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Droplet phase in a nonlocal isoperimetric problem under confinement

Banff International Research Station for Mathematical Innovation and Discovery

We address small volume fraction asymptotic properties of a nonlocal isoperimetric functional with a confinement term, derived as the sharp interface limit of a variational model for self-assembly of diblock copolymers under confinement by nanoparticle inclusion. We introduce a small parameter $\eta$ to represent the size of the domains of the minority phase, and study the resulting droplet regime as $\eta\to 0$. A key role is played by a parameter $M$ which gives the total volume of the droplets at order $\eta^3$ and its relation to existence and non-existence of minimizers to a nonlocal isoperimetric functional on $\mathbb{R}^3$. For large values of $M$, the minority phase splits into several droplets at an intermediate scale $\eta^{1/3}$, while for small $M$ minimizers form a single droplet converging to the maximum of the confinement density.

Mathematics; Partial differential equations; Statistical mechanics, structure of matter

video/mp4

Author affiliation: McMaster University

2017-10-30

Attribution-NonCommercial-NoDerivatives 4.0 International

http://hdl.handle.net/2429/63485

Unreviewed

http://creativecommons.org/licenses/by-nc-nd/4.0/