.82 0 1 8 20.48 21.05 3. 04 0 1 9 19. 87 20. 38 3. 25 0 1 10 12.67 14. 12 5.55 0 1 11 9.56 10. 29 5. 27 0 1 12 23.24 23.87 2. 36 0 1 13 8.26 7. 81 7. 81 0 1 14 10.44 10. 72 6.10 0 1 15 4.04 2.58 4. 80 0 1 16 1 .97* 0.71 0. 13 0 1 17 8.46 8. 27 7.18 0 1 18 4.05 3. 29 7.36 1 1 0 83.54 82.22 0.21 1 1 1 20. 83 21. 18 3. 13 1 1 2 11.74 12. 28 7.72 1 1 3 63. 58 69. 94 0. 36 1 1 4 49.91 53.45 0,58 1 1 5 8.04 8. 12 9.51 1 1 6 2.83 2. 08 5. 93 1 1 7 10.25 12.57 7.32 1 1 8 15.34 15.09 4.68 1 1 9 15.94 16. 38 4. 62 1 1 10 4.81 3. 10 5. 00 1 1 11 18. 13 18. 26 3. 44 1 1 12 5.76 3.54 6.89 1 1 13 16. 22 16. 19 3. 89 H K 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 •3 3 3 3 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 FO FC WEIGHT 14 15 16 17 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 0 1 2 3 4 5 7. 24 6.92 3.08* 0.25 9.56 8.93 7.96 7,18 49.39 50.43 68.70 69.59 31.20 30.08 69.94 71.77 12.00 12.49 45.82 46.29 39.08 39.02 12.39 13.17 11.07 10.99 13.97 14.02 5.74 5.40 2.93* 2.01 17.23 16.81 9.35 9.85 6. 50 6.31 4. 52 3.57 3.70 2.61 129.16 129.05 12.58 12.43 34.71 20. 22 11. 49 6. 03 3. 79 38. 86 1.48* 12.96 2.65* 23. 37 0. 00* 22. 46 3. 2 8* 3. 12* 42.74 0. 00* 16. 92 50. 24 26. 10 12. 39 18.62 14.72 4.58 15.61 8. 24 0. 87* 12. 70 6. 83 8.53 2.78* 3. 23 9. 41 38.07 22.78 12.53 35.71 21.07 11.47 5.30 2.53 39.60 0. 77 12.75 0.48 23.62 0. 40 22. 24 3.39 2.23 42.21 1.10 18.72 50. 77 26.67 12.77 18.45 15.02 5.30 15.75 8.32 1. 48 11.96 5.67 7.66 1.33 3. 33 9.69 38.82 23.24 12. 09 5.77 0. 36 7,32 8.06 0.61 0. 32 1. 45 0.30 7.03 0. 68 0.94 6.24 6.21 5.48 6. 17 0.24 3.46 6. 08 7.40 4.72 4.94 0.09 6. 80 1.18 3.11 6. 99 8.79 6. 21 0.95 0.08 5.64 0. 20 2.31 0.00 2.34 0.24 0.30 0. 80 0.01 4. 16 0.58 1.95 5. 96 3.46 4. 81 3.71 4. 13 5. 97 0.02 4 .96 8.41 9. 80 0.48 3.90 8.72 0. 98 2. 50 5.91 H K I FO FC WEIGHT 5 1 6 5,66 4.57 6.51 5 1 7 21.08 21. 36 2. 61 5 1 8 8.22 8. 81 5. 30 5 1 9 5.53 4.96 4.54 5 1 10 6.29 6. 02 5. 14 5 1 11 3,26* 2.33 0.26 5 1 12 14.63 14.71 4.72 5 1 13 3.76 3. 39 3. 67 6 1 0 10.19 10. 86 7.58 6 1 1 16.44 16. 32 4. 47 6 1 2 0.00* 1. 17 0.01 6 1 3 7,12 5. 73 8.68 6 1 4 4,91 4. 30 4.04 6 1 5 6.41 6. 36 5. 42 6 1 6 7.00 6.71 6.20 6 1 7 16. 21 15. 73 3. 30 6 1 8 4. 15 2.90 4. 46 6 1 9 2.87* 0.83 0.29 6 1 10 3. 28 0. 71 3.61 6 1 11 10.96 10.78 5, 12 6 1 12 0.00* 0.48 0.00 7 1 0 8.39 8. 40 9.06 7 1 1 8,26 7.77 8.53 7 1 2 14.59 14. 26 4. 89 7 1 3 19.36 19.41 3.08 7 1 4 8. 24 8. 48 5.79 7 1 5 14. 28 14. 57 4.81 7 1 6 6.81 6. 64 5. 56 7 1 7 5,38 4.94 4.42 7 1 8 2.03* 0.50 0,11 7 1 9 17.46 17. 63 3. 58 7 1 10 4.87 4.45 4.54 7 1 11 2.47* 1, 04 0.25 8 1 0 6.01 5. 19 5.72 8 1 1 12.87 13. 13 4.64 8 1 2 6.71 6. 50 6. 29 8 1 3 15. 30 15. 00 4.00 8 1 4 5.67 5. 22 4. 82 8 1 5 3.93 1. 97 4. 14 8 1 6 4.82 3.63 5.45 8 1 7 3.51 1. 69 3.95 8 1 8 2.76* O.07 0.24 8 1 9 3. 84 3. 96 3. 68 9 1~ 0 9.01 8.72 6.50 9 1 1 9.36 9. 76 6. 26 9 1 2 8.10 •8, 67 5.09 9 1 3 5.44 6. 09 4. 47 9 1 4 9.09 9. 98 6, 10 9 1 5 8.89 8. 66 7.59 9 1 6 3.45 0. 54 4. 26 9 1 7 6.64 6.78 5.29 9 1 8 5. 33 4. 35 8. 24 • 10 1 0 4.17 2. 84 4,50 10 1 1 3.24* 0. 34 0.35 10 1 2 6.03 6. 04 5.07 10 1 3 12.53 13.23 5.02 10 1 4 3.43* 4. 18 0. 24 10 1 5 8,03 8, 69 6.49 H K I FO FC WEIGHT 10 1 6 2. 80* 2.61 0.26 11 1 0 3.71 1.41 3. 95 11 1 1 7.32 7. 97 5. 13 11 1 2 5. 74 5.27 7.54 11 1 3 0. 00* 0.48 0.00 11 1 4.36 4.35 6.02 12 1 0 1.95* 1.90 0. 13 12 1 1 1.79* 2.32 0. 08 12 1 2 5.54 6.12 5.44 13 1 0 2. 82* 3.29 0. 26 13 2 1 5. 04 4.91 5. 59 13 2 2 1.43* 1.86 0. 06 13 2 "3 3. 15* 1.91 0.37 13 2 10. 61 11.91 5. 30 13 2 5 3.25* 2.97 0.25 13 2 6 5.42 5. 96 , 4.48 13 2 7 3.26* 2.04 0. 30 13 2 8 1.63* 1.71 0.06 13 2 9 4.94 4. 24 6.66 13 2 10 0. 00* 0.29 0.00 13 2 11 1. 38* 1.42 0.06 13 2 12 11.97 12.39 5.25 13 2 13 6. 94 7.88 4. 50 13 2 14 6.5 3 6.80 6.27 13 2 15 3.11* 1.01 0. 40 13 2 16 5.06 5.89 5.26 12 2 1 2.46* 0.76 0. 20 12 2 2 10. 52 10.90 5. 84 12 2 3 2.37* 2.15 0. 16 12 2 4 6.44 5.29 5.67 12 2 5 1.59* 0.39 0.07 12 2 6 3.76* 4. 14 0. 24 12 2 7 2.74* 2. 24 0. 18 12 2 8 11.14 12.12 5. 20 12 2 9 4. 24 2.99 3. 34 12 2 10 5. 34 4.25 6. 12 12 2 11 8. 63 8. 83 6. 17 12 2 12 9.24 9.83 5.47 12 2 13 6. 15 5. 86 7.30 12 2 14 3.10* 0.98 0.39 12 2 15 2.35* 0.97 0.15 12 2 16 6. 68 7. 47 5.27 12 2 17 2. 19* 2.08 0. 13 12 2 18 2. 27* 0.83 0.23 11 2 1 7. 18 6.61 5.78 11 2 2 2.99* 3.47 0.15 11 2 3 3.86 4.33 2.73 11 2 4 3.96 2.40 4.01 11 2 5 4.74 3.19 5.07 11 2 6 3.06* 1.97 0.21 11 2 7 5.25 3.44 5.65 11 2 8 5.96 5.89 3.83 11 2 9 3.78 3.36 2.63 11 2 10 13.08 13. 12 4.64 11 2 11 5.00 4.4 9 3.93 11 2 12 24. 97 25.34 1. 97 11 2 13 3.78 1.81 3. 87 11 2 14 17.45 17.88 3.30 H K L FO FC WEIGHT — 11 2 15 2. 12* 2. 00 0.13 - 11 2 16 4.39 3. 68 4. 24 - 11 2 17 2.71* 1.74 0. 26 -11 2 18 6.69 7. 19 6.01 - 10 2 1 9.45 10. 06 4. 52 - 10 2 2 7. 24 7.43 4.63 - 10 2 3 15.84 16. 03 3.57 - 10 2 4 16.84 17.02 3.55 -10 2 5 2.01* 2. 16 0,08 -10 2 6 8.16 7. 79 6.17 - 10 2 7 7.89 7. 91 4.48 - 10 2 8 21.62 22. 07 2. 38 - 10 2 9 9.74 9.09 5. 34 - 10 2 10 7.24 7. 06 5.71 - 10 2 11 13.25 14. 03 4. 64 - 10 2 12 8.56 9.20 5.00 10 2 13 13. 88 14. 51 4. 18 - 10 2 14 10.34 11. 12 4. 65 - 10 2 15 4.26 2. 57 4.78 - 10 2 16 8.64 8.93 5.60 -10 2 17 0.42* 2. 52 0.00 - 10 2 18 5.20 6.20 5.00 -9 2 1 4.44 3.46 3. 83 -9 2 2 7.63 6. 96 6.43 -9 2 3 11. 16 11. 56 5. 10 -9 2 4 16.63 16. 78 3. 64 -9 2 5 4.24 2. 80 3.35 -9 2 6 3.41 2. 85 3. 15 -9 2 7 7.88 7. 57 5.98 -9 2 8 20.58 22. 11 2.71 -9 2 9 5.60 5. 15 5.51 -9 2 10 17.58 17. 84 3.22 -9 2 11 9.47 10. 28 4. 90 -9 2 12 16.07 16. 16 3.75 -9 2 13 0.00* 0. 69 0.00 -9 2 14 3.98 3. 01 4. 13 -9 2 15 2.26* 0. 04 0. 12 -9 2 16 2.66* 1. 53 0. 18 -9 2 17 5. 23 4. 35 6.63 -g 2 18 9.11 9. 25 6.39 -8 2 1 21.21 20.58 2. 65 -8 2 2 14.83 14. 69 4.50 -8 2 3 6.70 6. 89 6. 48 -8 2 4 5.07 3. 42 5. 32 -8 2 5 8.18 7. 41 7. 15 -8 2 6 7.83 8. 17 8. 16 -8 2 7 4.02 3. 83 5.05 -8 2 8 13.69 13. 75 4. 68 -8 2 9 4.54 4.91 3.40 -8 2 10 4.39 3. 39 3.67 -8 2 11 4.22 3. 01 4. 06 -8 2 12 19.11 20. 19 3. 22 -8 2 13 2. 64* 2. 07 0. 18 -8 2 14 21.64 22. 04 2. 57 -8 2 15 10.22 10.72 5.11 -8 2 16 5.75 4. 93 6. 23 -8 2 17 4.90 3. 50 5.79 -8 2 18 11.64 11.97 5. 63 B K I FO FC HEIGHT 7 2 1 19.97 18. 81 3.03 7 2 2 66.68 62. 92 0. 33 7 2 3 41.49 40.07 0.82 7 2 4 47. 72 47.33 0.63 7 2 5 15. 24 14.72 4.62 7 2 6 27. 43 27.07 1. 82 7 2 7 6.69 5.61 7.82 7 2 8 36.45 36.18 1. 05 7 2 9 11.08 11. 14 6.47 7 2 10 3.01* 2.50 0.27 7 2 11 6.65 6.66 4. 86 7 2 12 11.97 12. 56 5.37 7 2 13 6.43 5.42 4.92 7 2 14 6.78 5.99 6.94 7 2 15 7.54 7.40 4.69 7 2 16 21. 22 22.07 2.55 7 2 17 4.85 6. 15 3. 17 7 2 18 13. 02 13.23 4.76 6 2 1 49.49 47.39 0.58 6 2 2 27. 15 26.35 1. 82 6 2 3 13. 51 13.07 5.18 6 2 4 3. 18* 2.63 0. 36 6 2 5 15. 15 13.43 4. 45 6 2 6 11. 14 12. 05 6.84 6 2 7 9.04 7.97 6.86 6 2 8 27. 16 28.36 1. 80 6 2 9 19.07 18.50 3.27 6 2 10 8. 67 8.25 6.45 6 2 11 11.91 11. 07 5.39 6 2 12 13.15 13. 11 4. 77 6 2 13 13. 22 13. 86 4.50 6 2 14 24.40 24.69 2.05 6 2 15 17.76 18.54 3.28 6 2 16 17.24 17.78 3.26 6 2 17 3.81 2.95 2. 78 6 2 18 6.66 7.45 4.23 5 2 1 5. 60 5.99 8.51 5 2 2 44. 41 41.33 0.73 5 2 3 49.20 44. 03 0.60 5 2 4 7.32 8.04 7.80 5 2 5 20. 94 20.72 2.94 5 2 6 4. 89 4.26 7. 41 5 2 7 12.26 11.58 6.45 5 2 8 22. 36 23.02 2. 53 5 2 9 8. 90 8.01 8.23 5 2 10 41.85 42.99 0.82 5 2 11 6.09 5.63 6.05 5 2 12 21.82 22. 87 2.47 5 2 13 23.87 24.37 2.21 5 2 14 14. 67 13.52 4. 40 5 2 15 2.21* 2.49 0.11 5 2 16 15.79 15.67 3.92 5 2 17 4.40 3.98 4. 84 5 2 18 15.81 16.64 4.01 4 2 1 19.44 17.59 3.24 4 2 2 55. 24 49.53 0.48 4 2 3 12.90 12. 36 5. 84 4 2 4 76.55 73.12 0.25 H K L FO FC WEIGHT -4 2 5 8.07 8. 49 7.79 -4 2 6 1-2.92 12. 40 6. 20 -4 2 7 26.05 25. 17 1.99 -4 2 8 10.48 11. 56 7. 34 -4 2 9 33.65 33. 18 1.25 -4 2 10 18. 25 17. 48 3.67 -4 2 11 8.11 7.81 6.99 -4 2 12 6.43 6. 98 5. 54 -4 2 13 7.57 7.27 7.73 -4 2 14 13.92 14. 62 4. 49 -4 2 15 6.05 6. 24 4. 74 -4 2 16 16.90 16.92 3. 85 -4 2 17 2.93* 1.60 0. 30 -4 2 18 9.41 8. 82 6. 91 -3 2 1 20.73 18. 12 2.98 -3 2 2 16.07 16. 47 4.39 -3 2 3 46.35 41. 54 0.68 -3 2 4 7.85 8. 39 8. 40 -3 2 5 1.60* 0. 83 0. 19 -3 2 6 4.03 3. 40 4.62 -3 2 7 11.61 12. 32 6. 20 -3 2 8 15.42 16.57 4.76 -3 2 9 4.19 4.36 6.26 -3 2 10 20.92 22. 22 2. 97 -3 2 11 10.26 10. 12 6.51 -3 2 12 3.46 3. 24 3. 15 -3 2 13 27.4 9 26.71 1.76 -3 2 14 26.37 27. 68 1. 93 -3 2 15 2.51* 1.21 0. 14 -3 2 16 8.72 8, 85 4. 94 -3 2 17 2. 84* 1. 71 0.30 -3 2 18 2.36* 0. 91 0. 19 -2 2 1 0.28* 1.01 0.01 -2 2 2 37.86 33. 08 0.99 -2 2 3 16. 25 14. 67 4.35 -2 2 4 86.09 84.78 0. 20 -2 2 5 39.32 41. 10 0.92 -2 2 6 46.74 4 7. 46 0.66 -2 2 7 0.00* 2. 15 0. 01 -2 2 8 1.60* 3. 46 0. 10 -2 2 9 16.69 15. 61 4.06 -2 2 10 30.72 32.03 1. 46 -2 2 11 6.65 6.39 6.09 -2 2 12 9.04 8. 58 5. 83 -2 2 13 5.99 5.51 4. 09 -2 2 14 20.97 22. 00 2. 74 -2 2 15 10.51 11.52 5,58 -2 2 16 6.50 6. 52 5. 17 -2 2 17 9.13 8. 17 7.82 -2 2 18 11.10 10. 92 5, 83 -1 2 1 13.28 12.70 4. 35 -1 2 2 46.37 44.89 0.65 -1 2 3 9.66 9.56 9. 14 -1 2 4 55.66 60. 91 0.47 -1 2 5 34.76 36. 98 1. 18 -1 2 6 8.83 10. 03 8. 03 -1 2 7 42.39 42. 80 0.81 -1 2 8 6.65 6.94 8.64 H K 1 FO FC WEIGHT 2 9 22.41 21.86 2. 53 2 10 24.77 25.41 2.13 2 11 20. 93 21.10 2.70 2 12 1. 24* 0.88 0.04 2 13 7.50 6.77 5. 80 2 14 6. 90 6.06 6.75 2 15 1. 32* 0.31 0. 04 2 16 4.19 4. 17 2. 69 2 17 2.97* 0.56 0.42 2 18 2. 84* 3.16 0.23 0 2 0 26.51 20.38 1.58 0 2 1 39. 84 41.81 0.85 0 2 2 35. 92 40.41 1.09 0 2 3 2.76* 3.39 0.42 0 2 4 27.47 33.09 1.81 0 2 5 1. 60* 0.34 0. 21 0 2 6 2.40* 1.70 0.33 0 2 7 17. 36 16.65 3.98 0 2 8 3.26 3.95 3.71 0 2 9 3. 90 4.24 3.70 0 2 10 19.47 21.01 3. 20 0 2 11 3.46 3. 82 3.07 0 2 12 3. 70 2.73 2.84 0 2 13 4. 46 2.53 4.71 0 2 14 14.85 15.67 4. 18 0 2 15 8.10 7.64 7.46 0 2 16 4. 68 5.47 2.94 0 2 17 4.00 3. 32 3.92 2 0 36. 01 36.65 1.06 2 1 11. 53 11.72 7.41 2 2 51. 48 55.54 0. 55 2 .3 21.39 23.55 2.89 2 4 51.94 56.76 0.54 2 5 26. 50 27. 37 1.93 2 6 27. 34 2 9.36 1.81 2 7 28.45 28.46 1.66 2 8 20.79 21.31 2.88 2 9 8.61 8.27 6.76 2 10 17.55 17, 36 3. 42 2 11 2.07* 1.54 0. 12 2 12 5. 84 4.19 6. 08 2 13 5. 12 3.89 5. 19 2 14 19.65 20. 15 2.92 2 15 4. 45 3.66 3. 91 2 17 0. 94* 0. 19 0.04 2 2 0 55. 92 56.26 0. 47 2 2 1 2. 10* 1. 39 0.43 2 2 2 5. 20 4.83 5.95 2 2 3 17. 33 17.46 4.03 2 2 4 23. 23 24.74 2.43 2 2 5 37.80 36.75 1.01 2 2 6 25.15 26.54 2.15 2 2 7 6. 44 5.00 7.90 2 2 8 34. 29 35.03 1. 19 2 2 9 12.99 13.02 5. 26 2 2 10 7.24 6.97 6.25 2 2 11 4. 80 3.64 5.35 2 2 12 9.08 8.67 7.00 H K I FO FC ¥ EIGHT 2 2 13 5.75 5. 74 3. 77 2 2 14 9.56 9.90 5.07 2 2 15 4. 33 4. 90 3.79 2 2 16 2.62* 0. 65 0.37 3 2 0 22.05 23. 11 2.72 3 2 1 46.79 46. 81 0. 66 3 2 2 10.11 9. 57 8.27 3 2 3 17.81 17.25 3.84 3 2 4 7.99 6.75 8. 57 3 2 5 20.02 20. 97 3.06 3 2 6 38.75 39. 45 0. 95 3 2 7 15.87 16.56 4.12 3 2 8 9.07 8. 75 7. 08 3 2 9 4.08 4.06 3. 56 3 2 10 7.87 7. 61 5.82 3 2 11 9.44 9.15 5.00 3 2 12 6.97 6.91 5. 41 3 2 13 4.78 5. 01 3. 24 3 2 14 3.49 2.08 3. 35 3 2 15 2.48* 0. 86 0. 31 4 2 0 2.72* 3. 95 0. 3 1 4 2 1 17.63 17.15 3.83 4 2 2 19.59 20. 74 3. 20 4 2 3 14.51 14.23 5.19 4 2 4 13.70 12. 54 5. 27 4 2 5 15.36 14. 65 4.40 4 2 6 13.55 14. 44 5.54 4 2 7 6.59 6. 67 6.47 4 2 8 3.21* 0.59 0. 38 4 2 9 2.66* 2. 83 0. 12 4 2 10 17.45 18. 82 3.49 4 2 11 4.51 4. 49 3. 39 4 2 12 0.93* 0.37 0.02 4 2 13 2.57* 1. 47 0.22 4 2 14 3.48 2. 81 3. 59 5 2 0 46.49 49.88 0.67 5 2 1 11. 13 10. 63 6. 83 5 2 2 10.00 10. 58 7. 91 5 2 3 6.03 5. 39 8. 72 5 2 4 11.32 11. 10 6.81 5 2 5 6.41 6. 70 4. 83 5 2 6 16.92 16. 85 3. 99 5 2 7 4.68 3. 98 3. 91 5 2 8 0.00* 0. 86 0. 00 5 2 9 4.39 3. 07 4.45 5 2 10 2.12* 1.51 0.11 5 2 11 6.59 6. 93 4. 78 5 2 12 0.00* 0. 46 0. 00 5 2 13 3.00* 0.27 0.43 6 2 0 44. 82 47. 34 0.71 6 2 1 3.47 3. 37 3. 89 6 2 2 14.10 15. 10 4.70 6 2 3 4.89 4. 44 5. 73 6 2 4 11.67 11. 10 6. 03 6 2 5 5. 16 4. 48 4. 61 6 2 6 22.38 23.49 2.44 6 2 7 2. 88* 0. 24 0.27 6 2 8 5.04 3.84 5.21 H K I FO FC WEIGHT 6 2 9 5. 24 4.81 3.36 6 2 10 13.58 13.54 4. 89 6 2 11 3. 40* 3. 16 0. 29 6 2 12 9.37 9.68 7. 30 7 2 0 13. 31 1 4. 30 4.59 7 2 1 2.96* 2.83 0.31 7 2 2 9.94 10. 27 5.34 7 2 3 2. 74* 0.59 0.21 7 2 4 6.46 5.66 6.85 7 2 5 7.79 7.77 5.64 7 2 6 9.09 9.23 5.73 7 2 7 5.91 6.17 4.65 7 2 8 2. 65* 1.33 0. 26 7 2 9 2.55* 1.48 0.20 7 2 10 13.17 13.88 4.71 8 2 0 14.65 16.06 4.50 8 2 1 5. 78 5. 81 4.16 8 2 2 13.95 14.68 4. 18 8 2 3 3. 46* 4. 11 0.19 8 2 a 8.65 8.98 5.70 8 2 5 1.92* 1.21 0.09 8 2 6 4. 68 4. 86 3.69 8 2 7 3.02* 1.60 0.24 8 2 8 10.43 10.90 5.67 8 2 9 8.86 8.16 10. 11 9 2 0 4. 53 4.06 3.51 9 2 1 2. 90* 0.71 0. 27 9 2 2 4. 25 2.63 4.25 9 2 3 6.97 7.36 4.29 9 2 9.6 5 10.41 5. 21 9 2 5 7.59 7.22 6,23 9 2 6 5.95 5. 84 6. 15 9 2 7 1. 49* 0. 90 0.07 10 2 0 11.65 11.54 5. 38 10 2 1 8. 50 7.24 7. 03 10 2 2 15.52 16.66 4.34 10 2 3 7. 87 8. 48 5. 32 10 2 a 3.97 1.86 5.30 10 2 5 3. 60 2.41 4.01 10 2 6 6.65 6.16 9. 51 11 2 0 7. 83 8.13 7. 50 11 2 1 4.93 2.82 6. 20 11 2 2 11. 12 1 1.56 5.40 11 2 3 3.42 1.89 3.78 11 2 4 6. 41 6.04 9.30 12 2 0 10.74 1 1.26 5.75 12 2 1 4. 22 2. 27 7.73 12 2 2 5. 29 4.25 11.55 13 3 3 1.76* 2. 56 0. 10 13 3 4 4. 47 4.36 4. 87 13 3 5 4. 83 5.74 4. 05 13 3 6 6.11 6.95 4.96 13 3 7 2. 94* 0.53 0. 30 13 3 8 2. 17* 0. 25 0.13 13 3 9 10. 81 11,77 4.81 13 3 10 2. 13* 0. 32 0, 13 13 3 11 5. 85 6.02 4.70 13 3 12 3. 03* 3.06 0. 27 H K L FO FC WEIGHT -13 3 13 1.57* 1.58 0. 09 -13 3 14 1 .96* 2. 36 0. 12 -12 3 1 5.65 7. 81 4. 12 -12 3 2 3.81 2. 12 3.96 -12 3 3 1.96* 0. 60 0. 10 -12 3 4 14.16 16. 99 3.75 -12 3 5 5.81 5.71 5.41 -12 3 6 2.02* 2. 24 0. 11 -12 3 7 4.61 5. 10 3.06 - 12 3 8 6.81 7.57 4.79 -12 3 9 9.45 10. 20 4. 91 -12 3 10 2.93* 2. 81 0. 17 -12 3 11 10.21 11. 30 4,58 -12 3 12 1.49* 2. 77 0. 05 -12 3 13 4.08 3. 66 3. 98 -12 3 14 3.04* 1.54 0.31 -12 3 15 5.67 5. 56 7.20 -12 3 16 3.70 4. 62 2.72 -11 3 1 9.62 10. 97 5.09 -11 3 2 10.74 13. 85 4. 88 - 11 3 3 4.41 5.68 2.70 -11 3 4 14.56 17.87 3.82 -11 3 5 8.99 8. 37 7.09 -11 3 6 1.14* 1. 96 0.02 - 11 3 7 9.29 9.63 5.11 -11 3 8 4 .25 2. 82 4.42 -11 3 9 5.50 4. 76 5.91 -11 3 10 9.31 9. 81 4.54 -11 3 11 8.79 9.24 5.19 -11 3 12 13. 28 13.78 4. 41 -11 3 13 4.65 5. 17 3. 15 -11 3 14 2. 95* 0. 79 0.24 -11 3 15 7.62 7. 81 6.03 -11 3 16 11 .52 12. 80 5.28 -11 3 17 3.59 3. 17 3.68 -10 3 1 4.19 4. 16 3.09 -10 3 2 11.00 11. 58 5.00 - 10 3 3 11.18 11.98 4.49 -10 3 4 16. 92 17. 68 3. 29 -10 3 5 16.11 17. 31 3.45 -10 3 6 14.78 14. 66 3. 93 - 10 3 7 3.38* 4. 33 0, 18 -10 3 8 11.64 11. 89 5.44 -10 3 9 6.90 6. 20 5.30 -10 3 10 6.61 6. 18 5. 10 - 10 3 11 14.64 15.67 3.95 -10 3 12 6.08 6. 35 4. 83 - 10 3 13 3.82* 4, 86 0.23 -10 3 14 2.56* 2. 60 0. 16 -10 3 15 4.97 4.73 3,93 -10 3 16 9.49 9. 33 6. 15 - 10 3 17 2.70* 1.91 0. 28 -10 3 18 2.39* 2.78 0. 17 -9 3 1 30.27 29.18 1.44 -9 3 2 21.08 21. 15 2.51 -9 3 3 9.42 8. 97 4.68 -9 3 4 12.56 12. 25 4. 53 -9 3 5 10.50 9. 68 5.35 B K I FO FC WEIGHT 9 3 6 2. 72* 2.50 0. 14 9 3 7 5. 90 5.99 4. 14 9 3 8 5. 30 2.77 4.54 9 3 9 3. 19* 2.55 0. 24 9 3 10 4.65 4.84 3. 72 9 3 11 2. 22* 2.84 0.12 9 3 12 13.00 12. 68 4.66 9 3 13 13. 6 2 13.44 4. 20 9 3 14 5. 86 5.54 6.39 9 3 15 21.72 22.39 2.52 9 3 16 6.72 6. 11 6.21 9 3 17 9.21 9.57 5.10 9 3 18 6. 54 6.31 6. 84 8 3 1 19.35 18. 28 3.05 8 3 2 16.69 14.98 3.70 8 3 3 25. 32 2 5.11 1.92 8 3 4 1. 29* 0. 46 0.04 8 3 5 10.50 8.95 6. 47 8 3 6 12. 80 12.65 4. 84 8 3 7 5.90 5.46 4.75 8 3 8 3.91 3.03 2.70 8 3 9 14.95 14.56 4.12 8 3 10 16.49 16.71 3.37 8 3 11 28.01 28.12 1.67 8 3 12 12. 36 12.39 4.46 8 3 13 13. 15 13.01 5.03 8 3 14 5.41 5.39 4.29 8 3 15 3. 92* 4. 89 ; 0.20 8 3 16 14. 82 14.71 4. 15 8 3 17 8.52 8. 85 7.07 8 3 18 3.18* 0. 96 0. 38 7 3 1 13. 36 12.41 4. 54 7 3 2 9. 88 9.67^ 5.80 7 3 3 1. 64* 1.39 0.07 7 3 4 2.55* 1.57 0.19 7 3 5 27.06 25.69 1.81 7 3 6 4.21 3.90 3.81 7 3 7 23. 68 23. 72 2.18 7 3 8 3.65 1.65 3. 60 7 3 9 9.98 9. 83 6.57 7 3 10 28. 26 29.52 1.61 7 3 11 25. 15 25.79 1.94 7 3 12 17.51 18. 26 3. 22 7 3 13 16. 33 16. 04 3.77 7 3 14 9.72 9.57 5.71 7 3 15 2. 17* 3.55 0. 08 7 3 16 8. 41 8.71 5. 15 7 3 17 1.51* 0.65 0.07 7 3 18 4. 33 3.81 3.29 6 3 1 27. 67 24.73 1.73 6 3 2 33. 34 30. 12 1. 21 6 3 3 7.23 5.24 6.60 6 3 4 6. 11 5. 3 9 6.06 6 3 5 4. 16 4.32 3. 33 6 3 6 30.87 29.39 1.42 6 3 7 23. 39 22.91 2.36 6 3 8 8. 51 7.22 6.29 6 3 9 8.40 8.01 6.40 H K L FO FC WEIGHT -6 3 10 1 .42* 0. 31 0.05 -6 3 11 3.25* 2.24 0. 28 -6 3 12 16.39 17. 35 4, 04 -6 3 13 13.92 13. 34 4.41 -6 3 14 12.34 12. 05 4.72 -6 3 15 19.85 20. 43 2. 86 -6 3 16 6.07 6. 42 4. 97 -6 3 17 8.01 8.36 5.54 -6 3 18 3.79 3. 86 3.02 -5 3 1 32.82 30. 26 1.29 -5 3 2 14. 28 12. 14 4. 55 -5 3 3 3.38 4.51 3,21 -5 3 4 2.32* 1. 27 0.23 -5 3 5 36. 81 34. 01 1. 04 -5 • 3 6 20.68 19.52 2.87 -5 3 7 33.54 32. 72 1.24 -5 3 8 7.16 7. 36 6. 87 -5 3 9 7.34 6. 96 7.41 -5 3 10 17.78 17. 24 3. 50 -5 3 11 22.79 23. 87 2.36 -5 3 12 7.06 7. 35, 5. 55 -5 3 13 11.53 11.62 5.36 -5 3 14 3.93 4. 08 2. 50 -5 3 15 14.48 14. 52 4, 15 -5 3 16 1.61* 0. 79 0. 06 -5 3 17 6.73 5. 87 5.83 -5 3 18 5.36 4.38 7. 90 -4 3 1 56. 10 49. 08 0. 46 -4 3 2 33.78 29. 94 1. 22 -4 3 3 61.11 52. 45 0.39 -4 3 4 11.35 9. 91 6. 07 -4 3 5 2. 45* 1. 46 0. 23 -4 3 6 13.75 11. 91 5.29 -4 3 7 7.74 8. 46 8. 10 -4 3 8 28.69 27. 13 1.67 -4 3 9 15.92 15. 27 4. 36 -4 3 10 10.65 10.31 5.43 -4 3 11 17.71 17. 70 3.43 -4 3 12 1.66* 0. 35 0.07 -4 3 13 13. 87 13. 80 4.34 -4 3 14 3.46* •1. 05 0. 33 -4 3 15 15.12 14. 32 4.29 -4 3 16 1.98* 0.29 0.09 -4 3 17 12.46 12. 33 5. 18 -4 3 18 1.94* 2. 36 0. 11 -3 3 1 6.71 7.37 6.76 -3 3 2 15.55 12. 06 4,49 -3 3 3 27.62 25. 51 1.77 -3 3 4 36.67 32. 81 1.05 -3 3 5 7.54 6.75 6.85 -3 3 6 33.67 32. 49 1. 26 -3 3 7 21 .51 22.01 2.69 -3 3 8 2. 83* 0. 39 0.41 -3 3 9 9.93 9. 60 6, 16 -3 3 10 6.97 6.62 5.92 -3 3 11 9.49 9. 58 7.46 -3 3 12 7.12 7.15 5.69 -3 3 13 12.65 12. 41 4. 65 H K I FO FC WEIGHT - 3 3 14 5.49 6.20 3. 21 -3 3 15 3. 90 1.91 3.72 -3 3 16 7.66 7.64 7.41 -3 3 17 7.87 7. 93 5. 88 -3 3 18 3.01* 1. 95 0. 37 -2 3 1 4.19 2.80 5.36 -2 3 2 36. 41 31.08 1.08 -2 3 3 2.03* 4. 36 0. 20 -2 3 4 23.64 22. 22 2.43 -2 3 5 24.41 24. 84 2.25 -2 3 6 7. 19 6.17 8.56 -2 3 7 50.06 50.66 0. 58 -2 3 8 4.64 2.81 6. 97 -2 3 9 13.04 13. 32 5.18 -2 3 10 6.36 6.46 5. 38 -2 3 11 17.75 18. 15 3.41 -2 3 12 11.79 11.75 4.95 -2 3 13 6.69 6.60 4.98 -2 3 14 18.91 19.87 3. 13 -2 3 15 3.67 1.44 3. 23 -2 3 16 3.68 2.14 3.76 -2 3 17 3. 47* 3.98 0.29 -2 3 18 3.09 1.87 4. 18 -1 3 1 55. 07 42.79 0. 48 -1 3 2 13. 12 12. 18 5.69 -1 3 3 35.06 34. 80 1. 16 -1 3 4 5.74 6.15 8.69 -1 3 5 3.77 3. 17 4.98 -1 3 6 40. 20 39.82 0.89 -1 3 7 17. 40 18.49 3.99 -1 3 8 43. 45 45. 04 0.77 -1 3 9 5. 27 3. 18 8.06 -1 3 10 10. 11 9.62 6.65 -1 3 11 14.67 15.20 4. 15 -1 3 12 1. 46* 0.39 0. 06 -1 3 13 8.34 7.41 6.92 -1 3 14 11. 17 12. 04 5.02 -1 3 15 12. 16 13. 15 5. 10 -1 3 16 4. 7 3 3.66 6.69 -1 3 17 9. 95 9.40 8.06 0 3 1 30. 88 33.59 1.46 0 3 2 65. 06 68.90 0.35 0 3 3 18.42 .19.70 3.62 0 3 4 14. 17 13.90 5.64 0 3 5 2. 88 2.35 4.66 0 3 6 13. 13 13. 94 5.42 0 3 7 27. 35 28. 85 1. 82 0 3 8 12.38 13.47 5.87 0 3 9 11.42 12.05 6. 34 0 3 10 4.84 6.54 3.62 0 3 11 8.53 9.08 6.09 0 3 12 14. 04 15.21 4.71 0 3 13 13.92 14.76 4. 41 0 3 14 16.01 16.99 3.96 0 3 15 3. 86 2. 91 3.38 0 3 16 2.65* 1.38 0.27 1 3 0 19. 89 20. 18 3. 18 1 3 1 13.92 15. 06 5.63 H K L FO FC WEIGHT 3 2 12.27 13. 03 6,73 3 3 30.55 33. 99 1.51 3 4 12.03 13.40 6.31 3 5 3.25 2. 11 3. 90 3 6 12.26 11.99 6.38 3 7 17.87 19.52 3.59 3 8 13.88 14. 00 1,81 3 9 6.67 7. 28 6.24 3 10 7.63 7. 93 5.98 3 11 12.86 13, 84 4. 68 3 12 2.74* 2.39 0.16 3 13 10.30 10.45 6.76 3 14 5. 43 5. 09 4. 97 3 15 2.87* 2.22 0.28 3 16 2.39* 1.75 0. 23 2 3 0 13. 85 15. 54 5. 41 2 3 1 14.30 13. 91 5. 39 2 3 2 16.60 -17. 86 4. 14 2 3 3 31.62 33. 45 1.41 2 3 4 7.45 7. 80 9. 14 2 3 5 6.35 6. 78 7. 86 2 3 6 3.72 3. 42 3.86 2 3 7 24.07 24. 81 2.29 2 3 8 13.86 13. 76 5. 13 2 3 9 10.31 11.93 4. 85 2 3 10 13.12 14. 36 4.64 2 3 11 6.27 4. 61 6.31 2 3 12 5.35 3. 46 5.72 2 3 13 4,52 3.10 5.36 2 3 14 4. 76 5, 10 3.99 2 3 15 3.06* 2. 52 0.32 3 3 0 12.79 12. 16 6. 14 3 3 1 16.03 16. 43 4. 33 3 3 2 8.48 9.20 7.21 3 3 3 27.40 28. 84 1.80 3 3 4 16.99 18. 62 3. 85 3 3 5 16.28 16. 35 4.17 3 3 6 8.96 8. 64 7. 33 3 3 7 6.85 7. 06 6. 43 3 3 8 5.47 6. 37 4. 80 3 3 9 2.30* 2. 05 0. 13 3 3 10 6.28 6. 04 6.35 3 3 11 8.68 9.44 5.89 3 3 12 3.09* 0. 33 0. 34 3 3 13 7.21 7. 11 7.03 3 3 14 5.19 4.55 7.30 4 ' 3 0 11.72 12. 07 6. 17 4 3 1 2.40* 1. 11 0.31 4 3 2 4.62 3. 67 7.74 4 3 3 15.40 16.57 4.39 4 3 4 1. 56* 0. 74 0.08 4 3 5 6.06 6. 51 5.34 4 3 6 14.55 14. 96 4. 81 4 3 7 11.87 13.03 5.06 4 3 8 4.85 3. 98 3. 77 4 3 9 11.68 11.63 5.40 4 3 10 15.17 16.45 4.13 4 3 11 11.72 11. 28 5. 81 H K I FO FC WEIGHT H K L 4 3 12 4.31 3.94 3.40 10 3 5 4 3 13 9. 44 9.79 6.67 11 3 0 5 3 0 17.73 19.21 3.75 11 3 1 5 3 1 7. 03 8.74 5.76 11 3 2 5 3 2 11. 39 10.89 6.25 11 3 3 5 3 3 14.69 15.53 4.73 12 3 0 5 3 H 2.42* 2.31 0.19 -13 4 8 5 3 5 6.54 6.20 4. 80 -13 4 9 5 3 6 9.31 9.98 4.63 -12 4 2 5 3 7 13.25 14. 45 4.57 -12 4 3 5 3 8 6.09 5.64 6.19 -12 4 4 5 3 9 17.31 18. 21 3.59 -12 4 5 5 3 10 6.75 6. 36 7. 59 -12 4 6 5 3 11 2. 35* 1.38 0. 19 -12 4 7 5 3 12 3. 98 3. 52 5.53 -12 4 8 6 3 0 0.98* 1.72 0.03 -12 4 9 6 3 1 12.92 12.85 5.74 -12 4 10 6 3 2 6. 45 5.76 6.44 -12 4 11 6 3 3 16. 26 17. 55 3. 98 -12 4 12 6 3 4 20.31 21.88 2. 92 -12 4 13 6 3 5 3. 92* 4.93 0.24 -12 4 14 6 3 6 8.82 9.44 4. 95 - 11 4 1 6 3 7 2.97* 0.73 0.28 -11 4 2 6 3 8 5.25 5. 34 4.34 -11 4 3 6 3 9 4.08 4.15 3.58 - 11 4 4 6 3 10 1.61* 0.33 0.07 -11 4 5 6 3 11 1.41* 0.21 0. 08 -11 4 6 7 3 0 2.43* 0.76 0. 19 -11 4 7 7 3 1 10.42 11.03 5.54 -11 4 8 7 3 2 8.32 8.87 5.23 - 11 4 9 7 3 3 26. 62 28.57 1 .80 -11 4 10 7 3 4 12.59 13. 27 5.15 - 11 4 11 7 3 5 6. 17 7.09 3. 83 -11 4 12 7 3 6 6.50 6.73 6.71 -11 4 13 7 3 7 7. 82 9.32 5. 20 -11 4 14 7 3 8 4.18 3.19 5.47 -11 4 15 7 3 9 4.94 4.34 6.08 -10 4 1 8 3 0 9.56 10.20 5. 16 -10 4 2 8 3 1 0. 68* 2.74 0.01 -10 4 3 8 3 2 13.42 14.09 4. 85 -10 4 4 8 3 3 7. 60 7.98 5. 40 -10 4 5 8 3 4 8. 33 8. 59 6.96 -10 4 6 8 3 5 8. 94 9.78 5. 21 -10 4 7 8' 3 6 2. 68* 1.69 0.29 -10 4 8 8 3 7 3.88 4.63 3.03 -10 4 9 8 3 8 3. 19 2.24 3.86 - 10 4 10 9 3 0 15. 14 16. 10 3.56 -10 4 11 9 3 1 13. 15 13.63 4. 94 -10 4 12 9 3 2 6.22 5.14 6. 30 -10 4 13 9 3 3 4. 15 3.91 3.12 -10 4 14 9 3 4 4. 90 5.28 4.37 -10 4 15 9 3 5 4. 68 3.77 6.65 -10 4 16 9 3 6 4. 90 4.53 6.32 -9 4 1 10 3 0 4. 16 3. 37 4.28 -9 4 2 10 3 1 6. 83 7.11 5. 62 -9 4 3 10 3 2 3. 54 1.31 4.05 -9 4 4 10 3 3 9. 89 10. 11 6.18 -9 4 5 10 3 4 1. 55* 1. 97 0.08 -9 4 6 FO FC WEIGHT 2.94* 2.29 0.44 12. 34 12. 80 4.59 5.16 5.64 4.56 3.39 2. 34 3. 91 4.11 3.90 6.70 2.63* 0.20 0.33 3.59 4.09 3.41 2.58* 1.12 0.27 11.97 13.18 5.29 2.89* 2. 45 0. 28 7.92 8.35 7.16 5.95 6.59 5.77 4.79 4.68 '4.31 2.79* 2.05 0.20 6.19 6. 16 6.79 2. 15* 0. 87 0. 12 5. 23 5. 28 6. 05 3.15* 2.61 0.35 9.42 10. 16 5.73 7.37 7. 08 7.55 2.88* 2.38 0.32 1.00* 0.33 0.03 1.78* 0.51 0.08 9.44 9. 43 6. 83 15.85 16.41 3.96 6.13 6.70 4.43 2.44* 2. 02 0. 12 7.95 8. 41 4. 53 4.84 4. 73 4. 14 6.58 5.78 5.74 5.34 4. 91 6.59 1.50* 1.34 0.05 3. 66* 2. 85 0. 28 3.75 1. 74 5.31 9.13 9.79 6.15 3.89 3. 44 4.04 3.38* 2.52 0.21 6. 53 6. 34 5. 39 14.38 14. 10 4. 07 3.99 0. 81 3.99 7.42 7. 85 5.47 3.09* 0. 96 0.20 5.74 6. 14 3.51 10.43 9. 94 5. 03 0.00* 2. 55 0.00 2.70* 2.67 0.16 6.09 5. 02 6.53 6. 24 6. 40 4. 29 2.75* 0.72 0.20 3.97 3. 52 2.81 7.91 8. 05 5. 65 7.09 6.57 6.19 3. 32* 3. 20 0. 17 18.44 17.26 3. 10 2.42* 0.55 0.12 3.84 2. 17 2.47 2.08* 2.44 0.07 5.19 3.70 3.78 H K L FO FC WEIGHT -9 4 7 17.78 17.47 3. 21 -9 4 8 23.99 23.82 2.06 -9 4 9 6. 94 6.43 5.00 -9 4 10 11. 48 11.62 4. 80 -9 4 11 3.70 1.16 3.41 -9 4 12 14. 52 15.27 3.99 -9 4 13 6. 04 6.40 3.96 -9 4 14 2. 66* 2.33 0.14 -9 4 15 6.67 6.02 8. 25 -9 4 16 11.80 11.70 5.55 -9 4 17 1.73* 0.77 0.11 -8 4 1 9.72 8. 24 5. 58 -8 4 2 20. 39 19.65 2. 64 -8 4 3 4.76 2.63 2.71 -8 4 4 26. 03 25.35 1.77 -8 4 5 3. 53* 2.26 0. 19 -8 4 6 6.45 5.08 4. 92 -8 4 7 4. 39 4.01 3. 16 -8 4 8 7.89 7.00 6.77 -8 4 9 4. 90 4.25 3. 54 -8 4 10 15.51 15. 17 4.18 -8 4 11 11. 16 11.01 4. 80 -8 4 12 15. 03 15.85 3.81 -8 4 13 3.60 0.40 3. 36 -8 4 14 10.75 10.45 5.84 -8 4 15 0. 00* 0. 92 0.00 -8 4 16 8.64 8.05 6. 20 -8 4 17 4.78 4.23 4. 86 -7 4 1 7.56 6.37 5.55 -7 4 2 6.73 6.91 4.39 -7 4 3 8. 13 7.71 5. 22 -7 4 4 24. 73 22.66 2. 11 -7 4 5 9. 66 9.36 4.70 -7 4 6 3.62* 2.45 0. 22 -7 4 7 15. 17 15.80 4. 19 -7 4 8 11.11 11.75 5. 14 -7 4 9 3.02* 1.41 0.20 -7 4 10 11.28 11.44 4. 81 -7 4 11 5. 71 5.38 3.30 -7 4 12 3.38* 2. 25 0.32 -7 4 13 3.95 2. 36 3. 69 -7 4 14 11.88 12.34 4. 87 -7 4 15 0. 26* 0.78 0.-00 -7 4 16 7.47 6. 68 6. 78 -7 4 17 0. 00* 1.26 0.00 -7 4 18 6. 85 6.64 8. 17 -6 4 1 1. 96* 0.28 0.07 -6 4 2 11.62 10.32 5.33 -6 4 3 2. 66* 2.61 0. 12 -6 4 4 25.5 5 24.87 1.96 -6 4 5 0. 00* 0.82 0.00 -6 4 6 5. 33 3.11 5. 00 -6 4 7 15. 69 14.19 3.89 -6 4 8 11. 58 11.82 4.69 -6 4 9 14.20 13.80 3.62 -6 4 10 4.23 3.44 3.06 -6 4 11 17. 02 17.81 3. 56 -6 4 12 12.46 12.24 4. 57 H K L FO FC WEIGHT -6 4 13 3.81 3. 07 3. 44 -6 4 14 11.91 12. 42 4. 80 -6 4 15 1. 78* 0. 30 0. 08 -6 4 16 3.56 2. 67 4. 25 -6 4 17 2.16* 1.46 0. 13 -6 4 18 3.48 3. 06 3. 81 -5 4 1 7.20 5.61 5.76 -5 4 2 2.86* 1.54 0.21 -5 4 3 3.46 0.72 3.38 -5 4 4 13.75 12. 91 4. 98 -5 4 5 17.31 16. 99 3.52 -5 4 6 4.23 4.53 2.66 -5 4 7 8.30 8. 24 5. 73 -5 4 8 30.23 28.53 1.46 -5 4 9 17.01 16. 80 3. 51 -5 4 10 2.49* 2. 40 0.11 -5 4 11 18.94 18.71 3.26 -5 4 12 4. 16 2. 94 2.70 -5 4 13 4.04 3.70 2.57 -5 4 14 13.32 13. 23 4. 47 -5 4 15 5.58 5.70 4.57 -5 4 16 4.92 3. 94 4. 60 -5 4 17 3.72 2.69 4.02 -4 4 1 24. 81 21.69 2. 12 -4 4 2 7.56 6.73 5.97 -4 4 3 7.32 6. 75 5. 23 -4 4 4 21.20 18. 03 2. 59 -4 4 5 5.75 4.95 5.54 -4 4 6 30.63 28. 62 1.45 -4 4 7 8.82 7. 84 5. 41 -4 4 8 29.41 29. 19 1.52 -4 4 9 29.05 29.70 1.53 -4 '4 10 33.54 34. 18 1.20 -4 4 11 4.64 3.92 3.36 -4 4 12 16.13 15. 86 3.73 -4 4 13 5.01 3. 54 4. 83 -4 4 14 15.80 15. 53 4. 14 -4 4 15 8.29 7. 68 7.38 -4 4 16 4.42 3. 13 5. 80 -4 4 17 0.19* 0.59 0.00 -3 4 1 24.35 20.06 •2. 16 -3 4 2 10.06 7. 20 7. 15 -3 4 3 27.32 24. 05 1.78 -3 4 4 27.34 24.68 1.77 -3 4 5 6.77 7. 28 5. 13 -3 4 6 25.97 24. 96 1.97 -3 4 7 12.03 12.03 6.06 -3 4 8 11.12 11. 29 6.19 -3 4 9 14.43 14. 92 4. 21 -3 4 10 4.44 4. 26 2. 72 -3 4 11 15.74 16. 11 3.67 -3 4 12 15.39 15.58 4. 20 -3 4 13 7.59 8. 06 5.49 -3 4 14 10.18 10. 25 5.77 -3 4 15 4.04 3. 53 3. 24 -3 4 16 0.00* 0.79 0.00 -3 4 17 3. 26 0. 61 4.02 -2 4 1 14.47 11.91 4.50 H K I FO FC HEIGHT -2 4 2 32. 64 27.05 1. 28 -2 4 3 3.32* 2.95 0.28 - -2 4 4 23. 20 22.98 2.38 -2 4 5 11.06 11.08 6. 51 -2 4 6 3.76 2. 86 4. 40 -2 4 7 4.36 4.12 4.75 -2 4 8 7.11 7.4 9 6.51 -2 4 9 13. 80 13.32 5.33 -2 4 10 7. 16 6.66 6.93 -2 4 11 3. 26* 3.35 0.16 -2 4 12 5. 84 5.36 5.72 -2 4 13 3. 25* 2. 08 0.31 -2 4 14 9.45 9.71 5.19 -2 4 15 2. 11* 1.27 0. 13 -2 4 16 2. 84* 1.39 0.29 -1 4 1 22. 48 18.42 2. 41 -1 4 3 25.01 23.92 2. 11 -1 4 4 21.54 22. 25 2.79 -1 4 5 6.77 7.73 6.16 -1 4 6 13. 37 13.48 4.73 -1 4 7 2.73* 0.11 0. 26 -1 4 8 24.93 25. 31 2.08 -1 4 9 7. 20 7.10 4.93 -1 4 10 15. 57 16.20 4.24 -1 4 11 8.05 8.59 5. 53 -1 4 12 8.62 8. 35 6.80 -1 4 13 2.84* 1.61 0.26 -1 4 14 15.05 15.07 4. 33 -1 4 15 3. 17 1.04 4.04 -1 4 16 3. 3 2* 3.44 0.35 0 4 0 60. 56 48.96 0.39 0 4 1 25. 28 25.30 2.07 0 4 2 17.83 17.49 3.86 0 4 3 9. 46 10.05 7.65 0 4 4 4. 02 2.80 4.53 0 4 5 3. 13* 1.70 0.40 0 4 6 28. 47 28.78 1.64 0 4 7 3.00* 2.64 0. 28 0 4 8 14.41 15.57 4.24 0 4 9 2. 40* 3. 18 0. 14 0 4 10 2. 95* 1.77 0.19 0 4 11 8. 50 8. 30 6.77 0 4 12 6.00 6.03 6. 10 0 4 13 9.77 9.28 7. 11 0 4 14 5. 80 6.08 4.59 0 4 15 3. 83 4.01 3. 46 1 4 0 24. 18 24.70 2. 17 1 4 1 5. 15 5. 13 5.13 1 4 2 19.50 20.50 3.19 1 4 3 11.00 11.10 6.27 1 4 4 5.70 5.19 6.09 1 4 5 4. 58 5.33 3.54 1 4 6 18.69 19.78 3.41 1 4 7 2.10* 2.22 0. 13 1 4 8 0. 00* 1.07 0.00 1 4 9 2. 33* 1.64 0.13 1 4 10 23.81 24.74 2.20 1 4 11 11. 46 12.02 5. 42 H K L FO FC HEIGHT 1 4 12 3.38* 3.20 0. 25 1 4 13 6. 19 6. 57 5.74 1 4 14 5.84 6. 05 6. 84 1 4 15 2.80* 0. 37 0.41 2 4 0 30.18 29. 01 1. 53 2 4 1 2.48* 1. 04 0.26 2 4 2 20.05 20. 43 3.01 2 4 3 7.98 7.71 7. 12 2 4 4 12.32 12. 48 5.68 2 4 5 3.31* 3. 71 0.26 2 4 6 3.43 1. 96 4.03 2 4 7 8.81 9. 29 6. 15 2 4 8 13.07 14. 49 4.63 2 4 9 4.29 3.67 4.25 2 4 10 25.49 26. 97 1.94 2 4 11 2.79* 0.46 0.26 2 4 12 1.56* 1. 31 0.07 2 4 13 4.93 4. 11 5.52 2 4 14 8.20 7.73 9.24 3 4 0 32.07 31. 47 1.35 3 4 1 5.66 4.65 9.50 3 4 2 30.91 31.32 1.44 3 4 3 7.85 7. 85 6.38 3 4 4 29.91 31. 37 1.49 3 4 5 21.10 22. 59 2.72 3 4 6 5.21 5.15 4.44 3 4 7 3. 21* 1. 32 0. 33 3 4 8 3.66 2. 26 3. 39 3 4 9 7.41 7.61 6.78 3 4 10 7.41 6. 47 7. 11 3 4 11 4.31 4. 37 3.71 3 4 12 2.70* 2.81 0. 19 3 4 13 8.07 8. 31 7. 86 4 4 0 1.57* 1. 86 0. 08 4 4 1 11.40 11. 81 5.94 4 4 2 10.09 9.99 6.07 4 4 3 4.28 4.01 4.05 4 4 4 29.66 30. 17 1. 55 4 4 5 6.39 6.74 4. 28 4 4 6 19.01 20. 11 3. 14 4 4 7 1.13* 1. 02 0.03 4 4 8 8.29 8. 49 5.66 4 4 9 2.78* 0. 14 0. 26 4 4 10 4.70 3.57 5.72 4 4 11 3.87 3. 19 3.92 4 4 12 7. 33 6. 95 9.02 5 4 0 22.37 22. 04 2.65 5 4 1 15. 39 15. 64 4.05 5 4 2 29.97 31.46 1.48 5 4 3 13. 19 13. 47 4.69 5 4 4 3.98 3. 23 2.82 5 4 5 6.55 6. 20 6.35 5 4 6 15.60 15.83 4.45 5 4 7 2.24* 0. 60 0.11 5 4 8 1.21* 2. 40 0.03 5 4 9 6.39 6. 03 5. 89 5 4 10 9.19 9. 97 5, 83 5 4 11 1.84* 0.92 0.13 H K I FO FC WEIGHT 6 4 0 8. 11 7. 87 7.46 6 4 1 17.08 17.94 3. 48 6 4 2 16. 11 17.15 3.64 6 4 3 17. 00 17. 92 3. 58 6 4 4 2. 13* 3.22 0.07 6 4 5 9.75 9.71 5. 65 6 4 6 3.02* 3.00 0.20 6 4 7 4.73 3.65 5. 42 6 4 8 2.93* 0.93 0.37 6 4 9 0.00* 0.61 0.00 6 4 10 6. 29 6. 30 7.95 7 4 0 6. 16 5.6 8 4. 77 7 4 1 8. 39 8.41 6.80 7 4 2 3.41* 2.4 2 0. 33 7 4 3 9.45 9.07 5.65 7 4 4 6. 80 6.73 5.14 7 4 5 6.32 6. 27 5. 28 7 4 6 5.56 5.29 6.81 7 4 7 1.76* 0.72 0. 11 7 4 8 2.32* 0.29 0.24 8 4 0 16. 96 17. 54 3 * 5 8 8 4 1 8.57 8.16 5.62 8 4 2 11. 05 11.14 4.96 8 4 3 2.61* 1.92 0.16 8 4 4 1. 99* 1.19 0.11 8 4 5 1.92* 0.59 0.12 8 4 6 12.20 13.32 5.56 8 4 7 3.91 3. 15 • 4.66 9 4 0 6. 11 5. 33 6. 40 9 4 1 2. 22* 1.70 0.12 9 4 2 7.67 8.14 5. 30 9 4 3 2.46* 1.4 3 0. 19 9 4 4 0.00* 0.14 0. 00 9 4 5 3.64 3.74 3.85 10 4 0 3.08* 1.91 0. 26 10 4 1 4. 62 3.99 4. 82 10 4 2 7. 18 7.0 8 7.97 10 4 3 4.65 3.76 9.49 11 4 0 6.24 6.08 8. 15 11 4 1 4. 38 4.27 5.53 11 5 3 3.36 2.30 3. 62 11 5 4 2. 24* 1.06 0. 18 11 5 5 8.39 8. 92 5. 81 11 5 6 7. 84 8.39 6.25 11 5 7 7.67 7.11 8.27 11 5 8 1. 9 9* 0. 28 0. 13 11 5 9 7.68 7.83 6.23 11 5 10 5.19 5.3 9 4.70 11 5 11 2.66* 2.57 0. 25 11 5 12 3.02* 2.42 0. 35 10 5 1 6. 22 6. 49 5 • 35 10 5 2 0. 00* 1.01 0.00 10 5 3 0. 84* 2.71 0. 02 10 5 4 2. 46* 2. 17 0.11 10 5 5 2. 33* 2.65 0. 10 10 5 6 5. 80 5.22 5.71 10 5 7 6.31 6.21 6.11 10 5 8 4.73 4. 08 3. 59 H K L FO FC WEIGHT -10 5 9 2. 88* 1. 51 0.25 -10 5 10 2.76* 0. 64 0. 25 -10 5 11 1.19* 1.39 0.04 -10 5 12 4.38 4. 18 5.33 -10 5 13 0.00* 1.28 0.00 -10 5 14 3 . 76 2. 04 5.79 -9 5 1 9.88 10.02 5. 16 -9 5 2 4.54 4.07 3.02 -9 5 3 3.77 2. 13 2. 83 -9 5 4 4.62 4.70 2.86 -9 5 5 7.74 7.65 4.89 -9 5 6 3.09* 0. 39 0. 22 -9 5 7 0.00* 2. 68 0. 00 -9 5 8 9.30 8. 70 7. 23 -9 5 9 5.02 6. 00 2.69 -9 5 10 9.55 8. 78 7.47 -9 5 11 13.59 14. 54 4. 27 -9 5 12 3.43* 3.15 0.25 -9 5 13 2.72* 1. 83 0. 1 9 -9 5 14 0.84* 0.73 0.02 -9 5 15 3.23* 3. 67 0.31 -8 5 1 8.21 8. 59 3.71 -8 5 2 3.64* 2. 56 0. 20 -8 5 3 7.13 6. 54 4.32 -8 5 4 8. 36 7. 43 5.62 -8 5 5 9.80 9. 72 4. 94 -8 5 6 12.83 12. 45 4.60 -8 5 7 7.82 8. 02 4.59 -8 5 8 1 3.85 14. 31 4. 09 -8 5 9 4.41 3.53 2.49 -8 5 10 5.48 4. 33 5. 96 -8 5 11 1.52* 3. 28 0. 04 -8 5 12 4.67 2. 92 5. 71 -8 5 13 5.79 5.74 5. 82 -8 5 14 1 .79* 1. 34 0.09 -8 5 15 8.25 8. 51 7.55 -7 5 1 5.63 5.75 2.71 -7 5 2 19.14 19. 23 2.73 -7 5 3 11.57 11. 41 4. 01 -7 5 5 3.09* 1. 33 0.20 -7 5 6 3.77* 4. 45 0. 21 -7 5 7 18. 15 16. 62 3. 11 -7 5 8 2.38* 2.29 0.09 -7 5 9 9.46 9. 01 4. 78 -7 5 10 7.89 7. 45 5. 42 -7 5 11 10.51 10. 94 4. 45 -7 5 12 2.86* 2. 59 0. 14 * -7 5 13 5.48 5.02 4.92 -7 5 14 3.19* 3. 04 0. 22 -7 5 15 4.98 4. 37 6. 11 -7 5 16 7.54 7.36 7.08 -6 5 1 23. 20 20. 42 2. 14 -6 5 2 4.61 3. 03 2. 46 -6 5 3 8.72 8. 85 5.51 -6 5 4 3.56* 2. 63 0. 15 -6 5 5 16.88 16. 06 3.38 -6 5 6 2.31* 2. 95 0.07 -6 5 7 25.69 24. 55 1.94 H K I FO FC WEIGHT 6 5 8 9.9 8 1 0 . 3 8 4.74 6 5 9 3. 1 0 * 0.71 0. 18 6 5 10 1 . 9 7 * 1.26 0. 08 6 5 11 17. 52 1 7 . 18 3. 83 6 5 12 4 . 9 5 3 . 9 3 5. 23 6 5 13 5.77 5.63 4.94 6 5 14 2. 2 6 * 2.34 0.11 6 5 15 3 . 6 3 2.84 3. 78 6 5 16 4.06 3.21 4.55 5 5 1 2 9 . 6 6 2 5 . 4 5 1.50 5 5 2 6.94 7.06 3.59 5 5 3 1 1 . 4 6 1 0 . 4 4 4 . 4 1 5 5 4 4.07 2.98 2. 19 5 5 5 1 1 . 0 9 1 0 . 7 4 4. 90 5 5 6 18. 15 1 7 . 1 8 3. 16 5 5 7 5. 51 4.91 4. 06 5 5 8 9.40 1 0 . 2 9 4.76 5 5 9 4.35 • 3.60 2. 85 5 5 10 10. 04 9.62 5. 45 5 5 11 17, 34 1 8 . 5 5 3 . 3 0 5 5 12 4 . 3 5 2 . 3 5 4. 3 5 5 5 13 2 . 9 5 * 2 . 7 1 0.20 5 5 14 2 . 3 1 * 0.52 0. 16 5 5 15 1 3 . 12 1 2 . 80 5.11 5 5 16 3. 8 5 3.53 4 . 1 9 4 5 1 3 . 0 0 * 1.84 0.10 4 5 •2 2 4 . 6 9 2 2 . 7 2 2.04 4 5 3 1 6 . 4 7 1 5 . 6 7 3.52 4 5 4 1 1 . 6 9 9.88 5.51 4 5 5 1 5 . 13 1 3 . 6 1 3.87 4 5 6 8.99 8. 8 3 4.36 4 t; 7 3. 81 1. 26 2. 52 4 5 8 1 1 . 66 1 2 . 29 5.24 4 5 9 3.97 3 . 9 5 2 . 5 3 4 5 10 1 3 . 8 6 1 3 . 7 2 4. 61 4 5 11 3 . 2 9 * 1.03 0. 30 4 5 12 6. 0 6 6.54 3 . 7 0 4 5 13 6.3 3 6.69 5.28 4 5 14 5. 34 4.31 6.95 4 5 15 3. 4 5 2.60 3.56 4 5 16 4 . 9 5 4 . 9 5 5 . 0 9 3 5 1 1 5 . 6 2 1 2 . 7 8 3. 60 3 5 2 1 1 . 9 4 1 0 . 0 5 4.71 3 5 3 2 1 . 8 9 2 0 . 0 0 2.48 3 5 4 1 0 . 7 7 9. 81 4.76 3 5 5 4.57 2.84 5.07 3 5 6 7.68 7 . 0 0 5.69 3 5 7 1 6 . 3 0 1 5 . 8 6 3 . 7 5 3 5 8 1 2 . 3 9 1 1 . 3 1 5 . 6 3 3 5 9 3 . 7 3 * 3. 7 2 0. 26 3 5 10 1 0 . 9 1 1 0 . 9 3 5 . 3 3 3 5 11 5. 66 5.28 4.12 3 5 12 7.95 7. 90 5.64 3 5 13 2. 0 2 * 0.59 0. 11 3 5 14 0. 0 0 * 0.71 0. 00 3 5 15 3 . 6 1 1.92 5. 91 2 5 1 1 4 . 4 4 1 2 . 9 6 3.61 2 5 2 1 3 . 2 3 1 1 . 7 2 4.00 H K L FO F C WEIGHT -2 5 3 5.02 4. 18 3. 8 3 -2 5 4 1 1 . 8 2 1 1 . 48 4. 84 -2 5 5 0 . 0 0 * 0. 52 0. 00 -2 5 6 3 . 2 9 * 2. 60 0. 25 -2 5 7 1 0 . 7 5 1 2 . 03 5.08 -2 5 8 1-1.11 1 0 . 57 4.93 -2 5 9 8.15 8. 19 6.75 -2 5 10 3 . 0 7 * 0.97 0.28 -2 5 11 2 7 . 2 4 2 7 . 9 2 1.79 -2 5 12 1 4 . 7 9 1 5 . 5 0 4.60 -2 5 13 8.87 8. 57 7.92 -2 5 14 2 . 4 1 * 1. 24 0.21 -2 5 15 0. 0 0 * 0.45 0.01 -1 5 1 4. 7 1 2. 06 3.07 -1 5 2 1 1 . 2 3 1 1 . 54 4.75 -1 5 3 2 6 . 4 6 2 6 . 65 1. 83 -1 5 4 3 . 2 8 * 2. 09 0.29 -1 5 5 3 . 4 8 0.50 3.81 -1 5 6 1 2 . 3 9 12. 65 5. 88 -1 5 7 1 6 . 8 6 1 8 . 21 3.65 -1 5 8 3 . 9 2 * 4. 61 0. 23 -1 5 9 3 2 . 4 3 3 4 . 48 1. 28 -1 5 10 1 . 9 4 * 1. 75 0. 08 -1 5 11 3 . 3 2 * 2. 24 0.34 -1 5 1.2 4.26 3. 34 3.49 -1 5 13 9.90 9.70 6.07 - 1 5 14 2 . 2 8 * 0. 92 0. 22 0 5 1 2 . 6 5 * 2 . 8 9 0. 13 0 5 2 8.00 6. 90 6.76 0 5 3 2 1 . 9 2 2 4 . 14 2. 58 0 5 4 1 . 7 1 * 0. 81 0.09 0 5 5 1 3 . 8 6 1 4 . 7 6 4.26 0 5 6 2 1 . 9 6 2 4 . 24 2. 44 0 5 7 1 2 . 8 2 1 3 . 38 4.63 0 5 8 ' 1 5 . 3 0 1 5 . 97 3.98 0 5 9 2 . 7 3 * 1.78 0. 16 0 5 10 9.52 9.27 5.78 0 5 11 6.59 5. 27 7.00 0 5 12 3 . 2 5 1.64 3.71 0 5 13 4. 17 4. 93 2. 92 0 5 14 3.84 3. 35 4.38 1 5 0 5.44 6. 14 3. 72 1 5 1 2 0 . 1 5 2 1 . 16 2.86 1 5 2 1 0 . 4 3 1 0 . 65 5. 68 1 5 3 4.51 4.73 4. 06 1 5 4 2 2 . 8 5 2 5 . 53 2. 34 1 5 5 1 1 . 1 4 1 1 . 5 1 6.43 1 5 6 6. 9 3 6. 62 5. 32 1 5 7 1 3 . 5 1 1 4 . 6 8 5.25 1 5 8 2 . 0 7 * 2. 07 0.09 1 5 9 8.27 8. 10 6.94 1 5 10 4 . 3 3 4. 82 3.30 1 5 11 8.94 9. 44 6. 57 1 5 12 4.01 3.40 4.12 1 5 13 6.33 5. 86 1 0 . 7 4 2 5 0 1 0 . 0 5 1 0 . 7 3 5. 18 2 5 1 2 8 . 2 1 2 8 . 32 1. 70 2 5 2 1 0 . 1 1 1 0 . 3 8 5.51 H K I FO FC WEIGHT 2 5 3 40.76 43. 27 0. 86 2 5 4 1.65* 2.15 0.05 2 5 5 12.73 13.55 4.69 2 5 6 3. 91 2.42 3.72 2 5 7 12.69 13.90 5.05 2 5 8 5.01 4.10 5. 13 2 5 9 8.02 8.62 5.87 2 5 10 4.48 4.65 3. 86 2 5 11 6. 20 6.01 8.44 2 5 12 3.01* 2.31 0.37 3 5 0 4. 51 3.48 3.97 3 5 1 20. 91 21.07 2. 89 3 5 2 15.42 16.25 4. 10 3 5 3 3.52* 2. 88 0.27 3 5 4 6. 00 5.67 6.15 3 5 5 3.18* 2.92 0.30 3 5 6 13.94 14. 48 5. 08 3 5 7 7.43 7.67 5.42 3 5 8 2.63* 4.03 0.16 3 5 9 0.00* 1.52 0.00 3 5 10 8.57 8.91 6. 98 3 5 11 2. 25* 1.41 0.21 4 5 0 5.34 4.73 4.23 4 5 1 3.33* 3.98 0. 23 4 5 2 6.12 5.46 5.99 4 5 3 3. 53 1.64 3.02 4 5 4 16. 92 17.16 3.74 4 5 5 7.96 7.55 6.51 4 5 6 1. 83* 0. 21 0.07 4 5 7 7.84 8.11 7.02 4 5 8 3. 81 3. 20 4. 17 4 5 9 4.56 3.09 6.29 4 5 10 3. 12* 2.95 0.28 5 5 0 2. 40* 2. 85 0.09 5 5 1 14.48 15.16 3. 84 5 5 2 4.76 5.89 2.51 5 5 3 16.61 16.31 4.06 5 5 4 1.97* 2. 05 0. 08 5 5 5 5.15 5.85 2.94 5 5 6 5.95 5.40 6.35 5 5 7 5.79 5.89 5. 25 5 5 8 9. 13 9.4 8 6.31 5 5 9 8. 23 8.37 7.40 6 5 0 4.94 3.44 4.66 6 - 5 1 8.73 8. 16 6. 53 6 5 2 0.72* 0.54 0. 01 6 5 3 13.83 13. 85 4. 70 6 5 4 3. 28* 2.80 0.33 6 5 5 2. 80* 0.72 0. 28 6 5 6 7.27 7.41 5.43 6 5 7 8. 76 9.36 5.87 6 5 8 3.30* 3. 11 0.37 7 5 0 6.88 6.62 7. 10 7 5 1 2. 82* 2.65 0. 16 7 5 2 2.92* 2.22 0.18 7 5 3 9.47 9.93 6. 12 7 5 4 2. 37* 1. 36 0. 16 7 5 5 9.28 9.90 5.60 H K L FO FC WEIGHT 7 5 6 2.85* 0. 30 0.33 8 5 0 5.71 4.84 6. 09 8 5 1 5.48 4.26 5.90 8 5 2 6.14 6. 16 5. 36 8 5 3 2.77* 1.66 0.22 8 5 4 1.69* 0. 56 0. 08 8 5 5 4.24 4.66 3,82 9 5 0 5.38 6.09 3.91 9 5 1 3.57 1.99 3. 19 9 5 2 2.55* 2.36 0. 18 9 5 3 6.02 6. 69 5.77 10 5 0 5.25 4. 45 6. 86 -9 6 2 5.28 5.46 3,93 -9 6 3 3.76* 4. 40 0.21 -9 6 4 5. 85 5. 90 3. 88 -9 6 5 3.94 3.30 3.19 -9 6 6 3.17* 2. 59 0.20 -9 6 7 3.81 3. 41 3. 03 -9 6 8 3.70 2.66 2. 98 -9 6 9 2.96* 2. 02 0. 24 -9 6 10 3.99 3. 44 3.13 -8 6 1 2. 87* -2. 22 0. 15 -8 6 2 3.63* 2. 10 0. 21 -8 6 3 3.09* 0. 80 0. 19 -8 6 4 9. 14 8. 84 4.96 -8 6 5 5.90 5.63 4.25 -8 6 6 2. 58* 3.74 0. 10 -8 6 7 8.32 7. 95 4.83 -8 6 8 9.59 8. 65 5. 85 -8 6 9 1. 17* 0. 45 0.03 -8 6 10 2.90* 0. 47 0.27 -8 6 11 4.09 4. 21 3.59 -8 6 12 5.79 5. 28 5.32 -7 6 1 7.74 7. 38 5.05 -7 6 2 8.02 6.27 4,97 -7 6 3 6. 12 6. 10 3.20 -7 6 4 4.23 2.47 3.02 -7 6 5 10.60 9. 87 5.05 -7 6 6 5.01 4.07 3. 86 -7 6 7 1. 87* 3. 24 0.05 -7 6 8 10.76 10. 54 5. 36 -7 6 9 4.32 3.95 2.83 -7 6 10 5. 23 4. 21 4.01 -7 6 11 5.97 5.71 5.17 -7 6 12 1.85* 0. 84 0. 10 -7 6 13 0.65* 0.77 0.01 -6 6 1 1.90* 0. 17 0.05 -6 6 2 9.17 8.21 4. 85 -6 6 3 3.75* 3. 31 0.16 -6 6 4 2.90* 1.23 0. 13 -6 6 5 5. 11 4. 26 2. 86 -6 6 6 5.36 4.09 3.09 -6 6 7 4.01 2. 15 2.70 -6 6 8 9.22 9. 97 4.44 -6 6 9 5.96 5. 32 3. 94 -6 6 10 9.49 9. 18 4. 91 -6 6 11 4.04 3.54 3.68 -6 6 12 3.73 3.73 2.90 H K 1 FO FC WEIGHT 6 6 13 8.46 8.62 6. 54 5 6 1 4.50 1.93 2.97 5 6 2 4. 30 1.78 2. 10 5 6 3 13. 96 12.59 3.88 5 6 4 13.43 13.01 3. 67 5 6 5 10.64 10.31 4.20 5 6 6 8.74 8.97 4.59 5 6 7 2.95* 3.09 0.13 5 6 8 3.78 1.39 3.49 5 6 9 2. 99* 4.90 0.12 5 6 10 9.75 10.55 6. 18 5 6 11 10. 60 10.56 6.37 5 6 12 9.64 9.74 5.62 5 6 13 6. 24 5.73 10.00 4 6 1 6. 61 6.21 2. 58 4 6 2 10.57 10.21 3. 69 4 6 3 4.48 3.03 2. 18 4 6 4 15.06 13.62 3.66 4 6 5 2.71* 1.46 0. 10 4 6 6 0.00* 0.45 0. 00 4 6 7 9.00 8.44 5.67 4 6 8 6. 58 6. 19 5.05 4 6 9 3.92 3.74 2.83 4 6 10 13.77 13. 73 5. 06 4 6 11 0.62* 0.13 0.01 4 6 12 2.77* 0.85 0. 26 4 6 13 2, 64* 1.07 0.29 3 6 1 4. 25* 3.48 0. 19 3 6 2 6. 26 5.82 3.02 3 € 3 11.66 11.36 4.23 3 6 4 11. 49 10.47 4.25 3 6 5 0. 00* 0.72 0. 00 3 6 6 4.02 1.97 3.72 3 6 7 14.14 15.59 4.52 3 6 8 11.48 12.41 4. 89 3 6 9 5. 58 4.41 6.03 3 6 10 8.00 7.39 6.24 3 6 11 3. 69 2.99 3. 22 3 6 13 0. 00* 1.13 0. 00 2 6 1 11. 43 9.05 4.25 2 6 2 11. 66 9.81 4. 24 2 6 3 17.37 16.52 3.28 2 6 4 17.4 3 17.87 3.44 2 6 5 25. 99 27.52 1.87 2 6 6 12.70 13.59 4. 54 2 6 7 13.27 14.25 4.76 2 6 8 7.50 8. 22 5. 45 2 6 c 9.53 10.37 7.07 2 6 10 10. 82 11.75 6. 14 2 6 11 2. 84* 0. 92 0.24 2 6 12 5.08 4.94 6.24 2 6 13 1. 60* 0.70 0. 11 1 6 1 18. 10 16.81 2. 64 1 6 2 3. 4 7* 2.76 0. 17 1 6 3 3. 68* 3.40 0. 19 1 6 4 25. 76 27.77 1.90 1 6 5 10. 17 9.95 5.52 1 6 6 3. 94 3.35 2. 54 H K L FO FC WEIGHT 1 6 7 4.41 4. 38 3. 10 1 6 8 4.96 4.54 5.29 1 6 9 9.62 9.67 7.24 1 6 10 4.40 4. 84 3.99 1 6 11 2.78* 3. 57 0. 19 1 6 12 5.31 4. 66 7. 34 0 6 0 7.92 6. 40 2.67 0 6 1 2. 29* 1.68 0. 11 0 6 2 22. 06 24. 30 2. 41 0 6 3 3.45* 0.73 0.33 0 6 4 0.00* 1.86 0.00 0 6 5 1.49* 2. 60 0.04 0 6 6 6. 84 6. 34 6. 46 0 6 7 3.81 1. 16 3. 66 0 6 8 1. 87* 0. 65 0.09 0 6 9 4.71 4.70 4.15 0 6 10 2.09* 2.34 0. 11 0 6 11 3.53 3. 04 3. 67 1 6 0 12.98 13. 54 4. 13 1 6 1 4 . 36 4.30 2.98 1 6 2 4.53 2.73 3.13 1 6 3 10.55 10. 83 5. 46 1 6 4 6.72 4.96 6.27 1 6 5 13.02 13. 82 5.44 1 6 6 10.41 11.25 6.55 1 6 7 2.98* 0. 17 0.29 1 6 8 15.07 17. 14 4.07 1 6 9 4.25 3. 11 5.65 1 6 10 9.73 10. 55 6. 01 1 6 11 2.66* 0. 85 0. 35 2 6 0 18.16 19. 35 3. 28 2 6 1 12. 86 13. 66 4. 50 2 6 2 2.50* 1. 54 0. 13 2 6 3 0.00* 0.33 0. 00 2 6 4 9.08 10. 02 4. 81 2 6 5 1.75* 1. 16 0. 07 2 6 6 13.40 14.88 4.62 2 6 7 5.23 5.02 4.19 2 6 8 3.42 0. 26 3.76 2 6 9 14. 81 15. 87 4.46 2 6 10 5.35 5.56 5.74 3 6 0 3.43* 2. 69 0. 16 3 6 1 2.03* 3. 18 0. 06 3 6 2 11.43 11. 96 4.58 3 6 3 2.65* 2. 13 0. 14 3 6 4 7.96 8. 67 4.43 3 6 5 8.16 8. 11 6.90 3 6 6 13.32 13. 76 4. 33 3 6 7 15.15 15.94 4. 12 3 6 8 3.61 2. 50 3.46 3 6 9 7.59 7. 80 7.30 4 6 0 13.79 14.41 4.57 4 6 1 0.00* 1.21 0. 00 4 6 2 3.49* 1. 74 0. 32 4 6 3 2.06* 1. 73 0. 09 4 6 4 2.33* 3.54 0. 09 4 6 5 2.79* 2. 68 0. 19 4 6 6 7.65 7. 82 6. 63 HI K 1 FO FC WEIGHT *! 6 7 3. 36 1.97 3. 20 4 6 8 5. 95 6.61 6.60 5 6 0 20. 20 21.69 2.86 5 6 1 8. 13 8. 81 4.58 /5 6 2 3. 76* 2.88 0. 28 5 6 3 7. 61 6.79 7.30 5 6 4 3. 46 1.94 3. 75 h 6 5 3.82 1.14 5.02 I 5 6 6 3. 21* 4. 09 0.27 6 6 0 5.0 8 4.6 3 3.90 6 6 1 12.54 12.55 5.38 6 6 2 1.43* 1.24 0.04 6 6 3 5.64 5.42 5.54 6 6 4 6. 34 5.86 6. 94 6 6 5 7.99 7. 97 7.39 7 6 0 5. 52 4.88 6.91 7 6 1 0. 00* 2.02 0.00 7 6 2 5.63 5.93 5.02 7 6 3 5. 74 5.03 5.95 8 6 0 7. 30 7.73 6. 59 8 6 1 3. 73 2. 10 4.71 -7 7 4 3.08* 0. 19 0.26 -7 7 5 7.32 8.66 5 • 26 -7 7 6 1. 20* 1.05 0. 04 -6 7 1 3.09* 1.64 0. 16 -6 7 2 2.95* 3.86 0. 12 -6 7 3 7.04 7. 16 4. 22 -6 7 4 4. 74 3.70 3. 01 -6 7 5 3.91* 2.86 0.25 -6 7 6 6. 18 6.93 3. 84 -6 7 7 4. 61 3.05 4.69 -6 7 8 2. 85* 2.32 0.22 -5 7 1 6.44 6.62 3. 46 -5 7 2 5. 21 3.63 3.52 -5 7 3 3. 23* 1.00 0. 15 -5 7 4 4.41 5.12 1. 96 -5 7 5 8. 50 7. 94 4.78 -5 7 6 10. 36 11.48 5. 11 -5 7 7 15.66 16.61 3. 75 -5 7 8 4.87 5.02 3.94 -5 7 9 3. 83 3.40 3.93 -a 7 1 11. 78 11.80 3. 64 -4 7 2 7.07 5.31 4.33 -4 7 3 5. 59 5.57 2.46 -4 7 a 18.53 18.98 2. 94 -4 7 5 2. 45* 2.07 0. 08 -4 7 6 2. 74* 2.76 0. 13 -4 7 7 9. 19 9.63 5. 60 -4 7 8 2. 56* 2. 90 0. 14 -4 7 9 3.79 2.56 4.72 -3 7 1 2.21* 1.59 0.05 -3 7 2 5. 92 5.50 2.45 -3 7 3 9. 45 8. 29 3. 84 -3 7 4 3. 23* 2. 38 0. 15 -3 7 5 6. 85 6.33 4. 17 -3 7 6 9.86 10.32 4.67 -3 7 7 0.63* 0.74 0.01 -3 7 8 2. 81* 1.19 0.27 H K L FO FC WEIGHT -3 7 9 4.10 3. 79 4.00 -2 7 1 11.02 10. 90 3. 52 -2 7 2 7.90 7. 79 2.90 -2 7 3 5.84 5. 30 3. 86 -2 7 4 8.00 7. 09 6.13 -2 7 5 2.44* 1.42 0, 12 -2 7 6 4.31 5. 27 2. 98 -2 7 7 8.34 8. 64 7.15 -2 7 8 6.08 7. 33 4. 6 9 -2 7 9 2.00* 1. 75 0. 13 -1 7 1 4.99 2. 79 2.46 -1 7 2 13. 24 13. 77 3.99 -1 7 3 3. 82* 3. 66 0. 23 -1 7 4 6.21 6. 95 4.25 -1 7 5 6.31 6. 81 4. 54 -1 7 6 4.92 3.40 6. 44 -1 7 7 7.83 8. 29 6.15 -1 7 8 3.29 2. 25 3.41 -1 7 9 4.34 3.67 6.24 0 7 1 5.54 3.70 5. 91 0 7 2 5.95 6. 80 3.83 0 7 3 9. 13 9. 79 5. 28 0 7 4 2.97* 0. 61 0. 22 0 7 5 2.04* 2. 13 0.09 0 7 6 7.00 7. 34 6.72 0 7 7 14.89 15. 80 4.78 0 7 8 4.62 4. 12 4,83 1 7 0 9.66 10. 27 5.16 1 7 1 14.73 15. 12 4.29 1 7 2 4.58 3.75 3.62 1 7 3 8.77 9. 30 5. 38 1 7 4 3.44* 3. 71 0.22 1 7 5 9.74 10. 30 6.83 1 7 6 3.50* 3. 06 0. 29 1 7 7 7 .89 8. 65 8.57 2 7 0 7.86 9.04 4.40 2 7 1 6.21 5. 66 7. 10 2 7 2 9.10 10.64 5.62 2 7 3 3.17* 2. 81 0. 27 2 7 4 1.71* 1. 47 0.07 2 7 5 3.92 4. 07 4.24 2 7 6 1.95* 1. 93 0. 13 3 7 0 10.47 10. 67 7, 19 3 7 1 3.91 0. 99 4.78 3 7 2 9.55 10. 09 6.01 3 7 3 8.08 9. 16 7. 35 3 7 4 4.48 4. 07 5.02 3 7 5 3.95 4.75 3. 18 4 7 0 2.38* 0. 73 0. 17 4 7 1 2.90* 1. 05 0. 27 4 7 2 2.69* 0.76 0.25 4 7 3 7.43 8. 49 6.95 4 7 4 3. 48 3. 25 3.52 5 7 0 2.98* 1.61 0. 31 5 7 1 1.28* 0.88 0.05 5 7 2 2.93* 0. 91 0. 38 6 7 0 3.08 1. 51 3. 87 * DENOTES AN UNOBSERVED REFLECTION Dichlorotstrakis (dimethylsulphoxide)ruthenium (II) Anthony Mercer and James Trotter Observed and calculated structure amplitudes, (re f l e c t i o n s with i n t e n s i t y < 3er(I) are marked with an asterisk) . The following planes which had j Fo-Fc| > 3<3-(F) were given zero weight in the f i n a l stages of refinement due tc suspected errors r e s u l t i n g from e x t i n c t i o n , absorption, or instrument malfunction: h k 1 Fo Fc h k 1 Fo Fc 1 2 4 120.4 197.0 0 8 0 130.6 218.0 3 0 T 121.6 222.9 1 8 1 131.8 1 87.5 4 2 T 145.4 207.2 4 0 2 143.0 186. 5 3 (i 1 132,7 182.0 i o 3 1G0. 4 174.7 2 0 0 85.5 165. 0 0 2 3 98.7 189.3 4 0 0 143. 4 193. 6 0 0 4 136.5 289.8 3 2 0 122 .7 181.4 0 2 5 126. 2 194. 8 1 6 0 114.1 196.7 H K L F O F C H K L F O F C 1 0 - 1 3 6.00* 5.33 2 2 n 41. 19 42.85 3 0 -13 5 .74 * 4.36 3 2 - 11 1.52* 1.89 1 1 -13 7 . 06 * 6.33 4 2 - 11 26. 18 26.67 2 1 -13 6 . 0 3 * 7.82 5 2 - 11 23.73 22.82 3 1 -13 24.74 23.03 6 2 - 11 15.64 15.28 2 2 - 13 0.00* 0.85 1 3 - 11 32.68 34. 16 3 2 - 1 3 2 .88 * 0.70 2 3 - 11 32. 15 33. 1 1 1 3 - 1 3 13.56 13.06 3 3 - 11 34.63 36. 15 2 3 -13 12.79 12.55 4 3 11 37.29 36.94 1 4 - 13 11.71 11.47 5 3 - 11 31.22 30.48 2 4 - 13 16.55 15.35 6 3 n 12.25 11.84 1 5 - 13 13.28 12.94 1 4 - 11 30.90 32.37 2 0 - 1 2 32.87 32.97 2 4 11 2 . 0 3 * 4.22 4 0 -12 25.83 25. 17 3 4 - 11 31.66 32.13 1 1 - 1 2 16.10 15.48 4 4 i 1 3 .92 * 5. 18 2 1 -12 6 . 5 4 * 6.88 5 4 - 11 20.41 20. 19 3 1 - 1 2 26,19 26.11 6 4 - 11 6 . 60 * 7.77 4 1 -12 26.98 26.01 1 5 - 11 39. 11 40.01 5 1 - 1 2 14.74 13.84 2 5 - 11 39.52 39.55 1 2 -12 22.34 22.33 3 5 - 11 37.66 38.41 2 2 - 1 2 5 . 01 * 5.14 4 5 11 32.29 32. 25 3 2 -12 30.55 29. 27 5 5 - 11 33.47 32.58 4 2 - 1 2 24.84 24.17 1 6 - 11 46.56 47.82 5 2 -12 19.71 19.24 2 6 11 28.50 29.39 1 3 -12 22.97 23.57 3 6 - 11 14.68 14.85 2 3 - 1 2 27.68 28.08 4 6 - 11 27.90 26.70 3 3 -12 26 . 5 1 26.33 5 6 - 11 0 .00 * 0. 18 4 3 - 12 30.10 28.69 1 7 - n 30.07 30.68 1 4 -12 16.02 16.32 2 7 - 11 25.75 25.32 2 4 - 1 2 18.32 17.99 3 7 11 14.23 15.28 3 4 -12 0 . 0 0 * 1.34 4 7 - 11 29. 14 28.79 4 4 - 1 2 16.63 15.97 5 7 11 28.79 27.92 1 5 -12 32. 21 32.34 1 8 11 14.99 14.31 2 5 -12 21.02 21.64 2 8 - 11 14. 15 14.16 3 5 - 1 2 29. 18 28.53 3 8 11 34.57 34. 17 4 5 - 12 33.29 32.25 4 8 - 11 9.51 10.02 1 6 - 1 2 6 . 60 * 7.16 1 9 i1 28.97 28.78 2 6 -12 10.81 11.01 2 9 - 11 34.24 33.01 3 6 - 1 2 16.96 16.14 3 9 - 11 15.85 ' 15.39 4 6 - 12 14.37 13.32 4 9 - 11 14.79 14.73 1 7 - 12 8. 34 7.67 1 10 - 11 6.24* 6.76 2 7 - 1 2 17.53 16.79 2 10 11 20.21 20.46 3 7 -12 23.00 23. 38 3 10 - n 6 .92 * 7.23 1 8 - 1 2 23.81 23.26 1 1 1 - 11 39.05 38.30 2 8 -12 16.43 15.89 2 11 11 28.81 27.45 3 8 - 1 2 11.68 11.08 3 11 ! 1 38.36 37.03 1 9 -12 12.54 12.67 1 12 - 11 11.96 10.88 2 9 - 1 2 13.26 12.63 2 0 10 32.42 34.50 1 0 -11 49.53 51.02 4 0 - 10 46.00 43.97 3 0 -11 40.09 40.59 6 0 10 10.75 1 1. 10 5 0 -1 1 12. 25 11. 12 1 1 - 10 13. 10 13.35 1 1 -11 25.79 26.58 2 1 10 7.71 8.04 2 1 -1 1 2. 11 * 0.81 3 1 - 10 38.54 37.41 3 1 -11 13.63 14.31 4 1 10 45.32 44.33 4 1 -11 31.37 31.82 5 1 10 42.75 42.37 5 1 -11 22.52 21.98 6 1 - 10 17.45 16.37 6 1 -11 25. 14 24.32 7 1 10 45.27 43.97 1 2 -11 5 . 4 1 * 6.66 1 2 - 10 33.77 34.52 H K L FO FC 2 2 -10 19.32 19. 13 3 2 -10 30,52 31.00 4 2 -10 16.19 16.65 5 2 -10 21.74 20.56 6 2 -10 19.42 19.24 7 2 -10 26.96 26.20 1 3 -10 , 48.97 50.81 2 3 -10 47. 35 48.48 3 3 -10 43.13 44.40 4 3 -10 72.69 72.44 5 3 -10 30.97 30.19 * 6 3 -10 36. 32 36. 10 7 3 -10 16.79 15.89 1 4 -10 22.75 23.05 2 4 -10 27.68 30.04 3 4 -10 29.74 29.22 4 4 -10 32.95 32.19 5 4 -10 21.07 20.40 6 4 -10 19.65 19.28 7 4 -10 3.30* 4.51 1 5 -10 46.30 48.25 2 5 -10 45.28 45. 19 3 5 -10 64.94 65.27 4 5 -10 30.42 30.17 5 5 -10 49.84 49. 13 6 5 -10 12.88 12.77 1 6 -10 27.36 27.66 2 6 -10 8.66 9.13 3 6 -10 41.52 42.59 4 6 -10 14.72 14.60 5 6 -10 23.55 22.65 6 6 -10 14.06 14,34 1 7 -10 30.30 30,06 2 7 -10 40.59 41.42 3 7 -10 2.4 2* 3. 82 4 7 -10 28.29 27.93 5 7 -10 13.52 12.74 6 7 -10 41.92 40. 68 1 8 -10 18.35 18.75 2 8 -10 44.08 46.07 3 8 -10 19.38 19.80 4 8 -10 33.33 33.78 5 8 -10 13.61 12.75 6 8 -10 13.59 12.97 1 9 -10 42.67 43.19 2 9 -10 14. 15 13.08 3 9 -10 20.73 20.51 4 9 -10 0.00* 1.29 5 9 -10 35.92 35.71 1 10 -10 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58.69 2 4 -7 3.46* 1. 16 3 4 -7 67.39 67.02 4 4 -7 11.02 10.43 5 4 -7 47,86 46.66 6 4 -7 0.00* 0.54 7 4 -7 48.45 49.90 8 4 -7 14.79 15.06 9 4 -7 36. 16 36.95 1 5 -7 77.77 78. 27 2 5 -7 11.07 9.90 3 5 -7 37.35 40.02 4 5 -7 33.70 34.21 5 5 -7 50.15 51.60 6 5 -7 23.61 24.06 7 5 -7 2.55* 0.61 8 5 -7 7.41 6.82 1 6 -7 105.83 107.08 2 6 -7 59.41 63.18 3 6 -7 9.21 8.70 4 6 -7 56.94 57.84 5 6 -7 1.73* 2.16 6 6 -7 62.72 61. 15 7 6 -7 25.38 25.93 8 6 -7 34.67 35.29 1 7 -7 10.50* 8.78 2 7 -7 51.31 54.07 3 7 -7 4.32* 4.72 4 7 -7 22.29 23.56 5 7 -7 2.56* 2. 14 6 7 -7 14.41 15.09 7 7 -7 32.52 32.93 8 7 -7 16.76 14.93 1 8 -7 23.69 24.89 2 8 -7 8.54 7.43 3 8 -7 50.36 52.47 4 8 -7 3.76* 2.97 5 8 -7 39.96 39.81 6 8 -7 4.52* 3.79 7 8 -7 41.67 41.92 8 8 -7 7.68 8.31 1 9 -7 67,60 66.83 2 9 -7 25,50 26.49 3 9 -7 22,55 22.50 4 9 -7 15.67 16.36 5 9 -7 31.37 32.14 H K L FO FC H K L FO FC 6 9 -7 25.83 25.41 6 1 -6 6.30 5.88 7 9 -7 20.23 19.93 7 1 -6 35.66 34,90 8 9 -7 13.. 90 13.93 8 1 -6 42.74 42.59 1 10 -7 1. 60* 1.02 9 1 -6 16.92 16.30 2 10 -7 55.21 56.64 1 2 -6 63. 1 1 67.94 3 10 -7 10.46 11.04 2 . 2 -6 55.23 58,92 4 10 -7 29.04 29.09 3 2 -6 119.99 124.38 5 10 -7 37.31 38.68 4 2 -6 1.40* 2.52 6 10 -7 44. 37 43. 20 5 2 -6 72.48 72.29 7 10 -7 22.24 22.46 6 2 -6 38.00 39. 13 1 11 -7 40.72 41.48 7 2 -6 75.28 76.06 2 1 1 -7 30.97 32.55 8 2 -6 25.85 26.92 3 1 1 -7 37.08 38.24 9 2 -6 44.68 46.89 4 11 -7 35.62 38.67 1 3 -6 55. 14 52.43 5 11 -7 26.39 26.01 2 3 -6 45.43 44.05 6 1 1 -7 28.20. 28.88 3 3 -6 28. 26 25.77 7 11 -7 5. 33* 3.26 4 3 -6 85. 19 85.35 1 12 -7 44.17 47.59 5 3 -6 62.99 63. 11 2 12 -7 23. 35 24.46 6 3 -6 30.40 32.00 3 12 -7 47.26 47. 3 1 7 3 -6 22.01 22.09 4 12 -7 20.72 21.26 8 3 -6 12.37 12.00 5 12 -7 52.97 52.71 9 3 -6 24.44 24.61 6 12 -7 28.52 30.13 1 4 -6 16.00 18.54 7 12 -7 17.88 18.27 2 4 -6 87.83 94.16 1 13 -7 31.36 33.15 3 4 -6 40.38 37.74 2 13 -7 70.27 72.98 4 4 -6 122.63 124.61 3 13 -7 41.95 43.44 5 4 -6 46.40 46.33 4 13 -7 28.08 27.90 6 4 -6 69.04 70.59 5 13 -7 15,68 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13.01 13.53 7 13 -6 19.70 19.23 1 14 -6 52. 20 53. 16 2 14 -6 61.77 64.11 3 14 -6 33.91 33.69 4 14 -6 11.21 11.01 5 14 -6 54. 11 54.77 6 14 -6 4.16* 0.94 1 15 -6 18.46 18. 17 2 15 -6 16.8 3 18.35 3 15 -6 43. 15 44.29 4 15 -6 5. 14* 4.02 5 15 -6 2.40* 1.16 6 15 -6 20.68 20.40 1 16 -6 32.23 33.24 2 16 -6 19.42 19.57 H K L FO F C 3 16 -6 25.0 3 25.45 4 16 -6 21.77 22. 14 5 16 -6 5.90* 6.50 1 17 -6 11.05 12.30 2 17 -6 7,46 8.45 3 17 -6 2.47* 0.60 4 17 -6 13.82 13.79 1 18 -6 37.33 38.78 2 18 -6 8.20 8.83 3 18 -6 12.72 13.64 1 19 -6 0.00* 3.77 1 0 -5 117.28 136.78 3 0 -5 134.78 148.80 5 0 -5 66.57 66.52 7 0 -5 69.68 69.50 9 0 -5 38.96 40.62 1 1 -5 73.97 75.81 2 1 -5 71.58 70.52 3 1 -5 26. 11 26.92 4 1 -5 57.62 58.38 5 1 -5 35.39 33.46 6 1 -5 24. 11 23.36 7 1 -5 27.96 28.52 8 1 -5 36.91 37.62 9 1 -5 36.77 37.40 1 2 -5 9.32 5.53 2 2 -5 104.08 107. 16 3 2 -5 13.40 14.94 4 2 -5 152.06 171.32 5 2 -5 54.70 53.69 6 2 -5 48.95 52.86 7 2 -5 15.29 15. 18 8 2 -5 60.84 62.15 9 2 -5 18.38 19.28 1 3 -5 71.60 74.88 2 3 -5 9.45 12.09 3 3 -5 108.73 113.24 4 3 -5 80. 16 78.21 5 3 -5 27.81 26.73 6 3 -5 23.72 22.44 7 3 -5 24. 15 24.64 8 3 -5 31. 16 31.91 9 3 -5 10.44 10.76 1 4 -5 111.07 124.71 2 4 -5 10.52 11.91 3 4 -5 141.39 164.09 4 4 -5 45.64 45.37 5 4 -5 94.32 94.78 6 4 -5 13.47 15.05 7 4 -5 60.38 61.91 8 4 -5 2.86* 1.82 9 4 -5 29.73 29.85 1 5 -5 59.09 59.93 2 5 -5 94.47 98.52 3 5 -5 10.75 12. 13 4 5 -5 91.4 1 91. 17 5 5 ,"5 78.20 75.43 6 5 -5 44.33 43.80 H K L FO FC 7 5 -5 18,00 18.06 8 5 -5 24.91 25.35 9 5 -5 25. 97 26.38 1 6 -5 91. 17 91. 30 2 6 -5 91.88 93.86 3 6 -5 44.77 45.58 4 6 -5 76.80 76.48 5 6 -5 28.9 5 30.01 6 6 -5 74.40 74.44 7 6 -5 33.50 34.4 2 8 6 -5 45.32 44.99 9 6 -5 4. 39* 3.08 1 7 -5 57.44 57. 15 2 7 -5 22. 20 21.98 3 7 -5 39.52 38. 69 4 7 -5 20.44 21 .1 1 5 7 -5 21. 38 22.32 6 7 -5 9. 13 7.49 7 7 -5 50. 11 49.79 8 7 -5 14.37 12.95 9 7 -5 27.91 27.90 1 8 -5 107.59 108.57 2 8 -5 48.84 48.80 3 8 -5 70.70 69.22 4 8 -5 13.53 13.86 5 8 -5 27.79 28.17 6 8 -5 17.31 17.44 7 8 -5 66.26 66.87 8 8 -5 3.63* 4. 25 9 8 -5 41.76 42.04 1 9 -5 4. 15* 6. 16 2 9 -5 49.85 51.04 3 9 -5 35.02 35. 1 1 4 9 -5 1.81* 1.44 5 9 -5 31.88 31.89 6 9 -5 36.73 36.05 7 9 -5 9.38 7.14 8 9 -5 25.26 24.60 1 10 -5 3.33* 4.48 2 10 -5 101,66 101.80 3 10 -5 8.06 9.07 4 10 -5 20,39 21.42 5 10 -5 32.82 33.23 6 10 -5 59,44 58.21 7 10 -5 23.32 , 23.57 8 10 -5 19.04 19.15 1 11 -5 28.32 28.36 2 11 -5 21.61 20.60 3 11 -5 39.59 39.69 4 11 -5 17.66 18.17 5 1 1 -5 58.93 57.76 6 1 1 -5 16.80 15.73 7 11 -5 33. 20 34.02 8 11 -5 16.75 16.02 1 12 -5 63.41 65.03 2 12 -5 43.79 43.84 3 12 -5 47.67 46.88 4 12 -5 0,00* 1.32 H K L FO FC 5 12 -5 52.80 51.22 6 12 -5 42.92 43.21 7 12 -5 33.34 33.43 1 13 -5 4.49* 6.82 2 13 -5 50.85 52.02 3 13 -5 36.53 38.24 4 13 -5 41.92 4 1.40 5 13 -5 2.73* 2.07 6 13 -5 64.87 63.99 7 13 -5 0.00* 2.87 1 14 -5 44.82 46.28 2 14 -5 49.07 48.51 3 14 -5 28.85 28.73 4 14 -5 30.87 29.80 5 14 -5 8.66* 7.84 6 14 -5 54.83 55.04 7 14 -5 1. 10* 1.36 1 15 -5 12.60 14.01 2 15 -5 33.44 34.92 3 15 -5 10.58 10.33 4 15 -5 2.07* 0.41 5 15 -5 18.56 19.91 6 15 -5 14.89 13.55 1 16 -5 54.00 54.35 2 16 -5 14.78 15.16 3 16 -5 15.53 15.00 4 16 -5 15.57 15.79 5 16 -5 35.39 36.78 1 17 -5 11.30 11.27 2 17 -5 7.82 8. 14 3 17 -5 15.22 15.09 4 17 -5 3.77* 4.45 5 17 -5 20.89 21.60 1 18 -5 0.00* 2.75 2 18 -5 36.66 37.49 3 18 -5 0.00* 2.31 4 18 -5 33.92 34.47 1 19 -5 14. 10 14.99 2 19 -5 0.00* 3.40 3 19 -5 27. 15 27.91 2 0 -4 38.09 27.26 4 0 -4 77.97 77.23 6 0 -4 31.88 31.56 8 0 -4 81. 12 82.65 10 0 -4 14.56 14.54 1 1 -4 85. 12 88.84 2 1 -4 36.03 36.40 3 1 -4 15.43 15.90 4 1 -4 44. 38 44.82 5 1 -4 13.83 15. 14 6 1 -4 11.29 12.18 7 1 -4 30.52 32.05 8 1 -4 56.05 57.55 9 1 -4 27.54 28.00 10 1 -4 20.31 21.17 2 2 -4 9.01 8. 13 3 2 -4 74.54 82.44 4 2 -4 3.64* 4.03 H K L FO FC 5 2 -4 38.63 39.54 6 2 -4 16.79 17. 52 7 2 -4 39.27 41.91 8 2 -4 21.52 21.79 9 2 -4 30.69 31.72 10 2 -4 0.00* 1.64 1 3 -4 22.77 24.88 2 3 -4 50.25 51 .77 3 3 -4 34.27 30.66 4 3 -4 42. 13 42.32 5 3 -4 73.82 72.3 8 6 3 -4 18.82 19.96 7 3 -4 7.19 6.44 8 3 -4 27.65 28.55 9 3 -4 28.85 29.33 10 3 -4 4.71* 6.31 1 4 -4 33.91 40.97 2 4 -4 91.77 92.89 3 4 -4 22.86 24.50 4 4 -4 1C9.72 113.23 5 4 -4 7.22 6.96 6 4 -4 50.72 52.13 7 4 -4 27.54 28.62 8 4 -4 46.07 45.72 9 4 -4 14.09 14.72' 10 4 -4 4.8 8* 3.65 1 5 -4 4.60 3.23 2 5 -4 69.47 67.59 3 5 -4 66.84 66.98 4 5 -4 52.89 51.03 5 5 -4 36.90 37.28 6 5 -4 14.07 14.82 7 5 -4 68.56 70.11 8 5 -4 4.68* 4.88 9 5 -4 12.14 11 .74 1 6 -4 70.66 74.01 2 6 -4 41. 33 42.79 3 6 -4 39.43 41 .54 4 6 -4 12.87 12.53 5 6 -4 59.31 59.10 6 6 -4 42.81 42.05 7 6 -4 61.31 61 .86 8 6 -4 25.08 24.70 9 6 -4 26.85 27.18 1 7 -4 92. 27 92.86 2 7 -4 31.45 33.77 3 7 -4 20.89 18.94 4 7 -4 21.94 22.25 5 7 -4 59.53 60.65 6 7 -4 28.67 29.08 7 7 -4 38.72 38.05 8 7 -4 33.22 32.90 9 7 -4 27.21 27.21 1 8 -4 66.85 66.95 2 8 -4 71.88 72.58 3 8 -4 9.4 4 7.13 4 8 -4 29. 22 30. 26 5 8 -4 10.17 10.37 H K L FO FC 6 8 -4 71.30 70.39 7 8 -4 23.80 23.61 8 8 -4 38.25 37.69 9 8 -4 12.40 12.53 1 9 -4 85.79 80.60 2 9 -4 7.20 6.64 3 9 -4 38. 19 37.66 4 9 -4 11.46 11.52 5 9 -4 6. 13 7.34 6 9 -4 2.97* 4.00 7 9 -4 24.88 26.03 8 9 -4 13.05 13.58 9 9 -4 20.74 21. 16 1 10 -4 9 3.08 93,75 2 10 -4 4.98* 3.67 3 10 -4 67.26 69.22 4 10 -4 31.01 30.45 5 10 -4 60.97 6 1.03 6 10 -4 42.23 39.98 7 10 -4 53.95 52.54 8 10 -4 5.56* 2.86 1 11 -4 29.05 27.48 2 11 -4 92.04 92.82 3 11 -4 13. 19 12.77 4 11 -4 54.69 54.38 5 11 -4 22.92 22.88 6 11 -4 51. 18 51.59 7 11 -4 10,46 9.89 8 11 -4 4.24* 1. 39 1 12 -4 10.83 11.54 2 12 -4 75.67 76.93 3 12 -4 12.83 12.98 4 12 -4 49.61 50.00 5 12 -4 30.88 30.47 6 12 -4 87.95 85.32 7 12 -4 12.80 12. 13 8 12 -4 16.67 15.22 1 13 -4 21.82 21.62 2 13 -4 19. 14 19.30 3 13 -4 67.24 67.42 4 13 -4 8.54 8.84 5 13 -4 52.97 5 2.50 6 13 -4 0.86* 1.56 7 13 -4 21.01 21.55 1 14 -4 52^96 54.69 2 14 -4 37. 21 38.43 3 14 -4 29.43 30.51 4 14 -4 13.58 14. 13 5 14 -4 73.07 71.99 6 14 -4 16.92 17.03 7 14 -4 39.56 3 9.95 1 15 -4 8.32 7.69 2 15 -4 33.21 33.03 3 15 -4 25,65 26. 12 4 15 -4 20.70 20.31 5 15 -4 29.08 28.65 6 15 -4 15.17 15.06 7 15 -4 5.30* 5. 14 H K L FO FC 1 1 6 - 4 0 . 0 0 * 1 . 6 5 2 1 6 - 4 4 6 . 6 8 4 7 . 6 6 3 1 6 - 4 1 1 . 0 1 1 0 . 8 9 4 1 6 - 4 3 2 . 6 5 3 2 . 3 8 5 1 6 - 4 1 . 6 9 * 3 . 0 5 6 1 6 - 4 3 0 . 3 4 2 9 . 8 2 1 1 7 - 4 2 9 . 2 0 2 8 . 9 0 2 1 7 - 4 1 7 . 4 6 1 7 . 3 9 3 1 7 - 4 2 0 . 0 3 1 9 . 5 9 4 1 7 - 4 2 1 . 9 6 2 2 . 6 7 5 1 7 - 4 2 . 9 8 * 1 . 0 7 1 1 8 - 4 6 7 . 5 6 6 8 . 6 9 2 1 8 - 4 1 1 . 5 3 1 2 . 3 9 3 1 8 - 4 3 5 . 3 4 3 6 . 7 1 4 1 8 - 4 1 1 . 6 0 1 1 . 2 6 1 1 9 - 4 3 1 . 2 1 3 2 . 0 6 2 1 9 - 4 1 3 . 3 3 1 3 . 9 1 3 1 9 - 4 1 1 . 0 9 1 1 . 2 2 1 2 0 - 4 0 . 0 0 * 1 , 7 6 2 2 0 - 4 4 4 . 2 0 4 5 . 5 0 1 0 - 3 6 5 . 8 6 6 8 . 1 4 3 0 - 3 3 1 . 4 1 3 0 . 4 9 5 0 - 3 2 2 . 1 4 1 9 . 1 9 7 0 - 3 5 4 . 5 4 5 4 . 2 7 9 0 - 3 5 3 . 2 8 5 5 . 4 6 1 1 - 3 , 1 7 , 4 7 1 7 . 7 6 2 1 - 3 4 1 . 9 4 3 7 . 7 7 3 1 - 3 2 9 . 0 1 3 2 . 0 0 1 - 3 3 9 . 5 9 3 7 . 8 5 5 1 - 3 3 4 . 9 0 3 7 . 2 1 6 1 - 3 1 8 . 1 8 1 9 . 1 7 7 1 - 3 3 9 . 9 3 4 1 . 5 4 8 1 - 3 1 3 . 4 8 1 3 . 8 0 9 1 - 3 3 1 . 4 4 3 2 . 4 2 1 0 1 - 3 0 . 0 0 * 2 . 2 2 1 2 - 3 1 4 . 0 3 1 5 . 2 9 2 2 - 3 4 1 . 6 4 4 2 . 0 1 3 2 - 3 6 4 . 4 3 6 0 . 9 9 4 2 - 3 9 5 . 5 4 9 4 . 5 2 5 2 - 3 2 3 . 0 7 2 1 . 3 1 6 2 - 3 1 2 . 3 0 1 2 . 3 3 7 2 - 3 1 6 . 7 1 1 5 . 3 1 8 2 - 3 8 3 . 4 8 8 6 . 6 9 9 2 - 3 2 5 . 7 9 2 7 . 2 0 1 0 2 - 3 9 . 3 3 7 . 5 9 1 3 - 3 1 1 . 0 0 1 0 . 2 7 2 3 - 3 5 0 . 7 5 4 8 . 8 6 3 3 - 3 8 6 . 4 9 8 5 . 5 5 a 3 - 3 4 . 4 0 * 2 . 7 8 5 3 - 3 2 7 . 6 4 3 0 . 1 6 6 3 - 3 3 5 . 5 0 3 4 . 7 8 7 3 - 3 3 4 . 8 1 3 4 . 6 8 8 3 - 3 2 2 . 7 6 2 3 . 0 1 9 3 - 3 1 4 . 4 5 1 5 . 1 9 1 0 3 - 3 0 . 0 0 * 2 . 7 4 1 4 - 3 5 6 . 0 3 5 3 . 0 5 2 4 - 3 7 4 . 2 7 7 3 . 7 3 3 4 - 3 9 5 . 2 2 9 2 . 9 9 H K L FO FC 4 4 - 3 1 8 . 9 7 1 8 . 1 8 5 4 - 3 1 0 5 . 6 1 1 0 4 . 0 4 6 4 - 3 4 . 4 6 * 4 . 7 1 7 4 - 3 5 4 . 1 1 5 5 . 2 2 8 4 - 3 1 7 . 2 3 1 7 . 6 9 9 4 - 3 2 7 . 7 9 2 8 . 7 7 1 0 4 - 3 2 . 8 4 * 2 . 9 5 1 5 - 3 1 0 6 . 6 5 1 2 4 . 1 7 2 5 - 3 6 . 8 3 7 . 5 0 3 5 - 3 1 8 . 1 1 1 8 . 3 4 4 5 - 3 4 8 . 6 3 4 6 . 8 6 5 5 - 3 5 9 , 1 7 5 7 . 5 5 6 5 - 3 6 9 . 2 1 6 8 . 5 9 7 5 - 3 3 9 . 0 9 4 0 . 0 2 8 5 - 3 1 6 . 7 8 1 7 . 5 2 9 5 - 3 3 3 . 2 9 3 3 . 6 5 1 0 5 - 3 5 . 7 3 * 5 . 5 1 1 6 - 3 4 9 . 5 6 4 8 . 6 1 2 6 - 3 4 8 . 5 6 4 5 . 7 0 3 6 - 3 3 . 7 8 * 7 . 3 6 4 6 - 3 5 4 . 7 1 5 3 . 1 6 5 6 - 3 1 1 . 9 5 1 1 . 2 2 6 6 - 3 5 9 . 2 2 5 8 . 0 2 7 6 - 3 1 4 . 7 4 1 3 . 9 5 8 6 - 3 4 3 . 8 8 4 3 . 6 1 9 6 - 3 0 . 0 0 * 1 . 7 9 1 7 - 3 6 . 9 1 5 . 6 1 2 7 - 3 8 7 . 6 5 8 0 . 8 1 3 7 - 3 8 . 6 7 6 . 5 9 4 7 - 3 6 . 3 3 3 . 6 7 5 7 - 3 1 1 . 3 9 1 1 . 2 4 6 7 - 3 3 . 0 1 * 0 . 5 2 7 7 - 3 3 6 . 9 3 3 6 . 6 2 8 7 - 3 4 . 1 7 * 3 . 1 0 9 7 - 3 7 . 9 6 7 . 3 6 1 8 - 3 8 6 . 3 8 8 8 . 3 6 2 8 - 3 7 . 0 1 6 . 4 9 3 8 - 3 6 9 . 4 3 6 7 . 3 6 4 8 - 3 2 4 , 1 6 2 0 . 5 8 5 8 - 3 2 3 . 2 2 2 0 . 9 9 6 8 - 3 1 1 . 6 2 1 1 . 2 8 7 8 - 3 4 2 . 3 5 4 1 . 8 2 8 8 - 3 7 . 1 7 7 . 1 2 9 8 - 3 3 0 . 1 5 2 9 . 8 3 1 9 - 3 4 6 . 1 1 4 7 . 0 5 2 9 - 3 6 4 . 5 1 6 4 . 6 2 3 9 - 3 5 2 . 5 6 4 9 . 8 9 4 9 - 3 1 0 . 9 3 1 0 . 6 0 5 9 - 3 1 0 . 6 3 1 0 . 4 7 6 9 - 3 3 . 5 6 * 2 . 0 8 7 9 - 3 3 . 1 7 * 3 . 0 4 8 9 - 3 3 . 4 6 * 1 . 3 0 9 9 - 3 3 9 . 3 5 3 9 . 0 0 1 1 0 - 3 2 3 . 0 5 2 2 . 1 2 2 - 1 0 - 3 1 2 5 . 8 7 1 2 7 . 3 2 3 1 0 - 3 3 1 . 5 9 3 0 . 7 1 4 1 0 - 3 5 3 . 8 1 5 2 . 9 2 5 1 0 - 3 6 . 0 5 • 5 . 5 4 H K L FO FC 6 10 -3 67.84 65.94 7 10 -3 15.78 14.44 8 10 -3 5.86* 3.64 9 10 -3 17.32 18.04 1 11 -3 53.98 53.31 2 11 -3 20.55 22.48 3 1 1 -3 44.39 45.58 4 1 1 -3 9.60 9. 83 5 11 -3 16.50 15.64 6 11 -3 19.82 19.75 7 11 -3 4.88* 6.94 8 11 -3 28.86 28.82 1 12 -3 53.77 51.70 2 12 -3 24.06 24.62 3 12 -3 85. 36 84.99 4 12 -3 5.00* 2 • 3.2 5 12 -3 87.55 87. 19 6 12 -3 39.68 40.07 7 12 -3 35. 03 34.34 8 12 -3 15.59 14.84 1 13 -3 5.49* 7.82 2 13 -3 37.88 38.70 3 13 -3 38. 13 39.40 4 13 -3 8.79 7.50 5 13 -3 7.65 8. 25 6 13 -3 22.00 21.05 7 13 -3 17.74 17.88 8 13 -3 0.00* 2.31 1 14 -3 23.35 25.00 2 14 -3 71,63 73.56 3 14 -3 54.93 56.32 4 14 -3 46.79 46.97 5 14 -3 10.25 10.67 6 14 -3 61.49 60.52 7 14 -3 7.93 8.66 1 15 -3 24.35 25.53 2 15 -3 28.86 28.88 3 15 -3 13.90 13.69 4 15 -3 10.36 9.28 5 15 -3 . 12.83 14. 29 6 15 -3 4.83* 6.38 7 15 -3 6.85* 6.27 1 16 -3 75.60 76.69 2 16 -3 20.58 21.96 3 16 -3 28. 60 29.22 4 16 -3 9.77 9.32 5 16 -3 36.23 36.45 6 16 -3 3.39* 1. 32 1 17 -3 36.82 38.30 2 17 -3 17.75 18.32 3 17 -3 17.80 18.56 4 17 -3 2.91* 2.75 5 17 -3 4.65* 3.89 6 17 -3 0.00* 3.54 1 18 -3 4.62* 2.27 2 18 -3 40.71 40.81 3 18 -3 9.64* 9.69 4 18 -3 36.85 37. 14 H K L FO FC 5 18 -3 * 8.69 7.63 1 19 -3 0.00* 3.44 2 19 -3 20.85 21.27 3 19 -3 18.35 19.21 4 19 -3 1.78* 0.69 1 20 -3 36.57 38.08 2 20 -3 1.74* 1. 17 3 20 -3 31.70 33.40 2 0 -2 38.50 33.53 4 0 -2 130.86 144.30 6 0 -2 6.00* 4.37 8 0 -2 100.71 105.44 10 0 -2 26.03 26.83 1 1 -2 29.85 33.47 2 1 -2 56.20 55.60 3 1 -2 64.63 64.69 4 1 -2 6.78 8.37 5 1 -2 25.59 25.28 6 1 -2 4.20* 3.58 7 1 -2 24.30 26.78 8 1 -2 13.80 14.66 9 1 -2 10.79 11.45 10 1 -2 12.30 12.88 1 2 -2 3.75* 7.91 2 2 -2 37.23 37.86 3 2 -2 126.94 156.61 4 2 -2 19.33 19.34 5 2 -2 108.23 113.65 6 2 -2 27.53 28.04 7 2 -2 57.85 58.84 8 2 -2 22.09 21.81 9 2 -2 52.45 56. 10 10 2 -2 3.33* 4.79 1 3 -2 30.84 29.65 2 3 -2 49.06 50. 19 3 3 -2 77.06 70.32 4 3 -2 45.57 44.35 5 3 -2 57.62 57.28 6 3 -2 7.71 7.25 7 3 -2 3.50* 3.46 8 3 -2 32.78 33. 32 9 3 -2 38.31 38.44 10 3 -2 13.52 14.66 1 4 -2 14.22 17. 17 2 4 -2 113.85 134.60 3 4 -2 16.41 15.57 4 4 -2 148. 13 172.79 5 4 -2 46.23 44.28 6 4 -2 115.74 110.33 7 4 -2 12.01 12.24 8 4 -2 75.55 74.49 9 4 -2 1.60* 1. 19 10 4 -2 14.84 15.09 1 5 -2 76. 16 75.25 2 5 -2 69. 15 65.36 3 5 -2 33.96 31.63 4 5 -2 27.65 27.91 5 5 -2 10.71 5.70 H K L FO FC 6 5 -2 34.64 33.0 3 7 5 -2 22.00 21.46 8 5 -2 3.08* 0.56 10 5 -2 4.22* 3.57 1 6 -2 61.31 62.55 2 6 -2 11.42 10.52 3 6 -2 1 12.42 112.92 4 6 -2 48. 12 44.36 5 6 -2 84.24 81.23 6 6 -2 17.38 17.15 7 6 -2 58.55 57. 13 8 6 -2 10.43 9.12 9 6 -2 57. 27 57.04 10 6 -2 7.39* 7.63 1 7 -2 107.99 115.04 2 7 -2 47.31 45.12 3 7 -2 10.11 5.90 4 7 -2 22.67 21.40 c u 7 -2 63.81 58.86 6 7 -2 4.00* 4.57 7 7 -2 21.69 21.42 8 7 -2 5.45* 0.59 9 7 -2 43.69 43.06 1 8 -2 30. 15 30.25 2 8 -2 120.01 128.28 3 8 -2 19.36 17.61 4 8 -2 9.05 4.68 5 8 -2 12.68 12. 13 6 8 -2 42. 12 39.19 7 8 -2 9.54 10.41 8 8 -2 36.23 34.83 9 8 -2 2.27* 1.00 1 9 -2 37.06 34.25 2 9 -2 25.92 26.06 3 9 -2 12.33 11 .67 4 9 -2 13. 28 12.57 5 9 -2 23.44 21.69 6 9 -2 29.37 28.22 7 9 -2 6.40* 7.27 8 9 -2 40.56 38.58 9 9 -2 6. 3 3* 5.04 1 10 -2 104.36 105.37 2 10 -2 22.00 18.87 3 10 -2 102.20 100.84 4 10 -2 47.23 45.77 5 10 -2 38.65 37.65 6 10 -2 49.21 48.88 7 10 -2 43. 13 41.00 8 10 -2 6.7 0* 4.89 9 10 -2 45. 27 43.88 1 11 -2 9.6 2 9.26 2 11 -2 10.47 9.50 3 11 -2 12. 35 8.78 4 1 1 -2 6.67 4.51 5 1 1 -2 31.40 31.53 6 11 -2 21.60 21.31 7 11 -2 43.47 42.91 8 11 -2 0.00* 1 .95 H K L FO FC 9 11 -2 27.59 27.62 1 12 -2 6.41 8.92 2 12 -2 126.65 ( 128.38 3 12 -2 5.88* 3.25 4 12 -2 48.21 46.85 5 12 -2 14.66 14. 14 6 12 -2 92.99 90.60 7 12 -2 12. 18 12.55 8 12 -2 23.67 21.80 1 13 -2 24.21 25.60 2 13 -2 48.31 47.78 3 13 -2 19.79 19. 19 4 13 -2 39.34 38.75 5 13 -2 12.22 11.99 6 13 -2 19.91 20.73 7 13 -2 19.66 18.72 8 13 -2 11.47 10.66 1 14 -2 66. 18 67.31 2 14 -2 53.31 51.55 3 14 -2 49.31 49.48 4 14 -2 4.98* 3.57 5 14 -2 61.88 61.30 6 14 -2 15.65 15.74 7 14 -2 37.09 36.51 1 15 -2 8.56 8.52 2 15 -2 4.52* 5.60 3 15 -2 85. 12 85.83 4 15 -2 9.68 9.07 5 15 -2 5.47* 6. 11 6 15 -2 8.97 7.92 7 15 -2 13.40 12. 13 1 16 -2 46.66 48.08 2 16 -2 56.90 58.00 3 16 -2 19.70 19.95 4 16 -2 32.93 3 2.58 5 16 -2 17. 19 17. 16 6 16 -2 31,43 31. 27 1 17 -2 11.26 12.23 2 17 -2 22. 11 22. 13 3 17 -2 4.29* 3.54 4 17 -2 15. 15 15.45 5 17 -2 3,89* 5.66 6 17 -2 11.45 12. 20 1 18 -2 51.38 51.99 2 18 -2 2.90* 2.88 3 18 -2 42.58 42.92 4 18 -2 3.60* 3.94 5 18 -2 39.43 39.96 1 19 -2 18.43 19. 15 2 19 -2 0.00* 2.31 3 19 -2 17.30 17.78 4 19 -2 13.02 12.83 1 20 -2 3.93* 3.73 2 20 -2 30.79 32. 11 3 20 -2 13.81 14.25 1 21 -2 2.50* 0.43 1 0 -1 0.00* 308.78 5 0 -1 63. 15 65.93 H K L FO FC H K L FO FC 7 0 -1 51.90 55.56 9 6 --I 13.79 14.78 9 0 -1 73.70 77.21 10 6 -1 49.31 49.31 1 1 -1 13.05 11.48 1 7 -1 37.80 36.00 2 1 -1 10.46 6.17 2 7 -1 38.42 34.59 3 1 -1 30.64 34.08 3 7 -1 7.06 10.74 4 1 -1 29.40 24.46 4 7 -1 61.79 55.08 5 1 -1 28. 18 28.60 5 7 -1 46.22 43.57 6 1 -1 40.43 39.62 6 7 -1 8. 10 5.00 7 1 -1 2.58* 0.80 7 7 -1 22.53 22. 16 "8 1 -1 13.04 13.97 8 7 -1 26.97 26.58 9 1 -1 27.85 28.89 9 7 -1 8.78 7.97 1 0 1 -1 13. 38 13.05 10 7 -1 3.73* 1.67 1 2 -1 4.79* 2.92 1 8 -1 127.46 162.08 2 2 -1 96.68 109.38 2 8 -1 55.40 53.66 3 2 - 1 29.83 25.37 3 8 -1 97.77 92.13 5 2 -1 21. 10 22.31 4 8 -1 6.43 6.34 6 2 -1 62. 19 58.91 5 8 -1 40.36 39.04 7 2 -1 10.88 7.64 6 8 -1 14.09 13.49 8 2 -1 106.87 108.22 7 8 - 1 73.58 71.94 9 2 -1 16.48 15.94 8 8 -1 1. 13* 3.64 10 2 -1 28.26 29. 13 9 8 -1 62.09 61.83 1 3 - 1 38.01 37.61 1 9 -1 0.00* 1.21 2 3 -1 60.49 57.66 2 9 - 1 4.46* 4.75 3 3 - 1 109.28 105.04 3 9 -1 33.06 30.08 4 3 -1 38.69 32.38 4 9 -1 15,28 13.82 5 3 - 1 54.45 50.17 5 9 -1 44. 11 42.41 6 3 -1 23.09 22.59 6 9 -1 7.60 8.31 7 3 - 1 7.85 4.52 7 9 -1 3,92* 2,22 8 3 -1 18.41 16.77 8 9 -1 5.71* 3.97 9 3 -1 9.38 8.30 9 9 -1 23.95 22.77 10 3 -1 12.79 12.90 1 10 -1 49. 13 47.31 1 4 - 1 78.88 78.00 2 10 -1 121.76 123. 32 2 4 -1 46.78 45.05 3 10 -1 12.90 11.37 4 4 -1 49.01 45.67 4 10 -1 40.81 38.57 5 4 -1 167. 14 194.00 5 10 -1 23.61 24.22 6 4 - 1 4.68* 0.28 6 10 -1 112.35 110.29 7 4 -1 94.55 90. 14 7 10 -1 20,92 21.24 8 4 - 1 9.01 8.96 8 10 -1 44.59 42.89 9 4 -1 67.75 65.96 9 10 -1 25.45 25. 33 10 4 -1 3.64* 1.50 1 11 -1 24.40 22.55 1 5 - 1 92.56 97.59 2 11 -1 16.78 16.40 2 5 -1 49.43 45. 18 3 11 -1 13.00 10.33 3 5 - 1 35. 31 30.06 4 11 -1 26.51 24.72 4 5 -1 10.56 10.69 5 11 -1 15.68 15.51 5 5 -1 100.90 93. 36 6 11 -1 23.88 22.36 6 5 -1 4.64* 4.48 7 11 -1 2.45* 3.96 7 5 -1 42.68 41.64 8 11 -1 26.37 26.31 8 5 - 1 15.73 15.80 9 11 -1 5.92* 5. 12 9 5 -1 17.09 16.38 1 12 -1 59.93 59.73 10 5 -1 9.14 9.06 2 12 -1 50.36 45. 12 1 6 - 1 53.80 58.03 3 12 -1 77.33 73.04 2 6 -1 125.99 168.29 4 12 - 1 8. 14 7.61 3 6 -1 80.68 74.17 5 12 -1 108.08 106,08 4 6 -1 113,38 109.19 6 12 - 1 58.75 57.25 5 6 -1 12.37 9.44 7 12 -1 74.94 72.74 6 6 -1 117.40 113.39 8 12 -1 13.24 12.79 7 6 -1 6.52* 6.27 1 13 -1 9.89 10.53 8 6 -1 82. 31 80. 16 2 13 -1 26.03 26.22 H K L FO FC 3 13 - •) 62.81 63.69 4 13 -1 12.60 11.56 5 13 - 1 0.00* 4.53 6 13 -1 26. 35 26.65 7 13 -1 12.27 13. 27 8 13 - 1 5.68* 5.55 1 14 -1 18.55 16. 86 2 14 - 1 77.43 76.73 3 14 -1 21. 12 22.26 4 14 -1 38. 25 37.40 5 14 - 1 26.53 25.97 6 14 -1 71.52 69. 13 7 14 - 1 25.32 25.95 8 14 -1 35.61 35.66 1 15 - 1 17.06 16.75 2 15 -1 53.57 52.87 3 15 - 1 7.86 7.61 4 15 -1 24. 18 24.41 5 15 -1 7. 15 6.51 6 15 -1 11. 20 11.02 7 15 - 1 13.32 13.31 1 16 -1 81.37 82. 19 2 16 - 1 23.66 23.07 3 16 - 1 42.94 42.88 4 16 - 1 0.41* 0.87 5 16 -1 , 26.71 26.37 6 16 - 1 14.19 15.54 7 16 - 1 28. 23 28.56 1 17 - 1 4.76* 6.92 2 17 -1 0.00* 1.50 3 17 - 1 28.92 29.61 4 17 -1 5.35* 4.00 5 17 -1 27.68 27.38 6 17 - 1 3.75* 4.62 1 18 - 1 21.90 21.82 2 18 -1 53.84 55.01 3 18 - 1 2.03* 1.41 4 18 -1 43.93 45.52 5 18 - 1 10.28 10.25 1 19 -1 0.70* 6.34 2 19 -1 6.69* 8.09 3 19 -1 4.08* 3.99 4 19 -1 11. 11 11.89 1 20 - 1 28.99 30.45 2 20 -1 2.70* 3.40 3 20 - 1 42.29 42.93 1 21 -1 10.8 3 11.27 2 21 - 1 7 .36* 7.44 6 0 0 8.97* 13.57 8 0 0 131.75 128.68 10 0 0 49.22 50.82 1 1 0 0.00* 3.79 2 1 0 91.35 105.83 3 1 0 59.02 52.00 4 1 0 64.37 57.83 5 1 0 14.85 11 .24 6 1 0 6.4 5* 7. 14 7 1 0 21.94 22.01 H K L FO FC 8 1 0 18.41 17.43 9 1 0 7. 13* 3.68 10 1 0 18.74 18.55 0 2 0 4.87* 1.35 1 2 0 0.00* 286.24 2 2 0 52.25 45.85 4 2 0 23. 13 20.00 5 2 0 113.46 107.91 6 2 0 0.00* 1.20 7 2 0 105.10 100.02 8 2 0 29.81 27. 15 9 2 0 77.78 75.41 10 2 0 4.72* 8.34 1 3 0 58.33 60.13 2 3 0 0.00* 3.70 3 3 0 87.74 84. 16 4 3 0 26.81 27.27 5 3 0 34.04 32.03 6 3 0 42.70 40.45 7 3 0 0.00* 2.85 8 3 0 10.34* 9.25 9 3 0 38.84 37.93 10 3 0 0.00* 0.43 0 4 0 0.00* 204.15 1 4 0 84.95 97.30 2 4 0 93.58 90.71 3 4 0 56.95 56.76 4 4 0 144.11 167. 14 5 4 0 12.82 12.57 6 4 0 143.83 140.44 7 4 0 16.48 15.75 8 4 0 1 11.63 106.85 9 4 0 16.23 15.74 10 4 0 25.21 24.71 1 5 0 87.37 88.77 2 5 0 71.83 67.49 3 5 0 1.72* 2.58 4 5 0 41. 10 39.06 5 5 0 43.50 42.31 6 5 0 0.00* 1.87 7 5 0 57.78 54.60 8 5 0 30.66 29.72 9 5 0 9.36 9.87 10 5 0 0.00* 0.96 0 6 0 83.76 103.25 2 6 0 20.69 17.32 3 6 0 134.47 159.23 4 6 0 28.94 24.65 5 6 0 130.85 124.77 6 6 0 0.00* 0.59 7 6 0 95.85 92.39 8 6 0 16.75 16.33 9 6 0 52.37 51.43 10 6 0 13.69 13.00 1 7 0 99.78 110.68 2 7 0 41.34 28.20 3 7 0 3.41* 5.61 4 7 0 13.22 9.77 H K L FO FC 5 7 0 35,4 8 36.63 6 7 0 16,37* 15.95 7 7 0 78.75 76.22 8 7 0 24.46 24.42 9 7 0 8.7 4 1 .82 10 7 0 11.95* 11.50 1 8 0 38.68 38.17 2 8 0 133.99 158.30 3 8 0 42.48 41.42 4 8 0 75.51 70.53 5 8 0 9.56 9.69 6 8 0 87.55 83.20 7 8 0 15.89 15. 30 8 8 0 37.67 33.94 9 8 0 11.29* 12. 13 1 9 0 30.88 27.37 2 9 0 10.48* 4.92 3 9 0 55.59 51.75 9 0 11.06 10.69 5 9 0 0. 00* 2.57 6 9 0 21.79 21.66 7 9 0 3.89* 2.64 8 9 0 3.57* 1 .37 9 9 0 6.95* 3.47 0 10 0 11.55* 13.36 1 10 0 90, 19 88.41 2 10 0 105.57 101.79 3 10 0 117.30 112.58 10 0 6.36* 4.41 5 10 0 85.20 81. 25 6 10 0 51.18 49.03 7 10 0 77. 14 74.69 8 10 0 11.88 11.98 9 10 0 30.26 31 .65 1 1 1 0 3. 20* 4.73 2 11 0 33.80 36.46 3 1 1 0 37.86 37.06 4 11 0 24.21 23. 18 5 1 1 0 7.35* 6.78 6 11 0 0.00* 2.55 7 1 1 0 5.69* 6.25 8 1 1 0 4.98* 4. 34 9 11 0 9. 25 8.72 0 12 0 0.00* 5.02 1 12 0 4,08* 7.62 2 12 0 104.09 101.94 3 12 0 40. 11 40.35 4 12 0 76.90 75.26 c; ~j 12 0 59.97 57.21 6 12 0 127.52 123.80 7 12 0 27.15 26.09 8 12 0 26. 32 26. 39 1 13 0 0.00* 2.79 2 13 0 0.00* 8.34 3 13 0 28.77 29.49 4 13 0 10.15* 11.68 5 13 0 0.00* 2.15 6 13 0 15.35 15.61 H K L ,F0 FC 7 13 0 4. 36* 4, 18 8 13 0 9. 15* 9. 21 0 14 0 27.71 26.09 1 14 0 51.67 51.10 2 14 0 29.24 28.94 3 14 0 59.26 57.77 4 14 0 29.51 30.51 5 14 0 66.95 63.77 6 14 0 45.06 44.00 7 14 0 45.95 46. 19 8 14 0 3.36* 0.33 1 15 0 24.33 25.44 2 15 0 15.94 18.08 3 15 0 46. 19 48.56 4 15 0 8.98* 8.48 5 15 0 22. 15 21.09 6 15 0 3.22* 2. 15 7 15 0 8.52 9. 16 0 16 0 87.43 87.41 1 16 0 27.80 26.98 2 16 0 61.63 61.32 3 16 0 34.36 35.31 4 16 0 32.97 32. 14 5 16 0 20.43 19.89 6 16 0 22.64 21.75 7 16 0 6.23* 5.86 1 17 0 0.00* 0.70 2 17 0 25. 11 24.64 3 17 0 15.39 15.53 4 17 0 17.53 17.35 5 17 0 9. 13* 9.57 6 17 0 • 0.00* 0.56 0 18 0 26. 15 24.92 1 18 0 61.52 62.34 2 18 0 16.23 16.63 3 18 0 42. 10 43.61 4 18 0 23.06 23.93 5 18 0 17.56 17.52 1 19 0 37.56 37.94 2 19 0 0.00* 0.29 3 19 0 25.50 27.22 4 19 0 2.58* 0.81 0 20 0 26.05 28.05 1 20 0 0.00* 0.55 2 20 0 23.76 25.49 3 20 0 13.55 14.59 1 21 0 9.38* 9.95 2 21 0 0.00* ,1.45 1 0 1 0.00* 235.74 3 0 1 1 19.89 159.21 5 0 1 48.28 49.84 7 0 1 51.31 52.26 9 0 1 44.61 47.91 0 1 1 45.08 39.08 1 1 1 26.08 23.30 2 1 1 67. 18 64.80 3 1 1 108.72 11 1.99 4 1 1 60.08 61.40 H K L , FO FC 5 1 1 9.18 8.49 6 1 1 "46.09 45.06 7 1 1 3.62* 2.58 8 1 1 14.39 13.53 9 1 1 16.04 15.67 10 1 1 9.82 9. 26 0 2 1 0.00* 271.73 1 2 1 52.05 49.55 2 2 1 27.68 3.82 3 2 1 47.40 45.34 4 2 1 133.86 142.76 5 2 1 20,47 16.94 6 2 1 53.46 52.42 7 2 1 10.46 6.26 8 2 1 98.53 95.25 9 2 1 7.94* 9.19 10 2 1 17.74 18.49 0 3 1 5.36 2.72 1 3 1 4.33 1.33 2 3 1 57.38 50.94 3 3 1 109.57 107.67 4 3 1 79.07 70.98 5 3 1 39.46 34.46 6 3 1 19.01 16.44 7 3 1 28.62 27.90 8 3 1 23.18 21.07 9 3 1 24.97 24.01 10 3 1 16.54 16.56 0 4 1 24.25 25.63 1 4 1 12.91 9.89 2 4 1 26.16 26.03 3 4 1 71.41 67.06 4 4 1 13.43 8.38 5 4 1 152.72 160.70 6 4 1 23,95 23.24 7 4 1 89.54 85.03 8 4 1 26.68 26.55 9 4 1 50.70 49.98 10 4 1 9.42 9.96 0 5 1 24.59 23.45 1 5 1 102.51 132.30 2 5 1 48.09 43.31 3 5 1 88.91 85.45 4 5 1 14.79 12.93 5 5 1 46.96 42.18 6 5 1 25.42 23.77 7 5 1 43.19 41.04 8 5 1 13.75 13. 36 9 5 1 23.56 22.37 ,10 5 1 3.05* 0.92 0 6 1 107.82 153.11 1 6 1 75.81 72.20 2 6 1 125.92 173.72 3 6 1 13.47 12.44 4 6 1 107.42, 104.63 5 6 1 2.08* 0.95 6 6 1 86.47 83.70 7 6 1 40.68 41.07 H K I FO FC 8 6 1 47.40 44.26 9 6 1 13.35 12.84 10 6 1 40.90 40.49 0 7 1 30.99 25. 15 1 7 1 1.92* 1.21 2 7 1 38.02 39.03 3 7 1 3.05* 2.93 4 7 1 32.82 30.65 5 7 1 4.63* 6.76 6 7 1 18.55 16.61 7 7 1 25.94 25.33 8 7 1 17.25 17.44 9 7 1 10.54 11.21 0 8 1 15.51 15.74 2 8 1 8.75 8.01 3 8 1 135.25 143.44 4 8 1 27.99 28.11 5 8 1 30.43 28.68 6 8 1 23.34 23.55 7 8 1 32.07 30.47 8 8 1 3.00* 0.59 9 8 1 34.72 34.93 0 9 1 30.02 27.51 1 9 1 48.34 44.88 2 9 1 25.50 22. 16 3 9 1 114.31 111.10 4 9 1 41.84 40.05 5 9 1 9.21 6.94 6 9 1 6.51 7.89 7 9 1 15.67 15.07 8 9 1 18.62 19. 14 9 9 1 30.26 31.43 0 10 1 90.83 83.57 1 10 1 30.00 31.04 2 10 1 140.08 152.83 3 10 1 37.08 33.40 4 10 1 48.11 47.44 5 10 1 23.74 23.05 6 10 1 76.98 75.61 7 10 1 8.41 7.26 8 10 1 13.66 11.92 9 10 1 7.57 7.47 0 11 1 11.12 11.92 1 11 1 45.97 40.81 2 11 1 68.36 63. 10 3 11 1 15.45 15.62 4 11 1 62.29 62. 19 5 11 1 0.00* 0.53 6 11 1 24.47 24.29 7 11 1 0.00* 2. 10 8 11 1 22.76 23.7 3 9 11 1 9.07 11.30 0 12 1 33.17 30.81 1 12 1 64.80 62.23 2 12 1 77.37 71.82 3 12 1 100.00 95.20 4 12 1 2.63* 1.08 5 12 1 90.74 89,72 H K L FO FC 6 12 <\ 49.65 48.09 7 12 1 59.84 57. 19 8 12 1 1.92* 3.69 0 13 1 49.30 46.75 1 13 1 34.46 34.26 2 13 1 0.00* 3.95 3 13 1 0.00* 0.99 4 13 1 11.98 10.54 5 13 1 26.49 26.01 6 13 1 0.83* 3.32 7 13 1 2.47* 1.03 8 13 1 19.22 20. 14 0 14 1 36.54 34.20 1 14 1 13. 54 14.49 2 14 1 97. 10 95.43 3 14 1 32.01 32.82 4 14 1 54. 10 54.78 5 14 1 21.34 21.30 6 14 1 65.45 63. 48 7 14 1 5.11* 5.86 0 15 1 29. 17 30.07 1 15 1 0.00* 0.51 2 15 1 10.06 13.20 3 15 1 0.00* 1.58 a 15 1 21.37 20.3 1 5 15 1 9.67 8.00 6 15 1 10.20 10.59 7 15 1 5.88* 6.83 0 16 1 51.52 52.15 1 16 1 73.24 72. 13 2 16 1 56.59 55.73 3 16 1 59.88 59.36 4 16 1 11.16 10. 10 5 16 1 21.87 21 .58 6 16 1 2.07* 1.41 7 16 1 34.04 34.26 0 17 1 0.00* 4. 32 1 17 1 60.41 59.29 2 17 1 0.57* 1 .48 3 17 1 0.00* 0.43 4 17 1 0.00* 0.95 5 17 1 25.89 26.02 6 17 1 4.65* 5.60 0 18 1 61.57 61.95 1 18 1 37.92 39.09 2 18 1 35. 14 34.83 3 18 1 28.63 27.33 4 18 1 38.09 39.13 5 18 1 18.60 18.56 0 19 1 20.51 20.43 1 19 1 4.46* 4.71 2 19 1 37.39 38.67 3 19 1 10.74 11.89 4 1 9 1 19.25 20.49 0 20 1 10.64 11.27 1 20 1 9.62 10. 19 20 1 0.00* 1 .05 3 20 1 24.75 26.35 H K I FC FC 0 21 1 11.00 1 1.81 1 21 1 13.56 13.72 2 21 1 4.55* 2.49 0 0 2 0.00* 232. 16 2 0 2 59.67 59.39 6 0 2 47.35 47.03 8 0 2 49.89 52.34 10 0 2 13.99 14. 17 0 1 2 9.24 13.42 1 1 2 43.66 47.85 2 1 2 2.31* 5.44 3 1 2 106.79 109. 15 4 1 2 47.50 44.61 5 1 2 11.53 10.88 6 1 2 2. 14* 0.29 7 1 2 12.72 13. 19 8 1 2 5.60* 2.68 9 1 2 21.20 23.09 10 1 2 12.09 12.69 0 2 2 67.23 75.81 1 2 2 68.70 72.73 2 2 2 22.50 21.02 3 2 2 89.77 89.41 4 2 2 12.83 12. 15 5 2 2 113.67 108.20 6 2 2 3.59* 6.25 7 2 2 29.08 28.81 8 2 2 1.94* 0.92 9 2 2 34.58 34.49 10 2 2 10.89 12. 17 0 3 2 55.38 60.22 1 3 2 45.28 44.44 2 3 2 80.24 77.75 3 3 2 103.55 102. 13 4 3 2 41.20 36.81 5 3 2 19.94 17.32 6 3 2 5.04* 1.34 7 3 2 18.00 15.80 8 3 2 23.83 23.70 9 3 2 29.95 29.88 10 3 2 2.92* 2.08 0 4 2 40.80 43.01 1 4 2 48.96 48.89 2 4 2 46.48 40.55 3 4 2 46.27 45.50 4 4 2 127.40 128.44 5 4 2 20.36 20.31 6 4 2 73.48 72.24 7 4 2 14.15 12.97 8 4 2 81.04 79.27 9 4 2 23.45 24.26 10 4 2 16.01 14.70 0 5 2 62.83 57.39 1 5 2 3.38* 0.23 2 5 2 15.77 12.04 3 5 2 44.44 38.09 4 5 2 6.93 4. 36 5 5 2 54.61 49. 11 I H K L FO FC 6 5 2 22.74 22.21 7 5 2 4.01* 4.06 8 5 2 12.36 13.63 9 5 2 9. 18 7.98 10 5 2 6.47* 6.79 0 6 2 45.81 43.48 1 6 2 101.05 102.86 2 6 2 16.20 11.08 3 6 2 75.68 71.07 4 6 2 33.41 31.25 5 6 2 95.60 89.23 6 6 2 12. 33 12. 19 7 6 2 41.29 39.64 8 6 2 2. 13* 0. 16 9 6 2 42.03 42.45 10 6 2 7.21* 9. 13 0 7 2 42.40 43. 32 1 7 2 8.55 8.89 2 7 2 28. 15 25.16 3 7 2 53.90 51.27 4 7 2 2.85* 3.33 5 7 2 71.27 65.36 6 7 2 9.52 9.52 7 7 2 30.00 30.00 8 7 2 15.75 15.86 9 7 2 5.68* 5.13 0 8 2 111.98 120.91 1 8 2 8.83 6.92 2 8 2 129.33 141.88 3 8 2 36.03 33. 39 4 8 2 25.18 24.79 5 8 2 13.87 12.53 6 8 2 22.70 22.10 7 8 2 8.54 8.91 8 8 2 24.84 23.6C 9 8 2 19. 25 19. 13 0 9 2 48.15 44.64 1 9 2 19.86 18.86 2 9 2 65.39 62.42 3 9 2 7.95 5.03 4 9 2 33.88 33.49 5 9 2 23.70 21. 17 6 9 2 5.98* 7.07 7 9 2 0.79* 1.72 8 9 2 19.91 18. 72 9 9 2 9.50 8. 26 0 10 2 31.08 29.88 1 10 2 91. 11 90.63 2 10 2 74.08 66.89 3 10 2 50.70 47.97 4 10 2 25.51 25.84 5 10 2 25,61 26.70 6 10 2 21.28 21.93 7 10 2 48. 27 47.07 8 10 2 14.25 14.63 9 10 2 44. 17 45.36 0 11 2 18.47 18.78 1 1 1 2 48. 10 45.52 H K L FO FC 2 11 2 41.08 40.98 3 11 2 87.08 83.71 4 1 1 2 20. 12 19.09 5 11 2 18. 24 16.99 6 11 2 10.82 11.28 7 11 2 8.54 8.54 8 11 2 6.85* 7. 12 0 12 2 9.42 11.63 1 12 2 3.06* 1. 12 2 12 2 86.53 83.91 3 12 2 3.89* 4.54 4 12 2 32.58 32.92 5 12 2 18.67 18.67 6 12 2 91.37 88.15 7 12 2 15.32 14.96 8 12 2 44. 14 44. 29 0 13 2 27.65 25.28 1 13 2 14.36 13.42 2 13 2 2.63* 4.34 3 13 2 15.65 14.05 4 13 2 7.08 8.20 5 13 2 7. 16 7.84 6 13 2 14.05 13.55 7 13 2 5.68* 4.93 8 13 2 5. 15* 5.32 0 14 2 21.55 23.45 1 14 2 59.38 61.61 2 14 2 16.27 15.64 3 14 2 64.64 63. 13 4 14 2 30.41 30.94 5 14 2 57. 13 57. 27 6 14 2 20.82 21.96 7 14 2 50.08 50. 12 0 15 2 12.22 12.90 1 15 2 27.02 27.23 2 15 2 43.88 42.42 3 15 2 57. 19 57.97 4 15 2 4.36* 5.24 5 15 2 11.48 1 1.91 6 15 2 0.00* 1.04 7 15 2 0.00* 3.93 0 16 2 76.33 76.28 1 16 2 46.82 46.98 2 16 2 72.03 72.30 3 16 2 0.99* 2.53 4 16 2 46.54 47.57 5 16 2 7.04 8.01 6 16 2 23.04 23.00 0 17 2 14.54 14.07 1 17 2 27.65 27.79 2 17 2 9.02 7.54 3 17 2 5.83* 7.63 4 17 2 14.32 13.92 5 17 2 5.35* 5.80 6 17 2 17.49 18.05 0 18 2 36.24 36.70 1 18 2 45.99 46.46 2 18 2 21.80 21.80 H K L FO FC 3 18 2 55,60 54.87 4 18 2 9.26 7.84 5 18 2 30.54 29.92 0 19 2 0.00* 3.35 1 19 2 19.18 18.57 2 19 2 0.00* 1.39 3 19 2 13.44 13.76 4 19 2 0.00* 0.59 0 20 2 18.58 18.74 1 20 2 2.77* 4.24 2 20 2 28. 39 27.93 3 20 2 0.00* 1.62 0 21 2 0.00* 2.00 1 21 2 0.00* 1.67 3 0 3 1 13.56 117.76 5 0 3 18.39 20.32 7 0 3 7.95 9.83 9 0 3 36. 17 38.03 0 1 3 84.54 108.69 1 1 3 68.67 72.74 2 1 3 21,88 20.77 3 1 3 48.15 53.6 2 4 1 3 57.97 57.92 5 1 3 28.44 26.44 6 1 3 2.06* 1 .09 7 1 3 21.71 22.47 8 1 3 26.78 27.76 9 1 3 8.39 8.17 10 1 3 3.96* 5.33 1 2 3 23.64 21.15 2 2 3 69.42 64.58 3 2 3 34.25 32. 25 4 2 3 117.20 118.98 5 2 3 3.02* 0.56 6 2 3 3.3 0* 3.06 7 2 3 14.50 14.08 8 2 3 79.41 80.30 9 2 3 9.50 9.62 10 2 3 30.66 32.15 0 3 3 0.00* 8.06 1 3 3 1C0.06 117.35 2 3 3 14.72 10. 19 3 3 3 36,00 34.35 4 3 3 56.55 52.31 5 3 3 77.68 75.98 6 3 3 7.80 6.79 7 3 3 13.90 14.44 8 3 3 16.46 15.83 9 3 3 25.29 26.04 10 3 3 13.45 14.70 0 4 3 10.45 5.16 1 4 3 52.45 53.53 2 4 3 16.48 15.75 3 4 3 27.11 27.67 4 4 3 6.63 7.24 5 4 3 116.34 111.56 6 4 3 29.15 29.61 7 4 3 74.04 71.93 fi K I FO FC 8 4 3 4.83* 5.62 9 4 3 57.88 57.77 10 4 3 1.82* 2.07 0 5 3 32.82 29.05 1 5 3 9.28 7.36 2 5 3 26.54 24. 19 3 5 3 27.05 24.60 4 5 3 89.80 86.51 5 5 3 57.67 53.27 6 5 3 38.47 36.71 7 5 3 48.90 48.90 8 5 3 10.50 9.56 9 5 3 4.06* 0.39 0 6 3 29.03 29.62 1 6 3 13.21 11.55 2 6 3 88.87 85.64 3 6 3 42.23 42. 10 4 6 3 75.61 72.22 5 6 3 54.59 51.21 6 6 3 70.81 67.05 7 6 3 20.77 21.06 8 6 3 56.00 54.87 9 6 3 13. 15 14.40 0 7 3 85.52 84.04 1 7 3 69.49 69. 10 2 7 3 49.96 43.64 3 7 3 33. 17 31.83 4 7 3 61.12 60.03 5 7 3 4 4.65 43. 15 6 7 3 24.04 22.38 7 7 3 14.91 14.59 8 7 3 33.91 35.33 9 7 3 7.52 7.50 0 8 3 48.71 43.30 1 8 3 106.48 108.96 2 8 3 42.91 42.05 3 8 3 82.68 82.55 4 8 3 18.36 17.79 5 8 3 45.70 43.85 6 8 3 17.04 17.06 7 8 3 47.63 45.72 8 8 3 11.57 11.38 9 8 3 30.91 30.67 0 9 3 62.86 61.31 1 9 3 2. 17* 1.06 2 9 3 72.71 66. 29 3 9 3 18.68 17.81 4 9 3 4.56* 2.43 5 9 3 35.58 34.73 6 9 3 26.54 25.60 7 9 3 20.21 21.00 8 9 3 8.94 7.74 9 9 3 15.77 15.95 0 10 3 53.03 53.96 1 10 3 6.70 7.02 2 10 3 79.42 78.33 3 10 3 24.52 23.46 4 10 3 28.84 28.25 H K L FO FC 5 10 3 3,92* 1.51 6 10 3 82.02 79.64 7 10 3 5.03* 0.65 8 10 3 35.22 34. 68 9 10 3 9.40 10.73 0 1 1 3 6. 8 9 4.92 1 11 3 30. 28 29.98 2 11 3 13.67 14.08 3 11 3 10.44 1 1.97 4 1 1 3 6.89 6.06 5 11 3 8.47 9.91 6 1 1 3 10.62 10.79 7 11 3 31. 25 30.69 8 1 1 3 11.98 11.61 0 12 3 53.75 53.20 1 12 3 12.18 11.45 2 12 3 14.97 14.51 3 12 3 41.37 41 .06 4 12 3 16.53 16.03 5 12 3 81.20 78.28 6 12 3 38.50 37.98 7 12 3 83.31 80.07 8 12 3 3.22* 1.23 0 13 3 10.34 8.37 1 13 3 10.48 13.06 2 1 3 3 11. 17 12. 17 3 13 3 44.73 46.17 4 13 3 6.05* 4.45 5 13 3 0.00* 1.03 6 13 3 26.33 24.98 7 13 3 10.21 12.26 8 13 ' 3 11. 10 11.32 0 14 3 28.46 29.63 1 14 3 11.29 11.41 2 14 3 69.71 69.02 3 14 3 13.82 14.56 4 14 3 58.99 57.14 5 14 3 9.49 9.47 6 14 3 68.37 66.35 7 14 3 23. 26 22.62 0 15 3 7.90 8.01 1 15 3 39.99 38. 34 2 15 3 18.34 17.51 3 15 3 7.09* 9.82 4 15 3 26.57 26.98 5 15 3 9. 20 8. 86 6 1 5 3 2.49* 7.42 7 15 3 6.92* 7.62 0 16 3 23.37 22.43 1 16 3 72.40 73. 30 2 16 3 8. 14 8.04 3 16 3 74.63 74.75 4 16 3 0.80* 1.85 5 16 3 18.46 18.12 6 16 3 9. 31 9.46 0 1 7 3 33.30 32.97 1 17 3 28.74 29.86 2 17 3 24.88 25.41 H K L FO FC 3 17 3 0.00* 3.80 4 17 3 5. 13* 4.20 5 17 3 28.66 29.73 0 18 3 69.27 69.55 1 18 3 15.37 15.54 2 18 3 49.88 49. 24 3 18 3 9.45* 10.79 4 18 3 38.90 39.01 5 18 3 21.28 21.61 0 19 3 19.93 20.83 1 19 3 9.00 9.75 2 19 3 '17.46 18. 11 3 19 3 0.00* 0.99 4 19 3 20.81 21.03 0 .20 3 10.56 10.68 1 20 3 36.20 35.72 2 20 3 8. 19 8.77 2 0 4 91.33 88.71 4 0 4 103.61 104.19 6 0 4 28.59 30.35 8 0 4 80.48 86.06 10 0 4 38. 36 41.80 0 1 4 71.44 74.61 1 1 4 108.58 149.24 2 1 4 26.53 25.50 3 1 4 28.87 28. 13 4 1 4 82.16 82.20 5 1 4 10.95 10,94 6 1 4 5.98 5. 15 7 1 4 2.04* 1.48 8 1 4 15.65 15. 14 9 1 4 32.55 34.95 10 1 4 3,59* 0.81 0 2 4 6. 18 7.36 1 2 4 110.60 143.58 2 2 4 42.88 40.38 3 2 4 61.94 61.21 4 2 4 25.30 25.27 5 2 4 94.97 96.08 6 2 4 1.79* 0.71 7 2 4 80.01 82. 18 8 2 4 10.43 11.03 9 2 4 68.41 71. 17 10 2 4 5.07* 5.85 0 3 4 70.26 71.99 1 3 4 45.00 42.55 2 3 4 42.08 38.87 3 3 4 75.82 71.48 4 3 4 55.89 54.86 5 3 4 31.60 32.61 6 3 4 2.54* 1.13 7 3 4 44.86 45.00 8 3 4 33.27 33.91 9 3 4 8.24 9,51 0 4 4 99.24 105. 12 1 4 4 66.76 61.80 2 4 4 74.20 70.82 3 4 4 2.36* 4.44 H K L FO FC 4 4 4 73.85 73.51 5 4 4 24.99 23.63 6 4 4 106.98 105.17 7 4 4 35.04 35.49 8 4 4 97.70 96.60 9 4 4 0.00* 0.26 0 5 4 9.07 5.81 1 5 4 67.36 64.33 2 5 4 38.65 36.70 3 5 4 17. 17 17.77 4 5 4 24.98 24.41 5 5 4 56.14 54.3 9 6 5 4 16.05 16.75 7 5 4 16.02 16.37 8 5 4 36.68 36.06 9. 5 4 19.86 20.13 0 6 4 54.08 51. 10 1 6 4 83.48 80.95 2 6 4 49.7 1 45. 12 3 6 4 79.77 76.26 4 6 4 29.55 28. 14 5 6 4 109.54 108.33 6 6 4 8.73 9.24 7 6 4 65.88 64.83 8 6 4 31.61 32.40 9 6 4 49.33 49.25 0 7 4 50.44 50. 19 1 7 4 42.38 41 .76 2 7 4 78. 21 76. 36 3 7 4 7.29 7.97 ii 7 4 54.22 53. 15 5 7 4 26.44 23.92 6 7 4 34.47 32.79 7 7 4 44.99 44.52 8 7 4 5.09* 2.66 9 7 4 3,80* 3.39 0 8 4 111.96 111.56 1 8 4 0.00* 1.97 2 8 4 149.07 169. 1 1 3 8 4 27.49 26.36 4 8 4 82.21 78.00 5 8 4 26.62 26.77 6 8 4 73.12 72.93 7 8 4 27.90 27.85 8 8 4 15.20 15. 11 9 8 4 3.09* 2.52 0 9 4 11.86 12.01 1 9 4 74.34 69.80 2 9 - 4 0.00* 3.76 3 9 4 59.49 58,13 4 9 4 33.08 30.76 5 9 4 21.38 21.27 6 9 4 26.99 27.09 7 9 4 30.66 30.26 8 9 4 8.39 4.99 9 9 4 14.38 14. 17 0 10 4 48.90 48.08 1 10 4 96.36 92.97 H K L FC FC 2 10 4 53.91 51.48 3 10 4 101.80 100.99 4 10 4 10.58 9.96 5 10 4 67.08 66. 11 6 10 4 25.57 25.22 7 10 4 48.89 47.61 8 10 4 6.51* 6.63 0 11 4 4.35* 1.30 1 11 4 28.36 30.85 2 11 4 26.54 25.64 3 11 4 27.12 26.95 4 11 4 10.71 10.68 5 11 4 31.12 30.90 6 11 4 58.66 57. 16 7 11 4 13.11 13.60 8 11 4 9.82 9.51 0 12 4 3.90* 1.42 1 12 4 12.77 11.50 2 12 4 73.82 72.21 3 12 4 21.25 20. 12 4 12 4 47.63 45.71 5 12 4 33. 13 32.95 6 12 ' 4 89.41 87.99 7 12 4 19.03 20.50 8 12 4 35.85 34.67 0 13 4 10. 19 9. 19 1 13 4 9.76 8.27 2 13 4 13.67 13.67 3 13 4 12.11 11.81 4 13 4 23.78 24. 13 5 13 4 40.73 41.19 6 13 4 0.00* 1.21 7 13 4 38.24 38.17 0 14 4 3.21* 0.21 1 14 4 35.91 3 5.89 2 14 4 27.74 27.9 3 3 14 4 76.08 74.46 4 14 4 0.00* 4.92 5 14 4 54.68 53.61 6 14 4 23.08 23.44 7 14 4 47.35 46.88 0 15 4 23.64 22.91 1 15 4 36.65 36.79 2 15 4 30. 15 30.86 3 15 4 39.29 40. 10 4 15 4 27.87 27.80 5 15 4 0.00* 4.02 6 15 4 30.44 31.22 0 16 4 71.33 70.24 1 16 4 24.81 25. 17 2 16 4 66.26 66.22 3 16 4 23.52 24.40 4 16 4 43.24 42. 19 5 16 4 17.64 17.22 6 16 4 22.58 21.87 0 17 4 0.00* 0.72 1 17 4 35.92 35.29 2 17 4 19.36 19.55 H K L FO • FC 3 17 4 21. 35 21.84 4 17 4 0.00* 3. 1 1 5 17 4 13.92 13.29 0 18 4 0.00* 3.26 1 18 4 37.57 36.93 2 18 4 24.73 24.38 3 18 4 36.21 36.96 4 18 4 32. 17 33.61 0 19 4 18,94 19.09 1 19 4 9.73 9.86 19 4 '6.30* 6.88 3 19 4 5. 18* 6.70 0 20 4 35.44 35.92 1 20 4 4.88* 5.15 2 20 4 12.88 12.78 1 0 5 1 18.65 148.10 3 0 5 125.0 3 136.50 5 0 5 127.17 134.44 7 0 5 60.54 63.97 0 1 5 97.03 106.08 1 1 5 35. 11 35. 13 2 1 5 39. 19 42.58 3 1 5 68.56 70.97 4 1 5 32.83 34.30 5 1 5 25.59 24. 27 6 1 5 6.68 8.16 7 .1 5 13.00 13. 56 8 1 5 34,33 35.88 9 1 5 14.02 15.28 1 2 5 7.90 7.14 2 2 5 96.42 99. 34 3 2 5 59.33 59.13 4 2 5 144.88 156.31 5 2 5 42.98 43.67 6 2 5 80.85 82.69 7 2 5 22.21 21.99 8 2 5 77.04 79.40 9 2 5 12.62 14.10 0 3 5 5. 1 1 1. 18 1 3 5 76.38 76.43 2 3 5 37. 27 32.26 3 3 5 28.82 27.77 4 3 5 89.91 86.58 5 3 5 40.40 39.38 6 3 5 31.44 30.77 7 3 5 21.13 21.90 8 3 5 24.22 25.40 9 3 5 45.52 49.15 0 4 5 21.03 19.99 1 4 5 97.88 102.06 2 4 5 27.52 27.34 3 4 5 63.07 61 .69 4 4 5 39.83 38.55 5 4 5 135.83 138.70 6 4 5 21.51 21. 17 7 4 5 79.29 79.62 8 4 5 26. 10 27,09 9 4 5 63.35 65.79 H K L FO IC 0 5 5 18.92* 20.91 1 5 5 19.06 21.03 2 5 5 16.27 17.47 3 5 5 70.96 67.93 4 5 5 30.73 28.56 5 5 5 12.96* 13.16 6 5 5 38.91 39. 18 7 5 5 25.76 26.60 8 5 5 25. 11 25.63 9 5 5 5.92* 5.95 0 6 5 83.06 80.04 1 6 5 41.97 38.53 2 6 5 116.29 117.48 3 6 5 22. 17 20.37 4 6 5 89.74 86.49 5 6 5 12.65 12. 16 6 6 5 79.48 79.08 7 6 5 54.95 55.07 8 6 5 49.28 48.86 9 6 5 5.21* 3.06 0 7 5 18.97 17.80 1 7 5 75.09 73.09 2 7 5 45.66 45.72 3 7 5 62.86 61.68 4 7 5 29.75 29.00 5 7 5 30. 18 28.63 6 7 5 8.41 8.53 7 7 5 14.47 15.01 8 7 5 6.81* 6.91 9 7 5 10.61 11.43 0 8 5 32.70 32.46 1 8 5 142.44 157.34 2 8 5 37. 10 36.88 3 8 5 117.04 113.57 4 8 5 33.82 33.91 5 8 5 64.93 62.76 6 8 5 23.89 23.48 7 8 5 27.90 27.20 8 8 5 12.32 12.91 0 9 5 29.37 28.74 1 9 5 5.68* 8.83 2 9 5 104.91 99. 39 3 9 5 94.47 90.74 4 9 5 13.82 13.27 5 9 5 25.53 23.81 6 9 5 31.98 3 1.89 7 9 5 14.09 13.00 8 9 5 13.43 14.42 0 10 5 98. 16 94.57 1 10 5 9.32 9.69 2 10 5 125.15 122.46 3 10 5 50.38 48.86 4 10 5 38.27 36.90 5 10 5 40.28 39.21 6 10 5 47.78 46.41 7 10 5 26.64 25.28 8 10 5 25.79 24.80 0 11 5 28.50 27.42 H K L FO FC 1 11 5 18.32 17.57 2 11 5 34.49 32.45 3 11 5 30. 11 29.34 4 1 1 5 41.86 40.70 5 1 1 5 18.33 17.86 6 1 1 5 31.44 31 .95 7 1 1 5 15.75 16. 13 8 1 1 5 4.10* 1.21 0 12 5 11.20 11.28 1 12 5 42.14 40.98 2 12 5 46. 90 45.79 3 12 5 43. 38 42.06 4 12 5 9.48 9.09 5 12 5 39.07 38.74 6 12 5 31.46 31.34 7 12 5 44.97 45. 17 0 13 5 18.38 17.53 1 13 5 13.40 12.93 2 13 5 41.05 39.25 3 13 5 11.94 11.07 4 13 5 20.08 19.58 5 13 5 17.00 17.00 6 13 5 39.87 40.88 7 13 5 0.00* 2.66 0 14 5 30.44 28.34 1 14 5 47. 48 47.28 2 14 5 60.96 59.08 3 14 5 0.00* 2.27 4 14 5 43.61 43. 13 5 14 5 4.53* 4.3 0 6 14 5 41.03 40.98 0 15 5 23.45 22.57 1 15 5 38. 39 36.99 2 15 5 6.32* 8.01 3 15 5 43.30 42.91 4 15 5 13.77 14.86 5 15 5 21. 21 22.38 6 15 5 0.00* 0.75 0 16 5 33.47 33.52 1 16 5 40.53 39.76 2 16 5 39.70 40.03 3 16 5 66.24 65.14 4 16 5 7.71 7.48 5 16 5 22.04 21 .50 0 17 5 28.64 29.39 1 17 5 17.20 16.46 2 17 5 36.81 36.09 3 17 5 5.16* 7.49 4 17 5 12.64 12. 14 5 17 5 19.46 19.57 0 18 5 39. 35 39.90 1 18 5 31.54 31.96 2 18 5 18.73 19.00 3 18 5 18. 11 18. 27 4 18 5 27.94 28.59 0 19 5 2.76* 7.59 1 19 5 15.90 16.51 2 19 5 6. 27* 6.06 H K L FO FC 0 0 6 116.17 135.91 2 0 6 91.05 94.07 4 0 6 145.24 156.29 6 0 6 4.64* 9. 26 8 0 6 23.44 24.48 0 1 6 65. 16 65.77 1 1 6 56.49 55.49 2 1 6 17.43 17.80 3 1 6 12.50 13. 18 4 1 6 62.65 62.27 5 1 6 27.84 28.46 6 . 1 6 3.61* 3.59 7 1 6 4.91* 5.02 8 1 6 15.03 15.40 9 1 6 14.08 ' 15.42 0 2 6 35.11 36.03 1 2 6 104.87 110.30 2 2 6 34.60 35.69 3 2 6 111.45 116.29 4 2 6 57.31 58.39 5 2 6 75.62 76.35 6 2 6 8.73 8.62 7 2 6 31.78 33.35 8 2 6 0.00* 2.91 9 2 6 29.61 31.51 0 3 6 6.31 7.91 1 3 6 10.03 11.53 2 3 6 27.02 26.65 3 3 6 53.00 51.63 4 3 6 34.25 32.60 5 3 6 30.96 29.95 6 3 6 18.74 18.47 7 3 6 31.81 32.45 8 3 6 27.98 29.98 9 3 6 8.44 10. 19 0 4 6 81.74 78.07 1 4 6 29.72 28.66 2 4 6 71. 19 68.50 3 4 6 52.05 48.94 4 4 6 95.08 93.69 5 4 6 7.77 6.09 6 4 6 51.54 51.56 7 4 6 18.81 19.51 8 4 6 50.47 51.43 9 4 6 17.21 17.95 0 5 6 61.22 62. 13 1 5 6 13.52 12. 1 1 2 5 6 26.51 26.69 3 5 6 13.25 1 1.81 4 5 6 15.09 13.39 5 5 6 44.50 44.53 6 5 6 0,00* 3.21 7 5 6 20.22 20. 19 8 5 6 29,04 31.03 9 5 6 11.89 11. 22 0 6 6 59.11 60. 18 1 6 6 79,23 80.81 2 6 6 16.53 14.42 H K L FO FC 3 6 6 67.09 65.95 4 6 6 14.80 14.81 5 6 6 70. 12 69.92 6 6 6 19.31 18, 18 7 6 6 45.9 2 45.61 8 6 6 8.84 9.58 0 7 6 21. 38 21. 19 1 7 6 56. 15 56.62 2 7 6 58.34 . 53,27 3 7 6 49.09 48,84 4 7 6 21. 24 21.27 5 7 6 29.07 28.35 6 7 6 24.77 23.4 1 7 7 6 8.83 8.90 8 7 6 6.66* 7̂ .04 0 8 6 91.19 86.21 1 8 6 22.63 20.56 2 8 6 96.09 93. 18 3 8 6 60.42 60.60 a 8 6 59.51 60.7 3 5 8 6 4.87* 3.67 6 8 6 48.07 47. 32 7 8 6 22.35 22.62 8 8 6 21.90 22.06 0 9 6 61.42 57.55 1 9 6 54. 10 51.87 2 9 6 67.78 65.41 3 9 6 35.59 35.47 4 9 6 30.07 30.91 5 9 6 11.97 12.76 6 9 6 15.04 12.35 7 9 6 2.66* 0.68 8 9 6 12.20 12.06 0 10 6 22.39 22.24 1 10 6 72. 87 70.82 2 10 6 46.08 45.99 3 10 6 49.35 48.08 4 10 6 32.69 31.36 5 10 6 30,79 30.36 6 10 6 30.97 31.29 7 10 6 45.56 45.76 8 10 6 0.00* 1.99 0 11 6 4.30* 1.09 1 11 6 20.35 20.84 2 11 6 38.79 37.37 3 11 6 44.08 44. 39 4 11 6 28.62 28.58 5 11 6 32. 19 30.51 6 11 6 16.38 16.98 7 11 6 22.32 22. 10 0 12 6 40.17 39.03 1 12 6 12.73 12.42 2 12 6 34.37 33. 12 3 12 6 0.00* 3.01 4 12 6 19.08 19.46 5 12 6 19.01 19.93 6 12 6 50.40 51. 26 7 12 6 24.93 26.59 H K L FO FC 0 13 6 30. 49 30. 19 1 13 6 29.03 28. 12 2 13 6 29.66 28.33 3 13 6 6.91* 5.60 4 13 6 9.18 9.09 5 13 6 6.99* 5.72 6 13 6 18.87 19.27 0 14 6 42. 14 41.06 1 14 6 23.03 22.63 2 14 6 20.97 22.09 3 14 6 52.88 52.37 4 14 6 15.33 15.55 5 14 6 30.45 31.96 6 14 6 18.08 18.40 0 15 6 26.40 25.62 1 15 6 40.49 40.72 2 15 6 46. 13 44.93 3 15 6 2.69* 4.42 4 15 6 9.51 9.61 5 15 6 26.88 27.71 0 16 6 42.27 40.70 1 16 6 38.50 39. 14 2 16 6 44.76 44.24 3 16 6 0.00* 2. 23 4 16 6 45.97 47. 18 5 16 6 14.47 15. 11 0 17 6 3.38* 0.26 1 17 6 41.21 41.01 2 17 6 15.60 15.04 3 17 6 21.07 21.64 4 17 6 20.84 21.21 0 18 6 14. 12 14,54 1 18 6 23.62 23.73 2 18 6 14.87 15,79 3 18 6 41.36 4 1.79 0 19 6 16,79 16.30 1 19 6 0.97* 2. 19 1 0 7 100.15 105.48 3 0 7 50.84 55.58 5 0 7 12.45* 10.76 7 0 7 16,25* 17.23 0 1 7 71.94 72.95 1 1 7 44.01 43.69 2 1 7 22.57 20.22 3 1 7 48.49 48.85 4 1 7 48. 36 47.82 5 1 7 15. 12 15. 10 6 1 7 19.22 19.47 7 1 7 3.53* 4.26 8 1 7 0.00* 2.26 0 2 7 100.78 101.59 1 2 7 27.36 27.84 2 2 7 50.62 49.64 3 2 7 30. 12 29.71 4 2 7 43.74 43. 36 5 2 7 4.93* 5.90 6 2 7 11.23 7.98 7 2 7 12. 10 10.94 H K L FO FC 8 2 7 30.08 31.43 0 3 7 56.22 55. 94 1 3 7 35. 31 35. 14 2 3 7 19.66 19.52 3 3 7 6.78 5.41 4 3 7 30.72 32.09 5 3 7 19.62 19.68 6 3 7 23.34 24.29 7 3 7 1.78* 2.82 8 3 7 29.23 29.83 0 4 7 37.26 38.38 1 4 7 72.97 73.21 2 4 7 5.39 7.51 3 4 7 21.97 22.90 4 4 7 2.19* 1.61 5 4 7 35.72 35.59 6 4 7 21.06 21.40 7 4 7 34.39 35.35 8 4 7 11.07 12.25 0 5 7 6.83 8.38 1 5 7 3.38* 4.28 2 5 7 9.49 7.60 3 5 7 0.00* 0.77 4 5 7 22.29 23.24 5 5 7 3.07* 2.44 6 5 7 20. 19 19.87 7 5 7 37.29 38.52 8 5 7 11.81 11.11 0 6 7 32.59 33.11 1 6 7 26.04 27.76 2 6 7 55.37 54.77 3 6 7 19.82 21. 12 4 6 7 40.77 40.59 5 6 7 63.62 63.32 6 6 7 47.01 46.61 7 6 7 13.92 14.89 8 6 7 21.62 21 .80 0 7 7 83.89 81.06 1 7 7 31.35 30.74 2 7 7 21. 32 18.98 3 7 7 42.91 42.86 4 7 7 1.32* 4.01 5 7 7 9.82 9.91 6 7 7 11.72 11.46 7 7 7 11.67 12.05 8 7 7 20. 15 21.51 0 8 7 36. 18 35.65 1 8 7 47.03 48.15 2 8 7 29. 32 28.28 3 8 7 51.32 52.15 4 8 7 6.38 3.49 5 8 7 46.70 46.04 6 8 7 9. 15 8. 31 7 8 7 25.04 25.40 8 8 7 3.56* 1.04 0 9 7 7.13 8.22 1 9 7 23.50 25.03 2 9 7 47.60 45.48 H K L FO FC 3 9 7 38.84 38.57 4 9 7 3. 16* 3. 22 5 9 7 12.34 12.55 6 9 7 26.00 25.50 7 9 7 35. 16 37.13 0 10 7 21.80 21. 15 1 10 7 12.81 12.77 2 10 7 46.91 45. 26 3 10 7 29.22 28.07 4 10 7 31.43 29.96 5 10 7 15.03 15.03 6 10 7 46. 11 44.94 7 10 7 14.49 15.78 0 11 7 30.53 31.71 1 11 7 0.00* 0.59 2 11 7 15.04 13.96 3 11 7 1.71* 1.36 4 11 7 14. 13 13.98 5 11 7 1.31* 1.62 6 11 7 34.75 35.35 7 11 7 32.77 32.94 0 12 7 20.49 18.49 1 12 7 13.91 15.82 2 12 7 17.71 17.01 3 12 7 34.57 32.58 4 12 7 2.70* 0.25 5 12 7 33.83 33. 12 6 12 7 21.06 22.52 0 13 7 4.36* 1.91 1 13 7 37.30 36.70 2 13 7 4.89* 5.24 3 13 7 9.39 8.26 4 13 7 8.57 7.52 5 13 7 19.07 18.86 6 13 7 43.28 42.99 0 14 7 15.22* 16.21 1 14 7 17.46 16.54 2 14 7 32.20 32.01 3 14 7 0.00* 2. 12 4 14 7 38.51 38.27 5 14 7 8.41 7.73 0 15 7 36.96 36.04 1 15 7 19.90 19.97 2 15 7 36.54 36.32 3 15 7 19. 12 19.13 4 15 7 14.21 14.83 5 15 7 12.30 12.79 0 16 7 4. 12* 6.28 1 16 7 19.91 20.43 2 16 7 18.75 18.53 3 16 7 50.92 51.18 4 16 7 11.24 1 1.98 0 17 7 26.85 26.69 1 17 7 26.51 26.82 2 17 7 30.30 31.40 3 17 7 20.78 20.78 0 18 7 47.90 48.73 1 18 7 3.37* 4.01 H K L FO FC 0 0 8 59.55 61.08 2 0 8 5. 11* 5.14 4 0 8 30.22 30.79 6 0 8 24.95 25.53 8 0 8 31.05 32.82 0 1 8 73.74 70.87 1 1 8 85.65 83. 51 2 1 8 22.72 22.49 3 1 8 35.47 35.97 4 1 8 51.53 51 .55 5 1 8 21.00 19.06 6 1 8 9.23 9.17 7 1 8 4.48* 1. 17 8 1 8 19.95 20.80 0 2 8 49. 19 48.21 1 2 8 39.28 40. 18 2 2 8 29.77 31.69 3 2 8 18.84 18.53 4 2 8 18.17 18.00 5 2 8 30.59 31.00 6 2 8 13.17 13.55 7 2 8 33.25 33.45 8 2 8 8.74 8.77 0 3 8 65,52 63.60 1 3 8 5.01* 2.58 2 3 8 6,61 5. 18 3 3 8 15.09 16.10 4 3 I 8 19,24 17.93 5 3 's 22.79 22.54 6 3 8 8.26 8.58 7 3 8 25. 20 26.76 8 3 8 34.51 36.16 0 4 8 26.88 25.61 1 4 8 44.25 42.72 2 4 8 9.93 11.31 3 4 8 3.02* 1.95 4 4 8 13.38 13.03 5 4 8 21.80 21 .35 6 4 8 31.04 31 .33 7 4 8 24.53 25.36 8 4 8 33.11 34.23 0 5 8 10.90 12. 12 1 5 8 37.36 36.23 2 5 8 10. 14 10. 12 3 5 8 7.47 6.97 4 5 8 24.00 22. 09 5 5 8 21.97 22.17 6 5 8 19. 11 18.81 7 5 8 25.63 26.33 8 5 8 16.77 17.07 0 6 8 41.19 41.69 1 6 8 52.37 54. 17 2 6 8 28.67 27.65 3 6 8 12.63 11.71 4 6 8 20.92 20.69 5 6 8 43.37 43.35 6 6 8 22.49 23.34 7 6 8 20.48 20,34 H K I FO FC 0 7 8 27,93 27. 12 1 7 8 7,75 8.33 2 7 8 57. 13 54.83 3 7 8 44.85 42. 12 4 7 8 27.54 28.49 5 7 8 19.93 19.30 6 7 8 37.34 36. 15 7 7 8 14.26 14.89 0 8 8 20.29 21.36 1 8 8 33.71 33.76 2 8 8 55.80 54.40 3 8 8 3.56* 2.92 4 8 8 34.37 33.68 5 8 8 24. 17 24.65 6 8 8 27.25 26.84 7 8 8 13.97 13.49 0 9 8 6.74 6.09 1 9 8 30.80 28.86 2 9 8 19. 13 17.41 3 9 8 61.55 59.77 4 9 8 31.98 32. 24 5 9 8 23.46 22.38 6 9 8 23.78 24.52 7 9 8 17.45 16.73 0 10 8 40. 10 39.02 1 10 8 55.52 55.01 2 10 8 5.06* 4.57 3 10 8 38.41 37.82 4 10 8 9.70 9.37 5 10 8 27. 15 26. 11 6 10 8 11.33 11.35 0 11 8 13.94 12.92 1 11 8 10. 15 10.14 2 11 8 36.83 35.97 3 11 8 11.89 10.23 4 11 8 10.26 9. 15 5 11 8 17.07 17.47 6 11 8 50,42 50.00 0 12 8 32.53 31.88 1 12 8 1.77* 4.41 2 12 8 48.83 48.22 3 12 8 1.93* 2.68 4 12 8 29. 11 27.81 5 12 8 3. 18* 0.37 6 12 8 24.05 23. 12 0 13 8 16.60 16.00 1 13 8 5.93* 5.63 2 13 8 12.00 11.57 3 13 8 18.59 17.69 4 13 8 5.68* 3.63 5 13 8 28.91 29.51 0 14 8 7.91 6.92 1 14 8 17.95 17.62 2 14 8 22.45 21.34 3 14 8 43.93 43.80 4 14 8 6.99* 8.52 0 15 8 5.36* 4.34 1 15 8 32.24 33.41 B K L FO FC 2 15 8 30.81 30.64 3 15 8 3.75* 4.06 4 15 . 8 22.35 21 .87 0 16 8 26.75 26. 13 0 16 8 27.29 26. 13 2 16 8 25.00 24.47 3 16 8 8.00* 9.25 0 17 8 18.39 17.55 1 17 8 30. 12 29.85 1 0 9 33.24 34.36 3 0 9 44.51 45.75 5 0 9 58.87 59.37 7 0 9 32.33 32.45 0 1 9 56.70 55.42 1 1 9 44.59 44.05 2 1 9 19.89 21. 17 3 1 9 45.42 45.96 4 1 9 63.40 64.02 5 1 9 44.86 45.33 6 1 9 21.09 20.80 7 1 9 19.27 20.68 0 2 9 16.62 16. 24 1 2 9 55.16 55.06 2 2 9 20.05 20.70 3 2 9 18.85 16.77 4 2 9 57.28 57.52 5 2 9 18.29 18.49 6 2 9 34.76 35.24 7 2 9 18.52 19.13 0 3 9 33. 32 34.31 1 3 9 39.13 37.74 2 3 9 4.70* 5.20 3 3 9 2.36* 1 .35 4 3 9 39.06 39. 16 5 3 9 43.87 44.23 6 3 9 15.70 15.39 7 3 9 30.71 32.23 0 4 9 9.48 9.22 1 4 9 30.52 31.35 2 4 9 15.81 15. 27 3 4 9 19.52 19.54 4 4 9 27. 23 27.79 5 4 9 41.88 43.03 6 4 9 0.00* 0.39 7 4 9 25. 15 26.04 0 5 9 39. 18 39.24 1 5 9 25.77 25.52 2 5 9 11.43 11.14 3 5 9 30.92 30.42 4 5 9 31.70 31 .03 5 5 9 19.51 19.07 6 5 9 40.23 41.17 7 5 9 11.41 11.12 0 6 9 25.83 26.13 1 6 9 21.55 21.12 2 6 9 38.45 38.18 3 6 9 21.57 21.71 4 6 9 35.97 34.85 H E L FO FC 5 6 9 27.34 27.58 6 6 9 33.82 34.59 7 6 9 8.80 8.74 0 7 9 20.88 21.09 1 7 9 50.28 48.54 2 7 9 51.30 50.77 3 7 9 58.33 58.21 4 7 9 43.69 42.55 5 7 9 35.95 35.40 6 7 9 2.39* 1.85 0 8 9 13. 19 13. 34 1 8 9 49.06 48. 13 2 8 9 16.45 16.72 3 8 9 25. 18 25.23 4 8 9 13.80 13.39 5 8 9 30. 11 30.70 6 8 9 4. 12* 2.03 0 9 9 26.72 27.14 1 9 9 20.86 20.06 2 9 9 82.85 81.14 3 9 9 43.67 43. 22 4 9 9 35.26 34.82 5 9 9 10.81 11.41 6 9 9 35.55 35.54 0 10 9 48.34 47. 16 1 10 9 25.07 25.28 2 10 9 39. 19 38. 23 3 10 9 12.47 12.22 4 10 9 15.56 15.46 5 10 9 8.98 10. 12 6 10 9 15.88 16. 12 0 11 9 6. 10* 4.80 1 11 9 40.80 38.47 2 11 9 14.75 13.52 3 11 9 46.28 45.22 4 11 9 10.49 11.21 5 11 9 21.74 21.95 0 12 9 0.00* 3.34 1 12 9 36.72 36. 29 2 12 9 3.63* 3.60 3 12 9 25.09 25.87 4 12 9 3.49* 3.55 5 12 9 9.32 9.88 0 13 9 19.63 18.70 1 13 9 10.76 9.76 2 13 9 43.00 42.77 3 13 9 3.61* 2.56 4 13 9 11.92 12. 22 0 14 9 19.85 19.73 1 14 9 23.47 23. 18 2 14 9 19.05 19.12 3 14 9 10.09 10.08 0 15 9 0.00* 1.58 1 15 9 39.23 37.51 2 15 9 0.00* 3.01 0 16 9 14.65 14.64 0 0 10 52.27 51.94 2 0 10 67.07 69.81 fi K L FO FC 4 0 10 57.97 58.27 6 0 10 27.62 28.69 0 1 10 55.85 55. 24 1 1 10 52.78 53.06 2 1 10 37.46 38. 10 r 1 10 54.88 55.80 4 1 10 64.02 64.90 5 1 10 53.99 54.92 6 1 10 22. 21 22. 87 0 2 10 16.86 16.37 1 2 10 55. 18 55.04 2 2 10 5.93* 5.82 3 2 10 59.9 1 60.35 4 2 10 21.53 21.50 5 2 10 33.92 34.00 6 2 10 7.43 8.78 0 3 10 47.95 48.31 1 3 10 40.51 40. 15 2 3 10 22.82 24.50 3 3 10 21.90 21.31 4 3 10 54.90 54.93 5 3 10 23.87 24.00 6 3 10 27.37 27.76 0 4 10 28.62 27.96 1 4 10 4.81* 4.96 2 4 10 54.65 54.68 3 4 10 37.23 37. 10 4 4 10 37.63 37.50 5 4 10 11.43 11.55 6 4 10 27.66 28.69 0 5 10 46.45 45.73 1 5 10 45.77 45.59 2 5 10 21.00 21.64 3 5 10 39.70 38.87 4 5 10 16.82 16.02 5 5 10 39. 19 39.99 6 5 10 14.37 13.40 0 6 10 45.51 44.66 1 6 10 36. 32 36.23 2 6 10 22.25 22.92 3 6 10 34.98 35.33 4 6 10 12.86 12.62 5 6 10 40.82 41.06 6 6 10 21.22 21.62 0 7 10 42. 49 42.74 1 7 10 32.42 31.33 2 7 10 59,98 59. 18 3 7 10 25.24 24.31 4 7 10 40.20 40.27 •5 7 10 10.85 10.74 6 7 10 35.24 36.34 0 8 10 18.77 18.29 1 8 10 5.94* 6. 23 2 8 10 26.42 25.44 3 8 10 27.86 26.87 4 8 10 26.45 26.30 c. 8 10 7.47* 8.61 0 9 10 26.24 25.55 H K L FO FC 1 9 10 44.90 43.72 2 9 10 23.35 22.78 3 9 10 58.76 57.44 4 9 10 8.50 7.04 5 9 10 20.37 20,13 0 10 10 7.63* 6.00 1 10 10 20.86 20.71 2 10 10 0.00* 2.90 3 10 10 16.72 17.00 4 10 10 18.41 18.83 0 11 10 32.47 31.64 1 11 10 18.37 16.90 2 11 10 42.86 42.73 3 11 10 6.82* 6.42 4 11 10 2. 17* 1.47 0 12 10 20. 10 20.18 1 12 10 1.33* 3.73 2 12 10 17.97 16.21 3 12 10 2.94* 3.23 0 13 10 8.25 7.99 1 13 10 28.02 27. 21 2 13 10 12.24 11.44 0 14 10 12.95 11.58 1 14 10 5.67* 2. 18 1 0 11 45.96 45. 26 3 0 11 17.81 18.59 5 0 11 13.69 14.10 0 1 11 49.77 49.44 1 1 11 49.59 48.77 2 1 11 34.61 34.90 3 1 11 32.33 33.03 4 1 11 37.24 38.98 5 1 11 26.65 27.46 0 2 11 49. 13 49.01 1 2 11 22.96 22.49 2 2 11 34.63 34.83 3 2 11 4.32* 0.35 4 2 11 13.88 14.25 5 2 11 2.93* 0.64 0 3 11 52.00 51.50 1 3 11 47.28 47.51 2 3 11 18.80 18.83 3 3 11 20.33 20.25 4 3 11 16.28 16.41 5 3 11 17.09 17.85 0 4 11 24.70 23.78 1 4 11 48. 18 47.66 2 4 11 3.71* 3.67 3 4 11 27.71 27.51 4 4 11 5.04* 3.59 5 4 11 22.21 23.02 0 5 11 49.04 48.48 1 5 11 22.29 22.60 2 5 11 30.73 30.27 3 5 11 8.45 7.87 4 5 11 13.55 14.63 5 5 11 25.79 25.87 0 6 11 23.19 22.75 e K L FO FC 1 6 11 21.89 21.13 2 6 11 35.97 35.42 3 6 11 17.44 / 17.56 4 6 11 25. 19 25.79 5 6 1 1 20.92 21.79 0 7 11 15.90 15.75 1 7 11 29. 13 28.85 2. 7 11 16.80 16.96 3 7 11 38.64 39.28 4 7 1 1 21.08 21.08 0 8 11 27.73 27.91 1 8 1 1 27.09 26.86 2 8 11 4.93* 5.95 3 8 11 21.29 21.52 4 8 1 1 10.09 9.12 0 9 11 10.59 10.49 1 9 11 15.79 15.52 2 9 1 1 42.27 39.75 3 9 1 1 17.95 17.00 4 9 1 1 17.80 17.20 0 10 1 1 20.32 19.34 1 10 1 1 0.00* 1. 12 2 10 11 26.72 26.01 3 10 1 1 12.83 12.27 0 11 1 1 29.65 27.64 1 11 11 6.63* 6.3 8 2 11 1 1 20.94 19.79 0 12 11 0.00* 0.65 1 12 1 1 » 17..40 16.41 0 0 12 20.16 19.78 2 0 12 5. 11* 4.75 4 0 12 6.54* 6.93 0 1 12 37.04 35.32 1 1 12 23. 28 22.73 2 1 12 11.20 12.02 3 1 12 7.69 7.27 4 1 12 20.69 20.55 0 2 12 11.13 10.64 1 2 12 16.90 16.56 2 2 12 20.23 19.35 3 2 12 8. 23 7.93 4 2 12 8.36 7.82 H K L FO FC 0 3 12 36.81 36.03 1 3 12 25.77 26.29 2 3 12 0.00* 2.28 3 3 12 10.37 9.95 4 3 12 4.93* 5.07 0 4 12 21.27 21.03 1 4 12 18.67 18.72 2 4 12 18. 1 1 17.78 3 4 12 10.27 10.00 4 4 12 14.59 13.78 0 5 12 16.96 17.87 1 5 12 18.01 18.04 2 5 12 18. 30 18.03 3 5 12 3.50* 0.60 0 6 12 22.08 21.29 1 6 12 22.68 22.29 2 6 12 ' 1.74* 0.06 3 6 12 8.46 8.09 0 7 12 14.57 14.05 1 7 12 15.80 15. 10 2 7 12 23.42 22. 24 3 7 12 29.61 28.53 0 8 12 22.50 21.93 1 8 12 3.65* 2.55 2 8 12 11.64 12.06 0 9 12 15.66 15.62 1 9 12 10.48 9.64 0 -2 13 7.48* 6.84 1 0 13 4.05* 4.34 0 1 13 12.50 12.98 1 1 13 15.47 15.22 2 1 13 2.02* 1.40 0 2 13 8.73 6.84 1 2 13 16.92 16.40 2 2 13 5.42* 7.03 0 3 13 25.26 24. 12 1 3 13 5.39* 5.27 2 3 13 13.89 13.27 0 4 13 5.33* 5.37 1 4 13 0.00* 2.93 0 5 13 18.99 18.09 1 5 13 19.88 19.08 DENOTES AN UNOBSERVED REFLECTION Acetyl-3-benzamido-2-keto-4-(2,4,4>6-tetra-C-acetyl glucopyranosyloxy)-A 3-pyrrolire Anthony Mercer, and James Trotter Observed and calculated structure amplitudes ( r e f l e c t i o n s with i n t e n s i t y < 3o-(I) are marked w.ith asterisk) . H K I FO FC HEIGHT 1 0- 11 8. 45 8.99 6.18 2 0-11 6. 17 6, 22 7. 12 1 0- 10 11. 92 1 2. 29 4. 99 2 0-10 7.09 8. 12 5. 28 3 0- 10 8. 74 10. 32 4. 68 4 0- 10 4. 07 4. 02 2..84 5 0- 10 0. 00* 0.42 0. 00 6 0- 10 3. 89 2. 25 4. 47 7 0- 10 3. 83 3. 01 3. 53 8 0- 10 2. 57* 3.03 0. 17 9 0- 10 5.77 6.56 6. 54 1 1-10 9. 47 10. 23 4. 79 2 1-10 4. 45 4.31 3. 94 3 1-10 3.36* 4. 19 0. 19 4 1-10 6. 89 7. 35 5. 35 5 1-10 9. 05 10. 34 5. 44 6 1 -10 4.61 3. 23 5. 69 7 1-10 3. 35* 3. 64 0. 26 ' 8 1-10 3. 6 0 3, 13 3. 48 9 1- 10 0. 00* 0, 36 0. 00 1 2-10 3. 13* 1.91 0. 21 2 2- 10 3. 10* 3.61 0. 21 3 2-10 4.90 3. 43 5.98 « 2-10 2.79* 2. 11 0. 18 5 2- 10 4. 10 4. 20 3.20 6 2- 10 1.30* 2. 67 0.04 7 2-10 3. 36 1. 79 4. 22 1 3- 10 4. 22 3. 95 3. 50 2 o — 10 2.92 0. 10 3 3-10 4. 15 3. 63 2. 95 a 3-10 6. 16 6. 90 4. 39 5 3-10 4.47 3. 60 4.21 1 0 -9 21. 07 21. 90 2. 56 2 0 -9 12. 58 12. 08 4. 23 3 0 -9 3. 04* 3.82 0. 19 4 0 -9 2. 24* 1,47 0. 11 5 0 -9 15. 07 16.81 3. 60 6 0 -9 3.87 3. 48 3. 02 7 0 -9 4. 14 3. 84 3. 36 8 0 -9 4.46 5. 00 3. 11 9 0 -9 10. 24 11.14 5. 22 10 0 -9 0. 00* 1. 63 0. 00 11 0 -9 4. 29 4. 36 4. C8 12 0 -9 4. 86 4. 96 4. 29 1 1 -9 9. 13 10. 50 5. 08 2 1 -9 2.79* 3. 22 0. 16 3 1 -9 13. 80 15. 49 4. 24 4 1 -9 3. 55* 4. 33 0. 20 5 1 -9 12. 97 14. 02 4. 39 6 1 -9 7. 14 7.47 5. 12 7 1 -9 2. 85* 5.54 0. 11 8 1 -9 4. 05 3. 77 4. 30 9 1 -9 6. 53 5. 69 5. 91 10 1 -9 2. 28* 1.93 0. 12 11 1 -9 3. 81 2.70 3. 53 12 1 -9 4. 17 2.75 5. 67 1 2 -9 5.67 5.25 4. 14 2 2 -9 9. 18 9. 29 5. 04 H K L FO FC HEIGHT 3 2 -9 4.60 5. 26 2. 67 4 2 -9 6. 06 4. 67 5. 30 5 2 -9 7.36 7. 80 6. 09 6 2 -9 2.43* 1. 98 0. 12 7 2 -9 5. 25 5. 55 3.92 8 2 -9 5. 28 4. 49 4. 91 9 2 -9 2.92* 3. 91 0. 19 10 2 -9 1. 56* 3. C4 0. 05 11 2 -9 5, 98 . 5. 47. 6. 52 1 3 -9 1. 46* 1. 18 0. 05 2 3 -9 12. 78 13. 67 4. 76 3 3 -9 1 . 38* 1. 94 0. 04 4 3 -9 4. 87 4. 95 3. 57 5 3 -9 2. 62* 4. 97 0. 12 6 3 -9 7. 83 8. 19 5.07 7 3 -9 3. 52 2. 1.8 2. 95 8 3 -9 2.51* 1. 78 0. 16 9 3 -9 3. 39* 3. 32 0. 28 10 3 -9 4.59 3. 93 5. 26 1 4 -9 4. 72 4. 59 3. 14 2 4 -9 0. 00* 0. 11 0. 00 3 4 -9 1 . 30* 0. 63 0. 04 4 4 -9 4. 96 4. 66 4. 16 5 4 -9 0.49* 3. 19 0. 00 6 4 -9 2.71* 2. 19 0. 16 7 4 -9 2. 52* 2. 09 0. 15 1 0 -8 11. 12 10. 92 4. 29 2 0 -8 4.68 4. 81 3, 42 3 0 - 3 21.30 2 1. 4 G 2. 50 4 0 -8 12. 55 12. H2 5. 73 5 0 -8 4. 54 3. 77 3. 59 6 0 -8 3. 72 4. C4 3. 17 7 0 -8 17. 70 18. 03 3. 51 8 0 -8 17. 96 19.31 3. 31 9 0 -8 3. 96 4. 03 2. 57 10 0 -8 0. 00* 0. 57 0.00 11 0 -8 3. 65 2. 17 3. 64 12 0 -8 3.58* 3. C4 0. 25 13 0 -8 6. 58 6. 45 6. 09 14 0 -8 2. 83* 1. 64 0. 24 15 0 -8 0.94* 1. 15 0. 02 1 1 -8 4. 26 4. 58 2. 94 2 1 -8 5.59 5. 94 3. 20 3 1 -8 8. 32 10. 25 4. 95 4 1 -8 7. 53 9. 21 5. 16 5 1 -8 5. 24 6. 58 3. 12 6 1 -8 8.78 10. 32 5. 26 7 1 -8 5. 92 6. 46 3. 41 8 1 -8 5.41 6. 22 3. 42 9 1 -8 2.18* 4. 67 0. 08 10 1 -8 2. 62* 2. 26 0. 14 11 1 -8 3.53* 4. 68 0. 24 12 1 -8 4. 17 3. 72 2. 88 13 1 -8 4.07 4. 87 2. 95 14 1 -8 4.10 3. 24 5. 19 15 1 -8 3. 94 3. 36 3. 50 1 2 -8 7.36 6. 35 5.67 2 2 -8 12. 56 13. 44 4. 41 H K I FO FC HEIGHT 3 2 -8 12.98 1 3. 67 4. 54 4 2 -8 6. 83 7.08 6. 13 5 2 -8 10. 68 10. 20 5. 64 6 2 -8 16.77 17. 26 3.86 7 2 -8 3. 23* 3.32 0. 21 8 2 -8 3.57* 2. 50 0. 30 9 2 -8 6. 17 6.53 4. 52 10 2 -8 5. 44 4. 67 6. 02 11 2 -8 0. 62* 0. 86 0. 01 12 2 -8 3.42* 2. 26 0. 31 13 2 -8 3.30* 3. 05 0. 21 14 2 -8 3. 51 2. 04 3.48 1 3 -8 8. 16 8.42 6. 37 2 3 -8 6. 00 6. 38 3. 89 3 3 -8 13. 14 14. 07 4. 15 4 3 -8 6. 60 6. 65 4. 22 5 3 -8 10. 71 10. 38 5. 07 6 3 -8 6. 11 7.50 3. 87 7 3 -8 4.75 4. 0 8 4. 06 8 3 -8 3. 92 3. 05 3. 13 9 3 -8 6.46 5. 96 5. 73 10 3 -8 2. 85* 2. 93 0. 17 11 3 -8 3. 31* 2. 45 0. 30 12 3 -8 3. 78* 3. 77 0. 27 13 3 -8 0. 00* 2. 23 0. 00 1 4 -8 6. 52 6.91 3. 62 2 4 -8 6. 21 6. 12 3. 93 3 4 -8 7. 91 8.72 4. 81 4 4 - c 5. J C 6. 80 3.93 5 4 -8 4.02 3.02 3. 28 6 4 -8 5. 68 5. 03 4. 31 7 4 -8 4. 36 3. 94 3. 17 8 4 -8 5.35 6.4 2 3. 66 9 4 -8 4. 04 3. 37 3. 10 10 4 -8 0. 00* 1.20 0.00 11 4 -8 3.81 4, 00 2.79 1 5 -8 3.55* 3.49 0. 22 2 5 -8 4. 45 3.55 3.42 3 5 -8 5. 94 6.32 3. 26 4 5 -8 5.31 5.58 3. 28 5 5 -8 3. 44* 2. 92 0. 23 6 5 -8 3.69 2. 94 2. 87 7 5 -8 3.42* 3. 32 0. 25 1 0 -7 19. 31 18.73 3. 14 2 0 -7 3. 53 2. 13 3. 59 3 0 -7 5. 19 5.06 4. 28 4 0 -7 4. 60 4. 09 4. 06 5 0 -7 0. 00* 2. 15 0. 00 6 0 -7 14. 34 16.31 4. 60 7 0 -7 3. 20* 0.45 0. 28 8 0 -7 5.40 6.00 4. 14 9 0 -7 13. 74 14. 44 4. 96 10 0 -7 2. 46* 1. 12 0. 14 11 0 -7 10. 61 11. 05 4. 77 12 0 -7 4. 99 3.98 5. 49 13 0 -7 6.88 7.39 5. 87 14 0 -7 5. 83 4. 36 6. 47 15 0 -7 0.00* 2.30 0. 00 H K L FO FC HEIGHT 16 0 -7 2. 26* 1. 62 0.13 17 0 -7 3. 94 2. 93 4. 29 1 1 -7 5. 15 5. 20 4. 89 2 1 -7 22. 19 20. 39 2.50 3 1 -7 12. 05 11. 06 5. 11 4 1 -7 8. 35 9. 25 7. 22 5 1 -7 4.18 5. 12 3. 48 6 1 -7 11.57 11. 56 5. 66 7 1 -7 9. 44 10. 49 . 5. 42 8 1 -7 11.68 1 1. 95 5. 01 9 1 -7 8. 49 9. 22 5. 40 10 1 -7 20. 22 22. 62 2. 87 11 1 -7 3.06* 3. 45 0. 19 12 1 -7 8. 32 9. 68 5. 55 13 1 -7 0. 00* 0. 71 0. 00 14 1 -7 2. 87* 1.71 C. 21 15 1 -7 3. 14* 1. 39 0. 35 16 1 -7 4.21 3. 11 5. 39 1 2 -7 10.36 11.51 6. 67 2 2 -7 9. 47 9. 58 5. 41 3 2 -7 3.64* 4. 55 0.26 4 2 -7 6. 99 7. 44 5. 06 5 2 -7 15.03 15. 49 4. 65 6 2 -7 4.93 4. 50 3.73 7 2 -7 19. 50 19. €3 2. 77 8 2 -7 8.11 9. C6 5. 28 9 2 -7 13.31 19. 51 3. 17 10 2 -7 4. 32 4. 55 3. 02 11 2 — 7 6.15 5. "0 4. 59 12 2 -7 2.79* 4. 33 0. 13 13 2 -7 3. 97 3. 99 2. 63 14 2 -7 2.24* 1. 75 0. 14 15 2 -7 2.22* 1. 30 0.16 16 2 -7 2.14* 1. 17 0. 13 1 3 -7 6. 54 6. 51 5.01 2 3 -7 6. 24 5.78 5. 50 3 3 -7 4 . 68 5. CO 3, 36 4 3 -7 22. 33 23. 75 2. 47 5 3 -7 5.42 5. 08 4. 48 6 3 -7 13.44 14. 04 4. 46 7 3 -7 6.92 7. 20 4. 61 8 3 -7 8. 05 8. 77 4. 96 9 3 -7 5.72 5. 40 4. 26 10 3 -7 7.79 7. S9 7.27 11 3 -7 4. 33 4. 96 2. 48 12 3 -7 2.31* 2. 14 0. 12 13 3 -7 1. 74* 1. 53 0. 07 14 3 -7 2.01* 0. 91 0. 11 15 3 -7 3.61 2. 94 3. 01 1 4 -7 16. 23 19. 12 3. 60 2 4 -7 8. 22 8. 17 5. 08 3 4 -7 3.31* 3. 99 C. 19 4 4 -7 4 .00* 4. 47 0. 22 5 4 -7 10.46 10. 57 4.74 6 4 -7 5. 22 -4. 09 4. 60 7 4 -7 7.06 8. 51 3. 94 8 4 -7 5. 88 6. 55 3. 73 9 4 -7 6.93 6. 44 7. 15 H K I r o FC WEIGHT 10 4 -7 3. 51* 2. 74 0. 25 11 4 -7 2.76* 4. 07 0. 17 12 4 -7 4. 62 4.66 3. 79 13 4 -7 2. 43* 1.98 0. 17 1 5 -7 5.17 5.68 2. 77 2 5 -7 5.78 6. 06 4.30 3 5 -7 2. 19* 1.81 0. 09 4 5 -7 3.85 4. 38 2. 49 5 5 -7 3. 63* 5.41 0. 16 6 5 -7 6. 3E 6. 26 4. 87 7 5 -7 1.91* 2. 67 0. 06 8 5 -7 3.52* 4. 21 0. 22 9 5 -7 4.73 5. 07 2. 85 10 5 -7 5.06 4. 36 3. 87 11 5 -7 2. 42* 0.81 0. 18 1 6 -7 7. 05 8. 28 4. 49 2 6 -7 4. 05 4. 23 2. 62 3 6 -7 4. 47 4.88 2. 34 4 6 -7 3. 67* 5. 49 0. 22 5 6 -7 6. 23 7. 88 3. 83 6 6 -7 0. 28* 0. 39 0. 00 1 0 -6 9.81 9.74 8. 05 2 0 -6 7.68 7. 51 7. 99 ~j 0 -6 6. 35 4. 74 6. 06 4 0 -6 21. 40 22.41 2.75 5 0 -6 14. 92 1 4. 99 4.70 6 0 -6 6. 24 4.98 5. 46 7 0 -6 19. 99 1 8.79 2. 90 ts 0 - 6 12 . 15 12.5 i 5 . i 5 9 0 -6 6. 19 7. 81 4. 95 10 0 -6 5.95 5.71 5. 69 11 0 -6 3.38* 3.32 0. 28 12 0 -6 2. 96* 3. 00 0. 20 13 0 -6 25.76 28.12 1.81 14 0 -6 6.77 6.67 5.83 15 0 -6 3. 83 3. 25 3. 03 16 0 -6 0. 00* 0. 96 0. 00 17 0 -6 4. 45 3. 59 5.35 18 0 -6 0. OC* 0. 89 0. 00 1 1 -6 2. 81* 1.65 0. 27 2 1 -6 11. 30 11. 30 5. 82 3 1 -6 14. 86 13. 83 4. 81 4 1 -6 6. 42 6. 07 6. 08 5 1 -6 16. 21 16.45 3. 88 6 1 -6 17.77 16.31 3. 66 7 1 -6 14. 89 13. 35 4. 59 8 1 -6 3. 64 4. 35 2. 86 9 1 -6 12. 59 14. 38 6. 06 10 1 -6 7. 53 8. 26 5. 67 11 1 -6 8.60 9.77 5.07 12 1 -6 15. 54 17.02 4. 11 13 1 -6 6. 10 6.71 4. 66 14 1 -6 2. 47* 0. 93 0. 16 15 1 -6 5. 53 6.45 4. 10 16 1 -6 3. 15* 3. 47 0.21 17 1 -6 3. 85 2. 61 4.51 18 1 -6 3. 40 3. 15 3. 29 1 2 -6 22.79 20.86 2.42 H K L FO FC WEIGHT 2 2 -6 5.86 4. 96 6. 63 3 2 -6 2.78* 2. 97 0. 23 4 2 -6 6.15 5. 30 5. 11 5 2 -6 4.20 4. 80 2. 71 6 2 -6 13. 46 14. 86 4. 60 7 2 -6 0. 59* 2. 08 0. 01 8 2 -6 13.90 14. 49 4. 53 9 2 -6 2. 85* 2. 22 0. 18 10 2 -6 16.48 17. 14 3.78 11 2 -6 9.78 9. 67 5.42 12 2 -6 3. 28* 2. 41 0. 28 13 2 -6 9.99 9. 82 6. 27 14 2 -6 4. 55 4. 70 2. 68 15 2 -6 4.72 2. 84 5. 31 16 2 -6 5.10 4. 16 4. 05 17 2 -6 3.51 0. 95 4, 24 1 3 -6 11.95 9. 96 5. 49 2 3 -6 14. 28 12. 56 4. 52 3 3 -6 4.40 3. 93 4. 06 4 3 -6 4.54 3. 70 4. 05 5 3 -6 6. 38 5. 26 5. 54 6 3 -6 5. 44 5. 29 4. 54 7 3 -6 10.67 9. 97 5. 33 8 3 -6 0.00* 2. 24 0. 00 9 3 -6 8.02 7. 63 5. 27 10 3 -6 7. 88 6. 69 6.50 11 3 -6 6. 29 7. 09 4.11 12 3 -6 8.98 9. 15 5. 66 i3 3 -6 2. 5 7 * 0 . 5 i u. 1 / 14 3 -6 5.78 4. 99 4. 45 15 3 -6 2.25* 1. 62 0. 12 16 3 -6 2. 90* 1. 02 0. 27 1 4 -6 12.88 12. 46 4. 60 2 4 -6 14.90 15. 79 4. 27 3 4 -6 3. 08* 4. 26 0. 17 4 4 -6 3.44* 5. 18 0. 20 5 4 -6 3.54* 2. 18 0. 28 6 4 -6 11.82 12. 29 4. 52 7 4 -6 7.47 7. 95 4. 38 8 4 -6 7. 88 7. 79 5.57 9 4 -6 6.97 6. 89 4. 47 10 4 -6 6.41 6. 83 4. 09 11 4 -6 4.08 4. 32 2. 69 12 4 -6 5. 18 4. 56 4. 68 13 4 -6 6.54 6. 67 5. 15 14 4 -6 4.21 2. 68 4. 08 15 4 -6 2.53* 0. 54 0. 23 1 5 -6 6. 32 5. 99 4. 82 2 5 -6 7.37 8. 17 4. 70 3 5 -6 15. 13 16. 31 3.79 4 5 -6 7.35 8. 33 3. 69 5 5 -6 13.76 14. 80 3.83 6 . 5 -6 13.02 14. 54 4. 16 7 5 -6 6. 67 6. 67 4. 90 8 5 -6 4. 09 3.59 3. 35 9 5 -6 4.57 4. 31 2. 36 10 5 -6 2.31* -2. 66 0. 10 11 5 -6 3.87 2. 67 2.80 H K L FO F C HEIGHT 12 5 -6 2. 5 2 * 2. 79 0.11 13 5 -6 2. 8 3 * 2.31 0.23 1 6 -6 5. 46 5.69 3. 02 2 6 -6 4. 04 3 . 7 3 2. 27 3 6 -6 4. 15 3. 76 2. 40 4 6 -6 2. 8 6 * 0. 28 0. 14 5 6 -6 1. 5 6 * 1. 40 0. 04 6 6 -6 4. 86 6. 41 3. 79 1 6 -6 3. 8 7 * 4. 58 0. 26 8 6 -6 4.44 2. 83 3. 68 9 6 -6 3 . 5 0 * 3. 39 0. 22 1 7 -6 4.66 5.50 2. 80 2 7 -6 3. 1 9 * 4. 22 0.15 1 0 -5 1 4 . 3 8 1 3 . 95 5. 15 2 0 -5 2 4 . 89 2 3 . 7 9 2. 14 3 0 _ t; 2 6 . 60 2 8 . 3 9 1. 96 4 0 -5 2 . 8 0 * 3. 07 0. 40 5 0 -5 18. 05 1 7 . 95 3. 40 ' 6 0 _ c 1 5 . 86 1 5 . 1 2 4. 43 7 0 -~* 5. 08 5. 20 5.71 8 0 -5 5. 35 5, 39 5. 93 9 0 -5 10 . 28 9. 68 7 . 3 6 10 0 -5 2 1 . 6 4 2 0 . 70 2. 57 11 0 -5 3. 82 3. 18 3. 80 12 0 - 5 8. 3 3 8. 76 6. 00 13 0 -5 5. 51 5. 34 4. 77 14 0 -5 1 1 . 2 3 1 2 . 20 5. 21 15 0 -5 6.71 5. 90 5. 00 A* ^ 1 U V 7.13 4.75 17 0 _ 5 2. 2 0 * 2. 06 0. 13 18 0 -5 2 . 6 7 * 2. 36 0. 20 19 0 -5 3 . 3 9 * 2. 16 0. 34 1 1 -5 2. 2 7 * 3.79 0. 24 2 1 -5 14. 32 1 3 . 9 1 5. 12 3 1 -5 18. 92 1 7 . 68 3. 58 4 1 -5 18. 9 3 16. 7 7 3.39 5 1 -5 8. 30 7. 13 8. 10 6 1 -5 2 1 . 5 9 1 8 . 8 3 2. 67 7 1 _ c 13 . 05 1 2 . 98 5. 40 8 1 -5 13 . 85 14. 46 4. 91 9 1 -5 2 . 4 8 * 1.38 0. 21 10 1 _ c 6. 66 6. 61 6. 85 11 1 -5 3. 94 4. 86 2. 76 12 1 -5 1 3 . 55 1 5 . 4 4 4.94 13 1 _ c 5. 29 5.64 4. 44 14 1 -5 8. 20 7. 76 7. 54 15 1 -5 3.63 1.40 3. 65 16 1 -5 7. 49 8.99 4. 65 17 1 -5 4. 47 2. 67 4. 96 18 1 -5 3 . 2 0 * 1. 90 0. 28 19 1 -5 0. OC* 0. 98 0. 00 1 2 -5 13. 31 1 1 . 1 5 5. 55 2 2 -5 17. 64 1 6 . 4 4 3.74 3 2 -5 1 9 . 51 1 7 . 0 8 3. 21 4 2 -5 2 8 . 50 2 6 . 50 1. 66 5 2 -5 1 6 . 0 9 1 4 . 4 5 4. 21 6 2 -5 3. 92 4. 32 4 . 4 5 7 2 -5 14. 80 1 3 . 30 4. 39 H K L FO FC H E I G H T 8 2 -5 1 7 . 0 4 14. 31 3. 74 9 2 -5 3. 1 0 * 2. 25 0. 26 10 2 -5 2 . 7 3 * 3. 62 0. 17 11 2 -5 1 6 . 4 1 . 1 6 . 60 3. 89 12 2 -5 6.67 7. 24 5. 60 13 2 -5 6.54 6. 91 4.49 14 2 -5 1 2 . 12 1 3 . 19 4. 60 15 2 -5 9.54 9. 80 5.65 16 2 -5 5 . 7 1 5. 61 4. 25 ;-7 2 -5 0 . 7 9 * 1. 85 0. 01 18 2 -5 3 . 3 3 * 2. 35 0. 32 19 2 -5 1. 5 1 * 0. 73 0. 07 1 3 -5 1 7 . 9 3 1 7 . 18 3. 51 2 3 -5 7. 23 6. 67 7. 09 3 3 -5 1 0 . 9 0 10. 52 5. 83 4 3 -5 6. 08 5. 7.8 5. 76 5 3 -5 8.78 7. 34 5. 28 6 3 -5 7.97 8. S8 6.78 7 3 -5 1 0 . 13 9. 68 5. 47 8 3 -5 1 3 . 84 1 5 . 19 4.62 9 3 -5 7 . 3 3 6. 98 5. 75 10 3 -5 7. 12 7. 24 4. 72 11 3 -5 6.46 6. 63 3. 61 12 3 - c 5.06 4. 89 3. 28 13 3 -5 6.60 7. 25 3. 75 14 3 -5 6.52 5. 95 5. 66 15 3 -5 4. 83 4. 96 2. 94 —' -5 3. 3 0 * 2. 82 0. 28 i ' 3 — 5 3.51 1.29 3.13 18 3 -5 1 . 7 9 * 1. 10 0. 10 1 4 -5 5. 22 3. 61 3. 27 2 4 -5 1 2 . 17 1 1 . 77 4. 36 3 4 -5 1 2 . 4 2 1 3 . 36 4. 62 4 4 -5 4. 22 3. 59 3. 07 5 4 -5 5.59 6. CO 3. 74 6 4 -5 3 . 6 1 * 0. 84 0. 28 7 4 -5 3. 3 9 * 0. 81 0. 29 8 4 -5 9. 33 1 0 . 58 5. 12 9 4 -5 1 2 . 2 3 1 2 . 53 4. 45 10 4 -5 5. 79 6. 09 3. 83 11 4 -5 5.97 5.01 5. 33 12 4 -5 7. 08 7. 63 3. 96 13 4 -5 7 . 8 9 6. 71 5. 47 14 4 -5 5.12 3. 95 4. 67 15 4 -5 0 . 6 6 * 1. 65 0. 01 16 4 -5 2 . 1 0 * 1. 71 0. 12 1 5 -5 4.74 4. 68 2. 52 2 5 -5 7. 19 7. 91 4. 06 3 5 -5 7 . 7 2 7. 97 4. 23 4 5 -5 1 8 . 6 1 2 0 . 50 3. 04 5 5 -5 4. 38 3. 39 2.74 6 5 -5 5.33 5.71 2.66 7 5 -5 5. 88 4. 43 3. 82 8 5 -5 4.97 6. 44 2. 31 9 5 -5 4.50 3 . 66 2. 61 10 5 -5 3 . 0 6 * 1.76 0. 23 11 5 -5 4 . 8 2 3. 50 3. 50 12 5 -5 3 . 5 9 * 2. 76 0. 26 H K I F O F C H E I G H T 13 5 -5 3.00* 0. 50 0. 21 14 5 -5 2.05* 1.39 0. 12 1 6 -5 0. 00* 2.93 0. 00 2 6 -5 2. 08* 0.98 0. 06 3 6 -5 8. 10 8. 29 4. 87 4 6 -5 9.17 9. 94 4. 22 5 6 -5 8. 20 10. 74 3. 97 6 6 -5 3. 97* 3. 87 0. 24 7 6 -5 6. 99 6. 47 3. 57 8 6 -5 3. 15* 4. 40 0. 15 9 6 -5 2. 94* 0. 37 0. 19 10 6 -5 3.34* 3.50 0.21 11 6 -5 4.69 4.85 2. 65 1 7 -5 2.26* 2.21 0. 07 2 7 -5 6. 50 7. 64 3. 65 3 7 -5 4.01* 2. 83 0. 24 4 7 -5 5.71 6. 04 3. 27 5 7 -5 1.92* 3. 85 0. 05 6 7 -5 2. 36* 1.70 0.09 7 7 -5 1. 87* 0. 70 0. 07 1 0 -4 29. 72 27. CS 1. 58 2 0 -4 54. 80 57. 33 0. 49 3 0 -4 22.97 24.56 2. 51 4 0 -4 42. 23 40. 70 0. 80 5 0 -4 8. 01 8. 18 10. 14 6 0 -4 19. 44 20. CS 3. 28 7 0 -4 19. 74 17. 04 3. 17 8 0 -4 15. 42 16. 23 4. 67 *-> **\ t* i j « 3 —v. #- *n » £. % 3 1 t~ <*•» r\ J • £. \J 10 0 -4 4. 72 4. 72 6. 02 11 0 -4 5.86 5.63 8. 37 12 0 -4 10. 41 9. 76 5. 89 13 0 -4 3. 18* 3.79 0. 29 14 0 -4 4. 7 3 4. 47 4.98 15 0 -4 4. 69 4.43 3. 11 16 0 -4 6. 83 7.73 4. 44 17 0 -4 6. 73 6. 55 4.92 18 0 -4 0. 00* 1. 25 0. 00 19 0 -4 2. 87* 1.51 0. 23 20 0 -4 3. 7S 1. 96 3. 71 1 1 -4 7. 6C 6. 39 9. 25 2 1 -4 46.92 42. 98 0. 66 3 1 -4 41.69 38. 12 0. 83 4 1 -4 37. 62 36. 12 1.01 5 1 -4 24. 93 22.44 2. 16 6 1 -4 38. 67 36.41 0. 96 7 1 -4 26. 79 26.27 1. 88 8 1 -4 17. 57 16. 23 3. 74 9 1 -4 16.15 17.48 4. 11 10 1 -4 27. 68 27. 64 1. 73 11 1 -4 9. 77 8. 70 7. 34 12 1 -4 7. 24 6.42 6. 13 13 1 -4 5.93 6.13 5.72 14 1 -4 7. 72 8. 58 5. 44 15 1 -4 6. 00 6. 25 5. 66 16 1 -4 4. 61 4. 82 2. 77 17 1 -4 7.25 8. 17 5. 19 18 1 -4 4. 33 3. 04 4.72 H K L F O F C H E I G H T 19 1 -4 4.39 4. 74 4. 09 20 1 -4 4. 01 3. 96 3. 37 1 2 -4 43.40 39. 39 0. 77 2 2 -4 39. 53 34. 75 0. 92 3 2 -4 21.72 19. 99 2. 71 4 2 -4 9.44 8. 55 7. 64 5 2 -4 35. 28 30. 64 1.14 6 2 -4 31.98 27. 46 1.35 7 2 -4 16. 82 15. 82 4. 08 8 2 -4 22. 65 21.31 2. 47 9 2 -4 8.74 9. 55 6. 54 10 2 -4 3.71 2. 75 3.51 11 2 -4 10.53 9. 71 5. 78 12 2 -4 5.'94 5. 19 5. 07 13 2 -4 6.55 5. 51 4. 99 14 2 -4 6.63 6. 44 4. 63 15 2 -4 6. 02 7. 31 3. 46 16 2 -4 6. 35 5. 75 5. 53 17 2 -4 7. 03 6. 90 5. 11 18 2 -4 3. 84 3. 25 3.23 19 2 -4 3.58* 3. S7 0. 24 1 3 -4 17.10 15. 10 3. 87 2 3 -4 19.64 20. 82 3. 21 3 3 -4 12. 79 12. 96 5. 34 4 •j -4 27. 81 28. 02 1.73 5 3 -4 21 . 05 20. 42 2. 78 6 3 -4 13. 34 13. 53 4. 88 7 3 -4 14 . 44 12. 63 4. 54 U -"» J ft — <•> s~ /> ̂  U • U £. ii - i «~ •* • / 0 (i r~ -» *•* • -J -J 9 3 -4 9. 94 11.01 6. 03 10 3 -4 5. 28 5. 28 4. 75 11 3 -4 13. 80 14. 76 4. 44 12 3 -4 5.41 5. 11 4.64 13 3 -4 6.55 6. 16 4. 51 14 3 -4 9.78 10. 33 5. 20 15 3 -4 7.19 8. 16 3. 99 16 3 -4 10.31 9. 34 5. 63 17 3 -4 5. 18 5. 33 3. 39 18 3 -4 3.81 2. 94 3. 53 19 3 -4 5. 06 4. 50 4. 21 1 4 -4 6. 25 5. 75 5. 65 2 4 -4 18.09 19. CO 3. 26 3 4 -4 8.34 7. 64 5. 76 4 4 -4 16. 26 15. 74 3. 67 5 4 -4 3. 09* 1. 84 0. 26 6 4 -4 13.43 13. 06 4. 41 7 4 -4 12.01 12. 18 4. 89 8 4 -4 6.12 6. 20 4. 07 9 4 -4 13. 06 13. C2 4. 34 10 4 -4 14. 25 14. 94 4. 16 11 4 -4 7.11 7. 39 4. 80 12 4 -4 4. 33 2. 98 2. 58 13 4 -4 13.49 12. 52 4. 32 14 4 -4 10. 24 10. 18 4. 72 15 4 -4 6.68 6. 41 5.06 16 4 -4 4.26 2. 30 3. 92 17 4 -4 3.48 1. 67 4. 27 1 5 -4 11.97 15. 25 4. 27 H K I FO FC WEIGHT 2 5 -4 6.56 8. 31 3.58 3 5 -4 3.76* 4. 18 0. 20 4 5 -4 4.45 4. 69 2.55 5 5 -4 4.82 4.49 3. 12 6 5 -4 5. 40 6. 38 2..45 7 5 -4 10. 28 9.41 4. 66 8 5 -4 3. 53* 4. 09 0.22 9 5 -4 10.66 11.25 4. 80 10 5 -4 16. 33 17. 38 3. 40 11 5 -4 4. 76 4. 38 3. 39 12 5 -4 7.75 8. 13 4. 30 13 5 -4 3. 08* 1.66 0. 16 14 5 -4 4. 18 2.64 3. 14 15 5 -4 3.86 2.77 3. 08 1 6 -4 15. 27 17. 59 3. 49 2 6 -4 10. 23 11.14 3. 38 3 6 -4 8.21 8. 35 4.51. 4 6 -4 3. 9 8* 3. 37 0. 21 5 6 -4 7. 14 7. 35 3. 60 6 6 -4 9. 80 9. 44 4. .32 7 6 -4 12. 15 12. 82 4. 28 8 6 -4 4. 60 3. 99 2. 35 9 6 -4 6. 68 6. 89 3. 83 10 6 -4 3.50* 3.99 0. 18 11 6 -4 0. 00* 2. 63 0. 00 12 6 -4 3.08* 2. 92 0. 19 13 6 -4 2. 91* 2. 59 0. 17 1 7 -4 4. 97 4, 96 2. 39 2 - 4 4. 3 7 * 6.3 2 0. 1 9 3 7 -4 5. 47 3. 15 4. 25 4 7 -4 8. 22 10.59 3.81 5 7 -4 5. 91 4. 43 4. 05 6 7 -4 3. 96* 3. 52 0. 18 7 7 -4 5. 33 5.75 2. 62 8 7 -4 4.01 4. 35 2. 34 9 7 -4 3. 51* 2.98 0. 20 1 0 _ 3 13. 04 1 3. 59 6.5 3 2 0 -3 38. 02 32. 90 1. 00 3 0 -3 22. 52 24. 19 2. 62 4 0 _3 27. 02 25.53 1.91 5 0 _ 3 24. 82 25. 70 2. 20 6 0 -3 13. 56 14. 61 5.71 7 0 -3 24. 29 25. 24 2. 30 8 0 -3 25. 73 23.71 2. 06 9 0 -3 15. 4C 15. 47 4. 64 10 0 -3 2. 91 0.59 4. 85 11 0 -3 19. 74 19.95 3. 17 12 0 -3 0. 00* 1.65 0. 00 13 0 -3 15. 11 15.87 4. 01 14 0 -3 11. 27 9.70 5. 47 15 0 -3 2.95* 1. 96 0. 28 16 0 -3 9. 61 10. 06 5. 37 17 0 -3 2. 33* 1. 15 0. 15 18 0 -3 4.77 4.39 4. 07 19 0 -3 5. 27 5.60 3.93 20 0 -3 5. 73 5.74 4. 69 21 0 -3 3.50 2.01 3. 48 1 1 -3 11. 69 12. 20 7. 67 H K L FO FC WEIGHT 2 •, -3 47.01 43. 39 0.66 3 1 -3 21. 02 23. 26 3. 00 4 1 -3 14. 61 16. 12 5. 46 5 1 -3 40.41 37. 58 0.89 6 1 -3 37. 65 36. 40 1. 01 7 1 -3 21.84 21. 94 2.78 8 1 -3 29. 54 27. 70 1. 59 9 1 -3 17. 67 17. 10 3. 80 10 1 -3 4. 29 4. 30 5.68 11 1 -3 19.45 18. 09 3. 21 12 1 -3 8. 97 8. 54 7. 15 13 • 1 -3 6. 02 7. 18 4. 88 14 1 -3 5. 64 5. 67 5. 48 15 1 -3 3.61* 4. 36 0. 25 16 1 -3 0. 00* 0. 36 0. 00 17 1 -3 6.41 7. 37 4. 12 18 1 -3 7. 89 8. 24 4. 77 19 1 -3 4.60 4. 25 3. 33 20 1 -3 5.56 5. 34 4. 65 21 1 -3 1.20* 1.65 0. 05 1 2 -3 28. 16 26. 22 1.75 2 2 -3 22. 08 19. 81 2. 73 3 2 -3 30.69 29. 04 1. 47 4 2 -3 33.01 33. S3 C. 99 5 2 -3 35. 09 33. 51 1. 13 6 2 -3 34 . 98 34. 6 8 1. 17 7 2 -3 24. 76 23. 62 2. 15 8 2 -3 22.55 1 9. 58 2.55 9 2 - 3 2 3.91 2 2. 63 2.33 10 2 -3 13.93 13. 84 5. 16 11 2 - 3 5.51 5. 38 5. 36 12 2 -3 3. 00* 2. 13 0. 30 13 2 - 3 11.41 13. 05 4. 84 14 2 -3 11.01 10. 45 5. 98 15 2 -3 2. 19* 2. 12 0. 12 16 2 -3 1 . 26* 1. 16 0. 04 17 2 -3 6. 63 6. 89 4. 20 18 2 -3 8.85 9. 37 4.60 19 2 -3 7. 13 7. 99 4. 27 20 2 -3 4 . 86 3. 86 5. 17 1 3 -3 30. 21 30. 73 1. 51 2 3 -3 34 . 80 32. 25 1.16 3 3 -3 28. 94 25. 77 1.61 4 3 -3 32.96 28. 76 1. 29 5 3 -3 17.78 13. 94 3. 72 6 3 -3 21 . 69 18. 99 2. 72 7 3 -3 16. 53 14. 96 4, 05 8 3 -3 21.08 18.71 2.66 9 3 -3 24. 12 22. 48 2. 19 1b 3 -3 18. 29 16. 86 3. 32 11 3 -3 11.32 12. C3 5. 05 12 3 -3 7.84 8. 54 5. 32 13 3 -3 6.09 6. 19 4. 56 14 3 -3 12.10 12. 99 4. 43 15 3 -3 5.77 5. 18 5. 18 16 3 -3 7. 55 7. 88 5. 29 17 3 -3 12.08 11. 39 4.30 18 3 -3 9.86 9. 69 5. 39 H K L FO FC WEIGHT 19 3 -3 2. 16* 1.77 0. 12 1 4 - 3 23. 7 7 21. 45 2. 20 2 4 -3 24. 86 23.53 2. 09 3 4 -3 16.92 15.95 3.70 4 4 -3 9. 18 8. 23 5. 4 3 5 4 -3 8 . 48 9. 36 7. 14 6 4 -3 4. 04 3. 95 3. 27 7 4 -3 7. 30 6. 92 4. 73 8 4 -3 8 . 21 8. 37 5. 05 9 4 - 3 12. 21 12. 96 5. 02 10 4 -3 11.68 11.56 4. 90 11 4 -3 4.76 4. 13 2. 58 12 4 -3 6.48 7. 05 3. 51 13 4 -3 9. 45 9. 43 5. 17 11 4. -3 10. 52 10. 32 4. 66 15 4 -3 2. 55 * 0. 53 0.13 16 4 -3 4. 52 3. 36 3, 94 17 4 - 3 4. 30 3. 53 3. 23 18 4 - 3 3. 3 3 * 2. 25 0. 28 1 5 -3 13.88 13. 27 4. 01 2 5 -3 10. 74 10. 89 4. 57 3 5 -3 16.47 17. 57 3. 48 a 5 -3 14.71 15. 85 3.91 5 5 -3 19. 38 21 . 29 2. 72 6 5 -3 7. 37 9.15 3. 84 7 5 -3 11, 06 1 1. 37 4. 57 8 5 -3 11. 27 11. 04 4.68 9 5 -3 15. 50 15. 47 3.65 10 o — j 3 . 9 2 ' 3. 76 6. 19 11 5 -3 12. 21 1 2. 17 3. 80 12 5 -3 10. 85 11. 05 4. 65 13 5 -3 6.47 6.52 3. 61 m 5 - 3 5. 02 3. 27 4. 51 15 5 - 3 3. 68 2. 27 3. 14 16 5 - 3 3. 44* 2. 70 0. 24 1 6 -3 10. 06 11. 23 3. 51 2 6 -3 8. 57 8. 94 4. 03 3 6 -3 14. 53 15.43 3. 82 4 6 -3 8.73 8. 49 4. 32 5 6 - 3 10. 89 1 1. 30 4. 44 6 6 -3 1 .71* 2. 27 0. 03 7 6 _ 3 3. 44* 3. 40 0. 16 8 6 - 3 2. 9 1 * 2. 81 0. 12 9 6 -3 0. 00 * 1. 28 0. 00 10 6 -3 10. 16 10. 40 4.70 11 6 -3 4. 27 3. 50 2. 49 12 6 -3 3. 67 * 4. 68 0. 20 13 6 -3 7. 76 7. 86 4. 86 14 6 _ 3 3. 41 * 3. 36 0. 18 1 7 -3 2 . 2 6 * 3.83 0. 05 2 7 -3 4.42 5. 03 1. 91 3 7 -3 7. 07 6.95 3. 97 4 7 -3 6. 50 6. 07 2. 95 5 7 -3 2. 5 1 * 4. 97 0.07 6 7 -3 2. 44* 3.31 0. 08 7 7 -3 5. 01 4.41 2. 49 8 7 - 3 5. 81 5.87 3. 57 9 7 -3 4. 42 3.30 2.61 H K L FO FC WEIGHT 10 7 - 3 4 .30 3. 22 2. 37 1 8 -3 5.89 7. 08 2. 74 2 8 -3 2. 49 * 1. 74 0. 07 3 8 - 3 3 . 4 7 * 2.21 0. 15 1 0 -2 10.42 11. 87 7.57 2 0 -2 25. 02 24. 66 2. 17 3 0 -2 19.75 22. 77 3.40 4 0 - 2 34. 40 33. 89 1. 22 5: 0 - 2 44. 42 46. C3 0.74 6 0 -2 45. 76 46. 14 0. 69 7 0 -2 40.36 42. 66 0. 89 8 0 -2 15. 76 14. 89 4.71 9 0 -2 17.54 17. 90 3. 94 10 0 -2 8.71 9. 00 8. 79 11 0 -2 2 . 1 3 * 0. C6 0. 28 12 0 -2 11.91 11. 28 6. 03 13 0 -2 9.88 10. 26 6. 10 14 0 -2 13. 75 14. 32 4. 67 15 0 -2 4.59 5. 82 4. 29 16 0 -2 2. 26 * 1.84 0. 13 17 0 -2 6.23 6. 58 4. 81 18 0 -2 4. 29 2. 90 4. 59 19 0 - 2 2. 25* 3.41 0. 11 20 0 -2 2. 50 * 2.15 0. 17 21 0 -2 5.92 5. 59 5. 21 1 1 -2 47. 23 45. 23 0. 65 2 1 -2 7 1 . 13 68. 38 0.29 3 1 -2 35. 62 32. 56 1. 13 4 1 -2 4 7 . 34 45. 63 0. 65 5 1 -2 16.63 17. C7 4 .55 6 1 -2 8. 68 8. 25 10.61 7 1 -2 18.61 16.23 3. 68 8 1 -2 20. 27 19. 98 3. 18 9 1 -2 12. 34 12.31 6. 55 10 1 -2 10. 51 12. 30 7. 29 11 1 -2 12. 94 14. 24 6. 07 12 1 -2 15. 20 15. 15 4. 37 13 1 -2 12.60 12. 04 5. 26 14 1 -2 7. 35 8. S7 5. 67 15 1 -2 5. 81 7. 15 4. 65 16 1 -2 3 .60 * 4. 58 0. 24 17 1 -2 5.68 5. 40 4. 35 18 1 -2 8. 00 7. 43 5.44 19 1 -2 0. 00* 0. 58 0.00 20 1 -2 2 . 9 7 * 2. 49 0. 19 21 1 -2 3.78 2. 90 3. 69 1 2 -2 7.81 8. 61 10. 32 2 2 -2 23.87 22. 40 2. 35 3 2 -2 40. 59 37. 82 0. 88 4 2 -2 33. 88 32. 02 1. 24 5 2 - 2 35.80 32. 23 1. 11 6 2 -2 30.54 27.45 1.49 7 2 -2 27.03 25. 16 1. 87 8 2 -2 7.42 7. 32 9. 06 9 2 -2 11.35 11. 94 6. 33 10 2 -2 7.99 8. 14 7.65 11 2 -2 9.11 9. 23 7. 25 12 2 -2 8.92 9.83 6. 10 H K 1 FO FC HEIGHT 13 2 -2 6. 60 6. 39 6. 67 14 2 -2 5. 95 7.43 3. 90 15 2 -2 6.67 7. 24 5. 60 16 2 -2 6. 35 6.81 4. 30 17 2 -2 4.30 3.76 3. 59 18 2 -2 4. 93 5. 92 2. 56 19 2 -2 2. 75* 0.73 0. 16 20 2 -2 7. 15 7.74 4. 49 21 2 -2 4.49 4. 18 3. 56 1 3 -2 10. 36 9. 2 1 6. 85 2 3 -2 33. 90 35. 62 1.21 3 3 -2 30. 98 30.68 1. 45 4 3 -2 44. 10 39. 62 0.74 5 3 -2 29. 71 27.77 1. 57 6 3 -2 30. 59 27. 34 1. 46 7 3 -2 12. 05 1 1. 07 6. 38 8 3 -2 4. 82 3.72 4. 71 9 3 -2 20. 60 18. 38 2. 87 10 3 -2 27.90 25. 37 1.70 11 3 -2 12. 85 13. 12 5. 09 12 3 -2 7. 10 7. 25 6. 11 13 3 -2 18.08 19. 52 3. 18 14 3 -2 3.43* 3. 28 0. 22 15 3 -2 12. 07 12. 10 4.3 8 16 3 -2 3. 80 1.95 2. 97 17 3 -2 4. 88 4. 24 4. 22 18 3 -2 1.91* 2. 64 0. 07 19 3 -2 4. 04 4.35 2. 53 20 3 -'2' 3. 2 3' * 3.96 0.2 3 1 4 -2 7. 59 9.47 6. 17 2 4 -2 16. 51 16.74 3. 96 3 4 -2 14. 29 14. 90 4. 57 4 4 -2 22. 72 21.04 2. 39 5 4 -2 9.54 9.13 6. 02 6 4 -2 15.03 14. 15 4. 35 7 4 -2 6.91 5. 22 5. 55 8 4 -2 17. 03 1 4.33 3.76 9 4 -2 17. 31 15.65 3. 32 10 4 -2 5. 32 4. 97 4. 13 11 4 -2 9.30 9.91 5. 46 12 4 -2 16. 22 16.28 3. 58 13 4 -2 7.21 6. 56 5.49 14 4 -2 16. 98 16.99 3. 28 15 4 -2 8.30 8. 34 4. 90 16 4 -2 9. 28 8.88 5. 69 17 4 -2 5. 55 4. 93 4. 32 18 4 -2 2. 49* 1.73 0. 15 19 4 -2 0.66* 1.69 0.01 1 5 -2 4. 14 5.65 2. 30 2 5 -2 8.72 9. 11 4. 29 3 5 -2 6. 94 7. 07 3. 31 4 5 -2 4.41 3. 08 3. 12 5 5 -2 9.67 10. 38 4. 51 6 5 -2 18.77 18.78 2. 92 7 5 -2 13.08 14. 24 4. 48 • 8 5 -2 5.77 6.61 3. 54 9 5 -2 7. 12 6. 94 3. 72 10 5 -2 6.55 7. 17 4. 00 H K L FO FC HEIGHT 11 5 -2 0.00* 2. 34 0. 00 12 5 -2 6.51 6. 39 4. 81 13 5 -2 6.29 6. 35 3. 98 14 5 -2 6.52 6. 91 4. 17 15 5 -2 0.52* 2. 22 0. 00 16 5 -2 5.58 4. C1 4. 00 17 5 -2 3. 66 3. 36 3. 01 1 6 -2 7. 08 9. 66 2. 91 2 6 -2 4.77 4. 05 2. 29 3 6 -2 9.44 11.75 3. 12 4 6 -2 7.02 8. 43 2. 52 5 6 -2 3. 97* 2. 93 0. 20 6 6 -2 13 . 03 15. 19 3. 65 7 6 -2 7.59 8. 92 3. 21 8 6 -2 5. 76 5. 15 2. 52 9 6 -2 2. 95* 2. 28 0. 14 10 6 -2 3. 30 9. 22 4. 39 11 6 -2 5. 82 6. 09 2. 55 12 6 -2 5. 59 5. C3 3. 65 13 6 -2 5. 40 4. 63 3. 76 14 6 -2 2.64* 3. C9 0.15 15 6 -2 6.98 6. 57 5. 84 1 7 -2 4.72 4. 93 2. 13 2 7 -2 3. 57* 6. 16 0. 13 3 7 -2 3.51* 3. 73 0. 12 4 7 -2 9.82 12. C3 3. 72 5 7 -2 10.02 10. 73 4. 36 6 7 -2 4. 47 2. 06 2. 28 7 7 - 2 0. GO* 37 G. 00 8 7 -2 4. 09* 4. 23 0. 18 9 7 -2 7. 77 8. 10 5. 25 10 7 -2 6.38 4. C1 3. 85 11 7 -2 0.00* 0. 94 0. 00 1 8 -2 4.70* 6. 40 0. 15 2 8 -2 4. 29* 2. 91 0.13 3 8 -2 4.21* 4. 67 0.12 4 8 -2 4.02* 4. 60 0. 14 5 8 -2 3. 06* 1. 26 0. 10 1 0 -1 6.54 5. 79 14.91 2 0 -1 51.15 5 3. 70 0.53 3 0 -1 52.04 52. 85 0. 53 4 0 -1 70. 88 74. Id 0. 29 5 0 -1 48.03 51. 20 0. 63 6 0 -1 24.78 25. 73 2. 27 7 0 -1 12. 96 12. 77 6. 64 8 0 -1 40. 81 41. 53 0. 86 9 0 -1 16.57 17. 86 4. 33 10 0 -1 44. 84 44. 73 0. 71 11 0 -1 4. 35 3. 32 5. 47 12 0 -1 8. 35 9. 05 8. 58 13 0 -1 8.79 7. 94 7. 00 14 0 -1 30. 19 30. 30 1. 45 15 0 -1 0. 93* 0. 76 0. 02 16 0 -1 8.81 8. 48 4. 49 17 0 -1 0. 00* 1. 10 0.00 18 0 -1 3.11* 0. 86 0. 18 19 0 -1 4. 52 4. 91 2. 38 20 0 -1 2.82* 1. 67 0.15 H K L FO FC WEIGHT 21 0 -1 7. 95 6.66 5. 08 1 1 -1 25. 85 21. 88 2. 02 2 1 -1 47. 86 44.52 0. 63 3 1 -1 26. 19 24. 95 1. 99 4 1 -1 61. 29 57. 17 0. 39 5 1 -1 27. 93 29.19 1.80 6 1 -1 20. 16 17. 87 3. 28 7 1 -1 14. 06 12. 82 5.71 8 1 -1 14. 99 15. 19 5. 27 9 1 -1 30. 87 32. 23 1. 45 10 1 -1 3. 65 6. 16 5. 06 11 1 -1 9.73 9. 27 7. 29 12 1 -1 4. 55 3.42 6. 15 13 1 -1 9.47 9.69 6.69 n 1 -1 12. 94 13. 01 5. 19 15 1 -1 9. 50 9. 00 7. 02 16 1 -1 5. 98 6. 20 3.21 17 1 -1 7.29 6.41 5. 92 18 1 -1 4. 06 3. 23 2. 44 19 1 -1 3. 99* 3. 84 0. 22 20 1 -1 4. 05 2. 81 2. 56 21 1 -1 5.45 4. 16 4.33 1 2 -1 58. 05 51.43 0. 44 2 2 -1 24. 90 20.22 2. 18 3 2 -1 9. 96 8. 29 8. 61 4 2 -1 53. 44 49.76 0. 51 5 2 -1 8. 70 8. 15 10. 73 6 2 -1 21. 36 23. 03 2.91 7 2 - -j 3.3 2 3.6 7 5 . 54 8 2 -1 16. 62 15. 40 4. 26 9 2 -1 23. 10 22.43 2. 46 10 2 -1 8.38 7.80 8. 13 11 2 -1 14. 15 12. 69 5. 03 12 2 -1 5. 78 6. 96 6. 60 13 2 -1 8. 19 8.53 5. 65 14 2 -1 5. 16 4. 70 4. 87 15 2 -1 7. 46 6. 93 5. 13 16 2 -1 5. 08 4.43 3. 15 17 2 -1 6. 7C 5. 70 4.64 18 2 -1 9. 85 9. 20 5. 34 19 2 -1 2. 27* 2.8 8 0. 07 20 2 -1 4. 87 2. 68 4. 32 21 2 -1 5. 09 3.79 3. 70 1 3 -1 16. 87 15. 11 4. 02 2 3 -1 5. 14 4. 96 6. 70 3 3 -1 40. 05 37. 20 0. 89 4 3 -1 17.51 16. 25 3. 89 5 3 -1 37. 71 35. 58 1. 00 6 3 -1 3. 54 1. 83 4.91 7 3 -1 12. 47 10. 64 6. 04 8 3 -1 3. 69 3.00 4. 13 9 3 -1 6. 04 6. 40 6.13 10 3 -1 5. 21 3.73 5. 65 11 3 -1 13. 37 13.76 4. 85 12 3 -1 15. 06 13. 85 4. 27 13 3 -1 2. 71* 1. 79 0. 17 14 3 -1 9. 36 8. 50 5. 44 15 3 -1 1.19* 2.41 0. 02 H K L FO FC WEIGHT 16 3 _1 5. 30 5. 12 2. 68 17 3 -1 10. 11 8. 79 4. 44 18 3 -1 0.58* 1. 21 0. 01 19 3 -1 4. 19 3. 02 2. 82 20 3 -1 0. 00* 1.9-6; 0. 00 1 4 -1 8.17 10. 21 5. 36 2 4 -1* 30. 30 28. 83 1. 46 3 4 -1 26.50 22. 54 1. 85 4 4 -1 9.12 7. 39 6.76 5 4 -1 4.40 5. 15 4.70 6 4 -1 9. 87 9. 18 6. 28 7 4 -1 10.04 9. 40 5.58 8 4 -1 15. 17 12. 75 4. 13 9 4 -1 13.04 12. 33 4. 64 10 4 -1 7. 57 6. 98 5. 07 11 4 -1 8.39 8. 62 4. 81 12 4 -1 4. 68 2. 77 2. 73 13 4 -1 19.28 18. 02 2. 86 14 4 -1 2. 75* 1. 63 0. 10 15 4 -1 6.42 6. 99 3. 33 16 4 -1 7.53 6. 88 4. 36 17 4 -1 7. 38 7. 46 3. 93 18 4 -1 6. 66 6. 50 3. 87 19 4 -1 3.76 2. 32 2. 35 1 5 -1 8. 37 8. 58 4. 04 2 5 -1 13.72 13. 52 4. 20 3 5 -1 9.85 10. 19 4. 11 4 5 -1 6.74 7. 96 4.07 5 5 - i y. 06 8. 74 5. 70 6 5 -1 5.81 4. 17 4.12 7 5 -1 10. 30 8. 80 5. 17 8 5 -1 3.31* 1. 65 0. 15 9 5 -1 6.42 5. 30 2. 97 10 5 -1 16.74 15. 48 3. 49 11 5 -1 10.29 10. 56 3. 99 12 5 -1 3.36* 4. 12 0. 15 13 5 -1 8.69 9. 09 4. 26 14 5 -1 0 . 00* 2. 91 0. 00 15 5 -1 7.57 6. 37 4.01 16 5 -1 6. 48 4. 97 3. 71 17 5 -1 4.32 2. 69 2. 84 1 6 -1 16. 17 16. 97 3. 13 2 6 -1 4. 17* 3. 85 0. 14 3 6 -1 12. 68 12.61 3. 01 4 6 -1 12. 17 10. 67 3. 57 5 6 -1 22. 25 21. 72 2. 12 6 6 -1 8.. 24 9. 75 3. 14 7 6 -1 12.86 9. 52 3. 69 8 6 -1 20. 88 19. 69 2. 32 9 6 -1 8.90 8. 45 3. 93 10 6 -1 8.07 6. 68 3. 66 11 6 -1 8.59 9. 26 5. 04 12 6 -1 6.05 5. 73 3. 64 13 6 -1 4.42 3. 29 2. 16 14 6 -1 4.68 3. 12 2.99 15 6 -1 3. 02* 2. 76 0. 18 1 7 -1 13.08 13. 04 3. 55 2 7 -1 11 .36 10. 98 3. 59 H K L FO FC HEIGHT 3 7 -1 6.77 6.82 2. 55 a 7 -1 10. 90 10. 29 3. 14 5 7 -1 4. 25* 4. 66 0. 13 6 7 -1 8. 12 6. 92 3. 36 7 7 -1 8. 68 7. 49 3. 27 8 7 -1 4. 23* 5. 27 0.19 9 7' -1 2. 58* 3.45 0. 08 10 7 -1 3. 03* 0. 94 0. 14 11 7 -1 6. 96 6,68 4. 35 12 7 -1 3. 94* 2. 48 0. 22 1 8 -1 5.49 6.44 1. 34 2 8 -1 3. 20* 4. 17 0, 06 3 8 -1 3. oe* 4. 11 0. 07 4 8 -1 5. 35 3.03 2. 06 5 8 -1 2. 17* 0. 73 0.05 6 8 -1 3. 43* 3. 91 0. 10 1 0 0 6.25 7.33 11. 05 2 0 0 43. 42 48.58 0. 70 3 0 0 10. 64 13. 28 4. 37 a 0 0 68. 74 83.66 0. 31 5 0 0 43. 14 50, 85 0.72 6 0 0 7. 45 7. 47 3. 39 7 0 0 0. 00* 5.33 0. 00 8 0 0 25. 65 31. 42 2. 09 9 0 0 4. 41 3. 50 5. 02 10 0 0 4.37 0. 63 4. 34 11 0 0 20. 69 23. 51 2. 86 12 0 0 9. 49 9. 50 5..88 <• «> 1 .J r\ \J s\ V <• » . ^ J . i • / T r\ <^ <* O. O I 14 0 0 3. 26* 4. 14 0. 22 15 0 0 3. 76 3 • 23 2. 93 16 0 0 1. 89* 1.91 0. 06 17 0 0 2. 73* 3.45 0. 17 18 0 0 8. 6C 8.09 4. 76 19 0 0 2. 10* 0. 38 0. 12 20 0 0 0.00* 0. 33 0. 00 21 0 0 2.59* 2. 06 0. 16 22 0 0 5. 09 3.58 3. 92 1 1 0 51. 36 46. C8 0. 52 2 1 0 57. 55 51.14 0.43 3 1 0 86. 93 82.54 0. 20 4 1 0 51. 45 52. 24 0. 55 5 1 0 31. 69 31. 18 1. 42 6 1 0 41. 89 43. 69 0.83 7 1 0 22. 16 24. 58 2. 70 8 1 0 6.27 6.99 10. 76 9 1 0 17. 15 18. 06 4. 08 10 1 0 4. 90 5. 19 8. 12 11 1 0 5. 58 6.42 6. 11 12 1 0 5. 33 4.63 6. 48 13 1 0 6. 30 6. 05 7. 72 14 1 0 9. 38 9.6 5 5. 59 15 1 0 6. 23 6.68 4. 39 16 1 0 11.41 11.32 4. 86 17 1 0 11. 55 11.43 4. 28 18 1 0 4. 85 5.41 2. 32 19 1 0 3. 50* 1.37 0. 21 20 1 0 2. 87* 1.08 0. 20 H K L FO FC HEIGHT 21 . 1 0 3.65* 3. C5 0. 27 0 2 0 43. 34 3 5. 95 0. 76 1 2 0 74.86 63. 10 0. 26 2 2 0 48.41 39. 39 0.62 3 2 0 63. 76 55. 52 0. 36 4 2 0 12.90 11. 85 6. 56 5 2 0 24. 28 25. 85 2. 28 6 2 0 34.63 32. 33 1. 19 7 2 0 25.02 25. 52 2. 17 8 2 0 13.71 15. 01 5. 58 9 2 0 14. 15 14. 99 5. 45 10 2 0 7.95 7. 89 7.72 11 2 0 8.02 7. 14 6. 31 12 2 0 15.73 17. C9 3. 91 13 2 0 7.01 8. 00 5.78 14 2 0 5. 98 7. 28 4. 40 15 2 0 4.77 4. 96 3. 32 16 2 0 4.05* 4. 76 0. 22 17 2 0 6. 58 7. 32 4. 02 18 2 0 4. 48 3. 60 3.49 19 JL 0 5.29 • 4. 56 3. 08 20 2 0 6.57 6. 08 4. 28 21 2 0 3.23* 1. 38 0. 24 1 3 0 10.42 8. 29 7. 00 2 3 0 16.03 15. 54 4. 65 3 3 0 33. 03 28. 18 1. 27 4 3 0 31. 13 30. 83 1.43 5 3 0 29.23 29. 35 .1 . 60 o X) I S * . / / 1 H . U O 7 3 0 33. 61 34. 51 1. 25 8 3 0 25. 59 26. 02 1. 98 9 3 0 9.59 10. 34 6. 85 10 3 0 5,70 4. 97 4. 63 11 3 0 14. 32 13. 62 4. 57 12 3 0 3.36 7. 53 5. 92 13 3 0 11.13 11. 96 4. 69 14 3 0 9.45 9. 37 5. 52 15 3 0 8.17 8. 10 4. 47 16 3 0 7.46 6. 73 4. 44 17 3 0 11. 50 11. 64 4. 13 18 3 0 9.71 9. 37 5.46 19 3 0 3. 16* 1. 98 0. 16 20 3 0 2.65* 1. 74 0. 14 0 4 0 73. 95 62. 63 0. 27 1 4 0 41. 43 33. 29 0. 82 2 4 0 22.62 19. 53 2. 46 3 4 0 13. 95 11. 57 4. 89 4 4 0 6.58 6. 50 4.99 5 4 0 12. 52 11. 50 5. 38 6 4 0 13.22 13. 70 5. 10 7 4 0 11.13 11. 18 5. 46 8 4 0 10. 12 10. C4 5.25 9 4 0 14.75 15. 65 4. 08 10 4 0 10.63 10. 78 5. 37 11 4 0 11. 84 10. 91 5. 16 12 4 0 8.48 8. 36 5.49 13 4 0 10.20 10. 63 4. 81 14 4 0 7. 57 6. 05 4.58 C3 H K L F O F C W E I G H T H K L F O F C W E I G H T 1 5 4 0 2 . 3 0 * 4 . 4 7 0 . 0 6 1 0 1 6 8 . 4 0 7 2 . 8 5 0 . 3 0 1 6 4 0 7 . 8 8 8 . 8 9 4 . 0 1 2 0 1 5 8 . 6 2 6 5 . 1 8 0 . 3 9 1 7 4 0 3 . 4 1 * 3 . 9 1 0 . 1 8 3 0 1 4 . 8 2 4 . 7 6 1 2 . 4 9 1 8 4 0 5 . 0 1 4 . 5 6 3 . 7 4 4 0 1 4 1 . 5 4 4 3 . 8 8 0 . 8 4 1 9 4 0 7 . 0 6 6 . 3 5 4 . 5 8 5 0 1 1 3 . 3 9 1 4 . 6 1 6 . 2 5 1 5 0 1 7 . 0 1 1 6 . 0 0 3 . 1 4 6 0 1 2 6 . 5 2 3 2 . 7 4 1 . 9 7 2 5 0 1 0 . 5 2 8 . 8 9 4 . 5 0 7 0 1 3 6 . 3 2 3 7 . 1 4 1 . 0 9 3 5 0 1 8 . 6 6 1 5 . 7 4 3 . 0 9 8 0 1 3 3 . 6 7 3 7 . 6 8 1 . 2 6 4 5 0 5 . 0 5 4 . 6 2 3 . 2 8 9 0 1 7 . 0 2 6 . 3 9 8 . 8 7 5 5 0 1 1 . 1 6 1 0 . 2 0 4 . 9 4 1 0 0 1 1 8 . 9 9 1 9 . 7 9 3 . 4 8 6 5 0 5 . 8 3 5 . 2 9 3 . 1 2 1 1 0 1 3 . 7 3 4 . 5 4 4 . 7 9 7 5 0 1 0 . 3 0 1 0 . 2 4 5 . 2 3 1 2 0 1 6 . 0 0 6 . 6 1 8 . 0 1 8 5 0 1 6 . 1 4 1 6 . 1 2 3 . 3 4 1 3 0 1 7 . 2 4 7 . 11 6 . 6 7 •9 5 0 1 4 . 2 8 1 5 . 2 9 3 . 5 1 1 4 0 1 1 1 . 8 4 1 1 . 9 2 5 . 2 8 1 0 5 0 2 0 . 7 0 1 9 . 9 3 2 . 5 3 1 5 0 1 2 . 6 5 * 1 . 0 6 0 . 2 0 1 1 5 0 1 6 . 8 8 1 5 . 8 9 3 . 1 7 1 6 0 1 8 . 0 4 9 . 3 4 5 . 2 8 1 2 5 0 5 . 4 3 4 . 6 5 3 . 2 3 1 7 0 1 2 . 2 7 * 1 . 2 5 0 . 0 9 1 3 5 0 5 . 0 9 4 . 6 6 2 . 8 9 1 8 0 1 1 2 . 6 7 1 2 . 5 1 4 . 9 5 1 4 5 0 8 . 3 2 7 . 5 8 5 . 2 5 1 9 0 1 2 . 8 3 * 2 . 8 5 0 . 1 2 1 5 5 0 5 . 6 9 4 . 8 3 3 . 4 2 2 0 0 1 2 . 5 7 * 1 . C 4 0 . 1 3 1 6 5 0 € . 5 3 5 . 6 5 3 . 7 3 2 1 0 1 3 . 4 3 * 2 . 1 0 0 . 3 1 1 7 5 0 0 . 9 9 * 1 . 0 5 0 . 0 2 0 1 1 1 4 . 3 4 1 5 . 0 9 5 . 6 7 0 6 0 1 2 . 8 2 1 1 . 4 1 2 . 8 9 1 1 1 2 3 . 8 0 2 5 . 3 5 2 . 3 3 1 6 0 5 . 6 5 4 . 5 2 2 . 0 3 2 1 1 € 6 . 6 6 6 9 . S 9 0 . 3 3 2 6 0 1 5 . 1 6 1 3 . 8 S 3 . 1 7 3 1 1 1 3 5 . 3 8 1 3 3 . 3 1 0 . 0 8 3 6 0 6 . 1 5 5 . 0 6 2 . 3 8 4 1 1 1 1 9 . 6 8 1 2 2 . 8 2 0 . 1 0 4 6 0 3 . 3 5 * 5 . 0 5 0 . 1 1 5 1 2 6 . 8 7 2 9 . 2 4 1 . 9 6 5 6 0 1 1 . 3 9 1 1 . 5 9 3 . 7 4 6 1 1 3 4 . 0 8 3 6 . 5 7 1 . 2 2 o y U o t— r\ —i i L'» i ~? r*\ f i ~> c • - J u -> i— r- T» •« Tl rr . 1 « - J _ J 7 6 0 2. 8 7 * 1 . 5 2 0 . 1 0 8 1 1 2 3 . 7 7 2 8 . C 5 2 . 3 7 8 6 0 1 7 . 5 7 1 6 . 8 1 3 . 1 3 9 1 1 2 0 . 2 2 2 3 . 1 9 3 . 0 9 9 6 0 1 2 . 6 7 1 3 . 4 1 4 . 0 1 1 0 1 1 1 6 . 6 3 1 7 . 9 0 4 . 1 4 1 0 6 0 1 0 . 7 7 9 . 4 5 4 . 4 8 1 1 1 1 1 5 . 8 1 1 5 . C 2 4 . 5 7 1 1 6 0 2 . 3 1 * 2 . 1 2 0 . C 9 1 2 1 1 7 . 7 5 6 . 9 7 7 . 5 3 1 2 6 0 5 . 0 1 3 . 5 2 2 . 8 8 1 3 1 1 5 . 0 6 5 . 4 3 4 . 8 4 1 3 6 0 7 . 4 5 7 . 4 3 4 . 1 2 1 4 1 1 5 . 0 1 7 . 1 0 3 . 1 2 1 4 6 0 4 . 3 3 3 . 6 2 2 . 6 5 1 5 1 1 5 . 3 4 6 . 5 1 4 . 1 9 1 5 6 0 2 . 5 7 * 3 . 4 2 0 . 1 0 1 6 1 1 6 . 2 3 7 . 4 0 4 . 3 3 1 7 0 3 . 6 4 * 3 . 5 5 0 . 1 0 1 7 1 1 8 . 3 3 8 . 4 2 5 . 5 1 2 7 0 6 . 9 0 7 . 0 5 2 . 6 4 1 8 1 1 4 . 9 6 5 . 3 1 2 . 8 1 3 7 0 6 . 6 6 5 . 8 8 2 . 5 2 1 9 1 1 0 . 0 0 * 1 . 6 8 0 . 0 0 4 7 0 1 2 . 4 3 1 2 . 6 1 3 . 4 1 2 0 1 1 2 . 0 5 * 1 . 1 9 0 . 1 1 5 7 0 1 4 . 9 9 1 4 . 5 9 3 . 2 2 2 1 1 1 4 . 3 1 3 . 9 2 2 . 7 6 6 7 0 1 . 2 6 * 2 . 3 5 0 . 0 2 0 2 1 3 4 . 7 0 3 6 . 4 4 1 . 1 8 7 7 0 1 3 . 5 4 1 2 . 8 4 3 . 5 6 1 2 1 6 3 . 2 9 6 7 . 3 0 0 . 3 7 8 7 0 1 1 . 2 6 1 0 . 9 6 4. 2 5 2 2 1 2 5 . 1 4 2 4 . 4 1 2 . 1 8 9 7 0 9 . 2 0 8 . 7 8 4 . 6 2 3 2 1 1 4 . 6 2 1 5 . 0 4 5 . 5 1 1 0 7 0 2 . 3 2 * 0 . 8 6 0 . 0 7 4 2 1 3 0 . 3 5 3 1 . 4 5 1 . 5 3 1 1 7 0 5 . 2 5 5 . 2 4 2 . 7 8 5 2 1 2 3 . 3 4 2 4 . 4 2 2 . 4 5 1 2 7 0 7 . 4 5 6 . 1 2 4 . 0 3 6 2 1 1 9 . 4 6 2 0 . 6 5 3 . 3 9 0 8 0 5 . 1 2 5 . 1 6 1 . 5 2 7 2 1 1 1 . 2 8 1 1 . 7 0 7 . 5 6 1 8 0 5 . 7 3 4 . 3 5 1 . 7 9 8 2 1 1 6 . 5 6 1 6 . 7 7 4 . 1 8 2 8 0 4 . 5 6 * 2 . 5 0 0 . 1 4 9 2 1 6 . 9 6 8 . 2 3 9 . 7 8 3 8 c 0 . 9 1 * 1 . 0 3 0 . 0 1 1 0 2 1 2 6 . 9 8 2 7 . 6 5 1 . 8 1 4 8 0 4 . 4 9 * 2 . 6 7 0 . 1 7 1 1 2 1 1 3 . 2 0 1 3 . 7 7 5 . 3 4 5 8 0 0 . 0 0 * 1 . 2 3 0 . 0 0 1 2 2 1 7 . 0 8 7 . 9 9 5 . 4 2 6 8 0 3 . 3 3 * 4 . 0 1 0 . 1 0 1 3 2 1 4 . 8 4 3 . 8 0 4 . 5 1 0 0 1 3 7 . 6 0 3 8 . 8 1 0 . 9 7 1 4 2 1 6 . 9 0 5 . 0 6 7 . 2 6 H K L FO FC WEIGHT 15 2 1 4. 49 3. 27 3. 07 16 2 1 4 . 7 5 3.91 3. 48 17 2 1 9. 39 9. 36 4. 96 18 2 1 5. 39 4.44 3. 69 19 2 1 2. 4 1 * 2. 07 0. 12 20 2 1 11. 35 1 1 . 5 5 4. 79 21 2 1 3.44 1. 30 3. 13 0 3 1 19. 67 2 0 . 76 3. 29 1 3 1 4 2 . 5 2 4 8.31 0. 79 2 3 1 25. 81 2 5 . 86 2. 02 3 3 1 47. 5 7 3 9 . 6 5 0. 64 4 3 1 2 7 . 3 2 2 4 . 7 6 1.81 5 3 1 23. 49 2 4 . 7 1 2. 35 6 3 1 26. 32 24. 31 1. 93 7 3. 1 3. 5 9 3.57 4. 07 8 3 1 21. 45 2 1 . 9 8 2 . 7 6 9 3 1 16. 45 1 5 . 4 3 3.9 3 10 3 1 8. 01 7. 01 7. 10 •11 3 1 7. 86 9.77 4. 62 12 3 1 4. 02 4. 52 2. 82 13 3 1 11. 84 11. 33 4. 60 14 3 1 9. 96 9. 70 5. 47 15 3 1 4. 91 5. 25 3. 04 16 3 1 2. 0 7 * 0. 68 0. 09 17 3 1 3. 93 4. 54 2. 35 18 3 1 4. 95 5.54 2. 47 19 3 1 4. 94 4. 94 3. 67 20 3 1 4 . 9 8 3. 62 5. 13 0 4 ~T 6. 93 5. 66 6. 07 1 4 1 2 6 . 37 2 4 . 83 1.90 2 4 1 17. 02 15. 46 3. 95 3 4 1 8. 16 7. 27 6.63 4 4 1 12. 96 1 0 . 6 8 5. 64 5 4 1 1 5 . 6 3 1 5 . 6 5 4. 15 6 4 1 22. 07 19. 69 2. 61 7 4 1 7. 73 7.09 6.60 8 4 1 5. 63 5. 25 4. 39 9 4 1 6. 01 6.72 4.61 10 4 1 6. 04 5. 07 5.40 11 4 1 8.61 8. 20 5. 37 12 4 1 10. 67 1 1 . 0 9 4,71 13 4 1 14. 3 9 15. 7 9 3. 97 14 4 1 12. 32 12. 21 4. 19 15 4 1 10. 71 1 0 . 6 2 4. 52 16 4 1 3. 8 1 * 3. 87 0.21 17 4 1 5. 18 4. 58 3. 67 18 4 1 '5. 83 5 . 1 5 3. 94 19 4 1 1. 9 4 * 1.32 0. 10 0 5 1 6.43 7. 97 4. 65 1 5 1 6.78 7.62 5. 23 2 5 1 6. 59 5. 65 5.04 3 5 1 2 0 . 25 1 7 . 3 9 2. 77 4 5 1 10. 70 9.33 5. 07 5 1 9.68 9.01 5. 24 6 5 1 4. 41 4. 42 2. 51 7 5 1 1 0 . 5 4 10. 13 5. 18 8 5 1 9.98 9. 17 5. 36 9 5 1 6. 7 0 6. 92 4. 30 H K L FO FC WEIGHT 10 5 1 2 . 9 9 13. 35 3. 85 11 5 1 10. 88 1 0 . 40 4. 36 12 5 1 15. 53 14. 94 3. 63 13 5 1 4. 47 3. 97 2.87 14 5 1 0 . 0 0 * 1. 37 0. 00 15 5 1 3 . 4 3 * 3. 07 0. 22 16 5 1 6,61 5. 49 5.06 17 5 1 2 . 7 9 * 2. 87 0. 16 0 6 1 4 . 1 5 * 3. 69 0. 19 1 6 1 7 . 1 8 6. 74 3. 48 2 6 1 3 . 6 3 * 4. 06 0. 17 3 6 1 5.66 6. C9 3. 17 4 6 1 12. 80 12. 72 4.40 5 6 1 5. 18 4. 00 3, 03 6 6 1 1 0 . 5 9 1 0 . 56 3. 66 7 6 1 5. 19 4. 33 2.4 9 8 6 1 4. 86 2. 92 2. 89 9 6 1 5.07 4. 55 2. 57 10 6 1 2 . 3 8 * 0. 83 0. 08 11 6 1 1 . 4 5 * 2. 04 0. 03 12 6 1 7 . 0 3 6. 68 3. 85 13 6 1 0. 0 0 * 0. 52 0. 00 14 6 1 6.37 5. 89 3. 94 15 6 1 3. 70 2. 20 2. 91 0 7 1 3 . 2 1 * 2. 58 0. 12 1 7 1 8.61 8. 65 3. 60 2 7 1 14. 39 14. 13 3. 65 3 7 1 5.61 5. 48 3. 13 4 7 4.4/* 5. 62 0.16 5 7 1 1 3 . 6 9 1 4 . 1 8 3. 56 6 7 1 6. 79 6.70 2. 92 7 7 1 6. 43 5. 66 3.49 8 7 1 7 . 0 9 6. 96 3. 51 9 7 1 11 .52 10. 93 4.72 10 7 1 7. 89 6.'66 4. 60 11 7 1 2 . 5 7 * 3. 44 0. 10 12 7 1 8. 16 6. 56 5. 35 0 8 1 2. 9 3 * 3.41 0. 10 1 8 1 3. 1 9 * 3. 40 0. 11 2 8 1 2. 4 8 * 0. 74 0. 08 3 8 1 4 . 1 9 * 3. 07 0. 20 4 8 1 0. 0 0 * 2. 26- 0. 00 5 8 1 2 . 5 4 * 2. 44 0. 08 6 8 1 3. 1 6 * 2. 05 0. 14 0 0 2 2 9 . 65 27. 02 1. 54 1 0 2 16. 27 17. 13 4. 76 2 0 2 1 6 . 9 3 1 6 . 7 9 4. 27 3 0 2 4 0 . 9 7 39. 24 0. 86 4> 0 2 1 0 7 . 0 1 1 1 1 . 5 5 0. 13 5 0 2 5 7 . 5 9 5 9 . 5 1 0.45 6 0 2 18. 83 18. 73 3. 62 7 0 2 27. 23 25. 53 1. 89 8 0 2 1 3 . 8 9 13. 98 5. 40 9 0 2 2 . 3 6 * 1. 07 0. 43 10 0 2 6. 21 6. 14 8. 51 11 0 2 16. 29 17. 22 4. 07 12 0 2 0. 0 0 * 2. 78 0. 00 13 0 2 3.27 1. 25 4. 25 H K I FO FC WEIGHT 14 0 2 4. 87 6. 15 3. 24 15 0 2 4. 96 3. 70 3. 79 16 0 2 0. 00* 3.67 0. 00 17 0 2 3. 76* 5. 14 0. 26 18 0 2 0. 00* 0. 37 0. 00 19 0 2 3. 59* 3. 08 0.23 20 0 2 3. 77 0. 74 3. 87 21 0 2 2. 42* 2. 16 0. 14 0 1 2 57.79 57.50 0. 44 1 1 2 69. 68 69. 16 0. 30 2 1 2 30. 10 28. 96 1. 56 3 1 2 80. 5 9 84. 06 0. 23 4 1 2 62. 55 63. 80 0. 38 5 1 2 52. 56 53. 25 0. 53 6 1 2 21. 15 23. 50 2. 90 7 1 2 15.61 16. 90 4.78 8 1 2 9. 25 9. 82 8. 23 9 1 2 16.74 17, 13 4. 16 i o 1 2 12. 16 13,01 6. 33 11 1 2 7. 49 8. 37 7. 35 12 1 2 2. 16* 3. 01 0. 16 13 1 2 6. 52 6. 90 6. 28 14 1 2 4. 80 5.60 3. 55 15 2 6. 1*2 7. 30 4.84 16 1 2 4. 15 3. 56 2. 96 17 1 2 5. 14 5.09 3. 64 18 1 2 1. 85* 1.12 0. 07 19 1 2 5. 19 5.16 3. 60 20 T 2 6. 07 /. 5 2 5.6 5 21 1 2 3. 83 3. 35 2.91 0 2 22. 08 24. 44 2. 77 1 2 2 31. 72 34.01 1.42 2 2 2 13. 76 14. 48 5. 63 3 2 2 22. 09 21. 54 2. 75 4 2 2 29. 33 30. 37 1.63 5 2 2 9.76 11. 24 8. 94 6 2 2 17. 4 6 17. 06 3.91 7 2 2 44. 94 43. 93 0. 72 8 2 2 34. 69 35. 35 1. 16 9 2 2 6. 91 6. 56 7. 07 10 2 2 19.42 20. 40 3. 13 11 2 2 7. 41 8. 07 7. 04 12 2 2 8. 00 7.88 5. 36 13 2 2 5. 82 4.89 5. 90 14 2 2 4.48 3. 22 2. 88 15 2 2 5. 50 4.64 4. 44 16 2 2 4.88 4.44 3. 50 17 2 2 9.21 9. 93 6. 14 18 2 2 4. 66 3. 17 3. 75 19 2 2 2. 44* 2. 63 0. 10 20 2 2 3. 90 3.59 3. 42 21 2 2 5. 96 5.25 5. 61 0 3 2 14. 14 15. 76 5. 26 1 3 2 11. 86 12. 89 6. 43 2 3 2 26. 95 24. 85 1. 84 3 3 2 25. 95 25. 25 1. 98 4 3 2 26. 16 26. 13 1. 97 5 3 2 8. 13 8.65 8.08 H K L FO FC WEIGHT 6 3 2 21.75 22. 56 2.71 7 3 2 10.77 11. 28 6. 64 8 3 2 16. 26 16. 76 4.13 9 3 2 6.44 7. 18 6. 28 10 3 2 7. 34 6. 25 7. 21 11 3 2 6.81 6.59 5.03 12 3 2 8.66 8. 68 6. 20 13 3 2 1. 86* 1. 33 0. 08 14 3 2 3. 29* 2. 45 0. 20 15 3 2 5.12 3.68 5. 60 16 3 2 5. 48 5. 21 5. 73 17 3 2 6.34 5. 52 4. 46 18 3 2 7.54 6. 78 5. 27 19 3 2 0.78* 1. 98 0. 01 20 3 2 4.62 4. 29 3. 43 0 4 2 14.40 14.28 4. 86 1 4 2 10.60 1 1. 08 6. 73 2 4 2 7.69 8. 31 6. 67 3 4 2 10. 43 9. 64 6. 26 4 4 2 19.31 18. 41 3. 03 5 4 2 5. 72 4. 95 6. 14 6 4 2 7.01 7. 05 5. 92 7 4 2 12. 09 12. 62 5. 62 8 4 2 2. 13* 0. 83 0. 13 9 4 2 4.22 3. 94 3. 64 10 4 2 5.50 4. 22 4. 65 11 4 2 1 .78* 4. 78 0. 05 12 4 2 11. 04 1 1. 59 4. 57 13 4 2 6.65 5. 04 5. 75 14 4 2 7.33 7.11 5. 08 15 4 2 7. 84 7. 91 4. 55 16 4 2 0.00* 0. 37 0. 00 17 4 2 2. 70* 3. 73 0. 11 18 4 2 4. 67 4. 76 3. 94 0 5 2 6.32 5. 91 4. 65 1 5 2 12.92 13. 05 4. 55 2 5 2 8.85 9.21 4. 77 3 5 2 23. 63 25. 74 2. 17 4 5 2 9. 54 10. 20 4. 67 5 5 2 19.05 19. 04 2. 99 6 5 2 5.06 3. 59 3.71 7 5 2 3.82 4. 86 2. 67 8 5 2 6.35 5. 63 4. 75 9 5 2 2. 44* 2. 53 0. 10 10 5 2 0.14* 1. 76 0. 00 11 5 2 5. 66 5. 94 3. 52 12 5 2 2. 29* 1. 67 0. 07 13 5 2 7.37 7. 66 3. 87 14 5 2 3.11* 2. 88 0. 15 15 5 2 1.37* 0. 82 0. 03 16 5 2 3.91 2. 25 3. 43 17 5 2 3.11* 2. 40 0. 20 0 6 2 8.52 9. 47 4.48 1 6 2 4.52 4. 92 2. 60 2 6 2 9.77 10. 68 4.6 3 3 6 2 9.04 9. 60 4. 11 4 6 2 11.29 11. 60 4. 21 5 6 2 4. 32 2. 28 2. 57 H K I FO FC HEIGHT 6 6 2 9.75 9. 91 4. 32 7 6 2 11. 13 11.16 4. 27 8 6 2 5.74 5.97 3. 01 9 6 2 6. 56 6. 27 3. 48 10 6 2 5. 06 4.00 2.90 11 6 2 7. 08 5.77 4. 29 12 6 2 4. 83 5.49 2.86 13 6 2 4. 07* 4. 29 0. 23 14 6 2 4. 89 4.33 4. 03 0 7 2 6. 91 7.57 2. 94 1 7 2 2. 36* 1.7 5 0. 07 2 7 2 3. 07* 3. 55 0. 09 3 7 2 5.41 6.70 2. 15 4 7 2 6. 23 5. 57 3.75 5 7 2 4. 56 3.53 2. 51 6 7 2 6. 03 7.00 3. 21 7 7 2 0. 00* 2. 82 0. 00 . 8 7 2 4.42 5.24 2. 20 9 7 2 5.69 4.71 3. 78 10 7 2 5. 33 6. 96 2. 51 11 7 2 3. 24* 2.77 0. 16 0 8 2 5. 16 6. 26 2. 72 1 8 2 6. 08 6. 73 2. 73 2 8 2 7. 4 1 7. 03 4. 14 3 8 2 6. 15 5.49 3. 53 4 8 2 3.34* 3.40 0. 14 5 8 2 6. 4 8 5. 92 3.49 0 0 3 55. 94 53. 33 0. 47 1 r\ U 3 -> r- <* ^ ~i * f. Z. J < I H £. • *• 7 2 0 3 26. 76 25. 06 1. 94 3 0 3 36. 72 34. 90 1. 06 4 0 3 10. 18 12. 20 8. 07 5 0 3 21. 84 23. 05 2. 76 6 0 3 31. 01 33.53 1. 38 7 0 3 5. 02 4.88 8.71 8 0 3 4. 89 4. 23 8. 57 9 0 3 9. 26 9. 62 7. 89 10 0 3 20. 50 20. 90 2. 90 11 0 3 12.26 13. 03 5. 85 12 0 3 23. 5u 25. 25 2. 25 13 0 3 3. 08* 4, 12 0. 19 14 0 3 15. 42 16. 15 3. 99 15 0 3 1.78* 2. 31 0. 06 16 0 3 4. 17 4. 28 2. 78 17 0 3 4. 10 3.46 3. 11 18 0 3 6. 63 5. 87 3. 91 19 0 3 2. 53* 3. 55 0. 10 20 0 3 2. 20* 1. 19 0. 11 21 0 3 2.95* 2. 25 0. 18 0 1 3 29. 97 30. 36 1. 59 1 1 3 27. 80 27. 42 1.81 2 1 3 32. 22 33. 38 1. 39 3 1 3 16. 84 17. 98 4. 33 4 1 3 40. 47 41.08 0. 88 5 1 3 35. 53 33. 08 1. 14 6 1 3 5. 42 5. 20 7. 53 7 1 3 30. 38 33.09 1.51 8 1 3 27. 50 28. 59 1. 77 H K L FO FC HEIGHT 9 3 33. 89 36. C5 1.21 10 1 3 32. 02 32. 05 1. 32 11 1 3 14.66 15. 27 4. 39 12 1 3 13. 20 13. 50 5. 27 13 1 3 5. 44 5. 70 4. 80 14 1 3 7. 69 7. 95 5. 51 15 1 3 13. 25 15. 51 3. 65 16 1 3 7. 95 8. 93 4. 23 17 1 3 6.12 6. 18 4. 23 18 1 3 4. 82 5. 32 3. 15 19 1 3 2. 56* 2. 74 0. 13 20 1 3 4.72 3. 22 4. 34 21 1 3 3.02* 3. 85 0. 17 0 2 3 37.77 38. 08 1. 00 1 2 3 4.06 4. 98 7. 71 2 2 3 13.83 14. 81 5. 81 3 2 3 26. 06 24. 06 1. 98 4 2 3 27. 59 28. 61 1. 80 5 2 3 8. 50 6. 43 8. 12 6 2 3 62. 80 60. 50 0. 37 7 2 3 19.48 21. 07 3. 30 8 2 3 24.90 26. 82 2. 13 9 2 3 12. 37 13. 65 5. 61 10 2 3 0.96* 2. 82 Q. 03 11 2 3 13.27 14. 80 5. 06 12 2 3 12.56 13. 27 5. 23 13 2 3 6.27 7. C7 3. 89 14 2 3 5.49 6. 13 2.94 i j> 2 3 0.37 O . O 1 16 2 3 2. 92* 2. 33 0. 13 17 2 3 2.71* 0. 81 0. 14 18 2 3 4. 19 4.61 2.18 19 2 3 4. 26 4. 29 2. 43 20 2 3 0.00* 1. 47 0. 00 0 3 3 20.90 20. C2 2. 88 1 3 3 22. 30 23. 15 2. 60 2 3 3 11. 22 12. 50 6.73 3 3 3 31 .49 30. 06 1. 41 4 3 •3 20. 86 22. 35 2. 93 5 3 3 10. 91 10. 27 6. 99 6 3 3 15.71 13. 78 4.39 7 3 3 2.48* 0. 95 0. 22 8 3 3 2. 75* 2. 96 0. 26 9 3 3 12. 33 13. 07 5. 72 10 3 3 11.88 11. 39 5. 90 11 3 3 10. 84 10. 53 5. 90 12 3 3 3.88 3. 36 2. 59 13 3 3 2.39* 2. 32 0. 11 14 3 3 8.37 8. 17 4. 42 15 3 3 4. 26* 4.71 0. 21 16 3 3 2.95* 3. 21 0. 13 17 3 3 0. 00* 2. 65 0. 00 18 3 3 6. 30 6.91 3.53 19 3 3 2.72* 3. 47 0. 12 0 4 3 24.46 27. 38 2. 08 1 4 3 20. 20 21. 35 2. 92 2 4 3 10.04 10. 33 ' 6.94 3 4 3 11.10 9. 42 6. 13 H K I FO FC WEIGHT 4 4 3 6.98 8. 06 5. 98 5 4 3 13. 46 13.41 5. 02 6 4 3 9. 46 9. 28 7. 08 7 4 3 6. 88 6. 87 7. 32 8 4 3 11. 45 1 1.77 5. 57 9 4 3 11. 62 11. 45 5..24 10 4 3 4. 03 3. 88 2. 67 11 4 3 3. 30* 2. 18 0. 19 12 4 3 6.62 8. 19 3. 71 13 4 3 5. 52 5.44 5. 05 14 4 3 4. 81 6. 3 9 2. 25 15 4 3 7.7 9 8. 06 3. 93 16 4 3 3. 90* 3. 30 0. 22 17 4 3 0. 00* 1. 05 0. 00 18 4 3 2.51* 3. 0 9 0.13 0 5 3 16.63 18.11 3. 44 1 5 3 6. 87 6.33 4.91 2 5 3 15. 27 16. 0 3 3. 93 3 5 3 6.32 7. 09 3. 84 4 5 3 14. 61 14.65 4. 43 5 5 3 11.30 10. 27 4. 35 6 5 3 2. 54* 2. 23 0.12 7 5 3 9. 11 10. 53 4. 54 3 c _> i 3. 56* 3. 06 C. 18 9 5 3 7.54 7. 89 3. 73 10 5 3 8.80 8. 85 5. 41 11 5 3 11. 72 12. 92 4.39 12 5 3 6. 80 6. 05 3. 95 i 3 5 3 6. i2 8. 12 5. 16 14 5 3 4. 11 3. 60 2. 56 15 5 3 2.62* 3. 33 0. 12 16 5 3.33* 1. 80 0.21 0 6 3 18. 79 20. 35 2. 78 1 6 3 9. 69 10. 23 3. 99 2 6 3 6.98 7. 57 3. 17 3 6 3 12. 40 1 3. 51 3. 96 4 6 3 8.64 8. 98 4. 40 5 6 3 9. 13 8.73 4. 45 6 6 3 10.75 10. 02 4. 49 7 6 3 8. 45 8. 66 4. 17 8 6 3 13. 99 14. 00 4. 04 9 6 3 6. 94 7.70 4. 04 10 6 3 4. 35 3.47 1 . 94 11 6 3 4. 04* 3. 18 0. 23 12 6 3 4. 87 5. 85 1. 97 13 6 3 2.65* 2.88 0. 11 14 6 3. 57* 2. 53 0. 25 0 7 3 8. 7C 8.07 4. 21 1 7 3 5. 78 7.09 2.90 2 7 3 5. 29 5.06 2. 98 3 7 3 6. 57 8. 14 3. 02 4 7 3 9. 16 9. 38 3. 35 5 7 3 8. 27 8. 74 3.79 6 7 3 4. 62 3.38 2. 57 7 7 3 3. 97* 2. 61 0. 20 8 7 3 5.29 5. 08 3. 36 9 7 3 4. 17* 4. 19 0. 21 10 7 3 3. 7C* 4. 99 0. 22 H K L FO FC WEIGHT 0 8 3 7.71 9. 02 3. 64 1 8 3 1.50* 3. 33 0. 04 2 8 3 9. 33 10. 04 4. 85 3 8 3 5. 14 3. 42 2. 95 0 0 4 8.11 10. 70 4.82 1 0 4 26. 84 27. 05 1. 93 2 0 4 4.05 2. 86 7. 88 3 0 4 31. 14 30. 26 1. 45 4 0 4 14.73 18. 16 4.61 5 0 4 20.20 19. 78 3.18 6 0 4 25. 30 26. 58 2. 09 7 0 4 12.91 12. 15 5. 67 8 0 4 5. 96 4. 79 5. 50 9 0 4 19.84 19. 96 3. 04 10 0 4 8. 17 7. 77 7. 24 11 0 4 1 . 39* 0. 42 0. 07 12 0 4 8.88 10. 06 5, 08 13 0 4 9. 42 9. 30 4. 9 3 14 0 4 17. 72 18. C8 3. 20 15 0 4 6. 75 8. 25 3. 74 16 0 4 3.38* 3.23 0. 17 17 0 4 0. 58* 0. 83 0. 01 18 0 4 4. 58 4. 16 3. 59 19 0 4 2. 33* 1. 92 0. 11 20 0 4 2. 33* 1. 93 0. 1.3 0 1 4 18.52 17. 95 3. 71 1 1 4 33. 13 30. 44 1.28 2 1 4 12. 07 10. 64 6. 61 3 4 34,6" 32. 33 i . IS 4 1 4 11. 59 11. 37 7. 01 5 1 4 31 .38 32. 56 1. 43 6 1 4 23. 71 23. 29 2, 31 7 1 4 36. 53 37. 68 1. 07 8 1 4 9. 29 9. 97 7. 22 9 1 4 39. 33 42. 42 0. 90 10 1 4 2. 29* 4. 65 0.15 11 1 4 21. 06 23. 14 2. 69 12 1 4 0. 00* 2. 34 0. 00 13 1 4 14. 02 15.54 4.45 14 1 4 9.07 9. 12 5, 84 15 1 4 5. 88 6. 40 3. 17 16 1 4 4.11 3. 35 3. 06 17 1 4 4. 38 4.69 3. 15 18 1 4 3. 36* 1. 42 0. 25 19 1 4 4 . 60 3. 52 2. 75 20 1 4 1.71* 1. 28 0. 08 0 2 4 20.57 21. 16 3. 08 1 2 4 16.76 18. 32 4. 17 2 2 4 16.34 17. 52 4. 2 3 3 2 4 22. 36 21.12 2. 63 4 2 4 14. 04 13. 75 5. 15 5 2 4 13. 24 12. 44 5.76 6 2 4 23. 51 23. 74 2. 33 7 2 4 26.03 27. 64 1. 97 8 2 4 18.43 17. 35 3. 35 9 2 4 8. 86 8. 47 8. 05 10 2 4 10.59 10. 01 6. 46 11 2 4 6.81 7. 64 4.61 H K I F O F C W E I G H T 1 2 2 4 8 . 7 9 8 . 8 7 5 . 2 2 1 3 2 4 1 2 . 1 0 1 3 . 9 7 4 . 1 9 1 4 2 4 5 . 2 2 4 . 7 2 3 . 7 8 1 5 2 4 5 . 0 5 4 . 9 0 3 . 3 8 1 6 2 4 5 . 9 4 7 . 1 1 2 . 9 8 1 7 2 4 3 . 3 5 * 3 . 2 8 0 . 1 6 1 8 2 4 8 . 1 8 7 . 4 7 5 . 4 6 1 9 2 4 3 . 8 3 2 . 6 1 3 . 3 1 0 3 4 2 0 . 5 4 2 2 . 2 2 2 . 9 1 1 3 4 1 6 . 3 1 1 6 . 3 4 4 . 1 8 2 3 4 5 . 5 9 6 . 5 3 7 . 2 0 3 3 4 6 . 0 0 7 . 3 2 6 . 6 1 4 3 4 1 6 . 4 9 1 7 , 3 1 4 . 1 5 5 3 4 1 2 . 3 0 1 1 . 2 6 5 . 7 4 6 3 4 1 3 . 6 1 1 3 . 4 2 5 . 0 7 7 3 4 1 5 . 3 8 1 5 . 9 0 4 , 3 2 8 3 4 2 1 . 8 6 2 0 . 9 9 2 . 5 2 9 3 4 1 3 . 5 4 1 1 . 7 3 5 . 1 6 1 0 3 4 3 . 6 9 * 1 . 2 - 2 0 . 2 9 1 1 3 4 1 1 . 5 8 1 2 . 2 2 4 . 3 8 1 2 3 4 5 . 6 7 4 . 1 9 5 . 2 5 1 3 3 4 7 . 5 4 7 . 3 8 3 . 6 6 1 4 3 4 3 . 3 6 * 3 . 2 8 0 . 2 0 1 5 3 4 6 . 2 9 6 . 0 1 4 . 2 3 1 6 3 4 3 . 2 0 * 1 . 2 8 0 . 1 8 1 7 3 4 3 . 2 2 * 3 . 7 1 0 . 1 6 1 8 3 4 5 . 6 6 5 . 9 7 4 . 5 0 0 4 4 1 7 . 1 8 1 6 . 2 9 3 . 7 9 1 4 4 3 6 . i \ j 1 . 0 6 2 4 4 1 1 . 2 4 1 1 . 2 4 5 . 5 7 3 4 4 8 . 3 9 9 . 1 2 6 . 1 1 4 4 4 3 . 2 3 * 1 . 8 2 0 . 2 3 5 4 4 1 7 . 4 6 1 7 . 3 8 3 . 5 7 6 4 4 1 6 . 3 5 1 6 . 9 1 3 . 7 8 7 4 4 9 . 2 3 8 . 8 4 5 . 1 1 8 4 4 7 . 0 6 7 . 4 8 4 . 6 8 9 4 4 2 . 3 2 * 3 . 4 0 0 . 0 8 1 0 4 4 6 . 9 3 7 . 0 8 4 . 0 1 1 1 4 4 5 . 6 3 7 . 0 6 3 . 0 1 1 2 4 4 3 . 3 8 * 2 . 6 8 0 . 1 7 1 3 4 4 9 . 1 3 8 . 7 0 5 . 2 8 1 4 4 4 8 . 5 6 9 . 5 9 4 . 1 8 1 5 4 4 7 . 0 5 7 . 0 2 4 . 8 6 1 6 4 4 5 . 2 9 4 . 2 5 3 . 8 8 1 7 4 4 2 . 1 8 * 1 . 8 5 0 . 1 0 0 5 4 1 0 . 1 1 1 0 . 2 1 4 . 3 1 1 5 4 5 . 6 1 6 . 2 2 3 . 0 0 2 5 4 1 5 . 0 0 1 5 . 5 2 3 . 7 3 3 5 4 1 2 . 9 9 1 4 . 1 3 3 . 8 5 4 5 4 9 . 7 0 1 0 . 7 1 4 . 6 7 5 5 4 9 . 8 6 1 0 . 6 5 4 . 2 3 6 5 4 ' 1 3 . 2 4 1 3 . 5 6 4 . 1 8 7 5 4 6 . 0 0 5 . 7 1 3 . 3 6 8 5 4 3 . 0 3 * 3 . 0 1 0 . 1 5 9 5 4 4 . 9 3 6 . 0 1 2 . 4 0 1 0 5 4 3 . 5 0 * 1 . 7 4 0 . 2 1 1 1 5 4 7 . 5 7 7 . 1 9 4 . 9 2 1 2 5 4 4 . 4 4 5 . 2 2 2 . 3 2 H K L F O F C W E I G H T 1 3 5 4 4 . 4 9 3 . 3 6 2 . 4 4 1 4 5 4 4 . 2 7 4 . 2 5 2 . 0 9 1 5 5 4 3 . 0 9 * 3 . 9 9 0 . 1 5 0 6 4 1 1 . 2 8 1 1 . 2 9 3 . 9 1 1 6 4 5 . 8 4 5 . 2 2 3 . 4 9 2 6 4 4 . 1 7 * 4 . 3 1 0 . 1 8 3 6 4 4 . 3 0 4 . 2 8 2 . 6 8 4 6 4 1 1 . 5 0 1 2 . 7 9 4 . 1 1 5 6 4 4 . 2 4 4 . 8 3 2 . 1 6 6 6 4 1 8 . 7 0 2 0 . 3 4 2 . 8 7 7 6 4 1 . 6 6 * 2 . 5 2 0 . 0 4 8 6 4 7 . 0 3 8 . 0 6 3 . 6 0 9 6 4 2 . 6 1 * 4 . 2 0 0 . 1 1 1 0 6 4 1 . 8 1 * 2 . 3 2 0 . 0 6 11 6 4 4 . 1 0 * 5 . 8 3 0 . 2 2 1 2 6 4 4 . 6 6 3 . 8 9 3 . 0 5 1 3 6 4 4 . 5 2 4 . 8 5 3 . 2 7 0 7 4 5 . 4 8 6 . 3 7 2 . 4 8 1 7 4 9 . 4 4 1 0 . 0 5 4 . 1 1 2 7 4 4 . 9 6 3 . 3 8 3 . 4 0 3 7 4 1 1 . 9 4 1 2 . 7 3 4 . 2 2 4 7 4 0 . 0 0 * 1 . 5 1 0 . 0 0 5 7 4 5 . 4 0 5 . 1 8 3 . 3 7 6 7 4 5 . 8 4 6 . 1 5 3 . 3 2 7 7 4 4 . 2 6 3 . 9 7 2 . 6 1 8 7 4 6 . 8 4 6 . 7 3 3 . 8 7 9 7 4 3 . 5 6 * 2 . 9 1 0 . 1 9 0 0 5 2 9 . 2 1 2 8 . € 7 1 . 6 2 1 G 5 2 0 , 8 3 2 0 . 4 5 3 . 0 0 2 0 5 6 . 3 6 4 . 6 6 9 . 5 8 3 0 5 8 . 6 2 7 . 9 9 9 . 0 1 4 0 5 7 . 5 8 6 . 2 6 9 . 5 6 5 0 5 2 . 9 9 * 2 . 2 1 0 . 3 8 6 0 5 0 . 0 0 * 1 . 3 6 0 . 0 1 7 0 5 7 . 2 2 8 . 4 7 6 . 5 4 8 0 5 9 . 9 7 1 1 . 6 0 6 . 8 7 9 0 5 1 1 . 9 9 1 2 . 4 9 5 . 5 3 1 0 0 5 5 . 9 7 6 . 2 5 4 . 8 3 11 0 5 1 2 . 3 8 1 2 . 4 2 4 . 8 4 1 2 0 5 1 0 . 1 7 1 0 . 9 2 5 . 6 1 1 3 0 5 6 . 7 0 6 . 9 6 3 . 9 8 1 4 0 5 7 . 1 1 6 . 6 6 5 . 0 5 1 5 0 5 2 0 . 1 5 1 9 . 5 1 2 . 6 5 1 6 0 5 1 4 . 2 6 1 3 . 3 5 4 . 0 0 1 7 0 5 0 . 0 0 * 2 . 8 0 0 . 0 0 1 8 0 5 5 . 4 3 5 . 4 3 4 . 0 1 1 9 0 5 4 . 5 2 2 . 5 9 3 . 5 9 0 1 5 6 . 3 0 5 . 5 3 9 . 3 8 1 1 5 3 5 . 3 5 3 1 . 5 2 1 . 1 3 2 1 5 2 2 . 6 0 1 9 . 4 6 2 . 5 4 3 1 5 2 2 . 0 3 2 0 . 3 9 2 . 6 5 4 1 5 1 5 . 4 2 1 6 . C 5 4 . 6 1 5 1 5 2 6 . 8 7 2 7 . 6 0 1 . 8 5 6 1 5 1 0 . 7 0 1 0 . 7 9 6 . 9 1 7 1 5 3 . 0 9 * 1 . 7 0 0 . 4 0 8 1 5 1 5 . 8 9 1 5 . 4 1 4 . 1 1 9 1 5 9 . 2 3 9 . 9 3 6 . 4 9 1 0 1 5 8 . 6 7 9 . 2 2 6 . 5 3 H K 1 FO FC HEIGHT 11 <| 5 14. 97 15. 28 4. 47 12 1 5 4. 37 4. 45 2. 94 13 1 5 4. 02 3.46 2. 77 11 1 5 11. 15 12.66 4. 56 15 1 5 4. 86 4.45 3. 19 16 1 5 4. 23 3.54 2. 58 17 1 5 7. 30 8. 01 3.46 18 1 5 4. 26 4.81 2. 95 19 1 5 3.39* 3.78 0. 22 0 2 5 20. 86 21. 30 2. 85 1 2 5 3. 27 4. 10 3. 97 2 2 5 5. 97 5. 86 6. 95 3 2 5 4. 27 3. 45 6.75 4 2 5 17. 07 16. 54 4. 05 5 2 16. 93 16.61 4. 12 6 2 5 8.79 8.57 7. 30 7 2 5 6. 40 7. 06 6. 27 8 2 5 16. 33 17. 40 3. 82 9 2 5 4. 54 4. 56 4. 80 10 2 5 8.17 7.55 5.31 11 2 5 14. 43 14. 81 4. 12 12 2 5 13. 41 14.62 4. 18 13 2 5 9. 87 10. 26 5. 54 14 2 5 11.76 12.70 4. 43 15 2 5 9. 97 10. 16 4. 41 16 2 5 6. 29 5. 80 5. 19 17 2 5 6. 71 5. 88 4. 92 18 2 5 4.57 4.54 2. 98 . j U <• fs t. It 1 »i. • M MM r\ -M 1 I * CJ 1 1 3 5 9.64 9. 13 7. 15 2 3 5 5. 08 3.84 7. 33 3 3 5 12.64 10.61 5. 55 4 3 5 3. 71 2. 53 3. 35 5 3 5 8. 26 8. 38 7. 15 6 3 5 8. 02 8. 27 6. 79 7 3 5 6. 58 6. 93 5. 23 8 3 5 8. 83 7. 91 6. 02 9 3 5 8. 26 8, 42 5. 60 10 3 5 13. 36 13. 39 4. 74 11 3 5 8. 40 8. 65 5. 03 12 3 5 5. 03 5.60 4. 24 13 3 5 4. 23 4. 11 2. 64 1" 3 . 5 4.24 5.77 2. 18 15 " '3""* 5 1. 32* 2. 59 0. 03 16 3 5 2. 28* 2. 35 0. 09 17 3 5 8. 92 8. 54 6. 84 0 a 5 10. 94 1 1.67 6. 12 1 a 5 4. 70 3. 43 4. 24 2 4 5 10. 00 9. 04 6. 20 3 4 5 10. 85 10. 49 5. 20 a 4 5 9.05 9.19 5. 54 5 4 5 6. 78 7. 30 5. 24 6 4 5 3.14* 1. 37 0.20 7 4 5 3. 52* 4.71 0.23 8 4 5 8. 45 8. 69 5. 15 9 4 5 12. 14 11.94 5. 20 10 4 5 6.61 6.74 3. 58 11 4 5 4. 24 2. 85 3.25 H K L FO FC HEIGHT 12 4 5 4.86 4. 95 2. 68 13 4 5 4. 67 4. 35 2. 20 14 4 5 4.91 4. 11 3. 39 15 4 5 3.71 1. 78 3. 01 16 4 5 5.25 5. 72 3. 29 0 5 5 16. 42 16. 66 3.45 1 5 5 16. 19 17. 33 3.36 2 5 5 11.06 11. 28 5. 16 3 5 5 10.35 9. 46 4.79 4 5 5 23.78 23. <J4 2. 16 5 5 5 5. 35 5. 56 2. 87 6 5 5 18.96 19. 50 2. 87 7 5 5 6.79 5. 92 4. 10 8 5 5 15.88 16. 51 3.52 9 5 5 3.97 3. 03 2. 35 10 5 5 8.18 7. 8.5 4.61 11 5 5 4.72 4. 60 2. 64 12 5 5 4 .20 3. 40 3. 42 13 5 5 3.36* 3. 05 0. 24 14 5 5 3.93 3. 35 3.08 0 6 5 2. 96* 3. 23 0. 12 1 6 5 7. 14 8. 22 3. 78 2 6 5 3. 78* 2. 52 0. 25 3 6 5 8.73 8. 64 4.79 4 6 5 4. 77 5. 08 2. 29 5 6 5 7.67 6.01 5. 93 6 6 5 7.52 7. 97 3. 99 7 6 5 6.73 6. 76 4. 82 r\ O O r- Cj -\ r- •* J - 1.29 /•N - A "> U » <C J 9 6 5 5.14 4. 29 3. 86 10 6 5 4. 86 3. 89 3. 24 11 6 5 3.51* 2. 57 0. 29 0 7 5 7. 54 6. 56 4. 38 1 7 5 4.59 3. 59 3.41 2 7 5 5.90 5. 60 4.0 1 3 7 5 5. 54 5. 87 3.79 4 7 5 3.62* 3. 40 0. 23 5 7 5 3.83* 3. 90 0. 23 6 7 5 3. 22* 2. 50 0. 18 7 7 5 3. 70* 3. 10 0. 28 0 0 6 5. 37 4. 64 7. 03 1 0 6 25. 24 22. 49 2. 11 2 0 6 13.83 14. 33 5. 06 3 0 6 3. 19* 2. 16 0. 29 4 0 6 3.47 3. 33 4. 85 5 0 6 33.76 31. 93 1. 21 6 0 6 5.02 4. 43 6. 50 7 0 6 10. 11 9. 90 6. 67 8 0 6 2.81* 1. 76 0. 26 9 0 6 0. 00* 0. 05 0. 00 10 0 6 3.92 3. 99 3. 87 11 0 6 2.31* 0. 07 0. 13 12 0 6 8.04 7. 60 4. 96 13 0 6 7. 04 7. 03 6. 93 14 0 6 1 .48* 1. 93 0. 04 15 0 6 1. 15* 0. 53 0. 03 16 0 6 5. 33 3. 69 4.62 17 0 6 5.01 3.52 4. 64 H K L FO FC HEIGHT 18 0 6 6. 21 5. 37 5.49 0 1 6 10. 27 10.67 6. 87 1 1 6 10. 93 11.75 6. 31 2 1 6 14. 51 14. 51 5. 01 3 1 6 8. 41 8. 32 8. 10 4 1 6 20. 15 19.42 2. 93 5 1 6 8. 62 6.71 6. 46 6 1 6 3. 36* 4. 13 0. 35 7 1 6 7. 20 6. 04 7. 36 8 1 6 7. 88 7. 23 6. 23 9 1 6 6. 41 6. 35 5.89 10 1 6 4. 54 5. 27 2. 40 11 1 6 12. 14 13. 29 5. 02 12 1 6 14.78 14. 94 3. 83 13 1. 6 4. 85 4.84 3. 33 14 1 6 4. 46 3. 11 3. 52 15 1 6 6. 06 6. 29 4. 27 16 1 6 3. 14* 3. 14 0. 19 17 1 6 4. 56 4. 40 4. 26 18 1 6 0. 00* 2.42 0. 00 0 2 6 11.48 11.46 6. 30 1 2 6 19. 85 19.33 3. 08 2 2 6 7. 55 6.69 6. 33 3 2 6 14. 77 14. 96 4. 56 4 2 6 9. 32 8. 48 7. 05 5 2 6 6.56 6. 14 6. 38 6 2 6 1.98* 1.79 0. 12 7 2 6 11.77 11.88 5. 35 6 2 6 4.99 5.4/ 3.42 9 2 6 22. 01 23. 08 2. 38 10 2 6 6. 80 7. 09 4. 66 11 2 6 7.67 7.66 5. 46 12 2 6 15. 33 15. 1 1 3. 85 13 2 6 5. 05 3.53 4. 19 14 2 6 6. 03 5. 18 6. 25 15 2 6 2.58* 1.62 0. 13 16 2 6 4. 45 2. 53 3. 96 17 2 6 4.39 3.72 2. 99 0 3 6 1. 66* 1. 82 0. 09 1 3 6 21. 03 21. 81 2. 62 2 3 6 0. 00* 1. 17 0. 00 3 3 6 6. 48 7. 50 5. 74 4 3 6 11.58 10. 91 5. 40 5 3 6 5. 43 4.73 6. 18 6 3 6 9. 43 10. 28 6. 39 7 3 6 1. 78* 2. 94 0. 07 8 3 6 9. 45 10. 07 5.98 9 3 6 6. 92 6. 44 5. 21 10 3 6 10. 27 11.31 5. 09 11 3 6 1.63* 2. 13 0. 05 12 3 6 4. 57 5. 11 3. 00 13 3 6 3. 40* 3.58 0. 21 14 3 6 0. OC* 2. 08 0. 00 15 3 6 9.60 8. 58 6. 59 16 3 6 8. 03 7. 50 6. 26 0 4 6 18. 08 18.72 3. 03 1 4 6 6. 87 6.44 6. 64 2 4 6 8. 53 8. 50 5. 01 H K L FO FC WEIGHT 3 4 6 13,96 14. 51 4. 62 4 4 6 11.84 11.51 5.50 5 4 6 13. 53 13. 09 4.91 6 4 6 11.76 12. 21 4. 66 7 4 6 3.19* 3. 67 0. 17 8 4 6 5.76 6. 05 3. 56 9 4 6 15. 35 15. 65 3. 83 10 4 6 7.10 7. 05 4. 91 11 4 6 6.80 5. 87 5.62 12 4 6 6.60 4. 93 5. 68 13 4 6 3.77* 2. 83 0. 23 14 4 6 2.76* 3. 22 0. 15 15 4 6 3.01* 1. 17 0. 30 0 5 6 11.38 10. 71 4. 96 1 5 6 4.70 3. 69 3. 25 2 5 6 14.20 15. 22 3.91 3 5 6 10.11 10. 90 4.60 4 5 6 6.59 7. 35 4.69 5 5 6 10.32 11. 11 4.56 6 5 6 3.93 3. 66 2. 40 7 5 6 6. 93 6. 56 4. 84 8 5 6 0.60* 3. 97 0.01 9 5 6 4.59 4. 44 3. 86 10 5 6 4.03 6. C8 2.26 11 5 6 3.25* 2. 06 0. 30 12 5 6 4.42 4. 90 3. 02 0 6 6 1.94* 3. 78 0. 05 1 6 6 6.71 7. 78 4. 18 2 6 6 5.22 4. 33 3. 72 3 6 6 8.05 8. 16 4. 32 4 6 6 3.70* 3. 02 0. 26 5 6 6 4.38 3. 73 3. 06 6 6 6 4.60 3. 10 4. 12 7 6 6 3.10* 4. C9 0. 17 8 6 6 3.23* 3. 20 0. 20 9 6 6 5.74 4. 39 5. 19 0 7 6 7.03 6. 36 5. 45 1 7 6 6. 81 6. 66 4. 75 2 7 6 3. 15* 0. 77 0. 26 0 0 7 2. 86* 5. 97 0. 26 1 0 7 25.21 23.78 2.03 2 0 7 6.51 8. 45 6.27 3 0 7 3. 11* 1. 33 0. 40 4 0 7 3.85 2. 59 3. 81 5 0 7 6. 36 6. 58 7. 27 6 0 7 4.76 4. 66 4. 48 7 0 7 7.69 7. 69 6.23 8 0 7 6.41 6. 71 6.25 9 0 7 14.00 14. 41 4. 30 10 0 7 4.10 3. 16 3. 43 11 0 7 5.36 4. 73 4. 62 12 0 7 11.96 11. 63 4. 79 13 0 7 11.51 10. 89 5. 26 14 0 7 7.10 6. 77 5. 92 15 0 7 4.92 4. 57 5.67 16 0 7 1.63* 1. 99 0. 07 0 1 7 4.99 4. 42 4. 85 1 1 7 13. 84 14. 75 4. 93 H K I FO ' FC WEIGHT 2 7 1.32* 1. 53 0.06 3 1 7 17. 91 16. 90 3. 42 4 1 7 6. 22 5. 76 5. 49 5 1 7 3. 80 5. 19 2. 86 6 1 7 7. 05 7. 50 6. 19 7 1 7 0. 00* 1. 55 0. 00 8 1 7 14. 78 14. 45 4. 37 9 1 7 3 .81* 3. 94 0. 24 10 1. 7 7. 57 7.98 5. 37 11 1 7 3. 07* 2. 11 0. 18 12 1 7 2 .49* 0. 88 0. 15 13 1 7 8. 46 8.66 4. 83 14 1 7 2. 13* 0. 15 0. 12 15 1 7 6. 31 6. 03 4. 97 16 1 7 2 .81* 2.54 0. 16 0 2 7 11. 37 10. 78 5. 82 1 2 7 9. 45 9.44 6. 77 2 2 7 6.18 5, 22 5. 24 3 2 7 7. 79 6. 66 5. 33 4 2 7 21. 06 20. 68 2.73 5 2 7 7. 83 8. 61 5. 01 6 2 7 10. 71 10. 59 5. 08 7 2 7 12. 23 11.59 4. 74 8 o c 7 1.51* 0.77 0.05 9 2 7 6. 70 5. 58 5. 78 10 2 7 8. 56 8. 57 5. 48 11 2 7 6. 31 7.42 4. 50 12 2 7 5. 49 6.61 3. 31 13 2 7 10. / 2 10. 1"5 5.11 14 2 7 2. 70* 2. 70 0.13 15 2 7 4. 22 4. 25 3.31 16 2 7 5.54 5. 10 4. 58 0 3 7 12. 23 11. 05 4. 64 1 3 7 13. 27 12. 53 4. 66 2 3 7 16. 57 16. 22 3. 76 3 3 7 6. 87 5. 87 6. 53 4 3 7 12. 82 12. 26 5. 24 5 3 7 14. 38 1 5. 27 4. 44 6 3 7 10, 59 10. 42 5. 70 7 3 7 5. 82 5.68 4. 40 8 3 7 12. 08 12. 19 5. 22 9 3 7 4. 13 3. 94 3. 32 10 3 7 7. 20 6.57 5.92 11 3 7 9. 6 8 9.76 4. 64 12 3 7 8.75 9. 34 6.49 13 3 7 9. 72 9.21 5. 98 14 3 7 5.78 6. 04 4.34 15 3 7 5. 97 6.08 5. 02 0 4 7 11.91 11. 17 5. 34 1 4 7 19. 52 20. 25 2. 91 2 4 7 7 .87 7. 58 5. 52 3 4 7 5. 06 4.95 5. 64 4 4 7 6.86 5.44 4. 37 5 4 7 9. 39 9. 60 5. 06 6 4 7 9. 14 8. 31 5. 57 7 4 7 9. 37 9. 21 6. 24 8 4 7 8.68 8.85 5. 55 9 4 7 4. 34 2. 81 3. 61 H K L FO FC WEIGHT 10 4 7 2 .65* 3. 63 0. 12 11 4 7 8.05 7. C8 5. 86 12 4 7 3. 88 3. 26 .3. 76 13 4 7 3.36* 2. 93 0. 29 0 5 7 7.06 7. 61 5. 02 1 5 7 8. 14 8. 04 4. 80 2 5 7 . 8 . 4 6 8. 83 5. 52 3 5 7 5.29 6.49 3. 23 4 5 7 3. 27* 3. 50 0.17 5 5 7 2. 38* 1. 51 0. 12 6 5 7 1.63* 2. C9 0. 06 7 5 7 4.20 3. 16 2. 97 8 5 7 7.02 6. 17 5. 53 9 5 7 6. 86 6. 38 5. 71 10 5 7 2 .61* •1.38 0. 23 0 6 7 9. 34 9. 1.4 6. 14 1 6 7 3.92 3. 33 2. 88 2 6 7 3 .10* 2. 10 0.22 3 6 7 3. 87 3. 50 2. 43 4 6 7 11.12 12. CS 5.18 5 6 7 3. 15* 2. 56 0. 31 6 6 7 5.50 5.21 5. 23 0 0 8 8. 35 8. 44 6. 26 1 0 8 13. 11 13. 51 4. 45 2 0 8 2 .25* 0. 26 0. 17 3 0 8 5.43 4. 94 5. 47 4 0 8 8. 28 8. C2 6. 76 5 0 8 9. 44 8. 83 5. 92 6 G 8 2 • 1 6 ̂  0.41 0 . 1 3 7 0 8 4.09 2. 97 2. 76 8 0 8 3 . 6 9 2. 63 2. 83 9 0 8 3 .79* 2. 70 0. 26 10 0 8 2. 42* 1 . 66 0. 15 11 0 8 4.08 4. 40 2. 62 12 0 8 3. 06* 1. 53 0. 24 13 0 8 2 .63* 0. 27 0. 19 14 0 8 3 .13* 1. 50 0. 29 15 0 8 2. 79* 0. 79 0. 27 0 1 8 8.10 7. 42 5. 45 1 1 8 8. 27 8. 08 5. 47 2 1 8 7.47 7. 53 5. 20 3 1 8 9.93 10. 07 5. 98 4 1 8 8.81 8. 99 4. 85 5 1 8 13. 26 12. 92 4. 71 6 1 8 9.29 9. C9 5. 19 7 1 8 10. 39 10. 60 5. 58 8 1 8 5.32 5. 87 3. 82 9 1 8 7. 38 7. 16 5. 12 10 1 8 4. 04 3. 35 3. 16 11 1 8 3. 95 2. 33 4. 03 12 1 8 4. 36 4. 56 2.55 13 1 8 1 . 78* 2. 99 0. 06 14 1 8 4.88 3.45 5. 08 0 2 8 1. 64* 2. 51 0. 05 1 2 8 8.57 8. 37 5. 86 2 2 8 12.85 12. 23 4. 82 3 2 8 7.36 6.51 4.79 4 2 8 . 4.96 4. 11 4. 45 H K I F O F C H E I G H T 5 2 8 7 . 8 1 8 . 1 7 5 . 4 5 6 2 8 1 0 . 3 3 1 0 . 4 8 4 . 3 1 7 2 8 6 . 7 5 6 . 3 3 5 . 6 7 8 2 8 8 . 3 1 8 . 5 9 5 . 4 3 9 2 8 2 . 6 1 * 3 . 8 3 0 . 1 3 1 0 2 8 3 . 3 9 * 2 . 6 5 0 . 2 7 1 1 2 8 5 . 6 8 5 . 4 7 4 . 2 0 1 2 2 8 4 . 5 0 3 . 5 5 3 . 3 1 1 3 2 8 3 . 3 1 * 1 . 8 8 0 . 3 1 1 1 2 8 1 . 5 6 * 1 . 2 9 0 . 0 7 0 3 8 5 . 3 6 4 . 5 6 4 . 6 6 1 3 8 8 . 0 2 7 . 5 8 4 . 2 8 2 3 8 5 . 2 4 4 . 4 4 3 . 1 7 3 3 8 1 6 . 1 6 1 6 . 3 9 3 . 6 7 4 3 8 1 5 . 4 1 1 5 . 0 0 3 . 8 3 5 3 8 9 . 1 2 9 . 0 9 4 . 4 6 6 3 8 6 . 2 8 6 . 5 5 4 . 4 4 7 3 8 9 . 7 8 9 . 7 0 6 . 1 2 8 3 8 7 . 1 4 7 . 6 3 4 . 3 7 9 3 8 2 . 6 6 * 1 . 4 2 0 . 1 8 1 0 3 8 3 . 9 7 2 . 7 7 3 . 2 9 1 1 3 8 3 . 7 7 3 . 5 5 3 . 2 4 1 2 3 8 8 . 1 8 7 , 1 8 5 , 0 7 0 4 8 6 . 1 2 5 . O S 4 . 3 6 1 4 8 5 . 8 7 6 . 1 1 3 . 5 6 2 4 8 1 0 . 0 2 9 . 0 9 5 . 4 9 3 4 8 5 . 2 5 5 . 0 8 3 . 6 8 a 4 8 7 . 4 5 6 . 8 1 5 . 1 5 5 4 6 3 . 1 5 * 4 . 0 0 0 . 1 4 6 4 8 3 . 2 0 * 2 . 5 3 0 . 2 0 7 4 8 5 . 0 7 4 . 6 4 4 . 5 5 8 4 8 4 . 6 8 4 . 5 9 4 , 2 9 9 4 8 1 . 4 1 * 0 . 8 5 0 . 0 5 1 0 4 8 2 . 8 8 * 0 . 9 0 0 . 2 1 0 5 8 1 . 1 3 * 1 . 9 9 0 . 0 2 1 5 8 3 . 4 3 * 2 . 5 3 0 . 2 0 2 5 8 6 . 7 6 5 . 5 4 5 . 2 4 3 5 8 3 . 1 6 * 1 . 5 2 0 . 2 7 a 5 8 2 . 8 6 * 2 . 4 9 0 . 1 5 5 5 8 4 . 3 3 3 . 5 0 4 . 1 4 6 5 8 7 . 3 0 7 . 5 2 5 . 3 3 7 5 8 2 . 9 2 * 3 . 2 9 0 . 2 2 0 0 9 3 . 2 7 * 0 . 2 5 0 . 2 6 1 0 9 1 1 . 0 0 1 0 . 6 8 4 . 9 6 2 0 9 0 . 0 0 * 0 . 8 6 0 . 0 0 3 0 9 1 . 9 8 * 1 . 1 0 0 . 0 8 0 9 0 . 0 0 * 2 . 3 1 0 . 0 0 5 0 9 6 . 3 2 6 . 6 7 5 . 3 0 6 0 9 3 . 7 4 3 . 1 2 2 . 7 5 7 0 9 3 . 0 3 * 3 . 3 8 0 . 1 7 8 0 9 5 . 8 6 5 . 2 1 5 . 0 6 9 0 9 3 . 5 9 * 1 . 7 2 0 . 3 0 1 0 0 9 5 . 9 4 5 . 6 5 5 . 5 1 1 1 0 9 0 . 0 0 * 0 . 5 7 0 . 0 0 1 2 0 9 2 . 9 7 * 0 . 7 1 0 . 2 8 0 1 9 4 . 6 6 3 . 6 1 3 . 8 3 1 1 9 1 2 . 4 5 1 0 . 3 3 4 . 7 2 2 1 9 9 . 4 6 8 . 8 9 6 . 1 6 H K L F O F C W E I G H T 3 9 3 . 0 2 * 1 . 1 7 0 . 1 7 4 1 9 4 . 6 0 3 . 3 2 3 . 7 1 5 1 9 5 . 7 2 5 . 1 7 4 . 0 3 6 1 9 5 . 2 9 5 . 1 8 3 . 7 0 7 1 9 7 . 4 6 7 . 2 8 5 . 1 4 8 i 9 0 . 0 0 * 1 . 9 9 0 . 0 0 9 1 9 - 1 0 . 4 3 1 0 . 2 0 5 . 1 7 1 0 1 9 4 . 4 8 2 . 7 3 5 . 1 9 1 1 1 9 3 . 8 3 4 . 2 0 2 . 8 4 1 2 1 9 3 . 6 6 3 . 9 7 2 . 9 2 0 2 9 5 . 0 0 4 . 7 7 • 3 . 4 2 1 2 9 4 . 4 0 4 . 8 9 2 . 3 9 2 2 9 4 . 8 7 4 . 0 8 5 . 1 1 3 2 9 5 . 2 3 6 . C8 4 . 3 8 4 2 9 5 . 4 5 5 . 2 2 5 . 7 4 5 2 9 4 . 3 0 3 . 1 6 3 . 4 3 6 2 9 4 . 2 3 2 . 6 2 3 . 3 8 7 2 9 8 . 0 6 9 . 1 9 4 . 8 6 8 2 9 5 . 7 5 6 . 3 1 3 . 7 3 9 2 9 4 . 4 6 3 . 5 5 3 . 3 2 1 0 2 9 3 . 1 5 * 1 . 3 2 0 . 2 8 1 1 2 9 6 . 1 5 6 . 5 2 4 . 2 3 0 3 9 3 . 9 3 2 . 9 3 3 . 0 2 1 3 9 8 . 8 7 7 . 4 3 6 . 2 5 2 3 9 8 . 8 7 8 . 0 6 4 . 9 7 3 3 Q 2 . 3 6 * 1 . 7 1 0 . 1 1 4 3 9 6 . 6 7 5 . 7 0 5 . 7 4 5 3 9 3 . 0 1 * 1 . 1 9 0 . - 2 3 6 3 9 3 . 33* 2 . 5 6 G . 2 3 7 3 9 3 . 9 0 2 . 2 3 4 . 3 4 8 • 3 9 1 . 5 0 * 2 . 1 3 0 . 0 5 9 3 9 2 . 6 9 * 2 . 6 0 0 . 1 9 0 4 9 6 . 8 7 6 . 4 7 3 . 6 5 1 4 9 6 . 0 4 5 . 8 4 4 . 0 9 2 4 9 8 . 1 3 7 . 4 8 4 . 6 7 3 4 9 4 . 6 9 3 . 7 6 4 . 4 4 4 4 9 2 . 0 2 * 2 . S 3 0 . 1 0 5 4 9 3 . 9 5 3 . S 3 2 . 5 2 6 4 9 5 . 2 5 5 . 4 3 3 . 9 8 7 4 9 3 . 4 3 1 . 5 6 3 . 3 5 0 0 1 0 6 . 5 1 4 . 4 6 5 . 6 3 1 0 1 0 5 . 8 9 4 . 5 7 5 . 1 4 2 0 1 0 1 2 . 8 0 1 1 . 9 7 4 . 4 5 3 0 1 0 0 . 0 0 * 0 . 3 1 0 . 0 0 4 0 1 0 1 . 8 6 * 0 . 6 3 0 . 0 8 5 0 1 0 2 . 6 6 * 2 . 3 9 0 . 1 9 6 0 1 0 4 . 0 2 2 . 4 4 2 . 8 5 7 0 1 0 2 . 0 3 * 0 . 4 5 0 . 1 0 8 0 1 0 4 . 4 9 5 . 4 6 2 . 7 0 9 0 1 0 1 . 2 2 * 0 . 1 8 0 . 0 4 0 1 1 0 6 . 2 2 5 . 8 0 4 . 6 1 1 1 1 0 9 . 3 5 8 . 3 9 5 . 1 2 2 1 1 0 1 2 . 6 7 1 1 . 6 5 5 . 1 3 3 1 1 0 9 . 8 9 8 . 9 8 5 . 7 4 4 1 1 0 0 . 0 0 * 0 . 7 8 0 . 0 0 5 1 1 0 6 . 8 3 6 . 2 4 5 . 2 9 6 1 1 0 4 . 1 4 5 . 2 9 2 . 5 5 7 1 1 0 4 . 2 4 1 . 9 3 5 . 2 6 H K L FO FC WEIGHT 8 1 10 2. 50* 4. 17 0.12 0 2 10 4. 85 3. 83 4. 39 1 2 10 4. 41 4.58 3. 19 2 2 10 5. 89 6. 28 3. 96 3 2 10 6.48 5.68 4. 44 4 2 10 5. 86 5. 53 3..56 5 2 10 13. 86 12.79 4. 73 6 2 10 6. 54 5. 74 5. 65 H K L FO FC WEIGHT 7 2 10 4. 17 3. 64 3. 55 0 3 10 7.76 6. 31 7. 00 1 3 10 3.56 3. 53 3. 20 2 3 10 5. 38 4. 87 5. 62 3 3 10 2.01* 1. 19 0. 11 4 3 10 6. 08 5. 45 6. 58 0 0 11 1. 80* 1. 72 0. 10 1 0 11 10.38 9. 45 5. 50 * DENOTES AN UNOBSERVED REFLECTION

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