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The structure determination of three inorganic and two organic compounds by x-ray diffraction Mercer, Anthony 1977-02-21

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THE STRUCTURE DETERMISATION OF THREE INORGANIC AND TWO ORGANIC COMPOUNDS BY X-RAY DIFFRACTION. By ANTHONY MERCER. .Sc., University of Bristol, England, 1972. A THESIS SUBMITTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY in the department of CHEMISTRY. We accept this thesis as conforming to the reguired standard. THE UNIVERSITY OF BRITISH COLUMBIA JUNE 1977. (c) Anthony Mercer, 1977 In presenting this thesis in partial fulfilment of the requirements for an advanced degree at the University of British Columbia, I agree that the Library shall make it freely available for reference and study. I further agree that permission for extensive copying of this thesis for scholarly purposes may be granted by the Head of my Department or by his representatives. It is understood that copying or publication of this thesis for financial gain shall not be allowed without my written permission. Department of Cm CWwSTft^f The University of British Columbia 2075 Wesbrook Place Vancouver, Canada V6T 1W5 Date 4 abstract This thesis deals with the current methods available for X-ray structure determination and with the crystal and molecular structure determination of five compounds using these methods. The five compounds are 1) [ 2,3-Bis (dimethylarsino)- 1, 1, 1,4, 4, 4-hexaf luorobut-2~ene-As,As3tricarbonyldiiodotungsten(II), Me^AsC (CF3 j~:C (CF^) AsBe*WXx (CO)3 2) Dimethylammonium trichlorotris(dimethylsulphoxide}-ruthenate(II) , [ ( (CE%)t SQ)% RuCla r [ (CH^i NHa J+ 3) Dichlorotetrakis{dimethylsulphoxide)ruthenium(II), (Me1SO)vfRuClx 4) 1,3,7-Triraethyl-2,6-dioxypuriae hydrochloride dihydrate (caffeine hydrochloride dihydrate), C8Hn ClNlf01.lH10 .5) 1-Acetyl-3-benzamido-2-keto-4- (2,3, 4, 6-tetra-O-acetyl-P-D-glucopyranosyloxy)-k3-pyrroline, The structures of compounds 1), 2), and 3) were determined by Patterson syntheses, compound 4) by centrosymmetric direct methods and compound 5) by non-centrosymmetric direct methods. All structures were then refined using full-matrix least-sguares procedures. The relevant crystal data for all five compounds can be found in Table A In the tungsten compound [1) ] the tungsten atom is seven-coordinate with a distorted capped octahedral environment, the capping group being a carbonyl. The capped face consists of the two remaining carbonyl groups and one of the arsenic atoms from the bidentate ligand. The uncapped face contains the two iodine atoms and the remaining arsenic iii Table.A Crystal data for the five compounds examined Space Group Unit Cell Dimensions Final R Factor 2) 3) 4) £2,/c ££2, a £24/n £2,/c a = 15.37 (2) 90.0 b 9.52 9(1) I 112.03 (2) 0. 067 c = 15. 967(3) I — 90.0 a 27.45 9(5) 90.0 b 9.925(1) = 90.0 0. 045 c 14.266(3) — 90.0 a = 8.9 39(3) 90.0 b 18.045(7) 1 91.52 (2) 0. 041 c 1 1.363(3) 90.0 a — 12.391 (4) 90.0 b 6.52 4(1) I = 118.82 (3) 0. 064 c = 17. 167(6) 90.0 a 19.629(5) = 90.0 b = 7.504(2) 1 = 90.53(2) 0. 079 c 9.830(2) tt = 90.0 5) P24 atom. The structure of the ruthenium compound [ 2) ] consists of two crystallcgraphically non-equivalent anions in the asymmetric unit linked by hydrogen bonding via dimethylammonium cations. The coordination geometry about the structurally similar anions is essentially that of an octahedron with the DHSO ligands being bonded to Ru via the sulphur atoms. The co-ordination geometry about the ruthenium atom for compound 3) is essentially octahedral with cis chlorine atoms; Of the four DMSO ligands three are S-bonded and one is O-bonded, the O-bonded ligand being trans to a S-bonded ligand. For caffeine hydrochloride [ 4) ] the fused ring system is essentially planar and protonated at the 9-positioh. The crystal contains two types of hydrogen bonding involving 0-H...C1 and N-H...0 interactions. The structure of compound 5) consists of a pyranose ring in the chair conformation with the four 0-acetyl substituents in equatorial positions; the pyranose ring is connected to a planar pyrroline ring via a £-oxygen bridge. V TABLE OF CONTENTS Pag e TITLE PAGE .............................................. i ABSTRACT ii TftBLE OF CONTENTS ....................................... v LIST OF TABLES ., viiLIST OF FIGURES .......................... ............ xi ACKNOWLEDGEMENTS xiiGENERAL INTRODUCTION 1 CHAPTER 1. AN INTRODUCTION TO X-RAY CRYSTALLOGRAPHY ..... 4 k) A practical viewpoint ........................ 5 B) A theoretical viewpoint ...................... 14 CHAPTER 2. CRYSTAL AND MOLECULAR STRUCTURE OF [2,3-BIS(DIHETHYLARSINO)-1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE AS, AS]TRICARBONYL DIIODOTUNGSTEN(II) ..................... 16 Introduction .................................... 17 Experimental 1Structure aaalysis .............................. 18 Results and discussion .......................... 26 vi CHS.PTES 3. CRYSTAL AND MOLECULAR STRUCTURE OF DIMETHYL AMMONIUM TRICHLO 80TRIS (DIMETHYLS ULPH OXIDE) BOTH EN AT E (II) . 39 Introduction 40 ExperimentalStructure analysis .............................. 41 Results and discussion .......................... 46 CHAPTER 4. CRYSTAL AND MOLECULAR STRUCTURE OF DICHLOROTETRAKIS(DIM ETHYLSULPHOXIDE) ROTH ENIUM (II) ...... . 53 Introduction 54 Experimental .................................... 54 Structure analysis .............................. 55 Results and discussion 59 CHAPTER 5. CRYSTAL AND MOLECULAR STRUCTURE OF 1,3,7-TRIMETHYL-2,6-DIOXYPURIN E HYDROCHLORIDE DIHYDRATE (CAFFEINE HYDROCHLORIDE DIHYDRATE) 69 Introduction .................................... 70 Experimental 7Structure analysis 71 Analysis of thermal motion ...................... 77 Results and discussion 84 vii CHAPTER 6. CRYSTAL AND MOLECULAR STRUCTURE OF 1—ACETYL-3-BENZAMIDO-2-KETO-4- (2,4, 4, 6-TETRA-O-ACETYL-p-D-GLUCOPYRANOSYLOXY)-&3—PYRROLINE 92 Introduction .................................... 93 Experimental 9Structure analysis .............................. 94 Results and discussion .......................... 100 SUMMARY 113 REFERENCES ................................. ..117 viii LIST OF TABLES Table Page [2, 3-Bis (dimethylarsino)- 1,1, 1, 4, 4, 4-hexaf luorobut-2-ene-As, As]tricarbonyldiiodotungsten (II) 1 The interatomic vectors and the solution to the Patterson function »•••• • 22 2 Crystal dimensions and face indices for the absorption correction 24 3 Final atomic coordinates 8 4 Final thermal parameters ......................... 29 5 Bond lengths 32 6 Bond angles ...................................... 3 3 7 Mean planes ...................................... 36 Dimethylammonium trichlorotris{dimethylsulphoxide)-ruthenate (II) 8 Final atomic coordinates ......................... 44 9 Final thernal parameters 45 10 Bond lengths ..................................... 48 11 Bond angles 49 12 Non-bonded contacts 51 i x Dichlorotetrakis (dimethylsulphoxide) ruthenium (II) 13 Final atomic coordinates 57 14 Final thermal parameters ......................... 5 8 15 Bond lengths 61 16 Bond angles 2 17 Mean planes ...................................... 63 18 Comparison of the structural data for some dimethylsulphoxide complexes ..................... 66 1,3,7-Trimethy1-2,6-dioxypurine hydrochloride dihydrate (Caffeine hydrochloride dihydrate) 19 Starting set of reflections 74 20 Results of the phase determination procedure ..... 76 21 Final atomic coordinates 78 22 Final thermal parameters ......................... 79 23 Bigid body thermal parameters .................... 8 1 2 4 Bond lengths 82 25 Bond angles 3 26 Structural data for some purine derivatives 87 27 Mean planes 89 28 Non-bonded contacts .............................. 90 X 1-Acetyl-3-benzamido-2- keto-4- (2,4, a ,6-tetra-O-acetyl-^-D-glticopyranosyloxy) pyrroline 29 Starting set of reflections . 96 30 Results of the phase determination procedure ..... 97 31 Final atomic coordinates ......................... 102 32 Final thermal parameters ......................... 10 4 33 Bond lengths 105 34 Bond angles ...................................... 106 35 Mean planes 107 36 Structural data for some pyranose rings .......... 10 9 37 Non-bonded contacts .............................. 111 xi LIST OF FIGURES Figure Page Introduction 1 The sphere of reflection 8 2 Flow chart of practical crystallography .......... 13 [2,3-Bis{dimethylarsino)~1,1,1,4,4,4-hexafluorobut-2-ene-As,As]tricarbonyldiiodotungsten (II) 3 Schematic diagram of compounds |1) and (2) 26 4 View of the molecule down the capping carbonyl group with the carbonyl group removed .................. 27 5 A stereoview of the molecule ..................... 31 6 The structure viewed down b ...................... 37 Dimethylammonium trichlorotris(dimethylsulphoxide)-ruthenate (II) 7 A general view of the structure .................. 47 8 The structure viewed down c ...................... 52 Dichlorotetrakis (dimethylsulphoxide) ruthenium(II) 9 A general view of the structure 60 10 The structure viewed down b ...................... 67 xii 1,3,7-Trimethyl-2,6-dioxypurine hydrochloride dihydrate (Caffeine hydrochloride dihydrate) 11 A general view of the structure .................. 80 12 Comparison of several imidazole ring compounds ... 8 5 13 The structure viewed down b ...................... 91 1-Acetyl-3-benzamido-2-keto-4-(2,4,4,6-tetra-O-acetyl-p-D-glucopyranosyloxy )-A3-pyrroline 14 (A) A stereoview of the structure 101 (B) The conventional chemical structure ..........101 15 The structure viewed down b ...................... 112 ACKNOWLEDGEMENTS I wish to express my gratitude to Professor James Trotter for his help and guidance throughout all stages of this work. I am also indebted to my fellow graduate students and postdoctoral fellows who have aided me at all times, and in particular to Dr. Steven Rettig, for his assistance in the later stages of the work and in the preparation of this thesis. I would also like to thank Dr. L. Mihichuk for the tungsten crystals (Chapter 2), Dr. R. McMillan for the two ruthenium compounds (Chapters 3 and 4), Dr. D. Lenard for the caffeine compound (Chapter 5), and Dr. A. Brink for the pyrroline crystals. I am grateful to the Killam Foundation for financial support in the form of a postgraduate scholarship in the years 1973-1974 and 1974-1975. Finally, I am very grateful to all the Canadian people I have met who have made the past five years such happy ones. 1 GENES AL INTRODUCTION 2 This thesis deals principally with the structure determination by single crystal X-ray diffraction of five compounds in their crystalline state. It illustrates by both theoretical and practical discussion the three major methods presently available for structure determination viz. the Patterson heavy atom synthesis, centrosymmetric direct methods, and non-centrosyrametric direct methods, and also contains a brief description of the practical aspects of X-ray crystallography. Chapter 1 deals with the practical aspects and is designed to explain some of the terms used in the experimental sections of Chapters 2-6, and also give the non-crystallographie reader of this thesis a limited background to crystallography. All crystallographic symbols and nomenclature appearing throughout this thesis have their conventional meanings described in the "International Tables for X-ray Crystallography" (1). Chapters 2-6 contain the description of the methods of structure analysis used, with a discussion of the resulting molecular and crystal structures found, for the five compounds examined. [2,3-bis (dimethylarsino)-1,1,1,4,4,4-hexafluoro-but-2-ene-As,Js]tricarbonyldiiodotungsten(II), di-methylammonium trichlorotris(dimethy lsulphoxide)ruthenate(II), and dichlorotetrakis (dimethylsulphoxide) ruthenium (II) were all solved using Patterson syntheses, 1,3,7-trimethyl-2,6-dioxypurine hydrochloride dihydrate was solved by centrosymmetric direct methods, and 1-acetyl-3-benzamido-2-keto-4- (2,3, 4,6-tetr a-O-acetyl-p-D-glucopyranosyloxy) 3 pyrroline was solved using non-centrosymmetric direct methods. These methods are discussed in detail for the tungsten, purine and pyrroline compounds repectively. For each of the five crystal structures the least-squares refinement was based on the minimization of ^ w(Fo-Fc) z where Fo and Fc are the observed and calculated structure factors and w is the assigned weighting factor. The anisotropic thermal factors employed in the refinement are U;; in the expression: f = f°exp[-2Tt2 (U M h2a*2 + Uix]c2b*2 • U^^c*2 + 2U,thka*b* + 2U u hfa*c** + 20^k4b*c*) ] o where £ is the tabulated scattering factor and f xs that corrected for thermal motion. The isotropic thermal parameters have the form: t = f°exp [-B (sine/A) 2 ] where B is related to the mean-square displacement, [j2, of the atom from its mean position by the expression: B = 8W2U2. CHAPTER 1 INTRODUCTION TO X-RAY CRYSTALLOGRAPHY 5 A) A PRACTICAL VIEWPOINT X-ray crystallography has grown from its infancy some 60 years ago to become what many would feel is the present day definitive means of structure determination. From the complex pattern of diffracted X-ray intensities a crystallographer is usually able to piece together the internal structure of the single crystal chcsen for study. The end results contain information valuable to both theoretical and practical scientists and as such are rarely equalled in terms of accuracy and reliability. Although the principles of X-ray crystallography are well established and are discussed in several standard texts (2-6), the brief synopsis of crystallographic terms and ideas given in this chapter, and the outline of the practical aspects of obtaining the necessary data, should be very useful to the non-crystallographer reading this thesis. Often a good X-ray crystallographic structure determination will depend upon the skill of the synthetic chemist to produce a suitable crystal. A satisfactory crystal would be uniform in internal structure, single (i.e. not twinned), with a reasonable size and shape. The perfect size and shape are difficult to define since they depend on a balance of contradictory factors (e.g. a larger size produces more intensity but introduces absorption effects that must be corrected); one equation for the optimum thickness is that 10ft = 2//*. where is the linear absorption coefficient. For organic compounds yuc<10cm-1 (for CuKa radiation) giving a t0pfc = 0.2cm which is a large crystal indeed. A more general 6 rule is that a uniform cross-section crystal of size 0.1 to 0.3 mm is preferred. Obviously it is easier to work with room temperature and air stable crystals though techniques have been developed so that the structures of thermal- and air-unstable crystals can still be determined. Once suitable crystals have been found, one is attached to the end of a glass fibre, with a little non-reactive adhesive, and mounted on a goniometer head. The goniometer head is specially designed to enable simple alignment of the crystal. It has two arcs which allow the crystal to be tipped by i 20° in each of two perpendicular planes, and two perpendicular slides which allow for lateral movement of the crystal. The crysta llcgrapher must now complete two distinct operations on the crystal. Firstly it is necessary to determine the size and shape of the unit cell which also provides additional information on the internal symmetry of the crystal. Without this 'geometry' information it would be impossible to undertake the second part which entails knowing the position of all diffracted X-rays and measuring the intensity of these 'reflections', since it is these intensities that can be ultimately related to the distribution of diffracting electrons in the unit cell, in other words the crystal structure. Bragg*s Law (7) for X-ray diffraction from a crystal is given by: n X = 2dsinG where n is an integer, X is the wavelength of X-ray 7 radiation, d is the interplanar spacing, and 8- is the angle between the incident beam and the particular crystal plane being considered. The planes that are ,reflecting, the X-rays are named by Miller indices, which relate to the intercepts any plane makes on a set of reference axes a, b, and c. If these intercepts are 1/k, V* (fractions of the unit cell edge) then the plane is said to have Miller indices of (h,k,i). Rearranging Bragg«s law gives sin© = nX . 1 2 d and a simplified view of diffraction can be obtained by considering a direct relationship between sin§ and 1/d which is the construct of Ewald (8) , in his reciprocal lattice. A reciprocal lattice can be defined by considering the normals to all possible direct lattice planes (h,k,£) drawn from the origin. Each normal is terminated at a point a distance 1/d^kJl from the origin, where dKK1 is the perpendicular distance between planes of the set (h,k,4). Now the diffracting planes have been replaced by points and a reciprocal lattice with axes a*, b* and c*, compared to the real axes a, b and c, has been produced. Combining the reciprocal lattice with the sphere of reflection allows for a simple visualization of the diffraction process (fig. 1). Whenever a reciprocal lattice point coincides with the surface of the sphere the conditions for Bragg reflection are fulfilled for the corresponding set of planes in direct space and a diffracted ray passes from the centre of the sphere through this point of contact. B Figure 1 Schematic drawing of a reciprocal lattice level (n) intersecting the sphere of reflection. Diffracted rays Fass frcn the centre of the sphere through the intersecting points. As the crystal rotates other points in the reciprocal lattice level contact the sphere but always on the circle. Extended rays will seet the cylindrical film at the same height if the crystal is correctly aligned. 9 The application of these concepts can be seen in the methods used for determining the geometry of the unit cell. For this either a Weissenberg or a Precession camera, but usually both as they are complementary, can be used. In a Weissenberg camera a cylinder of film is co-axial with a real rotation axis (e.g. c), the rotation axis being perpendicular to the X-ray beam. By the reciprocal lattice definition, the a*b* planes (i.e. hkO, hk1, hk2f etc.) of reciprocal lattice points must be perpendicular to the rotation axis and parallel to the beam (fig. 1) . On oscillation these points will cut the sphere in a circle, and should, when the diffracted rays through these intersecting points are extended, meet the film at the same height. Then on unrolling and developing the diffracted spots will lie on straight lines or rows on the film. Errors in alignment of the real axis will appear and can be corrected, and as the separation of the rows on the film is a function of the identity period of the lattice this repeat distance can be determined. . A plane of reflections (e.g. hkO) contains information about the axes a* and b* but in a compressed unseparable form and as previously stated appears as a row on the film. If, however, this or any similar row is isolated (using a screen) and the film is moved while the crystal is rotating the a* and b* axes will intersect the sphere of reflection at different times and should appear on the film in different places. This is the basis of the Weissenberg technique and it provides the necessary additional unit cell information; 1 0 e.g. as the distance travelled by the film is linearly related to the angle rotated by the crystal {1mm = 2°), by a measurement of the distance apart of the axes a* and b* on the film the angled* can be determined. The disadvantage of the Heissenberg method is that it produces a distorted view of the reciprocal lattice. The Buerger precession camera overcomes this by a complex machining which duplicates the motion of one reciprocal lattice plane (again isolated, by the placement of a screen and the film) by the motion of the film, producing an undistorted view of the reciprocal lattice. Obviously this produces similar *geometric* information, though the extent of reciprocal space available is less than that of the Weissenberg camera. The Heissenberg and precession photographs also provide symmetry information in the form of 'systematic absences* which often allows for the determination of the crystallographic space group. The 230 space groups arise from the distinct combinations of the possible symmetry elements i.e., rotation axes ( e.g. a two fold rotation designated by the symbol 2), mirror planes (m) , rotation-inversion axes (e. g. 2), screw axes (e.g. 2j, a rotation plus translation), and glide planes (e.g. a, a mirror plus translation) with the 14 Bravais lattices. The presence of screw axes, glide planes, and centered lattices lead to systematic absences, i.e. reflections that are systematically missing on the film. The combination of systematic absences and symmetry on the photograph provide the information from which the space 11 group can be determined.. Sometimes it is not possible to uniquely define the space group from the photographs e.g. P2, and P2, /m have the same systematic absences i.e. on the 3k0 row every odd numbered k reflection is missing. This absence is related to the presence of the two screw axis (2,) in the group. The additional symmetry element m in P2,/m produces no absences and hence the two groups are indistinguishable. Fortunately this causes few problems in the final structure determination process. Another important piece of information is Z the number of molecules per unit cell, which is usually found by measuring the density of the crystals by flotation methods. Using the density, the total molecular weight of the cell contents can be calculated and then compared with the molecular weight of the compound. This comparison should produce close to an integer ratio, even if the molecular weight is only known approximately, which corresponds to the number of molecules in the cell. Each space group has a characteristic number of asymmetric units which generally contain one molecule, so that Z may assist in determining or confirming the space group. Unfortunately, asymmetric units can contain more (Chapter 3) or less than one molecule. In practice if the space group is still in question, the usual approach is to attempt the solution in each of the possible space groups and see which one succeeds. The film techniques have produced the following data about the crystal: the three axial lengths a, b, and c 1 2 (reciprocal dimensions can be easily transformed into real lattice dimensions by the use of standard equations), the three angles and "6 , and the probable space group. With all this information it is now possible to proceed with the second stage which involves measuring the intensity of every independent reflection. From the lattice parameters and the space group a computer can easily calculate settings for the crystal and detector, with respect to the incident beam, such that the intensity of all the desired reflections can be measured. The crystal is transfered to the diffTactometer and accurately aligned using the intensity of axial reflections. Then the maximum position of several prominent reflections (chosen from the previously taken photographs) is carefully determined so that the cell dimensions can be more accurately refined. A new set of values for the relative positions of crystal and detector can then be determined. To measure the intensity of each reflection the detector is initially positioned to one side of the maximum so that the background can be measured. The detector then scans through the reflection peak, recording the intensity, and finally measures the background on the other side. Usually from the intensity data based on all the measured reflections it is possible to determine the structure of the crystal. A brief summary of these practical procedures is illustrated in the flow diagram Figure 2. 1 3 A) Geometry of diffraction measurements Choose crystal, attach to fibre on goniometer head I Crystal mounted i Take oscillation photographs , I Crystal correctly aligned axial repeat distance determined I Take Seissenberg and precession photographs Unit cell constants and space group determined B) Intensity of diffraction data Mount on diffractometer, more accurately determine cell constants, measure intensities of all necessary reflections I Structure factor amplitudes |Fobs| determined Figure 2 Flow chart illustrating the important steps in the practical aspects of X-ray crystallography 14 B) A THEORETICAL VIEWPOINT An atom (n) with fractional co-ordinates x , y , z referred to unit cell axes a, b, and c will scatter X-radiation with an amplitude fn, and a phase constant, relative to the origin, dependent on its position in the cell, The atomic scattering factor varies with the type of atom and its value is dependent upon sin8/X for the reflection being considered (values can be obtained from tables). Further corrections are made for the thermal motion of the atom (f is tabulated for stationary atoms) as mentioned in the general introduction. If there is more than one atom then the resultant from a combination of these diffracted waves is called the structure factor and can be expressed for a general plane (h,k,t) as F(hkl) = ^ f-exp[ 2lti (hx-• ky. + I z- ) 3 where the summation is over all atoms in the unit cell. An equivalent expression is n F (hkft) = [cos2U(hxj* ky.. + Azp • isin2ir (hx, * ky^* ^2^)3 i.e. F(hkl) can be represented as a complex number F(hkt) = A + iB or F (hk|) = 1F K%tt 1 (cos ci +isin* ) hence the complex resultant is characterised by an amplitude jF| and a phase constant V given by If I =J A2 + £2 and ^ = tan-1 B/A. The measured intensity Ivwt unfortunately only tells us about |FV<U | and not about « since generally 1 5 This lack of knowledge about phases is called *the phase problem* and its affect only becomes apparent when it is realized that if the structure factors are Fourier transforms of the periodic electron density of the crystal lattice then the electron density must be the Fourier transform of the structure factors. The general expression is £ (xyz)=i £££F(hk$) exp [-2*1 (hx + ky_ + Az) J y Vv * t hence once the structure factors F(hkl) are known the above series can be summed to give a representation of the entire crystal structure. Three major methods are presently used to overcome the fact that 1^ gives information on JFVWI| and not and they are discussed in the following chapters; Patterson heavy atom methods are discussed in Chapter 2, centrosymmetric direct methods in Chapter 5, and noncentrosymmetric direct methods in Chapter 6. 1 6 CHAPTER 2 CRYSTAL AND MOLECULAR STRUCTURE OF [ 2,3-BIS(DIMETHYL ARSINQ) — 1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE-AS,AS]TRICARBO»YLDIIODOTONGSTEN (II) 1 7 INTRODUCTION Preliminary n. m. r. data on [ 2,3-bis(dimethylarsino)-Irltl* 4, 4,4-hexaf luorobut-2-ene- As,As ")tricarbonyldiiodo-tungsten(II) seemed consistent with stereochemical nonrigidity (9), the existence of which has also been observed for seven-coordinate tantalum (10)., The X-ray crystal structure of HejAsC (CFS ) :C (CF3) AsMe^HIa, (C0W was undertaken to provide information, which could indicate the geometry of the most probable transition state, for the exchange processes occuring in solution.. EXPERIMENTAL [ 2 ,3-bis (diraethylarsino)- 1, 1, 1, 4, 4, 4-hexaf luorobut- 2-ene-As, As ]tricarbonyldiiodotungsten (II) was prepared by the dropwise addition of iodine to MexAsC (CF3) :C (CF3) AsMe^W (CO)H. , in CH^Cl^, with vigorous stirring under a Na atmosphere. flecrystallization from methylene chloride/faexane gave yellow plates. The crystal chosen for study was mounted with b parallel to the goniostat axis and was ca. 0.2 mm in length with a cross section of 0.2 x 0.0 4 mm. Unit-cell and space group data were obtained from film and diffTactometer measurements. Unit-cell parameters were refined by a least-squares treatment of sin26 values for 24 reflections measured on a diffTactometer with MoK«t radiation. Crystal Data. C M H »a As1FfcIz03 w, M = 893.40 o Monoclinic, a = 15.37(2), b = 9.529(1], c = 15. 967 (3) A, £ = 112.03(2)°, 0 = 2168(2) A3, Dm= 2.737 (3) gem-3 , Z= 4, 1 8 &c = 2.735 (4) gcra-3, F(QOO) = 1608 (20°C, HoK*, >\ = 0.71069 o A, /x = 118 cm-1). Absent reflections: hOl, l#2n and OkO , k#2n define uniquely the space group P2^/c (C| , No. 14). Intensities were measured on a Datex-automated General Electric XRD 6 diffTactometer, with a scintillation counter, Ho K<* (zirconium filter and pulse height analyser) , and a 9-2B scan at 2° min-* over a range of (1.80 * 0. 86 tan 0) degrees in 26, with 20 s background counts being measured at each end of the scan. Data were measured to 2€ = 45° (minimum e interplanar spacing 0.93 ft). A check reflection was monitored every 50 reflections throughout the data collection. The greatest deviation from the initial value was +10.1% and the final intensity was 1.007 times the initial value. Lorentz and polarization corrections were applied, and the structure amplitudes were derived. Of the 2778 independent reflections measured, 942 had intensities less than 3<r(l) above background where <r2 (I) = S + B * . (0.05S)2 with S = scan count and B = time averaged background count. These reflections were classified as unobserved and given zero weight in the refinement. Structure analysis As previously stated in Chapter 1 the electron density at a point <x,y,z) can be represented by a three dimensional Fourier series with the structure factors as coefficients C&,.2,z) =i!S£ F(h,k,<)exp[-2Tti(hx * ky + *z) ]. K U t F^t contains both an amplitude JF^W4 | and a phase * ^t but the intensity information only gives data on the 1 9 !F^wt|'s, hence the phase information is unknown. Patterson (11) solved this problem by use of a Fourier series with the phaseless quantities II^v.*'2 as coefficients i.e. f(x,!,z) =1 JF kJ2cos2n(hx + ky. + I z). y v u. <. This summation produced a map which contained peaks at positions corresponding to the interatomic vectors i.e. for co-ordinates u ,v ,w on the Patterson aap there exist atoms x ",2^2, and xx,2.x,z% such that u = x,-xt v = y_, -y_1 and w = z 4-z a where Xj_,y.t,za may be a symmetry related position of At first glance the Patterson synthesis appears to provide a simple solution to the phase problem. However, if there are N atoms in the cell, there will be N{N-1)/2 distinct Patterson vectors contained in a cell of the same size. This leads to a great deal of overlap and makes interpretation virtually impossible especially for structures involving many atoms of the same weight because in addition the height of the vector peak is proportional to the product of the atomic numbers of the atoms to which it corresponds. A consequence of this is that vectors between relatively •heavy* atoms will appear larger than vectors between the lighter atoms, and here lies the key to the solution of the phase problem for certain molecules. If a molecule contains a few *heavy' atoms the Patterson function will give information on this part of the molecule. 20 If the heavy atom(s) comprise the larger share of the structure factor, a first approximation to the phases may be obtained i.e. analytically Efc„ = ^fM.^iexp[2«i(hxH.* kiH.+ <zM.)] + t £u«Ti exp[ 2*i (hxL. • kIu. * i z u. ) ] if £«,»£ui then I^A exp[2TTi (hxWi+ JSIHi + I z„- ) ]. If this first approximation is used in the Fouriar summation the difference map produced may provide the positions of another part of the molecule. These positions of new atoms can be added to the old ones and used to improve the phases. The process is then repeated and it is hoped that this iterative procedure will result in the determination of the complete structure. This process of finding successive pieces of the structure is essentially the basis for all structure determinations including the direct methods described in Chapters .5 and 6. For this compound and the two ruthenium compounds (discussed in Chapters 3 and 4) the largest peaks on the Patterson ' syntheses would be expected to be between the single heavy atoms and their symmetry related positions in all three cases. Once the tungsten and ruthenium positions were determined the iterative procedure was used to find the rest of the molecules. Even the process of finding the heavy atoms is somewhat simplified by the phenomenon first pointed out by Harker (12). He showed that useful information is contained in certain planes and lines in the Patterson map which give rise 2 1 to vectors with one or two constant co-ordinates due to the presence of symmetry (other than centres) in the crystal. For example the tungsten compound's space group was P2t/c which has four molecules in the unit cell. Due to the symmetry elements of the group any atom that occurs at the general position x,y,z (I) will also occur at the symmetry related positions x,y,z (II); x, 1/2+y_, 1/2-z (III); and x,1/2-y,1/2+z (IV), The Patterson function contains peaks which correspond to the vectors between these symmetry related positions. e.g. the vector between position (I) and (III) is either (x# 1/2-y, 1/2+z) " <**Y.»z) = (0,1/2-2y,1/2) or (£,I#z) " (S,1/2-y,1/2 + z) = (0,-1/2+2y,-1/2) as 1/2 is eguivalent to -1/2 the two vectors become 0, 1/2-2y, 1/2 and 0, 1/2*-2y_, 1/2 i.e. 0,1/2 ± 2y,1/2 {note that these two vectors were related by a centre of symmetry hence all Patterson functions must be centrosymmetric). Table 1 gives the general vectors between all the four symmetry related positions (I), (II), (III), and (IV) in its first column. A search of the Patterson map was then undertaken to see if any of the peaks corresponded to these vectors which would be expected to be between the symmetry related tungsten atoms. The second column of this table indicates the respective peaks found on the map. Column three gives the possible values for the co-ordinates x,y_,z of the tungsten atcm. The map was also examined for the presence of W-I vectors and I-I vectors and from an overall 22 Table 1 Vectors between the symmetry related positions for the Space Group P2, /c and the possible solutions to the Patterson function for the tungsten compound 'General vectors for i Space Group P2l(/c Peak on Patterson ] Possible solution] function ' ' ' 0, 1/2t2y, 1/2 #2* ; 1/2t2y =0.28 | 0.00, 0.28, 0.50 J 2y = 0.22 or 0.78! ! ±2x, 1/2, 1/2±2z ; | 4. 2x = 0. 35 I #3 l 2x = 0.35 or 0.65 0.35, 0.50, 0.27 ! 1/2i2z=,0.27 ! 2z = 0.23 or 0. 77 • i.2x, ±2y, i-2z i #16 J 2x = 0.65 or 0. 35 0.65, 0.22, 0. 23 J,2y = 0.23 or 0.78 I 2z = 0.23 or 0.77 Peaks were ordered by size, i.e. #2 was the second highest 23 examination it was deduced that 2x = 1.35, 2y. = 0.78, and 2z = 0.77 or x = 0.68, 2 = 0.39, and z = 0.38 would be the values for the co-ordinates of the tungsten atom. One cycle of full-matrix least-squares refinement varying the isotropic thermal parameters and position of the tungsten atom produced an B factor of 0.54. A difference Fourier revealed the positions of the two iodine and the two arsenic atoms and a further two cycles varying the positional and anisotropic thermal parameters reduced R to 0.20. A difference map at this stage revealed the positions of the remaining 20 atoms, but two further cycles with anisotropic thermal parameters for the five * heavy* atoms and isotropic thermal parameters for the remaining atoms reduced B to only 0.16. Due to the high value of JLK (118cm-3) and the size of the crystal it was believed that such a high discrepency at this stage was probably due to neglecting the effects of absorption when calculating the structure amplitudes. An absorption correction using the computer program BICABS was therefore attempted (13). The faces of the crystal were carefully indexed and the dimensions measured. The values used in the correction are given in Table 2. Two cycles of refinement with the same atom parameters used in the last cycles, but the new structure amplitudes corrected for absorption, produced an H factor of 0.076. Convergence was finally reached after two more cycles, using an anomalous dispersion correction and anisotropic thermal parameters for the W, I, and As atoms, and isotropic Table 2 Crystal dimensions and indices of the faces used in absorption correction ' - ! k • 1 Distance to Centroid (cm.) ' • o ! 1 0 0.0228 I i -4 j -12 11 0.0197 ! i-i 0 0 0.0045 | • -1 • 0 0 0.0045 i • _-j • 0 1 0.0207 J ! i-i 0 -1 0.0207 2 5 thermal parameters for the remaining atoms, at 8 = 0.067 for the 1823 observed reflections. {The thirteen highest intensity reflections 102, 106, 204, 202, 204, 306, 504, 502, 604, 114, 514, 025, and 225 were not included in the B factor calculation due to probable instrumental error.) The scattering factors were taken from ref. 14 and anomalous scattering corrections from ref. 15. The weighting scheme: /]T= 1 if - 7^«3;Jw~= 74.3/JFoJ if |Fo| > 74.3 and yj w = 0.0 for unobserved reflections gave constant average values of W(Fo-Fc)2 over ranges of |Fo| and was employed in the final stages of refinement. The two CF groups on the chelate ring had high isotropic temperature factors; however an Fo electron density map calculated using the phases from all the other found atoms did not reveal any evidence of disorder in the groups or individual atoms. The final positional and thermal parameters are given in Tables 3 and 4 respectively. Measured and calculated structure factors are available from the U.B.C. Library. 26 RESULTS AND DISCUSSION CO X^Mv\CO A-A 1 2 M = W M = Mo X = I X = Br Y = As Y = P R. == CH3 R = CftHs A—A = r=C A—A = CH2—CH2 CFj CF3 Figure 3 Schematic diagram cf compounds (1) and (2) from text The seven-coordinate geometry about the tungsteD atcm in (1), [2,3-bis(dimethylarsinc)-1,1,1,4,a,4-hexafluorobut-2-ene-Aj,AsJtricarbonyldiiodotungsten(II) is similar to that found for (2) dibrcmctricarbcnyl[1,2-bis (diphenylphosphino) ethanejmclybdenum(II)-1-acetone (16) (Figure 3), this type of geometry being described as a considerably distorted capped octahedron. In this mclecule the capping group is cne cf the carbonyls [C(3)-0(3) ], the three atois defining the capped face are C(1), C (2) and As(1), while the uncapped face consists of the two iodine atoms 1(1) and 1(2) and the regaining arsenic atcm As (2). Figure 4 shows a projection down the W-C(3) bond. Although it would also be possible to describe the tungsten environment in terms of various distorted capped trigcnal prisms (17), a detailed analysis of C(4) 1(1)/ 1.17(A)J '0(1) ^V-29(4) 1.98(3)/ [N^C© As(1) 2.556(3) J>.> 2.856(2) 2.00(3) |As(2) VC(2) J.19C4) Figure 4 Projection of the coordination sphere of the molecule viewed dcwc the vector from the cartonyl grcup in the capping position (ctritted from the diagrair) to the tungsten atcm. Table 3 Final positional parameters (fractional X 104) with standard deviations in parentheses atom X 2 z w 6733 (1) 39 32 (1) 3840(1) I{1) 8344(1} 3338 (2) 3427 (1) 1(2) 5627 (1) 2858 (3) 2094(1) As (1) 805 3(2) 4102 (3) 5 396(2) As (2) 6956(2) 1347 (3) 4439(2) F (1) 9743 (20) 3296 (32) 7073( 19) F(2) 10241 (19) 2691 (29) 6121 (18) F{3) 9903 (23) 1333 (36) 7008(23) F(4) 7815(25) -1202 (36) 5435(22) F(5) 9209 (26) -663 (39) 5574(24) F{6) 8701 (23) -530 (37) 6578(24) 0(1) 6742(20) 6410 (31) 2526(19) 0(2) 4737(21) 3648 (31) 3926(19) 0(3) 6362(17) 65 56 (26) 4800(16) C(1) 6688 (24) 5473 (39) 297 8(23) C (2) 5494 (22) 3788 (33) 3893 (20) C (3) 6485(25) 5613 (40) 4431 (24) C (4) 8686(18) 2270 (28) 5757 (17) C(5) 8218 (19) 1142 (30) 5422(18) C (6) 9677(23) 2355 (36) 6418(21) C(7) 8525(40) -394 (58) 5735(36) C(8) 8997(22) 5506 (34) 5546(21) C{9) 7715 (23) 4521 (37) 6430(21} C(10) 6 981 (25) -73 (40) 3550(24} C<11) 6092 (24) 535 (38) 4927(22) 29 Table 4 Final thermal parameters and their estimated standard deviations 0 a) Anisotropic thermal parameters (U-- (A2) X 102) atom Uu Dtx 0„ UiX 0^ JJaa w 4.18( 6} 6.27( 7) 4. 15 ( 6) 0.16< 5) 1.49 ( 4) 0.17( 5) 1(1) 5.68(11) 9.35(15) 6. 56 (1 2)-1 . 14 (10) 3.27 ( 9)-1.43(10) 1 (2) 6.39(12) 14. 10(22) 5. 15 (11) -0. 22 (13) 0 .57 ( 9) - 1. 10 (12 ) As(1) 5. 12 (14) 4.59 (15) 4. 62 (1 4)-0. 18 ( 12) 1. 50 (11)-0. 11 (1 1) As(2) 6.37(17) 5.87(18) 5. 61 (1 6)-1. 83 (14) 2 . 21 (1 3)-0.7 4 (1 3) lb) Isotropic thermal parameters (U x 103) Atom U (A2) Atom U(A2) F(1) 11.7 (7) C(2) 5.8 (6) F(2) 11.0 (7) C{3) 7.0 (8) F(3) 13.6 (9) C(4) 4.5(5) F(4) 13.5 (9) C(5) 4.9(6) F(5) 15 (1) C{6) 5.9(7) F(6) 13.6 (9) C (7) 11 (1) 0(1) 9.3 (7) C(8) 6.1 (7) 0(2) 9.5(7) C(9) 6.5(7) 0(3) 7.4(5) C(10) 7.4 (8) C(1) 6.9 (8) C(11) 6.9(7) 30 differences between the basic polyhedra available for seven-coordinate molecules (18), indicates that in this type of molecule the ideal angle between the two larger coordinated atoms is 180° for a pentagonal bipyramid, ca. 90° for a capped octahedron, and 81.5° for a capped trigonal prism. From the I-B-I angle of 87.3° the choice of the capped octahedron would appear to describe the observed geometry most exactly. Figure 5 shows a general stereoscopic view of the molecule, with the atom labelling scheme. Individual bond lengths and angles, with standard deviations are given in Tables 5 and 6 respectively. The angles subtended at the tungsten atom between the unique carbon atom C(3) and the atoms in the capped face, and those between C(3) and the atoms in the uncapped face, average to 74 and 128° respectively. These angles are very similar to those found in other capped octahedral structures, i.e. 73.6 and 125.5° in (2), and 73 and 128° for [bis-(diphenylarsino) methane Jdibromodicarbonylmolybdenum (II) (19) . Similarly the angles subtended at the central metal atom by pairs of atoms in the capped, and pairs in the uncapped faces for both molecules (1) and (2) are comparable. In (1) they are an average of 112 and 86° respectively, while in (2) the mean values are 112.3 and 89.7°. another feature of a distorted capped octahedron (17) demonstrated by this molecule, is the close non-bonded contacts made between the capping group and the three atoms in the capped face. Hence in (1), C{3) is 2.46, 2.26, and o 2.73 A away from C (1) , C (2) , and Asp), compared to 2.29, Figure 5 general stereoscopic view of the molecule show the crystallographic numbering scheme. -fable 5 © Bond lengths (A) with standard deviations in parentheses © o Bond Length (A) Bond Length (A) W-I(1) 2.848 (2) W-I(2) 2.856 (2) W-As(1) 2.556 (3) W-As (2) 2.618 (3) W-C(1) 2.00 (4) H-C(2) 1.97 (4) S-C (3) 1.94 (3) As(1)-C(4) 1.98{3) As (1) -C(8) 1.92 (3) As(1)-C(9) 1.95 (3) As (2) -C (5) 2.00 (3) As (2) -C(10) 1.97 (4) As (2) -C(11) 1-93(3) C(1) -0(1) 1. 17(4) C(2) -0(2) 1. 19(4) C (3) -0(3) 1. 13(4) C(4) -C(5) 1. 29(4) C (4) -C (6) 1. 50 (4) C (5) -C (7) 1. 56 (6) C (6) -F{1) 1. 35(4) C (6) -F(2) 1. 31 (4) C (6) -F{3) 1. 18(4) C(7) -F{4) 1. 27(5) C (7) -F(5) 1. 20 (5) C(7) -F(6) 1. 28(5) 33 Table 6 Bond angles (deg.) with standard deviations in parentheses. Bonds Angle Bonds Angle I(1)-W-I(2) 87.3 (D W-As(2)-C (5) 110| 1) I (1)-W-As (1) 78.2 (1) W-As(2)-C (10) 115 j 1) I (1) -W-As (2) 83.8 [1) W-As(2) -C (11) 120| 1) I(1)-W-C(1) 78 (1) C (5)-As (2)-C (10) 103( 1) I (1)-W-C (2) 161 (1) C (5)-As (2) -C (11) 105i 1) I(1)-W-C(3) 128 (1) C (10) -As(2) -C (11) 10 3 [ 1) I (2)-W-As (1) 159.4 (D As(1)-C(4)-C(5) 119 (2) I (2) -W-As (2) 88.2 (1) As (1) -C (4) -C (6) 115| [2) I (2)-W-C(1) 75 (1) C (5)-C(4)-C (6) 127 | 3) I (2) -W-C (2) 77 <1) As (2) -C (5) -C (4) 118| [2) I (2) -W-C (3) 128{1) As (2) -C(5)-C(7) 116| [3) As(1) -W-As(2) 75.9 (1) C (4)-C(5)-C (7) 126 (3) As(1)-W-C(1) 116 (1) W-C (1) -0(1) 174| 3) As(1) -W-C (2) 113 (1) W-C (2)-0(2) 178 ( 3) As (1) -W-C (3) 73 (1) W-C (3) -0(3) 177 3) As (2) -W-C{1) 155 (1) C (4)-C(6)-F(1) 1 10 ;3) As (2) — W-C {2) 85 (1) C (4)-C (6)-.P(2) 1 16 (3) As (2) -W-C (3) 128 (1) C (4)-C(6) -F(3) 1 13 3) C(1)-W-C(2) 108 (1) F (1)-C(6)-F(2) 106 3) C(1)-W-C(3) 77 (1; F (1)-C{6) -F{3) 91 3) C{2) -W-C (3) 71 (1) F (2)-C (6)-F(3) 1 17 [3) W-As (1)-C (4) 111(1] C (5)-C(7)-F(4) 109 W-As (1)-C (8) 117 (1) C (5)-C(7) -F(5) 108 ;5) W-As(1)-C(9) 118(1; C (5)-C (7)-F(6) 111 4) C (4)-As(1)-C (8) 108 (1 F (4)-C(7) -F{5) 1 19 ;5) C(4)-As(1)-C(9) 101 (1| F (4)-C (7) -F (6) 99 [5) C (8)-As(1)-C(9) 100 (1) F (5)-C (7)-F(6) 1 10 (5) 34 2.29, and 2.70 A for the respective C{1) to C (2) , C (3) , and P(1) distances in molecule (2). The angle subtended at the central tungsten atom by the bidentate ligand is 75.9(1)°. This is similar to those subtended by the mutually cis atoms of the capped and uncapped faces (the mean value of the six such angles being 78°). The ligand therefore seems ideally suited to occupy an edge of the capped octahedron. The three angles mutually tj:aa§ are also very similar being 155, 159, and 161°, giving the geometry around the tungsten (see Figure 4) a reasonable Cjv symmetry. © The tungsten-iodine distances of 2.848 (2) and 2,856 (2} A would appear to be the first determinations of W-I bond lengths in a seven-coordinate environment. Tungsten-bromine distances in similar environments (20 and 21) have already been found to have a mean value of 2.65 A. Using a bromine o covalent1 radius of 1.14 A (22) we can estimate a W single o e bond radius of 1.51 A for this compound. With use of 1.33 A (22) for the iodine covalent radius, a predicted H-I bond c length would be 2.84 A, in reasonable agreement with the o value found (mean value 2.852 (2) A). Assuming the radii of o Mo(II) and H(II) are similar the value of 2.862 A found for the Mo-I distance in Mo(CNfi)bI*- (23) is also very close to these measured and predicted values., A similar argument e predicts a W-As bond length of 2.73 A, compared to the o 2.556 (3) and 2.618(3) A found experimentally. This significant shortening is thought to be due to some double bond character in the K-As bonds caused by (dir-dir) back 35 donation from the central metal atom. The two W-As bonds are also significantly different from each other, which can be explained by consideration of the respective trans ligands. A t£M§ ligand can affect the extent of back donation from the metal, hence the 1(2) atom trans to As(1), is not as strong a dir accepting group as the C(1)-0{1) group trans to As(2) which should result in a greater back donation to As(1). This will cause a shortening of the H-As(1) bond with respect to © the W-As{2) bond, the difference found being 0.062 A. The H-C and C-0 distances (mean values 1.97(4) and © 1.16(4) A) and the W-C-0 angles (mean value 176(3)°) are similar to those found in ether compounds with carbonyls joined to tungsten (24). The five membered ring is in a 'puckered' conformation. Table 7 gives the eguation of a weighted least-squares mean plane, with deviations of the atoms from the plane, and values for the dihedral angles in the ring. This type of •puckered* conformation, with both carbon atoms on the same side of the weighted least-squares mean plane for tha five membered ring, has been found in other compounds (25). The bend in the ring is probably to increase contacts between the methyl groups on the arsenic atoms and the adjacent carbonyl groups rather than the methyl-iodine contacts (26) . Neither the carbon-carbon double bond length of 1.29(4) A (expected 1.34 A } (27) , nor the H-As-C bond angle mean value of 110.5° (expected tetrahedral value of 109.5°) and the As-C-C bond angles, mean value of 118.5° (expected for sp2 hybridized carbons of 120.0°) are significantly different 36 Table 7 a) Equation of weighted least-squares mean plane* for the five membered ring atom A (A) A/<r B 0.0015 1.404 As{2) -0.0105 3.822 As(2) -0.0127 3.970 C(4) 0.7055 24.447 C(5) 0.6139 20.574 * plane: 0.894X - 0.151Y - 0.421Z = 4.240, where X,Y, and 2 are orthogonal angstrom coordinates derived as follows i-Xn r a 0 ccos P n rx-, III = I 0 b 0 i HI *-Z-« «- o 0 csin p -» «-z-« b) Dihedral angles in the five membered ring Atom 1 Atom 2 Atom 3 Atom 4 Angle (deg.) As (2) H As{1) C(4) 23(1) As (1) SJ As (2) C (5) -20 (1) W &s(1) C(4) C(5) -26(2) W As (2) C (5) C (4) 12 (2) As(1) C(4) C{5) As (2) 8 (2) Figure 6 & projection of the structure down the h axis. 38 £rom their stated expected values. Both the As(1)-C(4) and o As(2)-C(5) bond distances of 1.98(3) and 2.00(3) A are similar to the AS-CH3 bond lengths (mean, 1.98(3) A) as is found in other similar ligands (28). From the relative uncertainty of the positions of the two CF 3 groups, it seems unreasonable to attempt any meaningful discussion of their bond lengths and angles. The intermolecular packing appears to be governed solely by van der Kaals interactions. A projection of the structure down the b axis is shown in Figure 6. The n.m.r. data for this compound (9) indicated that molecular rearrangement must be occuring in solution. The crystal structure would suggest that the process involves rapid scrambling of the carbonyl groups and the iodine atoms, and simultaneous migration of the capping group over the faces of the [AstCxI^] octahedron; The sharpness of the spectra at -70°C indicates that the limiting spectrum corresponding to the solid state structure would be reached only at a much lower temperature. CHAPTER 3 CRYSTAL AND MOLECULAR STRUCTURE OF DIMETHYLAMMONIUM TRICHLOROTRIS (DIMETHYLSULPHOXIDE) RUTHENATE (II) . 40 INTRODUCTION From the results of the infrared and lH n.m.r. spectral data on dimethylammonium trichlorotris-(dimethylsulphoxide)ruthenate(II) (29) if was thought that all three dimethylsulphoxide ligands were S-bonded and that the anion was in the fac-configuration. The X-ray crystallographic study was undertaken to verify this assignment and determine structural parameters which could be useful in explaining the catalytic properties of these materials., EXPERIMENTAL Ruthenium trichloride trihydrate (1g# 39% Ru) and dimethylsulphoxide (1ml) were heated at 80°C in NN' -dimethylacetamide (20ml) under 1 atm hydrogen for 4h. The resulting red solution was set aside at room temperature (or concentrated to 10ml and cooled) and gave a bright yellow product which was washed with ether, and vacuum dried. Recrystallization of [ ((CH3 ) z SO)a RuCl3 ] [ (CHjJ^NH^] from dimethylacetamide gave yellow cubes. The crystal chosen for study was mounted with c parallel to the goniostat axis and was ca. 0.3 mm in length with a cross section of 0.25 x 0.2 5 mm. Unit cell and space group data were obtained from film and diffTactometer measurements. The unit-cell parameters were refined by a least-squares treatment of sin2© values for 20 reflections measured on a dif fr actometer with MoK«*. 41 radiation. Crystal Data. CgHabCl<3NOsRuS3, M = 487.9 Orthorhombic, © o a = 27.459(5), b = 9.925 (1), c= 14. 266 (3) A, 0 = 3887(1) A3, Dm= 1.67(1) gem-3, 1=8, Dc= 1. 667 (5) gcm~3 , o F(000) = 1984 (20 °C, HoK<* , X= 0.71069 A, /x = 15.036 cm-* ). Absent reflections: Okl, k+1 * 2n, hkO, h # 2n define the space group as either Pnma (D** , No. 62) or Pn2, a (C|v , No. ,33) . Intensities were measured on a Datex-automated General Electric XBD 6 diffTactometer, with a scintillation counter, Mo K<* (zirconium filter and pulse height analyser) , and a 8— 29 scan at 2° min"1 over a range of (1.80 + 0.86 tan 9) degrees in 2©, with 10 s background counts being measured at each end of the scan. Data were measured to 29 = 45° (minimum © interplanar spacing 0.93 A) . A check reflection was monitored every 50 reflections throughout the data collection. The greatest deviation from the initial value was +11.1% and the final intensity was 1.067 times the initial value. Lorentz and polarization corrections were applied, and the structure amplitudes were derived. No absorption correction was applied due to the low value of /*., and the fairly uniform shape of the crystal. Of the 2637 independent reflections measured, 676 had intensities less than 3«-(I) above background where «"2 (I) = S * B + (0.05S)2 with S = scan count and B = time averaged background count. These reflections were classified as unobserved and given zero weight in the refinement. STRUCTURE ANALYSIS In a similar manner to that described in the previous chapter a Patterson function was used to solve the structure of the compound. However, the initial attempt to solve the structure in the space group Pnma required a maximum at 0,0.5-2y,0 in the Patterson function. The three-dimensional Patterson map revealed no such peak other than the origin. If this was the case the y coordinate for the Ru atom would have to be 0.25, locating the atom on the crystallographic mirror plane. Although the anion could possess mirror symmetry, an attempt was then made to solve the structure in the non-centric space group, Pn2la. Since this space group has only four eguivalent positions, there must be two crystallographically non-equivalent molecules in the asymmetric unit. In Pn2,a the heavy atom vectors on the Patterson map are to be found on the Harker plane 2x, 1/2, 2y. Examination of the map gave the x and z coordinates of Ru(1) and Ru(2), but left their y values unspecified. In this space group, however, there is no unique origin point along the b axis so Ru (2) was arbitrarily assigned the y coordinate 0.000, which was kept constant throughout the later refinements. One cycle of full-matrix least-squares refinement of the positional and isotropic thermal parameters for these two ruthenium atoms produced an R factor of 0.45. A difference Fourier revealed the positions of the six chlorine and six sulphur atoms. Two further cycles for these fourteen atoms still varying the positional and isotropic thermal parameters gave an R value of 0.19. The difference map at this stage revealed the positions of the remaining 24 oxygen, nitrogen and carbon atoms. After several more cycles convergence was finally reached, using an anomalous scattering correction for the Ru, Cl, and S atoms, and varying the positional and anisotropic thermal parameters for all the atoms, at R ~ 0.045 for 1943 observed reflections (the following reflections were removed from the data set in the final stages of refinement due to suspected errors resulting from extinction, absorption, and instrument malfunction: 4 0 0, 2 4 0, 19 0 1, 21 0 1, 2 1 1, 10 0 2, 17 1 2, 14 0 3, 4 0 4, 9 0 4, 12 0 4, 3 0 5, 2 3 5, 8 0 7, 10 6 7, 19 0 8, 0 1 9, and 1 0 14.) Due to the additional expense involved in further refinement for a structure with so many variables, bearing in mind the reason behind the investigation, and the inherent difficulty with so many heavy atoms present, no attempt was made to determine or refine the positions of the hydrogen atoms in the RuCl3 (MezS0)^ molecules. The positions of the hydrogen atoms bonded directly to the nitrogen atoms in the e cations were calculated (assuming a N-H bond length of 0.99 A and a H-N-H angle of 108°.) to give an idea of the interionic bonding. These atoms were not included in the structure refinement. The scattering factors were taken from ref. 14 and anomalous scattering corrections (15) were applied for the Ru, Cl and S atoms. The weighting scheme: /~w =1 if |Fo| < 65; /w = 65/1 Foi if |Fo| > 65 and J~v = 0-0 for unobserved reflections gave constant average values of w (Fo-Fc)2 over ranges of |Foj and was used in the final stages of refinement. The final positional and thermal Table 8 Final positional parameters (fractional x 10*) with estimated standard deviations in parentheses Atom X I z Ru(1) 2560 (0) 4849 (2) 3945 ( 1) Ru (2) 283(0) 0 2858 ( 1) Cl (11) 1670(1) 4795(6) 3851 ( 3) Cl(12) 2489(2) 3399(5) 5299 { 3) Cl(13) 2563(2) 2834 (5) 2997 j [3) Cl (21) 1094 (2) 10090 (8) 2176 \ ,3) Cl{22) 469 (2) 2095(6) 3640 { A) Cl (23) 640 (2) 8823 (7) 4181| «0 S(11) 3381 (1) 4766 (6) 3943 < [3) S(12) 2556 (2) 6598 (5) 4961 | [3) S(13) 254 8(2) 6206 (5) 2680 | [3) S(21) 9543 (1) 10104(7) 3 556 | (3) S (22) 16(2) 1123 (6) 1567 (3) S (23) 128 (2) 7954(6) 2231 i [*») 0(111) 3657(5) 5966 (14) 4246 (11) 0 (121) 2672(5) 7981 (14) 4620 (9) 0(131) 3 026 (5) 6846 (13) 2425 (9) 0(211) 9154 (4) 9221(15) 3 198 (10) 0 (221) 948 7 (6) 1271 (18) 1434 (10) 0(231) 9823 (7) 7888 (17) 1401 (11) C(111) 3606(8) 3435 (22) 4669 (18) C(112) 3638 (8) 4336(23) 2772 (15) C(121) 2948(7) 6334 (20) 5956 (12) C (122) 1970(8) 6759(27) 5528 (16) C(131) 2 335(9) 5372 (22) 1655 (13) C(132) 2105(8) 7535(20) 2752 (14) C(211) 9575(7) -125 (37) 4788 (11) C (212) 9299 (6) 1795(26) 3530 (17) C(221) 293 (13) 2769 (24) 15 10 (21) C (222) 233 (9) 491(27) 499 (15) C{231) 9 857 (9) 6784 (28) 3017 (20) C(232) 675(11) 7074 (24) 2026 (26) N ( 1) 3646 (6) 880 9(18) 3556 (13) N(2) 1569 (6) 1629(15) 4378 (12) C(11) 3 297 (8) 9802 (28) 3173 (17) C(12) 3790(10) 9068 (28) 4564 (17) C(21) 1870 (7) 413 (19) 4212 (16) C (22) 1378 (9) 1719(22) 5336 (14) H(11) 3944 8818 3163 H(12) 3500 7900 3513 H(21) 1768 2438 4248 H (22) 1292 1624 3934 Table 9 Final thermal parameters and their estimated standard deviations anisotropic thermal pa ra me te r s (U ^ x 102 o A*} atom Ru(1) 3.28 (8) 2.10(6) 1. 82 (5) -0. 1 1 (8) -0.07(4) 0.04(6) Ru (2) 2.82(8) 3.56(7) 2.81 (6) -0.40 (6) -0.12 (6) 0.37 (9) Cl(11) 3.5(2) 4.1 (3) 4. 2(2) -0.5 (3) -0.2 I (2) 0.5 ( 3) Cl (12) 6.5 (3) 3.2 (3) 2.7 (2) -1. 1 (2) -0.9 [2) 1.4( 2) Cl(13) 6.5 (3) 2.7 (2) 3.4(2) 0.1 (2) -1.2 [2) -0.5 { 2) Cl (21) 3.4(2) 7.5 (3) 5.3(2) -0.4(3) 0.9 [2) 0.5( 3) Cl{22) 4.6(3) 4.5 (3) 6.4(3) -0.8 (2) -1.4 (3) - 1.3 ( 3) Cl (23) 5.5 (3) 6.9 (4) 4. 9(3) 0.1 (3) -1.3 [3) 2-0 | 3) S(11) 3.2(2) 3.4 (3) 3.7(2) 0.8 (2) 0. 1 (3) -0.9 | 2) S (12) 3.0 (2) 3.2 (2) 1.9(2) -0.2(2) 0.3( [2) -0.0( 2) S(13) 4.3 (3) 2. 1 (2) 1.9(2) 0.1 (2) 0.4 (2) 0. 1 ( 2) S(21) 3.4 (2) 5.1 (3) 3.0(2) -0.4 (3) 0.2 (2) 0.5 | 2) S (22) 4.7(3) 4.5 (3) 3.6(3} 0.3 (2) -0.7 (2) 1.3( 2) S(23) 5.7 (3) 3.8 (3) 5.6(3) -0.4 (2) -1.3 (3) 0.3| 3) 0(111) 2.5(7) 4.4(9) 9(1) -1.0 (6) 0.6 (?) -0.8 i 8) 0 (121) 5.5(8) 3.4 (7) 4.5(7) -0.7(6) 0.3 (6) 0.0j 7) 0(131) 4.8(8) 3.9(8) 4. 1 (7) -1.2 (7) 0.5 (6) 1.0i 6) 0 (211) 2. 1 (7) 7.2 (9) 6. 0(8) -1.6 (7) 0.4 (6) 0.4j 8) 0(221) 7(1) 9 (1) 4. 3 (8) 3 (1) -1.6 (8) 0.0 9) 0 (231) 13(1) 5(1) 5. 8(9) -0(1) -3(1) -0.2i 8) C{111) 4(1) 5(1) 9(2) 2(1) -2(1) 1 (1) C (112) 5(1) 6(1) 6(1) 2(1) -1(1) -3 (1) C (121) 5(1) 4 (1) 3(1) -1(1) -1. 1 (9) -0.3 | [9) C(122) 4(1) 9 (2) 5(1) -3 (1 ) 3(1) "2 (1) C (131) 9(2) 5 (1) 2.5 (9) 2(1) -2(1) - 0.6 | 9} C (132) 6(1) 4(1) 5(1) 1 (1) -0(1) 2 (D C(211) 6 (1) 11(2) 2.7 (9) 1(2) 1.6 (8) 1 (2) C (212) 1.2(9) 9 (2) 9(2) 2(1) 1(1) -4 (1) C (221) 16 (3) 4 (2) 10(2) -3(2) -2(2) 3 (1) C (222) 7(1) 10(2) 3(1) 1 (1) -0(1) 0 (1) C (231) 7 (2) 8 (2) 10 (2) -3(1} -3(2) 5(2) C (232) 9(2) 3(1) 18(3} 0(1) -2 (2) -0 (2) W(1) 5(1) 3.4 (9) 8(1) 1.0(9) 2(1] 0.6 [9) H(2) 3. 9(9) 2.4(9} 6(1) 0.7(7) 0.8 (8) -0.6 [8) C(11) 6(1) 6 (2) 9(1) 1(1) 3(1) 2 (2) C(21) 3(1) 4(1) 9(2} 0.6 (8) -0(1) -1 (D C(12) 10(2) 8 (2) 6(1) -3(2) -0(1] 0 (1) C (22) 7(2) 6 (2) 3(1) -1(1) -1(1) -0 (1) 46 parameters are given in Tables 8 and 9 respectively. Measured and calculated structure factors are available from the U.B.C. Library. RESULTS AND DISCUSSION The structure consists of two crystallographically non-equivalent anions in the asymmetric unit, linked by two non-eguivalent dimethylammonium cations. The atom labelling scheme is illustrated in Figure 7. Most corresponding bond lengths and angles are not significantly different between the two independent formula units, as can be seen from Tables 10 and 11. All three DMSO ligands are coordinated through the sulphur atoms, the coordination geometry about the ruthenium atoms being essentially that of an octahedron, with each DMSO ligand having a chlorine atom in a trans position. Slight distortion does occur, presumably due to steric interference between the DMSO groups, the Cl-Ru-Cl angles being slightly smaller than 90° [87.1-88.3(2)°, mean 87.6°] while those for S-Ru-S are slightly larger [ 92.0-93.4(2)°, mean 92.6°]. o o The Ru-S bond lengths [ 2.25 2-2. 273 (5) A, mean 2.261 A] are significantly longer while the S-0 distances [ 1.45-o o 1.50(1) A, mean 1.48 A] are shorter than those found in o o [ Ru (NH3 )s DMSO2* 2PFb-J (30) i.e. 2.188(3) A and 1.527 (8) A respectively. These changes in bond length indicate a decrease in the possible dir-jr«r back donation from the central metal to the sulphur atom caused by the competition from the other DMSO ligands for the available "W-donor orbitals. Similar effects are seen for trans-PdClj{DMS0)a [Pd-S o © 2.299 (2) A, and S-0 1.476(5) AJ (31) and cis-A general view of the structure showing the crystallographic numbering scheme. 48 Table J.0 o Bond Lengths (A) with standard deviations in parentheses. o o Bond Length (A) Bond Length (A) Bu (1) -Cl(1 1) 2. 450 (4) Ru (2) -Cl (21) 2. 430(4) Ru (1) -Cl (12) 2. 417(4) Ru (2) -Cl (22) 2. 414(5) Ru (1.) -Cl (13) 2. 415 (5) Ru (2) -Cl (23) 2. 427(5) Ru (1) -S(11) 2. 256 (4) Ru (2) -S (21) 2. 267(4) Ru (1) -S(12) 2. 261 (5) Ru (2) -S(22) 2. 273 (5) Ru (1) -S(13) 2. 252 (4) Bu(2) -S (23) 2. 260(5) S (11) -0(111) 1. 48(1) S (21) -0 (21 1) 1. 47 (1) S{12) -0 (121) 1. 49 (1) S (22) -0 (221) 1. 47(2) S {13) -0(131) 1. 50(1) S (23) -0 (231) 1. 45 (2) S (11) -C(111) 1. 79 (2) S (21) -C (21 1} 1. 77 (2) S (11) -C (112) 1. 86 (2) S (21) -C (212) 1. 8 1 (2) S (12) -C(121) 1. 80 (2) S (22) -C (221) 1. 80 (2) S (12) -C (122) 1. 81 (2) S (22) -C (222) 1. 75(2) S { 13) -C (131) 1. 78 (2) S (23) -C (231) 1. 78 (3) S (13) -C(132) 1. 80 (2) S (23) -C (232) 1. 7 6 (3) N(1) -C(11) 1. 48 (3) N(2) -C(21) 1. 48(2) N(1) -C(12) 1. 51 (3) N{2) -C (22) 1. 47(3) 4 9 Table jn Bond angles (deg) with standard deviations in parentheses. Bonds Angle (deg) Bonds Angle (deg) Cl(11) -Ru (1) -Cl (12) 87.1(2) Cl (21) -Ru (2) -Cl(22) 87.7 (2) Cl(11) -Ru( 1) -Cl(13) 87.4(2) Cl(21) -Ru (2) -Cl{2 3) 87.7 (2) Cl (1 1) -Ru(1) -s ( 11) 175.4 (2) Cl (21) -Ru (2) -S (21) 174.7 (2) Cl (11) -Ru (1) -s j 12) 92.7 (2) Cl (21 j -Ru(2) -S (22) 87.3(2) Cl(11) -Ru(1) -S ( 13} 87.4(2} Cl(21) -Ru (2) -S (23) 92.7 (2) Cl (12) -Ru (1) -Cl (13) 87.4 (2) Cl (22) -Ru (2) -Cl(23) 88.3 (2) Cl(12) -Ru{1) -s { 11) 93.4(2) Cl(22) -Ru (2) -S (21) 86. 9(2) Cl{12) -Ru{ 1) -S ( 12) 86.8(2) Cl (22; -Ru (2) -S (22) 91.2 (2) Cl (12) -Ru{1) -S | 13) 174.5 (2) Cl (22) -Ru (2) -S (23) 175.4 (2) Cl(13) -Ru(1) -s | 11) 88.0(2) Cl (23] -Ru (2) -S (21) 92.4 (2) Cl(13) -Ru (1) -S i 12) 174.2(2) Cl(23; -Ru (2) -S (22) 175.0 (2) Cl(13) -Ru (1) -s | 13) 92.6 (2) Cl (23] -Ru (2) -S (23) 87.2 (2) S(11) -Ru(1) -s I 12) 92.0(2) S (21) -Su (2) -S (22) 92.5 (2) S(11) -Ru (1) -s \ 13) 92. 0 (2) S (21) -Ru (2) -S (23) 92.6 (2) S(12) -Ru{ 1) -s | 13) 93. 1 (2) S (22) -Ru (2) -S (23) 9 3.4 (2) Eu(1) -S (11) -0 i 1 11) 118.9 (6) Su (2) -S(21) -0 (211) 118. 1 (6) Ru{1) -S (12) -0 i 121) 119.8 (5) Ru (2) -5(22) -0 (221) 118.2 (7) Ru(1) -S(13) -0 | 131) 115.7 (5) Ru (2) -S(23) -0 (231) 118. 2 (7) Ru(1) -S (11) -C I 1 11) 111.8 (8) Ru (2) -S(21) -C (2 11) 112. 6 (6) Ru(1) -S (11) -c 1 1 12) 1 12.8 (7) Ru(2) -S(21) -C (212) 111.4 (7) Ru(1) -S (12) -c 121) 113.0 (7) Ru (2) -S (22j -C (221) 110(1} Ru(1) -S (12) -C i 122) 111.1 (8) Ru (2) -S(22) -C (222) 114.8 (8) RU(1) -S{13) -C \ 131) 112.7(8) Ru (2) -S(23, -C (231) 115(1) Ru(1) -S (13) -C | 132) 113.8 (7) Ru (2) -S(23) -C (232) 110(1) 0(111) -S(11) -C i 1 11} 104.4 (9) 0 (211] |-S(21] -C (211) 108(1) 0(111) -S (1 1) -c [1 12) 104.6(9) 0 (211 -S{21) -C (212) 106(1) 0(121) -S{12) -c | 121) 105.3(8) 0 (221 i-S (22] -C (221) 109(1) 0(121) -S (12) -c 122) 105 (1) 0 (221 -S{22; -C (222) 105(1) 0(131) -S (13) ~C ! 131} 107 (1) 0 (231 i-S (23' -C (23 1) 104(1) 0(131) -S (13) -C [132) 107.1 (9) 0 (231 -S(23; -C (232) 110(1) C(11 1) -S(11) -c | [112) 103 (1) C (211 |-S(21] |-C (212) 99(1) C(121) -S (12) -c 1 122) 101 (1) C (221 -S(22) -C (222) 98 (1) C(131) -S{13) -c ;132) 100 (1) C (231 I -S(23] -C (232) 98(1) C(11) -13(1) -c { 12) 114 (2) C (21) -N (2) -C (22) 113(2) 50 o o Pa (N03 )x (DMS0)2 [ Pd-S 2.231(3) A, and S-0 1.463 (7) A] (32). The strong trans effect of sulphur-bonded DMSO ligands (33) is illustrated in the 8 u-Cl bond distances [2.414-2.450 (4) A, mean 2.426 A] which are significantly longer than © those for the mutually trans chlorine atoms [mean 2.390(7) A] in the octahedral complex RuClj(KzCbH^(CHj)) (P (CbHs)a)2. (CH3)l0 (34) . The' geometry about the sulphur atoms is the expected distorted tetrahedron with values of 115.7-119.8(5)°, mean 118.2°, for the 8u-S-0 angles, and 110-115(1)°, mean 112°, for the Hu-S-C angles. The values of the O-S-C angles [104-110(1)°, mean 106°], the C-S-C angles [ 98-103 (1)°, mean o o 100°], and the S-C bond lengths [1.7 5-1.86(2) A, mean 1.79 A] are very similar to those found for free DMSO [107°, 98° and e 1.80-1.82(1) A respectively] (35). The hydrogen atoms attached to the nitrogen atoms in the dimethylammonium cations are involved in hydrogen bonding to both non-eguivalent anions, forming a chain-like structure throughout the crystal lattice. H (11) and H(12) take part in N-H ..... 0 hydrogen bonding, while H(21) and H(22) are involved in N-H . . . Cl hydrogen bonding. Although heavy atom separations do not uniquely define the presence of hydrogen bonding, they can give a reasonable indication, values of typical heavy atom contact distances being 2.9 A o and 3.3 A for N .... 0. and N . . . Cl hydrogen bonded atoms (36 and 37). From Table 12 it can be seen that several of the separations are well above these values, tending to 5 1 Table 12 Values ofO . . . , N, 0. . . H, Cl ... N and Cl . . . H intermolecular contacts. -- . --Atoms Distance (A) Atoms Distance (A) 0 (111)-N (1) 2.99 (2) 0(111] -H(12) 2.2 0 (121) -K (1) 3.18(2) 0(121) -H (1 2) 2.8 0(131)-N{1) 3.05 (3) 0 (131 ] -H(12) 2.3 0 (21 1)-H{1). 2.89 (2) 0 (211) -H ( 11) 2.1 0 (221)-N (1) 3.36 (3) 0(221] -H(11) 2.9 0(231)-N (1) 3.36(3) 0(231) -H(11) 2.7 Cl(1 1)-N(2) 3.24(3) ci (11) -H(21) 2.4 Cl(12)-N (2) 3.35 (3) Cl(12) -H(21) 2.7 Cl (13)-N (2) 3.57 (4) Cl(13) -H(21) 2.8 Cl (21)-N (2) 3.73(4) Cl (21) -H (22) 3.0 Cl(22) —N (2) 3. 23 (3) Cl (22) -H (22) 2.3 Cl(23) -N{2) 3.79(4) Cl(23) -H (22) 3.3 Due to the hydrogen positions being calculated the errors in the 0 ....... H, and Cl ... H distances are subject to speculation. Fiqure 8 A stereoscopic diagram of the unit cell viewed down c; hydroqen bonds are indicated by dotted lines. rule out the presence of hydroqen bonding for these chlorine and oxygen atoms. Unfortunately the hydroqen positions must be somewhat speculative, but the trends indicated from the 0 . . . H and Cl . . . H separations support the findings for the heavy atom contacts. Typical observed H . - . 0 and o * e H . . . Cl distances are 2.0 A and 2.4 A compared to 2.6 A and 3.0 A for van der Haals contact only. The overall results would indicate the presence of at least six hydroqen bonds N(1)-H{12) . . . 0(111), N(1)-H(12) . . . 0(131), N(1)-H(11) . . . 0(211), N(2)-H(21) ... Cl(11), N(2)-H(21) . . . Cl(12) and N(2)-H(22) ... Cl(22). Fiqure 8 shows the contents of the unit cell viewed along c-with these hydrogen bonds indicated by the dotted lines. CHAPTER 4 CRYSTAL AND MOLECULAR STRUCTURE OF DXCHLOROTETRAKIS (DIMETHYLSULPHOXIDE) RUTHENIUM (II) 54 INTRODUCTION Infrared and *H n. m. r. ,spectral data on dichlorotetrakis (dimethylsulphoxide) ruthenium (II) indicated the possibility of a mixture of S-bonded and O-bonded dimethylsulphoxide ligands (38). The X-ray crystallographic study of [ (MejSO)i^RuCla, ] was undertaken to verify this unusual assignment, and provide additional information to that gained from the structure presented in Chapter 3 (29) on ruthenium dimethylsulphoxide complexes. EXPERIMENTAL 1g of ruthenium trichloride was refluxed in methanol (20ml) under hydrogen (1 atm) for approximately 8hr producing a blue solution. 4ml of dimethylsulphoxide were then added and the refluxing continued for a further 2 hours finally producing a red solution. Cooling and recrystallization of (MeiSO)H.RuCli from methanol gave yellow cubes. The crystal chosen for study was mounted with c* parallel to the goniostat axis and had dimensions of ca 0.20 x 0.20 x 0.2 5 mm. Unit-cell and space group data were obtained from film and diffractometer measurements. The unit-cell parameters were refined by a least-squares treatment of sin2© values for 21 reflections measured on a diffractometer with Mo K«t radiation.. Crystal ' Data. CfHi* CljO^uS^ , M = 484.54 , monoclinic, a = 8.939 (3), b = 18.045(7), c = 11.363(3) A, P= 91.52(2)° U = 1832 (1) A3, 0^= 1.74(1) gcm-3 Z = 4, 0t= 1.76(1) gcm-3, © F(000) = 984 (20°C, Mo K*, X= 0.71069 A, A= 15.66 cr>) . 55 Absent reflections: hOl, h>l # 2n, QkO, k # 2n define uniquely the space group P2,/n (C|^, No. 14). Intensities were measured on a Datex-automated General Electric XRD 6 diffractometer, with a scintillation counter, Mo K« (zirconium filter and pulse height analyser), and a 9-29 scan at 2° min-* over a range of {1.80 + 0.86 tan 9) degrees in 29, with 20 s background counts being measured at each end of the scan. Data were measured to 29 = 45° (minimum e inter planar spacing 0.93 A) . A check reflexion was monitored every 50 reflections throughout the data collection. The greatest deviation from the initial value was +7.8% and the final intensity was 0.962 times the initial value. Lorentz and polarization corrections were applied, and the structure amplitudes were derived. No absorption correction was applied due to the low value of/* , and the fairly uniform shape of the crystal. Of the 3231 independent reflections measured, 511 had intensities less than 3«-(I) above background where <rz(D = S + B * (0.05S)2 with S = scan count and B = time averaged background count. These reflections were classified as unobserved and given zero weight in the refinement. STRUCTURE ANALYSIS The position of the ruthenium atom was again determined from the three-dimensional Patterson function. One cycle of full-matrix least-squares refinement of the positional and isotropic thermal parameters for the ruthenium atom gave a R value of 0.48. The positions of the two chlorine atoms and the four sulphur atoms were revealed from a difference 56 Fourier, and two further isotropic cycles lowered R to 0.20. another difference map then revealed the positions of the remaining non-hydrogen atoms, a further three cycles using an anomalous scattering correction for the Ru, Cl, and S atoms, and refining the positional and anisotropic thermal parameters for all the atoms, lowered R to 0.047. a final difference Fourier performed at this stage indicated the positions of eleven of the twenty-four hydrogens, and the remaining thirteen positions were calculated allowing for minimum intramolecular interactions (see Table 13). The final conventional R factor for the 2720 observed reflections was R = 0.041. (15 reflections were given zero weight in the final stages of refinement due to suspected errors resulting from extinction, absorption, or instrument malfunction: 12 4, 3 0 1, 4 2 1, 3 4 1, 2 0 0, 4 0 0, 3 2 0, 1 6 0, 080, 181, 40 2, 1 0 3, 023, 004, 02 5). The scattering factors of ref. 14 were used for the non-hydrogen atoms and those of ref. 39 for the hydrogen atoms, anomalous scattering corrections (15) were applied for the Ru, Cl, and S atoms. The weighting scheme: fit ~ I£° 1/12.8 if JFo| < 12.8, J~i = 1 if 22.6 < |Fo| > 12.8, /T = 22.6/|FoJ if |Fo| > 22.6 and - 0.0 for unobserved reflections gave constant average values of w (Fo-Fc) 2 over ranges of IFoj and was employed in the final stages of refinement. The final positional and thermal parameters are given in Tables 13 and 14 respectively. Measured and calculated structure amplitudes are available from U.B.C. Library. Table 13 Final positional parameters {fractional x 10*) with estimated standard deviations in parentheses atom X I z EU 2484.2(4) 1 217.5 (2) 2654.5 (3) Cl{1) 5001 (1) 701 (1) 2652(1) Cl(2) 1570 (1) 9972 (1) 3040 (1) S(1) 2361 (2) 1051 (1) 690 (1) S (2) 3332 (1) 2403 ( 1) 2507(1) S{3) 63(1) 1591 (1) 2791 (1) S (4) 3528 (1) 766 (1) 5290(1) 0(1) 1036 (6) 1302 (3) 9984 (4) 0 (2) 30 41 (6) 2800(2) 1379(4) 0(3) 9657(5) 2378 (2) 2577 (4) 0(4) 27 65 (4) 1377(2) 4515(3) C{11) 3980(8) 1413 (4) 9964 (5) C (12) 2596 (9) 96 (4) 349(6) C(21) 5292(7) 2486 (4) 2867 (8) C (22) 2660 (7) 2982(3) 3649(6) C(31) 9396 (7) 1365 (4) 4216 (6) C{32) 8809 (6) 1047 (4) 1886(6) C (41) 2524(8) 843 (5) 6619(6) C{42) 5262(8) 1176 (4) 5778(7) H {11 1) 36 00 1851 10 H (112) * 48 19 1075 77 H(113) * 3739 1460 -887 H (121)* 20 55 -219 896 H(122) 2488 95 -500 H (123)* 36 86 -39 420 H{211) 6027 2329 2347 H (212) 5577 3058 3184 H (213) * 5432 2480 3753 H (221) * 1597 2888 3775 H (222) 2950 3004 4 429 H(223) 3081 3456 3520 H(311) -47 1638 4969 H (312) * -1516 1654 4370 H(313)* -869 832 4241 H (321) * -754 959 1111 H (322) -1170 490 2150 H{323)* -2150 1307 1770 H{41 1) 2392 1321 7080 H (412) 1447 1197 6664 H (413) * 2915 490 721 1 H (421) 4397 1421 6023 H{422) * 5795 829 6304 H (423)* 5867 1287 5100 •calculated positions 5 8 Table JJ Final thermal parameters and their estimated standard deviations (a) Anisotropic thermal parameters (U>- x 1Q2 A2) Atom 0 fi 21 fi S3 u 0 va fi 2.Z Hu 2. 08 ( 2) 2.59 ( 2) 3. 21 { 2) 0. 00 ( 1) 0 .09 ( 1) 0. 10 ( 1) Cl(1) 2. 33 ( 6) 4.3 8 ( 7) 5. 74 ( 8) 0. 62 ( 5) 0 .20 ( 5) 0. 09 ( 5) Cl(2) 3. 72 ( 6) 2.96 ( 6) 5. 42 ( 7) -0. 58 ( 5) -0 .01 ( 5) 0. 39 ( 5) S(1) 3. 82 ( 7) 5.23 { 7) 3. 34 ( 6) 0. 03 ( 6) -0 .03 ( 5} 0. 16 ( 5) S{2) 4. 00 ( 7) 2.75 ( 6) 5. 49 { 7) -0. 28 { 5) 1 .06 ( 5) 0.20 ( 5) S(3) 2. 39 ( 6) 3.84 { 7) 4. 92 ( 7) 0. 39 ( 5) 0 .28 ( 5) 0. 19 ( 5) S (4) 4. 00 ( 7) 3.51 ( 6) 3. 75 ( 6) 0. 19 ( 5) -0 .62 ( 5) -0.22 ( 5) 0(1) 5. 62 (29) 12.78 (51) 4. 73 (24) 1. 51 (26) -1 .56 (21) 1.8 6 (26) 0(2) 10. 47 (39) 4. 19 (24) 6. 45 (28) 0. 83 (25) 2 .49 (26) 1.74 (21) 0(3) 4. 18 (21) 4.0 8 (22) 9. 27 (32) 1. 78 (18) 0 .15 (20) 0.7 5 (21) 0(4) 4. 09 (20) 3.95 (19) 3. 39 (16) 0. 52 (15) -0 .27 (14) -0. 11 (14) C(11) 6. 89 (42) 5.7 8 (36) 4. 93 (32) 0. 76 (31) 2 .52 (29) 1.01 (28) C(12) 9. 73 (54) 6.32 (43) 5. 34 (3 5] -1. 56 (39) 1 .23 (34) -2.07 (32) C(21) 3. 82 (34) 5.88 (41) 13. 62 (7 0] -2. 27 (31) 1 .04 (38) -2. 00 (43) C (22) 6. 14 (38) 3.79 (31) 7. 86 (4 1) -1 . 15 (26) 1 .54 (31) -1. 85 (28) C (31) 4. 18 (33) 7.34 (43) 6. 08 (3 6] 0. 69 (29) 1 .93 (27) 0.14 (31) C (32) 2. 44 (26) 7.20 (40) 7. 31 (4 0) -0. 2 0 (26) -0 .81 (24) -0.78 (32) C (41) 7. 67 (46) 8.00 (48) 4. 62 (3 3] 2. 60 (38) 0 .90 (31) 1.65 (32) C (42) 4. 35 (34) 6.2 2 (41) 7. 42 (4 2) 0. 14 (27) -2 .56 (30) -0.10 (30) (b) Isotropic thermal parameters (U x 100) o Atom fi(A2) All Hydrogens 6.3 RESULTS AND DISCUSSION The co-ordination geometry about the ruthenium atom is essentially octahedral with cis chlorine atoms. Of the four DMSO ligands, three are sulphur-bonded and one is oxygen-bonded, the O-bonded ligand being trans to one of the S- bonded ligands <S(1}). The atom labelling scheme and a general view of the molecule are illustrated in Figure 9. Individual bond lengths and angles, with standard deviations, are given in Tables 15 and 16 respectively. Slight distortion does occur, the angles subtended at the central ruthenium atom between the three mutually cis S-bonded ligands being larger than 90°[92.6-94.9°, mean 94{1)°], while the values for the Cl-Ru-Cl, and the two Cl-Ru-0 angles are slightly less than 90°[87.8-88-7°, mean 88.2(5)°]. Equations of selected least-squares mean-planes with deviations of the atoms from these planes are given in Table 17. This distortion appears to be governed primarily by steric factors associated with the S-bonded DMSO groups. The Ru-Cl bond lengths, 2.435(1) A, are significantly longer than would be expected for a purely ©"-donor ligand. Typical values of mean Ru-Cl bond lengths in octahedral © complexes with trans chlorine atoms are 2. 390 (7) A in RuCl5(NiCvHv(CH1) ) (P(CfcHs)x)a. (CH3)z0 (34) and 2.398 (7) A in RuCl3 (NO) (PMePha.)^ (40). This lengthening is an indication of the strong trans effect of a S-bonded DMSO ligand (33). A general view of the structure showing the crystallographic numbering scheme. 6 1 Table 15 o Bond lengths <A) with standard deviations in parentheses Bond Length (&) Bond Length (&) Ru -Cl(1) 2.435(1) S(1)-C(11) 1.779(8) Ru -Cl(2) 2.435(1) S(1)-C(12) 1.808(6) Eu -S(1) 2. 252(1) S (2)-C (21) 1. 795(7) Eu -S (2) 2. 277(1) S(2)-C(21) 1.783(6) Ru -S(3) 2.276(1) S (3)-C (31) 1.787 (6) Ru -0(4) 2. 142 (3) S (3)-C (32) 1.794(6) S{1)-0 (1) 1.483(5) 0(4)-S(4) 1.557(4) S(2)-0(2) 1.485(5) S(4)-C(41) 1.783(6) S(3)-0{3) 1. 485 (5) S (4) -C (42) 1.793(6) 6 2 Table J6 Bond angles (deg) with standard deviations in parentheses. Bonds Angle Bonds Angle Cl (1) -Bu -Cl (2) 87.78 (5) Bu -S (2) -C(22) 112. 2(2) Cl (1) -Bu -S(1) 88.22 (5) Hu -S(3) -C (31) 109. 6(2) Cl(1) -Bu -S(2) 92.90(5) Bu -S (3) -C (32) 112. 3(2) Cl (1) -Bu -S (3) 173.49 (5) Bu -S(1) -0(1) 120.9(2) Cl{1) -Bu -0(4) 88.2(1) Bu -S{2) -0(2} 117. 7(2) Cl(2) -Bu -S(1) 92.69 (5) Bu -S (3) -0(3} 120. 1(2) Cl <2) -Bu -S(2) 173.85 (5) C (11) -S(1) -C{12) 98.6 (3) Cl{2) -Bu -S{3) 86.38(5) C(21) -S (2) -C(22) 97.5 (3) Cl (2) -Bu -0(4) 88.7 (1) C{31) -S(2) -C {32} 100. 1 (3) S (1) -Bu -S{2) 9 3. 44 (5) C(11) -S{ 1) -0(1) 106. 3(3) S{1) -Bu -S(3) 94.91 (5) C{12) -S{1) -0(1) 106. 0(4) S(1) t-Bu -0 (4) 176.1 (1) C(21) -S (2) -0(2) 107. 7(4) S(2) -Bu -S<3) 92.61 (5) C (22) -S (2) -0(2) 106. 9 (3) S(2) -Bu -0(4) 85.2 (1) C{31) -S (3) -0 (3) 106.3 (3) S(3) -Hu -0 (4) 88. 8(1) C (32) -S{3) -0(3) 106. 4(3) Bu -S(1) -C(11) 112.6(2) BU -0(4) -S (4) 120. 0(2) Su -S(1) -C(12) 110.0 (2) 0(4) -S(4) -C(41) 101 . 6(3) Hu -S (2) -C(21) 112.7 (2) 0(4) -S(4) -C (42) 104. 2(3) C{41) -S (4) -C {42} 99.0 (4) Table V7 Selected Weighted Least-Squares mean planes for RuClj {flea,SO)H. Plane through Ru, Cl (2) , S(1), S (2) , and 0(4) 0.999X + 0.049Y - 0.013Z = 2.249 Atom Ru Cl(2) S<1) S(2) 0(4) Distance (A) -0.042(1) -0. 100(1) -0. 079 (1) 0. 826 (1) 0. 139(4) Plane through Ru, Cl(1), S(1), S (3) , and 0(4) 0.335X + 0.933Y - 0. 129Z = 2.365 Atom Ru Cl(1) S(1) S (3) O (4) Distance (A) 0.013 (1) -0. 102(1) 0.003 (1) -0. 104( 1) 0.075(4) Plane through Ru, Cl (1) , Cl (2) , S (2) , and S(3) -0.043X * 0.024Y - 0.999Z = -3.0537 Atom Ru Cl(1) Cl(2) S(3) S (3) Distance (A) 0. 0009 (3) -0. 166(1) -0.027(1) 0.186 (1) -0.042( 1) In the interaction between the Ru and S atoms, the sulphur atom appears to be behaving as a weak "^-acceptor, as a shortening of the bond between a metal atom and a tf"-donor ligand should be observed if the «"-donor is trans to a strong T-acceptor. For example in £ Ru (N0)C1S ]2~ the equatorial Ru-Cl distances average 2.376(2) A while the chlorine atom trans to © the nitrosyl group is significantly shorter at 2. 357 (1) A <«••). However evidence supporting some TT-acceptor nature can be obtained from the Ru-S distances in the S-bonded DMSO ligands, which are trans to the two chlorine atoms. The mean © value of 2.277(1) A found for the Ru-S bond lengths indicates the presence of some dtr-£TT back donation from the central metal to the sulphur atom, assuming the single bond covalent e radii for ruthenium and sulphur are 1-33 and 1.04 A respectively., (22). However, this back donation is considerably less than that found in [ Ru (NHj)s (Me2SO) ]2* (30), where the Ru-S distance is © 2.188(3) A. The increased back donation found in the mono-sulphoxide is due to the lack of competition for the available tr-donor orbitals from other TT-acceptor ligands in the co-ordination sphere. A comparison of similar bond lengths and angles for [ RUCI3 (MeaS0)3 ]-. (Chapter 3, ref. 29), f Eu (NH3)S (MeaSO) ]2*„ (30)j and free DMSO (35) with those of RuCl 2.(MexS0)4. can be found in Table 18. Examples of the change in co-ordinating atom with the variation of the number of DMSO ligands attached are somewhat limited. In four-co-ordinate palladium complexes steric 65 influences appear to be of most importance (42) . [Pd(Ke^SO^d^] has exclusively sulphur-bonding, [ Pd (MejSO) ^.32+ has both sulphur and oxygen-bonded ligands in a cis configuration. as the size of the ligand increases mixed trans structures are produced, i.e. in the propyl and butyl cationic species, while only oxygen-bonded ligands occur in the iso-pentyl complex [Pd(Pe^SO)^ ]2+. This change in co-ordination is paralleled in these octahedral systems. [ BuClj (HeaSOJ-j j- (Chapter 3) has an all S-bonded cis structure, while the inclusion of another DMSO ligand approaches the [ Pd (-He 2. SO) ^ ]2 + situation, such that steric influences prohibit the formation of an all sulphur-bonded complex, but electronic effects keep the S-bonded ligands in a cis configuration. The decrease in central metal size in going from ruthenium to iron increases the steric interactions considerably, i.e. , [ FeCla (MezS0)a ]+ has a trans configuration in which all the DMSO ligands are oxygen-bonded (43) . The fiu-S bond length for the S-bonded dimethylsulphoxide o ligand trans to the O-bonded sulphoxide is 2.252 (1) .&. This © slight yet significant shortening (compared to 2.277(1) A) is due to the different atoms in the trans positions. The Eu-0 o distance is 2.142(3) A and is similar to the value of o 2.007 (6) A found for Fe-0 (43), considering the difference of o covalent radii of the two metals to be approximately 0.12 A (22). 66 Table J.8 Mean bond lengths and angles for (I) [ RuCla(HexSO)i ]-(II) RuCla(MexS0)% (III) [Ru (NH3)S (MexSO) j2* (IV) Free DMSO A) Bond o Lengths (A) (I) (II) (III) (IV) Ru-S 2.261 (8) 2. 277 (1) 2. 188 (3) -S-0 1.48(2) 1.485 (5) 1.527 (7) 1.471-1.531 S-C 1.79 (3) 1.790 (6) 1. 840(8) 1.80- 1.82 (1) BU-C1 2.43 (1) 2.435 (1 ) - -B) Bond Angles (deg) Bu-S-0 118(1) 119(1) 114.9(3) -Ru-S-C 112 (2) 112(1) 116(1) -O-S-C 106(2) 106.8(6) 104.2 (8) 107 C-S-C 100 (2) 99(1) 99.4(6) 98 67 Figure 10 A stereoscopic diagram of the unit cell viewed down b. There is considerable variation in the sulphur-oxyqen distances for the two types of differently co-ordinated dimethylsulphoxide ligands. In the sulphur-bonded ligands the mean value is 1.484(5) A, while in the oxygen-bonded liqand the distance is 1.557(4) A. This represents a considerable decrease -in the multiple bond character of the sulphur-oxygen linkeage caused iy the differences in co-ordination, though this is still somewhat short of the estimated S-0 single bond o length of 1.70 A (43). The molecular geometry of the r- S-bonded dimethylsulphoxide ligands is very similar to that found in free dimethylsulphoxide (41). The 0-S-C angles (mean value 106.6(6)°), C-S-C angles (mean value 99(1)°), and the S-C 68 bona lengths (mean value 1.79(1) A) compare with 107°, 98° and 1.80-1.82(1) A respectively. The corresponding mean values for the O-bonded ligand are also similar being 103 (1)°, 99.0(4)° and 1.788 (5) A. The other angles in the distorted tetrahedron have mean values of 112(2)° for Ru-S-C, 120(2)° for Ru-S-0 and 120.0(2)° for Bu-O-S. Figure 10 shows a stereoscopic view of the contents of the unit cell viewed down b. The crystal structures of this compound and the trichlorotris (dimethylsulphoxide) complex (Chapter 3) were consistent with the infrared and *H n.m.r. spectral data (29) for these compounds. 5 9 CHAPTER 5 CRYSTAL AND MOLECULAR STRUCTURE OF 1 , 3,7—TRIMETHYL-2,6-DIOXY PURINE HYDROCHLORIDE DIHYDRATE (CAFFEINE HYDROCHLORIDE DIHYDRATE) 70 INTRODUCTION The crystal structure determination of caffeine hydrochloride dihydrate was undertaken primarily to provide the necessary information to complement an ENDOR study on this compound. The renewed interest in this area is due to the discovery that caffeine will inhibit the post-radiation repair of chromosomal aberrations in irradiated DNA (44). EXP ERI MENTAL The white nearly trigonal prismatic crystals were grown by evaporation from a saturated solution of caffeine in hydrochloric acid. The crystal chosen for study (ca 0.4 X 0.3 X 0.2 mm.) was mounted with b parallel to the gbniostat axis. Unit-cell and space group data were obtained from film and diffractometer measurements. The unit-cell parameters were refined by a least-squares treatment of sin28 values for 22 reflections measured on a diffractometer with Cu K* radiation. Crystal Data. C$H„ ClN^O,..2H1>0, M = 266.7, monoclinic, a = 12.391(4), b = 6. 524 (1), c = 17.167(6) A, o P = 118.82(3)°, U= 1215.9(8) A3, Dm= 1.46, De= 1.457 g cm-3, z = 4, F(000) = 560. Space group P2,/c (C^ , No 14) from absent reflections hOl, 1 * 2n and OkO, k * 2n. /*(CuKo( radiation) = 29.19 cm-1. Intensities were measured on a Datex-automated General Electric XRD 6 diffractometer, with a scintillation counter, Cu K ot (nickel filter and pulse height analyser), and a -6-29 scan at 2° min-1 over a range of (1.80 * 0.86 tan 8) degrees 7 1 in 29, with 10 s background counts being measured at each end of the scan. Data were measured to 29 = 140° {minimum interplanar spacing 0.82 ft). A check reflection was monitored every 40 reflections throughout the data collection. The greatest deviation from the initial value was +21.1% and the final intensity was 0.85 times the initial value. Lorentz and polarization corrections were applied, and the structure amplitudes were derived. No absorption correction was applied due to the low value of /* and the fairly uniform shape of the crystal. Of the 2208 independent reflections measured, 451 had intensities less than 3 o-(I) above background where <fz{I) = S + B * (0.05S)2 with S = scan count and B = time averaged background count. These reflections were classified as unobserved and given zero weight in the refinement. STSDCTURE ANALYSIS Although the Patterson synthesis is very useful for compounds with one or a few 'heavy atoms', it is unsuitable for molecules in which many atoms have the same or similar atomic numbers, because no vectors will stand out on the Patterson Fourier map. Fortunately alternate 'direct methods' have been developed which rely on probability relationships between the phases of the 'stronger' reflections. In direct methods, normalized factors HHj are used which are essentially geometrical structure factors only, rather than containing, as does |FB|, the effects of atomic scattering factors and atomic thermal motion. They can be calculated as follows where S is an integer symmetry factor which depends upon the space group extinctions, flauptman and Karle (45) developed probability relationships, based on Sayre's work, which could be used to determine the phases of reflections. Basically, as seen in the eguation one estimate of the phase of H can be obtained from the phase addition of two reflections whose indices when added together give the indices of H. The weight to be given to this indication is equal to the product of the two normalised structure factors |EK1 and |EH |; the best estimate of the phase $M will be the weighted sum of all the indications. Obviously relationships between large J EKJ and |EMMJ*s will dominate the summations due to their weight and should produce a phase value somewhere near that for the whole summation. For a centrosymmetric space group (e.g. P2,/c, this compound) the phases can only be 0 or it, corresponding to the sign of + or -. Sayres equations then become where S means * the sign of, ^ means 'probably equal to*, and the relationship is known as a £-2 (referred to as a Sigma Two) relationship. That is the £-2 relationship for the reflection 4,2,1 is made up of the sum of all the pairs of reflections whose indices add to 4,2,1 e.g. 4,1,0, and 0,1,1; 8,6,4 and -4,-4,-3; 1,1,1 and 3,1,0; etc. 7 3 The probability, P, of the sign S being correct is given for each reflection by P = 0.5 + 0.5tanhl ^^l^il^IJ where ^/°\3'x is a constant dependent on the contents of the unit cell. A computer program developed by Long (46) was used to determine the structure of caffeine hydrochloride using these ideas. The program prepared a list of C""2 relationships between the 297 reflections with JE| > 1.50. Three of the largest IJM's were chosen with indices conforming to the parity rules derived from the space group {for P2,/c the suras of indices of any pair, and the sum of indices of all three could not produce the parity even,even,even) and by assigning positive signs to these reflections the origin was specified. Four more reflections (see Table 19 for the complete list), each having a large |EJ and many ^-2 relationships, were then selected and allowed to take on both + and - signs in turn producing sixteen (24) starting sets of signs. When Sayre's eguation is applied to any starting set, additional signs are determined, which in turn are used to determine more signs, and to redetermine those already predicted. In this case newly determined signs were not used to determine signs of additional reflections until the next cycle. This process is reiterated until there are no new additions or changes to the list. A consistency index 0 is defined as <IIH-«M,c-l«-*l> 0 = <ISMI- SlIJI IH-«1> 7 4 Table _19 Basic starting set of reflections for C1C€NH.02.HU .2H^0 h k 1 |EI 1) -3 1 1 2.70 ^ 2) -7 2 2 3.33 > origin determining 3) -4 1 2 2.42 J 4) 2 5 3 3.08 5) -2 5 11 3,17 6) -7 2 4 2.29 7) -9 3 1 2.82 75 where < > means the average value over all H. The true solution will usually have the highest consistency index, reguire the least number of cycles and converge to a set of signs which are approximately equally distributed between positive and negative. The results of the 16 starting sets are given in Table 20, and set 15 is outstanding in that it converged in 5 cycles with a very high consistency index of 0.92 and had 156 positive and 14 1 negative signs. An E map was computed using the 297 assigned values of E from this set. The positions of the 17 non-hydrogen atoms were indicated from the 17 highest peaks on the map. Two cycles of full-matrix least-squares refinement produced an B factor of 0.129 with isotropic temperature factors, while a further cycle using anisotropic temperature factors lowered the B factor to 0.088. A difference Fourier computed at this stage revealed the positions of the 15 hydrogen atoms. Further refinement with an anomalous scattering correction for the chlorine atom, anisotropic temperature factors for the non-hydrogen atoms, isotropic temperature factors for the hydrogen atoms and an overall extinction coefficient correction produced convergence at B = 0.064 for 1752 reflections with I > 3 cr (I) (5 reflections were given zero weight in the final stages of refinement due to suspected instrumental errors, -1 0 2, 1 2 16, -14 2, 3 6 12, -7 5 4). The atomic scattering factors for Cl, O, N, and C were taken from ref. 14, anomalous scattering correction from ref. 15, and scattering factors for the hydrogen atoms frcm ref. 39. The weighting Table 20 Comparison of the 16 solutions from Long's sign determination program. Set Signs of 7 Number of Number of Number of Consiste reflections cycles pluses minuses index 1 +++++++ 7 267 30 0. 850 2 -*+ + •+ + - 10 142 155 0. 608 3 +++•+-* 10 182 115 0. 685 4 — 7 147 150 0. 684 5 +++*-++ 6 143 154 0.717 6 «•+++—+- 7 140 157 0. 534 7 + —• 9 156 141 0. 598 8 8 142 155 0. 522 9 10 150 147 0.658 10 ++*-+*- 8 148 149 0. 523 11 + + +—#•-* 9 139 158 0. 713 12 +++-*— 7 140 157 0. 510 13 + + +-— + • 12 149 148 0.752 14 + + +—+- 7 150 147 0. 641 15 + + + + 5 156 141 0. 917 16 + + +- 12 144 153 0. 532 77 scheme w = 1/o-2 (F) where o-2 (F) is derived from the previously defined a2 (I) , gave constant average values of w(Fo-Fc) 2 over ranges of |Fo| and was employed in the final stages of refinement. The final positional and thermal parameters appear in Tables 21 and 22 respectively. Measured and calculated structure factors are available from the U.B.C. Library. THERMAL MOTION AND CORRECTION OF MOLECULAR GEOMETRY Tbe ellipsoids of thermal motion for the non-hydrogen atoms (excluding the chloride ion and the water molecules) are shown in Fig. 11. The thermal motion has been analysed in terms of the rigid-body modes of translation (T) , libration (L) , and screw (S) motion (47) using the computer program MGTLS. The r.m.s., standard deviation in the temperature o factors D-tj is 0.0017 A2 indicating that the whole molecule o (r.m.s. AUj^=0.0022 A2) is a reasonable rigid-body and that the thermal motion of the 9-membered fused ring system is remarkably well described by the rigid-body thermal parameters given in Table 23 (r.m.s. AU^= 0.0015 A2). The bond distances in the fused ring system have been corrected for libration (48 and 49) using shape parameters q2 of 0.08 for all the atoms involved. Independent motion corrections based on the &U:: (50 and 51) have been applied to the bond lengths for the non-hydrogen atoms attached to the fused ring system. The corrected and uncorrected bond lengths appear in Table 24. Bond angles, given in Table 25, changed by no more than 0.05°, thus the corrected angles are not reported. Table 21 Final positional parameters (fractional x 10*, Cl x 10s, H 103) with estimated standard deviations in parentheses Atom X I 2 Cl 98388 ( 8) 48847(15) 35370{ 6) 0(11) 6620( [ 2) 2332 ( 4) 1275 { 2) 0(13) 5748 [ 2) 699 2 ( 4} 2885 { 2) 0(1) ' 9101 | [ 3) 7633 { 5) 4695 ( 2) 0(2) » 8592 [ 3) 5884 ( 6) 1420( 2) N(1) 6 241 | [ 2) 4670 ( 4) 2095 { 2) N (3) 7359 [ 2) 1630{ 4) 2740 ( 2) N (7) 7063< t 2) 4033 { 4) 4459 ( 2) N (9) 7905 ( 3) 1232 ( 5) 4306 ( 2) C (2) 6733 [ 3) 2827 ( 5) 19 94 { 2) C(ft) 7381 [ 3) 2219( 5) 3503 { 2) C(5) 685H [ 3) 3971 { 5) 3586 ( 2) C(6) 6228 ( 3) 5376 { 5) 2865 ( 2) C(8) 7693| ( 3) 2 367 ( 5) 4872 { 2} C (10) 5591 ( ft) 5916{ 8) 1279{ 3) C{12) 8067< ( 5) -150 ( 7) 2705 { 3) C (14) 6647 ( ft) 5653 ( 6) 4848( 3) H(1 1) * 937 ( ft) 721 ( 7) 522 ( 3) H (12) • 9 27 ( 5) 692 ( 9) 432{ 4) H (21) * 888 ( ft) 540 ( 8) 19 8 { 3) H{22) « 905 ( 7} 724 (13) 149( 4) H(D 792 { 2) 205 ( 4) 547 ( 2) H (2) 8 32 ( ft) 4 ( 7) 44 2 { 3) H (3) 543 ( ft) 727 ( 8) 149( 3) H (4) 479 ( 6) 520 (10) 87 ( 4) a (5) 610 ( 5) 609 ( 9) 96 { 4) H (6) 806 ( 5) -18( 9) 218 ( 4) H{7) 779 ( 6) -137 ( 12) 282 ( 5) H (8) 885 ( 5) -16 ( 8) 329 ( 4) H (9) 6 96 ( ft) 548 ( 7) 545 ( 3) H(10) 584 ( 5) 584 ( 8) 449 ( 3) H{11) 700 ( ft) 704 ( 8) 473 ( 3) * indicates water molecule Table 22 Final thermal parameters and their estimated standard deviations (a) Anisotropic thermal parameters (tJ ^ x 103, x 10* for Cl A2) ~-Atom 2„ D 2»v 2.1. U 2x* Cl 606 ( 6) 468 ( 6) 479 ( 5) 72 ( 4) 27' I ( 4) 22 ( 0(11) 73 ( 2) 53 ( 2) 43 ( D -1( 1) 35 ( D -5( 1 0(13) 62( 2) 44 ( 2) 56 ( 2) 25( 1) 32 I 1) 11( 1 0(1) • 75 ( 2) 43 ( 2) 56 ( 2) 22 ( 1} 37 ( 2) 10 ( 1 0(2) • 72 ( 2) 63 ( 2) 50 ( 2) -13( 2) 20 ( 2) 2( 1 N(1) 37 ( D 40 ( 2) 36 { 1) 2( 1) 19 ( 1.) 5{ 1 N(3) 39 ( 1) 33 ( 1) 43 ( 2) M D 24 ( 1) -5( 1 N(7) 37 ( 1) 30 ( D 38 ( 1) 1( 1) 21 ( 1) -1( 1 N(9) "0 ( 1) 33 ( 2} 41 ( 2) 3{ 1) 20 ( 1) 3{ 1 C{2) 38( 2) 43 ( 2) 39 { 2) -7( 1) 22 ( 1) -4( 1 C(4) 31 ( 1) 31 ( 2) 39 ( 2) -2{ 1) 18 ( D - 1 ( 1 C(5) 34 ( 2) 27 ( 2) 37 { 2) 0{ 1) 20 ( D 2( 1 C{6) 34 ( 2) 38 ( 2) 42 ( 2) 2( D 21 ( 1) 5( 1 C (8) 38 ( 2) 38 ( 2) 32 ( 2) -1( 1) 14 ( 1) 2( 1 C(10) 64 ( 3) 62 ( 3) 42 ( 2) 16( 2) 24 ( 2) 12 ( 2 C(12) 68 ( 3) 41 ( 2) 65 ( 3) 18 ( 2) 40 ( 2) -2( 2 C(14) 59 ( 2) 42 ( 2} 45 ( 2) 6 ( 2) 32 ( 2) -3( 2 (b) Isotropic thermal parameters (0 x 103) Atom fi(A2) Atom 2(*2) H(11) » 59 (12) H (5) 103 (17) H(12)* 97 (18) H(6) 99(19) H(21) * 74 (14) H(7) 133(27) H (22) « 152(26) H (8) 89 (16) H (1) 17 ( 7) H{9) 69(13) H(2) 60 (13) H (10) 79(15) H(3) 79 (14) H(11) 79(14) H(4) 122 (23) 80 81 Table 23 Rigid-body thermal parameters for the 9-membered fused ring system L(x 10 deg2) J J-8-1 (11) 22{ 9) 58(12) -37 d3h; -6 (11) | 96 (35)Ji Principal axes of L i r.m.s. amplitude i • 3.6° J • 2,6 i ! 2-0 ; Direction 643 389 659 cosines 247 709 660 (X10 3) -725 58 8 36 0 [ Principal axes of T ' • r.m.s. amplitude ] ' 0.19(A) . ; o.i7 ; . 0.17 ! Direction 18 355 935 cosines -82 931 355 (X1Q3) 996 -83 12 o , ; r.m.s. A Uii (A*) • 0.0015 *Axes of reference are orthogonal Angstrom axes. E.s.d.*s of components of L are given in parentheses in units of the last places shown. Table 24 Bond Lengths (A) with standard deviations in parentheses Bond uncorr, corr. Bond uncorr. N{1) -C{2) 1. 396 (4) 1 .400 C{8)- H{1) 0.95(3) C (2) -N (3) 1. 376 (4) 1 .379 N(9) -H (2) 0. 9 2 (5) N (3) -C(4) 1. 351 (4) 1 .354 C(10) -H(3) 1.01 (5) C (4) -C<5) 1. 360 (4) 1 .363 C{10) -H(4) 1.02(7) C(5) -C{6) 1. 431 (5) 1 .434 C{10) -H{5) 1.02 (6) C (6) -N{1) 1. 4 07 (4) 1 .410 C{12) -H{6) 0.89 (6) C (4) -N (9) 1. 369 (4) 1 .372 C{12) -H(7) 0.92(8) N (9) -C{8) 1. 343(4) 1 .346 C{12) -H{8) 1.00 (6) C (8) -M(7) 1. 327 (4) 1 .330 C(14) -H(9) 0.92 (5) N (7] -C(5) 1. 392 (4) 1 .394 C(14) -H (10) 0. 89 (5) M (D -G{10) 1. 477 (5) 1 .477 C(14) -H(11) 1.07 (5) B (3) -C(12) 1. 474 (5) 1 .476 0(1). • -H(11) • 0.84 (4) -C(14) 1. 469 (5) 1 .471 0(1) * -H (12) ' 0.89 (6) C (2) -0(11) 1. 217 (4) 1 .218 0(2) * -H(21) « 0.90 (5) C (6' -0(13) 1. 218 (4) 1 .220 0(2) * -H (22) » 1.03 (8) 8 3 Table 25 Bond angles (deg.) with standard deviations in parentheses a) Angles for the non-hydrogen atoms and H(1) and H(2) Bond Angle Bond Angle N (1) -C (2) -N(3) 117. 2(3) C (2) - N (3) -C(12) 119. 2(3) c (2; -N (3) -C(4) 118. 6(3} C (4) -N (3) -C(12) 121. 9(3) N 13) -C (4] -C(5) 123. 8(3) N (3) -C (4) -N(9) 128.4(3) C(4) -C (5) -C(6) 122. 3(3) N (7) -C (5) -C(6) 131.0(3) C(5) -C (6] -N(1) 111. 0(3) C(5) -C(6) -0(13) 126.7(3) C(6) — N (1] -C(2) 127. 0(3) N{1) -C (6) -0(13) 122. 4(3) c(u; -c (5; -N(7) 106. 8(3) C{6) -N (1) -C(10) 117. 6(3) C (5) -N (7] -C(8) 107. 9(3) C (2) -N(1) -C(10) 115. 3 (3) N (7) -C(8) -N(9) 109. 6(3) C(5) -N (7) -C(14) 125. 8(3) C{8] -H (9) -C(4) 107. 8(3) C (8) -N (7) -C(14) 126. 3(3) N (9j -C(4] -C(5) 107. 9(3} N (7) -C (8) -H{1) 123 (2) N {1) -C{2] -0(11} 120. 7(3) N (9) -C (8) -H(1) 127 (2) N (3) -C (2) -0 (11) 122. 0(3) C (8) -N (9) -H (2) 128 (2) C (4) -N (9) -H (2) 124 (2) b) Angles involving hydrogen atoms not attached directly to the fused ring system Bond Angle Bond Angle N(1)-C(10)-H (3) 105(3) H(6)-C(12)-H(8) 122(5) N ( 1) —C (1 0) — H (4) 108(4) H (7) -C (12) —H (8) 94(5) N(1)-C(10)-H(5) 112(3) N (7)-C (14)-H (9) 112(3) H (3)-C (10)-H (4) 111(4) N (7) -C (1 4) -H (10) 108(3) H(3)-C(10)-H(5) 111(4) N(7)-C (14)-H (11) 105(2} H(4)-C(10)-H(5) 109(5) H(9) -C (14) -H (10) 121(4) N (3) -C (12) —H (6) 110(4) H (9)-C (14)-H (11) 109(4) N(3)-C(12)-H(7) 113(5) H (10)-C (14)-H (1 1) 100(4} N(3)-C(12)-H(8) 106(3) H (11) • -0 ( 1) « - H (12) • 119(4) H(6) -C(12)-fl(7) 111(6) H(21) »-0 (2)'-H(22) » 105(5) RESULTS AND DISCUSSION 1,3,7-Trimethyl-2,6-dioxypurine hydrochloride dihydra te (caffeine hydrochloride dihydrate) contains a caffeine molecule protonated at N{9). The caffeine molecule is hydrogen bonded to only one of the water molecules, by a strong N-H.,,0 hydrogen bond. Both water molecules are, however, hydrogen bonded to the chloride ion (0-H...C1). The atom numbering scheme can be seen in Fig. 11, except for the chloride ion Cl and the water molecules, H (11) »-0 (1) *-H (12) ' and H (21) *-0 (2) »-H (22) *. The effect of protonation on the bond lengths between atoms in the fused ring system is somewhat difficult to determine. The initial structure determination for caffeine (52) has fairly inaccurate bond lengths, and modifications to the structure may have resulted in the N (9) adduct studied by Shefter (53). Even so it can be said that, in terms of bond distances, a direct comparison indicates little significant difference between the protonated and non-protonated species. This might have been expected as Taylor (54) and Kistenmacher and Shigematsu (55) found parallel results for adenine compounds. Fig. 12 does however illustrate one interesting anomaly. An affect of protonation on compound (I) , isocaffeine (56) , would be expected to be a lengthening of the C-N double bond. This is indeed found in (II), methylguanine hydrobromide (59), but this bond is still shorter than the other C-N bonds. Protonation in the caffeine system, i.e. from (III), caffeine:5-chlorosalicylic acid adduct (53), also results in 85 H / Ztf V1.299 (A) C ^1.34 C8 —H || C—H CL /1.376 ^C\K/1-39 \ \ CH3 CH3 (I, (II) CH, CH, . /. x / C-"" \1.343 ^c^\l.327 II \ II \ .C H .C H V H (III) 'IV) Figure 12 Bond lengths and representation of the imidazole ring for (I) Isocaffeine, (II) Methylguanine hydrobromide, (III) Caffeine:S-chlorosalicylic acid adduct, • and (IV) Caffeine hydrochloride dihydrate 86 (a, lengthening of the C-N double bond, but now, as shown in (IV), this study, a shortening of the N(7)-C(8) bond also occurs. , A similar result can be found in another protonated [also at N (9) ] caffeine-like derivative, 7-methylxanthine hydrochloride monohydrate (58) which has a N(7)-C{8) distance of 1.325 A and a C(8)-N(9) distance of 1.338 A. Such findings indicate that the simple pictures drawn in Fig. 12 are inadequate in representing the protonated species, and that considerable electronic rearrangement must be occurring close to the protonated centre. This rearrangement does not seem to transfer to the rest of the molecule judging by the similarity between the remaining corresponding bond lengths in the protonated and non-protonated species. For the angles, significant changes do occur but only in the imidazole ring, a situation parallel to that found by Kistenmacher and Sorrell (58) . Table 26 illustrates the endocyclic imidazole bond angles for several purine derivatives. (Ill) caf eine adduct (53) , (V) theobromine (59) , (VI) 7-methyladenine dihydrochloride (60) , (VII) 7-methylxanthine hydrochloride (58) and (IV) this study. Compounds (III) and (V) are unprotonated, while (IV) , (VI) , and (VII) are protonated at N(9) . The changes in angles found on protonation are quite large, being up to 7.6° [ comparing N (9)-C (4)-C (5) in (IV) and (V) J. Compounds (IV) and (VII) are very similar, as is to be expected since there should be little effect on the imidazole ring due to the different substituents at N(1) and N(3) [hydrogen atoms for (VII) , methyl groups for (IV)] in the pyrimidine ring. 87 Table 26 A comparison of the endocyclic imidazole bond angles for several purine derivatives Atoms Angles (IJI) (V) (VI) (VII) (IV) C(4)-C{5)-N(7) 106.0 106. 1 105.9 106.6 106.8 C(5)-N(7)-C(8) 105.4 105.0 107.3 107.5 107.9 N(7)-C(8)-N(9) 113.6 114. 2 110.7 110.3 109.6 C(8) -N (?) -C{4) 103.4 103.2 108.1 107.5 107.8 N(9) -C(4)-C(5) 111.6 1 15.5 108. 1 108.2 107.9 (III) Caffeine:5-chlorosalicylic acid adduct (V) Theobromine (VI) 7-Hethyladenine dihydrochloride (VII) 7-Methylxanthine hydrochloride (IV) Caffeine hydrochloride dihydrate , this study. 88 The mean planes calculated for caffeine hydrochloride indicate that the protonated caffeine molecule is essentially planar. a plane calculated using all the non-hydrogen atoms in the caffeine molecule, and H{1) and H(2), indicates a © maximum deviation of only 0.19 a £ f or C(12) ]. For the fused ring atoms only, a comparison of the deviations found with their standard deviations shows the six-membered ring to be puckered, and the five-membered ring to be planar within experimental error. Table 27 gives the mean planes and distances'from the atoms to these planes. Caffeine hydrochloride, like several other purine type derivatives (61) e.g. hypoxanthine hydrochloride monohydrate (Table 27), is also bent along the C(4)-C{5) bond, the angle between the imidazole and the pyrimidine ring for caffeine hydrochloride being about 0.85°. The crystal contains two types of hydrogen bonds. 0-H. ..C1 hydrogen bonds occur between the water molecules and the chloride ion, and N-H...0 hydrogen bonds occur between the ring hydrogen H(2) and the water oxygen atom 0(1)'. The hydrogen bond between H(2) and 0(1)' is very strong H...0, I. 76(5} a, N-H.,,0 angle, 176(4)°, and is probably due to the very acidic nature of this proton. The proposition that N-H...0 hydrogen bonding exists between the caffeine molecule and one of the water molecules is further supported by the water H-O-H angles. For water 1, strongly hydrogen bonded, the angle is distorted, being 119(5)°, whereas for water 2 the angle is close to normal, being 105(5)°. Table 28 gives the distances and angles for the postulated intermolecular 89 fable 27 Equations of selected weighted least-squares mean planes with deviations (A) of the atoms from the planes 1) Calculated using N (1) ,8 (3) ,C (2) ,C (4) ,C (5) , and C (6) 0.833X + 0.487Y * 0.264Z = 7.296.* Hypoxanthine Caffeine hydrochloride monohydrate hydrochloride dihydrate N(1) 0.0013 -0. 0148(32) N(3) -0.0006 -0.0145(32C(2) -0.001 1 0.0334(38) C{4) 0.0020 -0.0020 (35) C(5) -0.0017 0.0123 (36) C(6) 0.0001 -0.0015 (38) other atoms N(7) -0.0183 0. 0288 (31) C{8) -0.0297 0.0279 (38) 8(9) -0.0111 0.0051 (33) 2) Calculated using N (7) ,N (9) ,C(4) ,C (5) ,C (8) . 0.825X + 0.493Y • 0.275Z = 7.318 N(7) -0.0010(30) N(9) -0.0013(33) C(4) 0.0006(35) C(5) 0.0004(36) C(8) 0.0020(37) Angle between planes 1) and 2) for the caffeine molecule is o equal to 0.85 o * X,Y, and 2 are orthogonal coordinates in A w.r.t. a,b,c*. 90 Table 28 Distances and angles in the interatomic contacts of the type D-H...A o © © D H A D-H (A) H. ..A (A) D. . .A (A) D-H...A (*) 0(1) • H(11) Cl 0,. 84 (8) 2 .32 (5) 3. 12(1) 162 (4) 0(1} • B{12) Cl 0. 89 (6) 2 .23(6} 3. 12(1} 172 (5) 0(2) ». H(21) Cl 0. 90(5) 2 .37(5) 3. 24(1) 167(4) 0(2)' H (22) Cl 1. 0 3(9) 2 .22 (8) 3. 24(1) 169 (6) N(9) H{2) 0(1) « 0. 92(5} 1 .76(5) 2. 684(4) 176 (4) * indicates water molecules 91 Fiqure 13 A stereoscopic diaqram of the unit-cell viewed down b, showinq the postulated hydroqen bondinq as dashed lines. bonding for this compound. A stereoview of the packing of the molecules in the crystal lattice, and . the postulated intermolecular hydrogen bonding can be seen in Fig. 13. In these-.crystals, unlike many other purine type derivatives, there appears to be no significant stacking of layers of molecules and hence no significant dipole overlap of hetero C-0 and C-N bonds contributing to the stability of the crystal-The crystal structure determination was useful because it allowed for a correlation between the proton and nitroqen hyperfine couplinq tensors, determined from the ENDOR spectroscopy on the X-irradiated crystal, and the molecular structure (62) . 92 CHAPTER 6 CRYSTAL AND MOLECULAR STRUCTURE OF 1-ACETYL-3-BENZAflIDG-2-KET0-4-(2,3,4,6-TETRA-O-ACETYL-£-D-GLUC0PYRAN0SYL0XY)-a3-PYRR0LINE INTRODUCTION From reactions of glycosyl bromide with 2-phenyloxazol-5-one (63) a P-glycoside considered to be 3-benzamido-1-benzoyl-2-keto-4~ (2, 3,4,6-tetr a-O-acetyl-P-D-glucopyranosyl-oxy)-A3-pyrroline was produced. On refluxing with acetic anhydride and sodium acetate in pyridine, one benzoate group was exchanged for an acetate group giving 1-acetyl-3-benzamido-2-keto-4-(2,3,4,6-tetra-0-acetyl-p-D-glucopyranosyloxy)-£3-pyrroline.,The crystal structure was undertaken to verify the initial assignment of structure based upon mass spectrum, n.m.r., and chemical data. EXPERIMENTAL Recrystallization of 1-acetyl-3-benzamido-2-keto-4-(2,3, 4, 6-tetr a- O-acet yl-fi-D-gl ucopyranosyloxy)-^3- pyrroline from hexane-acetone gave colourless rectangular crystals. The crystal chosen for study was mounted with b parallel to the goniostat axis and had dimensions of ca 0.20 X 0.20 X 0.07 mm. Unit-cell and space group data were obtained from film and diffractometer measurements. The unit-cell parameters were refined by a least-squares treatment of sin2© values for 19 reflections measured on a diffractometer with Cu KoC radiation. Crystal Data Ca^,H3©N10ii , M = 590.54 , monoclinic, © a = 19.629(5), b= 7. 504 (2), c = 9.830 (2) A, £= 90.53 (2)°, 0 = 1447.8 (6) A3, Z = 2, Oc = 1.35(1) gem-3, F{000) = 620 © (20°C, Cu K«, A= 1.5418 A, /x= 9.4 cm"1) . Absent reflections OkO, k * 2n define the space group £2^ (C|, No. 4). Intensities were measured on a Datex-automated General Electric XED 6 diffractometer, with a scintillation counter, Cu Kot (nickel filter and pulse height analyser) , and a 9-29 scan at 2° min-1 over a range of (1.80 * 0.86 tan 9) degrees in 29, with 10 s background counts being measured at each end of the scan. Data were measured to 29 = 120° (minimum o interplanar spacing 0.89 A) . A check reflection was monitored every 40 reflections throughout the data collection. The greatest deviation from the initial value was -4.5% and the final intensity was 1.04 times the initial value. Lorentz and polarization corrections were applied, and the structure amplitudes were derived. No absorption correction was applied due to the low value of /*.. Of the 2336 independent reflections measured, 49 8 had intensities less than 3«-(I) above background where o*2 (I) = S + B * (0.05S)2 with S = scan count and B = time averaged background count. These reflections were classified as unobserved and given zero weight in the refinement. STBOCTURE ANALYSIS As previously demonstrated in chapter 5, methods are available for the statistical determination of the phases of the structure factors directly from the structure amplitudes. The basis for these direct methods was discussed in chapter 5 for the centrosymmetric case in which the phases could only have values of 0 or IT (corresponding to • or - signs). When the space group is non-centrosymmetric the phases can have general values and cannot always be added together numerically. Fortunately J. Karle and I. Karle (64) have been 95 able to generalise the procedure already illustrated in the previous structure, to include the acentric structure. The procedure is very similar to that for centric structures; normalised structure factors were calculated and the 37 3 reflections with JEJ > 1.35 were chosen as the basis for the solution. Of these the 70 reflections with the largest JEj's were' searched for ^,-2 relationships and a manual expansion was attempted. The origin in P2( could be defined by the reflections 13 0 -6, 10-9 and 3 11 which were given phases of zero. The manual expansion indicated that if any three reflections cut of a group of six prominent reflections were given symbols then the phases of the majority of the 70 largest reflections could be determined in terms of these assigned symbols. After several unsuccessful runs using all 373 reflections the combination of origin, enantimorph fixing, and symbol reflections given in Table 29 produced satisfactory results. That is the solution involved using the previously mentioned origin reflections, fixing the enantimorph by allowing the phase of reflection 1 4 4 to only vary between 0 and 500 mc, and giving the reflections 5 6-1 and 4 11 various combinations of the phases 0, 250, 500, and 750 mc, leading to sixteen (2*) sets as indicated in Table 30. These sets were used as input to a computer program which determines phases using the tangent formula (given on page 98) of Karle and Hauptman (ref 65 and 66) , as the simple Sayre relationship cannot be used for non-centrosymmetric structures. , 96 Table 29 Basic starting set of reflections for 1-Acetyl-3-benzamido-2-keto-4-(2,3,4,6-tetra-O-acetyl-P-D-glucopyranosyloxy) - &3-pyrroline h k * in phase(mc) 13 0 -6 3. 30 0 ' 1 0 -9 2.85 0 * origin 3 1 1 2.72 0 -1 4 4 2. 49 2 50 5 6 -1 2. 47 a 4 1 1 2.67 b 97 Table 30 Besults for the sixteen starting sets in the phase determining procedure Set a (me) b (mc) t ©* Ek N* 1 0 0 0.52 116 0. 33 328 2 0 250 0.78 226 0.28 349 3 0 500 0.80 227 0.27 348 4 0 750 0.65 166 0.31 343 5 250 0 0.80 224 0.30 344 6 250 250 0.56 121 0.32 340 7 2 50 500 0.65 152 0.32 343 8 250 750 0.55 119 0.32 326 9 500 0 0.79 223 0. 29 345 10 500 250 0.60 141 0.31 336 1 1 500 500 0.59 169 0. 24 358 12 50 0 750 0.56 115 0.37 324 13 750 0 0.64 159 0. 32 339 14 750 250 0.56 125 0.33 333 15 750 50 0 0.72 200 0. 29 343 16 750 750 0.58 1 60 0.24 349 * Total N = 373 98 . § lEKEH.Klsin(^<t>H.K) tan Each reflection is examined in descending order of |E|, and a phase is determined for it from the previously known phases of pairs of ^-2 related reflections. The phases calculated in the first cycle can then be used in the second cycle to give more and better approximations to the correct phases. This process is continued until most of the phases have been determined and there is little change in the values of the calculated phases from cycle to cycle. Before a new phase was accepted various criteria must be satisfied; the consistencies tH and o< of the new phase had to exceed the arbitrary values 0.25 and 4.0 respectively, where J&2 * B2 t„ = ol = JE I.Vfl2 + B2 HJiKI.IIu.Kl If a new phase angle satisfies these criteria, it is used in the determination of the phases of other reflections in the following cycle*:If the phase angle in two successive cycles is different by 250 mc, then the phase is considered to be unknown in the following cycle and therefore cannot be used in the determination of other phases, but it is then recalculated in the next cycle. The final values of t, and the reliability index RKarle (Rk), given by £ | |EH| obs-|EM1 calc | Rk = — I 1 |EM|obs where lEMjcalc are derived from use of the tangent formula, for the sixteen starting sets, are given in Table 30. Both sets 11 and 16 looked promising but the E map was 99 calculated from set 11 as this had the greater number of phases determined (N). The E map based on set 11 gave positions for 36 of the 42 heavy atoms in its top 50 peaks. Fixing the y co-ordinate of atom 0(1) at 0.8300 to define the origin in the space group JP2t , and refining the remaining positional and isotropic thermal parameters for these 3 6 atoms, gave an B factor of 0.230. A difference Fourier revealed the positions of the remaining heavy atoms and two further cycles of full-matrix least-squares refinement with anisotropic thermal parameters for all the non-hydrogen atoms reduced B to 0.090. A difference Fourier at this stage positively revealed the positions of only 17 of the 30 hydrogen atoms. The remaining hydrogen atoms were given calculated positions. Due to the excessive expense and the nature of the problem, the refinement was concluded after two more cycles, varying only the heavy atom positional parameters and anisotropic temperature factors, but including the hydrogen atom positions and isotropic temperature o factors, 0 = 63 X 10~3 Az, in the refinement. The final E value was 0.079 for 1838 reflections with I > 3«-(i) . The atomic scattering factors and anomalous scattering correction for the C, N, and O atoms were taken from ref 14 and ref 15 respectively, and the scattering factors for the hydrogen atoms from ref 39. The weighting scheme: w = 1/o-2(F) where tr2 (F) is derived from the previously defined <r2 (I) gave uniform average values of w(Fo-Fc)2 over ranges of i£oj and was employed in the final stages of refinement. 100 An attempt was made to determine the absolute configuration of the molecule through anomalous scattering of the non-hydrogen atoms. The enantimorph in Table 31, (A), and that generated by changing y to -y, (B), were both refined and Hamilton's test (67) applied to the resulting R factor ratios. Unfortunately neither (A) nor (B) was proved to be significantly more correct. (A) was therefore chosen in view of the chemical evidence. The final positional and thermal parameters appear in Tables 31 and 32 respectively. Measured and calculated structure factors are available from the U.B.C. Library. RESULTS AMD DISCUSSION Fig. 14 shows a general stereoview of 1-acetyl-3-benz-amido-2-keto-4-(2,3,4,6-tetra-O-acety1-P-D-glucopyranosyl-oxy)-&3-pyrroline, with the crystallographic numbering scheme. Complete lists of bond lengths and angles are given in Tables 33 and 34 respectively. As expected the six-membered ring is in tbe chair conformation with equatorial substituents at positions 2, 3, 4, and 5. Table 35 gives a weighted least-squares mean plane for this ring and its molecular geometry is compared with similar compounds, 2,3,4,6- tetra-O-acetyl- l-cyano-p-fi-galactopyranose (68) and tetra-0-acetyl-<*-D-mann6pyranosyl chloride (69) , in Table 36. The average values for the bond lengths [C-C, 1.53(2) ; C-0, o 1.45(2) A], bond angles [112(3)°] and range of torsion angles [ 51.7 (7)-69.8 (7) ° ] are very close to those given by Kim and Jeffrey (70) as typical of other pyranose rings. The 0-acetyl groups attached to C(2), C (3) , C(4), and 10 1 Figure 1 4 (A) A general stereoview of the molecule showing the crystallographic numbering scheme OAc H BzN AcO N—Ac Figure 14(B) Diagram of the conventional chemical structure 102 Table 3J Final positional parameters (fractional x 10*, H x 103) with estimated standard deviations in parentheses Atom X 1 2 0 (1) 2462 ( 3) 830 0 6742 [ 5) 0 (2) 24 38< 3) 8305 (10) 3 798 ( 5) 0 (3) 3746 ( 3) 6996 (11) 2761 I 5) 0 (4) 4063( 3) 3691 (12) 3854 ( 6) 0 (5) 3194 ( 3) 5947 (10) 6654 ( 5} 0 (6) 3368 ( 3) 2618 (11) 7897 ( [ 6) 0 (7) 2739 ( **) 11172 (13) 4098< [ 9) 0 (8) 3049 { 5) 5920 (16) 1173 i [ 7) 0 (9) 5138{ 4) 420 3 (16) 4410 [ 8) 0 (10) 4195( 5) 2094 (28) 9253 (10) 0 (2») 742 ( 3) 8638 (10) 10065 [ 5) 0 (3') 1556 ( 3) 3482 (11) 100671 [ 5) 0 (4») 1241 ( 3) 10214 (10} 5670 j [ 5) » d') 1500 ( 3) 6368 (11) 9479 | [ 6) N (2«) 1378 ( 3) 10750 (11) 7937| [ 6) c (1) 2696 ( 4) 6858 (13) 5925 1 [ 7) c (2) 3000 ( 4) 7716 (12) 4623< [ 7) c (3) 3336 ( *») 6195 (14) 3829 | [ 8) c (4) 3818 ( <0 5135 (13) 4 7061 [ 8) c (5) 3423 ( *») 4384 (14) 5914 ( 8) c (6) 3842 ( 4) 3291 (15) 6881 | [ 8) c (7) 2370( 5) 10137 (16) 3593 [ 9) c (8) 1794 ( 5) 10462 (15) 2640| [ 9) c (9) 3557 { 6) 663 9 (16) 1459 | [ 8) c (10) 4101 ( 6) 7327 (21) 504 | [10) c (11) 4714 ( 5) 3471 (18) 3740 | [ 8) c (12) 4883 ( 6) 2091 (23) 2708( [ 8) c (13) 3622 ( 5) 2117 (19) 9044 i [11) c (14) 3068 { 5) 1436 (20) 9977 JO) c (2') 1204 ( 4) 8038 (13) 93 77 L 7) c (3») 1570 ( **) 8985 (13) 8274 | 7) c (4») 2019 ( <0 7866 (13) 7753 | 7) c (5») 2012 ( 4) 6 118 (13) 8459i 7) c [6«) 1296 ( <*) 492 9 (15) 10268 i [ 7) c (7f) 802 ( 5} 5234 (16) 11396i 8) Ci [8') 1183( 4) 11165 (15) 6638 8) c [9*) 900 ( ") 13067 (13) 6494 1 8) c [10') 1083 ( 5) 14088 (15) 5355 < 8) c (11».) 820 ( 5) 1580 5 (16) 52 14 ( 10) c (12«) 369 ( 5) 16449 (16) 6158 < 11) c (13*) 174 ( 5) 15410 (16) 72 85< 9) c (14») 445( <*) 13764 (14) 74 39 i 9) H (1) 229 615 555 H (2) 341 844 486 H (3) 293 544 324 H (4) 425 590 502 103 Table 31 (continued) Atom X Y Z H(5) 302 357 543 H(6A) 431 326 707 H (6B) * 409 216 633 H(8A) * 164 924 212 H (8B) * 135 1101 316 H(8C) * 195 1142 185 H (10A) 449 780 127 H(10B) * 432 619 -4 H (10C) * 387 820 -24 fl (12A) * 442 127 248 H (12B) 474 217 190 H(12C) 544 172 269 H (14A) 260 111 905 H (1 4B) * 317 2 1025 R (14C) * 306 218 1092 H(5'A) 246 551 858 H(5«B) * 188 503 776 H{7»A) 51 600 1147 H(7'B) 32 537 1074 H (7»C) 105 525 221 H(10*)* 142 1354 459 H (11«) 99 1613 424 H (12') * 16 1782 604 H (13«) -12 1600 826 H(14')* 31 1293 832 H (N2*) 106 1000 795 * calculated positions 104 Table 32 Final thermal parameters and their standard deviations in parentheses Anisotropic thermal parameters (U;\ x 103 A2) Atom In. £* 0 (1) 71 [ 3) 35{ 3) 48 ( 3) 1 I 3) 101 [ 2) -4( 3 0 (2) 71 [ ft) 40 { ft) 43 ( 3) 3 [ 3) -3 ( 2) 1 ( 3 0 (3) 71 ( 4) 68 { ft) 50 ( 3) -3 | 3) 4 [ 3) 1( 3 0 ;ft) 64| [ ft) 77( 5) 67 [ 3) 13 ( ft) 0 ( 3) -14( 4 0 (5) 62 ( 3) 51 { ft) 40 ( 3) 104 [ 3) -2 ( 2) -5( 3 0 [6) 69 [ ft) 68 ( 5) 78 ( ft) -1 [ ft) -11 ( 3) 17 ( 4 0 (7) 123 ( 6) 44 ( ft) 127 ( 6} -211 [ 5) -2 ft ( 5) 14( 5 0 (8) 133| [ 7) 147( 9) 49 [ ft) -8 ( 7) -13 ( ft) -10 { 5 0 (9) 75 ( 5) 145( 9) 109 ( 6) 29 | [ 5) 7 ( 4) - 17( 6 0 (10) 86 [ 6) 414 ( 25) 127 ( 7) -6 ( 9) -10 ( 5) 136( 12 0 (2«) 85 [ ft) 45 ( ft) 54 ( 3) IT j [ 3) 18 [ 3) 3( 3 0 (3«) 85| [ ft) 35 { ft) 62 ( 3) 15 ( 3) 5 ( 3) 6( 3 0 («*•) 106 ( 5) 44 { ft) 43 ( 3) 3j [ 4) -2 ( 3) 3( 3 N (1*) 67| [ ft) 29( ft) 50 ( ft) 12 ( 3) 2 ( 3) 0 ( 3 N (2*) 73 ( ft) 34 ( ft) 49 ( ft) 2| [•• ft) -3 ( 3) 6( 3 C (1) 50 [ ft) 50{ 5) 40 ( 4) 0 ( ft) -5 ( 3) ft( 4 C (2) 45 ( ft) 41 ( 5) 46 ( 4) -9 [ ft) -2 ( 3) 5( 4 c (3) 55 ( 5) 48 | 5) 55 ( ft) -3 [ ft) 6 [ ft) 6( 4 c (4) 54 [ 5) 40 { 5) 55 ( ft) 3 ( ft) 2 ( ft) -9 ( 4 c (5) 56 ( 5) 50 i 5) 55 ( ft) 114 [ ft) 4 ( ft) 1 ( 4 c (6) 55| [ 5) 68 { 7) 71 ( 5) 15 ( 5) 5 ( ft) 12( 5 c (7) 96 ( 7) 45 { °) 52 ( 5) -1\ [ 6) 7, ( 5) 20( 5 c (8) 103 i [ 7) 55 ( 6) 61 ( 5) 15 ( 6) -8 ( 5) 10{ 5 c (9) 87 ( 7) 73 { 8) 45 ( 5) 6 [ 6) -9 ( 5) -8{ 5 c (10) 106 4 ( 8) 125( 11) 64 (•• 6) 26 ( 8) 19 ( 6) 14( 7 c (11) 74 ( 7) 94 | 8) 45 ( 5) 261 [ 7) -5 ( ft) ~ 1 ( 5 c (12) 114 [9) 181 ( 13) 41 ( 5) 69 ( 9) -7 ( 5) -27( 7 c (13) 48 ( 6) 110 { 9) 92 ( 7) 15^ [ 6) -18 ( 5) 24( 7 c (14) 90 [ 7) 109 ( 10) 84 ( 7) 4 ( 7) 0 ( 6) 34( 7 c (2«) 60 ( 5) 42 | 5) 43 (ft) -9 j [ ft) -1 [ ft) - ft( 4 c (3*) 68 t 5} 38 ( 5) 37 ( ft) 15 ( ft) -14 ( ft) 2{ 4 c (4») 54 ( ft) 31 { 5) 48 ( ft) 0 [ ft) 2 ( ft) ft( 4 c (5*) 58j [ 5) 38 ( 5) 48 ( 4) 8 ( ft) 3 ( ft) -5( 4 c (6«) 77 ( 6) 43 | 5) 39 ( 4) Oi [ 5) -5 ( ft) 8( 4 c (7') 971 [ 7) 65( 6) 49 ( 5) 7 ( 6) 14 ( 5) 10{ 5 c (8«) 76 ( 6) 49 | 5) 43 ( 5) -11^ ( 5) -6 (ft) 7( 5 c (9') 61 j i 5) 38 ( 5) 61 ( 5) -5 ( ft) -14 ( ft) 8 ( 4 c (10*) 76 ( 6) 5.5 { 6) 49 ( 4) -9 < [ 5) -14 ( ft) 2( 4 c (11*) 91 ( 7) 48 j 6) 76 ( 6) -2 ( 6) -16 ( 6) 12{ 5 c (12*) 86 ( 7) 42 ( 6) 99 ( 8) 0 ( 5) -36 ( 6) 6( 6 c (13») 76 i [ 6) 55( 7) 74 ( 6) 5 ( 5) -13 ( 5) -1 < 5 c (14*) 60 ( 5) 45 j 6) 66 { 5) 8* [ 5) -4 ( ft) -4* 5 ° z * All H atoms had isotropic thermal parameters U = 63 X 10-3 A 105 Table 33 o Bond lengths (A) »ith standard deviations in parentheses Bond Length (A) Bond Length (A) C{1) -C{2) 1. 55 (1) C (1)- 0(1) 1.43 (1) C (2) -C(3) 1. 54 (1) 0 (1)- C (4* ) 1.37(1) C (3) -cm 1. 50 (1) C (4») -C (5») 1. 48 (1) C (4) -C{5) 1. 53(1) C (5«) - N (1») 1.44 (1) C(5) -0(5) 1. 45 (1) N (T) -C(2») 1.39(1) 0 (5) -C(1) 1. 39 (1) C (2») -C{3') 1. 49 (1) C(5) -C{6) 1. 50(1) c (3«) -C (4» ) 1-32(1) C (2) -0(2) 1. 43 (1) N (1 *) -C (6») 1.39( 1) C(3) -0(3) 1. 46 (1) C (6») -0(3 ») 1.22 (1) c (4) -0(4) 1. 45 (1) c (6«) -C (7« ) 1.50 (1) C (6) -0(6) 1. 46 (1) c (2«) -0{2») 1.22(1} 0(2) -C(7) 1. 40 (1) c (3«) -N{2«) 1.42(1) 0 (3) -C(9) 1. 36 (1) N (2«) -C(8«) 1.37(1) 0 (4) -C(11) 1. 29(1) c (8») -0 (4*) 1. 20(1) 0 (5) -C(13) 1. 29 (1) c (8») -C (9» ) 1.54 (1) C{7) -0(7) 1. 17 (1) c (9») -C (10») 1.41 (1) C(9) -0(8) 1. 17 (1) c (10' )-C(11») 1-39 (1) C(V I) -0(9) 1. .19 (1) c (11' )-C(12») 1.38 (1) C (13)-0 (10) 1. 14 (1) c (12' )-C{13») 1.41(1) C(7) -C(8) 1. 48 (1) c <13« )-C(14«) 1.35 (1) C (9] -C{10) 1. 52 (1) c (14« )-C{9*) 1.40(1) C(1 1)-C(12) 1. 49 (1) c (13) -C (14) 1- 52(1) 106 Table 34 Bond angles (deg.) with standard deviations in parentheses Bonds Angles Bonds Angle C (1) -C (2) -C{3) 106. 3 (6) 0 (1) -C(1) -C{2) 106. 1 ( 6) C{2) -C (3) -C{4) 111.9 (6) 0 (1) -C(1}-0(5) 108.2| 5) C (3) -C (4) -C{5) 108.5 (6) C (1) -0(1)-C (4«) 116.1 | 6) C (4) -C (5) -0 (5) 114. 4 (6) 0 (1) -C(4«)-C(5») 12 4.0 < 7) C(5) -0(5} -C(1) 111.0 (5) 0 (1) -C (4» )-C (3*) 124. 1 I 7) 0(5) -C(1) -C{2) 110. 8 [6) c (4' ) -C{5') -N (1«) 102.7{ 6) C{1) -C(2) -0 (2) 107.2 (5) c (5« )-N(1»)-C{2») 1 1 1.3 ( 6) C(3) -C (2) -0(2) 10 5.9 (6) N (1' ) -C (2» )-C (3») 10 6. 2 < 7) C (2) -C (3) -0 (3) 107. 6 17) c (2« ) -C (3») -C (4«) 10 7.9{ 7) C (4] -C{3) -0 (3) 106. 3 [6) c (3' ) -C (4» )-C (5») 11 1.8 | 6) C(3) -C(4) -0(4) 105.9 [6) c (5« ) -N (1') -C (6'} 1 19. 6( 7) C{5) -C (4) -0 (4) 110.2 (7) c (2» )-N (1 ») -C (6'} 128.3 ( 7) C (4) -C(5) -C (6) 114. 4 (6) N (1» ) -C (6» )-0 (3*) 1 18. 6( 7) 0 (5] -C (5) -C{6) 107. 1 (6) (1* )-C(6«)-C(7») 119.1{ 8) C (5) -C(6) -0(6) 105. 9 [6) 0 (3* ) -C (6*)-C (7») 122. 1 | 8) C (2) -0 (2) -C (7) 117.2 (7) N (1* ) -C (2* )-0 (2«) 127.4 ( 7) C (3) -0 (3) -C (9) 116.7 (7) C (3» ) -C(2») -0{2») 126.4^ 8) C(4) -0(4) -C(11) 118.5 (8) c (2« )-C(3«)-M(2») 119.2 ( 7) c (6; -0 (6) -C(13) 117.2 (7) c (4« ) -C{3*} -N (2«) 132.8{ 8) 0(2] -C(7) -C(8) 108. 9 (8) c (3* ) -N(2,)-C(8«) 120.3{ 7) 0(3] -C{9) -C{10) 109.2 (9) H (2» ) -C (8> )-0 (4») 12 5. 4 ( 9) o (4; -C (1 1 )-C{12) 112(1) N (2» ) -C(8F) -C(9») 1 1 3. 3 ( 8) 0(5] -C(13)-C{14) 110.7 (8) 0 (4« )-C (8«}-C (9«) 121.2) 7) o (2; -C(7) -0(7) 122. 4 [9) C (8» ) -C{9») -C{10») 1 19.0 ( 8) 0(3) -C(9) -0(8) 123.0 (9) c (8» )-C(9*)-C (14») 121.2{ 8) 0 (4] -C(11 )-0(9) 125(1) c (9» ) -C (1 0' )-C (1 1 • ) 1 19.0 ( 9) 0 (6) -C (13)-0 (10) 122(1) c (10 •) -C(11«) -C(12«) 120(1) 0(7) -C{7) -C{8) 128.7 (9) c (11 ')-C (12«)-C (13 «) 121 (1) 0 (8) -C (9) -C(10) 127. 8 [9) c (12 » )-TC (13' )-C(14« ) 119(1) o (9; -C{11 )-C(12) 122.6 (9) c (13*) -C(14»)-C(9») 121.4{ 9) 0 (10) -C{1 3) -C (1 4) 127 (1) c (14,}-C(9»)-C(10') 119. 7( 8) 107 Table 35 Weighted least-sguares mean planes a) Distances (A) of relevant atoms from the planes with standard deviations in parentheses Plane 1: Calculated using 0 (5) ,C (2), C (3) and C{5) Atom 0(5) C{5) Plane 0(2) C(8) Plane 0 (3) C{10) Plane 0(4) C(12) Plane 0(6) C(13) Plane N(1») C{4») 0{2») Plane 0(4') C(9») Plane C(9«) C (12«) C(8«) Distance -0.030{ 0.061 ( (A) 6) 8) A torn C(2) C (1) Distance 0. 050 { 0.700{ 8) 8) 2: 0(2) ,0(7) ,C (7) and 0.001 ( 5) 0 (7) 0.003( 9) C(2) 0(3) ,0(8) ,C(9) and 0.000 ( 8) 0 (8) 0.001(15) C(3) 0 (4) ,0 (9) ,C{11} and -0.002{ 7) 0(9) -0.007 (14) C(4) C(8) 0. 003 ( 8) 0.081( 7) C{10) 0.001(11) -0.205(10) C(12) -0.005(10) 0. 172 ( 9) Atom C(3) C(4) C (7) C{9) C(11) 5: 0(6) ,0 (10) ,C{6) ,C (13) and C(14) 0.005{ 8) 0(10) 0.017(20) C(6) -0.025(14) C(14) 0.004(14} C(5) N{1*),C(2«) ,C(3») ,C{4«) and C(5») •0.014( 6) C(2») 0.022( 8) C{3') 0.002( 8) C{5») 0.011( 8) 0(1) 0.050( 6) N(2») 0.007( 7) C(6») 7: 8: 0(4») ,N{2») ,C(8») 0.003( 7) N(2») 0.004( 8) C(3») and C (9') 0.003{ -0. 178{ 7) 8) Distance (A) -0.060 { 8) -0.740 ( 8) -0.010 ( 9) -0.002 (12) 0.0 18 (11) -0.003 (11) •0.479 (10) •0.013 ( 8) •0.062 ( 4) 0. 128 ( 8) C{8 •) -0.016 ( 9) C(9») ,C(10' ) ,C{11*) -0.004( 8} C (10«) -0.002(11) C(13f) 0-041 ( 9) ,C (12*) ,C(13») and C{14») 0.013( 9) C (11*) -0.011 (11) 0.010(10) C{14«) -0.005 ( 9) b) Dihedral angles between selected planes Plane Plane Angle (deg.) Plane Plane 1 2 118 16 13 83 6 7 14 103  8 15 39 7 8 Angle (deg.) 34 130 9 138 108 Table _35 (continued) c) Equations of planes: IX + mY •* nZ = £ where X, Y and Z are orthogonal angstrom coordinates derived as follows rXi r §. 0 ccos p -j rx-| III = | 0 b 0 | HJ *-Z-* i-OO csin p J *-z-" Plane 1 m n £ 1 0.924 0.365 0.115 8.086 2 -0.624 0.063 0.779 0.335 3 -0.466 0.883 -0.052 1.076 4 -0.048 -0.719 0.694 0.258 5 -0.091 0.923 0.374 4.122 6 0.681 0.340 0.649 9.603 7 0.920 0.354 -0. 166 3.979 8 0.761 0.379 0.526 8.375 109 Table 36 Comparison of structural data for the pyranose ring Distance Bond I *>. II III C(1)-C{2) 1.55(1) 1.528(7) 1 .529 (9) C (2)-C(3) 1.54(1) 1.50 0(7) 1 .56(1) C(3)-C(4) 1.50 (1) 1.523(6) 1 .476 (9) C(4)-C(5) 1.53 (1) 1.503 (7) 1 .524 (9) C{5)-0(5) 1. 45 (1) 1.441 (6) 1 . 443 (9) 0(5) -C(1) 1.39(1) 1.413 (5) 1 .366 (9) Angle (deg.) Bond I II III ** «fc 0{5)-C(1) -C(2) 110. 8 (6) 108.9(3) 1 16(1) C(1)-C(2) -C{3) 106.3(6) 1 10. 9 (4) 109(1) C(2)-C<3) -C{4) 111.9 (6) 112. 2 (4) 110(1) C(3)-C(4) -C{5) 10 8.5 (6) 109.4(4) 111(1) C(4)-C{5) -0(5) 114. 4 (6) 110.9 (4) 109( 1) C(5)-0<5) -C(1) 111.0 (5) 111.0(4) 117(1) Torsion Angles (deg.) Bond I II III C(1)-C(2) -C{3) -C{4) -51.7(7) -50.5 49 C(2)-C{3) -C{4) -C{5) 58.3(8) 49. 3 57 C(3)-C(4) -C(5) -0(5) -63.0(7) -55.3 57 C(4)-C{5) -0(5) -C(1) 69.8(7) 65.0 53 C(5) -0(5) -C(1) -C(2) -68.0(7) -64. 1 49 0{5)-C{1) -C(2) -C(3) 55.6 (7) 56. 8 45 I 1-Acetyl-3-benzamido-2-keto-4-(2,3,4,6-tetra-0 -acetyl-p-D-glycopyranosyloxy) -&3-pyrr oline. II 2,3,4,6-Tetra-O-acetyl-l-cyano-p-D-galactopyranose. ~ III Tetra-0-acetyl-*-p-mannopyranosyl chloride 110 C{6) are planar {fable 35). The average values for the bond lengths [Cring-0, 1.45(2); 0-C, 1.33(2); OO, 1.17(2); and C-e Cmethyl, 1.50(2) A] and angles [Cring-O-C, 117(1); Q-C*0 , 123(1); O-C-Cmethyl, 110(1); and 0*C-Cmethyl, 127(2)°] are close to the values expected for such groups. It should also be mentioned that the terminal atoms on these O-acetyl groups exhibit extensive thermal motion (see Table 32), in particular atom 0(10)., This is somewhat expected due to the length of these chains, and the lack of very strong inter- or intramolecular bonding which might help to constrain these atoms. The mean plane calculated for the 5-membered pyrroline ring (linked to the pyranose ring by a p-oxygen bridge) shows it to be planar within experimental error (Table 35). Other studies on pyrroline rings (71 and 72) found mean values for H (1 •)-C (2 •) , N(1')-C(5«), and C^'J-O^') of o 1.343 (5), 1.456 (8) and 1.2 30 (3) A respectively. The corresponding values for this compound are 1.39(1), 1.44(1) and 1.22(1) A. Any shortening in the first two distances is probably due to the acetyl substituent on N(1'). The values for the C(2«)-C{3*), C(4*)-C{5»), and C(3»)-C(4') bond o distances of 1.48 (1), 1.49 (1) and 1.32(1) A are very similar to those found by Boeyens and Kruger (73) [1.52, 1.52, and 1.31 A], The range of intra-annular angles for the pyrroline ring is from 102.7 to 111.8°. Weighted least-squares mean planes calculated for the benzamido group, the acetyl group attached to N(1*), and the benzene ring show them to be planar (Table 35). Again the ISMe 37 A) Intermolecular C-H...0 interactions (distances in A angles in deg.) D-H...A H. ..A D. ..A D-H. ..A C{7«)-H(7»B) ...0<2«) i 2.57(1) 3.53 (1) 142(1) C(8)-H(8C) ...0(3»)2 2.46(1) 3.42 (1) 146 (1) C (5)-H (5)...0(7)3 2.29(1) 3.28 (1) 148(1) C(10)-H(10A) ...0(10) * 2.68(1) 3.36 (1) 117 (1) B) Intramolecular 0...H contacts 0(2*)-0(2*) . 0(3»). 0(4») . 0{4»). 0(7)., 0(8).. 0(9) ., 0(10) . . , H (N2*) ..H(7'A) . . H(14A) ,.H (8B) ..H (10») ?H(2) .H{3) -H(4) . . H (6 A) 2.41 (1) 2. 46 (1) 2.91 (1) 2.55 (1) 2.47 (1) 2.55(1) 2.08 (1) 2.25 (1) 2.33 (1) -x, -1/2*y, 1-z x, 1 + y# -1 +z x, -1+y, z 1-x, 1/2+y, 1-z 112 Figure 15 A stereoscopic diagram of the unit-cell viewed down b bond lengths and angles are as expected for these groups. In the crystal there are extensive numbers of close H. ..0 intra- and intermolecular contacts which are summarized in Table 37. Of particular note is the significantly longer H(2)..-0(7) contact compared to the other axial hydrogen, acetyl oxygen contacts. This difference is probably due to steric constraints induced by a postulated intermolecular hydrogen bond between 0(7) and H(5). A stereoview of the packing of the molecules in the crystal lattice can be seen in Fig. 15. The crystal structure determination for this compound indicated that the structure suggested by the mass spectrum, n.m.r., and other chemical data was in fact correct. 113 SOMMA BY 1 1 n The aim of this research has been to determine the structures of the five molecules previously described. The structure determinations themselves involved the utilization of the three major methods currently available in X-ray crystallography for overcoming the phase problem and thereby deducing the crystal and molecular structure. For any compound the choice of the most suitable method for structure determination is essentially determined by the nature of the compound itself. Patterson methods, described in Chapter 2, involve a process in which it is essential that the molecule contain one or more 'heavy' atoms. The tungsten and the two ruthenium compounds (Chapters 2, 3, and 4) with their heavy metal atoms were therefore ideal for this method. If, however, a molecule contains only atoms which have the same or similar atomic numbers, e.g. most organic molecules, the Patterson synthesis is unsuitable. Although it may be possible to produce heavy atom derivatives of these molecules and hence use the Patterson method, alternate 'direct methods* have fortunately been developed which make it possible to determine the structures directly. The structure of the caffeine and pyrroline derivatives described in Chapters 5 and 6 were determined by use of these direct methods. The actual method used depends upon the space group of the compound. The caffeine structure was therefore determined by centrosymmetric direct methods (it crystallized in the centrosymmetric space group P2,/c) while the structure of the pyrroline compound was solved by non-centrosymmetric direct methods (it crystallized in the non-centrosymmetric 115 space group P2|). Although the five compounds sere essentially unrelated; and any meaningful correlation in terms of bonding, intermolecular interactions, etc., was impossible, the results for the individual molecules were both interesting and useful. The analysis of the seven-coordinate tungsten compound (Chapter 2) showed it to have a distorted capped octahedral geometry. The tungsten-iodine distances of 2.848(2) and o 2.856(2) A appeared to be the first determinations of 1-1 bond lengths in a seven-coordinate environment. The two ruthenium compounds had very similar octahedral structures. The tris complex (Chapter 3) had all three DMSO ligands sulphur-bonded in a cis configuration. In the tetrakis compound (Chapter 4) the extra ligand replaced one of the chlorine atoms but was coordinated through the oxygen atom. It is thought that steric influences prohibit the formation of an all sulphur-bonded complex, but electronic effects keep the S-bonded ligands in the cis configuration. Caffeine hydrochloride dihydrate (Chapter 5) contained a planar caffeine molecule protonated at N (9) . Of particular interest was the effect of protonation on the bond lengths between atoms in the fused ring system. It is believed that considerable rearrangement must be occuring close to the protonated centre, but that this rearrangement does not seem to be transferred to the rest of the molecule. The molecular geometry in the pyrroline compound (Chapter 6) was very similar to that found for other related 116 compounds. This compound did, however, exhibit extensive numbers of close C-H..,0 intra- and intermolecular contacts. Some degree of hydrogen bonding was also shown by another two of the compounds studied. The ruthenium anions in Chapter 3 were linked in a chain like structure throughout the lattice to the dimethylammonium cations via N-H...0 and N-H...C1 hydrogen bonds, while the caffeine crystals contained 0-H...C1 and N-H...0 hydrogen bonds. 117 Eef erences I. 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A.. „Rosenthal and A.J. Brink. J. Carbhydrates. Nucleosides. Nucleotides, 19 75, 2(4S5), 343. 64. J.,Karle and I.L. Karle. Acta Crist., 1966, 21, 849. 65. J.,Karle and a. Hauptman. Acta Cryst., 1956, 9, 635. 66. M.G.B. Drew, D.H. Templeton, and A. Zalkin. Acta Cryst., 1969, B25, 261; M.G.B. Drew. private communication.*' 67. 8.C. Hamilton, Acta Cr^st., 1965, 18, 502. 68. C. ,Foces-foces, F.H. Cano, and S. Garcia-blanco. Acta Cryst., 1976, B32, 964. 69. P. Herpin, R. Famery, J. Auge, S. David, and L. Guibe. Acta Cryst., 1976, B32, 209. ____ _ n n <• 70. S.H. Kim and G.A. Jeffrey. Acta Cryst., 1967, 22, 537. 71. L. Fanfani, A. Nunzi, P.F. Zanazzi, and A.R. Zanzari. Acta Cryst., 1974, B30, 127. 72. L. Dupont, 0. Dideberg, and A. Welter. Acta Cryst., 1975, B31, 1018. 0\ *. * 73. J.C.A. Boeyens and G.J. Kruger. Acta Cryst., 1970, B26, 668. James Trotter Additional data THE STRUCTURE DETERMINATION OF THREE INORGANIC AND TWO ORGANIC COMPOUNDS Bl X-RAY DIFFRACTION• By ANTHONY MERCER. B.Sc, University of Bristol, England, 1972. A THESIS SUBMITTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS POR THE DEGREE OF DOCTOR OF PHILOSOPHY in the department of CHEMISTBY. He accept this thesis as conforming to the reguired standard. THE ONIVERSITY OF BRITISH COLUMBIA JUNE 1977. @ Anthony Mercer, 1977 (2,3-Bis(dimethylarsino)-1,1,1,4,4,4-hexafluorobut-2-ene-As,As)tricarbonyl-diiodotungsten(II) j-Anthony Mercer and James Trotter Observed and calculated structure factor amplitudes (reflections with intensity < 3a(I) are marked with an asterisk). H K L FO FC H K L FO FC 0 0 2 83. 31 50.20 4 0 12 55.09 49. 16 0 0 4 252. 25 209.28 . 5 0 -14 56.04 57.08 0 0 6 22.58* 5.70 5 0 -12 29.03 25.80 0 0 8 16.39* 10.12 5 ' 0 -10 154.55 152.81 0 0 10 23.99 24.91 5 0 -8 47.16 50.26 0 0 12 186.74 179.12 5 0 -6 265.36 224.45 0 0 14 25.29* 27.56 5 0 0 0.00* 12.07 1 0 -14 34.70 40.04 5 0 2 248.26 272.36 1 0 -12 118.35 113.40 5 0 4 14.93* 13.86 1 0 -10 130.59 137.38 5 0 6 93.35 94.57 1 0 -8 46.69 52.02 5 0 8 125.78 116.24 1 0 -6 188.65 189.89 5 0 10 55.72 46.89 1 0 -4 91.47 86. 3 2 5 0 12 10.82* 23.48 1 0 2 287.92 229. 15 6 0 -14 50.92 48.43 1 0 4 16.05 10.96 6 0 -12 24.35* 19.60 1 0 8 56. 22 55.28 6 0 -10 112.57 112.05 1 0 10 158.41 156.61 6 0 -8 5.71* 13.09 1 0 12 95. 10 96.58 6 0 -6 30.70 31.27 1 0 14 20.24* 15.08 6 0 -2 17.01* 17.49 2 0 -14 183.92 182.45 6 0 0 413. 13 388.03 2 0 -12 42.07 45.19 6 0 2 149.64 161. 14 2 0 -10 41.61 45.01 6 0 4 95.40 86.08 2 0 -8 36.41 39.37 6 0 6 12.74* 4.23 2 0 -6 31.74 34.02 6 0 8 174.00 176.67 2 0 0 244. 11 249.09 6 0 10 27.74* 34.88 2 0 2 33.09 40.46 6 0 12 36.11 22.93 2 0 6 68.05 67. 13 7 0 -14 50.81 54.71 2 0 8 41.20 42.63 7 0 -12 15.62* 19.52 2 u 10 219.83 209.24 7 0 -10 25.7*4 2 1. 72 2 0 12 81.56 83.18 7 0 -8 81.67 79.39 2 0 14 22.47* 7.08 7 . 0 -6 257.23 226.89 3 0 -14 25. 17 18.29 7 0 -4 19.71* 9.6 1 3 0 -12 72.46 69.94 7 0 -2 128.63 119.22 3 0 -10 122.45 130.59 7 0 0 138.46 126. 18 3 0 -8 368.61 317.23 7 0 2 404.91 392.64 3 0 -4 38.02 22.62 7 0 4 11.99* 1.64 3 0 -2 108.28 103.01 7 0 6 211.37 196.32 3 0 0 46.31* 75.08 7 0 8 57.47 53.07 3 0 2 186.19 201.41 7 0 10 18.97* 8.38 3 0 4 275.08 238.99 8 0 -14 108.19 110.64 3 0 6 89. 80 85.67 8 0 -12 55.52 55.81 3 0 8 21.21* 27.37 8 0 -10 86.02 84.01 3 0 10 117.85 113.78 8 0 -8 176.99 171.76 3 0 12 84.81 80.70 8 0 -6 126.82 129.94 3 0 14 66. 17 71.10 8 0 -4 39.83 40.33 4 0 -14 151.54 157.32 8 0 -2 17.84* 19.90 4 0 -12 50.08 53.08 8 0 0 395.37 382.12 4 0 -10 239.08 234.94 8 ' 0 2 0.00* 7.03 4 0 -8 230.99 223.48 8 0 4 61.64 66.46 4 0 -6 90.77 94.54 8 0 6 41.87 46.63 4 0 -4 326.81 312.41 8 0 8 " -86.44 77.77 4 0 -2 367.98 311.76 8 0 10 32.86 31.28 4 0 0 115. 12 146.76 9 0 -14 19.08* 13.80 4 0 2 335. 17 315.37 9 0 -12 152.58 154.91 4 0 4 96.34 79.59 9 0 -10 204.41 201.03 4 0 6 140.24 147.29 9 0 -8 151.98 142.45 4 0 8 82.78 82.45 9 0 -6 65.23 49.23 4 0 10 161.64 162.37 9 0 -4 67.73 59. 12 H K L FO FC H 9 0 -2 86.22 92.11 15 9 0 0 163.55 153.83 15 9 0 2 13.03* 13.68 15 9 0 4 18.43* 15.97 15 9 0 6 145. 10 154.32 15 9 0 8 30.00* 28.05 15 10 0 -14 141.62 142.81 15 10 0 -12 60. 94 59.03 0 10 0 -10 48.09 45.77 0 10 0 -8 145. 17 139.78 0 10 0 -6 205.83 186.70 0 10 0 -4 259.76 243.68 0 10 0 -2 215.31 203.77 0 10 0 0 16.68* 21.11 0 10 0 2 60.92 65.39 0 10 0 4 84.76 74.07 0 10 0 6 77.87 66.42 0 10 0 8 13.44* 1.30 0 11 0 -14 0. 00* 8.52 0 11 0 -12 24.20* 22.97 0 11 0 -10 89.24 88.74 0 11 0 -8 197.83 192.37 0 11 0 -6 222.89 213.49 11 0 -4 104.56 110.40 11 0 -2 133.31 131.31 11 0 0 31.70* 43.80 11 0 2 62.53 60.69 11 0 4 116.72 106.46 11 0 6 39. 01 39.31 12 0 -14 35.09 29.77 12 0 -12 17.89* 6.97 12 0 -10 49.62 48.79 12 0 -8 114.59 113.39 12 0 -6 32.01 24.94 12 0 -4 162.50 166.4 6 12 0 -2 156.34 167.87 12 0 0 103.67 103.78 12 0 2 56.96 54.01 12 0 4 103.87 89.19 12 0 6 60. 17 46.35 13 0 -14 14.71* 8.22 13 0 -12 73.70 73.09 13 0 -10 35.62 33.73 13 0 -8 25.21* 24.53 13 0 -6 65.47 63. 17 13 0 -4 108.94 103.64 13 0 -2 150.63 147.27 13 0 0 0.00* 6.61 13 0 2 136.59 124.02 13 0 4 0.00* 2.27 14 0 --12 31.91 28.26 14 0 --10 60.71 52. 18 14 0 -8 37.97 37.73 14 0 -6 48.44 48. 15 14 0 -4 135.36 133.00 14 0 -2 3.36* 7.22 14 0 0 80.99 70.52 14 0 2 39.23 32.87 K L FO FC 0 -12 81.72 80.94 0 -10 44.66 36.78 0 -8 105.68 101.18 0 -6 20.60* 3.89 0 -4 42.94 50.58 0 -2 24.88* 13.52 0 0 22.55* 6.07 1 236.54 192. 10 2 242.78 204.34 3 188.28 164.27 4 144.52 137.36 5 161,72 148.28 6 372.87 311.87 7 . 150.98 146.34 8 129.68 121.6 1 9 87.28 87.73 10 44.37 40.68 11 36.05 30.62 12 0.00* 9.32 13 88. 58 82.66 14 0.00* 5.03 15 45.88 45.80 -15 14.58* 18.41 -14 44.74 44.03 -13 62.13 60.79 -12 38.71 38.84 -11 51.06 51.07 -10 24.39 25.46 -9 93.29 8 8.28 -8 0.00* 9.4 1 -7 219.26 194.37 -6 133.23 122.01 -5 66.74 72.61 -4 34.22 34.40 -3 84.86 89.89 -2 53.87 54.47 -1 187.36 160.05 0 451.01 475.80 1 266.44 256. 1 1 2 38.71 29.31 3 8.28* 5.07 5 375.95 324.34 6 172.78 166.94 7 129.58 127.62 8 15.44* 16.24 9 73.42 74.71 10 52.30 43.33 11 79.65 80.63 12 104.59 103.81 13 12.03* 9.74 14 14.65* 7.22 15 12.03* 18.37 15 83.46 82.54 14 30.63 30.37 . -13 65.68 64.70 — 12 98.96 99. 10 — 11 137.62 134.20 — 10 104.78 103.35 H K L FO 2 _! -9 90.04 2 -1 -8 110.14 2 -1 -7 67.20 . 2 -1 -6 183.82 2 -1 -5 41.85 2 -1 -4 135. 14 2 -1 -3 57.34 2 -1 -2 353.49 2 -1 -1 210.03 2 -1 0 98.22 2 -1 1 37. 84 2 -1 2 251.86 2 -1 3 190.32 2 -1 4 151.20 2 -1 5 39.73 2 -1 6 110.81 2 -1 7 162.50 2 -i 8 40.46 2 -1 9 31.11 2 -1 10 164.57 2 -1 11 154.36 2 -1 12 111.26 2 -1 13 38.90 2 -1 14 28.45 3 -1 -15 26.30* 3 -1 -14 165.14 3 -1 -13 102.52 3 -1 -12 83. 03 3 -i -11 34.85 3 - r -10 21.58 3 -1 -9 254.95 3 -1 -8 97.87 3 -1 -7 95.05 3 -1 -6 50. 80 3 -1 -5 101.19 3 -1 -4 147.50 3 -1 -3 43.94 3 -1 -2 276.93 3 -1 -1 73.99 3 -1 0 56. 14 3 -1 1 75. 34 3 -1 2 170.07 3 -1 3 122.39 3 -1 4 265.66 3 -1 5 190.06 3 -1 6 52.72 3 -1 7 39.49 3 -1 8 122.70 3 -i 9 173.80 3 -1 10 163.94 3 - -j 11 32.98 3 -1 12 19.79* 3 -1 13 34.62 3 -1 14 32.71 4 -1 -15 73. 13 4 -1 -14 52. 29 4 -1 -13 41.95 4 -1 -12 25.75 FC H 86.60 4 98.08 4 73.06 4 181.65 4 41.05 4 127.51 4 59.03 4 303.61 4 175.93 4 90.87 4 40.94 4 234.57 4 164.00 4 143.23 4 27.12 4 112. 15 4 161.03 4 40.38 4 32.92 4 152.67 4 145.81 4 112.17 4 39.94 4 25.03 4 23.16 4 160.40 5 104.43 5 81.35 5 31.31 5 22.82 5 235.06 5 101.33 5 93.16 5 41.18 5 95. 81 5 142.24 5 50.62 5 244.42 5 79.51 5 74.83 5 74.36 5 163.85 5 131.31 5 243.20 5 183.19 5 57.58 5 39.71 5 119.34 5 168.77 5 161.85 5 27.26 5 10.95 5 36.08 5 29.24 6 73.55 6 56.87 6 36.93 6 23.80 6 L FO FC -11 165.78 165.43 -10 54. 30 51.60 -9 62.28 59.43 -8 140. 16 133.37 -7 168.15 166.82 -6 261.08 227.45 -5 43.23 29.60 -4 297.31 263.10 -3 216.60 181.25 -2 380.37 335.74 -1 12.50* 21.43 0 138.25 145.48 1 79.45 87.38 2 48. 42 54.85 3 69.71 75.24 4 55. 65 67.39 5 38. 18 34.47 6 50. 46 49.00 7 93.39 92.47 8 65. 12 63.82 9 70.54 66.28 10 13.21* 9.92 11 97.78 92.17 12 0.00* 5. 10 13 0.00* 3.25 -15 24. 63 16.30 -14 25.22 27.44 -13 22.23* 23.43 -12 o ~> r\ ft i. . V H 19. 14 -11 81.04 79.31 -10 195.27 190.29 -9 272.89 247.94 -8 158.27 155.44 -7 42. 84 45.88 -6 36.09 38.46 -5 264.25 230.90 -3 40. 44 33.21 -2 62.68 48.83 -1 102.54 102.56 0 79.09 81.76 1 173.80 186.28 2 267.75 276.07 3 201.31 195.41 4 121.30 114.79 5 21.95* 23.97 6 85.32 81.91 7 97.03 93.51 8 30.26 30.47 9 86.76 83.97 10 19.37* 7.80 11 21. 12* 11.35 12 46.62 40.26 13 33.70 30.47 -15 20.14* 19.37 -14 20.79* 19.42 -13 84.85 84. 12 -12 48.62 53.56 -11 85.34 89.29 H K L FO 6 _-| -10 85. 31 6 -1 -9 59.77 6 -1 -8 46.45 6 -1 -7 97. 18 6 -1 -6 161.78 6 -1 -5 41.82 6 -1 -4 139.06 6 -1 -3 149.97 6 -1 -2 224.96 6 -1 -1 125.84 6 -1 0 136.54 6 -1 1 202.59 6 -1 2 228.54 6 -1 3 111.49 6 -1 4 81.66 6 -1 5 75. 13 6 -1 6 0.00* 6 -1 7 48.56 6 -1 8 11.95* 6 -1 9 81. 26 6 -1 10 18.00* 6 -1 11 27.35* 6 -1 12 32.41 7 -1 -15 35. 10 7 -1 -14 56. 15 7 -1 -13 73.75 7 -1 -12 30.00 7 -1 -11 116.51 7 -1 -10 21.76* 7 -1 -9 17.16* 7 -1 -8 167.21 7 -1 -7 95.03 7 -1 -6 75. 88 7 -1 -5 184.21 7 -1 -4 219.75 7 -1 -3 33. 11 7 -1 -2 11.43* 7 -1 -1 33. 1 1 7 -1 0 301.70 7 -1 1 225.94 7 -1 2 24.86* 7 -1 3 71.68 7 -1 4 0.02* 7 -1 5 122.85 7 -1 6 11.69* 7 -1 7 139. 19 7 -1 8 119.27 7 -1 9 12.21* 7 -1 10 41.57 7 -1 11 29.52 8 -1 -15 99.52 8 -1 -14 43.74 8 -1 -13 87. 83 8 -1 -12 66.67 8 -1 -11 70.51 8 -1 -10 116.92 8 -1 -9 52. 56 8 -1 -8 42.07 FC H 88.38 8 60.25 8 48. 13 8 100.09 8 154.18 8 40.73 8 129.98 8 141.10 8 232.04 8 127.43 8 138.88 8 217.90 8 259.24 8 116.39 8 94.97 8 70.04 8 19.15 8 45.59 8 12.68 9 81.25 9 7.52 9 25.45 9 28.68 9 37.91 9 52.47 9 72.72 9 32.09 9 117.42 9 19.15 9 13. 14 9 158.54 9 96.01 9 87.30 9 173.21 9 214.60 9 35.59 9 6.09 9 28.95 9 31 1.99 9 227.71 9 3.52 9 68.40 9 12.48 9 122.71 10 17.23 10 130.78 10 115.88 10 10.85 10 40.32 10 20.42 10 96.18 10 40.20 10 85.77 10 68.76 10 72.53 10 120.52 10 54.28 10 29.31 10 L FC FC -7 24. 54 14.05 -6 80.75 70.90 -5 52.38 49.44 -4 123.38 113.72 -3 17.94* 9.34 -2 63.29 62.54 -1 113.95 119.37 0 48. 89 51.01 1 61.90 62.89 2 123.54 108.71 3 93.66 91.88 4 34.96 52.77 5 51.83 55.48 6 168.21 168.09 7 1 12.30 115.48 8 69. 42 70.63 9 38.25 37.18 10 14.68* 22.79 15 11.29* 7.31 14 84.01 86.05 13 109.73 115.26 12 14.88* 8.69 11 56.24 60.97 10 57.90 58.90 -9 151.00 150.33 -8 72.00 74.50 -7 133.50 128.09 -6 170.48 158.04 -5 26.04 3 1.18 -4 160.20 165.80 -3 46. 25 48.01 -2 32.36 31.34 -1 64.48 69.14 0 130.04 128.88 1 78.74 77.29 2 63.48 57.40 3 48.44 38.47 4 104.02 96.58 5 160.54 155.58 6 69.72 72.23 7 46. 26 44.75 8 0.00* 5.19 9 37.09 38.89 15 84.75 82.02 14 28.89 22.58 13 38.07 39.08 12 85.26 89.56 11 115.02 117.51 10 112.55 112.93 -9 13.54* 21.32 -8 127.98 123.60 -7 140.42 137.48 -6 182.42 173.37 -5 25.26* 20.95 -4 30.40 33.31 -3 117.02 114.18 -2 17.35* 5.08 -1 45.98 44.75 H K L FO FC H K L FO FC 10 0 88.54 84.68 13 -V -10 18.29* 23. 14 10 -1 1 66.56 67. 13 13 -1 -9 68.75 65.93 10 -1 2 32.01 20.35 13 -1 -8 30.27* 29. 18 10 -1 3 27.93* 33.26 13 -7 13.48* 14.55 10 - 1 4 32.82* 31. 19 13 - 1 -6 0.00* 7.67 10 -1 5 31.07* 33.07 13 - 1 -5 59.13 58.71 10 -1 6 0.00* 1.60 13 - 1 -4 111.44 110.59 10 -1 7 52.06 47.72 13 - 1 -3 25.96* 24. 10 10 -1 8 26.30* 16.91 13 -1 -2 50.22 41.82 11 -1 -15 11.72* 21.63 13 - 1 -1 31.93 25.76 11 -1 -1" 72.28 75.26 13 -1 0 35.30 42.65 11 -1 -13 66.28 70.25 13 - 1 1 85. 87 86.22 11 -1 -12 29.09* 37.72 13 - 1 2 70.85 66.09 11 -1 -11 30.48* 33.44 13 - 1 3 92. 86 91.00 11 -1 -10 21.73* 35.65 13 - 1 4 64.87 64.98 11 -1 -9 158.29 158.65 14 - 1 -13 61.14 58.30 11 -1 -8 93.88 91.16 14 - 1 -12 48. 30 43.85 11 -1 -7 43.55 45.24 14 - 1 -11 16.00* 10.33 11 -1 -6 40.34 38.95 14 - 1 -10 17.18* 3.76 11 -1 -5 72. 1 1 70.73 14 - 1 -9 36.97 28.93 11 -1 -4 137.29 133.54 14 - 1 -8 67.40 63.75 11 -1 -3 41.28 26.53 14 - 1 -7 32.44* 31.33 11 -1 -2 150. 10 159.90 14 - 1 -6 0.00* 8.72 11 -1 -1 95.79 103.10 14 - 1 -5 49.33 49.91 11 -1 0 104.09 101.94 14 - 1 -4 15.08* 17.73 11 -1 1 79.07 77.27 14 -1 -3 39.06 30.17 11 -1 2 36.07 25. 14 14 - 1 -2 34.83 30.99 11 -1 3 115.40 114.93 14 - 1 -1 51.54 51.31 11 — i 4 0.00* 14.30 14 - 1 0 40. 83 32. 12 11 -1 5 53. 13 50.67 14 - 1 1 59.00 44.31 11 - 1 6 31.97* 20.34 14 - 1 2 92.12 88.23 11 - 1 7 21.85* 10.75 15 - 1 -12 25.12* 15.42 12 - 1 -15 14.09* 25.62 15 - 1 -11 57.36 61.50 12 - 1 -14 0.00* 4.12 15 - 1 -10 77.03 71.80 12 - 1 -13 32.33 31.52 15 - 1 -9 49. 15 43.90 12 - 1 -12 30.68 25.21 15 - 1 -8 77. 52 73.03 12 -1 -11 50. 28 49.38 15 - 1 -7 23.54* 28.26 12 - i -10 0.00* 9.76 15 - 1 -6 42. 50 44.03 12 -1 -9 0.00* 4.16 15 - 1 -5 21.80* 8.26 12 -1 -8 76.49 73.69 15 - 1 -4 17.90* 25.66 12 -1 -7 68.53 73.44 15 -1 -3 15.09* 10.30 12 -1 -6 96.89 99.04 15 -1 -2 33. 33 17.32 12 - 1 -5 51.89 56.25 15 - 1 -1 42.04 28.36 12 - 1 -4 94. 35 99. 17 15 - 1 0 44.81 43. 11 12 -1 -3 120.25 123.70 0 -2 0 76.85 96.57 12 - 1 -2 152.26 158.96 0 -2 1 317. 16 258.97 12 - 1 -1 49. 40 52.24 0 -2 2 274.32 229.66 12 -1 0 25.31* 12.37 0 -2 3 41.47 29. 19 12 -1 1 70.27 72.25 0 -2 4 42.83 35.48 12 - 1 2 48.24 39.92 0 -2 6 31.67 34.52 12 -1 3 24.19* 26.24 0 -2 7 248.81 224.42 12 -1 4 41.32 36.73 0 -2 8 41.84 48.31 12 -1 5 44.09 47.97 0 -2 9 19.02* 11.73 12 -1 6 39.78 32.06 0 -2 10 29.79 31.97 13 -1 -14 26.14* 31.79 0 -2 11 110.51 105.78 13 - 1 -13 32.07 31.30 0 -2 12 17.09* 2.63 13 - 1 -12 4 3.12 39.60 0 -2 13 16.38* 18.56 13 -1 -11 58. 68 64.84 0 -2 14 67.88 68.04 H K L FO FC 0 -r2 15 13.64* 13.64 1 -2 -15 85.10 85.53 1 -2 -14 0.00* 2.53 1 -2 -13 89.94 89.83 1 -2 -12 20.55* 22.25 1 -2-11 98.33 101.64 1 -2 -10 80.71 80.04 1 -2 -9 64.89 58.66 1 -2 -8 200.23 198.35 1 -2 -7 88.77 80.55 1 -2 -6 38.41 41.69 1 -2 -5 158.27 142.45 1 -2 -4 92.10 98.90 1 -2 -3 185.03 165.98 1 -2 -2 92.35 94.75 1 -2 -1 367.83 307.57 1-2 0 41.30* 50.99 1 -2 1 131.57 122.06 1 -2 2 33.34 38.59 1-2 3 323.04 288.39 1 -2 4 174.89 179.60 1 -2 5 122.19 123.32 1 -2 6 16.95* 19.88 1 -2 7 309.91 277.26 1-2 8 52.20 48.01 1 -2 9 94.27 87.37 1 -2 10 9.98* 9.80 1 -2 11 141.39 140.65 1 -2 12 72.66 76.89 1 -2 13 45.91 51.55 1 -2 14 44.74 46.43 1.-2 15 27.04 18.34 2 -2 -15 21.49* 19.43 2 -2 -14 8.39* 6.67 2 -2 -13 129.60 131.51 2 -2 -12 79.65 83.65 2 -2 -11 4.37* 12.80 2 -2 -10 102.29 106.79 2 -2 -9 205.12 196.69 2-2-8 16.68* 1.14 2 -2 -7 224.40 214.33 2 -2 -6 13.69* 25.40 , 2 -2 -5 5.65* 4.59 2 -2 -4 77.04 76.19 2 -2 -3 66.25 57.42 2 -2 -2 163.64 156.27 2 -2 -1 128.20 122.72 2-2 0 165.49 206.49 2 -2 1 104.37 108.80 2-2 2 293.23 280.32 2-2 3 31.46 29.89 2 -2 4 106.23 101.78 2-2 6 64.19 63.77 2 -2 7 78.53 78.47 2-2 8 0.00* 3.62 2-2 9 207.51 198.91 2 -2 10 12.80* 1.55 2 -2 11 52.38 52.58 fl K L FO FC 2 -2 12 58.80 59.46 2 -2 13 24.06* 29.46 2 -2 14 24.51* 15.87 3 -2 -15 91.49 96.90 3 -2 -14 8.83* 7.13 3 -2 -13 15.41* 21. 38 3 -2 -12 11.73* 7.26 3 -2 -11 191.74 191.54 3 -2 -10 68.63 67.03 3 -2 -9 100.97 101.21 3 -2 -8 37.76 36.66 3 -2 -7 213.99 197.26 3 -2 -6 167.19 160.77 3 -2 -5 20.99 23.49 3 -2 -4 197.24 170.90 3 -2 -3 134.45 122.49 3 -2 -2 46.56 51.18 3 -2 -1 37.90 29.51 3 -2 0 91.34 95. 19 3 -2 1 80. 10 94.66 3 -2 2 126.68 142.29 3 -2 3 158.43 154.99 3 -2 4 8.21* 14.49 3 -2 5 84. 28 80.93 3 -2 6 78. 35 78.26 3 -2 7 158.77 155.41 3 -2 8 76.44 77.04 3 -2 9 0.00* 3. 17 3 -2 10 8.70* 8.29 3 -2 .11 156.59 156.08 3 -2 12 7.81* 1.86 3 -2 13 31.11 33.94 3 -2 14 28.84* 25.74 4 -2-15 19.51* 11.58 4 -2 -14 22.42* 24.82 4 -2 -13 102.41 105.86 4 -2-12 17.98* 23.07 4 -2 -11 54.78 56.99 4 -2 -10 44.00 37.75 4 -2 -9 379.25 356.75 4-2 -8 127.80 128.06 4 -2 -7 20.69 13.22 4 -2 -6 99.77 103.34 4 -2 -5 232.80 207.13 4 -2 -4 28.42* 54.28 4 -2 -3 56.46 53.18 4-2 -2 54.64 63.34 4 -2 -1 17.06* 18.53 4-2 0 0.00* 26.50 * 4 -2 1 123.35 151.41 4 -2 2 61.93 73.13 4-2 3 219.20 221.50 4 -2 4 64.17 59.68 4-2 5 74.64 70.83 4-2 6 133.94 136.81 4-2 7 30.57 24.82 4-2 8 112.96 108.96 4 -2 9 203.09 191.68 H K L FO FC 4 -2 10 26.41 15.37 4 -2 11 27.76 25.80 4 -2 12 20.07* 2.28 4 -2 13 61.01 55.48 5 -2 -15 31.89 39.44 5 -2 -14 0.00* 2.73 5 -2 -13 67.85 69.49 5 -2 -12 26.65 28.58 5 -2 -11 174.98 175.95 5 -2 -10 23.67 26.83 5 -2 -9 11.48* 5.73 5 -2 -8 21.57 14.28 5 -2 -7 236.01 220.44 5 -2 -6 91.36 82.36 5 -2 -5 50. 17 51.67 5 -2 -4 85. 54 73.53 5 -2 -3 416.29 387.36 5 -2 -2 164. 19 172.93 5 -2 -1 143.13 144.41 5 -2 0 90.44 99.39 5 -2 1 143.51 146.14 5 -2 2 26.52 22.07 5 -2 3 85.09 96.77 5 -2 4 154.02 163.21 5 -2 5 71.78 73.05 5 -2 6 97.53 93.05 5 -2 7 27.84 30.05 5 -2 8 23.06* 7.57 5 -2 9 110.92 105.37 5 -2 10 36. 14 38.98 5 -2 1 1 69.78 71.67 5 -2 12 34.64 31.83 6 -2 -15 33.41 41.58 6 -2 -14 6.25* 2. 83 6 -2 -13 52.72 53.94 6 -2 -12 91.51 91.75 6 -2 -11 110.02 109.74 6 -2 -10 35.93 38.35 6 -2 -9 177.84 173.08 6 -2 -8 30.76 37.39 6 -2 -7 32.74 19.53 6 -2 -6 125.42 123.68 6 -2 -5 392.85 341.93 6 -2 -4 71.56 71.90 6 -2 -3 92.03 81.00 6 -2 -2 105.44 96. 17 6 -2 -1 63.54 62.96 6 -2 0 39.54 40.01 6 -2 1 229.92 225.61 6 — 2 2 24.13* 15.77 6 -2 3 175.95 193.79 6 -2 4 24. 14* 17.47 6 -2 5 124.64 129.63 6 -2 6 0.00* 16.02 6 -2 7 187.09 180.35 6 -2 8 32.27 31.40 6 -2 9 13.40* 14.23 6 -2 10 87.25 81.56 H K L FO FC 6 -2 11 0.00* 5.84 6 -2 12 41.45 41.47 7 -2 -15 97.35 96.02 7 -2 -14 58.61 56.74 7 -2 -13 83.65 84.04 7 -2 -12 71.73 72.86 7 -2 -11 14.52* 17.26 7 -2 -10 33. 12 31.78 7 -2 -9 58.14 59.47 7 -2 -8 49.35 46.75 7 -2 -7 72.39 61.12 7 -2 -6 15.75* 17.45 7 -2 -5 107.89 103.73 7 -2 -4 62.96 54.58 7 -2 -3 96.06 100.52 7 -2 -2 69.36 74.42 7 -2 -1 98.20 100.55 7 -2 0 158.92 162.31 7 -2 1 204.38 208.82 7 -2 2 49.03 42.04 7 -2 3 156.17 161.20 7 -2 4 15.21* 6.73 7 -2 5 82.69 87.61 7 -2 6 19.32* 5.81 7 -2 7 149. 17 149.25 7 -2 8 79.06 75. 18 7 -2 9 57.79 60.89 7 -2 10 39.78 38.75 7 -2 11 8.99* 9.25 8 -2 - 15 19.64* 19.86 8 -2 -14 37.60 41.90 8 -2 -13 128.66 134.95 8 -2 -12 0.00* 4.42 8 -2 -11 121.20 127.04 8 -2 -10 27.54 24. 38 8 -2 -9 106.50 104.06 8 -2 -8 53.07 52.39 8 -2 -7 116.37 107.33 8 -2 -6 90.82 80. 16 8 -2 -5 103.58 93.63 8 -2 -4 80.98 77.85 8 -2 -3 49.20 43.51 8 -2 -2 159.56 155.90 8 -2 -1 32.92 35.30 8 -2 0 39.57 43. 10 8 -2 1 181.33 183.86 8 -2 2 43.54 43.82 8 -2 3 34.26 34.40 8 -2 4 18.32* 16.66 8 -2 5 196.06 204.21 8 -2 6 27.91* 21.12 8 -2 7 98. 19 99.60 8 -2 8 23.77* 26.57 8 -2 9 47.19 43.80 8 -2 10 16.96* 21.76 9 -2 -15 120.19 119.86 9 -2 -14 26.15* 27.93 9 -2 -13 87.59 89.56 H K L FO FC 9 -2 -12 22.18* 21.98 9 -2 -11 161.26 167.93 9 -2 -10 69.88 70.10 9 -2 -9 35.21 31.96 9 -2 -8 80. 18 81.40 9 -2 -7 104.32 100.51 9 -2 -6 80. 16 75.93 9 -2 -5 20.35* 19.93 9 -2 -4 49.66 41.46 9 -2 -3 84. 18 85.46 9 -2 -2 21.24* 16.98 9 -2 -1 97. 29 95.06 9 -2 0 17.20* 8.57 9 -2 1 15.89* 9. 17 9 -2 2 46. 20 47.92 9 -2 3 68.44 66.95 9 -2 4 109. 12 116.41 9 -2 5 0.00* 25.61 9 -2 6 13.84* 4.68 9 -2 7 120.86 117.66 9 -2 8 8.33* 5.55 9 -2 9 37.26 31.04 10 -2 -15 14.25* 7.68 10 -2 -14 15.46* 11.17 10 -2 -13 131.03 135.25 10 -2 -12 22.48* 23.32 10 -2 -11 0.00* 10.36 10 -2 -10 0.00* 17.18 10 -2 -9 204.26 203. 15 10 -2 -8 18.92* 25.01 10 -2 -7 112.65 107.20 10 -2 -6 46.57 44.65 .10 -2 -5 115.42 106.42 10 -2 -4 47. 43 33.35 10 -2 -3 55.56 63.67 10 -2 -2 50.46 54.57 10 -2 -1 112.10 125.28 10 -2 0 85.83 83.10 10 -2 1 35.51 30.56 10 -2 2 88.43 88.2 8 10 -2 3 82.95 71.40 10 -2 4 55.60 50.35 10 -2 5 123.66 128.00 10 -2 6 30.04* 3.72 10 -2 7 28.10* 7.46 10 -2 8 0.00* 5.66 11 -2 -15 57.77 53.68 11 -2 -14 35.81 32.73 11 -2 -13 24.02* 5.62 11 -2 -12 9.30* 19.42 11 -2 -11 114.96 114.51 11 -2 -10 66.37 69.66 11 -2 -9 40.38 40. 1 1 11 -2 -8 34.16 33.52 11 -2 -7 165.56 165.51 11 -2 -6 75.72 76.87 11 -2 -5 78. 31 68.59 11 -2 -4 28.65* 23.90 fi K L FO FC 11 -2 -3 161.60 161.55 11 -2 -2 36.70 25. 10 11 -2 -1 51.48 52.69 11 -2 0 28.49* 29.83 11 -2 1 83.96 82.69 11 -2 2 42.28 44.98 11 -2 3 18.32* 7.22 11 -2 4 14.39* 12.84 11 -2 5 77. 36 74.6 1 11 -2 6 40.78 35.51 11 -2 7 0.00* 14.99 12 -2 -15 35. 54 34.25 12 -2 -14 5. 11* 10.72 12 -2 -13 14.77* 19.74 12 -2 -12 41.07 42.59 12 -2 -11 42.94 45.18 12 -2 -10 44. 32 39. 18 12 -2 -9 144.09 146.76 12 -2 -8 16.46* 12.84 12 -2 -7 23.99* 22. 19 12 -2 -6 10.89* 5.33 12 -2 -5 85.73 87.73 12 -2 -4 60.83 56.51 12 -2 -3 31.92* 38. 13 12 -2 -2 21.68* 18. 38 12 -2 -1 92.92 100.35 12 -2 0 0.00* 10. 30 12 -2 1 97.64 97.0 1 12 -2 2 11.54* 4.60 12 -2 3 136.84 139.80 12 -2 4 41.99 31.51 12 -2 5 18. 53* 13.68 13 -2 -14 10.05* 5.55 13 -2 - 13 59.73 59.4 1 13 -2 -12 23.29* 23.62 13 -2 -11 10.19* 16.96 13 -2 -10 53.24 51.00 13 -2 -9 19.06* 16.81 13 -2 -8 0.00* 6.4 1 13 -2 -7 31.28 28.64 13 -2 -6 52.02 52.64 13 -2 -5 27.89* 30.08 13 -2 -4 48.66 43.85 13 -2 -3 90. 12 104.80 13 -2 -2 38.67 33.89 13 -2 -1 66.57 71.07 13 -2 0 0.00* 11.14 13 -2 1 87.67 84.31 13 -2 2 O.OC* 8.44 13 -2 3 63.90 63.71 13 -2 4 26.00* 22.76 14 -2 -13 82.31 81.67 14 -2 -12 36.08 37.96 14 -2 -11 74.87 74.50 14 -2 -10 0.00* 12.22 14 -2 -9 0.00* 1.58 14 -2 -8 23.56* 29.48 14 -2 -7 20.42* 12.96 H K L FO FC 14 -2 -6 56.48 53. 15 14 -2 -5 28.27* 32.67 14 -2 -4 16.82* 3.24 14 -2 -3 23.03* 31.73 14 -2 -2 0. 00* 3.71 14 -2 -1 0.00* 4.06 14 -2 0 14.97* 28.02 14 -2 1 85. 13 88. 19 14 -2 2 24.78* 20.86 15 -2 -11 49.00 54.50 15 -2 -10 0.00* 11.93 15 -2 -9 33.94 28.96 15 -2 -8 25.69* 13.12 15 -2 -7 69.79 63.65 15 -2 -6 31.64* 29.63 15 -2 -5 39.95 35.82 15 -2 -4 18.20* 6.54 15 -2 -3 37.49 33.69 15 -2 -2 33.50 30.40 15 -2 -1 29.68* 31.94 15 -2 0 59.41 51.95 0 -3 1 99.71 99.94 0 -3 2 335.62 306. 17 0 -3 3 197.85 171.71 0 -3 4 26.84 20.23 0 -3 5 103.79 100.85 0 -3 6 122.60 126.62 0 -3 7 221.62 217.05 0 -3 8 176.37 165.5.0 0 -3 9 17.62* 19.02 0 -3 10 77.07 74.80 0 -3 1 1 18.46* 15.27 0 -3 12 24.59* 31.13 0 -3 13 10.36* 7.61 0 -3 14 45.62 54.4 5 0 -3 15 45.79 43.08 1 -3 -15 19.13* 21.48 1 -3 -14 123.22 122.35 1 -3 -13 48.69 49.22 1 -3 -12 67.92 68. 10 1 -3 -11 19.02* 10.15 1 -3 -10 70.81 73.73 1 -3 -9 4.51* 3.26 1 -3 -8 13.92* 11.53 1 -3 -7 94. 13 90.25 1 -3 -6 10.25* 11.90 1 -3 -5 75.60 73.54 1 -3 -4 169.39 162.69 1 -3 -3 82.44 87.51 1 -3 -2 311.86 280.99 1 -3 -1 237.59 212.00 1 -3 0 205.64 229.00 1 -3 1 170.72 160.30 1 -3 2 36.28 45.92 1 -3 3 98.93 100.19 1 -3 4 82.41 91.14 1 -3 5 308.56 279.61 1 -3 6 66.71 66.68 H K L FO FC 1 -3 7 20. 19* 15.41 1 -3 8 123.66 130.58 1 -3 9 99.26 91.36 1 -3 10 95.67 98.85 1 -3 11 4 1.15 41.17 1 -3 12 104.32 103.18 1 -3 13 14.02* 5.36 1 -3 14 38.41 42.47 2 -3 -15 34. 87 32.91 2 -3 -14 0.00* 10.27 2 -3 -13 14.54* 13.21 2 -3 -12 34. 52 32.69 2 -3 -11 131.56 135.30 2 -3 -10 4 3.74 39.72 2 -3 -9 21.51 17.32 2 -3 -8 149.73 148.27 2 -3 -7 58.52 55.75 2 -3 -6 98.67 86.03 2 -3 -5 84.94 88.94 2 -3 -4 295.52 269.39 2 -3 -3 225. 1 1 205.70 2 -3 -2 80.61 74.81 2 -3 -1 26.98 18.25 2 -3 0 98.47 95.40 2 -3 1 17.12* 5.25 2 -3 2 114.76 97.69 2 -3 3 101.56 97.94 2 -3 4 171.71 166.69 2 -3 5 .0.00* 4..2 2 2 -3 . 6 189.02 186.83 2 -3 7 133.52 138.99 2 -3 8 87.27 83.40 2 -3 9 65.95 63.89 2 -3 10 18.27* 18.69 2 -3 11 109.67 108. 12 2 -3 12 24.19* 13.45 2 -3 13 14.61* 2.43 2 -3 14 47.39 46.26 3 -3 -15 32.75 23.49 3 -3 -14 55.08 61.51 3 -3 -13 106.10 110.43 3 -3 -12 27.99 23.20 3 -3 -11 39.35 34.64 3 -3 -10 115.10 115. 13 3 -3 -9 151.76 150. 13 3 -3 -8 22.29 23.31 3 -3 -7 20.28 18.04 3 -3 -6 125.19 140. 16 3 -3 -5 23.16 15.58 3 -3 -4 223.74 203.20 3 -3 -3 39.16 33.41 3 -3 -2 223.05 206.21 3 -3 -1 17.67* 3.71 3 -3 0 206.92 226.72 3 -3 1 84.28 109.00 3 -3 2 189.97 206.64 3 -3 3 56.51 56.55 3 -3 4 110.23 117.76 H K L FO FC 3 -3 5 90.78 90.38 3 -3 6 73.52 75.24 3 -3 7 49. 17 51.91 3 -3 8 57.03 68.92 3 -3 9 168.00 161.98 3 -3 10 98.80 94.40 3 -3 11 4.06* 5.59 3 -3 12 90.21 93.04 3 -3 13 15.38* 24.87 4 -3 -15 41.96 39.52 4 -3 -14 13.53* 5.74 4 -3 -13 21.71* 25. 18 4 -3 -12 50.53 51. 13 4 -3 -11 92.58 96.61 4 -3 -10 143.64 148.88 4 -3 -9 54.87 57.82 4 -3 -8 87. 12 84.81 4 -3 -7 239.03 237. 17 4 -3 -6 129.68 119.67 4 -3 -5 27.59 26.57 4 -3 -4 165.46 160.44 4 -3 -3 99.31 100.34 4 -3 -2 31.30 39.95 4 -3 -1 191.84 206. 10 4 -3 0 149.74 175.24 4 -3 1 38.21 38.54 4 -3 2 145.74 148.79 4 -3 3 0.00* 16.53 4 -3 .4 137.91 142.71 4 -3 5 17.99* 15. 14 4 -3 6 33.80 40.44 4 -3 7 77.63 76.02 4 -3 8 81.62 83.94 4 -3 9 13.90* 17.66 4 -3 10 68.03 67.65 4 -3 11 39.36 40.32 4 -3 12 71.44 73.30 4 -3 13 33. 1 1 30.38 5 -3 -15 9.05* 2.89 5 -3 -14 33.90 32.3 1 5 -3 -13 10.82* 4.91 5 -3 -12 114. 17 117.17 5 -3 -11 21.34* 24.89 5 -3 -10 0.00* 3.65 5 -3 -9 209.61 205.70 5 -3 -8 12.81* 12.94 5 -3 -7 20.09* 4.55 5 -3 -6 29.91 25.90 5 -3 -5 174.67 166.22 5 -3 -4 253.89 233.31 5 -3 -3 38.88 34.05 5 -3 -2 222.55 206.00 5 -3 -1 19.55* 21.05 5 -3 0 162.89 181.22 5 -3 1 91.99 100.88 5 -3 2 118.08 127. 17 5 -3 3 110.04 119.64 5 -3 4 87.53 95.83 H K L FO FC 5 -3 5 80.25 72.64 5 -3 6 40.20 38.50 5 -3 7 36.79 30.35 5 -3 8 81.39 76.78 5 -3 9 33.32 25.83 5 -3 10 98. 13 101.60 5 -3 11 28.94* 31.62 5 -3 12 43.24 43.00 6 -3 -15 22.31* 33.42 6 -3 -14 38.62 43.29 6 -3 -13 7.06* 6.65 6 -3 -12 74.48 79.06 6 -3 -11 56.74 59.72 6 -3 -10 47.80 50. 15 6 -3 -9 40.45 4 0.70 6 -3 -8 16.52* 11.89 6 -3 -7 128.56 130.14 6 -3 -6 275.96 267.67 6 -3 -5 37.36 40.82 6 -3 -4 40.80 36.35 6 -3 -3 135.52 127.97 6 -3 -2 129.12 141.06 6 -3 -1 70.96 69.58 6 -3 0 56. 62 67.24 6 -3 1 142.68 141.09 6 -3 2 73.27 82.98 6 -3 3 187.86 210.20 6 -3 4 102.92 108.09 6 -3 5 2 7-. 9 6 29. 5 1 6 -3 6 138.92 142.43 6 -3 7 35.31 32.92 6 -3 8 64. 21 57.59 6 -3 9 4.70* 16.51 6 -3 10 33.06 26.98 6 -3 11 22.91* 22.02 7 -3 -15 12.21* 18.50 7 -3 -14 72.40 75.84 7 -3 -13 65.56 68.01 7 -3 -12 64.22 66.09 7 -3 -11 30.10 27.47 7 -3 -10 12.92* 10.94 7 -3 -9 6.32* 2.29 7 -3 -8 58.49 55.92 7 -3 -7 51.99 55.75 7 -3 -6 210.19 196.30 7 -3 -5 183.33 181.59 7 -3 -4 137.07 137.86 7 -3 -3 32.82 34.96 7 -3 -2 73.66 66.54 7 -3 -1 81.36 92.35 7 -3 0 182. 19 195.99 7 -3 1 128.20 136.95 7 -3 2 132.29 137.97 7 -3 3 19.30* 35.25 7 -3 4 80.25 92.36 7 -3 5 79.07 83.87 7 -3 6 70.44 67.93 7 -3 7 90.00 89.08 H K L FO FC 7 -3 8 45.31 45.45 7 -3 9 46.67 43.84 7 -3 10 15.34* 1 1.07 8 -3 -15 78.60 81.48 8 -3 -14 8.88* 11.61 8 -3 -13 20.74* 20.82 8 -3 -12 63.73 70.69 8 -3 -11 75.68 85.08 8 -3 -10 27.87 24.48 8 -3 -9 18.34* 8.87 8 -3 -8 194.60 200.24 8 -3 -7 36. 26 41.16 8 -3 -6 71.51 67.44 8 -3 -5 0.02* 12. 36 8 -3 -4 43.76 43.65 8 -3 -3 39.98 39.63 8 -3 -2 111.51 118.34 8 -3 -1 22.67* 23.93 8 -3 0 65.80 73.31 8 -3 1 27.51* 29.96 8 -3 2 107.89 106.42 8 -3 3 67.00 66.59 8 -3 4 109.76 116.21 8 -3 5 93. 10 96.57 8 -3 6 60.77 58.44 8 -3 7 98.58 106.02 8 -3 8 20. 19* 22. 18 8 -3 9 17.80* 14.76 8 -.3 1.0 46.77 .51.61 9 -3 -15 18.87* 4. 15 9 -3 -14 91.74 93.72 9 -3 -13 78.48 87. 13 9 -3 -12 15.84* 6.24 9 -3 -11 30.89 35.78 9 -3 -10 48.94 49.91 9 -3 -9 93.63 99.25 9 -3 -8 82.74 81.91 9 -3 -7 36.51 37.34 9 -3 -6 88.89 89.58 9 -3 -5 61.84 58.37 9 -3 -4 34.42 29.73 9 -3 -3 100.87 111.73 9 -3 -2 212.82 226.53 9 -3 -1 36.75 38.31 9 -3 0 113.20 114.07 9 -3 1 0.00* 5.17 9 -3 2 34.20 32.95 9 -3 3 30.62* 22.05 9 -3 4 19.31* 13.62 9 -3 5 90.63 102.02 9 -3 6 33.79* 31.90 9 -3 7 6.59* 13.96 9 -3 8 51.44 52.71 9 -3 9 13.71* 27.03 10 -3 -15 21.02* 31.09 10 -3 -14 45. 10 51.27 10 -3 -13 41.78 37.72 10 -3 -12 7.77* 14.49 H K L FO FC 10 -3 -11 109.62 114.85 10 -3 -10 89.48 92.54 10 -3 -9 29.35 38.55 10 -3 -8 107.99 108.70 10 -3 -7 1 16.66 118.87 10 -3 -6 12.56* 10.27 10 -3 -5 52.78 55. 19 10 -3 -4 143.69 149.82 10 -3 -3 32.04* 21.23 10 -3 -2 56.76 57.20 10 -3 -1 43.33 38.48 10 -3 0 45.56 48. 18 10 -3 1 52. 18 53.80 10 -3 2 17.36* 0.38 10 -3 3 27.93* 5. 15 10 -3 4 91.92 93.42 10 -3 5 21.92* 14.47 10 -3 6 50.95 50.09 10 -3 7 24.22* 25.45 11 -3 -15 8.01* 10.95 1 1 -3 -14 0.00* 18.53 11 -3 -13 53.24 56.71 11 -3 -12 22. 14* 19.21 11 -3 -11 16.63* 12.18 11 -3 -10 33.76 23.58 11 -3 -9 94.98 96.67 11 -3 -8 87.23 83.96 11 -3 -7 11.96* 24.20 11 _ 2 -6 38.57 40.. ,7 6 11 -3 -5 64.30 64.61 11 -3 -4 155.59 166.58 11 -3 -3 24.59* 15.48 11 -3 -2 87.92 98.33 11 -3 -1 75.77 85.33 11 -3 0 37.88 33.56 11 -3 1 89.33 89.68 11 -3 2 65. 25 70.78 1 1 -3 3 41.45 37.35 11 -3 4 22.55* 19.83 11 -3 5 0.00* 2.72 11 -3 6 51.39 40.22 12 -3 -14 14.20* 15.59 12 -3 -13 0.00* 8.80 12 -3 -12 21.27* 24.30 12 -3 -11 23.47* 23.65 12 -3 -10 103.49 111.95 12 -3 -9 52.89 52.51 12 _3 -8 0.00* 8.56 12 -3 -7 74.69 80.31 12 -3 -6 79.31 87.65 12 -3 -5 " 23.94* 14.91 12 -3 -4 0.00* 18.62 12 -3 -3 73.25 79.48 12 -3 -2 29.62* 32. 13 12 -3 -1 70.16 71.31 12 -3 0 50.25 4 4. 13 12 -3 1 37.97 37.47 12 -3 2 91.06 89.52 H K L FO FC 12 -3 3 39.74 33.20 12 -3 4 39.69 34.24 12 -3 5 35.95* 40.91 13 -3 -13 26.68* 35.27 13 -3 -12 44.21 49. 80 13 -3 -11 18.76* 11.92 13 -3 -10 56.04 50.02 13 -3 -9 51.48 43.79 13 -3 -8 34.09 31.82 13 -3 -7 27.52* 24.25 13 -3 -6 67.68 59.49 13 -3 -5 34.81* 42.44 13 -3 -4 124.78 124.47 13 -3 -3 19.18* 6.70 13 -3 -2 38.07 33.26 13 -3 -1 32.31 29.24 13 -3 0 85.45 83.44 13 -3 1 37.01 31.84 13 -3 2 18.06* 6.46 13 -3 3 72. 38 65.30 14 -3 -12 73. 28 75.03 14 -3 -11 26.30* 22.62 14 -3 -10 32.85 27.51 14 -3 -9 27.26* 7.38 14 -3 -8 36.43 39.29 14 -3 -7 32.68* 14.53 14 -3 -6 75.26 82.78 14 -3 -5 36.92* 34.64 '14 -3 -4 26.20* 24.66 14 -3 -3 26.36* 18.84 14 -3 -2 51.82 49.37 14 -3 -1 26.83* 3.75 14 -3 0 51.39 48.94 14 -3 1 48.42 44.75 15 -3 -10 19.66* 26.78 15 -3 -9 49. 48 45.98 15 -3 -8 29.47* 3.57 15 -3 -7 0.00* 18. 32 15 -3 -6 99. 19 97.51 15 -3 -5 29.47* 10.43 15 -3 -4 25.60* 33. 18 15 -3 -3 0.00* 16.57 15 -3 -2 34.17* 42.79 15 -3 -1 22.50* 5.62 0 -4 0 368.82 341.67 0 -4 1 147.33 134.08 0 -4 2 181.35 157.81 0 -4 3 46.87 45.82 0 -4 4 140.06 135.62 0 -4 5 17.27* 5.40 0 -4 6 20.75* 31.33 0 -4 7 160.17 157.40 0 -4 8 53.95 48. 19 0 -4 9 0.00* 15.83 0 -4 10 42.70 47.77 0 -4 11 30. 12 31.18 0 -4 12 62.73 57.72 0 -4 13 22.58* 18.52 H F L FO FC 0 -4 14 77.68 77.81 1 -4 -15 18.68* 16.25 1 -4 -14 7.34* 9.27 1 -4 -13 47.43 50.78 1 -4 -12 22.46* 17.87 1 -4 -11 74.39 67.28 1 -4 -10 21.47* 21.93 1 -4 -9 134.50 128.20 1 -4 -8 121.71 124.64 1 -4 -7 63.75 61.18 1 -4 -6 36.55 39.53 1 -4 -5 99.80 100.34 1 -4 -4 115.56 129.02 1 -4 -3 176.97 178.46 1 -4 -2 146.24 129.47 1 -4 -1 123.81 113.42 1 -4 0 36.42* 39.47 1 -4 1 97.77 102.62 1 -4 2 319.79 314.07 1 -4 3 62.17 60.95 1 -4 4 109.03 117.49 1 -4 5 13.57* 8.08 1 -4 6 169.82 158.82 1 -4 7 47.20 50.73 1 -4 8 23.09 20. 12 1 -4 9 19.57* 6.07 1 -4 10 35.87 40.40 1 -4 11 16.20* 5.16 1 -4 12 4.0 0* 3.17 1 -4 13 85.43 88.92 1 -4 14 59.55 61.61 2 -4 -15 27.22* 16.61 2 -4 -14 97.22 94.65 2 -4 -13 27.98 25.99 2 -4 -12 32.40 35.44 2 -4 -11 61.57 58. 15 2 -4 -10 92.83 89.09 2 -4 -9 91.91 90.80 2 -4 -8 58.17 64.74 2 -4 -7 1 12.96 112.28 2 -4 -6 35.48 27.84 2 -4 -5 17.40* 13.01 2 -4 -4 92.62 76. 13 2 -4 -3 144.19 141.42 2 -4 -2 240.62 217.67 2 -4 -1 35.21 39.87 2 -4 0 243.77 268.59 2 -4 1 74.96 79.58 2 -4 2 78.79 84.96 2 -4 3 179.62 184.56 2 -4 4 131.30 134.86 2 -4 5 9.74* 8.69 2 -4 6 38.34 32.23 2 -4 7 45.78... 41.79 2 -4 8 54.06 55.74 2 -4 9 12.20* 13.79 2 -4 10 114. 14 112.47 2 -4 11 38.37 39.51 H K L FO FC 2 -4 12 88. 19 89.28 2 -4 13 15.68* 16.48 3 -4 -15 34.87 30.28 3 -4 -14 11.45* 6.72 3 -4 -13 23.90 16.46 3 -4 -12 74.08 75.80 3 -4 -1 1 11.58* 4.54 3 -4 -10 99.49 102.54 3 -4 -9 28.83 24.93 3 -4 -8 63.20 64.24 3 -4 -7 70.26 73.44 3 -4 -6 71.12 69. 18 3 -4 -5 116.85 104.26 3 -4 -4 146. 10 122.56 3 -4 -3 195.24 185.25 3 -4 -2 13.62* 13.73 3 -4 -1 228.64 225.76 3 -4 0 113.48 134.79 3 -4 1 151.73 167. 14 3 -4 2 15.52* 8.23 3 -4 3 52. 15 49.39 3 -4 4 51.92 38.47 3 -4 5 9.96* 3.54 3 -4 6 152.68 155.37 3 -4 7 24.84 24. 15 3 -4 8 71. 14 79.91 3 -4 9 77.84 76.73 3 -4 10 39.22 36.61 3 -4 1 1 31.49 29.00 3 -4 12 50.99 58.60 3 -4 13 17.77* 3.77 4 -4 -15 32.66 32.92 4 -4 -14 65.81 68.6 1 4 -4 -13 29.90 26. 13 4 -4 -12 42.60 43.01 4 -4 -1 1 58. 46 63.22 4 -4 -10 69. 22 71.33 4 -4 -9 9.74* 5.06 4 -4 -8 50.16 51.74 4 -4 -7 94.56 96.66 4 -4 -6 69.05 74.33 4 -4 -5 82. 11 .89.87 4 -4 -4 320.43 306.85 4 -4 -3 76. 65 73. 16 4 -4 -2 177.93 159.28 4 -4 -1 18.47* 5.68 4 -4 0 38.99* 37.38 4 -4 1 67. 26 68.63 4 -4 2 111.88 109.05 4 -4 3 84. 13 90.84 4 -4 4 134.36 130.21 4 -4 5 148.40 144.07 4 -4 6 43.73 35. 10 4 -4 7 121.66 117.79 4 -4 8 63.78 58.75 4 -4 9 0.00* 5.40 4 -4 10 61.91 68.94 4 -4 11 14.92* 10.53 H K L FO FC 4 -4 12 32.29 20.97 5 -4 -15 7.08* 13.75 5 -4 - 14 21.21* 19.16 5 -4 -13 33. 17 36.63 5 -4 -12 20.25* 18.96 5 -4 -11 24.96 13.75 5 -4 -10 62. 34 67.54 5 -4 -9 0.00* 1.74 5 -4 -8 66.60 71.53 5 -4 -7 29. 86 3 5.68 5 -4 -6 247.39 230.85 5 -4 -5 109.95 110.08 5 -4 -4 59.63 54.36 5 -4 -3 22.28* 18.94 5 -4 -2 138.38 145.88 5 -4 -1 100.38 104.88 5 -4 0 83.36 93.79 5 -4 1 82.85 88.71 5 -4 2 99. 12 115.08 5 -4 3 144.37 151.81 5 -4 4 105.89 108.5 3 5 -4 5 64. 96 72.24 5 -4 6 29.35 38.34 5 -4 7 32.42 31.54 5 -4 8 31.77 29.22 5 -4 9 52.73 50.87 5 -4 10 0.00* 18.45 5 -4 11 27.32* 26.28 6 -4 -15 6. 10* 11.15 6 -4 - 14 0.00* 2.39 6 -4 -13 7.47* 14.01 6 -4 -12 64.88 62.42 6 -4 -11 113.65 120.39 6 -4 -10 13.84* 21.21 6 -4 -9 0.00* 1.90 6 -4 -8 66.09 61.78 6 -4 -7 137.57 140.28 6 -4 -6 105.52 101.61 6 -4 -5 50.97 48.87 6 -4 -4 205.87 189.87 6 -4 -3 62.80 63.92 6 -4 -2 101.57 107.33 6 -4 -1 18.89* 8.03 6 -4 0 240.72 265.91 6 -4 1 22.16* 29.20 6 -4 2 82.89 92. 17 6 -4 3 57.66 58.69 6 -4 4 23.24* 24.70 6 -4 5 15.22* 17.57 6 -4 6 43.31 44.85 6 -4 7 28.94 34.96 6 -4 8 30.74 34.06 6 -4 9 63. 88 62.77 6 -4 10 31.30 37.00 6 -4 11 46. 13 41.59 7 -4 -15 28.55 30.69 7 -4 -14 27.91 29.32 7 -4 -13 85.01 89.63 H K L FO FC 7 -4 -12 53.22 57.36 7 -4 -11 15.13* 22.81 7 -4 -10 18.47* 4.96 7 -4 -9 55.04 50.98 7 -4 -8 73.86 74.55 7 -4 -7 56.73 56.46 7 -4 -6 91.05 96.94 7 -4 -5 116.02 1 17.32 7 -4 -4 1 1.86* 15.63 7 -4 -3 22.24* 14.94 7 -4 -2 185.71 176.70 7 -4 -1 130.90 145.04 7 -4 0 43. 47 52.39 7 -4 1 7. 11* 6.48 7 -4 2 132.86 127.00 7 -4 3 61.07 68.37 7 -4 4 19.45* 2.13 7 -4 5 10.50* 12.0 1 7 -4 6 90.87 85.21 7 -4 7 31.09 21.72 7 -4 8 19.93* 9.96 7 -4 9 59.57 54.64 7 -4 10 54.62 57.55 8 -4 -15 14.40* 11.88 8 -4 -14 92. 06 92.53 8 -4 -13 0.00* 8.66 8 -4 -12 15.25* 6.68 8 -4 -11 26. 14 22.36 8 -4 -TO 26.41 24.03 8 -4 -9 10.77* 7.08 8 -4 -8 45. 22 44.29 8 -4 -7 165.10 158.65 8 -4 -6 132.50 126.59 8 -4 -5 23.41* 25.03 8 -4 -4 86.84 88. 63 8 -4 -3 110.54 1 17.96 8 -4 -2 122.29 129.33 8 -4 -1 103.47 110.51 8 -4 0 140.98 151.75 8 -4 1 33.89 36.24 8 -4 2 59.94 58.32 8 -4 3 0.00* 2.63 8 -4 4 73.36 82.22 8 -4 5 32.25 36.38 8 -4 6 .36.20 40. 82 8 -4 7 22.28* 26.42 8 -4 8 64.13 56.84 •8 -4 9 0.00* 2.00 9 -4 -15 23.23* 22.74 9 -4 -14 15.39* 20.3 4 9 -4 -13 6.35* 12.59 9 -4 -12 45.48 49.94 9 -4 -11 68. 30 65.26 9 -4 -10 47.89 51.42 9 -4 -9 53.06 48.31 9 -4 -8' 146.61 150.96 9 -4 -7 42.29 40.92 9 -4 -6 43.89 41.33 H K L FO FC 9 -4 -5 72.99 68.92 9 -4 -4 98. 59 97. 16 9 -4 -3 87.88 87.07 9 -4 -2 11.23* 13.56 9 -4 -1 97.06 101.95 9 -4 0 39.97 35.42 9 -4 1 3.70* 21.80 9 -4 2 78. 14 82.93 9 -4 3 66.74 64.85 9 -4 4 74.03 72.30 9 -4 5 60.64 52.91 9 -4 6 44.55 48.02 9 -4 7 0.00* 7.98 9 -4 8 37.75 35.09 10 -4 -14 52.41 59. 10 10 -4 -13 20.89* 1G.45 10 -4 -12 0.00* 3.74 10 -4 -11 24.51* 18.68 10 -4 -10 59.52 58.66 10 -4 34.39 37.74 10 -4 -8 121.83 126. 13 10 -4 -7 34.94 31.82 10 -4 -6 73.91 82.00 10 -4 -5 15.21* 21.25 10 -4 -4 94.98 102.36 10 -4 -3 68.98 67.94 10 -4 -2 120.89 129.9 1 10 -4 -1 11.04* 20. 37 TO -4 0 54.30 52.42 10 -4 1 93.07 98.76 10 -4 2 52.98 53.97 10 -4 3 82.25 86.35 10 -4 4 22.31* 4.72 10 -4 5 39.40 39.08 10 -4 6 23.91* 17.64 10 -4 7 17.13* 5. 13 11 -4 -14 22.76* 18.09 11 -4 -13 19.23* 23.89 11 -4 -12 22.50* 16.71 11 -4 -11 18.02* 2.92 11 -4 -10 96.84 95.05 11 -4 -9 61.26 61.43 11 -4 -8 39.02 42.15 11 -4 -7 41.50 42.20 11 -4 -6 90.53 94.01 11 -4 -5 0.00* 4.42 11 -4 -4 84.03 90.95 11 -4 -3 44.06 44.73 11 -4 -2 68.65 74. 12 11 -4 -1 68.75 72.21 11 -4 0 54.64 48.03 11 -4 1 27.45* 26.72 11 -4 2 52.71 57.86 11 -4 3 22.13* 21.50 11 -4 4 4.29* 20.04 11 -4 5 13.20* 2.53 12 -4 -13 19.04* 6.49 12 -4 -12 14.57* 17.22 H K L FO FC 12 -4 -11 68. 38 69.64 12 -4 -10 12.88* 8.69 12 -4 -9 16.52* 5.16 12 -4 -8 57.24 56.00 12 -4 -7 41.51 29.42 12 -4 -6 24.79* 19.25 12 -4 -5 0.00* 14.03 12 -4 -4 153.80 156.62 12 -4 -3 32.92* 29.99 12 -4 -2 52.63 68.30 12 -4 -1 24.61* 9.53 12 -4 0 60. 14 60. 15 12 -4 1 0.00* 1 .87 12 -4 2 24.98* 18.30 12 -4 3 33.13 24.96 12 -4 4 24.20* 17.23 13 -4 -12 37.23 37. 10 13 -4 -11 25.40* 22.40 13 -4 -10 38.75 30.66 13 -4 -9 50.59 46.66 13 -4 -8 12.13* 11.23 13 -4 -7 20.36* 7.63 13 -4 -6 92.61 96.39 13 -4 -5 110.00 109. 10 13 -4 -4 17.27* 8.46 13 "4 -3 0.00* 5.57 13 -4 -2 55.66 59.91 13 -4 -1 13.87* 3.24 .13 -4 .0 23.89* 16.81 13 -4 1 17.50* 3.71 13 -4 2 62.25 62.44 14 -4 -11 48.47 48.00 14 -4 -10 43.87 40.91 14 -4 -9 11.62* 17.27 14 -4 -8 15.66* 2.85 14 -4 -7 63.15 64.92 14 -4 -6 68.67 71.64 14 -4 -5 34.12* 15.32 14 -4 -4 58.32 60.95 14 -4 -3 27.15* 31.18 14 -4 -2 18.59* 12.25 14 -4 -1 25.36* - 8.29 14 -4 0 70.70 69.47 15 -4 -8 66.04 71.23 15 -4 -7 28.25* 18.88 15 -4 -6 0.00* 9.49 15 -4 -5 59.54 58.96 15 -4 -4 40.05 27.68 0 -5 1 128. 16 139.97 0 -5 2 180.36 184.42 0 -5 3 75.80 67.41 0 -5 4 0.00* 5.28 0 -5 5 57.08 64.73 0 -5 6 0.00* 9.53 0 -5 7 22.62* 17.48 0 -5 8 37.52 36.59 0 -5 9 123.81 129.89 0 -5 10 15.00* 5.63 H K L FO FC 0 -5 11 20.31* 27. 16 0 -5 12 35.30 32.79 0 -5 13 101.92 98.39 1 -5 -14 29.34 21.19 1 -5 -13 36.72 39.87 1 -5 -12 14.25* 7.00 1 -5 -11 73.30 75.45 1 -5 -10 27.10 22. 19 1 -5 -9 79.49 88.63 1 -5 -8 83. 16 87.00 1 -5 -7 178.41 171.09 1 -5 -6 51.26 58.22 1 -5 -5 96.81 92.46 1 -5 -4 71.75 70.38 1 -5 -3 187.98 186.39 1 -5 -2 25.61 26.06 1 -5 -1 48.29 46.92 1 -5 0 1 16.40 121.48 1 -5 1 83.39 88.44 1 -5 2 25.37 14.95 1 -5 3 70.09 77.91 1 -5 4 112.23 103.31 1 -5 5 111.97 115.58 1 -5 6 .11.52* 22.61 1 -5 7 159.50 162.95 1 -5 8 15.71* 25.03 1 -5 9 65.72 66.03 1 -5 10 50.87 56.59 1 -5 11 52.0.9 ..59.4 3 1 -5 12 20.00* 9.11 1 -5 13 5. 19* 3.87 2 -5 -14 6.46* 4.88 2 -5 -13 41.86 41.23 2 -5 -12 26. 11 21.59 2 -5 -11 26.38 30.6 1 2 -5 -10 27.63 23.63 2 -5 -9 1 12.91 119. 19 2 -5 -8 62.51 66.28 2 -5 -7 22.21 27.51 2 -5 -6 94.54 105.82 2 -5 -5 171.16 165.71 2 -5 -4 42. 11 35.54 2 -5 -3 163.31 170.32 2 -5 -2 17.45* 3.36 2 -5 -1 151.10 148.33 2 -5 0 28.78* 40.61 2 -5 1 12.23* 19.69 2 -5 2 152.55 150.78 2 -5 3 132.73 139.58 2 -5 4 37.49 29.75 2 -5 5 7.23* 4.51 2 -5 6 44.28 43.27 2 -5 7 104.81 110.91 2 -5 8 42.19 42.83 2 -5 9 35.69 32.94 2 -5 10 17.18* 10.74 2 -5 11 41.51 44.04 2 -5 12 37.06 41.61 H K L FO FC 2 -5 13 59.41 57.58 3 -5 -14 36.77 34.26 3 -5 -13 19.44* 11.73 3 -5 -12 17.70* 6.07 3 -5 -11 20.21* 20.05 3 -5 -10 14. 19* 21.86 3 -5 -9 132.57 134.10 3 -5 -8 57.28 61. 14 3 -5 -7 158.51 157.30 3 -5 -6 17.76* 13.69 3 -5 -5 102.01 100.66 3 -5 -4 112.04 120.16 3 -5 -3 106.73 101.34 3 -5 -2 34.76 20.98 3 -5 -1 0.00* 10.71 3 -5 0 5.97* 27.69 3 -5 1 99.48 104.52 3 -5 2 9.65* 3.4 3 3 -5 3 182.58 188.14 3 -5 4 71.15 69.08 3 -5 5 170.60 166.78 3 -5 6 5.72* 8.03 3 -5 7 71.72 67.92 3 -5 8 28.09 28.62 3 -5 9 47.68 52.58 3 -5 10 6.47* 3.05 3 -5 11 37.19 35.99 3 -5 12 16.42* 8.32 4 -5 -14 23,31* 8.76 4 -5 -13 0.00* 10.85 4 -5 -12 71.67 75.70 4 -5 -11 94.42 104.27 4 -5 -10 9.56* 2.53 4 -5 -9 13.51* 3.46 4 -5 -8 31.21 29.30 4 -5 -7 31.05 31.28 4 -5 -6 103. 15 102.09 4 -5 -5 12.71* 4.21 4 -5 -4 0.00* 7.00 4 -5 -3 101.49 96.97 4 -5 -2 96.88 84.90 4 -5 -1 150.00 151.89 4 -5 0 70.95 82.46 4 -5 1 172.43 198.76 4 -5 2 45.92 48.07 4 -5 3 68.05 71.78 4 -5 4 70.84 73.41 4 -5 6 45.46 50.69 4 -5 7 48.36 49.90 4 -5 8 26.35 22.33 4 -5 9 52.89 60.05 4 -5 10 12.48* 14.28 4 -5 11 82.67 83.68 5 -5 -15 25.01* 35.32 5 -5 -14 40.09 42.43 5 -5 -13 32.49 27.60 5 -5 -12 8.39* 0.21 5 -5 -11 129.87 132.89 H K L FO FC 5 -5 -9 64.44 74.36 5 -5 -8 24.89 29.90 5 -5 -7 14.63* 12.35 5 -5 -6 35.27 28.87 5 -5 -5 1 19.45 116.20 5 -5 -4 129.15 123.34 5 -5 -3 88.69 78.22 5 -5 -2 48.01 39.94 5 -5 -1 80.66 83.39 5 -5 0 97.94 109.59 5 -5 1 71.91 76.04 5 -5 2 29.95* 33.27 5 -5 3 1 15.28 122.67 5 -5 4 14.31* 5.08 5 -5 5 69.78 77.81 5 -5 6 32.52 28.79 5 -5 7 118. 10 120.73 5 -5 8 26.47* 2 1.14 5 -5 9 81.79 79.66 5 -5 10 23.87* 13.65 5 -5 11 46.72 45.66 6 -5 -15 15.73* 9.28 6 -5 -14 0.00* 5.89 6 -5 -12 24.28* 31.99 6 -5 -11 34.80 38.35 6 -5 -10 57.73 61.11 6 -5 -9 34. 10 32.80 6 -5 -8 43.59 43.95 6 -5 -7 50.03 54.92 6 -5 -6 26.65* 26.43 6 -5 ' -5 118.16 120.83 6 -5 -3 54.56 52.82 6 -5 -2 166.57 173.31 6 -5 -1 93.36 97.51 6 -5 0 48.02 53.26 6 -5 1 66.13 67.94 6 -5 2 25.02* 28. 12 6 -5 3 51.93 52.66 6 -5 4 4.43* 10.30 6 -5 5 105.36 108.89 6 -5 6 25.49* 18.85 6 -5 7 20.83* 22.57 6 -5 8 42.57 48.73 6 -5 9 89.02 84.52 6 -5 10 22.06* 14.49 7 -5 -14 8.63* 4.75 7 -5 -13 29.66 33. 12 7 -5 -12 34.22 39.23 7 -5 -11 106.76 111.18 7 -5 -10 19.21* 12.99 7 -5 -9 29.66 33.87 7 -5 -8 27.58 20.20 7 -5 -7 193.64 184.79 7 -5 -6 14.30* 7.55 7 -5 -5 35.87 29.30 7 -5 -4 47.30 49.41 7 -5 -3 45.20 41.61 7 -5 -2 27.1 1* 27.30 H K L FO FC 7 -5 -1 33.68* 33.49 7 -5 0 80.41 93.59 7 -5 1 82.28 93. 17 7 -5 2 36. 11 35.54 7 -5 3 62.58 78.45 7 -5 4 53. 36 55.43 7 -5 5 91.96 95.47 7 -5 6 21.16* 32.70 7 -5 7 59.95 68.08 7 -5 8 23.94* 3.59 7 -5 9 20.51* 23.75 8 -5 -14 17.86* 6.93 8 -5 -13 86.87 88.45 8 -5 -12 4.07* 6.74 8 -5 -11 15.49* 8.65 8 -5 -10 40.76 35.71 8 -5 -9 100.08 109.76 8 -5 -8 21.87* 4.45 8 -5 -7 52. 38 56.07 8 -5 -4 23.64* 5.61 8 -5 -3 27.75* 23.89 8 -5 -2 65.54 70.28 8 -5 -1 147.63 163.08 8 -5 0 41.58 43.83 8 -5 2 66.82 75.31 8 -5 3 101.12 102.30 8 -5 4 20.28* 12.18 8 -5 5 34. 37 28.86 8 -5 .6 15.64* 3.47 8 -5 7 31.84* 35.26 8 -5 8 7.04* 22.00 9 -5 -14 28.32* 26.86 9 -5 -13 59. 10 62.89 9 -5 -12 24.63* 22.3 1 9 -5 -11 36.88 37.09 9 -5 -10 29.93 25.57 9 -5 -9 69.58 73.91 9 -5 -8 74. 11 76.34 9 -5 -7 104.03 104.59 9 -5 -6 0.00* 6.49 9 -5 -5 1 27.35* 28.00 9 -5 -4 13.72* 21.62 9 -5 -3 99.05 99.84 9 -5 -2 27.86* 19.89 9 -5 -1 81.34 94.01 9 -5 0 28.22* 23.76 9 -5 1 99.95 100.15 9 -5 2 27.03* 26.46 9 -5 3 60.30 68.65 9 -5 4 40.28 31.50 9 -5 5 82.33 91.50 9 -5 6 0.00* 15.01 9 -5 7 40.55 39. 89 10 -5 -13 6.72* 8.04 10 -5 -12 24.02* 31.44 10 -5 -11 31.43 33.64 10 -5 -10 27.36* 30.72 10 -5 -9 20.05* 15.56 H K L FO FC 10 -5 -8 0.00* 6.36 10 -5 -7 30.03 28. 13 10 -5 -6 76.93 74.59 10 -5 -5 40.91 44.60 10 -5 -4 49.20 50. 19 10 -5 -3 110.55 113.83 10 -5 -2 32.79* 46.00 10 -5 -1 59.82 66.28 10 -5 0 28.28* 11.39 10 -5 1 31.85* 38.55 10 -5 2 35.28 24.28 10 -5 3 54.30 62.02 10 -5 4 45.71 36.89 10 -5 5 28.97* 35.29 10 -5 6 0.00* 2.30 11 -5 -13 19.32* 26.53 11 -5 -12 24.62* 18.34 11 -5 -11 37.00 44.18 11 -5 -10 32.00 24.49 11 -5 -9 82.24 86.4 1 11 -5 -8 34.71 38.07 11 -5 -7 22.37* 15.40 11 -5 -6 38.44 39.22 11 -5 -5 35.28 39. 10 11 -5 -4 73.69 73.63 11 -5 -3 39.41 29.42 11 -5 -2 24.92* 12.37 11 -5 -1 40.24 32.81 11 -5 0 30.73* 22.7 1 11 -5 1 20.10* 25.39 11 -5 2 8.80* 5.97 11 -5 3 100.56 99.40 11 -5 4 10.43* 2.64 12 -5 -12 6.77* 20.20 12 -5 -11 47.45 51.86 12 -5 -10 11.79* 14.79 12 -5 -9 50.97 54.53 12 -5 -8 13.72* 5.23 12 -5 -6 40.62 45. 15 12 -5 -5 66.93 70.47 12 -5 -4 31.59* 33.70 12 -5 -3 46.77 45.24 12 -5 -2 38. 10 41.88 12 -5 -1 19.20* 9.36 12 -5 0 20.59* 31.26 12 -5 1 59.16 64.09 12 -5 2 14.16* 15.69 12 -5 3 0.00* 3.63 13 -5 -11 89.12 94.34 13 -5 -10 25.47* 8.40 13 -5 -9 • 34.04 31.45 13 -5 -8 0.00* 13.19 13 -5 -7 48.68 44. 17 13 -5 -6 34.73* 20.99 13 -5 -5 34.55* 16.79 13 -5 -4 27.55* 26.85 13 -5 -3 37.35 43.96 13 -5 -2 28.55* 28.21 H K L FO FC 13 -5 -1 17.99* 16.86 13 -5 0 33.75* 42.80 13 -5 1 78.79 78.23 14 -5 -8 8.50* 11.32 14 -5 -7 22.81* 3.70 14 -5 -6 23.90* 5. 18 14 -5 -5 91. 38 88.75 14 -5 -4 0.00* 8.10 14 -5 -3 25.49* 9.30 14 -5 -2 37. 11 33.49 0 -6 0 78.57 71.71 0 -6 1 17.46* 20.58 0 -6 2 78.48 78.62 0 -6 3 59.40 61.77 0 -6 4 15. 11* 6.82 0 -6 5 122.47 117.76 0 -6 6 64.77 66.50 0 -6 7 100.57 106.49 0 -6 8 45.52 45.83 0 -6 9 24.54* 22. 17 0 -6 10 36. 36 36.88 0 -6 1 1 44.82 47.70 0 -6 12 75. 22 74.61 1 -6 -13 25.18* 27.71 1 -6 -12 47.49 42.93 1 -6 -11 21.44* 20.88 1 -6 -10 11.26* 16.68 1 -6 -9 115.48 114.44 -6 -8 131. 15 132.28 1 -6 -7 24.71 23.46 1 -6 -6 111.13 116.05 1 -6 -5 75.05 76.23 1 -6 -4 47.87 42.65 1 -6 -3 0.00* 3.71 1 -6 -2 7.63* 20.07 1 -6 -1 28.68 23.67 1 -6 0 0.00* 36.49 1 -6 1 60.32 54.29 1 -6 2 81.33 82.81 1 -6 3 135.31 136.24 1 -6 4 54. 17 55.35 1 -6 5 15.98* - 6.09 1 -6 6 85.59 83.76 1 -6 7 75. 17 75.47 1 -6 8 63.05 63. 13 1 -6 9 49.23 49.00 1 -6 10 36. 18 43.94 1 -6 1 1 15.67* 3.98 1 -6 12 40. 39 39.92 2 -6 -13 33.55 35.22 2 -6 -12 30.83 30. 14 2 -6 -11 59.75 54.08 2 -6 -10 47.44 47.98 2 -6 -9 102.44 103.62 2 -6 -8 69.48 66.32 2 -6 -7 77.28 78.23 2 -6 -6 83.29 76.35 2 -6 -5 33.73 33.38 H K L FO FC 2 -6 -4 10.48* 9.03 2 -6 -3 74.07 67.7 1 2 -6 -2 202.02 182.14 2 -6 -1 16.85* 8.61 2 -6 0 33.65* 35.05 2 -6 1 75.79 80.55 2 -6 2 74. 18 74.64 2 -6 3 1 17.41 109.94 2 -6 4 20.40* 5.08 2 -6 5 89.76 90.23 2 -6 6 21.41* 22.40 2 -6 7 19.60* 21.50 2 -6 8 18.87* 19.10 2 -6 9 70.01 75. 17 2 -6 10 18.91* 13.07 2 -6 11 40.55 40.68 2 -6 12 52.94 51.85 3 -6 -13 9. 86* 6.92 3 -6 -12 19.49* 16.78 3 -6 -11 93.43 93.00 3 -6 -10 23.15* 26. 17 3 -6 -9 13.33* 17.22 3 -6 -8 100.75 106.87 3 -6 -7 32.64 34.46 3 -6 -6 63. 53 61.01 3 -6 -5 90.05 91.34 3 -6 -4 134.85 127.05 3 -6 -3 58.73 47.05 3 D -2 / J. Oo 6 3.57 3 -6 -1 41.28 35.79 3 -6 0 47.41 59.14 3 -6 1 73. 30 87.90 3 -6 2 60.69 66.07 3 -6 3 32.45 25.81 3 -6 4 154.58 159.53 3 -6 5 15.12* 23.08 3 -6 6 0.00* 4.79 3 -6 7 107.92 109.91 3 -6 8 41.93 41.57 3 -6 9 12.37* 12.71 3 -6 10 33.83 27.98 3 -6 11 55.04 51.25 4 -6 -13 29.25 33. 19 4 . -6 -12 33.38 35.95 4 -6 -11 24.11* 27.87 4 -6 -10 19.88* 24.07 4 -6 -9 80.05 84.24 4 -6 -8 19.39* 24.56 4 -6 -7 86.84 80.56 4 -6 -6 9.56* 12.96 4 -6 -5 109.06 105.78 4 -6 -4 20.83* 6.22 4 -6 -3 27.09 22.68 4 -6 -2 128.55 128.83 4 -6 -1 17.11* 18.91 4 -6 0 21.51* 13.38 4 -6 1 33.26 15.09 4 -6 2 117.58 123.28 H K L FO FC 4 -6 3 75.03 73.82 1 -6 4 0.00* 5.97 4 . -6 5 85.99 92.28 4 -6 6 56.90 50.77 4 -6 7 80. 19 80.55 4 -6 8 33.61 36.74 4 -6 9 51.86 51.68 4 -6 10 65.98 67.69 5 -6 -13 37. 32 38.28 5 -6 -12 48.78 52. 18 5 -6 -11 63.59 61.03 5 -6 -10 82.83 87.78 5 -6 -9 19.90* 16.28 5 -6 -8 12. 1 1* 17.85 5 -6 -7 105.52 102.92 5 -6 -6 26. 34 25.97 5 -6 -5 13.98* 20.59 5 -6 -4 61.43 60.70 5 -6 -3 0.00* 22.26 5 -6 -2 56.72 64.31 5 -6 -1 21.12* 4.48 5 -6 0 17.81* 3.32 5 -6 1 53.83 62.96 5 -6 2 40.37 47.62 5 -6 3 17.60* 6.55 5 -6 4 89. 66 93. 34 5 -6 5 106.47 106.68 5 -6 6 37. 12 38.46 5 -6 7 11.86* 12.43 5 -6 8 86.76 88.25 5 -6 9 30.30* 25.56 5 -6 10 9.36* 4.00 6 -6 -13 14.08* 9.30 6 -6 -12 82.98 83.76 6 -6 -11 88.60 87.70 6 -6 -10 14.54* 19.88 6 -6 -9 56.63 52.33 6 -6 -8 21.52* 20.66 6 -6 -7 53.01 56. 10 6 -6 -6 73.86 69.00 6 -6 -5 40.97 40.08 6 -6 -4 62. 50 57.23 6 -6 -3 24.76* 15. 1 1 6 -6 -2 9.89* 24.65 6 -6 -1 45.00 46.71 6 -6 0 23.91* 11.45 6 -6 1 96.23 96.98 6 -6 2 61. 20 62.78 6 -6 3 65.93 67.34 6 -6 4 20.19* 6.23 6 -6 5 36.21 41.23 6 -6 6 31.76* 29.52 6 -6 7 45. 20 45.95 6 -6 8 52.96 54.82 6 -6 9 45.46 43.64 7 -6 --13 82.72 76.99 7 -6 --12 57.27 59.70 7 -6 --11 7.47* 12.24 H K L FO FC 7 -6 - 10 75.80 75.41 7 -6 -9 66.82 66.89 7 -6 -8 82. 35 84.42 7 -6 -7 39. 20 35.56 7 -6 -6 103.29 102.92 7 -6 -5 31.23 31.67 7 -6 -4 39.54 28. 17 7 -6 -3 59.21 55. 19 7 -6 -2 5.35* 23.72 7 -6 -1 86. 21 91.01 7 -6 0 49.28 62. 18 7 -6 1 16.97* 11.78 7 -6 2 4.44* 21.14 7 -6 3 68. 45 75.05 7 -6 4 13. 48* 14.85 7 -6 5 42.49 40.88 7 -6 6 43.95 46.69 7 -6 7 26.12* 22.08 7 -6 8 63. 33 54. 16 8 -6 -13 59.56 60.48 8 -6 -12 62.07 62. 11 8 -6 -11 54.88 54.94 8 -6 -10 30.75 27.28 8 -6 -9 4.06* 3.53 8 -6 -8 42.60 46.29 8 -6 -7 65.21 69.29 8 -6 -6 96.59 89.67 8 -6 -5 28.70* 26.28 8 -6 -4 46.08 37* 56 8 -6 -3 48.00 52.82 8 -6 -2 100.79 99.93 8 -6 -1 52.53 55.07 8 -6 0 36.82 49.60 8 -6 1 51.42 52.28 8 -6 2 36.87* ' 31.08 8 -6 3 19.81* 17.35 8 -6 4 22.12* 21.49 8 -6 5 69.36 82. 14 8 -6 6 31.62* 27.80 8 -6 7 46.71 41.43 9 -6 -13 13.38* 17.60 9 -6 -12 23.61* 19.00 9 -6 -11 34.43 40.42 9 -6 -10 0.00* 2.7 1 9 -6 -9 70.58 69.77 9 -6 -8 73.37 72.99 9 -6 -7 35.08 35.29 9 -6 -6 87.30 89.43 9 -6 -5 43. 89 38.93 9 -6 -4 34.18 41.23 9 -6 -3 • 37.02 35.10 9 -6 -2 18.74* 13.63 9 -6 -1 33.02* 24.74 9 -6 0 79.17 83. 12 9 -6 1 26.07* 17.26 9 -6 2 18.03* 18.72 9 -6 3 77.27 86. 19 9 -6 4 81.52 79.06 H K L FO FC 9 -6 5 38.31 27.43 9 -6 6 36.55 34.98 10 -6 -12 13.79* 15.70 10 -6 -11 29.27 22.06 10 -6 -10 7.03* 2.97 10 -6 -9 77.68 75.39 10 -6 -8 25.47* 11.12 10 -6 -7 22.12* 19.48 10 -6 -6 25.27* 22.31 10 -6 -5 0.00* 13.11 10 -6 -4 23.81* 3.98 10 -6 -3 0.00* 4.4 1 10 -6 -2 86.38 87.80 10 -6 -1 43.21 42.03 10 -6 0 34. 39 32. 14 10 -6 1 4 4.33 40.20 10 -6 2 34.94* 42.4 1 10 -6 3 71.93 70.65 10 -6 4 27.64* 9.99 11 -6 -11 58. 54 58.59 11 -6 -10 55.40 59.21 11 -6 -9 18.64* 9.89 11 -6 -8 35.92 31.50 11 -6 -7 30. 60 21.50 11 -6 -6 27.49* 16. 82 11 -6 -5 0.00* 9.40 11 -6 -4 0.00* 7.38 11 -6 -3 38.71* 45.45 11 -6 -2 10.7 8* 14.24 11 -6 -1 21.99* 10.27 11 -6 0 0.00* 21.18 11 -6 1 64.74- 56.64 11 -6 2 28.25* 27.79 11 -6 3 0. 00* 3.31 12 -6 -10 0.00* 16.48 12 -6 -9 36.80 40. 15 12 -6 -8 35.90 31.71 12 -6 -7 25. 19* 7.51 12 -6 -6 38. 19 37.52 12 -6 -5 28.84* 32. 12 12 -6 -4 22.88* 30.38 12 -6 -3 36.37* 43.79 12 -6 -2 18.80* 17.76 12 -6 -1 24.31* 22.97 12 -6 0 24.06* 6. 65 12 -6 1 47.25 39.93 13 -6 -8 27.84* 20. 17 13 -6 -7 32.09* 30.26 13 -6 -6 30.07* 33.64 13 -6 -5 33.99* 37.59 13 -6 -4 21.03* 18.49 13 -6 -3 8.76* 5.12 13 -6 -2 25.38* 2.36 0 -7 1 52.93 48.38 0 -7 2 49.36 52.21 0 -7 3 87. 14 82. 38 0 -7 4 25.54 21.80 0 -7 5 36.45 31.48 H K L FO FC 0 -7 6 79.01 83.67 0 -7 7 13.99* 21.05 0 -7 8 78. 16 75.97 0 -7 9 35.74 38.31 0 -7 10 47.49 44.17 0 -7 11 22.64* 29.71 1 -7 -12 54. 38 55.25 1 -7 -11 17.24* 11.79 1 -7 -10 43.87 44.50 1 -7 -9 14.60* 2.50 1 -7 -8 46.04 45.18 1 -7 -7 38.32 36.47 1 -7 -6 85.17 89.78 1 -7 -5 46.01 46.41 1 -7 -4 29.09 19.24 1 -7 -3 10.63* 7.06 1 -7 -2 165.21 158.59 1 -7 -1 17.30* 2.88 1 -7 0 1 11.67 113.86 1 -7 1 21.84* 3.61 1 -7 2 22.06* 20.71 1 -7 3 0.00* 10.46 1 -7 4 46.37 48.73 1 -7 5 20.40* 3.38 1 -7 6 27.47 22.90 1 -7 7 12.82* 6.03 1 -7 8 22.70* 22.89 1 -7 9 58.28 55.59 1 -7 10 0.00* 2.88 1 -7 11 2.59* 2.25 2 -7 -12 36.06 31.40 2 -7 -11 35.49 34.42 2 -7 -10 13.26* 8.48 2 -7 -9 17.01* 8.97 2 -7 -8 108.64 107.40 2 -7 -7 3.69* 6.60 2 -7 -6 51.17 55.27 2 -7 -5 46.77 36.92 2 -7 -4 123.34 121.84 2 -7 -3 52.87 53.30 2 -7 -2 69.75 62.85 2 -7 -1 122.51 110.52 2 -7 0 81.40 97.47 2 -7 1 11.96* 12.31 2 -7 2 20.46* 12.60 2 -7 3 13.00* 4.54 2 -7 4 83.58 88.94 2 -7 5 16.20* 16.55 2 -7 6 46.23 50.71 2 -7 7 77. 16 78.06 2 -7 8 28.96 21.22 2 -7 9 0.00* 8.98 2 -7 10 36.92 38.22 3 -7 -12 20.68* 2.37 3 -7 -11 21.66* 27.23 3 -7 -10 51.08 50.03 3 -7 -9 24.01* 22.14 3 -7 -8 10.40* 17.06 H K L FO FC 3 -7 -7 0.00* 11.40 3 -7 -6 49.42 48.03 3 -7 -5 0.00* 3.45 3 -7 -4 38.86 34.55 3 -7 -3 69.53 64.30 3 -7 -2 185.20 175.59 3 -7 -1 52.88 52.92 3 -7 0 34.18* 33.34 3 -7 1 17.12* 2.86 3 -7 2 120.09 124.90 3 -7 3 25.68* 21. 10 3 -7 4 35.55 29.07 3 -7 5 17.26* 8. 14 3 -7 6 39.54 42.22 3 -7 7 32.76 26. 30 3 -7 8 16.93* 20. 18 3 -7 9 3.49* 11.99 3 -7 10 54.78 52.27 4 -7 -12 2.92* 8.20 4 -7 -11 36.77 30.77 4 -7 -10 50.54 50.29 4 -7 -9 11.62* 17.44 4 -7 -8 36.53 38.47 4 -7 -7 61.74 57.76 4 -7 -6 18.35* 22.61 4 -7 -5 43. 16 39.68 4 -7 -4 108.19 105.40 4 -7 -3 88.58 80.23 •4 — / — 18.50* 1 8.0 0 4 -7 -1 47. 32 40. 86 4 -7 0 89.06 99.23 4 -7 1 11.54* 4.48 4 -7 2 22.12* 23.90 4 -7 3 63.75 72. 31 4 -7 4 107.40 116.00 4 -7 5 19.77* 20.60 4 -7 6 11.90* 17.55 4 -7 7 4 0.40 38. 12 4 -7 8 63.9 1 68.74 4 -7 9 31.02 31.16 5 -7 -12 55. 10 58.53 5 -7 -11 17.06* 3.29 5 -7 -10 17.94* 2.11 5 -7 -9 22.62* 15.68 5 -7 -8 16.75* 22.72 5 -7 -7 31.46 30.96 5 -7 -6 29. 16 23.90 .5 -7 -5 10.86* 12.67 5 -7 -4 74.84 75. 16 5 -7 -3 22.19* 2.22 5 -7 -2 72.39 71.90 5 -7 -1 22.38* 21.30 5 -7 0 37. 17 45.46 5 -7 1 37.92* 46.54 5 -7 2 98.81 110.08 5 -7 3 37.28 41.88 5 -7 4 12.99* 3.48 5 -7 5 11.14* 8.70 H K L FO FC 5 -7 6 44.89 45.31 5 -7 7 27.95* 1.01 5 -7 8 37.51 41.75 6 -7 -12 43.73 43.33 6 -7 -11 26.14* 21.92 6 -7 -10 72. 31 69.38 6 -7 -9 0.00* 1.38 6 -7 -8 56.91 55.91 6 -7 -7 87. 32 81.64 6 -7 -6 88.98 87.89 6 -7 -5 47.90 42.26 6 -7 -4 15.53* 3.33 6 -7 -3 17.83* 7.21 6 -7 -2 29.76* 32.95 6 -7 -1 0.00* 12.17 6 -7 0 0.00* 12.31 6 -7 1 65.60 58.27 6 -7 2 31.84* 43.41 6 -7 3 . 43.03 50.89 6 -7 4 38.20 43.16 6 -7 5 41.84 44. 36 6 -7 6 42. 59 38.86 6 -7 7 0.00* 0.51 7 -7 -12 61.63 64.77 7 -7 -11 20.23* 7.10 7 -7 -10 31.20 35.43 7 -7 -9 29.93 25.04 7 -7 -8 43.91 44.30 —* i -T — / -7 20.91* 10.35 1 -7 -6 92. 31 90.78 7 -7 -5 0.00* 6.29 7 -7 -4 75.79 77.26 7 -7 -3 25.79* 22.06 7 -7 -2 63.02 64.54 7 -7 -1 22.02* 9.66 7 -7 0 67.26 78.57 7 -7 1 22.28* 6.45 7 -7 2 25.04* 15.14 7 -7 3 21.64* 8.09 7 -7 4 19.74* 12.92 7 -7 5 36.73 35.06 7 -7 6 13.22* 6.65 8 -7 -11 20.48* 28.95 8 -7 -10 31.95 18.33 8 -7 -9 34. 83 36.87 8 -7 -8 93.37 92.33 8 -7 -7 23.29* 14.54 8 -7 -6 83.78 76.32 8 -7 -5 45.71 44.84 8 -7 -4 61.66 65.48 8 -7 -3 36.31* 40.37 8 -7 -2 59.50 46.24 8 -7 -1 35.49* 41.32 8 -7 0 58.83 68. 12 8 -7 1 33.39* 34.38 8 -7 2 37.78* 32.97 3 -7 3 55.52 55.70 8 -7 4 33.69* 43.59 H K L FO FC 8 -7 5 25.15* 1. 16 9 -7 -11 14.94* 14.19 9 -7 -10 28.50* 26. 15 9 -7 -9 0.00* 5.93 9 -7 -8 0. 00* 4.72 9 -7 -7 35.55 26.82 9 -7 -6 83.28 80. 19 9 -7 -5 9.83* 10.08 9 -7 -4 24.08* 24.36 9 -7 -3 0.00* 4.06 9 -7 , -2 103.50 1 10.42 9 -7 -1 33.09* 4.38 9 -7 0 49.63 56.31 9 -7 1 17.53* 12.04 9 -7 2 49.00 49.90 9 -7 3 0.00* 1.70 9 -7 4 0.00* 2.57 10 -7 -10 38.06 40.58 10 -7 -9 27.83* 23.87 10 -7 -8 56.90 52.87 10 -7 -7 23.03* 1.49 10 -7 -6 26. 16* 9.65 10 -7 -5 0.00* 12.26 10 -7 -4 61.13 58.74 10 -7 -3 26.53* 19.27 10 -7 -2 0.00* 14.65 10 -7 -1 66.56 68.91 10 -7 0 60.24 61.03 10 -7 i 1.2.9 0* 14.08 10 -7 2 5.56* 8.25 11 -7 -9 0.00* 6.46 11 -7 -8 46.98 39. 32 11 -7 -7 19.77* 0.68 11 -7 -6 0.00* 7.00 11 -7 -5 24.87* 14.89 11 -7 -4 22.25* 36.02 11 -7 -3 30.83* 28.32 11 -7 -2 58.58 62. 13 11 -7 -1 26.81* 8.04 11 -7 0 0.00* 8.68 12 -7 -6 51.52 47.64 12 -7 -5 37.51 26. 14 12 -7 -4 0.00* 8.99 0 -8 0 47.83 53.74 0 -8 1 42.74 35.52 0 -8 2 36.22 27.08 0 -8 3 22.26* 22.57 0 -8 4 31.84 35.70 0 -8 5 15.62* 13.88 0 -8 6 41.43 39.33 0 -8 7 83.50 •78.92 0 -8 8 24.07* 17.53 0 -8 9 24.95* 24. 10 1 -8 -10 31.12 27.30 1 -8 -9 36.72 34.54 1 -8 -8 29.70 24.11 1 -8 -7 12.04* 6. 19 1 -8 -6 12.88* 3.50 H K L FO FC ! -8 -5 49. 89 45.45 1 -8 -4 70.50 68.22 1 -8 -3 57. 19 60.20 1 -8 -2 41.22 4 1.14 1 -8 -1 135.47 124.29 1 -8 0 44.29* 39.79 1 -8 1 21.29* 23.06 1 -8 2 62.74 60.93 1 -8 3 18.43* 8.94 1 -8 4 5.87* 12.77 1 -8 5 47.70 42.26 1 -8 6 19.02* 12.18 1 -8 7 0.00* 8.76 1 -8 8 0.00* 5.25 1 -8 9 8.93* 15.80 2 -8 -10 22.52* 20.22 2 -8 -9 25.07* 27.78 2 -8 -8 9.93* 3.72 2 -8 -7 90.32 88.22 2 -8 -6 54.43 51.81 2 -8 -5 34. 87 32.02 2 -8 -4 0.00* 1.66 2 -8 -3 88.72 81.60 2 -8 -2 95.12 78.86 2 -8 -1 53.08 45.19 2 -8 0 47.81* 36.86 2 -8 1 36. 24 40.73 2 -8 2 27. 29* 43.00 2 -8 3 3.1.56 27.46 2 -8 4 7. 25* 18.92 2 -8 5 62.21 67.99 2 -8 6 18.82* 10.95 2 -8 7 16.30* 21.13 2 -8 8 3.44* 2.42 2 -8 9 0.00* 7.45 3 -8 -10 13.39* 14.80 3 -8 -9 44.53 38.73 3 -8 -8 24.41* 11.90 3 -8 -7 21.98* 16.86 3 -8 -6 8.93* 1 1.46 3 -8 -5 16.01* 3.01 3 -8 -4 77. 12 67.65 3 -8 -3 87.4-1 83.43 3 -8 -2 26.71* 1.39 3 -8 -1 101.87 101.65 3 -8 0 76.85 87.66 3 -8 1 32.48* 40.72 3 -8 2 12.79* 31.86 3 -8 3 85.26 79.13 3 -8 4 31.48 28. 10 3 -8 5 22.19* 15.83 3 -8 6 6.86* 2.26 3 -8 7 21.58* 15.85 3 -8 8 27.77* 26.24 4 -8 -10 16.54* 2.64 4 -8 -9 40.48 37.44 4 -8 -8 0.00* 12.66 4 -8 -7 0.00* 5.71 H K L FO FC 4 -8 -6 16.33* 18.32 4 -8 -5 18.77* 23.62 4 -8 -4 47. 31 35.27 4 -8 -3 62.05 56.95 4 -8 -2 65.86 66. 13 4 -8 -1 48.52 43.90 4 -8 0 28.79* 8. 17 4 -8 1 45.68 30.05 4 -8 2 57.59 55.09 4 -8 3 83. 30 93.67 4 -8 4 30.04* 18.68 4 -8 5 44.46 43.25 4 -8 6 28.23* 30.33 4 -8 7 8.87* 19.50 5 -8 -10 0.00* 9.99 5 -8 -9 24.73* 19. 84 5 -8 -8 20.87* 13.03 5 -8 -7 8.60* 20.47 5 -8 -6 37.31 37.55 5 -8 -5 31.32 35.73 5 -8 -4 9.53* 6.70 5 -8 -3 70.89 71.81 5 -8 -2 32.15* 38. 19 5 -8 -1 30.95* 9.40 5 -8 0 4 6.11 62.26 5 -8 1 79. 38 74.34 5 -8 2 27.81* 1 1.28 5 -8 3 48.57 55.20 5 -8 4 30.76* 31.47 5 -8 5 22.4 1* 9.90 5 -8 6 6.51* 9.61 6 -8 -10 28. 39 19. 16 6 -8 -9 7.71* 8.41 6 -8 -8 32. 10 21.78 6 -8 -7 57.96 52.67 6 -8 -6 38.03 32.76 6 -8 -5 36.69 33.76 6 -8 -4 50. 34 46. 80 6 -8 -3 34.47 19.35 6 -8 -2 0.00* 8.71 6 -8 -1 0.00* 7.20 6 -8 0 44.50 37.80 6 -8 1 39.53* "17.88 6 -8 2 34.88* 30.88 6 -8 3 53.93 58.77 6 -8 4 22.64* 6.52 6 -8 5 31.30* 20. 17 7 -8 -10 17.38* 8. 85 7 -8 -9 36.43 33.37 7 -8 -8 31.71 38.65 7 -8 -7 24.03* 29.52 7 -8 -6 30.36* 28.00 7 -8 -5 95.03 87.93 7 -8 -4 51.25 46.36 7 -8 -3 19.07* 15.46 7 -8 -2 52.30 59.56 7 -8 -1 45.40 53. 18 7 -8 0 16.21* 5.04 H K L FO FC 7 -8 1 37.43* 53.41 7 -8 2 15.45* 14.02 7 -8 3 0.00* 12.20 7 -8 4 0.00* 3.86 8 -8 -9 31.10 22. 16 8 -8 -8 8.42* 13.98 8 -8 -7 74.90 70.27 8 -8 -6 51.85 52.42 8 -8 -5 24.66* 3. 11 8 -8 -4 34.43* 33.34 8 -8 -3 40.01 37.40 8 -8 -2 32.90* 45.69 8 -8 -1 . 0.00* 23.64 8 -8 0 37.22* 36.53 8 -8 1 59.22 62.43 8 -8 2 24.42* 13.32 8 -8 3 23.79* 11.75 9 -8 -8 21.02* 26.84 9 -8 -7 33.52 24.81 9 -8 -6 17.71* 8.36 9 -8 -5 50. 89 44.85 9 -8 -4 66.42 60.07 9 -8 -3 48. 1 1 46. 15 9 -8 -2 27.45* 33.37 9 -8 -1 95. 12 94.73 9 -8 0 16.66* 29. 15 9 -8 1 0.00* 7.53 10 -8 -6 24.39* 27.65 10 -8 -5 26.98* 14.87 10 -8 -4 0.00* 2.33 10 -8 -3 26.46* 25.94 10 -8 -2 38.45* 37.90 0 -9 1 22.86* 25.12 0 -9 2 16.76* 17.09 0 -9 3 0.00* 3. 12 0 -9 4 31.71 37. 16 0 -9 5 56.50 54.28 0 -9 6 65. 92 57.59 0 -9 7 18.92* 13.43 1 -9 -7 85.08 78.43 1 -9 -6 18.14* 4.75 1 -9 -5 0.00* 10.75 1 -9 -4 16.39* 5.04 1 -9 -3 52. 40 49.48 1 -9 -2 20.72* 7.07 1 -9 -1 0.00* 6.69 1 -9 0 19.25* 19.64 1 -9 1 30.04* 39.05 1 -9 2 16.34* 9.03 1 -9 3 0.00* 2.69 1 -9 4 0.00* 3.03 1 -9 5 43.55 43.46 1 -9 6 0.00* 7.12 1 -9 7 15.89* 33.95 2 -9 -8 49.87 43.64 2 -9 -7 25.35* 26.11 2 -9 -6 43.09 41.74 2 -9 -5 66.01 54.54 H K L FO FC H K L FO FC 2 -9 -4 15.20* 14.95 5 -9 2 19.22* 12.36 2 -9 -3 24.70* 24.98 5 -9 3 60.16 66.81 2 -9 -2 24.28* 18.27 •5 -9 4 20.27* 9.21 2 -9 -1 71.33 65.82 6 -.9 -7 7.97* 5.47 2 -9 0 14.41* 17.75 6 -9 -6 30.78 19.18 2 -9 1 40.49 31.99 6 -9 -5 41.32 42.20 2 -9 2 45.33 41.75 6 -9 -4 33.91* 36.73 2 -9 3 43.49 41.34 6 -9 -3 10.77* 16.11 2 -9 4 42.83 47.40 6 -9 -2 49. 75 34.4 5 2 -9 5 20.15* 14.23 6 -9 -1 0.00* 19.94 2 -9 6 40.33 30.53 6 -9 0 38.73 26.57 3 -9 -8 21.21* 13.57 6 -9 1 46.57 38.51 3 -9 -7 42.68 42.03 6 -9 2 35.19* 32.49 3 -9 -6 0.00* 2.21 7 -9 -6 22.26* 0.68 3 -9 -5 26.12* 25. 84 7 -9 -5 27.60* 10.74 3 -9 -4 0.00* 2.55 7 -9 -4 0.00* 4.63 3 -9 -3 70.94 58.42 7 -9 -3 42. 35 39.44 3 -9 -2 34.42 23.03 7 -9 -2 6.36* 5.22 3 -9 -1 40.90* 47.90 7 -9 -1 30.56* 7.14 3 -9 0 19.23* 0.37 7 -9 0 24.07* 12.42 3 -9 1 43.09 32.22 0 -10 0 39.57 36.42 3 -9 2 0.00* 7.54 0 -10 1 9. 26* 7.40 3 -9 3 45.41 52.72 0 -10 2 10.14* 13.92 3 -9 4 11.87* 3.40 0 -10 3 13.54* 9.37 3 -9 5 52. 36 51.76 1 -10 -3 15.48* 16.65 4 -9 -8 43.72 34.89 1 -10 -2 31.31 24.97 4 -9 -7 35.59 29. 18 1 -10 -1 13.59* 11.83 4 -9 -6 0.00* 7.27 1 -10 0 43.85* 12.98 4 -9 -5 28.87 21.56 1 -10 1 41.34 33. 19 4 -9 -4' 29.39* 18. 80 1 -TO 2 0.00* 2.'60 4 -9 -3 54. 10 50.68 1 -10 3 5. 37* 14.76 4 -9 -2 28.48* 28. 18 2 -10 -3 28.47 18.96 4 -9 -1 23.97* 30.20 2 -10 -2 58.91 48.51 4 -9 0 41.86* 35.86 2 -10 -1 32.68* 24.89 4 -9 1 41.08* 45.08 2 -10 0 44.73* 23.56 4 -9 2 50.70 44.50 2 -10 1 31.55* 16.95 4 -9 3 39.94 43.55 2 -10 2 18.78* 17.26 4 -9 4 35.46 33. 1 1 3 -10 -3 30.62* 17.20 4 -9 5 41.88 44.80 3 -10 -2 30.59* 18.62 5 -9 -7 16.73* 18.49 3 -10 -1 3.02* 0.37 5 -9 -6 19.96* 3.30 3 -10 0 37.16* 13.33 5 -9 -5 23.09* 24.64 4 -5 5 77.04 76.62 5 -9 -4 19.44* 8.65 5 -5 -10 35.38 27.66 5 -9 -3 0.00* 7.4 0 6 -5 -13 107.56 109.68 5 -9 -2 24.37* 5.06 6 -5 -4 17.39* 12. 33 5 -9 -1 20.73* 16.35 8 -5 -6 75.60 79.70 5 -9 0 0.00* 8.38 8 -5 -5 86.74 83.54 5 -9 1 20.79* 12.34 8 -5 1 28.35* 19.79 i Dimethylammonium trichlorotris(dimethylsulphoxide)ruthenate(II) Anthony Mercer and James Trotter. Observed and calculated structure amplitudes (reflections with intensity < 3 (I) are marked with an asterisk). The following planes which had |Fo-Fc| > 3 (F) were given zero weight in the final stages of refinement due to suspected errors resulting from extinction, absorption, or instrument malfunction: h k 1 Fo Fc h k 1 Fo Fc 4 0 0 367.5 544.8 9 0 4 64. 8 92.0 2 4 0 45.8 6 0.4 12 0 4 54. 4 70.2 1 9 0 1 50. 0 66.3 3 0 5 96. 3 72.6 21 0 1 52.4 66.0 2 3 5 63.0 44.3 2 1 1 303.9 494. 4 8 0 7 37. 9 18.6 10 0 2 113.6 142.5 10 6 7 28. 2 11.2 17 1 2 26.2 8.7 19 0 8 74. 9 90. 8 14 0 3 77.4 94.4 0 1 9 61.4 42. 1 4 0 4 43.8 62. 2 1 0 14 38. 4 4, 1 H K L FO FC H K L FO FC 6 0 0 0. 00* 1 10.09 8 4 0 131.65 133.23 8 0 0 292.18 309.19 10 4 0 115.25 117.86 10 0 0 35 7. 89 400.62 12 4 0 17.30* 13. 80 12 0 0 164.03 172.55 14 4 0 236.08 227.54 14 0 0 252. 85 262.08 16 4 0 13 8. 41 131. 62 16 0 0 116.78 116. 14 18 4 0 40. 71 33* 32 18 0 0 137.67 144.95 20 4 0 47. 00 46, 67 20 0 0 102.57 93.97 22 4 0 82. 17 79. 88 22 0 0 146. 10 143. 18 24 4 0 47. 84 46. 87 24 0 0 96.27 94.51 26 4 0 9. 70* 2. 52 26 0 0 59.84 56. 50 2 5 0 65.76 57. 87 28 0 0 44. 54 46.22 4 5 0 97. 16 91.92 2 1 0 140.02 150.64 6 5 0 62. 21 5 2- 25 4 1 0 54. 74 55. 32 8 5 0 62. 97 60. 92 6 1 0 73. 35 67.32 10 5 0 172.78 157.77 8 1 0 91.36 79.80 12 5 0 103.32 105. 58 10 1 0 257.53 242.48 14 5 0 110.74 105.40 12 1 0 63. 03 63. 43 16 5 0 37. 13 38.44 14 1 0 134.59 122-02 18 5 0 31. 78 26. 18 16 1 0 38.09 38. 47 20 5 0 59. 76 62.20 18 1 0 88.24 87.76 22 5 0 53. 83 50.66 20 1 0 70. 99 73.78 24 5 0 97.50 96. 92 22 1 0 65.45 64.81 0 6 0 361. 13 328. 04 24 1 0 145.46 142. 13 2 6 0 151.22 137.90 26 1 0 44. 64 46.54 4 6 0 232,35 213.43 28 1 0 105.82 102.62 6 6 0 38. 81 43.09 0 2 0 279.75 285.41 8 6 0 196.51 185.64 2 2 0 10.37* 10. 17 10 6 0 166.85 165.58 4 2 0 114.75 91.52 12 6 0 179.29 172.33 6 2 0 78. 07 64.51 14 6 0 188. 81 188. 30 8 2 0 56.75 48. 25 16 6 0 35.28 34. 23 10 2 0 129.18 132-94 18 6 0 83-81 84- 63 12 2 0 52. 38 55.30 20 6 0 45. 45 41-39 14 2 0 215.50 213.85 22 6 0 113-77 11 1. 54 16 2 0 90.67 91.94 24 6 0 66. 05 64.72 18 2 0 43.02 44.01 2 7 0 36. 45 35.72 20 2 0 77. 98 79.82 4 7 0 22. 99* 21- 19 22 2 0 88.23 82-33 6 7 0 38. 03 3 5-37 24 2 0 34. 42 37. 87 8 7 0 0. 00* 2. 40 26 2 0 16.41* 24.22 10 7 0 86.30 87- 34 28 2 0 26.86* 26. 45 12 7 0 36. 32 39. 05 2 3 0 40.60 31.19 14 7 0 93. 13 92-75 4 3 0 114.48 1 15.34 16 7 0 0.00* 7. 15 6 3 0 65.86 78. 88 18 7 0 39. 41 43-87 8 3 0 49.02 51.73 20 7 0 51. 49 45. 09 10 3 0 124.48 141.70 0 8 0 173-56 170. 81 12 3 0 118.97 127.58 2 8 0 48.31 50.66 14 3 0 99.49 107.51 4 8 0 90. 15 96. 66 16 3 0 52. 22 50.01 6 8 0 28. 87 25. 12 18 3 0 49. 97 51.29 8 8 0 61.40 62. 85 20 3 0 38. 53 34. 62 10 8 0 106.07 103.22 22 3 0 28.89 24.92 12 8 0 50. 41 50. 24 24 3 0 125.42 120.27 14 8 0 97. 74 91.09 26 3 0 76.50 76.89 16 8 0 0. 00* 18. 24 28 3 0 66. 03 61. 56 18 8 0 37. 85 40-71 0 4 0 284.46 271.97 2 9 0 24.02* 19.53 4 4 0 211.21 205.48 4 9 0 47.77 44- 88 6 4 0 48. 24 59.07 6 9 0 63. 52 59.39 H K L FO FC H K L FO FC 8 9 0 19.56* 13.50 24 •j 1 71.84 66.55 10 9 0 66.79 65. 47 25 1 1 85.04 83. 46 12 9 0 40. 60 44.61 26 1 1 50.78 4 7. 98 14 9 0 50.58 47.37 27 1 1 2.84* 14, 11 0 10 0 145.77 137.79 28 1 1 23.71* 21. 83 2 10 0 87. 15 87.78 29 1 1 26.18* 29.38 4 10 0 76. 94 74.93 1 2 1 39.19 42. 00 6 10 0 6.59* 9. 11 2 2 1 31.80 36.09 8 10 0 42.59 41.70 3 2 1 140.17 129.51 2 0 1 12.29* 26.69 4 2 1 38.57 29- 47 3 0 1 64.43 77. 13 5 2 1 42. 33 38. 44 4 0 168.74 174.69 6 2 1 59.64 55. 91 5 0 0.00* 47.73 7 2 1 74.94 63.93 6 0 1 138.63 127. 14 8 2 1 40.63 37. 71 7 0 1 102.01 106.93 9 2 1 37.81 37.60 8 0 1 114. 11 142-65 10 2 1 101.01 102.72 9 0 1 247.89 246.95 11 2 1 31.99 31. 09 10 0 1 61.21* 89.66 12 2 1 160.54 164. 32 11 0 1 0. 00* 44.38 13 2 1 62.77 58. 46 12 0 1 212.09 213.91 14 2 1 55.43 58- 24 13 0 1 125.26 127.32 15 2 1 25.54 27.27 14 0 1 0. 00* 27-39 16 2 1 31.04 35. 09 15 0 1 32.04* 35.45 17 2 1 51.28 52- 09 16 0 1 44.04 47. 13 18 2 1 25.77 19.66 17 0 1 73.46 77. 51 19 2 1 11.35* 5- 89 18 0 1 5.24* 42- 14 20 2 1 22.64* 21. 29 20 0 1 103.73 101-38 21 2 1 32.28 30.42 22 0 1 65.75 71. 92 22 2 1 63. 43 56. 76 23 0 1 51.68 53. 28 23 2 1 35.07 34.93 24 0 1 0. 00* 10. 15 24 2 1 75.67 71. 90 25 0 1 46. 88 50.09 25 2 1 33.72 33. 35 26 0 1 1 17.61 116.36 26 2 1 117.75 111.64 27 0 1 0. 00* 51. 17 27 2 1 16.35* 25- 80 28 0 1 0. 00* 0.92 28 2 1 48.37 45. 83 29 0 1 46.93 48-95 0 3 1 50,16 3 6. 05 0 1 1 193.85 192.75 1 3 1 84.12 84.90 1 1 1 221.24 255.31 2 3 1 166-07 144.54 3 1 1 170. 99 185.76 3 3 1 137.12 125,81 4 1 1 28. 19 29.28 4 3 1 20.88 32.61 5 1 1 114.80 103.90 5 3 1 17-56* 14. 64 6 1 1 120.08 128. 19 6 3 1 155.04 160.77 7 1 1 1 14.27 123.66 7 3 1 61.37 56- 83 8 1 1 117.49 100.72 8 3 1 17.37* 29-34 9 1 1 161.64 162.22 9 3 1 58.84 49.34 10 1 1 163.26 160.74 10 3 1 118.53 11 7. 10 11 1 1 160.31 158-22 11 3 1 99.48 100.63 12 1 1 199.66 193.65 12 3 1 156.86 160.54 13 1 1 149.13 142.71 13 3 1 67.78 67. 40 14 1 1 49. 02 47.33 14 3 1 118.70 121. 61 15 1 1 88. 17 87.97 15 3 1 39.76 38.71 16 1 1 120.08 114.65 16 3 1 99.61 10 0.40 17 1 1 47.56 45. 47 17 3 1 77.78 79.90 18 1 1 38.7 5 35.38 18 3 1 92.84 94- 75 19 1 1 82.87 77.04 19 3 1 19.86* 16. 18 20 1 1 78. 80 77.76 20 3 1 68.11 63. 27 21 1 1 66.64 63. 60 21 3 1 22. 88* 20. 90 22 1 1 34.02 27.97 22 3 1 23.43* 22. 62 23 1 1 66. 16 65.66 23 3 1 12.07* 1 8. 42 H K L FO FC 24 3 1 57.01 54.78 25 3 1 33.87 30.56 26 3 1 23.78* 17.91 27 3 1 41.21 32.33 1 4 1 126.27 101.88 2 4 1 110.04 97.45 3 4 1 45.54 46. 18 4 4 1 94.79 89.95 5 4 1 33.58 33.35 6 4 1 47.91 46.03 7 4 1 66.47 62-22 8 4 1 90.19 89-94 9 4 1 24.62 21- 26 10 4 1 112.93 110.03 11 4 1 16.24* 13. 39 12 4 1 139.79 131-36 13 .4 1 90.96 87.38 14 4 1 48.74 37.74 15 4 1 32-90 34-77 16 4 1 70.49 60.07 17 4 1 42-08 43- 14 18 4 1 33.44 31-64 19 4 1 26.60 23-56 20 4 1 6.81* 8. 34 21 4 1 0.00* 4.89 22 4 1 63.43 61.60 23 4 1 77.11 73.75 24 4 1 26. 69* 29. 18 25 4 1 25. 90* 24- 40 26 4 1 78.47 74.70 0 5 1 117.30 106.97 1 5 1 160.52 141.69 2 5 1 236.35 231. 18 3 5 1 99.69 91.52 4 5 1 51.37 46.25 5 5 1 78.57 78.91 6 5 1 90.05 99.73 7 5 1 85.26 78.66 8 5 1 48.44 41.30 9 5 1 51.04 51.90 10 5 1 93.3 9 94-81 11 5 1 146.23 140.84 12 5 1 159.73 149.62 13 5 1 76.61 79. 29 14 5 1 103.53 105.38 15 5 1 88.83 86.34 16 5 1 110.14 107.17 17 5 1 30.68 34.23 18 5 1 39.24 40.79 19 5 1 20.35* 20.09 20 5 1 66.52 65. 44 21 5 1 76-71 74.34 22 5 1 33.33 29.76 23 5 1 51.26 50.66 24 5 1 52.78 52-77 25 5 1 37.85 37.69 1 6 1 101.07 85.87 2 6 1 53.18 52.21 H K L FO FC 3 6 1 42.27 33. 69 4 6 1 66.15 67. 21 5 6 1 55.70 49- 47 6 6 1 20.26* 26. 88 7 6 1 64.73 60-06 8 6 1 77.15 73.71 9 6 1 40.78 38.33 10 6 1 65. 16 68. 01 11 6 1 39.03 37. 50 12 6 1 106. 16 106.43 13 6 1 61.90 63. 06 14 6 1 40.83 48. 09 15 6 1 33.18 29.03 16 6 1 72.31 72. 27 17 6 1 63. 82 62. 57 18 6 1 21.77* 22. 02 19 6 1 25.12* 24- 46 20 6 1 37.96 35.60 21 6 1 51.89 53- 56 22 6 1 56.82 54. 45 23 6 1 48.42 4 9-97 0 7 1 87.66 85. 45 1 7 1 158.20 146- 00 2 7 1 124.01 108.57 3 7 1 101.39 90.23 4 7 1 15.62* 7.46 5 7 1 88.99 84. 11 6 7 1 66. 1 1 57. 22 7 7 1 67.88 64. 16 8 7 1 26.22 26. 03 9 7 1 93.09 86. 99 10 7 1 82.22 77. 31 11 7 1 105.82 100.77 12 7 1 95.25 95. 08 13 7 1 60.75 58. 81 14 7 1 55.29 52- 08 15 7 1 76.38 75. 17 16 7 1 59.20 55- 45 17 7 1 22.95* 20. 86 18 7 1 37.25 i 3 2. 92 19 7 1 44.43 43. 10 20 7 1 49.62 45. 63 21 7 1 46.92 45.50 1 8 1 18.60* 15. 08 2 8 1 27.51 27. 32 3 8 1 41.10 37. 80 4 8 1 42.41 35. 53 5 8 1 0.00* 3- 84 6 8 1 36.93 3 1. 20 7 8 1 20.62* 14.92 8 8 1 33.77 31.61 9 8 1 28.13 25. 22 10 8 1 37.32 34. 84 11 8 1 21.18* 3. 98 12 8 1 75.47 71.81 13 8 1 31.84 30.38 14 8 1 32.98 31. 63 15 8 1 15.06* 17-08 H K L FO FC H K L FO FC 16 8 1 43.56 39.94 2 ! 2 47. 90 43.27 17 8 1 18.00* 17.28 3 1 2 45.72 47.69 18 8 1 29. 98 29.47 4 1 2 102.73 94. 27 19 8 1 0.00* 0. 78 5 1 2 17.63* 17.91 0 9 1 68.21 64.56 6 1 2 64. 10 59.76 1 9 1 62. 16 60.64 7 1 2 134.22 128. 19 2 9 1 155.77 149.54 8 1 2 77.55 72. 46 3 9 1 53.56 53. 15 9 1 2 78.95 77. 94 4 9 1 22.26* 10.73 10 1 2 184. 34 175.46 5 9 1 31. 33 25.35 11 1 2 164.60 161.03 6 9 1 94. 14 91.56 12 1 2 172.26 163.01 7 9 1 27.88* 28.98 13 1 2 43. 17 42- 04 8 9 1 37.54 36.46 14 1 2 74.62 64. 15 9 9 1 39.21 37.60 15 1 2 93. 33 9 2. 27 10 9 1 55.43 52. 53 16 1 2 13.63* 1 4. 50 11 9 1 48.76 48.62 18 1 2 41.79 40. 66 12 9 1 90.28 89. 13 19 1 2 101.68 99. 13 13 9 1 45.90 46.68 20 1 2 16.22* 2. 48 14 9 1 21.05* 17. 28 21 1 2 53.32 4 7. 03 15 9 1 24.01* 15.75 22 1 2 36.46 39.01 1 10 1 12.40* 9. 19 23 1 2 71. 09 68. 08 2 10 1 12.27* 17.35 24 1 2 56.37 54. 47 3 10 1 21.75* 18.61 25 1 2 49. 90 48. 69 4 10 1 49.95 49.99 26 1 2 67.49 65. 99 5 10 1 15.53* 8. 22 27 1 2 41.61 40. 95 6 10 1 24.00* 25.51 28 1 2 25. 05* 23. 84 7 10 1 0. 00* 10.61 0 2 2 92. 74 80.68 8 10 1 59.22 53.78 1 2 2 217.23 205.98 9 10 1 31. 23 29. 92 2 2 2 67. 14 76, 86 0 0 2 202.12 187.70 3 2 2 128.25 136,10 1 0 2 300.48 348.79 4 2 2 85. 81 74-59 2 0 2 268.97 306.24 5 2 2 31.69 3 6.49 3 0 2 106.50 104.01 6 2 2 86. 41 94. 00 4 0 2 136.94 135.31 7 2 2 7. 72* 9.77 5 0 2 0. 00* 55.72 8 2 2 46. 67 37. 77 6 0 2 101.62 105.74 9 2 2 102.01 108. 29 7 0 2 0. 00* 17.04 10 2 2 37. 77 3 9.05 8 0 2 0.00* 20.33 11 2 2 113.43 114.29 9 0 2 252.84 253.45 12 2 2 79.01 79. 96 11 0 2 224.22 218.21 13 2 2 173.45 172.47 12 0 2 9.39* 71. 13 14 2 2 101.27 95. 23 13 0 2 124.27 121.63 15 2 2 13.21* 9.74 14 0 2 6. 65* 50.32 16 2 2 107. 12 105.60 15 0 2 88.28 93.83 17 2 2 97.51 95. 44 16 0 2 93. 53 95. 28 18 2 2 56. 13 52.70 17 0 2 7.21* 35.58 19 2 2 39.87 36. 96 18 0 2 18.33* 25.99 20 2 2 63. 17 61. 66 19 0 2 21.91* 31.61 21 2 2 47. 98 44. 59 20 0 2 60.55 61.22 22 2 2 34. 29 32.73 21 0 2 23.06* 34. 35 23 2 2 105.26 97.38 22 0 2 0.00* 28. 16 24 2 2 36. 15 34.90 23 0 2 86.35 82.63 25 2 2 22.43* 10. 83 24 0 2 0. 00* 34. 14 26 2 2 10.29* 13- 17 25 0 2 21.94* 32.53 27 2 2 69.92 62. 66 26 0 2 0.00* 16. 11 28 2 2 34. 10 30.27 27 0 2 57. 92 55.47 1 3 2 146.47 129.72 28 0 2 0.00* 14. 88 2 3 2 1 13.62 98-91 1 1 2 121.56 116.84 3 3 2 158.00 140. 47 H K L FO 4 3 2 151.98 5 3 2 144.25 6 3 2 50. 26 7 3 2 53.88 8 3 2 123.37 9 3 2 84.30 10 3 2 78. 83 11 3 2 71.64 12 3 2 58. 97 13 3 2 45.52 14 3 2 55.55 15 3 2 70.50 16 3 2 11.28* 17 3 2 29.43 18 3 2 52.29 19 3 2 70.92 20 3 2 17.98* 21 3 2 58.87 22 3 2 66.37 23 3 2 27.60* 24 3 2 55.54 25 3 2 54. 10 26 3 2 85.33 27 3 2 26.18* 0 4 2 2 10.64 1 4 2 192.66 2 4 2 103.83 3 4 2 208.94 4 4 2 73. 38 5 4 2 77.28 6 4 2 22.48* 7 4 2 44. 50 8 4 2 73.22 9 4 2 133.87 10 4 2 24. 71 11 4 2 101. 12 12 4 2 96. 17 13 4 2 195.25 14 4 2 73. 14 15 4 2 53.26 16 4 2 63.04 17 4 2 57. 35 18 4 2 53. 49 19 4 2 38. 41 20 4 2 55. 93 21 4 2 42. 46 22 4 2 64.36 23 4 2 97.43 24 4 2 39.56 25 4 2 44.75 26 4 2 7. 95* 1 5 2 106.19 2 5 2 75.56 3 5 2 90. 43 4 5 2 87.60 5 5 2 85.62 6 5 2 102.82 7 5 2 21.33* FC H 140.51 8 120.48 9 37.92 10 51. 85 11 126.51 12 79.93 13 84.99 14 71.87 15 63.81 16 43.40 17 54. 02 18 69. 15 19 21. 48 20 30.43 21 43.27 22 68.59 23 12.62 24 56.20 25 60.30 0 27. 45 1 49.74 2 51.49 3 81.45 4 25.67 5 207.61 6 171. 45 7 112.56 8 191.47 9 78.73 10 77.78 11 27. 13 12 45.30 13 75.78 14 133.83 15 15.70 16 95.95 17 93.31 18 187.89 19 66.09 20 47.91 21 61.34 22 54.47 23 48.21 1 39,73 2 52.95 3 41.85 4 64.08 5 94.95 6 38.80 7 42. 87 8 14.92 9 104.09 10 65. 81 11 85.33 12 76.69 13 84. 10 14 93. 15 15 19.35 16 K L FO FC 5 2 65.44 59. 81 5 2 27. 44 30. 11 5 2 102. 30 92- 62 5 2 99. 84 90. 57 5 2 102.54 97. 97 5 2 37. 11 38. 11 5 2 41. 57 43. 27 5 2 75.40 67. 82 5 2 4 3. 81 41. 05 5 2 10.76* 17- 49 5 2 14.53* 1-98 5 2 33.50 31. 58 5 2 12.03* 8. 43 5 2 70.68 63. 19 5 2 25.98* 24. 57 5 2 40.45 39. 16 5 2 31. 41 29. 08 5 2 70. 16 6 2. 70 6 2 57. 30 56. 99 6 2 149.48 133- 08 6 2 196.24 172. 04 6 2 130.88 123. 13 6 2 77.82 75. 02 6 2 49.76 45. 95 6 2 106.32 91. 87 6 2 62.95 65. 37 6 2 80.71 82. 46 6 2 113.29 107. 73 6 2 79. 05 74. 25 6 2 1 15.92 115. 14 6 2 122.46 121. 51 6 2 146. 19 144. 87 6 2 6. 91* 20, 48 6 2 38. 62 38. 23 6 2 92.79 9 2. 48 6 2 18.55* 19. 46 6 2 17,05* 19. 71 6 2 25.78* 22. 76 6 2 86. 22 81. 29 6 2 26.97* 29. 93 6 2 0. 00* 7. 72 6 2 75.40 71. 74 7 2 55. 04 54- 60 7 2 21.69* 15. 84 7 2 61. 65 57. 83 7 2 72. 55 68. 58 7 2 50. 13 48. 67 7 2 33. 90 33. 10 7 2 20. 97* 13. 44 7 2 50. 67 47. 64 7 2 33. 11 33. 10 7 2 30. 05 31. 60 7 2 52. 88 50. 97 7 2 84.73 80-75 7 2 23.55* 19-78 7 2 23.28* 20. 50 7 2 58. 45 57. 23 7 2 24.20* 15. 57 ( H K L FO FC H K L FO FC 17 7 2 0.00* 1 1. 77 12 0 3 45.42 61. 89 18 7 2 28.29* 31. 13 13 0 3 95. 86 10 2- 55 19 7 2 60. 82 57-81 15 0 3 70.33 67. 17 20 7 2 21.28* 8. 96 16 0 3 0- 00* 14. 87 21 7 2 16.55* 13.82 17 0 3 99. 64 100.97 0 8 2 79. 06 81.00 18 0 3 0. 00* 25. 69 1 8 2 1 10.97 100.89 19 0 3 46. 50 49. 05 2 8 2 30.06 28.66 20 0 3 39.96 42. 38 3 8 2 43.-47 39.32 21 0 3 46. 04 50. 51 4 8 2 54.92 56.56 22 0 3 0. 00* 3. 66 5 8 2 52. 84 52.96 23 0 3 0. 00* 23. 52 6 8 2 11.54* 9-26 24 0 3 7 0. 44 67. 95 7 8 2 29. 57 32. 44 25 0 3 0. 00* 15. 57 8 8 2 51.85 54. 21 ' 26 0 3 0. 00* 9.80 9 8 2 80- 35 77-44 27 0 3 0. 00* 1- 18 10 8 2 23.62* 21.78 28 0 3 42.31 42. 08 11 8 2 72.70 68. 81 0 1 3 195.60 208. 83 12 8 2 36. 98 28.24 1 1 3 77. 36 89.91 13 8 2 74.93 70. 12 2 1 3 54. 44 54. 40 14 8 2 60.51 60. 23 3 1 3 27.34 24. 48 15 8 2 29. 86 25. 19 4 1 3 81.89 78. 56 16 8 2 38. 48 33.37 5 1 3 160.63 148.98 17 8 2 50.28 50-36 6 1 3 113.86 117-24 18 8 2 38.47 37.25 7 1 3 128.78 109.38 1 9 2 25.59* 33.23 8 1 3 183.44 170. 18 2 9 2 29.99 27. 00 9 1 3 87.86 76. 15 3 9 2 27.23* 28. 48 10 1 3 99.90 91.98 4 9 2 23.43* 21.34 11 1 3 1 10.21 102.76 5 9 2 15.33* 12. 63 12 1 3 96.58 90. 69 6 9 2 42. 80 37-63 13 1 3 20.98* 29. 04 7 9 2 40. 41 38-31 14 1 3 160.64 153. 21 8 9 2 31. 20 35.51 15 1 3 70.27 64,73 9 9 2 15.57* 23. 27 16 1 3 86.21 81.56 10 9 2 67.74 65. 44 17 1 3 38. 26 32- 02 11 9 2 70.73 66.59 18 1 3 60. 29 55, 84 12 9 2 27.80* 30. 42 19 1 3 21.43* 17.20 13 9 2 29.95 24. 17 20 1 3 57. 15 54. 10 14 9 2 54.63 54-44 21 1 3 51. 00 48. 42 0 10 2 92. 13 90-78 22 1 3 98.64 92. 81 1 10 2 101.46 97.99 23 1 3 0. 00* 10. 43 2 10 2 37. 46 31. 18 24 1 3 37.77 31. 88 3 10 2 58. 62 55.76 25 1 3 58. 35 53. 84 4 10 2 62. 39 59-91 26 1 3 17.84* 25. 81 5 10 2 60.66 59.65 27 1 3 52.48 49. 84 6 10 2 14.96* 20-08 28 1 3 6.47* 18. 89 7 10 2 41.82 39. 19 1 2 3 110.58 105. 54 8 10 2 34.44 38. 26 2 2 3 73.40 84- 14 1 0 3 0.00* 29.38 3 2 3 145. 15 133.60 2 0 3 82.54 80. 40 4 2 3 133.54 131. 22 3 0 3 85.86 82.08 ' 5 2 3 66.46 65.71 4 0 3 90.57 85.26 6 2 3 85.64 85. 39 5 0 3 0. 00* 26. 58 7 2 3 74. 56 66.39 6 0 3 0.00* 6.48 8 2 3 60. 85 59. 04 7 0 3 81.54 89.95 9 2 3 48. 32 51.39 8 0 3 0- 00* 66. 84 10 2 3 165.23 155.51 9 0 3 0.00* 119. 14 11 2 3 52. 80 58- 06 10 0 3 244.73 239.60 12 2 3 42.53 41. 23 11 0 3 0.00* 69. 57 13 2 3 71.86 69. 21 H K 1 FO FC EI K L FO FC 14 2 3 72.02 73.02 16 4 3 38.01 39. 56 15 2 3 40. 15 42.77 17 4 3 51-30 52.79 16 2 3 95. 97 88. 57 18 4 3 23. 45* 29. 83 17 2 3 98.26 95.71 19 4 3 14. 31* 18. 90 18 2 3 19.92* 15. 34 20 4 3 30.34 26. 98 19 2 3 61.65 57.98 21 4 3 0. 00* 17. 94 20 2 3 77. 47 69.77 22 4 3 34.68 32. 70 21 2 3 62.05 56. 16 23 4 3 41. 65 44.93 22 2 3 30. 04 25.65 24 4 3 96.32 101. 37 23 2 3 34. 26 31.77 25 4 3 13.88* 22.26 24 2 3 118.06 108.38 26 4 3 13.86* 6. 58 25 2 3 28.59* 25.62 0 5 3 228.38 236.92 26 2 3 41. 86 37. 45 1 5 3 90.58 87. 72 27 2 3 25.73* 26.87 2 5 3 29. 06 20.90 28 2 3 52. 56 49.66 3 5 3 69. 62 66-39 0 3 3 434.78 440.67 4 5 3 106,31 117. 17 1 3 3 137.48 133.09 5 5 3 45.91 42.82 2 3 3 198.28 208.75 6 5 3 13.26* 11- 69 3 3 3 50.96 58.97 7 5 3 100.34 95.51 4 3 3 201.21 197.81 8 5 3 112.32 117.60 5 3 3 56.80 55.30 9 5 3 47. 22 48. 70 6 3 3 103.78 116.40 10 5 3 88.68 88. 18 7 3 3 88.67 99.83 11 5 3 93.36 91. 66 8 . 3 3 96.73 97.72 12 5 3 102.84 107.08 9 3 3 49.04 42.40 13 5 3 31.74 33.21 10 3 3 160.55 177.37 14 5 3 103. 28 102-98 11 3 3 119.96 135.02 15 5 3 42. 21 4 3. 27 12 3 3 142.58 148.56 16 5 3 0. 00* 10. 63 13 3 3 8. 04* 4.29 17 5 3 28- 00 29. 08 14 3 3 180.90 196.05 18 5 3 44. 36 47. 16 15 3 3 128.55 137.43 19 5 3 3. 57* 14. 58 16 3 3 0.00* 8.83 20 5 3 2.66* 12- 02 17 3 3 6.64* 14.24 21 5 3 33. 09 39.67 18 3 3 70.56 73.21 22 5 3 104. 05 106. 91 19 3 3 51.93 56.98 23 5 3 21.79* 18. 72 20 3 3 33.47 35.01 24 5 3 23.21* 23. 68 21 3 3 65. 12 66. 14 25 5 3 34.98 31. 84 22 3 3 137.01 143.78 1 6 3 105. 04 97. 20 23 3 3 16.25* 18.65 2 6 3 46.54 45. 84 24 3 3 40. 74 50.55 3 6 3 111. 53 108. 09 25 3 3 74.70 73.52 4 6 3 76. 14 78. 55 26 3 3 26.01* 22.31 5 6 3 72. 51 71.53 27 3 3 19.48* 21.42 6 6 3 84. 19 86. 62 1 4 3 125.46 126. 15 7 6 3 27. 42 23.62 2 4 3 86. 04 86.69 8 6 3 41.04 45. 55 3 4 3 127.25 130.83 9 6 3 18. 64* 22- 72 4 4 3 76. 43 80. 10 10 6 3 88.40 9 4. 23 5 4 3 76. 68 87. 19 11 6 3 27. 88 31. 81 6 4 3 127.40 129.78 12 6 3 21.22* 22.25 7 4 3 44. 28 48. 03 13 6 3 20.08* 27- 39 8 4 3 39.77 39.47 14 6 3 58. 12 62- 87 9 4 3 55. 89 52.37 15 6 3 24. 76* 20.97 10 4 3 100.59 100.82 16 6 3 31. 84 28.89 11 4 3 42.28 37.70 17 6 3 30.96 32. 09 12 4 3 24.60 23.82 18 6 3 27.29* 29. 26 13 4 3 59.74 58. 12 19 6 3 33.55 32-97 14 4 3 85.64 84.06 20 6 3 45. 47 45. 17 15 4 3 3.08* 10.54 21 6 3 26.30* 27- 57 H K L FO FC H K L FO FC 22 6 3 29.30 27.79 2 10 3 15.76* 21- 43 23 6 3 0.00* 3. 43 3 10 3 14.50* 17. 93 0 7 3 160.59 154.57 4 10 3 9. 24* 2 4- 36 1 7 3 46. 05 44. 73 5 10 3 19. 76* 2. 28 2 7 3 36. 52 34.59 6 10 3 20.24* 24. 22 3 7 3 51.01 54. 83 7 10 3 14.79* 7. 66 4 7 3 60.64 61.89 0 0 4 61. 50 61.92 5 7 3 34. 94 38.90 1 0 4 66. 14 66. 81 6 7 3 24.76* 30.72 2 0 4 20,19* 43. 32 7 7 3 21.12* 19.40 3 0 4 98. 05 94. 92 8 7 3 53.55 58.09 5 0 4 76.69 84. 89 9 7 3 52.87 54.02 6 0 4 24.64* 3 8. 90 10 7 3 71. 24 8 1. 23 7 0 4 93. 59 97- 84 11 7 3 18.95* 30. 14 8 0 4 144.03 148.69 12 7 3 35.69 36.29 10 0 4 101.52 121.77 13 7 3 49. 03 56.52 11 0 4 99. 20 110.92 14 7 3 81. 24 90.78 13 0 4 9,06* 34. 20 15 7 3 23.57* 31. 44 14 0 4 38. 98 41.36 16 7 3 13,03* 24.75 15 0 4 0. 00* 13. 07 17 7 3 47. 06 53. 87 16 0 4 39. 37 38. 81 18 7 3 38. 87 45.63 17 0 4 0. 00* 10. 62 19 7 3 17.60* 7.81 18 0 4 117.98 118.92 20 7 3 22.9 7* 9.88 19 0 4 30.45* 64.49 21 7 3 24.68* 22.96 20 0 4 45.97 56. 12 1 8 3 20.20* 24. 24 21 0 4 45. 26 52. 84 2 8 3 30.46 33.85 22 0 4 42.67 51. 05 3 8 3 30. 90 37.03 23 0 4 0. 00* 43. 53 4 8 3 30. 23 31.75 24 0 4 71. 19 78. 16 5 8 3 14.68* 21.59 25 0 4 0. 00* 28. 66 6 8 3 30.34 36.42 26 0 4 0. 00* 5. 80 7 8 3 11.75* 19.89 27 0 4 54. 81 5 1. 04 8 8 3 33.00 33.60 28 0 4 0. 00* 27. 75 9 8 3 29.93 30. 84 1 1 4 43. 54 43. 32 10 8 3 59.29 63.01 2 1 4 100. 10 101. 44 11 8 3 1. 11* 11. 49 3 1 4 142.58 146.00 12 8 3 48.45 49. 20 4 1 4 91.95 95. 18 13 8 3 43. 05 52. 19 5 1 4 60. 00 61. 98 14 8 3 22.00* 27. 4 2 6 1 4 50. 19 50. 12 15 8 3 24.25* 18.76 7 1 4 22. 19 17.77 16 8 3 23.95* 22-56 8 1 4 139.49 139.13 17 8 3 50.43 52. 42 9 1 4 63. 63 60.39 18 8 3 0.00* 20.43 10 1 4 84.62 85.51 0 9 3 91. 79 98. 47 11 1 4 54. 14 51. 62 1 9 3 64.92 66.96 12 1 4 109.92 110.69 2 9 3 83.58 86.98 13 1 4 76. 29 76. 69 3 9 3 86. 80 93. 98 14 1 4 0. 00* 7.36 4 9 3 38.60 44.00 15 1 4 71. 75 75- 88 5 9 3 41.38 40.98 16 1 4 32.85 35. 15 6 9 3 32.20 34.58 17 1 4 113.20 120.51 7 9 3 86. 00 92.30 18 1 4 45.75 44. 43 8 9 3 48.21 50. 63 19 1 4 78. 27 75. 44 9 9 3 34. 16 31.41 20 1 4 20.31* 19. 17 10 9 3 60. 57 65.86 21 1 4 63.03 6 2. 43 11 9 3 71.96 76.29 22 1 4 50.70 56. 55 12 9 3 46. 40 49.09 23 1 4 24.99* 17.88 13 9 3 42.34 48.89 24 1 4 48.93 4 9. 93 14 9 3 56.85 60.24 25 1 4 32. 15 32. 66 1 10 3 16.80* 19. 03 26 1 4 47.71 50. 19 H K L FO FC H K L FO FC 27 1 4 13.82* 7.84 2 4 4 245.72 252. 13 28 1 4 32. 59 29.66 3 4 4 125. 89 120.33 0 2 4 173.00 182-37 4 4 4 95. 25 88. 06 1 2 4 156. 13 155.70 5 4 4 62. 17 59. 42 2 2 4 349.27 352-35 6 4 4 116. 41 127.70 3 2 4 144.01 144. 15 7 4 4 130.08 136. 14 4 2 4 98.40 107, 18 8 4 4 74. 67 73- 30 5 2 4 44. 17 57. 54 9 4 4 26. 14 20. 04 6 2 4 100.39 100.94 10 4 4 199.87 205.99 7 2 4 193.52 206.62 11 4 4 107.78 114.88 8 2 4 85. 12 91.66 12 4 4 156.89 16 4- 44 9 2 4 53. 8 2 50.6 2 13 4 4 60. 84 59. 34 10 2 4 132.77 135.63 14 4 4 115.34 120.03 11 2 4 141.75 150.40 15 4 4 74. 54 72. 47 12 2 4 215.81 225.53 16 4 4 76. 13 77. 19 13 2 4 17.56* 15.57 17 4 4 24.30* 15. 00 14 2 4 57. 49 59.78 18 4 4 27. 47 30. 52 15 2 4 126.70 132.81 19 4 4 25.23* 24. 12 16 2 4 108.4 1 1 12.32 20 4 4 91. 82 96.90 17 2 4 16.72* 7.71 21 4 4 64.51 64. 58 18 2 4 51.91 48.28 22 4 4 33.74 33. 30 19 2 4 44.43 48.77 23 4 4 46. 43 5 0. 59 20 2 4 90. 18 93-35 24 4 4 87.43 88. 69 21 2 4 68. 89 66.08 25 4 4 45. 48 46. 82 22 2 4 60.77 62.63 1 5 4 86. 33 97.99 23 2 4 0. 00* 3.04 2 5 4 46.73 47.72 24 2 4 83.94 85.35 3 5 4 105.07 109.08 25 2 4 57. 63 60. 92 4 5 4 52. 50 51.64 26 2 4 42. 63 41. 68 5 5 4 56.33 57. 93 27 2 4 24.42* 29.20 6 5 4 54.66 52. 85 1 3 4 147.81 133.31 7 5 4 29. 21 20.73 2 3 4 49.48 50. 45 8 5 4 74.67 75. 10 3 3 4 156.79 144.87 9 5 4 39. 15 38.37 4 3 4 129. 11 138.34 10 5 4 44. 01 42.71 5 3 4 102.08 97.53 11 5 4 56.71 . 60. 09 6 3 4 98.46 101.85 12 5 4 109.99 112.23 7 3 4 105.78 96. 10 13 5 4 27. 56 25.72 8 3 4 89, 03 92.65 14 5 4 4. 64* 10. 41 9 3 4 37. 37 4 2.43 15 5 4 16.90* 23. 49 10 3 4 32.70 35.09 16 5 4 54.76 56. 07 11 3 4 50.81 50.36 17 5 4 32. 52 30. 93 12 3 4 91.95 96. 31 18 5 4 21. 84* 15.46 13 3 4 49.22 53.32 19 5 4 36.07 37.21 14 3 4 64-69 60.39 20 5 4 44.97 45. 15 15 3 4 46.79 45. 43 21 5 4 19.73* 26- 47 16 3 4 47.99 48. 37 22 5 4 45. 45 43. 71 17 3 4 94. 36 93.60 23 5 4 16.21* 10. 78 18 3 4 80.45 83.39 24 5 4 7. 86* 4. 63 19 3 4 31.82 29.43 0 6 4 18.41* 14.64 20 3 4 41.56 44. 17 1 6 4 41. 95 39.79 21 3 4 48.76 46.75 2 6 4 98. 38 97.21 22 3 4 98.54 96.92 3 6 4 56. 95 61- 98 2 3 3 4 45.05 45.70 4 6 4 32. 46 24. 48 24 3 4 37. 51 38.25 5 6 4 39.98 37-91 25 3 4 35.94 32.44 6 6 4 55. 92 57. 97 26 3 4 76.82 75.58 7 6 4 74. 92 76. 92 0 4 4 132.40 122.97 8 6 4 22.94* 2 1. 90 1 4 4 79. 19 78.08 9 6 4 33.50 41.28 H K L FO FC H K L FO FC 10 6 4 65.26 66.55 8 9 4 40. 26 41- 56 11 6 4 68.51 78.06 9 9 4 10.19* 2 0. 59 12 6 4 69.06 71.77 10 9 4 33. 92 34. 44 13 6 4 29. 15 31.73 1 1 9 4 34. 01 37. 43 14 6 4 0. 00* 7. 17 12 9 4 54. 54 55. 61 15 6 4 51. 24 57. 60 13 9 4 34. 45 36. 16 16 6 4 18.04* 25. 53 0 10 4 59. 85 66. 86 17 6 4 9.49* 20.25 1 10 4 27.28* 31. 14 18 6 4 44.79 43.95 2 10 4 81.93 82. 22 19 6 4 0. 00* 4.80 3 10 4 26.30* 24. 21 20 6 4 31.09 33.34 4 10 4 27.47* 26. 67 21 6 4 48.03 47. 48 5 10 4 19.45* 18.77 22 6 4 31. 30 28.91 1 0 5 0. 00* 22. 48 1 7 4 32.95 36.80 2 0 5 37. 86 46. 40 2 7 4 40.66 40.95 4 0 5 150. 15 153-05 3 7 4 68.65 69.26 5 0 5 98.58 88. 92 4 7 4 53.99 55.27 6 0 5 77.55 75.61 5 7 4 45. 42 49.93 7 0 5 26. 55 36. 54 6 7 4 35. 87 33.88 8 0 5 91.39 82- 80 7 7 4 46. 84 50. 34 9 0 5 11.60* 17, 04 8 7 4 58. 01 61.14 10 0 5 0. 00* 10. 11 9 7 4 24.93* 30. 12 11 0 5 47.31 55. 74 10 7 4 38.76 37.03 12 0 5 54. 41 61. 95 11 7 4 0. 00* 6.53 13 0 5 16.65* 39.71 12 7 4 36.80 34. 42 14 0 5 0. 00* 35. 10 13 7 4 64. 04 66.09 15 0 5 73.39 75- 13 14 7 4 32. 61 30.77 16 0 5 0. 00* 19. 43 15 7 4 12.88* 13.59 17 0 5 128.18 129.02 16 7 4 26.76 28.52 18 0 5 0. 00* 9. 17 17 7 4 62.09 65.36 19 0 5 93. 04 93. 11 18 7 4 35.68 40. 49 20 0 5 0. 00* 39.21 19 7 4 21.45* 20.94 21 0 5 21.16* 30. 88 20 7 4 28. 13 24. 68 22 0 5 0. 00* 18, 47 0 8 4 1 13.29 109.67 23 0 5 21. 51* 24. 95 1 8 4 20.19* 21. 85 24 0 5 0. 00* 22. 13 2 8 4 77. 82 78.94 25 0 5 16.71* 2 0. 27 3 8 4 38. 10 35.26 26 0 5 35. 41 36. 29 4 8 4 53. 06 45.67 27 0 5 7.75* 23- 30 5 8 4 23.35* 19. 10 0 1 5 210. 91 207.60 6 8 4 19.98* • 18.30 1 1 5 139.50 133.82 7 8 4 58.27 60.02 2 1 5 45. 35 46. 12 8 8 4 58.40 52-89 3 1 5 105. 28 103- 93 9 8 4 34. 45 32.59 4 1 5 149.00 147.20 10 8 4 57.54 56.70 5 1 5 65. 31 61. 77 11 8 4 60.91 57. 40 6 1 5 73. 23 69. 04 12 8 4 87. 94 87-70 7 1 5 1 13-75 115.08 13 8 4 24.34* 23. 38 8 1 5 3 8.59 37. 44 14 8 4 35. 06 39-28 9 1 5 174.42 175.30 15 8 4 44. 44 42. 21 10 1 5 51.74 57. 03 16 8 4 51.99 54.21 11 1 5 29.89 33. 02 17 8 4 7. 71* 14.28 12 1 5 27. 11 29. 76 1 9 4 31.52 23. 61 13 1 5 129.56 135.20 2 9 4 14.59* 16.52 14 1 5 82. 01 81. 76 3 9 4 25.59* 28.03 15 1 5 43. 38 44.58 4 9 4 23.55* 34.97 16 1 5 88. 12 88.. 43 5 9 4 26.97* 30.52 17 1 5 54. 17 54. 61 6 9 4 24.57* 29.08 18 1 5 28.60 25. 68 7 9 4 0. 00* 12.23 19 1 5 36. 44 37. 15 H K L FO FC H K L FO FC 20 1 5 78. 67 7 4.54 24 3 5 0.00* 17. 45 21 1 5 0- 00* 21.35 25 3 5 44. 10 40. 62 22 1 5 84.42 84. 19 26 3 5 14.50* 6. 04 23 1 5 97. 96 98. 12 1 4 5 88.64 87.91 24 1 5 46. 84 48. 00 2 4 5 31. 34 32.38 25 1 5 6.61* 4. 34 3 4 5 88. 68 99.59 26 1 5 12.21* 10.33 4 4 5 17.70* 15.65 27 1 5 39. 85 41.84 5 4 5 77. 98 87. 17 1 2 5 129.97 119.02 6 4 5 48. 48 47. 64 2 2 5 84.20 78.77 7 4 5 0. 00* 10.32 3 2 5 132.26 131.89 8 4 5 50. 61 49. 71 4 2 5 87. 31 81.73 9 4 5 44. 93 39. 00 5 2 5 106.05 106.04 10 4 5 89.87 88. 62 6 2 5 102.27 106,59 11 4 5 75. 17 74.62 7 2 5 20.29* 14.21 12 4 5 78. 07 75.78 8 2 5 44.30 44.36 13 4 5 43. 92 43. 46 9 2 5 18.14* 26.60 14 4 5 48.00 47. 67 10 2 5 60. 08 61. 44 15 4 5 73. 93 74, 24 11 2 5 108.75 1 13.77 16 4 5 14.09* 6. 09 12 2 5 35.27 22.61 17 4 5 18. 85* 21.70 13 2 5 46. 32 43. 92 18 4 5 18.37* 17. 52 14 2 5 27. 87 25.20 19 4 5 94. 16 9 1. 86 15 2 5 129.58 132.41 20 4 5 20.77* 2 5. 50 16 2 5 63.4 3 60.34 21 4 5 7.83* 18. 44 17 2 5 38. 41 37.81 22 4 5 0. 00* 14. 03 18 2 5 39. 14 38.77 23 4 5 80.78 80. 52 19 2 5 129.63 125.80 24 4 5 37. 29 35.53 20 2 5 47.30 51.04 25 4 5 34. 91 35. 22 21 2 5 42. 28 39.67 0 5 5 107.60 107. 24 22 2 5 18.23* 21. 07 1 5 5 118.43 119.41 23 2 5 79.29 79.74 2 5 5 33. 43 32.75 24 2 5 29. 60 32.49 3 5 5 24. 19 2 6.. 12 25 2 5 67. 21 67. 22 4 5 5 86. 96 84. 16 26 2 5 0. 00* 18.71 5 5 5 99. 70 97. 19 27 2 5 51.06 52. 00 6 5 5 51. 66 54. 95 0 3 5 150.73 131.77 7 5 5 58. 53 50. 51 1 3 5 272.46 269.23 8 5 5 130.66 128.83 3 3 5 182.74 172.46 9 5 5 99.02 97. 23 4 3 5 45.45 34.52 10 5 5 11. 10* 13. 61 5 3 5 237.75 249.6 2 11 5 5 66.67 72.20 6 3 5 0.00* 33.33 12 5 5 87. 80 88, 42 7 3 5 41.51 37.09 13 5 5 84.20 82. 97 8 3 5 52.37 48.68 14 5 5 31. 00 28.76 9 3 5 280.92 298.85 15 5 5 20.63* 11.21 10 3 5 21.68* 20.53 16 5 5 36. 25 40. 23 11 3 5 167.24 160.70 17 5 5 32. 45 26. 78 12 3 5 51.10 48. 18 18 5 5 38. 40 41.36 13 3 5 238.51 247.81 19 .5 5 29. 16 28. 08 14 3 5 37.76 33.68 20 5 5 17.05* 18.73 15 3 5 77. 11 69.21 2.1 5 5 14. 11* 16.45 16 3 5 51. 47 49.06 22 5 5 37.44 34. 39 17 3 5 80. 84 87.73 23 5 5 82. 14 80. 51 18 3 5 36.49 33.68 1 6 5 52. 58 47.96 19 3 5 68.26 66. 14 2 6 5 29. 55 28. 10 20 3 5 30.63 28.72 3 6 5 67.52 61. 39 21 3 5 64.37 63.64 4 6 5 46. 94 49.77 22 3 5 27.40* 27.30 5 6 5 74. 42 64. 10 23 3 5 1 18.61 114.63 6 6 5 33.69 31. 87 H K L FO , FC 7 6 5 36. 23 38.48 8 6 5 54. 55 56. 14 9 6 5 36. 14 34.75 10 6 5 41. 53 46.62 11 6 5 52. 71 58. 81 12 6 5 24. 92* 27. 28 13 6 5 8. 55* 15.35 in 6 5 9. 91* 15.37 15 6 5 52. 09 58. 16 16 6 5 29. 86 25. 11 17 6 5 33. 29 35.93 18 6 5 22. 42* 18.28 19 6 5 71. 85 72.50 20 6 5 13. 97* 10.26 21 6 5 12. 92* 10.38 22 6 5 15. 76* 11.70 0 7 5 40. 65 42. 13 1 7 5 112. 73 1 12.02 2 7 5 16. 78* 18.76 3 7 5 37. 94 35. 65 4 7 5 5. 85* 9.75 5 7 5 76. 75 83.64 6 7 5 0. 00* 10.56 7 7 5 47. 76 49.72 8 7 5 21. 79* 20. 54 9 7 5 107. 25 112-61 10 7 5 27. 45 28. 16 11 7 5 71. 30 70. 68 12 7 5 12. 27* 9. 68 13 7 5 93. 29 101.94 14 7 5 35. 91 36.04 15 7 5 33. 81 34.58 16 7 5 27. 31 25. 23 17 7 5 14. 20* 25. 19 18 7 5 17. 54* 19. 37 19 7 5 29. 85 30. 49 1 8 5 48. 40 50. 74 2 8 5 43. 26 46.75 3 8 5 41. 23 44. 65 4 8 5 30. 50 31.23 5 8 5 52. 41 62. 90 6 8 5 35. 32 35.51 7 8 5 14. 05* 14.66 8 8 5 34. 28 39. 14 9 8 5 21. 58* 33. 25 10 8 5 26. 59 24. 84 11 8 5 54. 20 54.31 12 8 5 0. 00* 1.96 13 8 5 36. 06 39.51 14 8 5 24. 93* 24.77 15 8 5 61. 44 59. 80 16 8 5 12. 24* 9.48 0 9 5 22. 08* 19.02 1 9 5 96. 46 100.26 2 9 5 22. 17* 26.54 3 9 5 56. 90 62.81 4 9 5 26. 97* 30-91 5 9 5 52. 84 53. 82 H K L FO FC 6 9 5 18. 46* 22.78 7 9 5 37. 21 38-38 8 9 5 17. 58* 13.71 9 9 5 90. 86 89.28 10 9 5 28. 57 3 2. 72 11 9 5 56. 73 61.61 0 0 6 83. 97 86-33 1 0 6 89. 35 93. 46 2 0 6 136. 93 130. 41 3 0 6 31. 12 30, 01 4 0 6 24. 83* 24. 62 5 0 6 45, 41 44. 82 6 0 6 15- 88* 8. 68 7 0 6 75. 73 83- 41 8 0 6 8. 59* 5.90 9 0 6 31. 63 37. 21 10 0 6 0. 00* 18. 84 11 0 6 108, 73 117.53 12 0 6 12. 58* 25. 03 13 0 6 42. 85 50. 70 14 0 6 0. 00* 32.32 15 0 6 67. 68 67. 93 16 0 6 0. 00* 8. 92 17 0 6 0. 00* 1.33 18 0 6 34. 48 35.68 19 0 6 8. 39* 19. 16 20 0 6 0. 00* 14. 58 21 0 6 78. 90 94. 92 22 0 6 77. 48 91. 45 23 0 6 0. 00* 9.51 24 0 6 0. 00* 16. 90 25 0 6 68. 75 74. 06 26 0 6 0. 00* 24. 08 1 1 6 75. 09 82. 17 2 1 6 148. 32 142. 57 3 1 6 69. 92 83. 64 4 1 6 69. 97 72. 44 5 1 6 86. 49 93. 17 6 1 6 79. 97 90. 07 7 1 6 52. 20 58. 51 8 1 6 37. 93 33. 46 9 1 6 46. 49 49. 81 10 1 6 39. 52 45. 09 11 1 6 33. 27 40. 32 12 1 6 39. 16 38. 13 13 1 6 49. 13 46. 14 14 1 6 29. 69 30.63 15 1 6 14-58* 13- 25 16 1 6 33. 91 33. 86 17 1 6 99. 05 105. 07 18 1 6 30. 31 31.93 19 1 6 62. 91 64, 82 20 1 6 29. 98 34. 46 21 1 6 70. 69 73. 18 22 1 6 24. 89* 25.62 23 1 6 25. 22* 24. 14 24 1 6 39. 99 41. 65 25 1 6 41. 66 39.22 FO FC 14. 41* 23. 36 144. 55 155. 89 150. 52 153. 87 135. 36 133. 03 191. 25 200. 66 88. 96 87. 62 71. 81 80. 80 68. 01 71. 10 217. 17 239. 42 96. 63 103. 02 57. 36 60. 67 1 15. 08 119. 82 191. 66 203. 96 96. 95 96. 36 96. 15 97. 27 102. 19 100, 47 76. 38 76. 80 56. 34 56. 92 38. 99 42. 08 78. 34 81. 73 14. 91* 9. 66 i2. 35* 16. 76 84. 34 85. 70 66. 75 72. 61 41. 59 41. 31 25. 79* 16. 23 45. 92 48. 87 31. 19 29. 12 73. 07 69. 61 14. 25* 20. 70 122. 69 119. 82 14. 83* 12. 35 79. 57 72-24 33. 98 31. 04 50. 02 50. 07 19. 9 1* 23. 81 42. 91 49. 21 76. 28 77. 18 29. 83 26. 50 17. 10* 31. 27 65. 76 71. 71 41. 61 43. 25 17. 22* 16. 70 73. 50 78-37 102. 48 104- 57 18. 01* 11. 20 42. 19 43. 19 52. 69 55. 13 93. 95 95. 84 13. 02* 21. 61 25. 26* 26. 92 43. 64 42. 78 63. 43 62- 11 80. 25 85. 94 101. 93 107. 03 69. 54 68. 84 75. 47 76. 53 64. 13 68. 97 H K L FO FC 5 4 6 77.47 73. 23 6 4 6 20. 97* 18. 44 7 4 6 118. 04 119. 24 8 4 6 106.77 110. 89 9 4 6 30.75 23. 89 10 4 6 23.95* 21. 58 11 4 6 126.56 128. 10 12 4 6 87.23 90. 44 13 4 6 32. 56 36. 62 14 4 6 39.79 39. 30 15 4 6 63. 08 65. 40 16 4 6 17.67* 17. 62 17 4 6 18.85* 24. 07 18 4 6 30.39 24. 10 19 4 6 32.60 38. 48 20 4 6 17.53* 2 0. 60 21 4 6 75. 96 84. 15 22 4 6 35.46 36. 07 23 4 6 5. 94* 10. 58 24 4 6 30. 10 28. 71 1 5 6 16.42* 24. 91 2 5 6 14.13* 17, 03 3 5 6 39. 63 45. 73 4 5 6 18.46* 16. 07 5 5 6 35. 56 3 9, 68 6 5 6 38. 50 42. 94 7 5 6 37.91 37. 06 8 5 6 24.90* 31- 55 9 5 6 38.13 31. 66 10 5 6 45.34 51. 31 11 5 6 20.60* 24. 88 12 5 6 42. 37 38. 14 13 5 6 53.52 55. 35 14 5 6 39, 89 46. 85 15 5 6 26.62* 31. 72 16 5 6 15.86* 20. 78 17 5 6 91. 30 94-33 18 5 6 11.66* 18. 93 19 5 6 56.35 58. 36 20 5 6 15.84* 8. 37 21 5 6 85. 64 88. 19 22 5 6 18.47* 10. 99 23 5 6 19.28* 15. 99 0 6 6 56. 27 56. 85 1 6 6 107. 65 104. 01 2 6 6 59.73 65. 30 3 6 6 109.29 110. 07 4 6 6 26. 43 22. 98 5 6 6 39. 41 39. 02 6 6 6 12.91* 30. 19 7 6 6 133. 15 144. 89 8 6 6 39. 84 41. 49 9 6 6 16.41* 2. 29 10 6 6 59.96 63. 74 11 6 6 106.05 111. 58 12 6 6 33. 46 37. 40 13 6 6 38. 64 37. 76 14 6 6 37,66 37. 52 H K L FO FC H K L FO FC 15 6 6 72. 00 77. 45 9 0 7 11.36* 5.41 16 6 6 20.18* 1 1 - 2 3 10 0 7 34. 18 33. 61 17 6 6 32. 10 26.58 11 0 7 24.12* 19. 23 18 6 6 23.38* 21. 50 12 0 7 34. 46 30. 24 19 6 6 28. 14 29- 84 13 0 7 0. 00* 4.35 20 6 6 18.85* 11.49 14 0 7 44. 41 49. 88 21 6 6 73-28 73- 17 15 0 7 0. 00* 4. 68 1 7 6 62. 88 63.07 16 0 7 0. 00* 33- 73 2 7 6 28.20 22. 47 17 0 7 76. 14 79.64 3 7 6 66.30 68.52 18 0 7 0. 00* 22. 86 4 7 6 26.68* 25. 15 19 0 7 63. 15 68. 83 5 7 6 59.45 59. 91 20 0 7 0. 00* 33. 09 6 7 6 32. 28 32. 58 21 0 7 54. 39 55.37 7 7 6 34.50 36.66 22 0 7 41. 92 50. 48 8 7 6 18. 11* 8.92 23 0 7 29.56* 42. 22 9 7 6 20.72* 27.04 24 0 7 43. 52 51. 34 10 7 6 32.46 30-54 25 0 7 0. 00* 18.60 11 7 6 0. 00* 12.79 0 1 7 235.61 243.23 12 7 6 29-84 28.40 1 1 7 24.59* 17.55 13 7 6 47. 35 54. 16 2 1 7 154.68 154.87 14 7 6 33.99 34.47 3 1 7 79. 53 7 5. 13 15 7 6 26.84* 29. 14 4 1 7 1 12.51 111.44 16 7 6 39. 15 44.57 5 1 7 116. 18 115-23 17 7 6 56. 17 61. 43 6 1 7 64. 35 62. 52 18 7 6 15.39* 17. 47 7 1 7 174.27 179. 13 0 8 6 80.44 80.07 8 1 7 100. 90 103. 47 1 8 6 96- 50 99. 11 9 1 7 84. 01 83. 79 2 8 6 91.21 90.05 10 1 7 137.33 137.52 3 8 6 80.22 81. 24 11 1 7 28. 50 34. 58 4 8 6 54.78 55.02 12 1 7 165.46 165- 53 5 8 6 79. 89 82.82 13 1 7 86. 29 87.88 6 8 6 80.73 87. 29 14 1 7 107.84 109.21 7 8 6 91.72 95. 27 15 1 7 49.23 45. 51 8 8 6 56. 59 56.49 16 1 7 47. 94 51. 17 9 8 6 64. 13 63.38 17 1 7 48.72 53. 64 10 8 6 83.41 85.67 18 1 7 27.32* 34. 22 11 8 6 116.62 119. 10 19 1 7 8.22* 18. 98 12 8 6 54. 51 55.54 20 1 7 55.90 56. 22 13 8 6 44. 17 44.64 21 1 7 50. 20 48. 69 14 8 6 59.28 63.47 22 1 7 57.61 56.56 15 8 6 61.64 63.46 23 1 7 36. 99 43. 46 1 9 6 22.93* 30.59 24 1 7 73. 30 74. 90 2 9 6 12.15* 16.91 25 1 7 25.32* 35. 10 3 9 6 35.26 36.43 1 2 7 61. 81 62. 49 4 9 6 15.95* 23.04 2 2 7 28. 27 30. 49 5 9 6 24.16* 30. 40 3 2 7 121. 03 122.85 6 9 6 25.93* 24. 10 4 2 7 30. 79 27. 47 7 9 6 17.06* 22. 70 5 2 7 107. 16 102. 94 8 9 6 0. 00* 4.63 6 2 7 34.64 35. 00 9 9 6 17.88* 5.91 7 2 7 51. 95 50. 40 10 9 6 24.04* 31.98 8 2 7 25. 87 27. 52 1 0 7 63.38 63.42 9 2 7 53. 28 4 8. 22 2 0 7 59. 38 57.29 10 2 7 74. 90 77. 53 3 0 7 91. 47 97.81 11 2 7 47. 92 46. 37 4 0 7 50. 53 42. 38 12 2 7 62. 89 65. 96 5 0 7 1 18.72 115.80 13 2 7 24.72* 27. 00 6 0 7 0. 00* 2.72 14 2 7 65. 73 67. 84 7 0 7 22.41* 30.99 15 2 7 29. 20 35-64 fl K 1 FO FC H K L FO FC 16 2 7 32.04 32.32 0 5 7 107.17 110.80 17 2 7 59.79 60. 17 1 5 7 23.27* 24-58 18 2 7 50. 09 52. 68 2 5 7 123. 95 115. 04 19 2 7 80.66 81.25 3 5 7 18. 25* 1 4. 37 20 2 7 45. 13 45.53 4 5 7 32.56 38. 18 21 2 7 44.35 43. 26 5 5 7 36. 61 42. 94 22 2 7 59. 78 59.93 6 5 7 40- 85 36. 53 23 2 7 25.12* 29. 26 7 5 7 74. 70 73. 06 24 2 7 40. 07 44.69 8 5 7 0. 00* 4. 40 25 2 7 32. 53 34. 27 9 5 7 75.71 73. 09 0 3 7 153.09 145.53 10 5 7 78.78 78. 00 1 3 7 41. 84 38. 18 11 5 7 28. 37 25- 84 2 3 7 72.77 83.78 12 5 7 69. 90 74.78 3 3 7 72.32 74. 13 13 5 7 32. 15 24. 71 4 3 7 24.56 22. 99 14 5 7 54.47 55. 11 5 3 7 105.37 112.90 15 5 7 16.68* 14. 13 6 3 7 10.89* 18.09 16 5 7 0. 00* 11.83 7 3 7 187.54 189.33 17 5 7 21.93* 11. 86 8 3 7 37.68 32. 05 18 5 7 9. 81* 21^25 9 3 7 106.79 113.62 19 5 7 45.24 46- 69 10 3 7 104.60 114.56 20 5 7 23.31* 14.79 11 3 7 99.80 104.24 21 5 7 55. 78 55. 07 12 3 7 82.75 84. 83 1 6 7 29. 67 27. 52 13 3 7 39.94 45. 13 2 6 7 0. 00* 12. 84 14 3 7 59.21 57. 13 3 6 7 44. 46 48.61 15 3 7 31.96 30.51 4 6 7 7. 45* 12. 56 16 3 7 17.70* 8. 16 5 6 7 49.40 44. 00 17 3 7 36. 1 1 40-23 6 6 7 13.00* 16. 82 18 3 7 18.35* 1 1.08 7 6 7 31.70 26. 45 19 3 7 38.53 37.32 8 6 7 29. 17 30. 34 20 3 7 13.37* 20.21 9 6 7 15. 46* 12. 12 21 3 7 66. 97 68. 59 11 6 7 31.34 35. 85 22 3 7 46.69 41.30 12 6 7 34. 82 36. 22 23 3 7 20.64* 14. 00 13 6 7 37. 62 36.24 24 3 7 44. 83 46.23 14 6 7 33.29 34.22 1 4 7 25.35 18-91 15 6 7 47.85 52. 85 2 4 7 18.53* 15.72 16 6 7 28. 01 24. 31 3 4 7 31. 17 37. 18 17 6 7 59. 00 59. 12 4 4 7 34.57 31.34 18 6 7 14.79* 25. 78 5 4 7 54.64 57.31 19 6 7 85.36 86. 29 6 4 7 2. 05* 9. 12 0 7 7 157.48 155. 16 7 4 7 38.66 36. 11 1 7 7 49. 05 5 0. 37 8 4 7 38.92 37.47 2 7 7 111.71 1 14. 62 9 4 7 38. 64 38. 29 3 7 7 42. 15 38. 06 10 4 7 26. 04 23.72 4 7 7 108.20 107.49 11 4 7 15.31* 6. 23 5 7 7 101. 10 101.69 12 4 7 48.97 51.75 6 7 7 60. 34 63. 98 13 4 7 44. 83 42.75 7 7 7 80. 01 86. 22 14 4 7 26.82* 31.72 8 7 7 100.09 101.36 15 4 7 48.40 46. 94 9 7 7 103.55 104.85 16 4 7 16.07* 12.41 10 7 7 112.05 118.80 17 4 7 105.24 108.29 11 7 7 35. 32 39-26 18 4 7 29. 10 34. 19 12 7 7 123.21 123.52 19 4 7 95. 30 92.93 13 7 7 48. 38 47. 58 20 4 7 21.21* 27. 40 14 7 7 8 5. 83 86-97 21 4 7 67.03 69.65 15 7 7 14.37* 17-21 22 4 7 46.01 48.06 16 7 7 57. 88 57. 47 23 4 7 36. 97 3 4.09 17 7 7 25. 07* 25.70 H K L FO 1 8 7 64. 99 2 8 7 6. 85* 3 8 7 59.70 4 8 7 13.21* 5 8 7 36.61 6 8 7 9. 90* 7 8 7 32. 07 8 8 7 13.35* 9 . 8 7 25.19* 10 8 7 31-33 11 8 7 20.44* 12 8 7 25.76* 13 8 7 19.75* 0 9 7 72. 84 1 9 7 48. 15 2 9 7 71. 38 3 9 7 59. 37 4 9 7 37, 87 5 9 7 6.07* 6 9 7 4. 57* 7 9 7 74. 12 0 0 8 105.64 1 0 8 210.05 2 0 8 93. 99 3 0 8 101.86 4 0 8 105. 12 5 0 8 214.33 6 0 8 41. 57 7 0 8 7. 28* 8 0 8 44. 04 9 0 8 209- 51 10 0 8 106-89 11 0 8 127.26 12 0 8 51.70 13 0 8 138.57 14 0 8 74. 90 15 0 8 57.78 16 0 8 24.30* 17 0 8 71.54 18 0 8 0. 00* 20 0 8 69.45 21 0 8 0. 00* 22 0 8 0. 00* 23 0 8 103.30 24 0 8 62.67 1 1 8 109. 15 2 1 8 35.67 3 1 8 77. 55 4 1 8 55.91 5 1 8 96.23 6 1 8 54.35 7 1 8 96.61 8 1 8 86,99 9 1 8 31. 86 10 1 8 12.88* 11 1 8 63.89 12 1 8 37. 62 13 1 8 47.00 FC H 69.51 14 7.06 15 67.60 16 10. 48 17 41.00 18 2. 17 19 30.71 20 24.71 21 26.55 22 29.63 23 18.74 24 31.05 0 7.27 1 73. 18 2 43.71 3 71.02 4 61.04 5 38.78 6 2. 36 7 17.23 8 78.76 9 109.85 10 206.24 11 90.28 12 95.39 13 90.23 14 216.31 15 41.86 16 8.38 17 40.94 18 208.04 19 1 10.34 20 124.00 21 59. 23 22 142.07 23 79.33 24 54, 57 1 46. 93 2 70.92 3 3.73 4 73. 46 5 0.52 6 16.32 7 106.73 8 71. 13 9 101.35 10 28.76 11 81. 48 12 51.57 13 98. 43 14 49.80 15 94.38 16 82.92 17 30.59 18 13-51 19 64. 09 20 38.09 21 49.64 22 K L FO FC 8 35. 49 41. 95 1 8 54. 33 55. 66 1 8 31. 72 30. 50 1 8 16,16* 21. 98 1 8 32. 00 33. 15 1 8 107. 83 106. 20 1 8 34. 03 36, 56 1 8 17.59* 14. 26 1 8 45. 07 46. 28 1 8 63.54 63. 30 1 8 31. 43 33. 94 2 8 76. 78 77. 07 2 8 125.09 122. 51 2 8 113. 73 109. 39 2 8 19. 64* 1 1. 04 2 8 53. 04 60. 66 2 8 173.44 171. 26 2 8 107. 13 99- 18 2 8 115.41 116. 88 2 8 43. 34 41. 86 2 8 180.25 182. 82 2 8 92.57 92. 52 2 8 57. 46 56. 17 2 8 78. 51 79. 66 2 8 106.63 107. 97 2 8 48. 20 49. 25 2 8 29. 09 36. 39 2 8 50.35 48. 09 2 8 29.25 26. 42 2 8 16. 03* 19. 58 2 8 47. 53 43. 33 2 8 41. 27 40. 95 2 8 27.54* 24. 25 2 8 28. 05 27. 67 2 8 58. 00 55. 88 2 8 38. 18 40. 23 3 8 43. 15 42. 96 3 8 24. 89 2 8. 37 3 8 58. 27 55. 81 3 8 29. 63 28. 33 3 8 105,48 104. 38 3 8 55. 13 5 8. 17 3 8 31. 81 29. 62 3 8 28.58 32. 11 3 8 14.49* 22. 37 3 8 2 2. 17* 18-59 3 8 14.79* 18. 41 3 8 42.05 4 5. 69 3 8 6.61* 12. 15 3 8 2 5.90* 15. 95 3 8 65.27 66. 96 3 8 21.90* 7. 78 3 8 67. 86 7 0. 99 3 8 21.37* 24. 07 3 8 87. 15 92. 02 3 8 24.83* ^ 29. 47 3 8 45.21 42. 56 3 8 15.23* 12. 28 H K L FO FC H K I FO FC 23 3 8 58.36 60.39 14 6 8 44. 57 42. 45 0 4 8 88.89 86.05 15 6 8 50. 93 48. 44 1 4 8 84. 27 82. 15 16 6 8 45. 82 48. 16 2 4 8 69.77 63.67 17 6 8 16.19* 22.90 3 4 8 36. 46 35.03 18 6 8 7, 30* 15. 52 4 4 8 54. 59 56.28 1 7 8 64.44 61. 94 5 4 8 89.07 90.58 2 7 8 9. 05* 19.62 6 4 8 37.64 33.38 3 7 8 6 5. 85 68- 80 7 4 8 77.75 78.62 4 7 8 38. 56 39.38 8 4 8 38.49 38.64 5 7 8 53. 49 52. 80 9 4 8 114.52 116. 17 6 7 8 0. 00* 17.46 10 4 8 63. 85 65.68 7 7 8 20.76* 19. 52 1 1 4 8 14.60* 9. 17 8 7 8 38. 08 4 2- 37 12 4 8 19.93* 21. 45 9 7 8 23. 18* 19. 80 13 4 8 68.74 67.75 10 7 8 5.79* 12-97 14 4 8 49. 36 51. 34 11 7 8 14. 32* 17. 84 15 4 8 32.44 33.63 12 7 8 28.15* 30.65 16 4 8 10.43* 18.42 13 7 8 26.35* 28.76 17 4 8 8. 13* 6.82 14 7 8 25.19* 27.75 18 4 8 41.43 42.91 15 7 8 48.74 4 5. 03 19 4 8 53.48 59.21 0 8 8 65. 93 64. 48 20 4 8 18.35* 22.66 1 8 8 84. 18 84. 48 21 4 8 20.88* 27.05 2 8 8 49.71 54.60 22 4 8 12.86* 16. 14 3 8 8 50. 70 54. 48 1 5 8 25.51* 26-89 4 8 8 23.78* 22. 16 2 5 8 8.37* 12.84 5 8 8 97. 39 104.36 3 5 8 18.80* 11. 25 6 8 8 17.63* 26. 01 4 5 8 14.63* 10.32 7 8 8 42. 34 44.77 5 5 8 45. 80 48. 22 8 8 8 29.64* 24. 32 6 5 8 21.74* 17.84 9 8 8 95. 28 98. 95 7 5 8 10.21* 14. 37 10 8 8 40. 96 46. 12 8 5 8 21.73* 26.62 11 8 8 38. 43 39.08 9 5 8 18.38* 24. 23 1 0 9 63.63 56. 88 10 5 8 20.24* 19.58 2 0 9 67.30 62. 35 11 5 8 56.32 57.63 3 0 9 108.75 107- 30 12 5 8 40. 57 39.37 4 0 9 62.75 61. 61 13 5 8 24.63* 26.30 5 0 9 55. 11 63.31 14 5 8 12.29* 19. 93 6 0 9 63. 62 67- 23 15 5 8 97.87 102.01 7 0 9 66. 80 66. 12 16 5 8 16.53* 9.90 8 0 9 37.3 6 36- 19 17 5 8 63.01 63.67 9 0 9 50.24 44.98 18 5 8 23.24* 25.62 10 0 9 30.14* 30. 60 19 5 8 94.58 94. 80 1 1 0 9 26.08* 25. 47 20 5 8 16.84* 23. 11 12 0 9 26.15* 12.91 0 6 8 90. 95 93. 14 13 0 9 82. 17 87. 16 1 6 8 98. 94 96. 68 14 0 9 32.10* 38. 84 2 6 8 74. 84 74.48 15 0 9 12.81* 13.78 3 6 8 58.40 53. 96 16 0 9 0. 00* 20.24 4 6 8 40. 07 45. 24 17 0 9 98.37 104.30 5 6 8 1 11.05 1 13.74 18 0 9 4. 00* 10.53 6 6 8 63.73 62.63 19 0 9 9. 77* 2.77 7 6 8 63.76 61.96 20 0 9 0. 00* 3. 66 8 6 8 38.91 38.95 21 0 9 91.93 91. 11 9 6 8 130.92 134.60 22 0 9 0.00* 3.47 10 6 8 74. 87 72.45 23 0 9 68. 35 65. 95 11 6 8 63. 62 6 0. 90 1 1 9 197.07 185- 37 12 6 8 76.46 76.87 2 1 9 143.41 137.25 13 6 8 90. 54 91.99 3 1 9 161. 81 158.74 H K L FO FC 4 1 9 73.10 71.01 5 1 9 0.00* 16. 01 6 1 9 51.31 54.20 7 1 9 179.29 181.65 8 1 9 107. 14 103. 32 9 1 9 51. 53 50.05 10 1 9 61.54 60.99 11 1 9 188.25 189.04 12 1 9 49, 30 52. 27 13 1 9 74.51 73.93 14 1 9 48.67 46.76 15 1 9 109.04 109.51 16 1 9 48.11 47.63 17 1 9 0. 00* 16.97 18 1 9 58.82 57. 45 19 1 9 24.31* 27.97 20 1 9 59.00 57.67 21 1 9 100.24 98.49 22 1 9 46. 93 46.90 23 1 9 35.67 34.15 1 2 9 80.92 78.51 2 2 9 19.93* 17.89 3 2 9 115.31 109.56 4 2 9 92.38 9 2,48 5 2 9 79.00 79.95 6 2 9 69.47 67.02 7 2 9 67.79 67.41 8 2 9 52.84 56.15 9 2 9 28.47 29.98 10 2 9 44. 29 45. 56 11 2 9 29.75 30.50 12 2 9 32.50 32-58 13 2 9 42-21 42.43 14 2 9 30.98 32.10 15 2 9 26.96* 29-56 16 2 9 25.88* 24.02 17 2 9 73.69 72-38 18 2 9 38. 13 35.62 19 2 9 49.69 44-56 20 2 9 21.74* 21.70 21 2 9 70.33 67.89 22 2 9 0-00* 11-20 0 3 9 36.48 32.75 1 3 9 77.94 74.15 2 3 9 44. 73 37.40 3 3 9 70.19 67.28 4 3 9 31.83 28,01 5 3 9 77.64 78.93 6 3 9 19.15* 17.79 7 3 9 95.96 94.92 8 3 9 28.51 27.30 9 3 9 49. 19 51-46 10 3 9 24.22* 21.18 11 3 9 104.17 106-32 12 3 9 20-37* 20.74 13 3 9 14.06* 16.12 14 3 9 37. 13 41. 18 15 3 9 60.56 60-74 H K L FO FC 16 3 9 23.82* 23-52 17 3 9 26. 74 24. 89 18 3 9 15.96* 17. 75 19 3 9 12-89* 13. 93 20 3 9 31.64 33- 07 21 3 9 47.40 44. 34 22 3 9 8. 66* 8. 71 1 4 9 27.24 27. 17 2 4 9 17.88* 14. 24 3 4 9 39. 58 42-61 4 4 9 33. 32 33. 60 5 4 9 44. 57 44. 99 6 4 9 20.59* 24. 33 7 4 9 16.26* 16. 91 8 4 9 44. 63 40. 79 9 4 9 41. 15 40. 93 10 4 9 30. 46 32. 34 11 4 9 34. 08 33- 94 12 4 9 63. 03 62. 35 13 4 9 56. 39 60. 89 14 4 9 20.03* 9. 50 15 4 9 42. 81 43. 39 16 4 9 30- 28 30. 11 17 4 9 81. 34 85. 40 18 4 9 35. 45 36. 13 19 4 9 52. 79 50. 76 20 4 9 0. 00* 4. 86 0 5 9 58. 55 53. 56 1 5 9 125. 46 125. 52 2 5 9 51.78 53. 58 3 5 9 107. 13 106. 70 4 5 9 58. 53 57. 81 5 5 9 43- 95 44. 29 6 5 9 97.31 100. 55 7 5 9 108.09 112. 11 8 5 9 20.81* 14. 07 9 5 9 78. 30 80. 69 10 5 9 78. 03 84. 15 11 5 9 132.63 131. 22 12 5 9 40- 87 36. 62 13 5 9 90.95 86. 42 14 5 9 33. 08 34. 72 15 5 9 54.35 54- 52 16 5 9 49.75 47. 35 17 5 9 35.37 34. 49 18 5 9 0. 00* 13. 94 19 5 9 15.82* 19. 19 1 6 9 38. 06 32. 16 2 6 9 40.39 39. 86 3 6 9 59. 22 56- 63 4 6 9 33. 52 33. 37 5 6 9 27. 48 24- 31 6 6 9 36.21 35. 78 7 6 9 24. 28* 21. 00 8 6 9 33. 19 36- 93 9 6 9 45. 62 50. 44 10 6 9 36.49 37. '20 11 6 9 28.51* 31. 47 H K L FO FC H K L FO FC 12 6 9 22.27* 23. 24 9 10 9, 45* 3. 46 13 6 9 57.27 59.71 10 1 10 83.50 82. 06 14 6 9 15.35* 11.97 11 1 10 54.79 54. 80 15 6 9 31.73 31.54 12 1 10 21.04* 23.25 16 6 9 20.50* 8.27 13 1 10 24.34* 24.75 0 7 9 51.64 53. 11 14 1 10 53. 24 46. 84 1 7 9 96.06 95. 55 15 1 10 64.63 59.25 2 7 9 28.11* 24.48 16 1 10 52. 44 52, 51 3 7 9 90.55 90.90 17 1 10 49. 36 47, 99 4 7 9 23.49* 28.61 18 1 10 23.35* 23. 07 5 7 9 28.06* 28.57 19 1 10 57. 45 54.77 6 7 9 19.43* 14.76 20 1 10 47. 03 46.23 7 7 9 96.43 96.47 21 1 10 15.59* 12. 80 8 7 9 23.25* 18.55 0 2 10 157.10 149.66 9 7 9 23.77* 29.42 1 2 10 58.39 56. 99 10 7 9 3. 16* 6.70 2 2 10 47. 96 47. 99 11 7 9 108.69 109.02 3 2 10 51. 74 4 7, 79 12 7 9 29.28 27.26 4 2 10 54. 65 52.30 13 7 9 48. 49 49.21 5 2 10 105. 23 101. 25 1 8 9 51.00 52. 20 6 2 10 19.61* 17. 68 2 8 9 27.75* 30. 43 7 2 10 40. 22 39. 26 3 8 9 50.72 50.76 8 2 10 43. 49 39. 48 4 8 9 40.65 39. 26 9 2 10 90. 05 91. 92 5 8 9 35.38 33.25 10 2 10 50. 81 49. 34 6 8 9 39.00 31.79 11 2 10 40.39 40. 73 7 8 9 38. 42 43.01 12 2 10 50. 59 52.29 8 8 9 28.83* 29.94 13 2 10 96. 81 92. 79 0 0 10 124.64 114.87 14 2 10 70. 61 72- 50 1 0 10 63. 12 60.90 15 2 10 49. 46 52. 34 2 0 10 125.57 126.05 16 2 10 28.78 27. 88 3 0 10 47. 31 45.64 17 2 10 51.30 49.71 4 0 10 83 . 96 83. 11 18 2 10 49. 44 44.71 5 0 10 70. 24 68.80 19 2 10 15.85* 14. 48 6 0 10 75.51 79.01 20 2 10 20.05* 16. 92 7 0 10 34. 06 29.65 21 2 10 40.30 37. 68 8 0 10 93.72 90. 46 1 3 10 70. 10 70.35 9 0 10 84.56 87.00 2 3 10 38.89 35. 32 10 0 10 88. 90 90.62 3 3 10 68.68 69.37 11 0 10 22.41* 4.30 4 3 10 34.09 32- 46 12 0 10 1 11.72 110.74 5 3 10 50.06 53. 23 13 0 10 68.36 71.64 6 3 10 50. 13 50. 48 14 0 10 1 14.81 1 14.90 7 3 10 34. 72 31.77 15 0 10 19.35* 14.80 8 3 10 48. 14 49. 74 16 0 10 12.33* 8.92 9 3 10 0. 00* 16. 60 17 0 10 0.00* 2.34 10 3 10 51. 12 52. 45 18 0 10 82.41 80.93 11 3 10 37. 49 38. 99 19 0 10 38. 52 38.71 12 3 10 18.30* 15. 43 20 0 10 14. 1 1* 16.26 13 3 10 24.15* 2 5. 15 21 0 10 0.00* 38.46 14 3 10 27.76* 29. 82 22 0 10 110.41 108.04 15 3 10 25. 17* 26. 08 1 1 10 58.54 59. 12 16 3 10 30.69 32.81 2 1 10 68.59 66.07 17 3 10 49.96 52. 42 3 1 10 107.95 99.04 18 3 10 24.77* 20. 42 4 1 10 40.74 39.21 19 3 10 46. 10 45. 48 5 1 10 74. 92 70.94 20 3 10 30. 79 26. 69 6 1 10 80, 97 78.63 0 4 10 153.40 155,62 7 1 10 22.13* 15.47 1 4 10 57. 63 50. 96 8 1 10 22.34* 24. 60 2 4 10 74. 74 66-46 H K L FO 3 4 10 21. 01* n 4 10 92. 77 5 4 10 55. 12 6 4 10 25. 84* 7 4 10 57. 16 8 4 10 1 16. 59 9 4 10 59. 23 10 4 10 66. 4 3 11 4 10 5. 72* 12 4 10 106. 36 13 4 10 48. 43 14 4 10 76. 31 15 4 10 33. 42 16 4 10 21. 75* 17 4 10 26. 35* 18 4 10 47. 51 19 4 10 22. 79* 1 5 10 46. 96 2 5 10 24. 64* 3 5 10 49. 14 4 5 10 28. 51 5 5 10 0. 00* 6 5 10 64. 43 7 5 10 28. 77 8 5 10 20. 72* 9 5 10 53. 82 10 5 10 80- 78 11 5 10 61. 24 12 5 10 8. 33* 13 5 10 29. 93* 14 5 10 73. 03 15 5 10 34. 12 16 5 10 47. 70 17 5 10 42. 71 0 6 10 129. 32 1 6 10 53. 36 2 6 10 83. 18 3 6 10 34. 58 4 6 10 88. 42 5 6 10 35. 42 6 6 10 45. 95 7 6 10 52. 35 8 6 10 76. 22 9 6 10 48. 04 10 6 10 78. 39 11 6 10 . 40. 31 12 6 10 65. 73 13 6 10 38. 31 14 6 10 80. 20 1 7 10 44. 30 2 7 10 18. 73* 3 7 10 47. 19 4 7 10 39. 68 5 7 10 48. 24 6 7 10 52. 38 7 7 10 23. 23* 8 7 10 22. 59* 9 7 10 26. 85* FC H 6.64 10 95.95 1 51.44 2 19.20 3 57.78 4 120.03 5 59.01 6 65.32 7 13. 47 8 104.94 9 44. 45 10 77.86 11 34.44 12 20.03 13 13.23 14 48. 14 15 14.02 16 45.39 17 21. 19 18 44.61 19 25.68 20 7.23 0 61.33 1 29.85 2 21-23 3 52. 58 4 75.98 5 56.79 6 18.53 7 36.74 8 71.29 9 33.36 10 43.96 11 42. 06 12 125-48 13 54. 52 14 82-52 15 32.61 16 85. 12 17 39-34 18 44- 46 19 54. 33 1 77. 61 2 44.39 3 78. 83 4 43. 72 5 62.65 6 39.88 7 80.06 8 46.73 9 29-54 10 47. 23 11 39.91 12 47. 37 13 48.89 14 19.06 15 19-31 16 22. 56 17 K L FO PC 7 10 36. 13 34- 88 0 11 19.69* 20. 42 0 11 25.87* 22. 67 0 11 7. 41* 1. 25 0 11 55.56 53. 74 0 11 58. 81 60. 61 0 11 23.15* 30. 93 0 11 21. 25* 24. 26 0 11 69. 83 68. 06 0 11 39. 83 42. 52 0 11 20.38* 20. 62 0 11 65.74 63. 92 0 11 10 4. 19 10 3. 26 0 11 28.48* 27. 32 0 11 29.44* 22. 97 0 11 66. 55 69. 62 0 11 37. 82 42. 67 0 11 20.04* 24. 61 0 11 50.26 49. 35 0 11 24.73* 24. 30 0 11 6. 16* 23. 02 1 11 66.61 60. 65 1 11 41. 89 37. 48 1 11 106.57 101. 89 1 11 44. 97 39. 81 1 11 20.30* 18. 47 1 11 43.26 42. 43 1 11 31. 40 32- 48 1 11 26-71 21. 06 1 11 21.05* 23. 90 1 11 65. 25 65. 47 1 11 69. 16 70. 54 1 11 8. 10* 10. 24 1 11 110.40 109. 68 1 11 53. 5 1 53. 23 1 11 5.54* 20. 21 1 11 21.39* 16. 59 1 11 75.07 72. 68 1 11 18- 58* 22. 54 1 11 46.62 43. 03 1 11 38.34 35. 75 2 11 64. 56 62. 83 2 11 26.78* 31. 11 2 11 49. 59 51. 82 2 11 51. 32 48. 69 2 11 63- 97 61. 46 2 11 29- 19 29. 51 2 11 27. 41 24. 47 2 11 62. 13 64- 67 2 11 0. 00* 10. 97 2 11 38.34 33. 22 2 11 31. 83 29. 44 2 11 59.47 59- 73 2 11 8.96* 10. 30 2 11 19,20* 13. 74 2 11 64.38 64. 07 2 11 0. 00* 13, 90 2 11 20.15* 15. 90 H K L FO FC H K L FO FC 18 2 1 1 25.97* 27.05 7 6 1 1 14.74* 4. 39 19 2 11 40.22 37.29 8 6 1 1 42. 50 43. 83 0 3 11 39.99 39.35 9 6 1 1 15.13* 1 1. 98 1 3 11 29.16 26. 42 10 6 1 1 27. 97 25. 16 ' 2 3 11 141.77 140.43 11 6 11 32.76 32.63 3 3 11 31.06 32.55 0 7 11 32. 09 30. 90 4 3 11 33.14 28.77 1 7 11 10.67* 11. 56 5 3 11 51.89 51.67 2 7 11 49.40 49. 25 6 3 11 63.41 59. 19 3 7 11 31. 09 27. 54 7 3 11 15.09* 7. 17 4 7 11 11.93* 18. 94 8 3 11 26.34* 23. 18 5 7 1 1 16.62* 8. 52 9 3 11 59.60 58. 14 0 0 12 88.21 89.30 10 3 11 79.15 74.45 1 0 12 70. 03 70. 34 11 3 11 24.41* 18.32 2 0 12 43. 68 42. 48 12 3 11 85.95 85.58 3 0 12 66. 44 6 4. 27 13 3 11 70.33 70.32 4 0 12 34. 50 32.61 14 3 11 38.51 36.28 5 0 12 18.26* 11.77 15 3 11 31.88 25.78 6 0 12 18.87* 33. 37 16 3 11 57.64 54. 28 7 0 12 48. 22 49. 22 17 3 11 52.91 51. 37 8 0 12 32. 10 30.30 18 3 11 10.94* 8. 17 9 0 12 30.88* 26. 55 1 4 11 72.03 74.36 10 0 12 31.67* 29. 10 2 4 11 20.09* 27.53 11 0 12 70. 94 68.46 3 4 11 36.47 37.70 12 0 12 40. 88 37. 62 4 4 11 57.65 56.35 13 0 12 60.68 61. 34 5 4 11 47.17 48. 98 14 0 12 78. 70 79.78 6 4 11 27.81 26.41 15 0 12 40. 48 42- 06 7 4 11 22.70* 20. 28 16 0 12 69. 87 65.79 8 4 11 70.45 67.82 17 0 12 22.83* 10.65 9 4 11 37.59 38.02 1 1 12 23,61* 26. 30 10 4 11 0.00* 16.83 2 1 12 19.53* 14. 09 11 4 11 50,68 51.12 3 1 12 26.25* 26. 28 12 4 11 69.60 63.79 4 1 12 50. 87 54. 19 13 4 11 14.75* 13.48 5 1 12 17.65* 7.27 14 4 11 19.91* 10.04 6 1 12 31. 41 32. 27 15 4 11 47.00 42.01 7 1 12 11. 56* 4. 12 16 4 11 27.71* 26.31 8 1 12 42.95 44. 74 0 5 11 80.84 74. 30 9 1 12 52. 54 52. 29 1 5 11 83.08 84.49 10 1 12 79. 88 76. 40 2 5 11 144.67 144.67 1 1 1 12 21.85* 19. 19 3 5 11 57.16 57.08 12 1 12 57. 61 56. 60 4 5 11 46.18 42. 22 13 1 12 54.97 58.87 5 5 11 92.07 97.47 14 1 12 40. 04 39. 92 6 5 11 66.43 70.04 15 1 12 15.31* 7- 67 7 5 11 31.83 26.73 16 1 12 16.85* 13-36 8 5 11 60.61 58. 28 17 1 12 46. 62 46. 90 9 5 11 82.46 85.33 0 2 12 77.73 75. 96 10 5 11 87.87 91. 44 1 2 12 98. 98 98.66 11 5 11 51.34 50.83 2 2 12 79. 41 78- 45 12 5 11 96.48 98.50 3 2 12 62. 60 60.74 13 5 11 58.12 61.08 4 2 12 58. 87 58- 06 14 5 11 37.14 43.58 5 2 12 32.70 31.21 1 6 11 48.52 52.43 6 2 12 40. 40 38. 82 2 6 11 20.99* 20. 11 7 2 12 55. 41 50.56 3 6 11 38.45 41.20 8 2 12 72.35 73.33 4 6 11 44.26 46. 30 9 2 12 51.70 50. 91 5 6 11 37.07. 39. 51 10 2 12 20. 47* 10-71 6 6 11 38.86 39.13 11 2 12 94.30 95. 10 H K L FO 12 2 12 49. 06 13 2 12 41. 90 14 2 12 53. 01 15 2 12 68. 89 16 2 12 58. 11 17 2 12 23. 51* 1 3 12 41. 74 2 3 12 33. 5 8 3 3 12 72. 59 4 3 12 33. 58 5 3 12 26. 99 6 3 12 53. 74 7 3 12 35. 66 8 3 12 8. 36* 9 3 12 28. 14* 10 3 12 57. 51 11 3 12 27. 70* 12 3 12 30. 84 13 3 12 46. 65 14 3 12 28. 72* 15 3 12 20. 19* 0 4 12 125. 23 1 4 12 126. 89 2 4 12 51. 70 3 4 12 101. 46 4 4 12 75. 76 5 4 12 57. 12 6 4 12 39. 29 7 4 12 87. 71 8 4 12 40. 69 9 4 12 77. 19 10 4 12 22. 68* 1 1 4 12 1 15. 31 12 4 12 22. 37* 13 4 12 71. 80 14 4 12 47. 00 1 5 12 36. 49 2 5 12 31. 96 3 5 12 45. 66 4 5 12 55. 62 5 5 12 19. 91* 6 5 12 46. 69 7 5 12 18. 98* 8 5 12 37. 44 9 5 12 39. 34 10 5 12 56. 51 11 5 12 0. 00* 0 6 12 60. 14 1 6 12 69. 38 2 6 12 50. 65 3 6 12 39. 34 4 6 12 16. 13* 5 6 12 29. 11 6 6 12 24. 96* 1 0 13 0. 00* 2 0 13 40. 36 3 0 13 18. 92* 4 0 13 28. 41* FC H 49.47 5 40. 41 6 55.87 7 68.70 8 56. 41 9 14. 07 10 45.93 11 29.27 12 73.49 13 35. 56 14 24.45 15 52. 47 0 37.33 1 12.63 2 25. 47 3 57.77 4 26. 10 5 31.41 6 45.95 7 31. 15 8 28.61 9 124.80 10 125.94 11 53. 52 12 100. 10 13 77. 50 14 56. 42 1 35.82 2 90.73 3 37. 96 4 73. 56 5 21.72 6 115.36 7 28.56 8 69.04 9 42.79 10 30.50 11 33.26 12 40.04 13 54.03 14 7.39 0 42. 92 1 12. 52 2 39. 16 3 41.59 4 55. 85 5 9.49 6 55. 80 7 68.89 8 50.29 9 38. 11 10 16.02 11 24. 54 12 27.36 1 0. 46 2 42. 40 3 0.80 4 25.74 5 K L FO FC 0 13 21.97* 6. 37 0 13 47.39 42. 72 0 13 51.61 51. 75 0 13 60. 03 59. 06 0 13 35. 46 35. 91 0 13 57.32 59. 35 0 13 45. 83 43. 61 0 13 46. 06 45. 84 0 13 23.08* 17. 30 0 13 64.60 64. 08 0 13 23.92* 20. 93 1 13 142.19 147. 71 1 13 84. 18 84. 00 1 13 31.28 25. 22 1 13 58. 47 54. 64 1 13 80.31 81. 12 1 13 59.21 61. 28 1 13 37.39 39. 56 1 13 50. 30 52. 91 1 13 52. 03 4 9-78 1 13 55.42 56. 96 1 13 73.99 74. 72 1 13 76. 95 75. 19 1 13 16.29* 4. 13 1 13 54.51 56. 77 1 13 91.76 90. 10 2 13 36.69 36. 63 2 13 31. 96 30. 57 2 13 38.64 32. 10 2 13 21.46* 16. 28 2 13 23.70* 26- 59 2 13 30.78 31. 96 2 13 0.00* 6. 59 2 13 28. 18 25. 79 2 13 24. 85* 17- 36 2 13 52.78 55. 71 2 13 32.57 31. 04 2 13 30. 68 30. 36 2 13 31.00 26. 47 2 13 65.37 66. 38 3 13 118. 76 119. 58 3 13 79.55 77. 46 3 13 22.45* 31. 25 3 13 66. 54 66. 79 3 13 83. 02 82- 29 3 13 40.33 41- 59 3 13 36. 98 36- 36 3 13 36. 18 33- 74 3 13 56.92 59. 57 3 13 64.04 65. 10 3 13 56. 48 56. 15 3 13 56.65 57. 64 3 13 25-77* 25. 10 4 13 33. 86 28. 10 4 13 46.20 44. 62 4 13 16.90* 21- 65 4 13 21.37* 26. 94 4 13 43. 56 37. 97 H K L FO FC H K L FO FC 6 4 13 50. 60 47.09 9 1 14 28.22* 26. 08 7 4 13 0.00* 11.01 10 1 14 35. 12 29. 92 8 4 13 37. 43 32-68 1 1 1 14 13.81* 22. 60 9 4 13 25.69* 27.71 0 2 1.4 55.99 55. 33 10 4 13 52.71 50.34 1 2 14 35. 82 32.38 0 5 13 1 13.69 116.85 2 2 14 120.59 124-71 1 5 13 63. 51 63.77 3 2 14 43. 18 48. 58 2 5 13 53. 83 49.73 4 2 14 41. 13 43- 67 3 5 13 66. 36 67.94 5 2 14 42. 78 38. 00 4 5 13 60. 37 60. 41 6 2 14 57. 05 61.03 5 5 13 29.02* 33.03 7 2 14 35. 48 42. 21 6 5 13 17.24* 23- 15 8 2 14 48. 92 53. 94 0 0 14 30,83* 22. 21 9 2 14 41. 1 1 43. 21 2 0 14 . 159. 19 162-28 1 3 14 33.45 31.37 3 0 14 12.20* 9.24 2 3 14 15.22* 13. 50 4 0 14 0. 00* 1 1.85 3 3 14 8.52* 8.90 5 0 14 25.83* 13.78 4 3 14 41.00 37. 37 6 0 14 53. 70 50-84 5 3 14 34.22 31.76 7 0 14 8. 19* 21. 71 6 3 14 0. 00* 6. 17 8 0 14 36. 25 38-02 7 3 14 10.46* 17. 52 9 0 14 19.50* 2.47 0 4 14 26.05* 24- 77 10 0 14 32.53* 33.07 1 4 14 40. 09 35. 15 11 0 14 21.29* 20. 11 2 4 14 107. 89 109-38 1 1 14 22.09* 18.64 1 0 15 37. 48 38. 85 2 1 14 30.56 21.43 2 0 15 28. 89* 24. 62 3 1 14 7.68* 13-42 3 0 15 15. 94* 13. 05 4 1 14 37.62 37-02 4 0 15 26.90* 24. 33 5 1 14 17.61* 5.94 0 1 15 1 18,59 122. 43 6 1 14 20.73* 17.88 1 1 15 67. 28 67.44 7 1 14 8. 38* 14.98 2 1 15 40. 12 3 8. 59 8 1 14 41. 38 37. 11 3 1 15 50.36 47.71 * DENOTES AN UNOBSERVED REFLECTION 20 1,3,7-Trimethyl-2,6-dioxypurine Hydrochloride Dihydrate (Caffeine Hydrochloride Dihydrate) Anthony Mercer and James Trotter. Observed and calculated structure amplitudes (reflections with intensity < 3«sr(T) are marked with an asterisk) . The following planes which had |Fo-Fc|> 3 (F) were given zero weight in the final stages of refinement due to suspected instrumental errors. Fo Fc Fo Fc 10 2 70.72 91.91 •14 2 6. 87 0. 36 7 5 4 4.78 0. 20 1 2 16 3. 87 0.93 3 6 12 4. 22 1. 2C ) H K L FO FC WEIGHT -13 0 2 10.05 9.88 5.67 -13 0 4 8. 14 8.34 5,44 -13 0 6 7.66 7.79 5.72 -13 0 8 12.23 12.89 4.92 -13 0 10 11. 23 12.00 5. 11 -13 0 12 9.62 10.06 6. 05 -13 0 14 13.42 14.30 4. 15 -13 0 16 8. 44 8.62 5.92 -12 0 2 6. 99 6.94 6. 37 -12 0 4 15. 55 15.51 3. 75 -12 0 6 16.58 16.18 3.68 -12 0 8 14. 4 2 15.75 4. 20 -12 0 10 3. 51* 4.77 0.23 -12 0 12 13. 95 13.85 4. 35 -12 0 14 7. 32 7. 40 5. 42 -12 0 16 0.95* 1.17 0.03 -12 0 18 18.60 20.11 2.79 -11 0 2 8. 13 7.29 6.24 -11 0 4 6.23 5.64 7.01 -11 0 6 16. 67 16.79 3. 50 -11 0 8 10.88 11.57 4.50 -11 0 10 10. 36 10.67 4. 89 -11 0 12 24.26 24. 19 2.04 -11 0 14 10. 93 11. 23 5. 95 -11 0 16 9. 92 9.40 6.57 -11 0 18 6. 14 6.11 6. 01 -10 0 2 11.10 10.69 5.01 -10 0 4 3.35* 1.53 0. 33 -10 0 6 12.68 13.33 4. 97 -10 0 8 4. 34 5.0 2 3. 46 -10 0 10 16.47 17. 06 3. 99 -10 0 12 4.51 4.07 5.50 -10 0 14 11. 32 11. 54 5. 80 -10 0 16 12.93 13.85 4. 59 -10 0 18 4.91 4.70 4. 18 -9 0 2 10.63 10.46 6.22 -9 0 4 31. 79 32. 17 1. 34 -9 0 6 3.25 2. 43 3. 95 -9 0 8 28. 52 2 8.51 1.60 -9 0 10 7. 23 6.82 7.41 -9 0 12 4.37 3. 23 3. 33 -9 0 14 19.88 2 0.48 2.94 -9 0 16 14.73 15.51 3.86 -9 0 18 20.02 19.78 2. 83 -8 0 2 3. 41 4. 10 3.91 -8 0 4 34. 93 36. 94 1. 13 -8 0 6 3.54 3. 96 6. 21 -8 0 8 6.02 5.97 7.71 -8 0 10 3. 69 1.95 6. 87 -8 0 12 19.78 20.08 2.92 -8 0 14 2.66* 1.83 0.15 -8 0 16 18.53 19.29 3.20 -8 0 18 12.39 12.30 4.87 -7 0 2 19. 17 19.88 3. 18 -7 0 4 38.70 39.06 0. 95 -7 0 6 1. 34* 0.82 0. 10 -7 0 8 24.63 24.35 2.13 -7 0 10 53. 74 54.29 0.50 H K L FO FC WEIGHT -7 0 12 22.77 23. 75 2. 43 -7 0 14 21.90 22. 56 2.41 -7 0 16 2. 11* 1. 24 0. 12 -7 0 18 8.15 7. 54 6.53 -6 0 2 14.14 14. 63 5.24 -6 0 4 64.77 66. 43 0. 35 -6 0 6 4.34 4. 81 5.94 -6 0 8 32.95 33. 54 1.30 -6 0 10 22.36 22. 22 2. 54 -6 0 12 11.79 11. 80 4. 82 -6 0 14 24.37 24.45 2.08 -6 0 16 22.89 23. 11 2. 38 -6 0 18 6.79 6. 58 6.04 -5 0 2 20.45 20. 14 3. 06 -5 0 4 41.05 41. 75 0. 86 -5 0 6 6.11 6. 05 8. 19 -5 0 8 3.86 4. 33 6. 30 -5 0 10 32.63 30. 23 1. 23 -5 0 12 20.41 20. 09 2.94 -5 0 14 27.16 27. 61 1.72 -5 0 16 4.12 5.05 3.26 -5 0 18 6.75 6. 65 5.06 -4 0 2 44.36 45.75 0.74 -4 0 4 4.31 4.57 11. 84 -4 0 6 34.72 35.47 1.18 -4 0 8 86.04 87. 24 0. 20 -4 0 10 33.24 33. 44 1.27 -4 0 12 18. 81 19. 16 3. 39 -4 0 14 19.34 19. 09 3. 13 -4 0 16 3.26* 0. 70 0.36 -4 0 18 5,48 4. 86 5. 35 -3 0 2 72.30 73. 10 0. 28 -3 0 4 37.51 36. 99 1.03 -3 0 6 78.09 79. 28 0. 24 -3 0 8 20.26 20.56 3. 04 -3 0 10 15.46 14. 86 4. 63 -3 0 12 1.50* 1. 61 0. 09 -3 0 14 21 .49 21. 09 2.75 -3 0 16 6.28 6. 45 4. 33 -3 0 18 17.82 17. 52 3.55 -2 0 2 1. 84* 0. 72 0. 60 -2 0 4 47 . 36 52. 90 0.59 -2 0 6 32.74 32. 20 1.33 -2 0 8 6.31 6. 91 8. 53 -2 0 10 2.80* 2.42 0. 39 -2 0 12 7.64 7. 10 7.14 -2 0 14 8.78 8. 85 6.55 -2 0 16 10.30 9. 58 6. 93 -2 0 18 4.12 4. 09 3.49 -1 0 4 3.55 3. 61 10.71 -1 0 6 112.12 117.39 0. 12 -1 0 8 24.86 25. 11 2. 16 -1 0 10 39. 15 39. 24 0. 94 -1 0 12 4.20 3. 73 5. 01 -1 0 14 22.83 23. 73 2. 28 0 16 8.24 7. 30 6.29 -1 0 18 5.36 4. 56 5.6 3 0 0 2 52.74 50. 94 0.52 H K L FO FC WEIGHT H K L 0 0 4 15. 5 8 14.94 3. 55 7 0 4 0 0 6 50.51 51.12 0.55 7 0 6 0 0 8 34. 36 32.73 1.16 7 0 8 0 0 10 34. 33 3 2.48 1.18 7 0 10 0 0 12 36.91 35.04 1.02 8 0 0 0 0 14 45. 24 44.42 0.69 8 0 2 0 0 16 8.74 8.01 4. 47 8 0 4 0 0 18 7.71 7.10 7.41 8 0 6 1 0 0 9.31 9.95 2. 10 8 0 8 1 0 2 8. 85 6.89 4.91 8 0 10 1 0 4 74. 64 74.39 0.27 9 0 0 1 0 6 30.66 29.44 1.48 9 0 2 1 0 8 3.64 3.97 5.47 9 0 4 1 0 10 46. 32 45. 92 0.68 9 0 6 1 0 12 33. 14 32. 58 1. 25 9 0 8 1 0 14 15.49 15.48 3. 89 10 0 0 1 0 16 7.70 7.46 6. 22 10 0 2 2 0 0 72.67 72.05 0. 27 10 0 4 2 0 2 36. 94 36.31 1.05 10 0 6 2 0 4 63.60 62.55 0.36 11 0 0 2 0 6 23. 62 2 5. 28 2.34 11 0 2 2 0 8 12.50 11.91 5. 58 11 0 4 2 0 10 8.64 8.43 5.76 12 0 0 2 0 12 9.98 9. 93 5.39 12 0 2 2 0 14 5.86 4.06 6. 88 13 0 0 2 0 16 6.74 6.00 7.05 -13 1 1 3 0 0 108. 82 96.59 0.13 -13 1 2 3 0 2 20. 69 18.99 2. 95 - 13 1 3 3 0 4 19. 82 19.22 3.17 -13 1 4 3 0 6 17.44 17. 65 3.76 -13 1 5 3 0 8 9.57 8.62 7. 18 -13 1 6 3 0 10 5.51 5. 34 3.59 - 13 1 7 3 0 12 23. 13 21.02 2. 34 -13 1 8 3 0 14 12.97 12. 28 5. 25 -13 1 9 4 0 0 6. 49 7.70 3.03 -13 1 10 0 2 8. 25 8. 30 8.75 - 13 1 11 4 0 4 31. 39 30. 74 1.40 -13 1 12 4 0 6 26.59 26. 33 1.85 -13 1 13 4 0 8 24.63 24. 11 2. 12 -13 1 14 4 0 10 28.99 28.21 1. 53 -13 1 15 4 0 12 21. 67 20. 56 2.46 -13 1 16 4 0 14 4. 84 3.49 6.25 -13 1 17 5 0 0 21.88 20. 92 2. 61 -12 1 1 5 0 2 89.93 83.51 0. 18 -12 1 2 5 0 4 20. 84 19.48 2. 86 -12 - 1 3 5 0 6 6. 06 5. 83 6.02 -12 1 4 5 0 8 3. 44* 2. 87 0.23 -12 1 5 5 0 10 4.91 4.74 4.00 -12 1 6 5 0 12 10. 53 10.70 5.39 -12 1 7 6 0 0 14.09 14.36 4.90 -12 1 8 6 0 2 20.34 20.03 2.96 -12 1 9 6 0 4 27. 68 26.86 1.76 -12 1 10 6 0 6 23.32 24.00 2. 20 -12 1 11 6 0 8 2. 49* 1.52 0.15 -12 1 12 6 0 10 9. 30 8.76 6.37 -12 1 13 6 0 12 2. 61* 1.02 0. 22 -12 1 14 7 0 0 14. 37 14.52 4. 98 -12 1 15 ^7 0 2 21. 09 19.26 2.75 -12 1 16 FO FC WEIGHT 27.69 26. 79 1.72 16.17 16.77 3.56 0.00* 0. 92 0. 00 11.62 10. 73 5.55 7.03 6.02 6.69 29.22 28.45 1.53 12. 26 12. 64 4.28 13.65 12. 86 4. 64 4. 11 4. 09 3. 12 3.14* 2.65 0.33 19.54 19. 39 2. 97 10.11 10.14 5.36 1.91* 0. 23 0.09 15.44 14.60 4.11 2.46* 2. 32 0. 18 6. 19 6. 29 4. 21 0.00* 0. 88 0. 00 3.16* 0.43 0.40 2.49* 0.59 0.28 4.34 4.09 2.70 19. 14 18. 24 2.98 1.98* 1.63 0.11 2.32* 1.23 0.18 6.39 6. 72 7. 10 2.88* 2. 63 0. 26 2.17* 2.49 0.14 7.90 7.89 6.10 1.55* 0.18 0.07 6.05 6. 57 4.28 7.97 8. 50 4.46 6.04 5. 47 5.79 3.62 0.57 4.28 4.09 3. 59 3. 54 6.66 6.83 4.93 3.33* 0.70 0.29 15.72 17. 03 3.46 7.75 7. 85 5.73 9.65 9.77 6.13 8.67 9.06 5.65 5.52 6.35 4.46 4.60 4. 90 4.03 6.91 7,06 6.16 4.84 3.69 6.50 1 .37* 0.03 0.06 2. 18* 1. 74 0. 10 2.72* 0.52 0.19 8.24 8. 05 5. 17 4.84 3.49 3.96 7.95 9.39 3.63 3.65 1. 66 3.75 7.07 6. 61 5.66 6.61 6.19 6.98 3.29* 2. 34 0.25 7.30 6. 53 5. 92 5.87 5. 08 6. 85 8.18 8. 27 5.48 8.56 7.80 8.14 3.44 0. 70 4. 64 H K I FO FC WEIGHT 12 1 17 3. 06* 1.87 0.26 12 1 18 6. 05 6.03 5. 96 11 1 1 11.79 11. 13 6. 21 11 1 2 4. 80 4.14 3.83 11 1 3 2.44* 0.99 0.14 11 1 4 11.12 11.22 4. 64 11 1 5 11.31 11.97 4.72 11 1 6 4. 56 5.94 2.42 11 1 7 9.06 9.12 5.39 11 1 8 3. 34 1.82 3. 47 11 1 9 3.78 1.23 4. 15 11 1 10 2.51* 1.14 0. 16 11 1 11 4.68 2.82 5.29 11 1 12 5. 82 5.44 4. 89 11 1 13 13.32 13. 33 4.71 11 1 14 5. 92 5.76 3. 38 11 1 15 9. 94 10.51 4.94 11 1 16 5. 21 3.59 6.75 11 1 17 10.53 10.88 5.06 11 1 18 5. 14 4.25 6.50 10 1 1 16.20 15.74 3.55 10 1 2 9.70 9.49 6.26 10 1 3 5.19 5.32 4.83 10 1 4 8.79 8.70 5.07 10 1 5 26. 04 25. 17 1.85 10 1 6 8. 30 8.81 5.16 10 1 7 14. 96 13.90 4. 23 10 1 8 6.77 5.52 6. 37 10 1 9 18.72 18.84 3.13 10 1 10 12.00 12.08 4. 86 10 1 11 24. 72 25.78 2.01 10 1 12 2.24* 1.11 0.14 10 113 3. 30* 1.98 0.26 10 1 14 8. 25 7. 84 5,14 10 1 15 16.71 16.53 3.79 10 1 16 7.81 7.22 4. 30 10 1 17 2. 38* 0.86 0. 16 10 1 18 11. 40 11. 55 5. 82 -9 1 1 19. 66 19.49 2.84 -9 1 2 2. 59* 3.59 0. 13 -9 1 3 13. 97 13. 34 4. 64 -9 1 4 2. 50* 1. 96 0. 18 -9 1 5 4.00 3.23 3.55 -9 1 6 13. 20 12.40 5.34 -9 1 7 17.55 17.55 3.55 -9 1 8 8.50 7.27 6. 46 -9 1 9 12. 57 14. 17 5.08 -9 1 10 16. 01 16. 20 3. 80 -9 1 11 11.61 1 1. 09 5.42 -9 1 12 7.41 7.46 5. 17 -9 1 13 4. 32 4.35 2.71 -9 1 14 5. 28 4.66 4.26 -9 1 15 15.65 15.38 4.23 -9 1 16 12.32 12.33 5. 33 -9 1 17 10.98 10.94 5.29 -9 1 18 3. 38* 2.31 0.31 -8 1 1 16. 66 15.84 3. 85 -8 1 2 4. 48 3.80 4.88 H K L FO FC WEIGHT -8 1 3 8.08 8. 66 6.78 -8 1 4 26.71 25. 01 1. 86 -8 1 5 18.40 18. 75 3. 37 -8 1 6 10.89 10. 26 5.70 -8 1 7 12.72 12. 84 6.00 -8 1 8 0. 74* 2. 17 0.02 -8 1 9 8,04 8. 25 6.37 -8 1 10 28. 12 27. 37 1.65 -8 1 11 23.64 23. 50 2. 26 -8 1 12 1.44* 3. 37 0. 04 -8 1 13 8.87 9. 51 4. 92 -8 1 14 16.74 16. 91 3.57 -8 1 15 5.57 4.53 4. 48 -8 1 16 16.63 16. 90 3.54 -8 1 17 4. 14 1. 94 3.76 -8 1 18 3, 88 4. 29 2.64 -7 1 1 24.72 23.64 2. 11 -7 1 2 18. 80 18. 56 3. 32 -7 1 3 13.86 13. 97 4. 86 -7 1 4 9.18 8. 89 7. 45 -7 1 5 27 . 93 28. 80 1.74 -7 1 6 12.56 12. 40 5.98 -7 1 7 4.93 5. 09 6. 10 -7 1 8 29.21 29. 05 1.60 -7 1 9 13.58 13. 05 5.55 -7 1 10 18.00 18. 22 3.55 -7 1 11 25.24 25. 89 2.00 -7 1 12 8.04 8. 14 6.62 -7 1 13 9.43 9.59 6.10 -7 1 14 3,81 2. 51 3.26 -7 1 15 13.33 12. 93 4.75 -7 1 16 7. 85 8. 19 5.04 -7 1 17 2.46* 1. 09 0. 16 -7 1 18 6.45 6. 05 6. 04 -6 1 1 34.05 32.91 1. 20 -6 1 2 27.72 27. 49 1.75 -6 1 3 48.63 46. 29 0.61 -6 1 4 15.84 15.81 4.28 -6 1 5 16.17 16. 21 4. 39 -6 1 6 11. 17 11. 60 6.83 -6 1 7 44.28 46. 90 0.73 -6 1 8 2. 13* 1. 60 0. 23 -6 1 9 11.41 10. 53 6. 68 -6 1 10 13.46 11.94 5.41 -6 1 11 3.61 3. 76 4. 11 -6 1 12 1.83* 0. 49 0.12 -6 1 13 14.39 13. 97 4.54 -6 1 14 3.34* 1. 22 0. 35 -6 1 15 21.53 22. 11 2.68 -6 1 16 7.38 6. 75 7. 29 -6 1 17 16.63 17. 04 3.65 -6 1 18 6.67 6. 37 6. 14 -5 1 1 23.27 22. 58 2.42 -5 1 2 12.00 11. 88 6. 40 -5 1 3 23.86 24.50 2.30 -5 1 4 16. 12 15. 28 4.48 -5 1 5 16. 10 16. 32 4. 43 -5 1 6 6.28 6. 11 8. 25 H K I FO FC WEIGHT 5 1 7 31.71 3 2.24 1.38 5 1 8 13.06 13. 11 5.74 5 1 9 7.70 6.73 8.34 5 1 10 15. 24 15. 16 4.61 5 1 11 19.93 20.23 3. 08 5 1 12 4.54 4.55 4.65 5 1 13 7. 90 7.79 6.16 5 1 14 3. 26* 3.35 0.22 5 1 15 10. 28 10.45 5.96 5 1 16 14.10 13.58 4.73 5 1 17 15.37 15.00 4.11 5 1 18 4. 64 2.84 5.70 4 1 1 48. 32 48.82 0.63 4 1 2 116.47 115.24 0.11 4 1 3 39.41 3 8.98 0.94 4 1 4 39. 68 3 7.42 0.93 4 1 5 7. 19 7.71 10.56 4 1 6 33.43 33.31 1.26 4 1 7 54. 85 56.98 0.49 4 1 8 6.40 6.72 8.63 4 1 9 14.67 14.83 5.07 4 1 10 28. 00 26. 18 1.77 4 1 11 36. 66 37.75 1.04 4 1 12 20.59 20.87 2.93 4 1 13 3. 00* 3. 47 0. 23 4 1 14 11.61 10.88 5. 90 4 1 15 17. 15 17.50 3. 49 4 1 16 2.68* 3.02 0.13 4 1 17 12. 61 11.72 5. 38 4 1 18 1.75* 2. 80 0.07 3 1 1 176.28 177.91 0.05 3 1 2 25.74 23. 28 2. 11 3 1 3 75. 86 73. 93 0. 26 3 1 4 37.51 38.48 1.02 3 1 5 18.74 18. 1 1 3.79 3 1 6 25. 19 25.02 2. 15 3 1 7 41.41 42.89 0. 84 3 1 8 8. 82 8.28 7.46 3 1 9 14. 82 13.61 5. 01 3 1 10 20.95 19.77 2.88 3 1 11 29. 82 30.73 1. 53 3 1 12 20.75 20.47 2.87 3 1 13 7. 56 7.73 5.95 3 1 14 21. 57 21.51 2.49 3 1 15 26. 04 26.40 1.87 3 1 16 16.43 15.99 4.02 3 1 17 9.56 8. 96 5.45 3 1 18 7.22 6.70 5.68 2 1 1 45.08 4 2.71 0.71 2 1 2 25. 67 25.46 1.81 2 1 3 37. 12 38. 85 1.07 2 1 4 40. 01 41.41 0.91 2 1 5 43.00 44.63 0.78 2 1 6 20.76 19.59 3.06 2 1 7 4. 12 2.86 6.23 2 1 8 8.53 9.73 7.41 2 1 9 15.24 13.76 5.05 2 1 10 22.4 2 21.51 2.53 H K L FO FC WEIGHT -2 1 11 38.37 38. 72 0. 97 -2 1 12 2.38* 0. 17 0.23 -2 1 13 34.38 34. 34 1.18 -2 1 14 14. 10 14.53 4. 52 -2 1 15 4.89 4.56 3.04 -2 1 16 1.84* 1. 28 0. 09 -2 1 17 9.51 9.73 5. 66 • -2 1 18 5.73 5. 35 6.48 -1 1 1 48.57 42. 93 0.61 -1 1 2 28.53 29.52 1.41 -1 1 3 28.89 31. 86 1.63 -1 1 4 22.08 24. 75 2.74 -1 1 5 47.80 53. 23 0.63 -1 1 6 8. 55 8. 21 9. 79 -1 1 7 51.29 56. 06 0. 55 -1 1 8 24.70 24. 91 •2 • 2 2 -1 1 9 5.21 4. 29 8.49 -1 1 10 10,87 10. 51 7.04 -1 1 11 2.14* 1.94 0. 19 -1 1 12 3.61 2. 04 5. 65 -1 1 13 4. 54 6. 17 2. 93 -1 1 14 15.13 15.75 4. 30 -1 1 15 9.51 9. 52 5. 51 -1 1 16 1.94* 0. 28 0.11 -1 1 17 7.25 7. 05 7. 28 -1 1 18 3.50 2. 04 4.64 0 1 1 27.60 30. 18 1. 75 0 1 2 21 .13 24. 22 2.96 0 1 3 6.63 7. 25 1 3.99 0 1 4 14.79 16.73 5. 12 0 1 5 3.03 2.72 6.29 0 1 6 37.51 40. 34 1.02 0 1 7 41.99 43. 75 0.82 0 1 8 20.48 21.05 3. 04 0 1 9 19. 87 20. 38 3. 25 0 1 10 12.67 14. 12 5.55 0 1 11 9.56 10. 29 5. 27 0 1 12 23.24 23.87 2. 36 0 1 13 8.26 7. 81 7. 81 0 1 14 10.44 10. 72 6.10 0 1 15 4.04 2.58 4. 80 0 1 16 1 .97* 0.71 0. 13 0 1 17 8.46 8. 27 7.18 0 1 18 4.05 3. 29 7.36 1 1 0 83.54 82.22 0.21 1 1 1 20. 83 21. 18 3. 13 1 1 2 11.74 12. 28 7.72 1 1 3 63. 58 69. 94 0. 36 1 1 4 49.91 53.45 0,58 1 1 5 8.04 8. 12 9.51 1 1 6 2.83 2. 08 5. 93 1 1 7 10.25 12.57 7.32 1 1 8 15.34 15.09 4.68 1 1 9 15.94 16. 38 4. 62 1 1 10 4.81 3. 10 5. 00 1 1 11 18. 13 18. 26 3. 44 1 1 12 5.76 3.54 6.89 1 1 13 16. 22 16. 19 3. 89 H K 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 •3 3 3 3 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 FO FC WEIGHT 14 15 16 17 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 0 1 2 3 4 5 7. 24 6.92 3.08* 0.25 9.56 8.93 7.96 7,18 49.39 50.43 68.70 69.59 31.20 30.08 69.94 71.77 12.00 12.49 45.82 46.29 39.08 39.02 12.39 13.17 11.07 10.99 13.97 14.02 5.74 5.40 2.93* 2.01 17.23 16.81 9.35 9.85 6. 50 6.31 4. 52 3.57 3.70 2.61 129.16 129.05 12.58 12.43 34.71 20. 22 11. 49 6. 03 3. 79 38. 86 1.48* 12.96 2.65* 23. 37 0. 00* 22. 46 3. 2 8* 3. 12* 42.74 0. 00* 16. 92 50. 24 26. 10 12. 39 18.62 14.72 4.58 15.61 8. 24 0. 87* 12. 70 6. 83 8.53 2.78* 3. 23 9. 41 38.07 22.78 12.53 35.71 21.07 11.47 5.30 2.53 39.60 0. 77 12.75 0.48 23.62 0. 40 22. 24 3.39 2.23 42.21 1.10 18.72 50. 77 26.67 12.77 18.45 15.02 5.30 15.75 8.32 1. 48 11.96 5.67 7.66 1.33 3. 33 9.69 38.82 23.24 12. 09 5.77 0. 36 7,32 8.06 0.61 0. 32 1. 45 0.30 7.03 0. 68 0.94 6.24 6.21 5.48 6. 17 0.24 3.46 6. 08 7.40 4.72 4.94 0.09 6. 80 1.18 3.11 6. 99 8.79 6. 21 0.95 0.08 5.64 0. 20 2.31 0.00 2.34 0.24 0.30 0. 80 0.01 4. 16 0.58 1.95 5. 96 3.46 4. 81 3.71 4. 13 5. 97 0.02 4 .96 8.41 9. 80 0.48 3.90 8.72 0. 98 2. 50 5.91 H K I FO FC WEIGHT 5 1 6 5,66 4.57 6.51 5 1 7 21.08 21. 36 2. 61 5 1 8 8.22 8. 81 5. 30 5 1 9 5.53 4.96 4.54 5 1 10 6.29 6. 02 5. 14 5 1 11 3,26* 2.33 0.26 5 1 12 14.63 14.71 4.72 5 1 13 3.76 3. 39 3. 67 6 1 0 10.19 10. 86 7.58 6 1 1 16.44 16. 32 4. 47 6 1 2 0.00* 1. 17 0.01 6 1 3 7,12 5. 73 8.68 6 1 4 4,91 4. 30 4.04 6 1 5 6.41 6. 36 5. 42 6 1 6 7.00 6.71 6.20 6 1 7 16. 21 15. 73 3. 30 6 1 8 4. 15 2.90 4. 46 6 1 9 2.87* 0.83 0.29 6 1 10 3. 28 0. 71 3.61 6 1 11 10.96 10.78 5, 12 6 1 12 0.00* 0.48 0.00 7 1 0 8.39 8. 40 9.06 7 1 1 8,26 7.77 8.53 7 1 2 14.59 14. 26 4. 89 7 1 3 19.36 19.41 3.08 7 1 4 8. 24 8. 48 5.79 7 1 5 14. 28 14. 57 4.81 7 1 6 6.81 6. 64 5. 56 7 1 7 5,38 4.94 4.42 7 1 8 2.03* 0.50 0,11 7 1 9 17.46 17. 63 3. 58 7 1 10 4.87 4.45 4.54 7 1 11 2.47* 1, 04 0.25 8 1 0 6.01 5. 19 5.72 8 1 1 12.87 13. 13 4.64 8 1 2 6.71 6. 50 6. 29 8 1 3 15. 30 15. 00 4.00 8 1 4 5.67 5. 22 4. 82 8 1 5 3.93 1. 97 4. 14 8 1 6 4.82 3.63 5.45 8 1 7 3.51 1. 69 3.95 8 1 8 2.76* O.07 0.24 8 1 9 3. 84 3. 96 3. 68 9 1~ 0 9.01 8.72 6.50 9 1 1 9.36 9. 76 6. 26 9 1 2 8.10 •8, 67 5.09 9 1 3 5.44 6. 09 4. 47 9 1 4 9.09 9. 98 6, 10 9 1 5 8.89 8. 66 7.59 9 1 6 3.45 0. 54 4. 26 9 1 7 6.64 6.78 5.29 9 1 8 5. 33 4. 35 8. 24 • 10 1 0 4.17 2. 84 4,50 10 1 1 3.24* 0. 34 0.35 10 1 2 6.03 6. 04 5.07 10 1 3 12.53 13.23 5.02 10 1 4 3.43* 4. 18 0. 24 10 1 5 8,03 8, 69 6.49 H K I FO FC WEIGHT 10 1 6 2. 80* 2.61 0.26 11 1 0 3.71 1.41 3. 95 11 1 1 7.32 7. 97 5. 13 11 1 2 5. 74 5.27 7.54 11 1 3 0. 00* 0.48 0.00 11 1 4.36 4.35 6.02 12 1 0 1.95* 1.90 0. 13 12 1 1 1.79* 2.32 0. 08 12 1 2 5.54 6.12 5.44 13 1 0 2. 82* 3.29 0. 26 13 2 1 5. 04 4.91 5. 59 13 2 2 1.43* 1.86 0. 06 13 2 "3 3. 15* 1.91 0.37 13 2 10. 61 11.91 5. 30 13 2 5 3.25* 2.97 0.25 13 2 6 5.42 5. 96 , 4.48 13 2 7 3.26* 2.04 0. 30 13 2 8 1.63* 1.71 0.06 13 2 9 4.94 4. 24 6.66 13 2 10 0. 00* 0.29 0.00 13 2 11 1. 38* 1.42 0.06 13 2 12 11.97 12.39 5.25 13 2 13 6. 94 7.88 4. 50 13 2 14 6.5 3 6.80 6.27 13 2 15 3.11* 1.01 0. 40 13 2 16 5.06 5.89 5.26 12 2 1 2.46* 0.76 0. 20 12 2 2 10. 52 10.90 5. 84 12 2 3 2.37* 2.15 0. 16 12 2 4 6.44 5.29 5.67 12 2 5 1.59* 0.39 0.07 12 2 6 3.76* 4. 14 0. 24 12 2 7 2.74* 2. 24 0. 18 12 2 8 11.14 12.12 5. 20 12 2 9 4. 24 2.99 3. 34 12 2 10 5. 34 4.25 6. 12 12 2 11 8. 63 8. 83 6. 17 12 2 12 9.24 9.83 5.47 12 2 13 6. 15 5. 86 7.30 12 2 14 3.10* 0.98 0.39 12 2 15 2.35* 0.97 0.15 12 2 16 6. 68 7. 47 5.27 12 2 17 2. 19* 2.08 0. 13 12 2 18 2. 27* 0.83 0.23 11 2 1 7. 18 6.61 5.78 11 2 2 2.99* 3.47 0.15 11 2 3 3.86 4.33 2.73 11 2 4 3.96 2.40 4.01 11 2 5 4.74 3.19 5.07 11 2 6 3.06* 1.97 0.21 11 2 7 5.25 3.44 5.65 11 2 8 5.96 5.89 3.83 11 2 9 3.78 3.36 2.63 11 2 10 13.08 13. 12 4.64 11 2 11 5.00 4.4 9 3.93 11 2 12 24. 97 25.34 1. 97 11 2 13 3.78 1.81 3. 87 11 2 14 17.45 17.88 3.30 H K L FO FC WEIGHT — 11 2 15 2. 12* 2. 00 0.13 -11 2 16 4.39 3. 68 4. 24 -11 2 17 2.71* 1.74 0. 26 -11 2 18 6.69 7. 19 6.01 -10 2 1 9.45 10. 06 4. 52 -10 2 2 7. 24 7.43 4.63 -10 2 3 15.84 16. 03 3.57 -10 2 4 16.84 17.02 3.55 -10 2 5 2.01* 2. 16 0,08 -10 2 6 8.16 7. 79 6.17 -10 2 7 7.89 7. 91 4.48 -10 2 8 21.62 22. 07 2. 38 -10 2 9 9.74 9.09 5. 34 -10 2 10 7.24 7. 06 5.71 -10 2 11 13.25 14. 03 4. 64 -10 2 12 8.56 9.20 5.00 10 2 13 13. 88 14. 51 4. 18 -10 2 14 10.34 11. 12 4. 65 -10 2 15 4.26 2. 57 4.78 -10 2 16 8.64 8.93 5.60 -10 2 17 0.42* 2. 52 0.00 -10 2 18 5.20 6.20 5.00 -9 2 1 4.44 3.46 3. 83 -9 2 2 7.63 6. 96 6.43 -9 2 3 11. 16 11. 56 5. 10 -9 2 4 16.63 16. 78 3. 64 -9 2 5 4.24 2. 80 3.35 -9 2 6 3.41 2. 85 3. 15 -9 2 7 7.88 7. 57 5.98 -9 2 8 20.58 22. 11 2.71 -9 2 9 5.60 5. 15 5.51 -9 2 10 17.58 17. 84 3.22 -9 2 11 9.47 10. 28 4. 90 -9 2 12 16.07 16. 16 3.75 -9 2 13 0.00* 0. 69 0.00 -9 2 14 3.98 3. 01 4. 13 -9 2 15 2.26* 0. 04 0. 12 -9 2 16 2.66* 1. 53 0. 18 -9 2 17 5. 23 4. 35 6.63 -g 2 18 9.11 9. 25 6.39 -8 2 1 21.21 20.58 2. 65 -8 2 2 14.83 14. 69 4.50 -8 2 3 6.70 6. 89 6. 48 -8 2 4 5.07 3. 42 5. 32 -8 2 5 8.18 7. 41 7. 15 -8 2 6 7.83 8. 17 8. 16 -8 2 7 4.02 3. 83 5.05 -8 2 8 13.69 13. 75 4. 68 -8 2 9 4.54 4.91 3.40 -8 2 10 4.39 3. 39 3.67 -8 2 11 4.22 3. 01 4. 06 -8 2 12 19.11 20. 19 3. 22 -8 2 13 2. 64* 2. 07 0. 18 -8 2 14 21.64 22. 04 2. 57 -8 2 15 10.22 10.72 5.11 -8 2 16 5.75 4. 93 6. 23 -8 2 17 4.90 3. 50 5.79 -8 2 18 11.64 11.97 5. 63 B K I FO FC HEIGHT 7 2 1 19.97 18. 81 3.03 7 2 2 66.68 62. 92 0. 33 7 2 3 41.49 40.07 0.82 7 2 4 47. 72 47.33 0.63 7 2 5 15. 24 14.72 4.62 7 2 6 27. 43 27.07 1. 82 7 2 7 6.69 5.61 7.82 7 2 8 36.45 36.18 1. 05 7 2 9 11.08 11. 14 6.47 7 2 10 3.01* 2.50 0.27 7 2 11 6.65 6.66 4. 86 7 2 12 11.97 12. 56 5.37 7 2 13 6.43 5.42 4.92 7 2 14 6.78 5.99 6.94 7 2 15 7.54 7.40 4.69 7 2 16 21. 22 22.07 2.55 7 2 17 4.85 6. 15 3. 17 7 2 18 13. 02 13.23 4.76 6 2 1 49.49 47.39 0.58 6 2 2 27. 15 26.35 1. 82 6 2 3 13. 51 13.07 5.18 6 2 4 3. 18* 2.63 0. 36 6 2 5 15. 15 13.43 4. 45 6 2 6 11. 14 12. 05 6.84 6 2 7 9.04 7.97 6.86 6 2 8 27. 16 28.36 1. 80 6 2 9 19.07 18.50 3.27 6 2 10 8. 67 8.25 6.45 6 2 11 11.91 11. 07 5.39 6 2 12 13.15 13. 11 4. 77 6 2 13 13. 22 13. 86 4.50 6 2 14 24.40 24.69 2.05 6 2 15 17.76 18.54 3.28 6 2 16 17.24 17.78 3.26 6 2 17 3.81 2.95 2. 78 6 2 18 6.66 7.45 4.23 5 2 1 5. 60 5.99 8.51 5 2 2 44. 41 41.33 0.73 5 2 3 49.20 44. 03 0.60 5 2 4 7.32 8.04 7.80 5 2 5 20. 94 20.72 2.94 5 2 6 4. 89 4.26 7. 41 5 2 7 12.26 11.58 6.45 5 2 8 22. 36 23.02 2. 53 5 2 9 8. 90 8.01 8.23 5 2 10 41.85 42.99 0.82 5 2 11 6.09 5.63 6.05 5 2 12 21.82 22. 87 2.47 5 2 13 23.87 24.37 2.21 5 2 14 14. 67 13.52 4. 40 5 2 15 2.21* 2.49 0.11 5 2 16 15.79 15.67 3.92 5 2 17 4.40 3.98 4. 84 5 2 18 15.81 16.64 4.01 4 2 1 19.44 17.59 3.24 4 2 2 55. 24 49.53 0.48 4 2 3 12.90 12. 36 5. 84 4 2 4 76.55 73.12 0.25 H K L FO FC WEIGHT -4 2 5 8.07 8. 49 7.79 -4 2 6 1-2.92 12. 40 6. 20 -4 2 7 26.05 25. 17 1.99 -4 2 8 10.48 11. 56 7. 34 -4 2 9 33.65 33. 18 1.25 -4 2 10 18. 25 17. 48 3.67 -4 2 11 8.11 7.81 6.99 -4 2 12 6.43 6. 98 5. 54 -4 2 13 7.57 7.27 7.73 -4 2 14 13.92 14. 62 4. 49 -4 2 15 6.05 6. 24 4. 74 -4 2 16 16.90 16.92 3. 85 -4 2 17 2.93* 1.60 0. 30 -4 2 18 9.41 8. 82 6. 91 -3 2 1 20.73 18. 12 2.98 -3 2 2 16.07 16. 47 4.39 -3 2 3 46.35 41. 54 0.68 -3 2 4 7.85 8. 39 8. 40 -3 2 5 1.60* 0. 83 0. 19 -3 2 6 4.03 3. 40 4.62 -3 2 7 11.61 12. 32 6. 20 -3 2 8 15.42 16.57 4.76 -3 2 9 4.19 4.36 6.26 -3 2 10 20.92 22. 22 2. 97 -3 2 11 10.26 10. 12 6.51 -3 2 12 3.46 3. 24 3. 15 -3 2 13 27.4 9 26.71 1.76 -3 2 14 26.37 27. 68 1. 93 -3 2 15 2.51* 1.21 0. 14 -3 2 16 8.72 8, 85 4. 94 -3 2 17 2. 84* 1. 71 0.30 -3 2 18 2.36* 0. 91 0. 19 -2 2 1 0.28* 1.01 0.01 -2 2 2 37.86 33. 08 0.99 -2 2 3 16. 25 14. 67 4.35 -2 2 4 86.09 84.78 0. 20 -2 2 5 39.32 41. 10 0.92 -2 2 6 46.74 4 7. 46 0.66 -2 2 7 0.00* 2. 15 0. 01 -2 2 8 1.60* 3. 46 0. 10 -2 2 9 16.69 15. 61 4.06 -2 2 10 30.72 32.03 1. 46 -2 2 11 6.65 6.39 6.09 -2 2 12 9.04 8. 58 5. 83 -2 2 13 5.99 5.51 4. 09 -2 2 14 20.97 22. 00 2. 74 -2 2 15 10.51 11.52 5,58 -2 2 16 6.50 6. 52 5. 17 -2 2 17 9.13 8. 17 7.82 -2 2 18 11.10 10. 92 5, 83 -1 2 1 13.28 12.70 4. 35 -1 2 2 46.37 44.89 0.65 -1 2 3 9.66 9.56 9. 14 -1 2 4 55.66 60. 91 0.47 -1 2 5 34.76 36. 98 1. 18 -1 2 6 8.83 10. 03 8. 03 -1 2 7 42.39 42. 80 0.81 -1 2 8 6.65 6.94 8.64 H K 1 FO FC WEIGHT 2 9 22.41 21.86 2. 53 2 10 24.77 25.41 2.13 2 11 20. 93 21.10 2.70 2 12 1. 24* 0.88 0.04 2 13 7.50 6.77 5. 80 2 14 6. 90 6.06 6.75 2 15 1. 32* 0.31 0. 04 2 16 4.19 4. 17 2. 69 2 17 2.97* 0.56 0.42 2 18 2. 84* 3.16 0.23 0 2 0 26.51 20.38 1.58 0 2 1 39. 84 41.81 0.85 0 2 2 35. 92 40.41 1.09 0 2 3 2.76* 3.39 0.42 0 2 4 27.47 33.09 1.81 0 2 5 1. 60* 0.34 0. 21 0 2 6 2.40* 1.70 0.33 0 2 7 17. 36 16.65 3.98 0 2 8 3.26 3.95 3.71 0 2 9 3. 90 4.24 3.70 0 2 10 19.47 21.01 3. 20 0 2 11 3.46 3. 82 3.07 0 2 12 3. 70 2.73 2.84 0 2 13 4. 46 2.53 4.71 0 2 14 14.85 15.67 4. 18 0 2 15 8.10 7.64 7.46 0 2 16 4. 68 5.47 2.94 0 2 17 4.00 3. 32 3.92 2 0 36. 01 36.65 1.06 2 1 11. 53 11.72 7.41 2 2 51. 48 55.54 0. 55 2 .3 21.39 23.55 2.89 2 4 51.94 56.76 0.54 2 5 26. 50 27. 37 1.93 2 6 27. 34 2 9.36 1.81 2 7 28.45 28.46 1.66 2 8 20.79 21.31 2.88 2 9 8.61 8.27 6.76 2 10 17.55 17, 36 3. 42 2 11 2.07* 1.54 0. 12 2 12 5. 84 4.19 6. 08 2 13 5. 12 3.89 5. 19 2 14 19.65 20. 15 2.92 2 15 4. 45 3.66 3. 91 2 17 0. 94* 0. 19 0.04 2 2 0 55. 92 56.26 0. 47 2 2 1 2. 10* 1. 39 0.43 2 2 2 5. 20 4.83 5.95 2 2 3 17. 33 17.46 4.03 2 2 4 23. 23 24.74 2.43 2 2 5 37.80 36.75 1.01 2 2 6 25.15 26.54 2.15 2 2 7 6. 44 5.00 7.90 2 2 8 34. 29 35.03 1. 19 2 2 9 12.99 13.02 5. 26 2 2 10 7.24 6.97 6.25 2 2 11 4. 80 3.64 5.35 2 2 12 9.08 8.67 7.00 H K I FO FC ¥ EIGHT 2 2 13 5.75 5. 74 3. 77 2 2 14 9.56 9.90 5.07 2 2 15 4. 33 4. 90 3.79 2 2 16 2.62* 0. 65 0.37 3 2 0 22.05 23. 11 2.72 3 2 1 46.79 46. 81 0. 66 3 2 2 10.11 9. 57 8.27 3 2 3 17.81 17.25 3.84 3 2 4 7.99 6.75 8. 57 3 2 5 20.02 20. 97 3.06 3 2 6 38.75 39. 45 0. 95 3 2 7 15.87 16.56 4.12 3 2 8 9.07 8. 75 7. 08 3 2 9 4.08 4.06 3. 56 3 2 10 7.87 7. 61 5.82 3 2 11 9.44 9.15 5.00 3 2 12 6.97 6.91 5. 41 3 2 13 4.78 5. 01 3. 24 3 2 14 3.49 2.08 3. 35 3 2 15 2.48* 0. 86 0. 31 4 2 0 2.72* 3. 95 0. 3 1 4 2 1 17.63 17.15 3.83 4 2 2 19.59 20. 74 3. 20 4 2 3 14.51 14.23 5.19 4 2 4 13.70 12. 54 5. 27 4 2 5 15.36 14. 65 4.40 4 2 6 13.55 14. 44 5.54 4 2 7 6.59 6. 67 6.47 4 2 8 3.21* 0.59 0. 38 4 2 9 2.66* 2. 83 0. 12 4 2 10 17.45 18. 82 3.49 4 2 11 4.51 4. 49 3. 39 4 2 12 0.93* 0.37 0.02 4 2 13 2.57* 1. 47 0.22 4 2 14 3.48 2. 81 3. 59 5 2 0 46.49 49.88 0.67 5 2 1 11. 13 10. 63 6. 83 5 2 2 10.00 10. 58 7. 91 5 2 3 6.03 5. 39 8. 72 5 2 4 11.32 11. 10 6.81 5 2 5 6.41 6. 70 4. 83 5 2 6 16.92 16. 85 3. 99 5 2 7 4.68 3. 98 3. 91 5 2 8 0.00* 0. 86 0. 00 5 2 9 4.39 3. 07 4.45 5 2 10 2.12* 1.51 0.11 5 2 11 6.59 6. 93 4. 78 5 2 12 0.00* 0. 46 0. 00 5 2 13 3.00* 0.27 0.43 6 2 0 44. 82 47. 34 0.71 6 2 1 3.47 3. 37 3. 89 6 2 2 14.10 15. 10 4.70 6 2 3 4.89 4. 44 5. 73 6 2 4 11.67 11. 10 6. 03 6 2 5 5. 16 4. 48 4. 61 6 2 6 22.38 23.49 2.44 6 2 7 2. 88* 0. 24 0.27 6 2 8 5.04 3.84 5.21 H K I FO FC WEIGHT 6 2 9 5. 24 4.81 3.36 6 2 10 13.58 13.54 4. 89 6 2 11 3. 40* 3. 16 0. 29 6 2 12 9.37 9.68 7. 30 7 2 0 13. 31 1 4. 30 4.59 7 2 1 2.96* 2.83 0.31 7 2 2 9.94 10. 27 5.34 7 2 3 2. 74* 0.59 0.21 7 2 4 6.46 5.66 6.85 7 2 5 7.79 7.77 5.64 7 2 6 9.09 9.23 5.73 7 2 7 5.91 6.17 4.65 7 2 8 2. 65* 1.33 0. 26 7 2 9 2.55* 1.48 0.20 7 2 10 13.17 13.88 4.71 8 2 0 14.65 16.06 4.50 8 2 1 5. 78 5. 81 4.16 8 2 2 13.95 14.68 4. 18 8 2 3 3. 46* 4. 11 0.19 8 2 a 8.65 8.98 5.70 8 2 5 1.92* 1.21 0.09 8 2 6 4. 68 4. 86 3.69 8 2 7 3.02* 1.60 0.24 8 2 8 10.43 10.90 5.67 8 2 9 8.86 8.16 10. 11 9 2 0 4. 53 4.06 3.51 9 2 1 2. 90* 0.71 0. 27 9 2 2 4. 25 2.63 4.25 9 2 3 6.97 7.36 4.29 9 2 9.6 5 10.41 5. 21 9 2 5 7.59 7.22 6,23 9 2 6 5.95 5. 84 6. 15 9 2 7 1. 49* 0. 90 0.07 10 2 0 11.65 11.54 5. 38 10 2 1 8. 50 7.24 7. 03 10 2 2 15.52 16.66 4.34 10 2 3 7. 87 8. 48 5. 32 10 2 a 3.97 1.86 5.30 10 2 5 3. 60 2.41 4.01 10 2 6 6.65 6.16 9. 51 11 2 0 7. 83 8.13 7. 50 11 2 1 4.93 2.82 6. 20 11 2 2 11. 12 1 1.56 5.40 11 2 3 3.42 1.89 3.78 11 2 4 6. 41 6.04 9.30 12 2 0 10.74 1 1.26 5.75 12 2 1 4. 22 2. 27 7.73 12 2 2 5. 29 4.25 11.55 13 3 3 1.76* 2. 56 0. 10 13 3 4 4. 47 4.36 4. 87 13 3 5 4. 83 5.74 4. 05 13 3 6 6.11 6.95 4.96 13 3 7 2. 94* 0.53 0. 30 13 3 8 2. 17* 0. 25 0.13 13 3 9 10. 81 11,77 4.81 13 3 10 2. 13* 0. 32 0, 13 13 3 11 5. 85 6.02 4.70 13 3 12 3. 03* 3.06 0. 27 H K L FO FC WEIGHT -13 3 13 1.57* 1.58 0. 09 -13 3 14 1 .96* 2. 36 0. 12 -12 3 1 5.65 7. 81 4. 12 -12 3 2 3.81 2. 12 3.96 -12 3 3 1.96* 0. 60 0. 10 -12 3 4 14.16 16. 99 3.75 -12 3 5 5.81 5.71 5.41 -12 3 6 2.02* 2. 24 0. 11 -12 3 7 4.61 5. 10 3.06 - 12 3 8 6.81 7.57 4.79 -12 3 9 9.45 10. 20 4. 91 -12 3 10 2.93* 2. 81 0. 17 -12 3 11 10.21 11. 30 4,58 -12 3 12 1.49* 2. 77 0. 05 -12 3 13 4.08 3. 66 3. 98 -12 3 14 3.04* 1.54 0.31 -12 3 15 5.67 5. 56 7.20 -12 3 16 3.70 4. 62 2.72 -11 3 1 9.62 10. 97 5.09 -11 3 2 10.74 13. 85 4. 88 - 11 3 3 4.41 5.68 2.70 -11 3 4 14.56 17.87 3.82 -11 3 5 8.99 8. 37 7.09 -11 3 6 1.14* 1. 96 0.02 - 11 3 7 9.29 9.63 5.11 -11 3 8 4 .25 2. 82 4.42 -11 3 9 5.50 4. 76 5.91 -11 3 10 9.31 9. 81 4.54 -11 3 11 8.79 9.24 5.19 -11 3 12 13. 28 13.78 4. 41 -11 3 13 4.65 5. 17 3. 15 -11 3 14 2. 95* 0. 79 0.24 -11 3 15 7.62 7. 81 6.03 -11 3 16 11 .52 12. 80 5.28 -11 3 17 3.59 3. 17 3.68 -10 3 1 4.19 4. 16 3.09 -10 3 2 11.00 11. 58 5.00 - 10 3 3 11.18 11.98 4.49 -10 3 4 16. 92 17. 68 3. 29 -10 3 5 16.11 17. 31 3.45 -10 3 6 14.78 14. 66 3. 93 - 10 3 7 3.38* 4. 33 0, 18 -10 3 8 11.64 11. 89 5.44 -10 3 9 6.90 6. 20 5.30 -10 3 10 6.61 6. 18 5. 10 - 10 3 11 14.64 15.67 3.95 -10 3 12 6.08 6. 35 4. 83 - 10 3 13 3.82* 4, 86 0.23 -10 3 14 2.56* 2. 60 0. 16 -10 3 15 4.97 4.73 3,93 -10 3 16 9.49 9. 33 6. 15 - 10 3 17 2.70* 1.91 0. 28 -10 3 18 2.39* 2.78 0. 17 -9 3 1 30.27 29.18 1.44 -9 3 2 21.08 21. 15 2.51 -9 3 3 9.42 8. 97 4.68 -9 3 4 12.56 12. 25 4. 53 -9 3 5 10.50 9. 68 5.35 B K I FO FC WEIGHT 9 3 6 2. 72* 2.50 0. 14 9 3 7 5. 90 5.99 4. 14 9 3 8 5. 30 2.77 4.54 9 3 9 3. 19* 2.55 0. 24 9 3 10 4.65 4.84 3. 72 9 3 11 2. 22* 2.84 0.12 9 3 12 13.00 12. 68 4.66 9 3 13 13. 6 2 13.44 4. 20 9 3 14 5. 86 5.54 6.39 9 3 15 21.72 22.39 2.52 9 3 16 6.72 6. 11 6.21 9 3 17 9.21 9.57 5.10 9 3 18 6. 54 6.31 6. 84 8 3 1 19.35 18. 28 3.05 8 3 2 16.69 14.98 3.70 8 3 3 25. 32 2 5.11 1.92 8 3 4 1. 29* 0. 46 0.04 8 3 5 10.50 8.95 6. 47 8 3 6 12. 80 12.65 4. 84 8 3 7 5.90 5.46 4.75 8 3 8 3.91 3.03 2.70 8 3 9 14.95 14.56 4.12 8 3 10 16.49 16.71 3.37 8 3 11 28.01 28.12 1.67 8 3 12 12. 36 12.39 4.46 8 3 13 13. 15 13.01 5.03 8 3 14 5.41 5.39 4.29 8 3 15 3. 92* 4. 89 ; 0.20 8 3 16 14. 82 14.71 4. 15 8 3 17 8.52 8. 85 7.07 8 3 18 3.18* 0. 96 0. 38 7 3 1 13. 36 12.41 4. 54 7 3 2 9. 88 9.67^ 5.80 7 3 3 1. 64* 1.39 0.07 7 3 4 2.55* 1.57 0.19 7 3 5 27.06 25.69 1.81 7 3 6 4.21 3.90 3.81 7 3 7 23. 68 23. 72 2.18 7 3 8 3.65 1.65 3. 60 7 3 9 9.98 9. 83 6.57 7 3 10 28. 26 29.52 1.61 7 3 11 25. 15 25.79 1.94 7 3 12 17.51 18. 26 3. 22 7 3 13 16. 33 16. 04 3.77 7 3 14 9.72 9.57 5.71 7 3 15 2. 17* 3.55 0. 08 7 3 16 8. 41 8.71 5. 15 7 3 17 1.51* 0.65 0.07 7 3 18 4. 33 3.81 3.29 6 3 1 27. 67 24.73 1.73 6 3 2 33. 34 30. 12 1. 21 6 3 3 7.23 5.24 6.60 6 3 4 6. 11 5. 3 9 6.06 6 3 5 4. 16 4.32 3. 33 6 3 6 30.87 29.39 1.42 6 3 7 23. 39 22.91 2.36 6 3 8 8. 51 7.22 6.29 6 3 9 8.40 8.01 6.40 H K L FO FC WEIGHT -6 3 10 1 .42* 0. 31 0.05 -6 3 11 3.25* 2.24 0. 28 -6 3 12 16.39 17. 35 4, 04 -6 3 13 13.92 13. 34 4.41 -6 3 14 12.34 12. 05 4.72 -6 3 15 19.85 20. 43 2. 86 -6 3 16 6.07 6. 42 4. 97 -6 3 17 8.01 8.36 5.54 -6 3 18 3.79 3. 86 3.02 -5 3 1 32.82 30. 26 1.29 -5 3 2 14. 28 12. 14 4. 55 -5 3 3 3.38 4.51 3,21 -5 3 4 2.32* 1. 27 0.23 -5 3 5 36. 81 34. 01 1. 04 -5 • 3 6 20.68 19.52 2.87 -5 3 7 33.54 32. 72 1.24 -5 3 8 7.16 7. 36 6. 87 -5 3 9 7.34 6. 96 7.41 -5 3 10 17.78 17. 24 3. 50 -5 3 11 22.79 23. 87 2.36 -5 3 12 7.06 7. 35, 5. 55 -5 3 13 11.53 11.62 5.36 -5 3 14 3.93 4. 08 2. 50 -5 3 15 14.48 14. 52 4, 15 -5 3 16 1.61* 0. 79 0. 06 -5 3 17 6.73 5. 87 5.83 -5 3 18 5.36 4.38 7. 90 -4 3 1 56. 10 49. 08 0. 46 -4 3 2 33.78 29. 94 1. 22 -4 3 3 61.11 52. 45 0.39 -4 3 4 11.35 9. 91 6. 07 -4 3 5 2. 45* 1. 46 0. 23 -4 3 6 13.75 11. 91 5.29 -4 3 7 7.74 8. 46 8. 10 -4 3 8 28.69 27. 13 1.67 -4 3 9 15.92 15. 27 4. 36 -4 3 10 10.65 10.31 5.43 -4 3 11 17.71 17. 70 3.43 -4 3 12 1.66* 0. 35 0.07 -4 3 13 13. 87 13. 80 4.34 -4 3 14 3.46* •1. 05 0. 33 -4 3 15 15.12 14. 32 4.29 -4 3 16 1.98* 0.29 0.09 -4 3 17 12.46 12. 33 5. 18 -4 3 18 1.94* 2. 36 0. 11 -3 3 1 6.71 7.37 6.76 -3 3 2 15.55 12. 06 4,49 -3 3 3 27.62 25. 51 1.77 -3 3 4 36.67 32. 81 1.05 -3 3 5 7.54 6.75 6.85 -3 3 6 33.67 32. 49 1. 26 -3 3 7 21 .51 22.01 2.69 -3 3 8 2. 83* 0. 39 0.41 -3 3 9 9.93 9. 60 6, 16 -3 3 10 6.97 6.62 5.92 -3 3 11 9.49 9. 58 7.46 -3 3 12 7.12 7.15 5.69 -3 3 13 12.65 12. 41 4. 65 H K I FO FC WEIGHT -3 3 14 5.49 6.20 3. 21 -3 3 15 3. 90 1.91 3.72 -3 3 16 7.66 7.64 7.41 -3 3 17 7.87 7. 93 5. 88 -3 3 18 3.01* 1. 95 0. 37 -2 3 1 4.19 2.80 5.36 -2 3 2 36. 41 31.08 1.08 -2 3 3 2.03* 4. 36 0. 20 -2 3 4 23.64 22. 22 2.43 -2 3 5 24.41 24. 84 2.25 -2 3 6 7. 19 6.17 8.56 -2 3 7 50.06 50.66 0. 58 -2 3 8 4.64 2.81 6. 97 -2 3 9 13.04 13. 32 5.18 -2 3 10 6.36 6.46 5. 38 -2 3 11 17.75 18. 15 3.41 -2 3 12 11.79 11.75 4.95 -2 3 13 6.69 6.60 4.98 -2 3 14 18.91 19.87 3. 13 -2 3 15 3.67 1.44 3. 23 -2 3 16 3.68 2.14 3.76 -2 3 17 3. 47* 3.98 0.29 -2 3 18 3.09 1.87 4. 18 -1 3 1 55. 07 42.79 0. 48 -1 3 2 13. 12 12. 18 5.69 -1 3 3 35.06 34. 80 1. 16 -1 3 4 5.74 6.15 8.69 -1 3 5 3.77 3. 17 4.98 -1 3 6 40. 20 39.82 0.89 -1 3 7 17. 40 18.49 3.99 -1 3 8 43. 45 45. 04 0.77 -1 3 9 5. 27 3. 18 8.06 -1 3 10 10. 11 9.62 6.65 -1 3 11 14.67 15.20 4. 15 -1 3 12 1. 46* 0.39 0. 06 -1 3 13 8.34 7.41 6.92 -1 3 14 11. 17 12. 04 5.02 -1 3 15 12. 16 13. 15 5. 10 -1 3 16 4. 7 3 3.66 6.69 -1 3 17 9. 95 9.40 8.06 0 3 1 30. 88 33.59 1.46 0 3 2 65. 06 68.90 0.35 0 3 3 18.42 .19.70 3.62 0 3 4 14. 17 13.90 5.64 0 3 5 2. 88 2.35 4.66 0 3 6 13. 13 13. 94 5.42 0 3 7 27. 35 28. 85 1. 82 0 3 8 12.38 13.47 5.87 0 3 9 11.42 12.05 6. 34 0 3 10 4.84 6.54 3.62 0 3 11 8.53 9.08 6.09 0 3 12 14. 04 15.21 4.71 0 3 13 13.92 14.76 4. 41 0 3 14 16.01 16.99 3.96 0 3 15 3. 86 2. 91 3.38 0 3 16 2.65* 1.38 0.27 1 3 0 19. 89 20. 18 3. 18 1 3 1 13.92 15. 06 5.63 H K L FO FC WEIGHT 3 2 12.27 13. 03 6,73 3 3 30.55 33. 99 1.51 3 4 12.03 13.40 6.31 3 5 3.25 2. 11 3. 90 3 6 12.26 11.99 6.38 3 7 17.87 19.52 3.59 3 8 13.88 14. 00 1,81 3 9 6.67 7. 28 6.24 3 10 7.63 7. 93 5.98 3 11 12.86 13, 84 4. 68 3 12 2.74* 2.39 0.16 3 13 10.30 10.45 6.76 3 14 5. 43 5. 09 4. 97 3 15 2.87* 2.22 0.28 3 16 2.39* 1.75 0. 23 2 3 0 13. 85 15. 54 5. 41 2 3 1 14.30 13. 91 5. 39 2 3 2 16.60 -17. 86 4. 14 2 3 3 31.62 33. 45 1.41 2 3 4 7.45 7. 80 9. 14 2 3 5 6.35 6. 78 7. 86 2 3 6 3.72 3. 42 3.86 2 3 7 24.07 24. 81 2.29 2 3 8 13.86 13. 76 5. 13 2 3 9 10.31 11.93 4. 85 2 3 10 13.12 14. 36 4.64 2 3 11 6.27 4. 61 6.31 2 3 12 5.35 3. 46 5.72 2 3 13 4,52 3.10 5.36 2 3 14 4. 76 5, 10 3.99 2 3 15 3.06* 2. 52 0.32 3 3 0 12.79 12. 16 6. 14 3 3 1 16.03 16. 43 4. 33 3 3 2 8.48 9.20 7.21 3 3 3 27.40 28. 84 1.80 3 3 4 16.99 18. 62 3. 85 3 3 5 16.28 16. 35 4.17 3 3 6 8.96 8. 64 7. 33 3 3 7 6.85 7. 06 6. 43 3 3 8 5.47 6. 37 4. 80 3 3 9 2.30* 2. 05 0. 13 3 3 10 6.28 6. 04 6.35 3 3 11 8.68 9.44 5.89 3 3 12 3.09* 0. 33 0. 34 3 3 13 7.21 7. 11 7.03 3 3 14 5.19 4.55 7.30 4 ' 3 0 11.72 12. 07 6. 17 4 3 1 2.40* 1. 11 0.31 4 3 2 4.62 3. 67 7.74 4 3 3 15.40 16.57 4.39 4 3 4 1. 56* 0. 74 0.08 4 3 5 6.06 6. 51 5.34 4 3 6 14.55 14. 96 4. 81 4 3 7 11.87 13.03 5.06 4 3 8 4.85 3. 98 3. 77 4 3 9 11.68 11.63 5.40 4 3 10 15.17 16.45 4.13 4 3 11 11.72 11. 28 5. 81 H K I FO FC WEIGHT H K L 4 3 12 4.31 3.94 3.40 10 3 5 4 3 13 9. 44 9.79 6.67 11 3 0 5 3 0 17.73 19.21 3.75 11 3 1 5 3 1 7. 03 8.74 5.76 11 3 2 5 3 2 11. 39 10.89 6.25 11 3 3 5 3 3 14.69 15.53 4.73 12 3 0 5 3 H 2.42* 2.31 0.19 -13 4 8 5 3 5 6.54 6.20 4. 80 -13 4 9 5 3 6 9.31 9.98 4.63 -12 4 2 5 3 7 13.25 14. 45 4.57 -12 4 3 5 3 8 6.09 5.64 6.19 -12 4 4 5 3 9 17.31 18. 21 3.59 -12 4 5 5 3 10 6.75 6. 36 7. 59 -12 4 6 5 3 11 2. 35* 1.38 0. 19 -12 4 7 5 3 12 3. 98 3. 52 5.53 -12 4 8 6 3 0 0.98* 1.72 0.03 -12 4 9 6 3 1 12.92 12.85 5.74 -12 4 10 6 3 2 6. 45 5.76 6.44 -12 4 11 6 3 3 16. 26 17. 55 3. 98 -12 4 12 6 3 4 20.31 21.88 2. 92 -12 4 13 6 3 5 3. 92* 4.93 0.24 -12 4 14 6 3 6 8.82 9.44 4. 95 - 11 4 1 6 3 7 2.97* 0.73 0.28 -11 4 2 6 3 8 5.25 5. 34 4.34 -11 4 3 6 3 9 4.08 4.15 3.58 - 11 4 4 6 3 10 1.61* 0.33 0.07 -11 4 5 6 3 11 1.41* 0.21 0. 08 -11 4 6 7 3 0 2.43* 0.76 0. 19 -11 4 7 7 3 1 10.42 11.03 5.54 -11 4 8 7 3 2 8.32 8.87 5.23 - 11 4 9 7 3 3 26. 62 28.57 1 .80 -11 4 10 7 3 4 12.59 13. 27 5.15 - 11 4 11 7 3 5 6. 17 7.09 3. 83 -11 4 12 7 3 6 6.50 6.73 6.71 -11 4 13 7 3 7 7. 82 9.32 5. 20 -11 4 14 7 3 8 4.18 3.19 5.47 -11 4 15 7 3 9 4.94 4.34 6.08 -10 4 1 8 3 0 9.56 10.20 5. 16 -10 4 2 8 3 1 0. 68* 2.74 0.01 -10 4 3 8 3 2 13.42 14.09 4. 85 -10 4 4 8 3 3 7. 60 7.98 5. 40 -10 4 5 8 3 4 8. 33 8. 59 6.96 -10 4 6 8 3 5 8. 94 9.78 5. 21 -10 4 7 8' 3 6 2. 68* 1.69 0.29 -10 4 8 8 3 7 3.88 4.63 3.03 -10 4 9 8 3 8 3. 19 2.24 3.86 - 10 4 10 9 3 0 15. 14 16. 10 3.56 -10 4 11 9 3 1 13. 15 13.63 4. 94 -10 4 12 9 3 2 6.22 5.14 6. 30 -10 4 13 9 3 3 4. 15 3.91 3.12 -10 4 14 9 3 4 4. 90 5.28 4.37 -10 4 15 9 3 5 4. 68 3.77 6.65 -10 4 16 9 3 6 4. 90 4.53 6.32 -9 4 1 10 3 0 4. 16 3. 37 4.28 -9 4 2 10 3 1 6. 83 7.11 5. 62 -9 4 3 10 3 2 3. 54 1.31 4.05 -9 4 4 10 3 3 9. 89 10. 11 6.18 -9 4 5 10 3 4 1. 55* 1. 97 0.08 -9 4 6 FO FC WEIGHT 2.94* 2.29 0.44 12. 34 12. 80 4.59 5.16 5.64 4.56 3.39 2. 34 3. 91 4.11 3.90 6.70 2.63* 0.20 0.33 3.59 4.09 3.41 2.58* 1.12 0.27 11.97 13.18 5.29 2.89* 2. 45 0. 28 7.92 8.35 7.16 5.95 6.59 5.77 4.79 4.68 '4.31 2.79* 2.05 0.20 6.19 6. 16 6.79 2. 15* 0. 87 0. 12 5. 23 5. 28 6. 05 3.15* 2.61 0.35 9.42 10. 16 5.73 7.37 7. 08 7.55 2.88* 2.38 0.32 1.00* 0.33 0.03 1.78* 0.51 0.08 9.44 9. 43 6. 83 15.85 16.41 3.96 6.13 6.70 4.43 2.44* 2. 02 0. 12 7.95 8. 41 4. 53 4.84 4. 73 4. 14 6.58 5.78 5.74 5.34 4. 91 6.59 1.50* 1.34 0.05 3. 66* 2. 85 0. 28 3.75 1. 74 5.31 9.13 9.79 6.15 3.89 3. 44 4.04 3.38* 2.52 0.21 6. 53 6. 34 5. 39 14.38 14. 10 4. 07 3.99 0. 81 3.99 7.42 7. 85 5.47 3.09* 0. 96 0.20 5.74 6. 14 3.51 10.43 9. 94 5. 03 0.00* 2. 55 0.00 2.70* 2.67 0.16 6.09 5. 02 6.53 6. 24 6. 40 4. 29 2.75* 0.72 0.20 3.97 3. 52 2.81 7.91 8. 05 5. 65 7.09 6.57 6.19 3. 32* 3. 20 0. 17 18.44 17.26 3. 10 2.42* 0.55 0.12 3.84 2. 17 2.47 2.08* 2.44 0.07 5.19 3.70 3.78 H K L FO FC WEIGHT -9 4 7 17.78 17.47 3. 21 -9 4 8 23.99 23.82 2.06 -9 4 9 6. 94 6.43 5.00 -9 4 10 11. 48 11.62 4. 80 -9 4 11 3.70 1.16 3.41 -9 4 12 14. 52 15.27 3.99 -9 4 13 6. 04 6.40 3.96 -9 4 14 2. 66* 2.33 0.14 -9 4 15 6.67 6.02 8. 25 -9 4 16 11.80 11.70 5.55 -9 4 17 1.73* 0.77 0.11 -8 4 1 9.72 8. 24 5. 58 -8 4 2 20. 39 19.65 2. 64 -8 4 3 4.76 2.63 2.71 -8 4 4 26. 03 25.35 1.77 -8 4 5 3. 53* 2.26 0. 19 -8 4 6 6.45 5.08 4. 92 -8 4 7 4. 39 4.01 3. 16 -8 4 8 7.89 7.00 6.77 -8 4 9 4. 90 4.25 3. 54 -8 4 10 15.51 15. 17 4.18 -8 4 11 11. 16 11.01 4. 80 -8 4 12 15. 03 15.85 3.81 -8 4 13 3.60 0.40 3. 36 -8 4 14 10.75 10.45 5.84 -8 4 15 0. 00* 0. 92 0.00 -8 4 16 8.64 8.05 6. 20 -8 4 17 4.78 4.23 4. 86 -7 4 1 7.56 6.37 5.55 -7 4 2 6.73 6.91 4.39 -7 4 3 8. 13 7.71 5. 22 -7 4 4 24. 73 22.66 2. 11 -7 4 5 9. 66 9.36 4.70 -7 4 6 3.62* 2.45 0. 22 -7 4 7 15. 17 15.80 4. 19 -7 4 8 11.11 11.75 5. 14 -7 4 9 3.02* 1.41 0.20 -7 4 10 11.28 11.44 4. 81 -7 4 11 5. 71 5.38 3.30 -7 4 12 3.38* 2. 25 0.32 -7 4 13 3.95 2. 36 3. 69 -7 4 14 11.88 12.34 4. 87 -7 4 15 0. 26* 0.78 0.-00 -7 4 16 7.47 6. 68 6. 78 -7 4 17 0. 00* 1.26 0.00 -7 4 18 6. 85 6.64 8. 17 -6 4 1 1. 96* 0.28 0.07 -6 4 2 11.62 10.32 5.33 -6 4 3 2. 66* 2.61 0. 12 -6 4 4 25.5 5 24.87 1.96 -6 4 5 0. 00* 0.82 0.00 -6 4 6 5. 33 3.11 5. 00 -6 4 7 15. 69 14.19 3.89 -6 4 8 11. 58 11.82 4.69 -6 4 9 14.20 13.80 3.62 -6 4 10 4.23 3.44 3.06 -6 4 11 17. 02 17.81 3. 56 -6 4 12 12.46 12.24 4. 57 H K L FO FC WEIGHT -6 4 13 3.81 3. 07 3. 44 -6 4 14 11.91 12. 42 4. 80 -6 4 15 1. 78* 0. 30 0. 08 -6 4 16 3.56 2. 67 4. 25 -6 4 17 2.16* 1.46 0. 13 -6 4 18 3.48 3. 06 3. 81 -5 4 1 7.20 5.61 5.76 -5 4 2 2.86* 1.54 0.21 -5 4 3 3.46 0.72 3.38 -5 4 4 13.75 12. 91 4. 98 -5 4 5 17.31 16. 99 3.52 -5 4 6 4.23 4.53 2.66 -5 4 7 8.30 8. 24 5. 73 -5 4 8 30.23 28.53 1.46 -5 4 9 17.01 16. 80 3. 51 -5 4 10 2.49* 2. 40 0.11 -5 4 11 18.94 18.71 3.26 -5 4 12 4. 16 2. 94 2.70 -5 4 13 4.04 3.70 2.57 -5 4 14 13.32 13. 23 4. 47 -5 4 15 5.58 5.70 4.57 -5 4 16 4.92 3. 94 4. 60 -5 4 17 3.72 2.69 4.02 -4 4 1 24. 81 21.69 2. 12 -4 4 2 7.56 6.73 5.97 -4 4 3 7.32 6. 75 5. 23 -4 4 4 21.20 18. 03 2. 59 -4 4 5 5.75 4.95 5.54 -4 4 6 30.63 28. 62 1.45 -4 4 7 8.82 7. 84 5. 41 -4 4 8 29.41 29. 19 1.52 -4 4 9 29.05 29.70 1.53 -4 '4 10 33.54 34. 18 1.20 -4 4 11 4.64 3.92 3.36 -4 4 12 16.13 15. 86 3.73 -4 4 13 5.01 3. 54 4. 83 -4 4 14 15.80 15. 53 4. 14 -4 4 15 8.29 7. 68 7.38 -4 4 16 4.42 3. 13 5. 80 -4 4 17 0.19* 0.59 0.00 -3 4 1 24.35 20.06 •2. 16 -3 4 2 10.06 7. 20 7. 15 -3 4 3 27.32 24. 05 1.78 -3 4 4 27.34 24.68 1.77 -3 4 5 6.77 7. 28 5. 13 -3 4 6 25.97 24. 96 1.97 -3 4 7 12.03 12.03 6.06 -3 4 8 11.12 11. 29 6.19 -3 4 9 14.43 14. 92 4. 21 -3 4 10 4.44 4. 26 2. 72 -3 4 11 15.74 16. 11 3.67 -3 4 12 15.39 15.58 4. 20 -3 4 13 7.59 8. 06 5.49 -3 4 14 10.18 10. 25 5.77 -3 4 15 4.04 3. 53 3. 24 -3 4 16 0.00* 0.79 0.00 -3 4 17 3. 26 0. 61 4.02 -2 4 1 14.47 11.91 4.50 H K I FO FC HEIGHT -2 4 2 32. 64 27.05 1. 28 -2 4 3 3.32* 2.95 0.28 --2 4 4 23. 20 22.98 2.38 -2 4 5 11.06 11.08 6. 51 -2 4 6 3.76 2. 86 4. 40 -2 4 7 4.36 4.12 4.75 -2 4 8 7.11 7.4 9 6.51 -2 4 9 13. 80 13.32 5.33 -2 4 10 7. 16 6.66 6.93 -2 4 11 3. 26* 3.35 0.16 -2 4 12 5. 84 5.36 5.72 -2 4 13 3. 25* 2. 08 0.31 -2 4 14 9.45 9.71 5.19 -2 4 15 2. 11* 1.27 0. 13 -2 4 16 2. 84* 1.39 0.29 -1 4 1 22. 48 18.42 2. 41 -1 4 3 25.01 23.92 2. 11 -1 4 4 21.54 22. 25 2.79 -1 4 5 6.77 7.73 6.16 -1 4 6 13. 37 13.48 4.73 -1 4 7 2.73* 0.11 0. 26 -1 4 8 24.93 25. 31 2.08 -1 4 9 7. 20 7.10 4.93 -1 4 10 15. 57 16.20 4.24 -1 4 11 8.05 8.59 5. 53 -1 4 12 8.62 8. 35 6.80 -1 4 13 2.84* 1.61 0.26 -1 4 14 15.05 15.07 4. 33 -1 4 15 3. 17 1.04 4.04 -1 4 16 3. 3 2* 3.44 0.35 0 4 0 60. 56 48.96 0.39 0 4 1 25. 28 25.30 2.07 0 4 2 17.83 17.49 3.86 0 4 3 9. 46 10.05 7.65 0 4 4 4. 02 2.80 4.53 0 4 5 3. 13* 1.70 0.40 0 4 6 28. 47 28.78 1.64 0 4 7 3.00* 2.64 0. 28 0 4 8 14.41 15.57 4.24 0 4 9 2. 40* 3. 18 0. 14 0 4 10 2. 95* 1.77 0.19 0 4 11 8. 50 8. 30 6.77 0 4 12 6.00 6.03 6. 10 0 4 13 9.77 9.28 7. 11 0 4 14 5. 80 6.08 4.59 0 4 15 3. 83 4.01 3. 46 1 4 0 24. 18 24.70 2. 17 1 4 1 5. 15 5. 13 5.13 1 4 2 19.50 20.50 3.19 1 4 3 11.00 11.10 6.27 1 4 4 5.70 5.19 6.09 1 4 5 4. 58 5.33 3.54 1 4 6 18.69 19.78 3.41 1 4 7 2.10* 2.22 0. 13 1 4 8 0. 00* 1.07 0.00 1 4 9 2. 33* 1.64 0.13 1 4 10 23.81 24.74 2.20 1 4 11 11. 46 12.02 5. 42 H K L FO FC HEIGHT 1 4 12 3.38* 3.20 0. 25 1 4 13 6. 19 6. 57 5.74 1 4 14 5.84 6. 05 6. 84 1 4 15 2.80* 0. 37 0.41 2 4 0 30.18 29. 01 1. 53 2 4 1 2.48* 1. 04 0.26 2 4 2 20.05 20. 43 3.01 2 4 3 7.98 7.71 7. 12 2 4 4 12.32 12. 48 5.68 2 4 5 3.31* 3. 71 0.26 2 4 6 3.43 1. 96 4.03 2 4 7 8.81 9. 29 6. 15 2 4 8 13.07 14. 49 4.63 2 4 9 4.29 3.67 4.25 2 4 10 25.49 26. 97 1.94 2 4 11 2.79* 0.46 0.26 2 4 12 1.56* 1. 31 0.07 2 4 13 4.93 4. 11 5.52 2 4 14 8.20 7.73 9.24 3 4 0 32.07 31. 47 1.35 3 4 1 5.66 4.65 9.50 3 4 2 30.91 31.32 1.44 3 4 3 7.85 7. 85 6.38 3 4 4 29.91 31. 37 1.49 3 4 5 21.10 22. 59 2.72 3 4 6 5.21 5.15 4.44 3 4 7 3. 21* 1. 32 0. 33 3 4 8 3.66 2. 26 3. 39 3 4 9 7.41 7.61 6.78 3 4 10 7.41 6. 47 7. 11 3 4 11 4.31 4. 37 3.71 3 4 12 2.70* 2.81 0. 19 3 4 13 8.07 8. 31 7. 86 4 4 0 1.57* 1. 86 0. 08 4 4 1 11.40 11. 81 5.94 4 4 2 10.09 9.99 6.07 4 4 3 4.28 4.01 4.05 4 4 4 29.66 30. 17 1. 55 4 4 5 6.39 6.74 4. 28 4 4 6 19.01 20. 11 3. 14 4 4 7 1.13* 1. 02 0.03 4 4 8 8.29 8. 49 5.66 4 4 9 2.78* 0. 14 0. 26 4 4 10 4.70 3.57 5.72 4 4 11 3.87 3. 19 3.92 4 4 12 7. 33 6. 95 9.02 5 4 0 22.37 22. 04 2.65 5 4 1 15. 39 15. 64 4.05 5 4 2 29.97 31.46 1.48 5 4 3 13. 19 13. 47 4.69 5 4 4 3.98 3. 23 2.82 5 4 5 6.55 6. 20 6.35 5 4 6 15.60 15.83 4.45 5 4 7 2.24* 0. 60 0.11 5 4 8 1.21* 2. 40 0.03 5 4 9 6.39 6. 03 5. 89 5 4 10 9.19 9. 97 5, 83 5 4 11 1.84* 0.92 0.13 H K I FO FC WEIGHT 6 4 0 8. 11 7. 87 7.46 6 4 1 17.08 17.94 3. 48 6 4 2 16. 11 17.15 3.64 6 4 3 17. 00 17. 92 3. 58 6 4 4 2. 13* 3.22 0.07 6 4 5 9.75 9.71 5. 65 6 4 6 3.02* 3.00 0.20 6 4 7 4.73 3.65 5. 42 6 4 8 2.93* 0.93 0.37 6 4 9 0.00* 0.61 0.00 6 4 10 6. 29 6. 30 7.95 7 4 0 6. 16 5.6 8 4. 77 7 4 1 8. 39 8.41 6.80 7 4 2 3.41* 2.4 2 0. 33 7 4 3 9.45 9.07 5.65 7 4 4 6. 80 6.73 5.14 7 4 5 6.32 6. 27 5. 28 7 4 6 5.56 5.29 6.81 7 4 7 1.76* 0.72 0. 11 7 4 8 2.32* 0.29 0.24 8 4 0 16. 96 17. 54 3 * 5 8 8 4 1 8.57 8.16 5.62 8 4 2 11. 05 11.14 4.96 8 4 3 2.61* 1.92 0.16 8 4 4 1. 99* 1.19 0.11 8 4 5 1.92* 0.59 0.12 8 4 6 12.20 13.32 5.56 8 4 7 3.91 3. 15 • 4.66 9 4 0 6. 11 5. 33 6. 40 9 4 1 2. 22* 1.70 0.12 9 4 2 7.67 8.14 5. 30 9 4 3 2.46* 1.4 3 0. 19 9 4 4 0.00* 0.14 0. 00 9 4 5 3.64 3.74 3.85 10 4 0 3.08* 1.91 0. 26 10 4 1 4. 62 3.99 4. 82 10 4 2 7. 18 7.0 8 7.97 10 4 3 4.65 3.76 9.49 11 4 0 6.24 6.08 8. 15 11 4 1 4. 38 4.27 5.53 11 5 3 3.36 2.30 3. 62 11 5 4 2. 24* 1.06 0. 18 11 5 5 8.39 8. 92 5. 81 11 5 6 7. 84 8.39 6.25 11 5 7 7.67 7.11 8.27 11 5 8 1. 9 9* 0. 28 0. 13 11 5 9 7.68 7.83 6.23 11 5 10 5.19 5.3 9 4.70 11 5 11 2.66* 2.57 0. 25 11 5 12 3.02* 2.42 0. 35 10 5 1 6. 22 6. 49 5 • 35 10 5 2 0. 00* 1.01 0.00 10 5 3 0. 84* 2.71 0. 02 10 5 4 2. 46* 2. 17 0.11 10 5 5 2. 33* 2.65 0. 10 10 5 6 5. 80 5.22 5.71 10 5 7 6.31 6.21 6.11 10 5 8 4.73 4. 08 3. 59 H K L FO FC WEIGHT -10 5 9 2. 88* 1. 51 0.25 -10 5 10 2.76* 0. 64 0. 25 -10 5 11 1.19* 1.39 0.04 -10 5 12 4.38 4. 18 5.33 -10 5 13 0.00* 1.28 0.00 -10 5 14 3 . 76 2. 04 5.79 -9 5 1 9.88 10.02 5. 16 -9 5 2 4.54 4.07 3.02 -9 5 3 3.77 2. 13 2. 83 -9 5 4 4.62 4.70 2.86 -9 5 5 7.74 7.65 4.89 -9 5 6 3.09* 0. 39 0. 22 -9 5 7 0.00* 2. 68 0. 00 -9 5 8 9.30 8. 70 7. 23 -9 5 9 5.02 6. 00 2.69 -9 5 10 9.55 8. 78 7.47 -9 5 11 13.59 14. 54 4. 27 -9 5 12 3.43* 3.15 0.25 -9 5 13 2.72* 1. 83 0. 1 9 -9 5 14 0.84* 0.73 0.02 -9 5 15 3.23* 3. 67 0.31 -8 5 1 8.21 8. 59 3.71 -8 5 2 3.64* 2. 56 0. 20 -8 5 3 7.13 6. 54 4.32 -8 5 4 8. 36 7. 43 5.62 -8 5 5 9.80 9. 72 4. 94 -8 5 6 12.83 12. 45 4.60 -8 5 7 7.82 8. 02 4.59 -8 5 8 1 3.85 14. 31 4. 09 -8 5 9 4.41 3.53 2.49 -8 5 10 5.48 4. 33 5. 96 -8 5 11 1.52* 3. 28 0. 04 -8 5 12 4.67 2. 92 5. 71 -8 5 13 5.79 5.74 5. 82 -8 5 14 1 .79* 1. 34 0.09 -8 5 15 8.25 8. 51 7.55 -7 5 1 5.63 5.75 2.71 -7 5 2 19.14 19. 23 2.73 -7 5 3 11.57 11. 41 4. 01 -7 5 5 3.09* 1. 33 0.20 -7 5 6 3.77* 4. 45 0. 21 -7 5 7 18. 15 16. 62 3. 11 -7 5 8 2.38* 2.29 0.09 -7 5 9 9.46 9. 01 4. 78 -7 5 10 7.89 7. 45 5. 42 -7 5 11 10.51 10. 94 4. 45 -7 5 12 2.86* 2. 59 0. 14 * -7 5 13 5.48 5.02 4.92 -7 5 14 3.19* 3. 04 0. 22 -7 5 15 4.98 4. 37 6. 11 -7 5 16 7.54 7.36 7.08 -6 5 1 23. 20 20. 42 2. 14 -6 5 2 4.61 3. 03 2. 46 -6 5 3 8.72 8. 85 5.51 -6 5 4 3.56* 2. 63 0. 15 -6 5 5 16.88 16. 06 3.38 -6 5 6 2.31* 2. 95 0.07 -6 5 7 25.69 24. 55 1.94 H K I FO FC WEIGHT 6 5 8 9.9 8 10.38 4.74 6 5 9 3. 10* 0.71 0. 18 6 5 10 1.97* 1.26 0. 08 6 5 11 17. 52 17. 18 3. 83 6 5 12 4.95 3.93 5. 23 6 5 13 5.77 5.63 4.94 6 5 14 2. 26* 2.34 0.11 6 5 15 3.63 2.84 3. 78 6 5 16 4.06 3.21 4.55 5 5 1 29.66 25.45 1.50 5 5 2 6.94 7.06 3.59 5 5 3 11.46 10.44 4.41 5 5 4 4.07 2.98 2. 19 5 5 5 11.09 10.74 4. 90 5 5 6 18. 15 17.18 3. 16 5 5 7 5. 51 4.91 4. 06 5 5 8 9.40 10. 29 4.76 5 5 9 4.35 • 3.60 2. 85 5 5 10 10. 04 9.62 5. 45 5 5 11 17, 34 18.55 3.30 5 5 12 4.35 2.35 4. 35 5 5 13 2.95* 2.71 0.20 5 5 14 2.31* 0.52 0. 16 5 5 15 13. 12 12. 80 5.11 5 5 16 3. 85 3.53 4.19 4 5 1 3.00* 1.84 0.10 4 5 •2 24.69 22.72 2.04 4 5 3 16.47 15.67 3.52 4 5 4 11.69 9.88 5.51 4 5 5 15. 13 13.61 3.87 4 5 6 8.99 8. 83 4.36 4 t; 7 3. 81 1. 26 2. 52 4 5 8 11. 66 12. 29 5.24 4 5 9 3.97 3.95 2.53 4 5 10 13.86 13.72 4. 61 4 5 11 3.29* 1.03 0. 30 4 5 12 6. 06 6.54 3.70 4 5 13 6.3 3 6.69 5.28 4 5 14 5. 34 4.31 6.95 4 5 15 3. 45 2.60 3.56 4 5 16 4.95 4.95 5.09 3 5 1 15.62 12.78 3. 60 3 5 2 11.94 10.05 4.71 3 5 3 21. 89 20.00 2.48 3 5 4 10.77 9. 81 4.76 3 5 5 4.57 2.84 5.07 3 5 6 7.68 7.00 5.69 3 5 7 16.30 15.86 3.75 3 5 8 12.39 11.31 5.63 3 5 9 3.73* 3. 72 0. 26 3 5 10 10.91 10.93 5.33 3 5 11 5. 66 5.28 4.12 3 5 12 7.95 7. 90 5.64 3 5 13 2. 02* 0.59 0. 11 3 5 14 0. 00* 0.71 0. 00 3 5 15 3.61 1.92 5. 91 2 5 1 14.44 12.96 3.61 2 5 2 13. 23 11.72 4.00 H K L FO FC WEIGHT -2 5 3 5.02 4. 18 3. 8 3 -2 5 4 11.82 11. 48 4. 84 -2 5 5 0.00* 0. 52 0. 00 -2 5 6 3.29* 2. 60 0. 25 -2 5 7 10.75 12. 03 5.08 -2 5 8 1-1.11 10. 57 4.93 -2 5 9 8.15 8. 19 6.75 -2 5 10 3.07* 0.97 0.28 -2 5 11 27.24 27.92 1.79 -2 5 12 14.79 15.50 4.60 -2 5 13 8.87 8. 57 7.92 -2 5 14 2.41* 1. 24 0.21 -2 5 15 0. 00* 0.45 0.01 -1 5 1 4.71 2. 06 3.07 -1 5 2 11.23 11. 54 4.75 -1 5 3 26.46 26. 65 1. 83 -1 5 4 3.28* 2. 09 0.29 -1 5 5 3.48 0.50 3.81 -1 5 6 12.39 12. 65 5. 88 -1 5 7 16.86 18. 21 3.65 -1 5 8 3.92* 4. 61 0. 23 -1 5 9 32.43 34. 48 1. 28 -1 5 10 1.94* 1. 75 0. 08 -1 5 11 3.32* 2. 24 0.34 -1 5 1.2 4.26 3. 34 3.49 -1 5 13 9.90 9.70 6.07 -1 5 14 2.28* 0. 92 0. 22 0 5 1 2.65* 2.89 0. 13 0 5 2 8.00 6. 90 6.76 0 5 3 21.92 24. 14 2. 58 0 5 4 1.71* 0. 81 0.09 0 5 5 13.86 14.76 4.26 0 5 6 21.96 24. 24 2. 44 0 5 7 12.82 13. 38 4.63 0 5 8 ' 15.30 15. 97 3.98 0 5 9 2.73* 1.78 0. 16 0 5 10 9.52 9.27 5.78 0 5 11 6.59 5. 27 7.00 0 5 12 3.25 1.64 3.71 0 5 13 4. 17 4. 93 2. 92 0 5 14 3.84 3. 35 4.38 1 5 0 5.44 6. 14 3. 72 1 5 1 20.15 21. 16 2.86 1 5 2 10.43 10. 65 5. 68 1 5 3 4.51 4.73 4. 06 1 5 4 22.85 25. 53 2. 34 1 5 5 11.14 11.51 6.43 1 5 6 6.93 6. 62 5. 32 1 5 7 13.51 14.68 5.25 1 5 8 2.07* 2. 07 0.09 1 5 9 8.27 8. 10 6.94 1 5 10 4.33 4. 82 3.30 1 5 11 8.94 9. 44 6. 57 1 5 12 4.01 3.40 4.12 1 5 13 6.33 5. 86 10.74 2 5 0 10.05 10.73 5. 18 2 5 1 28.21 28. 32 1. 70 2 5 2 10.11 10.38 5.51 H K I FO FC WEIGHT 2 5 3 40.76 43. 27 0. 86 2 5 4 1.65* 2.15 0.05 2 5 5 12.73 13.55 4.69 2 5 6 3. 91 2.42 3.72 2 5 7 12.69 13.90 5.05 2 5 8 5.01 4.10 5. 13 2 5 9 8.02 8.62 5.87 2 5 10 4.48 4.65 3. 86 2 5 11 6. 20 6.01 8.44 2 5 12 3.01* 2.31 0.37 3 5 0 4. 51 3.48 3.97 3 5 1 20. 91 21.07 2. 89 3 5 2 15.42 16.25 4. 10 3 5 3 3.52* 2. 88 0.27 3 5 4 6. 00 5.67 6.15 3 5 5 3.18* 2.92 0.30 3 5 6 13.94 14. 48 5. 08 3 5 7 7.43 7.67 5.42 3 5 8 2.63* 4.03 0.16 3 5 9 0.00* 1.52 0.00 3 5 10 8.57 8.91 6. 98 3 5 11 2. 25* 1.41 0.21 4 5 0 5.34 4.73 4.23 4 5 1 3.33* 3.98 0. 23 4 5 2 6.12 5.46 5.99 4 5 3 3. 53 1.64 3.02 4 5 4 16. 92 17.16 3.74 4 5 5 7.96 7.55 6.51 4 5 6 1. 83* 0. 21 0.07 4 5 7 7.84 8.11 7.02 4 5 8 3. 81 3. 20 4. 17 4 5 9 4.56 3.09 6.29 4 5 10 3. 12* 2.95 0.28 5 5 0 2. 40* 2. 85 0.09 5 5 1 14.48 15.16 3. 84 5 5 2 4.76 5.89 2.51 5 5 3 16.61 16.31 4.06 5 5 4 1.97* 2. 05 0. 08 5 5 5 5.15 5.85 2.94 5 5 6 5.95 5.40 6.35 5 5 7 5.79 5.89 5. 25 5 5 8 9. 13 9.4 8 6.31 5 5 9 8. 23 8.37 7.40 6 5 0 4.94 3.44 4.66 6 - 5 1 8.73 8. 16 6. 53 6 5 2 0.72* 0.54 0. 01 6 5 3 13.83 13. 85 4. 70 6 5 4 3. 28* 2.80 0.33 6 5 5 2. 80* 0.72 0. 28 6 5 6 7.27 7.41 5.43 6 5 7 8. 76 9.36 5.87 6 5 8 3.30* 3. 11 0.37 7 5 0 6.88 6.62 7. 10 7 5 1 2. 82* 2.65 0. 16 7 5 2 2.92* 2.22 0.18 7 5 3 9.47 9.93 6. 12 7 5 4 2. 37* 1. 36 0. 16 7 5 5 9.28 9.90 5.60 H K L FO FC WEIGHT 7 5 6 2.85* 0. 30 0.33 8 5 0 5.71 4.84 6. 09 8 5 1 5.48 4.26 5.90 8 5 2 6.14 6. 16 5. 36 8 5 3 2.77* 1.66 0.22 8 5 4 1.69* 0. 56 0. 08 8 5 5 4.24 4.66 3,82 9 5 0 5.38 6.09 3.91 9 5 1 3.57 1.99 3. 19 9 5 2 2.55* 2.36 0. 18 9 5 3 6.02 6. 69 5.77 10 5 0 5.25 4. 45 6. 86 -9 6 2 5.28 5.46 3,93 -9 6 3 3.76* 4. 40 0.21 -9 6 4 5. 85 5. 90 3. 88 -9 6 5 3.94 3.30 3.19 -9 6 6 3.17* 2. 59 0.20 -9 6 7 3.81 3. 41 3. 03 -9 6 8 3.70 2.66 2. 98 -9 6 9 2.96* 2. 02 0. 24 -9 6 10 3.99 3. 44 3.13 -8 6 1 2. 87* -2. 22 0. 15 -8 6 2 3.63* 2. 10 0. 21 -8 6 3 3.09* 0. 80 0. 19 -8 6 4 9. 14 8. 84 4.96 -8 6 5 5.90 5.63 4.25 -8 6 6 2. 58* 3.74 0. 10 -8 6 7 8.32 7. 95 4.83 -8 6 8 9.59 8. 65 5. 85 -8 6 9 1. 17* 0. 45 0.03 -8 6 10 2.90* 0. 47 0.27 -8 6 11 4.09 4. 21 3.59 -8 6 12 5.79 5. 28 5.32 -7 6 1 7.74 7. 38 5.05 -7 6 2 8.02 6.27 4,97 -7 6 3 6. 12 6. 10 3.20 -7 6 4 4.23 2.47 3.02 -7 6 5 10.60 9. 87 5.05 -7 6 6 5.01 4.07 3. 86 -7 6 7 1. 87* 3. 24 0.05 -7 6 8 10.76 10. 54 5. 36 -7 6 9 4.32 3.95 2.83 -7 6 10 5. 23 4. 21 4.01 -7 6 11 5.97 5.71 5.17 -7 6 12 1.85* 0. 84 0. 10 -7 6 13 0.65* 0.77 0.01 -6 6 1 1.90* 0. 17 0.05 -6 6 2 9.17 8.21 4. 85 -6 6 3 3.75* 3. 31 0.16 -6 6 4 2.90* 1.23 0. 13 -6 6 5 5. 11 4. 26 2. 86 -6 6 6 5.36 4.09 3.09 -6 6 7 4.01 2. 15 2.70 -6 6 8 9.22 9. 97 4.44 -6 6 9 5.96 5. 32 3. 94 -6 6 10 9.49 9. 18 4. 91 -6 6 11 4.04 3.54 3.68 -6 6 12 3.73 3.73 2.90 H K 1 FO FC WEIGHT 6 6 13 8.46 8.62 6. 54 5 6 1 4.50 1.93 2.97 5 6 2 4. 30 1.78 2. 10 5 6 3 13. 96 12.59 3.88 5 6 4 13.43 13.01 3. 67 5 6 5 10.64 10.31 4.20 5 6 6 8.74 8.97 4.59 5 6 7 2.95* 3.09 0.13 5 6 8 3.78 1.39 3.49 5 6 9 2. 99* 4.90 0.12 5 6 10 9.75 10.55 6. 18 5 6 11 10. 60 10.56 6.37 5 6 12 9.64 9.74 5.62 5 6 13 6. 24 5.73 10.00 4 6 1 6. 61 6.21 2. 58 4 6 2 10.57 10.21 3. 69 4 6 3 4.48 3.03 2. 18 4 6 4 15.06 13.62 3.66 4 6 5 2.71* 1.46 0. 10 4 6 6 0.00* 0.45 0. 00 4 6 7 9.00 8.44 5.67 4 6 8 6. 58 6. 19 5.05 4 6 9 3.92 3.74 2.83 4 6 10 13.77 13. 73 5. 06 4 6 11 0.62* 0.13 0.01 4 6 12 2.77* 0.85 0. 26 4 6 13 2, 64* 1.07 0.29 3 6 1 4. 25* 3.48 0. 19 3 6 2 6. 26 5.82 3.02 3 € 3 11.66 11.36 4.23 3 6 4 11. 49 10.47 4.25 3 6 5 0. 00* 0.72 0. 00 3 6 6 4.02 1.97 3.72 3 6 7 14.14 15.59 4.52 3 6 8 11.48 12.41 4. 89 3 6 9 5. 58 4.41 6.03 3 6 10 8.00 7.39 6.24 3 6 11 3. 69 2.99 3. 22 3 6 13 0. 00* 1.13 0. 00 2 6 1 11. 43 9.05 4.25 2 6 2 11. 66 9.81 4. 24 2 6 3 17.37 16.52 3.28 2 6 4 17.4 3 17.87 3.44 2 6 5 25. 99 27.52 1.87 2 6 6 12.70 13.59 4. 54 2 6 7 13.27 14.25 4.76 2 6 8 7.50 8. 22 5. 45 2 6 c 9.53 10.37 7.07 2 6 10 10. 82 11.75 6. 14 2 6 11 2. 84* 0. 92 0.24 2 6 12 5.08 4.94 6.24 2 6 13 1. 60* 0.70 0. 11 1 6 1 18. 10 16.81 2. 64 1 6 2 3. 4 7* 2.76 0. 17 1 6 3 3. 68* 3.40 0. 19 1 6 4 25. 76 27.77 1.90 1 6 5 10. 17 9.95 5.52 1 6 6 3. 94 3.35 2. 54 H K L FO FC WEIGHT 1 6 7 4.41 4. 38 3. 10 1 6 8 4.96 4.54 5.29 1 6 9 9.62 9.67 7.24 1 6 10 4.40 4. 84 3.99 1 6 11 2.78* 3. 57 0. 19 1 6 12 5.31 4. 66 7. 34 0 6 0 7.92 6. 40 2.67 0 6 1 2. 29* 1.68 0. 11 0 6 2 22. 06 24. 30 2. 41 0 6 3 3.45* 0.73 0.33 0 6 4 0.00* 1.86 0.00 0 6 5 1.49* 2. 60 0.04 0 6 6 6. 84 6. 34 6. 46 0 6 7 3.81 1. 16 3. 66 0 6 8 1. 87* 0. 65 0.09 0 6 9 4.71 4.70 4.15 0 6 10 2.09* 2.34 0. 11 0 6 11 3.53 3. 04 3. 67 1 6 0 12.98 13. 54 4. 13 1 6 1 4 . 36 4.30 2.98 1 6 2 4.53 2.73 3.13 1 6 3 10.55 10. 83 5. 46 1 6 4 6.72 4.96 6.27 1 6 5 13.02 13. 82 5.44 1 6 6 10.41 11.25 6.55 1 6 7 2.98* 0. 17 0.29 1 6 8 15.07 17. 14 4.07 1 6 9 4.25 3. 11 5.65 1 6 10 9.73 10. 55 6. 01 1 6 11 2.66* 0. 85 0. 35 2 6 0 18.16 19. 35 3. 28 2 6 1 12. 86 13. 66 4. 50 2 6 2 2.50* 1. 54 0. 13 2 6 3 0.00* 0.33 0. 00 2 6 4 9.08 10. 02 4. 81 2 6 5 1.75* 1. 16 0. 07 2 6 6 13.40 14.88 4.62 2 6 7 5.23 5.02 4.19 2 6 8 3.42 0. 26 3.76 2 6 9 14. 81 15. 87 4.46 2 6 10 5.35 5.56 5.74 3 6 0 3.43* 2. 69 0. 16 3 6 1 2.03* 3. 18 0. 06 3 6 2 11.43 11. 96 4.58 3 6 3 2.65* 2. 13 0. 14 3 6 4 7.96 8. 67 4.43 3 6 5 8.16 8. 11 6.90 3 6 6 13.32 13. 76 4. 33 3 6 7 15.15 15.94 4. 12 3 6 8 3.61 2. 50 3.46 3 6 9 7.59 7. 80 7.30 4 6 0 13.79 14.41 4.57 4 6 1 0.00* 1.21 0. 00 4 6 2 3.49* 1. 74 0. 32 4 6 3 2.06* 1. 73 0. 09 4 6 4 2.33* 3.54 0. 09 4 6 5 2.79* 2. 68 0. 19 4 6 6 7.65 7. 82 6. 63 HI K 1 FO FC WEIGHT *! 6 7 3. 36 1.97 3. 20 4 6 8 5. 95 6.61 6.60 5 6 0 20. 20 21.69 2.86 5 6 1 8. 13 8. 81 4.58 /5 6 2 3. 76* 2.88 0. 28 5 6 3 7. 61 6.79 7.30 5 6 4 3. 46 1.94 3. 75 h 6 5 3.82 1.14 5.02 I 5 6 6 3. 21* 4. 09 0.27 6 6 0 5.0 8 4.6 3 3.90 6 6 1 12.54 12.55 5.38 6 6 2 1.43* 1.24 0.04 6 6 3 5.64 5.42 5.54 6 6 4 6. 34 5.86 6. 94 6 6 5 7.99 7. 97 7.39 7 6 0 5. 52 4.88 6.91 7 6 1 0. 00* 2.02 0.00 7 6 2 5.63 5.93 5.02 7 6 3 5. 74 5.03 5.95 8 6 0 7. 30 7.73 6. 59 8 6 1 3. 73 2. 10 4.71 -7 7 4 3.08* 0. 19 0.26 -7 7 5 7.32 8.66 5 • 26 -7 7 6 1. 20* 1.05 0. 04 -6 7 1 3.09* 1.64 0. 16 -6 7 2 2.95* 3.86 0. 12 -6 7 3 7.04 7. 16 4. 22 -6 7 4 4. 74 3.70 3. 01 -6 7 5 3.91* 2.86 0.25 -6 7 6 6. 18 6.93 3. 84 -6 7 7 4. 61 3.05 4.69 -6 7 8 2. 85* 2.32 0.22 -5 7 1 6.44 6.62 3. 46 -5 7 2 5. 21 3.63 3.52 -5 7 3 3. 23* 1.00 0. 15 -5 7 4 4.41 5.12 1. 96 -5 7 5 8. 50 7. 94 4.78 -5 7 6 10. 36 11.48 5. 11 -5 7 7 15.66 16.61 3. 75 -5 7 8 4.87 5.02 3.94 -5 7 9 3. 83 3.40 3.93 -a 7 1 11. 78 11.80 3. 64 -4 7 2 7.07 5.31 4.33 -4 7 3 5. 59 5.57 2.46 -4 7 a 18.53 18.98 2. 94 -4 7 5 2. 45* 2.07 0. 08 -4 7 6 2. 74* 2.76 0. 13 -4 7 7 9. 19 9.63 5. 60 -4 7 8 2. 56* 2. 90 0. 14 -4 7 9 3.79 2.56 4.72 -3 7 1 2.21* 1.59 0.05 -3 7 2 5. 92 5.50 2.45 -3 7 3 9. 45 8. 29 3. 84 -3 7 4 3. 23* 2. 38 0. 15 -3 7 5 6. 85 6.33 4. 17 -3 7 6 9.86 10.32 4.67 -3 7 7 0.63* 0.74 0.01 -3 7 8 2. 81* 1.19 0.27 H K L FO FC WEIGHT -3 7 9 4.10 3. 79 4.00 -2 7 1 11.02 10. 90 3. 52 -2 7 2 7.90 7. 79 2.90 -2 7 3 5.84 5. 30 3. 86 -2 7 4 8.00 7. 09 6.13 -2 7 5 2.44* 1.42 0, 12 -2 7 6 4.31 5. 27 2. 98 -2 7 7 8.34 8. 64 7.15 -2 7 8 6.08 7. 33 4. 6 9 -2 7 9 2.00* 1. 75 0. 13 -1 7 1 4.99 2. 79 2.46 -1 7 2 13. 24 13. 77 3.99 -1 7 3 3. 82* 3. 66 0. 23 -1 7 4 6.21 6. 95 4.25 -1 7 5 6.31 6. 81 4. 54 -1 7 6 4.92 3.40 6. 44 -1 7 7 7.83 8. 29 6.15 -1 7 8 3.29 2. 25 3.41 -1 7 9 4.34 3.67 6.24 0 7 1 5.54 3.70 5. 91 0 7 2 5.95 6. 80 3.83 0 7 3 9. 13 9. 79 5. 28 0 7 4 2.97* 0. 61 0. 22 0 7 5 2.04* 2. 13 0.09 0 7 6 7.00 7. 34 6.72 0 7 7 14.89 15. 80 4.78 0 7 8 4.62 4. 12 4,83 1 7 0 9.66 10. 27 5.16 1 7 1 14.73 15. 12 4.29 1 7 2 4.58 3.75 3.62 1 7 3 8.77 9. 30 5. 38 1 7 4 3.44* 3. 71 0.22 1 7 5 9.74 10. 30 6.83 1 7 6 3.50* 3. 06 0. 29 1 7 7 7 .89 8. 65 8.57 2 7 0 7.86 9.04 4.40 2 7 1 6.21 5. 66 7. 10 2 7 2 9.10 10.64 5.62 2 7 3 3.17* 2. 81 0. 27 2 7 4 1.71* 1. 47 0.07 2 7 5 3.92 4. 07 4.24 2 7 6 1.95* 1. 93 0. 13 3 7 0 10.47 10. 67 7, 19 3 7 1 3.91 0. 99 4.78 3 7 2 9.55 10. 09 6.01 3 7 3 8.08 9. 16 7. 35 3 7 4 4.48 4. 07 5.02 3 7 5 3.95 4.75 3. 18 4 7 0 2.38* 0. 73 0. 17 4 7 1 2.90* 1. 05 0. 27 4 7 2 2.69* 0.76 0.25 4 7 3 7.43 8. 49 6.95 4 7 4 3. 48 3. 25 3.52 5 7 0 2.98* 1.61 0. 31 5 7 1 1.28* 0.88 0.05 5 7 2 2.93* 0. 91 0. 38 6 7 0 3.08 1. 51 3. 87 * DENOTES AN UNOBSERVED REFLECTION Dichlorotstrakis (dimethylsulphoxide)ruthenium (II) Anthony Mercer and James Trotter Observed and calculated structure amplitudes, (reflections with intensity < 3er(I) are marked with an asterisk) . The following planes which had j Fo-Fc| > 3<3-(F) were given zero weight in the final stages of refinement due tc suspected errors resulting from extinction, absorption, or instrument malfunction: h k 1 Fo Fc h k 1 Fo Fc 1 2 4 120.4 197.0 0 8 0 130.6 218.0 3 0 T 121.6 222.9 1 8 1 131.8 1 87.5 4 2 T 145.4 207.2 4 0 2 143.0 186. 5 3 (i 1 132,7 182.0 i o 3 1G0. 4 174.7 2 0 0 85.5 165. 0 0 2 3 98.7 189.3 4 0 0 143. 4 193. 6 0 0 4 136.5 289.8 3 2 0 122 .7 181.4 0 2 5 126. 2 194. 8 1 6 0 114.1 196.7 H K L FO FC H K L FO FC 1 0 -13 6.00* 5.33 2 2 n 41. 19 42.85 3 0 -13 5.74* 4.36 3 2 - 11 1.52* 1.89 1 1 -13 7.06* 6.33 4 2 - 11 26. 18 26.67 2 1 -13 6.03* 7.82 5 2 - 11 23.73 22.82 3 1 -13 24.74 23.03 6 2 -11 15.64 15.28 2 2 -13 0.00* 0.85 1 3 - 11 32.68 34. 16 3 2 -13 2.88* 0.70 2 3 - 11 32. 15 33. 1 1 1 3 -13 13.56 13.06 3 3 - 11 34.63 36. 15 2 3 -13 12.79 12.55 4 3 11 37.29 36.94 1 4 -13 11.71 11.47 5 3 - 11 31.22 30.48 2 4 -13 16.55 15.35 6 3 n 12.25 11.84 1 5 -13 13.28 12.94 1 4 - 11 30.90 32.37 2 0 -12 32.87 32.97 2 4 11 2.03* 4.22 4 0 -12 25.83 25. 17 3 4 - 11 31.66 32.13 1 1 -12 16.10 15.48 4 4 i 1 3.92* 5. 18 2 1 -12 6.54* 6.88 5 4 - 11 20.41 20. 19 3 1 -12 26,19 26.11 6 4 - 11 6.60* 7.77 4 1 -12 26.98 26.01 1 5 - 11 39. 11 40.01 5 1 -12 14.74 13.84 2 5 - 11 39.52 39.55 1 2 -12 22.34 22.33 3 5 - 11 37.66 38.41 2 2 -12 5.01* 5.14 4 5 11 32.29 32. 25 3 2 -12 30.55 29. 27 5 5 - 11 33.47 32.58 4 2 -12 24.84 24.17 1 6 - 11 46.56 47.82 5 2 -12 19.71 19.24 2 6 11 28.50 29.39 1 3 -12 22.97 23.57 3 6 - 11 14.68 14.85 2 3 -12 27.68 28.08 4 6 - 11 27.90 26.70 3 3 -12 26 . 5 1 26.33 5 6 - 11 0.00* 0. 18 4 3 -12 30.10 28.69 1 7 - n 30.07 30.68 1 4 -12 16.02 16.32 2 7 - 11 25.75 25.32 2 4 -12 18.32 17.99 3 7 11 14.23 15.28 3 4 -12 0.00* 1.34 4 7 - 11 29. 14 28.79 4 4 -12 16.63 15.97 5 7 11 28.79 27.92 1 5 -12 32. 21 32.34 1 8 11 14.99 14.31 2 5 -12 21.02 21.64 2 8 - 11 14. 15 14.16 3 5 -12 29. 18 28.53 3 8 11 34.57 34. 17 4 5 -12 33.29 32.25 4 8 - 11 9.51 10.02 1 6 -12 6.60* 7.16 1 9 i1 28.97 28.78 2 6 -12 10.81 11.01 2 9 - 11 34.24 33.01 3 6 -12 16.96 16.14 3 9 - 11 15.85 ' 15.39 4 6 -12 14.37 13.32 4 9 - 11 14.79 14.73 1 7 -12 8. 34 7.67 1 10 - 11 6.24* 6.76 2 7 -12 17.53 16.79 2 10 11 20.21 20.46 3 7 -12 23.00 23. 38 3 10 - n 6.92* 7.23 1 8 -12 23.81 23.26 1 1 1 - 11 39.05 38.30 2 8 -12 16.43 15.89 2 11 11 28.81 27.45 3 8 -12 11.68 11.08 3 11 ! 1 38.36 37.03 1 9 -12 12.54 12.67 1 12 - 11 11.96 10.88 2 9 -12 13.26 12.63 2 0 10 32.42 34.50 1 0 -11 49.53 51.02 4 0 - 10 46.00 43.97 3 0 -11 40.09 40.59 6 0 10 10.75 1 1. 10 5 0 -1 1 12. 25 11. 12 1 1 - 10 13. 10 13.35 1 1 -11 25.79 26.58 2 1 10 7.71 8.04 2 1 -1 1 2. 11* 0.81 3 1 - 10 38.54 37.41 3 1 -11 13.63 14.31 4 1 10 45.32 44.33 4 1 -11 31.37 31.82 5 1 10 42.75 42.37 5 1 -11 22.52 21.98 6 1 - 10 17.45 16.37 6 1 -11 25. 14 24.32 7 1 10 45.27 43.97 1 2 -11 5.41* 6.66 1 2 - 10 33.77 34.52 H K L FO FC 2 2 -10 19.32 19. 13 3 2 -10 30,52 31.00 4 2 -10 16.19 16.65 5 2 -10 21.74 20.56 6 2 -10 19.42 19.24 7 2 -10 26.96 26.20 1 3 -10 , 48.97 50.81 2 3 -10 47. 35 48.48 3 3 -10 43.13 44.40 4 3 -10 72.69 72.44 5 3 -10 30.97 30.19 * 6 3 -10 36. 32 36. 10 7 3 -10 16.79 15.89 1 4 -10 22.75 23.05 2 4 -10 27.68 30.04 3 4 -10 29.74 29.22 4 4 -10 32.95 32.19 5 4 -10 21.07 20.40 6 4 -10 19.65 19.28 7 4 -10 3.30* 4.51 1 5 -10 46.30 48.25 2 5 -10 45.28 45. 19 3 5 -10 64.94 65.27 4 5 -10 30.42 30.17 5 5 -10 49.84 49. 13 6 5 -10 12.88 12.77 1 6 -10 27.36 27.66 2 6 -10 8.66 9.13 3 6 -10 41.52 42.59 4 6 -10 14.72 14.60 5 6 -10 23.55 22.65 6 6 -10 14.06 14,34 1 7 -10 30.30 30,06 2 7 -10 40.59 41.42 3 7 -10 2.4 2* 3. 82 4 7 -10 28.29 27.93 5 7 -10 13.52 12.74 6 7 -10 41.92 40. 68 1 8 -10 18.35 18.75 2 8 -10 44.08 46.07 3 8 -10 19.38 19.80 4 8 -10 33.33 33.78 5 8 -10 13.61 12.75 6 8 -10 13.59 12.97 1 9 -10 42.67 43.19 2 9 -10 14. 15 13.08 3 9 -10 20.73 20.51 4 9 -10 0.00* 1.29 5 9 -10 35.92 35.71 1 10 -10 34.46 35.44 2 10 -10 1.15* 2.07 3 10 -10 •35.96 37.29 4 10 -10 14. 14 13.99 5 10 -10 14.92 13.73 1 1 1 -10 27.64 28.23 2 1 1 -10 65.55 65. 19 3 11 -10 10.92 10.76 4 1 1 -10 20.55 20.04 H K L FO FC 1 12 -10 0.00* 4.45 2 12 -10 27.43 27.82 3 12 -10 0.00* 4.67 4 12 -10 20. 54 19.01 1 13 -10 52.20 5 2.53 2 13 -10 14.22 12.81 3 13 -10 38.82 38.00 1 14 -10 21.03 20.72 1 0 -9 22. 18 22.08 3 0 -9 38.38 38.75 5 0 -9 28.46 27.37 7 0 -9 17.21 16.52 1 1 -9 19.28 19. 19 2 1 -9 27.07 27. 12 3 1 -9 28.53 28.75 4 1 -9 49.35 49.72 5 1 -9 17.54 16.52 6 1 -9 8.03 7.39 7 1 -9 20.23 19. 38 8 1 -9 36. 14 35.48 1 2 -9 27.77 27.74 2 2 -9 13.90 11.57 3 2 -9 14.78 15.26 4 2 -9 40.76 39.98 5 2 -9 42.49 41.79 6 2 -9 5.56* 6.49 7 2 -9 7.19 7.07 8 2 -9 15.77 14.75 1 3 -9 36. 13 38.92 2 3 -9 31.71 34.00 3 3 -9 86.94 88.23 4 3 -9 51.65 51.93 5 3 -9 35.44 36.91 6 3 -9 12.44 11.58 7 3 -9 15.33 15. 10 1 4 -9 11.67 1 1.77 2 4 -9 10.95 12.61 3 4 -9 ' 21.65 21.26 4 4 -9 20. 18 20.64 5 4 -9 14.67 13.92 6 4 -9 2.44* 1.44 7 4 -9 21.88 22.04 1 5 -9 25. 13 24.88 2 5 -9 68.90 71.81 3 5 -9 30.59 32.40 4 5 -9 50. 17 50.46 5 5 -9 40.90 40.45 6 5 -9 16.78 15.99 7 5 -9 8.68 7.66 1 6 -9 28. 11 28.44 2 6 -9 33.48 36.34 3 6 -9 24.59 25. 27 4 6 -9 23.09 23.42 5 6 -9 1.75* 0.51 6 6 -9 18.77 18.65 7 6 -9 31.01 30.42 1 7 -9 34. 30 35.88 2 7 -9 5.51* 4.65 fl K I FO FC 3 7 -9 26.8 1 28.06 4 7 -9 7.72 7.12 c •mJ 7 -9 24.64 24.58 6 7 -9 24.98 24. 14 7 7 -9 30.92 29.42 1 8 -9 32.07 33.76 2 8 -9 15.27 15.59 3 8 -9 29.48 31.03 4 8 -9 0.00* 0.87 5 8 -9 7. 17 7. 13 6 8 -9 5.31* 4.64 7 8 -9 17.81 16.95 1 9 -9 7.61 6.58 2 9 -9 40.40 41.09 3 9 -9 4.96* 3.28 4 9 -9 5.07* 4. 25 5 9 -9 21. 16 20.23 6 9 -9 47.84 47.77 1 10 -9 10,30 10.68 2 10 -9 42.51 44. 16 3 10 -9 3.96* 3.95 4 10 -9 7.64 6. 33 5 10 -9 21. 12 21.07 6 10 -9 12. 68 11.14 1 11 -9 39.49 41.40 2 1 1 -9 12,97 13.52 3 1 1 -9 31.53 31.33 4 1 1 -9 15.20 15.46 5 1 1 -9 40.09 40. 17 1 12 -9 46.38 46.93 2 12 -9 7. 29* 8. 32 3 12 -9 14.79 16.56 4 12, -9 6.71* 5.99 5 12 -9 17.92 17.08 1 13 -9 6.23* 6.54 2 13 -9 51.30 53.53 3 13 -9 20.66 20.67 4 13 -9 20.83 19.62 1 14 -9 14.94 15.01 2 14 -9 17,78 18.27 3 14 -9 1.71* 0.92 4 14 -9 20.34 19.74 1 15 -9 23.10 23.89 2 15 -9 12.57 13. 24 2 0 -8 27.9 6 29.57 4 0 -8 39. 45 42. 27 6 0 -8 3.78* 2.22 8 0 -8 26.21 25.57 1 1 -8 35.65 34.21 2 1 -8 11.29 10.28 3 1 -8 17.48 17.60 4 1 -8 22.60 23.04 5 1 -8 3.21* 1.65 6 1 -8 2.88* 5.03 7 1 -8 33.72 33.07 8 1 -8 40.61 39.98 1 2 -8 31.99 33.60 2 2 -8 27.52 27.60 H K L FO FC 3 2 -8 26.74 29. 23 4 2 -8 17.33 17.69 5 2 -8 10.20 1 1.60 6 2 -8 15.78 16. 15 7 2 -8 19.35 18.53 8 2 -8 9.69 8.09 1 3 -8 27. 18 26.37 2 3 -8 50.68 50,83 3 3 -8 32.90 34,96 4 3 -8 38.96 40.54 5 3 -8 44.41 44.26 6 3 -8 11.49 11.36 7 3 -8 10.38 10. 10 8 3 -8 21.78 22. 10 1 4 -8 41.33 42.84 2 4 -8 30.58 30.61 3 4 -8 4.79* 4.48 4 4 -8 19.20 20. 12 5 4 -8 22.90 23.03 6 4 -8 20.72 21.16 7 4 -8 25.21 25.52 8 4 -8 24.95 25.14 1 5 -8 34.23 34.42 2 5 -8 33.52 34.21 3 5 -8 44.53 46.27 4 5 -8 48.20 48.91 5 5 -8 10.86 11.21 6 5 -8 29.41 29.82 7 5 -8 13.77 12.82 8 5 -8 7.45 8.26 1 6 -8 17. 19 19.15 2 6 -8 29.38 28.98 3 6 -8 27. 13 28.07 4 6 -8 2.24* 5.70 5 6 -8 26.66 27,96 6 6 -8 39.36 39. 14 7 6 -8 38.22 38.09 8 6 -8 15. 16 14.27 1 7 -8 ' 23.77 23.39 2 7 -8 27.39 28.38 3 7 -8 12.56 12.66 4 7 -8 0.00* 2.82 5 7 -8 41.63 40.78 6 7 -8 21.87 21.07 7 7 -8 7.50* 7.23 1 8 -8 20. 13 20.26 2 8 -8 21.54 22. 19 3 8 -8 14.40 15.08 4 8 -8 3.49* 5.99 5 8 -8 3.42* 2. 10 6 8 -8 41.13 40.46 7 8 -8 19.36 18.44 1 9 -8 26.06 25.82 2 9 -8 7.94 7.79 3 9 -8 4.25* 3.97 4 9 -8 29.47 29.64 5 9 -8 23. 18 23.21 6 9 -8 31.67 31.58 H K L FO FC 7 9 -8 29.06 28.61 1 10 -8 25.74 24.86 2 10 -8 5.50* 5.89 3 10 -8 13.45 13. 17 4 10 -8 11 .07 10.79 5 10 -8 18.40 19.10 6 10 -8 26.04 25.00 7 10 -8 25.82 25.44 1 11 -8 7.53 9. 24 2 11 -8 62.59 62.44 3 11 -8 26.86 27.82 11 -8 19,40 18.81 5 11 -8 29.83 30.34 6 11 -8 41,34 40.85 1 12 -8 6.61* 4.87 2 12 -8 35.9 4 37.19 3 12 -8 1.99* 2.01 4 12 -8 15.48 15. 25 5 12 -8 8.89 8.77 6 12 -8 38.59 38.05 1 13 -8 25.73 25.66 v 2X 13 -8 24.41 25.38 3 13 -8 41.08 42. 13 4 13 -8 17.68 18.61 5 13 -8 40.07 39.39 1 14 -8 27.23 28.39 2 14 -8 8.99 9.62 3 14 -8 9.24 8.83 4 14 -8 10.43 11.01 14 -8 43.99 44.29 1 15 -8 14.77 14.87 2 15 -8 20.84 22.13 3 15 -8 24.9 6 25.35 4 15 -8 11.71 11.50 1 16 -8 5.36* 4. 32 2 16 -8 20.91 20.59 3 16 -8 5.64* 5.29 1 17 -8 15.77 15.67 1 0 -7 66. 14 70.44 3 0 -7 49,50 51.67 5 0 -7 28.61 29.64 7 0 -7 54.38 53. 10 9 0 -7 46.41 46.10 1 1 -7 20.60 21.40 2 1 -7 42.50 39.31 3 1 -7 17.00 15.83 4 1 -7 19.05 19.89 5 1 -7 10,75 9.98 6 1 -7 10.44 10.23 7 1 -7 38. 31 37.3 3 8 1 -7 45.68 45.50 9 1 -7 22. 12 21.69 1 2 -7 19.30 • 19.36 2 2 -7 38.75 40. 16 3 2 -7 48.50 46.71 4 2 -7 60.08 60. 38 5 2 -7 32.55 32.14 6 2 -7 31,37 29.93 H K 1 FC FC 7 2 -7 13.58 14. 17 8 2 -7 59.54 60.33 9 2 -7 18.86 19.28 1 3 -7 14.92 12.45 2 3 -7 14. 15 15.50 3 3 -7 34.53 33.72 4 3 -7 59. 15 59.87 5 3 -7 24.46 24. 37 6 3 -7 22.44 23.81 7 3 -7 38.79 40.01 8 3 -7 22.95 23.62 9 3 -7 0.00* 0.51 1 4 -7 5 5.17 58.69 2 4 -7 3.46* 1. 16 3 4 -7 67.39 67.02 4 4 -7 11.02 10.43 5 4 -7 47,86 46.66 6 4 -7 0.00* 0.54 7 4 -7 48.45 49.90 8 4 -7 14.79 15.06 9 4 -7 36. 16 36.95 1 5 -7 77.77 78. 27 2 5 -7 11.07 9.90 3 5 -7 37.35 40.02 4 5 -7 33.70 34.21 5 5 -7 50.15 51.60 6 5 -7 23.61 24.06 7 5 -7 2.55* 0.61 8 5 -7 7.41 6.82 1 6 -7 105.83 107.08 2 6 -7 59.41 63.18 3 6 -7 9.21 8.70 4 6 -7 56.94 57.84 5 6 -7 1.73* 2.16 6 6 -7 62.72 61. 15 7 6 -7 25.38 25.93 8 6 -7 34.67 35.29 1 7 -7 10.50* 8.78 2 7 -7 51.31 54.07 3 7 -7 4.32* 4.72 4 7 -7 22.29 23.56 5 7 -7 2.56* 2. 14 6 7 -7 14.41 15.09 7 7 -7 32.52 32.93 8 7 -7 16.76 14.93 1 8 -7 23.69 24.89 2 8 -7 8.54 7.43 3 8 -7 50.36 52.47 4 8 -7 3.76* 2.97 5 8 -7 39.96 39.81 6 8 -7 4.52* 3.79 7 8 -7 41.67 41.92 8 8 -7 7.68 8.31 1 9 -7 67,60 66.83 2 9 -7 25,50 26.49 3 9 -7 22,55 22.50 4 9 -7 15.67 16.36 5 9 -7 31.37 32.14 H K L FO FC H K L FO FC 6 9 -7 25.83 25.41 6 1 -6 6.30 5.88 7 9 -7 20.23 19.93 7 1 -6 35.66 34,90 8 9 -7 13.. 90 13.93 8 1 -6 42.74 42.59 1 10 -7 1. 60* 1.02 9 1 -6 16.92 16.30 2 10 -7 55.21 56.64 1 2 -6 63. 1 1 67.94 3 10 -7 10.46 11.04 2 . 2 -6 55.23 58,92 4 10 -7 29.04 29.09 3 2 -6 119.99 124.38 5 10 -7 37.31 38.68 4 2 -6 1.40* 2.52 6 10 -7 44. 37 43. 20 5 2 -6 72.48 72.29 7 10 -7 22.24 22.46 6 2 -6 38.00 39. 13 1 11 -7 40.72 41.48 7 2 -6 75.28 76.06 2 1 1 -7 30.97 32.55 8 2 -6 25.85 26.92 3 1 1 -7 37.08 38.24 9 2 -6 44.68 46.89 4 11 -7 35.62 38.67 1 3 -6 55. 14 52.43 5 11 -7 26.39 26.01 2 3 -6 45.43 44.05 6 1 1 -7 28.20. 28.88 3 3 -6 28. 26 25.77 7 11 -7 5. 33* 3.26 4 3 -6 85. 19 85.35 1 12 -7 44.17 47.59 5 3 -6 62.99 63. 11 2 12 -7 23. 35 24.46 6 3 -6 30.40 32.00 3 12 -7 47.26 47. 3 1 7 3 -6 22.01 22.09 4 12 -7 20.72 21.26 8 3 -6 12.37 12.00 5 12 -7 52.97 52.71 9 3 -6 24.44 24.61 6 12 -7 28.52 30.13 1 4 -6 16.00 18.54 7 12 -7 17.88 18.27 2 4 -6 87.83 94.16 1 13 -7 31.36 33.15 3 4 -6 40.38 37.74 2 13 -7 70.27 72.98 4 4 -6 122.63 124.61 3 13 -7 41.95 43.44 5 4 -6 46.40 46.33 4 13 -7 28.08 27.90 6 4 -6 69.04 70.59 5 13 -7 15,68 16.77 7 4 -6 3.26* 2.83 6 13 -7 24.81 25.80 8 4 -6 50.88 52,92 1 14 -7 23.57 25.00 9 4 -6 16.31 17. 16 2 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11.21 11.01 5 14 -6 54. 11 54.77 6 14 -6 4.16* 0.94 1 15 -6 18.46 18. 17 2 15 -6 16.8 3 18.35 3 15 -6 43. 15 44.29 4 15 -6 5. 14* 4.02 5 15 -6 2.40* 1.16 6 15 -6 20.68 20.40 1 16 -6 32.23 33.24 2 16 -6 19.42 19.57 H K L FO FC 3 16 -6 25.0 3 25.45 4 16 -6 21.77 22. 14 5 16 -6 5.90* 6.50 1 17 -6 11.05 12.30 2 17 -6 7,46 8.45 3 17 -6 2.47* 0.60 4 17 -6 13.82 13.79 1 18 -6 37.33 38.78 2 18 -6 8.20 8.83 3 18 -6 12.72 13.64 1 19 -6 0.00* 3.77 1 0 -5 117.28 136.78 3 0 -5 134.78 148.80 5 0 -5 66.57 66.52 7 0 -5 69.68 69.50 9 0 -5 38.96 40.62 1 1 -5 73.97 75.81 2 1 -5 71.58 70.52 3 1 -5 26. 11 26.92 4 1 -5 57.62 58.38 5 1 -5 35.39 33.46 6 1 -5 24. 11 23.36 7 1 -5 27.96 28.52 8 1 -5 36.91 37.62 9 1 -5 36.77 37.40 1 2 -5 9.32 5.53 2 2 -5 104.08 107. 16 3 2 -5 13.40 14.94 4 2 -5 152.06 171.32 5 2 -5 54.70 53.69 6 2 -5 48.95 52.86 7 2 -5 15.29 15. 18 8 2 -5 60.84 62.15 9 2 -5 18.38 19.28 1 3 -5 71.60 74.88 2 3 -5 9.45 12.09 3 3 -5 108.73 113.24 4 3 -5 80. 16 78.21 5 3 -5 27.81 26.73 6 3 -5 23.72 22.44 7 3 -5 24. 15 24.64 8 3 -5 31. 16 31.91 9 3 -5 10.44 10.76 1 4 -5 111.07 124.71 2 4 -5 10.52 11.91 3 4 -5 141.39 164.09 4 4 -5 45.64 45.37 5 4 -5 94.32 94.78 6 4 -5 13.47 15.05 7 4 -5 60.38 61.91 8 4 -5 2.86* 1.82 9 4 -5 29.73 29.85 1 5 -5 59.09 59.93 2 5 -5 94.47 98.52 3 5 -5 10.75 12. 13 4 5 -5 91.4 1 91. 17 5 5 ,"5 78.20 75.43 6 5 -5 44.33 43.80 H K L FO FC 7 5 -5 18,00 18.06 8 5 -5 24.91 25.35 9 5 -5 25. 97 26.38 1 6 -5 91. 17 91. 30 2 6 -5 91.88 93.86 3 6 -5 44.77 45.58 4 6 -5 76.80 76.48 5 6 -5 28.9 5 30.01 6 6 -5 74.40 74.44 7 6 -5 33.50 34.4 2 8 6 -5 45.32 44.99 9 6 -5 4. 39* 3.08 1 7 -5 57.44 57. 15 2 7 -5 22. 20 21.98 3 7 -5 39.52 38. 69 4 7 -5 20.44 21 .1 1 5 7 -5 21. 38 22.32 6 7 -5 9. 13 7.49 7 7 -5 50. 11 49.79 8 7 -5 14.37 12.95 9 7 -5 27.91 27.90 1 8 -5 107.59 108.57 2 8 -5 48.84 48.80 3 8 -5 70.70 69.22 4 8 -5 13.53 13.86 5 8 -5 27.79 28.17 6 8 -5 17.31 17.44 7 8 -5 66.26 66.87 8 8 -5 3.63* 4. 25 9 8 -5 41.76 42.04 1 9 -5 4. 15* 6. 16 2 9 -5 49.85 51.04 3 9 -5 35.02 35. 1 1 4 9 -5 1.81* 1.44 5 9 -5 31.88 31.89 6 9 -5 36.73 36.05 7 9 -5 9.38 7.14 8 9 -5 25.26 24.60 1 10 -5 3.33* 4.48 2 10 -5 101,66 101.80 3 10 -5 8.06 9.07 4 10 -5 20,39 21.42 5 10 -5 32.82 33.23 6 10 -5 59,44 58.21 7 10 -5 23.32 , 23.57 8 10 -5 19.04 19.15 1 11 -5 28.32 28.36 2 11 -5 21.61 20.60 3 11 -5 39.59 39.69 4 11 -5 17.66 18.17 5 1 1 -5 58.93 57.76 6 1 1 -5 16.80 15.73 7 11 -5 33. 20 34.02 8 11 -5 16.75 16.02 1 12 -5 63.41 65.03 2 12 -5 43.79 43.84 3 12 -5 47.67 46.88 4 12 -5 0,00* 1.32 H K L FO FC 5 12 -5 52.80 51.22 6 12 -5 42.92 43.21 7 12 -5 33.34 33.43 1 13 -5 4.49* 6.82 2 13 -5 50.85 52.02 3 13 -5 36.53 38.24 4 13 -5 41.92 4 1.40 5 13 -5 2.73* 2.07 6 13 -5 64.87 63.99 7 13 -5 0.00* 2.87 1 14 -5 44.82 46.28 2 14 -5 49.07 48.51 3 14 -5 28.85 28.73 4 14 -5 30.87 29.80 5 14 -5 8.66* 7.84 6 14 -5 54.83 55.04 7 14 -5 1. 10* 1.36 1 15 -5 12.60 14.01 2 15 -5 33.44 34.92 3 15 -5 10.58 10.33 4 15 -5 2.07* 0.41 5 15 -5 18.56 19.91 6 15 -5 14.89 13.55 1 16 -5 54.00 54.35 2 16 -5 14.78 15.16 3 16 -5 15.53 15.00 4 16 -5 15.57 15.79 5 16 -5 35.39 36.78 1 17 -5 11.30 11.27 2 17 -5 7.82 8. 14 3 17 -5 15.22 15.09 4 17 -5 3.77* 4.45 5 17 -5 20.89 21.60 1 18 -5 0.00* 2.75 2 18 -5 36.66 37.49 3 18 -5 0.00* 2.31 4 18 -5 33.92 34.47 1 19 -5 14. 10 14.99 2 19 -5 0.00* 3.40 3 19 -5 27. 15 27.91 2 0 -4 38.09 27.26 4 0 -4 77.97 77.23 6 0 -4 31.88 31.56 8 0 -4 81. 12 82.65 10 0 -4 14.56 14.54 1 1 -4 85. 12 88.84 2 1 -4 36.03 36.40 3 1 -4 15.43 15.90 4 1 -4 44. 38 44.82 5 1 -4 13.83 15. 14 6 1 -4 11.29 12.18 7 1 -4 30.52 32.05 8 1 -4 56.05 57.55 9 1 -4 27.54 28.00 10 1 -4 20.31 21.17 2 2 -4 9.01 8. 13 3 2 -4 74.54 82.44 4 2 -4 3.64* 4.03 H K L FO FC 5 2 -4 38.63 39.54 6 2 -4 16.79 17. 52 7 2 -4 39.27 41.91 8 2 -4 21.52 21.79 9 2 -4 30.69 31.72 10 2 -4 0.00* 1.64 1 3 -4 22.77 24.88 2 3 -4 50.25 51 .77 3 3 -4 34.27 30.66 4 3 -4 42. 13 42.32 5 3 -4 73.82 72.3 8 6 3 -4 18.82 19.96 7 3 -4 7.19 6.44 8 3 -4 27.65 28.55 9 3 -4 28.85 29.33 10 3 -4 4.71* 6.31 1 4 -4 33.91 40.97 2 4 -4 91.77 92.89 3 4 -4 22.86 24.50 4 4 -4 1C9.72 113.23 5 4 -4 7.22 6.96 6 4 -4 50.72 52.13 7 4 -4 27.54 28.62 8 4 -4 46.07 45.72 9 4 -4 14.09 14.72' 10 4 -4 4.8 8* 3.65 1 5 -4 4.60 3.23 2 5 -4 69.47 67.59 3 5 -4 66.84 66.98 4 5 -4 52.89 51.03 5 5 -4 36.90 37.28 6 5 -4 14.07 14.82 7 5 -4 68.56 70.11 8 5 -4 4.68* 4.88 9 5 -4 12.14 11 .74 1 6 -4 70.66 74.01 2 6 -4 41. 33 42.79 3 6 -4 39.43 41 .54 4 6 -4 12.87 12.53 5 6 -4 59.31 59.10 6 6 -4 42.81 42.05 7 6 -4 61.31 61 .86 8 6 -4 25.08 24.70 9 6 -4 26.85 27.18 1 7 -4 92. 27 92.86 2 7 -4 31.45 33.77 3 7 -4 20.89 18.94 4 7 -4 21.94 22.25 5 7 -4 59.53 60.65 6 7 -4 28.67 29.08 7 7 -4 38.72 38.05 8 7 -4 33.22 32.90 9 7 -4 27.21 27.21 1 8 -4 66.85 66.95 2 8 -4 71.88 72.58 3 8 -4 9.4 4 7.13 4 8 -4 29. 22 30. 26 5 8 -4 10.17 10.37 H K L FO FC 6 8 -4 71.30 70.39 7 8 -4 23.80 23.61 8 8 -4 38.25 37.69 9 8 -4 12.40 12.53 1 9 -4 85.79 80.60 2 9 -4 7.20 6.64 3 9 -4 38. 19 37.66 4 9 -4 11.46 11.52 5 9 -4 6. 13 7.34 6 9 -4 2.97* 4.00 7 9 -4 24.88 26.03 8 9 -4 13.05 13.58 9 9 -4 20.74 21. 16 1 10 -4 9 3.08 93,75 2 10 -4 4.98* 3.67 3 10 -4 67.26 69.22 4 10 -4 31.01 30.45 5 10 -4 60.97 6 1.03 6 10 -4 42.23 39.98 7 10 -4 53.95 52.54 8 10 -4 5.56* 2.86 1 11 -4 29.05 27.48 2 11 -4 92.04 92.82 3 11 -4 13. 19 12.77 4 11 -4 54.69 54.38 5 11 -4 22.92 22.88 6 11 -4 51. 18 51.59 7 11 -4 10,46 9.89 8 11 -4 4.24* 1. 39 1 12 -4 10.83 11.54 2 12 -4 75.67 76.93 3 12 -4 12.83 12.98 4 12 -4 49.61 50.00 5 12 -4 30.88 30.47 6 12 -4 87.95 85.32 7 12 -4 12.80 12. 13 8 12 -4 16.67 15.22 1 13 -4 21.82 21.62 2 13 -4 19. 14 19.30 3 13 -4 67.24 67.42 4 13 -4 8.54 8.84 5 13 -4 52.97 5 2.50 6 13 -4 0.86* 1.56 7 13 -4 21.01 21.55 1 14 -4 52^96 54.69 2 14 -4 37. 21 38.43 3 14 -4 29.43 30.51 4 14 -4 13.58 14. 13 5 14 -4 73.07 71.99 6 14 -4 16.92 17.03 7 14 -4 39.56 3 9.95 1 15 -4 8.32 7.69 2 15 -4 33.21 33.03 3 15 -4 25,65 26. 12 4 15 -4 20.70 20.31 5 15 -4 29.08 28.65 6 15 -4 15.17 15.06 7 15 -4 5.30* 5. 14 H K L FO FC 1 16 -4 0.00* 1 .65 2 16 -4 46.68 47.66 3 16 -4 11.01 10. 89 4 16 -4 32.65 32.38 5 16 -4 1.69* 3.05 6 16 -4 30.34 29.82 1 17 -4 29.20 28.90 2 17 -4 17.46 17.39 3 17 -4 20.03 19.59 4 17 -4 21.96 22.67 5 17 -4 2.98* 1.07 1 18 -4 67.56 68.69 2 18 -4 11.53 12. 39 3 18 -4 35.34 36.71 4 18 -4 11.60 11.26 1 19 -4 31. 21 32.06 2 19 -4 13.33 13.91 3 19 -4 11.09 11.22 1 20 -4 0.00* 1,76 2 20 -4 44.20 45.50 1 0 -3 65.86 68. 14 3 0 -3 31.41 30.49 5 0 -3 22.14 19. 19 7 0 -3 54.54 54.27 9 0 -3 53. 28 55.46 1 1 -3 , 17,47 17.76 2 1 -3 41.94 37.77 3 1 -3 29.01 32.00 1 -3 39.59 37.85 5 1 -3 34.90 37.21 6 1 -3 18. 18 19. 17 7 1 -3 39.93 41 .54 8 1 -3 13.48 13. 80 9 1 -3 31.44 32.42 10 1 -3 0.00* 2. 22 1 2 -3 14.03 15.29 2 2 -3 41.64 42.01 3 2 -3 64.43 60.99 4 2 -3 95.54 94.52 5 2 -3 23.07 21.31 6 2 -3 12.30 12.33 7 2 -3 16.71 15.31 8 2 -3 83.48 86.6 9 9 2 -3 25.79 27.20 10 2 -3 9.33 7.59 1 3 -3 11.00 10. 27 2 3 -3 50.75 48.86 3 3 -3 86.49 85.55 a 3 -3 4.40* 2.78 5 3 -3 27.64 30. 16 6 3 -3 35.50 34.78 7 3 -3 34.81 34.68 8 3 -3 22.76 23.01 9 3 -3 14.45 15.19 10 3 -3 0.00* 2.74 1 4 -3 56.03 53.05 2 4 -3 74.27 73.73 3 4 -3 95.22 92.99 H K L FO FC 4 4 -3 18.97 18.18 5 4 -3 105.61 104.04 6 4 -3 4.46* 4.71 7 4 -3 54. 1 1 55.22 8 4 -3 17.23 17.69 9 4 -3 27.79 28.77 10 4 -3 2.84* 2.95 1 5 -3 106.65 124. 17 2 5 -3 6.83 7.50 3 5 -3 18. 11 18.34 4 5 -3 48.63 46.86 5 5 -3 59, 17 57.55 6 5 -3 69.21 68.59 7 5 -3 39.09 40.02 8 5 -3 16.78 17.52 9 5 -3 33.29 33.65 10 5 -3 5.73* 5.51 1 6 -3 49.56 48.61 2 6 -3 48.56 45.70 3 6 -3 3.78* 7.36 4 6 -3 54.71 53.16 5 6 -3 11.95 11. 22 6 6 -3 59.22 58.02 7 6 -3 14.74 13.95 8 6 -3 43.88 43.61 9 6 -3 0.00* 1.79 1 7 -3 6.91 5.61 2 7 -3 87.65 80.81 3 7 -3 8.67 6.59 4 7 -3 6.33 3.67 5 7 -3 11.39 11.24 6 7 -3 3.01* 0.52 7 7 -3 36.93 36.62 8 7 -3 4. 17* 3. 10 9 7 -3 7.96 7.36 1 8 -3 86.38 88.36 2 8 -3 7.01 6.49 3 8 -3 69.43 67.36 4 8 -3 24, 16 20.58 5 8 -3 23.22 20.99 6 8 -3 11.62 1 1.28 7 8 -3 42.35 41.82 8 8 -3 7. 17 7. 12 9 8 -3 30. 15 29.83 1 9 -3 46. 11 47.05 2 9 -3 64.51 64.62 3 9 -3 52.56 49.89 4 9 -3 10.93 10.60 5 9 -3 10.63 10.47 6 9 -3 3.56* 2.08 7 9 -3 3. 17* 3.04 8 9 -3 3.46* 1.30 9 9 -3 39.35 39.00 1 10 -3 23.05 22. 12 2 - 10 -3 125.87 127.32 3 10 -3 31.59 30.71 4 10 -3 53.81 52.92 5 10 -3 6.05 • 5.54 H K L FO FC 6 10 -3 67.84 65.94 7 10 -3 15.78 14.44 8 10 -3 5.86* 3.64 9 10 -3 17.32 18.04 1 11 -3 53.98 53.31 2 11 -3 20.55 22.48 3 1 1 -3 44.39 45.58 4 1 1 -3 9.60 9. 83 5 11 -3 16.50 15.64 6 11 -3 19.82 19.75 7 11 -3 4.88* 6.94 8 11 -3 28.86 28.82 1 12 -3 53.77 51.70 2 12 -3 24.06 24.62 3 12 -3 85. 36 84.99 4 12 -3 5.00* 2 • 3.2 5 12 -3 87.55 87. 19 6 12 -3 39.68 40.07 7 12 -3 35. 03 34.34 8 12 -3 15.59 14.84 1 13 -3 5.49* 7.82 2 13 -3 37.88 38.70 3 13 -3 38. 13 39.40 4 13 -3 8.79 7.50 5 13 -3 7.65 8. 25 6 13 -3 22.00 21.05 7 13 -3 17.74 17.88 8 13 -3 0.00* 2.31 1 14 -3 23.35 25.00 2 14 -3 71,63 73.56 3 14 -3 54.93 56.32 4 14 -3 46.79 46.97 5 14 -3 10.25 10.67 6 14 -3 61.49 60.52 7 14 -3 7.93 8.66 1 15 -3 24.35 25.53 2 15 -3 28.86 28.88 3 15 -3 13.90 13.69 4 15 -3 10.36 9.28 5 15 -3 . 12.83 14. 29 6 15 -3 4.83* 6.38 7 15 -3 6.85* 6.27 1 16 -3 75.60 76.69 2 16 -3 20.58 21.96 3 16 -3 28. 60 29.22 4 16 -3 9.77 9.32 5 16 -3 36.23 36.45 6 16 -3 3.39* 1. 32 1 17 -3 36.82 38.30 2 17 -3 17.75 18.32 3 17 -3 17.80 18.56 4 17 -3 2.91* 2.75 5 17 -3 4.65* 3.89 6 17 -3 0.00* 3.54 1 18 -3 4.62* 2.27 2 18 -3 40.71 40.81 3 18 -3 9.64* 9.69 4 18 -3 36.85 37. 14 H K L FO FC 5 18 -3 * 8.69 7.63 1 19 -3 0.00* 3.44 2 19 -3 20.85 21.27 3 19 -3 18.35 19.21 4 19 -3 1.78* 0.69 1 20 -3 36.57 38.08 2 20 -3 1.74* 1. 17 3 20 -3 31.70 33.40 2 0 -2 38.50 33.53 4 0 -2 130.86 144.30 6 0 -2 6.00* 4.37 8 0 -2 100.71 105.44 10 0 -2 26.03 26.83 1 1 -2 29.85 33.47 2 1 -2 56.20 55.60 3 1 -2 64.63 64.69 4 1 -2 6.78 8.37 5 1 -2 25.59 25.28 6 1 -2 4.20* 3.58 7 1 -2 24.30 26.78 8 1 -2 13.80 14.66 9 1 -2 10.79 11.45 10 1 -2 12.30 12.88 1 2 -2 3.75* 7.91 2 2 -2 37.23 37.86 3 2 -2 126.94 156.61 4 2 -2 19.33 19.34 5 2 -2 108.23 113.65 6 2 -2 27.53 28.04 7 2 -2 57.85 58.84 8 2 -2 22.09 21.81 9 2 -2 52.45 56. 10 10 2 -2 3.33* 4.79 1 3 -2 30.84 29.65 2 3 -2 49.06 50. 19 3 3 -2 77.06 70.32 4 3 -2 45.57 44.35 5 3 -2 57.62 57.28 6 3 -2 7.71 7.25 7 3 -2 3.50* 3.46 8 3 -2 32.78 33. 32 9 3 -2 38.31 38.44 10 3 -2 13.52 14.66 1 4 -2 14.22 17. 17 2 4 -2 113.85 134.60 3 4 -2 16.41 15.57 4 4 -2 148. 13 172.79 5 4 -2 46.23 44.28 6 4 -2 115.74 110.33 7 4 -2 12.01 12.24 8 4 -2 75.55 74.49 9 4 -2 1.60* 1. 19 10 4 -2 14.84 15.09 1 5 -2 76. 16 75.25 2 5 -2 69. 15 65.36 3 5 -2 33.96 31.63 4 5 -2 27.65 27.91 5 5 -2 10.71 5.70 H K L FO FC 6 5 -2 34.64 33.0 3 7 5 -2 22.00 21.46 8 5 -2 3.08* 0.56 10 5 -2 4.22* 3.57 1 6 -2 61.31 62.55 2 6 -2 11.42 10.52 3 6 -2 1 12.42 112.92 4 6 -2 48. 12 44.36 5 6 -2 84.24 81.23 6 6 -2 17.38 17.15 7 6 -2 58.55 57. 13 8 6 -2 10.43 9.12 9 6 -2 57. 27 57.04 10 6 -2 7.39* 7.63 1 7 -2 107.99 115.04 2 7 -2 47.31 45.12 3 7 -2 10.11 5.90 4 7 -2 22.67 21.40 c u 7 -2 63.81 58.86 6 7 -2 4.00* 4.57 7 7 -2 21.69 21.42 8 7 -2 5.45* 0.59 9 7 -2 43.69 43.06 1 8 -2 30. 15 30.25 2 8 -2 120.01 128.28 3 8 -2 19.36 17.61 4 8 -2 9.05 4.68 5 8 -2 12.68 12. 13 6 8 -2 42. 12 39.19 7 8 -2 9.54 10.41 8 8 -2 36.23 34.83 9 8 -2 2.27* 1.00 1 9 -2 37.06 34.25 2 9 -2 25.92 26.06 3 9 -2 12.33 11 .67 4 9 -2 13. 28 12.57 5 9 -2 23.44 21.69 6 9 -2 29.37 28.22 7 9 -2 6.40* 7.27 8 9 -2 40.56 38.58 9 9 -2 6. 3 3* 5.04 1 10 -2 104.36 105.37 2 10 -2 22.00 18.87 3 10 -2 102.20 100.84 4 10 -2 47.23 45.77 5 10 -2 38.65 37.65 6 10 -2 49.21 48.88 7 10 -2 43. 13 41.00 8 10 -2 6.7 0* 4.89 9 10 -2 45. 27 43.88 1 11 -2 9.6 2 9.26 2 11 -2 10.47 9.50 3 11 -2 12. 35 8.78 4 1 1 -2 6.67 4.51 5 1 1 -2 31.40 31.53 6 11 -2 21.60 21.31 7 11 -2 43.47 42.91 8 11 -2 0.00* 1 .95 H K L FO FC 9 11 -2 27.59 27.62 1 12 -2 6.41 8.92 2 12 -2 126.65 ( 128.38 3 12 -2 5.88* 3.25 4 12 -2 48.21 46.85 5 12 -2 14.66 14. 14 6 12 -2 92.99 90.60 7 12 -2 12. 18 12.55 8 12 -2 23.67 21.80 1 13 -2 24.21 25.60 2 13 -2 48.31 47.78 3 13 -2 19.79 19. 19 4 13 -2 39.34 38.75 5 13 -2 12.22 11.99 6 13 -2 19.91 20.73 7 13 -2 19.66 18.72 8 13 -2 11.47 10.66 1 14 -2 66. 18 67.31 2 14 -2 53.31 51.55 3 14 -2 49.31 49.48 4 14 -2 4.98* 3.57 5 14 -2 61.88 61.30 6 14 -2 15.65 15.74 7 14 -2 37.09 36.51 1 15 -2 8.56 8.52 2 15 -2 4.52* 5.60 3 15 -2 85. 12 85.83 4 15 -2 9.68 9.07 5 15 -2 5.47* 6. 11 6 15 -2 8.97 7.92 7 15 -2 13.40 12. 13 1 16 -2 46.66 48.08 2 16 -2 56.90 58.00 3 16 -2 19.70 19.95 4 16 -2 32.93 3 2.58 5 16 -2 17. 19 17. 16 6 16 -2 31,43 31. 27 1 17 -2 11.26 12.23 2 17 -2 22. 11 22. 13 3 17 -2 4.29* 3.54 4 17 -2 15. 15 15.45 5 17 -2 3,89* 5.66 6 17 -2 11.45 12. 20 1 18 -2 51.38 51.99 2 18 -2 2.90* 2.88 3 18 -2 42.58 42.92 4 18 -2 3.60* 3.94 5 18 -2 39.43 39.96 1 19 -2 18.43 19. 15 2 19 -2 0.00* 2.31 3 19 -2 17.30 17.78 4 19 -2 13.02 12.83 1 20 -2 3.93* 3.73 2 20 -2 30.79 32. 11 3 20 -2 13.81 14.25 1 21 -2 2.50* 0.43 1 0 -1 0.00* 308.78 5 0 -1 63. 15 65.93 H K L FO FC H K L FO FC 7 0 -1 51.90 55.56 9 6 --I 13.79 14.78 9 0 -1 73.70 77.21 10 6 -1 49.31 49.31 1 1 -1 13.05 11.48 1 7 -1 37.80 36.00 2 1 -1 10.46 6.17 2 7 -1 38.42 34.59 3 1 -1 30.64 34.08 3 7 -1 7.06 10.74 4 1 -1 29.40 24.46 4 7 -1 61.79 55.08 5 1 -1 28. 18 28.60 5 7 -1 46.22 43.57 6 1 -1 40.43 39.62 6 7 -1 8. 10 5.00 7 1 -1 2.58* 0.80 7 7 -1 22.53 22. 16 "8 1 -1 13.04 13.97 8 7 -1 26.97 26.58 9 1 -1 27.85 28.89 9 7 -1 8.78 7.97 1 0 1 -1 13. 38 13.05 10 7 -1 3.73* 1.67 1 2 -1 4.79* 2.92 1 8 -1 127.46 162.08 2 2 -1 96.68 109.38 2 8 -1 55.40 53.66 3 2 - 1 29.83 25.37 3 8 -1 97.77 92.13 5 2 -1 21. 10 22.31 4 8 -1 6.43 6.34 6 2 -1 62. 19 58.91 5 8 -1 40.36 39.04 7 2 -1 10.88 7.64 6 8 -1 14.09 13.49 8 2 -1 106.87 108.22 7 8 - 1 73.58 71.94 9 2 -1 16.48 15.94 8 8 -1 1. 13* 3.64 10 2 -1 28.26 29. 13 9 8 -1 62.09 61.83 1 3 - 1 38.01 37.61 1 9 -1 0.00* 1.21 2 3 -1 60.49 57.66 2 9 - 1 4.46* 4.75 3 3 - 1 109.28 105.04 3 9 -1 33.06 30.08 4 3 -1 38.69 32.38 4 9 -1 15,28 13.82 5 3 - 1 54.45 50.17 5 9 -1 44. 11 42.41 6 3 -1 23.09 22.59 6 9 -1 7.60 8.31 7 3 - 1 7.85 4.52 7 9 -1 3,92* 2,22 8 3 -1 18.41 16.77 8 9 -1 5.71* 3.97 9 3 -1 9.38 8.30 9 9 -1 23.95 22.77 10 3 -1 12.79 12.90 1 10 -1 49. 13 47.31 1 4 - 1 78.88 78.00 2 10 -1 121.76 123. 32 2 4 -1 46.78 45.05 3 10 -1 12.90 11.37 4 4 -1 49.01 45.67 4 10 -1 40.81 38.57 5 4 -1 167. 14 194.00 5 10 -1 23.61 24.22 6 4 - 1 4.68* 0.28 6 10 -1 112.35 110.29 7 4 -1 94.55 90. 14 7 10 -1 20,92 21.24 8 4 - 1 9.01 8.96 8 10 -1 44.59 42.89 9 4 -1 67.75 65.96 9 10 -1 25.45 25. 33 10 4 -1 3.64* 1.50 1 11 -1 24.40 22.55 1 5 - 1 92.56 97.59 2 11 -1 16.78 16.40 2 5 -1 49.43 45. 18 3 11 -1 13.00 10.33 3 5 - 1 35. 31 30.06 4 11 -1 26.51 24.72 4 5 -1 10.56 10.69 5 11 -1 15.68 15.51 5 5 -1 100.90 93. 36 6 11 -1 23.88 22.36 6 5 -1 4.64* 4.48 7 11 -1 2.45* 3.96 7 5 -1 42.68 41.64 8 11 -1 26.37 26.31 8 5 - 1 15.73 15.80 9 11 -1 5.92* 5. 12 9 5 -1 17.09 16.38 1 12 -1 59.93 59.73 10 5 -1 9.14 9.06 2 12 -1 50.36 45. 12 1 6 - 1 53.80 58.03 3 12 -1 77.33 73.04 2 6 -1 125.99 168.29 4 12 - 1 8. 14 7.61 3 6 -1 80.68 74.17 5 12 -1 108.08 106,08 4 6 -1 113,38 109.19 6 12 - 1 58.75 57.25 5 6 -1 12.37 9.44 7 12 -1 74.94 72.74 6 6 -1 117.40 113.39 8 12 -1 13.24 12.79 7 6 -1 6.52* 6.27 1 13 -1 9.89 10.53 8 6 -1 82. 31 80. 16 2 13 -1 26.03 26.22 H K L FO FC 3 13 - •) 62.81 63.69 4 13 -1 12.60 11.56 5 13 - 1 0.00* 4.53 6 13 -1 26. 35 26.65 7 13 -1 12.27 13. 27 8 13 - 1 5.68* 5.55 1 14 -1 18.55 16. 86 2 14 - 1 77.43 76.73 3 14 -1 21. 12 22.26 4 14 -1 38. 25 37.40 5 14 - 1 26.53 25.97 6 14 -1 71.52 69. 13 7 14 - 1 25.32 25.95 8 14 -1 35.61 35.66 1 15 - 1 17.06 16.75 2 15 -1 53.57 52.87 3 15 - 1 7.86 7.61 4 15 -1 24. 18 24.41 5 15 -1 7. 15 6.51 6 15 -1 11. 20 11.02 7 15 - 1 13.32 13.31 1 16 -1 81.37 82. 19 2 16 - 1 23.66 23.07 3 16 - 1 42.94 42.88 4 16 - 1 0.41* 0.87 5 16 -1 , 26.71 26.37 6 16 - 1 14.19 15.54 7 16 - 1 28. 23 28.56 1 17 - 1 4.76* 6.92 2 17 -1 0.00* 1.50 3 17 - 1 28.92 29.61 4 17 -1 5.35* 4.00 5 17 -1 27.68 27.38 6 17 - 1 3.75* 4.62 1 18 - 1 21.90 21.82 2 18 -1 53.84 55.01 3 18 - 1 2.03* 1.41 4 18 -1 43.93 45.52 5 18 - 1 10.28 10.25 1 19 -1 0.70* 6.34 2 19 -1 6.69* 8.09 3 19 -1 4.08* 3.99 4 19 -1 11. 11 11.89 1 20 - 1 28.99 30.45 2 20 -1 2.70* 3.40 3 20 - 1 42.29 42.93 1 21 -1 10.8 3 11.27 2 21 - 1 7 .36* 7.44 6 0 0 8.97* 13.57 8 0 0 131.75 128.68 10 0 0 49.22 50.82 1 1 0 0.00* 3.79 2 1 0 91.35 105.83 3 1 0 59.02 52.00 4 1 0 64.37 57.83 5 1 0 14.85 11 .24 6 1 0 6.4 5* 7. 14 7 1 0 21.94 22.01 H K L FO FC 8 1 0 18.41 17.43 9 1 0 7. 13* 3.68 10 1 0 18.74 18.55 0 2 0 4.87* 1.35 1 2 0 0.00* 286.24 2 2 0 52.25 45.85 4 2 0 23. 13 20.00 5 2 0 113.46 107.91 6 2 0 0.00* 1.20 7 2 0 105.10 100.02 8 2 0 29.81 27. 15 9 2 0 77.78 75.41 10 2 0 4.72* 8.34 1 3 0 58.33 60.13 2 3 0 0.00* 3.70 3 3 0 87.74 84. 16 4 3 0 26.81 27.27 5 3 0 34.04 32.03 6 3 0 42.70 40.45 7 3 0 0.00* 2.85 8 3 0 10.34* 9.25 9 3 0 38.84 37.93 10 3 0 0.00* 0.43 0 4 0 0.00* 204.15 1 4 0 84.95 97.30 2 4 0 93.58 90.71 3 4 0 56.95 56.76 4 4 0 144.11 167. 14 5 4 0 12.82 12.57 6 4 0 143.83 140.44 7 4 0 16.48 15.75 8 4 0 1 11.63 106.85 9 4 0 16.23 15.74 10 4 0 25.21 24.71 1 5 0 87.37 88.77 2 5 0 71.83 67.49 3 5 0 1.72* 2.58 4 5 0 41. 10 39.06 5 5 0 43.50 42.31 6 5 0 0.00* 1.87 7 5 0 57.78 54.60 8 5 0 30.66 29.72 9 5 0 9.36 9.87 10 5 0 0.00* 0.96 0 6 0 83.76 103.25 2 6 0 20.69 17.32 3 6 0 134.47 159.23 4 6 0 28.94 24.65 5 6 0 130.85 124.77 6 6 0 0.00* 0.59 7 6 0 95.85 92.39 8 6 0 16.75 16.33 9 6 0 52.37 51.43 10 6 0 13.69 13.00 1 7 0 99.78 110.68 2 7 0 41.34 28.20 3 7 0 3.41* 5.61 4 7 0 13.22 9.77 H K L FO FC 5 7 0 35,4 8 36.63 6 7 0 16,37* 15.95 7 7 0 78.75 76.22 8 7 0 24.46 24.42 9 7 0 8.7 4 1 .82 10 7 0 11.95* 11.50 1 8 0 38.68 38.17 2 8 0 133.99 158.30 3 8 0 42.48 41.42 4 8 0 75.51 70.53 5 8 0 9.56 9.69 6 8 0 87.55 83.20 7 8 0 15.89 15. 30 8 8 0 37.67 33.94 9 8 0 11.29* 12. 13 1 9 0 30.88 27.37 2 9 0 10.48* 4.92 3 9 0 55.59 51.75 9 0 11.06 10.69 5 9 0 0. 00* 2.57 6 9 0 21.79 21.66 7 9 0 3.89* 2.64 8 9 0 3.57* 1 .37 9 9 0 6.95* 3.47 0 10 0 11.55* 13.36 1 10 0 90, 19 88.41 2 10 0 105.57 101.79 3 10 0 117.30 112.58 10 0 6.36* 4.41 5 10 0 85.20 81. 25 6 10 0 51.18 49.03 7 10 0 77. 14 74.69 8 10 0 11.88 11.98 9 10 0 30.26 31 .65 1 1 1 0 3. 20* 4.73 2 11 0 33.80 36.46 3 1 1 0 37.86 37.06 4 11 0 24.21 23. 18 5 1 1 0 7.35* 6.78 6 11 0 0.00* 2.55 7 1 1 0 5.69* 6.25 8 1 1 0 4.98* 4. 34 9 11 0 9. 25 8.72 0 12 0 0.00* 5.02 1 12 0 4,08* 7.62 2 12 0 104.09 101.94 3 12 0 40. 11 40.35 4 12 0 76.90 75.26 c; ~j 12 0 59.97 57.21 6 12 0 127.52 123.80 7 12 0 27.15 26.09 8 12 0 26. 32 26. 39 1 13 0 0.00* 2.79 2 13 0 0.00* 8.34 3 13 0 28.77 29.49 4 13 0 10.15* 11.68 5 13 0 0.00* 2.15 6 13 0 15.35 15.61 H K L ,F0 FC 7 13 0 4. 36* 4, 18 8 13 0 9. 15* 9. 21 0 14 0 27.71 26.09 1 14 0 51.67 51.10 2 14 0 29.24 28.94 3 14 0 59.26 57.77 4 14 0 29.51 30.51 5 14 0 66.95 63.77 6 14 0 45.06 44.00 7 14 0 45.95 46. 19 8 14 0 3.36* 0.33 1 15 0 24.33 25.44 2 15 0 15.94 18.08 3 15 0 46. 19 48.56 4 15 0 8.98* 8.48 5 15 0 22. 15 21.09 6 15 0 3.22* 2. 15 7 15 0 8.52 9. 16 0 16 0 87.43 87.41 1 16 0 27.80 26.98 2 16 0 61.63 61.32 3 16 0 34.36 35.31 4 16 0 32.97 32. 14 5 16 0 20.43 19.89 6 16 0 22.64 21.75 7 16 0 6.23* 5.86 1 17 0 0.00* 0.70 2 17 0 25. 11 24.64 3 17 0 15.39 15.53 4 17 0 17.53 17.35 5 17 0 9. 13* 9.57 6 17 0 • 0.00* 0.56 0 18 0 26. 15 24.92 1 18 0 61.52 62.34 2 18 0 16.23 16.63 3 18 0 42. 10 43.61 4 18 0 23.06 23.93 5 18 0 17.56 17.52 1 19 0 37.56 37.94 2 19 0 0.00* 0.29 3 19 0 25.50 27.22 4 19 0 2.58* 0.81 0 20 0 26.05 28.05 1 20 0 0.00* 0.55 2 20 0 23.76 25.49 3 20 0 13.55 14.59 1 21 0 9.38* 9.95 2 21 0 0.00* ,1.45 1 0 1 0.00* 235.74 3 0 1 1 19.89 159.21 5 0 1 48.28 49.84 7 0 1 51.31 52.26 9 0 1 44.61 47.91 0 1 1 45.08 39.08 1 1 1 26.08 23.30 2 1 1 67. 18 64.80 3 1 1 108.72 11 1.99 4 1 1 60.08 61.40 H K L , FO FC 5 1 1 9.18 8.49 6 1 1 "46.09 45.06 7 11 3.62* 2.58 8 1 1 14.39 13.53 9 1 1 16.04 15.67 10 1 1 9.82 9. 26 0 2 1 0.00* 271.73 1 2 1 52.05 49.55 2 2 1 27.68 3.82 3 2 1 47.40 45.34 4 2 1 133.86 142.76 5 2 1 20,47 16.94 6 2 1 53.46 52.42 7 2 1 10.46 6.26 8 2 1 98.53 95.25 9 2 1 7.94* 9.19 10 2 1 17.74 18.49 0 3 1 5.36 2.72 1 3 1 4.33 1.33 2 3 1 57.38 50.94 3 3 1 109.57 107.67 4 3 1 79.07 70.98 5 3 1 39.46 34.46 6 3 1 19.01 16.44 7 3 1 28.62 27.90 8 3 1 23.18 21.07 9 3 1 24.97 24.01 10 3 1 16.54 16.56 0 4 1 24.25 25.63 1 4 1 12.91 9.89 2 4 1 26.16 26.03 3 4 1 71.41 67.06 4 4 1 13.43 8.38 5 4 1 152.72 160.70 6 4 1 23,95 23.24 7 4 1 89.54 85.03 8 4 1 26.68 26.55 9 4 1 50.70 49.98 10 4 1 9.42 9.96 0 5 1 24.59 23.45 1 5 1 102.51 132.30 2 5 1 48.09 43.31 3 5 1 88.91 85.45 4 5 1 14.79 12.93 5 5 1 46.96 42.18 6 5 1 25.42 23.77 7 5 1 43.19 41.04 8 5 1 13.75 13. 36 9 5 1 23.56 22.37 ,10 5 1 3.05* 0.92 0 6 1 107.82 153.11 1 6 1 75.81 72.20 2 6 1 125.92 173.72 3 6 1 13.47 12.44 4 6 1 107.42, 104.63 5 6 1 2.08* 0.95 6 6 1 86.47 83.70 7 6 1 40.68 41.07 H K I FO FC 8 6 1 47.40 44.26 9 6 1 13.35 12.84 10 6 1 40.90 40.49 0 7 1 30.99 25. 15 1 7 1 1.92* 1.21 2 7 1 38.02 39.03 3 7 1 3.05* 2.93 4 7 1 32.82 30.65 5 7 1 4.63* 6.76 6 7 1 18.55 16.61 7 7 1 25.94 25.33 8 7 1 17.25 17.44 9 7 1 10.54 11.21 0 8 1 15.51 15.74 2 8 1 8.75 8.01 3 8 1 135.25 143.44 4 8 1 27.99 28.11 5 8 1 30.43 28.68 6 8 1 23.34 23.55 7 8 1 32.07 30.47 8 8 1 3.00* 0.59 9 8 1 34.72 34.93 0 9 1 30.02 27.51 1 9 1 48.34 44.88 2 9 1 25.50 22. 16 3 9 1 114.31 111.10 4 9 1 41.84 40.05 5 9 1 9.21 6.94 6 9 1 6.51 7.89 7 9 1 15.67 15.07 8 9 1 18.62 19. 14 9 9 1 30.26 31.43 0 10 1 90.83 83.57 1 10 1 30.00 31.04 2 10 1 140.08 152.83 3 10 1 37.08 33.40 4 10 1 48.11 47.44 5 10 1 23.74 23.05 6 10 1 76.98 75.61 7 10 1 8.41 7.26 8 10 1 13.66 11.92 9 10 1 7.57 7.47 0 11 1 11.12 11.92 1 11 1 45.97 40.81 2 11 1 68.36 63. 10 3 11 1 15.45 15.62 4 11 1 62.29 62. 19 5 11 1 0.00* 0.53 6 11 1 24.47 24.29 7 11 1 0.00* 2. 10 8 11 1 22.76 23.7 3 9 11 1 9.07 11.30 0 12 1 33.17 30.81 1 12 1 64.80 62.23 2 12 1 77.37 71.82 3 12 1 100.00 95.20 4 12 1 2.63* 1.08 5 12 1 90.74 89,72 H K L FO FC 6 12 <\ 49.65 48.09 7 12 1 59.84 57. 19 8 12 1 1.92* 3.69 0 13 1 49.30 46.75 1 13 1 34.46 34.26 2 13 1 0.00* 3.95 3 13 1 0.00* 0.99 4 13 1 11.98 10.54 5 13 1 26.49 26.01 6 13 1 0.83* 3.32 7 13 1 2.47* 1.03 8 13 1 19.22 20. 14 0 14 1 36.54 34.20 1 14 1 13. 54 14.49 2 14 1 97. 10 95.43 3 14 1 32.01 32.82 4 14 1 54. 10 54.78 5 14 1 21.34 21.30 6 14 1 65.45 63. 48 7 14 1 5.11* 5.86 0 15 1 29. 17 30.07 1 15 1 0.00* 0.51 2 15 1 10.06 13.20 3 15 1 0.00* 1.58 a 15 1 21.37 20.3 1 5 15 1 9.67 8.00 6 15 1 10.20 10.59 7 15 1 5.88* 6.83 0 16 1 51.52 52.15 1 16 1 73.24 72. 13 2 16 1 56.59 55.73 3 16 1 59.88 59.36 4 16 1 11.16 10. 10 5 16 1 21.87 21 .58 6 16 1 2.07* 1.41 7 16 1 34.04 34.26 0 17 1 0.00* 4. 32 1 17 1 60.41 59.29 2 17 1 0.57* 1 .48 3 17 1 0.00* 0.43 4 17 1 0.00* 0.95 5 17 1 25.89 26.02 6 17 1 4.65* 5.60 0 18 1 61.57 61.95 1 18 1 37.92 39.09 2 18 1 35. 14 34.83 3 18 1 28.63 27.33 4 18 1 38.09 39.13 5 18 1 18.60 18.56 0 19 1 20.51 20.43 1 19 1 4.46* 4.71 2 19 1 37.39 38.67 3 19 1 10.74 11.89 4 1 9 1 19.25 20.49 0 20 1 10.64 11.27 1 20 1 9.62 10. 19 20 1 0.00* 1 .05 3 20 1 24.75 26.35 H K I FC FC 0 21 1 11.00 1 1.81 1 21 1 13.56 13.72 2 21 1 4.55* 2.49 0 0 2 0.00* 232. 16 2 0 2 59.67 59.39 6 0 2 47.35 47.03 8 0 2 49.89 52.34 10 0 2 13.99 14. 17 0 1 2 9.24 13.42 1 1 2 43.66 47.85 2 1 2 2.31* 5.44 3 1 2 106.79 109. 15 4 1 2 47.50 44.61 5 1 2 11.53 10.88 6 1 2 2. 14* 0.29 7 1 2 12.72 13. 19 8 1 2 5.60* 2.68 9 1 2 21.20 23.09 10 1 2 12.09 12.69 0 2 2 67.23 75.81 1 2 2 68.70 72.73 2 2 2 22.50 21.02 3 2 2 89.77 89.41 4 2 2 12.83 12. 15 5 2 2 113.67 108.20 6 2 2 3.59* 6.25 7 2 2 29.08 28.81 8 2 2 1.94* 0.92 9 2 2 34.58 34.49 10 2 2 10.89 12. 17 0 3 2 55.38 60.22 1 3 2 45.28 44.44 2 3 2 80.24 77.75 3 3 2 103.55 102. 13 4 3 2 41.20 36.81 5 3 2 19.94 17.32 6 3 2 5.04* 1.34 7 3 2 18.00 15.80 8 3 2 23.83 23.70 9 3 2 29.95 29.88 10 3 2 2.92* 2.08 0 4 2 40.80 43.01 1 4 2 48.96 48.89 2 4 2 46.48 40.55 3 4 2 46.27 45.50 4 4 2 127.40 128.44 5 4 2 20.36 20.31 6 4 2 73.48 72.24 7 4 2 14.15 12.97 8 4 2 81.04 79.27 9 4 2 23.45 24.26 10 4 2 16.01 14.70 0 5 2 62.83 57.39 1 5 2 3.38* 0.23 2 5 2 15.77 12.04 3 5 2 44.44 38.09 4 5 2 6.93 4. 36 5 5 2 54.61 49. 11 I H K L FO FC 6 5 2 22.74 22.21 7 5 2 4.01* 4.06 8 5 2 12.36 13.63 9 5 2 9. 18 7.98 10 5 2 6.47* 6.79 0 6 2 45.81 43.48 1 6 2 101.05 102.86 2 6 2 16.20 11.08 3 6 2 75.68 71.07 4 6 2 33.41 31.25 5 6 2 95.60 89.23 6 6 2 12. 33 12. 19 7 6 2 41.29 39.64 8 6 2 2. 13* 0. 16 9 6 2 42.03 42.45 10 6 2 7.21* 9. 13 0 7 2 42.40 43. 32 1 7 2 8.55 8.89 2 7 2 28. 15 25.16 3 7 2 53.90 51.27 4 7 2 2.85* 3.33 5 7 2 71.27 65.36 6 7 2 9.52 9.52 7 7 2 30.00 30.00 8 7 2 15.75 15.86 9 7 2 5.68* 5.13 0 8 2 111.98 120.91 1 8 2 8.83 6.92 2 8 2 129.33 141.88 3 8 2 36.03 33. 39 4 8 2 25.18 24.79 5 8 2 13.87 12.53 6 8 2 22.70 22.10 7 8 2 8.54 8.91 8 8 2 24.84 23.6C 9 8 2 19. 25 19. 13 0 9 2 48.15 44.64 1 9 2 19.86 18.86 2 9 2 65.39 62.42 3 9 2 7.95 5.03 4 9 2 33.88 33.49 5 9 2 23.70 21. 17 6 9 2 5.98* 7.07 7 9 2 0.79* 1.72 8 9 2 19.91 18. 72 9 9 2 9.50 8. 26 0 10 2 31.08 29.88 1 10 2 91. 11 90.63 2 10 2 74.08 66.89 3 10 2 50.70 47.97 4 10 2 25.51 25.84 5 10 2 25,61 26.70 6 10 2 21.28 21.93 7 10 2 48. 27 47.07 8 10 2 14.25 14.63 9 10 2 44. 17 45.36 0 11 2 18.47 18.78 1 1 1 2 48. 10 45.52 H K L FO FC 2 11 2 41.08 40.98 3 11 2 87.08 83.71 4 1 1 2 20. 12 19.09 5 11 2 18. 24 16.99 6 11 2 10.82 11.28 7 11 2 8.54 8.54 8 11 2 6.85* 7. 12 0 12 2 9.42 11.63 1 12 2 3.06* 1. 12 2 12 2 86.53 83.91 3 12 2 3.89* 4.54 4 12 2 32.58 32.92 5 12 2 18.67 18.67 6 12 2 91.37 88.15 7 12 2 15.32 14.96 8 12 2 44. 14 44. 29 0 13 2 27.65 25.28 1 13 2 14.36 13.42 2 13 2 2.63* 4.34 3 13 2 15.65 14.05 4 13 2 7.08 8.20 5 13 2 7. 16 7.84 6 13 2 14.05 13.55 7 13 2 5.68* 4.93 8 13 2 5. 15* 5.32 0 14 2 21.55 23.45 1 14 2 59.38 61.61 2 14 2 16.27 15.64 3 14 2 64.64 63. 13 4 14 2 30.41 30.94 5 14 2 57. 13 57. 27 6 14 2 20.82 21.96 7 14 2 50.08 50. 12 0 15 2 12.22 12.90 1 15 2 27.02 27.23 2 15 2 43.88 42.42 3 15 2 57. 19 57.97 4 15 2 4.36* 5.24 5 15 2 11.48 1 1.91 6 15 2 0.00* 1.04 7 15 2 0.00* 3.93 0 16 2 76.33 76.28 1 16 2 46.82 46.98 2 16 2 72.03 72.30 3 16 2 0.99* 2.53 4 16 2 46.54 47.57 5 16 2 7.04 8.01 6 16 2 23.04 23.00 0 17 2 14.54 14.07 1 17 2 27.65 27.79 2 17 2 9.02 7.54 3 17 2 5.83* 7.63 4 17 2 14.32 13.92 5 17 2 5.35* 5.80 6 17 2 17.49 18.05 0 18 2 36.24 36.70 1 18 2 45.99 46.46 2 18 2 21.80 21.80 H K L FO FC 3 18 2 55,60 54.87 4 18 2 9.26 7.84 5 18 2 30.54 29.92 0 19 2 0.00* 3.35 1 19 2 19.18 18.57 2 19 2 0.00* 1.39 3 19 2 13.44 13.76 4 19 2 0.00* 0.59 0 20 2 18.58 18.74 1 20 2 2.77* 4.24 2 20 2 28. 39 27.93 3 20 2 0.00* 1.62 0 21 2 0.00* 2.00 1 21 2 0.00* 1.67 3 0 3 1 13.56 117.76 5 0 3 18.39 20.32 7 0 3 7.95 9.83 9 0 3 36. 17 38.03 0 1 3 84.54 108.69 1 1 3 68.67 72.74 2 1 3 21,88 20.77 3 1 3 48.15 53.6 2 4 1 3 57.97 57.92 5 1 3 28.44 26.44 6 1 3 2.06* 1 .09 7 1 3 21.71 22.47 8 1 3 26.78 27.76 9 1 3 8.39 8.17 10 1 3 3.96* 5.33 1 2 3 23.64 21.15 2 2 3 69.42 64.58 3 2 3 34.25 32. 25 4 2 3 117.20 118.98 5 2 3 3.02* 0.56 6 2 3 3.3 0* 3.06 7 2 3 14.50 14.08 8 2 3 79.41 80.30 9 2 3 9.50 9.62 10 2 3 30.66 32.15 0 3 3 0.00* 8.06 1 3 3 1C0.06 117.35 2 3 3 14.72 10. 19 3 3 3 36,00 34.35 4 3 3 56.55 52.31 5 3 3 77.68 75.98 6 3 3 7.80 6.79 7 3 3 13.90 14.44 8 3 3 16.46 15.83 9 3 3 25.29 26.04 10 3 3 13.45 14.70 0 4 3 10.45 5.16 1 4 3 52.45 53.53 2 4 3 16.48 15.75 3 4 3 27.11 27.67 4 4 3 6.63 7.24 5 4 3 116.34 111.56 6 4 3 29.15 29.61 7 4 3 74.04 71.93 fi K I FO FC 8 4 3 4.83* 5.62 9 4 3 57.88 57.77 10 4 3 1.82* 2.07 0 5 3 32.82 29.05 1 5 3 9.28 7.36 2 5 3 26.54 24. 19 3 5 3 27.05 24.60 4 5 3 89.80 86.51 5 5 3 57.67 53.27 6 5 3 38.47 36.71 7 5 3 48.90 48.90 8 5 3 10.50 9.56 9 5 3 4.06* 0.39 0 6 3 29.03 29.62 1 6 3 13.21 11.55 2 6 3 88.87 85.64 3 6 3 42.23 42. 10 4 6 3 75.61 72.22 5 6 3 54.59 51.21 6 6 3 70.81 67.05 7 6 3 20.77 21.06 8 6 3 56.00 54.87 9 6 3 13. 15 14.40 0 7 3 85.52 84.04 1 7 3 69.49 69. 10 2 7 3 49.96 43.64 3 7 3 33. 17 31.83 4 7 3 61.12 60.03 5 7 3 4 4.65 43. 15 6 7 3 24.04 22.38 7 7 3 14.91 14.59 8 7 3 33.91 35.33 9 7 3 7.52 7.50 0 8 3 48.71 43.30 1 8 3 106.48 108.96 2 8 3 42.91 42.05 3 8 3 82.68 82.55 4 8 3 18.36 17.79 5 8 3 45.70 43.85 6 8 3 17.04 17.06 7 8 3 47.63 45.72 8 8 3 11.57 11.38 9 8 3 30.91 30.67 0 9 3 62.86 61.31 1 9 3 2. 17* 1.06 2 9 3 72.71 66. 29 3 9 3 18.68 17.81 4 9 3 4.56* 2.43 5 9 3 35.58 34.73 6 9 3 26.54 25.60 7 9 3 20.21 21.00 8 9 3 8.94 7.74 9 9 3 15.77 15.95 0 10 3 53.03 53.96 1 10 3 6.70 7.02 2 10 3 79.42 78.33 3 10 3 24.52 23.46 4 10 3 28.84 28.25 H K L FO FC 5 10 3 3,92* 1.51 6 10 3 82.02 79.64 7 10 3 5.03* 0.65 8 10 3 35.22 34. 68 9 10 3 9.40 10.73 0 1 1 3 6. 8 9 4.92 1 11 3 30. 28 29.98 2 11 3 13.67 14.08 3 11 3 10.44 1 1.97 4 1 1 3 6.89 6.06 5 11 3 8.47 9.91 6 1 1 3 10.62 10.79 7 11 3 31. 25 30.69 8 1 1 3 11.98 11.61 0 12 3 53.75 53.20 1 12 3 12.18 11.45 2 12 3 14.97 14.51 3 12 3 41.37 41 .06 4 12 3 16.53 16.03 5 12 3 81.20 78.28 6 12 3 38.50 37.98 7 12 3 83.31 80.07 8 12 3 3.22* 1.23 0 13 3 10.34 8.37 1 13 3 10.48 13.06 2 1 3 3 11. 17 12. 17 3 13 3 44.73 46.17 4 13 3 6.05* 4.45 5 13 3 0.00* 1.03 6 13 3 26.33 24.98 7 13 3 10.21 12.26 8 13 ' 3 11. 10 11.32 0 14 3 28.46 29.63 1 14 3 11.29 11.41 2 14 3 69.71 69.02 3 14 3 13.82 14.56 4 14 3 58.99 57.14 5 14 3 9.49 9.47 6 14 3 68.37 66.35 7 14 3 23. 26 22.62 0 15 3 7.90 8.01 1 15 3 39.99 38. 34 2 15 3 18.34 17.51 3 15 3 7.09* 9.82 4 15 3 26.57 26.98 5 15 3 9. 20 8. 86 6 1 5 3 2.49* 7.42 7 15 3 6.92* 7.62 0 16 3 23.37 22.43 1 16 3 72.40 73. 30 2 16 3 8. 14 8.04 3 16 3 74.63 74.75 4 16 3 0.80* 1.85 5 16 3 18.46 18.12 6 16 3 9. 31 9.46 0 1 7 3 33.30 32.97 1 17 3 28.74 29.86 2 17 3 24.88 25.41 H K L FO FC 3 17 3 0.00* 3.80 4 17 3 5. 13* 4.20 5 17 3 28.66 29.73 0 18 3 69.27 69.55 1 18 3 15.37 15.54 2 18 3 49.88 49. 24 3 18 3 9.45* 10.79 4 18 3 38.90 39.01 5 18 3 21.28 21.61 0 19 3 19.93 20.83 1 19 3 9.00 9.75 2 19 3 '17.46 18. 11 3 19 3 0.00* 0.99 4 19 3 20.81 21.03 0 .20 3 10.56 10.68 1 20 3 36.20 35.72 2 20 3 8. 19 8.77 2 0 4 91.33 88.71 4 0 4 103.61 104.19 6 0 4 28.59 30.35 8 0 4 80.48 86.06 10 0 4 38. 36 41.80 0 1 4 71.44 74.61 1 1 4 108.58 149.24 2 1 4 26.53 25.50 3 1 4 28.87 28. 13 4 1 4 82.16 82.20 5 1 4 10.95 10,94 6 1 4 5.98 5. 15 7 1 4 2.04* 1.48 8 1 4 15.65 15. 14 9 1 4 32.55 34.95 10 1 4 3,59* 0.81 0 2 4 6. 18 7.36 1 2 4 110.60 143.58 2 2 4 42.88 40.38 3 2 4 61.94 61.21 4 2 4 25.30 25.27 5 2 4 94.97 96.08 6 2 4 1.79* 0.71 7 2 4 80.01 82. 18 8 2 4 10.43 11.03 9 2 4 68.41 71. 17 10 2 4 5.07* 5.85 0 3 4 70.26 71.99 1 3 4 45.00 42.55 2 3 4 42.08 38.87 3 3 4 75.82 71.48 4 3 4 55.89 54.86 5 3 4 31.60 32.61 6 3 4 2.54* 1.13 7 3 4 44.86 45.00 8 3 4 33.27 33.91 9 3 4 8.24 9,51 0 4 4 99.24 105. 12 1 4 4 66.76 61.80 2 4 4 74.20 70.82 3 4 4 2.36* 4.44 H K L FO FC 4 4 4 73.85 73.51 5 4 4 24.99 23.63 6 4 4 106.98 105.17 7 4 4 35.04 35.49 8 4 4 97.70 96.60 9 4 4 0.00* 0.26 0 5 4 9.07 5.81 1 5 4 67.36 64.33 2 5 4 38.65 36.70 3 5 4 17. 17 17.77 4 5 4 24.98 24.41 5 5 4 56.14 54.3 9 6 5 4 16.05 16.75 7 5 4 16.02 16.37 8 5 4 36.68 36.06 9. 5 4 19.86 20.13 0 6 4 54.08 51. 10 1 6 4 83.48 80.95 2 6 4 49.7 1 45. 12 3 6 4 79.77 76.26 4 6 4 29.55 28. 14 5 6 4 109.54 108.33 6 6 4 8.73 9.24 7 6 4 65.88 64.83 8 6 4 31.61 32.40 9 6 4 49.33 49.25 0 7 4 50.44 50. 19 1 7 4 42.38 41 .76 2 7 4 78. 21 76. 36 3 7 4 7.29 7.97 ii 7 4 54.22 53. 15 5 7 4 26.44 23.92 6 7 4 34.47 32.79 7 7 4 44.99 44.52 8 7 4 5.09* 2.66 9 7 4 3,80* 3.39 0 8 4 111.96 111.56 1 8 4 0.00* 1.97 2 8 4 149.07 169. 1 1 3 8 4 27.49 26.36 4 8 4 82.21 78.00 5 8 4 26.62 26.77 6 8 4 73.12 72.93 7 8 4 27.90 27.85 8 8 4 15.20 15. 11 9 8 4 3.09* 2.52 0 9 4 11.86 12.01 1 9 4 74.34 69.80 2 9 - 4 0.00* 3.76 3 9 4 59.49 58,13 4 9 4 33.08 30.76 5 9 4 21.38 21.27 6 9 4 26.99 27.09 7 9 4 30.66 30.26 8 9 4 8.39 4.99 9 9 4 14.38 14. 17 0 10 4 48.90 48.08 1 10 4 96.36 92.97 H K L FC FC 2 10 4 53.91 51.48 3 10 4 101.80 100.99 4 10 4 10.58 9.96 5 10 4 67.08 66. 11 6 10 4 25.57 25.22 7 10 4 48.89 47.61 8 10 4 6.51* 6.63 0 11 4 4.35* 1.30 1 11 4 28.36 30.85 2 11 4 26.54 25.64 3 11 4 27.12 26.95 4 11 4 10.71 10.68 5 11 4 31.12 30.90 6 11 4 58.66 57. 16 7 11 4 13.11 13.60 8 11 4 9.82 9.51 0 12 4 3.90* 1.42 1 12 4 12.77 11.50 2 12 4 73.82 72.21 3 12 4 21.25 20. 12 4 12 4 47.63 45.71 5 12 4 33. 13 32.95 6 12 ' 4 89.41 87.99 7 12 4 19.03 20.50 8 12 4 35.85 34.67 0 13 4 10. 19 9. 19 1 13 4 9.76 8.27 2 13 4 13.67 13.67 3 13 4 12.11 11.81 4 13 4 23.78 24. 13 5 13 4 40.73 41.19 6 13 4 0.00* 1.21 7 13 4 38.24 38.17 0 14 4 3.21* 0.21 1 14 4 35.91 3 5.89 2 14 4 27.74 27.9 3 3 14 4 76.08 74.46 4 14 4 0.00* 4.92 5 14 4 54.68 53.61 6 14 4 23.08 23.44 7 14 4 47.35 46.88 0 15 4 23.64 22.91 1 15 4 36.65 36.79 2 15 4 30. 15 30.86 3 15 4 39.29 40. 10 4 15 4 27.87 27.80 5 15 4 0.00* 4.02 6 15 4 30.44 31.22 0 16 4 71.33 70.24 1 16 4 24.81 25. 17 2 16 4 66.26 66.22 3 16 4 23.52 24.40 4 16 4 43.24 42. 19 5 16 4 17.64 17.22 6 16 4 22.58 21.87 0 17 4 0.00* 0.72 1 17 4 35.92 35.29 2 17 4 19.36 19.55 H K L FO • FC 3 17 4 21. 35 21.84 4 17 4 0.00* 3. 1 1 5 17 4 13.92 13.29 0 18 4 0.00* 3.26 1 18 4 37.57 36.93 2 18 4 24.73 24.38 3 18 4 36.21 36.96 4 18 4 32. 17 33.61 0 19 4 18,94 19.09 1 19 4 9.73 9.86 19 4 '6.30* 6.88 3 19 4 5. 18* 6.70 0 20 4 35.44 35.92 1 20 4 4.88* 5.15 2 20 4 12.88 12.78 1 0 5 1 18.65 148.10 3 0 5 125.0 3 136.50 5 0 5 127.17 134.44 7 0 5 60.54 63.97 0 1 5 97.03 106.08 1 1 5 35. 11 35. 13 2 1 5 39. 19 42.58 3 1 5 68.56 70.97 4 1 5 32.83 34.30 5 1 5 25.59 24. 27 6 1 5 6.68 8.16 7 .1 5 13.00 13. 56 8 1 5 34,33 35.88 9 1 5 14.02 15.28 1 2 5 7.90 7.14 2 2 5 96.42 99. 34 3 2 5 59.33 59.13 4 2 5 144.88 156.31 5 2 5 42.98 43.67 6 2 5 80.85 82.69 7 2 5 22.21 21.99 8 2 5 77.04 79.40 9 2 5 12.62 14.10 0 3 5 5. 1 1 1. 18 1 3 5 76.38 76.43 2 3 5 37. 27 32.26 3 3 5 28.82 27.77 4 3 5 89.91 86.58 5 3 5 40.40 39.38 6 3 5 31.44 30.77 7 3 5 21.13 21.90 8 3 5 24.22 25.40 9 3 5 45.52 49.15 0 4 5 21.03 19.99 1 4 5 97.88 102.06 2 4 5 27.52 27.34 3 4 5 63.07 61 .69 4 4 5 39.83 38.55 5 4 5 135.83 138.70 6 4 5 21.51 21. 17 7 4 5 79.29 79.62 8 4 5 26. 10 27,09 9 4 5 63.35 65.79 H K L FO IC 0 5 5 18.92* 20.91 1 5 5 19.06 21.03 2 5 5 16.27 17.47 3 5 5 70.96 67.93 4 5 5 30.73 28.56 5 5 5 12.96* 13.16 6 5 5 38.91 39. 18 7 5 5 25.76 26.60 8 5 5 25. 11 25.63 9 5 5 5.92* 5.95 0 6 5 83.06 80.04 1 6 5 41.97 38.53 2 6 5 116.29 117.48 3 6 5 22. 17 20.37 4 6 5 89.74 86.49 5 6 5 12.65 12. 16 6 6 5 79.48 79.08 7 6 5 54.95 55.07 8 6 5 49.28 48.86 9 6 5 5.21* 3.06 0 7 5 18.97 17.80 1 7 5 75.09 73.09 2 7 5 45.66 45.72 3 7 5 62.86 61.68 4 7 5 29.75 29.00 5 7 5 30. 18 28.63 6 7 5 8.41 8.53 7 7 5 14.47 15.01 8 7 5 6.81* 6.91 9 7 5 10.61 11.43 0 8 5 32.70 32.46 1 8 5 142.44 157.34 2 8 5 37. 10 36.88 3 8 5 117.04 113.57 4 8 5 33.82 33.91 5 8 5 64.93 62.76 6 8 5 23.89 23.48 7 8 5 27.90 27.20 8 8 5 12.32 12.91 0 9 5 29.37 28.74 1 9 5 5.68* 8.83 2 9 5 104.91 99. 39 3 9 5 94.47 90.74 4 9 5 13.82 13.27 5 9 5 25.53 23.81 6 9 5 31.98 3 1.89 7 9 5 14.09 13.00 8 9 5 13.43 14.42 0 10 5 98. 16 94.57 1 10 5 9.32 9.69 2 10 5 125.15 122.46 3 10 5 50.38 48.86 4 10 5 38.27 36.90 5 10 5 40.28 39.21 6 10 5 47.78 46.41 7 10 5 26.64 25.28 8 10 5 25.79 24.80 0 11 5 28.50 27.42 H K L FO FC 1 11 5 18.32 17.57 2 11 5 34.49 32.45 3 11 5 30. 11 29.34 4 1 1 5 41.86 40.70 5 1 1 5 18.33 17.86 6 1 1 5 31.44 31 .95 7 1 1 5 15.75 16. 13 8 1 1 5 4.10* 1.21 0 12 5 11.20 11.28 1 12 5 42.14 40.98 2 12 5 46. 90 45.79 3 12 5 43. 38 42.06 4 12 5 9.48 9.09 5 12 5 39.07 38.74 6 12 5 31.46 31.34 7 12 5 44.97 45. 17 0 13 5 18.38 17.53 1 13 5 13.40 12.93 2 13 5 41.05 39.25 3 13 5 11.94 11.07 4 13 5 20.08 19.58 5 13 5 17.00 17.00 6 13 5 39.87 40.88 7 13 5 0.00* 2.66 0 14 5 30.44 28.34 1 14 5 47. 48 47.28 2 14 5 60.96 59.08 3 14 5 0.00* 2.27 4 14 5 43.61 43. 13 5 14 5 4.53* 4.3 0 6 14 5 41.03 40.98 0 15 5 23.45 22.57 1 15 5 38. 39 36.99 2 15 5 6.32* 8.01 3 15 5 43.30 42.91 4 15 5 13.77 14.86 5 15 5 21. 21 22.38 6 15 5 0.00* 0.75 0 16 5 33.47 33.52 1 16 5 40.53 39.76 2 16 5 39.70 40.03 3 16 5 66.24 65.14 4 16 5 7.71 7.48 5 16 5 22.04 21 .50 0 17 5 28.64 29.39 1 17 5 17.20 16.46 2 17 5 36.81 36.09 3 17 5 5.16* 7.49 4 17 5 12.64 12. 14 5 17 5 19.46 19.57 0 18 5 39. 35 39.90 1 18 5 31.54 31.96 2 18 5 18.73 19.00 3 18 5 18. 11 18. 27 4 18 5 27.94 28.59 0 19 5 2.76* 7.59 1 19 5 15.90 16.51 2 19 5 6. 27* 6.06 H K L FO FC 0 0 6 116.17 135.91 2 0 6 91.05 94.07 4 0 6 145.24 156.29 6 0 6 4.64* 9. 26 8 0 6 23.44 24.48 0 1 6 65. 16 65.77 1 1 6 56.49 55.49 2 1 6 17.43 17.80 3 1 6 12.50 13. 18 4 1 6 62.65 62.27 5 1 6 27.84 28.46 6 . 1 6 3.61* 3.59 7 1 6 4.91* 5.02 8 1 6 15.03 15.40 9 1 6 14.08 ' 15.42 0 2 6 35.11 36.03 1 2 6 104.87 110.30 2 2 6 34.60 35.69 3 2 6 111.45 116.29 4 2 6 57.31 58.39 5 2 6 75.62 76.35 6 2 6 8.73 8.62 7 2 6 31.78 33.35 8 2 6 0.00* 2.91 9 2 6 29.61 31.51 0 3 6 6.31 7.91 1 3 6 10.03 11.53 2 3 6 27.02 26.65 3 3 6 53.00 51.63 4 3 6 34.25 32.60 5 3 6 30.96 29.95 6 3 6 18.74 18.47 7 3 6 31.81 32.45 8 3 6 27.98 29.98 9 3 6 8.44 10. 19 0 4 6 81.74 78.07 1 4 6 29.72 28.66 2 4 6 71. 19 68.50 3 4 6 52.05 48.94 4 4 6 95.08 93.69 5 4 6 7.77 6.09 6 4 6 51.54 51.56 7 4 6 18.81 19.51 8 4 6 50.47 51.43 9 4 6 17.21 17.95 0 5 6 61.22 62. 13 1 5 6 13.52 12. 1 1 2 5 6 26.51 26.69 3 5 6 13.25 1 1.81 4 5 6 15.09 13.39 5 5 6 44.50 44.53 6 5 6 0,00* 3.21 7 5 6 20.22 20. 19 8 5 6 29,04 31.03 9 5 6 11.89 11. 22 0 6 6 59.11 60. 18 1 6 6 79,23 80.81 2 6 6 16.53 14.42 H K L FO FC 3 6 6 67.09 65.95 4 6 6 14.80 14.81 5 6 6 70. 12 69.92 6 6 6 19.31 18, 18 7 6 6 45.9 2 45.61 8 6 6 8.84 9.58 0 7 6 21. 38 21. 19 1 7 6 56. 15 56.62 2 7 6 58.34 . 53,27 3 7 6 49.09 48,84 4 7 6 21. 24 21.27 5 7 6 29.07 28.35 6 7 6 24.77 23.4 1 7 7 6 8.83 8.90 8 7 6 6.66* 7^.04 0 8 6 91.19 86.21 1 8 6 22.63 20.56 2 8 6 96.09 93. 18 3 8 6 60.42 60.60 a 8 6 59.51 60.7 3 5 8 6 4.87* 3.67 6 8 6 48.07 47. 32 7 8 6 22.35 22.62 8 8 6 21.90 22.06 0 9 6 61.42 57.55 1 9 6 54. 10 51.87 2 9 6 67.78 65.41 3 9 6 35.59 35.47 4 9 6 30.07 30.91 5 9 6 11.97 12.76 6 9 6 15.04 12.35 7 9 6 2.66* 0.68 8 9 6 12.20 12.06 0 10 6 22.39 22.24 1 10 6 72. 87 70.82 2 10 6 46.08 45.99 3 10 6 49.35 48.08 4 10 6 32.69 31.36 5 10 6 30,79 30.36 6 10 6 30.97 31.29 7 10 6 45.56 45.76 8 10 6 0.00* 1.99 0 11 6 4.30* 1.09 1 11 6 20.35 20.84 2 11 6 38.79 37.37 3 11 6 44.08 44. 39 4 11 6 28.62 28.58 5 11 6 32. 19 30.51 6 11 6 16.38 16.98 7 11 6 22.32 22. 10 0 12 6 40.17 39.03 1 12 6 12.73 12.42 2 12 6 34.37 33. 12 3 12 6 0.00* 3.01 4 12 6 19.08 19.46 5 12 6 19.01 19.93 6 12 6 50.40 51. 26 7 12 6 24.93 26.59 H K L FO FC 0 13 6 30. 49 30. 19 1 13 6 29.03 28. 12 2 13 6 29.66 28.33 3 13 6 6.91* 5.60 4 13 6 9.18 9.09 5 13 6 6.99* 5.72 6 13 6 18.87 19.27 0 14 6 42. 14 41.06 1 14 6 23.03 22.63 2 14 6 20.97 22.09 3 14 6 52.88 52.37 4 14 6 15.33 15.55 5 14 6 30.45 31.96 6 14 6 18.08 18.40 0 15 6 26.40 25.62 1 15 6 40.49 40.72 2 15 6 46. 13 44.93 3 15 6 2.69* 4.42 4 15 6 9.51 9.61 5 15 6 26.88 27.71 0 16 6 42.27 40.70 1 16 6 38.50 39. 14 2 16 6 44.76 44.24 3 16 6 0.00* 2. 23 4 16 6 45.97 47. 18 5 16 6 14.47 15. 11 0 17 6 3.38* 0.26 1 17 6 41.21 41.01 2 17 6 15.60 15.04 3 17 6 21.07 21.64 4 17 6 20.84 21.21 0 18 6 14. 12 14,54 1 18 6 23.62 23.73 2 18 6 14.87 15,79 3 18 6 41.36 4 1.79 0 19 6 16,79 16.30 1 19 6 0.97* 2. 19 1 0 7 100.15 105.48 3 0 7 50.84 55.58 5 0 7 12.45* 10.76 7 0 7 16,25* 17.23 0 1 7 71.94 72.95 1 1 7 44.01 43.69 2 1 7 22.57 20.22 3 1 7 48.49 48.85 4 1 7 48. 36 47.82 5 1 7 15. 12 15. 10 6 1 7 19.22 19.47 7 1 7 3.53* 4.26 8 1 7 0.00* 2.26 0 2 7 100.78 101.59 1 2 7 27.36 27.84 2 2 7 50.62 49.64 3 2 7 30. 12 29.71 4 2 7 43.74 43. 36 5 2 7 4.93* 5.90 6 2 7 11.23 7.98 7 2 7 12. 10 10.94 H K L FO FC 8 2 7 30.08 31.43 0 3 7 56.22 55. 94 1 3 7 35. 31 35. 14 2 3 7 19.66 19.52 3 3 7 6.78 5.41 4 3 7 30.72 32.09 5 3 7 19.62 19.68 6 3 7 23.34 24.29 7 3 7 1.78* 2.82 8 3 7 29.23 29.83 0 4 7 37.26 38.38 1 4 7 72.97 73.21 2 4 7 5.39 7.51 3 4 7 21.97 22.90 4 4 7 2.19* 1.61 5 4 7 35.72 35.59 6 4 7 21.06 21.40 7 4 7 34.39 35.35 8 4 7 11.07 12.25 0 5 7 6.83 8.38 1 5 7 3.38* 4.28 2 5 7 9.49 7.60 3 5 7 0.00* 0.77 4 5 7 22.29 23.24 5 5 7 3.07* 2.44 6 5 7 20. 19 19.87 7 5 7 37.29 38.52 8 5 7 11.81 11.11 0 6 7 32.59 33.11 1 6 7 26.04 27.76 2 6 7 55.37 54.77 3 6 7 19.82 21. 12 4 6 7 40.77 40.59 5 6 7 63.62 63.32 6 6 7 47.01 46.61 7 6 7 13.92 14.89 8 6 7 21.62 21 .80 0 7 7 83.89 81.06 1 7 7 31.35 30.74 2 7 7 21. 32 18.98 3 7 7 42.91 42.86 4 7 7 1.32* 4.01 5 7 7 9.82 9.91 6 7 7 11.72 11.46 7 7 7 11.67 12.05 8 7 7 20. 15 21.51 0 8 7 36. 18 35.65 1 8 7 47.03 48.15 2 8 7 29. 32 28.28 3 8 7 51.32 52.15 4 8 7 6.38 3.49 5 8 7 46.70 46.04 6 8 7 9. 15 8. 31 7 8 7 25.04 25.40 8 8 7 3.56* 1.04 0 9 7 7.13 8.22 1 9 7 23.50 25.03 2 9 7 47.60 45.48 H K L FO FC 3 9 7 38.84 38.57 4 9 7 3. 16* 3. 22 5 9 7 12.34 12.55 6 9 7 26.00 25.50 7 9 7 35. 16 37.13 0 10 7 21.80 21. 15 1 10 7 12.81 12.77 2 10 7 46.91 45. 26 3 10 7 29.22 28.07 4 10 7 31.43 29.96 5 10 7 15.03 15.03 6 10 7 46. 11 44.94 7 10 7 14.49 15.78 0 11 7 30.53 31.71 1 11 7 0.00* 0.59 2 11 7 15.04 13.96 3 11 7 1.71* 1.36 4 11 7 14. 13 13.98 5 11 7 1.31* 1.62 6 11 7 34.75 35.35 7 11 7 32.77 32.94 0 12 7 20.49 18.49 1 12 7 13.91 15.82 2 12 7 17.71 17.01 3 12 7 34.57 32.58 4 12 7 2.70* 0.25 5 12 7 33.83 33. 12 6 12 7 21.06 22.52 0 13 7 4.36* 1.91 1 13 7 37.30 36.70 2 13 7 4.89* 5.24 3 13 7 9.39 8.26 4 13 7 8.57 7.52 5 13 7 19.07 18.86 6 13 7 43.28 42.99 0 14 7 15.22* 16.21 1 14 7 17.46 16.54 2 14 7 32.20 32.01 3 14 7 0.00* 2. 12 4 14 7 38.51 38.27 5 14 7 8.41 7.73 0 15 7 36.96 36.04 1 15 7 19.90 19.97 2 15 7 36.54 36.32 3 15 7 19. 12 19.13 4 15 7 14.21 14.83 5 15 7 12.30 12.79 0 16 7 4. 12* 6.28 1 16 7 19.91 20.43 2 16 7 18.75 18.53 3 16 7 50.92 51.18 4 16 7 11.24 1 1.98 0 17 7 26.85 26.69 1 17 7 26.51 26.82 2 17 7 30.30 31.40 3 17 7 20.78 20.78 0 18 7 47.90 48.73 1 18 7 3.37* 4.01 H K L FO FC 0 0 8 59.55 61.08 2 0 8 5. 11* 5.14 4 0 8 30.22 30.79 6 0 8 24.95 25.53 8 0 8 31.05 32.82 0 1 8 73.74 70.87 1 1 8 85.65 83. 51 2 1 8 22.72 22.49 3 1 8 35.47 35.97 4 1 8 51.53 51 .55 5 1 8 21.00 19.06 6 1 8 9.23 9.17 7 1 8 4.48* 1. 17 8 1 8 19.95 20.80 0 2 8 49. 19 48.21 1 2 8 39.28 40. 18 2 2 8 29.77 31.69 3 2 8 18.84 18.53 4 2 8 18.17 18.00 5 2 8 30.59 31.00 6 2 8 13.17 13.55 7 2 8 33.25 33.45 8 2 8 8.74 8.77 0 3 8 65,52 63.60 1 3 8 5.01* 2.58 2 3 8 6,61 5. 18 3 3 8 15.09 16.10 4 3 I8 19,24 17.93 5 3 's 22.79 22.54 6 3 8 8.26 8.58 7 3 8 25. 20 26.76 8 3 8 34.51 36.16 0 4 8 26.88 25.61 1 4 8 44.25 42.72 2 4 8 9.93 11.31 3 4 8 3.02* 1.95 4 4 8 13.38 13.03 5 4 8 21.80 21 .35 6 4 8 31.04 31 .33 7 4 8 24.53 25.36 8 4 8 33.11 34.23 0 5 8 10.90 12. 12 1 5 8 37.36 36.23 2 5 8 10. 14 10. 12 3 5 8 7.47 6.97 4 5 8 24.00 22. 09 5 5 8 21.97 22.17 6 5 8 19. 11 18.81 7 5 8 25.63 26.33 8 5 8 16.77 17.07 0 6 8 41.19 41.69 1 6 8 52.37 54. 17 2 6 8 28.67 27.65 3 6 8 12.63 11.71 4 6 8 20.92 20.69 5 6 8 43.37 43.35 6 6 8 22.49 23.34 7 6 8 20.48 20,34 H K I FO FC 0 7 8 27,93 27. 12 1 7 8 7,75 8.33 2 7 8 57. 13 54.83 3 7 8 44.85 42. 12 4 7 8 27.54 28.49 5 7 8 19.93 19.30 6 7 8 37.34 36. 15 7 7 8 14.26 14.89 0 8 8 20.29 21.36 1 8 8 33.71 33.76 2 8 8 55.80 54.40 3 8 8 3.56* 2.92 4 8 8 34.37 33.68 5 8 8 24. 17 24.65 6 8 8 27.25 26.84 7 8 8 13.97 13.49 0 9 8 6.74 6.09 1 9 8 30.80 28.86 2 9 8 19. 13 17.41 3 9 8 61.55 59.77 4 9 8 31.98 32. 24 5 9 8 23.46 22.38 6 9 8 23.78 24.52 7 9 8 17.45 16.73 0 10 8 40. 10 39.02 1 10 8 55.52 55.01 2 10 8 5.06* 4.57 3 10 8 38.41 37.82 4 10 8 9.70 9.37 5 10 8 27. 15 26. 11 6 10 8 11.33 11.35 0 11 8 13.94 12.92 1 11 8 10. 15 10.14 2 11 8 36.83 35.97 3 11 8 11.89 10.23 4 11 8 10.26 9. 15 5 11 8 17.07 17.47 6 11 8 50,42 50.00 0 12 8 32.53 31.88 1 12 8 1.77* 4.41 2 12 8 48.83 48.22 3 12 8 1.93* 2.68 4 12 8 29. 11 27.81 5 12 8 3. 18* 0.37 6 12 8 24.05 23. 12 0 13 8 16.60 16.00 1 13 8 5.93* 5.63 2 13 8 12.00 11.57 3 13 8 18.59 17.69 4 13 8 5.68* 3.63 5 13 8 28.91 29.51 0 14 8 7.91 6.92 1 14 8 17.95 17.62 2 14 8 22.45 21.34 3 14 8 43.93 43.80 4 14 8 6.99* 8.52 0 15 8 5.36* 4.34 1 15 8 32.24 33.41 B K L FO FC 2 15 8 30.81 30.64 3 15 8 3.75* 4.06 4 15 . 8 22.35 21 .87 0 16 8 26.75 26. 13 0 16 8 27.29 26. 13 2 16 8 25.00 24.47 3 16 8 8.00* 9.25 0 17 8 18.39 17.55 1 17 8 30. 12 29.85 1 0 9 33.24 34.36 3 0 9 44.51 45.75 5 0 9 58.87 59.37 7 0 9 32.33 32.45 0 1 9 56.70 55.42 1 1 9 44.59 44.05 2 1 9 19.89 21. 17 3 1 9 45.42 45.96 4 1 9 63.40 64.02 5 1 9 44.86 45.33 6 1 9 21.09 20.80 7 1 9 19.27 20.68 0 2 9 16.62 16. 24 1 2 9 55.16 55.06 2 2 9 20.05 20.70 3 2 9 18.85 16.77 4 2 9 57.28 57.52 5 2 9 18.29 18.49 6 2 9 34.76 35.24 7 2 9 18.52 19.13 0 3 9 33. 32 34.31 1 3 9 39.13 37.74 2 3 9 4.70* 5.20 3 3 9 2.36* 1 .35 4 3 9 39.06 39. 16 5 3 9 43.87 44.23 6 3 9 15.70 15.39 7 3 9 30.71 32.23 0 4 9 9.48 9.22 1 4 9 30.52 31.35 2 4 9 15.81 15. 27 3 4 9 19.52 19.54 4 4 9 27. 23 27.79 5 4 9 41.88 43.03 6 4 9 0.00* 0.39 7 4 9 25. 15 26.04 0 5 9 39. 18 39.24 1 5 9 25.77 25.52 2 5 9 11.43 11.14 3 5 9 30.92 30.42 4 5 9 31.70 31 .03 5 5 9 19.51 19.07 6 5 9 40.23 41.17 7 5 9 11.41 11.12 0 6 9 25.83 26.13 1 6 9 21.55 21.12 2 6 9 38.45 38.18 3 6 9 21.57 21.71 4 6 9 35.97 34.85 H E L FO FC 5 6 9 27.34 27.58 6 6 9 33.82 34.59 7 6 9 8.80 8.74 0 7 9 20.88 21.09 1 7 9 50.28 48.54 2 7 9 51.30 50.77 3 7 9 58.33 58.21 4 7 9 43.69 42.55 5 7 9 35.95 35.40 6 7 9 2.39* 1.85 0 8 9 13. 19 13. 34 1 8 9 49.06 48. 13 2 8 9 16.45 16.72 3 8 9 25. 18 25.23 4 8 9 13.80 13.39 5 8 9 30. 11 30.70 6 8 9 4. 12* 2.03 0 9 9 26.72 27.14 1 9 9 20.86 20.06 2 9 9 82.85 81.14 3 9 9 43.67 43. 22 4 9 9 35.26 34.82 5 9 9 10.81 11.41 6 9 9 35.55 35.54 0 10 9 48.34 47. 16 1 10 9 25.07 25.28 2 10 9 39. 19 38. 23 3 10 9 12.47 12.22 4 10 9 15.56 15.46 5 10 9 8.98 10. 12 6 10 9 15.88 16. 12 0 11 9 6. 10* 4.80 1 11 9 40.80 38.47 2 11 9 14.75 13.52 3 11 9 46.28 45.22 4 11 9 10.49 11.21 5 11 9 21.74 21.95 0 12 9 0.00* 3.34 1 12 9 36.72 36. 29 2 12 9 3.63* 3.60 3 12 9 25.09 25.87 4 12 9 3.49* 3.55 5 12 9 9.32 9.88 0 13 9 19.63 18.70 1 13 9 10.76 9.76 2 13 9 43.00 42.77 3 13 9 3.61* 2.56 4 13 9 11.92 12. 22 0 14 9 19.85 19.73 1 14 9 23.47 23. 18 2 14 9 19.05 19.12 3 14 9 10.09 10.08 0 15 9 0.00* 1.58 1 15 9 39.23 37.51 2 15 9 0.00* 3.01 0 16 9 14.65 14.64 0 0 10 52.27 51.94 2 0 10 67.07 69.81 fi K L FO FC 4 0 10 57.97 58.27 6 0 10 27.62 28.69 0 1 10 55.85 55. 24 1 1 10 52.78 53.06 2 1 10 37.46 38. 10 r 1 10 54.88 55.80 4 1 10 64.02 64.90 5 1 10 53.99 54.92 6 1 10 22. 21 22. 87 0 2 10 16.86 16.37 1 2 10 55. 18 55.04 2 2 10 5.93* 5.82 3 2 10 59.9 1 60.35 4 2 10 21.53 21.50 5 2 10 33.92 34.00 6 2 10 7.43 8.78 0 3 10 47.95 48.31 1 3 10 40.51 40. 15 2 3 10 22.82 24.50 3 3 10 21.90 21.31 4 3 10 54.90 54.93 5 3 10 23.87 24.00 6 3 10 27.37 27.76 0 4 10 28.62 27.96 1 4 10 4.81* 4.96 2 4 10 54.65 54.68 3 4 10 37.23 37. 10 4 4 10 37.63 37.50 5 4 10 11.43 11.55 6 4 10 27.66 28.69 0 5 10 46.45 45.73 1 5 10 45.77 45.59 2 5 10 21.00 21.64 3 5 10 39.70 38.87 4 5 10 16.82 16.02 5 5 10 39. 19 39.99 6 5 10 14.37 13.40 0 6 10 45.51 44.66 1 6 10 36. 32 36.23 2 6 10 22.25 22.92 3 6 10 34.98 35.33 4 6 10 12.86 12.62 5 6 10 40.82 41.06 6 6 10 21.22 21.62 0 7 10 42. 49 42.74 1 7 10 32.42 31.33 2 7 10 59,98 59. 18 3 7 10 25.24 24.31 4 7 10 40.20 40.27 •5 7 10 10.85 10.74 6 7 10 35.24 36.34 0 8 10 18.77 18.29 1 8 10 5.94* 6. 23 2 8 10 26.42 25.44 3 8 10 27.86 26.87 4 8 10 26.45 26.30 c. 8 10 7.47* 8.61 0 9 10 26.24 25.55 H K L FO FC 1 9 10 44.90 43.72 2 9 10 23.35 22.78 3 9 10 58.76 57.44 4 9 10 8.50 7.04 5 9 10 20.37 20,13 0 10 10 7.63* 6.00 1 10 10 20.86 20.71 2 10 10 0.00* 2.90 3 10 10 16.72 17.00 4 10 10 18.41 18.83 0 11 10 32.47 31.64 1 11 10 18.37 16.90 2 11 10 42.86 42.73 3 11 10 6.82* 6.42 4 11 10 2. 17* 1.47 0 12 10 20. 10 20.18 1 12 10 1.33* 3.73 2 12 10 17.97 16.21 3 12 10 2.94* 3.23 0 13 10 8.25 7.99 1 13 10 28.02 27. 21 2 13 10 12.24 11.44 0 14 10 12.95 11.58 1 14 10 5.67* 2. 18 1 0 11 45.96 45. 26 3 0 11 17.81 18.59 5 0 11 13.69 14.10 0 1 11 49.77 49.44 1 1 11 49.59 48.77 2 1 11 34.61 34.90 3 1 11 32.33 33.03 4 1 11 37.24 38.98 5 1 11 26.65 27.46 0 2 11 49. 13 49.01 1 2 11 22.96 22.49 2 2 11 34.63 34.83 3 2 11 4.32* 0.35 4 2 11 13.88 14.25 5 2 11 2.93* 0.64 0 3 11 52.00 51.50 1 3 11 47.28 47.51 2 3 11 18.80 18.83 3 3 11 20.33 20.25 4 3 11 16.28 16.41 5 3 11 17.09 17.85 0 4 11 24.70 23.78 1 4 11 48. 18 47.66 2 4 11 3.71* 3.67 3 4 11 27.71 27.51 4 4 11 5.04* 3.59 5 4 11 22.21 23.02 0 5 11 49.04 48.48 1 5 11 22.29 22.60 2 5 11 30.73 30.27 3 5 11 8.45 7.87 4 5 11 13.55 14.63 5 5 11 25.79 25.87 0 6 11 23.19 22.75 e K L FO FC 1 6 11 21.89 21.13 2 6 11 35.97 35.42 3 6 11 17.44 / 17.56 4 6 11 25. 19 25.79 5 6 1 1 20.92 21.79 0 7 11 15.90 15.75 1 7 11 29. 13 28.85 2. 7 11 16.80 16.96 3 7 11 38.64 39.28 4 7 1 1 21.08 21.08 0 8 11 27.73 27.91 1 8 1 1 27.09 26.86 2 8 11 4.93* 5.95 3 8 11 21.29 21.52 4 8 1 1 10.09 9.12 0 9 11 10.59 10.49 1 9 11 15.79 15.52 2 9 1 1 42.27 39.75 3 9 1 1 17.95 17.00 4 9 1 1 17.80 17.20 0 10 1 1 20.32 19.34 1 10 1 1 0.00* 1. 12 2 10 11 26.72 26.01 3 10 1 1 12.83 12.27 0 11 1 1 29.65 27.64 1 11 11 6.63* 6.3 8 2 11 1 1 20.94 19.79 0 12 11 0.00* 0.65 1 12 1 1 » 17..40 16.41 0 0 12 20.16 19.78 2 0 12 5. 11* 4.75 4 0 12 6.54* 6.93 0 1 12 37.04 35.32 1 1 12 23. 28 22.73 2 1 12 11.20 12.02 3 1 12 7.69 7.27 4 1 12 20.69 20.55 0 2 12 11.13 10.64 1 2 12 16.90 16.56 2 2 12 20.23 19.35 3 2 12 8. 23 7.93 4 2 12 8.36 7.82 H K L FO FC 0 3 12 36.81 36.03 1 3 12 25.77 26.29 2 3 12 0.00* 2.28 3 3 12 10.37 9.95 4 3 12 4.93* 5.07 0 4 12 21.27 21.03 1 4 12 18.67 18.72 2 4 12 18. 1 1 17.78 3 4 12 10.27 10.00 4 4 12 14.59 13.78 0 5 12 16.96 17.87 1 5 12 18.01 18.04 2 5 12 18. 30 18.03 3 5 12 3.50* 0.60 0 6 12 22.08 21.29 1 6 12 22.68 22.29 2 6 12 ' 1.74* 0.06 3 6 12 8.46 8.09 0 7 12 14.57 14.05 1 7 12 15.80 15. 10 2 7 12 23.42 22. 24 3 7 12 29.61 28.53 0 8 12 22.50 21.93 1 8 12 3.65* 2.55 2 8 12 11.64 12.06 0 9 12 15.66 15.62 1 9 12 10.48 9.64 0 -2 13 7.48* 6.84 1 0 13 4.05* 4.34 0 1 13 12.50 12.98 1 1 13 15.47 15.22 2 1 13 2.02* 1.40 0 2 13 8.73 6.84 1 2 13 16.92 16.40 2 2 13 5.42* 7.03 0 3 13 25.26 24. 12 1 3 13 5.39* 5.27 2 3 13 13.89 13.27 0 4 13 5.33* 5.37 1 4 13 0.00* 2.93 0 5 13 18.99 18.09 1 5 13 19.88 19.08 DENOTES AN UNOBSERVED REFLECTION Acetyl-3-benzamido-2-keto-4-(2,4,4>6-tetra-C-acetyl glucopyranosyloxy)-A3-pyrrolire Anthony Mercer, and James Trotter Observed and calculated structure amplitudes (reflections with intensity < 3o-(I) are marked w.ith asterisk) . H K I FO FC HEIGHT 1 0-11 8. 45 8.99 6.18 2 0-11 6. 17 6, 22 7. 12 1 0-10 11. 92 1 2. 29 4. 99 2 0-10 7.09 8. 12 5. 28 3 0-10 8. 74 10. 32 4. 68 4 0-10 4. 07 4. 02 2..84 5 0-10 0. 00* 0.42 0. 00 6 0-10 3. 89 2. 25 4. 47 7 0-10 3. 83 3. 01 3. 53 8 0-10 2. 57* 3.03 0. 17 9 0-10 5.77 6.56 6. 54 1 1-10 9. 47 10. 23 4. 79 2 1-10 4. 45 4.31 3. 94 3 1-10 3.36* 4. 19 0. 19 4 1-10 6. 89 7. 35 5. 35 5 1-10 9. 05 10. 34 5. 44 6 1 -10 4.61 3. 23 5. 69 7 1-10 3. 35* 3. 64 0. 26 ' 8 1-10 3. 6 0 3, 13 3. 48 9 1-10 0. 00* 0, 36 0. 00 1 2-10 3. 13* 1.91 0. 21 2 2-10 3. 10* 3.61 0. 21 3 2-10 4.90 3. 43 5.98 « 2-10 2.79* 2. 11 0. 18 5 2-10 4. 10 4. 20 3.20 6 2-10 1.30* 2. 67 0.04 7 2-10 3. 36 1. 79 4. 22 1 3-10 4. 22 3. 95 3. 50 2 o — 10 2.92 0. 10 3 3-10 4. 15 3. 63 2. 95 a 3-10 6. 16 6. 90 4. 39 5 3-10 4.47 3. 60 4.21 1 0 -9 21. 07 21. 90 2. 56 2 0 -9 12. 58 12. 08 4. 23 3 0 -9 3. 04* 3.82 0. 19 4 0 -9 2. 24* 1,47 0. 11 5 0 -9 15. 07 16.81 3. 60 6 0 -9 3.87 3. 48 3. 02 7 0 -9 4. 14 3. 84 3. 36 8 0 -9 4.46 5. 00 3. 11 9 0 -9 10. 24 11.14 5. 22 10 0 -9 0. 00* 1. 63 0. 00 11 0 -9 4. 29 4. 36 4. C8 12 0 -9 4. 86 4. 96 4. 29 1 1 -9 9. 13 10. 50 5. 08 2 1 -9 2.79* 3. 22 0. 16 3 1 -9 13. 80 15. 49 4. 24 4 1 -9 3. 55* 4. 33 0. 20 5 1 -9 12. 97 14. 02 4. 39 6 1 -9 7. 14 7.47 5. 12 7 1 -9 2. 85* 5.54 0. 11 8 1 -9 4. 05 3. 77 4. 30 9 1 -9 6. 53 5. 69 5. 91 10 1 -9 2. 28* 1.93 0. 12 11 1 -9 3. 81 2.70 3. 53 12 1 -9 4. 17 2.75 5. 67 1 2 -9 5.67 5.25 4. 14 2 2 -9 9. 18 9. 29 5. 04 H K L FO FC HEIGHT 3 2 -9 4.60 5. 26 2. 67 4 2 -9 6. 06 4. 67 5. 30 5 2 -9 7.36 7. 80 6. 09 6 2 -9 2.43* 1. 98 0. 12 7 2 -9 5. 25 5. 55 3.92 8 2 -9 5. 28 4. 49 4. 91 9 2 -9 2.92* 3. 91 0. 19 10 2 -9 1. 56* 3. C4 0. 05 11 2 -9 5, 98 . 5. 47. 6. 52 1 3 -9 1. 46* 1. 18 0. 05 2 3 -9 12. 78 13. 67 4. 76 3 3 -9 1 . 38* 1. 94 0. 04 4 3 -9 4. 87 4. 95 3. 57 5 3 -9 2. 62* 4. 97 0. 12 6 3 -9 7. 83 8. 19 5.07 7 3 -9 3. 52 2. 1.8 2. 95 8 3 -9 2.51* 1. 78 0. 16 9 3 -9 3. 39* 3. 32 0. 28 10 3 -9 4.59 3. 93 5. 26 1 4 -9 4. 72 4. 59 3. 14 2 4 -9 0. 00* 0. 11 0. 00 3 4 -9 1 . 30* 0. 63 0. 04 4 4 -9 4. 96 4. 66 4. 16 5 4 -9 0.49* 3. 19 0. 00 6 4 -9 2.71* 2. 19 0. 16 7 4 -9 2. 52* 2. 09 0. 15 1 0 -8 11. 12 10. 92 4. 29 2 0 -8 4.68 4. 81 3, 42 3 0 - 3 21.30 2 1. 4 G 2. 50 4 0 -8 12. 55 12. H2 5. 73 5 0 -8 4. 54 3. 77 3. 59 6 0 -8 3. 72 4. C4 3. 17 7 0 -8 17. 70 18. 03 3. 51 8 0 -8 17. 96 19.31 3. 31 9 0 -8 3. 96 4. 03 2. 57 10 0 -8 0. 00* 0. 57 0.00 11 0 -8 3. 65 2. 17 3. 64 12 0 -8 3.58* 3. C4 0. 25 13 0 -8 6. 58 6. 45 6. 09 14 0 -8 2. 83* 1. 64 0. 24 15 0 -8 0.94* 1. 15 0. 02 1 1 -8 4. 26 4. 58 2. 94 2 1 -8 5.59 5. 94 3. 20 3 1 -8 8. 32 10. 25 4. 95 4 1 -8 7. 53 9. 21 5. 16 5 1 -8 5. 24 6. 58 3. 12 6 1 -8 8.78 10. 32 5. 26 7 1 -8 5. 92 6. 46 3. 41 8 1 -8 5.41 6. 22 3. 42 9 1 -8 2.18* 4. 67 0. 08 10 1 -8 2. 62* 2. 26 0. 14 11 1 -8 3.53* 4. 68 0. 24 12 1 -8 4. 17 3. 72 2. 88 13 1 -8 4.07 4. 87 2. 95 14 1 -8 4.10 3. 24 5. 19 15 1 -8 3. 94 3. 36 3. 50 1 2 -8 7.36 6. 35 5.67 2 2 -8 12. 56 13. 44 4. 41 H K I FO FC HEIGHT 3 2 -8 12.98 1 3. 67 4. 54 4 2 -8 6. 83 7.08 6. 13 5 2 -8 10. 68 10. 20 5. 64 6 2 -8 16.77 17. 26 3.86 7 2 -8 3. 23* 3.32 0. 21 8 2 -8 3.57* 2. 50 0. 30 9 2 -8 6. 17 6.53 4. 52 10 2 -8 5. 44 4. 67 6. 02 11 2 -8 0. 62* 0. 86 0. 01 12 2 -8 3.42* 2. 26 0. 31 13 2 -8 3.30* 3. 05 0. 21 14 2 -8 3. 51 2. 04 3.48 1 3 -8 8. 16 8.42 6. 37 2 3 -8 6. 00 6. 38 3. 89 3 3 -8 13. 14 14. 07 4. 15 4 3 -8 6. 60 6. 65 4. 22 5 3 -8 10. 71 10. 38 5. 07 6 3 -8 6. 11 7.50 3. 87 7 3 -8 4.75 4. 0 8 4. 06 8 3 -8 3. 92 3. 05 3. 13 9 3 -8 6.46 5. 96 5. 73 10 3 -8 2. 85* 2. 93 0. 17 11 3 -8 3. 31* 2. 45 0. 30 12 3 -8 3. 78* 3. 77 0. 27 13 3 -8 0. 00* 2. 23 0. 00 1 4 -8 6. 52 6.91 3. 62 2 4 -8 6. 21 6. 12 3. 93 3 4 -8 7. 91 8.72 4. 81 4 4 - c 5. JC 6. 80 3.93 5 4 -8 4.02 3.02 3. 28 6 4 -8 5. 68 5. 03 4. 31 7 4 -8 4. 36 3. 94 3. 17 8 4 -8 5.35 6.4 2 3. 66 9 4 -8 4. 04 3. 37 3. 10 10 4 -8 0. 00* 1.20 0.00 11 4 -8 3.81 4, 00 2.79 1 5 -8 3.55* 3.49 0. 22 2 5 -8 4. 45 3.55 3.42 3 5 -8 5. 94 6.32 3. 26 4 5 -8 5.31 5.58 3. 28 5 5 -8 3. 44* 2. 92 0. 23 6 5 -8 3.69 2. 94 2. 87 7 5 -8 3.42* 3. 32 0. 25 1 0 -7 19. 31 18.73 3. 14 2 0 -7 3. 53 2. 13 3. 59 3 0 -7 5. 19 5.06 4. 28 4 0 -7 4. 60 4. 09 4. 06 5 0 -7 0. 00* 2. 15 0. 00 6 0 -7 14. 34 16.31 4. 60 7 0 -7 3. 20* 0.45 0. 28 8 0 -7 5.40 6.00 4. 14 9 0 -7 13. 74 14. 44 4. 96 10 0 -7 2. 46* 1. 12 0. 14 11 0 -7 10. 61 11. 05 4. 77 12 0 -7 4. 99 3.98 5. 49 13 0 -7 6.88 7.39 5. 87 14 0 -7 5. 83 4. 36 6. 47 15 0 -7 0.00* 2.30 0. 00 H K L FO FC HEIGHT 16 0 -7 2. 26* 1. 62 0.13 17 0 -7 3. 94 2. 93 4. 29 1 1 -7 5. 15 5. 20 4. 89 2 1 -7 22. 19 20. 39 2.50 3 1 -7 12. 05 11. 06 5. 11 4 1 -7 8. 35 9. 25 7. 22 5 1 -7 4.18 5. 12 3. 48 6 1 -7 11.57 11. 56 5. 66 7 1 -7 9. 44 10. 49 . 5. 42 8 1 -7 11.68 1 1. 95 5. 01 9 1 -7 8. 49 9. 22 5. 40 10 1 -7 20. 22 22. 62 2. 87 11 1 -7 3.06* 3. 45 0. 19 12 1 -7 8. 32 9. 68 5. 55 13 1 -7 0. 00* 0. 71 0. 00 14 1 -7 2. 87* 1.71 C. 21 15 1 -7 3. 14* 1. 39 0. 35 16 1 -7 4.21 3. 11 5. 39 1 2 -7 10.36 11.51 6. 67 2 2 -7 9. 47 9. 58 5. 41 3 2 -7 3.64* 4. 55 0.26 4 2 -7 6. 99 7. 44 5. 06 5 2 -7 15.03 15. 49 4. 65 6 2 -7 4.93 4. 50 3.73 7 2 -7 19. 50 19. €3 2. 77 8 2 -7 8.11 9. C6 5. 28 9 2 -7 13.31 19. 51 3. 17 10 2 -7 4. 32 4. 55 3. 02 11 2 — 7 6.15 5. "0 4. 59 12 2 -7 2.79* 4. 33 0. 13 13 2 -7 3. 97 3. 99 2. 63 14 2 -7 2.24* 1. 75 0. 14 15 2 -7 2.22* 1. 30 0.16 16 2 -7 2.14* 1. 17 0. 13 1 3 -7 6. 54 6. 51 5.01 2 3 -7 6. 24 5.78 5. 50 3 3 -7 4 . 68 5. CO 3, 36 4 3 -7 22. 33 23. 75 2. 47 5 3 -7 5.42 5. 08 4. 48 6 3 -7 13.44 14. 04 4. 46 7 3 -7 6.92 7. 20 4. 61 8 3 -7 8. 05 8. 77 4. 96 9 3 -7 5.72 5. 40 4. 26 10 3 -7 7.79 7. S9 7.27 11 3 -7 4. 33 4. 96 2. 48 12 3 -7 2.31* 2. 14 0. 12 13 3 -7 1. 74* 1. 53 0. 07 14 3 -7 2.01* 0. 91 0. 11 15 3 -7 3.61 2. 94 3. 01 1 4 -7 16. 23 19. 12 3. 60 2 4 -7 8. 22 8. 17 5. 08 3 4 -7 3.31* 3. 99 C. 19 4 4 -7 4 .00* 4. 47 0. 22 5 4 -7 10.46 10. 57 4.74 6 4 -7 5. 22 -4. 09 4. 60 7 4 -7 7.06 8. 51 3. 94 8 4 -7 5. 88 6. 55 3. 73 9 4 -7 6.93 6. 44 7. 15 H K I ro FC WEIGHT 10 4 -7 3. 51* 2. 74 0. 25 11 4 -7 2.76* 4. 07 0. 17 12 4 -7 4. 62 4.66 3. 79 13 4 -7 2. 43* 1.98 0. 17 1 5 -7 5.17 5.68 2. 77 2 5 -7 5.78 6. 06 4.30 3 5 -7 2. 19* 1.81 0. 09 4 5 -7 3.85 4. 38 2. 49 5 5 -7 3. 63* 5.41 0. 16 6 5 -7 6. 3E 6. 26 4. 87 7 5 -7 1.91* 2. 67 0. 06 8 5 -7 3.52* 4. 21 0. 22 9 5 -7 4.73 5. 07 2. 85 10 5 -7 5.06 4. 36 3. 87 11 5 -7 2. 42* 0.81 0. 18 1 6 -7 7. 05 8. 28 4. 49 2 6 -7 4. 05 4. 23 2. 62 3 6 -7 4. 47 4.88 2. 34 4 6 -7 3. 67* 5. 49 0. 22 5 6 -7 6. 23 7. 88 3. 83 6 6 -7 0. 28* 0. 39 0. 00 1 0 -6 9.81 9.74 8. 05 2 0 -6 7.68 7. 51 7. 99 ~j 0 -6 6. 35 4. 74 6. 06 4 0 -6 21. 40 22.41 2.75 5 0 -6 14. 92 1 4. 99 4.70 6 0 -6 6. 24 4.98 5. 46 7 0 -6 19. 99 1 8.79 2. 90 ts 0 -6 12. 15 12.5 i 5. i 5 9 0 -6 6. 19 7. 81 4. 95 10 0 -6 5.95 5.71 5. 69 11 0 -6 3.38* 3.32 0. 28 12 0 -6 2. 96* 3. 00 0. 20 13 0 -6 25.76 28.12 1.81 14 0 -6 6.77 6.67 5.83 15 0 -6 3. 83 3. 25 3. 03 16 0 -6 0. 00* 0. 96 0. 00 17 0 -6 4. 45 3. 59 5.35 18 0 -6 0. OC* 0. 89 0. 00 1 1 -6 2. 81* 1.65 0. 27 2 1 -6 11. 30 11. 30 5. 82 3 1 -6 14. 86 13. 83 4. 81 4 1 -6 6. 42 6. 07 6. 08 5 1 -6 16. 21 16.45 3. 88 6 1 -6 17.77 16.31 3. 66 7 1 -6 14. 89 13. 35 4. 59 8 1 -6 3. 64 4. 35 2. 86 9 1 -6 12. 59 14. 38 6. 06 10 1 -6 7. 53 8. 26 5. 67 11 1 -6 8.60 9.77 5.07 12 1 -6 15. 54 17.02 4. 11 13 1 -6 6. 10 6.71 4. 66 14 1 -6 2. 47* 0. 93 0. 16 15 1 -6 5. 53 6.45 4. 10 16 1 -6 3. 15* 3. 47 0.21 17 1 -6 3. 85 2. 61 4.51 18 1 -6 3. 40 3. 15 3. 29 1 2 -6 22.79 20.86 2.42 H K L FO FC WEIGHT 2 2 -6 5.86 4. 96 6. 63 3 2 -6 2.78* 2. 97 0. 23 4 2 -6 6.15 5. 30 5. 11 5 2 -6 4.20 4. 80 2. 71 6 2 -6 13. 46 14. 86 4. 60 7 2 -6 0. 59* 2. 08 0. 01 8 2 -6 13.90 14. 49 4. 53 9 2 -6 2. 85* 2. 22 0. 18 10 2 -6 16.48 17. 14 3.78 11 2 -6 9.78 9. 67 5.42 12 2 -6 3. 28* 2. 41 0. 28 13 2 -6 9.99 9. 82 6. 27 14 2 -6 4. 55 4. 70 2. 68 15 2 -6 4.72 2. 84 5. 31 16 2 -6 5.10 4. 16 4. 05 17 2 -6 3.51 0. 95 4, 24 1 3 -6 11.95 9. 96 5. 49 2 3 -6 14. 28 12. 56 4. 52 3 3 -6 4.40 3. 93 4. 06 4 3 -6 4.54 3. 70 4. 05 5 3 -6 6. 38 5. 26 5. 54 6 3 -6 5. 44 5. 29 4. 54 7 3 -6 10.67 9. 97 5. 33 8 3 -6 0.00* 2. 24 0. 00 9 3 -6 8.02 7. 63 5. 27 10 3 -6 7. 88 6. 69 6.50 11 3 -6 6. 29 7. 09 4.11 12 3 -6 8.98 9. 15 5. 66 i3 3 -6 2. 57* 0. 5 i u. 1 / 14 3 -6 5.78 4. 99 4. 45 15 3 -6 2.25* 1. 62 0. 12 16 3 -6 2. 90* 1. 02 0. 27 1 4 -6 12.88 12. 46 4. 60 2 4 -6 14.90 15. 79 4. 27 3 4 -6 3. 08* 4. 26 0. 17 4 4 -6 3.44* 5. 18 0. 20 5 4 -6 3.54* 2. 18 0. 28 6 4 -6 11.82 12. 29 4. 52 7 4 -6 7.47 7. 95 4. 38 8 4 -6 7. 88 7. 79 5.57 9 4 -6 6.97 6. 89 4. 47 10 4 -6 6.41 6. 83 4. 09 11 4 -6 4.08 4. 32 2. 69 12 4 -6 5. 18 4. 56 4. 68 13 4 -6 6.54 6. 67 5. 15 14 4 -6 4.21 2. 68 4. 08 15 4 -6 2.53* 0. 54 0. 23 1 5 -6 6. 32 5. 99 4. 82 2 5 -6 7.37 8. 17 4. 70 3 5 -6 15. 13 16. 31 3.79 4 5 -6 7.35 8. 33 3. 69 5 5 -6 13.76 14. 80 3.83 6 . 5 -6 13.02 14. 54 4. 16 7 5 -6 6. 67 6. 67 4. 90 8 5 -6 4. 09 3.59 3. 35 9 5 -6 4.57 4. 31 2. 36 10 5 -6 2.31* -2. 66 0. 10 11 5 -6 3.87 2. 67 2.80 H K L FO FC HEIGHT 12 5 -6 2. 52* 2. 79 0.11 13 5 -6 2. 83* 2.31 0.23 1 6 -6 5. 46 5.69 3. 02 2 6 -6 4. 04 3.73 2. 27 3 6 -6 4. 15 3. 76 2. 40 4 6 -6 2. 86* 0. 28 0. 14 5 6 -6 1. 56* 1. 40 0. 04 6 6 -6 4. 86 6. 41 3. 79 1 6 -6 3. 87* 4. 58 0. 26 8 6 -6 4.44 2. 83 3. 68 9 6 -6 3.50* 3. 39 0. 22 1 7 -6 4.66 5.50 2. 80 2 7 -6 3. 19* 4. 22 0.15 1 0 -5 14.38 13. 95 5. 15 2 0 -5 24. 89 23.79 2. 14 3 0 _ t; 26. 60 28.39 1. 96 4 0 -5 2.80* 3. 07 0. 40 5 0 -5 18. 05 17. 95 3. 40 ' 6 0 _ c 15. 86 15.12 4. 43 7 0 -~* 5. 08 5. 20 5.71 8 0 -5 5. 35 5, 39 5. 93 9 0 -5 10. 28 9. 68 7.36 10 0 -5 21.64 20. 70 2. 57 11 0 -5 3. 82 3. 18 3. 80 12 0 - 5 8. 33 8. 76 6. 00 13 0 -5 5. 51 5. 34 4. 77 14 0 -5 11.23 12. 20 5. 21 15 0 -5 6.71 5. 90 5. 00 A* ^ 1 U V 7.13 4.75 17 0 _ 5 2. 20* 2. 06 0. 13 18 0 -5 2.67* 2. 36 0. 20 19 0 -5 3.39* 2. 16 0. 34 1 1 -5 2. 27* 3.79 0. 24 2 1 -5 14. 32 13.91 5. 12 3 1 -5 18. 92 17. 68 3. 58 4 1 -5 18. 93 16. 77 3.39 5 1 -5 8. 30 7. 13 8. 10 6 1 -5 21.59 18.83 2. 67 7 1 _ c 13. 05 12. 98 5. 40 8 1 -5 13. 85 14. 46 4. 91 9 1 -5 2.48* 1.38 0. 21 10 1 _ c 6. 66 6. 61 6. 85 11 1 -5 3. 94 4. 86 2. 76 12 1 -5 13. 55 15.44 4.94 13 1 _ c 5. 29 5.64 4. 44 14 1 -5 8. 20 7. 76 7. 54 15 1 -5 3.63 1.40 3. 65 16 1 -5 7. 49 8.99 4. 65 17 1 -5 4. 47 2. 67 4. 96 18 1 -5 3.20* 1. 90 0. 28 19 1 -5 0. OC* 0. 98 0. 00 1 2 -5 13. 31 11.15 5. 55 2 2 -5 17. 64 16.44 3.74 3 2 -5 19. 51 17.08 3. 21 4 2 -5 28. 50 26. 50 1. 66 5 2 -5 16.09 14.45 4. 21 6 2 -5 3. 92 4. 32 4.45 7 2 -5 14. 80 13. 30 4. 39 H K L FO FC HEIGHT 8 2 -5 17.04 14. 31 3. 74 9 2 -5 3. 10* 2. 25 0. 26 10 2 -5 2.73* 3. 62 0. 17 11 2 -5 16.41. 16. 60 3. 89 12 2 -5 6.67 7. 24 5. 60 13 2 -5 6.54 6. 91 4.49 14 2 -5 12. 12 13. 19 4. 60 15 2 -5 9.54 9. 80 5.65 16 2 -5 5.71 5. 61 4. 25 ;-7 2 -5 0.79* 1. 85 0. 01 18 2 -5 3.33* 2. 35 0. 32 19 2 -5 1. 51* 0. 73 0. 07 1 3 -5 17.93 17. 18 3. 51 2 3 -5 7. 23 6. 67 7. 09 3 3 -5 10.90 10. 52 5. 83 4 3 -5 6. 08 5. 7.8 5. 76 5 3 -5 8.78 7. 34 5. 28 6 3 -5 7.97 8. S8 6.78 7 3 -5 10. 13 9. 68 5. 47 8 3 -5 13. 84 15. 19 4.62 9 3 -5 7.33 6. 98 5. 75 10 3 -5 7. 12 7. 24 4. 72 11 3 -5 6.46 6. 63 3. 61 12 3 - c 5.06 4. 89 3. 28 13 3 -5 6.60 7. 25 3. 75 14 3 -5 6.52 5. 95 5. 66 15 3 -5 4. 83 4. 96 2. 94 —' -5 3. 30* 2. 82 0. 28 i ' 3 — 5 3.51 1.29 3.13 18 3 -5 1.79* 1. 10 0. 10 1 4 -5 5. 22 3. 61 3. 27 2 4 -5 12. 17 11. 77 4. 36 3 4 -5 12.42 13. 36 4. 62 4 4 -5 4. 22 3. 59 3. 07 5 4 -5 5.59 6. 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C2 4. 34 10 4 -4 14. 25 14. 94 4. 16 11 4 -4 7.11 7. 39 4. 80 12 4 -4 4. 33 2. 98 2. 58 13 4 -4 13.49 12. 52 4. 32 14 4 -4 10. 24 10. 18 4. 72 15 4 -4 6.68 6. 41 5.06 16 4 -4 4.26 2. 30 3. 92 17 4 -4 3.48 1. 67 4. 27 1 5 -4 11.97 15. 25 4. 27 H K I FO FC WEIGHT 2 5 -4 6.56 8. 31 3.58 3 5 -4 3.76* 4. 18 0. 20 4 5 -4 4.45 4. 69 2.55 5 5 -4 4.82 4.49 3. 12 6 5 -4 5. 40 6. 38 2..45 7 5 -4 10. 28 9.41 4. 66 8 5 -4 3. 53* 4. 09 0.22 9 5 -4 10.66 11.25 4. 80 10 5 -4 16. 33 17. 38 3. 40 11 5 -4 4. 76 4. 38 3. 39 12 5 -4 7.75 8. 13 4. 30 13 5 -4 3. 08* 1.66 0. 16 14 5 -4 4. 18 2.64 3. 14 15 5 -4 3.86 2.77 3. 08 1 6 -4 15. 27 17. 59 3. 49 2 6 -4 10. 23 11.14 3. 38 3 6 -4 8.21 8. 35 4.51. 4 6 -4 3. 9 8* 3. 37 0. 21 5 6 -4 7. 14 7. 35 3. 60 6 6 -4 9. 80 9. 44 4. .32 7 6 -4 12. 15 12. 82 4. 28 8 6 -4 4. 60 3. 99 2. 35 9 6 -4 6. 68 6. 89 3. 83 10 6 -4 3.50* 3.99 0. 18 11 6 -4 0. 00* 2. 63 0. 00 12 6 -4 3.08* 2. 92 0. 19 13 6 -4 2. 91* 2. 59 0. 17 1 7 -4 4. 97 4, 96 2. 39 2 - 4 4. 3 7 * 6.3 2 0. 1 9 3 7 -4 5. 47 3. 15 4. 25 4 7 -4 8. 22 10.59 3.81 5 7 -4 5. 91 4. 43 4. 05 6 7 -4 3. 96* 3. 52 0. 18 7 7 -4 5. 33 5.75 2. 62 8 7 -4 4.01 4. 35 2. 34 9 7 -4 3. 51* 2.98 0. 20 1 0 _ 3 13. 04 1 3. 59 6.5 3 2 0 -3 38. 02 32. 90 1. 00 3 0 -3 22. 52 24. 19 2. 62 4 0 _3 27. 02 25.53 1.91 5 0 _ 3 24. 82 25. 70 2. 20 6 0 -3 13. 56 14. 61 5.71 7 0 -3 24. 29 25. 24 2. 30 8 0 -3 25. 73 23.71 2. 06 9 0 -3 15. 4C 15. 47 4. 64 10 0 -3 2. 91 0.59 4. 85 11 0 -3 19. 74 19.95 3. 17 12 0 -3 0. 00* 1.65 0. 00 13 0 -3 15. 11 15.87 4. 01 14 0 -3 11. 27 9.70 5. 47 15 0 -3 2.95* 1. 96 0. 28 16 0 -3 9. 61 10. 06 5. 37 17 0 -3 2. 33* 1. 15 0. 15 18 0 -3 4.77 4.39 4. 07 19 0 -3 5. 27 5.60 3.93 20 0 -3 5. 73 5.74 4. 69 21 0 -3 3.50 2.01 3. 48 1 1 -3 11. 69 12. 20 7. 67 H K L FO FC WEIGHT 2 •, -3 47.01 43. 39 0.66 3 1 -3 21. 02 23. 26 3. 00 4 1 -3 14. 61 16. 12 5. 46 5 1 -3 40.41 37. 58 0.89 6 1 -3 37. 65 36. 40 1. 01 7 1 -3 21.84 21. 94 2.78 8 1 -3 29. 54 27. 70 1. 59 9 1 -3 17. 67 17. 10 3. 80 10 1 -3 4. 29 4. 30 5.68 11 1 -3 19.45 18. 09 3. 21 12 1 -3 8. 97 8. 54 7. 15 13 • 1 -3 6. 02 7. 18 4. 88 14 1 -3 5. 64 5. 67 5. 48 15 1 -3 3.61* 4. 36 0. 25 16 1 -3 0. 00* 0. 36 0. 00 17 1 -3 6.41 7. 37 4. 12 18 1 -3 7. 89 8. 24 4. 77 19 1 -3 4.60 4. 25 3. 33 20 1 -3 5.56 5. 34 4. 65 21 1 -3 1.20* 1.65 0. 05 1 2 -3 28. 16 26. 22 1.75 2 2 -3 22. 08 19. 81 2. 73 3 2 -3 30.69 29. 04 1. 47 4 2 -3 33.01 33. 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C3 5. 05 12 3 -3 7.84 8. 54 5. 32 13 3 -3 6.09 6. 19 4. 56 14 3 -3 12.10 12. 99 4. 43 15 3 -3 5.77 5. 18 5. 18 16 3 -3 7. 55 7. 88 5. 29 17 3 -3 12.08 11. 39 4.30 18 3 -3 9.86 9. 69 5. 39 H K L FO FC WEIGHT 19 3 -3 2. 16* 1.77 0. 12 1 4 - 3 23. 77 21. 45 2. 20 2 4 -3 24. 86 23.53 2. 09 3 4 -3 16.92 15.95 3.70 4 4 -3 9. 18 8. 23 5. 4 3 5 4 -3 8. 48 9. 36 7. 14 6 4 -3 4. 04 3. 95 3. 27 7 4 -3 7. 30 6. 92 4. 73 8 4 -3 8. 21 8. 37 5. 05 9 4 -3 12. 21 12. 96 5. 02 10 4 -3 11.68 11.56 4. 90 11 4 -3 4.76 4. 13 2. 58 12 4 -3 6.48 7. 05 3. 51 13 4 -3 9. 45 9. 43 5. 17 11 4. -3 10. 52 10. 32 4. 66 15 4 -3 2. 55* 0. 53 0.13 16 4 -3 4. 52 3. 36 3, 94 17 4 -3 4. 30 3. 53 3. 23 18 4 -3 3. 33* 2. 25 0. 28 1 5 -3 13.88 13. 27 4. 01 2 5 -3 10. 74 10. 89 4. 57 3 5 -3 16.47 17. 57 3. 48 a 5 -3 14.71 15. 85 3.91 5 5 -3 19. 38 21. 29 2. 72 6 5 -3 7. 37 9.15 3. 84 7 5 -3 11, 06 1 1. 37 4. 57 8 5 -3 11. 27 11. 04 4.68 9 5 -3 15. 50 15. 47 3.65 10 o — j 3.92' 3. 76 6. 19 11 5 -3 12. 21 1 2. 17 3. 80 12 5 -3 10. 85 11. 05 4. 65 13 5 -3 6.47 6.52 3. 61 m 5 -3 5. 02 3. 27 4. 51 15 5 -3 3. 68 2. 27 3. 14 16 5 - 3 3. 44* 2. 70 0. 24 1 6 -3 10. 06 11. 23 3. 51 2 6 -3 8. 57 8. 94 4. 03 3 6 -3 14. 53 15.43 3. 82 4 6 -3 8.73 8. 49 4. 32 5 6 -3 10. 89 1 1. 30 4. 44 6 6 -3 1.71* 2. 27 0. 03 7 6 _ 3 3. 44* 3. 40 0. 16 8 6 -3 2. 91* 2. 81 0. 12 9 6 -3 0. 00* 1. 28 0. 00 10 6 -3 10. 16 10. 40 4.70 11 6 -3 4. 27 3. 50 2. 49 12 6 -3 3. 67* 4. 68 0. 20 13 6 -3 7. 76 7. 86 4. 86 14 6 _ 3 3. 41* 3. 36 0. 18 1 7 -3 2.26* 3.83 0. 05 2 7 -3 4.42 5. 03 1. 91 3 7 -3 7. 07 6.95 3. 97 4 7 -3 6. 50 6. 07 2. 95 5 7 -3 2. 51* 4. 97 0.07 6 7 -3 2. 44* 3.31 0. 08 7 7 -3 5. 01 4.41 2. 49 8 7 -3 5. 81 5.87 3. 57 9 7 -3 4. 42 3.30 2.61 H K L FO FC WEIGHT 10 7 -3 4.30 3. 22 2. 37 1 8 -3 5.89 7. 08 2. 74 2 8 -3 2. 49* 1. 74 0. 07 3 8 -3 3.47* 2.21 0. 15 1 0 -2 10.42 11. 87 7.57 2 0 -2 25. 02 24. 66 2. 17 3 0 -2 19.75 22. 77 3.40 4 0 -2 34. 40 33. 89 1. 22 5: 0 -2 44. 42 46. C3 0.74 6 0 -2 45. 76 46. 14 0. 69 7 0 -2 40.36 42. 66 0. 89 8 0 -2 15. 76 14. 89 4.71 9 0 -2 17.54 17. 90 3. 94 10 0 -2 8.71 9. 00 8. 79 11 0 -2 2.13* 0. C6 0. 28 12 0 -2 11.91 11. 28 6. 03 13 0 -2 9.88 10. 26 6. 10 14 0 -2 13. 75 14. 32 4. 67 15 0 -2 4.59 5. 82 4. 29 16 0 -2 2. 26* 1.84 0. 13 17 0 -2 6.23 6. 58 4. 81 18 0 -2 4. 29 2. 90 4. 59 19 0 -2 2. 25* 3.41 0. 11 20 0 -2 2. 50* 2.15 0. 17 21 0 -2 5.92 5. 59 5. 21 1 1 -2 47. 23 45. 23 0. 65 2 1 -2 71. 13 68. 38 0.29 3 1 -2 35. 62 32. 56 1. 13 4 1 -2 47. 34 45. 63 0. 65 5 1 -2 16.63 17. C7 4.55 6 1 -2 8. 68 8. 25 10.61 7 1 -2 18.61 16.23 3. 68 8 1 -2 20. 27 19. 98 3. 18 9 1 -2 12. 34 12.31 6. 55 10 1 -2 10. 51 12. 30 7. 29 11 1 -2 12. 94 14. 24 6. 07 12 1 -2 15. 20 15. 15 4. 37 13 1 -2 12.60 12. 04 5. 26 14 1 -2 7. 35 8. S7 5. 67 15 1 -2 5. 81 7. 15 4. 65 16 1 -2 3.60* 4. 58 0. 24 17 1 -2 5.68 5. 40 4. 35 18 1 -2 8. 00 7. 43 5.44 19 1 -2 0. 00* 0. 58 0.00 20 1 -2 2.97* 2. 49 0. 19 21 1 -2 3.78 2. 90 3. 69 1 2 -2 7.81 8. 61 10. 32 2 2 -2 23.87 22. 40 2. 35 3 2 -2 40. 59 37. 82 0. 88 4 2 -2 33. 88 32. 02 1. 24 5 2 -2 35.80 32. 23 1. 11 6 2 -2 30.54 27.45 1.49 7 2 -2 27.03 25. 16 1. 87 8 2 -2 7.42 7. 32 9. 06 9 2 -2 11.35 11. 94 6. 33 10 2 -2 7.99 8. 14 7.65 11 2 -2 9.11 9. 23 7. 25 12 2 -2 8.92 9.83 6. 10 H K 1 FO FC HEIGHT 13 2 -2 6. 60 6. 39 6. 67 14 2 -2 5. 95 7.43 3. 90 15 2 -2 6.67 7. 24 5. 60 16 2 -2 6. 35 6.81 4. 30 17 2 -2 4.30 3.76 3. 59 18 2 -2 4. 93 5. 92 2. 56 19 2 -2 2. 75* 0.73 0. 16 20 2 -2 7. 15 7.74 4. 49 21 2 -2 4.49 4. 18 3. 56 1 3 -2 10. 36 9. 2 1 6. 85 2 3 -2 33. 90 35. 62 1.21 3 3 -2 30. 98 30.68 1. 45 4 3 -2 44. 10 39. 62 0.74 5 3 -2 29. 71 27.77 1. 57 6 3 -2 30. 59 27. 34 1. 46 7 3 -2 12. 05 1 1. 07 6. 38 8 3 -2 4. 82 3.72 4. 71 9 3 -2 20. 60 18. 38 2. 87 10 3 -2 27.90 25. 37 1.70 11 3 -2 12. 85 13. 12 5. 09 12 3 -2 7. 10 7. 25 6. 11 13 3 -2 18.08 19. 52 3. 18 14 3 -2 3.43* 3. 28 0. 22 15 3 -2 12. 07 12. 10 4.3 8 16 3 -2 3. 80 1.95 2. 97 17 3 -2 4. 88 4. 24 4. 22 18 3 -2 1.91* 2. 64 0. 07 19 3 -2 4. 04 4.35 2. 53 20 3 -'2' 3. 2 3' * 3.96 0.2 3 1 4 -2 7. 59 9.47 6. 17 2 4 -2 16. 51 16.74 3. 96 3 4 -2 14. 29 14. 90 4. 57 4 4 -2 22. 72 21.04 2. 39 5 4 -2 9.54 9.13 6. 02 6 4 -2 15.03 14. 15 4. 35 7 4 -2 6.91 5. 22 5. 55 8 4 -2 17. 03 1 4.33 3.76 9 4 -2 17. 31 15.65 3. 32 10 4 -2 5. 32 4. 97 4. 13 11 4 -2 9.30 9.91 5. 46 12 4 -2 16. 22 16.28 3. 58 13 4 -2 7.21 6. 56 5.49 14 4 -2 16. 98 16.99 3. 28 15 4 -2 8.30 8. 34 4. 90 16 4 -2 9. 28 8.88 5. 69 17 4 -2 5. 55 4. 93 4. 32 18 4 -2 2. 49* 1.73 0. 15 19 4 -2 0.66* 1.69 0.01 1 5 -2 4. 14 5.65 2. 30 2 5 -2 8.72 9. 11 4. 29 3 5 -2 6. 94 7. 07 3. 31 4 5 -2 4.41 3. 08 3. 12 5 5 -2 9.67 10. 38 4. 51 6 5 -2 18.77 18.78 2. 92 7 5 -2 13.08 14. 24 4. 48 • 8 5 -2 5.77 6.61 3. 54 9 5 -2 7. 12 6. 94 3. 72 10 5 -2 6.55 7. 17 4. 00 H K L FO FC HEIGHT 11 5 -2 0.00* 2. 34 0. 00 12 5 -2 6.51 6. 39 4. 81 13 5 -2 6.29 6. 35 3. 98 14 5 -2 6.52 6. 91 4. 17 15 5 -2 0.52* 2. 22 0. 00 16 5 -2 5.58 4. C1 4. 00 17 5 -2 3. 66 3. 36 3. 01 1 6 -2 7. 08 9. 66 2. 91 2 6 -2 4.77 4. 05 2. 29 3 6 -2 9.44 11.75 3. 12 4 6 -2 7.02 8. 43 2. 52 5 6 -2 3. 97* 2. 93 0. 20 6 6 -2 13 . 03 15. 19 3. 65 7 6 -2 7.59 8. 92 3. 21 8 6 -2 5. 76 5. 15 2. 52 9 6 -2 2. 95* 2. 28 0. 14 10 6 -2 3. 30 9. 22 4. 39 11 6 -2 5. 82 6. 09 2. 55 12 6 -2 5. 59 5. C3 3. 65 13 6 -2 5. 40 4. 63 3. 76 14 6 -2 2.64* 3. C9 0.15 15 6 -2 6.98 6. 57 5. 84 1 7 -2 4.72 4. 93 2. 13 2 7 -2 3. 57* 6. 16 0. 13 3 7 -2 3.51* 3. 73 0. 12 4 7 -2 9.82 12. C3 3. 72 5 7 -2 10.02 10. 73 4. 36 6 7 -2 4. 47 2. 06 2. 28 7 7 - 2 0. GO* 37 G. 00 8 7 -2 4. 09* 4. 23 0. 18 9 7 -2 7. 77 8. 10 5. 25 10 7 -2 6.38 4. C1 3. 85 11 7 -2 0.00* 0. 94 0. 00 1 8 -2 4.70* 6. 40 0. 15 2 8 -2 4. 29* 2. 91 0.13 3 8 -2 4.21* 4. 67 0.12 4 8 -2 4.02* 4. 60 0. 14 5 8 -2 3. 06* 1. 26 0. 10 1 0 -1 6.54 5. 79 14.91 2 0 -1 51.15 5 3. 70 0.53 3 0 -1 52.04 52. 85 0. 53 4 0 -1 70. 88 74. Id 0. 29 5 0 -1 48.03 51. 20 0. 63 6 0 -1 24.78 25. 73 2. 27 7 0 -1 12. 96 12. 77 6. 64 8 0 -1 40. 81 41. 53 0. 86 9 0 -1 16.57 17. 86 4. 33 10 0 -1 44. 84 44. 73 0. 71 11 0 -1 4. 35 3. 32 5. 47 12 0 -1 8. 35 9. 05 8. 58 13 0 -1 8.79 7. 94 7. 00 14 0 -1 30. 19 30. 30 1. 45 15 0 -1 0. 93* 0. 76 0. 02 16 0 -1 8.81 8. 48 4. 49 17 0 -1 0. 00* 1. 10 0.00 18 0 -1 3.11* 0. 86 0. 18 19 0 -1 4. 52 4. 91 2. 38 20 0 -1 2.82* 1. 67 0.15 H K L FO FC WEIGHT 21 0 -1 7. 95 6.66 5. 08 1 1 -1 25. 85 21. 88 2. 02 2 1 -1 47. 86 44.52 0. 63 3 1 -1 26. 19 24. 95 1. 99 4 1 -1 61. 29 57. 17 0. 39 5 1 -1 27. 93 29.19 1.80 6 1 -1 20. 16 17. 87 3. 28 7 1 -1 14. 06 12. 82 5.71 8 1 -1 14. 99 15. 19 5. 27 9 1 -1 30. 87 32. 23 1. 45 10 1 -1 3. 65 6. 16 5. 06 11 1 -1 9.73 9. 27 7. 29 12 1 -1 4. 55 3.42 6. 15 13 1 -1 9.47 9.69 6.69 n 1 -1 12. 94 13. 01 5. 19 15 1 -1 9. 50 9. 00 7. 02 16 1 -1 5. 98 6. 20 3.21 17 1 -1 7.29 6.41 5. 92 18 1 -1 4. 06 3. 23 2. 44 19 1 -1 3. 99* 3. 84 0. 22 20 1 -1 4. 05 2. 81 2. 56 21 1 -1 5.45 4. 16 4.33 1 2 -1 58. 05 51.43 0. 44 2 2 -1 24. 90 20.22 2. 18 3 2 -1 9. 96 8. 29 8. 61 4 2 -1 53. 44 49.76 0. 51 5 2 -1 8. 70 8. 15 10. 73 6 2 -1 21. 36 23. 03 2.91 7 2 - -j 3.3 2 3.6 7 5 . 54 8 2 -1 16. 62 15. 40 4. 26 9 2 -1 23. 10 22.43 2. 46 10 2 -1 8.38 7.80 8. 13 11 2 -1 14. 15 12. 69 5. 03 12 2 -1 5. 78 6. 96 6. 60 13 2 -1 8. 19 8.53 5. 65 14 2 -1 5. 16 4. 70 4. 87 15 2 -1 7. 46 6. 93 5. 13 16 2 -1 5. 08 4.43 3. 15 17 2 -1 6. 7C 5. 70 4.64 18 2 -1 9. 85 9. 20 5. 34 19 2 -1 2. 27* 2.8 8 0. 07 20 2 -1 4. 87 2. 68 4. 32 21 2 -1 5. 09 3.79 3. 70 1 3 -1 16. 87 15. 11 4. 02 2 3 -1 5. 14 4. 96 6. 70 3 3 -1 40. 05 37. 20 0. 89 4 3 -1 17.51 16. 25 3. 89 5 3 -1 37. 71 35. 58 1. 00 6 3 -1 3. 54 1. 83 4.91 7 3 -1 12. 47 10. 64 6. 04 8 3 -1 3. 69 3.00 4. 13 9 3 -1 6. 04 6. 40 6.13 10 3 -1 5. 21 3.73 5. 65 11 3 -1 13. 37 13.76 4. 85 12 3 -1 15. 06 13. 85 4. 27 13 3 -1 2. 71* 1. 79 0. 17 14 3 -1 9. 36 8. 50 5. 44 15 3 -1 1.19* 2.41 0. 02 H K L FO FC WEIGHT 16 3 _1 5. 30 5. 12 2. 68 17 3 -1 10. 11 8. 79 4. 44 18 3 -1 0.58* 1. 21 0. 01 19 3 -1 4. 19 3. 02 2. 82 20 3 -1 0. 00* 1.9-6; 0. 00 1 4 -1 8.17 10. 21 5. 36 2 4 -1* 30. 30 28. 83 1. 46 3 4 -1 26.50 22. 54 1. 85 4 4 -1 9.12 7. 39 6.76 5 4 -1 4.40 5. 15 4.70 6 4 -1 9. 87 9. 18 6. 28 7 4 -1 10.04 9. 40 5.58 8 4 -1 15. 17 12. 75 4. 13 9 4 -1 13.04 12. 33 4. 64 10 4 -1 7. 57 6. 98 5. 07 11 4 -1 8.39 8. 62 4. 81 12 4 -1 4. 68 2. 77 2. 73 13 4 -1 19.28 18. 02 2. 86 14 4 -1 2. 75* 1. 63 0. 10 15 4 -1 6.42 6. 99 3. 33 16 4 -1 7.53 6. 88 4. 36 17 4 -1 7. 38 7. 46 3. 93 18 4 -1 6. 66 6. 50 3. 87 19 4 -1 3.76 2. 32 2. 35 1 5 -1 8. 37 8. 58 4. 04 2 5 -1 13.72 13. 52 4. 20 3 5 -1 9.85 10. 19 4. 11 4 5 -1 6.74 7. 96 4.07 5 5 - i y. 06 8. 74 5. 70 6 5 -1 5.81 4. 17 4.12 7 5 -1 10. 30 8. 80 5. 17 8 5 -1 3.31* 1. 65 0. 15 9 5 -1 6.42 5. 30 2. 97 10 5 -1 16.74 15. 48 3. 49 11 5 -1 10.29 10. 56 3. 99 12 5 -1 3.36* 4. 12 0. 15 13 5 -1 8.69 9. 09 4. 26 14 5 -1 0 . 00* 2. 91 0. 00 15 5 -1 7.57 6. 37 4.01 16 5 -1 6. 48 4. 97 3. 71 17 5 -1 4.32 2. 69 2. 84 1 6 -1 16. 17 16. 97 3. 13 2 6 -1 4. 17* 3. 85 0. 14 3 6 -1 12. 68 12.61 3. 01 4 6 -1 12. 17 10. 67 3. 57 5 6 -1 22. 25 21. 72 2. 12 6 6 -1 8.. 24 9. 75 3. 14 7 6 -1 12.86 9. 52 3. 69 8 6 -1 20. 88 19. 69 2. 32 9 6 -1 8.90 8. 45 3. 93 10 6 -1 8.07 6. 68 3. 66 11 6 -1 8.59 9. 26 5. 04 12 6 -1 6.05 5. 73 3. 64 13 6 -1 4.42 3. 29 2. 16 14 6 -1 4.68 3. 12 2.99 15 6 -1 3. 02* 2. 76 0. 18 1 7 -1 13.08 13. 04 3. 55 2 7 -1 11 .36 10. 98 3. 59 H K L FO FC HEIGHT 3 7 -1 6.77 6.82 2. 55 a 7 -1 10. 90 10. 29 3. 14 5 7 -1 4. 25* 4. 66 0. 13 6 7 -1 8. 12 6. 92 3. 36 7 7 -1 8. 68 7. 49 3. 27 8 7 -1 4. 23* 5. 27 0.19 9 7' -1 2. 58* 3.45 0. 08 10 7 -1 3. 03* 0. 94 0. 14 11 7 -1 6. 96 6,68 4. 35 12 7 -1 3. 94* 2. 48 0. 22 1 8 -1 5.49 6.44 1. 34 2 8 -1 3. 20* 4. 17 0, 06 3 8 -1 3. oe* 4. 11 0. 07 4 8 -1 5. 35 3.03 2. 06 5 8 -1 2. 17* 0. 73 0.05 6 8 -1 3. 43* 3. 91 0. 10 1 0 0 6.25 7.33 11. 05 2 0 0 43. 42 48.58 0. 70 3 0 0 10. 64 13. 28 4. 37 a 0 0 68. 74 83.66 0. 31 5 0 0 43. 14 50, 85 0.72 6 0 0 7. 45 7. 47 3. 39 7 0 0 0. 00* 5.33 0. 00 8 0 0 25. 65 31. 42 2. 09 9 0 0 4. 41 3. 50 5. 02 10 0 0 4.37 0. 63 4. 34 11 0 0 20. 69 23. 51 2. 86 12 0 0 9. 49 9. 50 5..88 <• «> 1 .J r\ \J s\ V <• ». ^ J. i • / T r\ <^ <* O. O I 14 0 0 3. 26* 4. 14 0. 22 15 0 0 3. 76 3 • 23 2. 93 16 0 0 1. 89* 1.91 0. 06 17 0 0 2. 73* 3.45 0. 17 18 0 0 8. 6C 8.09 4. 76 19 0 0 2. 10* 0. 38 0. 12 20 0 0 0.00* 0. 33 0. 00 21 0 0 2.59* 2. 06 0. 16 22 0 0 5. 09 3.58 3. 92 1 1 0 51. 36 46. C8 0. 52 2 1 0 57. 55 51.14 0.43 3 1 0 86. 93 82.54 0. 20 4 1 0 51. 45 52. 24 0. 55 5 1 0 31. 69 31. 18 1. 42 6 1 0 41. 89 43. 69 0.83 7 1 0 22. 16 24. 58 2. 70 8 1 0 6.27 6.99 10. 76 9 1 0 17. 15 18. 06 4. 08 10 1 0 4. 90 5. 19 8. 12 11 1 0 5. 58 6.42 6. 11 12 1 0 5. 33 4.63 6. 48 13 1 0 6. 30 6. 05 7. 72 14 1 0 9. 38 9.6 5 5. 59 15 1 0 6. 23 6.68 4. 39 16 1 0 11.41 11.32 4. 86 17 1 0 11. 55 11.43 4. 28 18 1 0 4. 85 5.41 2. 32 19 1 0 3. 50* 1.37 0. 21 20 1 0 2. 87* 1.08 0. 20 H K L FO FC HEIGHT 21 . 1 0 3.65* 3. C5 0. 27 0 2 0 43. 34 3 5. 95 0. 76 1 2 0 74.86 63. 10 0. 26 2 2 0 48.41 39. 39 0.62 3 2 0 63. 76 55. 52 0. 36 4 2 0 12.90 11. 85 6. 56 5 2 0 24. 28 25. 85 2. 28 6 2 0 34.63 32. 33 1. 19 7 2 0 25.02 25. 52 2. 17 8 2 0 13.71 15. 01 5. 58 9 2 0 14. 15 14. 99 5. 45 10 2 0 7.95 7. 89 7.72 11 2 0 8.02 7. 14 6. 31 12 2 0 15.73 17. C9 3. 91 13 2 0 7.01 8. 00 5.78 14 2 0 5. 98 7. 28 4. 40 15 2 0 4.77 4. 96 3. 32 16 2 0 4.05* 4. 76 0. 22 17 2 0 6. 58 7. 32 4. 02 18 2 0 4. 48 3. 60 3.49 19 JL 0 5.29 • 4. 56 3. 08 20 2 0 6.57 6. 08 4. 28 21 2 0 3.23* 1. 38 0. 24 1 3 0 10.42 8. 29 7. 00 2 3 0 16.03 15. 54 4. 65 3 3 0 33. 03 28. 18 1. 27 4 3 0 31. 13 30. 83 1.43 5 3 0 29.23 29. 35 .1 . 60 o X) IS*. / / 1 H . 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C4 5.25 9 4 0 14.75 15. 65 4. 08 10 4 0 10.63 10. 78 5. 37 11 4 0 11. 84 10. 91 5. 16 12 4 0 8.48 8. 36 5.49 13 4 0 10.20 10. 63 4. 81 14 4 0 7. 57 6. 05 4.58 C3 H K L FO FC WEIGHT H K L FO FC WEIGHT 15 4 0 2. 30* 4. 47 0. 06 1 0 1 68.40 72. 85 0. 30 16 4 0 7. 88 8.89 4. 01 2 0 1 58.62 65. 18 0. 39 17 4 0 3.41* 3.91 0. 18 3 0 1 4.82 4. 76 12. 49 18 4 0 5. 01 4.56 3. 74 4 0 1 41.54 43. 88 0. 84 19 4 0 7. 06 6. 35 4. 58 5 0 1 13.39 14. 61 6. 25 1 5 0 17.01 16. 00 3. 14 6 0 1 26.52 32.74 1. 97 2 5 0 10. 52 8. 89 4. 50 7 0 1 36.32 37. 14 1. 09 3 5 0 18.66 15.74 3. 09 8 0 1 33.67 37. 68 1.26 4 5 0 5. 05 4.62 3. 28 9 0 1 7.02 6. 39 8. 87 5 5 0 11.16 10. 20 4. 94 10 0 1 18.99 19. 79 3. 48 6 5 0 5. 83 5. 29 3.12 11 0 1 3.73 4. 54 4. 79 7 5 0 10. 30 10. 24 5. 23 12 0 1 6.00 6. 61 8. 01 8 5 0 16. 14 16. 12 3. 34 13 0 1 7.24 7. 11 6. 67 •9 5 0 14.28 15.29 3. 51 14 0 1 11.84 11.92 5. 28 10 5 0 20. 70 19. 93 2. 53 15 0 1 2.65* 1. 06 0. 20 11 5 0 16.88 15. 89 3. 17 16 0 1 8.04 9. 34 5.28 12 5 0 5. 43 4.65 3. 23 17 0 1 2.27* 1. 25 0. 09 13 5 0 5.09 4. 66 2. 89 18 0 1 12.67 12.51 4. 95 14 5 0 8. 32 7. 58 5.25 19 0 1 2.83* 2. 85 0. 12 15 5 0 5.69 4.83 3. 42 20 0 1 2.57* 1. C4 0. 13 16 5 0 €.53 5.65 3.73 21 0 1 3.43* 2. 10 0. 31 17 5 0 0. 99* 1. 05 0. 02 0 1 1 14.34 15. 09 5. 67 0 6 0 12. 82 11.41 2. 89 1 1 1 23.80 25. 35 2. 33 1 6 0 5. 65 4. 52 2. 03 2 1 1 €6.66 69. S9 0. 33 2 6 0 15. 16 13.8S 3. 17 3 1 1 135.38 133.31 0. 08 3 6 0 6. 15 5. 06 2. 38 4 1 1 119.68 122.82 0. 10 4 6 0 3.35* 5. 05 0.11 5 1 26.87 29. 24 1. 96 5 6 0 11. 39 11.59 3. 74 6 1 1 34.08 36. 57 1. 22 o y U o t— r\ —i i L'» i ~? r*\ f i ~> c • -J u -> i— r- T» •« Tl rr. 1 « -J _J 7 6 0 2. 87* 1.52 0. 10 8 1 1 23.77 28. C5 2. 37 8 6 0 17. 57 16. 81 3. 13 9 1 1 20.22 23. 19 3. 09 9 6 0 12. 67 13. 41 4. 01 10 1 1 16.63 17. 90 4. 14 10 6 0 10.77 9.45 4. 48 11 1 1 15.81 15. C2 4.57 11 6 0 2. 31* 2. 12 0. C9 12 1 1 7.75 6. 97 7. 53 12 6 0 5.01 3. 52 2. 88 13 1 1 5.06 5. 43 4. 84 13 6 0 7.45 7. 43 4. 12 14 1 1 5. 01 7. 10 3. 12 14 6 0 4. 33 3. 62 2. 65 15 1 1 5. 34 6. 51 4. 19 15 6 0 2. 57* 3. 42 0. 10 16 1 1 6.23 7. 40 4. 33 1 7 0 3. 64* 3. 55 0. 10 17 1 1 8.33 8. 42 5.51 2 7 0 6. 90 7. 05 2. 64 18 1 1 4.96 5. 31 2. 81 3 7 0 6. 66 5. 88 2. 52 19 1 1 0.00* 1. 68 0. 00 4 7 0 12. 43 12.61 3.41 20 1 1 2.05* 1. 19 0. 11 5 7 0 14.99 1 4. 59 3. 22 21 1 1 4.31 3. 92 2. 76 6 7 0 1. 26* 2. 35 0. 02 0 2 1 34.70 36. 44 1. 18 7 7 0 13.54 12. 84 3. 56 1 2 1 63.29 67. 30 0. 37 8 7 0 11. 26 10. 96 4. 25 2 2 1 25.14 24. 41 2. 18 9 7 0 9. 20 8.78 4. 62 3 2 1 14.62 15. 04 5. 51 10 7 0 2.32* 0. 86 0. 07 4 2 1 30.35 31. 45 1. 53 11 7 0 5. 25 5. 24 2.78 5 2 1 23.34 24. 42 2. 45 12 7 0 7. 4 5 6. 12 4. 03 6 2 1 19.46 20. 65 3. 39 0 8 0 5. 12 5. 16 1. 52 7 2 1 11.28 11.70 7.56 1 8 0 5. 73 4. 35 1. 79 8 2 1 16.56 16. 77 4. 18 2 8 0 4. 56* 2. 50 0. 14 9 2 1 6.96 8. 23 9.78 3 8 c 0. 91* 1. 03 0.01 10 2 1 26.98 27.65 1.81 4 8 0 4. 49* 2. 67 0. 17 11 2 1 13.20 13. 77 5. 34 5 8 0 0. 00* 1. 23 0. 00 12 2 1 7.08 7. 99 5.42 6 8 0 3. 33* 4. 01 0. 10 13 2 1 4.84 3. 80 4.51 0 0 1 37. 60 38. 81 0. 97 14 2 1 6.90 5.06 7. 26 H K L FO FC WEIGHT 15 2 1 4. 49 3. 27 3. 07 16 2 1 4.75 3.91 3. 48 17 2 1 9. 39 9. 36 4. 96 18 2 1 5. 39 4.44 3. 69 19 2 1 2. 41* 2. 07 0. 12 20 2 1 11. 35 11.55 4. 79 21 2 1 3.44 1. 30 3. 13 0 3 1 19. 67 20. 76 3. 29 1 3 1 42.52 4 8.31 0. 79 2 3 1 25. 81 25. 86 2. 02 3 3 1 47. 57 39.65 0. 64 4 3 1 27.32 24.76 1.81 5 3 1 23. 49 24.71 2. 35 6 3 1 26. 32 24. 31 1. 93 7 3. 1 3. 59 3.57 4. 07 8 3 1 21. 45 21.98 2.76 9 3 1 16. 45 15.43 3.9 3 10 3 1 8. 01 7. 01 7. 10 •11 3 1 7. 86 9.77 4. 62 12 3 1 4. 02 4. 52 2. 82 13 3 1 11. 84 11. 33 4. 60 14 3 1 9. 96 9. 70 5. 47 15 3 1 4. 91 5. 25 3. 04 16 3 1 2. 07* 0. 68 0. 09 17 3 1 3. 93 4. 54 2. 35 18 3 1 4. 95 5.54 2. 47 19 3 1 4. 94 4. 94 3. 67 20 3 1 4.98 3. 62 5. 13 0 4 ~T 6. 93 5. 66 6. 07 1 4 1 26. 37 24. 83 1.90 2 4 1 17. 02 15. 46 3. 95 3 4 1 8. 16 7. 27 6.63 4 4 1 12. 96 10.68 5. 64 5 4 1 15.63 15.65 4. 15 6 4 1 22. 07 19. 69 2. 61 7 4 1 7. 73 7.09 6.60 8 4 1 5. 63 5. 25 4. 39 9 4 1 6. 01 6.72 4.61 10 4 1 6. 04 5. 07 5.40 11 4 1 8.61 8. 20 5. 37 12 4 1 10. 67 11.09 4,71 13 4 1 14. 39 15. 79 3. 97 14 4 1 12. 32 12. 21 4. 19 15 4 1 10. 71 10.62 4. 52 16 4 1 3. 81* 3. 87 0.21 17 4 1 5. 18 4. 58 3. 67 18 4 1 '5. 83 5.15 3. 94 19 4 1 1. 94* 1.32 0. 10 0 5 1 6.43 7. 97 4. 65 1 5 1 6.78 7.62 5. 23 2 5 1 6. 59 5. 65 5.04 3 5 1 20. 25 17.39 2. 77 4 5 1 10. 70 9.33 5. 07 5 1 9.68 9.01 5. 24 6 5 1 4. 41 4. 42 2. 51 7 5 1 10.54 10. 13 5. 18 8 5 1 9.98 9. 17 5. 36 9 5 1 6. 70 6. 92 4. 30 H K L FO FC WEIGHT 10 5 12.99 13. 35 3. 85 11 5 1 10. 88 10. 40 4. 36 12 5 1 15. 53 14. 94 3. 63 13 5 1 4. 47 3. 97 2.87 14 5 1 0.00* 1. 37 0. 00 15 5 1 3.43* 3. 07 0. 22 16 5 1 6,61 5. 49 5.06 17 5 1 2.79* 2. 87 0. 16 0 6 1 4.15* 3. 69 0. 19 1 6 1 7.18 6. 74 3. 48 2 6 1 3.63* 4. 06 0. 17 3 6 1 5.66 6. C9 3. 17 4 6 1 12. 80 12. 72 4.40 5 6 1 5. 18 4. 00 3, 03 6 6 1 10.59 10. 56 3. 66 7 6 1 5. 19 4. 33 2.49 8 6 1 4. 86 2. 92 2. 89 9 6 1 5.07 4. 55 2. 57 10 6 1 2.38* 0. 83 0. 08 11 6 1 1.45* 2. 04 0. 03 12 6 1 7.03 6. 68 3. 85 13 6 1 0. 00* 0. 52 0. 00 14 6 1 6.37 5. 89 3. 94 15 6 1 3. 70 2. 20 2. 91 0 7 1 3.21* 2. 58 0. 12 1 7 1 8.61 8. 65 3. 60 2 7 1 14. 39 14. 13 3. 65 3 7 1 5.61 5. 48 3. 13 4 7 4.4/* 5. 62 0.16 5 7 1 13.69 14.18 3. 56 6 7 1 6. 79 6.70 2. 92 7 7 1 6. 43 5. 66 3.49 8 7 1 7.09 6. 96 3. 51 9 7 1 11 .52 10. 93 4.72 10 7 1 7. 89 6.'66 4. 60 11 7 1 2.57* 3. 44 0. 10 12 7 1 8. 16 6. 56 5. 35 0 8 1 2. 93* 3.41 0. 10 1 8 1 3. 19* 3. 40 0. 11 2 8 1 2. 48* 0. 74 0. 08 3 8 1 4.19* 3. 07 0. 20 4 8 1 0. 00* 2. 26- 0. 00 5 8 1 2.54* 2. 44 0. 08 6 8 1 3. 16* 2. 05 0. 14 0 0 2 29. 65 27. 02 1. 54 1 0 2 16. 27 17. 13 4. 76 2 0 2 16.93 16.79 4. 27 3 0 2 40. 97 39. 24 0. 86 4> 0 2 107.01 111.55 0. 13 5 0 2 57.59 59.51 0.45 6 0 2 18. 83 18. 73 3. 62 7 0 2 27. 23 25. 53 1. 89 8 0 2 13.89 13. 98 5. 40 9 0 2 2.36* 1. 07 0. 43 10 0 2 6. 21 6. 14 8. 51 11 0 2 16. 29 17. 22 4. 07 12 0 2 0. 00* 2. 78 0. 00 13 0 2 3.27 1. 25 4. 25 H K I FO FC WEIGHT 14 0 2 4. 87 6. 15 3. 24 15 0 2 4. 96 3. 70 3. 79 16 0 2 0. 00* 3.67 0. 00 17 0 2 3. 76* 5. 14 0. 26 18 0 2 0. 00* 0. 37 0. 00 19 0 2 3. 59* 3. 08 0.23 20 0 2 3. 77 0. 74 3. 87 21 0 2 2. 42* 2. 16 0. 14 0 1 2 57.79 57.50 0. 44 1 1 2 69. 68 69. 16 0. 30 2 1 2 30. 10 28. 96 1. 56 3 1 2 80. 5 9 84. 06 0. 23 4 1 2 62. 55 63. 80 0. 38 5 1 2 52. 56 53. 25 0. 53 6 1 2 21. 15 23. 50 2. 90 7 1 2 15.61 16. 90 4.78 8 1 2 9. 25 9. 82 8. 23 9 1 2 16.74 17, 13 4. 16 io 1 2 12. 16 13,01 6. 33 11 1 2 7. 49 8. 37 7. 35 12 1 2 2. 16* 3. 01 0. 16 13 1 2 6. 52 6. 90 6. 28 14 1 2 4. 80 5.60 3. 55 15 2 6. 1*2 7. 30 4.84 16 1 2 4. 15 3. 56 2. 96 17 1 2 5. 14 5.09 3. 64 18 1 2 1. 85* 1.12 0. 07 19 1 2 5. 19 5.16 3. 60 20 T 2 6. 07 /. 5 2 5.6 5 21 1 2 3. 83 3. 35 2.91 0 2 22. 08 24. 44 2. 77 1 2 2 31. 72 34.01 1.42 2 2 2 13. 76 14. 48 5. 63 3 2 2 22. 09 21. 54 2. 75 4 2 2 29. 33 30. 37 1.63 5 2 2 9.76 11. 24 8. 94 6 2 2 17. 4 6 17. 06 3.91 7 2 2 44. 94 43. 93 0. 72 8 2 2 34. 69 35. 35 1. 16 9 2 2 6. 91 6. 56 7. 07 10 2 2 19.42 20. 40 3. 13 11 2 2 7. 41 8. 07 7. 04 12 2 2 8. 00 7.88 5. 36 13 2 2 5. 82 4.89 5. 90 14 2 2 4.48 3. 22 2. 88 15 2 2 5. 50 4.64 4. 44 16 2 2 4.88 4.44 3. 50 17 2 2 9.21 9. 93 6. 14 18 2 2 4. 66 3. 17 3. 75 19 2 2 2. 44* 2. 63 0. 10 20 2 2 3. 90 3.59 3. 42 21 2 2 5. 96 5.25 5. 61 0 3 2 14. 14 15. 76 5. 26 1 3 2 11. 86 12. 89 6. 43 2 3 2 26. 95 24. 85 1. 84 3 3 2 25. 95 25. 25 1. 98 4 3 2 26. 16 26. 13 1. 97 5 3 2 8. 13 8.65 8.08 H K L FO FC WEIGHT 6 3 2 21.75 22. 56 2.71 7 3 2 10.77 11. 28 6. 64 8 3 2 16. 26 16. 76 4.13 9 3 2 6.44 7. 18 6. 28 10 3 2 7. 34 6. 25 7. 21 11 3 2 6.81 6.59 5.03 12 3 2 8.66 8. 68 6. 20 13 3 2 1. 86* 1. 33 0. 08 14 3 2 3. 29* 2. 45 0. 20 15 3 2 5.12 3.68 5. 60 16 3 2 5. 48 5. 21 5. 73 17 3 2 6.34 5. 52 4. 46 18 3 2 7.54 6. 78 5. 27 19 3 2 0.78* 1. 98 0. 01 20 3 2 4.62 4. 29 3. 43 0 4 2 14.40 14.28 4. 86 1 4 2 10.60 1 1. 08 6. 73 2 4 2 7.69 8. 31 6. 67 3 4 2 10. 43 9. 64 6. 26 4 4 2 19.31 18. 41 3. 03 5 4 2 5. 72 4. 95 6. 14 6 4 2 7.01 7. 05 5. 92 7 4 2 12. 09 12. 62 5. 62 8 4 2 2. 13* 0. 83 0. 13 9 4 2 4.22 3. 94 3. 64 10 4 2 5.50 4. 22 4. 65 11 4 2 1 .78* 4. 78 0. 05 12 4 2 11. 04 1 1. 59 4. 57 13 4 2 6.65 5. 04 5. 75 14 4 2 7.33 7.11 5. 08 15 4 2 7. 84 7. 91 4. 55 16 4 2 0.00* 0. 37 0. 00 17 4 2 2. 70* 3. 73 0. 11 18 4 2 4. 67 4. 76 3. 94 0 5 2 6.32 5. 91 4. 65 1 5 2 12.92 13. 05 4. 55 2 5 2 8.85 9.21 4. 77 3 5 2 23. 63 25. 74 2. 17 4 5 2 9. 54 10. 20 4. 67 5 5 2 19.05 19. 04 2. 99 6 5 2 5.06 3. 59 3.71 7 5 2 3.82 4. 86 2. 67 8 5 2 6.35 5. 63 4. 75 9 5 2 2. 44* 2. 53 0. 10 10 5 2 0.14* 1. 76 0. 00 11 5 2 5. 66 5. 94 3. 52 12 5 2 2. 29* 1. 67 0. 07 13 5 2 7.37 7. 66 3. 87 14 5 2 3.11* 2. 88 0. 15 15 5 2 1.37* 0. 82 0. 03 16 5 2 3.91 2. 25 3. 43 17 5 2 3.11* 2. 40 0. 20 0 6 2 8.52 9. 47 4.48 1 6 2 4.52 4. 92 2. 60 2 6 2 9.77 10. 68 4.6 3 3 6 2 9.04 9. 60 4. 11 4 6 2 11.29 11. 60 4. 21 5 6 2 4. 32 2. 28 2. 57 H K I FO FC HEIGHT 6 6 2 9.75 9. 91 4. 32 7 6 2 11. 13 11.16 4. 27 8 6 2 5.74 5.97 3. 01 9 6 2 6. 56 6. 27 3. 48 10 6 2 5. 06 4.00 2.90 11 6 2 7. 08 5.77 4. 29 12 6 2 4. 83 5.49 2.86 13 6 2 4. 07* 4. 29 0. 23 14 6 2 4. 89 4.33 4. 03 0 7 2 6. 91 7.57 2. 94 1 7 2 2. 36* 1.7 5 0. 07 2 7 2 3. 07* 3. 55 0. 09 3 7 2 5.41 6.70 2. 15 4 7 2 6. 23 5. 57 3.75 5 7 2 4. 56 3.53 2. 51 6 7 2 6. 03 7.00 3. 21 7 7 2 0. 00* 2. 82 0. 00 . 8 7 2 4.42 5.24 2. 20 9 7 2 5.69 4.71 3. 78 10 7 2 5. 33 6. 96 2. 51 11 7 2 3. 24* 2.77 0. 16 0 8 2 5. 16 6. 26 2. 72 1 8 2 6. 08 6. 73 2. 73 2 8 2 7. 4 1 7. 03 4. 14 3 8 2 6. 15 5.49 3. 53 4 8 2 3.34* 3.40 0. 14 5 8 2 6. 4 8 5. 92 3.49 0 0 3 55. 94 53. 33 0. 47 1 r\ U 3 -> r- <* ^ ~i * f. Z. J < I H £. • *• 7 2 0 3 26. 76 25. 06 1. 94 3 0 3 36. 72 34. 90 1. 06 4 0 3 10. 18 12. 20 8. 07 5 0 3 21. 84 23. 05 2. 76 6 0 3 31. 01 33.53 1. 38 7 0 3 5. 02 4.88 8.71 8 0 3 4. 89 4. 23 8. 57 9 0 3 9. 26 9. 62 7. 89 10 0 3 20. 50 20. 90 2. 90 11 0 3 12.26 13. 03 5. 85 12 0 3 23. 5u 25. 25 2. 25 13 0 3 3. 08* 4, 12 0. 19 14 0 3 15. 42 16. 15 3. 99 15 0 3 1.78* 2. 31 0. 06 16 0 3 4. 17 4. 28 2. 78 17 0 3 4. 10 3.46 3. 11 18 0 3 6. 63 5. 87 3. 91 19 0 3 2. 53* 3. 55 0. 10 20 0 3 2. 20* 1. 19 0. 11 21 0 3 2.95* 2. 25 0. 18 0 1 3 29. 97 30. 36 1. 59 1 1 3 27. 80 27. 42 1.81 2 1 3 32. 22 33. 38 1. 39 3 1 3 16. 84 17. 98 4. 33 4 1 3 40. 47 41.08 0. 88 5 1 3 35. 53 33. 08 1. 14 6 1 3 5. 42 5. 20 7. 53 7 1 3 30. 38 33.09 1.51 8 1 3 27. 50 28. 59 1. 77 H K L FO FC HEIGHT 9 3 33. 89 36. C5 1.21 10 1 3 32. 02 32. 05 1. 32 11 1 3 14.66 15. 27 4. 39 12 1 3 13. 20 13. 50 5. 27 13 1 3 5. 44 5. 70 4. 80 14 1 3 7. 69 7. 95 5. 51 15 1 3 13. 25 15. 51 3. 65 16 1 3 7. 95 8. 93 4. 23 17 1 3 6.12 6. 18 4. 23 18 1 3 4. 82 5. 32 3. 15 19 1 3 2. 56* 2. 74 0. 13 20 1 3 4.72 3. 22 4. 34 21 1 3 3.02* 3. 85 0. 17 0 2 3 37.77 38. 08 1. 00 1 2 3 4.06 4. 98 7. 71 2 2 3 13.83 14. 81 5. 81 3 2 3 26. 06 24. 06 1. 98 4 2 3 27. 59 28. 61 1. 80 5 2 3 8. 50 6. 43 8. 12 6 2 3 62. 80 60. 50 0. 37 7 2 3 19.48 21. 07 3. 30 8 2 3 24.90 26. 82 2. 13 9 2 3 12. 37 13. 65 5. 61 10 2 3 0.96* 2. 82 Q. 03 11 2 3 13.27 14. 80 5. 06 12 2 3 12.56 13. 27 5. 23 13 2 3 6.27 7. C7 3. 89 14 2 3 5.49 6. 13 2.94 i j> 2 3 0.37 O . O 1 16 2 3 2. 92* 2. 33 0. 13 17 2 3 2.71* 0. 81 0. 14 18 2 3 4. 19 4.61 2.18 19 2 3 4. 26 4. 29 2. 43 20 2 3 0.00* 1. 47 0. 00 0 3 3 20.90 20. C2 2. 88 1 3 3 22. 30 23. 15 2. 60 2 3 3 11. 22 12. 50 6.73 3 3 3 31 .49 30. 06 1. 41 4 3 •3 20. 86 22. 35 2. 93 5 3 3 10. 91 10. 27 6. 99 6 3 3 15.71 13. 78 4.39 7 3 3 2.48* 0. 95 0. 22 8 3 3 2. 75* 2. 96 0. 26 9 3 3 12. 33 13. 07 5. 72 10 3 3 11.88 11. 39 5. 90 11 3 3 10. 84 10. 53 5. 90 12 3 3 3.88 3. 36 2. 59 13 3 3 2.39* 2. 32 0. 11 14 3 3 8.37 8. 17 4. 42 15 3 3 4. 26* 4.71 0. 21 16 3 3 2.95* 3. 21 0. 13 17 3 3 0. 00* 2. 65 0. 00 18 3 3 6. 30 6.91 3.53 19 3 3 2.72* 3. 47 0. 12 0 4 3 24.46 27. 38 2. 08 1 4 3 20. 20 21. 35 2. 92 2 4 3 10.04 10. 33 ' 6.94 3 4 3 11.10 9. 42 6. 13 H K I FO FC WEIGHT 4 4 3 6.98 8. 06 5. 98 5 4 3 13. 46 13.41 5. 02 6 4 3 9. 46 9. 28 7. 08 7 4 3 6. 88 6. 87 7. 32 8 4 3 11. 45 1 1.77 5. 57 9 4 3 11. 62 11. 45 5..24 10 4 3 4. 03 3. 88 2. 67 11 4 3 3. 30* 2. 18 0. 19 12 4 3 6.62 8. 19 3. 71 13 4 3 5. 52 5.44 5. 05 14 4 3 4. 81 6. 3 9 2. 25 15 4 3 7.7 9 8. 06 3. 93 16 4 3 3. 90* 3. 30 0. 22 17 4 3 0. 00* 1. 05 0. 00 18 4 3 2.51* 3. 0 9 0.13 0 5 3 16.63 18.11 3. 44 1 5 3 6. 87 6.33 4.91 2 5 3 15. 27 16. 0 3 3. 93 3 5 3 6.32 7. 09 3. 84 4 5 3 14. 61 14.65 4. 43 5 5 3 11.30 10. 27 4. 35 6 5 3 2. 54* 2. 23 0.12 7 5 3 9. 11 10. 53 4. 54 3 c _> i 3. 56* 3. 06 C. 18 9 5 3 7.54 7. 89 3. 73 10 5 3 8.80 8. 85 5. 41 11 5 3 11. 72 12. 92 4.39 12 5 3 6. 80 6. 05 3. 95 i 3 5 3 6. i2 8. 12 5. 16 14 5 3 4. 11 3. 60 2. 56 15 5 3 2.62* 3. 33 0. 12 16 5 3.33* 1. 80 0.21 0 6 3 18. 79 20. 35 2. 78 1 6 3 9. 69 10. 23 3. 99 2 6 3 6.98 7. 57 3. 17 3 6 3 12. 40 1 3. 51 3. 96 4 6 3 8.64 8. 98 4. 40 5 6 3 9. 13 8.73 4. 45 6 6 3 10.75 10. 02 4. 49 7 6 3 8. 45 8. 66 4. 17 8 6 3 13. 99 14. 00 4. 04 9 6 3 6. 94 7.70 4. 04 10 6 3 4. 35 3.47 1 . 94 11 6 3 4. 04* 3. 18 0. 23 12 6 3 4. 87 5. 85 1. 97 13 6 3 2.65* 2.88 0. 11 14 6 3. 57* 2. 53 0. 25 0 7 3 8. 7C 8.07 4. 21 1 7 3 5. 78 7.09 2.90 2 7 3 5. 29 5.06 2. 98 3 7 3 6. 57 8. 14 3. 02 4 7 3 9. 16 9. 38 3. 35 5 7 3 8. 27 8. 74 3.79 6 7 3 4. 62 3.38 2. 57 7 7 3 3. 97* 2. 61 0. 20 8 7 3 5.29 5. 08 3. 36 9 7 3 4. 17* 4. 19 0. 21 10 7 3 3. 7C* 4. 99 0. 22 H K L FO FC WEIGHT 0 8 3 7.71 9. 02 3. 64 1 8 3 1.50* 3. 33 0. 04 2 8 3 9. 33 10. 04 4. 85 3 8 3 5. 14 3. 42 2. 95 0 0 4 8.11 10. 70 4.82 1 0 4 26. 84 27. 05 1. 93 2 0 4 4.05 2. 86 7. 88 3 0 4 31. 14 30. 26 1. 45 4 0 4 14.73 18. 16 4.61 5 0 4 20.20 19. 78 3.18 6 0 4 25. 30 26. 58 2. 09 7 0 4 12.91 12. 15 5. 67 8 0 4 5. 96 4. 79 5. 50 9 0 4 19.84 19. 96 3. 04 10 0 4 8. 17 7. 77 7. 24 11 0 4 1 . 39* 0. 42 0. 07 12 0 4 8.88 10. 06 5, 08 13 0 4 9. 42 9. 30 4. 9 3 14 0 4 17. 72 18. C8 3. 20 15 0 4 6. 75 8. 25 3. 74 16 0 4 3.38* 3.23 0. 17 17 0 4 0. 58* 0. 83 0. 01 18 0 4 4. 58 4. 16 3. 59 19 0 4 2. 33* 1. 92 0. 11 20 0 4 2. 33* 1. 93 0. 1.3 0 1 4 18.52 17. 95 3. 71 1 1 4 33. 13 30. 44 1.28 2 1 4 12. 07 10. 64 6. 61 3 4 34,6" 32. 33 i. IS 4 1 4 11. 59 11. 37 7. 01 5 1 4 31 .38 32. 56 1. 43 6 1 4 23. 71 23. 29 2, 31 7 1 4 36. 53 37. 68 1. 07 8 1 4 9. 29 9. 97 7. 22 9 1 4 39. 33 42. 42 0. 90 10 1 4 2. 29* 4. 65 0.15 11 1 4 21. 06 23. 14 2. 69 12 1 4 0. 00* 2. 34 0. 00 13 1 4 14. 02 15.54 4.45 14 1 4 9.07 9. 12 5, 84 15 1 4 5. 88 6. 40 3. 17 16 1 4 4.11 3. 35 3. 06 17 1 4 4. 38 4.69 3. 15 18 1 4 3. 36* 1. 42 0. 25 19 1 4 4 . 60 3. 52 2. 75 20 1 4 1.71* 1. 28 0. 08 0 2 4 20.57 21. 16 3. 08 1 2 4 16.76 18. 32 4. 17 2 2 4 16.34 17. 52 4. 2 3 3 2 4 22. 36 21.12 2. 63 4 2 4 14. 04 13. 75 5. 15 5 2 4 13. 24 12. 44 5.76 6 2 4 23. 51 23. 74 2. 33 7 2 4 26.03 27. 64 1. 97 8 2 4 18.43 17. 35 3. 35 9 2 4 8. 86 8. 47 8. 05 10 2 4 10.59 10. 01 6. 46 11 2 4 6.81 7. 64 4.61 H K I FO FC WEIGHT 12 2 4 8.79 8.87 5.22 13 2 4 12. 10 13. 97 4. 19 14 2 4 5.22 4. 72 3.78 15 2 4 5. 05 4. 90 3. 38 16 2 4 5.94 7.11 2. 98 17 2 4 3. 35* 3.28 0. 16 18 2 4 8. 18 7. 47 5. 46 19 2 4 3. 83 2. 61 3. 31 0 3 4 20. 54 22. 22 2. 91 1 3 4 16. 31 16.34 4. 18 2 3 4 5.59 6.53 7. 20 3 3 4 6. 00 7. 32 6.61 4 3 4 16.49 17, 31 4. 15 5 3 4 12. 30 1 1. 26 5. 74 6 3 4 13.61 13.42 5. 07 7 3 4 15. 38 15. 90 4, 32 8 3 4 21. 86 20. 99 2. 52 9 3 4 13.54 11.73 5. 16 10 3 4 3. 69* 1.2-2 0. 29 11 3 4 11.58 12. 22 4.38 12 3 4 5.67 4. 19 5. 25 13 3 4 7. 54 7. 38 3. 66 14 3 4 3. 36* 3. 28 0. 20 15 3 4 6.29 6. 01 4. 23 16 3 4 3. 20* 1. 28 0. 18 17 3 4 3. 22* 3. 71 0. 16 18 3 4 5. 66 5. 97 4. 50 0 4 4 17. 18 16. 29 3.79 1 4 4 36. i \j 1.06 2 4 4 11. 24 11. 24 5. 57 3 4 4 8. 39 9. 12 6. 11 4 4 4 3. 23* 1.82 0. 23 5 4 4 17.46 17. 38 3. 57 6 4 4 16. 35 16. 91 3.78 7 4 4 9.23 8.84 5. 11 8 4 4 7. 06 7. 48 4. 68 9 4 4 2. 32* 3.40 0. 08 10 4 4 6. 93 7. 08 4. 01 11 4 4 5. 63 7. 06 3. 01 12 4 4 3. 38* 2. 68 0. 17 13 4 4 9. 13 8. 70 5. 28 14 4 4 8. 56 9. 59 4. 18 15 4 4 7. 05 7.02 4. 86 16 4 4 5. 29 4. 25 3. 88 17 4 4 2. 18* 1. 85 0. 10 0 5 4 10. 11 10.21 4.31 1 5 4 5. 61 6.22 3. 00 2 5 4 15.00 15. 52 3.73 3 5 4 12. 99 14. 13 3. 85 4 5 4 9.70 10.71 4. 67 5 5 4 9. 86 10.65 4. 23 6 5 4 '13.24 13.56 4. 18 7 5 4 6. 00 5. 71 3. 36 8 5 4 3. 03* 3. 01 0. 15 9 5 4 4. 93 6. 01 2. 40 10 5 4 3. 50* 1. 74 0. 21 11 5 4 7. 57 7. 19 4. 92 12 5 4 4. 44 5. 22 2. 32 H K L FO FC WEIGHT 13 5 4 4.49 3. 36 2. 44 14 5 4 4. 27 4. 25 2. 09 15 5 4 3.09* 3. 99 0. 15 0 6 4 11. 28 11. 29 3. 91 1 6 4 5. 84 5. 22 3. 49 2 6 4 4. 17* 4. 31 0. 18 3 6 4 4. 30 4.28 2. 68 4 6 4 11.50 12. 79 4. 11 5 6 4 4.24 4. 83 2. 16 6 6 4 18.70 20. 34 2. 87 7 6 4 1.66* 2. 52 0.04 8 6 4 7.03 8. 06 3. 60 9 6 4 2.61* 4. 20 0.11 10 6 4 1.81* 2. 32 0. 06 11 6 4 4.10* 5. 83 0. 22 12 6 4 4.66 3. 89 3.05 13 6 4 4. 52 4. 85 3. 27 0 7 4 5.48 6.37 2.48 1 7 4 9. 44 10. 05 4. 11 2 7 4 4. 96 3. 38 3. 40 3 7 4 11.94 12.73 4. 22 4 7 4 0. 00* 1. 51 0. 00 5 7 4 5.40 5. 18 3. 37 6 7 4 5.84 6. 15 3. 32 7 7 4 4. 26 3. 97 2. 61 8 7 4 6. 84 6. 73 3. 87 9 7 4 3.56* 2. 91 0. 19 0 0 5 29.21 28. €7 1. 62 1 G 5 20, 83 20. 45 3.00 2 0 5 6. 36 4. 66 9. 58 3 0 5 8.62 7. 99 9.01 4 0 5 7.58 6. 26 9. 56 5 0 5 2. 99* 2. 21 0. 38 6 0 5 0.00* 1. 36 0. 01 7 0 5 7.22 8. 47 6. 54 8 0 5 9. 97 11. 60 6. 87 9 0 5 11.99 12. 49 5.53 10 0 5 5. 97 6.25 4. 83 11 0 5 12. 38 12. 42 4. 84 12 0 5 10. 17 10. 92 5. 61 13 0 5 6.70 6. 96 3. 98 14 0 5 7. 11 6. 66 5. 05 15 0 5 20. 15 19. 51 2. 65 16 0 5 14. 26 13. 35 4. 00 17 0 5 0.00* 2. 80 0.00 18 0 5 5.43 5. 43 4. 01 19 0 5 4.52 2. 59 3. 59 0 1 5 6. 30 5. 53 9. 38 1 1 5 35. 35 31. 52 1. 13 2 1 5 22.60 19. 46 2. 54 3 1 5 22.03 20. 39 2. 65 4 1 5 15.42 16. C5 4.61 5 1 5 26. 87 27. 60 1. 85 6 1 5 10.70 10. 79 6.91 7 1 5 3.09* 1. 70 0.40 8 1 5 15.89 15. 41 4. 11 9 1 5 9.23 9. 93 6. 49 10 1 5 8.67 9. 22 6. 53 H K 1 FO FC HEIGHT 11 <| 5 14. 97 15. 28 4. 47 12 1 5 4. 37 4. 45 2. 94 13 1 5 4. 02 3.46 2. 77 11 1 5 11. 15 12.66 4. 56 15 1 5 4. 86 4.45 3. 19 16 1 5 4. 23 3.54 2. 58 17 1 5 7. 30 8. 01 3.46 18 1 5 4. 26 4.81 2. 95 19 1 5 3.39* 3.78 0. 22 0 2 5 20. 86 21. 30 2. 85 1 2 5 3. 27 4. 10 3. 97 2 2 5 5. 97 5. 86 6. 95 3 2 5 4. 27 3. 45 6.75 4 2 5 17. 07 16. 54 4. 05 5 2 16. 93 16.61 4. 12 6 2 5 8.79 8.57 7. 30 7 2 5 6. 40 7. 06 6. 27 8 2 5 16. 33 17. 40 3. 82 9 2 5 4. 54 4. 56 4. 80 10 2 5 8.17 7.55 5.31 11 2 5 14. 43 14. 81 4. 12 12 2 5 13. 41 14.62 4. 18 13 2 5 9. 87 10. 26 5. 54 14 2 5 11.76 12.70 4. 43 15 2 5 9. 97 10. 16 4. 41 16 2 5 6. 29 5. 80 5. 19 17 2 5 6. 71 5. 88 4. 92 18 2 5 4.57 4.54 2. 98 . j U <• fs t. It 1 »i. • M MM r\ -M 1 I * CJ 1 1 3 5 9.64 9. 13 7. 15 2 3 5 5. 08 3.84 7. 33 3 3 5 12.64 10.61 5. 55 4 3 5 3. 71 2. 53 3. 35 5 3 5 8. 26 8. 38 7. 15 6 3 5 8. 02 8. 27 6. 79 7 3 5 6. 58 6. 93 5. 23 8 3 5 8. 83 7. 91 6. 02 9 3 5 8. 26 8, 42 5. 60 10 3 5 13. 36 13. 39 4. 74 11 3 5 8. 40 8. 65 5. 03 12 3 5 5. 03 5.60 4. 24 13 3 5 4. 23 4. 11 2. 64 1" 3 . 5 4.24 5.77 2. 18 15 " '3""* 5 1. 32* 2. 59 0. 03 16 3 5 2. 28* 2. 35 0. 09 17 3 5 8. 92 8. 54 6. 84 0 a 5 10. 94 1 1.67 6. 12 1 a 5 4. 70 3. 43 4. 24 2 4 5 10. 00 9. 04 6. 20 3 4 5 10. 85 10. 49 5. 20 a 4 5 9.05 9.19 5. 54 5 4 5 6. 78 7. 30 5. 24 6 4 5 3.14* 1. 37 0.20 7 4 5 3. 52* 4.71 0.23 8 4 5 8. 45 8. 69 5. 15 9 4 5 12. 14 11.94 5. 20 10 4 5 6.61 6.74 3. 58 11 4 5 4. 24 2. 85 3.25 H K L FO FC HEIGHT 12 4 5 4.86 4. 95 2. 68 13 4 5 4. 67 4. 35 2. 20 14 4 5 4.91 4. 11 3. 39 15 4 5 3.71 1. 78 3. 01 16 4 5 5.25 5. 72 3. 29 0 5 5 16. 42 16. 66 3.45 1 5 5 16. 19 17. 33 3.36 2 5 5 11.06 11. 28 5. 16 3 5 5 10.35 9. 46 4.79 4 5 5 23.78 23. <J4 2. 16 5 5 5 5. 35 5. 56 2. 87 6 5 5 18.96 19. 50 2. 87 7 5 5 6.79 5. 92 4. 10 8 5 5 15.88 16. 51 3.52 9 5 5 3.97 3. 03 2. 35 10 5 5 8.18 7. 8.5 4.61 11 5 5 4.72 4. 60 2. 64 12 5 5 4 .20 3. 40 3. 42 13 5 5 3.36* 3. 05 0. 24 14 5 5 3.93 3. 35 3.08 0 6 5 2. 96* 3. 23 0. 12 1 6 5 7. 14 8. 22 3. 78 2 6 5 3. 78* 2. 52 0. 25 3 6 5 8.73 8. 64 4.79 4 6 5 4. 77 5. 08 2. 29 5 6 5 7.67 6.01 5. 93 6 6 5 7.52 7. 97 3. 99 7 6 5 6.73 6. 76 4. 82 r\ O O r-Cj -\ r- •* J- 1.29 /•N -A "> U » <C J 9 6 5 5.14 4. 29 3. 86 10 6 5 4. 86 3. 89 3. 24 11 6 5 3.51* 2. 57 0. 29 0 7 5 7. 54 6. 56 4. 38 1 7 5 4.59 3. 59 3.41 2 7 5 5.90 5. 60 4.0 1 3 7 5 5. 54 5. 87 3.79 4 7 5 3.62* 3. 40 0. 23 5 7 5 3.83* 3. 90 0. 23 6 7 5 3. 22* 2. 50 0. 18 7 7 5 3. 70* 3. 10 0. 28 0 0 6 5. 37 4. 64 7. 03 1 0 6 25. 24 22. 49 2. 11 2 0 6 13.83 14. 33 5. 06 3 0 6 3. 19* 2. 16 0. 29 4 0 6 3.47 3. 33 4. 85 5 0 6 33.76 31. 93 1. 21 6 0 6 5.02 4. 43 6. 50 7 0 6 10. 11 9. 90 6. 67 8 0 6 2.81* 1. 76 0. 26 9 0 6 0. 00* 0. 05 0. 00 10 0 6 3.92 3. 99 3. 87 11 0 6 2.31* 0. 07 0. 13 12 0 6 8.04 7. 60 4. 96 13 0 6 7. 04 7. 03 6. 93 14 0 6 1 .48* 1. 93 0. 04 15 0 6 1. 15* 0. 53 0. 03 16 0 6 5. 33 3. 69 4.62 17 0 6 5.01 3.52 4. 64 H K L FO FC HEIGHT 18 0 6 6. 21 5. 37 5.49 0 1 6 10. 27 10.67 6. 87 1 1 6 10. 93 11.75 6. 31 2 1 6 14. 51 14. 51 5. 01 3 1 6 8. 41 8. 32 8. 10 4 1 6 20. 15 19.42 2. 93 5 1 6 8. 62 6.71 6. 46 6 1 6 3. 36* 4. 13 0. 35 7 1 6 7. 20 6. 04 7. 36 8 1 6 7. 88 7. 23 6. 23 9 1 6 6. 41 6. 35 5.89 10 1 6 4. 54 5. 27 2. 40 11 1 6 12. 14 13. 29 5. 02 12 1 6 14.78 14. 94 3. 83 13 1. 6 4. 85 4.84 3. 33 14 1 6 4. 46 3. 11 3. 52 15 1 6 6. 06 6. 29 4. 27 16 1 6 3. 14* 3. 14 0. 19 17 1 6 4. 56 4. 40 4. 26 18 1 6 0. 00* 2.42 0. 00 0 2 6 11.48 11.46 6. 30 1 2 6 19. 85 19.33 3. 08 2 2 6 7. 55 6.69 6. 33 3 2 6 14. 77 14. 96 4. 56 4 2 6 9. 32 8. 48 7. 05 5 2 6 6.56 6. 14 6. 38 6 2 6 1.98* 1.79 0. 12 7 2 6 11.77 11.88 5. 35 6 2 6 4.99 5.4/ 3.42 9 2 6 22. 01 23. 08 2. 38 10 2 6 6. 80 7. 09 4. 66 11 2 6 7.67 7.66 5. 46 12 2 6 15. 33 15. 1 1 3. 85 13 2 6 5. 05 3.53 4. 19 14 2 6 6. 03 5. 18 6. 25 15 2 6 2.58* 1.62 0. 13 16 2 6 4. 45 2. 53 3. 96 17 2 6 4.39 3.72 2. 99 0 3 6 1. 66* 1. 82 0. 09 1 3 6 21. 03 21. 81 2. 62 2 3 6 0. 00* 1. 17 0. 00 3 3 6 6. 48 7. 50 5. 74 4 3 6 11.58 10. 91 5. 40 5 3 6 5. 43 4.73 6. 18 6 3 6 9. 43 10. 28 6. 39 7 3 6 1. 78* 2. 94 0. 07 8 3 6 9. 45 10. 07 5.98 9 3 6 6. 92 6. 44 5. 21 10 3 6 10. 27 11.31 5. 09 11 3 6 1.63* 2. 13 0. 05 12 3 6 4. 57 5. 11 3. 00 13 3 6 3. 40* 3.58 0. 21 14 3 6 0. OC* 2. 08 0. 00 15 3 6 9.60 8. 58 6. 59 16 3 6 8. 03 7. 50 6. 26 0 4 6 18. 08 18.72 3. 03 1 4 6 6. 87 6.44 6. 64 2 4 6 8. 53 8. 50 5. 01 H K L FO FC WEIGHT 3 4 6 13,96 14. 51 4. 62 4 4 6 11.84 11.51 5.50 5 4 6 13. 53 13. 09 4.91 6 4 6 11.76 12. 21 4. 66 7 4 6 3.19* 3. 67 0. 17 8 4 6 5.76 6. 05 3. 56 9 4 6 15. 35 15. 65 3. 83 10 4 6 7.10 7. 05 4. 91 11 4 6 6.80 5. 87 5.62 12 4 6 6.60 4. 93 5. 68 13 4 6 3.77* 2. 83 0. 23 14 4 6 2.76* 3. 22 0. 15 15 4 6 3.01* 1. 17 0. 30 0 5 6 11.38 10. 71 4. 96 1 5 6 4.70 3. 69 3. 25 2 5 6 14.20 15. 22 3.91 3 5 6 10.11 10. 90 4.60 4 5 6 6.59 7. 35 4.69 5 5 6 10.32 11. 11 4.56 6 5 6 3.93 3. 66 2. 40 7 5 6 6. 93 6. 56 4. 84 8 5 6 0.60* 3. 97 0.01 9 5 6 4.59 4. 44 3. 86 10 5 6 4.03 6. C8 2.26 11 5 6 3.25* 2. 06 0. 30 12 5 6 4.42 4. 90 3. 02 0 6 6 1.94* 3. 78 0. 05 1 6 6 6.71 7. 78 4. 18 2 6 6 5.22 4. 33 3. 72 3 6 6 8.05 8. 16 4. 32 4 6 6 3.70* 3. 02 0. 26 5 6 6 4.38 3. 73 3. 06 6 6 6 4.60 3. 10 4. 12 7 6 6 3.10* 4. C9 0. 17 8 6 6 3.23* 3. 20 0. 20 9 6 6 5.74 4. 39 5. 19 0 7 6 7.03 6. 36 5. 45 1 7 6 6. 81 6. 66 4. 75 2 7 6 3. 15* 0. 77 0. 26 0 0 7 2. 86* 5. 97 0. 26 1 0 7 25.21 23.78 2.03 2 0 7 6.51 8. 45 6.27 3 0 7 3. 11* 1. 33 0. 40 4 0 7 3.85 2. 59 3. 81 5 0 7 6. 36 6. 58 7. 27 6 0 7 4.76 4. 66 4. 48 7 0 7 7.69 7. 69 6.23 8 0 7 6.41 6. 71 6.25 9 0 7 14.00 14. 41 4. 30 10 0 7 4.10 3. 16 3. 43 11 0 7 5.36 4. 73 4. 62 12 0 7 11.96 11. 63 4. 79 13 0 7 11.51 10. 89 5. 26 14 0 7 7.10 6. 77 5. 92 15 0 7 4.92 4. 57 5.67 16 0 7 1.63* 1. 99 0. 07 0 1 7 4.99 4. 42 4. 85 1 1 7 13. 84 14. 75 4. 93 H K I FO ' FC WEIGHT 2 7 1.32* 1. 53 0.06 3 1 7 17. 91 16. 90 3. 42 4 1 7 6. 22 5. 76 5. 49 5 1 7 3. 80 5. 19 2. 86 6 1 7 7. 05 7. 50 6. 19 7 1 7 0. 00* 1. 55 0. 00 8 1 7 14. 78 14. 45 4. 37 9 1 7 3.81* 3. 94 0. 24 10 1. 7 7. 57 7.98 5. 37 11 1 7 3. 07* 2. 11 0. 18 12 1 7 2.49* 0. 88 0. 15 13 1 7 8. 46 8.66 4. 83 14 1 7 2. 13* 0. 15 0. 12 15 1 7 6. 31 6. 03 4. 97 16 1 7 2.81* 2.54 0. 16 0 2 7 11. 37 10. 78 5. 82 1 2 7 9. 45 9.44 6. 77 2 2 7 6.18 5, 22 5. 24 3 2 7 7. 79 6. 66 5. 33 4 2 7 21. 06 20. 68 2.73 5 2 7 7. 83 8. 61 5. 01 6 2 7 10. 71 10. 59 5. 08 7 2 7 12. 23 11.59 4. 74 8 o c 7 1.51* 0.77 0.05 9 2 7 6. 70 5. 58 5. 78 10 2 7 8. 56 8. 57 5. 48 11 2 7 6. 31 7.42 4. 50 12 2 7 5. 49 6.61 3. 31 13 2 7 10. / 2 10. 1"5 5.11 14 2 7 2. 70* 2. 70 0.13 15 2 7 4. 22 4. 25 3.31 16 2 7 5.54 5. 10 4. 58 0 3 7 12. 23 11. 05 4. 64 1 3 7 13. 27 12. 53 4. 66 2 3 7 16. 57 16. 22 3. 76 3 3 7 6. 87 5. 87 6. 53 4 3 7 12. 82 12. 26 5. 24 5 3 7 14. 38 1 5. 27 4. 44 6 3 7 10, 59 10. 42 5. 70 7 3 7 5. 82 5.68 4. 40 8 3 7 12. 08 12. 19 5. 22 9 3 7 4. 13 3. 94 3. 32 10 3 7 7. 20 6.57 5.92 11 3 7 9. 6 8 9.76 4. 64 12 3 7 8.75 9. 34 6.49 13 3 7 9. 72 9.21 5. 98 14 3 7 5.78 6. 04 4.34 15 3 7 5. 97 6.08 5. 02 0 4 7 11.91 11. 17 5. 34 1 4 7 19. 52 20. 25 2. 91 2 4 7 7.87 7. 58 5. 52 3 4 7 5. 06 4.95 5. 64 4 4 7 6.86 5.44 4. 37 5 4 7 9. 39 9. 60 5. 06 6 4 7 9. 14 8. 31 5. 57 7 4 7 9. 37 9. 21 6. 24 8 4 7 8.68 8.85 5. 55 9 4 7 4. 34 2. 81 3. 61 H K L FO FC WEIGHT 10 4 7 2.65* 3. 63 0. 12 11 4 7 8.05 7. C8 5. 86 12 4 7 3. 88 3. 26 .3. 76 13 4 7 3.36* 2. 93 0. 29 0 5 7 7.06 7. 61 5. 02 1 5 7 8. 14 8. 04 4. 80 2 5 7 .8.46 8. 83 5. 52 3 5 7 5.29 6.49 3. 23 4 5 7 3. 27* 3. 50 0.17 5 5 7 2. 38* 1. 51 0. 12 6 5 7 1.63* 2. C9 0. 06 7 5 7 4.20 3. 16 2. 97 8 5 7 7.02 6. 17 5. 53 9 5 7 6. 86 6. 38 5. 71 10 5 7 2.61* •1.38 0. 23 0 6 7 9. 34 9. 1.4 6. 14 1 6 7 3.92 3. 33 2. 88 2 6 7 3.10* 2. 10 0.22 3 6 7 3. 87 3. 50 2. 43 4 6 7 11.12 12. CS 5.18 5 6 7 3. 15* 2. 56 0. 31 6 6 7 5.50 5.21 5. 23 0 0 8 8. 35 8. 44 6. 26 1 0 8 13. 11 13. 51 4. 45 2 0 8 2.25* 0. 26 0. 17 3 0 8 5.43 4. 94 5. 47 4 0 8 8. 28 8. C2 6. 76 5 0 8 9. 44 8. 83 5. 92 6 G 8 2 • 16 ^ 0.41 0.13 7 0 8 4.09 2. 97 2. 76 8 0 8 3.69 2. 63 2. 83 9 0 8 3.79* 2. 70 0. 26 10 0 8 2. 42* 1. 66 0. 15 11 0 8 4.08 4. 40 2. 62 12 0 8 3. 06* 1. 53 0. 24 13 0 8 2.63* 0. 27 0. 19 14 0 8 3.13* 1. 50 0. 29 15 0 8 2. 79* 0. 79 0. 27 0 1 8 8.10 7. 42 5. 45 1 1 8 8. 27 8. 08 5. 47 2 1 8 7.47 7. 53 5. 20 3 1 8 9.93 10. 07 5. 98 4 1 8 8.81 8. 99 4. 85 5 1 8 13. 26 12. 92 4. 71 6 1 8 9.29 9. C9 5. 19 7 1 8 10. 39 10. 60 5. 58 8 1 8 5.32 5. 87 3. 82 9 1 8 7. 38 7. 16 5. 12 10 1 8 4. 04 3. 35 3. 16 11 1 8 3. 95 2. 33 4. 03 12 1 8 4. 36 4. 56 2.55 13 1 8 1 . 78* 2. 99 0. 06 14 1 8 4.88 3.45 5. 08 0 2 8 1. 64* 2. 51 0. 05 1 2 8 8.57 8. 37 5. 86 2 2 8 12.85 12. 23 4. 82 3 2 8 7.36 6.51 4.79 4 2 8 . 4.96 4. 11 4. 45 H K I FO FC HEIGHT 5 2 8 7.81 8. 17 5.45 6 2 8 10. 33 10. 48 4. 31 7 2 8 6.75 6. 33 5. 67 8 2 8 8. 31 8.59 5. 43 9 2 8 2. 61* 3. 83 0.13 10 2 8 3. 39* 2. 65 0. 27 11 2 8 5.68 5.47 4. 20 12 2 8 4.50 3. 55 3. 31 13 2 8 3. 31* 1. 88 0. 31 11 2 8 1.56* 1. 29 0.07 0 3 8 5. 36 4.56 4. 66 1 3 8 8. 02 7.58 4. 28 2 3 8 5. 24 4.44 3. 17 3 3 8 16. 16 16. 39 3. 67 4 3 8 15. 41 15.00 3. 83 5 3 8 9.12 9. 09 4. 46 6 3 8 6. 28 6. 55 4. 44 7 3 8 9. 78 9.70 6. 12 8 3 8 7. 14 7. 63 4. 37 9 3 8 2.66* 1.42 0. 18 10 3 8 3. 97 2.77 3. 29 11 3 8 3. 77 3. 55 3. 24 12 3 8 8. 18 7, 18 5,07 0 4 8 6. 12 5. OS 4. 36 1 4 8 5.87 6.11 3. 56 2 4 8 10. 02 9. 09 5. 49 3 4 8 5. 25 5. 08 3. 68 a 4 8 7. 45 6. 81 5. 15 5 4 6 3. 1 5 * 4.00 0.14 6 4 8 3. 20* 2. 53 0. 20 7 4 8 5. 07 4. 64 4. 55 8 4 8 4. 68 4. 59 4, 29 9 4 8 1. 41* 0. 85 0. 05 10 4 8 2. 88* 0. 90 0. 21 0 5 8 1.13* 1.99 0. 02 1 5 8 3. 43* 2. 53 0. 20 2 5 8 6.76 5. 54 5. 24 3 5 8 3. 16* 1.52 0. 27 a 5 8 2.86* 2.49 0. 15 5 5 8 4.33 3. 50 4. 14 6 5 8 7. 30 7.52 5. 33 7 5 8 2. 92* 3. 29 0. 22 0 0 9 3. 27* 0. 25 0.26 1 0 9 11.00 10.68 4.96 2 0 9 0. 00* 0. 86 0. 00 3 0 9 1.98* 1. 10 0.08 0 9 0.00* 2.31 0. 00 5 0 9 6. 32 6. 67 5. 30 6 0 9 3. 74 3. 12 2. 75 7 0 9 3.03* 3. 38 0. 17 8 0 9 5. 86 5.21 5. 06 9 0 9 3. 59* 1. 72 0. 30 10 0 9 5. 94 5.65 5. 51 11 0 9 0.00* 0.57 0. 00 12 0 9 2. 97* 0. 71 0. 28 0 1 9 4. 66 3.61 3. 83 1 1 9 12. 45 10. 33 4. 72 2 1 9 9.46 8.89 6. 16 H K L FO FC WEIGHT 3 9 3.02* 1. 17 0. 17 4 1 9 4. 60 3. 32 3. 71 5 1 9 5.72 5. 17 4. 03 6 1 9 5.29 5. 18 3.70 7 1 9 7. 46 7. 28 5. 14 8 i 9 0. 00* 1. 99 0.00 9 1 9- 10. 43 10. 20 5. 17 10 1 9 4. 48 2. 73 5.19 11 1 9 3. 83 4.20 2. 84 12 1 9 3. 66 3. 97 2. 92 0 2 9 5.00 4. 77 •3. 42 1 2 9 4.40 4. 89 2. 39 2 2 9 4. 87 4. 08 5. 11 3 2 9 5.23 6. C8 4. 38 4 2 9 5.45 5. 22 5. 74 5 2 9 4. 30 3. 16 3. 43 6 2 9 4.23 2. 62 3. 38 7 2 9 8. 06 9. 19 4. 86 8 2 9 5.75 6. 31 3. 73 9 2 9 4.46 3. 55 3. 32 10 2 9 3. 15* 1. 32 0. 28 11 2 9 6. 15 6. 52 4. 23 0 3 9 3.93 2. 93 3. 02 1 3 9 8. 87 7. 43 6. 25 2 3 9 8. 87 8. 06 4. 97 3 3 Q 2. 36* 1. 71 0. 11 4 3 9 6.67 5.70 5.74 5 3 9 3.01* 1. 19 0.-23 6 3 9 3. 33* 2. 56 G. 23 7 3 9 3.90 2. 23 4. 34 8 • 3 9 1. 50* 2. 13 0. 05 9 3 9 2. 69* 2. 60 0. 19 0 4 9 6. 87 6. 47 3. 65 1 4 9 6. 04 5. 84 4. 09 2 4 9 8. 13 7. 48 4. 67 3 4 9 4.69 3. 76 4. 44 4 4 9 2. 02* 2. S3 0. 10 5 4 9 3.95 3. S3 2. 52 6 4 9 5. 25 5. 43 3. 98 7 4 9 3.43 1. 56 3. 35 0 0 10 6.51 4. 46 5. 63 1 0 10 5. 89 4. 57 5. 14 2 0 10 12. 80 11. 97 4. 45 3 0 10 0.00* 0. 31 0. 00 4 0 10 1. 86* 0. 63 0. 08 5 0 10 2. 66* 2. 39 0. 19 6 0 10 4.02 2. 44 2. 85 7 0 10 2. 03* 0. 45 0. 10 8 0 10 4. 49 5. 46 2. 70 9 0 10 1. 22* 0. 18 0. 04 0 1 10 6.22 5. 80 4.61 1 1 10 9.35 8. 39 5. 12 2 1 10 12.67 11. 65 5. 13 3 1 10 9.89 8. 98 5. 74 4 1 10 0.00* 0. 78 0. 00 5 1 10 6. 83 6. 24 5. 29 6 1 10 4.14 5. 29 2.55 7 1 10 4. 24 1. 93 5.26 H K L FO FC WEIGHT 8 1 10 2. 50* 4. 17 0.12 0 2 10 4. 85 3. 83 4. 39 1 2 10 4. 41 4.58 3. 19 2 2 10 5. 89 6. 28 3. 96 3 2 10 6.48 5.68 4. 44 4 2 10 5. 86 5. 53 3..56 5 2 10 13. 86 12.79 4. 73 6 2 10 6. 54 5. 74 5. 65 H K L FO FC WEIGHT 7 2 10 4. 17 3. 64 3. 55 0 3 10 7.76 6. 31 7. 00 1 3 10 3.56 3. 53 3. 20 2 3 10 5. 38 4. 87 5. 62 3 3 10 2.01* 1. 19 0. 11 4 3 10 6. 08 5. 45 6. 58 0 0 11 1. 80* 1. 72 0. 10 1 0 11 10.38 9. 45 5. 50 * DENOTES AN UNOBSERVED REFLECTION 

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