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UBC Theses and Dissertations
Synthesis and characterization of sulfur-bridged terpyridine-like Ru(II) coordination complexes and dinuclear Ru(II) sulfoxide complexes Cross, Trevor
Abstract
A new set of sulfur-bridged oligopyridine proligands was synthesized with each having different functional groups in the 4ʹ position. Three new homoleptic Ru(II) complexes with these new tridentate ligands were synthesized and were found to have no geometric strain about the Ru(II) metal center due to the expanded ligand cage about the metal. In addition, a heteroleptic Ru(II) complex with one of these new ligands and a terpyridine ligand was made. The heteroleptic complex was found to be emissive at 77 K while the homoleptic compounds were non-emissive. These photophysical and electrochemical properties of these new complexes were also probed, and Lever Electrochemical parameters assigned. Photoactive mononuclear and dinuclear Ru(II) sulfoxide complexes were synthesized. The mononuclear complexes were found to have photoswitching activity that is consistent with reversible photoisomerization. A dinuclear complex was synthesized to probe if two photoisomerizations on the same complex was feasible. The dinuclear complex was found to undergo an irreversible photoreaction, and no evidence of two photoisomerizations was found
Item Metadata
Title |
Synthesis and characterization of sulfur-bridged terpyridine-like Ru(II) coordination complexes and dinuclear Ru(II) sulfoxide complexes
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Creator | |
Publisher |
University of British Columbia
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Date Issued |
2019
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Description |
A new set of sulfur-bridged oligopyridine proligands was synthesized with each having
different functional groups in the 4ʹ position. Three new homoleptic Ru(II) complexes with these
new tridentate ligands were synthesized and were found to have no geometric strain about the
Ru(II) metal center due to the expanded ligand cage about the metal. In addition, a heteroleptic
Ru(II) complex with one of these new ligands and a terpyridine ligand was made. The heteroleptic
complex was found to be emissive at 77 K while the homoleptic compounds were non-emissive.
These photophysical and electrochemical properties of these new complexes were also probed,
and Lever Electrochemical parameters assigned.
Photoactive mononuclear and dinuclear Ru(II) sulfoxide complexes were synthesized. The
mononuclear complexes were found to have photoswitching activity that is consistent with
reversible photoisomerization. A dinuclear complex was synthesized to probe if two
photoisomerizations on the same complex was feasible. The dinuclear complex was found to
undergo an irreversible photoreaction, and no evidence of two photoisomerizations was found
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Genre | |
Type | |
Language |
eng
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Date Available |
2019-08-27
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Provider |
Vancouver : University of British Columbia Library
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Rights |
Attribution-NonCommercial-NoDerivatives 4.0 International
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DOI |
10.14288/1.0380672
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URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
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Graduation Date |
2019-11
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Campus | |
Scholarly Level |
Graduate
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Rights URI | |
Aggregated Source Repository |
DSpace
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Rights
Attribution-NonCommercial-NoDerivatives 4.0 International