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UBC Theses and Dissertations
Solution H₂S Chemistry of Pd-bis(Diphenylphosphino)methane (DPM) complexes; catalytic conversion of H₂S to H₂ Wong, Terrance Yu Hung
Abstract
This thesis describes studies on the interaction of H₂S with mono- and dinuclear Pd - dpm
(bis(diphenylphosphino)methane) complexes with the ultimate goal being to catalyze the
conversion of H₂S to H₂ and elemental sulfur (S₈).
Solution kinetic and mechanistic studies were performed on the abstraction of sulfur from
Pd₂X₂(µ-S)(µ-dpm)₂ [X = Cl (2a), Br (2b), I (2c)] using dpm to give, respectively, Pd₂X₂(dpm)₂
[X = Cl (1a), Br (1b), I (1c)] and dpm(S) (process 2 → 1):
[More abstract follows which cannot be rendered here; please see pp.3+ of the accompanying pdf file].
Item Metadata
| Title |
Solution H₂S Chemistry of Pd-bis(Diphenylphosphino)methane (DPM) complexes; catalytic conversion of H₂S to H₂
|
| Creator | |
| Publisher |
University of British Columbia
|
| Date Issued |
1996
|
| Description |
This thesis describes studies on the interaction of H₂S with mono- and dinuclear Pd - dpm
(bis(diphenylphosphino)methane) complexes with the ultimate goal being to catalyze the
conversion of H₂S to H₂ and elemental sulfur (S₈).
Solution kinetic and mechanistic studies were performed on the abstraction of sulfur from
Pd₂X₂(µ-S)(µ-dpm)₂ [X = Cl (2a), Br (2b), I (2c)] using dpm to give, respectively, Pd₂X₂(dpm)₂
[X = Cl (1a), Br (1b), I (1c)] and dpm(S) (process 2 → 1):
[More abstract follows which cannot be rendered here; please see pp.3+ of the accompanying pdf file].
|
| Extent |
11328762 bytes
|
| Genre | |
| Type | |
| File Format |
application/pdf
|
| Language |
eng
|
| Date Available |
2009-03-17
|
| Provider |
Vancouver : University of British Columbia Library
|
| Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
|
| DOI |
10.14288/1.0059521
|
| URI | |
| Degree (Theses) | |
| Program (Theses) | |
| Affiliation | |
| Degree Grantor |
University of British Columbia
|
| Graduation Date |
1996-11
|
| Campus | |
| Scholarly Level |
Graduate
|
| Aggregated Source Repository |
DSpace
|
Item Media
Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.