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UBC Theses and Dissertations
Synthesis and reactivity of macrocyclic β-keto lactones Sharadendu, Anurag
Abstract
As a part of a continuing study of the chemistry and conformational behaviour of
macrocyclic β-keto lactones, 3-oxo-13-tetradecanolide (74) and 3-oxo-15-hexadecanolide (84) were synthesized via intra- and intermolecular
alcoholysis of hydroxy Meldrum's acid derivatives. A number of 14- and
16-membered lactones, derived from 74 and 84 were used to investigate a
series of alkylation and reduction reactions.
[more abstract available in pdf]
Item Metadata
| Title |
Synthesis and reactivity of macrocyclic β-keto lactones
|
| Creator | |
| Publisher |
University of British Columbia
|
| Date Issued |
1996
|
| Description |
As a part of a continuing study of the chemistry and conformational behaviour of
macrocyclic β-keto lactones, 3-oxo-13-tetradecanolide (74) and 3-oxo-15-hexadecanolide (84) were synthesized via intra- and intermolecular
alcoholysis of hydroxy Meldrum's acid derivatives. A number of 14- and
16-membered lactones, derived from 74 and 84 were used to investigate a
series of alkylation and reduction reactions.
[more abstract available in pdf]
|
| Extent |
7314188 bytes
|
| Genre | |
| Type | |
| File Format |
application/pdf
|
| Language |
eng
|
| Date Available |
2009-02-18
|
| Provider |
Vancouver : University of British Columbia Library
|
| Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
|
| DOI |
10.14288/1.0059553
|
| URI | |
| Degree (Theses) | |
| Program (Theses) | |
| Affiliation | |
| Degree Grantor |
University of British Columbia
|
| Graduation Date |
1996-05
|
| Campus | |
| Scholarly Level |
Graduate
|
| Aggregated Source Repository |
DSpace
|
Item Media
Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.